Brian Stoltz
#65,348
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American chemist
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Brian Stoltzchemistry Degrees
Chemistry
#881
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#1439
Historical Rank
#372
USA Rank
Organic Chemistry
#141
World Rank
#182
Historical Rank
#55
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Chemistry
Brian Stoltz's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Brian Stoltz Influential?
(Suggest an Edit or Addition)According to Wikipedia, Brian M. Stoltz is currently a professor of chemistry at the California Institute of Technology. The primary focus of his research is chemical synthesis with an emphasis on expanding the scope of allylic alkylation for the preparation of complex molecules possessing unique structural, biological, and physical properties. His research involves the total synthesis of natural products such as dragmacidin F and -cyanthiwigin F, and development of synthetic reactions to access quaternary stereocenters. Specifically, he has focused on the allylic alkylation of enolates, developing an enantioselective variant in 2004.
Brian Stoltz's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist (2010) (2528)
- A comprehensive history of arynes in natural product total synthesis. (2012) (591)
- Catalytic enantioselective construction of quaternary stereocenters: assembly of key building blocks for the synthesis of biologically active molecules. (2015) (456)
- The enantioselective Tsuji allylation. (2004) (389)
- Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways (2011) (300)
- Catalytic C-H bond functionalization with palladiumII: aerobic oxidative annulations of indoles. (2003) (288)
- Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst (2015) (269)
- Enantioselective Tsuji allylations. (2007) (267)
- Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters. (2005) (259)
- The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis. (2013) (256)
- The palladium-catalyzed oxidative kinetic resolution of secondary alcohols with molecular oxygen. (2001) (248)
- The direct acyl-alkylation of arynes. (2005) (240)
- The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination (2018) (226)
- Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis (1999) (213)
- The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation (2008) (206)
- The first total synthesis of dragmacidin d. (2002) (190)
- Oxidative cyclizations in a nonpolar solvent using molecular oxygen and studies on the stereochemistry of oxypalladation. (2005) (189)
- Orthogonal synthesis of indolines and isoquinolines via aryne annulation. (2008) (183)
- Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate (2006) (180)
- Palladium-catalyzed oxidative wacker cyclizations in nonpolar organic solvents with molecular oxygen: a stepping stone to asymmetric aerobic cyclizations. (2003) (178)
- Natural products as inspiration for the development of asymmetric catalysis (2008) (175)
- Palladium Catalyzed Aerobic Dehydrogenation: From Alcohols to Indoles and Asymmetric Catalysis (2004) (172)
- Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations. (2017) (172)
- Direct oxidative Heck cyclizations: intramolecular Fujiwara-Moritani arylations for the synthesis of functionalized benzofurans and dihydrobenzofurans. (2004) (170)
- Enantioselective Construction of Quaternary N-Heterocycles by Palladium-Catalyzed Decarboxylative Allylic Alkylation of Lactams (2011) (167)
- Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to five-, six-, and seven-membered β-substituted cyclic enones: enantioselective construction of all-carbon quaternary stereocenters. (2011) (167)
- Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangements. (2014) (160)
- Catalytic enantioselective stereoablative alkylation of 3-halooxindoles: facile access to oxindoles with C3 all-carbon quaternary stereocenters. (2009) (156)
- Enantioselective decarboxylative alkylation reactions: catalyst development, substrate scope, and mechanistic studies. (2011) (150)
- Construction of vicinal tertiary and all-carbon quaternary stereocenters via Ir-catalyzed regio-, diastereo-, and enantioselective allylic alkylation and applications in sequential Pd catalysis. (2013) (148)
- Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators (2016) (146)
- Enantio-, diastereo-, and regioselective iridium-catalyzed asymmetric allylic alkylation of acyclic β-ketoesters. (2013) (146)
- The total synthesis of (+)-dragmacidin F. (2004) (144)
- Gas phase production and loss of isoprene epoxydiols. (2014) (143)
- The catalytic asymmetric total synthesis of elatol. (2008) (137)
- Side chain chemistry mediates backbone fragmentation in hydrogen deficient peptide radicals. (2009) (137)
- Atmospheric autoxidation is increasingly important in urban and suburban North America (2017) (130)
- Asymmetric synthesis of QUINAP via dynamic kinetic resolution. (2013) (125)
- The catalytic enantioselective, protecting group-free total synthesis of (+)-dichroanone. (2006) (124)
- A convergent and enantioselective synthesis of (+)-amurensinine via selective C-H and C-C bond insertion reactions. (2006) (119)
- Pd-catalyzed enantioselective aerobic oxidation of secondary alcohols: applications to the total synthesis of alkaloids. (2008) (119)
- Potassium tert-Butoxide-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study. (2017) (117)
- Lewis acid mediated (3 + 2) cycloadditions of donor-acceptor cyclopropanes with heterocumulenes. (2012) (110)
- Mechanism and enantioselectivity in palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones: insights from computation and experiment. (2013) (110)
- Benzannulated bicycles by three-component aryne reactions. (2011) (105)
- Catalytic enantioselective decarboxylative protonation. (2006) (105)
- Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates. (2016) (104)
- Regioselective reactions of highly substituted arynes. (2010) (102)
- C-H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes. (2008) (99)
- The inner-sphere process in the enantioselective Tsuji allylation reaction with (S)-t-Bu-phosphinooxazoline ligands. (2007) (98)
- A facile and modular synthesis of phosphinooxazoline ligands. (2007) (91)
- Design and Implementation of an Efficient Synthetic Approach to Furanosylated Indolocarbazoles: Total Synthesis of (+)- and (−)-K252a (1997) (90)
- A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres (2010) (90)
- The structural and synthetic implications of the biosynthesis of the calycanthaceous alkaloids, the communesins, and nomofungin (2006) (89)
- Development of an enantiodivergent strategy for the total synthesis of (+)- and (-)-dragmacidin f from a single enantiomer of quinic Acid. (2005) (88)
- Biomimetic approach to communesin B (a.k.a. nomofungin) (2003) (87)
- A palladium-catalyzed vinylcyclopropane (3+2) cycloaddition approach to the Melodinus alkaloids. (2011) (85)
- The biology and chemistry of the zoanthamine alkaloids. (2008) (85)
- Ionic and Neutral Mechanisms for C-H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide. (2017) (84)
- Progress toward the Synthesis of garsubellin A and related phloroglucins: the direct diastereoselective synthesis of the bicyclo[3.3.1]nonane core. (2002) (84)
- General and Practical Potassium Methoxide/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides. (2018) (79)
- The reaction mechanism of the enantioselective Tsuji allylation: inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric C-C bond formation. (2012) (79)
- Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement. (2016) (76)
- Enantioselective Total Synthesis of Nigelladine A via Late-Stage C-H Oxidation Enabled by an Engineered P450 Enzyme. (2017) (76)
- Unusual allylpalladium carboxylate complexes: identification of the resting state of catalytic enantioselective decarboxylative allylic alkylation reactions of ketones. (2009) (72)
- Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts. (2021) (71)
- Application of Reactive Enols in Synthesis: A Versatile, Efficient, and Stereoselective Construction of the Welwitindolinone Carbon Skeleton (1999) (68)
- Stereoselective Lewis acid mediated (3+2) cycloadditions of N-H- and N-sulfonylaziridines with heterocumulenes. (2014) (67)
- Catalytic enantioselective approach to the eudesmane sesquiterpenoids: total synthesis of (+)-carissone. (2009) (66)
- Enantioselective construction of α-quaternary cyclobutanones by catalytic asymmetric allylic alkylation. (2013) (66)
- Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins. (2014) (66)
- A concise total synthesis of (-)-quinocarcin via aryne annulation. (2008) (65)
- A computational model relating structure and reactivity in enantioselective oxidations of secondary alcohols by (-)-sparteine-Pd(II) complexes. (2004) (64)
- Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides. (2010) (64)
- The catalytic enantioselective total synthesis of (+)-liphagal. (2011) (63)
- Palladium-catalyzed asymmetric conjugate addition of arylboronic acids to heterocyclic acceptors. (2013) (63)
- Palladium-catalyzed enantioselective oxidation of chiral secondary alcohols: access to both enantiomeric series. (2008) (63)
- Synthesis of C(3) benzofuran-derived bisaryl quaternary centers: approaches to diazonamide A. (2000) (62)
- TOTAL SYNTHESIS OF (+)-RK-286C, (+)-MLR-52, (+)-STAUROSPORINE, AND (+)-K252A (1996) (62)
- Palladium-catalyzed oxidative kinetic resolution with ambient air as the stoichiometric oxidation gas. (2004) (61)
- Enantioselective protonation. (2009) (61)
- Catalytic enantioselective stereoablative reactions: an unexploited approach to enantioselective catalysis. (2007) (60)
- Homogeneous pd-catalyzed enantioselective decarboxylative protonation. (2008) (60)
- Palladium-catalyzed enantioselective oxidation of alcohols: a dramatic rate acceleration by Cs2CO3/t-BuOH. (2003) (60)
- Aryne acyl-alkylation in the general and convergent synthesis of benzannulated macrolactone natural products: an enantioselective synthesis of (-)-curvularin. (2010) (60)
- A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine (2014) (60)
- Enantioselective synthesis of α-secondary and α-tertiary piperazin-2-ones and piperazines by catalytic asymmetric allylic alkylation. (2015) (59)
- Alkali Metal-Hydroxide-Catalyzed C(sp)-H Bond silylation. (2017) (58)
- Total Synthesis of (+)- and (-)-K252a (1995) (58)
- Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives through Iridium-Catalyzed Allylic Alkylation. (2017) (58)
- Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates. (2017) (58)
- Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis (2019) (57)
- Gas-phase synthesis of charged copper and silver Fischer carbenes from diazomalonates: mechanistic and conformational considerations in metal-mediated wolff rearrangements. (2003) (56)
- The total synthesis of (--)-lemonomycin. (2003) (56)
- The palladium-catalyzed aerobic kinetic resolution of secondary alcohols: reaction development, scope, and applications. (2009) (56)
- Catalytic enantioselective alkylation of substituted dioxanone enol ethers: ready access to Calpha-tetrasubstituted hydroxyketones, acids, and esters. (2008) (55)
- Expedient synthesis of 3-hydroxyisoquinolines and 2-hydroxy-1,4-naphthoquinones via one-pot aryne acyl-alkylation/condensation. (2009) (54)
- Non-carbonyl-stabilized metallocarbenoids in synthesis: the development of a tandem rhodium-catalyzed bamford-stevens/thermal aliphatic claisen rearrangement sequence. (2002) (53)
- Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles. (2015) (50)
- Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine (2014) (50)
- Design and Implementation of an Efficient Synthetic Approach to Pyranosylated Indolocarbazoles: Total Synthesis of (+)-RK286c, (+)-MLR-52, (+)-Staurosporine, and (−)-TAN-1030a (1997) (49)
- Convergency and divergency as strategic elements in total synthesis: the total synthesis of (-)-drupacine and the formal total synthesis of (+/-)-cephalotaxine, (-)-cephalotaxine, and (+)-cephalotaxine. (2007) (49)
- Enantioselective total synthesis of (+)-cassiol. (2009) (49)
- The development of a facile tandem Wolff/Cope rearrangement for the synthesis of fused carbocyclic skeletons. (2003) (49)
- Development of a Rhodium Carbenoid-Initiated Claisen Rearrangement for the Enantioselective Synthesis of α-Hydroxy Carbonyl Compounds (1999) (48)
- Enantioselective Synthesis of Vicinal All-Carbon Quaternary Centers via Iridium-Catalyzed Allylic Alkylation. (2018) (48)
- Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine (2015) (47)
- Synthetic efforts toward cyathane diterpenoid natural products. (2009) (47)
- A catalytic, asymmetric formal synthesis of (+)-hamigeran B. (2011) (47)
- Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts. (2017) (46)
- Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a]indolone Substrates: Efficient Syntheses of (-)-Goniomitine, (+)-Aspidospermidine, and (-)-Quebrachamine. (2016) (44)
- Catalyst-Controlled Selective Functionalization of Unactivated C-H Bonds in the Presence of Electronically Activated C-H Bonds. (2018) (43)
- Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates. (2018) (42)
- Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids. (2018) (41)
- Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation. (2016) (41)
- Structural features and reactivity of (sparteine)PdCl2: a model for selectivity in the oxidative kinetic resolution of secondary alcohols. (2008) (41)
- Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF3 Complex. (2016) (41)
- Ring-contraction strategy for the practical, scalable, catalytic asymmetric synthesis of versatile γ-quaternary acylcyclopentenes. (2011) (41)
- The Resolution of Important Pharmaceutical Building Blocks by Palladium-Catalyzed Aerobic Oxidation of Secondary Alcohols (2004) (40)
- Catalytic C–H bond silylation of aromatic heterocycles (2015) (40)
- Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives. (2017) (39)
- Total syntheses of cyanthiwigins B, F, and G. (2011) (39)
- An experimentally derived model for stereoselectivity in the aerobic oxidative kinetic resolution of secondary alcohols by (sparteine)PdCl2. (2004) (39)
- A unified synthetic approach to the pyrazinone dragmacidins. (2006) (38)
- Welwitindolinone C synthetic studies. Construction of the welwitindolinone carbon skeleton via a transannular nitrone cycloaddition. (2010) (38)
- A ligand-free solid-supported system for Sonogashira couplings: applications in nucleoside chemistry. (2005) (38)
- Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (-)-Aspewentins A, B, and C. (2015) (38)
- A general enantioselective route to the chamigrene natural product family. (2010) (38)
- Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles (2014) (38)
- Synthesis of the carbocyclic core of zoanthenol: implementation of an unusual acid-catalyzed cyclization. (2007) (37)
- Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds. (2016) (37)
- Enantioselective Total Synthesis of Nicandrenones (2000) (37)
- Recent Advances in Homogeneous Catalysts for the Asymmetric Hydrogenation of Heteroarenes. (2020) (37)
- Synthesis of Aryl Ketoamides via Aryne Insertion into Imides. (2016) (37)
- Synergistic O3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol (2018) (36)
- Production and Fate of C4 Dihydroxycarbonyl Compounds from Isoprene Oxidation. (2016) (35)
- Preparation of 3,3-disubstituted oxindoles by addition of malonates to 3-halo-3-oxindoles (2007) (34)
- Enantioselective total synthesis of the reported structures of (-)-9-epi-presilphiperfolan-1-ol and (-)-presilphiperfolan-1-ol: structural confirmation and reassignment and biosynthetic insights. (2012) (34)
- Expanding insight into asymmetric palladium-catalyzed allylic alkylation of N-heterocyclic molecules and cyclic ketones. (2013) (34)
- Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids. (2017) (34)
- Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A. (2017) (33)
- Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account (2018) (32)
- Palladium(II)-catalyzed allylic C-H oxidation of hindered substrates featuring tunable selectivity over extent of oxidation. (2015) (32)
- The formal total synthesis of dragmacidin B, trans-dragmacidin C, and cis- and trans-dihydrohamacanthins A (2005) (31)
- Molecular recognition of arginine in small peptides by supramolecular complexation with dibenzo-30-crown-10 ether (2002) (30)
- Oxidative Heck‐Type Reactions (Fujiwara–Moritani Reactions) (2009) (30)
- Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride. (2016) (30)
- Palladium-catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands (2011) (29)
- Biosynthesis and chemical synthesis of presilphiperfolanol natural products. (2014) (29)
- Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides. (2013) (29)
- Selective Nucleic Acid Capture with Shielded Covalent Probes (2013) (29)
- Total syntheses of (-)-transtaganolide A, (+)-transtaganolide B, (+)-transtaganolide C, and (-)-transtaganolide D and biosynthetic implications. (2013) (29)
- Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones (2015) (28)
- Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes. (2019) (28)
- Nickel-Catalyzed Intramolecular C-O Bond Formation: Synthesis of Cyclic Enol Ethers. (2016) (28)
- Efforts toward rapid construction of the cortistatin A carbocyclic core via enyne-ene metathesis. (2010) (28)
- Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-Carbon Quaternary Stereocenters. (2011) (27)
- A general approach to the basiliolide/transtaganolide natural products: total syntheses of basiliolide B, epi-8-basiliolide B, transtaganolide C, and transtaganolide D. (2011) (27)
- PREPARATION OF (S)-tert-ButylPHOX (Oxazole, 4-(1,1-dimethylethyl)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro- (4S)-). (2009) (27)
- Deracemization of Quaternary Stereocenters by Pd‐Catalyzed Enantioconvergent Decarboxylative Allylation of Racemic β‐Ketoesters. (2006) (27)
- Progress toward the synthesis of the basiliolides and transtaganolides: an intramolecular pyrone Diels-Alder entry into a novel class of natural products. (2008) (27)
- Effects of a Modified Dye-Labeled Nucleotide Spacer Arm on Incorporation by Thermophilic DNA Polymerases (2006) (26)
- Characterization of Reactive Organometallic Species via MicroED (2019) (26)
- Synthesis of diverse β-quaternary ketones via palladium-catalyzed asymmetric conjugate addition of arylboronic acids to cyclic enones. (2015) (26)
- Catalytic Reduction of Alkyl and Aryl Bromides Using Propan-2-ol. (2017) (26)
- A Comprehensive History of Arynes in Natural Product Total Synthesis (2012) (26)
- Progress toward the total synthesis of saudin: development of a tandem Stille-oxa-electrocyclization reaction. (2005) (26)
- Total Synthesis of the Norhasubanan Alkaloid Stephadiamine. (2018) (25)
- Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals. (2018) (25)
- A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H (2014) (25)
- Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams. (2016) (24)
- Development of a simple system for the oxidation of electron-rich diazo compounds to ketones (2016) (24)
- A C–N insertion of β-lactam to benzyne: unusual formation of acridone (2012) (24)
- Enantioselective synthesis of dialkylated N-heterocycles by palladium-catalyzed allylic alkylation. (2015) (24)
- Total Synthesis of (±)-Phomoidride D. (2018) (24)
- PREPARATION OF (S)-2-Allyl-2-methylcyclohexanone (Cyclohexanone, 2-methyl-2-(2-propen-1-yl)-, (2S)-). (2009) (23)
- Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis. (2018) (23)
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol. (2020) (23)
- Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones (2015) (23)
- Enantioconvergent catalysis (2016) (23)
- Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: preparation of mono-, bi-, and tricyclic systems. (2012) (22)
- Total Synthesis and Protein Kinase Activity of C(7) Methyl Derivatives of K252a (1999) (22)
- Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate. (2016) (22)
- A simple and effective procedure for removal of tri-n-butyltin halides from reaction mixtures (1999) (21)
- Enantioselective synthesis of the 5-6-7 carbocyclic core of the gagunin diterpenoids. (2013) (21)
- Synthesis of 2-quinuclidonium by eliminating water: experimental quantification of the high basicity of extremely twisted amides. (2007) (21)
- Convergent and diastereoselective synthesis of the polycyclic pyran core of saudin. (2006) (21)
- Palladium-Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ-Lactams with Aryl Chlorides and Bromides. (2019) (20)
- Molecular mousetraps: gas-phase studies of the covalent coupling of noncovalent complexes initiated by reactive carbenes formed by controlled activation of diazo precursors. (2003) (20)
- Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules (2015) (19)
- Biomimetic approaches to gas phase peptide chemistry: combining selective binding motifs with reactive carbene precursors to form molecular mousetraps (2003) (19)
- Modularity: Adding New Dimensions to Total Synthesis (2019) (19)
- Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues. (2015) (19)
- Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation-Binding Salen Nickel Complexes. (2019) (19)
- Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade. (2018) (19)
- The development and scope of a versatile tandem Stille-oxa-electrocyclization reaction (2007) (18)
- The stereoselective ring contraction of a pyranosylated indolocarbazole. A biosynthetic link between K252a and staurosporine (1996) (18)
- Palladium-Catalyzed Enantioselective Csp3-Csp3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks. (2018) (18)
- An Efficient Protocol for the Palladium-catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst. (2015) (18)
- A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core. (2016) (18)
- Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)-C(sp3) Cross-Coupling. (2020) (18)
- Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade (2016) (17)
- Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin. (2013) (17)
- A unified approach to the daucane and sphenolobane bicyclo[5.3.0]decane core: enantioselective total syntheses of daucene, daucenal, epoxydaucenal B, and 14-para-anisoyloxydauc-4,8-diene. (2013) (17)
- An efficient synthesis of the carbocyclic core of zoanthenol (2009) (17)
- Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C-H Functionalization Studies. (2018) (17)
- Confirmation of the absolute configuration of (-)-aurantioclavine (2011) (16)
- Enantioselective synthesis of gem-disubstituted N-Boc diazaheterocycles via decarboxylative asymmetric allylic alkylation† †Electronic supplementary information (ESI) available: Experimental procedures, 1H NMR, 13C NMR, and IR spectra. See DOI: 10.1039/c8sc03967d (2018) (16)
- The total syntheses of basiliolide C, epi-basiliolide C, and protecting-group-free total syntheses of transtaganolides C and D. (2014) (16)
- Progress toward the synthesis of the transtaganolide/basiliolide natural products: an Ireland–Claisen approach (2009) (16)
- Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents. (2017) (15)
- 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of α-diazo-β-ketoesters (2006) (15)
- The Total Synthesis of (-)-Scabrolide A. (2020) (15)
- A rapid and convergent synthesis of the integrastatin core. (2011) (15)
- Synthesis of bis(indole)-1,2,4-triazinones (2005) (15)
- Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones. (2017) (15)
- Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines. (2020) (15)
- Enantioselective synthesis of a hydroxymethyl-cis-1,3-cyclopentenediol building block. (2012) (14)
- Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents. (2015) (14)
- Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation (2014) (14)
- Highly functionalized donor-acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids. (2015) (14)
- Enantioselective Synthesis of Vicinal All‐Carbon Quaternary Centers via Iridium‐Catalyzed Allylic Alkylation (2018) (14)
- Heterogeneous reductive isomerization reaction using catalytic Pd/C and H2. (2005) (14)
- Chemical Shifts of Trace Impurities : CommonLaboratory Solvents , Organics , and Gases in DeuteratedSolvents Relevant to the OrganometallicChemist (2010) (13)
- High-Throughput Screening of the Asymmetric Decarboxylative Alkylation Reaction of Enolate-Stabilized Enol Carbonates. (2010) (13)
- Catalytic C—H Bond Functionalization with Palladium(II): Aerobic Oxidative Annulations of Indoles. (2003) (13)
- Late-Stage Diversification: A Motivating Force in Organic Synthesis. (2021) (13)
- Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Translactonization-Cope or Cyclopropanation-Cope Rearrangements as Key Steps. (2017) (13)
- Substituent effects and nearly degenerate transition states: rational design of substrates for the tandem Wolff-Cope reaction. (2004) (13)
- Synthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX. (2015) (13)
- Preparation of (S)-tert-ButylPHOX (2009) (12)
- Unexpected decarbonylation during an acid-mediated cyclization to access the carbocyclic core of zoanthenol (2009) (12)
- An Unexpected Ireland-Claisen Rearrangement Cascade During the Synthesis of the Tricyclic Core of Curcusone C: Mechanistic Elucidation by Trial-and-Error and Automatic Artificial Force-Induced Reaction (AFIR) Computations. (2019) (11)
- Escherichia coli K1 Modulates Peroxisome Proliferator-Activated Receptor γ and Glucose Transporter 1 at the Blood-Brain Barrier in Neonatal Meningitis. (2016) (11)
- Unified Enantioselective, Convergent Synthetic Approach toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation-State Manipulation of the Carbocyclic Core. (2019) (11)
- Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters. (2008) (11)
- Progress Toward the Total Synthesis of Hamigerans C and D: A Direct Approach to an Elaborated 6-7-5 Carbocyclic Core (2017) (11)
- A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand (2013) (11)
- THE DIRECT ACYL-ALKYLATION OF ARYNES. PREPARATION OF METHYL 2-(2-ACETYLPHENYL)ACETATE. (2009) (10)
- Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C-H Functionalization. (2018) (10)
- A covalent p97/VCP ATPase inhibitor can overcome resistance to CB-5083 and NMS-873 in colorectal cancer cells. (2021) (10)
- Angiotensin II receptor type 1--a novel target for preventing neonatal meningitis in mice by Escherichia coli K1. (2014) (10)
- Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates† †Electronic supplementary information (ESI) available: Experimental procedures, NMR and IR spectra, SFC traces, X-ray crystallographic data. CCDC 1908785. For ESI and c (2019) (10)
- Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters. (2015) (10)
- Catalytic enantioselective total synthesis of (+)-eucomic acid. (2016) (9)
- Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones. (2020) (9)
- Global Diastereoconvergence in the Ireland-Claisen Rearrangement of Isomeric Enolates: Synthesis of Tetrasubstituted α-Amino Acids. (2020) (9)
- Short Enantioselective Formal Synthesis of (–)-Platencin (2018) (8)
- Novel annulation products derived by selective attack on the C(18) angular methyl group of the cardenolide ouabain (1999) (8)
- A mild and efficient approach to enantioenriched α-hydroxyethyl α,β-unsaturated δ-lactams. (2016) (8)
- Enantioselective Synthesis of 15-Deoxy-Δ12,14-Prostaglandin J2. (2019) (8)
- Alkylations of Enols and Enolates (2014) (8)
- A ring expansion approach to pyranosylated indolocarbazoles (1995) (8)
- Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation (2018) (7)
- The synthesis of desamido analogs of staurosporine, RK-286c, and TAN-1030a (1996) (7)
- Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones. (2019) (7)
- Preparation of (S)‐2‐Allyl‐2‐Methylcyclohexanone (2009) (7)
- Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones (2016) (7)
- Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands† †Electronic supplementary information (ESI) available. CCDC 1843946 and 1954885. For ESI and crystallographic data in CIF or (2020) (7)
- Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents (2012) (7)
- Cu-Catalyzed Enantioselective Allylic Alkylation with a γ- Butyrolactone-Derived Silyl Ketene Acetal. (2019) (7)
- The synthesis of C-3β functionalized indoles via a hydroboration/Suzuki-Miyaura coupling sequence. (2006) (6)
- A FISCHER INDOLIZATION STRATEGY TOWARD THE TOTAL SYNTHESIS OF (-)-GONIOMITINE. (2017) (6)
- Palladium‐Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins. (2014) (6)
- Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin. (2018) (6)
- Enantioselective Total Synthesis of the Reported Structures of ( − )-9-epi-Presilphiperfolan-1-ol and ( − )-Presilphiperfolan-1-ol : Structural Confirmation and Reassignment , New Biosynthetic Insights (2012) (6)
- The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16'-epi-Leucophyllidine. (2021) (6)
- Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol. (2016) (6)
- The Transition Metal Catalyzed [π2s + π2s + σ2s + σ2s] Pericyclic Reaction: Woodward-Hoffmann Rules, Aromaticity, and Electron Flow. (2020) (6)
- Ir-Catalyzed Asymmetric Allylic Alkylation of Dialkyl Malonates Enabling the Construction of Enantioenriched All-Carbon Quaternary Centers. (2022) (6)
- Catalytic Enantioselective Stereoablative Alkylation of 3‐Halooxindoles: Facile Access to Oxindoles with C3 All‐Carbon Quaternary Stereocenters. (2010) (6)
- The utility of the classical and oxidative heck reactions in natural product synthesis : Studies directed toward the total synthesis of dragmacidin F (2006) (6)
- Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin-Derived Enol Carbonates. (2019) (6)
- Probing Trends in Enantioinduction via Substrate Design: Palladium-Catalyzed Decarboxylative Allylic Alkylation of α-Enaminones. (2020) (5)
- Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones. (2019) (5)
- 3.01 Alkylations of Enols and Enolates (2014) (5)
- Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters. (2014) (5)
- Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N -acyl indole-derived enol carbonates † (2019) (5)
- Preparation of (S)-tert-ButylPyOx and Palladium-catalyzed Asymmetric Conjugate Addition of Arylboronic Acids. (2016) (5)
- Progress toward the Enantioselective Synthesis of Curcusones A-D via a Divinylcyclopropane Rearrangement Strategy. (2019) (5)
- Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core. (2019) (5)
- Enantioselective total synthesis of (−)-myrifabral A and B† (2020) (5)
- Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity. (2019) (5)
- Synthetic Efforts Toward Cyathane Diterpenoid Natural Products (2009) (4)
- Design and Implementation of an Efficient Synthetic Approach to Furanosylated Indolocarbazoles: Total Synthesis of (+)- and (-)-K252a. (1998) (4)
- Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements (2014) (4)
- An Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization. (2020) (4)
- Potassium tert-Butoxide-Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes (2016) (4)
- A New Method for the Cleavage of Nitrobenzyl Amides and Ethers. (2014) (4)
- Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy. (2017) (4)
- Design and Implementation of an Efficient Synthetic Approach to Pyranosylated Indolocarbazoles: Total Synthesis of (+)-RK286c, (+)-MLR-52, (+)-Staurosporine, and (-)-TAN-1030a. (1998) (3)
- New synthetic methods—VII (2003) (3)
- Palladium‐Catalyzed Decarbonylative Dehydration for the Synthesis of α‐Vinyl Carbonyl Compounds and Total Synthesis of (‐)‐Aspewentins A, B, and C. (2015) (3)
- Synthesis of Enantioenriched gem-Disubstituted 4-Imidazolidinones by Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation. (2021) (3)
- A Small-scale Procedure for Acid-catalyzed Ketal Formation. (2019) (3)
- Rapid Synthesis of an Electron‐Deficient t‐BuPHOX Ligand: Cross‐Coupling of Aryl Bromides with Secondary Phosphine Oxides. (2011) (3)
- Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade (2016) (3)
- A Synthetic Strategy toward Eight-Membered Cyclic Amines by Cycloetherification and Claisen Rearrangement. (2021) (3)
- Stereoselective Lewis Acid Mediated [3 + 2] Cycloadditions of N-H- and N-Sulfonylaziridines with Heterocumulenes. (2014) (3)
- Chapter 13 - A Dipolar Cycloaddition Strategy for the Synthesis of 3,8-Diazabicyclo[3.2.1]Octane Tetrahydroisoquinoline Antitumor Antibiotics: The Total Synthesis of (−)-Lemonomycin (2012) (3)
- Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization† †Electronic supplementary information (ESI) available. CCDC 1999209. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d0sc02366c (2020) (2)
- Palladium‐Catalyzed Enantioselective Oxidation of Alcohols: A Dramatic Rate Acceleration by Cs2CO3/t‐BuOH. (2003) (2)
- Discovery of novel modulators for the PPARα (peroxisome proliferator activated receptor α): Potential therapies for nonalcoholic fatty liver disease. (2021) (2)
- Part-per-Trillion Trace Selective Gas Detection Using Frequency Locked Whispering-Gallery Mode Microtoroids. (2022) (2)
- Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one. (2016) (2)
- Palladium‐Catalyzed Enantioselective Oxidation of Chiral Secondary Alcohols: Access to Both Enantiomeric Series. (2008) (2)
- Direct Oxidative Heck Cyclizations: Intramolecular Fujiwara—Moritani Arylations for the Synthesis of Functionalized Benzofurans and Dihydrobenzofurans. (2005) (2)
- Synthesis of Papaverine (2008) (2)
- Synthetic strategy toward ineleganolide: A cautionary tale. (2021) (2)
- 2‐Diazoacetoacetic Acid, an Efficient and Convenient Reagent for the Synthesis of α‐Diazo‐β‐ketoesters. (2006) (2)
- The Palladium‐Catalyzed Aerobic Kinetic Resolution of Secondary Alcohols: Reaction Development, Scope, and Applications. (2010) (2)
- Iridium-catalyzed asymmetric trans-selective hydrogenation of 1,3-disubstituted isoquinolines (2022) (2)
- Synthesis of Diverse β‐Quaternary Ketones via Palladium‐Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Cyclic Enones. (2015) (2)
- Synthesis of γ-Quaternary Acylcyclopentenes viaa Ring-Contraction Strategy (2011) (2)
- Correction: Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade† †Electronic supplementary information (ESI) available: X-ray crystal structure analysis of enone ent-12A. CCDC 1885720. For ESI and crystallographic data in CIF or other electronic format see (2019) (2)
- Protonation, Alkylation, Arylation, and Vinylation of Enolates (2011) (2)
- Asymmetric Synthesis of Quaternary Stereocenters via Metal Enolates (2017) (2)
- Transition‐Metal‐Free Catalytic C ─ H Bond Silylation (2019) (2)
- Asymmetric Total Synthesis of Havellockate. (2022) (2)
- Enantioselective Synthesis of α‐Quaternary Mannich Adducts by Palladium‐Catalyzed Allylic Alkylation: Total Synthesis of (+)‐Sibirinine. (2015) (1)
- Discussion Addendum for: Preparation of ( S )‐ tert ‐ButylPHOX and ( S )‐2‐Allyl‐2‐Methylcyclohexanone (2019) (1)
- Ring‐Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ‐Quaternary Acylcyclopentenes. (2011) (1)
- A Convergent and Enantioselective Synthesis of (+)‐Amurensinine via Selective C—H and C—C Bond Insertion Reactions. (2007) (1)
- Identifying the Imperative Role of Metal-Olefin Interactions in Catalytic C-O Reductive Elimination from Nickel(II). (2021) (1)
- Correction to A Comprehensive History of Arynes in Natural Product Total Synthesis. (2018) (1)
- Biomimetic Approach to Communesin B (a.k.a. Nomofungin). (2003) (1)
- Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates (2012) (1)
- Synthesis of (+)-Liphagal (2011) (1)
- Palladium‐Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols (2002) (1)
- Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation‐Binding Salen Nickel Complexes (2019) (1)
- Frequency Locked Microtoroid Optical Resonators as a Non-Invasive Tumor Biopsy Alternative (2013) (1)
- Correction to "Reaction Mechanism, Origins of Enantioselectivity, and Reactivity Trends in Asymmetric Allylic Alkylation: A Comprehensive Quantum Mechanics Investigation of a C(sp3)-C(sp3) Cross-Coupling". (2020) (1)
- Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to 5-6-and 7-Membered β-substituted Cyclic Enones : Enantioselective Construction of All-Carbon Quaternary Stereocenters (2011) (1)
- Synthesis of non-natural cyanthiwigin–gagunin hybrids through late-stage diversification of the cyanthiwigin natural product core (2020) (1)
- Enantioselective Total Synthesis of Nicandrenones. (2001) (1)
- Copper‐Catalyzed Enantioselective Allylic Alkylation with a γ‐Butyrolactone‐Derived Silyl Ketene Acetal (2019) (1)
- Discussion Addendum For: The Direct Acyl‐Alkylation of Arynes. Preparation of Methyl 2‐(2‐acetylphenyl)acetate (2019) (1)
- Biosynthesis and Chemical Synthesis of Presilphiperfolanol Natural Products (2014) (1)
- New directions in natural product synthesis. (2018) (1)
- Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand. (2019) (1)
- 2-Diazoacetoacetic acid, an efficient and convenient reagent for the synthesis of alpha-diazo-beta-ketoesters. (2006) (1)
- Tetrahedron Young Investigator Award ~ 2016 (2016) (1)
- Oxidative kinetic resolution-Claisen rearrangement sequence to enantioenriched arylcycloalkenes (2006) (1)
- The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16′‐ epi ‐Leucophyllidine (2021) (1)
- Synthesis of (-)-Quinocarcin (2009) (1)
- Enantioselective Synthesis of α‐Secondary and α‐Tertiary Piperazin‐2‐ones and Piperazines by Catalytic Asymmetric Allylic Alkylation. (2015) (1)
- Total Synthesis and Protein Kinase Activity of C ( 7 ) Methyl Derivatives of K 252 a (1999) (1)
- Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones† (2020) (1)
- Corrigendum: Enantioselective Construction of α‐Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation (2013) (0)
- The Formal Total Synthesis of Dragmacidin B, trans‐Dragmacidin C, and cis‐ and trans‐Dihydrohamacanthins A. (2005) (0)
- Total Synthesis of (+)‐ and (‐)‐K252a. (1996) (0)
- Sensitive and Selective Nucleic Acid Capture with Shielded Covalent Probes (2012) (0)
- The Resolution of Important Pharmaceutical Building Blocks by Palladium-Catalyzed Aerobic Oxidation of Secondary Alcohols. (2004) (0)
- Development and application of a palladium-catalyzed enantioselective conjugate addition (2014) (0)
- Palladium‐Catalyzed, Asymmetric Baeyer—Villiger Oxidation of Prochiral Cyclobutanones with PHOX Ligands. (2011) (0)
- Biocatalytic Deracemization of Secondary Alcohols (2011) (0)
- A Unified Approach to the Daucane and Sphenolobane Bicyclo ACHTUNGTRENNUNG[5.3.0]decane Core: Enantioselective Total Syntheses of Daucene, Daucenal, Epoxydaucenal B, and 14-para-Anisoyloxydauc-4,8-diene (2013) (0)
- A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F (I) and Perophoramidine (II). (2014) (0)
- Arylation of Enolates (2011) (0)
- Decarboxylative Protonation of Malonic Acids (2011) (0)
- Development of a Non-Directed Petasis-Type Reaction by an Aromaticity-Disrupting Strategy. (2023) (0)
- Alkylation of Enolates via Chiral Transition-Metal Catalysts (2011) (0)
- Total synthesis of (±)-phomoidride D: A 22 year odyssey (2018) (0)
- Total Synthesis of (+)-RK-286c (VIa), (+)-MLR-52 (VII), (+)- Staurosporine (VIb), and (+)-K252a (VIII). (2010) (0)
- Vinylation of Enolates (2011) (0)
- Using β-Hydroxy Sulfoxide Brønsted Acids (2011) (0)
- Deracemization of Amino Acids and Amines (2011) (0)
- Development of a palladium-catalyzed enantioselective conjugate addition of arylboronic acids to cyclic conjugate acceptors (2013) (0)
- Catalytic Enantioselective Stereoablative Reactions: An Unexploited Approach to Enantioselective Catalysis (2008) (0)
- Syntheses of Basiliolide B and C8-Epimer and TranstaganolidesC and D (2011) (0)
- Cover Picture: Molecular Mousetraps: Gas‐Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors (Angew. Chem. Int. Ed. 9/2003) (2003) (0)
- Discussion Addendum for: Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids. (2021) (0)
- Suzuki-Type Arylation of Amides (2011) (0)
- The Development and Scope of a Versatile Tandem Stille-Oxa-Electrocyclization Reaction. (2007) (0)
- Total Synthesis of Strempeliopidine and Non-Natural Stereoisomers through a Convergent Petasis Borono-Mannich Reaction. (2023) (0)
- Synthesis and Exploration of Electronically Modified (R)‐5,5‐Dimethyl‐(p‐CF3)3‐i‐PrPHOX in Palladium‐Catalyzed Enantio‐ and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)‐(p‐CF3)3‐t‐BuPHOX. (2015) (0)
- Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium‐Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross‐Coupling of Functionalized Electrophiles. (2014) (0)
- Using Pseudoephedrine Auxiliaries (2011) (0)
- Deracemization of α-Amino Acids (2011) (0)
- Using Hydrazone-Type Auxiliaries (2011) (0)
- Kinetic Resolution of Secondary Alcohols via Transfer Hydrogenation (2011) (0)
- A Ring Expansion Approach to Pyranosylated Indolocarbazoles. (1996) (0)
- Decarboxylative Allylic Alkylation of β-Keto Esters with Palladium Catalysts (2011) (0)
- Abstract 6258: The discovery and preclinical characterization of the potent covalent KRASG12C inhibitor UCT-001024 (2023) (0)
- Protonation of Enolates with Chiral Proton Donors (2011) (0)
- Alkylation of Enolates (2011) (0)
- Enantioselective Formal Synthesis of ( – )-Platencin (2018) (0)
- Enantioselective Protonation of Enolates (2011) (0)
- Synthesis of Elatol (2008) (0)
- Isotope effects at the origin of life: Fingerprints of the Strecker synthesis (2022) (0)
- Kinetic Resolution of Secondary Alcohols via Nitroxyl Radical Based Systems (2011) (0)
- The Synthesis of Desamido Analogues of Staurosporine, RK-286c, and TAN- 1030a. (1997) (0)
- Palladium(II)‐Catalyzed Allylic C—H Oxidation of Hindered Substrates Featuring Tunable Selectivity over Extent of Oxidation. (2016) (0)
- A Concise Total Synthesis of (‐)‐Quinocarcin (IV) via Aryne Annulation. (2009) (0)
- ( R )‐ N,N '‐Dimethyl‐1,1'‐Binaphthyldiamine (2020) (0)
- Palladium‐Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All‐Carbon Quaternary Stereocenters. (2012) (0)
- Catalytic enantioselective synthesis of carbocyclic and heterocyclic spiranes via a decarboxylative aldol cyclization † (2020) (0)
- Alkylation of α-Bromoamides Using Nickel Catalysts (2011) (0)
- Progress Toward the Synthesis of the Transtaganolide/Basiliolide Natural Products: An Ireland—Claisen Approach. (2009) (0)
- Pd-Catalyzed Asymmetric Conjugate Addition of ArylboronicAcids to Cyclic Enones (2011) (0)
- Catalytic Reduction of Alkyl and Aryl Bromides Using Isopropanol (2017) (0)
- A Unified Synthetic Approach to the Pyrazinone Dragmacidins (2007) (0)
- Palladium‐Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β‐Unsaturated Cyclic Electrophiles (2015) (0)
- Alkylation of Enolates via Chiral Metalloenamines (2011) (0)
- Biocatalytic Kinetic Resolution of Secondary Alcohols (2011) (0)
- Alkylation of Amide Enolates via Chiral Auxiliaries (2011) (0)
- Total Synthesis of (–)-Scabrolide A and (–)-Yonarolide (2023) (0)
- Award Address (ACS Award for Creative Work in Synthetic Organic Chemistry sponsored by MilliporeSigma). Complex natural products as a driving force for discovery in organic chemistry (2017) (0)
- Intertwined nature of chemical synthesis and the discovery process (2010) (0)
- A Simple and Effective Procedure for Removal of Tri‐n‐butyltin Halides from Reaction Mixtures. (1999) (0)
- Protonation of Enolates with Chiral Proton Acceptors (2011) (0)
- Rapid and Convergent Synthesis of a 2,4′‐Linked Tri‐Oxazole in an Approach to Poly‐Oxazoles. (2013) (0)
- Synthesis of Enantioenriched γ‐Quaternary Cycloheptenones Using a Combined Allylic Alkylation/Stork—Danheiser Approach: Preparation of Mono‐, Bi‐, and Tricyclic Systems. (2012) (0)
- Kinetic Resolution of Secondary Alcohols Using Manganese–Salen Complexes (2011) (0)
- Synthesis of enantioenriched 2,2-disubstituted pyrrolidines via sequential asymmetric allylic alkylation and ring contraction. (2022) (0)
- Biocatalytic Enantioselective Protonation (2011) (0)
- Using Ruthenium Catalysts (2011) (0)
- Quaternary Carbon Center Formation by Decarboxylation of Allyl β-Ketoesters (2006) (0)
- Palladium- and Nickel-Catalyzed Arylation with Aryl Trifluoromethanesulfonates (2011) (0)
- Chemical and Chemo-Enzymatic Deracemization of Secondary Alcohols (2011) (0)
- Asymmetric Stereoablative Alkylation of 3-Halooxindoles (2010) (0)
- Photooxidation Products of Isoprene Epoxydiols (IEPOX) and IEPOX-Derived Secondary Organic Aerosol (2014) (0)
- Synthesis of (-)-Drupicine (2008) (0)
- Deracemization via Oxidation–Reduction Coupled Processes (2011) (0)
- Kumada-Type Arylation of Ketones (2011) (0)
- Using Iridium Catalysts (2011) (0)
- The Synthesis of C-3β Functionalized Indoles via a Hydroboration/Suzuki—Miyaura Coupling Sequence. (2007) (0)
- Double Catalytic Enantioselective Alkylation: Total Synthesisof (-)-Cyanthiwigin F (2008) (0)
- Nickel-Catalyzed Vinylation with Vinylsilanes (2011) (0)
- Using Lewis Acid Activated Brønsted Acids (2011) (0)
- Unusual Allylpalladium Carboxylate Complexes : Identification of the Resting State of Catalytic Enantioselective Decarboxylative Ketone Allylic Alkylation Reactions (2010) (0)
- MicroED structure of thiostrepton at 1.9 A resolution (2018) (0)
- Some Unusual Transformations of a Highly Reactive α-Bromocaranone (2021) (0)
- Lewis Acid Mediated [3 + 2] Cycloadditions of Donor—Acceptor Cyclopropanes with Heterocumulenes. (2013) (0)
- Knowledge Updates 2016/2 (2016) (0)
- A Dipolar Cycloaddition Strategy for the Synthesis of 3,8-Diazabicyclo[3.2.1]octane Tetrahydroisoquinoline Antitumor Antibiotics. The Total Synthesis of (-)-Lemonomycin (2013) (0)
- Palladium- and Nickel-Catalyzed Arylation with Aryl Halides (2011) (0)
- Thiol‐Reactive Inhibitors of Cdc48/p97 AAA ATPase as Potential Anti‐Cancer Therapeutics (2008) (0)
- Using Palladium Catalysts (2011) (0)
- A Mild and Efficient Approach to Enantioenriched α‐Hydroxyethyl α,β‐Unsaturated δ‐Lactams. (2016) (0)
- Silylation of Aromatic Heterocycles with Potassium tert-Butoxide Catalyst (2015) (0)
- Nickel‐Catalyzed Intramolecular C—O Bond Formation: Synthesis of Cyclic Enol Ethers. (2016) (0)
- Deracemization of Primary, Secondary, and Tertiary Amines (2011) (0)
- Palladium-catalyzed decarboxylative allylic alkylation ofdiastereomeric -ketoesters (2014) (0)
- Cuprous Chloride Accelerated Stille Reactions. A General and Effective Coupling System for Sterically Congested Substrates and for Enantioselective Synthesis. (1999) (0)
- Using Oxazolidinone Auxiliaries (2011) (0)
- Recent developments in stereoselective iridium-catalyzed allylic alkylation methodologies (2017) (0)
- Palladium‐Catalyzed Decarboxylative Allylic Alkylation of Diastereomeric β‐Ketoesters. (2014) (0)
- Twists and turns of lactam research (2017) (0)
- Stereoselective reactions of carbonyl and imino groups (2011) (0)
- Catalytic Enantioselective Decarboxylation-Protonation (2006) (0)
- Development of Palladium-Catalyzed Decarboxylative Cross-Coupling of (2-Azaaryl)carboxylates with Aryl Halides. (2013) (0)
- Hydrolysis of Enol Esters (2011) (0)
- Decarboxylative Allylic Alkylation of Enol Carbonates and Silanes with Palladium Catalysts (2011) (0)
- The Catalytic Enantioselective, Protecting Group‐Free Total Synthesis of (+)‐Dichroanone. (2006) (0)
- Construction of Tertiary Chiral Centers by Pd‐Catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents. (2015) (0)
- CCDC 1061009: Experimental Crystal Structure Determination (2016) (0)
- Vinylation of Enolates via Chiral Auxiliary Control (2011) (0)
- Progress Toward the Synthesis of the Basiliolides and Transtaganolides: An Intramolecular Pyrone Diels—Alder Entry into a Novel Class of Natural Products. (2008) (0)
- What is a Cross-Coupling? An Argument for a Universal Definition. (2022) (0)
- Nickel-Catalyzed Arylations with Arylmetals (2011) (0)
- Using Imine-Type Auxiliaries (2011) (0)
- Cyclic alkanes transfer dehydrogenation using homogeneous iridium pincer catalysts (2018) (0)
- Novel approach to antitumor antibiotics: Using the power of benzyne in synthesis (2012) (0)
- Abstract 5991: Development and characterization of a novel CDK4/6 inhibitor for the treatment of CDK4/6 dependent cancers (2023) (0)
- Accretion Product Formation in the Self-Reaction of Ethene-Derived Hydroxy Peroxy Radicals (2023) (0)
- Oxidative Kinetic Resolution—Claisen Rearrangement Sequence to Enantioenriched Arylcycloalkenes. (2007) (0)
- Investigations of an Unexpected [2+2] Photocycloaddition in the Synthesis of (-)-Scabrolide A from Quantum Mechanics Calculations. (2022) (0)
- Using Camphorsultam Auxiliaries (2011) (0)
- Tetrahedron reports on organic chemistry: Editors (2003) (0)
- Negishi-Type Arylation of Ketones (2011) (0)
- Oxidative Kinetic Resolution of α-Hydroxy Esters, Amides, Thioesters, and Phosphonates (2011) (0)
- The Total Synthesis of (-)-Lemonomycin. (2004) (0)
- Development of an Enantiodivergent Strategy for the Total Synthesis of (+)‐ and (‐)‐Dragmacidin F from a Single Enantiomer of Quinic Acid. (2005) (0)
- Reoxidation by Bulk Oxidants (2011) (0)
- Arylation of Enolates with Aryl Halides and Trifluoromethanesulfonates Using Chiral Transition-Metal Catalysts (2011) (0)
- Decarboxylative Conjugate Addition/Allylic Alkylation Cascades with Palladium Catalysts (2011) (0)
- Titelbild: Molecular Mousetraps: Gas‐Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors (Angew. Chem. 9/2003) (2003) (0)
- C—H Bond Functionalizations with Palladium(II): Intramolecular Oxidative Annulations of Arenes. (2008) (0)
- Abstract 4044: Development of UCT-01-097, a novel orally available ERK1/2 inhibitor for the treatment of ERK1/2 dependent cancers (2023) (0)
- Development of a Simple System for the Oxidation of Electron-Rich Diazo Compounds to Ketones. (2016) (0)
- Benzannulated Bicycles by Three‐Component Aryne Reactions. (2011) (0)
- Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones. (2016) (0)
- Abstract 6254: The discovery and preclinical characterization of the SAM-competitive PRMT5 inhibitor UCT-000445 (2023) (0)
- Biocatalytic Kinetic Resolution of Amino Acids and Amines (2011) (0)
- A Convergent Total Synthesis of (+)-Ineleganolide. (2023) (0)
- Alkylation of Enolates with Chiral Counterions (2011) (0)
- Catalytic enantioselective synthesis of tetrasubstituted chromanones via palladium-catalyzed asymmetric conjugate arylation using chiral pyridine-dihydroisoquinoline ligands (2020) (0)
- The Structural and Synthetic Implications of the Biosynthesis of the Calycanthaceous Alkaloids, the Communesins, and Nomofungin. (2006) (0)
- Synthesis of Chiral α-Substituted Ketones via Enantioselective Protonation (2008) (0)
- Pd-Catalyzed Asymmetric Synthesis of α-HydroxyKetones, Acids and Esters (2008) (0)
- Part-per-trillion trace gas detection using frequency-locked whispering gallery mode microtoroids (2021) (0)
- Oxidative Kinetic Resolution of Activated Secondary Alcohols (2011) (0)
- Nickel-Catalyzed Vinylation with Vinylzirconocenes (2011) (0)
- Hiyama-Type Arylation of Esters (2011) (0)
- Kinetic Resolution Using Molecular Oxygen as Terminal Oxidant (2011) (0)
- Deracemization via Oxidative Kinetic Resolution (2011) (0)
- The Palladium‐Catalyzed Oxidative Kinetic Resolution of Secondary Alcohols with Molecular Oxygen. (2001) (0)
- Synthesis of (+)-Cassiol (2009) (0)
- Synthesis of (-)-Amurensinine (2007) (0)
- Palladium-Catalyzed Vinylation with Vinyl Halides (2011) (0)
- Non‐Carbonyl‐Stabilized Metallocarbenoids in Synthesis: The Development of a Tandem Rhodium‐Catalyzed Bamford—Stevens/Thermal Aliphatic Claisen Rearrangement Sequence. (2003) (0)
- Preparation of 3,3‐Disubstituted Oxindoles by Addition of Malonates to 3‐Halo‐3‐oxindoles. (2008) (0)
- Alkylation of Tin Enolates Using Chromium Catalysts (2011) (0)
- Palladium-Catalyzed Asymmetric Alkylation of β-KetoEsters (2010) (0)
- Development of a Rhodium Carbenoid Initiated Claisen Rearrangement for the Enantioselective Synthesis of α‐Hydroxy Carbonyl Compounds. (1999) (0)
- The Construction of All‐Carbon Quaternary Stereocenters by Use of Pd‐Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis (2013) (0)
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