Aaron Sadow
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Aaron Sadowchemistry Degrees
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Inorganic Chemistry
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Chemistry
Aaron Sadow's Degrees
- PhD Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Aaron Sadow Influential?
(Suggest an Edit or Addition)According to Wikipedia, Aaron David Sadow is an American chemist. Sadow earned a bachelor's of science degree in chemistry from Pennsylvania State University in 1997, and authored the honors thesis New Process for Synthesis of Polymers via Oxidative Carbonylation using Palladium Catalysts under the direction of Ayusman Sen. Sadow completed his doctoral dissertation, Early Transition Metal Complexes in σ-Bond Metathesis: The Activation of Si–H, Si–C, and C–H Bonds, in 2003, advised by T. Don Tilley of the University of California, Berkeley, then pursued postdoctoral research at ETH Zurich. Sadow joined the Iowa State University faculty in August 2005. In 2016, he was promoted to a full professorship. Sadow is a founding researcher for the Program on Plastics, Ecosystems, and Public Health, established in 2019 and based at the Institute for Sustainability and Energy at Northwestern University. Sadow was named the director of Ames National Laboratory's Institute for Cooperative Upcycling of Plastics in 2020, one of the Energy Frontier Research Centers established that year by the United States Department of Energy. Sadow is a 2022 fellow of the American Association for the Advancement of Science.
Aaron Sadow's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Upcycling Single-Use Polyethylene into High-Quality Liquid Products (2019) (155)
- Dynamic Nuclear Polarization Solid-State NMR in Heterogeneous Catalysis Research (2015) (139)
- Catalytic upcycling of high-density polyethylene via a processive mechanism (2020) (132)
- Enantioselective addition of secondary phosphines to methacrylonitrile: catalysis and mechanism. (2005) (127)
- Nickel(II)-catalyzed highly enantioselective hydrophosphination of methacrylonitrile. (2004) (124)
- Magnesium-catalyzed hydroboration of esters: evidence for a new zwitterionic mechanism (2014) (110)
- Tris(oxazolinyl)boratomagnesium-catalyzed cross-dehydrocoupling of organosilanes with amines, hydrazine, and ammonia. (2011) (108)
- A highly enantioselective zirconium catalyst for intramolecular alkene hydroamination: significant isotope effects on rate and stereoselectivity. (2011) (106)
- Concerted C-N and C-H bond formation in a magnesium-catalyzed hydroamination. (2010) (102)
- Selective Hydrogenation of Phenol Catalyzed by Palladium on High-Surface-Area Ceria at Room Temperature and Ambient Pressure (2015) (100)
- Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium. (2003) (97)
- Magnesium-Catalyzed Mild Reduction of Tertiary and Secondary Amides to Amines (2015) (96)
- Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. (2005) (94)
- Role Of CO2 As a Soft Oxidant For Dehydrogenation of Ethylbenzene to Styrene over a High-Surface-Area Ceria Catalyst (2015) (83)
- Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst. (2003) (81)
- Acceptorless photocatalytic dehydrogenation for alcohol decarbonylation and imine synthesis. (2012) (75)
- Coordinatively Saturated Tris(oxazolinyl)borato Zinc Hydride-Catalyzed Cross Dehydrocoupling of Silanes and Alcohols (2011) (74)
- Mesoporous Silica-Supported Amidozirconium-Catalyzed Carbonyl Hydroboration (2015) (71)
- Lewis acid-mediated beta-hydride abstraction reactions of divalent M(C(SiHMe(2))(3))(2)THF(2) (M = Ca, Yb). (2009) (68)
- Highly enantioselective zirconium-catalyzed cyclization of aminoalkenes. (2013) (68)
- Optically active, bulky tris(oxazolinyl)borato magnesium and calcium compounds for asymmetric hydroamination/cyclization (2011) (67)
- Palladium-catalyzed enantioselective allylic phosphination. (2008) (66)
- Concerted C–N/C–H Bond Formation in Highly Enantioselective Yttrium(III)-Catalyzed Hydroamination (2011) (58)
- Intermolecular β-Hydrogen Abstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl Compounds (2013) (54)
- A zwitterionic zirconium complex that catalyzes hydroamination of aminoalkenes at room temperature. (2010) (47)
- Conversion of a zinc disilazide to a zinc hydride mediated by LiCl. (2010) (47)
- Direct 3D Printing of Catalytically Active Structures (2017) (45)
- Remarkably robust monomeric alkylperoxyzinc compounds from tris(oxazolinyl)boratozinc alkyls and O2. (2012) (43)
- Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds. (2003) (40)
- Homoleptic Divalent Dialkyl Lanthanide-Catalyzed Cross-Dehydrocoupling of Silanes and Amines (2016) (34)
- A New Scorpionate Ligand: Tris(4,4-dimethyl-2-oxazolinyl)borate and Its Zirconium(IV) Complexes (2008) (34)
- Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters (2015) (33)
- Interconverting Lanthanum Hydride and Borohydride Catalysts for C=O Reduction and C-O Bond Cleavage. (2019) (32)
- Ligand exchange reactions and hydroamination with tris(oxazolinyl)borato yttrium compounds. (2009) (32)
- Zirconium-catalyzed desymmetrization of aminodialkenes and aminodialkynes through enantioselective hydroamination. (2015) (32)
- Enhanced Reactivity of Cationic Hafnocene Complexes toward σ-Bond Metathesis Reactions. Si−H and Si−C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions (2003) (29)
- Effects of biradical deuteration on the performance of DNP: towards better performing polarizing agents. (2016) (27)
- Bis(oxazolinyl)phenylborane: a Lewis acid-containing ligand for methide abstraction-based coordination to aluminum(III). (2010) (26)
- Lewis base mediated β-elimination and Lewis acid mediated insertion reactions of disilazido zirconium compounds. (2013) (24)
- In Silico Design of DNP Polarizing Agents: Can Current Dinitroxides Be Improved? (2017) (24)
- Improved strategies for DNP-enhanced 2D 1H-X heteronuclear correlation spectroscopy of surfaces. (2017) (24)
- Enhanced Reactivity of Cationic vs Neutral Hafnocene Complexes in Stoichiometric and Catalytic σ-Bond Metathesis Reactions Involving Si−H and Si−C Bonds (2001) (22)
- Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants (2021) (22)
- Organometallic Complexes of Bulky, Optically Active, C3-Symmetric Tris(4S-isopropyl-5,5-dimethyl-2-oxazolinyl)phenylborate (ToP*) (2015) (22)
- Reactions of Tris(oxazolinyl)phenylborato Rhodium(I) with C−X (X = Cl, Br, OTf) Bonds: Stereoselective Intermolecular Oxidative Addition (2010) (21)
- A tris(alkyl)yttrium compound containing six beta-agostic Si-H interactions. (2009) (21)
- Cerium-Catalyzed Hydrosilylation of Acrylates to Give α-Silyl Esters. (2017) (20)
- β-SiH-Containing Tris(silazido) Rare-Earth Complexes as Homogeneous and Grafted Single-Site Catalyst Precursors for Hydroamination (2017) (20)
- Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers (2019) (20)
- Activation of Arene C−H Bonds by a Cationic Hafnium Silyl Complex Possessing an α-Agostic Si−H Interaction (2002) (20)
- Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene. (2015) (20)
- Toward hydrogen economy: Selective guaiacol hydrogenolysis under ambient hydrogen pressure (2020) (20)
- Enhancing the Sensitivity of Solid-State NMR Experiments with Very Low Gyromagnetic Ratio Nuclei with Fast Magic Angle Spinning and Proton Detection. (2018) (19)
- Nonclassical β-hydrogen elimination of hydrosilazido zirconium compounds via direct hydrogen transfer. (2012) (19)
- Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins. (2022) (19)
- Easily prepared chiral scorpionates: tris(2-oxazolinyl)boratoiridium(i) compounds and their interactions with MeOTf. (2008) (18)
- Direct 17O dynamic nuclear polarization of single-site heterogeneous catalysts. (2018) (17)
- Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds. (2013) (17)
- Suppressing 1H Spin Diffusion in Fast MAS Proton Detected Heteronuclear Correlation Solid-State NMR Experiments. (2019) (16)
- Synthesis and Oxidation Catalysis of [Tris(oxazolinyl)borato]cobalt(II) Scorpionates (2016) (16)
- Transition metal-like carbocatalyst (2020) (15)
- Homoleptic Trivalent Tris(alkyl) Rare Earth Compounds. (2017) (15)
- Anodic electrochemistry of Mn and Re tricarbonyl complexes of tris(oxazolinyl)phenyl borate ligands: comparison to tris(pyrazolyl) borate complexes (2011) (15)
- Abstraction of β-hydrogen vs. alkyl groups in reactions of dialkylzinc compounds and bis(oxazolinyl)borane. (2012) (14)
- Structure, bonding, and ligand-based reactions of zwitterionic boratoiridium(I) complexes with oxazolinyl scorpionate ligands (2009) (14)
- Synthetic Lubricants Derived from Plastic Waste and their Tribological Performance. (2021) (13)
- Mixed N-Heterocyclic Carbene–Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions (2014) (13)
- Rare Earth and Main Group Metal Poly(hydrosilyl) Compounds (2017) (13)
- Two-step conversion of Kraft lignin to nylon precursors under mild conditions (2020) (12)
- Cyclopentadienyl-bis(oxazoline) Magnesium and Zirconium Complexes in Aminoalkene Hydroaminations (2015) (12)
- Zwitterionic Trivalent (Alkyl)lanthanide Complexes in Ziegler-Type Butadiene Polymerization (2018) (12)
- Silica-supported Organolanthanum Catalysts for C-O Bond Cleavage in Epoxides. (2020) (12)
- Polymer-mounted N3P(MeNCH2CH2)3N: a green, efficient and recyclable catalyst for room-temperature transesterifications and amidations of unactivated esters (2011) (12)
- Synthesis of monomeric Fe(II) and Ru(II) complexes of tetradentate phosphines. (2011) (12)
- A Quasi-Atomic Analysis of Three-Center Two-Electron Zr-H-Si Interactions. (2018) (11)
- Oxygen insertion reactions of mixed N-heterocyclic carbene-oxazolinylborato zinc alkyl complexes. (2014) (10)
- Palladium(II)-Catalyzed Terpolymerization of Alkane-α,ω-Dinitrite Esters, Alkenes, and Carbon Monoxide to Polysuccinates (1997) (9)
- β-SiH rich zinc silyl compounds: Reductive elimination and β-hydrogen abstraction (2014) (8)
- Piano-Stool Lutetium Amido and Imido Compounds Supported by a Constrained Bis(oxazoline)cyclopentadienyl Ligand. (2015) (8)
- Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand. (2017) (7)
- Allylic C-H bond activation and functionalization mediated by tris(oxazolinyl)borato rhodium(I) and iridium(I) compounds. (2011) (7)
- Alkali and Alkaline Earth Element‐Catalyzed Hydroboration Reactions (2020) (6)
- C-H bond activation of ethylene by a zirconacycle. (2013) (6)
- Basic Research Needs for Catalysis Science to Transform Energy Technologies: Report from the U.S. Department of Energy, Office of Basic Energy Sciences Workshop May 8–10, 2017, in Gaithersburg, Maryland (2017) (6)
- Alkynylaluminum Synthesis Catalyzed by a Zwitterionic Neodymium(III) Heterobimetallic Compound (2018) (5)
- Nucleophilicity of Neutral versus Cationic Magnesium Silyl Compounds (2013) (5)
- Palladium and rhodium complexes containing 1,3-bis(oxazolinyl)propyl (Probox) ligands: Macrocycles and pincer compounds (2010) (5)
- Direct hydrosilylation by a zirconacycle with β-hydrogen. (2014) (5)
- Observing the three-dimensional dynamics of supported metal complexes (2021) (3)
- Cobalt(ii) acyl intermediates in carbon-carbon bond formation and oxygenation. (2018) (3)
- Unusual structural motif in a zwitterionic Fe(II) complex of a tetradentate phosphine. (2012) (3)
- Rare Earth Catalyzed C-H Bond Alumination of Terminal Alkynes. (2020) (3)
- Rare earth arylsilazido compounds with inequivalent secondary interactions. (2018) (3)
- CO Displacement in an Oxidative Addition of Primary Silanes to Rhodium(I). (2019) (3)
- Rapid and ordered carbonylation and oxygenation of a cobalt(ii) methyl. (2017) (3)
- Hydrosilane σ‐Adduct Intermediates in an Adaptive Zinc‐Catalyzed Cross‐dehydrocoupling of Si−H and O−H Bonds (2021) (2)
- Redox Chemistry of Bis(oxazolinyl)cyclopentadienyl and -fluorenyl Rhodium and Iridium Organometallic Compounds (2018) (2)
- Effect of Macro- and Microstructures on Catalytic Hydrogenolysis of Polyolefins (2022) (2)
- Surface ligands enhance the catalytic activity of supported Au nanoparticles for the aerobic α-oxidation of amines to amides (2022) (2)
- Determining the Three-Dimensional Structures of Silica-Supported Metal Complexes from the Ground Up. (2021) (2)
- Zirconium‐Catalyzed Desymmetrization of Aminodialkenes and Aminodialkynes Through Enantioselective Hydroamination. (2015) (1)
- Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane (2023) (1)
- Polymer-Mounted N3=P(MeNCH2CH2)3N: A Green, Efficient and Recyclable Catalyst for Room-Temperature Transesterifications and Amidations of Unactivated Esters. (2012) (1)
- Catalytic conversion reactions in nanoporous systems with concentration-dependent selectivity: Statistical mechanical modeling. (2016) (1)
- Magnesium‐Catalyzed Hydroboration of Esters: Evidence for a New Zwitterionic Mechanism. (2014) (1)
- Heteroleptic Four-Coordinate Tris(oxazolinyl)borato Iron(II) Compounds. (2019) (1)
- Substituent-Enhanced Intermolecular Catalytic Ene-yne Metathesis for Efficient 1,3-Diene Synthesis (2021) (1)
- Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores (2022) (1)
- Ancillary Steric Effects on the Activation of SiH Bonds in Arylsilazido Rare-Earth Compounds (2021) (1)
- Dipolar Heteronuclear Correlation Solid-State NMR Experiments between Half-Integer Quadrupolar Nuclei: The Case of 11B–17O (2022) (1)
- Synthesis of the Precursor of the Chiral Ligand MeC(Ox iPr ) 2 CpH (2011) (0)
- Synthesis and Characterization of Tris(oxazolinyl)borato Copper(II) and Copper(I) Complexes (2021) (0)
- Stereoselective C N Bond Formation by Hydroamination of Olefins, Alkyne, Allenes, and Dienes (2013) (0)
- Dalton Transactions (2014) (0)
- Single-Site Amidozirconium Catalysts for Hydroboration (2015) (0)
- Cover Feature: Synthetic Lubricants Derived from Plastic Waste and their Tribological Performance (ChemSusChem 19/2021) (2021) (0)
- Magnesium-catalyzed hydrosilylation of a , b-unsaturated esters † (2016) (0)
- Magnesium‐Catalyzed Hydrosilylation of α,β‐Unsaturated Esters. (2016) (0)
- Synthesis of Platinum Nanoparticles on Strontium Titanate Nanocuboids via Surface Organometallic Grafting for the Catalytic Hydrogenolysis of Plastic Waste (2023) (0)
- Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis (2023) (0)
- Zinc (2022) (0)
- Transition metal-like carbocatalyst Transition metal-like carbocatalyst (2020) (0)
- The Synthesis and Characterization of New, Robust Titanium (IV) Scorpionate Complexes (2010) (0)
- Erratum to “Toward hydrogen economy: Selective guaiacol hydrogenolysis under ambient hydrogen pressure” [Appl. Catal. B: Environ. 270 (2020) 118890] (2020) (0)
- Activation of arene C[bond]H bonds by a cationic hafnium silyl complex possessing an alpha-agostic Si[bond]H interaction. (2002) (0)
- Virtual Special Issue on Catalysis at the U.S. Department of Energy’s National Laboratories (2016) (0)
- CCDC 1497112: Experimental Crystal Structure Determination (2016) (0)
- New Talent Showcasing the strength of research being carried out by tomorrow ' s leaders in the field of inorganic chemistry (2009) (0)
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