Alexandre Alexakis
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Chemistry
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(Suggest an Edit or Addition)Alexandre Alexakis's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions. (2008) (760)
- Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation. (2007) (424)
- Enantioselective Copper-Catalysed Conjugate Addition (2002) (385)
- Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters. (2010) (370)
- Carbometallation (C-Metallation) of Alkynes: Stereospecific Synthesis of Alkenyl Derivatives (1981) (287)
- Diamine-catalyzed asymmetric Michael additions of aldehydes and ketones to nitrostyrene. (2002) (238)
- A highly effective phosphoramidite ligand for asymmetric allylic substitution. (2004) (233)
- Copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted enones. Construction of all-carbon quaternary chiral centers. (2006) (214)
- The Use of N‐Alkyl‐2,2′‐bipyrrolidine Derivatives as Organocatalysts for the Asymmetric Michael Addition of Ketones and Aldehydes to Nitroolefins (2004) (206)
- Dramatic improvement of the enantiomeric excess in the asymmetric conjugate addition reaction using new experimental conditions. (2002) (204)
- Asymmetric Michael Addition of α-Hydroxyketones to Nitroolefins Catalyzed by Chiral Diamine (2003) (185)
- Copper‐Catalyzed Asymmetric Allylic Alkylation (2008) (178)
- Chiral acetals in asymmetric synthesis (1990) (174)
- Organocopper Conjugate Addition Reaction in the Presence of Trimethylchlorosilane. (1986) (172)
- Enantioselective copper-catalyzed conjugate addition to trisubstituted cyclohexenones: construction of stereogenic quaternary centers. (2005) (167)
- Enantioselective organocatalytic fluorination-induced Wagner-Meerwein rearrangement. (2013) (166)
- Phosphoramidite ligands in iridium-catalyzed allylic substitution. (2006) (146)
- First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sulfones. (2005) (141)
- Copper-catalyzed asymmetric conjugate addition of trialkylaluminium reagents to trisubstituted enones: construction of chiral quaternary centers. (2007) (136)
- Transition Metal Catalyzed Enantioselective Allylic Substitution in Organic Synthesis (2012) (136)
- Regiodivergent 1,4 versus 1,6 asymmetric copper-catalyzed conjugate addition. (2008) (136)
- Enantioselective organocatalytic conjugate addition of aldehydes to vinyl sulfones and vinyl phosphonates as challenging Michael acceptors. (2009) (133)
- Chiral phosphorus ligands for the asymmetric conjugate addition of organocopper reagents (1993) (125)
- Enantioselective one-pot organocatalytic Michael addition/gold-catalyzed tandem acetalization/cyclization. (2009) (120)
- Very efficient phosphoramidite ligand for asymmetric iridium-catalyzed allylic alkylation. (2004) (113)
- Novel Biphenol Phosphoramidite Ligands for the Enantioselective Copper-Catalyzed Conjugate Addition of Dialkyl zincs (2001) (110)
- 3,3'-bimorpholine derivatives as a new class of organocatalysts for asymmetric Michael addition. (2006) (109)
- Biphenol-based phosphoramidite ligands for the enantioselective copper-catalyzed conjugate addition of diethylzinc. (2004) (109)
- Highly enantioselective direct vinylogous Michael addition of γ-butenolide to enals. (2011) (104)
- SimplePhos monodentate ligands: synthesis and application in copper-catalyzed reactions. (2007) (103)
- Copper-catalyzed asymmetric conjugate addition of aryl aluminum reagents to trisubstituted enones: construction of aryl-substituted quaternary centers. (2008) (102)
- Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands (2001) (97)
- Access to high levels of molecular complexity by one-pot iridium/enamine asymmetric catalysis. (2011) (94)
- Asymmetric conjugate addition of diethyl zinc to enones with chiral phosphorus ligands derived from TADDOL (1998) (94)
- Formation of quaternary chiral centers by N-heterocyclic carbene-Cu-catalyzed asymmetric conjugate addition reactions with Grignard reagents on trisubstituted cyclic enones. (2010) (92)
- Enantioselective organocatalytic conjugate addition of aldehydes to nitrodienes. (2008) (90)
- Mechanistic aspects on the formation of chiral allenes from propargylic ethers and organocopper reagents (1990) (90)
- Asymmetric Synthesis with N‐Heterocyclic Carbenes. Application to the Copper‐Catalyzed Conjugate Addition (2003) (89)
- Boron fluoride promoted opening of epoxides by organocopper and cuprate reagents (1986) (87)
- Tandem copper-catalyzed enantioselective allylation-metathesis. (2002) (87)
- A new reagent for the determination of the optical purity of primary, secondary, and tertiary chiral alcohols and of thiols (1992) (86)
- Synthesis and Application of Chiral Phosphorus Ligands Derived from TADDOL for the Asymmetric Conjugate Addition of Diethyl Zinc to Enones (2000) (86)
- Organocatalyzed asymmetric reactions via microwave activation. (2006) (84)
- Kinetic study of various phosphoramidite ligands in the iridium-catalyzed allylic substitution. (2005) (82)
- Enantioselective iridium-catalyzed allylic arylation. (2009) (77)
- Organocatalyzed Conjugate Addition of Carbonyl Compounds to Nitrodienes/Nitroenynes and Synthetic Applications (2010) (76)
- Chiral Diamines for a New Protocol To Determine the Enantiomeric Composition of Alcohols, Thiols, and Amines by 31P, 1H, 13C, and 19F NMR (1994) (75)
- Diastereoselective syn or anti opening of propargylic epoxides. Synthesis of α-allenic alcohols (1991) (74)
- Enantioselective copper-catalyzed conjugate addition of trimethylaluminium to β,γ-unsaturated α-ketoesters. (2012) (74)
- Resolution and asymmetric synthesis of ortho-substituted (benzaldehyde)tricarbonylchromium complexes (1992) (71)
- First enantioselective organocatalytic conjugate addition of aldehydes to vinyl phosphonates. (2007) (71)
- Highly enantioselective copper(I)-phosphoramidite-catalysed additions of organoaluminium reagents to enones. (2005) (69)
- Tandem enantioselective conjugate addition: electrophile trapping reactions. Application in the formation of syn or anti aldols. (2001) (69)
- N-Heterocyclic carbene-catalyzed annulation of α-cyano-1,4-diketones with ynals. (2012) (68)
- Enantioselective copper catalysed 1,4-conjugate addition reactions using chiral N-heterocyclic carbenes (2005) (68)
- Formation of quaternary stereogenic centers by NHC-Cu-catalyzed asymmetric conjugate addition reactions with Grignard reagents on polyconjugated cyclic enones. (2012) (67)
- Organocatalytic Michael addition, a convenient tool in total synthesis. First asymmetric synthesis of (−)-botryodiplodin (2003) (66)
- A new chiral ligand for the asymmetric conjugate addition of organocopper reagents to enones (1991) (66)
- Copper-catalyzed enantioselective synthesis of axially chiral allenes. (2012) (65)
- Acceleration of the conjugate addition of diethyl zinc to enones by either Cu(OTf)2 or trivalent phosphorus ligands (1997) (64)
- Asymmetric conjugate addition of diethyl zinc to enones with tartrate chiral phosphite ligands (1997) (64)
- Enantioselective Copper-Catalyzed SN2′ Substitution with Grignard Reagents (2001) (63)
- beta-Disubstituted allylic chlorides: substrates for the Cu-catalyzed asymmetric SN2' reaction. (2006) (61)
- Enantioselective organocatalytic iodination-initiated Wagner-Meerwein rearrangement. (2013) (61)
- Vinyl-copper derivatives XIII: Synthesis of conjugated dienes of very high stereoisomeric purity (1981) (60)
- Asymmetric cleavage of chiral acetals by R2CuLi,BF3 reagents (1984) (60)
- Diversity-oriented synthesis towards conceptually new highly modular aminal-pyrrolidine organocatalysts. (2008) (60)
- Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles. (2012) (60)
- Enantioselective and regiodivergent copper-catalyzed conjugate addition of trialkylaluminium reagents to extended nitro-Michael acceptors. (2010) (59)
- The copper-catalyzed asymmetric allylic substitution (2006) (59)
- Iridium-catalyzed asymmetric allylic substitution with aryl zinc reagents. (2007) (59)
- Titanium Induced Coupling of Imines to Symmetrical Vicinal (R*,R*)-Diamines (1988) (59)
- Copper-Catalyzed Asymmetric Synthesis: Alexakis/Copper-Catalyzed Asymmetric Synthesis (2014) (59)
- Mild protection and deprotection of alcohols as ter-butyl ethers in the field of pheromone synthesis (1988) (59)
- Reactivity of RCu,BF3 and R2CuLi,BF3 towards the ether linkage. Epoxides, acetals and orthoformates (1984) (58)
- Copper-catalyzed asymmetric conjugate addition with chiral SimplePhos ligands. (2009) (58)
- Enantioselective halogenative semi-pinacol rearrangement: extension of substrate scope and mechanistic investigations. (2015) (57)
- Rhodium-catalyzed asymmetric 1,4-addition of aryl alanes to trisubstituted enones: binap as an effective ligand in the formation of quaternary stereocenters. (2010) (57)
- Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications. (2002) (57)
- Resolution and determination of enantiomeric excesses of chiral aldehydes via chiral imidazolidines (1988) (57)
- Vinylcopper derivatives. XI. Reactivity of Z-alkenylcuprates towards various electrophiles. Application to the synthesis of some natural products (1980) (55)
- Asymmetric organocatalytic 1,6-conjugate addition of aldehydes to dienic sulfones. (2011) (55)
- A New Efficient Synthesis of (R,R)-2,2′-Bipyrrolidine: An Interesting Chiral 1,2-Diamine with C2 Symmetry (2000) (55)
- One-pot asymmetric conjugate addition-trapping of zinc enolates by activated electrophiles. (2006) (54)
- On the use of phosphoramidite ligands in copper-catalyzed asymmetric transformations with trialkylaluminum reagents. (2006) (54)
- Copper-free asymmetric allylic alkylation with Grignard reagents. (2010) (54)
- Asymmetric conjugate addition to alpha-halo enones: dramatic effect of styrene on the enantioselectivity. (2006) (52)
- Cu-catalysed asymmetric 1,4-addition of Me3Al to nitroalkenes. Synthesis of (+)-ibuprofen (2005) (51)
- General methodology for the synthesis of conjugated dienic insect sex pheromones (1984) (51)
- Copper-catalyzed enantioselective intramolecular conjugate addition/trapping reactions: synthesis of cyclic compounds with multichiral centers. (2007) (51)
- New experimental conditions for tandem hydroalumination/Cu-catalyzed asymmetric conjugate additions to β-substituted cyclic enones. (2011) (49)
- Catalytic Asymmetric Conjugate Addition on Macrocyclic and Acyclic Enones. Synthesis of R-(-)-Muscone (1999) (49)
- The hydroalumination of ω-terbutoxy alkynes an easy access to ω-hydroxy alkenyl iodides application to the synthesis of dienic insect pheromones (1988) (49)
- Copper catalyzed enantioselective allylic substitution by MeMgX (2004) (48)
- Preparation and Utilization of Chiral Dihydropyridines. Synthesis of Chiral Indoloquinolizines and Benzoquinolizines (1994) (48)
- Highly enantioselective and regioselective copper-catalyzed 1,4 addition of grignard reagents to cyclic enynones. (2011) (48)
- Copper-catalyzed enantioselective 1,4-addition to alpha,beta-unsaturated aldehydes. (2010) (47)
- Aminal–Pyrrolidine Organocatalysts – Highly Efficient and Modular Catalysts for α‐Functionalization of Carbonyl Compounds (2010) (47)
- Enantioselective 1,6-conjugate addition to cyclic dienones catalyzed by the Cu-DiPPAM complex. (2010) (47)
- Chiral p-monodentate phosphoramidite and phosphite ligands for the enantioselective Pd-catalyzed allylic alkylation (2006) (46)
- Enyne chlorides: substrates for copper-catalyzed asymmetric allylic alkylation. (2012) (46)
- Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents (2009) (46)
- Tandem enantioselective conjugate addition--cyclopropanation. Application to natural products synthesis. (2002) (46)
- Chiral animals: Powerful auxiliaries in asymmetric synthesis (1996) (45)
- 1,4-Dichloro- and 1,4-dibromo-2-butenes as substrates for Cu-catalyzed asymmetric allylic substitution. (2007) (45)
- Stereochemical aspects on the formation of chiral allenes from propargylic ethers and epoxides (1992) (45)
- Copper-catalyzed asymmetric synthesis (2014) (45)
- Asymmetric conjugate addition to alkylidene malonates (2001) (45)
- Reactivity and diastereoselectivity of Grignard reagents toward the hydrazone functionality in toluene solvent (1992) (44)
- Conceptually new chiral tertiary C2 symmetric diamines in asymmetric synthesis (2003) (44)
- Reactivity of RCu,BF3 and R2 CuLi,BF3 towards allylic acetals and ethers (1984) (42)
- Simple 1,2‐Diamine Ligands for Asymmetric Addition of Aryllithium Reagents to Imines (2005) (41)
- Organocatalytic addition on 1,2-bis(sulfone)vinylenes leading to an unprecedented rearrangement. (2009) (41)
- Identification of a valuable kinetic process in copper-catalyzed asymmetric allylic alkylation. (2011) (41)
- Chiral, Chelating Hydroxyalkyl and Hydroxyaryl N-Heterocyclic Carbenes: Design, Synthesis, and Application in Copper-Catalyzed Asymmetric Conjugate Addition (Cu-ACA) (2010) (40)
- An easy and fast way to determine the enantiomeric purity of substituted cyclanones (1993) (40)
- Enantioselective addition of organolithium reagents on isoquinoline (2002) (40)
- Chiral aminal termplates 61. Diastereoselectivity of hydrazone alkylation. Asymmetric synthesis of α-aminoaldehydes (1991) (40)
- Enantioselective Addition of Methyllithium to Aromatic Imines Catalyzed by C2 Symmetric Tertiary Diamines. (2005) (39)
- Copper-catalyzed asymmetric 1,4-addition of alkenyl alanes to N-substituted-2-3-dehydro-4-piperidones. (2012) (39)
- Enantioselective 1,6-conjugate addition of dialkylzinc reagents to acyclic dienones catalyzed by Cu-DiPPAM complex-extension to asymmetric sequential 1,6/1,4-conjugate addition. (2013) (39)
- Asymmetric conjugate addition of diethyl zinc to enones with chiral phosphine ligands (1997) (39)
- Asymmetric conjugate addition of metal alkyl reagents catalyzed by copper complexes with BINPO, a hemilabile P,O-heterobidentate axially chiral ligand (2005) (39)
- Dynamic kinetic asymmetric transformation in copper catalyzed allylic alkylation. (2009) (39)
- High diversity on simple substrates: 1,4-dihalo-2-butenes and other difunctionalized allylic halides for copper-catalyzed S(N)2' reactions. (2008) (38)
- Chiral acetals in enantio- and diastereoselective substitution or elimination reactions (1988) (38)
- Copper(I) thiolate catalysts in asymmetric conjugate addition reactions. (2004) (38)
- Are allenes formed from propargylic ethers through a syn or anti displacement (1986) (37)
- Chiral Aminal Templates - Diastereoselective Addition To Hydrazones - An Asymmetric-synthesis of Alpha-amino Aldehydes (1995) (37)
- Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands (2004) (37)
- Vinyl-Copper Derivatives; X1. Alkylation of (Z)-Dialkenylcuprates (1979) (37)
- Diastereoselective conjugate addition with acetals, oxazolidines and imidazolidines as chiral auxiliaries (1988) (37)
- Improved optical resolution of R*,R* N,N'-dimethyl 1,2-diphenyl ethylene diamine (1988) (36)
- Biphenol-based ligands for Cu-catalyzed asymmetric conjugate addition (2004) (36)
- Chiral NHC Ligands for the Copper‐Catalyzed Asymmetric Conjugate Addition of Grignard Reagents (2012) (35)
- Asymmetric conjugate addition to α-substituted enones/enolate trapping. (2014) (35)
- A practical, solvent free, one-pot synthesis of C2-symmetrical secondary amines (2004) (35)
- Tandem reactions with chiral enolates: preparation of allylic alcohols via trapping with vinyl oxiranes. (2010) (34)
- Chiral trifluoro diamines as convenient reagents for determining the enantiomeric purity of aldehydes by use of fluorine-19 NMR spectroscopy (1989) (34)
- Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation (2012) (34)
- Copper-catalyzed Enantioselective Allylic Substitution (2011) (34)
- Significant asymmetric amplification in enantioselective Cu/DiPPAM-catalyzed 1,6- and 1,4-conjugate additions of diethylzinc to (di)enones. (2012) (34)
- Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial Chirality (2010) (34)
- Alkenyl copper reagents—18 : Carbocupration of acetylenic acetals and ketals synthesis of manicone, geranial and 2,4 (E,Z)-dienals☆ (1984) (34)
- Highly Enantioselective One‐Pot Copper‐Catalyzed 1,4 Addition/Organocatalyzed α‐Substitution of Enals (2010) (34)
- 1,2-Sulfone rearrangement in organocatalytic reactions. (2011) (34)
- Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases (1997) (33)
- Monoaminals of glyoxal: versatile chirons. (1995) (33)
- Copper‐Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Substrates: Application of Dynamic Kinetic Asymmetric Transformation (DYKAT) (2010) (32)
- A Highly Stereoselective Preparation of 1,4- and 1,5-Alkadienes (1978) (32)
- Asymmetric synthesis of 1,2- and 1,4-dihydroquinolines (1999) (32)
- Influence of the Double‐Bond Geometry of the Michael Acceptor on Copper‐Catalyzed Asymmetric Conjugate Addition (2007) (31)
- A PRACTICAL AND EFFICIENT SYNTHESIS OF ENANTIOMERICALLY PURE DI-TERT-BUTYL-ETHANEDIAMINE (1999) (31)
- Copper-catalyzed propargylic substitution of dichloro substrates: enantioselective synthesis of trisubstituted allenes and formation of propargylic quaternary stereogenic centers. (2014) (31)
- Vinyl-copper derivatives 151 : an efficient synthesis of polysubstituted conjugated dienes (1982) (31)
- Highly enantioselective organocascade intermolecular iminium/enamine Michael addition on enals. (2011) (31)
- Enantioselective ortho-Lithiation of Aminals of benzaldehyde chromiumtricarbonyl complex (1995) (30)
- Copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams. (2013) (30)
- Asymmetric addition of alpha-hetero-disubstituted aldehydes to vinyl sulfones; formation of highly functionalized tetrasubstituted carbon centres. (2010) (30)
- Diastereoselective β-elimination. Synthesis of chiral alkoxy-allenes (1985) (30)
- ENANTIOSELECTIVE NUCLEOPHILIC OPENING OF MESO EPOXIDES BY ORGANOLITHIUM REAGENTS (1998) (30)
- Boron fluoride promoted cleavage of acetals by organocopper reagents. Application to asymmetric synthesis (1989) (30)
- Formation of quaternary stereogenic centers by copper-catalyzed asymmetric conjugate addition reactions of alkenylaluminums to trisubstituted enones. (2013) (30)
- Enantio- and regioselective conjugate addition of organometallic reagents to linear polyconjugated nitroolefins. (2013) (30)
- Practical and efficient synthesis of C2 symmetrical diamines with Zn/Me3SiCl (1998) (29)
- Chiral aminal templates 3 diastereoselectivity of organometallic attack on aldehydes bearing a chiral imidazolidine group (1990) (29)
- A new reagent for a very simple and efficient determination of enantiomeric purity of alcohols by 31P NMR (1990) (29)
- Diastereoselective synthesis of α-allenic alcohols from propargylic epoxides (1989) (29)
- Enantioselective nucleophilic addition of organometallic reagents to quinoline: regio-, stereo- and enantioselectivity (2004) (29)
- Copper catalyzed asymmetric conjugate addition-bromination of α,β-unsaturated ketones: a highly efficient one-pot reaction for the synthesis of chiral α-bromo-β-alkylketones (2005) (29)
- Ultrasound-Assisted Cleavage of N-N Bonds in Hydrazines by Raney Nickel (1991) (28)
- Alkenyl Copper Reagents. Part 26. Carbocupration of Alkynes by Organocopper Reagents Bearing a Protected Hydroxy or Thiol Function. (1985) (28)
- Copper‐Catalyzed Asymmetric Conjugate Addition (2014) (27)
- Direct Organocatalysed Double Michael Addition of α‐Angelica Lactone to Enones (2016) (27)
- Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagents (1990) (27)
- Omega-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation. (2010) (27)
- Domino asymmetric conjugate addition-conjugate addition. (2014) (27)
- Acetals as chiral auxillaries Part 4 (1) (1987) (26)
- Vinly copper reagents-16. Synthesis of conjugated dienes via the addition of vinyl cuprates to acetylene (1982) (26)
- Enantioselective addition of organolithium reagents to quinoline catalyzed by 1,2-diamines (2005) (26)
- New Bifunctional Substrates for Copper-Catalyzed Asymmetric Conjugate Addition Reactions with Trialkylaluminium (2009) (26)
- Palladium mediated synthesis of conjugated E or Z enones and unsymmetrical divinyl ketones. one-pot preparation of isoegomaketone (1986) (26)
- Enantioselective copper-catalyzed conjugate addition of trimethylaluminum to β,γ-unsaturated α-ketoamides: efficient access to γ-methyl-substituted carbonyl compounds. (2013) (25)
- - and ?-Disubstituted Olefins: Substrates for Copper-Catalyzed Asymmetric Allylic Substitution (2008) (25)
- Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents (1981) (25)
- Enantioselective opening of cyclic vinyl epoxides with organoaluminium reagents catalysed by copper salts (2004) (25)
- Direct trapping of sterically encumbered aluminum enolates. (2013) (25)
- Diastereoselective conjugate addition to chiral α,β ethylenic acetals (1986) (25)
- Copper catalyzed tandem asymmetric conjugate addition–cyclization reaction in the presence of chiral phosphoramidite ligands (2005) (25)
- Conformationally stabilized catalysts by fluorine insertion: tool for enantioselectivity improvement. (2011) (24)
- Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes☆ (1990) (24)
- Copper-catalysed ring opening of polycyclic meso-hydrazines with trialkylaluminium reagents and SimplePhos ligands. (2010) (24)
- Enantioselective organocatalytic conjugate addition of alpha-aminoketone to nitroolefins. (2008) (24)
- Radical cyclizations of 1,4-dihydropyridines. Synthesis of chiral fused nitrogen heterocycles. Synthesis of lupinine and epilupinine (1998) (23)
- A new synthetic approach to pseudoguaianes. (1978) (23)
- Construction of bicyclo[3.2.1]octanes with four stereogenic centers by organocatalytic domino Michael/Aldol reaction. (2014) (23)
- Enantioselective halogenative semi-pinacol rearrangement: a stereodivergent reaction on a racemic mixture. (2014) (23)
- Tandem asymmetric conjugate addition-enolacetates formation of enantiomerically enriched zinc and aluminium enolates (2007) (23)
- γ-Tributylstannyl-β-metallated acrolein : a versatile synthon (1991) (23)
- Enantioselective ortho-lithiation of benzaldehyde chromiumtricarbonyl complex (1995) (22)
- Formation of chiral fluoroalkyl products through copper-free enantioselective allylic alkylation catalyzed by an NHC ligand. (2012) (22)
- A highly efficient synthesis of (Z) γ-iodo allylic alcohols (1991) (22)
- Enantioselective catalytic fluorinative aza-semipinacol rearrangement. (2014) (22)
- Alkenyl-copper derivatives 24 (1983) (21)
- Diastereoselective Alkylation of (Arene)tricarbonylchromium and Ferrocene Complexes Using a Chiral, C2‐Symmetrical 1,2‐Diamine as Auxiliary (2005) (21)
- Organocatalyst-mediated enantioselective intramolecular Michael addition of aldehydes to vinyl sulfones (2010) (21)
- A new approach to conjugated dienes synthesis of the pheromones of lobesja botrana and bombyx morj (1989) (21)
- A practical and efficient synthesis of chiral N,N-disubstituted C2 symmetric diamines derived from (R,R)-1,2-diaminocyclohexane (2001) (21)
- Formation of contiguous quaternary and tertiary stereocenters by sequential asymmetric conjugate addition of Grignard reagents to 2-substituted enones and Mg-enolate trapping. (2015) (21)
- Highly stereoselective synthesis of the insect sex pheromone of Phthorimaea operculella and of propylure (1978) (21)
- Copper-free asymmetric allylic alkylation with a Grignard reagent: design of the ligand and mechanistic studies. (2013) (21)
- Alkenyl copper reagents 26. Carbocupration of alkynes by reagents bearing a protected hydroxy or thiol function (1985) (21)
- Simple stereospecific synthesis of the insect sex pheromones of cossus cossus, eupoecilia ambiguella and orgyia pseudotsugata (1980) (21)
- Alkenyl Copper Derivatives 251: Synthesis of E or Z Enol Ethers by Carbocupration of Alkoxy‐Allenes (1984) (21)
- Copper-free asymmetric allylic alkylation using grignard reagents on bifunctional allylic bromides. (2012) (20)
- Highly diastereo- and enantioselective organocatalytic domino Michael/aldol reaction of acyclic 3-halogeno-1,2-diones to α,β-unsaturated aldehydes. (2013) (20)
- Copper-free asymmetric allylic alkylation of trisubstituted cyclic allyl bromides using Grignard reagents. (2013) (20)
- A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines (2006) (20)
- Allylic organobismetallic reagents - Part 1 (1989) (20)
- Unusual 1,2-migration in organoaluminiun chemistry, promoted by BF3.OEt2. (1990) (20)
- Epimerization and kinetic resolution in copper-catalyzed enantioselective 1,4-additions of organozinc reagents to 6-substituted cyclohex-2-enones (2002) (20)
- The use of N-iPr-2,2'-bipyrrolidine derivatives as organocatalysts for asymmetric Michael additions (2006) (19)
- Chiral bromine–lithium exchange catalyzed by diamines (2009) (19)
- Synthesis and applications of chiral bis-THF in asymmetric synthesis (2004) (18)
- Organomanganese(II) reagents. V. Organomanganous chlorides as a new reagent for ketone synthesis via mixed or symmetrical anhydrides (1980) (18)
- Expeditious synthesis of the four isomers of methyl dimorphecolate (1991) (18)
- Transition metal-free asymmetric and diastereoselective allylic alkylation using Grignard reagents: construction of vicinal stereogenic centers via kinetic resolution (2014) (18)
- Organolithium/Chiral Lewis Base/BF3: a Versatile Combination for the Enantioselective Desymmetrization of meso‐Epoxides (2005) (18)
- Enantioselective synthesis of indoloquinolizidines (1991) (17)
- Determination of enantiomeric purity of hydroxy biaryls using 1H and 31P NMR on their diazaphospholidine derivatives (1994) (17)
- Lithium Compounds in Organic Synthesis (2014) (17)
- Phosphoramidite ligands for the enantioselective iridium-catalyzed asymmetric hydroboration of meso-bicyclic hydrazines (2005) (17)
- Regioselective SN2 Opening of Vinylic Epoxides with Trialkylzincates and Trialkylaluminates (2004) (16)
- Remote Asymmetric Induction. New Mechanistic Insights Concerning the SN‘ and SN‘‘ Substitution in Organocopper Chemistry (1996) (16)
- Organovinylcopper compounds V. Regioselectivity in the addition of alkyl copper-magnesium bromide reagents on various propargyl derivatives (1975) (16)
- Boron trifluoride assisted opening of epoxides by lithium alkenyl aluminate reagents (1989) (16)
- (R,R)-and (S,S)-N,N'-dimethyl-1,2-diphenylethylene-1,2-diamine (2003) (16)
- Fine-tunable monodentate phosphoroamidite and aminophosphine ligands for Rh-catalyzed asymmetric hydroformylation (2010) (16)
- A new strategy for the synthesis of the pheromones of Lobesia Botrana and Bombyx Mori (1988) (16)
- Determination of the absolute configuration of chiral aryl-alkyl carbinols using organophosphorus diamine derivatizing agents by 31P NMR spectroscopy (2004) (16)
- Copper‐Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple‐Bond Systems (2014) (16)
- Preparation of chiral hexahydroquinolizinones and tetrahydroindolizinones by regio- and diastereoselective sonochemical cyclization of chiral dihydropyridines (1996) (16)
- Practical Synthesis of SimplePhos Ligands: Further Development of Alkyl‐Substituted Phosphanamines (2013) (15)
- Isomerization of meso Diamines into their C2 Symmetrical d,l Isomers (1998) (15)
- Determination of the enantiomeric excess of chiral carboxylic acids by 31P NMR with C2 symmetrical diamines (2001) (15)
- Organocopper reagents for the synthesis of saturated, and α,β-ethylenic aldehydes and ketones (1984) (15)
- Chiral aminal templates 5. Preparation of chiral 3-carboxaldehydes-1,4-dihydropyridines (1991) (15)
- Copper-catalyzed asymmetric addition of diethylzinc to Boc-protected imines (2008) (15)
- Enantioselective 1,4-additions of ClMeAl(CH=CHR) (R = alkyl, alkenyl, Ph) to cyclohexenones. (2014) (14)
- TADDOL organophosphorus derivatising agents for the determination of the enantiomeric excess of chiral alcohols and carboxylic acids by 31P and 1H NMR spectroscopy (2000) (14)
- Regioselective SN2 opening of α,β-ethylenic epoxides by RLi–BF3 combination (2000) (14)
- Alkenylcopper derivatives. 24. Stereospecific synthesis of enones by palladium-catalyzed acylation of alkenylcopper reagents (1984) (14)
- Conjugate Addition Reactions (2008) (13)
- Formation of All-Carbon Quaternary Centers by Copper-Catalyzed Asymmetric Conjugate Addition (2008) (13)
- First diastereoselective asymmetric carbometallation of chiral vinyl metals (1998) (13)
- Evaluation of the Chiral DIANANE Backbone as Ligand for Organolithium Reagents (2012) (13)
- A completely stereoselective intramolecular diels-alder reaction in the substituted cyclohexanol series (1989) (13)
- Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy (2006) (12)
- Enantioselective catalytic rearrangement of cyclohexene oxide with new homochiral bis-lithium amide bases (2004) (12)
- Asymmetric Bromine–Lithium Exchange: Application toward the Synthesis of New Biaryl‐Diphosphine Ligands (2015) (12)
- Synthesis and application of a new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines (2007) (12)
- Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring‐Closing Metathesis (2013) (12)
- Asymmetric bromine-lithium exchange: application toward the synthesis of natural product. (2013) (12)
- Creation of Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl Alanes to α,β-Unsaturated Cyclic Ketones (2010) (11)
- Chiral aminals in asymmetric synthesis (1996) (11)
- Alkenylcopper Derivatives; 211,2. Synthesis of Allylic Amides and Amines by Amidomethylation of Alkenyl-Copper and -Cuprate Reagents (1984) (11)
- Creation of highly congested quaternary centers via Cu-catalyzed conjugate addition of alkenyl alanates to β-substituted cyclic enones. (2013) (11)
- Reactivity of allyl-zinc (and copper) reagents towards allenic ethers and α-metallated allenic ethers (1990) (11)
- Improvements and Applications of the Transition Metal‐Free Asymmetric Allylic Alkylation using Grignard Reagents and Magnesium Alanates (2015) (11)
- Regio and enantioselective synthesis of 4-carbomethoxymethyl-1,4 dihydropyridines (1994) (11)
- Copper catalyzed reductive metallation of a propargylic epoxide to an allenyl lithium reagent (1989) (10)
- Copper-catalyzed asymmetric conjugate addition with Grignard reagents and SimplePhos ligands (2009) (10)
- Effect of BF3·Et2O reagent on the base-promoted rearrangements of epoxides attached to eight-membered rings (2000) (10)
- Bulky P*‐Chirogenic Diazaphospholidines as Monodentate Ligands for Asymmetric Catalysis (2009) (10)
- Spiroannelation via gem-dihalocyclopropane substrates and a cyclocuprate species (1983) (10)
- Alkenylcopper Derivatives; 221,2. Stereoselective Synthesis of Allylic Thioethers (1984) (9)
- Furanoside phosphite–phosphoroamidite and diphosphoroamidite ligands applied to asymmetric Cu-catalyzed allylic substitution reactions (2012) (9)
- SYNTHESIS OF REGIOSELECTIVELY DEUTERATED HYDROXY CONJUGATED DIENES (1995) (9)
- Catalytic Enantioselective Total Synthesis of Riccardiphenol B (2016) (9)
- A new approach to the bicyclo[3.2.1]octane ring system: Intramolecular michael and aldol reactions of 3-(5-oxohexyl)-2-cyclopentenones (1978) (9)
- Unusually facile palladium catalysed oxidation of imidazolidines and oxazolidines (2001) (8)
- NEW ORGANOCOPPER SYNTHETIC METHODS. α,β‐DIALKYLATION OF α,β‐ETHYLENIC KETONES: SYNTHESIS OF SESQUITERPENES * (1977) (8)
- Copper catalysed asymmetric ring opening reaction of oxabenzonorbornadienes with grignard and aluminium reaggents (2009) (7)
- Synthesis of (Z,Z)-3, 13-octadecadien-1-yl acetate Component of the sex pheromone ofSynanthedon tenuis (1983) (7)
- The Conjugate Addition Reaction (2008) (7)
- Conjugate addition of organocuprates to γ-methyl-δ-oxy-α,β-enones. Influence of the alkoxy substituent on the diastereoselection (1992) (7)
- Enantioselective Copper‐Catalyzed Conjugate Addition (2003) (7)
- Alkenylcopper Derivatives; 271. Synthesis of 1-Alkenyl Thioethers by Cleavage of Disulfides with 1-Alkenyl-copper Reagents (1985) (6)
- Enantioselective copper-catalyzed conjugate addition to 2-or 3-substituted cyclopent -2 -en -1 -ones : Construction of stereogenic quaternary carbon centers (2007) (6)
- Copper-catalyzed asymmetric conjugate addition to challenging Michael acceptors and synthesis of relevant target molecules. (2012) (6)
- Direct Organocatalytic Construction of Bicyclo[3.2.1]octanes by Domino Michael/Aldol Reaction with β,γ-Unsaturated 1,2-Keto Amides (2014) (5)
- Enantioselective Copper‐Catalyzed Conjugate Addition to Trisubstituted Cyclohexenones: Construction of Stereogenic Quaternary Centers. (2005) (5)
- Synthesis and use of a phosphoramidite ligand for the copper-catalyzed enantioselective allylic substitution. Tandem allylic substitution/ring-closing metathesis (2004) (5)
- Copper-mediated asymmetric transformations (2002) (5)
- Synthesis of (Z)-13-hexadecen-11-yn-1-yl acetate Major component of sex pheromone of the processionary moth (1983) (5)
- Organocatalytic asymmetric annulation of 1,3-bis(alkoxycarbonyl)buta-1,3-dienes and aldehydes. (2013) (5)
- Highly Enantioselective Direct Vinylogous Michael Addition of γ‐Butenolide to Enals. (2011) (5)
- Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR (2006) (5)
- Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents (1996) (4)
- Carbocupration of acetylenic acetals and ketals: synthesis of α-β ethylenic acetals, and of dienals and dienones (1983) (4)
- Copper-catalysed kinetic resolution of cyclic alkenyl cyclopropane malonates with organoaluminium and Grignard reagents (2010) (4)
- Alkenyl copper reagents—26 (1985) (4)
- Regio- and diastereoselective SN2′ or SN2″ reactions on chiral acetals of cyclic aldehydes promoted by PhCu, BF3 (2001) (4)
- Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex (1999) (4)
- Z‐1‐Iodohexene (2003) (4)
- Copper-Catalyzed Enantioselective Conjugate Addition to α,β-Unsaturated Aldehydes with Various Organometallic Reagents (2016) (3)
- Some aspects of the reactivity of RCu/BF3 reagents towards the ether linkage (1988) (3)
- New P-chiral polyfluoroalkyl phosphorodiamidite ligand in asymmetric transformations catalyzed by palladium and copper complexes (2008) (3)
- SimplePhos as Efficient Ligandfor the Copper-Catalyzed Kinetic Resolution of Cyclic Vinyloxiraneswith Grignard Reagents (2008) (3)
- Asymmetric Synthesis Using Organocopper Reagents (2000) (3)
- Copper‐Catalyzed Asymmetric Ring‐Opening Reaction of Oxabenzonorbornadienes with Grignard and Aluminum Reagents. (2009) (3)
- A Practical and Efficient Synthesis of Enantiomerically Pure Di-tert-butylethanediamine. (1999) (3)
- Enantioselective 1,4‐Additions of ClMeAl(CH=CHR) (R = Alkyl, Alkenyl, Ph) to Cyclohexenones. (2014) (3)
- Asymmetric bromine-lithium exchange: on the importance of both the diamine ligand and the organolithium reagent. (2015) (3)
- Asymmetric Conjugate Addition (1996) (2)
- Copper‐Catalyzed Enantioselective Conjugate Addition (2010) (2)
- Diastereoselective Synthesis of α-Allenic Alcohols from Propargylic Epoxides. (1989) (2)
- Creation of Quaternary Stereogenic Centers via Copper‐Catalyzed Asymmetric Conjugate Addition of Alkenyl Alanes to α,β‐Unsaturated Cyclic Ketones. (2010) (2)
- SimplePhos as Efficient Ligand for the Copper‐Catalyzed Kinetic Resolution of Cyclic Vinyloxiranes with Grignard Reagents. (2008) (2)
- A New Efficient and Stereoselective Synthesis of 1,3E,5Z-Undecatriene (2006) (2)
- Asymmetric Michael addition of alpha-hydroxyketones to nitroolefins catalyzed by chiral diamine. (2003) (2)
- The Copper‐Catalyzed Asymmetric Allylic Substitution (2007) (2)
- Copper-Catalyzed Asymmetric Conjugate Addition to α-Alkylidene Cycloalkanones (2015) (2)
- A New Reagent (I) for the Determination of the Optical Purity of Primary, Secondary, and Tertiary Chiral Alcohols and of Thiols. (1992) (2)
- New Chiral Ligand for the Asymmetric Conjugate Addition of Organocopper Reagents to Enones. (1991) (2)
- Copper‐Catalyzed Asymmetric Allylic Alkylation of Racemic Cyclic Substrates: Application of Dynamic Kinetic Asymmetric Transformation (DYKAT). (2010) (2)
- Chiral Phosphorus Ligands for the Asymmetric Conjugate Addition of Organocopper Reagents. (1994) (2)
- Copper‐Catalyzed Asymmetric Allylic Alkylation (Eur. J. Org. Chem. 22/2008) (2008) (2)
- Synthesis and use of 3,3'-bimorpholine derivatives in asymmetric Michael addition and intramolecular aldol reaction (2007) (2)
- SIMPLE STEREOSPECIFIC SYNTHESIS OF THE INSECT SEX PHEROMONES OF COSSUS COSSUS, EUPOECILIA AMBIGUELLA, AND ORGYIA PSEUDOTSUGATA (1980) (2)
- Chiral Trifluorodiamines as Convenient Reagents for Determining the Enantiomeric Purity of Aldehydes by Use of 19F NMR Spectroscopy. (1989) (2)
- Mild Protection and Deprotection of Alcohols as tert-Butyl Ethers in the Field of Pheromone Synthesis. (1988) (2)
- ALKENYL COPPER REAGENTS - 18. CARBOCUPRATION OF ACETYLENIC ACETALS AND KETALS. SYNTHESIS OF MANICONE, GERANIAL AND 2,4-(E,Z)-DIENALS (1984) (2)
- Chiral Aminal Templates: Diastereoselective Addition to Hydrazones; an Asymmetric Synthesis of α-Amino Aldehydes. (1995) (2)
- Organocatalytic Michael Addition, a Convenient Tool in Total Synthesis. First Asymmetric Synthesis of (-)-Botryodiplodin. (2004) (2)
- Diamine‐Catalyzed Asymmetric Michael Additions of Aldehydes and Ketones to Nitrostyrene. (2003) (2)
- Chiral aminal templates. Diastereo- and enantioselectivity in 1,4 (conjugate) and 1,2 additions with organometallic reagents (1993) (2)
- Enantioselective Organocatalytic Conjugate Addition of α‐Aminoketone to Nitroolefins. (2009) (2)
- Asymmetric Addition of α-Hetero-Disubstituted Aldehydes to Vinyl Sulfones; Formation of Highly Functionalized Tetrasubstituted Carbon Centers. (2010) (1)
- CARBOMETALATION (C-METALATION) OF ALKYNES: STEREOSPECIFIC SYNTHESIS OF ALKENYL DERIVATIVES (1982) (1)
- Catalytic Asymmetric Conjugate Addition on Macrocyclic and Acyclic Enones. Synthesis of R-(-)-Muscone. (2000) (1)
- Alkenyl-copper derivatives. 19. Synthesis of conjugated dienes and styrenes by coupling of alkenyl cuprates with alkenyl and aryl halides (1983) (1)
- Simple 1,2-Diamine Ligands for Asymmetric Addition of Aryllithium Reagents to Imines. (2006) (1)
- Copper-Catalyzed Kinetic Resolution of 1,3-Cyclohexadiene Monoepoxide with Grignard Reagents (2007) (1)
- Enantioselective Copper-Catalyzed SN2′ Substitution with Grignard Reagents. (2001) (1)
- Biphenol‐Based Ligands for Cu‐Catalyzed Asymmetric Conjugate Addition. (2004) (1)
- Tandem Copper‐Catalyzed Enantioselective Allylation—Metathesis. (2003) (1)
- VINYLCOPPER DERIVATIVES. XIII. SYNTHESIS OF CONJUGATED DIENES OF VERY HIGH STEREOISOMERIC PURITY (1981) (1)
- Formation of Chiral Fluoroalkyl Products Through Copper‐Free Enantioselective Allylic Alkylation Catalyzed by an NHC Ligand. (2013) (1)
- Asymmetric organocopper chemistry : Cu-catalyzed conjugate addition and allylic substitution (2004) (1)
- Formation of all‐Carbon Quaternary Centers by Copper‐Catalyzed Asymmetric Conjugate Addition (2009) (1)
- Copper (I) promoted asymmetric transformations : a long standing challenge (1999) (1)
- Copper-Catalyzed Enantioselective 1,4-Addition to α,β-Unsaturated Aldehydes. (2010) (1)
- Organocatalytic Conjugate Addition in Stereoselective Synthesis (2013) (1)
- Enantioselective Organocatalytic Fluorination-Induced Wagner—Meerwein Rearrangement. (2014) (1)
- A Practical, Solvent‐Free, One‐Pot Synthesis of C2‐Symmetrical Secondary Amines. (2004) (1)
- Copper‐Catalyzed Asymmetric Conjugate Addition of Grignard Reagents to Trisubstituted Enones. Construction of All‐Carbon Quaternary Chiral Centers. (2006) (1)
- ω‐Ethylenic Allylic Substrates as Alternatives to Cyclic Substrates in Copper‐ and Iridium‐Catalyzed Asymmetric Allylic Alkylation. (2010) (1)
- Rhodium and Copper-Catalyzed Asymmetric Conjugate Addition of Alkenyl Nucleophiles (2013) (1)
- Mechanistic Aspects on the Formation of Chiral Allenes from Propargylic Ethers and Organocopper Reagents. (2010) (1)
- Organolithium/Chiral Lewis Base/BF3: A Versatile Combination for the Enantioselective Desymmetrization of meso-Epoxides. (2005) (1)
- VINYL COPPER REAGENTS. 17. CARBOCUPRATION OF ALKYNES BY ORGANOCUPRATES AND -COPPER DERIVATIVES (1983) (1)
- Reactivity and Diastereoselectivity of Grignard Reagents Toward the Hydrazone Functionality in Toluene Solvent. (1993) (1)
- Copper‐Catalyzed Reductive Metalation of a Propargylic Epoxide to an Allenyllithium Reagent. (1989) (1)
- Enantio‐ and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins. (2014) (1)
- Copper‐Catalyzed Asymmetric 1,4‐Addition of Alkenyl Alanes to N‐Substituted‐2‐3‐dehydro‐4‐piperidones. (2012) (1)
- Synthesis of Regioselectively Deuterated Hydroxy Conjugated Dienes. (2010) (1)
- Resolution and Determination of Enantiomeric Excesses of Chiral Aldehydes via Chiral Imidazolidines. (1988) (1)
- New access to conjugated dienes via carbocupration of alkynes (1983) (1)
- VINYLIC ORGANOCOPPER DERIVATIVES. VI. REGIOSELECTIVE ADDITION OF ORGANOCUPRATES ON α-ACETYLENIC ACETALS. SYNTHESIS OF A GERANIAL ACETAL (1976) (1)
- An Easy and Fast Way to Determine the Enantiomeric Purity of Substituted Cyclanones. (1994) (0)
- ASYMMETRIC SYNTHESIS OF ALDEHYDES FROM CHIRAL α,β-UNSATURATED OXAZOLIDINES AND ORGANOCUPRATES (1983) (0)
- Special topic issue on the theme of organometallics in organic synthesis (2006) (0)
- Formation of Contiguous Quaternary and Tertiary Stereocenters by Sequential Asymmetric Conjugate Addition of Grignard Reagents to 2‐Substituted Enones and Mg—Enolate Trapping. (2015) (0)
- Alkenyl-copper derivatives. 20. Preparation of polysubstituted conjugated dienes by coupling of alkenyl halides with alkenyl copper reagents (1983) (0)
- SPIROANNELATION VIA GEM‐DIHALOCYCLOPROPANE SUBSTRATES AND A CYCLOCUPRATE SPECIES (1984) (0)
- Asymmetric Conjugate Addition-Bromination of α,β-Unsaturated Ketones (2005) (0)
- Novel Biphenol Phosphoramidite Ligands for the Enantioselective Copper‐Catalyzed Conjugated Addition of Dialkyl Zincs. (2002) (0)
- A New Reagent for a Very Simple and Efficient Determination of Enantiomeric Purity of Alcohols by 31P NMR. (1990) (0)
- Boron Trifluoride Assisted Opening of Epoxides by Lithium Alkenyl Aluminate Reagents. (1990) (0)
- Copper‐Catalyzed Asymmetric Conjugate Addition to Challenging Michael Acceptors and Synthesis of Relevant Target Molecules (2012) (0)
- Copper-Catalyzed Addition of Diethylzinc to Boc-ProtectedImines (2008) (0)
- Stereochemical Effects of Trimethylsilyl Chloride (TMSCl) on the Conjugate Addition of Organocopper Reagents. (1990) (0)
- Regio and Enantioselective Synthesis of 4‐Carbomethoxymethyl‐1,4‐ dihydropyridines. (1994) (0)
- A Highly Efficient Synthesis of Z‐γ‐Iodo Allylic Alcohols. (1992) (0)
- VINYLIC ORGANOCOPPER COMPOUNDS. VIII. STUDY OF THE REGIOSELECTIVITY OF THE ADDITION OF ORGANOCOPPER DERIVATIVES TO HETEROSUBSTITUTED ALKYNES. USE OF THE FORMED VINYLIC ORGANOCOPPER COMPLEXES IN SYNTHESIS (1978) (0)
- Conjugate Addition to α-Halo Enones (2007) (0)
- Chiral Aminal Templates. Part 5. Preparation of Chiral 1,4‐ Dihydropyridine‐3‐carboxaldehydes. (1991) (0)
- Diastereoselective Conjugate Addition with Acetals, Oxazolidines, and Imidazolidines as Chiral Auxiliaries. (1989) (0)
- Chiral Diamines for a New Protocol to Determine the Enantiomeric Composition of Alcohols, Thiols, and Amines by 31P, 1H, 13C, and 19F NMR. (1994) (0)
- A Completely Stereoselective Intramolecular Diels-Alder Reaction in the Substituted Cyclohexanol Series. (1990) (0)
- Copper‐Catalyzed Propargylic Substitution of Dichloro Substrates: Enantioselective Synthesis of Trisubstituted Allenes and Formation of Propargylic Quaternary Stereogenic Centers. (2015) (0)
- Copper‐Catalyzed Enantioselective Synthesis of Axially Chiral Allenes. (2013) (0)
- Chiral NHC Ligands for the Copper-Catalyzed Asymmetric Conjugate Addition of Grignard Reagents. (2013) (0)
- Preparation of Chiral Hexahydroquinolizinones and Tetrahydroindolizinones by Regio‐ and Diastereoselective Sonochemical Cyclization of Chiral Dihydropyridines. (1996) (0)
- REACTIVITY OF RCU,BF3 AND R2CULI,BF3 TOWARD THE ETHER LINKAGE. EPOXIDES, ACETALS AND ORTHOFORMATES (1984) (0)
- Alkenylcopper derivatives 27. Synthesis of alkenyl thioethers by alkenyl copper cleavage of disulfides (1985) (0)
- Diastereoselective Conjugate Addition to Chiral α,β-Ethylenic Acetals. (1986) (0)
- DIRECT HALOGEN SUBSTITUTION OF 1,2-HALOHYDRINS BY ORGANOMAGNESIUMS AND -LITHIUMS IN PRESENCE OF COPPER SALT (1979) (0)
- STUDY OF A MODEL OF ASYMMETRIC INDUCTIONS α,β-UNSATURATED OXAZOLIDINES PREPARED FROM EPHEDRINE (1984) (0)
- True Nature of Ligands in Cu-Catalyzed Reactions with Al(alkyl)3 (2006) (0)
- Unusually Facile Palladium-Catalyzed Oxidation of Imidazolidines and Oxazolidines. (2001) (0)
- Asymmetric Synthesis with N‐Heterocyclic Carbenes. Application to the Copper‐Catalyzed Conjugate Addition. (2003) (0)
- New P-Chiral Polyfluoroalkyl Phosphorodiamidite Ligand in Asymmetric Transformations Catalyzed by Palladium and Copper Complexes. (2009) (0)
- The Use of N-isopropyl-2,2′-bipyrrolidine Derivatives as Organic Catalysts for Asymmetric Michael Additions (2007) (0)
- - and ?-disubstituted olefins for copper-catalyzed asymmetric allylic substitution (2004) (0)
- Reactivity of Allylzinc (and -copper) Reagents Towards Allenic Ethers and α-Metalated Ethers. (1991) (0)
- γ-Tributylstannyl β-Metallated Acrolein: A Versatile Synthon. (1992) (0)
- Improved Optical Resolution of (R*,R*)-N,N′-Dimethyl-1,2-diphenylethylenediamine. (1988) (0)
- Cu-Catalyzed Asymmetric S N 2' Reaction on-Disubstituted Allylic Chlorides (2006) (0)
- Unusual 1,2-Migration in Organoaluminum Chemistry, Promoted by BF3·OEt2. (1990) (0)
- Catalytic Enantioselective Deprotonation of meso-Epoxides Utilizing Homochiral Bis-lithium Amide Bases. (1997) (0)
- Ultrasound-Assisted Cleavage of N-N Bonds in Hydrazines by Raney Nickel. (2010) (0)
- Cu-Catalyzed Highly Enantioselective 1,4-Additionof Grignard Reagents (2011) (0)
- Some Aspects of the Reactivity of RCu/Boron Trifluoride Reagents Towards the Ether Linkage (1989) (0)
- Diastereoselective Alkylation of (Arene)tricarbonylchromium and Ferrocene Complexes Using a Chiral, C2‐Symmetrical 1,2‐Diamine as Auxiliary. (2005) (0)
- Copper-Catalyzed Kinetic Resolution of Cyclic Alkenyl Cyclopropane Malonates with Organoaluminum and Grignard Reagents. (2010) (0)
- Synthesis and Use of 3,3′-Bimorpholine Derivatives in Asymmetric Michael Addition and Intramolecular Aldol Reaction. (2007) (0)
- Asymmetric Conjugate Addition of Diethyl Zinc to Enones with Tartrate Chiral Phosphite Ligands. (1998) (0)
- Copper‐Catalyzed Asymmetric Conjugate Addition of Trialkylaluminum Reagents to Trisubstituted Enones: Construction of Chiral Quaternary Centers. (2008) (0)
- Enantioselective Nucleophilic Opening of meso Epoxides by Organolithium Reagents. (1999) (0)
- Copper‐Catalyzed Ring Opening of Polycyclic meso‐Hydrazines with Trialkylaluminum Reagents and SimplePhos Ligands. (2010) (0)
- Asymmetric Cleavage of Chiral α,β‐Ethylenic Acetals by Organolithium Reagents. (1997) (0)
- Asymmetric Bromine—Lithium Exchange: Application Toward the Synthesis of New Biaryl‐Diphosphine Ligands. (2016) (0)
- Enantioselective 1,6-Conjugate Addition to Cyclic Dienones Catalyzed by the Cu—DiPPAM Complex. (2011) (0)
- Boron Fluoride Promoted Opening of Epoxides by Organocopper and Cuprate Reagents. (1987) (0)
- Tandem Enantioselective Conjugate Addition—Cyclopropanation. Application to Natural Products Synthesis. (2003) (0)
- Carbocupration: A Potent Tool for the Synthesis of Insect Sex Attractants (1987) (0)
- Enantioselective Copper-Catalyzed Conjugated Addition and Allylic Substitution Reactions (2008) (0)
- A NEW SYNTHETIC APPROACH TO PSEUDOGUAIANES (1979) (0)
- Asymmetric Conjugate Addition of Grignard Reagents to Enones (2006) (0)
- VINYLCOPPER DERIVATIVES; X. ALKYLATION OF (Z)‐DIALKENYLCUPRATES (1980) (0)
- REACTION OF ORGANOLITHIUMS AND ORGANOMAGNESIUMS WITH PROPIOLACTONE IN THE PRESENCE OF COPPER SALTS. SYNTHESIS OF CARBOXYLIC ACIDS (1980) (0)
- Stereoselective Synthesis of all four Stereoisomers of 8,10-Dodecadien-1-yl Acetate (1991) (0)
- First Diastereoselective Asymmetric Carbometallation of Chiral Vinyl Metals. (1998) (0)
- Highly Diastereo‐ and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3‐Halogeno‐1,2‐diones to α,β‐Unsaturated Aldehydes. (2013) (0)
- Enantioselective Opening of Cyclic Vinyl Epoxides with Organoaluminum Reagents Catalyzed by Copper Salts. (2004) (0)
- SimplePhos Monodentate Ligands: Synthesis and Application in Copper‐Catalyzed Reactions. (2008) (0)
- A New Approach to Conjugated Dienes. Synthesis of the Pheromones of Lobesia botrana and Bombyx mori. (1989) (0)
- Formation of Quaternary Stereogenic Centers by NHC—Cu‐Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic Enones. (2012) (0)
- Diastereoselective β-Elimination. Synthesis of Chiral Alkoxy-allenes. (1986) (0)
- Asymmetric Synthesis of 1,2- and 1,4-Dihydroquinolines. (1999) (0)
- Enantioselective One‐Pot Organocatalytic Michael Addition/Gold‐Catalyzed Tandem Acetalization/Cyclization. (2010) (0)
- Enantioselective Copper‐Catalyzed Conjugate Addition of Trimethylaluminum to β,γ‐Unsaturated α‐Ketoesters. (2012) (0)
- One‐Pot Asymmetric Conjugate Addition—Trapping of Zinc Enolates by Activated Electrophiles. (2006) (0)
- Copper‐Free Asymmetric Allylic Alkylation of Trisubstituted Cyclic Allyl Bromides Using Grignard Reagents. (2014) (0)
- Copper‐Free Asymmetric Allylic Alkylation Using Grignard Reagents on Bifunctional Allylic Bromides. (2012) (0)
- Synthesis and Reactivity of Chiral Alkoxyallenes Prepared by Carbocupration of Propargylic Acetals. (1993) (0)
- Copper-Catalyzed Conjugate Addition to 2- or 3-Substituted Cylcopent-2-en-1-ones (2007) (0)
- Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene—Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones. (2011) (0)
- ALKENYLCOPPER DERIVATIVES; 21. SYNTHESIS OF ALLYLIC AMIDES AND AMINES BY AMIDOMETHYLATION OF ALKENYLCOPPER AND -CUPRATE REAGENTS (1984) (0)
- A Practical and Efficient Synthesis of Chiral N,N-Disubstituted C2 Symmetric Diamines Derived from (R,R)-1,2-Diaminocyclohexane. (2001) (0)
- Untitled Document (2001) (0)
- Copper-Catalyzed Asymmetric Allylic Substitution (2007) (0)
- Boron Fluoride Promoted Cleavage of Acetals by Organocopper Reagents. Application to Asymmetric Synthesis. (1989) (0)
- ChemInform Abstract: Dramatic Improvement of the Enantiomeric Excess in the Asymmetric Conjugate Addition Reaction Using New Experimental Conditions. (2002) (0)
- VINYL ORGANOCOPPER COMPOUNDS. IX. ADDITION OF ORGANIC COPPER DERIVATIVES TO ACETYLENE (1980) (0)
- Reactivity of organomanganese derivatives. VIII. Preparation of ketones by acylation of organomanganese compounds. Effect of acylating agent, solvents, and ligands (1984) (0)
- Conjugate Addition of Organocuprates to γ-Methyl-δ-oxy-. alpha.,β-enones. Influence of the Alkoxy Substituent on the Diastereoselection. (1992) (0)
- Kinetic Resolution of 1,3-Cyclohexadiene Epoxide with Grignards (2007) (0)
- Asymmetric Michael Addition of α‐Hydroxyketones to Nitroolefins Catalyzed by Chiral Diamine. (2003) (0)
- VINYL ORGANOCOPPER DERIVATIVES. 14. ARYLATION OF VINYL CUPRATES (1982) (0)
- Asymmetric Conjugate Addition of Metal Alkyl Reagents Catalyzed by Copper Complexes with BINPO: A Hemilabile P,O‐Heterobidentate Axially Chiral Ligand. (2006) (0)
- Expeditious Synthesis of the Four Isomers of Methyl Dimorphecolate (I). (1992) (0)
- Asymmetric Conjugate Addition of Diethyl Zinc to Enones with Chiral Phosphine Ligands. (1998) (0)
- Acceleration of the Conjugate Addition of Diethyl Zinc to Enones by Either Cu(OTf)2 or Trivalent Phosphorus Ligands. (2010) (0)
- Addition of Trialkylaluminium Regents to Extended MichaelAcceptors (2010) (0)
- Enantioselective Organocatalytic Iodination-Initiated Wagner—Meerwein Rearrangement. (2014) (0)
- Asymmetric Conjugate Addition to α‐Substituted Enones/Enolate Trapping. (2014) (0)
- TADDOL Organophosphorus Derivatizing Agents for the Determination of the Enantiomeric Excess of Chiral Alcohols and Carboxylic Acids by 31P and 1H NMR Spectroscopy. (2001) (0)
- Copper‐Catalyzed Asymmetric Conjugate Addition of Alkenyl‐ and Alkylalanes to α,β‐Unsaturated Lactams. (2013) (0)
- Synthesis and Application of a New Pseudo C2‐Symmetric Tertiary Diamine for the Enantioselective Addition of MeLi to Aromatic Imines. (2008) (0)
- Allylic Organobismetallic Reagents. Part 1. (1990) (0)
- Copper-Catalyzed Enantioselective Allylic Substitution by MeMgX. (2005) (0)
- VINYLIC ORGANOCOPPER DERIVATIVES. VII. ADDITION OF ACETYLENE ON LITHIUM CUPRATES. SYNTHESIS OF HOMO- AND HETERO Z-VINYLCUPRATES (1976) (0)
- ALKENYL COPPER DERIVATIVES. 25: SYNTHESIS OF E OR Z ENOL ETHERS BY CARBOCUPRATION OF ALKOXYALLENES (1984) (0)
- Conceptually New Chiral Tertiary C2 Symmetric Diamines in Asymmetric Synthesis. (2004) (0)
- Chiral Aminal Templates. Part 3. Diastereoselectivity of Organometallic Attack on Aldehydes Bearing a Chiral Imidazolidine Group. (1990) (0)
- Improvements and Applications of the Transition Metal-Free Asymmetric Allylic Alkylation Using Grignard Reagents and Magnesium Alanates. (2016) (0)
- Chiral Aminal Templates. Part 6. Diastereoselectivity of Hydrazone Alkylation. Asymmetric Synthesis of α‐Amino Aldehydes. (1991) (0)
- Enantioselective 1,6-Conjugate Addition of Dialkylzinc Reagents to Acyclic Dienones Catalyzed by Cu-DiPPAM Complex—Extension to Asymmetric Sequential 1,6/1,4-Conjugate Addition. (2014) (0)
- Enantioselective Copper-Catalyzed Conjugate Addition Using Chiral Diaminocarbene Ligands. (2002) (0)
- Asymmetric allylic alkylation catalysed by iridium (2007) (0)
- REACTIVITY OF RCU,BF3 AND R2CULI,BF3 TOWARD ALLYLIC ACETALS AND ETHERS (1984) (0)
- VINYL COPPER REAGENTS. 16. SYNTHESIS OF CONJUGATED DIENES VIA THE ADDITION OF F VINYL CUPRATES TO ACETYLENE (1983) (0)
- A New Pseudo C2‐Symmetric Tertiary Diamine for the Enantioselective Addition of MeLi to Aromatic Imines. (2006) (0)
- REACTIVITY OF ORGANOMANGANESE DERIVATIVES. VI. CARBONATION (1980) (0)
- Copper-Catalyzed Asymmetric Addition of Diethylzinc to Boc-Protected Imines. (2009) (0)
- Fine-Tunable Monodentate Phosphoramidite and Aminophosphine Ligands for Rh-Catalyzed Asymmetric Hydroformylation. (2011) (0)
- Enantioselective and Regiodivergent Copper-Catalyzed Conjugate Addition Trialkylaluminum Reagents to Extended Nitro-Michael Acceptors. (2010) (0)
- Organocatalyzed Conjugate Addition of Carbonyl Compounds to Nitrodienes/Nitroenynes and Synthetic Applications. (2010) (0)
- ALKENYLCOPPER DERIVATIVES; 27. SYNTHESIS OF 1-ALKENYL THIOETHERS BY CLEAVAGE OF DISULFIDES WITH 1-ALKENYLCOPPER REAGENTS (1985) (0)
- Enyne Chlorides: Substrates for Copper‐Catalyzed Asymmetric Allylic Alkylation. (2012) (0)
- Domino Asymmetric Conjugate Addition—Conjugate Addition. (2014) (0)
- New Bifunctional Substrates for Copper-Catalyzed Asymmetric Conjugate Addition Reactions with Trialkylaluminium. (2010) (0)
- Chiral Amines as Organocatalysts for Asymmetric Conjugate Addition to Nitroolefins and Vinyl Sulfones via Enamine Activation (2007) (0)
- Conjugate Addition of Aryl Alanes to Form Quaternary Stereocenters (2010) (0)
- One-Pot Iridium and Enamine Catalysis (2011) (0)
- N‐Heterocyclic Carbene Catalyzed Annulation of α‐Cyano‐1,4‐diketones with Ynals. (2013) (0)
- SimplePhos Monodentate Ligands: Synthesis and Applications (2008) (0)
- Cu‐Catalyzed Asymmetric 1,4‐Addition of Me3Al to Nitroalkenes. Synthesis of (+)‐Ibuprofen. (2005) (0)
- The Hydroalumination of ω-tert-Butoxyalkynes: An Easy Access to ω-Hydroxyalkenyl Iodides. Application to the Synthesis of Dienic Insect Pheromones. (1989) (0)
- Enantioselective Copper‐Catalyzed Conjugate Addition of Dialkyl Zinc to Nitro‐Olefins. (2000) (0)
- A copper (II) complex of a new chiral tridentate imidazoline ligand (1997) (0)
- A New Efficient and Stereoselective Synthesis of 1,3E,5Z‐Undecatriene. (1992) (0)
- Synthesis and Use of a Phosphoramidite Ligand for the Copper-Catalyzed Enantioselective Allylic Substitution. Tandem Allylic Substitution/Ring- (2004) (0)
- Construction of Aryl-Substituted Quaternary Centers by ConjugateAddition (2009) (0)
- Synthesis and Applications of Chiral Bis‐THF in Asymmetric Synthesis. (2005) (0)
- Conjugate Addition and Subsequent Enolate Trapping with Electrophiles (2006) (0)
- Copper-Catalyzed Desymmetrization of Oxabenzonorbornadienes with Aluminum Reagents. (2009) (0)
- Dienic Sulfones as Efficient 1,6-Acceptors in the Additionof Aldehydes (2011) (0)
- Preparation and Utilization of Chiral Dihydropyridines. Synthesis of Chiral Indoloquinolizines and Benzoquinolizines. (1994) (0)
- Alkenyl copper derivatives 28. Stereospecific synthesis of tertiary allylic amines of (E) or (Z) configuration (1984) (0)
- Phosphoramidite Ligands in Iridium‐Catalyzed Allylic Substitution (2006) (0)
- ALKENYLCOPPER DERIVATIVES; 22. STEREOSELECTIVE SYNTHESIS OF ALLYLIC THIOETHERS (1984) (0)
- Regioselective SN2 Opening of Vinylic Epoxides with Trialkylzincates and Trialkylaluminates. (2004) (0)
- Copper-Catalyzed Asymmetric Conjugate Addition with Grignard Reagents and SimplePhos Ligands. (2010) (0)
- Preface (2006) (0)
- COMPARISON BETWEEN THE ADDITION REACTION OF ORGANOCOPPER, ORGANOCUPRATE REAGENTS AND ORGANOMAGNESIUM COMPOUNDS IN THE PRESENCE OF A CATALYTIC AMOUNT OF COPPER(I) SALT TO PROPARGYLIC ALCOHOL (1977) (0)
- Acetals as Chiral Auxiliaries. Part 4. Asymmetric Synthesis of γ,δ-Ethylenic Aldehydes. An Approach to the California Red Scale Pheromone. (1987) (0)
- Enantioenriched Cyclic Compounds by Allylic Alkylation and Metathesis (2014) (0)
- Metal‐Catalyzed Asymmetric Conjugate Addition Reaction: Formation of Quaternary Stereocenters (2011) (0)
- Transition Metal‐Free Asymmetric and Diastereoselective Allylic Alkylation Using Grignard Reagents: Construction of Vicinal Stereogenic Centers via Kinetic Resolution. (2015) (0)
- Formation of all-carbon chiral quaternary centers by copper catalysed asymmetric cojugate addition (2007) (0)
- β‐ and γ‐Disubstituted Olefins: Substrates for Copper‐Catalyzed Asymmetric Allylic Substitution. (2008) (0)
- Effect of BF3×Et2O Reagent on the Base-Promoted Rearrangements of Epoxides Attached to Eight-Membered Rings. (2001) (0)
- Titanium Induced Coupling of Imines to Symmetrical Vicinal (R*,R*)-Diamines. (1988) (0)
- A NEW APPROACH TO THE BICYCLO(3.2.1)OCTANE RING SYSTEM: INTRAMOLECULAR MICHAEL AND ALDOL REACTIONS OF 3-(5-OXOHEXYL)-2-CYCLOPENTENONES (1979) (0)
- Radical Cyclizations of 1,4‐Dihydropyridines. Synthesis of Chiral Fused Nitrogen Heterocycles. Synthesis of Lupinine and Epilupinine. (1998) (0)
- Chiral Cycloalkenes by an Asymmetric Allylic Alkylation-RCMProcedure (2010) (0)
- Palladium Mediated Synthesis of Conjugated E or Z Enones and Unsymmetrical Di- vinyl Ketones. (1986) (0)
- Practical and Efficient Synthesis of C2 Symmetrical Diamines with Zn/Me3SiCl. (1998) (0)
- Chiral Diamines in Asymmetric Synthesis (2010) (0)
- Michael Addition Catalyzed by a Chiral Bimorpholine (2006) (0)
- Epimerization and Kinetic Resolution in Copper‐Catalyzed Enantioselective 1,4‐Additions of Organozinc Reagents to 6‐Substituted Cyclohex‐2‐enones. (2003) (0)
- Construction of Enantioenriched Cyclic Compounds by Asymmetric Allylic Alkylation and Ring-Closing Metathesis. (2014) (0)
- Enantioselective Michael Addition-Cyclization Reaction (2007) (0)
- 1,4- versus 1,6-Selective Asymmetric Copper-Catalyzed ConjugateAddition (2009) (0)
- Effect of the Double Bond Geometry on the Enantioselectivity of ACA (2008) (0)
- Enantioselective ortho-Lithiation of Benzaldehyde Chromiumtricarbonyl Complex. (1996) (0)
- Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of α-Allenic Alcohols. (1991) (0)
- Regioselective SN2 opening of a,-ethylenic epoxides by RLiBF3 combination (2001) (0)
- Enantioselective Addition of Aryllithium Reagents to Aromatic Imines Mediated by 1,2-Diamine Ligands. (2004) (0)
- Cover Picture: Eur. J. Org. Chem. 19/2002 (2002) (0)
- Chiral Aminal Templates. Part 4. Chiral Aryl Metallic Reagents: Reactions with Aldehydes. (1990) (0)
- 3,3′‐Bimorpholine Derivatives as a New Class of Organocatalysts for Asymmetric Michael Addition. (2006) (0)
- Asymmetric Conjugate Addition of Diethyl Zinc to Enones with Chiral Phosphorus Ligands Derived from TADDOL. (2010) (0)
- Furanoside Phosphite—Phosphoroamidite and Diphosphoroamidite Ligands Applied to Asymmetric Cu-Catalyzed Allylic Substitution Reactions. (2012) (0)
- Copper-Catalyzed Kinetic Resolution of 1,3-Cyclohexadiene Monoepoxide with Grignard Reagents. (2007) (0)
- VINYLCOPPER DERIVATIVES. 15. AN EFFICIENT SYNTHESIS OF POLYSUBSTITUTED CONJUGATED DIENES (1982) (0)
- Enantioselective Copper‐Catalyzed Conjugate Addition of Trimethylaluminum to β,γ‐Unsaturated α‐Ketoamides: Efficient Access to γ‐Methyl‐Substituted Carbonyl Compounds. (2014) (0)
- Combining Gold- and Organocatalysis (2010) (0)
- Asymmetric Conjugate Addition to Alkylidene Malonates. (2001) (0)
- Copper-Catalyzed 1,6-Conjugate Addition to Cyclic Dienones (2011) (0)
- Enantioselective Conjugate Addition of Aldehydes to Vinyl Phosphonates (2007) (0)
- Enantioselective Addition of Organolithium Reagents to Quinoline Catalyzed by 1,2‐Diamines. (2005) (0)
- Highly Enantioselective Copper(I)‐Phosphoramidite‐Catalyzed Additions of Organoaluminum Reagents to Enones. (2005) (0)
- Enantioselective Synthesis of Indoloquinolizidines. (1992) (0)
- Diversity‐Oriented Synthesis Towards Conceptually New Highly Modular Aminal—Pyrrolidine Organocatalysts. (2009) (0)
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