Adrian G. Brook

Adrian G. Brook's AcademicInfluence.com Rankings

Adrian G. Brook

Chemistry

#3425

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#4442

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chemistry Degrees

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Chemistry

Adrian G. Brook's Degrees

PhD Chemistry University of California, Berkeley
Masters Chemistry University of California, Berkeley
Bachelors Chemistry University of California, Berkeley

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Adrian G. Brook's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Molecular Rearrangements of Organosilicon Compounds (1974) (507)
Stable solid silaethylenes (1982) (219)
A solid silaethene: isolation and characterization (1981) (201)
Synthesis of Silyl and Germyl Ketones (1967) (171)
RELATIVELY STABLE SILAETHYLENES. PHOTOLYSIS OF ACYLPOLYSILANES (1979) (141)
The Chemistry of Silenes (1996) (134)
Tris(trimethylsilyl)silyllithium · 3 THF: a stable crystalline silyllithium reagent (1982) (126)
The Spectral and Chemical Properties of α-Silyl Ketones (1960) (97)
Isomerism of Some α-Hydroxysilanes to Silyl Ethers (1958) (88)
Triphenylsilyl Phenyl Ketone (1957) (80)
Keto Derivatives of Group IV Organometalloids (1969) (71)
Stereochemistry of the formation and thermalrearrangement of .beta.-ketosilanes (1967) (65)
Photoisomerization of Acylsilanes to Siloxycarbenes, and Their Reactions with Polar Reagents (1973) (63)
Hydrogen transfer. Part IV. The use of quinones of high potential as dehydrogenation reagents (1954) (54)
Photochemical rearrangements of stable silenes (1989) (50)
Preparation and reactions of triarylsilylmethylmetallic reagents (1970) (49)
Resolution of an Asymmetric Organogermanium Compound, Methyl-α-naphthylphenylgermane (1963) (48)
Synthesis of some tris(trimethylsilyl)germyl compounds (1986) (48)
Isomerization of Some α-Hydroxysilanes to Silyl Ethers. II1 (1959) (47)
Carbon-13 and silicon-29 chemical shifts and coupling constants involving tris(trimethylsilyl)silyl systems (1982) (45)
Preparation and reactions of sulfoxides and phosphine oxides containing silicon and germanium (1968) (45)
1,2-Siloxetanes: Formation, Structure, and Rearrangements. (1987) (42)
The Photochemistry of Silyl Ketones in Alcohol (1967) (41)
Silicon-29 NMR studies of relatively stable silaethylenes (1979) (41)
Mechanism of the α-silylcarbinol to silyl ether rearrangement (1967) (41)
Reactions of silyl and germyl ketones with alkylidenephosphoranes (1967) (40)
Thermal Rearrangements of Organosilicon and Organogermanium Compounds1 (1955) (40)
Stereochemistry at asymmetric carbon in the silylcarbinol to alkoxysilane rearrangement (1971) (39)
Stable silene geometric isomers (1992) (38)
The mechanism of the β-ketosilane to siloxyalkene thermal rearrangement (1975) (38)
A new anion rearrangement involving silyl migration to oxygen (1984) (36)
Optical stability of asymmetric silyl radicals (1969) (36)
Optically active silyl- and germylmethyllithium reagents and the stereochemistry of carbene insertions into the silicon-hydrogen and germanium-hydrogen bonds (1970) (35)
1,4-Silyl rearrangements of siloxyalkenes to siloxyketones during peroxidation (1974) (35)
Base-catalyzed Elimination Reactions of Triphenylsilanecarboxylic Acid and its Derivatives (1955) (33)
Displacements at Asymmetric Germanium. Methyl-α-naphthylphenylgermyllithium and its Derivatives (1963) (33)
Silyl-substituted α,β-Unsaturated Ketones from the Reaction of Silylvinylmetallic Reagents with Acid Anhydrides (1973) (33)
Silaaziridines from the reaction of isonitriles with stable silenes (1988) (32)
Silicon-carbon double bonds: new route, new substituents, new behavior (1976) (31)
The Rearrangement of α-Silyl Ketones with Alkoxides (1962) (31)
Hydrogen transfer. Part V. Dehydrogenation reactions with diphenylpicrylhydrazyl (1954) (30)
Photolysis of 1,1-Diphenylsilacyclohexanone in Diethyl Fumarate. The Trapping of a Siloxycarbene by an Electron-Deficient Olefin (1971) (30)
The Alkaline Cleavage of Tetrasubstituted Silanes (1953) (30)
The Reaction of Triphenylsilylpotassium with Organic Halides, a Case of Halogen-Metal Interconversion1 (1957) (29)
Analogs of Hexaphenylethane. III. Triphenylmethyltriphenylgermane, Triphenylgermanecarboxylic Acid and Some of Its Derivatives1 (1954) (28)
Reactions of stable silenes with Grignard reagents (1991) (28)
Reaction of a silene with a silacyclopropane to yield a disilacyclopropane (1985) (28)
Stereochemistry of α-Silylcarbinol Rearrangements. II. The Absolute Configuration of Asymmetric Silanes (1963) (28)
Cleavage of Hexaphenyldisilane by Sodium and Lithium (1954) (28)
REACTIONS OF THE STILBENE-DISODIUM AND -DILITHIUM ADDUCTS (1953) (28)
Alkoxycarbenes from the thermolysis of silyl ketals (1969) (27)
Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals (1971) (27)
σ→π*, A reassignment of the long wavelength uv transition in acyl-silanes and -germanes by photoelectron spectroscopy (1974) (27)
Thermal Rearrangement of Silanecarboxylate Esters1 (1957) (27)
Photoisomerization of a highly substituted silene (1985) (26)
Reaction of Diazomethane with Silyl Ketones (1967) (26)
SPECTRAL PROPERTIES OF p-SUBSTITUTED BENZOYLTRIPHENYLSILANES (1965) (26)
The Thermal Rearrangement of α-Substituted Silanes (1975) (25)
Isomerization of α-Hydroxysilanes to Silyl Ethers. III. Triphenylsilylcarbinol* (1961) (25)
Reactions of Silenes: A New Silene to Silene Thermal Rearrangement (1995) (25)
1-Sila-3-azacyclobutanes: the insertion of isocyanides into silaaziridines (1989) (25)
Photolysis of Acylsilanes in Cyclohexane and Other Solvents (1973) (25)
Photolysis of acylpolysilanes containing .alpha.-hydrogens. Formation of linear head-to-head silene dimers (1987) (24)
Reactions of stable silenes with dienes and alkenes: [2 + 2], [2 + 4] and ene reactions (1987) (24)
Base-catalyzed rearrangement of aminomethylsilanes to methylaminosilanes (1974) (24)
Nucleophilic Attack of Siloxycarbenes on Carbonyl Groups. The Formation of Oxiranes (1971) (24)
The bromination, debromination and debromosilylation of silylstyrenes and other vinylsilanes (1976) (23)
One thing leads to another―from silylcarbinols to silaethylenes (1986) (23)
Siloxycarbenes from the thermolysis of acylsilanes (1975) (23)
SPECTRAL AND CHEMICAL PROPERTIES OF β- AND γ-FUNCTIONAL SILANES (1964) (21)
1,1-Diphenylsila-2-cyclohexanone1 (1965) (21)
The synthesis of silyl- and germyldiazoalkanes via tosylhydrazones (1969) (21)
Bis-silyl and bis-germyl ketones (1966) (19)
Bis(metalloidal)ketones (1968) (19)
Stereochemistry of the silylcarbinol to silyl ether rearrangement (1967) (19)
Reactions of silenes with .alpha.,.beta.-unsaturated aldehydes and ketones (1991) (18)
A silathiirane and a silaselenirane from a stable silene (1994) (18)
The Configuration of (+)-Methyl-α-naphthylphenylmethane, -silane, and -germane (1963) (17)
Bis(silyl)enamines or silylaziridines from the thermal reactions of azides with alkenylsilanes (1978) (17)
Tetra-substituted Aryl Silanes (1953) (17)
Cycloaddition Reactions of Silyldiazoalkanes Involving Rearrangements from Carbon to Nitrogen (1974) (17)
Cycloaddition and other reactions of silenes with .alpha.,.beta.-unsaturated esters (1991) (16)
Photochemistry of acyldisilanes (1992) (16)
Analogs of Hexaphenylethane. II.* Triphenylmethyltriphenylsilane (1953) (16)
Studies of the rearrangements of aminoalkylsilanes to alkylaminosilanes (1977) (15)
DIBENZOYLSILANES AND SUBSTITUTED BENZOYLSILANES (1963) (15)
The configurations of the diastereomeric 1-chloromercuri-2-methoxycyclo-hexanes (1951) (15)
Cycloaddition Reactions of Silyldiazoalkanes (1971) (15)
Correlation of the absolute configurations of R-(+)- methyl(1-naphtyl)phenylgermane and (+)-ethyl(1-naphthyl) phenylgermane (1968) (14)
Thermal rearrangement of epoxysilanes (1975) (14)
The Reaction of Triphenylsilymetallics with Benzophenone, A Reinvestigation. I1 (1960) (14)
Stereochemistry and mechanisms of the reactions of acylsilanes with alkoxides (1978) (14)
Ring insertion reactions of silaaziridines with aldehydes and isocyanates (1993) (14)
Inductive effects in acylsilanes and acyldisilanes (1968) (14)
Oxymercuration of 2,6-Dimethylhepten-5-ol-2 (1952) (13)
HYDROGEN ABSTRACTION REACTIONS OF DIPHENYLPICRYLHYDRAZYL (1958) (13)
Acylsilane Photolyses: 1,1-Diphenyl-1-Silacyclohexanone-2 in Cyclohexane (1975) (13)
Crystal structures of four sterically crowded 1,3-disilacyclobutanes (1989) (12)
Silylcarbonium ions from the reaction of silylcarbinols with boron trifluoride (1970) (12)
Rearrangements and electrophilic substitutions of α-silylcarbonium ions (1964) (12)
.alpha.-Silyl-cis-stilbenes from silylcarbonium ions and from the platinum-catalyzed addition of silanes to diphenylacetylene (1968) (11)
Thermal and base-catalyzed rearrangements of silylacetic acids (1968) (11)
Synthesis of α,β-Unsaturated Acylsilanes and an Unusual Thermal Reaction Involving a Siladiene (1996) (11)
Synthesis of cyclic acylsilanes (1975) (11)
The Photochemistry of Organosilicon Compounds (1999) (10)
Attempted preparation of silaethylenes from silanecarboxylate esters (1984) (10)
Synthesis, resolution, and absolute configuration of 1-phenyl-1-methyl-1-silacyclohexanone-2 (1970) (10)
The reaction of silyldiazoalkanes with acids. The thermal rearrangement of α-substituted benzyltriphenylsilanes (1969) (10)
Cycloaddition reactions of stable silenes with acylsilanes (1993) (10)
Communications- Alkoxide-Catalyzed Rearrangements of Benzoyltriphenylsilane (1960) (10)
Reactions and rearrangements of carbon-functional organosilicon compounds (1966) (10)
THE MECHANISM OF OXYMERCURATION OF ALKENES (1950) (10)
Preparation and X-ray crystal structure of a carbamylsilane (1991) (10)
sp2‐Hybridized silicon: Parameters for molecular modeling (1990) (9)
PMR studies of silycarbinols and related compounds (1967) (9)
The Resolution of 2,3-Diphenylbutane (1947) (9)
Acylsilanes from the pyrolysis of silyl esters of α-ketoacids (1975) (8)
The crystal structure and absolute configuration of (+)-α-(1-naphthylphenylmethylsilyl)benzyl p-bromobenzoate (1972) (7)
Mass-spectral rearrangements of acyloxysilanes and -germanes (1968) (7)
Complex rearrangements of polysilylacylsilanes from treatment with titanium tetrachloride (1993) (7)
Silacyclopropanes from the reaction of silenes with Wittig reagents (1988) (6)
Reaction of imines with silenes. Stable silazetidines (1993) (6)
Bromoalkyl-and bromovinyl-silanes (1976) (6)
The stereospecific synthesis and rearrangement of an α-hydroxysilane (1962) (6)
SOME MOLECULAR REARRANGEMENTS OF ORGANOSILICON COMPOUNDS (1974) (6)
syn-bromination of trans-triphenylsilylstyrene and its anti-debromosilylation (1976) (6)
The Reaction of Triphenylsilymetallics with Benzophenone. II. Triphenylsiloxydiphenylmethylpotassium (1960) (5)
Structure of 2-(1-adamantyl)-2-trimethylsiloxy-1,1-bis(trimethylsily)-1-silaethylene (1985) (4)
Insertion reactions of nitrosobenzene and ketenes into silaaziridines (2003) (4)
The Formation of Tetraarylsilanes from the Reactions of Triarylsilylmetallic Compounds.1 II. Reactions with Triarylsilanes (1954) (4)
The syntheses and properties of C-silylimines and their thermal rearrangements to N-silylenamines (1978) (4)
The mass spectra of some tris(trimethylsilyl)acylsilanes and tris(trimethylsilyl)silanes (1982) (3)
New Compounds. Some Mercuri Cyclohexanes (1950) (3)
Rearrangements from the reactions of silenes with trimethylsilylketene (1993) (3)
COMPARISON OF METHOXYMERCURIALS DERIVED FROM CYCLOPENTENE AND CYCLOHEXENE (1953) (3)
The Oxymercuration of Δ1-Terpineol* (1957) (2)
Additions and Corrections-The Reaction of Triphenylsilylmetallics with Benzophenone. II. Triphenylsiloxydiphenylmethylpotassium (1961) (2)
Attempted stabilization of silaethylenes with aryl or trifluoromethyl groups (1982) (2)
Essay 9 - Molecular Rearrangements of Organosilicon Compounds (1980) (2)
The significance of the "mercurinium ion" in oxymercuration. (1951) (2)
Reactions of Amines with Silenes and Acylsilanes. (2000) (1)
The Reactions of Triphenylsilyllithium with Stilbene (1955) (1)
Photolysis of Acylpolysilanes Containing α-Hydrogens. Formation of Linear Head-to-Head Silene Dimers. (1987) (1)
1-Sila-3-azacyclobutanes: The Insertion of Isocyanides into Silaaziridines. (1989) (0)
ACYLSILANE PHOTOLYSES. 1,1-DIPHENYL-1-SILACYCLOHEXAN-2-ONE IN CYCLOHEXANE (1976) (0)
New Photochemical Behavior of Silenens Derived from Acylsilanes (1986) (0)
A Silathiirane and a Silaselenirane from a Stable Silene. (1994) (0)
THERMAL REARRANGEMENTS OF EPOXYSILANES (1975) (0)
Synthesis of α,β-Unsaturated Acylsilanes and an Unusual Thermal Reaction Involving a Siladiene. (1996) (0)
Silaaziridines from the Reaction of Isonitriles with Stable Silenes. (1989) (0)
ACYLSILANES FROM THE PYROLYSIS OF SILYL ESTERS OF α-KETO ACIDS (1976) (0)
Ring Insertion Reactions of Silaaziridines with Aldehydes and Isocyanates. (1993) (0)
PHOTOISOMERIZATION OF ACYLSILANES TO SILOXYCARBENES, AND THEIR REACTION WITH POLAR REAGENTS (1973) (0)
Crystal Structures of Four Sterically Crowded 1,3-Disilacyclobutanes. (1989) (0)
Cycloaddition and Other Reactions of Silenes with α,β‐ Unsaturated Esters. (1991) (0)
SILYL-SUBSTITUTED ALPHA,BETA-UNSATURATED KETONES FROM THE REACTION OF SILYLVINYLMETALLIC REAGENTS WITH ACID ANHYDRIDES (1973) (0)
Photochemical Rearrangements of Stable Silenes. (1989) (0)
Cycloaddition Reactions of Stable Silenes with Acylsilanes. (1994) (0)
Stable Silene Geometric Isomers. (1992) (0)
1,2-BIS(TRIMETHYLSILYL)-1,2-DIMESITYLETHENE. FORMATION FROM 1,1-DIMESITYL-2-BROMOETHENE (1997) (0)
Photochemistry of Acyldisilanes. (1992) (0)
Insertion Reactions of Nitrosobenzene and Ketenes into Silaaziridines. (2004) (0)
One Thing Leads to Another. From Silylcarbinols to Silaethylenes (1986) (0)
BROMOALKYL- AND BROMOVINYLSILANES (1977) (0)
Carbosilanes: Synthesis and Reactions (1987) (0)
THE MECHANISM OF THE BETA-KETOSILANE TO SILOXYALKENE THERMAL REARRANGEMENT (1975) (0)
SYNTH., TRENNUNG UND ABSOLUTE KONFIG. VON 1-PHENYL-1-METHYL-1-SILACYCLOHEXANON-(2) (1970) (0)
Reactions of Stable Silenes with Dienes and Alkenes: (2 + 2), (2 + 4), and Ene Reactions. (1988) (0)
Preparation and X‐Ray Crystal Structure of a Carbamoylsilane. (1991) (0)
THE THERMAL REARRANGEMENT OF ALPHA-SUBSTITUTED SILANES (1975) (0)
Cycloaddition Reactions and Rearrangements of Stable Silenes and Their Derivatives (1991) (0)
SIGMA-PI(*), A REASSIGNMENT OF THE LONG WAVELENGTH UV TRANSITION IN ACYL-SILANES AND -GERMANES BY PHOTOELECTRON SPECTROSCOPY (1974) (0)
Reaction of Imines with Silenes. Stable Silazetidines. (1993) (0)
TRIS(TRIMETHYLSILYL)SILYLLITHIUM.3THF (1988) (0)
Synthesis of Some Tris(trimethylsilyl)germyl Compounds. (1986) (0)
RECENT STUDIES OF THE PHOTOCHEMISTRY OF ACYLSILANES (1975) (0)
Rearrangements from the Reactions of Silenes with Trimethylsilylketene. (1993) (0)
Silacyclopropanes from the Reaction of Silenes with Wittig Reagents. (1988) (0)
Additions and Corrections - The Photochemistry of Silyl Ketones in Alcohol (1967) (0)
Reactions of Silenes with a,-Unsaturated Aldehydes and Ketones. (1991) (0)
Reactions of Stable Silenes with Grignard Reagents. (1991) (0)
TRIS(TRIMETHYLSILYL)SILYLLITHIUM.3 THF: A STABLE CRYSTALLINE SILYLLITHIUM REAGENT (1982) (0)

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What Schools Are Affiliated With Adrian G. Brook?

Adrian G. Brook is affiliated with the following schools:

University of California, Berkeley
Stanford University
University of Toronto