Amir H. Hoveyda
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American chemist
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Amir H. Hoveydachemistry Degrees
Chemistry
#153
World Rank
#340
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#81
USA Rank
Organic Chemistry
#30
World Rank
#45
Historical Rank
#17
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Chemistry
Why Is Amir H. Hoveyda Influential?
(Suggest an Edit or Addition)According to Wikipedia, Amir H. Hoveyda is an American organic chemist and professor of chemistry at Boston College, and held the position of department chair until 2018. In 2019, he embarked as researcher at the Institute of Science and Supramolecular Engineering at University of Strasbourg.
Amir H. Hoveyda's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts (2000) (1460)
- Substrate-directable chemical reactions (1993) (991)
- Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts. (2003) (878)
- The remarkable metal-catalysed olefin metathesis reaction (2007) (725)
- A Recyclable Ru-Based Metathesis Catalyst (1999) (664)
- Catalytic Z-selective olefin cross-metathesis for natural product synthesis (2011) (290)
- Samarium-catalyzed intramolecular Tishchenko reduction of .beta.-hydroxy ketones. A stereoselective approach to the synthesis of differentiated anti 1,3-diol monoesters (1990) (287)
- A recyclable chiral Ru catalyst for enantioselective olefin metathesis. Efficient catalytic asymmetric ring-opening/cross metathesis in air. (2002) (283)
- A readily available chiral Ag-based N-heterocyclic carbene complex for use in efficient and highly enantioselective Ru-catalyzed olefin metathesis and Cu-catalyzed allylic alkylation reactions. (2005) (272)
- Efficient boron-copper additions to aryl-substituted alkenes promoted by NHC-based catalysts. enantioselective Cu-catalyzed hydroboration reactions. (2009) (253)
- Ru complexes bearing bidentate carbenes: from innocent curiosity to uniquely effective catalysts for olefin metathesis. (2004) (241)
- Efficient C-B bond formation promoted by N-heterocyclic carbenes: synthesis of tertiary and quaternary B-substituted carbons through metal-free catalytic boron conjugate additions to cyclic and acyclic alpha,beta-unsaturated carbonyls. (2009) (240)
- Highly selective methods for synthesis of internal (α-) vinylboronates through efficient NHC-Cu-catalyzed hydroboration of terminal alkynes. Utility in chemical synthesis and mechanistic basis for selectivity. (2011) (229)
- Enantioselective conjugate silyl additions to cyclic and acyclic unsaturated carbonyls catalyzed by Cu complexes of chiral N-heterocyclic carbenes. (2010) (213)
- Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis (2008) (210)
- Enantioselective synthesis of boron-substituted quaternary carbons by NHC-Cu-catalyzed boronate conjugate additions to unsaturated carboxylic esters, ketones, or thioesters. (2010) (209)
- Catalytic asymmetric olefin metathesis. (2001) (208)
- Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex. (2009) (190)
- Discovery of Chiral Catalysts through Ligand Diversity: Ti‐Catalyzed Enantioselective Addition of TMSCN to meso Epoxides (1996) (187)
- Rhodium(I)- and iridium(I)-catalyzed hydroboration reactions: scope and synthetic applications (1992) (187)
- NHC-Cu-catalyzed enantioselective hydroboration of acyclic and exocyclic 1,1-disubstituted aryl alkenes. (2011) (184)
- Chiral Ru-based complexes for asymmetric olefin metathesis: enhancement of catalyst activity through steric and electronic modifications. (2003) (183)
- Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis (2011) (178)
- Bidentate NHC-based chiral ligands for efficient Cu-catalyzed enantioselective allylic alkylations: structure and activity of an air-stable chiral Cu complex. (2004) (176)
- Modular peptide-based phosphine ligands in asymmetric catalysis: efficient and enantioselective Cu-catalyzed conjugate additions to five-, six-, and seven-membered cyclic enones. (2001) (171)
- Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes. (2009) (171)
- Vicinal diboronates in high enantiomeric purity through tandem site-selective NHC-Cu-catalyzed boron-copper additions to terminal alkynes. (2009) (170)
- All-carbon quaternary stereogenic centers by enantioselective cu-catalyzed conjugate additions promoted by a chiral N-heterocyclic carbene. (2007) (168)
- A practical method for enantioselective synthesis of all-carbon quaternary stereogenic centers through NHC-Cu-catalyzed conjugate additions of alkyl- and arylzinc reagents to beta-substituted cyclic enones. (2006) (166)
- Enantioselective synthesis of allylboronates bearing a tertiary or quaternary B-substituted stereogenic carbon by NHC-Cu-catalyzed substitution reactions. (2010) (165)
- Highly Z-selective metathesis homocoupling of terminal olefins. (2009) (164)
- Simple Organic Molecules as Catalysts for Enantioselective Synthesis of Amines and Alcohols (2012) (162)
- Enantioselective silyl protection of alcohols catalysed by an amino-acid-based small molecule (2006) (161)
- Metal-free catalytic enantioselective C-B bond formation: (pinacolato)boron conjugate additions to α,β-unsaturated ketones, esters, Weinreb amides, and aldehydes promoted by chiral N-heterocyclic carbenes. (2012) (158)
- Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids (1999) (156)
- Highly site- and enantioselective Cu-catalyzed allylic alkylation reactions with easily accessible vinylaluminum reagents. (2008) (154)
- Readily accessible and easily modifiable Ru-based catalysts for efficient and Z-selective ring-opening metathesis polymerization and ring-opening/cross-metathesis. (2013) (154)
- Catalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and more. (2010) (150)
- Alpha-selective Ni-catalyzed hydroalumination of aryl- and alkyl-substituted terminal alkynes: practical syntheses of internal vinyl aluminums, halides, or boronates. (2010) (146)
- Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen−Mo Complex (1998) (146)
- Cu-catalyzed chemoselective preparation of 2-(pinacolato)boron-substituted allylcopper complexes and their in situ site-, diastereo-, and enantioselective additions to aldehydes and ketones. (2013) (144)
- Evolution of Catalytic Stereoselective Olefin Metathesis: From Ancillary Transformation to Purveyor of Stereochemical Identity (2014) (144)
- Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex (2014) (143)
- Rhodium(I)-catalyzed hydroboration of olefins. The documentation of regio- and stereochemical control in cyclic and acyclic systems (1988) (143)
- Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta-substituted cyclic enones. (2008) (142)
- Multifunctional organoboron compounds for scalable natural product synthesis (2014) (142)
- Ag-catalyzed asymmetric mannich reactions of enol ethers with aryl, alkyl, alkenyl, and alkynyl imines. (2004) (141)
- Catalytic asymmetric alkylations of ketoimines. Enantioselective synthesis of N-substituted quaternary carbon stereogenic centers by Zr-catalyzed additions of dialkylzinc reagents to aryl-, alkyl-, and trifluoroalkyl-substituted ketoimines. (2008) (140)
- Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution. (2012) (138)
- Ag-catalyzed diastereo- and enantioselective vinylogous Mannich reactions of alpha-ketoimine esters. Development of a method and investigation of its mechanism. (2009) (133)
- Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to acyclic aliphatic enones. (2002) (133)
- High-value alcohols and higher-oxidation-state compounds by catalytic Z-selective cross-metathesis (2015) (132)
- Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. (2009) (132)
- Enantioselective synthesis of allylsilanes bearing tertiary and quaternary Si-substituted carbons through Cu-catalyzed allylic alkylations with alkylzinc and arylzinc reagents. (2007) (131)
- Synthesis of quaternary carbon stereogenic centers through enantioselective Cu-catalyzed allylic substitutions with vinylaluminum reagents. (2010) (130)
- Total synthesis of anti-HIV agent chloropeptin I. (2003) (125)
- Zr-Catalyzed Kinetic Resolution of Allylic Ethers and Mo-Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)-Nebivolol (1998) (124)
- Enantioselective CC and CH Bond Formation Mediated or Catalyzed by Chiral ebthi Complexes of Titanium and Zirconium (1996) (124)
- Chiral N-heterocyclic carbenes in natural product synthesis: application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C. (2007) (123)
- Metal-free catalytic C-Si bond formation in an aqueous medium. Enantioselective NHC-catalyzed silyl conjugate additions to cyclic and acyclic α,β-unsaturated carbonyls. (2011) (122)
- Small peptides as ligands for catalytic asymmetric alkylations of olefins. Rational design of catalysts or of searches that lead to them? (2004) (121)
- Three-component catalytic asymmetric synthesis of aliphatic amines. (2001) (118)
- Chromenes through Metal-Catalyzed Reactions of Styrenyl Ethers. Mechanism and Utility in Synthesis (1998) (118)
- Enantioselective synthesis of propargylamines through Zr-catalyzed addition of mixed alkynylzinc reagents to arylimines. (2003) (116)
- Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper-Catalyzed Allylic Substitutions. (2001) (115)
- Immobilization of Olefin Metathesis Catalysts on Monolithic Sol-Gel: Practical, Efficient, and Easily Recyclable Catalysts for Organic and Combinatorial Synthesis. (2001) (113)
- Stereoisomerically pure trisubstituted vinylaluminum reagents and their utility in copper-catalyzed enantioselective synthesis of 1,4-dienes containing Z or E alkenes. (2010) (111)
- Three-component enantioselective synthesis of propargylamines through Zr-catalyzed additions of alkyl zinc reagents to alkynylimines. (2003) (110)
- Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis (2016) (109)
- Stereogenic-at-metal Zn- and Al-based N-heterocyclic carbene (NHC) complexes as bifunctional catalysts in Cu-free enantioselective allylic alkylations. (2009) (109)
- Exceptionally E- and β-selective NHC-Cu-catalyzed proto-silyl additions to terminal alkynes and site- and enantioselective proto-boryl additions to the resulting vinylsilanes: synthesis of enantiomerically enriched vicinal and geminal borosilanes. (2013) (108)
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization through Ring-Closing Metathesis (1998) (108)
- Catalytic enantioselective alkylations of tetrasubstituted olefins. Synthesis of all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to enones. (2005) (108)
- Enantioselective synthesis of alkyne-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed allylic substitution reactions with (i-Bu)2(alkynyl)aluminum reagents. (2011) (107)
- Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to β-substituted cyclic enones. (2011) (107)
- Enantioselective synthesis of nitroalkanes bearing all-carbon quaternary stereogenic centers through Cu-catalyzed asymmetric conjugate additions. (2005) (106)
- Cascade Catalysis in Synthesis. An Enantioselective Route to Sch 38516 (and Fluvirucin B1) Aglycon Macrolactam (1995) (103)
- Enantioselective total synthesis of clavirolide C. Applications of Cu-catalyzed asymmetric conjugate additions and Ru-catalyzed ring-closing metathesis. (2008) (102)
- Highly enantioselective Cu-catalyzed conjugate additions of dialkylzinc reagents to unsaturated furanones and pyranones: preparation of air-stable and catalytically active Cu-peptide complexes. (2005) (102)
- Three-component Ag-catalyzed enantioselective vinylogous mannich and Aza-Diels-Alder reactions with alkyl-substituted aldehydes. (2008) (102)
- Kinetic resolution of 1,2-diols through highly site- and enantioselective catalytic silylation. (2007) (102)
- CHIRAL MO-BINOL COMPLEXES : ACTIVITY, SYNTHESIS, AND STRUCTURE. EFFICIENT ENANTIOSELECTIVE SIX-MEMBERED RING SYNTHESIS THROUGH CATALYTIC METATHESIS (1999) (101)
- Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum. (2009) (101)
- A highly efficient and practical method for catalytic asymmetric vinylogous Mannich (AVM) reactions. (2006) (100)
- Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes. (2011) (100)
- Aluminum-catalyzed asymmetric addition of TMSCN to aromatic and aliphatic ketones promoted by an easily accessible and recyclable peptide ligand. (2002) (99)
- Directed catalytic asymmetric olefin metathesis. Selectivity control by enoate and ynoate groups in Ru-catalyzed asymmetric ring-opening/cross-metathesis. (2007) (98)
- Efficient enantioselective synthesis of functionalized tetrahydropyrans by Ru-catalyzed asymmetric ring-opening metathesis/cross-metathesis (AROM/CM). (2004) (98)
- Enantioselective total synthesis of erogorgiaene: applications of asymmetric Cu-catalyzed conjugate additions of alkylzincs to acyclic enones. (2004) (98)
- Cu-catalyzed asymmetric allylic alkylations of aromatic and aliphatic phosphates with alkylzinc reagents. An effective method for enantioselective synthesis of tertiary and quaternary carbons. (2004) (98)
- Enantioselective Synthesis of Trisubstituted Allenyl-B(pin) Compounds by Phosphine-Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu-Allenyl Intermediates. (2018) (97)
- Mechanism of enantioselective Ti-catalyzed Strecker reaction: peptide-based metal complexes as bifunctional catalysts. (2001) (96)
- High‐Throughput Strategies for the Discovery of Catalysts (1998) (95)
- Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A. (2013) (94)
- SEARCH FOR CHIRAL CATALYSTS THROUGH LIGAND DIVERSITY : SUBSTRATE-SPECIFIC CATALYSTS AND LIGAND SCREENING ON SOLID PHASE (1997) (93)
- Enantioselective synthesis of arylamines through Zr-catalyzed addition of dialkylzincs to imines. Reaction development by screening of parallel libraries. (2001) (93)
- Quaternary carbon stereogenic centers through copper-catalyzed enantioselective allylic substitutions with readily accessible aryl- or heteroaryllithium reagents and aluminum chlorides. (2010) (92)
- Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis. (2013) (92)
- Molybdenum chloride catalysts for Z-selective olefin metathesis reactions (2017) (91)
- Efficient and practical Ag-catalyzed cycloadditions between arylimines and the Danishefsky diene. (2003) (91)
- Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups (2016) (90)
- Enantioselective synthesis of homoallylic amines through reactions of (pinacolato)allylborons with aryl-, heteroaryl-, alkyl-, or alkene-substituted aldimines catalyzed by chiral C1-symmetric NHC-Cu complexes. (2011) (90)
- A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis. (2001) (87)
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Ring-Closing Metathesis (2000) (87)
- Catalytic diastereo- and enantioselective additions of versatile allyl groups to N-H ketimines. (2017) (87)
- Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes. (2005) (86)
- Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1) (1997) (85)
- H-bonding as a control element in stereoselective Ru-catalyzed olefin metathesis. (2009) (85)
- Lewis base activation of grignard reagents with N-heterocyclic carbenes. Cu-free catalytic enantioselective additions to gamma-chloro-alpha,beta-unsaturated esters. (2006) (84)
- Broadly applicable Z- and diastereoselective ring-opening/cross-metathesis catalyzed by a dithiolate ru complex. (2014) (84)
- Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts. (2011) (82)
- Regarding the mechanism of olefin metathesis with sol-gel-supported Ru-based complexes bearing a bidentate carbene ligand. Spectroscopic evidence for return of the propagating Ru carbene. (2005) (82)
- Catalytic SN2'- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis. (2016) (82)
- Cu-catalyzed enantioselective conjugate additions of alkyl zinc reagents to unsaturated N-acyloxazolidinones promoted by a chiral triamide phosphane. (2003) (82)
- Catalytic enantioselective addition of organoboron reagents to fluoroketones controlled by electrostatic interactions (2016) (81)
- Ti-Catalyzed Regio- and Enantioselective Synthesis of Unsaturated α-Amino Nitriles, Amides, and Acids. Catalyst Identification through Screening of Parallel Libraries (2000) (81)
- Reduction of .beta.-hydroxy ketones with catecholborane. A stereoselective approach to the synthesis of syn-1,3-diols (1990) (81)
- Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene. (2016) (81)
- Isolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures. (2011) (80)
- Monodentate non-C(2)-symmetric chiral N-heterocyclic carbene complexes for enantioselective synthesis. Cu-catalyzed conjugate additions of aryl- and alkenylsilylfluorides to cyclic enones. (2009) (80)
- Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre. (2018) (80)
- Zirconium-catalyzed asymmetric carbomagnesation (1993) (79)
- Kinetically controlled E-selective catalytic olefin metathesis (2016) (79)
- Cu-catalyzed enantioselective conjugate addition of alkylzincs to cyclic nitroalkenes: catalytic asymmetric synthesis of cyclic alpha-substituted ketones. (2002) (79)
- Stereoselective formation of carbon-carbon bonds through metal catalysis. The zirconium-catalyzed ethylmagnesiation reaction (1991) (79)
- Catalytic enantioselective silylation of acyclic and cyclic triols: application to total syntheses of cleroindicins D, F, and C. (2009) (78)
- Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis. (2009) (78)
- Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis. (2005) (78)
- Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes. (2012) (78)
- NHC-Cu-catalyzed protoboration of monosubstituted allenes. Ligand-controlled site selectivity, application to synthesis and mechanism. (2013) (77)
- A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis (2014) (77)
- Enantioselective Synthesis of α-Alkyl-β,γ-unsaturated Esters through Efficient Cu-Catalyzed Allylic Alkylations (2003) (76)
- Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers By Mo-Catalyzed Olefin Metathesis (2001) (76)
- Efficient catalytic enantioselective synthesis of unsaturated amines: preparation of small- and medium-ring cyclic amines through mo-catalyzed asymmetric ring-closing metathesis in the absence of solvent. (2002) (75)
- Al-catalyzed enantioselective alkylation of alpha-ketoesters by dialkylzinc reagents. enhancement of enantioselectivity and reactivity by an achiral Lewis base additive. (2005) (75)
- Catalytic asymmetric ring-opening metathesis/cross metathesis (AROM/CM) reactions. Mechanism and application to enantioselective synthesis of functionalized cyclopentanes. (2001) (75)
- RU-CATALYZED REARRANGEMENT OF STYRENYL ETHERS. ENANTIOSELECTIVE SYNTHESIS OF CHROMENES THROUGH ZR- AND RU-CATALYZED PROCESSES (1997) (73)
- Copper-catalyzed enantioselective allylic substitution with readily accessible carbonyl- and acetal-containing vinylboron reagents. (2012) (72)
- Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds. (2015) (72)
- NHC-Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes. (2012) (71)
- Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts. (2006) (71)
- Efficient enantioselective synthesis of piperidines through catalytic asymmetric ring-opening/cross-metathesis reactions. (2007) (70)
- Catalytic and Enantioselective Route to Medium-Ring Heterocycles. Asymmetric Zirconium-Catalyzed Ethylmagnesation of Seven- and Eight-Membered Rings (1996) (70)
- Practical and highly enantioselective synthesis of beta-alkynyl-beta-amino esters through Ag-catalyzed asymmetric mannich reactions of silylketene acetals and alkynyl imines. (2005) (70)
- Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes. (2009) (69)
- Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis. (2013) (69)
- Enantioselective Total Synthesis of Antifungal Agent Sch 38516 (1996) (68)
- Enantioselective synthesis of boron-substituted quaternary carbon stereogenic centers through NHC-catalyzed conjugate additions of (pinacolato)boron units to enones. (2014) (68)
- Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR')(OR'')(pyrrolyl): enyne metathesis with high oxidation state catalysts. (2007) (66)
- Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations. (2003) (66)
- Efficient cu-catalyzed asymmetric conjugate additions of alkylzincs to trisubstituted cyclic enones. (2002) (65)
- Mo-catalyzed asymmetric olefin metathesis in target-oriented synthesis: enantioselective synthesis of (+)-africanol. (2004) (64)
- Z-selective metathesis homocoupling of 1,3-dienes by molybdenum and tungsten monoaryloxide pyrrolide (MAP) complexes. (2012) (63)
- The First Polymer-Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis (2002) (62)
- Combining NHC-Cu and Brønsted base catalysis: enantioselective allylic substitution/conjugate additions with alkynylaluminum reagents and stereospecific isomerization of the products to trisubstituted allenes. (2013) (62)
- Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates. (2007) (61)
- Enantioselective synthesis of medium-ring heterocycles, tertiary ethers, and tertiary alcohols by Mo-catalyzed ring-closing metathesis. (2002) (61)
- Aluminum-catalyzed asymmetric alkylations of pyridyl-substituted alkynyl ketones with dialkylzinc reagents. (2008) (61)
- Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles. (2002) (59)
- Enantioselective synthesis of cyclic secondary amines through Mo-catalyzed asymmetric ring-closing metathesis (ARCM). (2003) (59)
- Versatile Homoallylic Boronates by Chemo-, SN 2'-, Diastereo- and Enantioselective Catalytic Sequence of Cu-H Addition to Vinyl-B(pin)/Allylic Substitution. (2017) (58)
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis (1999) (58)
- Efficient Cu-catalyzed asymmetric conjugate additions of alkylzinc reagents to aromatic and aliphatic acyclic nitroalkenes. (2004) (58)
- Enantioselective Silyl Protection of Alcohols Promoted by a Combination of Chiral and Achiral Lewis Basic Catalysts (2013) (58)
- Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles. (2007) (57)
- Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity (2014) (57)
- Reactivity and selectivity differences between catecholate and catechothiolate Ru complexes. Implications regarding design of stereoselective olefin metathesis catalysts. (2014) (56)
- Zirconium-catalyzed ethylmagnesiation of hydroxylated terminal alkenes; a catalytic and diastereoselective carbon-carbon bond-forming reaction (1993) (56)
- Directed Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers (1995) (56)
- Kinetically E-Selective Macrocyclic Ring-Closing Metathesis (2016) (55)
- N-Heterocyclic Carbene-Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes. (2015) (55)
- A chiral Ag-based catalyst for practical, efficient, and highly enantioselective additions of enolsilanes to alpha-ketoesters. (2006) (54)
- Z- and enantioselective ring-opening/cross-metathesis with enol ethers catalyzed by stereogenic-at-Ru carbenes: reactivity, selectivity, and Curtin-Hammett kinetics. (2012) (54)
- Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C1 (2014) (53)
- Synthetic studies of the furan-carbonyl photocycloaddition reaction: a total synthesis of (±)-avenaciolide (1984) (53)
- Supported chiral Mo-based complexes as efficient catalysts for enantioselective olefin metathesis. (2004) (53)
- Catalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu-F β-Elimination. (2019) (53)
- Lewis Acid Catalyzed Borotropic Shifts in the Design of Diastereo- and Enantioselective γ-Additions of Allylboron Moieties to Aldimines. (2016) (53)
- Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis (2017) (52)
- The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes. (2009) (51)
- The mechanism of the zirconium-catalyzed carbomagnesiation reaction. Efficient and selective catalytic carbomagnesiation with higher alkyls of magnesium (1992) (51)
- Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide. (2014) (51)
- Delayed catalyst function enables direct enantioselective conversion of nitriles to NH2-amines (2019) (50)
- Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis. (2006) (50)
- Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene. (2016) (49)
- Zirconium-Catalyzed Kinetic Resolution of Pyrans (1994) (49)
- Siloxanes: versatile templates for acyclic stereocontrol. Synthesis of the C27-C33 segment of rapamycin (1992) (49)
- Practical, Broadly Applicable, α-Selective, Z-Selective, Diastereoselective, and Enantioselective Addition of Allylboron Compounds to Mono-, Di-, Tri-, and Polyfluoroalkyl Ketones. (2017) (49)
- Preparation of Macrocyclic Z-Enoates and (E,Z)- or (Z,E)-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis (2014) (48)
- In Situ Methylene Capping: A General Strategy for Efficient Stereoretentive Catalytic Olefin Metathesis. The Concept, Methodological Implications, and Applications to Synthesis of Biologically Active Compounds. (2017) (48)
- Enantioselective synthesis of quaternary carbon stereogenic centers through copper-catalyzed conjugate additions of aryl- and alkylaluminum reagents to acyclic trisubstituted enones. (2013) (48)
- An enantiomerically pure adamantylimido molybdenum alkylidene complex. An effective new catalyst for enantioselective olefin metathesis. (2003) (48)
- Cu-Catalyzed Asymmetric Conjugate Additions of Dialkyl- and Diarylzinc Reagents to Acyclic β-Silyl-α,β-unsaturated Ketones. Synthesis of Allylsilanes in High Diastereo- and Enantiomeric Purity (2007) (47)
- A robust, efficient, and highly enantioselective method for synthesis of homopropargyl amines. (2012) (47)
- A multicomponent Ni-, Zr-, and Cu-catalyzed strategy for enantioselective synthesis of alkenyl-substituted quaternary carbons. (2014) (47)
- Ni-Catalyzed Asymmetric Addition of Grignard Reagents to Unsaturated Cyclic Acetals. The Influence of Added Phosphine on Enantioselectivity (1998) (47)
- Regiodivergent reactions through catalytic enantioselective silylation of chiral diols. Synthesis of sapinofuranone A. (2011) (47)
- Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols (2001) (45)
- Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum. (2009) (44)
- An Efficient, Practical, and Enantioselective Method for Synthesis of Homoallenylamides Catalyzed by an Aminoalcohol-Derived, Boron-Based Catalyst (2014) (44)
- Catalytic Enantioselective Synthesis of Quaternary All-Carbon Stereogenic Centers. Preparation of α,α‘-Disubstituted β,γ-Unsaturated Esters through Cu-Catalyzed Asymmetric Allylic Alkylations (2005) (44)
- Catalytic Z-selective cross-metathesis with secondary silyl- and benzyl-protected allylic ethers: mechanistic aspects and applications to natural product synthesis. (2013) (44)
- Combinatorial catalyst discovery. (1999) (44)
- A photochemical route to the formation of threo aldols (1983) (44)
- Practical and Broadly Applicable Catalytic Enantioselective Additions of Allyl-B(pin) Compounds to Ketones and α-Ketoesters. (2016) (43)
- Enantio-, Diastereo-, and Regioselective Zirconium-Catalyzed Carbomagnesation of Cyclic Ethers with Higher Alkyls of Magnesium. Utility in Synthesis and Mechanistic Implications (1995) (42)
- Isocomplestatin: total synthesis and stereochemical revision. (2005) (40)
- NHC–Cu-Catalyzed Addition of Propargylboron Reagents to Phosphinoylimines. Enantioselective Synthesis of Trimethylsilyl-Substituted Homoallenylamides and Application to the Synthesis of S-(−)-Cyclooroidin (2014) (40)
- Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems. (2019) (40)
- New Chiral Molybdenum Catalysts for Asymmetric Olefin Metathesis that Contain 3,3‘-Disubstituted Octahydrobinaphtholate or 2,6-Dichlorophenylimido Ligands (2002) (40)
- Modular Mo-based catalysts for efficient asymmetric olefin metathesis. Catalytic enantioselective synthesis of cyclic ethers and acetals (2000) (39)
- Investigations of reactions between chiral molybdenum imido alkylidene complexes and ethylene: Observation of unsolvated base-free methylene complexes, metalacyclobutane and metalacyclopentane complexes, and molybdenum(IV) olefin complexes (2004) (39)
- Synthesis of (±)-tetrapetalone A-Me aglycon. (2014) (39)
- Stereoselective zirconium-catalyzed ethylmagnesiation of homoallylic alcohols and ethers. The influence of internal Lewis bases on substrate reactivity (1991) (38)
- Zirconocene-catalyzed kinetic resolution of dihydrofurans (1995) (38)
- E- and Z-, Di-, and trisubstituted alkenyl nitriles through catalytic cross-metathesis (2019) (37)
- Catalyst discovery through combinatorial chemistry. (1998) (36)
- The influence of anionic ligands on stereoisomerism of Ru carbenes and their importance to efficiency and selectivity of catalytic olefin metathesis reactions. (2014) (36)
- Evaluation of Enantiomerically Pure Binaphthol-Based Molybdenum Catalysts for Asymmetric Olefin Metathesis Reactions that Contain 3,3‘-Diphenyl- or 3,3‘-Dimesityl-Substituted Binaphtholate Ligands. Generation and Decomposition of Unsubstituted Molybdacyclobutane Complexes (2001) (35)
- Synthesis, isolation, characterization, and reactivity of high-energy stereogenic-at-Ru carbenes: stereochemical inversion through olefin metathesis and other pathways. (2012) (34)
- Pentacoordinate Ruthenium(II) Catecholthiolate and Mercaptophenolate Catalysts for Olefin Metathesis: Anionic Ligand Exchange and Ease of Initiation (2016) (33)
- Regio- and stereoselective carbon-carbon bond formation through transition metal catalysis. The influence of catalyst chirality on selective ethylmagnesation of chiral, nonracemic alcohols and ethers (1993) (31)
- Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes. (2011) (31)
- Asymmetric Synthesis of Acyclic Amines Through Zr‐ and Hf‐Catalyzed Enantioselective Alkylzinc Reagents to Imines (2005) (31)
- Stereoselective Heteroatom-Assisted Allylic Alkylation of Cyclic Ethers with Grignard Reagents. A Convenient Route to Enantiomerically Pure Carbocycles (1997) (31)
- Enantioselective synthesis of cyclic allylboronates by Mo-catalyzed asymmetric ring-closing metathesis (ARCM). A one-pot protocol for net catalytic enantioselective cross metathesis (2004) (30)
- Racemic Vinylallenes in Catalytic Enantioselective Multicomponent Processes: Rapid Generation of Complexity through 1,6-Conjugate Additions. (2019) (30)
- Syntheses of Molybdenum Oxo Alkylidene Complexes through Addition of Water to an Alkylidyne Complex. (2018) (30)
- Zr-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis (1999) (29)
- Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes. (2013) (29)
- Synthesis of Z- or E-Trisubstituted Allylic Alcohols and Ethers by Kinetically Controlled Cross-Metathesis with a Ru Catechothiolate Complex. (2017) (29)
- Phosphine-directed stereo- & regioselective Ni-catalyzed reactions of Grignard reagents with allylic ethers (1998) (28)
- Controllable ROMP Tacticity by Harnessing the Fluxionality of Stereogenic-at-Ruthenium Complexes. (2016) (26)
- Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives (2019) (26)
- Ru-Based Catechothiolate Complexes Bearing an Unsaturated NHC Ligand: Effective Cross-Metathesis Catalysts for Synthesis of ( Z)-α,β-Unsaturated Esters, Carboxylic Acids, and Primary, Secondary, and Weinreb Amides. (2019) (25)
- Traceless Protection for More Broadly Applicable Olefin Metathesis. (2019) (24)
- Synthesis of alternating trans-AB copolymers through ring-opening metathesis polymerization initiated by molybdenum alkylidenes. (2015) (24)
- Electronically Activated Organoboron Catalysts for Enantioselective Propargyl Addition to Trifluoromethyl Ketones. (2017) (23)
- SN2″-Selective and Enantioselective Substitution with Unsaturated Organoboron Compounds and Catalyzed by a Sulfonate-Containing NHC-Cu Complex. (2018) (23)
- Syntheses of Molybdenum Oxo Benzylidene Complexes. (2018) (23)
- Sulfonate N-Heterocyclic Carbene-Copper Complexes: Uniquely Effective Catalysts for Enantioselective C-C, C-B, C-H, and C-Si Bond Formation. (2020) (23)
- Diastereoselective Intramolecular Cycloaddition of Vinylsilanes and Silyl Nitronates. Effective Control of Remote Acyclic Asymmetry. (1999) (22)
- A Recyclable Ru‐Based Metathesis Catalyst. (1999) (22)
- Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems (1996) (21)
- Copper-Hydride-Catalyzed Enantioselective Processes with Allenyl Boronates. Mechanistic Nuances, Scope, and Utility in Target-Oriented Synthesis. (2019) (21)
- Enantioselective Total Synthesis of (-)-Deoxoapodine. (2017) (21)
- Zr-Catalyzed Olefin Alkylations and Allylic Substitution Reactions with Electrophiles (2000) (21)
- Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands (2014) (20)
- Impact of Ethylene on Efficiency and Stereocontrol in Olefin Metathesis : When to Add It, When to Remove It, and When to Avoid It. (2020) (20)
- Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile. (2016) (20)
- Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes. (2012) (20)
- Zr-catalyzed electrophilic carbomagnesation of aryl olefins. Mechanism-based control of Zr-Mg ligand exchange. (2001) (19)
- Vicinal Diboronates in High Enantiomeric Purity Through Tandem Site-Selective NHC—Cu-Catalyzed Boron—Copper Additions to Terminal Alkynes. (2010) (19)
- Operationally simple, efficient, and diastereoselective synthesis of cis-2,6-disubstituted-4-methylene tetrahydropyrans catalyzed by triflic acid. (2006) (18)
- Regarding a Persisting Puzzle in Olefin Metathesis with Ru Complexes: Why are Transformations of Alkenes with a Small Substituent Z-Selective? (2016) (18)
- Synthesis of Molybdenum Imido Alkylidene Complexes Containing N,N‘-Disubstituted 2,2‘-Bisamido-1,1‘-binaphthyl Ligands (2000) (18)
- Olefins turned alkylating agents: diastereoselective intramolecular Zr-catalyzed olefin alkylations. (2002) (18)
- Highly diastereoselective hydrosilation reactions. Spirocyclic siloxanes: Sources of Si-based Lewis acids (1996) (17)
- γ-, Diastereo-, and Enantioselective Addition of MEMO-Substituted Allylboron Compounds to Aldimines Catalyzed by Organoboron-Ammonium Complexes. (2018) (17)
- N-Substituted tertiary and O-substituted quaternary carbon stereogenic centers by site-, diastereo- and enantioselective vinylogous Mannich reactions. (2015) (17)
- Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand (2015) (16)
- Diastereoselective Heteroatom-Directed Conjugate Addition of Silylcuprate Reagents to Unsaturated Carbonyls. A Stereoselective Route to .beta.-Carbonyl Siloxanes1 (1994) (16)
- Catalytic Enantioselective Addition of an Allyl Group to Ketones Containing a Tri-, a Di-, or a Monohalomethyl Moiety. Stereochemical Control Based on Distinctive Electronic and Steric Attributes of C-Cl, C-Br, and C-F Bonds. (2019) (16)
- Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers by Catalytic Asymmetric Conjugate Additions of Alkyl and Aryl Aluminum Reagents to Five-, Six-, and Seven-Membered-Ring β-Substituted Cyclic Enones. (2009) (16)
- Synthesis of amino sugars through a highly diastereoselective dipolar cycloaddition. Enantioselective synthesis of the carbohydrate segment of Sch 38516 (1997) (16)
- Catalytic homologation of vinyltributylstannane to allyltributylstannane by Mo(IV) complexes in the presence of ethylene. (2004) (16)
- Regio- and Enantioselective Synthesis of Trifluoromethyl-Substituted Homoallylic a -Tertiary NH2-Amines by Reactions Facilitated by a Threonine-Based Boron-Containing Catalyst. (2020) (15)
- Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2. (2017) (15)
- Practical, efficient, and broadly applicable synthesis of readily differentiable vicinal diboronate compounds by catalytic three-component reactions. (2017) (15)
- Streamlined Catalytic Enantioselective Synthesis of α-Substituted β,γ-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers. (2020) (14)
- Silica-Supported Molybdenum-Oxo alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis. (2019) (14)
- Stereoselective Chelate-Controlled Addition of Grignard Reagents to Unsaturated Medium-Ring Heterocycles. (1999) (13)
- Efficient C—B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons Through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls. (2009) (12)
- Diversity‐Based Identification of Efficient Homochiral Organometallic Catalysts for Enantioselective Synthesis (2005) (12)
- Catalyst‐Controlled Stereoselective Olefin Metathesis (2015) (12)
- Syntheses of Molybdenum Adamantylimido and t-Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine. (2017) (12)
- Samarium-Catalyzed Intramolecular Tishchenko Reduction of β-Hydroxy Ketones. A Stereoselective Approach to the Synthesis of Differentiated Anti 1,3-Diol Monoesters. (1990) (12)
- Molybdenum Imido Alkylidene Complexes Containing Biphen Ligands that Have Silyl Groups Attached through the 6 and 6‘ Methyl Group Carbon Atoms (2001) (12)
- A Catalytic Approach for Enantioselective Synthesis of Homoallylic Alcohols Bearing a Z-Alkenyl Chloride or Trifluoromethyl Group. A Concise and Protecting Group-Free Synthesis of Mycothiazole. (2019) (11)
- New Enantiomerically Pure Alkylimido Mo-Based Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts. (2007) (11)
- Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand (2014) (10)
- Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts. (2006) (9)
- NHC‐Cu‐Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1‐Disubstituted Aryl Alkenes. (2011) (9)
- Combinatorial catalysis: identification of potent chiral catalysts through fluorescent bead signaling. (1999) (9)
- Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes (2020) (8)
- Asymmetric Carbon-Carbon Bond-Forming Reactions (2010) (8)
- Directed regioselective Ni-catalyzed alkylation and hydride addition of allylic ethers. A remarkable turnover in regioselectivity (1996) (8)
- Synthesis of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF3, Phosphonium, CN. (2018) (8)
- Chiral Zirconium Catalysts for Enantioselective Synthesis (2003) (7)
- Catalytic Ring-Closing Metathesis and the Development of Enantioselective Processes (1998) (7)
- Efficient Boron—Copper Additions to Aryl‐Substituted Alkenes Promoted by NHC‐Based Catalysts. Enantioselective Cu‐Catalyzed Hydroboration Reactions. (2009) (7)
- α-Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes: Practical Syntheses of Internal Vinyl Aluminums, Halides, or Boronates. (2010) (7)
- A Practical Method for Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers Through NHC-Cu-Catalyzed Conjugate Additions of Alkyl- and Arylzinc Reagents to β-Substituted Cyclic Enones. (2006) (7)
- Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class (2022) (6)
- Ru Complexes Bearing Bidentate Carbenes: From Innocent Curiosity to Uniquely Effective Catalysts for Olefin Metathesis (2004) (6)
- Oxo 2-Adamantylidene Complexes of Mo(VI) and W(VI) (2021) (6)
- Catalytic Enantioselective Synthesis of Allylic Boronates with a Trisubstituted Alkenyl Fluoride and Conversion to Compounds with a F-Substituted Stereogenic Quaternary Center. (2019) (6)
- Cover Picture: Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts (Angew. Chem. Int. Ed. 38/2003) (2003) (6)
- Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts [J. Am. Chem. Soc. 2000, 122, 8168−8179]. (2001) (6)
- Lewis Base Activation of Grignard Reagents with N-Heterocyclic Carbenes. Cu-Free Catalytic Enantioselective Additions to γ-Chloro-α,β-Unsaturated Esters. (2007) (5)
- Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis (2010) (5)
- Zr-catalyzed diastereo- and enantioselective diene cyclizations. An unexpected synthesis of chiral aldehydes (2003) (5)
- Sulfonate N‐Heterocyclic Carbene–Copper Complexes: Uniquely Effective Catalysts for Enantioselective Synthesis of C−C, C−B, C−H, and C−Si Bonds (2020) (5)
- The Remarkable Metal‐Catalyzed Olefin Metathesis Reaction (2008) (5)
- Chiral N‐Heterocyclic Carbenes in Natural Product Synthesis: Application of Ru‐Catalyzed Asymmetric Ring‐Opening/Cross‐Metathesis and Cu‐Catalyzed Allylic Alkylation to Total Synthesis of Baconipyrone C. (2007) (5)
- Catalytic Enantioselective Ring-Closing Metathesis by a Chiral Biphen—Mo Complex. (1998) (5)
- Al-Catalyzed Enantioselective Alkylation of α-Ketoesters by Dialkylzinc Reagents. Enhancement of Enantioselectivity and Reactivity by an Achiral Lewis Base Additive. (2006) (4)
- Reduction of β‐Hydroxy Ketones with Catecholborane. A Stereoselective Approach to the Synthesis of syn‐1,3‐Diols. (1991) (4)
- Chiral Titanocenes and Zirconocenes in Synthesis (2008) (4)
- Formation of Vinyl-, Vinylhalide- or Acyl-Substituted Quaternary Carbon Stereogenic Centers Through NHC—Cu-Catalyzed Enantioselective Conjugate Additions of Si-Containing Vinylaluminums to β-Substituted Cyclic Enones. (2011) (4)
- Asymmetric Catalysis in Target‐Oriented Synthesis (2005) (4)
- Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper-Catalyzed Allylic Substitutions This research was supported by the National Institutes of Health (GM47480 and GM57212). Additional funds were provided by DuPont. (2001) (4)
- Enantioselective Synthesis of Boron‐Substituted Quaternary Carbons by NHC—Cu‐Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters. (2011) (4)
- Catalytic, Enantioselective, Copper–Boryl Additions to Alkenes (2019) (4)
- Diastereo- and enantioselective synthesis of compounds with a trifluoromethyl- and fluoro-substituted carbon centre. (2022) (4)
- Polymer‐supported Olefin Metathesis Catalysts for Organic and Combinatorial Synthesis (2005) (4)
- Activation of B–B and B–Si Bonds and Synthesis of Organoboron and Organosilicon Compounds through Lewis Base‐Catalyzed Transformations (n → n *) (2016) (4)
- E- and Z-Trisubstituted macrocyclic alkenes for natural product synthesis and skeletal editing (2022) (4)
- Impact of Ethylene on Efficiency and Stereocontrol in Olefin Metathesis: When to Add It, When to Remove It, and When to Avoid It (2020) (4)
- Enantioselective Synthesis of Homoallylic Amines Through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl-, or Alkene-Substituted Aldimines Catalyzed by Chiral C1-Symmetric NHC—Cu Complexes. (2011) (4)
- Cross-Metathesis Reaction. Generation of Highly Functionalized Olefins from Unsaturated Alcohols. (2001) (3)
- Modular Pyridinyl Peptide Ligands in Asymmetric Catalysis: Enantioselective Synthesis of Quaternary Carbon Atoms Through Copper‐Catalyzed Allylic Substitutions. (2001) (3)
- Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts. (2001) (3)
- Catalytic Enantioselective Conjugate Addition of Stereodefined Di‐ and Trisubstituted Alkenylaluminum Compounds to Acyclic Enones (2020) (3)
- Zirconium-Catalyzed Kinetic Resolution of Pyrans. (1994) (3)
- Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine—Cu Complex. (2015) (3)
- Boosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand σ Donation. (2021) (3)
- Enantioselective Synthesis of Silyl Ethers Through Catalytic Si ─ O Bond Formation (2019) (3)
- Zirconium-Catalyzed Asymmetric Carbomagnesation. (1993) (3)
- H‐Bonding as a Control Element in Stereoselective Ru‐Catalyzed Olefin Metathesis. (2009) (3)
- Exceptionally E‐ and β‐Selective NHC—Cu‐Catalyzed Proto‐Silyl Additions to Terminal Alkynes and Site‐ and Enantioselective Proto‐Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes. (2013) (3)
- Catalytic Enantioselective Olefin Metathesis in Natural Product Synthesis. Chiral Metal-Based Complexes that Deliver High Enantioselectivity and More (2010) (3)
- Three-Component Ag-Catalyzed Enantioselective Vinylogous Mannich and Aza-Diels—Alder Reactions with Alkyl-Substituted Aldehydes. (2009) (3)
- Catalytic Enantioselective Synthesis of Quaternary All‐Carbon Stereogenic Centers. Preparation of α,α′‐Disubstituted β,γ‐Unsaturated Esters Through Cu‐Catalyzed Asymmetric Allylic Alkylations. (2005) (2)
- Rhodium(I)-Catalyzed Hydroboration of Olefins. The Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems. (1989) (2)
- Highly Efficient Molybdenum‐Based Catalysts for Enantioselective Alkene Metathesis. (2009) (2)
- α-Selective Nickel-Catalyzed Hydroalumination ofTerminal Alkynes (2010) (2)
- Monodentate Non-C2-symmetric Chiral N-Heterocyclic Carbene Complexes for Enantioselective Synthesis. Cu-Catalyzed Conjugate Additions of Aryl- and Alkenylsilylfluorides to Cyclic Enones. (2009) (2)
- Combining NHC—Cu and Broensted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes. (2013) (2)
- Fieser's Reagents for Organic Synthesis, Volume 18 By Tse-Lok Ho (National Chiao Tung University). John Wiley & Sons, Inc.: New York. 1999. xii + 504 pp. $79.95. ISBN 0-471-24477-5. (1999) (2)
- Directed Catalytic Asymmetric Olefin Metathesis (2007) (2)
- NHC Copper Catalyzed Enantioselective Conjugate Addition (2010) (2)
- Metal-Catalyzed Kinetic Resolution Processes (1998) (2)
- Catalytic and Enantioselective Route to Medium‐Ring Heterocycles. Asymmetric Zirconium‐Catalyzed Ethylmagnesation of Seven‐ and Eight‐ Membered Rings. (1996) (2)
- A Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring-Opening/Cross Metathesis in Air [J. Am. Chem. Soc. 2002, 124, 4954−4955]. (2003) (2)
- Erratum to: “Cross-metathesis reaction. Generation of highly functionalized olefins from unsaturated alcohols” (2001) (2)
- Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B‐Substituted Stereogenic Carbon by NHC‐Cu‐Catalyzed Substitution Reactions. (2011) (2)
- Ru-Catalyzed Rearrangement of Styrenyl Ethers. Enantioselective Synthesis of Chromenes Through Zr- and Ru-Catalyzed Processes. (1997) (2)
- Modular Peptide‐Based Phosphine Ligands in Asymmetric Catalysis: Efficient and Enantioselective Cu‐Catalyzed Conjugate Additions to Five‐, Six‐, and Seven‐Membered Cyclic Enones. (2001) (2)
- Efficient and Practical Ag‐Catalyzed Cycloadditions Between Arylimines and the Danishefsky Diene. (2003) (2)
- Tandem Catalytic Asymmetric Ring‐Opening Metathesis/Ring‐Closing Metathesis. (2000) (2)
- Enantioselective Silyl Protection of Alcohols Catalyzed by an Amino-Acid-Based Small Molecule. (2007) (2)
- Synthesis of Quaternary Carbon Stereogenic Centers Through Enantioselective Cu‐Catalyzed Allylic Substitutions with Vinylaluminum Reagents. (2011) (2)
- Ni-Catalyzed Asymmetric Addition of Grignard Reagents to Unsaturated Cyclic Acetals. The Influence of Added Phosphine on Enantioselectivity. (1998) (2)
- Zr-Catalyzed Olefin Alkylations and Allylic Substitution Reactions with Electrophiles. (2000) (2)
- A Multicomponent Ni‐, Zr‐, and Cu‐Catalyzed Strategy for Enantioselective Synthesis of Alkenyl‐Substituted Quaternary Carbons. (2014) (2)
- Chiral Ru‐Based Complexes for Asymmetric Olefin Metathesis: Enhancement of Catalyst Activity Through Steric and Electronic Modifications. (2004) (2)
- Cascade Catalysis in Synthesis. An Enantioselective Route to Sch 38516 (and Fluvirucin B1) Aglycon Macrolactam. (1995) (1)
- Enantioselective Total Synthesis of Antifungal Agent Sch 38516. (1997) (1)
- Enantioselective Synthesis of Unsaturated Cyclic Tertiary Ethers by Mo‐Catalyzed Olefin Metathesis. (2001) (1)
- Immobilization of Olefin Metathesis Catalysts on Monolithic Sol—Gel: Practical, Efficient and Easily Recyclable Catalysts for Organic and Combinatorial Synthesis. (2002) (1)
- Highly Selective Methods for Synthesis of Internal (α‐) Vinylboronates Through Efficient NHC—Cu‐Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity. (2011) (1)
- Catalytic Enantioselective Alkylation of Alkenes by Chiral Metallocenes (2008) (1)
- Enantioselective Synthesis of Cyclic Secondary Amines Through Mo‐Catalyzed Asymmetric Ring‐Closing Metathesis (ARCM). (2004) (1)
- A Chiral Ag‐Based Catalyst for Practical, Efficient, and Highly Enantioselective Additions of Enolsilanes to α‐Ketoesters. (2006) (1)
- Catalytic Asymmetric Ring‐Opening Metathesis/Cross Metathesis (AROM/CM) Reactions. Mechanism and Application to Enantioselective Synthesis of Functionalized Cyclopentanes. (2001) (1)
- Catalyst Discovery Through Combinatorial Chemistry (1999) (1)
- Directed Regio- and Stereoselective Nickel-Catalyzed Addition of Alkyl Grignard Reagents to Allylic Ethers. (1995) (1)
- Organoaluminum Compounds in Catalytic Enantioselective CC Bond Forming Reactions (2016) (1)
- Frontispiece: Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives (2019) (1)
- Copper-Catalyzed Enantioselective Hydroboration (2011) (1)
- Efficient Enantioselective Synthesis of Functionalized Tetrahydropyrans by Ru‐Catalyzed Asymmetric Ring‐Opening Metathesis/Cross‐Metathesis (AROM/CM). (2005) (1)
- Stereoselective Formation of Carbon-Carbon Bonds Through Metal Catalysis. The Zirconium-Catalyzed Ethylmagnesation Reaction. (1991) (1)
- Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems. (1996) (1)
- Preparation of Macrocyclic (2014) (1)
- Highly Enantioselective Cu‐Catalyzed Conjugate Additions of Dialkylzinc Reagents to Unsaturated Furanones and Pyranones: Preparation of Air‐Stable and Catalytically Active Cu‐Peptide Complexes. (2005) (1)
- Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids. (1999) (1)
- Stereoselective Heteroatom‐Assisted Allylic Alkylation of Cyclic Ethers with Grignard Reagents. A Convenient Route to Enantiomerically Pure Carbocycles. (1997) (1)
- Supported Chiral Mo‐Based Complexes as Efficient Catalysts for Enantioselective Olefin Metathesis. (2005) (1)
- Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers Through NHC—Cu-Catalyzed Allylic Substitution Reactions with (iBu)2(Alkynyl)aluminum Reagents. (2011) (1)
- NHC-Catalyzed Boron Conjugate Additions to α,β-UnsaturatedCarbonyl Compounds (2009) (1)
- Phosphine-Directed Stereo- and Regioselective Ni-Catalyzed Reactions of Grignard Reagents with Allylic Ethers. (1998) (1)
- Dichlorobis(cyclopentadienyl)titanium (2013) (1)
- Ag‐Catalyzed Asymmetric Mannich Reactions of Enol Ethers with Aryl, Alkyl, Alkenyl, and Alkynyl Imines. (2004) (1)
- Small Peptides as Ligands for Catalytic Asymmetric Alkylations of Olefins. Rational Design of Catalysts or of Searches that Lead to Them (2004) (1)
- Combinatorial Approaches to Chiral Catalyst Discovery (2001) (1)
- Cu-Catalyzed Asymmetric Conjugate Additions of Dialkyl- and Diarylzinc Reagents to Acyclic β-Silyl-α,β-unsaturated Ketones. Synthesis of Allylsilanes in High Diastereo- and Enantiomeric Purity. (2007) (1)
- Enol Ethers as Substrates for Efficient Zand Enantioselective Ring-Opening / Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes : (2012) (1)
- Catalytic Enantioselective Olefin Metathesis Reactions (2011) (1)
- Room-Temperature Z-Selective Homocoupling of alpha-Olefins by Tungsten Catalysts (2011) (1)
- Aluminum‐Catalyzed Asymmetric Addition of TMSCN to Aromatic and Aliphatic Ketones Promoted by an Easily Accessible and Recyclable Peptide Ligand. (2002) (1)
- Zr‐Catalyzed Kinetic Resolution of Allylic Ethers and Mo‐Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)‐Nebivolol. (1999) (1)
- Tandem Catalytic Asymmetric Ring-Opening Metathesis/Cross Metathesis. (2000) (1)
- Copper-NHC Catalyst for Hydroboration (2009) (1)
- Primo Levi's The Periodic Table. A search for patterns in times past. (2004) (1)
- Mo-Catalyzed Asymmetric Synthesis of Dihydrofurans. Catalytic Kinetic Resolution and Enantioselective Desymmetrization Through Ring-Closing Metathesis. (1999) (1)
- Enantioselective Synthesis of Cyclic Enol Ethers and All‐Carbon Quaternary Stereogenic Centers Through Catalytic Asymmetric Ring‐Closing Metathesis. (2006) (1)
- Catalytic Enantioselective Alkylations of Tetrasubstituted Olefins. Synthesis of All‐Carbon Quaternary Stereogenic Centers Through Cu‐Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Enones. (2006) (1)
- Stereoselective Zirconium‐Catalyzed Ethylmagnesation of Homoallylic Alcohols and Ethers. The Influence of Internal Lewis Bases on Substrate Reactivity. (1992) (1)
- A Broadly Applicable NHC—Cu‐Catalyzed Approach for Efficient, Site‐, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis. (2014) (1)
- A Recyclable Chiral Ru Catalyst for Enantioselective Olefin Metathesis. Efficient Catalytic Asymmetric Ring‐Opening/Cross Metathesis in Air. (2002) (1)
- Asymmetric Silylation: Extension to Kinetic Resolution (2007) (0)
- Kinetic Resolution of 1,2‐Diols Through Highly Site‐ and Enantioselective Catalytic Silylation. (2008) (0)
- Selective NHC–Cu-Catalyzed Allylic Substitution (2012) (0)
- Directed Regioselective Ni-Catalyzed Alkylation and Hydride Addition of Allylic Ethers. A Remarkable Turnover in Regioselectivity. (1996) (0)
- All-Carbon Quaternary Stereogenic Centers via Cu-Catalyzed Conjugate Additions (2006) (0)
- CCDC 1584030: Experimental Crystal Structure Determination (2017) (0)
- Zr‐Catalyzed Electrophilic Carbomagnesation of Aryl Olefins. Mechanism‐Based Control of Zr—Mg Ligand Exchange. (2001) (0)
- ChemInform Abstract: Catalytic Asymmetric Olefin Metathesis (2002) (0)
- Catalytic Cross-Metathesis Reactions That Afford E- and Z-Trisubstituted Alkenyl Bromides: Scope, Applications, and Mechanistic Insights. (2023) (0)
- Substrate‐Directable Chemical Reactions (1993) (0)
- The First Polymer‐Supported and Recyclable Chiral Catalyst for Enantioselective Olefin Metathesis. (2002) (0)
- Modular Mo‐Based Catalysts for Efficient Asymmetric Olefin Metathesis. Catalytic Enantioselective Synthesis of Cyclic Ethers and Acetals. (2001) (0)
- Enantioselective synthesis of alpha-alkyl-beta,gamma-unsaturated esters through efficient cu-catalyzed allylic alkylations. (2003) (0)
- Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and Their Utility in Copper‐Catalyzed Enantioselective Synthesis of 1,4‐Dienes Containing Z or E Alkenes. (2010) (0)
- High-Throughput Strategies for the Discovery of Catalysts (1999) (0)
- Cu-Catalyzed Enantioselective Allylic Substitution with Vinylboron Reagents (2012) (0)
- Catalytic Asymmetric Allylic Alkylation with Vinylaluminum Reagents (2008) (0)
- Synthesis of Vicinal Diboronates by Cu(I)-Catalyzed B-CuAddition to Alkynes (2010) (0)
- Synthesis of 2,6-Hexa-Tert-Butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu₃C₆H₂)₂C₆H₃X, Where X = I, Li, OH, SH, N₃, or NH₂ (2017) (0)
- Total Synthesis of (-)Clavirolide C (2009) (0)
- Desymmetrization of meso-Diols via Enantioselective Silylation (2006) (0)
- Cu-catalyzed asymmetric conjugate additions of dialkyl- and diarylzinc reagents to acyclic beta-silyl-alpha,beta-unsaturated ketones. Synthesis of allylsilanes in high diastereo- and enantiomeric purity. (2007) (0)
- CCDC 848335: Experimental Crystal Structure Determination (2012) (0)
- Synthesis of Chiral -Silylketones and E -Allylsilanes (2007) (0)
- Al-Catalyzed Enantioselective Dialkylzinc Addition to α-Ketoesters (2006) (0)
- Silica‐Supported Molybdenum Oxo Alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis (2019) (0)
- Stereoselective Chelate‐Controlled Addition of Grignard Reagents to Unsaturated Medium‐Ring Heterocycles. (1999) (0)
- Asymmetric Silyl Transfer by Transition-Metal-Free NHC Catalysis (2011) (0)
- Stereoselective Addition of Grignard Reagents to Alkenes (2000) (0)
- Applications of Zr-Catalyzed Carbomagnesation and Mo-Catalyzed Macrocyclic Ring Closing Metathesis in Asymmetric Synthesis. Enantioselective Total Synthesis of Sch 38516 (Fluvirucin B1). (1998) (0)
- Nature supp info accepted version C (2011) (0)
- Three‐Component Enantioselective Synthesis of Propargylamines Through Zr‐Catalyzed Additions of Alkyl Zinc Reagents to Alkynylimines. (2003) (0)
- Domino Asymmetric Ring-Opening/Cross Metathesis Reaction (2007) (0)
- Ag(II)-Catalyzed Asymmetric Mukaiyama Aldol Reaction of α-Keto Esters (2006) (0)
- Synthesis of Linear (Z)‐α,β‐Unsaturated Esters by Catalytic Cross‐Metathesis. The Influence of Acetonitrile. (2016) (0)
- Enantioselective Synthesis of Cyclic Amides and Amines Through Mo‐Catalyzed Asymmetric Ring‐Closing Metathesis. (2005) (0)
- Mo-Based Complexes with Two Aryloxides and a Pentafluoroimido Ligand: Catalysts for Efficient Z-Selective Synthesis of a Macrocyclic Trisubstituted Alkene by Ring-Closing Metathesis (2013) (0)
- Search for Chiral Catalysts Through Ligand Diversity: Substrate- Specific Catalysts and Ligand Screening on Solid Phase. (1997) (0)
- Copper-NHC Catalysts for Asymmetric Conjugate Addition (2009) (0)
- CCDC 1034282: Experimental Crystal Structure Determination (2014) (0)
- Siloxanes: Versatile Templates for Acyclic Stereocontrol. Synthesis of the C27-C33 Segment of Rapamycin. (2010) (0)
- Room for one more on board? (2001) (0)
- Zirconocene‐Catalyzed Kinetic Resolution of Dihydrofurans. (1995) (0)
- Site‐ and Enantioselective Formation of Allene‐Bearing Tertiary or Quaternary Carbon Stereogenic Centers Through NHC—Cu‐Catalyzed Allylic Substitution. (2012) (0)
- Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1 , 2-Citation Lam (2018) (0)
- Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes". (2017) (0)
- Asymmetric Silylation of Triols (2009) (0)
- Efficient Cu‐Catalyzed Asymmetric Conjugate Addition of Alkylzinc Reagents to Aromatic and Aliphatic Acyclic Nitroalkenes. (2004) (0)
- Publisher Correction: Stereodefined alkenes with a fluoro-chloro terminus as a uniquely enabling compound class (2022) (0)
- Molybdenum-Catalyzed Enantioselective Alkene Metathesis (2009) (0)
- Frontispiz: Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives (2019) (0)
- Synthesis of Baconipyrone C (2007) (0)
- Total Synthesis of anti‐HIV Agent Chloropeptin I (I). (2003) (0)
- Copper-Catalyzed Asymmetric Allylic Substitution with ArylaluminumReagents (2011) (0)
- SYNTHETIC STUDIES OF THE FURAN-CARBONYL PHOTOCYCLOADDITION REACTION. A TOTAL SYNTHESIS OF (.+-.)-AVENACIOLIDE (1985) (0)
- Synthesis of P-Stereogenic Centers Through Ring-Closing Metathesis (2009) (0)
- Molybdenum-Catalyzed Z- and Enantioselective Ring-Opening/Cross-MetathesisReactions (2009) (0)
- Quaternary Carbon Stereocenters via NHC-Cu Induced Conjugate Addition (2007) (0)
- 1,4-Addition of Alkyl and Aryl-Aluminums to Cyclic Enones (2008) (0)
- Enantioselective C-C and C-H Bond Formation Mediated or Catalyzed by Chiral Ethylenebis(tetrahydroindenyl) Complexes of Titanium and Zirconium (1996) (0)
- Z-Trisubstituted α,β-Unsaturated Esters and Acid Fluorides through Stereocontrolled Catalytic Cross-Metathesis. (2023) (0)
- Molybdenum and Tungsten Imido Alkylidene Complexes as Efficient Olefin‐Metathesis Catalysts. (2003) (0)
- Copper‐Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl‐ and Acetal‐Containing Vinylboron Reagents. (2012) (0)
- Efficient Cu‐Catalyzed Asymmetric Conjugate Additions of Alkylzincs to Trisubstituted Cyclic Enones. (2003) (0)
- Metal‐Free Catalytic Enantioselective C—B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β‐Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N‐Heterocyclic Carbenes. (2012) (0)
- Cu-Catalyzed Enantioselective Conjugate Addition of Alkylzincs to Cyclic Nitroalkenes: Catalytic Asymmetric Synthesis of Cyclic α-Substituted Ketones. (2002) (0)
- Proline‐Based N‐Oxides as Readily Available and Modular Chiral Catalysts. Enantioselective Reactions of Allyltrichlorosilane with Aldehydes. (2005) (0)
- CCDC 869154: Experimental Crystal Structure Determination (2012) (0)
- Molybdenum, [(S)‐3,3′‐Bis(1,1‐dimethylethyl)‐5,5′, 6,6′‐tetramethyl[1,1′‐biphenyl]‐2,2′‐diolato(2−)‐κO,κO′]‐2‐methyl‐2‐phenylpropylidene)[tricyclo[3.3.1.1]decan‐1‐aminato(2−)] (2007) (0)
- Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers. Preparation of alpha,alpha'-disubstituted beta,gamma-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations. (2005) (0)
- Highly Diastereoselective Hydrosilation Reactions. Spirocyclic Siloxanes: Sources of Si-Based Lewis Acids. (2010) (0)
- Enantioselective Conjugated Addition of Vinylaluminums toCyclic Enones (2011) (0)
- Catalytic Z-Selective Olefin Cross-Metathesis (2011) (0)
- N-Heterocyclic Carbene—Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes. (2015) (0)
- Zirconium‐Catalyzed Ethylmagnesation of Hydroxylated Terminal Alkenes: A Catalytic and Diastereoselective Carbon‐Carbon Bond‐Forming Reaction. (1993) (0)
- Regio- and Stereoselective Carbon-Carbon Bond Formation Through Transition Metal Catalysis. The Influence of Catalyst Chirality on Selective Ethylmagnesation of Chiral, Nonracemic Alcohols, and Ethers. (1993) (0)
- Enantioselective Conjugate Addition of Organozinc Reagents to Enones (2006) (0)
- Enantioselective Synthesis of Arylamines Through Zr‐Catalyzed Addition of Dialkylzincs to Imines. Reaction Development by Screening of Parallel Libraries. (2001) (0)
- Catalytic and Stereoselective Transformations with Easily Accessible and Purchasable Allyl and Alkenyl Fluorides. (2022) (0)
- Dichloro[[2‐(1‐methylethoxy‐O)phenyl]‐methylene] (tricyclohexylphosphine) Ruthenium (2013) (0)
- Purification of Alkene Stereoisomers through Z-Selective Ethenolysis (2011) (0)
- Copper-Catalyzed Allylic Alkylation of Trisubstituted VinylaluminumReagents (2010) (0)
- Synthesis of Amino Sugars Through a Highly Diastereoselective Dipolar Cycloaddition. Enantioselective Synthesis of the Carbohydrate Segment of Sch 38516. (1998) (0)
- Synthesis of (+)-Quebrachamine (2009) (0)
- Zr-Catalyzed Kinetic Resolution of Aliphatic Cyclic Allylic Ethers. Carbocycles to Heterocycles by Ru- and Mo-Catalyzed Ring-Opening and Ring-Closing Metathesis. (2000) (0)
- CCDC 988229: Experimental Crystal Structure Determination (2014) (0)
- New Enantiomerically Pure Alkylimido Molybdenum-Based Alkylidene Complexes . Synthesis , Characterization , and Activity as Chiral Olefin Metathesis Catalysts (0)
- Direct Catalytic Asymmetric Olefin Metathesis. Selectivity Control by Enoate and Ynoate Groups in Ru‐Catalyzed Asymmetric Ring‐Opening/Cross‐Metathesis. (2007) (0)
- Catalytic Z‐Selective Cross‐Metathesis with Secondary Silyl‐ and Benzyl‐Protected Allylic Ethers: Mechanistic Aspects and Applications to Natural Product Synthesis. (2013) (0)
- Proline-Based N-Oxides as Modular Chiral Catalysts for Allylation (2005) (0)
- [(1S)‐3,3′‐bis(1,1‐dimethylethyl)‐5,5′,6,6′‐tetramethyl[1,1′‐biphenyl]‐2,2′‐diolato(2‐)‐O,O′][2,5‐bis(1‐methylethyl)benzenaminato(2‐)](2‐methyl‐2‐phenylpropylidene)molybdenum [(S)‐Schrock‐Hoveyda catalyst] (2003) (0)
- Enantioselective Synthesis of Allylboronates by NHC CopperCatalyzed Substitution (2010) (0)
- Diastereoselective Heteroatom‐Directed Conjugate Addition of Silylcuprate Reagents to Unsaturated Carbonyls. A Stereoselective Route to β‐Carbonyl Siloxanes. (1995) (0)
- Allenylboronic Acid Pinacol Ester (2015) (0)
- Catalytic Z-Selective Cross-Metathesis in Complex Molecule Synthesis: A Convergent Stereoselective Route to Disorazole C[subscript 1] (2014) (0)
- Highly Site‐ and Enantioselective Cu‐Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents. (2008) (0)
- Combinatorial Catalysis: Identification of Potent Chiral Catalysts Through Fluorescent Bead Signaling (2000) (0)
- A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis This research was supported by the National Institutes of Health (GM-59426) and the National Science Foundation (CHE-9905806 to A. H. H. and CHE-9988766 to R. R. S.). (2001) (0)
- Enantioselective Addition of Boronated Allylcopper Derivatives (2016) (0)
- NHC—Cu‐Catalyzed Addition of Propargylboron Reagents to Phosphinoylimines. Enantioselective Synthesis of Trimethylsilyl‐Substituted Homoallenylamides and Application to the Synthesis of S‐(‐)‐Cyclooroidin. (2014) (0)
- Metathesis Homocoupling of Terminal Olefins (2010) (0)
- Ru- and Mo-Catalyzed Asymmetric Synthesis of Pyrans and Piperidines (2007) (0)
- Three‐Component Catalytic Asymmetric Synthesis of Aliphatic Amines. (2002) (0)
- Stereoselectivity in Synthesis By Tse-Lok Ho (National Chiao Tung University). John Wiley & Sons, Inc.: New York. 1999. xiii + 333 pp. $94.95. ISBN 0-471-32922-3. (1999) (0)
- Rhodium(I)- and Iridium(I)-Catalyzed Hydroboration Reactions: Scope and Synthetic Applications. (1992) (0)
- CCDC 1584032: Experimental Crystal Structure Determination (2017) (0)
- Organocatalyzed Asymmetric Allylic Alkylation of Grignard Reagents (2007) (0)
- Copper-Catalyzed Allylic Alkylations for the Synthesis of Chiral Allylsilanes (2007) (0)
- Dichloro{[2‐(1‐methylethoxy‐O)phenyl]‐methylene} tricyclohexylphosphine ruthenium (Hoveyda–Grubbs Catalyst) (2003) (0)
- Enantioselective Synthesis of Cyclic Allylboronates by Mo-Catalyzed Asymmetric Ring-Closing Metathesis (ARCM). A One-Pot Protocol for Net Catalytic Enantioselective Cross Metathesis. (2004) (0)
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