Akira Sekiguchi
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Computer Science
Akira Sekiguchi's Degrees
- PhD Computer Science University of Tokyo
- Masters Computer Science Kyoto University
- Bachelors Computer Science Kyoto University
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(Suggest an Edit or Addition)Akira Sekiguchi's Published Works
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Published Works
- A Stable Compound Containing a Silicon-Silicon Triple Bond (2004) (388)
- Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds (2010) (214)
- Reactivity of a Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward π-Bonds: Stereospecific Addition and a New Route to an Isolable 1,2-Disilabenzene (2007) (154)
- Aromaticity of group 14 organometallics: experimental aspects. (2007) (136)
- Heavy cyclopropenes of Si, Ge, and Sn--a new challenge in the chemistry of group 14 elements. (2003) (128)
- Heteronuclear Heavy Alkenes E=E' (E, E' = Group 14 Elements): Germasilenes, Silastannenes, Germastannenes...Next Stop? (2004) (108)
- A Free Cyclotrigermenium Cation with a 2π-Electron System (1997) (102)
- The missing hexasilaprismane : synthesis, X-ray analysis, and photochemical reactions (1993) (101)
- Chemistry of organosilicon compounds. 293. Preparation, characterization, and crystal structures of octasilacubanes and octagermacubanes (1992) (100)
- Stable silyl, germyl, and stannyl cations, radicals, and anions: heavy versions of carbocations, carbon radicals, and carbanions. (2007) (98)
- Lithiosilanes and their application to the synthesis of polysilane dendrimers (2000) (97)
- Disilenyllithium from Tetrasila-1,3-butadiene: A Silicon Analogue of a Vinyllithium (2004) (96)
- Isolable silyl and germyl radicals lacking conjugation with pi-bonds: synthesis, characterization, and reactivity. (2002) (95)
- An isolable disilyne anion radical and a new route to the disilenide ion upon reduction of a disilyne. (2007) (92)
- The Chemistry of Disilyne with a Genuine Si–Si Triple Bond: Synthesis, Structure, and Reactivity (2006) (87)
- Access to a stable Si2N2 four-membered ring with non-Kekulé singlet biradical character from a disilyne. (2011) (82)
- Isolable anion radical of blue disilene (tBu2MeSi)2Si=Si(SiMetBu2)2 formed upon one-electron reduction: synthesis and characterization. (2004) (81)
- Cyclotrisilenylium ion: the persilaaromatic compound. (2005) (78)
- Synthesis and Characterization of a Cyclobutadiene Dianion Dilithium Salt: Evidence for Aromaticity (2000) (78)
- The Homocyclotrisilenylium Ion: A Free Silyl Cation in the Condensed Phase (2000) (77)
- Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry (2008) (76)
- An N-heterocyclic carbene-disilyne complex and its reactivity toward ZnCl2. (2010) (76)
- Cyclobutadiene dianions consisting of heavier group 14 elements: synthesis and characterization. (2004) (72)
- Tetrakis(trimethylsilyl)tetrahedrane. (2002) (72)
- Bis(tri-tert-butylsilyl)silylene: triplet ground state silylene. (2003) (67)
- (tBu2MeSi)2Sn=Sn(SiMetBu2)2: a distannene with a >Sn=Sn< double bond that is stable both in the solid state and in solution. (2006) (64)
- Cyclotrigermenes: A New Unsaturated Ring System (1995) (64)
- [(Me3Si)2CHGe]6, the First Hexagermaprismane (1989) (63)
- The cation cluster of heavier group 14 elements: a free germyl cation with trishomoaromaticity. (2002) (62)
- Tetrasilatetrahedranide: a silicon cage anion. (2003) (62)
- The First Three-Membered Unsaturated Rings Consisting of Different Heavier Group 14 Elements: 1-Disilagermirene with a SiSi Double Bond and Its Isomerization to a 2-Disilagermirene with a SiGe Double Bond (2000) (62)
- An isolable NHC-stabilized silylene radical cation: synthesis and structural characterization. (2012) (60)
- Addition of amines and hydroborane to the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) giving amino- and boryl-substituted disilenes. (2010) (59)
- Cyclotetrasilenyl: the first isolable silyl radical. (2001) (59)
- ChemInform Abstract: A New Approach to the Synthesis of Unsymmetrical Disilenes and Germasilene: Unusual 29Si NMR Chemical Shifts and Regiospecific Methanol Addition. (2001) (58)
- The First Metalladiene of Group 14 Elements with a Silole-Type Structure with SiGe and CC Double Bonds (2000) (58)
- A “Push−Pull” Phosphasilene and Phosphagermene and Their Anion-Radicals (2009) (56)
- Reactivity of the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) toward silylcyanide: two pathways to form the bis-adduct [RSiSiR(CNSiMe3)2] with some silaketenimine character and a 1,4-diaza-2,3-disilabenzene analogue. (2008) (56)
- Disilenyl Anions Derived from Reduction of Tetrakis(di-tert-butylmethylsilyl)disilene with Metal Naphthalenide through a Disilene Dianion Intermediate: Synthesis and Characterization (2005) (56)
- Tin-centered radical and cation: stable and free. (2003) (53)
- Chemistry of organosilicon compounds. 263. Synthesis, properties, and molecular structure of highly distorted hexakis(trimethylsilyl)benzene (1990) (52)
- Stable aromatic compounds containing heavier Group 14 elements (2000) (52)
- Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond. (2006) (51)
- Tomography of Reaction-Diffusion Microemulsions Reveals Three-Dimensional Turing Patterns (50)
- A synthon for the silicon-silicon triple bond (1986) (50)
- Si‐, Ge‐, and Sn‐Centered Free Radicals: From Phantom Species toGrams‐Order‐Scale Materials (2005) (49)
- Recent Developments in the Reactivity of Stable Disilynes (2012) (48)
- Silacarbonyl and silathiocarbonyl ylides (1987) (48)
- An Unexpected Reaction of Silacyclopropene To Form an Organodilithiosilane: Isolation and Characterization of a 1,1-Dilithiosilane Derivative (1999) (47)
- Isolable p- and m-[((t)Bu2MeSi)2Si]2C6H4: disilaquinodimethane vs triplet bis(silyl radical). (2011) (45)
- Evidence of the formation of oxasilacyclopropane from the reaction of silylene with ketone (1977) (45)
- Stable cyclic silenes from reaction of disilenides with carboxylic acid chlorides. (2007) (45)
- Nearly planar nonsolvated monomeric silyl- and germyllithiums as a result of an intramolecular CH-Li agostic interaction. (2002) (45)
- Stereochemistry of the addition of diarylsilylenes to cis- and trans-2-butenes (1988) (44)
- The first nonconjugated mononuclear benzene dianion. Isolation and characterization of bis[(tetrahydrofuran)lithium(I)] hexakis(trimethylsilyl)benzenide (1991) (43)
- Hexakis(trimethylsilyl)tetrahedranyltetrahedrane. (2005) (43)
- Tetrasilacyclobutadiene (tBu2MeSi)4Si4 : A new ligand for transition-metal complexes (2005) (43)
- The first isolable 1,1-dilithiogermane and its unusual dimeric structure--an effective reagent for the preparation of double-bonded derivatives of group 14 elements. (2002) (42)
- Tetrakis(di-tert-butylmethylsilyl)distannene and its anion radical. (2004) (42)
- Conversion of a disilenide into a silene: silyl-anion-substituted silene by a sila-Peterson-type reaction from an sp2-type silyl anion. (2007) (42)
- Isolation and characterization of 1,2-dilithio[tetrakis(trimethylsilyl)]ethane. The first crystal structure of nonconjugated 1,2-dilithioethane (1989) (41)
- Bis[(dimethoxyethane)lithium(I)] 1,2,4,5-tetrakis(trimethylsilyl)benzenide. The first 6C-8.pi. antiaromatic benzene dianion (1991) (41)
- Unsymmetrically substituted disilyne Dsi(2)(i)PrSi-Si≡Si-SiNpDsi(2) (Np = CH(2)(t)Bu): synthesis and characterization. (2010) (40)
- High-power electrochemical energy storage system employing stable radical pseudocapacitors. (2014) (40)
- A stable Schrock-type hafnium-silylene complex. (2006) (39)
- A stable silaborene: synthesis and characterization. (2006) (39)
- Isolable silylene anion radical: structural characteristics in the solid state and in solution. (2007) (39)
- Chemistry of organosilicon compounds. 297. Lithium pentakis(dimethylsilyl)cyclopentadienide and formation of isolable coordination complexes with ketones: [(R2C:O)Li.{C5(SiMe2H)5}] (1993) (39)
- The first stable methyl-substituted disilene: Synthesis, crystal structure, and regiospecific MeLi addition (2003) (38)
- Base-free molybdenum and tungsten bicyclic silylene complexes stabilized by a homoaromatic contribution. (2009) (38)
- From a Cyclobutadiene Dianion to a Cyclobutadiene: Synthesis and Structural Characterization of Tetrasilyl-Substituted Cyclobutadiene This work was supported by a Grant-in-Aid for Scientific Research (Nos. 10304051, 12020209, 12042213) from the Ministry of Education, Science, and Culture of Japan, a (2001) (37)
- The heavy analogue of CpLi: lithium 1,2-disila-3-germacyclopentadienide, a 6pi-electron aromatic system. (2005) (37)
- Chemistry of Organosilicon Compounds. 314. Preparation of (Pentamethyldisilanyl)lithium and Two Isomers of (Heptamethyltrisilanyl)lithium. Structural Characterization of (CH3)5Si2Li (1995) (37)
- Synthesis and Striking Reactivity of an Isolable Tetrasilyl-Substituted Trisilaallene (2011) (37)
- Synthesis of Unsymmetrically Substituted Cyclotrigermenes and the First Example of Cis Configuration around the GeGe Double Bond (1999) (37)
- A (Tetrasilacyclobutadiene)tricarbonyliron complex [{eta4-(tBu2MeSi)4Si4}Fe(CO)3]: the silicon cousin of pettit's (cyclobutadiene)tricarbonyliron complex [(eta4-H4C4)Fe(CO)3]. (2006) (37)
- Cage and Cluster Compounds of Silicon, Germanium, and Tin (1995) (37)
- A new disilene with π-accepting groups from the reaction of disilyne RSi≡SiR (R = Si(i)Pr[CH(SiMe3)2]) with isocyanides. (2012) (36)
- Air-stable disilacyclopropene with a SI=C bond and its conversion to disilacyclopropenylium ion: silicon-carbon hybrid 2pi-electron systems. (2007) (35)
- Carbonylation of cyclotrisilenes. (2013) (35)
- Si3C2-rings: from a nonconjugated trisilacyclopentadiene to an aromatic trisilacyclopentadienide and cyclic disilenide. (2009) (35)
- Heteronuclear Double Bonds E=E' (E = Heavy Group 14 Element, E' = Group 13-16 Element) (2010) (35)
- [(tBu2MeSi)3Ge]+: an isolable free germyl cation lacking conjugation to pi bonds. (2003) (35)
- Functionalized Cyclic Disilenes via Ring Expansion of Cyclotrisilenes with Isocyanides (2013) (35)
- The chemistry of organosilicon compounds. 302. Regio- and stereochemistry and kinetics in the addition reactions of alcohols to phenyl-substituted disilenes (1993) (34)
- The first halogen-substituted cyclotrigermenes: a unique halogen walk over the three-membered ring skeleton and facial stereoselectivity in the Diels-Alder reaction. (2002) (34)
- The isolable cation radical of disilene: synthesis, characterization, and a reversible one-electron redox system. (2008) (34)
- The first spectroscopic detection of silaylides in the reaction of dimesitylsilylene with phosphorus, sulfur, and nitrogen-containing substrates. The stability of silaylides (1988) (33)
- The first silastannene >si=sn<: a new doubly-bonded system of heavier group 14 elements. (2002) (33)
- Heavy ferrocene: a sandwich complex containing Si and Ge atoms. (2007) (33)
- Interaction of π-bonds of the silicon–silicon triple bond with alkali metals: An isolable anion radical upon reduction of a disilyne (2009) (33)
- Chemistry of oxasilacyclopropane. 2. Formations of dioxasilacyclopentanes in the reaction of oxasilacyclopropane derivatives with adamantanone and norbornone (1978) (32)
- Isomeric metamorphosis: Si3E (E = S, Se, and Te) bicyclo[1.1.0]butane and cyclobutene. (2008) (32)
- 1,2-Disilacyclobut-2-enes: donor-free four-membered cyclic silenes from reaction of disilenides with vinylbromides. (2008) (32)
- OXASILACYCLOPROPANE. ISOLATION AND CHARACTERIZATION (1983) (32)
- Cyclic polyenes of heavy group 14 elements: new generation ligands for transition-metal complexes. (2008) (31)
- Rare-Earth Cyclobutadienyl Sandwich Complexes: Synthesis, Structure and Dynamic Magnetic Properties. (2018) (31)
- Interplay of EnE'3-nC valence isomers (E, E' = Si, Ge): bicyclo[1.1.0]butanes with very short bridging bonds and their isomerization to alkyl-substituted cyclopropenes. (2007) (31)
- Dynamics of the Excited State of Polysilane Dendrimers: Origin of the Broad Visible Emission of Branched Silicon Chains (2001) (30)
- Observation of a thermally accessible triplet state resulting from rotation around a main-group π bond. (2015) (30)
- Toward a silicon version of metathesis: from Schrock-type titanium silylidenes to silatitanacyclobutenes. (2013) (30)
- Reaction of Dilithiosilane R2SiLi2 and Dilithiogermane R2GeLi2 (R = SiMetBu2) with MesBCl2 (Mes = 2,4,6-trimethylphenyl): Evidence for the Formation of Silaborene R2Si=BMes and Germaborene R2Ge=BMes (2005) (29)
- Silylium Ion to silylium Ion Rearrangement Caused by 1, 3-Methyl Migration (2004) (29)
- Hydroboration of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2), Giving Boryl-Substituted Disilenes (2011) (28)
- Reactivity of the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) toward Nitriles: Unexpected Formation of Triaza-1,4-disilabicyclo[2.2.2]octa-2,5,7-triene Derivatives (2009) (28)
- A chemical trick: how to make a digermene from a disilene, formation of 3delta-1,2,3,4-disiladigermetene. (2003) (28)
- A Free Silylium Ion: A Cyclotetrasilenylium Ion with Allylic Character (2008) (28)
- An Isolable Boryl-substituted Disilene from the Reaction of an sp2-type Silyl Anion with Haloboranes: Synthesis and Characterization (2008) (28)
- Time-resolved absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide. (1983) (28)
- On the Role of cis,trans-(t-Bu3SiGeCl)3 in the Reaction of GeCl2·Dioxane with Tri-tert-butylsilylsodium: Evidence for Existence of Digermanylsodium t-Bu3SiGe(Cl)2Ge(Cl)(Na)Sit-Bu3 and Digermene t-Bu3Si(Cl)GeGe(Cl)Sit-Bu3 (2000) (28)
- [Me(PhMe2Si)2SiLi] and [Ph(Me3Si)2SiLi]: Preparation, Characterization, and Evidence for an Intramolecular LiPh Interaction† (1997) (28)
- Tetrasilacyclobutadiene and Cyclobutadiene Tricarbonylruthenium Complexes: [η4-(tBu2MeSi)4Si4]Ru(CO)3 and [η4-(Me3Si)4C4]Ru(CO)3 (2009) (28)
- From tetragermacyclobutene to tetragermacyclobutadiene dianion to tetragermacyclobutadiene transition metal complexes. (2011) (28)
- Tetrahedranyllithium: synthesis, characterization, and reactivity. (2003) (27)
- Cyclotetrasilenide ion: a reversible redox system of cyclotetrasilenyl cation, radical, and anion. (2002) (27)
- Isolation of Hypervalent Group-16 Radicals and Their Application in Organic-Radical Batteries. (2016) (26)
- R2GeSnR‘2 and RR‘GeSnRR‘ (R = SiMetBu2, R‘ = 2,4,6-iPr3C6H2): The New Stable Germastannenes (2003) (26)
- Synthesis and Structure of Cyclotrigermenium Salt of the Tetrakis{3,5-bis(trifluoromethyl)phenyl}borate Anion. A Stable Free Germyl Cation in the Condensed Phase (1998) (26)
- Group-14-Element-Based Hybrid Dendrimers. Synthesis and Characterization of Dendrimers with Alternating Si and Ge Atoms in the Chains (1998) (26)
- Decompositions of polysilylated diazomethanes: silene formations by selective silyl migration (1987) (25)
- Tri-tert-butylsilylsilylenes with alkali metal substituents ((t)Bu3Si)SiM (M = Li, K): electronically and sterically accessible triplet ground states. (2008) (25)
- Observation of the predicted negative Faraday A MCD term in a cyclobutadiene dianion. (2001) (25)
- Silyl-substituted 1,4-disila(dewar benzene) : New synthesis and unexpected insertion of CO into the Si-Si bond to form a disilyl ketone (2005) (25)
- Lithium and Sodium Complexes of a Tetrasilylethylene Dianion (1995) (25)
- Tetrasila-1,3-butadiene and its transformation to disilenyl anions (2007) (25)
- Silylium Ions Stabilized by an Si–X–Si Three-center Bond (X = Halogen or Hydrogen) (2004) (25)
- High-pressure synthesis, structure and novel photochemical reactions of 7,7,8,8-tetramethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene (1991) (24)
- New Fused Bicyclic Cyclotrigermanes from Cycloaddition Reactions of Cyclotrigermene. (2000) (24)
- SiGe2 and Ge3: cyclic digermenes that undergo unexpected ring-expansion reactions. (2005) (24)
- Eta(5)-1,2,3-trisilacyclopentadienyl--a ligand for transition metal complexes: rhodium half-sandwich and ruthenium sandwich. (2009) (24)
- The first bicyclo[1.1.0]butane dianion of heavier group 14 elements. (2004) (23)
- Heavy analogues of the 6π-electron anionic ring systems: Cyclopentadienide ion and cyclobutadiene dianion (2007) (23)
- Stable mononuclear radical anions of heavier group 13 elements: [(tBu2MeSi)3E.-].[K+(2.2.2-Cryptand)] (E = Al, Ga). (2005) (23)
- Spirobis(pentagerma[1.1.1]propellane): a stable tetraradicaloid. (2013) (23)
- 1,2-Silaoxetene (1984) (22)
- 4,8-Dichloroocta-t-butyltetracyclo[3.3.0.02,7.03,6]octagermane (1989) (22)
- Silicon version of enamines: Amino-substituted disilenes by the reactions of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) with amines (2011) (22)
- Chemistry of silylcarbene. V. 1,2-Silaoxetane intermediate in the gas phase decomposition of silyl phenyl ketones. New route for the formation of a silicon-carbon double bond (1975) (22)
- Silabenzene and silafulvene by ring contraction and expansion of cyclic silylcarbenes (1985) (22)
- Aromaticity of the Cyclobutadiene Dianion: Structural Characteristics and Magnetic Properties (2002) (21)
- Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene. (2017) (21)
- Isolable Alkali-Metal-Substituted Silyl Radicals (tBu2MeSi)2SiM (M = Li, Na, K): Electronically and Sterically Accessible Planar Silyl Radicals (2008) (21)
- Structural diversity of the tris(di-Tert-butylmethylsilyl)stannyl anion: Monomeric vs dimeric, lithium coordinated vs lithium free (2004) (21)
- 2,4-Disila-1-germatricyclo[2.1.0.0(2,5)]pentane: a new type of cage compound of group 14 elements with an extremely long Ge-C bridge bond and an "Umbrella"-type configuration of a Ge atom. (2002) (21)
- Perfluoroaryltetrahedranes: tetrahedranes with extended sigma-pi conjugation. (2009) (21)
- Stibasilene Sb═Si and its lighter homologues: a comparative study. (2014) (21)
- 1,3-Disila-2-gallata- and -indataallenic Anions [>SiMSi<]-.Li+ (M = Ga, In): compounds featuring double bonds between elements of groups 13 and 14. (2004) (21)
- 1,1,2,2-Tetrakis(dimethylsilyl)-1,2-ethanediylithium-bis(diethyl ether):Observation of a SiHLi Agostic Interaction† (1997) (20)
- 1,2-Silaoxetane. Isolation and characterization in the reaction of silaethylene with ketones (1982) (20)
- Ring Contraction of 1,2-Digermacyclohexa-1,4-diene to (Germacyclopent-3-enyl)germylene (2001) (20)
- [[(Me3Si)2CH]2(i)PrSi(NHC)Si═Si(Me)Si(i)Pr[CH(SiMe3)2]2]+: a molecule with disilenyl cation character. (2012) (20)
- Making Stable Radicals of Heavy Elements of Groups 14 and 13: The Might of Silyl Substitution (2008) (19)
- Matrix Isolation and Ultraviolet Spectra of Germylenes (1987) (19)
- Novel organometallic reagents: geminal dianionic derivatives of the heavy group 14 elements. (2011) (19)
- A new route to 1,4-disilabenzenes and 1,4-disilabarrelenes (1988) (19)
- Gas-phase pyrolysis of phenyltrimethylsilyldiazomethane. Intramolecular chemistry of phenyltrimethylsilylcarbene (1977) (19)
- A two-and-a-half-layer sandwich: potassium salt of anionic (η(4)-tetrasilacyclobutadiene)(η(5)-cyclopentadienyl)ruthenium. (2010) (19)
- Reactivity of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) toward bis(silylcyanide) forming a 1,4‐diaza‐2,3‐disilabenzene analog (2010) (19)
- Doubly charged four-membered ring systems : Cyclobutadiene dianions and heavy cyclobutadiene dianions (2006) (19)
- Unexpected Hydrolithiation of M=M'Double Bond (M, M'=Si, Ge) with ^tBuLi (2004) (19)
- 6-Silafulvene via silylcarbene rearrangement from diazo-2-silacyclohexa-3,5-diene (1981) (19)
- Comment on "Disproving a silicon analog of an alkyne with the aid of topological analyses of the electronic structure and ab initio molecular dynamics calculations". (2006) (18)
- Reaction of disilagermirenes with phenylacetylene: from a germasilene GeSi to a metalladiene of the type SiGeCC (2001) (18)
- Pyrolysis of methylsilyl phenyl ketones. Formation of silene in the decomposition of an intermediate silaoxetane (1977) (18)
- 1,4,5-trigermabicyclo[2.1.0]pent-2-en-5-ylium: the isolable bishomocyclopropenylium ion containing a heavier group 14 element. (2003) (18)
- Silathiacyclopropane. Isolation and characterization (1984) (18)
- (η5-Cyclopentadienyl)(η4-tetrasila-and η4-trisilagermacyclobutadiene)cobalt : Sandwich Complexes Featuring Heavy Cyclobutadiene Ligands (2007) (18)
- A blue digermene (t-Bu2MeSi)2Ge=Ge(SiMet-Bu2)2. (2011) (18)
- Silicon-Centered Cations (2017) (17)
- Dianion Dialkali Metals of 2,2′,5,5′-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures (1995) (17)
- 1,2,5,6-Tetrasilabenzobenzvalene : A Valence Isomer of 1,2,3,4-Tetrasilanaphthalene (2007) (17)
- Photoisomerization of Persilyl-Substituted Silacyclopropene: Formation of Stable Persilyl-Substituted 1-Silaallene, and Its Reactivity (2001) (17)
- Isomerization of silene to ketene in the photolysis of pentamethyldisilanyldiazoacetate (1981) (17)
- Computational study of tetrasilylcyclobutadiene dianion and its dilithium salt. 6e–6c Three-dimensional aromaticity (2005) (17)
- From Borapyramidane to Borole Dianion. (2018) (16)
- 1,6,7-Trigermabicyclo[4.1.0]hept-3-en-7-yl: The Isolable Bicyclic Germyl Radical (2004) (16)
- Lithiosilanes with Si–Si Bonds: Synthesis and 6Li, 7Li, and 29Si NMR Studies (1998) (16)
- Sulfur-substituted tetrahedranes. (2011) (16)
- Silylacetylene dendrimers: synthesis and characterization (1999) (16)
- Photochemical decomposition of trimethylsilyl diazoacetates in alcohols (1979) (16)
- Improving battery safety by reducing the formation of Li dendrites with the use of amorphous silicon polymer anodes (2015) (15)
- Intramolecular reaction of silene. Evidence for the isomerization of silaacrylate to alkoxyketene (1987) (15)
- Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups. (1995) (15)
- Electronic Structure of Stable Radicals of the Heavy Group 14 Elements: UV-Photoelectron Spectroscopy Characterization (2008) (15)
- Theoretical study on the relationship between diradical character and second hyperpolarizabilities of four-membered-ring diradicals involving heavy main-group elements. (2015) (15)
- Heavy cyclopropene analogues R4SiGe2 and R4Ge3 (R = SiMetBu2) : New members of the cyclic digermenes family (2007) (15)
- Unusual reactivity of a disilyne with 4-dimethylaminopyridine: formation of an intramolecularly N-coordinated silylene and its isomerization to a zwitterionic silyl anion. (2011) (15)
- Heavy Analogs of Alkenes, 1,3‐Dienes, Allenes and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb (2010) (15)
- Ring expansion of silacyclopentadienylcarbene to silabenzene (1984) (15)
- Electronic Structure of Bis(silyl)carbon-, Bis(silyl)silicon-, and Bis(silyl)germanium-Centered Radicals (R3Si)2XE• (E = C, Si, Ge; X = H, Re(CO)5, F): EPR and DFT Studies† (2010) (15)
- A stable silagermene (tBu3Si)2Si=Ge(mes)2 (mes = 2,4,6-trimethylphenyl): Synthesis, X-ray crystal structure, and thermal isomerization (2008) (15)
- Thia- and selenasilaboriranes and 1,3,2,4-dioxasilaboretane from a stable silaborene (2007) (14)
- Pyramidanes: The Covalent Form of the Ionic Compounds (2016) (14)
- Cyclobutadiene to tetrahedrane: Valence isomerization induced by one-electron oxidation† (2011) (14)
- Cage Compounds of Si and Ge: Synthesis and Structures (1994) (14)
- Pentagermapyramidane: crystallizing the "transition-state" structure. (2015) (14)
- Photo-induced electron transfer reaction of polysilanes. Intramolecular trapping of a transient silyl radical cation with a nucleophile (1991) (13)
- DIRECT SYNTHESIS OF TERMINAL OLEFINS FROM KETONES. APPLICATION OF (CHLOROMETHYL)TRIMETHYLSILANE TO A WITTIG REACTION (1979) (13)
- 3Δ-1,2,3,4-Disilagermastannetene: the first cyclic germastannene (2004) (13)
- Role of alkoxysilylketenes and the absence of carbon-silicon double bonds in the gas-phase decomposition of trimethylsilyldiazoacetates (1975) (13)
- Crystal structures of the first generation of phenyl-substituted and permethyl-substituted dendritic polysilanes (1999) (13)
- Cyclotrigermenium Ion, a Free Germyl Cation with 2π-Electron System (1997) (13)
- Pentasilatricyclo[2.1.0.0(2,5)]pentane and its anion. (2009) (13)
- 1,3-Digerma-2-gallata-and -indataallenic Anions : The First Compounds with Ge=Ga or Ge=In Double Bonds (2008) (13)
- Disilagermirenes: heavy cyclopropenes of Si and Ge atoms (2003) (13)
- Photoisomerization of perfluoroaryltetrahedranes to perfluoroarylcyclobutadienes. (2011) (12)
- Reaction of Bis[bis(trimethylsilyl)methyl]germylene with Tris(4-tert-butylphenyl)methylium Ion: Formation of a Unique Germyl Cation Weakly σ-Coordinated to Aromatic Group (2002) (12)
- Silicon‐, Germanium‐, and Tin‐Centered Cations, Radicals, and Anions (2006) (12)
- Tetrakis(di‐tert‐butylmethylsilyl)digermene: Synthesis, Structure, Electrochemical Properties, and Reactivity (2014) (12)
- Addition of methyllithium to disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]), giving a disilenyllithium, and its unexpected isomerization to a disilacyclopropylsilyllithium (2010) (12)
- Pyrolysis of silylphenyldiazomethanes. Rearrangement of silylcarbenes to compounds containing an SiC double bond (1975) (12)
- A Schrock-Type Germylene Complex: (η5-C5H4Et)2(PMe3)Hf═Ge(SiMetBu2)2 (2015) (12)
- Synthesis of silyl ketone by the photosensitized oxygenation of silyl diazo compounds (1979) (12)
- PHOTOLYSIS AND PYROLYSIS OF POLYSILYLATED DIAZOMETHANES. EFFECTIVE MIGRATING TENDENCY OF TRIMETHYLSILYL GROUP TO A CARBENE CENTER (1983) (12)
- Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]4 and Conversion to [R(Cl)Ge]4. The First Functionalized Cyclotetragermanes (1992) (12)
- An (η3-Disilaallyl)lithium Derivative: Interconversion of π-Allyl-Type Bonding and η1 Coordination to a Silyllithium Fragment (2009) (11)
- Reaction of cyclotrisilene with phenylacetylene: an unusual product with a bicyclo[3.2.0]hepta-3,6-diene skeleton (2001) (11)
- Tetraanion Tetralithium with 8 Center/12 Electron π-System Stabilized by Silyl Groups. Synthesis and Characterization (1998) (11)
- A Cationic Phosphapyramidane. (2016) (11)
- Useful Application of Thiosilanes for Preparation of Symmetrical and Unsymmetrical Dialkyl Sulfides (1983) (11)
- Synthesis and Molecular Structure of a Dilithium Salt of the cis-Diphenylcyclobutadiene Dianion (2000) (11)
- A Supercharged Anion with a Silyl-Substituted Eight-Center, Twelve-Electron π System: Synthesis and Characterization of the Tetralithium Salt of an Octasilyl-Substituted Trimethylenecyclopentene Tetraanion† (1997) (11)
- Crystal Structures of Unsolvated Lithiosilanes with Si–Si Bonds (1999) (10)
- Matrix Isolation of Silenes and Their Ultraviolet Absorptions (1986) (10)
- Interconversion of cyclotrimetallenes and dihalocyclotrimetallanes consisting of group 14 elements (2001) (10)
- Reactions of oxasilacyclopropane. Generation of silanediyl by photo and thermal induced cycloelimination (1983) (10)
- Tetrakis(trimethylsilyl)cyclobutadiene Dianion Alkaline Earth Metal Salts: New Members of the 6π-Electron Aromatics Family (2008) (10)
- Formation of a benzosilacyclopentene. Formation of a silacyclopropane by intramolecular insertion of a silylcarbene (1974) (10)
- Heavy Analogs of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes (2010) (10)
- Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity (2004) (10)
- Tetrasilyl-substituted cyclobutadiene dianion dilithium salt: synthesis and structure (2004) (10)
- A Diels–Alder super diene breaking benzene into C2H2 and C4H4 units (2014) (10)
- Formation and Structure of Protonated Tetrasilatetrahedrane-monooxide, (tert-Bu3Si)4Si4OH+ (1999) (10)
- Isolable aryl-substituted silyl radicals: synthesis, characterization, and reactivity. (2014) (10)
- 1,2,9,10,17,18‐Hexasila[2.2.2](1,3,5)cyclophane, a Cage‐like Phane Containing Three Si–Si Units (1989) (10)
- Germathiirane intermediate from the reaction of germylene with thioketones (1985) (9)
- THE FIRST ISOLATION AND FULL CHARACTERIZATION OF FULVENE DIANION. SYNTHESIS AND X-RAY STRUCTURE OF DILITHIUM HEXASILYLFULVENE DIANION (1998) (9)
- Matrix isolation of silaacrylate and its photochemical reaction (1985) (9)
- Theoretical Study on the Enhancement of the Second Hyperpolarizabilities of Si-, Ge-Disubstituted Quinodimethanes: Synergy Effects of Open-Shell Nature and Intramolecular Charge Transfer (2015) (9)
- Electrochemical properties and computations of stable radicals of the heavy group 14 elements (Si, Ge, and Sn). (2009) (9)
- Dye-sensitized photooxidation of silyl diazo compounds. Intramolecular oxygen transfer of carbonyl oxides (1982) (9)
- 1,3,5-[(tBu2MeSi)2Si]3C6H3: Isolable Si-centered Triradical with a High-spin Quartet Ground State (2015) (9)
- Pyrolysis of 1-(trimethylsilyl)-1-alkanols. New carbene precursors of silylcarbene and phenylcarbene (1980) (8)
- [2+2] Cycloadduct of Titanium Silylidene and Benzonitrile (2019) (8)
- A new pathway in the reaction of disilene with carbonyl compounds: an 'ene' reaction instead of cycloaddition. (2001) (8)
- Silylcarbene-to-Silene Rearrangement: Stable 1,2-Dihydrosilenes in Solution via the Silylcarbene Route (2008) (8)
- Synthesis and Reduction of Silyl-Substituted [5]Radialene. Characterization and Structure of a [5]Radialene Tetraanion with a Ten-Center, Fourteen-Electron π-System (2000) (8)
- From a Si3-Cyclopropene to a Si3S-Bicyclo[1.1.0]butane to a Si3S-Cyclopropene to a Si3S2-Bicyclo[1.1.0]butane: Back-and-Forth, and In-Between. (2015) (8)
- Photo-oxygenation of diphenyldiazomethane in the presence of phenyl trimethylsilyl ketone. Oxygen transfer from carbonyl oxide to the silyl ketone (1979) (8)
- SYNTHETIC APPLICATION OF THIOSILANES TO THIOESTERS (1982) (7)
- Photochemical Generation of Chlorine-substituted Digermenes and Their Rearrangement to Germylgermylenes (2002) (7)
- Formation of Dialkyl α-Siloxybenzylphosphonate via 1,2-Anionic Rearrangement of a Silyl Group (1978) (7)
- Isolation and characterization of the tetralithium salt of [5]radialene tetraanion stabilized by silyl groups (1999) (7)
- Heavy Metallocenes of the Group 8 Metals: Ferrocene and Ruthenocene Derivatives (2013) (7)
- Two-coordinate Group 13 Element (Al, Ga) Centered Cations Formed by Silyl Group Migration: Synthesis and Characterization (2007) (7)
- Synthesis and Reduction of Octasilyl[4]radialene. Structure and Dynamic Study of [4]Radialene Dianion with Eight-Center Ten-Electron π-System (1998) (7)
- Preparation and reactions of a disilyne synthon, 7,7′‐bis(7‐methyl‐1,4,5,6‐tetraphenyl‐7‐sila‐2,3‐benzo‐norbornadiene) (2010) (7)
- Ozonolysis of silyl diazo compounds and silyl ketones (1979) (7)
- Intramolecular Oligomerization of Disilalkylene{-Me_2Si(CH_2)_nSiMe_2-}Bridged Cyclic Triacetylenes^1 (1996) (7)
- Cyclotrigermenium Ion by Oxidation of Cyclotrigermene with Trityl Tetrakis {3,5-Bis(Trifluoromethyl)Phenyl}Borate and Trityl Tetrakis(Pentafluoro-Phenyl)Borate. A Stable Free Germyl Cation in the Condensed Phase (1999) (7)
- Cross-coupling reaction of a highly strained molecule: synthesis of σ-π conjugated tetrahedranes. (2013) (7)
- Trapping of silylenes by 9,10-dimethylanthracene: 2,3:5,6-dibenzo-7-silabicyclo[2.2.1]hepta-2,5-dienes (1986) (6)
- Intramolecular reaction of carbonyl oxide. Formation of a silyl ester in the photosensitized oxygenation of a silyl diazo compound (1979) (6)
- Chemistry of Organosilicon Compound. 289. Thermolyses of Hexakis(trimethylsilyl)benzene and Pentakis(trimethylsilyl)toluene. The First Unique Trimethylsilyl-Triggered Rupture of Benzene Rings. (1991) (6)
- From a (Silatrigerma)cyclobutenylium Ion to a (Silatrigerma)cyclobutenyl Radical, and Back. (2020) (6)
- TIME-RESOLVED AND LOW-TEMPERATURE ABSORPTION SPECTROSCOPIC STUDIES ON 10-SILAANTHRACEN-9(10H)-YLIDENE (1983) (6)
- Anion Chemistry of Silyl-Substituted π-Electron Systems Based on Four- and Five-Membered Rings (1999) (6)
- Dihydrosilaanthracenylidene and dihydroanthracenylidene (1983) (6)
- Matrix Effect. Dimerization of Silylenes at 77 K in the Matrix (1987) (6)
- Heavy Analogs of Carbanions: Si‐, Ge‐, Sn‐ and Pb‐Centered Anions (2010) (6)
- 1,1,2,2,9,9,10,10-Octamethyl-1,2,9,10- tetragerma[2.2]paracyclophane: the first [2.2]paracyclophane bridged by two GeGe bonds (1990) (6)
- Mass Spectral Fragmentations of Polysilanylalkanols. The Analogies between Mass Spectrometry and Photo-Induced Electron Transfer (1991) (6)
- A Facile Synthesis of Tetrakis(trimethylsilyl)butatriene Properties and Cycloadditions (1988) (6)
- A New Approach to the Synthesis of Unsymmetrical Disilenes and Germasilene: Unusual 29Si NMR Chemical Shifts and Regiospecific Methanol Addition. (2002) (5)
- Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene: [(HMe2Si)2C=C(SiMe2H)2]2−[M+(ligand)n]2. Evidence for SiH–Alkali Metal Agostic Interactions (1999) (5)
- Polyhedral Silicon Compounds (1999) (5)
- Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System (1996) (5)
- Synthesis of Cyclic Silyl Diazo Compounds (1982) (5)
- Synthesis and Characterization of the Dilithium Salt of the Octasilyl[4]radialene Dianion: Evidence for a Lithium Walk on the Eight-Center, Ten-Electron π-Electron System. (1998) (5)
- Dilithium 1,4-Disilacyclohexa-2,5-diene-1,4-diide by the Reduction of 1,4-Disilabicyclo[2.2.0]hexa-2,5-diene: Synthesis and Characterization (2006) (5)
- Reduction of the 1,4,5,8-tetrasila-1,4,5,8-tetrahydroanthracene derivative with lithium metal. Isolation and characterization of the tetralithium salt of a tetraanion, and observation of an Si–H⋯Li+ interaction (1999) (4)
- Thermal generation of bis(trimethylsilyl)methylsilylene. Rearrangement of the silylene to a silaethylene via 1,2-shift of trimethylsilyl group (1983) (4)
- Distorted Saturated Hydrocarbons (2009) (4)
- Isolation and characterization of the monomeric and dimeric structures of tetrakis(trimethylsilyl)butatriene dianion dilithium (2001) (4)
- Silanediyl to sila-alkene conversions. Generation and rearragement of cyclopropylsilanediyl (1982) (4)
- The study of bonding in pyramidanes [(Me3Si)4C4]E (E = Ge, Sn, Pb) by optical (Raman, UV–vis) spectroscopy and quantum-chemical methods (2017) (4)
- The hexasiladigermacubane dianion (2010) (4)
- Synthesis of silyldiazoketones from lithium pentamethyldisilanyldiazomethane with acid chlorides (1983) (4)
- Multiply Bonded Compounds of Group 14 Elements (2013) (4)
- Formation of Indan and 2,3-Dihydrobenzofuran via Intramolecular Insertion of Phenylcarbene (1977) (4)
- UV‐Photoelectron Spectroscopy of a Tetrakis(trimethylsilyl)tetrahedrane and Its Pentafluorophenyl Derivative (2013) (4)
- Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System: Synthesis and Characterization (1999) (4)
- Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium–Bridged Structures and Unexpected Anionic Rearrangement (1993) (4)
- Radical Hydrodehalogenation of Aryl Halides with H2 Catalyzed by a Phenanthroline-Based PNNP Cobalt(I) Complex (2022) (3)
- Reaction of stannylcarbene with sulphides. A novel C–S insertion of stannylcarbene into C–S bonds (1979) (3)
- Heavy Analogs of Carbenium Ions: Si‐, Ge‐, Sn‐ and Pb‐Centered Cations (2010) (3)
- Photochemical reaction of silyl‐substituted 1,4‐disila(dewar‐benzene) with isocyanide and phenylacetylene (2008) (3)
- Stable Silyl, Germyl, and Stannyl Cations, Radicals, and Anions: Heavy Versions of Carbocations, Carbon Radicals, and Carbanions (2007) (3)
- Photochemical isomerization of 1,2,5-trisilabicyclo[3.2.0]hepta-3,6-diene to 1,4,7-trisilabicyclo[2.2.1]hepta-2,5-diene. (2003) (3)
- Reduction of tetrakis(trimethylsilyl)butatriene by lithium: Monomeric and dimeric structures of the dilithium butatriene dianion (2002) (3)
- Chemistry of Organosilicon Compounds. Part 303. The “Missing” Hexasilaprismane: Synthesis, X‐Ray Analysis, and Photochemical Reactions. (1993) (3)
- Synthesis and Structure of Cyclotrigermenium Salts of Tetrakis{3,5‐bis(trifluoromethyl)phenyl}borate, Tetrakis(pentafluorophenyl)borate and Tetrakis{4‐[tert‐butyl(dimethyl)silyl]‐2,3,5,6‐tetrafluorophenyl}borate: A Stable Free Germyl Cation in the Condensed Phase (2000) (3)
- Si3S-, Si3Se-, Si3Te-Bicyclo[1.1.0]butanes and Si3S2-Bicyclo[1.1.1]pentane (2011) (3)
- Chemistry of Germanium-Characteristics and Similarity as a Group 14 Element. Synthesis and Characterization of Cyclotetragemane and Ladder Polygermane with Functional Groups. (1994) (3)
- Arsagermene, a compound with an –AsGe double bond (2018) (3)
- Chemistry of Silyl Diazo Compounds (1977) (3)
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- Cyclobutadiene Dianion Dilithium: a New Aromatic Ring System (2001) (3)
- Chemistry of Organosilicon Compounds 279. Molecular Structure of Phenyl(tris(trimethylsilyl))ethylene Dilithium Complex. An Orthogonal Dianion. (1992) (3)
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- Long-Range Metal–Ligand Cooperation by Iron Hydride Complexes Bearing a Phenanthroline-Based Tetradentate PNNP Ligand (2021) (2)
- Diphenyltetrahedrane Derivative: A Molecule with an Extended π–σ–π Conjugation (2015) (2)
- 1,1-bis(trimethylsilyl)-1-alkanols as silylcarbene equivalent (1980) (2)
- Chemistry of Organosilicon Compounds. Part 334. Intramolecular Oligomerization of Disilalkylene (-Me2Si(CH2)nSiMe2-) Bridged Cyclic Triacetylenes. (1997) (2)
- The Chemistry of Disilyne with a Genuine Si—Si Triple Bond: Synthesis, Structure, and Reactivity (2006) (2)
- Tetrasilacyclobutadiene (tBu2MeSi)4Si4: A New Ligand for Transition-Metal Complexes. (2005) (2)
- Heteronuclear Heavy Alkenes E=E′ (E,E′ = Group 14 Elements): Germasilenes, Silastannenes, Germastannenes...Next Stop? (2004) (2)
- Group 14 element cationic pentagonal–pyramidal complexes Ea[η5-Eb5(SiMe3)5]+ (Ea = Si–Pb, Eb = Si, Ge): A quantum-chemical study (2016) (2)
- Making a Cyclotrigermene from a Digermene (2011) (2)
- Photo-energy Transfer in σ-π Conjugated Polysilanes Prepared by Platinum-catalyzed Reactions of Arylacetylenes with Layered Polysilane (2020) (2)
- Hybrid group 15(E 15 )–group 14(E 14 ) element cationic pyramidal structures E 15 [E 14 4 (SiR 3 ) 4 ] + : A DFT study (2017) (2)
- Co(I) complexes with a tetradentate phenanthroline-based PNNP ligand as a potent new metal-ligand cooperation platform. (2020) (2)
- FOREWORD INTERACTION OF 1-DISILAGERMIRENE WITH CARBONYL COMPOUNDS (2002) (2)
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- 1,2-Dibromo-3Δ-1,2,3,4-disiladigermetene (2011) (2)
- 1-Chloroalumole (2022) (2)
- 1,1-Dilithiosilanes, 1,1-Dilithiogermanes, 1,1-Dilithiostannanes and Related Compounds: Organometallic Reagents of the new Generation (2015) (2)
- Isolation and Molecular Structure of Persilyalated [5]Radialene: Intramolecular Cyclization of a Macrocyclic Pentayne with Mn(CO)3(Me-Cp) (1998) (2)
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- (Tetragermacyclobutadiene)ruthenium tricarbonyl [η4-(But2MeSi)4Ge4]Ru(CO)3 (2013) (1)
- Synthesis, Properties, and Molecular Structure of Tetrakis(pentamethyldisilanyl)ethylene (1990) (1)
- Chemistry of Carbonyl Oxides (1981) (1)
- Exotic Polyhedral Oligogermanes and Related Molecules (1992) (1)
- Cage Compounds of Heavier Group 14 Elements (2003) (1)
- Disilagermirene and Silagermasilirene: from a Stable Disilene to a Stable Germasilene (2001) (1)
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- Cyclic Polyenes of Heavy Group 14 Elements: New Generation Ligands for Transition‐Metal Complexes (2008) (1)
- Cover Picture: Hexakis(trimethylsilyl)tetrahedranyltetrahedrane (Angew. Chem. Int. Ed. 36/2005) (2005) (1)
- Heteronuclear Double Bonds E=E′ (E: Heavy Group 14 Element, E′: Group 13—16 Element) (2010) (1)
- Heavy Analogs of Aromatic Compounds (2010) (1)
- Spiro[2,5-dibenzo-1,4-disilacyclohexa-2,5-diene-1,7′-2′,5′- dibenzo-1′,4′,7′-trisilanorbornadiene]: Unusual Dimerization of Silyl-Substituted 9,10-Disila(Dewar Anthracene) (2010) (1)
- Aromaticity of Group 14 Organometallics: Experimental Aspects (2007) (1)
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- Photolysis of Silyldiazomethane. The Migrating Tendencies of the Groups on Silicon Atom. (1977) (0)
- PHOTOOXYGENATION OF DIPHENYLDIAZOMETHANE IN THE PRESENCE OF PHENYL TRIMETHYLSILYL KETONE. OXYGEN TRANSFER FROM CARBONYL OXIDE TO THE SILYL KETONE (1979) (0)
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- PHOTOSENSITIZED DECOMPOSITIONS OF OXASILACYCLOPROPANE; UNUSUAL CARBENE FORMATION (1985) (0)
- PYROLYSIS OF SILYLPHENYLDIAZOMETHANES, REARRANGEMENT OF SILYLCARBENES TO COMPOUNDS CONTAINING A SI=C DOUBLE BOND (1975) (0)
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- Doubly Charged Four-Membered Ring Systems: Cyclobutadiene Dianions and Heavy Cyclobutadiene Dianions (2007) (0)
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- Unsaturated Three-Membered Rings of Heavier Group 14 Elements (2003) (0)
- REACTION OF STANNYLCARBENE WITH SULFIDES. A NOVEL CARBON-SULFUR INSERTION OF STANNYLCARBENE INTO CARBON-SULFUR BONDS (1980) (0)
- 1,1,2,2,9,9,10,10-Octamethyl-1,2,9,10-tetragerma(2.2)paracyclophane: The First (2.2)Paracyclophane Bridged by Two Ge-Ge Bonds. (1990) (0)
- A Super Diene Busts Up Benzene (2014) (0)
- Heavier Group 14 Element Redox Systems (2015) (0)
- Arsagermene, a compound with an -As[double bond, length as m-dash]Ge[double bond splayed right] double bond. (2018) (0)
- Isolation and Molecular Structure of Persilylated [5]Radialene: Intramolecular Cyclization of a Macrocyclic Pentayne with Mn(CO)3(Me—Cp). (1999) (0)
- SiGe2 and Ge3: Cyclic Digermenes that Undergo Unexpected Ring‐Expansion Reactions. (2006) (0)
- SILANEDIYL-TO-SILAALKENE CONVERSIONS. GENERATION AND REARRANGEMENT OF CYCLOPROPYLSILANEDIYL (1982) (0)
- Hybrid Bicyclo[1.1.0]butanes [(R4Si3)CH2] and [(R4Si2Ge)CH2] (R = SiMetBu2): Synthesis and Thermal Isomerization to Alkyl-Substituted Cyclopropenes [R3Si3]CH2R and [R3Si2Ge]CH2R (2023) (0)
- Chemistry of Organosilicon Compounds. Part 281. Photo-Induced Electron Transfer Reaction of Polysilanes. Intramolecular Trapping of a Transient Silyl Radical Cation with a Nucleophile. (1992) (0)
- ( tBu 2 MeSi ) 2 Sn d Sn ( SiMetBu 2 ) 2 : A Distannene with a > Sn d Sn < Double Bond That Is Stable Both in the Solid State and in Solution (0)
- Disilyne with a Silicon—Silicon Triple Bond: A New Entry to Multiple Bond Chemistry (2008) (0)
- SYNTHETIC APPLICATION OF THIOSILANES TO THIO ESTERS (1982) (0)
- The first spectroscopic detection of silaylides in the reaction of dimesitylsilylene with P, S, and N heteroatom-containing substrates. The stability of silaylides (1988) (0)
- Reactivity of a disilyne RSi identical with SiR (R=SiiPr[CH(SiMe3)2]2) toward pi-bonds: stereospecific addition and a new route to an isolable 1,2-disilabenzene. (2007) (0)
- Reaction of Cyclotrisilene with Phenylacetylene: An Unusual Product with a Bicyclo[3.2.0]hepta-3,6-diene Skeleton. (2001) (0)
- Berichtigung: Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene (2020) (0)
- A New Route to 1,4-Disilabenzenes and 1,4-Disilabarrelenes. (1988) (0)
- Chemistry of Organosilicon Compounds. Part 263. Synthesis, Properties, and Molecular Structure of Highly Distorted Hexakis(trimethylsilyl)benzene. (1990) (0)
- Germathiirane Intermediate from the Reaction of Germylene with Thioketones. (1986) (0)
- Chemistry of Ethylene Dianions and Benzene Dianions (1992) (0)
- Preparation and Reactions of a Disilyne Synthon, 7,7-Bis(7-methyl-1,4,5,6-tetraphenyl-7-sila-2,3-benzo-norbornadiene). (1988) (0)
- Tuning Philicity of Dichlorosilylene: Nucleophilic Behavior of the Dichlorosilylene–NHC Complex Cl2Si–IPr (2019) (0)
- Titelbild: Hexakis(trimethylsilyl)tetrahedranyltetrahedrane (Angew. Chem. 36/2005) (2005) (0)
- Corrigendum: Spectroscopic Observation of the Triplet Diradical State of a Cyclobutadiene. (2020) (0)
- Heavy Cyclopropenes of Si, Ge, and Sn — A New Challenge in the Chemistry of Group 14 Elements (2003) (0)
- Organosilicon Compounds. Part 302. Regio‐ and Stereochemistry and Kinetics in the Addition Reactions of Alcohols to Phenyl‐Substituted Disilenes. (1994) (0)
- CCDC 1833284: Experimental Crystal Structure Determination (2018) (0)
- Tetrasilacyclobutadiene ((t)Bu(2)MeSi)(4)Si(4): a new ligand for transition-metal complexes. (2005) (0)
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