Alexander M. Spokoyny
Researcher
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Chemistry
Alexander M. Spokoyny's Degrees
- Bachelors Chemistry University of California, Berkeley
Why Is Alexander M. Spokoyny Influential?
(Suggest an Edit or Addition)According to Wikipedia, Alexander M. Spokoyny is an American chemist and associate professor in chemistry and biochemistry at UCLA and a faculty member of the California NanoSystems Institute . Education Spokoyny has started his research career as an undergraduate student at UCLA working in the laboratory of M. Frederick Hawthorne. He received his Ph.D. degree in 2011 from Northwestern University in inorganic and materials chemistry working with Chad Mirkin. Spokoyny then conducted a post-doctoral research stint at MIT in chemical biology until 2014 working jointly with Stephen L. Buchwald and Bradley L. Pentelute on peptide stapling and organometallic bioconjugation chemistry.
Alexander M. Spokoyny's Published Works
Published Works
- Infinite coordination polymer nano- and microparticle structures. (2009) (656)
- Carborane-based metal-organic frameworks as highly selective sorbents for CO(2) over methane. (2008) (315)
- A perfluoroaryl-cysteine S(N)Ar chemistry approach to unprotected peptide stapling. (2013) (293)
- Organometallic Palladium Reagents for Cysteine Bioconjugation (2015) (274)
- Synthesis, Properties, and Gas Separation Studies of a Robust Diimide-Based Microporous Organic Polymer (2009) (248)
- A coordination chemistry dichotomy for icosahedral carborane-based ligands. (2011) (222)
- Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials. (2007) (218)
- Ni(III)/(IV) bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells. (2010) (177)
- Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry (2016) (159)
- Chemical reduction of a diimide based porous polymer for selective uptake of carbon dioxide versus methane. (2010) (143)
- A “click-based” porous organic polymer from tetrahedral building blocks (2011) (138)
- Separation of gas mixtures using Co(II) carborane-based porous coordination polymers. (2010) (124)
- Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands. (2016) (123)
- Increased Electrical Conductivity in a Mesoporous Metal-Organic Framework Featuring Metallacarboranes Guests. (2018) (122)
- Gas-sorption properties of cobalt(II)--carborane-based coordination polymers as a function of morphology. (2009) (113)
- Rapid Flow‐Based Peptide Synthesis (2014) (111)
- Arylation Chemistry for Bioconjugation. (2019) (107)
- New ligand platforms featuring boron-rich clusters as organomimetic substituents (2013) (101)
- Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. (2010) (99)
- Carborane-based pincers: synthesis and structure of SeBSe and SBS Pd(II) complexes. (2009) (98)
- Synthesis and Applications of Perfunctionalized Boron Clusters. (2018) (96)
- Organometallic Gold(III) Reagents for Cysteine Arylation. (2018) (96)
- Luminescent metal complexes featuring photophysically innocent boron cluster ligands (2016) (91)
- Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes. (2012) (79)
- Surface Dipole Control of Liquid Crystal Alignment. (2015) (76)
- Cage-Walking: Vertex Differentiation by Palladium-Catalyzed Isomerization of B(9)-Bromo-meta-Carborane. (2017) (75)
- B-N, B-O, and B-CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B-Bromo-Carboranes. (2016) (73)
- A molecular cross-linking approach for hybrid metal oxides (2018) (71)
- Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants. (2016) (68)
- Dodecaborane‐Based Dopants Designed to Shield Anion Electrostatics Lead to Increased Carrier Mobility in a Doped Conjugated Polymer (2019) (58)
- Convergent diversity-oriented side-chain macrocyclization scan for unprotected polypeptides. (2013) (54)
- Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design (2010) (53)
- Enzymatic "click" ligation: selective cysteine modification in polypeptides enabled by promiscuous glutathione S-transferase. (2013) (49)
- Forging Unsupported Metal-Boryl Bonds with Icosahedral Carboranes. (2016) (39)
- Enzyme-Catalyzed Macrocyclization of Long Unprotected Peptides (2014) (38)
- Metal-catalyzed cross-coupling chemistry with polyhedral boranes. (2019) (36)
- SiO2 Aerogel Templated, Porous TiO2 Photoanodes for Enhanced Performance in Dye-Sensitized Solar Cells Containing a Ni(III)/(IV) Bis(dicarbollide) Shuttle (2011) (35)
- An Organometallic Strategy for Assembling Atomically Precise Hybrid Nanomaterials. (2019) (35)
- Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions. (2016) (32)
- Defect-Tolerant Aligned Dipoles within Two-Dimensional Plastic Lattices. (2015) (31)
- Infinite Coordination Polymer Nano‐ and Microparticle Structures (2009) (31)
- Tunable Dopants with Intrinsic Counterion Separation Reveal the Effects of Electron Affinity on Dopant Intercalation and Free Carrier Production in Sequentially Doped Conjugated Polymer Films (2020) (30)
- Work Function Control of Germanium through Carborane-Carboxylic Acid Surface Passivation. (2017) (29)
- Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands (2018) (27)
- Boron-dipyrromethene-functionalized hemilabile ligands as "turn-on" fluorescent probes for coordination changes in weak-link approach complexes. (2013) (27)
- Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands. (2011) (25)
- Selective formation of heteroligated Pt(II) complexes with bidentate phosphine-thioether (P,S) and phosphine-Selenoether (P,Se) ligands via the halide-induced ligand rearrangement reaction. (2010) (22)
- Sonochemical Synthesis of Small Boron Oxide Nanoparticles. (2018) (21)
- Off-Cycle Processes in Pd-Catalyzed Cross-Coupling of Carboranes. (2019) (20)
- Carborane Guests for Cucurbit[7]uril Facilitate Strong Binding and On-Demand Removal. (2020) (20)
- Oxidative Generation of Boron-Centered Radicals in Carboranes. (2019) (20)
- Reversible Silver Electrodeposition from Boron Cluster Ionic Liquid (BCIL) Electrolytes. (2018) (19)
- Improved synthesis of icosahedral carboranes containing exopolyhedral B-C and C-C bonds. (2018) (18)
- Cross-linking dots on metal oxides (2019) (16)
- Buchwald-Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands. (2018) (14)
- A Perfluoroaryl-Cysteine S[subscript N]Ar Chemistry Approach to Unprotected Peptide Stapling (2013) (13)
- Perfunctionalized Dodecaborate Clusters as Stable Metal-Free Active Materials for Charge Storage. (2018) (13)
- Magnesium Reagents Featuring a 1,1′‐Bis(o‐carborane) Ligand Platform (2017) (13)
- Sterically Unprotected Nucleophilic Boron Cluster Reagents. (2019) (12)
- Metal-Free Peralkylation of the closo-Hexaborate Anion (2017) (11)
- A Super-Oxidized Radical Cationic Icosahedral Boron Cluster. (2020) (11)
- An Organometallic Strategy for Cysteine Borylation. (2021) (10)
- Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation. (2018) (10)
- Expanding the Scope of Palladium-Catalyzed B - N Cross-Coupling Chemistry in Carboranes. (2020) (10)
- Plasticity of the nickel(II) coordination environment in complexes with hemilabile phosphino thioether ligands. (2011) (10)
- The Long-Lasting Blues: A New Record for Phosphorescent Organic Light-Emitting Diodes (2017) (8)
- Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1'-bis(o-carborane) backbone. (2019) (8)
- Gold(III) Aryl Complexes as Reagents for Constructing Hybrid Peptide-Based Assemblies via Cysteine S-Arylation. (2020) (8)
- A highly-selective chloride microelectrode based on a mercuracarborand anion carrier (2019) (7)
- An Inorganic Twist in Nanomaterials: Making an Atomically Precise Double Helix (2016) (7)
- Cross-linked porous polyurethane materials featuring dodecaborate clusters as inorganic polyol equivalents. (2019) (7)
- Carborane RAFT agents as tunable and functional molecular probes for polymer materials (2019) (6)
- Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions. (2019) (6)
- Multivalent Cluster Nanomolecules for Inhibiting Protein-Protein Interactions. (2019) (5)
- A molecular boron cluster-based chromophore with dual emission. (2020) (4)
- Enhancing Cycling Stability of Tungsten Oxide Supercapacitor Electrodes via a Boron Cluster-Based Molecular Cross-Linking Approach (2020) (4)
- Imparting Scientific Literacy through an Online Materials Chemistry General Education Course (2021) (3)
- Ex Vivo and In Vivo Evaluation of Dodecaborate-Based Clusters Encapsulated in Ferumoxytol Nanoparticles. (2021) (3)
- Dynamic Nuclear Polarization Using 3D Aromatic Boron Cluster Radicals. (2020) (2)
- Erratum: Ni(III)/(IV) Bis(dicarbollide) as a fast, noncorrosive redox shuttle for dye-sensitized solar cells (Journal of the American Chemical Society (2010) 132 (4580-4582)) (2011) (2)
- "Mr. Boron", an Inorganic Chemistry Icon, Turns 90. (2019) (2)
- Narratives of undergraduate research, mentorship, and teaching at UCLA (2021) (1)
- Icosahedral m-Carboranes Containing Exopolyhedral B-Se and B-Te Bonds. (2021) (1)
- Electronic Structure of Superoxidized Radical Cationic Dodecaborate-Based Clusters. (2021) (1)
- Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies (2022) (1)
- Publisher Correction: A molecular cross-linking approach for hybrid metal oxides (2018) (1)
- Metal-Catalyzed and Metal-Free Nucleophilic Substitution of 7-I-B18H21. (2022) (1)
- Mr. Inorganic Chemistry: M. Frederick Hawthorne (August 24, 1928-July 8, 2021). (2021) (1)
- Designer porous solids tackle separations of fluoroorganics (2021) (0)
- An Organometallic Gold(III) Reagent for 18F Labeling of Unprotected Peptides and Sugars in Aqueous Media. (2022) (0)
- Cover Feature: Magnesium Reagents Featuring a 1,1′‐Bis(o‐carborane) Ligand Platform (Eur. J. Inorg. Chem. 38‐39/2017) (2017) (0)
- Arene C–H borylation strategy enabled by a non-classical boron cluster-based electrophile (2023) (0)
- Tuning counterion chemistry to reduce carrier localization in doped semiconducting carbon nanotube networks (2023) (0)
- Organometallic S-arylation Reagents for Rapid PEGylation of Biomolecules. (2022) (0)
- Rapid Flow-Based Peptide Synthesis Citation (2014) (0)
- Tuning Counterion Chemistry to Reduce Carrier Localization in Doped Thermoelectric Carbon Nanotube Networks (2022) (0)
- Cysteine Borylation in Unprotected Peptides (2021) (0)
- OxidativeGeneration of Boron-Centered Radicals inCarboranes (2020) (0)
- UNIVERISTY OF CALIFORNIA Los Angeles Synthesis of Yttrium and Aluminum Complexes Supported by a Mono-Substituted Ferrocene Ligand (2015) (0)
- Synthesis and luminescence of monohalogenated B18H22 clusters (2022) (0)
- Synthetic Investigations Featuring Boron-Rich and Multidentate Chalcoether-Containing Ligands (2011) (0)
- Fast, non-corrosive redox shuttles for dye-sensitized solar cells based on boron clusters (2010) (0)
- Benchmarking the dynamic luminescence properties and UV stability of B18H22-based materials. (2022) (0)
- Selective Chloride Ion Sensing Microelectrodes using a Boron Cluster Ionophore (2018) (0)
- Synthesis and structural properties of a 2D Zn(II) dodecahydroxy-closo-dodecaborate coordination polymer. (2022) (0)
- UNIVERSITY OF CALIFORNIA Los Angeles Rational design of platinum-based ultrafine nanowire material for superior electro-catalytic properties A dissertation submitted in partial satisfaction of the requirements for the degree Doctor of Philosophy in Chemistry by (2017) (0)
- Abiotic Main Group Pharmacophore Renders a New Class of Antimicrobial Agents (2022) (0)
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