Alain Krief
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Alain Krief's Degrees
- PhD Computer Science Université Paris Cité
- Masters Computer Science Université Paris Cité
- Bachelors Mathematics Université Paris Cité
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(Suggest an Edit or Addition)Alain Krief's Published Works
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Published Works
- Organoselenium Chemistry I (1988) (355)
- Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI(2), the Kagan Reagent. (1999) (347)
- Synthetic methods using α-heterosubstituted organometallics (1980) (218)
- Efficicient, high yield, oxidation of thiols and selenols to disulphides and diselenides (1990) (133)
- One-world chemistry and systems thinking. (2016) (124)
- Syntheses of tetraheterofulvalenes and of vinylene triheterocarbonates-strategy and practice (1986) (115)
- Reorienting chemistry education through systems thinking (2018) (98)
- Synthesis of selenoacetals (1985) (75)
- The role of chemistry in inventing a sustainable future. (2015) (75)
- Fake science and the knowledge crisis: ignorance can be fatal (2019) (60)
- Cleavage of selenoacetals by clay-supported metal nitrates (1984) (53)
- Stereoselective synthesis of methyl (1R) trans- and (1R) cis-hemicaronaldehydes from natural tartaric acid: Application to the synthesis of s-bioallethrin and deltamethrin insecticides§ (1989) (49)
- Cleavage of Selenium Compounds by Butyllithium. A New, Regiospecific, Allyl Alcohol Synthon (1974) (44)
- CHEMOSELECTIVE REDUCTION OF ORGANOSELENOCYANATES TO DISELENIDES AND SELENOLATES (1997) (42)
- Synthesis of diselenides and selenides from elemental selenium (2002) (42)
- Efficient regioselective syntheses of α and β cuparenones. A new approach for the construction of the cyclopentane ring (1983) (40)
- Transformation of selenides to alkylhalides new routes for homologization of primary alkylhalides (1976) (38)
- Synthesis and Reactions of Unstabilized α‐Selenonio Alkylides (1974) (37)
- Self-generated hierarchically porous titania with high surface area: photocatalytic activity enhancement by macrochannel structure. (2012) (37)
- Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums (1989) (35)
- Novel functional group transformations involving alkyl phenyl selenones (1985) (35)
- Synthesis and synthetic applications of 1-metallo-1-selenocyclopropanes and -cyclobutanes and related 1-metallo-1-silylcyclopropanes (1987) (34)
- New regiospecific routes to olefins from β-hydroxy selenides (1976) (34)
- Synthesis using 1-lithio 1-seleno alkenes (1982) (32)
- Synthesis of α-selenoalkyllithium compounds (1989) (32)
- Diastereoselective synthesis of dimethyl cyclopropane-1,1-dicarboxylates from a γ-alkoxy-alkylidene malonate and sulfur and phosphorus ylides (1998) (31)
- Synthesis of Olefins from α‐Silyl Carbanions and Carbonyl Compounds (1976) (31)
- Catalytic asymmetric dihydroxylation of α-methylstyrene by air (1999) (30)
- Reduction or alkylative reduction of the carbonyl group (1976) (30)
- Synthesis, structural reassignment, and biological activity of type B MAO inhibitors based on the 5H-indeno[1,2-c]pyridazin-5-one core. (2006) (30)
- From tartaric acid to the most biologically active insecticides: Straightforward enantioselective synthesis of deltamethrin (1988) (30)
- Reactivity of Phenyl Vinyl Selenide with Nucleophiles and Bases (1978) (30)
- New Synthetic Route to Di‐ and Trisubstituted Epoxides (1975) (30)
- A New Reagent for Stereospecific Synthesis of Aziridines from Olefins (1974) (30)
- Synthesis of selenones: a comparative study (1985) (29)
- α-Selenocyclobutyllithium as a 2-lithio-1,3-diene equivalent. regioselective (100%) synthesis of ipsenol (1980) (29)
- Original method for the ring enlargement of cyclic ketones (1984) (29)
- Stereoselective isomerisations of disubstituted olefins via seleniranes and thiiranes (1975) (29)
- Trans-Chelating Chiral Peralkyldiphosphine Ligands (R,R)-(S,S)-2,2"-Bis(1-(dialkylphosphino)ethyl)-1,1''-biferrocenes (AlkylTRAPs) and Their Transition Metal Complexes. (1997) (28)
- Novel synthesis of selenones: Application to the synthesis of alkyl cyclopropanecarboxylates (1988) (28)
- A new design for the synthesis of chrysanthemic esters and analogs And for the “pear ester” synthesis (1976) (28)
- Thionyl Chloride/Triethylamine: A Powerful Reagent for Regiospecific and Stereospecific Formation of Olefins from β-Hydroxyselenides. (1976) (27)
- A New Route to Epoxides (1975) (27)
- Synthesis of arylcycloalkanes from ω-alkenyl benzylselenides (1994) (26)
- Regioselective 1–4 addition of acyl and equivalents to α-enones (1979) (25)
- Allyl methyl selenides : valuable reagents for the synthesis of allyllithiums and α-metallo allyl selenides (1984) (25)
- 1,1-Bis(phenylseleno)- and 1,1-bis(methylseleno)-alkyllithiums as building blocks in organic synthesis (1979) (25)
- Phosphorus tri-iodide (PI3), a powerful deoxygenating agent (1980) (24)
- Efficient Syntheses of Diselenides from Selenols (1988) (24)
- On the mechanism of the synthesis of aryl cyclopropanes from γ-benzenesulfonyloxyalkyl seleno and tin derivatives and n-butyllithium. (1992) (24)
- Synthesis of 2-lithio-1,3-diselenanes and 2-lithio-1,3-dithianes by Se/Li exchange: First successful trapping of axially oriented 2-lithio-1,3-diselenanes (1996) (24)
- Synthesis and reactivity of α-lithio α-trimethylsilyl cyclopropanes and related derivatives (1982) (23)
- New synthetic route to 9,10-imino-phenanthrene (1979) (23)
- Reaction of 1,3-diselenanes with metal amides (1996) (23)
- Cleavage of the CSe bond of cyclic selenoacetals derived from 4-t-butyl cyclohexanone with butyllithiums and tin and silyl hydrides (1993) (23)
- About the mechanism of sterol biosynthesis (1987) (22)
- Novel synthesis of benzyllithiums from benzylselenides (1985) (22)
- Chemoselective Reduction of Organoselenocyanates to Diselenides (1997) (22)
- Hemisynthesis of methyl pyrethroates from γ-alkoxy-alkylidene malonates and isopropylidenediphenylsulfurane and isopropylidenetriphenylphosphorane (2004) (22)
- Unusual Stereofacial Differentiation in the Reduction of Bicyclo[3.1.0]hexanones by Luche's Reagent (NaBH4-CeCl3) (1991) (21)
- Exploratory study on α-metallo selenones: original syntheses of oxaspiropentanes (1988) (21)
- On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium (1992) (21)
- Enantioselective synthesis of chiral caronic esters : application to the syntheses of (1R)-trans-chrysanthemic acid and its (1R)-cis-dibromo vinyl analogue from dimethyl fumarates (1983) (21)
- Regioselective syntheses of polycyclic compounds by carbanion-mediated polycyclisation of olefins. (1991) (21)
- Stereochemistry of the C3 addition of 1-lithio 1,1-bis methylselenoalkanes to methyl cyclohexenones (1981) (21)
- The Chemical Sciences and Equality, Diversity, and Inclusion. (2018) (21)
- Regiospecific synthetic routes to α-seleno carbonyl compounds and to αβ-unsaturated carbonyl compounds (1976) (21)
- New stereospecific synthesis of cis and trans d,1-chrysanthemic esters and analogs via a common intermediate (1978) (20)
- Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides (1980) (20)
- Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols (1981) (20)
- Synergistic effects of carbon doping and coating of TiO2 with exceptional photocurrent enhancement for high performance H2 production from water splitting (2021) (19)
- 1-4 Addition of carbanions to α-β unsaturated carbonyl compounds in the presence of HMPA : first evidence of kinetic control. (1979) (19)
- Mild reduction of α-halo ketones to ketones promoted by PI3 or P2I4 (1981) (19)
- β‐HYDROXY α‐SILYL SELENIDES AS VERSATILE INTERMEDIATES IN ORGANIC SYNTHESIS (1979) (19)
- Regioselective ad [C,C] connective routes to oxetanes and tetrahydrofuranes (1980) (19)
- A New Route to Compounds Bearing Two Contiguous Quaternary Centres (1990) (18)
- Alkylations of Sulfur- and Selenium-containing Carbanions (1991) (18)
- New synthetic route to (1R)-trans-chrysanthemic ester and to the (1R)-cis-gem-dibromovinyl analog from a common intermediate (1982) (18)
- Cleavage (Deprotection) of Selenoacetals to Carbonyl Compounds ; A Comparative Study (1979) (18)
- Original syntheses of epoxides involving organoselenium intermediates (1989) (18)
- Material circularity and the role of the chemical sciences as a key enabler of a sustainable post-trash age (2020) (18)
- Synthesis and Diels-Alder reactions of allylidenecyclopropane (1983) (18)
- Novel stereoselective route to cis-chrysanthemic acid (1988) (18)
- New synthetic routes to vinyl sulfides, ketene thioacetals and their seleno analogues from carbonyl compounds (1981) (18)
- Original reactions of α,α-dithio aryl alkanes with butyllithiums (1991) (18)
- A new general route to olefins from selenides (1980) (18)
- Regiochemistry of the ring expansion of unsymmetrically substituted ketones involving β-hydroxyalkylselenides (1987) (18)
- Comparison between ‘IgY technology’ from chickens and ‘IgG technology’ from mice for production of tailor-made antibodies (2002) (18)
- Synthesis of Diselenoacetals and O‐(Trimethylsilyl)monoselenoacetals (1977) (18)
- Stereochemical outcome of benzyllithiums synthesis from selenides (1992) (17)
- Stereoselective syntheses of 1,2-dialkyl-1-phenyl cyclopentanes involving intramolecular carbolithiation of olefins (1996) (17)
- Metal-Mediated, Completely Diastereofacial Conjugate Addition of Trialkylstannylmetal Reagents to γ-Alkoxy-α,β-Unsaturated Esters. (1999) (17)
- Synthesis of Homoallyl Selenides and Sulfides by Allylation of α-Seleno- and α -Thioalkyllithiums in the Presence of Copper(I) Salts (1984) (17)
- Model Tool to Describe Chemical Structures in XML Format Utilizing Structural Fragments and Chemical Ontology (2010) (17)
- Photo-Oxygenation of Selenides - A New Pathway to Selenoxides (1976) (17)
- Novel synthetic route γ-oxo-acrylates application to the synthesis of pyrenophorin antibiotic (1984) (17)
- Diphosphorus tetraiodine (P2I4) a valuable reagent for regioselective synthesis of iodoalkanes from alcohols (1979) (17)
- Regio and stereochemically controlled ring opening of epoxides with grignard reagents. Stereocontrolled synthesis of the steroid side chains. first stereoselective hemisynthesis of 20s isolanosterol. (1982) (16)
- Phosphorus Triiodide and Diphosphorus Tetraiodide, New Reagents for Deprotecting Acetals and Ketals (1980) (16)
- Novel enantioselective syntheses of optically active (1R)-cis- and (1R)-trans-chrysanthemic acids. (1993) (16)
- Metallation of benzyl selenides and of α-aryl selenoacetals. Scope and limitations. (1986) (16)
- Reaction of 1,3-diselenanes with organolithiums (1996) (16)
- Allylselenides possessing a terminal double bond first regioselective synthesis and reactions (1983) (16)
- From Khoi-San indigenous knowledge to bioengineered CeO2 nanocrystals to exceptional UV-blocking green nanocosmetics (2022) (16)
- Cyclopropanone diselenoketals interesting building blocks in organic synthesis (1978) (16)
- Comparison between alkylseleno, arylseleno and arylthio substituents stabilizing alkyllithium compounds (1989) (16)
- Original syntheses of arylcycloalkanes (1987) (16)
- Original syntheses of carbonyl compounds and gem-dihalocyclopropanes from β-hydroxyalkylselenides (1987) (16)
- Stereoselective syntheses of 1,2-dialkyl-1-phenyl-cyclopentanes by intramolecular carbolithiation of vinyl sulfides. (1995) (16)
- Syntheses of alkali selenolates from diorganic diselenides and alkali metal hydrides : scope and limitations (1992) (16)
- New deoxygenation reactions of sulfoxides, selenoxides and primary nitroalkanes to sulfides, selenides and nitriles (1979) (15)
- 1H and 13C studies of alkenes, epoxides and cyclic thionocarbonates (1977) (15)
- Novel one step synthesis of epoxides from β-hydroxy-selenides and sulfides (1984) (15)
- Synthesis of 2,2-dimethyl-4-cyclopentene-1,3-dione and 5,5-dimethyl-4-hydroxy-2-cyclopenten-1-one (1996) (15)
- Assignment of Configuration of Olefins, Diols, and Epoxides. Quantitative Analysis of Their Stereoisomeric Mixtures (1977) (15)
- Novel synthesis of vinyl cyclopropane carboxylic acids: Application to the synthesis of (d,l)- and (d)-cis-chrysanthemic acid (1996) (15)
- Mesoporous titanium dioxide (TiO2) with hierarchically 3D dendrimeric architectures: formation mechanism and highly enhanced photocatalytic activity. (2013) (15)
- New Synthesis of ketene thioacetals, vinylsulfides and their seleno analogues (1982) (15)
- Synthesis of primary-alkyl selenols and selenides from primary-alkyl thiols involving diphenyl sulfonium salts. (2005) (14)
- Regiospecific synthesis of alkylidene cyclopropanes (1980) (14)
- Syntheses of rac- and optically active 2-alkyl-γ-butyrolactones and 2 -alkyl-cyclobutanones (1998) (14)
- Hydrothermal and surfactant treatment to enhance the photocatalytic activity of hierarchically meso–macroporous titanias (2013) (14)
- Streoselective syntheses of cyclopropane derivatives from γ-alkoxy-α,β-unsaturated carbonyl compounds and isopropylidene transfer reagents (1993) (14)
- Conditions-Driven Selective Synthesis of Selenides and Selenols from Elemental Selenium (2004) (14)
- Novel synthesis of tertiary alkyl, secondary and tertiary benzyl, and allyl selenides from the corresponding alcohols (1984) (14)
- Isomerisation of 2,2-dimethyl dimedone to ( d, l) cis-chrysanthemic acid † Dedicated with great appreciation to Prof. Pierre Sinay on the occasion of his 62nd birthday. † (2000) (14)
- New method for the ring enlargement of cyclic ketones (1982) (14)
- Stereochemical control in the hydrolysis of an ynamine-cyclopentenone adduct : a stereoselective route to diastereoisomeric 2-(1-cyclopentyl 3-oxo) propionic acids. (1970) (13)
- A novel method for the geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones (1986) (13)
- Controlled regiospecific addition of 1-lithio 1-seleno acetates to α,β-unsaturated ketones (1978) (13)
- 2-Metallo-2-nitropropanes as isopropylidene transfer reagents for the cyclopropanation of electrophilic alkenes. Application to the synthesis of trans-chrysanthemic acid (1985) (13)
- Simple synthetic route to chrysanthemic acid and hemicaronic aldehyde (1979) (13)
- A total stereospecific synthesis of d,1 cis and d,1 trans chrysanthemic esters☆ (1976) (13)
- Olefin synthesis from selenides and selenoxides t.butylhydroperoxide-alumina, a powerful reagent for selenide oxidation-elimination (1978) (13)
- New Regiospecific and stereoselective route to β-hydroxy selenides A (C,C) connective and stereospecific route to olefins and epoxides (1976) (13)
- First synthesis of 3-O-methyl-scyllo-inosamine, a natural product which favors the Rhizobium–Leguminosae symbiosis (2004) (13)
- Condition-driven selective syntheses of dialkyl diselenides involving elemental selenium and sodium borohydride (2005) (13)
- 3-Methylseleno-2-[methylselenomethyl]-propene valuable precursor of trimethylenemethane and trimethylenemethane dianion (1997) (13)
- Fragmentation of 4 -sulfonylbicyclo [3.1.0]hexan -2 -ones as the key step in the enantioselective synthesis of (1R ) -cis -chrysanthemic acid involving desymmetrization of 3,3,6,6-tetramethylbicyclo [3.1.0] hexane-2,4-dione (2007) (12)
- Asymmetric Synthesis of Cyclopropane-1,1-Dicarboxylates from a γ-Alkoxy-Alkylidenemalonate (1999) (12)
- Efficient Syntheses of (d, l) and (d) Selenomethionine (1989) (12)
- Inspired by flowers: synthetic routes to scalemic deltamethrinic acid. (2009) (12)
- Connective (C–C) route to hindered epoxides and olefins from hindered ketones (1982) (12)
- 2-lithio-2-phenylsulfonyl propane as efficient precursor of gem-dimethyl cyclopropane carboxylic acids (1985) (12)
- Synthesis of pyrethroic acids from natural products and from isomeric compounds: Strategy and practice (1994) (12)
- ω-Alkenyl-α-Methoxy-Benzyllithiums : Original Synthesis and Reactivity (1997) (12)
- New regiospecific route to β-γ unsaturated alcohols and β-γ unsaturated ketones new methodology for α-β unsaturated ketones synthesis (1978) (12)
- γ-Silyloxy-Benzyllithiums : Stereochemistry of the Retro-[1,4]-Brook Rearrangement (1997) (12)
- Synthesis of organolithium compounds from phenyl selenides (1995) (12)
- Science in the Post-Truth Era (2017) (11)
- Synthesis of 1-phenylseleno-1-vinyl and 1-methylseleno-1-vinyl cyclopropanes by formal dehydration of β-hydroxycyclopropyl selenides (1981) (11)
- Oxidation of allylselenides with the Sharpless AD-reagents (1997) (11)
- The Need for Cultural Competence in Science: A Practical Approach to Enhancing Equality, Diversity, and Inclusion. (2019) (11)
- Regio and stereospecific synthesis of α,β-unsaturated esters lactones and acids (1978) (11)
- Tuning the structure of a hierarchically porous ZrO2 for dye molecule depollution (2012) (11)
- Olefins syntheses from β-hydroxysulfides (1980) (11)
- Regioselective Synthetic Routes to 1,4-Dicarbonyl Compounds and Some α-Hydroxy Carbonyl Compounds from 1,1-bis(Thio)-and bis(Seleno)-allkyllithiums (1983) (11)
- α‐Halogenoalkyl Selenides and α‐(Phenylseleno)alkanide Anions (1977) (11)
- Straightforward synthesis of isopropylidenediphenylsulfurane and application to industrially viable stereoselective synthesis of deltamethrin insecticide (1990) (11)
- Regioselective syntheses of polyalkyleted cyclopentanones (1982) (11)
- C/se bond cleavage of functionalized selenides by lithium arenides : Application to the geminal di-allylation of the carbonyl group of aldehydes and ketones. (1995) (11)
- Synthetic routes to cyclopropylidenecarbinols and to cyclopropylidienes (1981) (11)
- Conversion of des-6-methyl-2,3-oxidosqualene to 19-norlanosterol by 2,3-oxidosqualene-sterol cyclase. (1971) (11)
- Novel synthesis of methyl caronate (1986) (11)
- Zinc-Mediated Synthesis of Tertiary Alkyl Selenides from Tertiary Alkyl Halides (2005) (11)
- Elucidation of the absolute configuration of rhizopine by chiral supercritical fluid chromatography and vibrational circular dichroism. (2015) (11)
- From grape to grape: novel stereoselective syntheses of chiral pyrethroids - synthesis of the most potent commercially available insecticides (1990) (10)
- SYNTHESIS AND DIELS‐ALDER REACTIONS OF ALLYLIDENECYCLOPROPANE (1983) (10)
- Synthesis of alkali metal carboxylates and carboxylic acids using "wet" and "anhydrous" alkali metal hydroxides. (2010) (10)
- Reduction of thiiranes to alkenes and alkanes (1983) (10)
- EnCOrE (Encyclope'die de Chimie Organique Electronique): an Original Way to Represent and Transfer Knowledge from Freshmen to Researchers in Organic Chemistry (2003) (10)
- New reactions of 1-seleno-1-vinyl cyclopropanes (1981) (10)
- The Periodic Table of the Chemical Elements and Sustainable Development (2019) (10)
- Singlet oxygen oxidation of selenides to selenoxides (2002) (10)
- Asymmetric dihydroxylation of C,C double bonds using catalytic amounts of osmium tetroxide, selenides, and air (2002) (10)
- Novel synthesis of arylcyclopropane derivatives from α-selenobenzyllithiums and epoxides (1992) (10)
- Regio and stereoselective synthesis of 1-methylseleno-1-vinyl and 1-phenylseleno-1-vinyl cyclopropanes (1981) (10)
- Synthesis and cyclisation of ω-alkenyl allyllithiums (1992) (10)
- Arylation of n-Hexylthiol and n-Hexyl Phenyl Sulfide Using Diphenyliodonium Triflate: Synthetic and Mechanistic Aspects - Application to the Transformation of n-Hexylthiol to n-Hexylselenide (2006) (10)
- Blocking the hype-hypocrisy-falsification-fakery pathway is needed to safeguard science. (2020) (10)
- Original synthesis and reactivity of 1,3-benzodiselenolanes (1999) (10)
- Synthetic route to vinyl selenides and vinyl selenoxides (1978) (10)
- Stereochemistry of the intramolecular carbolithiation of vinyl sulfides (1997) (10)
- Original Synthesis of 1,2-Oxathiolan-2-oxides and Vinyl Cyclopropane Carboxylic Esters (1997) (10)
- Enantioselective synthesis of 1(R)-trans-chrysanthemic acid (2002) (9)
- Novel synthetic route to aryl alkanes from aromatic aldehydes and ketones. Novel geminal dialkylation of the carbonyl group of aromatic aldehydes and ketones (1986) (9)
- Catalytic Asymmetric Dihydroxylation of C,C Double Bonds with Osmium Tetroxide Using Selenoxides as Co-oxidants (2001) (9)
- α-Methoxy-Benzylmetals : Original Synthesis and Reactivity (1997) (9)
- Comparative study for the introduction of a masked nucleophilic acyl moiety at the C(3) site of α,β-unsaturated aldehydes and esters (1980) (9)
- New synthesis of tetrahydropyrans from tetrahydrofurans (1992) (9)
- Synthetic connective route to allyl alcohols from carbonyl compounds (1978) (9)
- New reagent for conversion of olefins to β-hydroxyselenides (1979) (9)
- Synthesis of 1-Aryl-2-Vinyl Cyclopropanes by Intramolecular Carbolithiation (1997) (9)
- Diphosphorus tetraiodide. A valuable reagent in cyclopropane chemistry (1983) (9)
- A conceptual basis to encode and detect organic functional groups in XML. (2013) (9)
- Influence of magnesium bromide on the regioselectivity of the cycloaddition of ynamines with cyclenones: difference in reactivity between cyclohexenones and cyclopentenones. (1981) (9)
- Novel Stereoselective Synthesis of Arylcyclopropanes (1990) (9)
- Synthetic Studies Towards Milbemycin Beta(3) - Rapid Construction of a Model Spiroketal Subunit Using the Intramolecular Silyl Modified Sakurai (isms) Methodology (1995) (9)
- Stereochemical outcome of reactions involving 1,1-bis(seleno) 4-tert-butyl cyclohexanes (1991) (8)
- ”Three Components” Synthesis of Vinyl Cyclopropane Carboxylic Acids (1995) (8)
- New Synthesis of (d,l)cis-2-Desmethyl and 2,2-Di-desmethyl Chrysanthemic Acids (1991) (8)
- New stereoselective routes from alcohols to secondary alkyl bromides with retention of configuration (1980) (8)
- Interactive Construction of EnCOrE (Learning by Building and Using an Encyclopedia) (2004) (8)
- Alkylhalides synthesis from selenoxides a new homologization process (1976) (8)
- Reduction vs. acetalisation of some carbonyl compounds by means of methylselenol and Lewis acids (1980) (8)
- Ring expansion of cyclenones: an unusual regioselectivity (1986) (8)
- Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation (1996) (8)
- Realigning science, society and policy in uncertain times (2020) (8)
- Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI2, the Kagan Reagent (1999) (7)
- On the structure of a-metallo benzylselenides (1986) (7)
- Comparison of the behavior of oxidosqualene cyclases from pig liver and yeast toward epoxy-squalene analogues possessing a Δ 18–19 Z or E C, C Double bond. (1991) (7)
- Unusual regiochemical control of the reactivity of some organometallics with chalcone (1983) (7)
- Organoselenium Chemistry I: Functional Group Transformations (1988) (7)
- Synthesis of 1-Aryl-2-vinylcycloalkanes by Intramolecular Carbolithiation (2000) (7)
- Unusual but not unexpected reactions of α-halogenoselenides (1978) (7)
- Synthesis of vinyl sulphides, azido sulphides, and olefins from β-hydroxy-sulphides (1980) (6)
- Evidence of an equilibrium between selenides and osmium(VIII) reagents and selenoxides and osmium(VI) reagents. (2002) (6)
- Novel results on the biocyclisation of 2,3-oxidosqualene analogs by sterol cyclase (1993) (6)
- 2.6 – Selenium Stabilization (1991) (6)
- Novel synthesis of (d,l) trans-chrysanthemic acid involving a β-diketone fragmentation (2002) (6)
- Preparation and Synthetic Utility of 2-Methylselenomethyl Allyl Methyl Selenide. A Valuable Precursor to 2-Silylmethylallyllithiums (1998) (6)
- Synthesis of Hexylselenol and Hexylselenides from Hexylthiol Involving Hexylthiolanium Salts (2006) (6)
- Diastereoselective Epoxidation of Compound Bearing a Cyclohex-3-enol Moiety: Application to the Enantioselective Synthesis of (1R)-trans-Chrysanthemic Acid and (1R)-cis-Deltametrinic Acid (2008) (6)
- On the mechanism of the chrysanthemic ester synthesis (1979) (6)
- The SCIentific publishing conundrum: A perspective from chemistry (2017) (6)
- Synthesis of selenolates from stannyl and silyl alkylselenides (1993) (5)
- Re-imagining Priorities for Chemistry: A Central Science for "Freedom from Fear and Want". (2021) (5)
- Reactions involving inorganic compounds (2000) (5)
- Pyrocine synthesis - a new approach to chrysanthemic ester (1978) (5)
- A Highly Potent Reagent for Regioselective and Stereo‐specific Synthesis of Polyenes Bearing Terminal Aziridine Groups (1974) (5)
- Beryllium Dichloride: Efficient promoter for the Addition of Organolithiums and Organomagnesiums to Cyclohexen-2-one (1997) (5)
- Selected regiocontrolled transformations applied to the synthesis of (1S)-cis-chrysanthemic acid from (1S)-3,4-epoxy-2,2,5,5-tetramethylcyclohexanol. (2008) (5)
- The Chemical Sciences and Health: Strengthening Synergies at a Vital Interface (2017) (5)
- Mechanism of the reaction of some organometallic compounds with α-enones (1982) (5)
- About the mechanism of the rearrangement of β-hydroxyalkylselenides to ketones (1989) (5)
- Selective synthesis of mixed (O,Se) acetals and of (Se,Se) acetals from (O,O) acetals (1993) (5)
- cis-4,6-Dimethyl-2-phenyl-1,3-diselenane (1998) (5)
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- cis-4,6-Dimethyl-2-phenyl-1,3-diselenane. (2010) (0)
- Synthesis of 2‐Lithio‐1,3‐diselenanes and 2‐Lithio‐1,3‐dithianes by Se/ Li Exchange: First Successful Trapping of Axially Oriented 2‐Lithio‐1, 3‐diselenanes. (1997) (0)
- Powerful Alternative Asymmetric Catalytic Dihydroxylation of Olefins (1998) (0)
- Comparison Between Alkylseleno, Arylseleno and Arylthio Substituents Stabilizing Alkyllithium Compounds. (1989) (0)
- SPECIFIC OXIDATION OF β-HYDROXYSELENIDES TO α,β-UNSATURATED KETONES AND α-SELENO CARBONYL DERIVATIVES (1979) (0)
- Formalizing the mechanism of the allylic substitution reaction (SN’): application to the highly enantio- and diastereo-selective syntheses of 1-phenyl-2-vinyl-cyclopentanes (2018) (0)
- REACTIVITY OF MIXED SULFO-SELENO ACETALS AND OXO-SELENO ACETALS WITH N-BUTYLLITHIUM, A NEW ROUTE TO SUBSTITUTED EPOXIDES PART 1 (1975) (0)
- Adventures in Chemistry and in Information Technology: Using Chemistry Skill to Finance Partnership with Computers. (2016) (0)
- CONNECTIVE (C-C) ROUTE TO HINDERED EPOXIDES AND OLEFINS FROM HINDERED KETONES (1982) (0)
- New Synthesis of Tetrahydropyrans from Tetrahydrofurans. (1992) (0)
- Formalizing the mechanism of the allylic substitution reaction (SN’): application to the highly enantio- and diastereo-selective syntheses of 1-phenyl-2-vinyl-cyclopentanes (2018) (0)
- Novel Stereoselective Synthesis of Arylcyclopropanes. (1991) (0)
- Pyrethroid insecticides Chapter IVa. Reactivity of chrysanthemic acid and its lower esters (2021) (0)
- INFLUENCE OF MAGNESIUM BROMIDE ON THE REGIOSELECTIVITY OF THE CYCLOADDITION OF YNAMINES WITH CYCLOENONES: DIFFERENCE IN REACTIVITY BETWEEN CYCLOHEXENONES AND CYCLOPENTENONES (1981) (0)
- SYNTHETIC ROUTES TO ALPHA-SELENOACETALS, ALPHA-SELENONIO SULFIDES, ALPHA-SELENONIO ETHERS, ALPHA-SELENONIO AMINE AND ALPHA-SELENONIO SILANE (1975) (0)
- Ring Expansion of Cyclenones: An Unusual Regioselectivity. (1986) (0)
- Chemistry in a post-Covid-19 world (2020) (0)
- DETERMINATION OF THE CONFIGURATION OF OLEFINS, DIOLS, AND EPOXIDES, QUANTITATIVE ANALYSIS OF MIXTURES OF THEIR STEREOISOMERS (1977) (0)
- PHOSPHORUS TRIIODIDE (PI3), A POWERFUL DEOXYGENATING AGENT (1980) (0)
- On the Mechanism of the Synthesis of Arylcyclopropanes from γ- Benzenesulfonyloxyalkyl Seleno and Tin Derivatives and n-Butyllithium. (1993) (0)
- NEW REACTIONS OF 1-SELENO-1-VINYLCYCLOPROPANES (1982) (0)
- N‐Bromosuccinimide–Sodium Azide (2001) (0)
- DIPHOSPHORUS TETRAIODIDE (P2I4). A VALUABLE REAGENT FOR REGIOSELECTIVE SYNTHESIS OF IODO ALKANES FROM ALCOHOLS (1979) (0)
- REGIOSELECTIVE SYNTHESES OF POLYALKYLATED CYCLOPENTANONES (1983) (0)
- Pyrethroid insecticides. Chapter II: Synthesis of rethrolones (2021) (0)
- SYNTHESIS OF OLEFINS FROM α-SILYL CARBANIONS AND CARBONYL COMPOUNDS (1976) (0)
- Synthesis of Organolithium Compounds Using Lithium 4,4′-Di- tertbutylbiphenylide (1995) (0)
- Original Syntheses of Molecules Containing Adjacent Quaternary Carbons (1991) (0)
- CYCLOPROPANONE DISELENOKETALS, INTERESTING BUILDING BLOCKS IN ORGANIC SYNTHESIS (1979) (0)
- Synthetic Studies Towards Milbemycin β3. Rapid Construction of a Model Spiroketal Subunit Using the Intramolecular Silyl Modified Sakurai (ISMS) Methodology (1995) (0)
- Selective Synthesis of Mixed (O,Se) Acetals and of (Se,Se) Acetals from (O,O) Acetals. (1994) (0)
- Reaction of 1,3-Diselenanes with Metal Amides. (1996) (0)
- Reactions of Dibenzyl Diselenides with Alkali Metal Hydrides. (1993) (0)
- SYNTHESES OF SQUALENE EPOXIDE AND LANOSTEROL ANALOGS FOR A BIOSYNTHETIC EXPERIMENT (1979) (0)
- 2‐Lithio‐2‐phenylsulfonyl Propane as Efficient Precursor of gem‐Dimethyl Cyclopropane Carboxylic Acids. (1986) (0)
- REGIO‐ AND STEREOCHEMICALLY CONTROLLED RING OPENING OF EPOXIDES WITH GRIGNARD REAGENTS. STEREOCONTROLLED SYNTHESIS OF THE STEROID SIDE CHAINS. FIRST STEREOSELECTIVE HEMISYNTHESIS OF 20S‐ISOLANOSTEROL (1983) (0)
- REGIOSPECIFIC SYNTHESIS OF α,β-UNSATURATED EPOXIDES (1976) (0)
- Stereocontrolled Synthesis of [3.1.0]Bicyclohexanones by Cyclopropanation of Enones with Benzylidene Sulfuranes. (2002) (0)
- Pyrethroid insecticides Chapter IVb. Selected transformations of chrysanthemic acid and its lower esters to Pyrethroid.Use of the Wittig and related reactions (2022) (0)
- α-HALOALKYL SELENIDES AND α-(PHENYLSELENO)ALKANIDE ANIONS (1977) (0)
- Synthesis of Organolithium Compounds from Phenyl Selenides. (1996) (0)
- Science of Synthesis, Volume 30: Acetals: O/N, S/S, S/N and N/N and Higher Heteroatom Analogues (2008) (0)
- New Routes to gem Dialkylcyclopropanecarboxylic Acids. Application to the Synthesis of Chrysanthemic Acids (1987) (0)
- PHOTOOXYGENATION OF SELENIDES-A NEW ROUTE TO SELENIUM OXIDES (1976) (0)
- STEREOSPECIFIC SYNTHESIS OF Z AND E C16OMEGA-JODO DELTA(9) FATTY ACIDS FROM NATURAL ALEURITIC ACID (1975) (0)
- About the Mechanism of the Rearrangement of β-Hydroxyalkyl Selenides to Ketones. (1989) (0)
- A New Route to Compounds Bearing Two Contiguous Quaternary Centres. (1991) (0)
- Application of Homonuclear Chemical Shift Correlation NMR to the Study of the Cyclization Products of Unnatural δ18-19-(Z)-Epoxysqualene (1988) (0)
- Climate change: reasons, requirements, and realities (2022) (0)
- NEW DEOXYGENATION REACTIONS OF SULFOXIDES, SELENOXIDES AND PRIMARY NITRO ALKANES TO SULFIDES, SELENIDES AND NITRILES (1980) (0)
- ω-Alkenyl-α-methoxy-benzyllithiums: Original Synthesis and Reactivity. (1997) (0)
- Stereochemical Outcome of Benzyllithiums Synthesis from Selenides. (1992) (0)
- “Three Components” Synthesis of Vinyl Cyclopropane Carboxylic Acids. (1995) (0)
- STEREOSPECIFIC ENZYMIC CYCLIZATION OF A SYNTHETIC 2,3-OXIDOSQUALENE ANALOG BEARING AN 18Z CARBON-CARBON DOUBLE BOND (1979) (0)
- α‐Methoxy‐benzylmetals: Original Synthesis and Reactivity. (1997) (0)
- Synthesis of 1-Aryl-2-vinyl Cyclopropanes by Intramolecular Carbolithiation. (1998) (0)
- 3,6-Dimethyl-o-phenylenedimethanol (2009) (0)
- REDUCTION VS. ACETALIZATION OF SOME CARBONYL COMPOUNDS BY MEANS OF METHYLSELENOL AND LEWIS ACIDS (1980) (0)
- Stereochemical Outcome of the Reaction of Some α‐Selenoalkyllithiums with 4‐t‐Butyl Cyclohexanone (2010) (0)
- NOVEL SYNTHESIS OF BENZYLLITHIUMS FROM BENZYL SELENIDES (1985) (0)
- ALLYL SELENIDES POSSESSING A TERMINAL DOUBLE BOND. FIRST REGIOSELECTIVE SYNTHESIS AND REACTIONS (1983) (0)
- NEW REGIOSPECIFIC AND STEREOSELECTIVE ROUTE TO β‐HYDROXY SELENIDES. A (C‐C) CONNECTIVE AND STEREOSPECIFIC ROUTE TO OLEFINS AND EPOXIDES (1976) (0)
- Reactions Involving Metallic or Amorphous Selenium with Organic Molecules (1988) (0)
- Synthesis of Alkali Metal Carboxylates and Carboxylic Acids Using “Wet” and “Anhydrous” Alkali Metal Hydroxides (2010) (0)
- Reactions of Imidoselenium Compounds (1988) (0)
- Asymmetric Synthesis of Cyclopropane‐1,1‐dicarboxylates from a γ‐Alkoxy‐alkylidenemalonate. (2000) (0)
- Efficient Syntheses of (d,l)- and (d)-Selenomethionine. (1990) (0)
- 1-4 ADDITION OF CARBANIONS TO .alpha±beta. UNSATURATED CARBONYL COMPOUNDS IN THE PRESENCE OF HMPA: FIRST EVIDENCE OF KINETIC CONTROL (1979) (0)
- Novel Variations of the Asymmetric Catalytic Dihydroxylation of olefins (2000) (0)
- New Insight in the Synthesis and Reactivity of Selenenic Acids (2010) (0)
- CLEAVAGE (DEPROTECTION) OF SELENOACETALS TO CARBONYL COMPOUNDS; A COMPARATIVE STUDY (1980) (0)
- Reactions Involving Benzeneseleninic Anhydride (BSA) and Related Reagents (1988) (0)
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