Alexander Shilov
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Russian chemist, professor and academician of the Russian Academy of Sciences
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Chemistry
Alexander Shilov 's Degrees
- PhD Chemistry Moscow State University
Why Is Alexander Shilov Influential?
(Suggest an Edit or Addition)According to Wikipedia, Alexander E. Shilov was a Russian chemist, one of the leading figures in Physical Organic Chemistry and Catalysis. Shilov was born in Ivanovo, Russia, studied chemistry in Kiev and received his diploma degree in 1952 from Kiev State University. In 1952-1955 he began working with Nobel Laureate Nikolay Semyonov toward his Ph.D. at the Academy of Sciences in Moscow. After postdoctoral studies with Sir Cyril Norman Hinshelwood at Oxford University in London, he returned to the Institute of Biochemical Physics , where he became Director and Professor at Moscow State University. In 1952 he moved to Institute of Problems of Chemical Physics, Russian Academy of Sciences in Chernogolovka , where he became the Head of Laboratory. In 1990 he was elected to the Academy of Scienсes of the USSR, which was in someway equivalent to getting a financial endowment for his research.
Alexander Shilov 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Nitrogen fixation in solution (1995) (233)
- Activation and Catalytic Reactions of Alkanes in Solutions of Metal Complexes (1987) (85)
- New Nitrogenase Model for Reduction of Molecular Nitrogen in Protonic Media (1971) (83)
- Oxygen Atom Transfer into C−H Bond in Biological and Model Chemical Systems. Mechanistic Aspects (1999) (61)
- Inorganic models of photosystem II of plant photosynthesis. Catalytic and photocatalytic oxidation of water with participation of manganese compounds (1981) (57)
- Biomimetic alkane oxidation in the presence of iron complexes (1989) (47)
- Catalytic reduction of dinitrogen in protic media: chemical models of nitrogenase (1987) (44)
- Fixation of Nitrogen in Solution in the Presence of Transition Metal Complexes (1974) (42)
- Activation of the C–H bond by metal complexes (1990) (38)
- Activation of alkanes by transition metal complexes (1978) (33)
- Polynuclear molybdenum(VI)–molybdenum(V) complex: a precursor of the catalyst for dinitrogen reduction (1989) (28)
- Gold helps bacteria to oxidize methane. (2002) (27)
- Formation of anionic σ-aryl complexes of platinum (IV) in the reaction of H2PtCl6 with aromatic compounds. The crystal and molecular structures of platinum (IV) complexes of naphthalene and ortho-nitrotoluene (1981) (26)
- Five-coordinate carbon hydroxylation mechanism (1996) (26)
- Complexes of Molecular Nitrogen (1969) (25)
- Catalytic and photocatalytic oxygen evolution from water in the presence of manganese complexes (1989) (24)
- A chemical model of cytochrome P-450: mono-oxygenase-like activation of dioxygen (1987) (23)
- Structure of the intermediate iron(0) complex isolated from the dinitrogen fixing system LiPh + FeCl3 (1983) (23)
- Kinetics of oxidation of water by Mn(IV) sulfate in acid media (1976) (21)
- Reduction of nitrogen to hydrazine in a binuclear complex of iron (1971) (21)
- Isolation of a binuclear complex intermediate in the reaction of molecular nitrogen with titanium compounds (1971) (20)
- HETEROMETALLIC BI- AND POLYMOLYBDENUM COMPLEXES : PRECURSORS OF THE CATALYSTS FOR DINITROGEN REDUCTION (1993) (20)
- The role of free ions in reactions of olefins with soluble complex catalysts (2007) (20)
- Regioselectivity changes in hexane hydroxylation by iodozobenzene catalyzed by tetraarylporphyrinatoiron complexes (1985) (16)
- A comparison of the reduction of dinitrogen by a vanadium(ii)—catechol system with that by the active centre of nitrogenase (1976) (16)
- Chemical models of metallo-enzymes (1988) (16)
- Alkane oxidation by an iron complex-hydrogen peroxide system in acetonitrile. The model of methanemonooxygenase (1990) (15)
- A Synthetic Au–Rutin Complex as a Functional Model of the Active Site of the Au-Protein from Micrococcus luteus (2004) (15)
- Mono- and binuclear σ-aryl iron-lithium hydrides; synthesis and molecular structure (1992) (14)
- Intermediate complexes in chemical and biological nitrogen fixation (1992) (14)
- Isolation of a new intermediate complex in the nitrogen-fixing system (π-C5H5)2TiCl + MeMgI + N2 (1972) (13)
- A manganese cluster bound to a bilayer membrane: a chemical model for the oxygen-forming centre of photosynthesis (1987) (13)
- Structure of {[(.eta.5-C5H5)2Zr(.mu.-P(C6H5))]2}{[(THF)3Li]2(.mu.-Cl)} and Its Implications for the Nature of Dilithium Dinitrogen Complex (1995) (12)
- Catalytic reduction of acetylene in the presence of molybdenum and iron clusters, including FeMo cofactor of nitrogenase (1998) (12)
- Methane Oxidation Catalyzed by the Au-Protein from Micrococcus luteus (2001) (12)
- [Model of the active center of cytochrome P-450. Alkane oxidation catalyzed by iron(III) porphyrin in microheterogeneous media]. (1984) (12)
- Hydrazine-producing intermediate in the nitrogen fixing system: cp2TiCl2+ PriMgCl + N2 (1973) (12)
- The electrochemical properties of nitrogen-fixating Mo(III) and the reduction of Mo(V) in alkaline methanolic media influenced by Mg2+ ions (1986) (12)
- Formation of ozone during the reduction of potassium permanganate in sulfuric acid solutions (2005) (11)
- Molybdenum complexes as catalysts for the reduction of molecular nitrogen in protic media (1975) (10)
- Catalytic reduction of acetylene and dinitrogen with the participation of the iron-molybdenum cofactor of nitrogenase and synthetic polynuclear molybdenum(iii) complexes (1998) (9)
- PHENAZINE DI-N-OXIDE RADICAL CATION REACTIONS WITH BASES, EVIDENCE FOR OXYGEN CATION TRANSFER (1993) (9)
- Electrochemical model of alkane oxidation by cytochrome P-450 (1987) (9)
- Parallel formation of hydrazine and ammonia in dinitrogen reduction in the system Na(Hg)−Ti(OH)3−Mo(III) (1977) (9)
- Role of acids in reduction of acetylene catalyzed by molybdenum-thiol complexes (1974) (8)
- Mechanism of electron transfer in dinitrogen fixation in the system Ti(III)−Mo(III) (1975) (8)
- Kinetics and mechanism of methane oxidation in aqueous solutions of platinum complexes. Direct evidence for a methylplatinum intermediate (1983) (7)
- Catalytic oxidation of water with the participation of manganese compounds in neutral and slightly acid media (1979) (7)
- DINITROGEN FIXATION IN SOLUTION IN THE PRESENCE OF IRON COMPLEXES. INTERMEDIATES AND MECHANISM (1992) (7)
- Crystal and molecular structures of hexameric lithium dimethylnaphthylsilanolate, [LiOSiNpMe2]6 (1987) (6)
- Mathematical modelling of kinetics of adenosine 5'-triphosphate hydrolysis catalyzed by Zn2+ ion in the pH range 7.1-7.4. (2000) (6)
- Isolation and investigation of the complex Li3[FeNp3N2]·nEt2O - the product of interaction of molecular nitrogen with a naphthyl derivative of zero-valent iron (1985) (6)
- Why was manganese chosen by nature to catalyze oxygen evolution in photosynthesis (1989) (6)
- Metal complexes in biomimetic chemical reactions: N b2 s fixation in solution, activation, and oxidation of alkanes, chemical models of photosynthesis (1996) (6)
- Molecular structure and reactions of azobenzene complexes with iron-lithium compounds (1998) (6)
- Formation of methyl platinum complex in the reaction of methane with chloroplatinic acid (1980) (5)
- A KINETIC STUDY OF A VANADIUM(II) : MAGNESIUM HYDROXIDE SYSTEM (1994) (5)
- Concerted reactions of polynuclear metalloenzymes and their functional chemical models (2011) (5)
- FORMATION OF RADICALS IN REACTIONS BETWEEN VALENCY-SATURATED MOLECULES (1966) (5)
- Kinetics of dinitrogen reduction in the presence of a vanadium(II)-catechol complex (1976) (4)
- Kinetic evidence of nitrogen reduction in the coordination sphere of a polynuclear complex (1999) (4)
- Electrochemical and ESR studies of au-protein from Micrococcus luteus (2000) (4)
- Photocleavage of Water in Organized Molecular Systems (1988) (4)
- Possible chain mechanism of oxygen atom transfer (1990) (4)
- KINETICS AND MECHANISM OF HYDROLYSIS OF ADENOSINE 5'-TRIPHOSPHATE CATALYZED BY ZN2+ION. CONFORMATION AND SELECTIVITY - PART 2 (1996) (4)
- The role of cocatalysts in the catalytic nitrogen reduction by sodium amalgam (1995) (4)
- Catalytic hydrolysis of ATP. pH-Dependence of the selectivity (1995) (3)
- Activation of Cminus signH Bonds by Metal Complexes. (1997) (3)
- Oxidation of 1,4-dimethylcyclohexane by perchloric acid catalyzed by polyphenylferrosiloxane (1998) (3)
- Multielectron Oxidation of Water in a Chemical Model of the Active Center of Photosystem II of Natural Photosynthesis (2004) (3)
- ON THE PAPER “PYROLYSIS OF ALLYL CHLORIDE” BY L. J. HUGHES AND W. F. YATES (1961) (3)
- Mathematical modeling of kinetics of adenosine-5’-triphosphate hydrolysis catalyzed by the Zn2+ ion in the pH range 8.5–9.0 (2000) (3)
- State primary standard for the units of magnetic induction, magnetic flux, magnetic moment, and magnetic induction gradient (2012) (3)
- Phospholipid-dependent catalytic dinitrogen reduction in the presence of molybdenum complexes (1983) (3)
- Six-Electron Oxidation of Water into Ozone in Natural Photosynthesis (2005) (3)
- Kinetics and mechanism of adenosine 5′-triphosphate hydrolysis catalyzed by the Cu2+ ion: The role of conformation and the catalytic effect of the OH− ion (2006) (3)
- Biomimetic catalysis: Transition metal complexes as chemical models of important enzymes (1999) (2)
- IRON-MOLYBDENUM COFACTOR OF NITROGENASE AS A CATALYST OF ACETYLENE REDUCTION WITH ZINC AMALGAM (1997) (2)
- Reaction of an iron-lithium complex with tolane and the structure of dilithiumtetraphenylbutadiene formed (1995) (2)
- 16 – Catalytic Nitrogen Fixation in Solution (1983) (2)
- REDUCTION OF MOLECULAR NITROGEN BY TI(II) IN A PROTONIC MEDIUM (1993) (2)
- Organized molecular systems in catalysis (1990) (2)
- Novel mechanism of aliphatic hydroxylation in enzymatic and biomimetic systems: problems of the reaction dynamics. (1999) (2)
- Activation of C—H Bonds by Metal Complexes (1998) (2)
- State primary standard of the units of magnetic induction and magnetic flux and their ratios (1991) (2)
- Infrared spectra of complexes of molecular nitrogen with iron(II) compounds (1971) (2)
- Complex of bis(Dithioacetylacetonato)iron(II) with carbon monoxide, nitric oxide, and molecular oxygen (1970) (2)
- N. N. Semnov and the chemistry of 20th century (to 100th anniversary of his birth) (1997) (1)
- A new intermediate complex of molecular nitrogen in the system Cp2TiCl−CH3MgI−N2 (1974) (1)
- Catalytic reduction of nitrogen with sodium amalgam in a phospholipid film at low temperatures (1988) (1)
- Catalytic hydroxylation of alkanes via an intermediate with pentacoordinated carbon: Problems of the reaction dynamics (1997) (1)
- Acetylene reduction by hydroxides of transition metals (1976) (1)
- Reduction of molecular nitrogen in a protic medium with participation of Fe-S and Mo-Fe-S clusters (1993) (1)
- MECHANISM OF OXYGEN TRANSFER IN HYDROXYLATION OF ALKANES BY HIGH VALENCE METAL COMPLEXES IN CHEMICAL AND BIOLOGICAL SYSTEMS (1995) (1)
- SYNTHESIS AND STRUCTURE OF Δ-NAPHTHYL DERIVATIVE OF PLATINUM(IV) FORMED IN THE REACTION OF NAPHTHALENE WITH HEXACHLOROPLATINIC ACID (1980) (1)
- The possibility of catalytic hydrogenation of nitrogen in solutions (1973) (1)
- Electron paramagnetic resonance of complexes of vanadiun chloride with organoaluminum compounds (1961) (1)
- Substrate selectivity and kinetic isotope effect of cycloalkane oxidation accompanied with activation of molecular oxygen by metalloporphyrins (1993) (1)
- Chemical Nitrogen Fixation in Solution (1995) (1)
- Oxygen Atom Transfer into C—H Bond in Biological and Model Chemical Systems. Mechanistic Aspects (1999) (1)
- Electron Transfer in Catalytic Dinitrogen Reduction (2008) (1)
- Energy distribution in the products of elementary reactions of polyatomic radicals with molecules (1974) (1)
- Electron paramagnetic resonance and structures of Ti(III) complexes formed on reduction of Ti(IV) cyclopentadienyl compounds by aluminum alkyl derivatives (1965) (1)
- Reduction of carbon monoxide by molybdenum-containing hydroxide systems (1998) (1)
- Activation and Catalytic Reactions of Saturated Hydro- carbons in the Presence of Transition Metal Complexes (2001) (1)
- Reduction of molecular nitrogen in methanol with iron compounds (1991) (1)
- Complexes formed by molecular nitrogen with divalent osmium compounds (1968) (1)
- Formation and redox properties of a complex of phenazine di-N-oxide with a proton (1992) (1)
- Dinitrogen Fixation. Fast Amalgam and Electrochemical Catalytic N2 Reduction at Ambient Temperature and Pressure. (1987) (1)
- The kinetics of cyclohexane oxidation by molecular oxygen in the presence of iron porphyrins and a reducing agent (1993) (1)
- Catalysis with Organized Molecular Systems (1993) (1)
- Catalytic Reduction of Acetylene and Dinitrogen with the Participation of the Iron-Molybdenum Cofactor of Nitrogenase and Synthetic Polynuclear Complexes of Molybdenum(III). (2010) (0)
- Expanding the Range of Reproduction of the Magnetic Induction of a Constant Field of Get 12–2011, the State Primary Standard of the Unit of Magnetic Induction, Unit of Magnetic Flux, Unit of Magnetic Moment, and Unit of Magnetic Induction Gradient (2020) (0)
- Reproduction of the ampere from the proton gyromagnetic ratio and quantum magnetoresonance phenomena (1986) (0)
- POSSIBLE MECHANISM OF C-C BOND CLEAVAGE IN THE OXIDATION OF ALKANES MEDIATED BY IRON COMPOUNDS (1999) (0)
- Reduction of molecular nitrogen with tantalum (III) hydroxide (1986) (0)
- Development of the Standards Base in the Field of Measurements of Magnetic Induction and Magnetic Flux (2018) (0)
- Catalytic reduction of acetylene in systems based on iron and sulfides (1982) (0)
- The reduction of acetylene by complexes of the transition metals with pyrocatechol (1975) (0)
- Mechanism of electron transfer in dinitrogen fixation in the system Ti(III)−Mo(III) (1975) (0)
- Manganese catalyst of oxidation of water attached to a bilayer lipid membrane (1987) (0)
- A Standard Quantum Measuring System for Reproduction and Measurement of Low Direct Magnetic Field in the Range 0.1 μT-1.5 mT (2004) (0)
- Electrochemical reduction of nitrogen in the presence of the titanium (III)-molybdenum (III)-guanidine hydrochloride system (1985) (0)
- High value of kinetic isotopic effect during hydroxylation of cyclohexane catalyzed by iron porphyrins (1989) (0)
- Research of long-time stability of an atomic magnetic resonance standard system for reproduction of direct current and magnetic flux density (2002) (0)
- Zonal harmonics calculation to compensatethe magnetic field heterogeneity in a magnet gap. (2019) (0)
- Reduction of molecular nitrogen by hydrogen in solutions (1975) (0)
- A standard quantum measuring system for reproduction and measurement of low direct magnetic field in the range 0.1 /spl mu/T-1.5 mT (2004) (0)
- The mechanism of the reduction of unsaturated compounds by bivalent chromium salts (1967) (0)
- The kinetics and mechanism of the reduction of short-bond compounds in aqueous solutions of salts containing bivalent chromium (1967) (0)
- Electrochemical Properties of Nitrogen-Fixating Mo(III) and the Reduction of Mo(V) in Alkaline Methanolic Media Influenced by Mg2+Ions. (1986) (0)
- Oxidation of Ethylbenzene by Phenazine-Di-N-Oxide Radical Cation (1991) (0)
- Research on expanding the range of reproduction of magnetic flux density of the DC field of the state primary standard GET12-2011 (2020) (0)
- Catalytic Behavior of Isolated FeMo-Cofactor of Nitrogenase in Non-Protein Surroundings (2000) (0)
- Structure of carbonyl complexes of molybdenum formed in the system Ti(OH)3+MoOCl3+CO (1979) (0)
- Catalysis of reductive hydrolysis of molecular deuterium by a rhodium complex: D/sub 2/ + 2e/sup -/ + 2H/sup +/. -->. 2HD (Rh) (1986) (0)
- Catalytic activity of polynuclear manganese complexes for oxygen evolution from water using a one-electron oxidant (1993) (0)
- Mechanism of the formation of ethane in the interaction of acetylene in the presence of molybdenum thiol catalysts. [Reduction with sodium borohydride] (1976) (0)
- The kinetics of the reaction between fluorine and ethylene in a diffusion flame (1968) (0)
- Formation of a ?-crotyl complex of Ti (III) in the reaction between (?-C5H5)2TiCl2 and EtMgBr (1970) (0)
- Reduction of molecular nitrogen by the hydroxide Ta(OH)3-Mo(OH)3 (1992) (0)
- Diniitrogen fixation: Chemistry and models (1989) (0)
- Regioselectivity Changes in Hexane Hydroxylation by Iodozobenzene Catalyzed by Tetraarylporphyrinato-Iron Complexes. (1986) (0)
- Electron paramagnetic resonance in the system R3Al-TiCl4 (1958) (0)
- Coupling of one-electron transfer with multielectron steps in redox catalysis (1999) (0)
- Electronic paramagnetic resonance of the products of the reaction of various Ti(IV) compounds with triethylgallium (1969) (0)
- Polynuclear Iron and Molybdenum Complexes as Catalysts of Reduction of Nitrogenase Substrates (1998) (0)
- IUPAC ACTIVATION OF ALKANES BY TRANSITION METAL COMPLEXES (2006) (0)
- Electrochemical reduction of nitrogen at atmospheric pressure, catalyzed by molybdenum complexes. Electrosynthesis of the catalyst (1986) (0)
- Kinetic simulation of the enzymatic oxidation of methane (2008) (0)
- Effect of base on the oxidation of alkanes by sodium hypochlorite in catalysis by Fe(III) tetramesitylporphyrin : acceleration and change in selectivity of the reaction (1992) (0)
- Hydroxylation of lower alkanes, catalyzed by tetra(o-nitro-phenyl) porphyrin of trivalent iron (1988) (0)
- [Biological fixation of molecular nitrogen and its chemical modelling]. (1971) (0)
- Intermolecular association and general basic catalysis in hydrolysis of adenosine 5'-triphosphate catalyzed by a divalent metal ion. II. Analysis of the products of the reaction of hydrolysis of the Zn/sup 2+/-5/prime/-ATP complex (1988) (0)
- Nitrogenase and Its Chemical Models (1995) (0)
- [Chemical mechanism of coupling during hydrolysis and formation of the high energy bond of ATP]. (1977) (0)
- Photocatalytic formation of hydrogen sensitized by a selected set of dyes (1982) (0)
- Kinetics of the reduction of molecular nitrogen by niobium(III) hydroxide (1987) (0)
- 967. The benzoylation of substituted anilines. An investigation into the effects of polar substituents on the heat of reaction (1960) (0)
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