Eric Block
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American chemist
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Chemistry
Eric Block's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Eric Block Influential?
(Suggest an Edit or Addition)According to Wikipedia, Eric Block is an American chemist whose research has focused on the chemistry of organosulfur and organoselenium compounds, Allium chemistry , and the chemistry of olfaction. As of 2018, he is Distinguished Professor of Chemistry Emeritus at the University at Albany, SUNY.
Eric Block's Published Works
Published Works
- The chemistry of garlic and onions. (1985) (968)
- The Organosulfur Chemistry of the Genus Allium – Implications for the Organic Chemistry of Sulfur (1992) (900)
- Encoding social signals in the mouse main olfactory bulb (2005) (389)
- Chemical speciation influences comparative activity of selenium-enriched garlic and yeast in mammary cancer prevention. (2000) (295)
- The chemistry of alkyl thiosulfinate esters. 9. Antithrombotic organosulfur compounds from garlic: structural, mechanistic, and synthetic studies (1986) (273)
- Garlic and Other Alliums: The Lore and the Science (2009) (253)
- Allium chemistry: HPLC analysis of thiosulfinates from onion, garlic, wild garlic (ramsoms), leek, scallion, shallot, elephant (great-headed) garlic, chive, and Chinese chive. Uniquely high allyl to methyl ratios in some garlic samples (1992) (244)
- The chemistry of alkyl thiosulfate esters. 8. (E,Z)-Ajoene: a potent antithrombotic agent from garlic (1984) (220)
- Selenium speciation in enriched and natural samples by HPLC-ICP-MS and HPLC-ESI-MS with perfluorinated carboxylic acid ion-pairing agents. (2000) (214)
- Reactions of organosulfur compounds (1978) (210)
- Effect of raw garlic vs commercial garlic supplements on plasma lipid concentrations in adults with moderate hypercholesterolemia: a randomized clinical trial. (2007) (177)
- Allium Chemistry: Identification of Selenoamino Acids in Ordinary and Selenium-Enriched Garlic, Onion, and Broccoli Using Gas Chromatography with Atomic Emission Detection (1995) (154)
- Speciation of selenoamino acids and organoselenium compounds in selenium-enriched yeast using high-performance liquid chromatography-inductively coupled plasma mass spectrometry (1997) (135)
- High-performance liquid chromatography of selenium compounds utilizing perfluorinated carboxylic acid ion-pairing agents and inductively coupled plasma and electrospray ionization mass spectrometric detection. (2000) (127)
- Characterization of the biological activity of gamma-glutamyl-Se-methylselenocysteine: a novel, naturally occurring anticancer agent from garlic. (2001) (123)
- Allium chemistry: GC-MS analysis of thiosulfinates and related compounds from onion, leek, scallion, shallot, chive, and Chinese chive (1992) (123)
- o-lithiothiophenol equivalents: Generation, reactions, and applications in synthesis of hindered thiolate ligands (1989) (122)
- 2-phosphino- and 2-phosphinylbenzenethiols: new ligand types (1989) (112)
- 1-Butyryl-Glycerol: A novel angiogenesis factor secreted by differentiating adipocytes (1990) (112)
- Applications of direct analysis in real time mass spectrometry (DART-MS) in Allium chemistry. 2-propenesulfenic and 2-propenesulfinic acids, diallyl trisulfane S-oxide, and other reactive sulfur compounds from crushed garlic and other Alliums. (2010) (108)
- High-performance liquid chromatography of selenoamino acids and organo selenium compounds. Speciation by inductively coupled plasma mass spectrometry. (1997) (103)
- Identification of the principal selenium compounds in selenium-enriched natural sample extracts by ion-pair liquid chromatography with inductively coupled plasma- and electrospray ionization-mass spectrometric detection (1999) (100)
- Crucial role of copper in detection of metal-coordinating odorants (2012) (98)
- Lipoxygenase inhibitors from the essential oil of garlic. Markovnikov addition of the allyldithio radical to olefins (1988) (93)
- .alpha.-Haloalkanesulfonyl bromides in organic synthesis. 5. Versatile reagents for the synthesis of conjugated polyenes, enones, and 1,3-oxathiole 1,1-dioxides (1986) (87)
- Chemistry of alkyl thiosulfinate esters. VI. Preparation and spectral studies (1974) (83)
- Chemistry of alkyl thiosulfinate esters. VII. Mechanistic studies and synthetic applications (1974) (81)
- Applications of direct analysis in real time-mass spectrometry (DART-MS) in Allium chemistry. (Z)-butanethial S-oxide and 1-butenyl thiosulfinates and their S-(E)-1-butenylcysteine S-oxide precursor from Allium siculum. (2010) (79)
- Inhibition of soybean lipoxygenase and mouse skin tumor promotion by onion and garlic components. (1989) (74)
- Implausibility of the vibrational theory of olfaction (2015) (73)
- Organosulfur chemistry of garlic and onion: Recent results (1993) (72)
- Allium Chemistry: Supercritical Fluid Extraction and LC−APCI−MS of Thiosulfinates and Related Compounds from Homogenates of Garlic, Onion, and Ramp. Identification in Garlic and Ramp and Synthesis of 1-Propanesulfinothioic Acid S-Allyl Ester (1997) (72)
- Allium Chemistry: Synthesis and Sigmatropic Rearrangements of Alk(en)yl 1-Propenyl Disulfide S-Oxides from Cut Onion and Garlic1 (1996) (71)
- The chemistry of mixed organosulfur-silicon compounds (1988) (71)
- Coordination chemistry of sterically hindered thiolate ligands. Preparation and structural characterization of the oligomeric homoleptic complexes [o-trimethylsilylbenzenethiolato]copper dodecamer and [o-trimethylsilylbenzenethiolato]silver octamer and a comparison to the structure of the cadmium mo (1989) (71)
- Garlic and Other Alliums (2010) (71)
- Analytical selenoamino acid studies by chromatography with interfaced atomic mass spectrometry and atomic emission spectral detection (1998) (70)
- Allium chemistry: synthesis, natural occurrence, biological activity, and chemistry of Se-alk(en)ylselenocysteines and their gamma-glutamyl derivatives and oxidation products. (2001) (66)
- 3‐ and 3,6‐Silylated 2‐Pyridinethiols: New Hindered Bidentate Ligands and Their Novel Silver and Copper Clusters (1988) (65)
- Onion (Allium cepa L.) thiosulfinates respond to increasing sulfur fertility (1994) (65)
- Identification of selenium species in selenium-enriched garlic, onion and broccoli using high-performance ion chromatography with inductively coupled plasma mass spectrometry detection (1996) (65)
- Allium chemistry : identification of natural abundance organoselenium compounds in human breath after ingestion of garlic using gas chromatography with atomic emission detection (1995) (64)
- Flash vacuum pyrolysis studies. 5. Methanesulfenic acid (1978) (64)
- In vitro and in vivo isotope effects with hepatitis C protease inhibitors: enhanced plasma exposure of deuterated telaprevir versus telaprevir in rats. (2009) (64)
- Steric control of aggregation in neutral silver(I) thiolates, [AgSR]n. Crystal and molecular structures of [AgSCH(SiMe3)2]8, a discrete molecular biscycle of weakly interacting [AgSCH(SiMe3)2]4 units, and of [AgSC(SiPhMe2)3]3 and [AgSC(SiMe3)3] ... (1987) (64)
- Element selective characterization of stability and reactivity of selenium species in selenized yeast (2004) (61)
- Sulfur-bridged carbocycles. II. Extrusion of the sulfur bridge (1969) (60)
- New Synthetic Approaches to Symmetrical Sulfur-Bridged Carbocycles (1966) (57)
- Characterization of selenium species in biological extracts by enhanced ion-pair liquid chromatography with inductively coupled plasma-mass spectrometry and by referenced electrospray ionization-mass spectrometry (1999) (55)
- Allium chemistry: identification of natural abundance organoselenium volatiles from garlic, elephant garlic, onion, and Chinese chive using headspace gas chromatography with atomic emission detection (1994) (55)
- Advances in Sulfur Chemistry (1992) (53)
- Mercury(II) and methylmercury(II) complexes of novel sterically hindered thiolates: carbon-13 and mercury-199 NMR studies and the crystal and molecular structures of [MeHg(SC6H2-2,4,6-Pr-iso3)], [Hg(SC6H4-2-SiMe3)2], [Hg(2-SC5H3N-3-SiMe3)2], and [Hg{(2-SC6H4)2SiMe2}]2 (1990) (53)
- Molecular mechanism of activation of human musk receptors OR5AN1 and OR1A1 by (R)-muscone and diverse other musk-smelling compounds (2018) (50)
- Flash vacuum pyrolysis studies. 7. Structure and origin of the onion lachrymatory factor. A microwave study (1979) (50)
- Smelling Sulfur: Copper and Silver Regulate the Response of Human Odorant Receptor OR2T11 to Low-Molecular-Weight Thiols. (2016) (50)
- Identification and synthesis of a novel selenium-sulfur amino acid found in selenized yeast: Rapid indirect detection NMR methods for characterizing low-level organoselenium compounds in complex matrices. (2004) (49)
- Flash vacuum pyrolysis studies. 9. Photoelectron spectra and molecular properties. 101. Synthesis and thermal decomposition of 1,3-dithietane and its S-oxides (1982) (47)
- Synthesis, Properties, Oxidation, and Electrochemistry of 1,2-Dichalcogenins (2000) (47)
- Zwiebelanes: novel biologically active 2,3-dimethyl-5,6-dithiabicyclo[2.1.1]hexane 5-oxides from onion (1989) (46)
- Synthesis, structure, and chemistry of new, mixed group 14 and 16 heterocycles: nucleophile-induced ring contraction of mesocyclic dications. (2006) (45)
- Total Synthesis of Thiarubrine B [3-(3-Buten-1-ynyl)-6-(1,3-pentadiynyl)-1,2-dithiin], the Antibiotic Principle of Giant Ragweed (Ambrosia trifida) (1994) (45)
- Preparations, structures and reactions of molybdenum complexes of triorgano silylated pyridine-2-thiols (1991) (45)
- Localizing the chemical forms of sulfur in vivo using X-ray fluorescence spectroscopic imaging: application to onion (Allium cepa) tissues. (2009) (44)
- Carbon-13 and oxygen-17 nuclear magnetic resonance studies of organosulfur compounds: the four-membered ring sulfone effect (1980) (43)
- Pro-angiogenesis action of arsenic and its reversal by selenium-derived compounds. (2006) (43)
- A novel chemotype of kinase inhibitors: Discovery of 3,4-ring fused 7-azaindoles and deazapurines as potent JAK2 inhibitors. (2010) (42)
- The chemistry of sulfines. 13. 2-Thiabicyclo[2.2.1]hept-5-ene and its S-oxides and 3-alkyl derivatives: sulfine and sulfene cyclopentadiene Diels-Alder adducts. Conversion of the cyclopentadiene-sulfine adducts into 2-oxa-3-thiabicyclo[3.3.0]oct-7-enes, novel bicyclic sultenes (1987) (41)
- Allium chemistry: Natural abundance of organoselenium compounds from garlic, onion and related plants and in human garlic breath (1996) (41)
- FLASH VACUUM PYROLYSIS STUDIES. 6. ALLENE EPISULFIDE (1978) (40)
- Chemistry of alkyl thiosulfinate esters. II. Sulfenic acids from dialkyl thiolsulfinate esters (1972) (39)
- 1,2-Dichalcogenins: Simple Syntheses of 1,2-Diselenins, 1,2-Dithiins, and 2-Selenathiin. (1999) (39)
- The chemistry of sulfines. 6. Dimer of the onion lachrymatory factor: the first stable 1,2-dithietane derivative (1980) (38)
- Allium chemistry: identification of organosulfur compounds in ramp (Allium tricoccum) homogenates. (1998) (38)
- Allenyl chloromethyl sulfones, new dienophile-diene synthons. A simple iterative ring-growing procedure (1990) (38)
- 1,3-Dithietane (1976) (37)
- Off-Line Supercritical Fluid Extraction of Thiosulfinates from Garlic and Onion (1994) (36)
- Silacyclobutenes: a simple synthesis (1978) (36)
- The lachrymatory factor of the onion: an NMR study☆ (1980) (35)
- Allium Chemistry: Synthesis of 1-[Alk(en)ylsulfinyl]propyl Alk(en)yl Disulfides (Cepaenes), Antithrombotic Flavorants from Homogenates of Onion (Allium cepa) (1997) (35)
- Liquid sulfur as a reagent: synthesis of polysulfanes with 20 or more sulfur atoms with characterization by UPLC-(Ag+)-coordination ion spray-MS (2013) (35)
- Molecular Basis of Mammalian Odor Discrimination: A Status Report. (2018) (35)
- Organic Chemistry of Sulfur (1978) (32)
- Photoelectron Spectrum of H2CSO (1976) (31)
- The sulfur chemistry of shiitake mushroom. (2003) (31)
- QM/MM model of the mouse olfactory receptor MOR244-3 validated by site-directed mutagenesis experiments. (2014) (30)
- Gas-phase determination of the geometric requirements of the silicon .beta.-effect. Photoelectron and Penning ionization electron spectroscopic study of silylthiiranes and -oxiranes. Synthesis and chemistry of trans-2,3-bis(trimethylsilyl)thiirane (1988) (30)
- The crystal and molecular structure of a tetranuclear copper thiolate cluster, [Cu{SC6H3-2,6-(SiMe3)2}]4 (1990) (29)
- Infrared spectra of matrix-isolated sulfine (1979) (29)
- Electrochemical and chemical oxidation of dithia-, diselena-, ditellura-, selenathia-, and tellurathiamesocycles and stability of the oxidized species. (2010) (28)
- Catalytic disproportionation and reduction of hydrazine by sulfur-ligated molybdenum(IV) complexes. Characterization of the catalytic precursor [(2-SC5H3N-3-SiMe3)Cl2Mo(.mu.-S2)(.mu.-2-SC5H3NH-3-SiMe3)MoCl2(2-SC5H3N-3-SiMe3)].cntdot.thf (1992) (28)
- (Z,Z)-d,l-2,3-Dimethyl-1,4-butanedithial S,S'-dioxide: a novel biologically active organosulfur compound from onion. Formation of vic-disulfoxides in onion extracts (1990) (28)
- Simple Total Syntheses of Biologically Active Pentathiadecane Natural Products, 2,4,5,7,9-Pentathiadecane 2,2,9,9-Tetraoxide (Dysoxysulfone), from Dysoxylum richii, and 2,3,5,7,9-Pentathiadecane 9,9-Dioxide, the Misidentified Lenthionine Precursor SE-3 from Shiitake Mushroom (Lentinus edodes) (1994) (28)
- Allium Chemistry: Structure, Synthesis, Natural Occurrence in Onion (Allium cepa), and Reactions of 2,3-Dimethyl-5,6-dithiabicyclo[2.1.1]hexane S-Oxides (1996) (28)
- Fifty years of smelling sulfur (2013) (28)
- Aversion of European starlings (Sturnus vulgaris) to garlic oil treated granules: garlic oil as an avian repellent. Garlic oil analysis by nuclear magnetic resonance spectroscopy. (2004) (27)
- Silver(I) clusters of the sterically-hindered bidentate ligand, 3-(dimethylphenyl)silyl-2-pyridinethiol. The crystal and molecular structures of [Ag(SC5H3N-3-SiMe2,Ph)]6 and [Ag8(SC5H3N-3-SiMe2Ph)6][Ag(NO3)2]2·2CH3OH·CH2Cl2 (1990) (26)
- Recent results in the organosulfur and organoselenium chemistry of genus Allium and Brassica plants. Relevance for cancer prevention. (1996) (26)
- Complexes of group 15 metals with sterically hindered thiolate ligands. Crystal and molecular structures of [Sb(2-SC5H4N)3], [Sb(2-SC5H3N-3-SiMe3)3], and [Bi(2-SC5H3N-3-SiMe3)3] (1991) (26)
- Chemistry of sulfines. 12. Unusually facile thio-Claisen rearrangement of 1-alkenyl 2-alkenyl sulfoxides: a new sulfine synthesis (1985) (26)
- Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS2N2], [NiS2P2] and [NiS2O2] cores (1991) (26)
- The “syn-effect” in sulfines and carbonyl oxides: Conformational preferences of CH3CHSO and CH3CHOO☆☆☆ (1981) (25)
- Synthesis and Structural Characterization of Neutral Silver(I) Complexes with Arenephosphinothiols. Crystal Structures of [Ag4{2-(Ph2P)-6-(Me3Si)C6H6S}4] and [Ag4{2-(Ph2PO)-6-(Me3Si)C6H3S}4] (1999) (25)
- Flavorants from Garlic, Onion, and Other Alliums and Their Cancer‐ Preventive Properties (1994) (25)
- Organosulfur compounds in organic synthesis. 1. Bromomethanesulfonyl bromide in organic synthesis. Formation and base-induced reactions of .alpha.,.beta.-unsaturated halomethyl sulfones (1983) (25)
- Organic Sulfur Compounds in Organic Synthesis. (1971) (24)
- Coordination chemistry of molybdenum with novel thiolate ligands. The crystal and molecular structures of a binuclear complex with a MoMo triple bond [Mo2(SC6H4oPPh2)3Cl3] and of [Mo(SC6H3-2-SiMe3-6-P(O)Ph2)2Cl2], a species exhibiting [MoO2S2Cl2] coordination (1989) (24)
- A new sulfene synthesis (1983) (24)
- Supercritical fluid chromatography of garlic (Allium sativum) extracts with mass spectrometric identification of allicin. (1994) (23)
- Halido-thiolate complexes of Mo(III), Mo(IV) and Mo(V): Synthesis, characterization and crystal and molecular structures of [MoCl4{SC5H2NH-3,6-(SiMe2But)2}2],(Ph4P)[MoBr4(SC5H3NH-3-SiMe3)2], [MoBr3(SC5H3NH-3-SiMe3)3] and (Ph4P)[MoOBr3(SC5H3N-3-SiMe3)] (1990) (23)
- .alpha.-Haloalkanesulfonyl bromides in organic synthesis. 3. .alpha.-Alkylidene ketones and 1,3-oxathiole 3,3-dioxides from trimethylsilyl enol ethers (1984) (23)
- Spirocyclic sulfur and selenium ligands as molecular rigid rods in coordination of transition metal centers. (2005) (23)
- Crushing Garlic and Slicing Onions: Detection of Sulfenic Acids and Other Reactive Organosulfur Intermediates from Garlic and Other Alliums using Direct Analysis in Real-Time Mass Spectrometry (DART-MS) (2011) (23)
- Syntheis and structural characterization of cyclo-pentakis [bis(μ-trimethylsilylthiomethane)nickel(II)], [Ni(SCH2SiMe3)2]5, a pentametallic tiara structure (1988) (22)
- Sulfur-bridged carbocycles. III. Photocyclization of .beta.,.beta.'-diphenyldivinyl sulfide (1969) (22)
- The role of metals in mammalian olfaction of low molecular weight organosulfur compounds. (2017) (22)
- Chemistry of alkyl thiolsulfinate esters. IV. Mechanistic study of the disproportionation reaction (1973) (22)
- Serendipitous synthesis of alkyl trimethylsilyldithioformates by trapping of bis(trimethylsilyl)thione with alkanesulfenic acids. Synthesis of bis- and tris(trimethylsilyl)methanethiols. (1985) (22)
- Fluorinated Analogs of Organosulfur Compounds from Garlic (Allium sativum): Synthesis, Chemistry and Anti-Angiogenesis and Antithrombotic Studies (2017) (21)
- Reply to Turin et al.: Vibrational theory of olfaction is implausible (2015) (20)
- Electron impact induced processes of thermally and photochemically labile organic sulfur compounds. Mass spectral study of dialkyl thiolsulfonates, disulfides, trisulfides, and .alpha.-disulfones (1975) (20)
- The Organo‐Sulfur Chemistry of the Genus Allium. Implications for the Organic Chemistry of Sulfur (1992) (20)
- Onion essential oil chemistry. Cis-and trans-2-mercapto-3,4-dimethyl 2,3-dihydrothiophene from pyrolysis of bis(1-propenyl) disulfide (1990) (20)
- 1H–{125Te} indirect detection in nuclear magnetic resonance spectra of organotellurium compounds (1997) (20)
- Structure determination of a new cyclodepsipeptide antibiotic from fusaria fungi (1985) (20)
- Chemistry of alkyl thiolsulfinate esters. III. tert-Butanethiosulfoxylic acid (1972) (19)
- Allium chemistry: Use of new instrumental techniques to “see” reactive organosulfur species formed upon crushing garlic and onion (2010) (19)
- In Pursuit of Cyclopropanethione: Cyclopropanethione S-Oxide and S,S-Dioxide' (1992) (19)
- Synthesis, electrochemistry, and gas-phase photoelectron spectroscopic and theoretical studies of 3,6-bis(perfluoroalkyl)-1,2-dithiins. (2003) (18)
- Trifluoroselenomethionine: A New Unnatural Amino Acid (2016) (18)
- Gas-Phase Photoelectron Spectroscopic and Theoretical Studies of 1,2-Dichalcogenins: Ionization Energies, Orbital Assignments, and an Explanation of Their Color (2000) (18)
- The first X-ray crystal structural characterizations of alkali metal alkyl thiolates: X-ray crystal structures of [Li2(thf)4{SCH(SiMe3)2}2] and [Li2(thf)3.5{SC(SiMe3)3}2](thf = tetrahydrofuran) (1985) (17)
- Synthesis and reactions of 3-mercaptocyclobutanol and derivatives. Preparation of a 2,4-dithiabicyclo[3.1.1]heptane (1986) (17)
- Diallyl sulfoxide: A convenient source of thioacrolein for diels-alder trapping (1990) (17)
- Copper-mediated thiol potentiation and mutagenesis-guided modeling suggest a highly conserved copper-binding motif in human OR2M3 (2019) (17)
- The first coordination complexes of selenones: a structural comparison with complexes of sulfones. (2003) (17)
- Synthesis of methanethial S-oxide (sulfine) and alkanethial S,S-dioxides by fluorodesilylation. Stereochemistry of their cyclopentadiene Diels-Alder adducts (1985) (17)
- Oxidation of disulfides with the triphenyl phosphite ozonide (1971) (17)
- Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC5H3N-3-SiMe3)2] (1991) (17)
- Microwave structural studies of organoselenium compounds 1. Microwave spectra, molecular structure, and methyl barrier to internal rotation of dimethyl diselenide (2004) (17)
- Dependence of superoxide anion production on extracellular and intracellular calcium ions and protein kinase C in PMA-stimulated bovine neutrophils. (1999) (17)
- α-Haloalkanesulfonyl bromides in organic synthesis. II: A useful new 1,3-diene synthesis (1983) (17)
- BIOLOGICAL ACTIVITY OF ALLIUM COMPOUNDS: RECENT RESULTS (2005) (17)
- Electrophilic Addition of X Y Reagents to Alkenes and Alkynes (1991) (16)
- Allium chemistry: simple synthesis of antithrombotic cepaenes from onion and deoxycepaenes from oil of shallot by reaction 1-propenethiolate with sulfonyl halides (1992) (16)
- α-haloalkanesulfonyl bromides in organic synthesis. 4. Regioselective γ-deprotonation of α,β-unsaturated sulfones. A simple synthesis of 2-alkyl-1,3-butadienes. (1984) (16)
- Chemistry of alkyl thiolsulfinate esters. V. Novel synthesis of .alpha.-heteroatom substituted disulfides (1973) (16)
- Perthio- and perseleno-1,3-butadienes, -but-1-ene-3-ynes, and -[3]-cumulenes: one-step syntheses from 1,4-dilithio-1,3-butadiyne. (2003) (16)
- [[(2-Tetrahydrofuranyl)- and (2-tetrahydropyranyl)thio]methyl]lithium: methanethiol carbanion equivalents (1985) (16)
- Prepackaged Ramberg–Bäcklund reagents: useful tools for organic synthesis (2004) (16)
- Powder Diffraction Study of a Coordination Polymer Comprised of Rigid Building Blocks: [Rh2(O2CCH3)4·μ2-Se2C5H8-Se,Se‘]∞ (2004) (15)
- Challenges and Artifact Concerns in Analysis of Volatile Sulfur Compounds (2012) (15)
- Complexes of Group 12 metals with sterically-hindered thiolate ligands. The crystal and molecular structures of [Zn2(2-SC5H3N-3-SiMe3)4] and [CdI2(2-SC5H3NH-6-SiMe2But)2] (1991) (15)
- Small organoselenium molecules. 1. Dimethyl selenoxide: structure, complexation, and gas-phase transformation. (2003) (15)
- Thiolate chemistry of the main group metals. The synthesis and structures of [Sn(2- SC5H3N-3-SiMe3)4] and [Pb3(2-SC5H3N-3-SiMe3)6] (1991) (15)
- Unstable intermediates in the gas-phase. Formation of thioformaldehyde from trithiolan (1977) (14)
- Visible‐light Photochemistry and Phototoxicity of Thiarubrines (1999) (14)
- Synthesis and structural characterization of [Cu(SC6H4-o-SiMe3)]12, an unusual example of a ‘paddle-wheel’ dodecametallic thiolate cluster (1988) (14)
- Headspace–gas chromatography with atomic emission and mass selective detection for the determination of organoselenium compounds in elephant garlic (1994) (14)
- Photochemically Generated Thiyl Free Radicals Observed by X-ray Absorption Spectroscopy. (2017) (14)
- Ajothiolanes: 3,4-Dimethylthiolane Natural Products from Garlic ( Allium sativum). (2018) (14)
- The four-membered-ring chemical shift anomaly (1983) (14)
- The synthesis and crystal and molecular structure of mer-tris(3-trimethylsilyl-2-pyridinethiolato)cobalt(III) (1991) (14)
- Microwave Spectra, Molecular Structure, and Electric Dipole Moment of 1,2-Dithiin (1996) (14)
- Facts and Artifacts in Allium Chemistry. (1994) (13)
- Complexes of rhenium with sterically hindered thiolate ligands. Crystal structure of Re(SC6H4-o-SiMe3){NC(SC6H4-o-SiMe3)CH3}2(PPh3)2], a complex exhibiting coordinated thiolimidate groups formed via nucleophilic attack and reduction by thiolate of coordinated acetonitrile (1989) (13)
- The Organosulfur Chemistry of the Onion (1991) (12)
- Semiochemical responsive olfactory sensory neurons are sexually dimorphic and plastic (2019) (12)
- Enhanced Grain Drying by Conduction Heating Using Molecular Sieves (1988) (12)
- Microwave Investigation of (Z)- and (E)-Ethanethial S-Oxide (1996) (12)
- The Search for Anticarcinogenic Organoselenium Compounds from Natural Sources (1998) (11)
- Insights into the Chemical Biology of Selenium (2008) (11)
- The chemistry of sulfines. 10. 2-Thiabicyclo[2.2.1]hept-5-ene endo-2-oxide derivatives: stereospecific formation, rearrangement to bicyclic sultenes, and conversion to 5-alkylidene-2-cyclopentenones (1985) (11)
- The chemistry of sulfines. 9. A novel synthesis of α-chloroalkyl alkanethiosulfonate esters (1982) (11)
- Comments on Garlic Chemistry: Stability of S-(2-Propenyl) 2-Propene-1-sulfinothioate (Allicin) in Blood, Solvents, and Simulated Physiological Fluids (1997) (11)
- Interaction of C−Si, C−Sn, and Si−Si σ-Bonds with Chalcogen Lone Pairs (2007) (11)
- Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3] (1991) (11)
- Fifty years of smelling sulfur: From the chemistry of garlic to the molecular basis for olfaction (2017) (10)
- Interferon-gamma inhibits adenosine A2A receptor function in hepatic stellate cells by STAT1-mediated repression of adenylyl cyclase. (2010) (10)
- The Si−Si Effect on Ionization of β-Disilanyl Sulfides and Selenides (2006) (10)
- Peeling the Onion (1997) (9)
- Garlic as a Functional Food: A Status Report (1998) (9)
- Recent Advances in the Chemistry of 1,2-Dithiins (1999) (8)
- SPECTROSCOPIC, THEORETICAL, AND ELECTROCHEMICAL STUDIES OF 1,2-DITHIINS (1997) (8)
- 5.14 – Thietanes, Thietes and Fused-ring Derivatives (1984) (8)
- Chloromethanesulfonylethene and dichloromethanesulfonylethene: new reagents for tandem Diels-Alder/Ramberg-Bäcklund reactions. (2004) (8)
- .alpha.-Disulfide carbonium ions (1974) (8)
- D,L- AND MESO-BIS(ALPHA -MERCAPTOBENZYL)DIMETHYLSILANE : NEW HINDERED BIDENTATE LIGANDS AND A NOVEL BINUCLEAR MOLYBDENUM COMPLEX FORMED THEREFROM (1990) (8)
- Copper(I) complexes of sterically-hindered 2-pyridinethione ligands. Crystal structures of [CuCl(2-SC5H2NH-3-SiMe3-6-SiEt3)2] and the disulfide, [- 2-SC5H2N-3,6-(SiMe2But)2]2 (1991) (8)
- Peeling the onion: Organosulfur and -selenium phytochemicals in genus Allium plants (1997) (7)
- Smelling Sulfur: Discovery of a Sulfur-Sensing Olfactory Receptor that Requires Copper (2013) (7)
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- Electrophile-Induced Ring Opening (2008) (0)
- Addition of α,ω-Dithiols to Thiete 1,1-Dioxides (2008) (0)
- The Chemistry of Alkyl Thiosulfinate Esters. Part 9. Antithrombotic Organosulfur Compounds from Garlic: Structural, Mechanistic, and Synthetic Studies. (1987) (0)
- Four membered rings with one oxygen, sulfur, or selenium atom (1991) (0)
- Chloromethanesulfonylethene and Dichloromethanesulfonylethene: New Reagents for Tandem Diels—Alder/Ramberg—Baecklund Reactions. (2004) (0)
- Dihydrodiol Formation or Oxidation/Dimerization (2007) (0)
- Addition of Heteroatoms (2008) (0)
- Heating Dialk-1-enyl Disulfides (2007) (0)
- Oxidation of Thietan-3-ol to Thietan-3-one (2008) (0)
- Allylic Bromination of 4,5-Dihydrothiepin 1,1-Dioxide (2007) (0)
- THE CHEMISTRY OF SULFINES. 10. 2-THIABICYCLO(2.2.1)HEPT-5-ENE ENDO-2-OXIDE DERIVATIVES: STEREOSPECIFIC FORMATION, REARRANGEMENT TO BICYCLIC SULTENES, AND CONVERSION TO 5-ALKYLIDENE-2-CYCLOPENTENONES (1985) (0)
- From 4,4-Dibromo-3-methylbut-3-ene-1-thiol (2007) (0)
- Lithiation of 3,4-Dihydro-2-thiopyrans, 2-Thiopyrans, and 4-Thiopyrans (2007) (0)
- Aromatization of 2,3-Dihydrothiophenes (2007) (0)
- Addition Reactions Involving Thiophene 1-Oxides (2007) (0)
- Gas-Phase Determination of the Geometric Requirements of the Silicon β-Effect. Photoelectron and Penning Ionization Electron Spectroscopic Study of Silylthiiranes and -oxiranes. Synthesis and Chemistry of trans-2,3-Bis(trimethylsilyl) (1988) (0)
- Substitution of Hydrogen (2007) (0)
- Addition and Elimination of Halogen (2007) (0)
- Complexes of Rhenium with Sterically Hindered Thiolate Ligands. Crystal Structure of (Re(SC6H4‐o‐SiMe3)(NC(SC6H4‐o‐SiMe3)CH3)2(PPh3)2), a Complex Exhibiting Coordinated Thiolimidate Groups Formed via Nucleophilic Attack and Reduction by Thiolate of Coordinated Acetonitrile. (1989) (0)
- [2+2]-Photochemical Cycloadditions to 2,3-Dihydrothiophene 1,1-Dioxide (2007) (0)
- Ring Transformations of 1,3,4-Oxadiselenolanes with Trivalent Phosphorus Reagents (2008) (0)
- Cyclopalladation of Benzyl Methyl Sulfide (2007) (0)
- [4+2] and [2+2] Cycloadditions of 2-Methylenethietes (2007) (0)
- Ring Transformations of 3-Halomethyl-2,3-dihydroselenazolium Salts with Base (2008) (0)
- Synthesis of a 1,2-Dihydro-2-benzothiepin by Cathodic Reduction of a Benzyl Dithiopivaloate (2007) (0)
- Reaction of 1,3-Dihalides with Telluride Ion (2008) (0)
- Ring Enlargement of Thiirenes (2007) (0)
- Addition of Sulfenes to Unsaturated Compounds (2008) (0)
- Isomerization of 2,5-Dihydrothiophenes (2007) (0)
- Base-Catalyzed Isomerization of 2,5-Dihydrothiophene 1,1-Dioxides (2007) (0)
- Reduction of the Sulfoxide Group (2007) (0)
- Synthesis, Properties, Oxidation, and Electrochemistry of 1,2‐Dichalcogenins. (2000) (0)
- α-HALOALKANESULFONYL BROMIDES IN ORGANIC SYNTHESIS. 4. REGIOSELECTIVE Γ-DEPROTONATION OF α,β-UNSATURATED SULFONES. A SIMPLE SYNTHESIS OF 2-ALKYL-1,3-BUTADIENES (1985) (0)
- Cyclization of α-Phosphonovinyl Radicals (2007) (0)
- Ring Contraction by Desulfurization of 1,2-Dithiolanes (2008) (0)
- Ring-Opening Reactions of Thiaoxabicyclo[3.2.1]octanes and Thiaoxabicyclo[3.3.1]nonanes (2007) (0)
- By Formation of One C—C Bond (2001) (0)
- Addition of Organic Groups (2008) (0)
- Intramolecular Sulfenyl Bromide–Alkene Addition (2008) (0)
- The Si-Si effect on ionization of beta-disilanyl sulfides and selenides. (2006) (0)
- UNSTABLE INTERMEDIATES IN THE GAS-PHASE. FORMATION OF THIOFORMALDEHYDE FROM TRITHIOLANE (1977) (0)
- Indirect Detection in Nuclear 1H-{125Te} Magnetic Resonance Spectra of Organotellurium Compounds (1997) (0)
- Photochemical or Thermal Cycloaddition of Thiocarbonyl Compounds and Alkenes (2008) (0)
- Lithiation of 2,3-Dihydrothiophene and Its Reactions with Electrophiles (2007) (0)
- Bamford–Stevens Elimination of the Tosylhydrazone of Dihydrothiophen-3(2)-one (2007) (0)
- 2-(Chloromethyl)oxirane-Related Systems (2008) (0)
- Reaction of 1,3-Dihalides or 1,3-Disulfonates with Sulfide Ion (2008) (0)
- Reaction of Zirconacycles with Sulfur Monochloride (2007) (0)
- Elimination Reactions Leading to Thiacyclohept-2-enes, Thiacyclooct-2-enes, and Related Systems (2007) (0)
- Recent Advances in the Chemistry of 1,2‐Dithiins (2001) (0)
- From 3-(Difluoromethylene)-2-methyl-6-phenylhexane-1-thiol (2007) (0)
- Halido-Thiolate Complexes of Mo(III), Mo(IV) and Mo(V): Synthesis, Characterization and Crystal and Molecular Structures of (MoCl4(SC5H2NH-3,6-(SiMe2tBu)2)2), (Ph4P)(MoBr4(SC5H3NH-3-SiMe3)2), (MoBr3(SC5H3NH-3-SiMe3)3) and (Ph4P)(MoOBr (1990) (0)
- THE CHEMISTRY OF SULFINES. 9. A NOVEL SYNTHESIS OF α‐CHLOROALKYL ALKANETHIOSULFONATE ESTERS (1983) (0)
- Cycloaddition of Selenocarbonyl Compounds and Alkenes (2008) (0)
- Complexes of molybdenum with novel sterically-hindered thiolate ligands (1989) (0)
- Addition of Amines to 2-Methylenethiete 1,1-Dioxides (2008) (0)
- Lithium 2‐Lithiobenzenethiolate (2001) (0)
- By Formation of One S—C and One C—C Bond (2008) (0)
- 2‐Thiabicyclo(2.2.1)hept‐5‐ene and Its S‐Oxides and 3‐Alkyl Derivatives: Sulfine and Sulfene Cyclopentadiene Diels‐Alder Adducts. Conversion of the Cyclopentadiene‐Sulfine Adducts into 2‐Oxa‐3‐thiabicyclo‐(3.3.0)oct‐7‐enes, Novel Bicyclic Sultenes. (1987) (0)
- Reaction of Ammonium Hydrosulfide with 3-Adamantan-2-ylidene-1,1,1-trifluoropropan-2-one (2008) (0)
- Photochemical Conversion of a 2-Thiopyran into a 4-Thiopyran (2007) (0)
- Ring Contraction of Thiophene 1,1-Dioxides (2007) (0)
- Reaction of Dienes with Sulfur Compounds (2008) (0)
- O-Alkylation of Thietane 1-Oxides (2008) (0)
- Synthesis by Substituent Modification (2007) (0)
- Intramolecular Cycloaddition of Sulfenic Acid to Alkenes (2008) (0)
- Desilylation with Tetrabutylammonium Fluoride (2008) (0)
- Dimerization of 2,3-Dihydrothiophene and Its 1,1-Dioxide (2007) (0)
- Intermolecular Processes Involving Metal Complexes of Thioaldehydes (2008) (0)
- Diels–Alder Additions (2007) (0)
- Lithiation of 2,3,4,5-Tetrahydrothiepin 1-Oxide (2007) (0)
- THE CHEMISTRY OF ALKYL THIOSULFINATE ESTERS. 9. SERENDIPITIOUS SYNTHESIS OF ALKYL TRIMETHYLSILYDITHIOFORMATES BY TRAPPING OF BIS(TRIMETHYLSILYL)THIONE WITH ALKANESULFENIC ACIDS. SYNTHESIS OF BIS- AND TRIS(TRIMETHYLSILYL)METHANETHIOLS (1985) (0)
- Reduction by Catalytic Hydrogenation or with Sodium Borohydride (2008) (0)
- Reaction of Thiones with Quadricyclane (2008) (0)
- 3,4-Dihydro-2-thiopyrans from 2,3-Dihydrothiophenium Methylides (2007) (0)
- Substitution of Heteroatoms (2001) (0)
- Substitution of Hydrogen or Metals (2007) (0)
- Carbamates-Analysis by API LC/MS (2001) (0)
- COMMENTS ON: GARLIC CHEMISTRY : STABILITY OF S-(2-PROPENYL) 2-PROPENE-1-SULFINOTHIOATE (ALLICIN) IN BLOOD, SOLVENTS, AND SIMULATED PHYSIOLOGICAL FLUID S BY BLANIA, G. ET AL. (1997) (0)
- Zwiebelanes: Novel Biologically Acitve 2,3-Dimethyl-5,6-dithiabicyclo(2.1.1)hexane 5-Oxides from Onion (1989) (0)
- Formal Exchange of Ring Members with Retention of Ring Size (2007) (0)
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