Andréa E. Merbach

Andréa E. Merbach's AcademicInfluence.com Rankings

Andréa E. Merbach

Chemistry

#3037

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#4020

Historical Rank

Inorganic Chemistry

#139

World Rank

#151

Historical Rank

Physical Chemistry

#386

World Rank

#435

Historical Rank

chemistry Degrees

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Chemistry

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Andréa E. Merbach's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging (2013) (694)
Inorganic and bioinorganic solvent exchange mechanisms. (2005) (518)
Structural and Dynamic Parameters Obtained from 17O NMR, EPR, and NMRD Studies of Monomeric and Dimeric Gd3+ Complexes of Interest in Magnetic Resonance Imaging: An Integrated and Theoretically Self-Consistent Approach1 (1996) (480)
Water exchange on metal ions: experiments and simulations (1999) (365)
A simple multinuclear NMR thermometer (1982) (363)
Superparamagnetic gadonanotubes are high-performance MRI contrast agents. (2005) (298)
First solvation shell of the Cu(II) aqua ion: evidence for fivefold coordination. (2001) (293)
Water-soluble gadofullerenes: toward high-relaxivity, pH-responsive MRI contrast agents. (2005) (288)
Conformational and Coordination Equilibria on DOTA Complexes of Lanthanide Metal Ions in Aqueous Solution Studied by (1)H-NMR Spectroscopy. (1997) (268)
Relaxivity of MRI Contrast Agents (2002) (205)
Perspectives in Coordination Chemistry (1992) (188)
Oxygen-17 NMR study of water exchange on gadolinium polyaminopolyacetates [Gd(DTPA)(H2O)]2- and [Gd(DOTA)(H2O)]- related to NMR imaging (1993) (174)
High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II) (1980) (157)
.pi.-Arene Aqua Complexes of Cobalt, Rhodium, Iridium, and Ruthenium: Preparation, Structure, and Kinetics of Water Exchange and Water Substitution (1995) (149)
High relaxivity confined to a small molecular space: a metallostar-based, potential MRI contrast agent. (2005) (143)
MOLECULAR DYNAMICS SIMULATION STUDY OF LANTHANIDE IONS LN3+ IN AQUEOUS SOLUTION INCLUDING WATER POLARIZATION. CHANGE IN COORDINATION NUMBER FROM 9 TO 8 ALONG THE SERIES (1995) (141)
The Slowest Water Exchange at a Homoleptic Mononuclear Metal Center: Variable-Temperature and Variable-Pressure 17O NMR Study on [Ir(H2O)6]3+ (1996) (138)
GdIII complexes with fast water exchange and high thermodynamic stability: potential building blocks for high-relaxivity MRI contrast agents. (2003) (132)
The impact of rigidity and water exchange on the relaxivity of a dendritic MRI contrast agent. (2002) (130)
The hydration of Dy3+ and Yb3+ in aqueous solution: A neutron scattering first order difference study (1989) (128)
The Role of Water Exchange in Attaining Maximum Relaxivities for Dendrimeric MRI Contrast Agents (1996) (127)
First 17O NMR Observation of Coordinated Water on Both Isomers of [Eu(DOTAM)(H2O)]3+: A Direct Access to Water Exchange and its Role in the Isomerization (2000) (119)
Gadonanotubes as ultrasensitive pH-smart probes for magnetic resonance imaging. (2008) (115)
From monomers to micelles: investigation of the parameters influencing proton relaxivity (2002) (114)
Substitution Reactions of Solvated Metal Ions (1995) (114)
The elucidation of solvent exchange mechanisms by high-pressure NMR studies (1982) (110)
Use of high pressure kinetic studies in determining inorganic substitution mechanisms (1987) (106)
Denaturant-induced movement of the transition state of protein folding revealed by high-pressure stopped-flow measurements. (2000) (105)
Water exchange on [Gd(H2O)8]3+ and [Gd(PDTA)(H2O)2]‐ in aqueous solution: A variable‐pressure, ‐temperature and ‐magnetic field 17O NMR study (1993) (104)
Water-exchange, electronic relaxation, and rotational dynamics of the MRI contrast agent [Gd(DTPA-BMA)(H2O)] in aqueous solution: a variable pressure, temperature, and magnetic field oxygen-17 NMR study (1994) (101)
Oxygen-17 nuclear magnetic resonance kinetic study of water exchange on the lanthanide(III) aqua ions (1988) (100)
High Relaxivity for Monomeric Gd(DOTA)‐Based MRI Contrast Agents, Thanks to Micellar Self‐Organization (1999) (99)
A starburst-shaped heterometallic compound incorporating six densely packed gd(3+) ions. (2006) (99)
Rotational dynamics account for pH-dependent relaxivities of PAMAM dendrimeric, Gd-based potential MRI contrast agents. (2005) (97)
EPR spectroscopy of MRI-related Gd(III) complexes: simultaneous analysis of multiple frequency and temperature spectra, including static and transient crystal field effects. (2001) (96)
17O nuclear magnetic resonance in aqueous solutions of Cu2+ : the combined effect of Jahn-Teller inversion and solvent exchange on relaxation rates (1991) (96)
High-pressure NMR study. 38. Water-exchange mechanisms on the terbium to thulium octaaqualanthanide(III) ions: a variable-pressure oxygen-17 NMR study (1989) (91)
Water exchange on magnesium(II) in aqueous solution: a variable temperature and pressure 17O NMR study (1997) (91)
A change in coordination number from nine to eight along the lanthanide(III) aqua ion series in solution: a neutron diffraction study (1995) (90)
High-pressure oxygen-17 Fourier transform nuclear magnetic resonance spectroscopy. Mechanism of water exchange on iron(III) in acidic aqueous solution (1981) (89)
Destroying gadofullerene aggregates by salt addition in aqueous solution of Gd@C(60)(OH)(x) and Gd@C(60)[C(COOH(2))](10). (2005) (88)
High-pressure NMR kinetics. Part 34. Variable-temperature and variable-pressure NMR kinetic study of solvent exchange on hexaaquaruthenium(3+) and -(2+) and hexakis(acetonitrile)ruthenium(2+) (1988) (87)
Rigid MIIL2Gd2III (M = Fe, Ru) complexes of a terpyridine-based heteroditopic chelate: a class of candidates for MRI contrast agents. (2005) (86)
Triaqua(benzene)ruthenium(II) and triaqua(benzene)osmium(II): synthesis, molecular structure, and water-exchange kinetics (1988) (81)
Water Exchange on Hexaaquavanadium(III): a Variable-Temperature and Variable-Pressure 17O-NMR Study at 1.4 and 4.7 Tesla (1985) (81)
Lanthanide(III) complexes of DOTA-glycoconjugates: a potential new class of lectin-mediated medical imaging agents. (2004) (80)
Variable-Temperature and Variable-Pressure 17O-NMR Study of Water Exchange of Hexaaquaaluminium(III)†‡ (1985) (80)
Water‐Exchange Mechanism of Tetraaquapalladium(II). A Variable‐Pressure and Variable‐Temperature Oxygen‐17 NMR Study (1984) (79)
Coordination equilibria and water exchange kinetics of lanthanide(III) propylenediaminetetraacetates and other magnetic resonance imaging related complexes (1995) (77)
Recent developments in solvation and dynamics of the lanthanide(III) ions (1988) (76)
The titanyl question revisited (1987) (76)
Physicochemical and MRI characterization of Gd3+-loaded polyamidoamine and hyperbranched dendrimers (2007) (75)
Relaxivity of gadolinium (III) complexes: theory and mechanism (2013) (74)
Gd(DTPA‐bisamide)alkyl Copolymers: A Hint for the Formation of MRI Contrast Agents with Very High Relaxivity (1999) (74)
Magnetic‐Field‐Dependent Electronic Relaxation of Gd3+ in Aqueous Solutions of the Complexes [Gd(H2O)8]3+, [Gd(propane‐1,3‐diamine‐N,N,N′,N′‐tetraacetate)(H2O)2]−, and [Gd(N,N′‐bis[(N‐methylcarbamoyl)methyl]‐3‐azapentane‐1,5‐diamine‐3,N,N′‐triacetate)(H2O)] of interest in magnetic‐resonance imaging (1993) (72)
Molecular Dynamics Simulation Study of Lanthanide Ions Ln3+ in Aqueous Solution. Analysis of the Structure of the First Hydration Shell and of the Origin of Symmetry Fluctuations (1995) (70)
First in vivo MRI assessment of a self-assembled metallostar compound endowed with a remarkable high field relaxivity. (2006) (69)
Structure and reactivity of ruthenium half-sandwich compounds: crystal and molecular structure and acetonitrile exchange kinetics and mechanism of tris(acetonitrile)(h6-benzene)ruthenium(2+) and tris(acetonitrile)(h5-cyclopentadienyl)ruthenium(+) (1991) (67)
Gadolinium(III) complexes of mono- and diethyl esters of monophosphonic acid analogue of DOTA as potential MRI contrast agents: solution structures and relaxometric studies. (2007) (67)
Accelerating water exchange for GdIII chelates by steric compression around the water binding site. (2002) (67)
A highly stable gadolinium complex with a fast, associative mechanism of water exchange. (2003) (66)
Interpretation of Activation Volumes for Water Exchange Reactions Revisited: Ab Initio Calculations for Al3+, Ga3+, and In3+, and New Experimental Data (1998) (66)
Raman and infrared study of hexamethylphosphoramide complexes of lanthanide perchlorates (1975) (64)
A benzene-core trinuclear GdIII complex: towards the optimization of relaxivity for MRI contrast agent applications at high magnetic field. (2008) (63)
High pressure NMR kinetics. 19. Variable pressure and temperature nuclear magnetic resonance and visible spectrophotometric studies of lanthanide ions in dimethylformamide: solvation and solvent exchange dynamics (1983) (63)
Similarities and differences between the isoelectronic GdIII and EuII complexes with regard to MRI contrast agent applications (2001) (63)
High pressure kinetics. A decisive dimension in mechanistic studies of inorganic reactions (1992) (62)
NUCLEAR AND ELECTRONIC RELAXATION OF EU2+(AQ): AN EXTREMELY LABILE AQUA ION (1999) (62)
Structures and Dynamics of Lanthanide(III) Complexes of Sugar-Based DTPA-bis(amides) in Aqueous Solution: A Multinuclear NMR Study (1997) (62)
Understanding paramagnetic relaxation phenomena for water-soluble gadofullerenes (2007) (62)
Towards rational design of fast water-exchanging Gd(dota-like) contrast agents? Importance of the M/m ratio. (2001) (61)
Reactivity of the organometallic fac-[(CO)3ReI(H2O)3]+ aquaion. Kinetic and thermodynamic properties of H2O substitution. (2003) (61)
A general approach to the electronic spin relaxation of Gd(III) complexes in solutions. Monte Carlo simulations beyond the Redfield limit (2001) (61)
Second-order globalisation for the determination of activation parameters in kinetics (1994) (60)
Adducts of tin(IV) tetrahalides with neutral Lewis bases. I. Vibrational study of the cis-trans isomerism in solution (1976) (60)
Fine-tuning water exchange on Gd(III) poly(amino carboxylates) by modulation of steric crowding. (2005) (60)
Self-assembly of multinuclear coordination species with chiral bipyridine ligands: silver complexes of 5,6-CHIRAGEN(o,m,p-xylidene) ligands and equilibrium behaviour in solution. (2001) (59)
Molecular dynamics simulations of MRI-relevant GdIII chelates: direct access to outer-sphere relaxivity. (2001) (59)
Coordination equilibrium— a clue for fast water exchange on potential magnetic resonance imaging contrast agents? (1999) (59)
A COMPARISON OF THE LABILITY OF MONONUCLEAR OCTAHEDRAL AND DINUCLEAR TRIPLE-HELICAL COMPLEXES OF COBALT(II) (1997) (59)
[CpRu((R)-Binop-F)(H2O)][SbF6], a new fluxional chiral Lewis acid catalyst: synthesis, dynamic nmr, asymmetric catalysis, and theoretical studies. (2004) (57)
Novel macrocyclic EuII complexes: fast water exchange related to an extreme M-O water distance. (2003) (57)
A high-frequency EPR study of frozen solutions of Gd(III) complexes: straightforward determination of the zero-field splitting parameters and simulation of the NMRD profiles. (2006) (57)
Unexpectedly large change of water exchange rate and mechanism on [Ln(DTPA-BMA)(H2O)] complexes along the lanthanide(III) series (1995) (57)
Structural Investigation of the Aqueous Eu2+ Ion: Comparison with Sr2+ Using the XAFS Technique (2002) (55)
Supramolecular assembly of an amphiphilic Gd(III) chelate: tuning the reorientational correlation time and the water exchange rate. (2006) (55)
High-pressure NMR kinetics. Part 41. Dissociative substitution in four-coordinate planar platinum(II) complexes as evidenced by variable-pressure high-resolution proton NMR magnetization transfer experiments (1989) (55)
How does internal motion influence the relaxation of the water protons in Ln(III)DOTA-like complexes? (2002) (55)
Two approaches to high-resolution high-pressure nuclear magnetic resonance☆☆☆ (1978) (54)
Oxygen‐17 NMR and EPR studies of water exchange from the first coordination sphere of gadolinium(III) aquoion and gadolinium(III) propylenediaminetetra‐acetate (1980) (53)
Applications of advanced experimental techniques: high pressure NMR and computer simulationsBased on the presentation given at Dalton Discussion No. 4, 10–13th January 2002, Kloster Banz, Germany. (2002) (53)
A Multinuclear NMR Study on the Structure and Dynamics of Lanthanide(III) Complexes of the Poly(amino carboxylate) EGTA4- in Aqueous Solution (1997) (53)
Second Coordination Shell Water Exchange Rate and Mechanism: Experiments and Modeling on Hexaaquachromium(III) (1996) (52)
Solution and Solid‐State Characterization of EuII Chelates: A Possible Route Towards Redox Responsive MRI Contrast Agents (2000) (51)
Water Exchange and Rotational Dynamics of the Dimeric Gadolinium(III) Complex [BO{Gd(DO3A)(H(2)O)}(2)]: A Variable-Temperature and -Pressure (17)O NMR Study(1). (1996) (51)
Direct measurement of a prominent outer-sphere electron self-exchange: kinetic parameters for the hexaaquaruthenium(II)/(III) couple determined by oxygen-17 and ruthenium-99 NMR (1985) (51)
High-Pressure Studies as a Novel Approach in Determining Inclusion Mechanisms: Thermodynamics and Kinetics of the Host-Guest Interactions for a-Cyclodextrin Complexes (2000) (51)
Crystal structure of and mechanism of water exchange on (Mo sub 3 O sub 4 (OH) sub 2 sub 9 ) sup 4+ from x-ray and oxygen-17 NMR studies (1989) (50)
Tetrasolventoberyllium(II): high-pressure evidence for a sterically controlled solvent-exchange mechanism crossover (1990) (50)
High-pressure NMR kinetics. 21. Activation parameters and mechanism for water exchange of tetraaquaplatinum(II) studied by high-pressure oxygen-17 NMR spectroscopy (1985) (48)
Dinuclear, bishydrated Gd(III) polyaminocarboxylates with a rigid xylene core display remarkable proton relaxivities. (2005) (47)
The effect of pyridinecarboxylate chelating groups on the stability and electronic relaxation of gadolinium complexes. (2005) (45)
Unexpected Differences in the Dynamics and in the Nuclear and Electronic Relaxation Properties of the Isoelectronic [EuII(DTPA)(H2O)]3- and [GdIII(DTPA)(H2O)]2- Complexes (DTPA = Diethylenetriamine Pentaacetate)1 (2000) (45)
Lipari-Szabo approach as a tool for the analysis of macromolecular gadolinium(III)-based MRI contrast agents illustrated by the [Gd(EGTA-BA-(CH2)12)]nn+ polymer (2001) (45)
Novel heteroditopic chelate for self-assembled gadolinium(III) complex with high relaxivity. (2004) (45)
Structure and Dynamics of a Trinuclear Gadolinium(III) Complex: The Effect of Intramolecular Electron Spin Relaxation on Its Proton Relaxivity(1). (1998) (44)
Solvent exchange on metal ions (2003) (44)
Trinuclear Lanthanoid Complexes of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol with a Unique, Sandwich-Type Cage Structure(1). (1998) (44)
Evidence for a Chelate-Induced Changeover in the Substitution Mechanism of Aquated Copper(II). Volume Profile Analyses of Water Exchange and Complex-Formation Reactions (1994) (43)
Solid-state and solution properties of the lanthanide complexes of a new heptadentate tripodal ligand: a route to gadolinium complexes with an improved relaxation efficiency. (2001) (43)
139La NMR and quantitative FT-IR investigation of the interaction between Ln(III) ions and various anions in organic solvents (1987) (42)
High pressure NMR kinetics. Part 30. Water exchange on hexaaquagallium(III): high-pressure evidence for a dissociative exchange mechanism (1987) (42)
High-pressure stopped-flow spectrometer for kinetic studies of fast reactions by absorbance and fluorescence detection. (1996) (41)
Direct assessment of water exchange on a Gd(III) chelate bound to a protein (1998) (41)
Mono- and bimetallic lanthanide(III) phenolic cryptates obtained by template reaction: solid state structure, photophysical properties and relaxivity † (2000) (41)
Mechanisms of Water Exchange between Lanthanide(III) Aqua Ions [Ln(H2O)n]3+ and bulk water: A Molecular Dynamics Simulation Approach Including High‐Pressure Effects (1996) (41)
NMR conformational study of the lanthanide(III) complexes of DOTA in aqueous solution (1995) (41)
Mechanistic aspects of the reversible binding of SO2 on arylplatinum complexes: Experimental and ab initio studies (2001) (40)
Functionalization of PAMAM dendrimers with nitronyl nitroxide radicals as models for the outer‐sphere relaxation in dentritic potential MRI contrast agents (2003) (40)
Gadolinium‐based linear polymer with temperature‐independent proton relaxivities: a unique interplay between the water exchange and rotational contributions (1998) (40)
TUNING WATER-EXCHANGE RATES ON (CARBOXYMETHYL)IMINOBIS-(ETHYLENENITRILO)TETRAACETATE (DTPA)-TYPE GADOLINIUM(III) COMPLEXES (1997) (40)
Variable‐pressure oxygen‐17 NMR study of water exchange on hexaaquarhodium(III) (1991) (40)
Inorganic and Bioinorganic Solvent Exchange Mechanisms (2005) (39)
Kinetics and mechanism of solvent-exchange and anation reactions of sterically hindered diethylenetriamine complexes of palladium(II) in aqueous solution (1989) (38)
Relevance of the ligand exchange rate and mechanism of fac-[(CO)3M(H2O)3]+ (M = Mn, Tc, Re) complexes for new radiopharmaceuticals. (2006) (38)
Solvent Exchange and Jahn-Teller Inversion on Cu2+ in Water and N,N'-Dimethylformamide: A High-Pressure 17O NMR Study (1995) (37)
Phosphinic derivative of DTPA conjugated to a G5 PAMAM dendrimer: an 17O and 1H relaxation study of its Gd(III) complex. (2006) (37)
Molecular dynamics simulation of [Gd(egta)(H(2)O)](-) in aqueous solution: internal motions of the poly(amino carboxylate) and water ligands, and rotational correlation times. (2002) (37)
High-pressure NMR kinetics. 6. Oxygen-17 PT NMR study of the effect of pressure on the exchange of water on nickel(II) (1979) (36)
Water contributes actively to the rapid crossing of a protein unfolding barrier. (2002) (36)
High pressure NMR kinetics. 8. High-pressure kinetic evidence for an associative-dissociative changeover for solvent exchange mechanism on the divalent metal ions along the first-row transition metals (1979) (35)
High-pressure, high-resolution NMR probe working at 400 MHZ (1990) (35)
Adducts of tin(IV) tetrahalides with neutral Lewis bases. II. Quantitative study of the Cis-trans equilibria by NMR (1977) (35)
In vivo MRI assessment of a novel GdIII-based contrast agent designed for high magnetic field applications. (2008) (34)
Multiexponential electronic spin relaxation and Redfield's limit in Gd(III) complexes in solution: consequences for 17O/1H NMR and EPR simultaneous analysis. (2002) (34)
Synthesis, variable temperature and pressure 17O NMR study of bis(alkylamide) derivatives of [(Gd-DTPA)(H2O)]2- - An assessment of the substitution effect on water exchange kinetics (2002) (33)
Complete Carbonylation of fac‐[Tc(H2O)3(CO)3]+ under CO Pressure in Aqueous Media: A Single Sample Story! (2000) (33)
A new heptadentate tripodal ligand leading to a gadolinium complex with an improved relaxation efficiency (2001) (32)
A high-pressure probe for high-resolution nuclear magnetic resonance☆☆☆ (1978) (32)
Unexpected aggregation of neutral, xylene-cored dinuclear GdIII chelates in aqueous solution. (2006) (31)
MD simulations of acyclic and macrocyclic Gd3+-based MRI contrast agents: influence of the internal mobility on water proton relaxivity. (2003) (31)
Adducts of titanium tetrahalides with neutral Lewis bases. Part I. Structure and stability: a vibrational and multinuclear NMR study (1987) (31)
Design of Gd(III)-based magnetic resonance imaging contrast agents: static and transient zero-field splitting contributions to the electronic relaxation and their impact on relaxivity. (2007) (30)
High pressure NMR kinetics. 29. Variable-temperature, -pressure, and -frequency oxygen-17 NMR study of water exchange on hexaaquatitanium(III): a limiting associative mechanism? (1987) (30)
IONIZATION OF STRONG ELECTROLYTES XI. THE MOLECULAR STATES OF NITRIC ACID AND PERCHLORIC ACID (1968) (29)
Destruction of perfluoroalkyl surfactant aggregates by β-cyclodextrin (2004) (29)
Mechanistic changeover for the water substitution on fac-[(CO)3Re(H2O)3]+ revealed by high-pressure NMR. (2004) (28)
Formation and in situ characterization of the first dihydrogen aqua complex: [Ru(H2O)5(H2)]2+ (1998) (28)
High-pressure thermodynamic and kinetic NMR study of nonacarbonyl(m3-(1,3,5-trithiane)tetrairidium: the "merry-go-round" process (1992) (27)
EPR on aqueous Gd3+ complexes and a new analysis method considering both line widths and shifts (2000) (27)
High-pressure stopped-flow study of the complexation of vanadium(II) with thiocyanate in water: further evidence for the associative character of substitution on this metal ion (1983) (27)
Syntheses and crystal and molecular structures of the hexakis(N,N-dimethylformamide) complexes of ruthenium(II) and ruthenium(III) (1995) (26)
Solvent exchange in hexakis(methanol)copper(II) ion. Oxygen-17 NMR variable-temperature, pressure, and frequency study (1986) (26)
High-pressure NMR kinetics. 47. Solvent-exchange mechanisms of nonaqueous square-planar tetrasolvates: a high-pressure proton NMR investigation (1991) (26)
T1e in four Gd3+ chelates: LODEPR measurements and models for electron spin relaxation (2002) (26)
Effect of pressure on the rates of sigmatropic shifts. Volume as an indication of a wide mechanistic range (1983) (25)
Kinetic studies on the first dihydrogen aquacomplex, [Ru(H2)(H2O)5]2+ : Formation under H2 pressure and catalytic H/D isotope exchange in water (2006) (25)
A novel 3D Nd(III)–Bi(III) coordination polymer generated from EDTA ligand (2004) (25)
Proton NMR kinetic study of ligand exchange on bis(1,4-dithiane)platinum(II), bis(1,4-dithiane)palladium(II), and tetrakis(dimethyl sulfide)platinum(II) (1991) (25)
Trans- and Cis-Water Reactivities in d(6) Octahedral Ruthenium(II) Pentaaqua Complexes: Experimental and Density Functional Theory Studies(1)(,)(2). (1997) (25)
High-pressure nuclear magnetic resonance kinetics. 5. Proton nuclear magnetic resonance study of the effect of pressure on the exchange of nonaqueous solvents on nickel(II) and cobalt(II) (1979) (24)
Equilibrium behavior and proton transfer kinetics of the dioxotetracyanometalate complexes of molybdenum(IV), tungsten(IV), technetium(V), and rhenium(V): carbon-13 and oxygen-17 NMR study (1994) (24)
Spectroscopic Study of the Hydration Equilibria and Water Exchange Dynamics of Lanthanide(III) Complexes of 1,7-Bis(carboxymethyl)-1,4,7,10-tetraazacyclododecane (DO2A) (2000) (24)
Rhodium(III) and Iridium(III) Solvates of the Form [(h5-C5Me5)M(S)3]2+ as Models for the Reactivity of Half-Sandwich Compounds (1997) (24)
A model for sequential threading of alpha-cyclodextrin onto a guest: a complete thermodynamic and kinetic study in water. (2001) (23)
Solution X-ray Absorption Fine Structure Study of the Eu2+ and Sr2+ Ions: Unexpected Solvent and Metal Ion Dependencies of the Solvation Numbers (2002) (23)
High pressure NMR kinetics. Part 22. Mechanism of dimethyl sulfide intermolecular exchange and trans-cis isomerization of tin tetrachloride-2 dimethyl sulfide (SnCl4.cntdot.2Me2S). Variable-pressure proton NMR and variable-temperature tin-119 magnetization transfer NMR studies (1985) (23)
Volumes of Activation for Dimethylsulfoxide and N,N‐Dimethylformamide Exchange with Hexasolvates of Aluminium (III) and Gallium (III) Ions in Deuterionitromethane Solution (1980) (23)
The binding of dinitrogen to ruthenium(II) in aqueous solution (1991) (22)
An extreme water exchange rate: the europium(II) aqua ion (1997) (22)
Oxidation of mixed-valence Co(III)/Fe(II) complexes reversed at high pH: a kinetico-mechanistic study of water oxidation. (2004) (22)
Adducts of tin(IV) tetrahalides with neutral lewis bases. III. Dynamic study by NMR (1977) (22)
Monocomplex formation reactions of hexaaquaruthenium(II): a mechanistic study (1993) (21)
ACCURATE NMR TEMPERATURE MEASUREMENTS (1965) (21)
High Resolution Variable Pressure NMR for Chemical Kinetics (1990) (21)
High pressure carbon-13 FT-NMR. Acetonitrile exchange with [Co(CH3CN)6](ClO4)2 (1981) (21)
Mechanistic Investigation on the Water Substitution in the η5-Organometallic Complexes Cp*Ir(H2O)32+ and Cp*Rh(H2O)32+ (1999) (21)
Lanthanide(III) chelates of DTPA bis(amide) glycoconjugates: potential imaging agents targeted at the asyaloglycoprotein receptor (2005) (21)
Steric Effects on Water-Exchange Mechanisms of Aquapentakis(amine)metal(III) Complexes (Metal = Chromium, Cobalt, Rhodium). A Variable-Pressure Oxygen-17 NMR Study (1994) (21)
High-pressure NMR kinetics. Part 14. High-pressure NMR evidence for an associative interchange mechanism, Ia, for solvent exchange on iron(III) (1982) (21)
17O-NMR, EPR, and NMRD characterization of [Gd(DTPA-BMEA)(H2O)]. A neutral MRI contrast agent (1998) (20)
High-pressure, high-resolution nuclear magnetic resonance (HPHR-NMR): a tool in chemical kinetics (1977) (20)
Can octahedral t2g6 complexes substitute associatively? The case of the isoelectronic ruthenium(II) and rhodium(III) hexaaquaions. (2000) (20)
Dimethylformamide-Exchange Mechanism on Some First-Row Divalent Transition-Metal Ions†‡§ (1987) (20)
Lanthanide(III)–1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid complexes in acidic medium: significant decrease in water exchange rate† (1999) (20)
Monte Carlo simulations of the tripositive lanthanide ions in aqueous solution (1993) (20)
The first measurements of activation volumes for hydride fluxionality on metal clusters. Intramolecular exchange of hydrides on osmium and ruthenium complexes, H(.mu.-H)Os3(CO)10(PPh3) and (.mu.-H)2Ru3(.mu.3-CHCO2Me)(CO)9 (1991) (19)
A tripod gadolinium(III) poly(amino carboxylate) relevant to magnetic resonance imaging: structural and dynamical 17O NMR and 1H NMRD studies (1998) (19)
Variable temperature multinuclear NMR. Investigation of dimethylformamide exchange on the octakis (N,N‐dimethylformamide)‐thulium(III) ion (1982) (19)
Quantitative Formation in Water of [Ru(CO)(H2O)5]2+ from Hexaaquaruthenium(II) and Carbon Monoxide (1991) (19)
High-pressure kinetic study of formation and dissociation of first- and second-row d10 divalent metal ion complexes with bipyridine in aqueous solution: a cation size dependent reaction mechanism (1988) (19)
13C and (15)N NMR Mechanistic Study of Cyanide Exchange on Oxotetracyanometalate Complexes of Re(V), Tc(V), W(IV), Mo(IV), and Os(VI). (1998) (19)
NMR study of ligand exchange and electron self-exchange between oxo-centered trinuclear clusters [Fe3(μ3-O)(μ-O2CR)6(4-R'py)3](+/0). (2011) (19)
Variable-pressure kinetic and equilibrium study of monocomplex formation of copper(II) and zinc(II) with 2-chloro-1,10-phenanthroline in aqueous solution (1989) (18)
Mechanistic diversity covering 15 orders of magnitude in rates: cyanide exchange on [M(CN)(4)](2-) (M = Ni, Pd, and Pt). (2002) (18)
Mechanism of substitution on trinuclear incomplete cuboidal [M3X4(OH2)9]4+ ions: kinetic studies of water exchange and substitution by Cl– on [Mo3S4(OH2)9]4+ (1993) (18)
Variable pressure spectrophotometric equilibrium and 139La NMR kinetic studies of lanthanum (III) ion complex formation with 2,6-dicarboxy-4-hydroxypyridine in aqueous solution (1989) (18)
High-pressure NMR kinetics. Part 9. High-pressure oxygen-17 Fourier-transform NMR. Evidence for the associative nature of substitution reactions on manganese(2+) in water (1979) (18)
Planning a kinetic and mechanistic study with cerium(IV) (1976) (18)
Kinetic and Mechanistic Studies of Substitution Reactions of Solvated Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Ions with 2,2′:6′,2″-Terpyridine and Several 2,2′:6′,2″-Terpyridine Derivatives. Evidence for the Formation of Intermediates (2001) (18)
Water exchange kinetics on lanthanide(III) ions: a variable temperature and pressure 17O NMR study (1987) (18)
Multinuclear NMR Studies of Ligand-Exchange Reactions on Analogous Technetium(V) and Rhenium(V) Complexes. Relevance to nuclear medicine (1992) (18)
Adducts of niobium(V) and tantalum(V) halides. XII. Dissociative-associative crossover for the ligand-substitution mechanism in octahedral adducts of niobium(V) and tantalum(V) halides (1975) (18)
Nuclear magnetic resonance study of praseodymium europium ytterbium ethylenediaminetetraacetates (1978) (18)
Structural elucidation of oligomeric aqua-molybdenum cations in solution by 17O NMR (1987) (18)
Five coordinate tetramethylcyclam complexes of Co(II) and Ni(II); associative interchange and dissociative mechanisms for solvent exchange in acetonitrile (1983) (17)
The Reaction Volume for the Equilibrium between the Lanthanide (III) ennea- and octaaqua lons as a diagnostic aid for their water-exchange mechanisms. Preliminary Communication (1988) (17)
Adducts of Niobium(V) and Tantalum(V) Halogenides. IX. Relative stability of the adducts of the chlorides and bromides with some dialkylchalcogenides (1974) (17)
Aqueous catalytic dimerisation of ethylene: characterization of the reaction intermediates [Ru(CH2CH2)(H2O)5](tos)2 and [Ru(CH2CH2)2(H2O)4](tos)2(tos = toluene-p-sulfonate) (1993) (16)
Synthesis and complexation properties of DTPA-N,N''-bis[bis(n-butyl)]-N'-methyl-tris(amide). Kinetic stability and water exchange of its Gd3+ complex. (2005) (16)
High pressure nuclear magnetic resonance kinetics. 3. Proton nuclear magnetic resonance study of the effect of temperature and pressure on the exchange of acetonitrile on nickel(II) (1979) (16)
Variable-pressure study of a molybdenum(III) reaction: first definitive evidence for the associative nature of complex formation on hexaaquamolybdenum(III) (1987) (16)
The organometallic fac-[(CO)3Mn(H2O)3]+ aquaion: base-hydrolysis and kinetics of H2O-substitution. (2004) (16)
Multiple-Frequency and Variable-Temperature EPR Study of Gadolinium(III) Complexes with Polyaminocarboxylates: Analysis and Comparison of the Magnetically Dilute Powder and the Frozen-Solution Spectra (2009) (16)
Mechanism of pyridine-ligand exchanges at the different labile sites of 3d heterometallic and mixed valence mu3-oxo trinuclear clusters. (2008) (16)
Activation Volumes of Substitution Reactions on Neutral and Cationic Organometallic Platinum(IV) Complexes: Definite Proof of Selective Associative Activation (2004) (16)
Solution kinetic behaviour of lanthanide (III) polyaminocarboxylates from oxygen-17 NMR studies (1995) (16)
Proton nuclear magnetic resonance study of N,N-dimethylformamide exchange on (N,N-dimethylformamide)(2,2",2""-tris(dimethylamino)triethylamine)manganese(II) and its cobalt(II) and copper(II) analogs (1984) (15)
High-pressure NMR kinetics. 36. 1H NMR kinetic study of dimethyl sulfoxide exchange on tetrakis(dimethyl sulfoxide)platinum(II) at variable temperature and pressure (1989) (15)
Carbon-13 and argon-17, NMR studies of the solution and equilibrium behavior of selected oxocyanorhenate(V) complexes (1992) (15)
High-pressure NMR kinetics. 7. High-pressure NMR evidence for the dissociative-associative crossover in the ligand substitution mechanism of octahedral adducts of niobium(V) and tantalum(V) halides (1979) (15)
High-pressure proton NMR study of acetonitrile exchange kinetics on [Rh2(CH3CN)10]4+ and 17O NMR investigation of aqueous solutions of [Rh2(H2O)10]4 + (1993) (14)
Substitution Studies of Second- and Third-Row Transition Metal OXO Complexes (2000) (14)
Aspects of aqueous ruthenium(II) chemistry (2001) (14)
Positively charged GdIII cryptates: slow, associative water exchange. (2006) (14)
Structure and dynamics of lanthanide ions and lanthanide complexes in solution (1994) (14)
Stereochemically nonrigid pentacoordinate nickel(II) complexes. X-ray structure of bromotetrakis(trimethylphosphine)nickel(II) tetrafluoroborate and the solution study of [NiX(PMe3)4]BF4 (X = chlorine, bromine, iodine) (1978) (14)
Gd3+ chelates of interest in magnetic resonance imaging (MRI): studies using 17O NMR and EPR at several magnetic fields (1994) (14)
Variable pressure kinetic and equilibrium study of the complexation of the beryllium(II) ion with 4-isopropyltropolone in acidic aqueous solution (1991) (13)
Towards binuclear polyaminocarboxylate MRI contrast agents? Spectroscopic and MD study of the peculiar aqueous behavior of the LnIII chelates of OHEC (Ln=Eu, Gd, and Tb): implications for relaxivity. (2003) (13)
Kinetics and thermodynamics for complex formation between palladium(II) and dimethyl sulfoxide as a function of temperature and pressure (1987) (13)
Solution structure and dynamics of five-Coordinate nickel(II) complexes with trimethylphosphine (1979) (13)
Molecular tweezers as synthetic receptors: the effect of pressure and temperature on the formation of host-guest complexes (2002) (13)
Variable-temperature and variable-pressure 1H NMR studies of dimethylsulfide exchange on trans-bis(dimethylsulfide)dichloropalladium(II) in various solvent [1] (1983) (12)
Adducts of titanium tetrahalides with neutral Lewis bases. Part II. Kinetics and reaction mechanism: a variable temperature and variable pressure proton NMR study (1986) (12)
HPLC separation of diastereomers of Ln(III)-ethylenepropylene-triamine-pentaacetate complexes. Direct assessment of their water exchange rate. (2003) (12)
Mechanism of Complex Formation of Ruthenium(II) Aquacomplexes with H2C:CH2, MeCN, Me2SO, and CO: Metal-Water Bond Rupture as Rate-Determining Step (1998) (12)
Variable‐Temperature and ‐Pressure 31P‐NMR Study of the Intramolecular PPh3 Migration in the Cluster Compound [Ir2Rh2(CO)11PPh3] (1994) (12)
Calculated volume and energy profiles for water exchange on t2g6 rhodium(III) and iridium(III) hexaaquaions: conclusive evidence for an Ia mechanism. (2004) (12)
Kinetics and mechanism of complex formation of nickel(II) with tetra-N-alkylated cyclam in N,N-dimethylformamide (DMF): comparative study on the reactivity and solvent exchange of the species Ni(DMF)6(2+) and Ni(DMF)5Cl+. (2000) (12)
NMR study of ternary complexes of some paramagnetic lanthanide ethylenediaminetetraacetates with iminodiacetate, methyliminodiacetate and cetate nitrilotriacetate☆☆☆ (1978) (12)
A PCP‐Pincer RuII–Terpyridine Building Block as a Potential “Antenna Unit” for Intramolecular Sensitization (2007) (12)
Adducts of zirconium and hafnium tetrachlorides with neutral Lewis bases. Part I. Structure and stability: a vibrational and NMR study (1990) (12)
Nuclear magnetic resonance studies of rare earths polyaminocarboxylates. IV. Nitrilotriacetates [1, 2] (1978) (12)
Stopped-flow fourier-transform NMR and NMR line broadening studies of the rates of dimethyl sulphoxide exchange with the hexakis(dimethylsulphoxide) complexes of aluminium(III), gallium(III) ions in nitromethane solution (1980) (11)
Kinetics and Mechanism of Oxygen Exchange and Inversion along the M:O Axis in the Diprotonated and Monoprotonated Dioxotetracyanometalate Complexes of Re(V), Tc(V), W(IV), and Mo(IV) (1995) (11)
Speciation and kinetics related to catalytic carbonylation in the presence of cis-[Ir(CO)2I2]P(C6H5)4 under CO and H2 pressures. (2000) (11)
Isomerization mechanisms of stereolabile tris- and bis-bidentate octahedral cobalt(II) complexes: X-ray structure and variable temperature and pressure NMR kinetic investigations. (2010) (11)
Mechanism of CO exchange on cis-[M(CO)2X2]- complexes (M=Rh,Ir;X=Cl, Br, or I). (2000) (11)
A Demonstrated Example of Competing D and Id Mechanisms for Dimethylformamide Exchange on the Octakis (dimethylformamide)-erbium (III) Ion (1983) (10)
Separation and characterization of the two diastereomers for [Gd(DTPA-bz-NH2)(H2O)]2-, a common synthon in macromolecular MRI contrast agents: their water exchange and isomerization kinetics. (2005) (10)
The rate of the hexa-aquaruthenium (II)/(III)self exchange reaction: 17O and 99Ru n.m.r. spectroscopic studies (1984) (10)
Determination of the rate of cis/trans isomerization of the octahedral adducts of Tin(IV) tetrachloride with dimethyl sulfide by tin-119 NMR magnetization transfer (1984) (10)
Lanthanide ions as magnetic resonance imaging agents. Nuclear and electronic relaxation properties. Applications. (2003) (9)
High-pressure NMR kinetics. 55. Mechanisms of axial and equatorial dimethyl sulfoxide exchange on pentakis(dimethyl sulfoxide) oxotitanium(2+). A variable-temperature and -pressure proton NMR study (1992) (9)
High-pressure NMR kinetics. 54. N,N-dimethylformamide exchange on hexakis(N,N-dimethylformamide)titanium(III): a variable-temperature and pressure proton and oxygen-17 NMR study (1992) (9)
Adducts of zirconium and hafnium tetrachlorides with neutral Lewis bases. 2. Kinetics and mechanism: a variable-temperature and -pressure proton NMR study (1990) (9)
Cyanide and chloride exchange on homoleptic gold(III) square-planar complexes: variable pressure kinetic investigation by heteronuclear NMR☆ (2002) (9)
Intramolecular dynamics of five-coordinate iron carbonyl complexes with olefinic ligands as studied by variable-pressure 1H-NMR spectroscopy (1988) (9)
A Variable‐Pressure 2D 1H‐NMR Study of the Mechanism of Trimethyl Phosphate Intermolecular Exchange and cis/trains‐Isomerisation of Tetrachlorobis(trimethyl phosphate)zirconium(IV) (1990) (8)
Lanthanide Complexes Formed with the Tri- and Tetraacetate Derivatives of Bis(aminomethyl)phosphinic Acid: Equilibrium, Kinetic and NMR Spectroscopic Studies (2012) (8)
HIGH PRESSURE NUCLEAR MAGNETIC RESONANCE KINETICS. 3. PROTON NUCLEAR MAGNETIC C RESONANCE STUDY OF THE EFFECT OF TEMPERATURE AND PRESSURE ON THE EXCHANGE OF ACETONITRILE ON NICKEL(II) (1979) (8)
Adducts of niobium(V) and tantalum(V) halides. XIV. Structure and relative stability of the adducts with some phosphoryl compounds (1976) (8)
Adducts of antimony(V) pentachloride with neutral Lewis bases. Part I. Structure and stability: a vibrational and NMR study (1986) (8)
Solution and solid-state characterization of Eu(II) chelates: a possible route towards redox responsive MRI contrast agents. (2000) (8)
Kinetics of Solvent Exchange Reactions at High Pressure (1988) (8)
A 1H NMR rate study of nitriles adducts with NbCl5 and TaCl5 (1969) (8)
UV–Vis observation of different transitions for both isomeric species in Eu(III) DOTA-like complexes (2001) (7)
Coordination equilibrium in an Ln(III) macrocyclic chelate modulated by a reversible interaction with a weakly donor substituent (2002) (7)
Electron Transfer Spectra of Some Adducts of Niobium (V), Tantalum (V), Titanium (IV) and Zirconium (IV) Halides with Lewis Bases† (1975) (7)
Metal Complexes as MRI Contrast Enhancement Agents (2004) (7)
The Periodic Table and Kinetics? (2019) (7)
High-pressure NMR kinetics. 52. Variable-temperature and -pressure studies of solvent exchange, complex formation, and dissociation of vanadium(III) in DMSO (1992) (7)
Activation volume for ligand exchange in labile tetrahedral complexes: triphenylphosphine (TPP) exchange with dibromobis(triphenylphosphine)cobalt by high-pressure proton NMR (1979) (7)
Structural XAFS Investigation of Eu2+ and Sr2+ Poly(amino carboxylates): Consequences for Water Exchange Rates on MRI-Relevant Complexes (2003) (6)
Applications of Advanced Experimental Techniques: High Pressure NMR and Computer Simulations (2002) (6)
Variable-temperature and variable-pressure 1H NMR studies of R,S,S,R-1,4,8,11-Tetramethyl-1,4,8,11-Tetraazacyclotetradecanenickel(II) perchlorate in aqueous solution (1980) (6)
Relatively slow water exchange in a pentaco-ordinate macrocyclic cobalt(II) complex (1977) (6)
Variable-Pressure Kinetic Study of Formation and Dissociation of Octahedral Divalent Metal Ion Monocomplexes in N,N-Dimethylformamide: Dissociative Reaction Mechanisms through the First Row from Manganese to Nickel (1989) (6)
Interpretation of volumes of activation and the effect of bond length changes of the nonexchanging ligands (1980) (6)
Water Exchange on Metal Ions: The Effect of Pressure (2002) (6)
Kinetic study and crystal structure of tetrakis(1,4-thioxane)palladium(II). A comparison between platinum(II) and palladium(II) reactivity (1997) (5)
Water exchange dynamics: the key for high relaxivity contrast agents in medical magnetic resonance imaging (1998) (5)
Solvent Effects on Solvent Exchange Reactions at Nickel(II) Centers (1975) (5)
The Mechanism of Solvent Exchange on the Hexakis(trimethylphosphate)scandium(III) Ion. A Variable Temperature and Variable Pressure Scandium-45 NMR Study [1] (1987) (5)
Water-exchange study revealed unexpected substitution behavior of [(CO)2(NO)Re(H2O)3]2+ in aqueous media. (2006) (5)
Structure and dynamics of lanthanide(III) ions in solution: a neutron scattering contribution (1991) (5)
Variable-temperature and variable-pressure kinetic and equilibrium studies of formation and dissociation of [V(H2O)5NCS]2+ (1989) (5)
The first high-pressure high-resolution NMR probe for a normal bore cryomagnet1 (1994) (5)
Volume profile of the degenerate equilibration of a classical norbornyl ion (1979) (5)
Variable-pressure 1H NMR studies of hexamethylphosphoramide and trimethyl phosphate exchange on dioxouranium(VI) (1993) (4)
Pressure effect of the proton NMR spectra of organic compounds in the presence of lanthanide shift reagents. A formally associative process characterized by volume expansion (1987) (4)
Ionization of strong electrolytes. IX. Proton magnetic resonance in the ternary system HNO3-DNO3-H2O-D2O (1967) (4)
Electron transfer spectra of the hexachloro- and hexabromoniobate(V) and tantalate(V) anions (1974) (4)
Volume profile of the degenerate equilibration of a nonclassical 7-norbornadienyl cation (1981) (4)
Temperature measurement under high pressure using commercial platinum resistors (1979) (4)
Ligand Effects on the Rate and Mechanism of Solvent Exchange at Rhodium(III) and Iridium(III) (1996) (4)
Variable temperature proton (8 to 360 MHz) and carbon-13 (50 MHz) N.M.R. study of the dimethylsulphoxide exchange on iron(III) (1982) (4)
Dimethyl formamide exchange on hexakis (dimethyl formamide)-magnesium (II): A1H NMR high-pressure study (1991) (4)
Intramolecular site exchange of carbonyl ligands in the cluster compounds nonacarbonyl {μ3-[η3-(1,3,5-trithiane)]}triruthenium ([Ru3(CO)9{μ3-(η3-C3H6S3)}]) and (tert-butyl isocyanide)octacarbonyl-{μ3-[η3-(1,3,5-trithiane)]}triruthenium ([Ru3(t-BuNC)(CO)8{μ3-(η3-C3H6S3)}]) (1993) (4)
Mixed trimethylphosphine—trimethylphosphite pentacoordinate d8 nickel(II) complexes (1980) (3)
Solution structure and ligand exchange in the five-coordinate molecular complexes NiX2(PMe3)3 (1976) (3)
Mechanistic information from a high pressure nuclear magnetic resonance study of methanol exchange between hexamethanolnickel(II) and solvent (1977) (3)
Adducts of niobium(V) and tantalum(V) halides. XV. Ligand exchange of the adducts with some phosphoryl compounds (1977) (3)
High-pressure stopped-flow study of complex formation on nickel(II) ion in dimethylformamide. Possible existence of a 5-coordinate intermediate (1984) (3)
High pressure 17O NMR study of solvent exchange on square planar complexes: Water exchange on [Pd(dien)H2O]2+ (1989) (3)
The first volume profile for a host–guest interaction: a variable pressure kinetic study of an inclusion reaction with α-cyclodextrin (1996) (3)
Reaction between [Ru(H2O)6]2+ and DMF: A Complete Volume Profile of a Monocomplex Formation Reaction on a d6 Low Spin Aquaion (1999) (3)
NMR under high gas pressure (1996) (3)
High‐Pressure Stopped‐Flow Study of the Kinetics of Base Hydrolysis of the Dichromate Ion by Hydroxide Ion, Ammonia, Water, and 2,6‐Lutidine in Aqueous Solution (1983) (3)
solvent exchange reactions (1987) (3)
Molecular Dynamics of Gd(III) Complexes in Aqueous Solution by HF EPR (2004) (3)
High-pressure nmr study of water exchange on magnetic resonance imaging contrast agents (1994) (2)
NMR studies of rare earth polyaminocarboxylates. Part V. Nuclear magnetic resonance study of praseodymium, europium and ytterbium ethylenediaminetetraacetates (1978) (2)
Structural and Dynamic Study of SnCl4 · 2 Me2O and SnCl4 · 2 Me2Se Preliminary communication (1975) (2)
Solvent exchange on metal ions: A variable pressure NMR approach (1995) (2)
Structural Investigation of the Aqueous Eu 2+ Ion: Comparison with Sr 2+ Using th (2002) (2)
Phosphine site exchange in [NiX(PMe3)4]X via an Ia mechanism with a 20-electron transition state (1979) (2)
Future Perspectives: Applications of High Pressure in Supramolecular Chemistry (2002) (2)
Similarities and Differences Between the Isoelectronic Gd(III) and Eu(II) Complexes with Regard to MRI Contrast Agent Applications (2001) (2)
Chemical kinetics at high pressure (1990) (2)
High-pressure NMR kinetic evidence for a dissociative-associative changeover for the trimethylphosphate exchange with hexasolvates along the series aluminium(III), gallium(III) and indium(III) (1980) (2)
Associative mechanism of substitution in octahedral adducts of tantalum(V) halides (1974) (2)
Effect of pressure on chemically induced dynamic nuclear polarization (1982) (2)
Destruction of perfluoroalkyl surfactant aggregates by beta-cyclodextrin. (2004) (2)
Structure in solution and acetonitrile intermolecular exchange process of the antimony pentachloride-acetonitrile adduct (1978) (2)
Molecular dynamics simulation of Gadolinium(III) complexes in aqueous solution (2001) (2)
The Titanyl Question Revisited. (1987) (2)
HIGH-PRESSURE NMR KINETICS. PART 25. VARIABLE-TEMPERATURE AND VARIABLE-PRESSURE OXYGEN-17 NMR STUDY OF WATER EXCHANGE OF HEXAAQUAALUMINUM(III) (1985) (2)
Kinetics at High Pressure (2007) (2)
Isomerization mechanisms of a labile Co(II) octahedral complex (2006) (2)
VARIABLE PRESSURE OXYGEN-17 FTNMR AND STOPPED-FLOW KINETIC STUDY OF WATER EXCHANGE AND DMSO SUBSTITUTION ON SQUARE-PLANAR TETRAAQUA-PALLADIUM (II) AND -PLATINUM (II) (1984) (1)
HIGH-PRESSURE NMR KINETICS. 21. ACTIVATION PARAMETERS AND MECHANISM FOR WATER R EXCHANGE OF TETRAAQUAPLATINUM(II) STUDIED BY HIGH-PRESSURE OXYGEN-17 NMR SPECTROSCOPY (1985) (1)
High Pressure NMR Kinetics. Part 41. Dissociative Substitution in Four-Coordinate Planar Platinum(II) Complexes As Evidenced by Variable-Pressure High-Resolution Proton NMR Magnetization Transfer Experiments (1990) (1)
A DEMONSTRATED EXAMPLE OF COMPETING D AND ID MECHANISMS FOR DIMETHYLFORMAMIDE EXCHANGE ON THE OCTAKIS(DIMETHYLFORMAMIDE)ERBIUM(III) ION (1983) (1)
Solvent Exchange on Hexakis(methanol)copper(II) Ion. 17O NMR Variable‐Temperature, ‐Pressure, and ‐Frequency Study (1986) (1)
Unprecedented dimethyl sulfoxide conformational equilibria andkinetics on[Ir(Me2SO)3(η-C5Me5)][PF6]2 (1997) (1)
High-Pressure Stopped-Flow Study of Inclusion Reactions with α-Cyclodextrin: Dynamic Aspects in Host-Guest Interactions (1996) (1)
High pressure cyanide exchange study on a square-planar tetracyanometalate complex of Pt(II) (2000) (1)
Reaction Volume for the Equilibrium Between the Lanthanide(III) Ennea- and Octaaqua Ions as a Diagnostic Aid for Their Water-Exchange Mechanisms. (1989) (1)
Technical issues of Fast Field Cycling NMR Relaxometry (2005) (1)
High-Pressure NMR Kinetics. Part 30. Water Exchange on Hexaaquagallium(III): High-Pressure Evidence for a Dissociative Interchange Exchange Mechanism. (1987) (1)
Quantifying transient conformational transitions of Na,K-ATPase: Volume changes and activation volumes (2000) (1)
DMSO exchange on [Gd(DMSO)8]3+—a variable pressure17O NMR study (2004) (1)
Crystal Structure of and Mechanism of Water Exchange on (Mo3O4(OH2)9)4+ from X-Ray and Oxygen-17 NMR Studies. (1989) (1)
Invitation to attend the Fall Meeting of the New Swiss Chemical Society in Lausanne, Wednesday, October 15, 1997 (1997) (1)
HIGH‐PRESSURE NMR KINETICS. PART 24. WATER EXCHANGE ON HEXAAQUAVANADIUM(III): : A VARIABLE‐TEMPERATURE AND VARIABLE‐PRESSURE OXYGEN‐17 NMR STUDY AT 1.4 AND 4.7 TESLA (1985) (1)
19F NMR study of mixed pentafluorochlorotantalum-trimethylphosphate adducts in solution (1976) (1)
High-Pressure NMR Kinetics. Part 31. Adducts of Titanium Tetrahalides with Neutral Lewis Bases. Part 2. Kinetics and Reaction Mechanism: A Variable Temperature and Variable Pressure Proton NMR Study (1988) (1)
High Pressure NMR Kinetics. Part 34. Variable‐Temperature and Variable‐Pressure NMR Kinetic Study of Solvent Exchange on Ru(H2O)3+ 6, Ru(H2O)2+ 6, and Ru(CH3CN)2+ 6 (1988) (1)
Seven new COST chemistry actions (2000) (0)
Pressure Effect of the 1H NMR Spectra of Organic Compounds in the Presence of Lanthanoid Shift Reagents. A Formally Associative Process Characterized by Volume Expansion. (1988) (0)
HIGH-PRESSURE, HIGH-RESOLUTION NUCLEAR MAGNETIC RESONANCE (HPHR-NMR)- A TOOL IN CHEMICAL KINETICS (1977) (0)
HIGH-PRESSURE NMR KINETICS. PART 9. HIGH-PRESSURE OXYGEN-17 FOURIER-TRANSFORM M NMR. EVIDENCE FOR THE ASSOCIATIVE NATURE OF SUBSTITUTION REACTIONS ON MANGANESE(2+) IN WATER (1980) (0)
17O NMR Kinetic Study of Water Exchange on the Lanthanoid(III) Aqua Ions. (1988) (0)
Adducts of Antimony(V) Pentachloride with Neutral Lewis Bases. (1986) (0)
High‐Pressure NMR Study. Part 33. Dimethylformamide‐Exchange Mechanism on Some First‐Row Divalent Transition‐Metal Ions. (1987) (0)
ELECTRON TRANSFER SPECTRA OF THE HEXACHLORO‐ AND HEXABROMONIOBATE(V) AND TANTALATE(V) ANIONS (1975) (0)
HIGH-PRESSURE STOPPED-FLOW STUDY OF THE KINETICS OF BASE HYDROLYSIS OF THE DICHROMATE ION BY HYDROXIDE ION, AMMONIA, WATER, AND 2,6-LUTIDINE IN AQUEOUS SOLUTION (1984) (0)
ADDITION COMPOUNDS OF NIOBIUM(V) AND TANTALUM(V) HALIDES .7. COMPOUNDS OF NIOBIUM(V) CHLORIDE WITH PHOSPHORUS OXYTRICHLORIDE AND OXYTRIBROMIDE (1972) (0)
High-Pressure Kinetic Study of Formation and Dissociation of First- and Second-Row d10 Divalent Metal Ion Complexes with Bipyridine in Aqueous Solution: A Cation Size Dependent Reaction Mechanism. (1988) (0)
High-Pressure NMR Kinetics. Part 26. Adducts of Antimony(V) Pentachloride with Neutral Lewis Bases. (1986) (0)
Determination of quaternary amines in natural extracts by NMR spectroscopy (1975) (0)
Merbach, Andre: From High‐Pressure NMR to Medical MRI (2010) (0)
Molecular dynamics simulations of MRI-relevant Gd ( III ) chelates : direct access to outer-sphere relaxivity [ postprint version ] (2015) (0)
Reactivity of the novel organometallic aqua-ion [(CO)2(NO)Re(H2O) 3]2+: Kinetics of H2O substitution and 17O exchange of CO ligands (2005) (0)
Molecular dynamics simulations of MRI-relevant Gd ( III ) chelates : direct access to outer-sphere relaxivity [ postprint version ] (2015) (0)
High‐Pressure NMR Kinetics. Part 89. Nuclear and Electronic Relaxation of Eu2+(aq): An Extremely Labile Aqua Ion. (2000) (0)
High-Pressure Stopped-Flow Studies to Characterize Transient Conformational Transitions of a Membrane Enzyme: Na, K-ATPase (2003) (0)
Potassium ion-ammonium ion--chromate ion--sulfate ion--water quaternary system. I. Isotherms at 25.deg. of limited ternary systems (1968) (0)
HIGH-PRESSURE NMR KINETICS. PART 12. HIGH-PRESSURE CARBON-13 FT-NMR. ACETONITRILE EXCHANGE WITH HEXAKISACETONITRILECOBALT(2+) PERCHLORATE (1981) (0)
PROTON NUCLEAR MAGNETIC RESONANCE STUDY OF N,N-DIETHYLFORMAMIDE EXCHANGE ON (N,N-DIETHYLFORMAMIDE)(2,2′,2“-TRIS(DIMETHYLAMINO)TRIETHYLAMINE)COBALT(II) AND ITS COPPER(II) ANALOG (1985) (0)
In situ high-gas pressure NMR spectroscopy. Synthesis and catalysis (1997) (0)
Structural Elucidation of Oligomeric Aqua-molybdenum by "0 NMR (1987) (0)
Molecular Dynamics of Gd(III) Complexes in Aqueous Solution by HF EPR - preprint version (2005) (0)
Swiss Chemical Society with new staff and head office in Bern (2003) (0)
ADDUCTS OF NIOBIUM(V) AND TANTALUM(V) HALOGENIDES PART 9, RELATIVE STABILITY OF THE ADDUCTS OF THE CHLORIDES AND BROMIDES WITH SOME DIALKYLCHALCOGENIDES (1974) (0)
SPECIFIC DETERMINATION BY ATOMIC ABSORPTION OF POTASSIUM, RUBIDIUM, AND CESIUM IN THEIR MIXTURES. (1969) (0)
VARIABLE TEMPERATURE MULTINUCLEAR NMR. INVESTIGATION OF DIMETHYLFORMAMIDE EXCHANGE ON THE OCTAKIS(N,N-DIMETHYLFORMAMIDE) THULIUM(III) ION (1982) (0)
PROTON NUCLEAR MAGNETIC RESONANCE STUDY OF N,N-DIMETHYLFORMAMIDE EXCHANGE ON (N,N-DIMETHYLFORMAMIDE)(2,2′,2′′-TRIS(DIMETHYLAMINO)TRIETHYLAMINE)MANGANESE(II) AND ITS COBALT(II) AND COPPER(II) ANALOGS (1984) (0)
Structural Elucidation of Oligomeric Aqua-molybdenum Cations in Solution by 17O NMR. (1987) (0)
Spectrophotometric and Nuclear Magnetic Resonance Study of Temperature- and Pressure-induced Changes in the Intimate Solvation of Neodymium(III) in N,N-Dimethylformamide and Trimethylphosphate (Untersuchung der Gleichgewichte für die (1982) (0)
Triaquo(benzene)ruthenium(II) and Triaquo(benzene)osmium(II): Synthesis, Molecular Structure, and Water-Exchange Kinetics. (1988) (0)
HIGH-PRESSURE NMR KINETICS. PART 23. WATER-EXCHANGE MECHANISM OF TETRAAQUAPALLADIUM(II). A VARIABLE-PRESSURE AND VARIABLE-TEMPERATURE OXYGEN-17 NMR STUDY (1984) (0)
Solvent exchange and complex formation reactions of Pd(II) in aqueous solution: mechanistic information from high pressure studies (1990) (0)
DIRECT MEASUREMENT OF A PROMINENT OUTER-SPHERE ELECTRON SELF-EXCHANGE: KINETIC PARAMETERS FOR THE HEXAAQUARUTHENIUM(II)/(III) COUPLE DETERMINED BY OXYGEN-1 AND RUTHENIUM-99 NMR (1985) (0)
Graphic solution of problems of simple crystallization (1965) (0)
High-pressure NMR kinetics. Part 26. Adducts of antimony(V) pentachloride with neutral Lewis bases. Part II. Kinetics and reaction mechanism: a variable temperature and variable pressure proton NMR study (1986) (0)
Preparation of (ethylene)-(propylene)-triaminepentaacetic acid derivatives for use in the production of pharmaceutical agents (2003) (0)
Determination of niobium and tantalum in the adducts of their pentahalides by atomic absorption (1974) (0)
STRUCTURE IN SOLUTION AND ACETONITRILE INTERMOLECULAR EXCHANGE PROCESS OF THE ANTIMONY PENTACHLORIDE‐ACETONITRILE ADDUCT (1978) (0)
ELECTRON TRANSFER SPECTRA OF SOME ADDUCTS OF NIOBIUM(V), TANTALUM(V), TITANIUM(IV), AND ZIRCONIUM(IV) HALIDES WITH LEWIS BASES. XI (1976) (0)
DISSOCIATIVE-ASSOCIATIVE CROSSOVER FOR THE LIGAND-SUBSTITUTION MECHANISM IN OCTAHEDRAL ADDUCTS (I) OF NIOBIUM(V) AND TANTALUM(V) HALIDES (1975) (0)
Specific determination of potassium, rubidium, and cesium in their mixtures by atomic absorption [spectrophotometry] (1969) (0)
CpRu ( ( R )-Binop-F ) ( H 2 O ) ] [ SbF 6 ] , a New Fluxional Chiral Lewis Acid Catalyst : Synthesis , Dynamic NMR , Asymmetric Catalysis , and Theoretical Studies ALEZRA , Valérie (2017) (0)
High-Pressure NMR Study. Part 38. Water-Exchange Mechanisms on the Terbium to Thulium Octaaqualanthanide(III) Ions: A Variable-Pressure 17O NMR Study. (1989) (0)
New COST chemistry actions (1997) (0)
HIGH PRESSURE NMR KINETICS. PART 22. MECHANISM OF DIMETHYL SULFIDE INTERMOLECULAR EXCHANGE AND TRANS-CIS ISOMERIZATION OF TIN TETRACHLORIDE-2 DIMETHYL SULFIDE (SNCL4.CNTDOT.2ME2S). VARIABLE-PRESSURE PROTON NMR AND VARIABLE-TEMPERATURE (1985) (0)
Multiple Frequency and Variable Temperature EPR study of Gd ( III ) polyaminocarboxylates : analysis and comparison of the magnetically dilute powder and the frozen solution spectra (2009) (0)
HIGH-PRESSURE NUCLEAR MAGNETIC RESONANCE KINETICS. 5. PROTON NUCLEAR MAGNETIC C RESONANCE STUDY OF THE EFFECT OF PRESSURE ON THE EXCHANGE OF NONAQUEOUS SOLVENTS ON NICKEL(II) AND COBALT(II) (1979) (0)
NMR STUDY OF TERNARY COMPLEXES OF SOME PARAMAGNETIC LANTHANIDE ETHYLENEDIAMINETETRAACETATES WITH IMINODIACETATE, METHYLIMINODIACETATE AND NITRILOTRIACETATE. PART VI (1978) (0)
Nuclear magnetic resonance study of scandium, yttrium, lanthanum, and lutetium ethylenediaminetetraacetates (1969) (0)
Adducts of Titanium Tetrahalides with Neutral Lewis Bases. Part 1. Structure and Stability: A Vibrational and Multinuclear NMR Study. (1988) (0)
The rate of the hexaaquaruthenium(II)/(III) self-exchange reaction: oxygen-17 and ruthenium-99 NMR spectroscopic studies (1984) (0)
Molecular dynamics simulations of the internal mobility of Gd3+-based MRI contrast agents: consequences for water proton relaxivity (2004) (0)
HIGH-PRESSURE NMR KINETICS. PART 18. FIVE-COORDINATE TETRAMETHYLCYCLAM COMPLEXES OF COBALT(II) AND NICKEL(II); ASSOCIATIVE INTERCHANGE AND DISSOCIATIVE MECHANISMS FOR SOLVENT EXCHANGE IN ACETONITRILE (1983) (0)
STRUCTURAL AND DYNAMIC STUDY OF SNCL4.2ME2O AND SNCL4.2ME2SE (1975) (0)
STEREOCHEMICALLY NONRIGID PENTACOORDINATE NICKEL(II) COMPLEXES. X-RAY STRUCTURE OF BROMOTETRAKIS(TRIMETHYLPHOSPHINE)NICKEL(II) TETRAFLUOROBORATE AND THE SOLUTION STUDY OF (NIX(PME3)4)BF4 (X = CHLORINE, BROMINE, IODINE) (1979) (0)
Mechanism of Substitution on Trinuclear Incomplete Cuboidal (M3X4(OH2) 9)4+ Ions: Kinetic Studies of Water Exchange and Substitution by Cl‐ on (Mo3S4(OH2)9)4+. (1993) (0)
Conformational changes in Na+/K+-ATPase induced by cation binding (1998) (0)
NUCLEAR MAGNETIC RESONANCE STUDIES OF RARE EARTHS POLYAMINOCARBOXYLATES. IV. NITRILOTRIACETATES (1978) (0)
High-Pressure NMR Kinetics. Part 17. Variable-temperature and Variable-pressure 1H NMR Studies of Dimethylsulfide Exchange on trans-Bis(dimethylsulfide)dichloropalladium(II) in Various Solvents (Bestimmung der Geschwindigkeitskonstant (1983) (0)
Variable pressure NMR and spectrophotometric study of lanthanide solvation in DMF (1984) (0)
Kinetics and mechanism of complex formation of nickel(II) with tetra-N-alkylated cyclam in N,N-Dimethylformanide (DMF): comparative study on the reactivity and solvent exchange of the species Ni(DMF)6 2+ and Ni(DMF)5Cl+ (DMF = N,N-Dimethylformanide) (2000) (0)
a New Fluxional Chiral Lewis Acid Catalyst : Synthesis , Dynamic NMR , Asymmetric Catalysis , and Theoretical Studies (2015) (0)
Variable-Temperature and Variable-Pressure Kinetic and Equilibrium Studies of Formation and Dissociation of (V(H2O)5NCS)2+ (1990) (0)
Stability and hydrolysis constants of N-hydroxyethyliminodiacetates of the rare earths (1974) (0)
ADDUCTS OF TIN(VI) TETRAHALIDES WITH NEUTRAL LEWIS BASES. II. QUANTITATIVE STUDY OF THE CIS-TRANS EQUILIBRIUMS BY NMR (1977) (0)
Rhodium(III) and Iridium(III) Solvates of the Form [(eta(5)-C(5)Me(5))M(S)(3)](2+) as Models for the Reactivity of Half-Sandwich Compounds(1). (1997) (0)
Monocomplex formation and dissociation of some first row divalent transition metal ions with 2-chloro-1,10-phenanthroline by the high-pressure stopped-flow technique (1992) (0)
Addition compounds of niobium(V) and tantalum(V) halides. II. Relative stability of addition compounds of niobium and tantalum chlorides with some ethers, sulfides, and nitriles (1971) (0)
Formation and in situ Characterization of the First Dihydrogen Aqua Complex: [Ru(H2O)5(H2)]2+. (1999) (0)
HPLC separation of diastereomers of LnIII-ethylenepropylene-triamine-pentaacetate complexes. Direct assessment of their water exchange rateElectronic supplementary information (ESI) available: Table S1?S4 and Figs. S1 and S2. See http://www.rsc.org/suppdata/cc/b3/b308253a/ (2003) (0)
High Pressure NMR Kinetics. Part 29. Variable-Temperature, -Pressure, and -Frequency 17O NMR Study of Water Exchange on Hexaaquatitanium(III): A Limiting Associative Mechanism? (1987) (0)
The Binding of Dinitrogen to Ruthenium(II) in Aqueous Solution. (1992) (0)

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École Polytechnique Fédérale de Lausanne
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