Arthur Carty
Canadian chemist
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(Suggest an Edit or Addition)According to Wikipedia, Arthur J. Carty, , is a Canadian academic and former National Science Advisor to the Government of Canada. Carty was the inaugural director of the Waterloo Institute for Nanotechnology at the University of Waterloo, special advisor to the President on international science and technology collaboration and research professor in the department of chemistry. From 2004-08, he served as Canada's first national science advisor to the prime minister and to the Government of Canada. Prior to his appointment as national science advisor, he was president of the National Research Council, Canada's leading knowledge and innovation organization, for ten years .
Arthur Carty's Published Works
Published Works
- Platinum(II) complexes with pyridyl azolate-based chelates: synthesis, structural characterization, and tuning of photo- and electrophosphorescence. (2006) (156)
- Structural chemistry and reactivity of cluster bound acetylides: close relatives of the carbides? (1982) (148)
- In Search of High‐Performance Platinum(II) Phosphorescent Materials for the Fabrication of Red Electroluminescent Devices (2005) (141)
- Unusual complex containing bridging vanadyl groups. Crystal structure of N,N'-propylenebis(salicylaldiminato)oxovanadium(IV) (1970) (140)
- Highly Efficient Red Phosphorescent Osmium(II) Complexes for OLED Applications (2004) (134)
- Organic Light‐Emitting Diodes based on Charge‐Neutral RuII Phosphorescent Emitters (2005) (130)
- Orange and Red Organic Light‐Emitting Devices Employing Neutral Ru(II) Emitters: Rational Design and Prospects for Color Tuning (2006) (111)
- Rational Color Tuning and Luminescent Properties of Functionalized Boron‐Containing 2‐Pyridyl Pyrrolide Complexes (2005) (101)
- Luminescent platinum(II) complexes containing isoquinolinyl indazolate ligands: synthetic reaction pathway and photophysical properties. (2007) (67)
- Hydrogénation of phosphido bridged ruthenium clusters. A view of P—C bond activation and cleavage in the coordinatively unsaturated molecule Ru3(CO)9(μ2-PPh2)(μ2-H): conversion of μ2-PPh2 to μ3-PPh (1982) (62)
- Carbene complexes: XX. Electron-rich carbeneiron(0) trigonal bipyramidal carbonyls and their germanium(II) and tin(II) analogues [Fe(CO)3(L)(L′)] (L = CN(Me)(CH2)2NMe, L′ = PEt3, 3 CO's equatorial; or L = M(OAr)2 (equatorial: M = Ge OR Sn, Ar = C6H2But2-2,6-Me-4), L′ = CO) (1986) (59)
- Synthesis of Some New Phosphino Acetylenes (1971) (56)
- Synthesis and spectroscopic characterization of binuclear, phosphido-bridged .sigma.-.pi.-acetylido complexes of iron. X-ray structure of a triphenylphosphine derivative (1977) (53)
- Electrophilic “Fischer Type” Phosphinidene Complexes of Molybdenum, Tungsten, and Ruthenium (2001) (52)
- Models for linear acetylide polymers: synthesis and single-crystal x-ray structures of the ruthenium(II) acetylide and diacetylides Ru(CO)2(PEt3)2[(C.tplbond.C)nR]2 (n = 1, R = SiMe3; n = 2, R = SiMe3, H) (1992) (51)
- Coordination complexes of acetylene diphosphines. I. Diphosphine-bridged binuclear copper(I) and gold(I) complexes of bis(diphenylphosphino)acetylene (1969) (51)
- Nature of Hg+-L-cysteine complexes implicated in mercury biochemistry. (1977) (51)
- Nitrato and Acetylacetonato Complexes of Copper(I) (1971) (50)
- A thermally stable and sterically unprotected terminal electrophilic phosphinidene complex of cobalt and its conversion to an eta(1)-phosphirene. (2003) (50)
- Phosphido-Bridged Iron Group Clusters (1982) (50)
- Terminal Aminophosphinidene Complexes of Iron, Ruthenium, and Osmium (2003) (49)
- A remarkable ligand orientational effect in osmium-atom-induced blue phosphorescence. (2004) (49)
- Chemical transformations on phosphido-bridged clusters. Synthesis of the 48- and 50-electron acetylide complexes Ru3(CO)n[.mu.3-.eta.2-C.tplbond.C(CHMe2)](.mu.-PPh2) (n = 8, 9) and their reactions with diazomethane. Carbon-carbon bond forming reactions and the conversion of acetylide to allenyl clus (1988) (46)
- Homometallic and Heterometallic Transition Metal Allenyl Complexes: Synthesis, Structure, and Reactivity (1995) (46)
- Platinum cluster compounds: X-ray structures of phosphido-bridged bi- and tri-nuclear complexes with strong metal–metal bonds derived from [Pt(PPh3)4] (1975) (45)
- Chemical alkylation of lead (II) salts to tetraalkyllead (IV) in aqueous solution (1980) (44)
- Acetylene additions to saturated and unsaturated clusters: four-electron addition with and without carbon monoxide loss (1984) (43)
- Coupling of acetylenes held proximate to a metal: alkyne-alkyne interactions in cis-phosphinoacetylene complexes, including structural characterization of the unsymmetrical diphosphine 1-phenyl-2,3-bis(diphenylphoshino)naphthalene and three platinum(II) complexes of Ph2PC.tplbond.CPh (1979) (41)
- Carbon disulfide complexes of zerovalent iron: synthesis and spectroscopic properties. X-ray crystal structure of (.eta.2-carbon disulfide)dicarbonyl(trimethylphosphine)(triphenylphosphine)iron(0) (1978) (41)
- En route to the formation of high-efficiency, osmium(II)-based phosphorescent materials. (2006) (40)
- Coordinatively and Electronically Unsaturated Tetraruthenium Clusters: Reversible Triple CO Addition to Ru4(CO)9(μ-PPh2)[μ4-Ph2PCC(Ph)CC(Ph)] (1998) (39)
- Coordination complexes of acetylenic phosphines and diphosphines : V. Acetylene bridged derivatives of dicobalt octacarbonyl (1973) (39)
- Synthesis and Structural Characterization of the First Thermally Stable, Neutral, and Electrophilic Phosphinidene Complexes of Vanadium (2011) (39)
- Reactivity of Terminal, Electrophilic Phosphinidene Complexes of Molybdenum and Tungsten. Nucleophilic Addition at Phosphorus and P−P Bond Forming Reactions with Phosphines and Diphosphines (2007) (38)
- Coupling of Acetylide Ligands on an Electron-Rich Tetraruthenium Diphosphido Framework: Synthesis, Structure, and Reactivity Studies of Ru4(CO)9(μ-PPh2)2(C2But)2 and Ru4(CO)8(μ-PPh2)2(C4But2) (1996) (38)
- Skeletal reactivity of metallophosphorus clusters. Nido-Ru4(CO)10(.mu.-CO)2[PhPC(Ph)C(Ph)] and closo-Ru4(CO)9(.mu.-CO)2(PhP)[C(Ph)C(Ph)] via acetylene incorporation into the nido framework of the phosphinidene cluster Ru4(CO)13(.mu.3-PPh) (1985) (37)
- Polynuclear acetylides. Synthesis, spectroscopic features and structural systematics for a complete triad of .mu.2-.eta.2-complexes: M2(CO)6(.mu.2-.eta.2-C.tplbond.CR)(.mu.-PPh2) (M = Fe, Ru, Os) (1988) (37)
- Synthesis and characterization of fluorinated aminoalkoxide and iminoalkoxide gallium complexes: Application in chemical vapor deposition of Ga2O3 thin films (2004) (37)
- Reactivity of Electrophilic Terminal Phosphinidene Complexes: P−P Bond Forming Reactions with Phosphines and Diphosphines (2001) (37)
- Deposition of Silver Thin Films Using the Pyrazolate Complex [Ag(3,5‐(CF3)2C3HN2)]3 (2005) (37)
- Deposition of Ru and RuO2 thin films employing dicarbonyl bis-diketonate ruthenium complexes as CVD source reagents (2003) (36)
- Polycarbon Ligand Chemistry: Electronic Interactions between a Mononuclear Ruthenium Fragment and a Cobalt−Carbon Cluster Core (1999) (36)
- Reactivity of electrophilic micro-phosphinidene complexes with N-heterocyclic carbenes: formation of the first main group element adducts of 'abnormal' carbene ligands. (2006) (35)
- Growth of IrO2 Films and Nanorods by Means of CVD: An Example of Compositional and Morphological Control of Nanostructures† (2003) (35)
- Metal-halogen stretching vibrations in coordination complexes of gallium, indium and thallium (1969) (35)
- Fluorinated aminoalkoxide and ketoiminate indium complexes as MOCVD precursors for In2O3 thin film deposition. (2003) (35)
- (.mu.-H)2M3(CO)8(.mu.-PPh2)2 (M = Fe, Ru, Os): an isostructural triad of phosphido-bridged hydrides. Rational synthesis and structural characterization (1985) (34)
- Open and closed ruthenium and osmium clusters with μ3-acetylide and phosphido bridges (1981) (33)
- Syntheses, X-ray crystal structure, and vibrational spectra of L-cysteinato(methyl)mercury(II) monohydrate (1975) (33)
- Synthesis and phosphorus-31 NMR studies of unsymmetrical cis-diphosphinoalkenes and their complexes with nickel(II), palladium(II), and platinum(II) (1979) (33)
- Fluorinated aminoalkoxide CuII complexes: new CVD precursors for deposition of copper metal (2002) (33)
- Perchlorato, Nitrato, and Acetylacetonato Complexes of Copper(I). The Crystal and Molecular Structure of Perchloratobis(tricyclohexyiphosphine)Copper(I) (1975) (33)
- Reactivity of phosphido-bridged heteronuclear compounds: insertion of carbon monoxide and diphenylacetylene into the phosphido bridge of RuCo(CO)7(.mu.-PPh2). X-ray structure of RuCo(CO)5(.mu.-CO)[.mu.-.eta.2-PPh2C(O)C(Ph)C(Ph)] (1984) (32)
- Facile ruthenium-ruthenium bond cleavage and reformation in a pentanuclear carbonyl cluster: synthesis and x-ray structural studies of Ru5(CO)13(.mu.4-.eta.2-C.tplbond.CPh)(.mu.-PPh2) and its CO adduct Ru5(CO)14(.mu.5-.eta.2-C.tplbond.CPh)(.mu.-PPh2) (1983) (32)
- Reactions of uncoordinated acetylenes held proximate to a metal. Products from the hydrolysis of cis-dichlorobis(3,3,3-trifluoropropynyldiphenylphosphine)palladium(II) (1975) (31)
- New CVD precursors capable of depositing copper metal under mixed O2/Ar atmosphere. (2005) (31)
- Butterfly cluster complexes of the group VIII transition metals (1988) (31)
- Co-ordination compounds of indium. Part IV. Adducts of indium(III) chloride, bromide, and iodide with neutral donors (1966) (31)
- Tin-119 Moessbauer spectra. I. Tertiary phosphine adducts of tin tetrachloride (1970) (31)
- Synthesis and characterization of di-.mu.-thiocyanatobis[hydrogen bis(diphenylphosphinato)]dipalladium (II). Complex containing a novel symmetrically hydrogen-bonded anion (1974) (30)
- A one step synthesis of phosphine substituted sulphur capped clusters from phosphine sulphides: X-ray crystal structures of [Fe3(CO)8(µ2-CO)(µ3-S)(Ph2PC2Pri)] and [Ru3(CO)8(µ3-S)2(Ph2PC2But)] (1988) (29)
- Synthesis of Fe4(CO)8(µ-PPh2)2(µ4-η1,η1,η2,η2-C2Ph)2via coupling of acetylides at a binuclear centre: a molecule with through-the-cluster carbon–carbon bonding? (1997) (29)
- Ru5(CO)13(C.tplbond.CPh)(PPh2): a square pyramidal ruthenium cluster with a single .mu.4-bound acetylide (1981) (29)
- Iridium Metal Thin Films and Patterned IrO2 Nanowires Deposited Using Iridium(I) Carbonyl Precursors (2006) (29)
- Coordination complexes of gallium(III) and indium(III) halides. I. Complexes with triarylphosphines (1967) (28)
- Phosphorus chemical shift tensors of phosphido ligands in ruthenium carbonyl compounds: (31)P NMR spectroscopy of single-crystal and powder samples and ab initio calculations. (2002) (28)
- Formation and Stabilization of a Decanuclear CuII Wheel Linked by Chloride and O⋅⋅⋅H−N Hydrogen Bonds (2001) (28)
- Enyne and Butatriene Ligands from the Reaction of Diynes on the Square Face of the Hydrido Phosphinidene Cluster (.mu.-H)2Ru4(CO)12(.mu.3-PPh) (1994) (28)
- Nucleophilic attack at carbon in .sigma.,.pi.-acetylides. Bridging one carbon and two carbon iminium ion complexes via addition of cyclohexylamine to [Fe2(CO)6(C2Ph)(PPh2)]. X-ray structures of [Fe2(CO)6{CHC(NHC6H11-c)(Ph)}PPh2] and [Fe2(CO)6{C(NHC6H11-c)CHPh}(PPh2)].0.5C6H6 (1978) (28)
- Polycarbon ligand complexes: Synthesis, molecular structures, and selected EHMO studies of Ru-4, Ru-5, and Ru-6 clusters with carbon ligands derived from phosphinodiynes (1998) (28)
- Tailored synthesis of hydrocarbon chains via carbon-carbon coupling reactions of diynes and alkynes on the square face of a ruthenium Ru4P cluster (1992) (28)
- Reactivity of terminal electrophilic phosphinidene complexes : Synthesis of the first rhenium phosphinidene, [Re(CO)5(η1-PNiPr2)][AlCl4], and novel reactions with azobenzene (2005) (27)
- Phosphorus Monoxide, the Analog of NO: Generation of Coordinated PO via Hydrolysis of an Aminophosphinidene Ligand. X-ray Structure of the Anion [Ru4(CO)12(.mu.3-PO)]- (1994) (27)
- Terminal chloroaminophosphido and aminophosphinidene complexes of molybdenum (2001) (27)
- Co-ordination chemistry of bivalent Group 4B heavy metal donors M[N(SiMe3)2]2(M = Ge or Pb) or Ge[CH(SiMe3)2]2; and the crystal and molecular structure of [Cr(CO)5(Ge{CH(SiMe3)2}2)] (1977) (27)
- Coordination complexes of acetylene diphosphines. II. Diphosphine bridged palladium(II) and platinum(II) derivatives (1969) (27)
- Silylmethyl and related complexes. 7. Bulky, monomeric, heavy Group III metal trialkyls and the crystal and molecular structure of tris[bis(trimethylsilyl)methyl]indium (1980) (27)
- Stereochemistry of nickel(II) halide-phosphine complexes by far-infrared spectroscopy (1968) (27)
- Synthesis and structure of .pi.-phosphinacetylene complexes of zerovalent palladium and platinum (1974) (26)
- An accurate determination of the molecular structure of Fe3(CO)9(.mu.3-.eta.2-.perp.-C2Et2): a seminal type of acetylene complex (1988) (26)
- Reactivity of multisite-bound ligands. Nucleophilic attack at carbon in cluster acetylides by isocyanides and amination of the products. X-ray structures of H Ru3(CO)9[C(CN-t-Bu)CPh] and Os3(CO)9[C{C(NH-n-Bu)(NH-t-Bu)}CPh](PPh2) (1983) (25)
- Chemistry of phosphido-bridged Group VIII compounds. Molecular structures of the platinum dimers [PtCl(PPh2)(PPh2H)]2 and [Pt(Ph2PCH2CH2PPh2)(PPh2)]2Cl2 (1982) (25)
- Transition Metal Carbonyl Compounds (2004) (25)
- Metal-templated diyne cyclodimerization and cyclotrimerization. (2005) (25)
- Hydrodimetalation of alkynes and diynes: diiron complexes of .mu.-.eta.1:.eta.2-alkenyl ligands with pendant alkynes: crystal and molecular structure of Fe2(CO)6(.mu.-PPh2)(.mu.2-.eta.1:.eta.2-CH:CH2) and Fe2(CO)6(.mu.-PPh2)(.mu.2-.eta.1:.eta.2-C(C.tplbond.CMe):CHMe) (1992) (24)
- Chemistry of phosphido-bridged mixed-metal complexes. Insertion of alkynes into the phosphido bridge of (CO)4Ru(.mu.-PPh2)Co(CO)3. X-ray structures of (CO)3Ru(.mu.-Ph2PC(O)C(Ph):C(Ph))Co(CO)3, (CO)3Ru(.mu.-Ph2PC(O)C(SiMe3):C(H))Co(CO)3, and (CO)3Ru(.mu.-Ph2PC(Ph):C(Ph))Co(CO)3 (1990) (24)
- Multisite-bound vinylidenes on heterometallic clusters. Reformulation of (.eta.5-C5H5Ni)Ru3(CO)9(.mu.4-.eta.2-C:CHR) (R = tert-Bu) as hydrido-bridged (.mu.-H)(.eta.5-C5H5Ni)Ru3(CO)9(.mu.4-.eta.2-C:CHR). Molecular structure of the isopropyl derivative (R = iso-Pr) and an improved synthetic method (1983) (24)
- Mixed thiocyanate complexes of platinum(II). Crystal structure of cis-thiocyanatoisothiocyanatobis(3,3-dimethylbutynldiphenylphosphine)platinum(II) (1974) (24)
- Phosphido-bridged mixed-metal (ruthenium/cobalt) compounds via the reaction of (arene)RuCl2(PPh2X) (X = H, Cl) with Co2(CO)8: x-ray structure of RuCo2(.mu.-PPh2)2(.mu.-CO)(CO)7 (1984) (24)
- Deposition of Iridium Thin Films Using New IrI CVD Precursors (2002) (24)
- NATURE OF MERCURY(2+) ION-L-CYSTEINE COMPLEXES IMPLICATED IN MERCURY BIOCHEMISTRY (1977) (24)
- Carbon-13 NMR shifts of bridging acetylides in polynuclear complexes (1988) (24)
- The chromium–heavy group 5 donor bond: a comparison of structural changes within the series [Cr(CO)5(XPh3)](X = P, As, Sb, or Bi)via their X-ray crystal structures (1979) (24)
- Coordination complexes of acetylenic phosphines and diphosphines. IV. Characterization and Moessbauer spectra of derivatives of cyclopentadienyliron dicarbonyl dimer and cyclopentadienyliron dicarbonyl halides (1970) (23)
- Octahedral bis(acetylide) and bis(diacetylide) complexes of ruthenium(II) with linear C2MC2 and C4MC4 chains: The first X-ray structures of the all trans bis(acetylides) Ru(CO)2(CCPh)2(PEt3)2 and Ru(CO)2(CCH)2(PEt3)2 (1992) (23)
- Ru5(CO)16(.mu.-PPh2)(.mu.5-P): a low-nuclearity cluster with a partially encapsulated phosphide (1983) (23)
- Reversible formation of ruthenium cluster (.mu.-H)Ru4(CO)10(.mu.-PPh2)[.mu.4-.eta.1(P),.eta.1(P),.eta.1(P),.eta.1,.eta.2-[C6H4]PPh] from the electron-rich cluster Ru4(CO)13(.mu.-PPh2)2: the first example of a molecule with a five-coordinate bis(aryl)phosphido bridge (1992) (23)
- Subvalent Group 4B metal alkyls and amides. Part 6. Oxidative addition of an alkyl or aryl halide to bis[bis(trimethylsilyl)methyl]tin(II); hydrogen-1 nuclear magnetic resonance data on the tin(IV) adducts and a single-crystal X-ray study of tris[bis(trimethylsilyl)methyl]chlorotin(IV) (1977) (23)
- Binding of heavy metals at biologically important sites. Synthesis and molecular structure of aquo(bromo)-DL-penicillaminatocadmium(II) dihydrate (1977) (23)
- Chemistry of multisite-bound ligands. Addition of amines to .mu.-.eta.2-acetylides: dipolar, electron-rich .mu.-.eta.1- and .mu.-.eta.2-alkylidene and .mu.-.eta.1-vinylidene diiron hexacarbonyl complexes (1983) (23)
- Coordination complexes of gallium(III) and indium(III) halides. II. Far-infrared spectra of gallium(III) halide complexes with triarylphosphines (1967) (22)
- Synthesis and structure of metallocarbon clusters bearing pendant ethynyl ligands. X-ray crystal structures of Os3(CO)9(μ-CO)(μ3-η1,η1,η2-Me3SiCCC2CCSiMe3), Os3Ru(CO)12(μ4-η1,η2,η1,η2-Me3SiCCC2CCSiMe3), Ru4(CO)12(μ4-η1,η2,η1,η2-Me3SiCCC2CCSiMe3) and {Ru4(CO)12}{Co2(CO)6}(μ4-η1,η2,η1,η2:μ-η2,η2-Me3Si (1999) (22)
- Synthesis, spectroscopic, and X-say structural characterization of methylmercury-d , l -selenocysteinate monohydrate, a key model for the methylmercury(II)-selenoprotein interaction (1983) (22)
- CHAIN EXTENSION AND C-C BOND FORMATION ON C4 POLYCARBON LIGANDS : NOVEL CHEMISTRY OF SIGMA -PI -BUTADIYNYL COMPLEXES WITH CARBENE SOURCES (1996) (22)
- Syntheses of new ruthenium clusters containing sulfur, ynyl and diynyl ligands. Crystal structures of [Ru3(CO)9(μ-η2-SCCSiMe3)(μ3-η2-CCSiMe3)], [Ru4(CO)12(μ4-S)(μ-η2-CCSiMe3)2] and [Ru4(CO)9(μ-CO)2(μ4-S)(μ4-η2-C(SiMe3)C(CCSiMe3)] (2001) (21)
- Structural versatility of Ru4 butterflies. The molecular structures of Ru4(CO)13(.mu.-PPh2)(.mu.-.eta.2-C.tplbond.C-t-Bu) and Ru4(CO)8(.mu.-PPh2)2(.mu.-.eta.2-C.tplbond.C-t-Bu)(.mu.3-.eta.2-C.tplbond.C-t-Bu)(Ph2PC.tplbond.C-t-Bu).1/2C6H14: clusters with almost planar metal frameworks (1982) (21)
- Polycarbon ligand chemistry. Novel behaviour ofµ-η1,η2α,β-butadiynyls towards metal fragment additions (1997) (21)
- Coordination complexes of acetylenic phosphines and diphosphines (1973) (21)
- 1,6-Bis(trimethylsilyl)hexa-1,3,5-triyne as a precursor to ruthenium clusters containing highly ethynylated ligands (1998) (20)
- Solid-state phosphorus-31 NMR investigations of phosphido-bridged complexes: chemical shift bond angle correlations (1989) (20)
- The selenium-mercury interaction: synthesis, spectroscopic and x-ray structural studies of methylmercury-selenourea complexes (1979) (20)
- Electron Rich Cluster Chemistry: Synthesis and Molecular and Electronic Structures of the Series of Clusters Ru4(CO)13(.mu.-PR2)2 with Expanded Metal Frameworks (1994) (20)
- SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL CHARACTERIZATION OF BIS(DIPHENYLPHOSPHINO(PHENYL)ACETYLENE)HEXACARBONYLDIIRON(0), AN ALKYNE DERIVATIVE OF IRON PENTACARBONYL (1977) (20)
- Some new diphosphine-bridged nickel carbonyl and cyclopentadienyl compounds (1969) (20)
- Synthesis and structure of the cluster ion pair [Ru3(CO)9[mu-P(NPri2)2]3][Ru6(CO)15(mu 6-C)[mu-P(NPri2)2]]. A theoretical overview of M3(mu-PR2)3 frameworks. (2000) (20)
- σ,π-acetylido complexes via PC bond cleavage of phosphinoacetylenes: X-ray structure of Fe2(CO)6(CCPh)(PPh2) (1973) (20)
- Phosphorus Monoxide Coordination Chemistry: Synthesis and Structural Characterization of Tetranuclear Clusters Containing a PO Ligand (1996) (19)
- THE INTERACTION OF ORGANOMERCURY POLLUTANTS WITH BIOLOGICALLY IMPUTANT SITES, AN X‐RAY STUDY OF THE 2 TO 1‐COMPLEX BETWEEN METHYLMERCURY AND PENICILLAMINE (1973) (19)
- Chemical transformations on phosphido-bridged clusters. Methyne, methylene transfer, and ketene forming reactions involving the μ-methylene cluster Ru3(CO)7(μ-CH2){μ3-η3-CH2=C=C(i-Pr)}(μ-PPh2). X-ray structures of (μ-H)Ru3(CO)7{μ3-η4-CH=C(i-Pr)C=CH2}(μ-PPh2) and Ru3(CO)6(μ-CO){μ3-η4-CH2=C(i-Pr)C=CH2 (1988) (19)
- Synthesis, Characterization, and Photophysical Properties of Luminescent Gallium and Indium Complexes Constructed using Tridentate 6-Azolyl-2,2′-bipyridine Chelates (2008) (19)
- Reactivity patterns of thermally stable, terminal, electrophilic phosphinidene complexes towards diazoalkanes: oxidation at the phosphorus centre and formation of P-bound eta1-phosphaazine, eta1-phosphaalkene and eta3-diazaphosphaallene complexes. (2005) (19)
- Reactivity patterns of heterobinuclear carbonyls: site selectivity in substitution reactions of (CO)4Ru(μ-PPh2)Co(CO)3 with phosphines and the X-ray structure of (Ph3P)Ru(CO)3(μ-PPh2)Co(CO)3 (1986) (19)
- Coordination behavior of monoalkynylphosphines with metal carbonyls: X-ray crystal structure of Co4(CO)10(Ph2 PCCCF3)2 (1971) (19)
- Reactions of the (2-pyridyl) pyrrolide platinum(II) complex driven by sterically encumbered chelation: a model for the reversible attack of alcohol at the coordinated carbon monoxide. (2008) (19)
- Synthesis and Characterization of Ruthenium Complexes with Two Fluorinated Amino Alkoxide Chelates. The Quest to Design Suitable MOCVD Source Reagents (2003) (19)
- Synthesis and structure of a series of tungsten(II) and tungsten(VI) diynyl and diyndiyl complexes (2003) (19)
- Planar 64-electron butterfly clusters with elongated metal–metal bonds: synthesis and molecular structures of Ru4(CO)13(µ-PPh2)2 and Ru4(CO)10(µ-PPh2)4 (1988) (18)
- Metallocene derivatives of early transition elements. Part 4. Synthesis and crystal structures of a series of zirconocene(IV) halides [Zr(η-C5H4SiMe3)2X2](X = Cl or Br) and [Zr{η-C5H3(SiMe3)2-1,3}2X2](XF, Br, or I) (1987) (18)
- Synthesis of σ-π-phosphinidene sulfide complexes [Mn2 (CO)n(μ-η1,η2 -P (NR2 )=S )] (n = 8, 9) via direct sulfuration of electrophilic μ-phosphinidenes and photochemical transformation to a trigonal prismatic Mn2P2S2 cluster (2007) (18)
- Solid-state structures of group IIIb metal chloride adducts with 2,2',2''-terpyridyl (1972) (18)
- Reactivity of electrophilic μ-phosphinidene complexes with heterocumulenes: formation of the first σ-π-aminophosphaimine complexes [Mn2(CO)8{μ-η1,η2-P(NiPr2)NR}] and diazoalkane insertions into metal–phosphorus bonds (2005) (18)
- Mixed transition metal-main group atom clusters as potential models for M[sub x]X (010) and M[sub 4] (100) surfaces. Synthesis and spectroscopic and structural characterization of M[sub 4](CO)[sub 13]([mu][sub 3]-PPh) (M = Ru, Os). Pyramidal clusters with M[sub 3]P square faces (1993) (18)
- Deposition of Conductive Ru and RuO2 Thin Films Employing a Pyrazolate Complex [Ru(CO)3(3,5‐(CF3)2‐pz)]2 as the CVD Source Reagent (2003) (18)
- Oxidative addition of an alcohol to the alkylgermanium(II) compound Ge[CH(SiMe3)2]2; molecular structure of Ge[CH(SiMe3)2]2(H)OEt (1981) (18)
- Synthesis, crystal structure, and infrared spectra of trans-dithiocyanato-bis-[(3,3-dimethylbutynyl)diphenylphosphine]palladium(II) (1973) (17)
- Carbon-carbon bond formation on multisite-bound unsaturated ligands: synthesis of .mu.2-.eta.2-allenyl complexes via carbene addition to the binuclear acetylides Ru2(CO)6(.mu.2-.eta.2-C.tplbond.CR)(.mu.-PPh2) (1986) (17)
- Chemistry of .eta.2-CS2 - metal complexes: synthesis of dithiolene complexes of iron via acetylene additions to Fe(.eta.2-CS2)(CO)2(PR3)2. X-ray structure of Fe[S2C(COMe)C(C6H4NO2)](CO)[P(OMe)3]2 (1981) (17)
- Competitive nucleophilic attack between carbon and metal atoms in bridging hydrocarbyls: x-ray structures of Fe2(CO)5(.mu.-PPh2)[.mu.-C:C(Ph)PPh2CH2PPh2], a novel zwitterionic vinylidene complex, and Fe2(CO)4(.mu.-PPh2)(.mu.2-.eta.2-C.tplbond.CCHMe2)(.mu.-Ph2PCH2CH2PPh2), a diphosphine-bridged acety (1992) (17)
- The coordination of alkynes to four metal atoms in square planar clusters. Crystal structure and cluster contraction and expansion reactions of (η5-C5H5)2Ni2Fe2(CO)6(μ4,η2-C2Ph2) (1985) (17)
- Intramolecular interactions in bis(pentamethylcyclopentadienyl) complexes: X-ray structures of (η5-C5Me5)2Zr(OH)(Cl) and (η5-C5Me5)2Zr(OH)2 (1985) (17)
- Facile and quantitative activation of dihydrogen by the phosphinidene-stabilized ruthenium cluster Ru4(CO)13(.mu.3-PPh): synthesis and spectroscopic and structural characterization of (.mu.-H)2Ru4(CO)12(.mu.3-PPh) (1992) (16)
- PROTON MAGNETIC RESONANCE AND INFRARED SPECTRA OF SOME COMPLEXES OF N,N-DIMETHYLACETAMIDE (1966) (16)
- A New Allenyl Bonding Mode in Binuclear Complexes: Characterization and Molecular Structures of M2(CO)6(.mu.-PPh2)(.mu.-.eta.1:.eta.2.beta..gamma.-C(Ph():C:CH2) (M = Ru, Os) (1994) (16)
- Phosphorus-31 chemical shift tensors of phosphinidene ligands in ruthenium carbonyl cluster compounds: A 31P single-crystal and CP/MAS-NMR study (1995) (16)
- Transformations of alkynyl ligands at iron centres: alkenyl formation via addition of PPh3 and enyne generation via head-to-head coupling and addition of benzene (1999) (16)
- C–C bond-making by trapping of a nucleophilic carbene (from an electron-rich olefin) by a σ–π-acetylido(hexacarbonyl)di-iron complex; X-ray crystal and molecular structure of [(OC)3FeC(+CNMeCH2CH2NMe)(Ph)Fe(CO)3PPh2] (1978) (16)
- Binuclear copper(I) complexes with bridging bis(diphenylphosphino)acetylene groups (1968) (16)
- Synthesis of mixed metal clusters from binuclear precursors: X-ray structure of (η5-C5H5)2(CO)5(μ-PPh72)(μ4-η2-CCPh a molecule with a μ4-acetylide on a spiked triangular metal framework (1985) (16)
- Acetylide generation and coupling on electron-rich Ru3 clusters (2002) (16)
- Reactivity of unsaturated clusters. Phosphoruscarbon bond activation, hydrogen migration and acetylene interconversion in the reactions of 46-electron (H)Ru3(CO)9(μ-PPh2) with Ph2PCCR (R = Ph, But, Pri). X-ray structure of Ru3(CO)9(μ-PPh2)2(μ3-η2-HCCPh): a new type of 5-vertex, 7-skeletal pair clust (1987) (16)
- Metal carbonyl complexes of cyclic azines. I. Reactions of Fe2(CO)9, Ru3(CO)12, and [Rh(CO)2Cl]2 with 3,5,7-triphenyl-4H-1,2-diazepine and 3,5,7-triphenyl-4,5,6-trihydro-1,2-diazepine (1972) (16)
- Diphenyldiazomethane as a six-electron .mu.4-ligand in metal cluster chemistry: structural characterization of Ru5(CO)12(.mu.4-.eta.2-C.tplbond.CR)(.mu.4-N2CPh2)(.mu.-PPh2) (R = Ph) and the product of CO insertion into the nitrogen-nitrogen bond in Ru5(CO)13(.mu.4-.eta.2-C2R)(.mu.4-NC(O)NCPh2)(.mu.- (1986) (16)
- Acetylene–acetylide coupling via reactions of phosphido-bridged σ–π-acetylides with alkynes. X-Ray crystal structures of [Fe2(CO)5{PPh2C(O)C(But)CC(CO2Et)C(CO2Et)}] and [Fe2(CO)5{PPh2C(Ph)C(CO2Et)CC(But)CO}] (1976) (16)
- Electron-rich cluster chemistry. Stepwise transformation of rhomboidal 64-electron Ru4(CO)13{.mu.-P(NiPr2)2}2 to 62-electron butterfly and 60electron tetrahedral clusters via .mu.4-.eta.2-CO coordination and hydrogenolysis (1993) (16)
- Coordination complexes of gallium(III) and indium(III) halides. V. Trialkyl and mixed alkyl–aryl phosphine complexes of indium(III) chloride, bromide, and iodide (1970) (15)
- Synthesis and structure of π-acetylene complexes of zerovalent iron and nickel: sym-di-μ-phenyldiphenylphosphino-acetylene-bis {tricarbonyliron(0)} and sym-di-μ-t-butyldiphenylphosphinoacetylene-bis {carbonylnickel(0)} (1974) (15)
- Phosphorus-31 nuclear magnetic resonance spectra of palladium and platinum thiocyanate complexes. Probe of metal-thiocyanate bonding and novel source of phosphorus-phosphorus and phosphorus-nitrogen coupling constants (1976) (15)
- Carbon chain growth via methylene (CH2) additions to cluster-bound unsaturates: conversion of .mu.3-.eta.2-acetylides to .mu.3-.eta.3-allenyl and .mu.3-.eta.4-2,3-butadienylidene complexes with diazomethane (1984) (15)
- Two-carbon three-electron ligands. Phosphonium–betaine complexes via nucleophilic attack by phosphites on a σ-π-acetylide di-iron hexacarbonyl derivative (1975) (15)
- Methylmercury(II) selenolates. synthesis and characterization of MeHgSeMe and MeHgSePh, and 1H and 199Hg nmr studies of ligand exchange in MeHg(II) thiolates and selenolates, including amino acid complexes (1983) (15)
- Phosphorus-based 1,3-dipoles as three-electron one-carbon ligands: x-ray structure of μ-[phenyl(dicyclohexylphosphonio)ethenidyl]-μ-(diphenylphosphido)hexacarbonyldiiron, Fe2(CO)6[CC(PCy2H)Ph](PPh2) (1978) (15)
- Chemical transformations on phosphido-bridged clusters. Reactions of the .mu.3-.eta.3-allenyl complex Ru3(CO)8{.mu.3-.eta.3-CH2C:C(i-Pr)}(.mu.-PPH2). Reversible CO addition, adduct formation with P(OMe)3, hydrogenation, and alkyne insertion (1988) (15)
- The reactivity of terminal chloroaminophosphido ligands towards metal carbonyl complexes. Formation of μ2- and μ3-phosphinidene clusters (2003) (15)
- New Reaction Pathways for μ-η1,η2-Allenyl Ligands: On−Off Allenyl Coordination and CO Insertion into the Hydrocarbyl Bridge in Ru2(CO)6(μ-PPh2){μ-η1,η2α,β-C(Ph)CCPh2} (1997) (15)
- Synthesis and crystal structure analysis of bis(.eta.5-cyclopentadienyl)-.mu.-[trifluoromethyl(oxodiphenylphosphino)acetylene]-dinickel(0) (1977) (14)
- Comparison of the closo trigonal-bipyramidal structures of .mu.3-.eta.2-.perp.-acetylene and -acetylide clusters: synthesis of (.eta.5-C5H5)NiFe2(CO)6(.mu.3-.eta.2-C.tplbond.CPr-iso) and x-ray structures of (.eta.-C5H5)NiFe2(CO)5(L)(.mu.3-.eta.2-C.tplbond.CR) (R = Pr-iso, L = CO; R = Bu-tert, L = PP (1991) (14)
- Early High Oxidation State−Late Low Oxidation State Mixed-Metal Organometallics: Examples of Oxo-Bridged Tungsten−Ruthenium Acetylide Clusters (1997) (14)
- Binding of inorganic mercury at biological sites: crystal structures of Hg2+ complexes with sulphur amino-acids (1976) (14)
- Electron rich acetylide clusters; molecular and electronic structure and reactions of Os3(CO)7(µ2-η2-CCR)2(µ-PPh2)2(R = Ph, Pri); 50-electron species with expanded metal frameworks (1990) (14)
- Synthesis and Characterization of Tris(β‐ketoiminato)ruthenium(III) Complexes: Potential Precursors for CVD of Ru and RuO2 Thin Films (2004) (14)
- Five-coordinated halogenomercurate(II) complexes: crystal structures of bis(L-tryptophanium) trichloromercurate(II) and bis(D,L-homocysteine thiolactonium) tetrabromomercurate(II) (1981) (14)
- Reactivity patterns for .mu.-.eta.1:.eta.2-allenyl complexes. A novel synthetic route to dimetallacyclopentanes and dimetallacyclopentenes via regiospecific additions of carbon, nitrogen, and phosphorus nucleophiles to Ru2(CO)6(.mu.-.eta.1:.eta.2-PhC:C:CH2)(.mu.-PPh2) (1991) (14)
- Differentiating metal centers in homopolynuclear systems: use of the oxodiphenylphosphoranido diphenylphosphidoxo .mu.PH2P:0) ligand as a versatile bridging group and a comparison with related .mu.-diphenylphosphido (.mu.-PPh2) complexes (1987) (14)
- Synthesis, phosphorus-31 shift correlated two-dimensional (COSY) nuclear magnetic resonance spectra, and structure of the tris(trimethyl phosphite)-substituted phosphido-bridged heteronuclear dimer [(MeO)3P]2(CO)2Ru(.mu.-PPh2)Co(CO)2[P(OMe)3] (1986) (14)
- Encapsulated phosphides: Ru8(CO)21(.mu.6-P)(.mu.4-PPh)(.mu.2-PPh2), a molecule with a six-coordinate phosphorus atom in a condensed cluster (1989) (14)
- Coordination complexes of acetylene diphosphines. Part III. Silver(I) and mercury(II) complexes (1969) (13)
- Structural characterisation of an acetylenic diphosphine derivative of π-cyclopentadienyliron dicarbonyl dimer: an unusual Mössbauer effect (1969) (13)
- Comparison of the molecular structures of trans-di(isothiocyanato)bis(triphenylphosphine)palladium(II) and trans-di(thiocyanato)bis(triphenyl phosphite)palladium(II) (1976) (13)
- A triad of electron-rich .mu.2-alkylidene complexes M2(CO)6[.mu.-CHC(Ph)NEt2](.mu.-PPh2) (M = Fe, Ru, Os) via the addition of diethylamine to the acetylides M2(CO)6(.mu.2-.eta.2-C.tplbond.CPh)(.mu.-PPh2): spectroscopic properties and structural chemistry (1988) (13)
- NUCLEAR MAGNETIC RESONANCE SPECTRA AND CONDUCTIVITIES OF SOME METAL ACETYLACETONATES (1965) (13)
- Synthesis and X-ray molecular structure of [Ru3(CO)6(µ2-C2But)(µ2–η2-C2But)(PPh2)2(Ph2PC2-But)]; a cluster containing symmetrical and unsymmetrical edge bridging alkynyl groups (1979) (13)
- Synthesis and characterization of mixed ruthenium/platinum mu(4)-phosphinidene, phosphorus monoxide, and related clusters. (2001) (13)
- Transmethylation of metals in aquatic systems (1987) (13)
- Trinuclear ferracyclopentadiene complexes via oligomerization of phosphino- and arsino-acetylenes. X-ray structure of Fe3(CO)8[Ph2PC4(CF3)2](Ph2) (1972) (13)
- Reactivity patterns for multisite-bound acetylides. Nucleophilic attack at the .alpha.-carbon in .mu.2-.eta.2-acetylides. Bridging 2-amino-1-metallaphenethylidene complexes via addition of primary amines to M2(CO)6(.mu.2-.eta.2-C.tplbond.CPh)(.mu.-PPh2) (M = Fe, Ru, Os) (1990) (13)
- NiRu4(CO)9(µ-PPh2)2(µ4-CCPri)2: a pentanuclear mixed metal cluster with a novel metal framework (1982) (13)
- π-complexes of 1H-1,2-diazepines. Synthesis and characterization of tricarbonyliron and -ruthenium derivatives (1971) (13)
- Coordination complexes of gallium(in) and indium(III) halides. III. Complexes of gallium(III) halides with 2,2′-bipyridyl (1968) (12)
- Self-Reducible CuII Source Reagents for the CVD of Copper (2001) (12)
- X-Ray crystallographic and spectroscopic studies of the binding of methylmercury by the sulphur amino-acid DL-penicillamine: models for methylmercury poisoning of proteins (1977) (12)
- Directed synthesis of phosphorus-substituted cyclopentadienones and cyclobutadienes via metal carbonyl promoted coupling of acetylenes held proximate to a metal (1984) (12)
- A monosubstituted derivative of dicobalt octacarbonyl containing bridging carbonyl groups: [Co2(CO)7]2Ph2PCCPPh2 (1970) (12)
- Phosphido-phosphinidene transformations. Ru3(CO)6-[P(Ph)C(Ph)C(Ph)](μ-PPh2)2: A novel six vertex nido-pentagonal bipyramidal structure via reductive elimination and acetylene insertion at a triruthenium centre (1990) (12)
- Trans-Aquacarbonyldichlorobis(triethylphosphine)ruthenium, an aquo carbonyl complex of ruthenium: synthesis, structural characterization, and reactivity (1993) (12)
- Novel phosphido-bridged cations [M2(CO)8(.mu.-PPh2)]BF4 (M = iron, ruthenium): synthesis, reactivity, and x-ray structure of an isoelectronic and structural analog of Ru2(CO)9 (1990) (12)
- Polycarbon ligands: synthesis and characterization of the phosphinodiynes Ph2PC≡C-C≡CR (R = But, Ph, SiMe3), the μ-η1,η2α,β-butadiynyl complexes Ru2(CO)6-(μ-PPh2)(μ-η1,η2α,β-C≡C-C≡CR), and the molecular structure of a cobalt carbonyl derivative Ru2(CO)6(μ-PPh2)(μ-η1,η2α,β:-μ-η2,η2γ,δ-C≡C-C≡CBut)Co2( (1996) (12)
- Carbon disulphide iron carbonyl complexes: X-ray crystal structure of Fe(η2-CS2) (CO)2 (PMe3) (PPh3) (1977) (12)
- A trans-effect in gallium complexes: the crystal structure of trichloro-(2,2′,2″-terpyridyl)gallium(III) (1970) (12)
- Reactions of σ-π alkenyl complexes [Fe2(CO)6(μ-alkenyl)(μ-PPh2)] with bis(diphenylphosphino)methane (dppm); carbonyl substitution, migratory carbonyl insertion, phosphorus–carbon bond formation and cleavage, proton shift and alkenyl isomerisation reactions (1999) (12)
- Iron tricarbonyl complexes of 1(1H),2-diazepine and methyl substituted derivatives. Novel fluxional organometallic compounds (1973) (12)
- Cycloaddition to a nitrogen-bridged iron complex. Preparation and crystal structure of the maleic anhydride adduct of µ-(3,6-diphenylpyridazine)–hexacarbonyldi-iron (1972) (12)
- A new class of palladium and platinum complexes: Diphosphine bridged M2X4L2 species. (L=Bis diphenylphosphinoacetylene) (1968) (12)
- Fundamental studies on phosphorus-31 relaxation mechanisms: The importance of chemical shift anisotropy and its implications for sup 31 P NMR studies of organometallic compounds (1989) (11)
- The Coordination Chemistry of Indium (2007) (11)
- Co-ordination chemistry of indium. Part VI. Far-infrared spectra of indium trihalide adducts with neutral donors (1968) (11)
- Triangular iron-silver clusters via the addition of silver electrophiles to electron-rich iron-iron bonds (1983) (11)
- Notes. Crystal structure of [Ni2Ru3(η-C5H5)2(CO)9(µ5-PPh)], an open square-pyramidal cluster obtained via condensation of co-ordinatively unsaturated [Ru3(µ-H)(CO)9(µ-PPh2)] with [Ni2(η-C5H5)2(CO)2] (1986) (11)
- The first observation of 1J(Ru,P) in phosphorus-31 CP/MAS NMR spectra of solid ruthenium compounds (1993) (11)
- Coordination complexes of gallium(III) and indium(III) halides. VI. The structures of gallium(III) halide complexes with 1,10-phenanthroline (1970) (10)
- Phosphorus monoxide as a quadruply bridging ligand: syntheses and X-ray crystal structures of Ru5(CO)15(µ4-PF) and [H2NCy2][Ru5(CO)15(µ4-PO)] (1998) (10)
- Preparation of Pt–Ru Alloyed Thin Films Using a Single‐Source CVD Precursor (2003) (10)
- Carbonylation and amination of .mu.-.eta.2-acetylides in M2(CO)6(.mu.-.eta.2-C.tplbond.CPh)(PPh2): synthesis of .mu.-O:CCHC(Ph)NR2 complexes and the x-ray structure of Ru2(CO)6[.mu.-O:CCHC(Ph)NEt2](PPh2) (1983) (10)
- Tris(alkynyl)phosphines (RCC)3P as a source of functionalized phosphido and phosphinidene clusters: a complete triad of [M3(CO)9(µ3-η2-CCBut){µ2-P(CCBut)2}] complexes and the X-ray structure of a novel square-planar alkynylphosphinidene cluster [Ru4(CO)10(µ4-η4-ButCC-CCBut){µ4-P(CCBut)}] (1991) (10)
- Acetyleneiron tetracarbonyls: classical organometallic intermediates. synthesis and x-ray crystal structure of Fe2(CO)8(Ph2PC≡CBu-t) (1978) (10)
- Chemistry of .eta.2-CS2 complexes. Mononuclear iron compounds containing alkoxythiocarbonyl and chelating Ph2PCH:C(R)S ligands via coupling of coordinated CS2 and phosphinoacetylenes: x-ray structure of Fe(CO)[P(OMe)3][Ph2PCH:CCMe3S][CS(OMe)] (1982) (10)
- Tricarbonyl(4-7-.eta.-1(1H),2-diazepine)iron(0). Fluxional pathways (1976) (10)
- Novel behaviour of dialkylamino-substituted propargylic alcohols in reactions with arene ruthenium(II) complexes (1994) (10)
- Steric and Electronic Effects on the Stereochemistry and Molecular Structure of Nitrato Tris(diphenylmethylphosphine)Copper(I) (1971) (10)
- Synthesis, Characterization, and Reactivity Study of Triosmium Acetylide Cluster Complexes Bearing a (C5Me5)W(O)2 Fragment (1997) (10)
- Polynuclear acetylide chemistry: acetylide to acetylene transformation at a binuclear center via carbon-carbon and carbon-nitrogen bond-forming reactions. X-ray structure of Os2(CO)6[.mu.-.eta.2-.dblvert.-C[C(NHBu-tert)(NEt2)]CPh](.mu.-PPh2) (1990) (9)
- Electronic Structures of Transition Metal Phosphorus Monoxide Complexes (2000) (9)
- Synthesis and Structural Characterization of Two Tetraruthenium Bis(phosphinidene) Clusters with 62- and 64-Electron Counts: Ru4(CO)11(μ4-PPh)(μ4-PNPri2) and Ru4(CO)12(μ4-PNPri2)2 (1998) (9)
- Reactions of acetylenes held proximate to a metal. Addition of hydrogen chloride to cis-dichlorobis(3,3,3-trifluoropropynyldiphenylphosphine)palladium(II) and -platinum(II). The x-ray structure of trans-PdCl2[Ph2PCH:C(Cl)CF3]2 (1975) (9)
- Synthetic routes to butadienyl complexes. Double addition of methylene to an acetylide and hydrometallation of an ene–yne. X-Ray crystal structure of [Fe2(CO)5{µ-η2,η3-H2CC(Me)CCH2}(µ-PPh2)] (1991) (9)
- Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system (1970) (9)
- Precursors of quadruply bridging phosphorus monoxide ligands: synthesis and structural characterization of a new family of anionic fluoro and alkoxyphosphinidene clusters Ru5(CO)15(μ4-PR) (R = NiPr2, NCy2, F, OMe, OEt, OiPr): generation and structure of [H2NCy2][Ru5(CO)15(μ4-PO)] (2000) (9)
- Phosphorus Monoxide Coordination Chemistry (1997) (9)
- Binuclear metal carbonyls: molecular structure of .mu.-chloro-.mu.-(diphenylphosphido)-hexacarbonyldiiron(Fe-Fe) (1980) (9)
- Novel intramolecular rearrangements in a trinuclear iron complex derived from a phosphino acetylene (1974) (9)
- From butadiynyl (–CC–CCR) ligands to alkylidyne–carbides: synthesis and characterisation of the unusual hexanuclear ruthenium carbido clusters [Ru6(CO)13(µ-CO)2(µ-PPh2)(µ5-C)(µ3-C–CCR)](R = But, Ph) (1995) (9)
- Ru4(CO)10(CCHPri)(OH)(PPh2) : a tetranuclear ruthenium carbonyl cluster with µ4-vinylidene and face-bridging hydroxo-groups; X-ray crystal structures of Ru4(CO)10(CCHPri)(OR)(PPh2)(R = H or Et) (1981) (9)
- Halo- and carboxylato-bridged binuclear iron carbonyls (1979) (9)
- Synthesis, structure, bonding and reactivity in clusters of the lower phosphorus oxides (2002) (9)
- Chemistry of µ-η1: η2α,β-butadiynyls: chain extension on C4 polycarbon ligands (1995) (9)
- Triangular iron-silver clusters (1979) (9)
- Phosphido bridged iron carbonyl hydrides: synthesis and X-ray structure of (µ-H)2Fe3(CO)8(µ-PPh2)2 (1984) (8)
- A triad of stable, cationic, .mu.-hydrido, .mu.-alkylidene complexes, [(.mu.-H)M2(CO)6[.mu.-CHC(Ph)NEt2] (.mu.-PPh2)]X (M = Fe, Ru, Os; X = BF4, PF6) via the protonation of an alkylidene-bridged, electron-rich metal-metal bond (1987) (8)
- Chemistry on the rhomboidal Ru4 faces of the clusters RU4(CO)13(μ-PR2)2: Novel small molecule, ligand, and skeletal transformations (1992) (8)
- New electron rich Ru3P4 and Ru4P3 phosphido clusters: synthesis and molecular structures of the expanded triangular and butterfly clusters (μ-H)Ru3(CO)6(μ-PPh2)3[μ-P(Ph)C6H4] and (μ-H)2Ru4(CO)10(μ3-PPh)(μPPh2)2 (1993) (8)
- Hydroxyphosphinidene complexes. Novel organometallic cluster acids and precursors of coordinated phosphorus monoxide (1997) (8)
- The first heptaruthenium cluster: X-ray crystal structure of Ru7(CO)18(µ4-PPh)2, a molecule consisting of fused square pyramidal polyhedra (1987) (8)
- Phospido-bridged mixed metal complexes. Reaction of (CO)4Ru(μ-PPh2)Co(CO)3 with bis(diphenylphosphino)methane (dppm): Synthesis and crystal structures of heterobimetallic (RuCo) compounds with chelating and bridging dppm ligands (1987) (8)
- EXPANDED ELECTRON RICH POLYPHOSPHIDO CLUSTERS : A CLASS OF POLYNUCLEAR MOLECULES WITH UNUSUAL ELECTRONIC, MOLECULAR STRUCTURES AND REACTIVITY (1994) (8)
- Unusual phosphinoacetylene–iron carbonyl complex: synthesis and X-ray structure of [Fe3(CO)7{Ph2PC(CO2Me)C(CF3)C2(CF3)}(PPh2)]2C6H6 (1974) (8)
- 1160. Co-ordination compounds of indium. Part I. Some cationic complexes of indium(III) (1964) (8)
- Conversion of a .mu.-.eta.2-acetylide to a .mu.-.eta.2-.dblvert.-acetylene via successive nucleophilic additions. X-ray structure of Os2(CO)6[.mu.-.eta.2-C{C(NH-tert-Bu)(S-n-Bu)}CPh](.mu.-PPh2) (1987) (8)
- Oxide bridged mixed metal organometallics: the reaction of Ru4(CO)13[μ3-PN(R)2] R=iPr, Cy with Cp*W(O)2CCPh (1999) (7)
- Site selectivity in substitution reactions of heterobinuclear (CO)4Ru(.mu.-PPh2)Co(CO)3(Ru-Co): synthesis and characterization of terminal anionic hydrido and halo complexes [Et4N][(X)(CO)3Ru(.mu.-PPh2)Co(CO)3]. X-ray structure of [Et4N][(H)(CO)3Ru(.mu.-PPh2)Co(CO)3] (1989) (7)
- Synthesis and transformations of 60-, 62-, and 64-electron Co4(CO)x(PNR2)2 (x = 8, 9, 10) clusters (2004) (7)
- Synthesis and crystal structure of an unusal trinuclear ferracyclobutene complex, Fe3(CO)8[Ph2PC4(CF3)2](PPh2) (1974) (7)
- Synthesis, Structural, and Theoretical Analysis of Ru4(CO)12(μ-PF2)(μ4-P): Is the μ4-P Atom a Three-Electron or a Five-Electron Donor? (2001) (7)
- The formation of mixed metal aminophosphinidene clusters via reactions of terminal chloroaminophosphido complexes with Co2(CO)8 (2003) (7)
- Binuclear iron carbonyl complexes with 1,3-dipoles as bridging one-carbon, three-electron ligands; X-ray structure of [Fe2(CO)6{CH·C(Ph):NEt2}(PPh2)]·C6H6 (1976) (7)
- .pi. Complexes of nitrogen heterocycles. Molecular structure of tricarbonyl(.eta.4-1(1H),2(2H)-diazepinium)iron trifluoroacetate, a fluxional molecule from the protonation of tricarbonyl(.eta.4-1(1H),2-diazepine)iron (1976) (7)
- Steric effects in a distorted square planar bis-(2,2′-bipyridyl) metal complex: X-ray crystal structure of aquobis-(2,2′-bipyridyl)palladium(II) nitrate (1972) (7)
- [Ru4(CO)10(µ-CO)(µ4-PPh)(µ4-η2-PhNNPh)]: the first example of an azobenzene molecule coordinated on a square metal face (1991) (7)
- Synthesis and X-ray structure of Fe2 (CO)6[P(C6F5)2][(C6F5)2PC4(C6H5)2]: A new type of organoiron complex containing a 3-electron donor phosphorus heterocycle (1975) (7)
- Two Tetracobalt Cluster Complexes: Preparation and Molecular Structures of Co4(μ-dppm)2(μ-CO)3(CO)5 and CO4(μ-CO)3(CO)6(η-C6H6) (2001) (6)
- The First Metal Cluster Containing a P2O Ligand: (CO)13Ru4(μ6,η2-P2O)Ru4(CO)13 (1997) (6)
- A Study of Unsaturated Pyrazolate-Bridged Diruthenium Carbonyl Complexes (2002) (6)
- Relative sign determination of phosphorus-carbon coupling constants by 2D carbon-13 NMR spectroscopy (1989) (6)
- 14 N–31P, 15N–15P, and 31P–31P coupling constants from the 31P nuclear magnetic resonance spectra of square planar platinum(II) and palladium(II) thiocyanate complexes (1975) (6)
- Cluster Compounds Bearing both High- and Low-Valent Transition Metal Fragments: The Reactions of Imido Carbonyl Cluster Ru3(CO)10(μ3-NPh) with Dioxo Acetylide Complexes (C5Me5)W(O)2(CCR), R = Ph and CMeCH2 (1998) (6)
- In It to WIN It (2010) (6)
- Models for the methylmercury–protein interaction: a comparison of the molecular structures of methyl-L-cysteinatomercury(II) and methyl-DL-methioninemercury(II) (1974) (6)
- Transformation of mu4-phosphinidenes at an Ru5 center: isolation and structural characterization of hydroxyphosphinidene cluster acids, fluorophosphinidenes, and a novel mu5-phosphide. (2005) (6)
- Reflections on science advisory systems in Canada (2016) (6)
- Neutral and cationic (.eta.2-dithioalkyl ester)iron(II) complexes. Synthesis, spectroscopic studies, and x-ray structure of [Fe(.eta.2-CS2CH2Ph)(CO)2(PMe3)2]PF6 (1981) (6)
- Reactions of µ-η2-allenyl complexes: coupling of diphenylacetylene with Ru2(CO)6-[µ-σ,η2-PhCCCH2](µ-PPh2) and the X-ray crystal structure of a novel tetranuclear cyclopentadienyl complex [Ru2(CO)4{µ-σ(C,O),η7-C5MePh2(C6H4)(O)}(µ-PPh2)]2·2C7H8 (1988) (6)
- Heterobimetallic (RuCo) complexes with chelating and bridging Ph2PCH2PPh2 (dppm) ligands (1986) (6)
- Cluster bound phosphinovinylidenes and phosphinitovinylidenes from alkynilphosphines and their oxides: synthesis and structures of [Ru3(CO)9{μ3-σ,σ,η3-CPh2)}] and [Fe3(CO)9{μ3-σ,σ,η3-C)}] (1988) (6)
- CARBON-CARBON BOND FORMATION VIA COUPLING OF ISONITRILES WITH μ2-η2-ACETYLIDES (1981) (6)
- Crystal structure of (DL-methioninato)methylmercury(II) (1977) (6)
- The interconversion of quasi-planar butterfly and tetrahedral tetraruthenium cluster geometries: X-ray crystal structure of tetrahedral [H2ru4(CO)10(µ-PPh2)2] (1990) (6)
- SYNTHESIS AND STRUCTURE OF PI-PHOSPHINOACETYLENE COMPLEXES OF ZEROVALENT PALLADIUM AND PLATINUM (1974) (5)
- Dicarbonylbis(η5‐Cyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium (2007) (5)
- Oxide bridged early–late metal organometallics: thesynthesis of complexes with W–O–Ru W–O–P bridges fn2 fn2 Dedicated to the Lord Jack Lewis on the occasionof his 70th birthday. (1998) (5)
- Reaction of a diazepine with chlorodicarbonylrhodium(I) dimer; the molecular structure of chloro-cis-dicarbonyl-(3,5,7-triphenyl-4H-1,2-diazepine)rhodium(I) (1971) (5)
- Crystal and molecular structure of chloro[1-(diphenylphosphino)-3,3,3-trifluoropropen-2-olato](ethoxydiphenylphosphine)palladium(II)–dichloromethane (1976) (5)
- Preparation and crystal structure of a novel hydroxo-bridged gallium complex [Ga2(OH)2Cl2(C14H17N3)2]Cl2,H2O (1972) (5)
- Differentiating metal sites in homopolynuclear systems via incorporation of π-donors: Complexes of bridging phosphidoxo (Ph2P)O) ligands (1988) (5)
- Effect of ruthenium cluster on the photoluminescence of chemically derivatized porous silicon (2003) (5)
- Synthesis of 62-electron square planar clusters with group 15 and 16 main group atoms: Structural characterization of Ru4(CO)11(μ4-PPh)(μ4-S) and Ru4(CO)10(μ4-PPh)(μ4-Se)(PEt3): Bonding preferences in cappingNido Ru4(CO)13(μ3-PPh) (1991) (5)
- Novel cleavage of phosphinoacetylene by palladium(II) and platinum(II): preparation and structure of complexes of 1,3-bis(diphenylphosphino)-2-tri-fluoromethylpropene derived from 3,3,3-trifluoropropynyldiphenylphosphine (1973) (5)
- Bonding mode of thiocyanate in palladium(II) phosphite complexes: X-ray structure of trans-dithiocyanatobis(triphenyl phosphite)palladium(II) (1974) (5)
- Carbon-13 NMR shifts of bridging hydrocarbyls derived from the addition of nucleophiles to complexed organic ligands in DI- and polynuclear complexes (1992) (5)
- Stereospecific, transition metal-mediated synthesis of unsymmetrical cis olefinic diphosphines (1978) (4)
- REVERSIBLE COORDINATION OF THE HIGH OXIDATION STATE DIOXO-ACETYLIDE FRAGMENT (C5ME5)W(O)2(CCPH) TO A HEXARUTHENIUM CLUSTER FRAME (1998) (4)
- CHEMISTRY OF MULTISITE-BOUND LIGANDS. ADDITION OF AMINES TO .mu±eta.2-ACETYLIDES: DIPOLAR, ELECTRON-RICH .mu±eta.1- AND .mu±eta.2-ALKYLIDENE AND .mu±eta.1-VINYLIDENE DIIRON HEXACARBONYL COMPLEXES (1983) (4)
- The synthesis and reactivity of a mixed nitrosyl- phosphinidene cluster of ruthenium: Formation of nitride and nitrene clusters (2002) (4)
- Nucleophilic attack on co-ordinated phosphinoacetylenes: products from the hydrolysis of cis-PdCl2(Ph2PCCCF3)2 and the X-ray structure of a 1-diphenylphosphino-3,3,3-trifluoropropen-2-olato complex (1974) (4)
- Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of ruthenium. (2002) (4)
- N,O- and S,O-bonded Hg(II) complexes with S-substituted amino acids: synthesis and crystal structures of bis(S-methyl-L-cysteinato)mercury(II) and bis(D,L-ethioninato)-mercury(II) diperchlorate (1981) (4)
- Synthesis and skeletal isomerization of the phosphinidene acetylide cluster complexes [Ru4(CO)10(µ4-PPh)(CCPh){WL(CO)}] where L = C5Me5 or C5H5 (1998) (4)
- Base-induced coupling of acetylenes held proximate to a metal: structures of unsymmetrical diphosphine complexes of platinum(II) containing strong vinyl alcohol–amine hydrogen bonds (1976) (4)
- Evidence for metal–phosphorus dπ–dπ bonding from ν(CC) Raman shifts in complexes of bis(diphenylphosphino)acetylene (1968) (4)
- η2-Alkoxythiocarbonyl and chelating Ph2PCHC(R)S-ligands via intramolecular coupling of co-ordinated CS2 and Ph2PCCR; X-ray crystal structure of Fe(CO)[P(OMe)3][Ph2PCHC(But)S][CS(OMe)] (1980) (4)
- Stereochemistry of Metal Complexes: Phosphido Bridging Ligands (1988) (4)
- Facile oxidative addition of diphenylphosphine to the pentanuclear cluster Ru5(CO)13(µ4-η2-C2Ph)(µ-PPh2) without CO loss: X-ray crystal structure of the 78-electron complex (µ-H)Ru5(CO)13(µ4-η2-C2Ph)(µ-PPh2)2 (1986) (4)
- Poly-carbon chemistry: reactions of the multi-sitecoordinated diyndiyl ligand in{Fe2(CO)6(μ-PPh2)}2(μ-η1,η2∶μ-η1,η2-CC–CC) with the nucleophilesP(OMe)3 and NHEt2 (2001) (3)
- SILYLMETHYL AND RELATED COMPLEXES. 7. BULKY, MONOMERIC, HEAVY GROUP III METAL L TRIALKYLS AND THE CRYSTAL AND MOLECULAR STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)METHYL)INDIUM (1981) (3)
- Binding of methylmercury by amino-acids: X-ray structure of DL-penicillaminatomethylmercury(II) (1973) (3)
- The Synthesis and Reactivity of New μ2- and μ3-Aminophosphinidene Cobalt Complexes (2004) (3)
- BisTert‐Butylphosphido (T‐Bup(H)‐) Bridged Dimers of Rhodium(+1) and Nickel(+1) Containing Rh=Rh Double and Ni—Ni Single Bonds (2007) (2)
- Chemistry of polynuclear allenyl complexes: The μ-η1 : η2-allenyl diruthenium system Ru2(CO)6(μ-PPh2)(μ-η1 :η2-C(Ph)CCH2). Dimetallocycles via CC, CN and CS bond forming reactions and the X-ray structure of Ru2(CO)6(μ-PPh2)[μ-η1 : η1-PhCC{C(EtS)N(H)tBu}CH2] (1994) (2)
- STABILIZATION OF THE cis CONFIGURATION OF DIHALO BIS(TERTIARY PHOSPHINE) PALLADIUM(II) COMPLEXES BY PHOSPHINOACETYLENES (1973) (2)
- Clusters containing metal–metal bonds linking high- and low-valent metal centres: synthesis and structure of Ru3(CO)12{Mo(NAr)2} (2000) (2)
- Reactivity of photophido-bridged heterobinculear complexes: site-selective carbonyl substitution by a hydride. Synthesis and structural characterisation of NEt4[H(CO)3Ru(µ-PPh2)Co(CO)3] (1984) (2)
- The Mössbauer Parameters in Tin(IV) and Europium(III) Compounds (1971) (2)
- The Interaction of Organomercury Pollutants with Biologically Important Sites: An X-ray study of the 2:1 Complex between Methylmercury and Penicillamine (1973) (2)
- Homometallic and Heterometallic Transition‐Metal Allenyl Complexes: Synthesis, Structure, and Reactivity (1995) (2)
- Novel P–O bond forming reactions via coupling of phosphinidene and phosphidoxo groups on a tetranuclear ruthenium cluster: face capping Ph2POPR ligands and the X-ray structure of Ru4(CO)8(µ-CO)(µ3-η2-CCBut)[µ3-η2-PPh2(OPPh)] (1994) (1)
- Reaction of the Hexa-1,3,5-triyne Me3SiC≡CC≡CC≡CSiMe3 with Ru4(CO)13(μ3-PPh): Parallels with the Chemistry of Alkynes and Diynes (2004) (1)
- PLATINUM CLUSTER COMPOUNDS, X-RAY STRUCTURES OF PHOSPHIDO-BRIDGED BI- AND TRINUCLEAR COMPLEXES WITH STRONG METAL-METAL BONDS DERIVED FROM (PT(PPH3)4) (1975) (1)
- The n.m.r. spectra of substituted diphosphines and their derivatives. Deceptively simple spectra (1967) (1)
- Research spotlight: Bionanotechnology: small can have a big impact in the medical sciences: a WIN-win situation. Part 1. (2010) (1)
- Bionanotechnology: small can have a big impact in the medical sciences: a WIN-win situation. Part 2. (2010) (1)
- Remarkable two-step, four-electron oxidative addition reactions at phosphorus [P(I)–P(V)] in terminal electrophilic phosphinidene complexes (2007) (1)
- A Phosphino Bridged Ruthenium Cluster: Nonacarbonyl‐μ‐Hydrido‐(μ‐Diphenylphosphino)Triruthenium(0) (2007) (1)
- Co-Funding in Canada: Another View (2005) (1)
- SYNTHESIS AND CHARACTERIZATION OF DI‐MU‐THIOCYANATO‐BIS(HYDROGEN BIS(DIPHENYLPHOSPHINATO))DIPALLADIUM(II). A COMPLEX CONTAINING A NOVEL SYMMETRICALLY HYDROGEN‐BONDED ANION (1974) (0)
- NOVEL INTRAMOLECULAR REARRANGEMENTS IN A TRINUCLEAR IRON KOMPLEX DERIVED FROM A PHOSPHINOACETYLENE (1974) (0)
- Chemistry on the Rhomboidal Tetraatomic Ruthenium Faces of the Clusters Ru4(CO)13(μ-Pr2)2: Novel Small Molecule, Ligand, and Skeletal Transformations (1993) (0)
- Π COMPLEXES OF NITROGEN HETEROCYCLES. MOLECULAR STRUCTURE OF TRICARBONYL(η4-1(1H),2(2H)-DIAZEPINIUM)IRON TRIFLUOROACETATE, A FLUXIONAL MOLECULE FROM THE PROTONATION OF TRICARBONYL(η4-1(1H),2-DIAZEPINE)IRON (1976) (0)
- CRYSTAL AND MOLECULAR STRUCTURE OF CHLORO(1-(DIPHENYLPHOSPHINO)-3,3,3-TRIFLUOROPROPEN-2-OLATO)(ETHOXYDIPHENYLPHOSPHINE)PALLADIUM(II)-DICHLOROMETHANE (1976) (0)
- COORDINATION COMPLEXES OF ACETYLENIC PHOSPHINES AND DIPHOSPHINES PART 6, CARBONYL- AND PI-CYCLOPENTADIENYL-NICKEL DERIVATIVES OF 3,3,3-TRIMETHYLPROPYNYLDIPHENYLPHOSPHINE AND PHENYLETHYNYLDIPHENYLPHOSPHINE (1974) (0)
- CARBON-CARBON BOND-MAKING BY TRAPPING OF A NUCLEOPHILIC CARBENE (FROM AN ELECTRON-RICH OLEFIN) BY A .SIGMA±PI.-ACETYLIDO(HEXACARBONYL)DI-IRON COMPLEX; X-RAY CRYSTAL AND MOLECULAR STRUCTURE (1979) (0)
- NUCLEOPHILIC ATTACK ON CO‐ORDINATED PHOSPHINO‐ACETYLENES, PRODUCTS FROM THE HYDROLYSIS OF CIS‐PDCL2(PH2PC‐CCF3)2 AND THE X‐RAY STRUCTURE OF A 1‐DIPHENYLPHOSPHINO‐3,3,3‐TRIFLUOROPROPEN‐2‐OLATO COMPLEX (1974) (0)
- SIGMA,PI-ACETYLIDO COMPLEXES VIA P-C BOND CLEAVAGE OF PHOSPHINOACETYLENES, X-RAY STRUCTURE OF FE2(CO)6(C-C-C6H5)(P(C6H5)2) (1974) (0)
- SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL TRINUCLEAR FERRACYCLOBUTENE COMPLEX, FE3(CO)8((C6H5)2PC4(CF3)2)(P(C6H5)2) (1974) (0)
- POLYCARBON LIGAND CHEMISTRY. NOVEL BEHAVIOUR OF MU -ETA 1,ETA 2ALPHA ,BETA-BUTADIYNYLS TOWARDS METAL FRAGMENT ADDITIONS (1997) (0)
- Metallocene Derivatives of Early Transition Elements. Part 4. Synthesis and Crystal Structures of a Series of Zirconocene(IV) Halides (Zr(η-C5H4SiMe3)2X2) (X: Cl or Br) and (Zr(η-C5H3(SiMe3)2-1,3)2X2) (X: F, Br, or I). (1987) (0)
- RU5(CO)13(CCPH)(PPH2): A SQUARE PYRAMIDAL RUTHENIUM CLUSTER WITH A SINGLE μ4-BOUND ACETYLIDE (1981) (0)
- Iron: Synthesis and Spectroscopic Properties. X-ray Crystal Structure of ( q2-Carbon disulfide)dicarbonyl( trimethylphosphine) (triphenylphosphine)iron( 0) (1978) (0)
- Cluster Compounds Bearing both High-and Low-Valent Transition Metal Fragments : The Reactions of Imido Carbonyl Cluster Ru 3 ( CO ) 10 ( μ 3-NPh ) with Dioxo Acetylide (1998) (0)
- RU5(CO)16(μ-PPH2)(μ5-P): A LOW-NUCLEARITY CLUSTER WITH A PARTIALLY ENCAPSULATED PHOSPHIDE (1983) (0)
- MULTISITE-BOUND VINYLIDENES ON HETEROMETALLIC CLUSTERS. REFORMULATION OF (η5-C5H5NI)RU3(CO)9(μ4-η2-C:CHR) (R = TERT-BU) AS HYDRIDO-BRIDGED (μ-H)(η5-C5H5NI)RU3(CO)9(μ4-η2-C:CHR). MOLECULAR STRUCTURE OF THE ISOPROPYL DERIVATIVE (R = ISO (1983) (0)
- Chemistry of Multisite-Bound Ligands: Crystal and Molecular Structure of HRu3(CO)8- (CC-t-Bu)(PPh2OEt) (Raumgruppe P1, Z=2). (1982) (0)
- UNUSUAL PHOSPHINOACETYLENE-IRON CARBONYL COMPLEX, SYNTHESIS AND X-RAY STRUCTURE OF (FE3(CO)7(PH2PC(CO2ME)C(CF3)C2(CF3))(PPH2))2C6H6 (1975) (0)
- BASE-INDUCED COUPLING OF ACETYLENES HELD PROXIMATE TO A METAL- STRUCTURES OF UNSYMMETRICAL DIPHOSPHINE COMPLEXES OF PLATINUM(II) CONTAINING STRONG VINYL ALCOHOL-AMINE HYDROGEN BONDS (1976) (0)
- Self-Reducible CuII Source Reagents for the CVD of Copper. (2001) (0)
- Erratum: Reflections on science advisory systems in Canada (2016) (0)
- SYNTHESIS AND STRUCTURE OF PI-ACETYLENE COMPLEXES OF ZERO-VALENT IRON AND NICKEL, SYM-DI-MU-PHENYLDIPHENYLPHOSPHINOACETYLENE-BIS-(TRICARBONYLIRON(0)) AND SYM-DI-MU-T-BUTYLDIPHENYLPHOSPHINOACETYLENE-BIS-(CARBONYLNICKEL(0)) (1974) (0)
- Polycarbon ligands: synthesis and characterization of the phosphinodiynes Ph2PC=CmC=CR (R = But, Ph, SiMe,), the -butadiynyl complexes Ru,(CO),- (1996) (0)
- Nucleophilic Attack at Carbon in σ,π-Acetylides. Bridging One Carbon and Two Carbon Iminium Ion Complexes via Addition of Cyclohexylamine to [Fe2(CO)6 · (C2Ph)(PPh2)]. X-Ray Structures of [Fe2(CO)6(CHC(NHC5H11-c)(Ph))PPh2) and [Fe2(CO (1978) (0)
- SUBVALENT GROUP 4A METAL ALKYLS (1978) (0)
- IRON TRICARBONYL COMPLEXES OF 1(1H), 2-DIAZEPINE AND METHYL SUBSTITUTED DERIVATIVES. NOVEL FLUXIONAL ORGANOMETALLIC COMPOUNDS (1973) (0)
- SYNTHESIS AND CRYSTAL STRUCTURE ANALYSIS OF BIS(η5-CYCLOPENTADIENYL)-μ-(TRIFLUOROMETHYL(OXODIPHENYLPHOSPHINO)ACETYLE# NE)-DINICKEL(0) (1977) (0)
- SYNTHESIS OF FE4(CO)8(MU -PPH2)2(MU 4-ETA 1,ETA 1,ETA 2,ETA 2-C2PH)2 VIA COUPLING OF ACETYLIDES AT A BINUCLEAR CENTRE : A MOLECULE WITH THROUGH-THE-CL USTER CARBON-CARBON BONDING? (1997) (0)
- ACETYLENEIRON TETRACARBONYLS- CLASSICAL ORGANOMETALLIC INTERMEDIATES. SYNTHESIS AND X-RAY CRYSTAL STRUCTURE OF OCTACARBONYL(TERT-BUTYLETHYNYLDIPHENYLPHOSPHINE)DIIRON (1978) (0)
- COMPARISON OF THE MOLECULAR STRUCTURES OF TRANS-DI(ISOTHIOCYANATO)BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II) AND TRANS-DI(THIOCYANATO)BIS-(TRIPHENYL PHOSPHITE)PALLADIUM(II) (1976) (0)
- The First Heptaruthenium Cluster: X-Ray Crystal Structure of Ru7(CO)18(μ4-PPh)2, a Molecule Consisting of Fused Square Pyramidal Polyhedra. (1988) (0)
- SYNTHESIS AND X-RAY STRUCTURE OF FE2(CO)6(P(C6F5)2)((C6F5)2PC4(C6H5)2), A NEW TYPE OF ORGANOIRON COMPLEX CONTAINING A 3-ELECTRON DONOR PHOSPHORUS HETEROCYCLE (1975) (0)
- CHEMISTRY OF MU -ETA 1:ETA 2ALPHA ,BETA -BUTADIYNYLS : CHAIN EXTENSION ON C4 POLYCARBON LIGANDS (1995) (0)
- Reactivity of electrophilic micro-phosphinidene complexes with heterocumulenes: formation of the first sigma-pi-aminophosphaimine complexes [Mn2(CO)8{micro-eta1,eta2-P(NiPr2)=NR}] and diazoalkane insertions into metal-phosphorus bonds. (2005) (0)
- Comparative chemistry of - ? 1 : ? 2-allenyl and - ? 1 : ? 2-acetylide complexes: ? 5-cyclopentadi (1996) (0)
- TWO-CARBON THREE-ELECTRON LIGANDS, PHOSPHONIUM-BETAINE COMPLEXES VIA NUCLEOPHILIC ATTACK BY PHOSPHITES ON A SIGMA-PI-ACETYLIDE DI-IRON HEXACARBONYL DERIVATIVE (1975) (0)
- TRICARBONYL(4-7-η-1(1H),2-DIAZEPINE)IRON(0). FLUXIONAL PATHWAYS (1976) (0)
- RUTHENIUM METALLOPHOSPHORUS CLUSTERS: RU5(CO)12(μ4-PPH)(μ3-CCH2CHME2)(μ2-PPH2) AND HRU5(CO)10(μ4-PPH)2(μ3-PPH)(μ2-PPH2), FACE-CAPPED-OCTAHEDRAL AND PENTAGONAL-BIPYRAMIDAL CLUSTERS VIA STEPWISE REDUCTION OF AN ACETYLIDE (1984) (0)
- Synthesis, 31P Shift Correlated Two-Dimensional (COSY) Nuclear Magnetic Resonance Spectra, and Structure of the Tris(trimethyl phosphite)-Substituted Phosphido-Bridged Heteronuclear Dimer ((MeO)3P)2(CO)2Ru(μ-PPh2)Co(CO)2(P(OMe)3). (1987) (0)
- NOVEL CLEAVAGE OF A PHOSPHINOACETYLENE BY PALLADIUM(II) AND PLATINUM(II), PREPARATION AND STRUCTURE OF COMPLEXES OF 1,3‐BIS‐(DIPHENYLPHOSPHINO)‐2‐TRI‐FLUOROMETHYLPROPENE DERIVED FROM 3,3,3‐TRIFLUOROPROPYNYLDIPHENYLPHOSPHINE (1973) (0)
- NRC a Model for Bottom-Up Approach to Innovation (1997) (0)
- Fundamental Studies on 31P Relaxation Mechanisms: The Importance of Chemical Shift Anisotropy and Its Implications for 31P NMR Studies of Organometallic Compounds. (1989) (0)
- Encapsulated Phosphides: Ru8(CO)21(μ6‐P)(μ4‐PPh)(μ2‐PPh2), a Molecule with a Six‐Coordinate Phosphorus Atom in a Condensed Cluster. (1989) (0)
- Crystal Structure of (Ni2Ru3(η-C5H5)2(CO)9(μ5-PPh)), an Open Square-Pyramidal Cluster Obtained via Condensation of Coordinatively Unsaturated (Ru3(μ-H)(CO)9(μ-PPh2)) with (Ni2(η-C5H5)(CO)2). (1987) (0)
- REACTIONS OF ACETYLENES HELD PROXIMATE TO A METAL. ADDITION OF HYDROGEN CHLORIDE TO CIS-DICHLOROBIS(3,3,3-TRIFLUOROPROPYNYLDIPHENYLPHOSPHINE)PALLADIUM(II) AND -PLATINUM(II). THE X-RAY STRUCTURE OF TRANS-PDCL2(PH2PCH-C(CL)CF3)2 (1976) (0)
- X-RAY CRYSTALLOGRAPHIC AND SPECTROSCOPIC STUDIES OF THE BINDING OF METHYLMERCURY BY THE SULFUR AMINO-ACID DL-PENICILLAMINE- MODELS FOR METHYLMERCURY POISONING OF PROTEINS (1978) (0)
- MIXED THIOCYANATE COMPLEXES OF PLATINUM(II), CRYSTAL STRUCTURE OF CIS-THIOCYANATOISOTHIOCYANATOBIS(3,3-DIMETHYLBUTYRYLDIPHENYLPHOSPHINE)PLATINUM(II) (2002) (0)
- Differentiating Metal Sites in Homopolynuclear Systems via Incorporation of π-Donors: Complexes of Bridging Phosphidoxo (Ph2P=O) Ligands (1989) (0)
- A Canadian Vision of International Astronomy and Astrophysics (2003) (0)
- REDUCTION OF AN ACETYLIDE CCR TO AN IMINOETHYL GROUP CH2C(R):NR′ IN A BINUCLEAR IRON COMPLEX VIA HYDROGEN MIGRATION FROM NITROGEN TO CARBON: X-RAY STRUCTURE OF FE2(CO)6(CH2C(PH)NME)(PPH2) (1980) (0)
- Conversion of a .mu±eta.2-Acetylide to a .mu±eta.2-||-Acetylene via Successive Nucleophilic Additions. X-Ray Structure of Os2(CO)6(.mu±eta.2-C(C(NH-t-Bu)(S-n-Bu))-CPh)(μ-PPh2). (1988) (0)
- CHEMISTRY OF η2-CS2 - METAL COMPLEXES: SYNTHESIS OF DITHIOLENE COMPLEXES OF IRON VIA ACETYLENE ADDITIONS TO FE(η2-CS2)(CO)2(PR3)2. X-RAY STRUCTURE OF FE(S2C(COME)C(C6H4NO2))(CO)(P(OME)3)2 (1982) (0)
- PERCHLORATO, NITRATO, AND ACETYLACETONATO COMPLEXES OF COPPER(I), THE CRYSTAL AND MOLECULAR STRUCTURE OF PERCHLORATOBIS(TRICYCLOHEXYLPHOSPHINE)COPPER(I) (1975) (0)
- BINUCLEAR IRON CARBONYL COMPLEXES WITH 1,3-DIPOLES AS BRIDGING ONE-CARBON, THREE-ELECTRON LIGANDS, X-RAY STRUCTURE OF (FE2(CO)6(CH.C(PH)-NET2)(PPH2)).C6H6 (1976) (0)
- Reversible Formation of (μ‐H)Ru4(CO)10(μ‐PPh2)(μ4‐η1(P),. eta.1(P),η1(P),η1,η2‐(C6H4)PPh) from the Electron‐Rich Cluster Ru4(CO)13(μ‐PPh2)2: The First Example of a Molecule with a Five‐Coordinate Bis(aryl)phosphido Bridge (1993) (0)
- Novel Phosphido-Bridged Cations (M2(CO)8(μ-PPh2))BF4 (M: Fe, Ru): Synthesis, Reactivity, and X-Ray Structure of an Isoelectronic and Structural Analogue of Ru2(CO)9. (1991) (0)
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