Adrian G. Brook
#137,991
Most Influential Person Now
Chemist
Adrian G. Brook's AcademicInfluence.com Rankings
Download Badge
Chemistry
Adrian G. Brook's Degrees
- PhD Chemistry University of California, Berkeley
- Masters Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Adrian G. Brook Influential?
(Suggest an Edit or Addition)Adrian G. Brook's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Molecular Rearrangements of Organosilicon Compounds (1974) (507)
- Stable solid silaethylenes (1982) (219)
- A solid silaethene: isolation and characterization (1981) (201)
- Synthesis of Silyl and Germyl Ketones (1967) (171)
- RELATIVELY STABLE SILAETHYLENES. PHOTOLYSIS OF ACYLPOLYSILANES (1979) (141)
- The Chemistry of Silenes (1996) (134)
- Tris(trimethylsilyl)silyllithium · 3 THF: a stable crystalline silyllithium reagent (1982) (126)
- The Spectral and Chemical Properties of α-Silyl Ketones (1960) (97)
- Isomerism of Some α-Hydroxysilanes to Silyl Ethers (1958) (88)
- Triphenylsilyl Phenyl Ketone (1957) (80)
- Keto Derivatives of Group IV Organometalloids (1969) (71)
- Stereochemistry of the formation and thermalrearrangement of .beta.-ketosilanes (1967) (65)
- Photoisomerization of Acylsilanes to Siloxycarbenes, and Their Reactions with Polar Reagents (1973) (63)
- Hydrogen transfer. Part IV. The use of quinones of high potential as dehydrogenation reagents (1954) (54)
- Photochemical rearrangements of stable silenes (1989) (50)
- Preparation and reactions of triarylsilylmethylmetallic reagents (1970) (49)
- Resolution of an Asymmetric Organogermanium Compound, Methyl-α-naphthylphenylgermane (1963) (48)
- Synthesis of some tris(trimethylsilyl)germyl compounds (1986) (48)
- Isomerization of Some α-Hydroxysilanes to Silyl Ethers. II1 (1959) (47)
- Carbon-13 and silicon-29 chemical shifts and coupling constants involving tris(trimethylsilyl)silyl systems (1982) (45)
- Preparation and reactions of sulfoxides and phosphine oxides containing silicon and germanium (1968) (45)
- 1,2-Siloxetanes: Formation, Structure, and Rearrangements. (1987) (42)
- The Photochemistry of Silyl Ketones in Alcohol (1967) (41)
- Silicon-29 NMR studies of relatively stable silaethylenes (1979) (41)
- Mechanism of the α-silylcarbinol to silyl ether rearrangement (1967) (41)
- Reactions of silyl and germyl ketones with alkylidenephosphoranes (1967) (40)
- Thermal Rearrangements of Organosilicon and Organogermanium Compounds1 (1955) (40)
- Stereochemistry at asymmetric carbon in the silylcarbinol to alkoxysilane rearrangement (1971) (39)
- Stable silene geometric isomers (1992) (38)
- The mechanism of the β-ketosilane to siloxyalkene thermal rearrangement (1975) (38)
- A new anion rearrangement involving silyl migration to oxygen (1984) (36)
- Optical stability of asymmetric silyl radicals (1969) (36)
- Optically active silyl- and germylmethyllithium reagents and the stereochemistry of carbene insertions into the silicon-hydrogen and germanium-hydrogen bonds (1970) (35)
- 1,4-Silyl rearrangements of siloxyalkenes to siloxyketones during peroxidation (1974) (35)
- Base-catalyzed Elimination Reactions of Triphenylsilanecarboxylic Acid and its Derivatives (1955) (33)
- Displacements at Asymmetric Germanium. Methyl-α-naphthylphenylgermyllithium and its Derivatives (1963) (33)
- Silyl-substituted α,β-Unsaturated Ketones from the Reaction of Silylvinylmetallic Reagents with Acid Anhydrides (1973) (33)
- Silaaziridines from the reaction of isonitriles with stable silenes (1988) (32)
- Silicon-carbon double bonds: new route, new substituents, new behavior (1976) (31)
- The Rearrangement of α-Silyl Ketones with Alkoxides (1962) (31)
- Hydrogen transfer. Part V. Dehydrogenation reactions with diphenylpicrylhydrazyl (1954) (30)
- Photolysis of 1,1-Diphenylsilacyclohexanone in Diethyl Fumarate. The Trapping of a Siloxycarbene by an Electron-Deficient Olefin (1971) (30)
- The Alkaline Cleavage of Tetrasubstituted Silanes (1953) (30)
- The Reaction of Triphenylsilylpotassium with Organic Halides, a Case of Halogen-Metal Interconversion1 (1957) (29)
- Analogs of Hexaphenylethane. III. Triphenylmethyltriphenylgermane, Triphenylgermanecarboxylic Acid and Some of Its Derivatives1 (1954) (28)
- Reactions of stable silenes with Grignard reagents (1991) (28)
- Reaction of a silene with a silacyclopropane to yield a disilacyclopropane (1985) (28)
- Stereochemistry of α-Silylcarbinol Rearrangements. II. The Absolute Configuration of Asymmetric Silanes (1963) (28)
- Cleavage of Hexaphenyldisilane by Sodium and Lithium (1954) (28)
- REACTIONS OF THE STILBENE-DISODIUM AND -DILITHIUM ADDUCTS (1953) (28)
- Alkoxycarbenes from the thermolysis of silyl ketals (1969) (27)
- Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals (1971) (27)
- σ→π*, A reassignment of the long wavelength uv transition in acyl-silanes and -germanes by photoelectron spectroscopy (1974) (27)
- Thermal Rearrangement of Silanecarboxylate Esters1 (1957) (27)
- Photoisomerization of a highly substituted silene (1985) (26)
- Reaction of Diazomethane with Silyl Ketones (1967) (26)
- SPECTRAL PROPERTIES OF p-SUBSTITUTED BENZOYLTRIPHENYLSILANES (1965) (26)
- The Thermal Rearrangement of α-Substituted Silanes (1975) (25)
- Isomerization of α-Hydroxysilanes to Silyl Ethers. III. Triphenylsilylcarbinol* (1961) (25)
- Reactions of Silenes: A New Silene to Silene Thermal Rearrangement (1995) (25)
- 1-Sila-3-azacyclobutanes: the insertion of isocyanides into silaaziridines (1989) (25)
- Photolysis of Acylsilanes in Cyclohexane and Other Solvents (1973) (25)
- Photolysis of acylpolysilanes containing .alpha.-hydrogens. Formation of linear head-to-head silene dimers (1987) (24)
- Reactions of stable silenes with dienes and alkenes: [2 + 2], [2 + 4] and ene reactions (1987) (24)
- Base-catalyzed rearrangement of aminomethylsilanes to methylaminosilanes (1974) (24)
- Nucleophilic Attack of Siloxycarbenes on Carbonyl Groups. The Formation of Oxiranes (1971) (24)
- The bromination, debromination and debromosilylation of silylstyrenes and other vinylsilanes (1976) (23)
- One thing leads to another―from silylcarbinols to silaethylenes (1986) (23)
- Siloxycarbenes from the thermolysis of acylsilanes (1975) (23)
- SPECTRAL AND CHEMICAL PROPERTIES OF β- AND γ-FUNCTIONAL SILANES (1964) (21)
- 1,1-Diphenylsila-2-cyclohexanone1 (1965) (21)
- The synthesis of silyl- and germyldiazoalkanes via tosylhydrazones (1969) (21)
- Bis-silyl and bis-germyl ketones (1966) (19)
- Bis(metalloidal)ketones (1968) (19)
- Stereochemistry of the silylcarbinol to silyl ether rearrangement (1967) (19)
- Reactions of silenes with .alpha.,.beta.-unsaturated aldehydes and ketones (1991) (18)
- A silathiirane and a silaselenirane from a stable silene (1994) (18)
- The Configuration of (+)-Methyl-α-naphthylphenylmethane, -silane, and -germane (1963) (17)
- Bis(silyl)enamines or silylaziridines from the thermal reactions of azides with alkenylsilanes (1978) (17)
- Tetra-substituted Aryl Silanes (1953) (17)
- Cycloaddition Reactions of Silyldiazoalkanes Involving Rearrangements from Carbon to Nitrogen (1974) (17)
- Cycloaddition and other reactions of silenes with .alpha.,.beta.-unsaturated esters (1991) (16)
- Photochemistry of acyldisilanes (1992) (16)
- Analogs of Hexaphenylethane. II.* Triphenylmethyltriphenylsilane (1953) (16)
- Studies of the rearrangements of aminoalkylsilanes to alkylaminosilanes (1977) (15)
- DIBENZOYLSILANES AND SUBSTITUTED BENZOYLSILANES (1963) (15)
- The configurations of the diastereomeric 1-chloromercuri-2-methoxycyclo-hexanes (1951) (15)
- Cycloaddition Reactions of Silyldiazoalkanes (1971) (15)
- Correlation of the absolute configurations of R-(+)- methyl(1-naphtyl)phenylgermane and (+)-ethyl(1-naphthyl) phenylgermane (1968) (14)
- Thermal rearrangement of epoxysilanes (1975) (14)
- The Reaction of Triphenylsilymetallics with Benzophenone, A Reinvestigation. I1 (1960) (14)
- Stereochemistry and mechanisms of the reactions of acylsilanes with alkoxides (1978) (14)
- Ring insertion reactions of silaaziridines with aldehydes and isocyanates (1993) (14)
- Inductive effects in acylsilanes and acyldisilanes (1968) (14)
- Oxymercuration of 2,6-Dimethylhepten-5-ol-2 (1952) (13)
- HYDROGEN ABSTRACTION REACTIONS OF DIPHENYLPICRYLHYDRAZYL (1958) (13)
- Acylsilane Photolyses: 1,1-Diphenyl-1-Silacyclohexanone-2 in Cyclohexane (1975) (13)
- Crystal structures of four sterically crowded 1,3-disilacyclobutanes (1989) (12)
- Silylcarbonium ions from the reaction of silylcarbinols with boron trifluoride (1970) (12)
- Rearrangements and electrophilic substitutions of α-silylcarbonium ions (1964) (12)
- .alpha.-Silyl-cis-stilbenes from silylcarbonium ions and from the platinum-catalyzed addition of silanes to diphenylacetylene (1968) (11)
- Thermal and base-catalyzed rearrangements of silylacetic acids (1968) (11)
- Synthesis of α,β-Unsaturated Acylsilanes and an Unusual Thermal Reaction Involving a Siladiene (1996) (11)
- Synthesis of cyclic acylsilanes (1975) (11)
- The Photochemistry of Organosilicon Compounds (1999) (10)
- Attempted preparation of silaethylenes from silanecarboxylate esters (1984) (10)
- Synthesis, resolution, and absolute configuration of 1-phenyl-1-methyl-1-silacyclohexanone-2 (1970) (10)
- The reaction of silyldiazoalkanes with acids. The thermal rearrangement of α-substituted benzyltriphenylsilanes (1969) (10)
- Cycloaddition reactions of stable silenes with acylsilanes (1993) (10)
- Communications- Alkoxide-Catalyzed Rearrangements of Benzoyltriphenylsilane (1960) (10)
- Reactions and rearrangements of carbon-functional organosilicon compounds (1966) (10)
- THE MECHANISM OF OXYMERCURATION OF ALKENES (1950) (10)
- Preparation and X-ray crystal structure of a carbamylsilane (1991) (10)
- sp2‐Hybridized silicon: Parameters for molecular modeling (1990) (9)
- PMR studies of silycarbinols and related compounds (1967) (9)
- The Resolution of 2,3-Diphenylbutane (1947) (9)
- Acylsilanes from the pyrolysis of silyl esters of α-ketoacids (1975) (8)
- The crystal structure and absolute configuration of (+)-α-(1-naphthylphenylmethylsilyl)benzyl p-bromobenzoate (1972) (7)
- Mass-spectral rearrangements of acyloxysilanes and -germanes (1968) (7)
- Complex rearrangements of polysilylacylsilanes from treatment with titanium tetrachloride (1993) (7)
- Silacyclopropanes from the reaction of silenes with Wittig reagents (1988) (6)
- Reaction of imines with silenes. Stable silazetidines (1993) (6)
- Bromoalkyl-and bromovinyl-silanes (1976) (6)
- The stereospecific synthesis and rearrangement of an α-hydroxysilane (1962) (6)
- SOME MOLECULAR REARRANGEMENTS OF ORGANOSILICON COMPOUNDS (1974) (6)
- syn-bromination of trans-triphenylsilylstyrene and its anti-debromosilylation (1976) (6)
- The Reaction of Triphenylsilymetallics with Benzophenone. II. Triphenylsiloxydiphenylmethylpotassium (1960) (5)
- Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene (1985) (4)
- Insertion reactions of nitrosobenzene and ketenes into silaaziridines (2003) (4)
- The Formation of Tetraarylsilanes from the Reactions of Triarylsilylmetallic Compounds.1 II. Reactions with Triarylsilanes (1954) (4)
- The syntheses and properties of C-silylimines and their thermal rearrangements to N-silylenamines (1978) (4)
- The mass spectra of some tris(trimethylsilyl)acylsilanes and tris(trimethylsilyl)silanes (1982) (3)
- New Compounds. Some Mercuri Cyclohexanes (1950) (3)
- Rearrangements from the reactions of silenes with trimethylsilylketene (1993) (3)
- COMPARISON OF METHOXYMERCURIALS DERIVED FROM CYCLOPENTENE AND CYCLOHEXENE (1953) (3)
- The Oxymercuration of Δ1-Terpineol* (1957) (2)
- Additions and Corrections-The Reaction of Triphenylsilylmetallics with Benzophenone. II. Triphenylsiloxydiphenylmethylpotassium (1961) (2)
- Attempted stabilization of silaethylenes with aryl or trifluoromethyl groups (1982) (2)
- Essay 9 - Molecular Rearrangements of Organosilicon Compounds (1980) (2)
- The significance of the "mercurinium ion" in oxymercuration. (1951) (2)
- Reactions of Amines with Silenes and Acylsilanes. (2000) (1)
- The Reactions of Triphenylsilyllithium with Stilbene (1955) (1)
- Photolysis of Acylpolysilanes Containing α-Hydrogens. Formation of Linear Head-to-Head Silene Dimers. (1987) (1)
- 1-Sila-3-azacyclobutanes: The Insertion of Isocyanides into Silaaziridines. (1989) (0)
- ACYLSILANE PHOTOLYSES. 1,1-DIPHENYL-1-SILACYCLOHEXAN-2-ONE IN CYCLOHEXANE (1976) (0)
- New Photochemical Behavior of Silenens Derived from Acylsilanes (1986) (0)
- A Silathiirane and a Silaselenirane from a Stable Silene. (1994) (0)
- THERMAL REARRANGEMENTS OF EPOXYSILANES (1975) (0)
- Synthesis of α,β-Unsaturated Acylsilanes and an Unusual Thermal Reaction Involving a Siladiene. (1996) (0)
- Silaaziridines from the Reaction of Isonitriles with Stable Silenes. (1989) (0)
- ACYLSILANES FROM THE PYROLYSIS OF SILYL ESTERS OF α-KETO ACIDS (1976) (0)
- Ring Insertion Reactions of Silaaziridines with Aldehydes and Isocyanates. (1993) (0)
- PHOTOISOMERIZATION OF ACYLSILANES TO SILOXYCARBENES, AND THEIR REACTION WITH POLAR REAGENTS (1973) (0)
- Crystal Structures of Four Sterically Crowded 1,3-Disilacyclobutanes. (1989) (0)
- Cycloaddition and Other Reactions of Silenes with α,β‐ Unsaturated Esters. (1991) (0)
- SILYL-SUBSTITUTED ALPHA,BETA-UNSATURATED KETONES FROM THE REACTION OF SILYLVINYLMETALLIC REAGENTS WITH ACID ANHYDRIDES (1973) (0)
- Photochemical Rearrangements of Stable Silenes. (1989) (0)
- Cycloaddition Reactions of Stable Silenes with Acylsilanes. (1994) (0)
- Stable Silene Geometric Isomers. (1992) (0)
- 1,2-BIS(TRIMETHYLSILYL)-1,2-DIMESITYLETHENE. FORMATION FROM 1,1-DIMESITYL-2-BROMOETHENE (1997) (0)
- Photochemistry of Acyldisilanes. (1992) (0)
- Insertion Reactions of Nitrosobenzene and Ketenes into Silaaziridines. (2004) (0)
- One Thing Leads to Another. From Silylcarbinols to Silaethylenes (1986) (0)
- BROMOALKYL- AND BROMOVINYLSILANES (1977) (0)
- Carbosilanes: Synthesis and Reactions (1987) (0)
- THE MECHANISM OF THE BETA-KETOSILANE TO SILOXYALKENE THERMAL REARRANGEMENT (1975) (0)
- SYNTH., TRENNUNG UND ABSOLUTE KONFIG. VON 1-PHENYL-1-METHYL-1-SILACYCLOHEXANON-(2) (1970) (0)
- Reactions of Stable Silenes with Dienes and Alkenes: (2 + 2), (2 + 4), and Ene Reactions. (1988) (0)
- Preparation and X‐Ray Crystal Structure of a Carbamoylsilane. (1991) (0)
- THE THERMAL REARRANGEMENT OF ALPHA-SUBSTITUTED SILANES (1975) (0)
- Cycloaddition Reactions and Rearrangements of Stable Silenes and Their Derivatives (1991) (0)
- SIGMA-PI(*), A REASSIGNMENT OF THE LONG WAVELENGTH UV TRANSITION IN ACYL-SILANES AND -GERMANES BY PHOTOELECTRON SPECTROSCOPY (1974) (0)
- Reaction of Imines with Silenes. Stable Silazetidines. (1993) (0)
- TRIS(TRIMETHYLSILYL)SILYLLITHIUM.3THF (1988) (0)
- Synthesis of Some Tris(trimethylsilyl)germyl Compounds. (1986) (0)
- RECENT STUDIES OF THE PHOTOCHEMISTRY OF ACYLSILANES (1975) (0)
- Rearrangements from the Reactions of Silenes with Trimethylsilylketene. (1993) (0)
- Silacyclopropanes from the Reaction of Silenes with Wittig Reagents. (1988) (0)
- Additions and Corrections - The Photochemistry of Silyl Ketones in Alcohol (1967) (0)
- Reactions of Silenes with a,-Unsaturated Aldehydes and Ketones. (1991) (0)
- Reactions of Stable Silenes with Grignard Reagents. (1991) (0)
- TRIS(TRIMETHYLSILYL)SILYLLITHIUM.3 THF: A STABLE CRYSTALLINE SILYLLITHIUM REAGENT (1982) (0)
This paper list is powered by the following services:
What Schools Are Affiliated With Adrian G. Brook?
Adrian G. Brook is affiliated with the following schools:
