Guy Bertrand
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American chemist
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Guy Bertrand chemistry Degrees
Chemistry
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Organic Chemistry
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Chemistry
Guy Bertrand 's Degrees
- PhD Chemistry University of California, Berkeley
- Masters Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Guy Bertrand Influential?
(Suggest an Edit or Addition)According to Wikipedia, Guy Bertrand, born on July 17, 1952, at Limoges is a chemistry professor at the University of California, San Diego. Bertrand obtained his B.Sc. from the University of Montpellier in 1975 and his Ph.D. from the Paul Sabatier University, Toulouse, in 1979. He was a postdoctoral researcher at Sanofi Research, France, in 1981.
Guy Bertrand 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Stable cyclic carbenes and related species beyond diaminocarbenes. (2010) (804)
- Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. (2005) (696)
- Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center (2007) (653)
- Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. (2015) (557)
- Analogous .alpha.,.alpha.'-bis-carbenoid, triply bonded species: synthesis of a stable .lambda.3-phosphino carbene-.lambda.5-phosphaacetylene (1988) (541)
- Stable Carbenes. (2000) (512)
- Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. (2017) (435)
- Stable singlet carbenes as mimics for transition metal centers. (2011) (435)
- Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines (2011) (413)
- Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. (2008) (348)
- 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes. (2013) (348)
- A Brief Survey of our Contribution to Stable Carbene Chemistry. (2011) (344)
- Carbene-Stabilized Main Group Radicals and Radical Ions. (2013) (338)
- Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). (2010) (312)
- Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. (2008) (279)
- Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene (2010) (277)
- Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime (2019) (275)
- Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. (2009) (235)
- CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. (2006) (228)
- Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. (2010) (217)
- Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes (2007) (215)
- Singlet Diradicals: from Transition States to Crystalline Compounds (2002) (214)
- Carbene activation of P4 and subsequent derivatization. (2007) (212)
- A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. (2005) (203)
- [Bis(diisopropylamino)phosphino]trimethylsilylcarbene: A Stable Nucleophilic Carbene (1989) (201)
- NHC-mediated aggregation of P4: isolation of a P12 cluster. (2007) (199)
- Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. (2014) (198)
- Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. (2010) (179)
- Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). (2010) (177)
- Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. (2009) (176)
- Cyclopropenylidenes: From Interstellar Space to an Isolated Derivative in the Laboratory (2006) (175)
- Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). (2007) (175)
- 1,2,4-Triazole-3,5-diylidene: A Building Block for Organometallic Polymer Synthesis (1997) (168)
- Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. (2008) (166)
- Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. (2010) (162)
- A Singlet Phosphinidene Stable at Room Temperature (2016) (161)
- Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. (2011) (156)
- A crystalline phosphinyl radical cation. (2010) (150)
- Cyclische Alkylaminocarbene (CAACs): Neues von guten Bekannten (2017) (147)
- Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. (2011) (145)
- Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne “click reaction” (2015) (143)
- Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. (2015) (139)
- Stable non-N-heterocyclic carbenes (non-NHC): recent progress (2004) (133)
- Carbene Chemistry: From Fleeting Intermediates to Powerful Reagents (2002) (132)
- Isolation of a C5-Deprotonated Imidazolium, a Crystalline “Abnormal” N-Heterocyclic Carbene (2009) (128)
- Synthesis, reactivity, and ligand properties of a stable alkyl carbene. (2004) (127)
- Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. (2010) (121)
- Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. (2007) (117)
- Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. (2008) (116)
- Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. (2009) (116)
- A stable P-heterocyclic carbene. (2005) (115)
- Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. (2007) (111)
- A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom–Transfer Agent (2012) (109)
- Neutral and Cationic Tetracoordinated Aluminum Complexes Featuring Tridentate Nitrogen Donors: Synthesis, Structure, and Catalytic Activity for the Ring-Opening Polymerization of Propylene Oxide and (d,l)-Lactide (1998) (108)
- 1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes. (2018) (107)
- Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. (2012) (107)
- Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. (2013) (106)
- Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). (2011) (104)
- Borylenes: An Emerging Class of Compounds. (2017) (103)
- A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. (2012) (103)
- "Quick-Silver" from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. (2019) (103)
- Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. (2009) (103)
- Gold-catalyzed hydroarylation of alkenes with dialkylanilines. (2014) (103)
- A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. (2009) (102)
- Soluble Allotropes of Main-Group Elements (2008) (102)
- Singlet (Phosphino)phosphinidenes are Electrophilic. (2016) (101)
- An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. (2014) (99)
- Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. (2008) (96)
- Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. (2014) (95)
- Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. (2005) (94)
- Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. (2013) (94)
- Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals. (2015) (93)
- Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. (2009) (93)
- Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. (2020) (92)
- Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. (2011) (92)
- (Amino)(aryl)carbenes: stable singlet carbenes featuring a spectator substituent. (2001) (92)
- DBU and DBN are Strong Nucleophiles: X‐Ray Crystal Structures of Onio‐ and Dionio‐Substituted Phosphanes (1993) (91)
- [Bis(diisopropylamino)phosphino]trimethylsilyl-carben: Ein stabiles nucleophiles Carben† (1989) (90)
- One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl₃ adduct. (2014) (86)
- N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals (2011) (85)
- Aluminum Chloride-Promoted Transamidation Reactions (1994) (82)
- Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. (2013) (82)
- Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. (2014) (79)
- Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. (2015) (79)
- Stability and electronic properties of imidazole-based mesoionic carbenes. (2011) (79)
- Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. (2016) (77)
- Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. (2014) (76)
- Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. (2016) (75)
- Stable (amino)(phosphino)carbenes: difunctional molecules. (2002) (74)
- Stable abnormal N-heterocyclic carbenes and their applications. (2020) (74)
- Chemical bonding: Rethinking carbon. (2009) (73)
- Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. (2015) (70)
- Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. (2004) (69)
- Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir–η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion (2016) (67)
- Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. (2006) (66)
- Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). (2016) (65)
- Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl. (2004) (65)
- Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. (2018) (65)
- Synthesis of a room-temperature-stable dimeric copper(I) hydride. (2011) (65)
- Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). (2014) (65)
- Carbenes introduction. (2009) (63)
- Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. (2013) (62)
- Synthesis, reactivity, and crystal structure of the first methylenephosphonium ion: a severely twisted valence isoelectronic olefin (1989) (62)
- Synthesis and x-ray crystal structure of [(iso-Pr2N)2P(H)CP(N-iso-Pr2)2]+CF3SO3-: a carbene, a cumulene, or a phosphaacetylene? (1992) (60)
- A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. (2006) (60)
- Sigma-bond stretching: a static approach for a dynamic process. (2004) (60)
- Are Allenes with Zwitterionic Character Still Allenes? Of Course! (2009) (59)
- Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. (2017) (59)
- Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. (2014) (59)
- What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis? (2018) (58)
- 1,2,4-Triazolium-5-ylidene and 1,2,4-triazol-3,5-diylidene as new ligands for transition metals (2000) (57)
- Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. (2013) (57)
- Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. (2014) (56)
- Synthesis of the first .alpha.-diazophosphines. Phosphorous-carbon multiple-bond character of phosphinocarbenes (1985) (55)
- Tandem copper hydride–Lewis pair catalysed reduction of carbon dioxide into formate with dihydrogen (2018) (54)
- Copper(I) Complexes Bearing Carbenes Beyond Classical N‐Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry” (2015) (54)
- Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. (2018) (53)
- Deprotonierung eines Borhydrids und Synthese eines Carben‐ stabilisierten Borylanions (2013) (53)
- Amino-aryl-carbenes: alternative ligands for transition metals? (2004) (53)
- Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. (2015) (52)
- The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. (2015) (52)
- An air-stable oxyallyl radical cation. (2013) (51)
- Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. (2011) (50)
- Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene] (2014) (50)
- Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. (2015) (50)
- Stable four-π-electron, four-membered heterocyclic cations and carbenes (2006) (49)
- Evidence for the coexistence of two bond-stretch isomers in solution. (2004) (49)
- Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. (2016) (49)
- NHC-CAAC Heterodimers with Three Stable Oxidation States. (2016) (48)
- N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. (2016) (47)
- Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. (2011) (47)
- Synthesis of Carbenes Through Substitution Reactions at a Carbene Center (2003) (47)
- Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. (2017) (47)
- A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. (2016) (46)
- Synthesis and structure of 1,2,4-triazol-2-ium-5-ylidene complexes of Hg(II), Pd(II), Ni(II), Ni(0), Rh(I) and Ir(I) (2002) (46)
- Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. (2008) (45)
- Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). (2004) (45)
- Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. (2018) (45)
- Stable P-heterocyclic carbenes: scope and limitations. (2007) (44)
- Theoretical investigations on some C2SiH4 isomers (1979) (44)
- On the Electronic Structure of (Phosphino)(silyl)carbenes: Single-Crystal X-ray Diffraction and ELF Analyses (2000) (43)
- Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups (2019) (43)
- Borylene: eine aufstrebende Verbindungsklasse (2017) (43)
- Crystalline Monomeric Allenyl/Propargyl Radical. (2017) (42)
- Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc02668k Click here for additional data file. (2016) (41)
- Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. (2016) (41)
- Electronic structure of .lambda.5-phosphaacetylene and corresponding triplet methylenes (1991) (41)
- Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. (2013) (40)
- Trigonal Planar Phosphorus Cations (1997) (39)
- Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. (2006) (39)
- Photochemical and thermal rearrangement of heavier main-group element azides (1986) (39)
- Synthesis and Reactivity of Cyclic 6-Membered Six-.pi.- and Four-Membered Four-.pi. Electron Ylides (1994) (39)
- Phosphinocarbene-phosphaalkene rearrangement and intramolecular Wittig-like reaction involving a phosphorus vinyl ylide. (1986) (38)
- Isolation of bridging and terminal coinage metal-nitrene complexes. (2014) (38)
- A new route to bis(2,4,6-tri-tert-butylphenyl)diphosphene via silylated compound (1982) (38)
- Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. (2016) (38)
- Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. (2008) (38)
- λ5‐Phosphetes, Benzo‐λ5‐Phosphetes, Naphtho‐λ5‐Phosphetes: Four‐π‐, Eight‐π‐, and Twelve‐π‐Electron Systems (1996) (37)
- Synthesis of a 2H‐Azirine by [1 + 2] Cycloaddition of a Phosphinocarbene with a Nitrile and Its Ring‐Expansion to a 1,2λ5‐Azaphosphete (1995) (37)
- Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. (2009) (36)
- First Evidence for an Intermediate Nitrilo-λ5-phosphane † (1984) (36)
- Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. (2015) (36)
- Synthesis and structure of the first cyclodiphosphazene. Dimerization of a phosphonitrile :P.tplbond.N (1984) (35)
- Apparent 1,2-Silyl Migrations in Aromatic Carbenes Occur by Intermolecular Silyl Exchanges (1998) (35)
- Ein‐, Zwei‐ und Drei‐Elektronen‐Reduktion eines CAAC‐SbCl3‐ Addukts (2014) (35)
- Synthesis and reactivity of diazomethylenephosphoranes (P=C=N2). New phosphacumulene ylides and first stable pseudo-unsaturated diazo derivatives (1987) (35)
- Synthesis and reactivity of a stable nitrile imine (1988) (34)
- The Dramatic Influence of Diamidoamine Ligands on the Structure and Reactivity of Low-Valent Tin and Bismuth Derivatives (1999) (34)
- Synthesis and reactivity of stable phosphorus-substituted nitrilimines. X-ray crystal structure of C-[bis(diisopropylamino)thioxophosphoranyl]-N-[bis(diisopropylamino)phosphanyl]nitrilimine (1990) (34)
- Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. (2009) (34)
- Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. (2002) (34)
- Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. (2011) (34)
- Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. (2004) (34)
- Synthesis of a Stable 1.lambda.5,2.lambda.3-Diphosphete: the First Codimer of a .lambda.3-Phosphaalkyne with a .lambda.5-Phosphaalkyne (1995) (34)
- Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. (2015) (33)
- Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. (2007) (33)
- Synthesis of onio‐, dionio‐, and trionio‐substituted phosphines; the nucleophilic behavior of DBN and DBU toward main group electrophiles (1995) (33)
- Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). (2013) (33)
- Isolierung neutraler mono‐ und dinuklearer Goldkomplexe von cyclischen Alkyl(amino)carbenen (2013) (33)
- Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future (2020) (33)
- (CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand (2017) (32)
- Stereoselectivity and Stereospecificity of Cyclopropanation Reactions with Stable (Phosphanyl)(silyl)carbenes (2000) (32)
- Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. (2017) (32)
- On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). (2003) (32)
- Synthesis and Molecular Structure of a 1,2λ5-Azaphosphete: A Cyclic 4-π-Electron Ylide. (1993) (32)
- Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. (2009) (31)
- The stable pentamethylcyclopentadienyl cation remains unknown. (2002) (31)
- Synthesis, Characterization and Dynamic Behavior of Mono‐ and Dinuclear Palladium(II) Carbene Complexes Derived From 1,1′‐Methylenebis(4‐alkyl‐1,2,4‐triazolium) Diiodides (1999) (31)
- L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. (2018) (31)
- The Deprotonated Iminophosphorane o-C6H4PPh2P=NSiMe3 as a Novel Chelating Ligand in Organocopper(I) and -zinc(II) Chemistry (1999) (31)
- Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. (2004) (31)
- From 2‐Phosphino‐2H‐Phosphirene to 1‐Phosphino‐1H‐Phosphirene, 1λ5,2λ3‐Diphosphete, and 1,2‐Dihydro‐1λ3,2λ3‐Diphosphete: an Experimental and Theoretical Study (1999) (30)
- β- and α-Hydride abstraction in Gold(I) alkyl complexes. (2013) (30)
- Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis (2021) (29)
- The Modest Undressing of a Silicon Center (2004) (29)
- Stable (aryl)(phosphino)carbenes: new ligands for transition metals. (2002) (29)
- (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles (2017) (28)
- ?3-Phosphinocarbenes ?5-phosphaacetylenes (1994) (28)
- Organometallics Roundtable 2011 (2012) (28)
- Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt. (2003) (28)
- Tuning the nucleophilicity in cyclopropenylidenes. (2008) (28)
- Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). (2012) (28)
- Cross-coupling reactions between stable carbenes. (2014) (28)
- Synthesis and Structure of the First Chiral Tetracoordinated Aluminum Cation (1996) (27)
- Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. (2012) (27)
- A simple access to transition metal cyclopropenylidene complexes. (2015) (26)
- Binding phosphinidenes to transition-metal fragments (1985) (26)
- Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex (1984) (26)
- A room temperature stable 1,3-diphosphaallyl radical (1997) (26)
- A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. (2011) (26)
- Ligand Behavior of a (Z)-Phosphazide (a 1,2,3,4λ5-Triazaphosphinine) and of the Corresponding Phosphazene (a 1,2λ5-Azaphosphete) (1996) (26)
- Synthesis and rearrangement of diphosphorus analogues of amidinium salts. (2002) (25)
- Carbodicarbenes, carbon(0) derivatives, can dimerize. (2013) (25)
- Mesoionic carbene-Breslow intermediates as super electron donors: Application to the metal-free arylacylation of alkenes (2021) (25)
- The Stable (Phosphino)(Silyl)Carbene As A Useful Building Block: Synthesis And Reactivity of 2‐Phosphorus‐Substituted 2H‐Azirines (1997) (24)
- Ylidic Four π Electron Four-Membered λ5 -Phosphorus Heterocycles: Electronical Isomers of Heterocyclobutadienes. (1998) (24)
- Nitrilimine: von der Charakterisierung in Matrix zu stabilen Verbindungen (1994) (24)
- Reductive Elimination at Carbon under Steric Control. (2019) (24)
- The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. (2017) (24)
- Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes (2020) (23)
- Zinc(II), Samarium(III) and Tin(II) Complexes Featuring a Tridentate Nitrogen Donor for the Ring‐Opening Copolymerization of (D,L)‐Lactide and Glycolide (2002) (23)
- An improved synthesis of key intermediates in metallole Group IVB chemistry (1983) (23)
- Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals. (2006) (23)
- Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. (2007) (23)
- The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. (2008) (23)
- The first asymmetric cyclopropanation reactions involving a stable carbene. (2001) (23)
- (Phosphino)(aryl)carbenes: effect of aryl substituents on their stabilization mode. (2003) (22)
- Nitrilimines: Evidence for the Allenic Structure in Solution, Experimental and Ab Initio Studies of the Barrier to Racemization, and First Diastereoselective (3 + 2)-Cycloaddition (1997) (22)
- Synthesis and X-ray crystal structure of the first diphosphirenium salt (1991) (22)
- Photolytic rearrangement of phosphorus azide : evidence for a transient metaphosphonimidate. (1980) (22)
- Reactivity of a Phosphanylcarbene (λ5‐Phosphaacetylene) with Lewis Acids: X‐Ray Crystal Structures of the First Carbene‐Gallane Complex and C‐Gallyl‐Substituted Phosphorus Ylide (1994) (21)
- The “Phosphonioyl(phosphoranediyl)carbene” [(iPr2N)2P(H)CP(NiPr2)2]+ as a Source of New 1,3‐Diphosphaallene Ylides: The First Carbodiphosphoranes with P ? H Bonds (1993) (21)
- Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. (2011) (21)
- Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. (2004) (21)
- Let's Play with Valence Isomers : The Influence of Different Main Group Elements on Their Relative Stability (2007) (21)
- Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2. (2011) (21)
- Synthesis, Structure, and Reactivity of a 1σ4,3σ2‐Diphosphaallene (2000) (20)
- 1σ4,2σx-Diphosphetes (x = 2−6): On the Persistence of the P−P Bond (1997) (20)
- Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds. (2008) (20)
- Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. (2009) (20)
- α,β-(Phosphino)(aminocarbene) and α,ω-(Phosphino)(oxyaminocarbene): New Bidentate Ligands for Transition Metal Complexes (2004) (19)
- Synthetic Utility of Stable Phosphanylcarbenes: Synthesis and Crystal Structure of an α-(Lithiomethylene)phosphorane. (1999) (19)
- Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO. (2020) (19)
- Formation of nitrilimines and diazo compounds from lithiated and stannyl diazo derivatives : scope and mechanism (1992) (19)
- The influence of C(sp3)H-Selenium Interactions on the 77 Se NMR Quantification of the p -Accepting Properties of Carbenes. (2020) (19)
- DBU und DBN als starke Nucleophile: Kristallstrukturen onio‐ und dioniosubstituierter Phosphane (1993) (19)
- Lawesson's Reagent: An Efficient 1,3-Dipole Trapping Agent (1995) (19)
- Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations (1994) (19)
- Mechanism of the exchange reaction of halodiazirines with nucleophiles revisited. Synthesis of neutral, mono- or dicationic 4-16-membered phosphorus heterocycles (1996) (19)
- Synthesis and evolution of phosphanylcarbene–borane adducts (1993) (19)
- Synthesis of Stable Multifunctional C-Phosphonio Phosphorus Vinyl Ylides. (1996) (18)
- Transmetalation Reaction of Dimethylzinc and (Bis(2-pyridyl)methyl)lithium (2000) (18)
- Ein luftstabiles Oxyallyl‐Radikalkation (2013) (18)
- A Distillable C‐ and N‐Silylated Nitrile Imine (1989) (18)
- New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. (2006) (18)
- A persistent P,N-heterocyclic carbene. (2008) (18)
- Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation reactions. (2019) (18)
- Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise (2015) (18)
- Synthesis and reactivity of stable silyl-substituted nitrilimines (1991) (18)
- Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. (2008) (18)
- Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes. (2008) (18)
- Phosphonitriles: versatile intermediates (1986) (18)
- Synthesis of stable boryl-substituted diazomethane and nitrilimines (1991) (17)
- X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. (1996) (17)
- Spontane Bildung stabiler Phosphino(silyl)carbene aus instabilen Diazoverbindungen (1990) (17)
- Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. (2005) (17)
- Synthesis of phosphaformamidines and phosphaformamidinates. (2007) (17)
- Evidence for Imidoylnitrene Intermediates in the Reaction of Bromophenyldiazirine with Phosphines: First Ring-Expansion Reaction of a Diazirine (1994) (17)
- 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. (2008) (17)
- Versatile photochemical behavior of phosphorus azides: Curtius-type rearrangement and diverse fates of .alpha.-phosphorus nitrenes (1985) (17)
- C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. (2012) (17)
- First Direct Evidence for Nitrile Imine‐Diazo Isomerization. Synthesis of Relatively Stable N‐Silylated Nitrile Imines (1988) (16)
- N-Phosphino- and N-Phosphonionitrilimines: From Nucleophilic to Electrophilic 1,3-Dipoles. (1997) (16)
- Reactions of a Stable (Phosphanyl)(silyl)carbene with Aliphatic Aldehydes: [2+1] versus [2+2] Addition to a Carbonyl Group (2003) (16)
- Synthesis and Reactivity of a Stable η2-(Diphosphirenylium)W(CO)5 Complex (1997) (16)
- The Azide-Nitrilimine Analogy in Aluminum Chemistry. (1998) (16)
- An N‐Phosphino C‐ThiophosphinoyI Nitrilimine as a Formal 1,4 Dipole: Synthesis of 1,2,3λ5‐Diaza‐ and 1,2,4,3λ5‐Triazaphosphinines (1990) (16)
- A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. (2005) (16)
- Reaction of the (trimethylsilyl)diazomethane anion with metal complexes: synthesis and x-ray study of iodomethyltris(trimethylphosphine)rhodium(III) (trimethylsilyl)diazomethane, RhICH3(PMe3)3{C(N2)SiMe3} (1987) (16)
- Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. (2019) (16)
- Intercepting a Transient Phosphino-Arsinidene. (2018) (16)
- A crystalline monosubstituted carbene (2018) (15)
- α‐ und β‐Hydridabstraktion in Gold(I)‐alkylkomplexen (2013) (15)
- From 1σ4, 2σ2 to 1σ4, 2σn‐Diphosphetes (n = 3–6): The Surprising Persistence of the PP bond (1996) (15)
- New synthesis and first x-ray crystal study of a C-borylated phosphorus ylide (1991) (15)
- Erster Hinweis auf ein intermediäres Nitrilo‐λ5‐phosphan (1984) (15)
- Recently reported crystalline isothiazole carbenes: myth or reality. (2007) (15)
- Nucleophilic additions to a diphosphirenium salt: ring opening and ring expansion reactions (1994) (15)
- The first "naked" primary phosphanide anion [ArPH](-). (2002) (15)
- Transition metal complexes and cycloaddition products of pentafluorophenyl isocyanide (1998) (15)
- Dimerization of a Cyclo‐1σ4,3σ2,4σ2‐Triphosphapentadienyl Radical: Evidence for Phosphorus–Phosphorus Odd‐Electron Bonds (2005) (15)
- Ruthenium Carbene Complexes Containing a Triazolidene Cationic Ligand (2001) (15)
- Stable Cyclic Carbenes and Related Species Beyond Diaminocarbenes (2011) (15)
- Synthesis and Reactivity of the First Spectroscopically Observed 1H-Diazirine (1996) (14)
- Kinetics and mechanism of the pyrolysis of 6-oxa-3,3-dimethyl-3-silabicyclo[3.1.0]hexane, a dimethylsilanone precursor (1985) (14)
- Free and Supported Phosphorus Ylides as Strong Neutral Brønsted Bases. (1999) (14)
- Gold‐vermittelte Cyclisierung: ob sechsgliedriges mesoionisches Carben oder acyclischer (Aryl)(heteroaryl)‐Carbenkomplex – entscheidend ist die Oxidationsstufe (2013) (14)
- Transient Amino-Hydrazino-Carbenes: A Radical Pathway for Intramolecular 1,2-Migration Reactions (2007) (14)
- Evidence for radical fragmentations from persistent singlet carbenes. (2005) (14)
- BIS(PHOSPHINO)CARBODIIMIDE : A BIS(1,3)-DIPOLE (1994) (14)
- THE INFERIOR P-DONOR ABILITY OF PHOSPHANYL VERSUS AMINO SUBSTITUENTS : CONSEQUENCES ON THE STABILITY AND REACTIVITY OF PHOSPHANYL- AND AMINOCARBENES (1998) (14)
- Synthesis and reactivity of a stable crystalline diastereomerically pure trifluoromethanesulfinic acid derivative: (S)-(−)-1-trifluoromethylsulfinyl-(R)-4-phenyloxazolidin-2-one (2003) (14)
- Preparation of mono- and bis(germyl)nitrilimines from germylenes and stannyl diazo derivatives (1994) (14)
- Synthese eines 2H‐Azirins durch [1 + 2]‐Cycloaddition eines Phosphinocarbens an ein Nitril und Anschließende Ringerweiterung zu einem 1,2λ5‐Azaphosphet (1995) (13)
- Reactivity of a stable phosphinonitrene towards small molecules. (2015) (13)
- Stannylene and germylene as powerful dechlorinated reagents : new route to diphosphene (1983) (13)
- Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. (2003) (13)
- Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts. (2006) (13)
- Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. (2016) (13)
- STEREOSPECIFIC FORMATION OF A 1,2λ3 -AZAPHOSPETANE IN THE THERMOLYSIS OF BIS[BIS(DIISOPROPYLAMINO)PHOSPHANYL] DIAZOMETHANE (1990) (13)
- Silaheterocyclen, XXIII. Synthese und Thermolyseverhalten von Si-funktionellen 2-Silaazetidinen (1993) (13)
- Effect of lithiation on the reactivity of diazo derivatives with sulfonylalkynes: application to the synthesis of three isomeric trisubstituted pyrazoles (1999) (12)
- Addition of a Diphosphirenium Salt to Palladium(0) Complexes: The First Examples of Diphosphametallacyclobutenes (1995) (12)
- Easy and Efficient Generation of Reactive Anions with Free and Supported Ylides as Neutral Brønsted Bases (2000) (12)
- Synthesis of the first distillable .alpha.-boranyldiazomethane. Direct evidence for a lithioboranyldiazomethane-lithioboranylisodiazomethane [(>BCNN-,Li+)-(>BNNC-,Li+)] rearrangement (1991) (12)
- Phosphorous Chemistry: Introduction (1994) (12)
- A crystalline phosphenium salt featuring the electron-withdrawing 2,6-bis(trifluoromethyl)phenyl group (2002) (12)
- Formation of the monoanion [Ar*P(BH3)(mu-BH2)2H]- with a symmetrically bridging hydride from the attempted synthesis of the dianion [Ar*P(BH3)3]2-. (2001) (12)
- Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis. (2020) (12)
- Aluminum Chloride-Promoted Aminolysis of N-Tosyl Lactams (1994) (12)
- Photolytic rearrangement of germanium azides. Evidence for transient germa-imines (1981) (12)
- The Chemistry of Phosphinocarbenes (1999) (12)
- Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. (2005) (12)
- Stable N‐Phosphanyl Nitrilimines: Reactivity on the Periphery of the Nitrilimine Skeleton (1991) (12)
- Reaction of a stable phosphinocarbene with germane- and stannanediyls: evidence for C-phosphinogerma and C-phosphinostannaethene to C-germyl- and C-stannylphosphaalkene rearrangements (1992) (12)
- REACTIVITY OF PHOSPHONITRILES WITH LOW-COORDINATED PHOSPHORUS DOUBLE-BONDED COMPOUNDS (1989) (12)
- First structural characterization of an α-diazophosphane: crystal structure of bis[bis(diisopropylamino)phosphanyl]diazomethane [(i-Pr2N)2P]2CN2 (1989) (11)
- Experimental and computational studies of anti-Bredt amidinium salts. (2013) (11)
- New routes to free and coordinated 1H-diphosphirenes (1997) (11)
- TUNGSTEN CARBONYL COMPLEXES OF 1H-DIPHOSPHIRENES AND DIPHOSPHIRENYLIUM SALTS (1999) (11)
- Cyclic(Alkyl)(Amino)Carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes. (2021) (11)
- The Phosphorus Version of the Oxaspiropentene−Cyclobutenone Rearrangement (2010) (11)
- A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. (2002) (11)
- A Straightforward Synthesis of Nitrilimines; X‐Ray Crystal Structure of a Nitrilimine Stabilized by Non‐Heteroatom Substituents (1992) (10)
- C‐Phosphoniophosphaalkenes as Precursors of 1σ4,3σ2‐Diphosphaallenes: Scope and Limitations (2005) (10)
- First example of prototropism in iminobis(phosphines) induced by phosphorus alkylation (1986) (10)
- The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis† †Electronic supplementary information (ESI) available: Experimental procedures, NMR spectra. CCDC 1919315. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02810b (2019) (10)
- Structural investigation into the suprising stability of free and complexed bis(amino) phosphine azides (1995) (10)
- Ein N-Phosphino-C-thiophosphinoylnitrilimin als formaler 1,4-Dipol: Synthese von 1,2,3λ5-Diaza- und 1,2,4,3λ5-Triazaphosphininen† (1990) (10)
- Ylidische viergliedrige Vier‐π‐Elektronen‐λ5‐Phosphorheterocyclen: elektronische Heterocyclobutadien‐Isomere (1998) (10)
- The Quest for Diphosphirenium and Diphosphirenylium Salts, Diheteroatom-Containing Cyclopropenium Analogues (1999) (10)
- (Aryl)(phosphanyl)Carbene: Ground‐ and Excited‐State Reactions (2003) (10)
- Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. (2009) (10)
- First evidence for a Curtius-type rearrangement involving a pentacoordinated atom (1984) (10)
- Synthesis and X-ray crystal structure of bis(germyl)carbodiimides. Spectroscopic characterization of (hydrogeno)(germyl)cyanamides (1998) (10)
- Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. (2008) (10)
- Von 1σ4, 2σ2‐ zu 1σ4, 2σn‐Diphospheten (n = 3–6): die überraschende Beständigkeit der P‐P‐Bindung (1996) (10)
- Synthesis of a Cationic 1,3‐Diphospha‐2,4‐dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidal μ2‐Phosphinidene (1996) (9)
- An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene. (2007) (9)
- Reaktivität eines Phosphanylcarbens (λ5‐Phosphaacetylens) gegenüber Lewis‐Säuren: Strukturen des ersten Carben‐Gallan‐Komplexes und eines C‐Gallyl‐substituierten Phosphor‐Ylids (1994) (9)
- Evidence for .alpha.-phosphanyl-.alpha.'-sulfinylcarbene to .alpha.-phosphoranyl-.alpha.'-sulfanylcarbene rearrangement. Synthesis of 2-oxo- and 2-thioxo-1,2-.lambda.5-azaphosphetanes (1989) (9)
- Direct Evidence for a Nitrile Imine–Imidoylnitrene Rearrangement: X‐Ray Crystal Structure of an Unusual Nitrene Complex (1990) (9)
- .lambda.5-Phosphonitriles and .lambda.3-Phosphinonitrenes: Evidence for Nitrene-Lewis Acid Adducts (1994) (9)
- X-ray crystal structure and reactivity of an N-phosphonio-substituted nitrilimine: a stable electrophilic nitrilimine (1991) (9)
- An Efficient Synthesis of Azathia Analogs of Platelet-Activating Factor (1984) (9)
- Stable Singlet Carbenes (2005) (8)
- Introduction to main group chemistry. (2010) (8)
- The serendipitous discovery of a readily available redox-bistable molecule derived from cyclic(alkyl)(amino)carbenes (2018) (8)
- Ein destillierbares C‐ und N‐silyliertes Nitrilimin (1989) (8)
- A new reaction involving 1,5-diazabicyclo[4.3.0]non-5-ene as a nucleophile and a two proton donor (1995) (8)
- Das „Phosphonioyl(phosphorandiyl)carben” [(iPr2N)2P(H)CP(NiPr2)2]+ als Quelle neuartiger Diphosphaallene mit Ylid-Struktur: die ersten Car-bodiphosphorane mit H-substituiertem Phosphor† (1993) (8)
- The ‘one-pot’ syntheses of α,α′-diphosphino-substituted imines: a unique reaction of bulky bis(dialkylamino)chlorophosphines (2001) (8)
- Reactivity of a (Diazomethylene)phosphorane with Alkylating Agents and Lewis Acids; Synthesis of the First α-Diazoalkylborates† (1991) (8)
- Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. (2003) (8)
- Erster direkter Nachweis einer Nitrilimin‐Diazo‐Isomerisierung und Synthese relativ stabiler N‐silylierter Nitrilimine (1988) (8)
- Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes. (2019) (8)
- A New Route to Nitrile Oxides via α‐Nitrosodiazo Derivatives (1988) (8)
- First evidence for a curtius type rearrangement involving a charged atom. An easy synthesis of an iminophosphonium salt (1984) (7)
- Aluminum Chloride Promoted Aminolysis of Lactams (1992) (7)
- a-Diazophosphines Stables Analogie ?3-Phosphinocarbene/?5-Phosphaacetylene (1986) (7)
- Synthesis of N-bonded diazoalkane complexes via the reaction of the trimethylsilyldiazomethane anion with M(CO)5PPh3(M = Cr; W): X-ray structure of W(CO)4(PPh3)[N2C(SiMe3)2] (1988) (7)
- Transition metal complexes featuring a diazo group on a ligand: x-ray crystal structure of manganese complex [exo-(Me3SiCN2)-.eta.5-C6H6]Mn (CO)3 (1993) (7)
- Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. (2020) (7)
- A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. (2006) (7)
- Le rearrangement de claisen en series siliciee et germaniee: silaethylene et germaethylene (1981) (7)
- Synthesis and electrocyclic ring opening of 1,3,2.lambda.3,4.lambda.5-diazadiphosphetenes (1987) (7)
- Photochemical behavior of thioxophosphoranyl diazo compounds: evidence for transient .lambda.5-phosphathiirenes and for structural isomerizations of the diazo group (1992) (7)
- Phosphonitriles: Versatile Intermediates. (1986) (7)
- nido-Five-vertex clusters: in and out of boron chemistry. (2003) (7)
- Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino)carbene gold(I) complexes (2016) (7)
- A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. (2016) (7)
- Diphosphorus-Containing Unsaturated Three-Membered Rings: Comparison of Carbon, Nitrogen, and Phosphorus Chemistry (2003) (7)
- Photolysis of Phosphoniums and Phosphoranes Azides (1983) (6)
- Gold‐Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine. (2011) (6)
- Stable Phosphanyl Silyl Carbenes: Synthesis and Reactivity. (1992) (6)
- (CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes. (2022) (6)
- Transient Palladadiphosphanylcarbenes: Singlet Carbenes with an “Inverse” Electronic Configuration (pπ2 instead of σ2) and Unusual Transannular Metal–Carbene Interactions (πC→pd Donation and σPd→C Back-donation) (2007) (6)
- Asymmetric induction at silicon from prochiral silaethylenes (1980) (6)
- C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. (2003) (6)
- Synthesis of a Persistent 1σ3,3σ3‐Diphosphaallyl Cation Featuring a Localized Phosphorus−Carbon Double Bond (2004) (6)
- Eine einfache Synthese von Nitriliminen; Röntgenstrukturanalyse eines nicht durch Heteroatomsubstituenten stabilisierten Nitrilimins (1992) (5)
- Azides of heavier main group elements: The reluctance of phosphine azides to undergo a curtius-type rearrangement (1985) (5)
- Präparativer Nutzen stabiler Phosphanylcarbene: Synthese und Kristallstruktur eines α‐(Lithiomethylen)phosphorans (1999) (5)
- Triple-Bonded-Like Tricoordinated Phosphorus Species P= (1987) (5)
- Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties. (2022) (5)
- The Influence of C(sp 3 )H–Selenium Interactions on the 77 Se NMR Quantification of the π‐Accepting Properties of Carbenes (2020) (5)
- Surprising reactivity of very crowded phosphinic derivatives (1982) (5)
- Substitution Reactions at Nitrilimine Skeletons (1992) (5)
- PHOSPHORUS-NITROGEN TRIPLE-BONDED SPECIES (1986) (5)
- Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents. (2020) (5)
- Ligand properties of 1H-diphosphirenes and diphosphirenylium salts towards iron carbonyl fragments (1999) (5)
- Phosphanylcarbenes: From Unstable Intermediates to X-Ray Characterized Compounds (1993) (5)
- Role of the 2,6-Bis(trifluoromethyl)phenyl Group on the Acidity of the Corresponding Phosphane (‡) (2004) (5)
- Glaisen rearrangement in the silicon series. (1979) (4)
- The peculiar behavior of a diphosphirenium salt towards sodium η5-cyclopentadienyl(dicarbonyl)ferrate (2000) (4)
- Synthesis and multinuclear NMR characterization of iminophosphoranyl phosphines and silanes (1996) (4)
- Reaction of a stable aminoarylcarbene with 2-chloroacrylonitrile: dearomatizing cyclization rather than cyclopropanation (2004) (4)
- Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three‐Component Preparation of 1,2‐Dihydroquinoline Derivatives. (2009) (4)
- Thermal and metal-catalyzed rearrangements of bis(stannyl)diazo derivatives into carbodiimides : carbodiimide-transfer reactions (1993) (4)
- N-Cyano-P-Hydrogenoiminophosphorane Trimethylchlorostannane Adducts (R(2)P(H)=n-C-N-Center-Dot-Me(3)SnCl) and Related Species - Building-Blocks for bis(Carbodiimides) of Phosphorus (1994) (4)
- Synthesis of extended polyphosphacumulenes. (2006) (4)
- The surprisingly facile dehydrohalogenation of a hydrazonoyl chloride into a stable phosphorus-substituted nitrilimine (1992) (4)
- Stable Singlet Carbenes as Organic Superbases. (2021) (4)
- Ein neuer Weg zu Nitriloxiden über α-Nitroso-diazo-Derivate† (1988) (4)
- A Synthetic and Structural Investigation (2009) (4)
- Preparation of novel low-coordinate chloro and azido phosphorus-nitrogen compounds. Attempted synthesis of cyclodiphosphazenes (1991) (4)
- The reactions of some azides with an anionic phosphorus(III) complex (1985) (4)
- Nachweis einer Nitrilimin‐Imidoylnitren‐Umlagerung: Röntgenstrukturanalyse eines ungewöhnlichen Nitren‐Komplexes (1990) (3)
- Synthesis and structural characterization of unusual amido samarium(III) complexes (2003) (3)
- The First Coordination of an (α-Diazo)phosphine to a Transition-Metal Center (2003) (3)
- Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis (2019) (3)
- Diphosphetes—substituent stabilized ring systems (2000) (3)
- SYNTHESE DE LA d,l-(ACETOXY-2 OCTADECYLTHIO-1) PROPYL-3 PHOSPHORYLCHOLINE OU THIA-PAF (1984) (3)
- Oxidation of a stable 1,3-diborata-2,4-diphosphonio-cyclobutane-1,3-diyl (2010) (3)
- DIE AZID-NITRILIMIN-ANALOGIE IN DER ALUMINIUM-CHEMIE (1998) (3)
- Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. (2020) (3)
- anti‐Bredt N‐Heterocyclic Carbene: An Efficient Ligand for the Gold(I)‐Catalyzed Hydroamination of Terminal Alkynes with Parent Hydrazine. (2013) (3)
- Das elektrophile Verhalten von stabilen Phosphanylcarbenen gegenüber den freien Elektronenpaaren des Phosphoratoms (1999) (3)
- The first nitrogen NMR spectroscopic study of nitrile imides (nitrilimines) (1991) (3)
- Reaktivität eines (Diazomethylen)phosphorans gegenüber Alkylierungsmitteln und Lewis-Säuren; Synthese der ersten α-Diazoalkylborate† (1991) (3)
- Electron-impact and flash-vacuum pyrolysis of trivalent and pentavalent phosphorus azides: generation of original unsaturated mono-, di-, and tricoordinated phosphorus cations (1990) (2)
- First Example of Prototropism in Iminobis(phosphines) Induced by Phosphorus Alkylation. (1986) (2)
- Modern Arene Chemistry: Concepts, Synthesis and Applications. Edited by Didier Astruc (2004) (2)
- Synthesis and Reactivity of the First Stable λ5-Phosphaacetylene (1990) (2)
- Ein kationisches 1,3-Diphospha-2,4-dipallada(II)-tricyclo[1.1.1]pentan-Derivat: das erste strukturell charakterisierte pyramidale μ2-Phosphiniden†‡ (1995) (2)
- Synthesis and reactivity of diazomethylenephosphoranes (P=C=N2) (1992) (2)
- Use of Phosphorus for Stabilizing Highly Reactive Organic Species: Nitrileimines and Pseudo-Diazoalkenes (1990) (2)
- Ansätze eines systembezogenen Bruchsicherheitsnachweises am Beispiel vorgespannter verbundfreier Schalenträger. (1986) (2)
- 2,2,4,4‐Tetrabromo‐1,1,3,3‐tetramethylcyclodiborazane (2007) (2)
- Synthese De LaD,1-(Acetoxy-3 Octadecylthio-1) Propyl-2 Phosphorylcholine: Un Isomere Geometrique Du Thia-Paf (1986) (2)
- 4-π-Electron 4-Membered Phosphorus Heterocycles (1996) (2)
- Reactions of a Stable (Phosphanyl)(silyl)carbene with Aliphatic Aldehydes: [2 + 1] versus [2 + 2] Addition to a Carbonyl Group. (2003) (1)
- An Air-Stable "Masked" Bis(imino)carbene: A Carbon-Based Dual Ambiphile. (2023) (1)
- Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). (2007) (1)
- Synthesis and Rearrangement of Intramolecularly Stabilized 1σ2,3. sigma.2‐Diphosphaallylic Cations into Intramolecularly Stabilized 1. sigma.1,3σ3‐Diphosphaallylic Cations. (1994) (1)
- The triplet state of deprotonated mesoionic carbene Breslow intermediates is thermally accessible: Distal difunctionalization of aldehydes (2022) (1)
- Stable Singlet Diradicals Based on Boron and Phosphorus (2006) (1)
- Free and Supported Phosphorus Ylides as Strong Neutral Broensted Bases. (2010) (1)
- EVIDENCE FOR A TRANSIENT ACYLPHOSPHENIUM ION (1997) (1)
- Effects of a strong electron-withdrawing N-boryl substituent on the stability of nitrilimines : surprising dimerization involving the nitrilimine heteroatom substituents with formation of (fused) bicyclic [3.3.0] and [4.3.0] derivatives (1994) (1)
- Easy and Efficient Generation of Reactive Anions with Free and Supported Ylides as Neutral Broensted Bases. (2000) (1)
- Synthesis and characterization of a pyrazolium bearing N-heterocyclic carbene–palladium(II) complex (2013) (1)
- Free and supported phosphorus ylides: efficient, neutral non-nucleophilic Brønsted bases with a wide utility in organic synthesis (2000) (1)
- Neuartige stabile Aldehyde: Formylphosphane und Formylphosphanoxide (1999) (1)
- Synthesis of a 2H-Azirine by (1 + 2)-Cycloaddition of a Phosphinocarbene and a Nitrile Followed by Ring Enlargement to a 1,2. lambda.5-Azaphosphete. (1995) (1)
- Substitution Reactions at Nitrilimine Skeletons. (1992) (1)
- Synthesis and Reactivity of Cyclic 4-π Electron Ylides: Non-Antiaromatic Inorganic Ring Systems (1994) (1)
- Stable Singlet Carbenes as Organic Superbases (2021) (1)
- Synthesis and X‐Ray Crystal Structure of the First Diphosphirenium Salt. (1992) (1)
- Titelbild: Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2 (Angew. Chem. 42/2011) (2011) (1)
- Photolytic Rearrangement of Phosphorus, Germanium, and Silicon Azides: Evidence for New Hybridized Species (1981) (1)
- Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes". (2019) (1)
- Free and Supported Phosphorus Ylides: Efficient, Neutral Non‐nucleophilic Bronsted Bases with a Wide Utility of Organic Synthesis (2001) (0)
- Synthesis of the First Distillable α-Boranyldiazomethane. Direct Evidence of Lithioboranyldiazomethane-Lithioboranylisodiazomethane ((> BCNN-,Li+)-(> BNNC-,Li+)) Rearrangement. (1991) (0)
- A Straightforward Synthesis of Nitrilimines; X‐Ray Crystal Structure of a Nitrilimine Not Stabilized by Heteroatom Substituents. (1992) (0)
- Ligand Behavior of a (Z)‐Phosphazide (a 1,2,3,4λ5‐ Triazaphosphinine) and of the Corresponding Phosphazene (a 1,2λ 5‐Azaphosphete). (1996) (0)
- Cyclic (amino)(barrelene)carbenes: an original family of CAACs through a novel synthetic pathway. (2022) (0)
- Spontaneous Formation of Stable Phosphino(silyl)carbenes from Unstable Diazo Compounds. (1991) (0)
- polyorganosiloxanes of Preparation Method (pos) by polycondensation / redistribution of oligosiloxanes, in the presence of a superbase and employed superbases (2001) (0)
- Synthesis, Structure, and Reactivity of a 1σ4,3σ2-Diphosphaallene. (2000) (0)
- DELOCALIZATION ACROSS A SILICON ATOM. FORMATION OF A SILICENIUM ION IN THE TRAPPING OF 2-METHYL-2-SILA-1,3-BUTADIENE (1978) (0)
- Use of zinc derivatives as polymerization of cyclic esters (2002) (0)
- A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes (2023) (0)
- Bis(stannyl)diazo Derivatives and Their Structural Isomers: Powerful CN22‐Transfer Agents (1996) (0)
- A new approach to the synthesis of diazomethylenephosphoranes (P=C=N2) (1995) (0)
- A Career in Catalysis: Jean-Marie M. Basset (2022) (0)
- Ambivalent Role of Rotamers in Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Enantioselective Ring-Opening Cross-Metathesis (2023) (0)
- λ3-Phosphinocarbenes λ3-Phosphaacetylenes (1995) (0)
- A NEW ROUTE TO BIS(2,4,6-TRI-TERT-BUTYLPHENYL)DIPHOSPHENE VIA A SILYLATED COMPOUND (1983) (0)
- Electronic Structure of λ5-Phosphaacetylenes and Corresponding Triplet Methylenes. (2010) (0)
- First Evidence for a Curtius-Type Rearrangement Involving a Pentacoordinated Atom. (1985) (0)
- FIRST ASYMMETRIC SYNTHESIS OF FUNCTIONALIZED MONOAROMATIC OR NONAROMATIC SILANES FROM PROCHIRAL SILAETHYLENES (1982) (0)
- Synthesis and Reactivity of Diazomethylenephosphoranes. (1993) (0)
- Metal complexes with tridentate ligand as polymerization catalysts. (1998) (0)
- New organometallic complexes comprising cationic heterocyclic carbenes and their method of preparing (1998) (0)
- From Unstable Diazoalkenes to Stable Pseudo-Diazoalkenes: Creating Useful Synthons from Reactive Intermediates (1996) (0)
- PHOTOLYTIC REARRANGEMENT OF GERMANIUM AZIDES. EVIDENCE FOR TRANSIENT GERMAIMINES (1981) (0)
- The “One-Pot” Syntheses of α,α′-Diphosphino-Substituted Imines: A Unique Reaction of Bulky Bis(dialkylamino)chlorophosphines. (2001) (0)
- Main Group Chemistry—1999 ICMGC Award (2002) (0)
- Organophosphorus Compounds. Part 123. Trimethylsilylphosphaacetylene as Cycloaddition Partner for 1,3-Dipoles. (1998) (0)
- ORGANOPHOSPHORUS COMPOUNDS ; 123. TRIMETHYLSILYLPHOSPHAACETYLENE AS CYCLOADDITION PARTNER FOR 1,3-DIPOLES (1997) (0)
- A New Approach to the Synthesis of Diazomethylenephosphoranes. (1996) (0)
- THE SILICON-CARBON DOUBLE BOND. A SURVEY OF RECENT EXPERIMENTAL AND THEORETICAL RESULTS (1982) (0)
- Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). (2023) (0)
- FIRST EVIDENCE FOR A CURTIUS-TYPE REARRANGEMENT INVOLVING A CHARGED ATOM. AN EASY SYNTHESIS OF AN IMINOPHOSPHONIUM SALT (1984) (0)
- The Stable (Phosphino)(silyl)carbene (I) as a Useful Building Block: Synthesis and Reactivity of 2‐Phosphorus‐Substituted 2H‐Azirines. (1998) (0)
- Reaction of a Stable Phosphinocarbene with Germane‐ and Stannanediyls: Evidence for C‐Phosphanylgerma‐ and C‐Phosphanylstannaethene to C‐ Germyl‐ and C‐Stannylphosphaalkene Rearrangements. (2010) (0)
- Synthesis and Reactivity of Stable Phosphorus-Substituted Nitrilimines. X-Ray Crystal Structure of C-(Bis(diisopropylamino)thioxophosphoranyl)-N-(bis(diisopropylamino)phosphanyl)nitrilimine. (1990) (0)
- λ5-Phosphonitriles-λ3-Phosphinonitrenes: Evidence for Nitrene-Lewis Acid Adducts. (1994) (0)
- X-ray crystal structure and reactivity of an N-phosphonio-substituted (2008) (0)
- Stable Versions of Transient Singlet Carbenes (2002) (0)
- Novel compounds containing a Group 13 element that is bonded with a mono- or dianionic tridentate ligand, a process for their preparation and their use as polymerization catalysts (1997) (0)
- Photochemical and Thermal Rearrangement of Heavier Main‐Group Element Azides (1986) (0)
- C-Phosphanylgerma- and C-Phosphanykmnaethene to C-Germyl- and C-Stannylphosphaalkene Rearrangements (1992) (0)
- λ5-Phosphetes, Benzo-λ5-phosphetes, Naphtho-λ5- phosphetes: Four-π-, Eight-π-, and Twelve-π-Electron Systems. (1996) (0)
- How To Enhance the Efficiency of Breslow Intermediates for SET Catalysis. (2023) (0)
- Straightforward synthesis of polyallylphosphazenes from poly(dichlorophosphazene) (1993) (0)
- Effect of Lithiation on the Reactivity of Diazo Derivatives with Sulfonylalkynes: Application to the Synthesis of Three Isomeric Trisubstituted Pyrazoles. (1999) (0)
- The Bis(diisopropylamino)phosphino Group: A Wonderful Tool for the Stabilization and NMR Characterization of Highly Reactive Species (1995) (0)
- A Stable P-Heterocyclic Carbene (2005) (0)
- Stable N-Phosphanyl Nitrilimines: Reactivity on the Periphery of the Nitrilimine Skeleton. (1991) (0)
- Process for the preparation of new N-substituted derivatives of 5-amino-phenylpyrazole, new N-substituted derivatives of 5-amino-phenylpyrazole and their use as parasiticidal agents and / or insecticides (2001) (0)
- From 2-Phosphino-2H-phosphirene to 1-Phosphino-1H-phosphirene, 1λ5,2λ3-Diphosphete, and 1,2-Dihydro-1λ3,2λ3-diphosphete: An Experimental and Theoretical Study. (2010) (0)
- Reactivity of a (Diazomethylene)phosphorane Toward Alkylation Agents and Lewis Acids; Synthesis of the First α-Diazoalkylborates. (1991) (0)
- Production of acyl isocyanate (1996) (0)
- THERMOLYSIS OF 6‐OXA‐3‐SILABICYCLO(3.1.0)HEXANES: A NEW CONVENIENT ROUTE TO SILICON‐OXYGEN Π‐BONDED SPECIES (1984) (0)
- Oxidation-induced ring expansion of a 2-phosphino-2H-azirine (1998) (0)
- An N‐Phosphanyl‐C‐thiophosphoranylnitrilimine as Formal 1,4‐Dipole. Synthesis of 1,2,3λ5‐Diaza‐ and 1,2,4,3λ5‐Triazaphosphinines. (1990) (0)
- Main group chemistry – 2002 ICMGC award (2004) (0)
- X‐Ray Crystal Structure and Reactivity of an N‐Phosphonio‐Substituted Nitrilimine: A Stable Electrophilic Nitrilimine (1991) (0)
- Let′s Play with Valence Isomers: The Influence of Different Main Group Elements on Their Relative Stability (2007) (0)
- Aluminum Chloride Promoted Aminolysis of Lactams. (1993) (0)
- PREPARATION OF MONO(GERMYL)NITRILIMINES AND BIS(GERMYL)NITRILIMINES FROM GERMYLENES AND STANNYL DIAZO DERIVATIVES (1994) (0)
- Stable Carbenes: From Laboratory Curiosities to Powerful Tools (2013) (0)
- Preparation of Novel Low-Coordinate Chloro and Azido P-N Compounds. Attempted Synthesis of Cyclodiphosphazenes. (1992) (0)
- PHOTOLYTIC REARRANGEMENT OF PHOSPHORUS AZIDE: EVIDENCE FOR A TRANSIENT METAPHOSPHONIMIDATE (1981) (0)
- Asymmetric cyclic alkyl amino carbene (CAAC) ruthenium complexes as improved catalysts for ethenolysis (2013) (0)
- Metal-complex with a tridentatligand as polymerization catalysts (1998) (0)
- FIRST THERMAL ISOMERIZATIONS OF β-CHLORO SILICON COMPOUNDS INDUCED BY A β-VINYL GROUP (1981) (0)
- Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. (2022) (0)
- 2-II and 3-II-electron diphosphorus-containing 3-membered heterocycles (1999) (0)
- An air-stable radical with a redox-chameleonic amide. (2022) (0)
- Unsaturated Reactive Intermediates in Organosilicon Chemistry ‐ Recent Results (1986) (0)
- Use of Tin Derivatives for the Synthesis of Polyphosphazenes Featuring Phosphorus-Carbon Bonds (1993) (0)
- SYNTHESIS AND REARRANGEMENTS OF α‐FUNCTIONAL RINGS OF GERMANIUM‐ 6‐OXA‐2,2‐DIPHENYL‐2‐GERMABICYCLO(3.1.0)HEXANE AND 1,1‐DIPHENYL‐1‐GERMACYCLOPENTAN‐2‐OL. COMPARATIVE STUDY WITH ISOLOGOUS DERIVATIVES OF SILICON (1978) (0)
- On the Advantage of Cyclic over Acyclic Carbenes to Access (2017) (0)
- Synthesis, Reactivity, and Crystal Structure of the First Methylenephosphonium Ion: A Severely Twisted Valence Isoelectronic Olefin. (1989) (0)
- Synthesis of Onio‐, Dionio‐, and Trionio‐Substituted Phosphines; the Nucleophilic Behavior of DBN and DBU Towards Main Group Electrophiles. (1996) (0)
- Synthesis and Evolution of Phosphanylcarbene‐Borane Adducts. (1993) (0)
- Mesoionic Carbene-Catalyzed Formyl Alkylation of Aldehydes. (2023) (0)
- Cover Picture: (Aryl)(phosphanyl)Carbene: Ground‐ and Excited‐State Reactions (Eur. J. Org. Chem. 11/2003) (2003) (0)
- Highly Robust and Efficient Blechert-Type Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Olefin Metathesis (2023) (0)
- Morphological Peculiarities of the Niobium Oxidation. Part 1. Evolution of the Morphology in Dependence on the Temperature Range. (1992) (0)
- Cover Picture: σ‐Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. Int. Ed. 5/2004) (2004) (0)
- Co-h 1 PCO and Cuh 2 PCO complexes , conversion of an Ir – h 1 PCO complex into a dimetalladiphosphene , and an interaction-free PCO anion † (2016) (0)
- Titelbild: σ‐Bond Stretching: A Static Approach for a Dynamic Process (Angew. Chem. 5/2004) (2004) (0)
- SYNTHESES AND THERMAL REARRANGEMENTS OF 2-SILA- AND 3-SILA-6,6-DICHLOROBICYCLO(3.1.0)HEXANES (1978) (0)
- Stable α-Diazophosphines. Analogy between λ3-Phosphinocarbene and λ5-Phosphaacetylene. (1987) (0)
- Diphosphetes—Substituent Stabilized Ring Systems. (2001) (0)
- Synthesis and Reactivity of Stable Silyl‐Substituted Nitrilimines. (1991) (0)
- Ammonia and hydrazine. Transition-metal-catalyzed hydroamination and metal-free catalyzed functionalization (2012) (0)
- REACTIONS OF PHOSPHORUS ELECTROPHILES WITH ((η5-C5ME5)FE(CO)2)-; SPECTROSCOPIC EVIDENCE FOR A PHOSPHINIDENE COMPLEX (1985) (0)
- Six-coordinate ruthenium water oxidation catalysts bearing equatorial polypyridinedicarboxylato and axial phosphine ligands (2022) (0)
- Phosphonitriles: Powerful Intermediates in Heterocyclic Chemistry (1987) (0)
- Reactivity of Phosphonitriles with Low‐Coordinated Phosphorus Double‐Bonded Compounds. (1989) (0)
- Synthesis and Reactivity of a Stable Crystalline Diastereomerically Pure Trifluoromethanesulfinic Acid Derivative: (S)‐(‐)‐1‐Trifluoromethylsulfinyl‐(R)‐4‐phenyloxazolidine‐2‐one. (2003) (0)
- Photochemical Behavior of Thioxophosphoranyl Diazo Compounds: Evidence for Transient λ5-Phosphathiirenes and for Structural Isomerizations of the Diazo Group. (1992) (0)
- Formation of polyaza-phospholes and -phospholyl anions from diazomethylenephosphoranes induced by pseudo-aromaticity (1993) (0)
- Our Contribution to Stable Carbene Chemistry (2012) (0)
- Trialkylsilyldiazomethane Derivatives: Wonderful Chemical Building Blocks (2008) (0)
- Chemistry. The modest undressing of a silicon center. (2004) (0)
- XIIth European Colloquium on Heterocyclic Chemistry “Phosphorus azides, powerful reagents in heterocyclic chemistry” (2010) (0)
- Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Z-Stereoselective (Asymmetric) Olefin Metathesis (2022) (0)
- The “Phosphonioyl(phosphorandiyl)carbene” ((iPr2N)P(H)CP(NiPr2)2)+ as a Source of Novel Diphosphaallenes with Ylide Structure: The First Carbodiphosphoranes with H‐Substituted Phosphorus. (1993) (0)
- Cover Picture: Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2 (Angew. Chem. Int. Ed. 42/2011) (2011) (0)
- DBU and DBN as Strong Nucleophiles: X-Ray Crystal Structures of Onioand Dionio-Substituted Phosphines. (1993) (0)
- Phosphinocarbenes: The Only Stable Carbenes Exhibiting Electron‐Deficient Character (1999) (0)
- On the way to phosphino-phosphaalkynes (1999) (0)
- Synthesis of d,l-(3-Acetoxy-1-octadecylthio)propyl-2-phosphorylcholine: A Geometrical Isomer of Thia-PAF. (1987) (0)
- Organometallics (Roundtable 2011) (2012) (0)
- One-Pot Synthesis and Reactivity of New Tetrazoles, 1,3,4-Oxa- and 1,2,3-Thiadiazoles. (1998) (0)
- CLAISEN REARRANGEMENT IN THE SILICON SERIES (1979) (0)
- Use of zinc derivatives as catalysts for polymerization of cyclic esters. (2002) (0)
- First Direct Evidence for Nitrile Imine‐Diazo Isomerization. Synthesis of Relatively Stable N‐Silylated Nitrile Imines. (1989) (0)
- Silaheterocycles. Part 23. Synthesis and Thermolysis Reactions of Si- Functionalized 2-Silaazetidines. (1993) (0)
- nido-Cluster mit fünf Ecken: ein allgemeines Konzept aus der Borchemie† (2003) (0)
- Gold(I)-Catalyzed Hydroammoniumation and Methylaminationof Alkynes to Indoles (2010) (0)
- Copper(I) Complexes Bearing Carbenes Beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in “Click Chemistry”. (2016) (0)
- Neue Verbindungen, welche ein Element der Gruppen 11,12 oder 14 und ein dreizähniges Ligand enthalten, Verfahren zu ihrer Herstellung und ihre Verwendung, insbesondere als Polymerisationskatalysator (1997) (0)
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