Anthony John Kirby

Anthony John Kirby's AcademicInfluence.com Rankings

Anthony John Kirby

Chemistry

#2537

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#3460

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Organic Chemistry

#378

World Rank

#447

Historical Rank

chemistry Degrees

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Chemistry

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Anthony John Kirby's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen (1982) (745)
Effective Molarities for Intramolecular Reactions (1980) (480)
Enzyme Mechanisms, Models, and Mimics (1996) (343)
Gemini surfactants: new synthetic vectors for gene transfection. (2003) (318)
The Reactivity of Phosphate Esters. Monoester Hydrolysis (1967) (237)
The Organic Chemistry of Phosphorus (1967) (205)
Exploring the Limits of Efficiency of Proton-Transfer Catalysis in Models and Enzymes (1997) (164)
The Reactivity of Nucleophilic Reagents toward the p-Nitrophenyl Phosphate Dianion1 (1965) (160)
Rational approaches to the design of cationic gemini surfactants for gene delivery. (2001) (143)
Off-the-shelf proteins that rival tailor-made antibodies as catalysts (1996) (135)
Structure and efficiency in intramolecular and enzymic catalysis. Catalysis of amide hydrolysis by the carboxy-group of substituted maleamic acids (1972) (132)
The Most Twisted Amide: Structure and Reactions. (1998) (103)
Bond length and reactivity. Stereoelectronic effects on bonding in acetals and glucosides (1984) (92)
The reactivity of phosphate esters. Reactions of diesters with nucleophiles (1970) (88)
Estimating pKa values for pentaoxyphosphoranes. (2002) (87)
Synthesis, structure and reactions of the most twisted amide (2001) (79)
The reactivity of phosphate esters. Diester hydrolysis (1970) (76)
Simple correlation between bond length and reactivity. Combined use of crystallographic and kinetic data to explore a reaction coordinate (1984) (75)
Glucopyranoside-Based Surfactants as Pseudostationary Phases for Chiral Separations in Capillary Electrophoresis (1994) (74)
The lysozyme mechanism sorted — after 50 years (2001) (73)
The hydrolysis of aspirin. Intramolecular general base catalysis of ester hydrolysis. (1967) (71)
The reactivity of phosphate esters. Multiple structure–reactivity correlations for the reactions of triesters with nucleophiles (1970) (66)
Efficient intramolecular general acid catalysis of nucleophilic attack on a phosphodiester. (2006) (61)
Characterization of Proton-Transfer Catalysis by Serum Albumins (2000) (56)
A novel class of cationic gemini surfactants showing efficient in vitro gene transfection properties (2000) (55)
BOND LENGTH AND REACTIVITY. VARIABLE LENGTH OF THE CARBON-OXYGEN SINGLE BOND (1984) (54)
Novel spermine-based cationic gemini surfactants for gene delivery. (2001) (54)
SPONTANEOUS, MILLISECOND FORMATION OF A TWISTED AMIDE FROM THE AMINO ACID,AND THE CRYSTAL STRUCTURE OF A TETRAHEDRAL INTERMEDIATE (1998) (52)
An improved synthesis of phosphoenol pyruvate (1963) (50)
Three Dimensional Structure of Adenosine Triphosphate (1970) (49)
On the magnitude and specificity of medium effects in enzyme-like catalysts for proton transfer. (2001) (49)
Stereoelectronic effects on acetal hydrolysis (1984) (48)
The most reactive amide as a transition-state mimic for cis-trans interconversion. (2015) (47)
Mechanism and stereoelectronic effects in the lysozyme reaction. (1987) (47)
Fundamentals of phosphate transfer. (2015) (46)
Hydroxylamine as an oxygen nucleophile. Structure and reactivity of ammonia oxide. (2006) (46)
Chapter 2 Hydrolysis and Formation of Esters of Organic Acids (1972) (46)
Gemini Surfactants: New Synthetic Vectors for Gene Transfection (2003) (42)
Bimolecular nucleophilic substitution on an acetal (1978) (42)
Phosphorylimidazole derivatives: potentially biosignaling molecules. (2011) (42)
Intramolecular catalysis of phosphodiester hydrolysis by two imidazoles. (2010) (40)
The mechanism of the reaction between trialkyl phosphites and α-halogenated ketones (1965) (39)
Thorpe-Ingold effects in cyclizations to five-membered and six-membered rings containing planar segments. The rearrangement of N(1)-alkyl-substituted dihydroorotic acids to hydantoinacetic acids in base. (2004) (39)
Efficient intramolecular general-acid catalysis of the reactions of alpha-effect nucleophiles and ammonia oxide with a phosphate triester. (2009) (39)
Efficient intramolecular general acid catalysis of enol ether hydrolysis. Hydrogen-bonding stabilisation of the transition state for proton transfer to carbon (1994) (39)
Crystallographic Approaches to Transition State Structures (1994) (37)
A mechanism for efficient proton-transfer catalysis. Intramolecular general acid catalysis of the hydrolysis of 1-arylethyl ethers of salicylic acid (1999) (36)
The potential of catalytic antibodies. (1996) (36)
The reactivity of phosphate esters: reactions of monoesters with nucleophiles. Nucleophilicity independent of basicity in a bimolecular substitution reaction (1968) (35)
The role of the carboxy-group in intramolecular catalysis of acetal hydrolysis. The hydrolysis of substituted 2-methoxymethoxybenzoic acids (1974) (34)
The Design of Phosphorylating Agents (1964) (34)
New light on phosphate transfer from triesters. (2013) (34)
Synthesis of 8-substituted 1-naphthylamine derivatives. exceptional reactivity of the substituents. (1989) (34)
Structure and mechanism in intramolecular catalysis. The hydrolysis of substituted aspirins. (1967) (34)
Kinetics and mechanism of the reversible isomerization of aspartic acid residues in tetrapeptides (1995) (33)
Base Catalysis of the Reaction of Secondary Amines with p-Nitrophenyl Phosphate. Kinetic Evidence for an Addition Intermediate in Nucleophilic Aromatic Substitution1 (1965) (33)
Intramolecular catalysis of amide hydrolysis by two carboxy-groups (1974) (32)
Hydroxylamine as an oxygen nucleophile. Chemical evidence from its reaction with a phosphate triester. (2008) (32)
The search for efficient intramolecular proton transfer from carbon: the kinetically silent intramolecular general base-catalysed elimination reaction of O-phenyl 8-dimethylamino-1-naphthaldoximes (2005) (31)
Theoretical study of the importance of the spectator groups on the hydrolysis of phosphate triesters. (2012) (31)
Intramolecular general acid catalysis of phosphate transfer. nucleophilic attack by oxyanions on the PO3 2- group. (2005) (31)
Efficient intramolecular general acid catalysis of vinyl ether hydrolysis by the neighbouring carboxylic acid group (1991) (31)
From enzyme models to model enzymes (2009) (30)
Bond length and reactivity : the gauche effect. A combined crystallographic and theoretical investigation of the effects of β-substituents on C-OX bond length (1992) (29)
Intramolecular general base catalysis in the hydrolysis of a phosphate diester. Calculational guidance to a choice of mechanism. (2013) (29)
Linear relationship between bond length and reactivity (1979) (29)
MECHANISM OF RNA CLEAVAGE BY IMIDAZOLE CATALYSIS VS MEDIUM EFFECTS (1995) (28)
Intramolecular catalysis of amide hydrolysis by the carboxy-group. Rate determining proton transfer from external general acids in the hydrolysis of substituted maleamic acids (1974) (28)
Distortion of the amide bond in amides and lactams. Photoelectron-spectrum and electronic structure of 3,5,7-trimethyl-1-azaadamantan-2-one, the most twisted amide (1999) (28)
The spontaneous hydrolysis of acetals: sensitivity to the leaving group (1978) (27)
Activating water: important effects of non-leaving groups on the hydrolysis of phosphate triesters. (2011) (27)
Synthesis and acid catalyzed hydrolysis of B2,5 type conformationally constrained glucopyranosides: incorporation into a cellobiose analogue (2004) (26)
Ammonia oxide makes up some 20% of an aqueous solution of hydroxylamine. (2010) (26)
A desaurin from a cyclic phosphorane (1966) (26)
Supramolecular Polymer/Surfactant Complexes as Catalysts for Phosphate Transfer Reactions (2017) (25)
Biochemistry: Enzymes under the nanoscope (2008) (25)
The synthesis and aggregation properties of a novel anionic gemini surfactant (1998) (25)
Anatomy of an SN1 reaction. Crystal structure-reactivity correlations for 1-arylethanol derivatives (1986) (25)
Efficiency of proton transfer catalysis. Intramolecular general acid catalysis of the hydrolysis of dialkyl acetals of benzaldehyde (1997) (25)
Structure and antimicrobial activity of new bile acid-based gemini surfactants (2002) (25)
Nucleophilic attack by oxyanions on a phosphate monoester dianion: the positive effect of a cationic general Acid. (2004) (25)
Mechanisms of catalysis by imidazole buffers of the hydrolysis and isomerisation of RNA models (1998) (25)
Neighboring Group Participation in Phosphate Ester Hydrolysis (1963) (24)
Most efficient intramolecular general acid catalysis of acetal hydrolysis by the carboxy group (1994) (24)
Catalysis of the Kemp elimination by antibodies elicited against a cationic hapten (1997) (22)
Acceleration of P-O cleavage reactions of phosphate monoester dianions in dipolar aprotic solvents (1986) (22)
Kinetics and mechanism of the cleavage of the peptide bond next to asparagine (1996) (22)
First experimental evidence for a synperiplanar stereoelectronic effect in the acid hydrolysis of acetal (1993) (21)
Dephosphorylation reactions of mono-, di-, and triesters of 2,4-dinitrophenyl phosphate with deferoxamine and benzohydroxamic acid. (2012) (21)
Intramolecular general acid catalysis of phosphate monoester hydrolysis. The hydrolysis of salicyl phosphate (1972) (20)
3,5,7-trimethyl-1-azatricyclo[3.3.1.1(3,7)]decan-2-ylidene, an aminocarbene without pi conjugation. (2002) (20)
Stereoelectronic effects on bond length and reactivity (1987) (19)
Intramolecular nucleophilic catalysis of ester hydrolysis by the ionized carboxyl group. The hydrolysis of 3,5-dinitroaspirin anion. (1968) (19)
A study of the structure and chiral selectivity of micelles of two isomeric D-glucopyranoside-based surfactants (1998) (19)
Structure and chemistry of a zwitterionic amine-aldehyde adduct. (2002) (18)
2,4-Dinitrophenyl Phosphate (1966) (17)
The crystal structure of 2-(4-chlorophenoxy)-tetrahydropyran (1982) (17)
Activating water: efficient intramolecular general base catalysis of the hydrolysis of a phosphate triester. (2009) (17)
Reactions of alpha-nucleophiles with a model phosphate diester (2008) (17)
Stereoelectronic effects at carboxylate oxygen : similar basicity of the E and Z lone pairs in solution (1991) (17)
Phenol oxidation and biosynthesis. XVII. Investigations on the biosynthesis of sinomenine. (1968) (16)
Toward bifunctional antibody catalysis. (2006) (15)
Kinetic and computational evidence for an intermediate in the hydrolysis of sulfonate esters. (2012) (15)
Stereoelectronic effects at oxygen. A very large effect on the hydrolysis of a conformationally locked acetal: implications for β-glycosidase mechanisms (1984) (15)
Exceptional reactivity of the aromatic ring in 8-substituted 1-naphthol derivatives. Ready reduction to tetralins (1988) (15)
Intramolecular displacement of alkoxide ions by the ionised carboxy-group: hydrolysis of alkyl hydrogen dialkylmaleates (1974) (15)
Concurrent nucleophilic and general acid catalysis of the hydrolysis of a phosphate triester (2002) (15)
Comprar From Enzyme Models to Model Enzymes | Hollfelder, Florian | 9780854041756 | Royal Society of Chemistry (2009) (15)
Major mechanistic differences between the reactions of hydroxylamine with phosphate di- and tri-esters. (2013) (14)
The case of the missing acetylene. The mechanism of an intramolecular SN(V) reaction and a new route to 1-methylbenzo[de]quinolines (1999) (14)
Synthesis of B2,5 type conformationally constrained glucopyranosides (2003) (14)
Intramolecular proton-transfer catalysis of nucleophilic catalysis of acetal hydrolysis. The hydrolysis of 8-dimethylamino-1-methoxymethoxynaphthalene (1989) (14)
The spontaneous formation of amides. The mechanism of lactam formation from 3-(2-aminophenyl)propionic acid (1980) (14)
Structure and efficiency in intramolecular and enzymic catalysis: intramolecular general base catalysis. Hydrolysis of monoaryl malonates (1976) (14)
The crystal structure of 1,2,3,4,6-penta-O-acetyl-β-d-glucopyranose1 (1982) (13)
Structure–activity studies on amides inhibiting photosystem II (1991) (13)
Torsional effects on reactivity in glycosyl transfer (2002) (13)
General base catalysis vs. medium effects in the hydrolysis of an RNA model (2002) (13)
Stereoelectronic control of the hydrolysis of a conformationally locked acetal (1984) (12)
Intramolecular nucleophilic catalysis in the hydrolysis of substituted aspirin acids. (1968) (12)
Highly efficient intramolecular general acid catalysis of enol ether hydrolysis, with rapid proton transfer to carbon (1994) (12)
Nonspecific catalysis by protein surfaces (2000) (12)
Intramolecular nucleophilic attack by urea nitrogen. Reactivity–selectivity relationships for the general acid–base catalysed cyclisations of ureido acids and esters (1989) (12)
Models for nuclease catalysis: Mechanisms for general acid catalysis of the rapid intramolecular displacement of methoxide from a phosphate diester (1993) (12)
Stereoelectronic effects on reactivity. Crystal-structure–reactivity correlations for acetals with synperiplanar lone pairs (1997) (11)
Phosphorylation of 1,3-Di(N-alkyl)Azoles by Phosphorus(V) Acid Chlorides — a Route to Potential Haptens Derived from Phosphinic Acids (1995) (11)
Dephosphorylation reactions with deferoxamine, a potential chemical nuclease. (2011) (11)
Structure-activity studies of sulfate transfer: the hydrolysis and aminolysis of 3'-phosphoadenosine 5'-phosphosulfate (PAPS). (1995) (11)
A model for olefin hydration: intramolecular nucleophilic addition of phenolate oxygen to the unactivated double bond (1984) (11)
Intramolecular catalysis of phosphate diester hydrolysis. Nucleophilic catalysis by the neighbouring carboxy-group of the hydrolysis of aryl 2-carboxyphenyl phosphates (1970) (11)
Structural Correlations for Nucleophilic Addition to the CO Group: The Solvation Angle (2003) (11)
Intramolecular catalysis of phosphate triester hydrolysis. Nucleophilic catalysis by the neighbouring carboxy-group of the hydrolysis of diaryl 2-carboxyphenyl phosphates (1972) (10)
2,6-Lutidine (2001) (10)
Structure and reactivity of phosphate diesters. Dependence on the nonleaving group (2015) (10)
Series nucleophilic catalysis in the hydrolysis of 3-acetoxyphthalate. Intramolecular catalysis of ester hydrolysis by the carboxyl group once removed (1968) (10)
The reaction of activated RNA species with aqueous fluoride ion: a convenient synthesis of nucleotide 5′-phosphorofluoridates and a note on the mechanism (2014) (10)
Intramolecular hydride transfer from a 1,4-dihydropyridine to an α-ketoester in aqueous solution. A model for lactate dehydrogenase (1987) (10)
The synthesis and micellar properties of a novel anionic surfactant (1994) (10)
Intramolecular general acid catalysis of intramolecular nucleophilic catalysis of the hydrolysis of a phosphate diester (1983) (10)
Stereoelectronic effects at oxygen. The hydrolysis of 2-aryloxy-trans-1-oxadecalins (1984) (10)
Bond length-reactivity correlations for sulfate monoesters. The crystal structure of potassium 4-nitrophenyl sulfate, C6H4KNO6S (2005) (10)
Stabilisation of the thromboxane ring system by electron-withdrawing substituents: synthesis and attempted cyclisation of substituted tetrahydropyran-2,4-diols (1990) (10)
Intramolecular nucleophilic addition of phenolate oxygen to double bonds activated by carboxyl and carboxylate groups. Relative reactivity, stereochemistry, and mechanism (1988) (9)
Multiple bond length–reactivity correlations (1986) (9)
Syntheses and structures of anomeric quaternary ammonium β-glucosides and comments on the anomeric C–N bond lengths (2009) (9)
Free energy relationships and intramolecular general acid catalysis (2004) (9)
Intramolecular general base catalysis in the hydrolysis of 3-dimethylaminopropionates (1977) (9)
Stereoelectronic interactions between hetero-atoms (1999) (9)
Intramolecular nucleophilic addition of phenolate to unactivated double and triple bonds. Relative reactivity, regiospecificity, stereochemistry, and mechanism (1984) (9)
Kinetics and mechanism of the cyclization of omega-(p-nitrophenyl)-hydantoic acid amides: steric hindrance to proton transfer causes a 10(4)-fold change in rate. (2003) (8)
Models for enzyme-catalysed phosphate transfer: comparisons of reactivity towards a neighbouring hydroxy group for phosphodiester anions and acids. General base catalysis of the cyclisation of a hydroxyalkyl phosphate triester (1994) (8)
The spontaneous hydrolysis of 2-pyridyl phosphate is a good model for the special mechanism for the hydrolysis of phosphate monoester monoanions†‡ (2013) (8)
Stereoelectronic control of acetal hydrolysis (1978) (8)
Intramolecular attack by the hydroxy group on phosphate diesters is both general acid and general base catalysed (1992) (8)
Concerted general acid and nucleophilic catalysis of acetal hydrolysis. A simple model for the lysozyme mechanism (2002) (8)
3,4,4aα,10aα‐Tetrahydro‐7,9‐dinitro‐2H,5H‐[1]benzopyrano[2,3‐b]pyran (1979) (8)
Anilide formation from an aliphatic ester. The mechanism of cyclisation of methyl 3-(2-aminophenyl)propionate (1979) (8)
Molecular recognition of transition states (1993) (7)
Equatorial 2-phenoxy-trans-1-oxadecalin (1978) (7)
The gem-dimethyl effect on reactivities in cyclizations through tetrahedral intermediates. Cyclization of methyl-substituted methyl amides of 5-(p-nitrophenyl)hydantoic acids (1996) (7)
The crystal structure of 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose1 (1982) (7)
Intramolecular nucleophilic attack on carboxylate by ureide anion. General acid–base catalysis of the alkaline cyclisation of 2,2,3,5-tetramethylhydantoic acid (1984) (7)
Stereoelectronic effects on acetal cleavage. The separation of the π-donor and σ-acceptor properties of oxygen (1984) (7)
Acid–Base Catalysis by Enzymes (2010) (7)
Anomeric and Gauche Effects: Some Basic Stereoelectronics (1993) (6)
Intramolecular catalysis of sulphate diester hydrolysis by one and two carboxy groups. The hydrolysis of aryl 2-carboxyphenyl sulphates (1986) (6)
A photosensitive protecting group for phosphate esters (1967) (6)
2e-(4-Nitrophenoxy)-trans-1-oxadecalin (1979) (6)
Crystal structure of phenyl-α-d-glucopyranoside1 (1982) (6)
Stereoelectronic control of acetal cleavage. Separation of the π-donor and σ-acceptor properties of oxygen (1979) (6)
Solvent effects on aromatic nucleophilic substitution by the ANRORC mechanism. Hydrolysis of 2-chloro-3,5-dinitropyridine (1995) (6)
INTRAMOLECULAR-CATALYZED SULFONAMIDE HYDROLYSIS. VII. THE THORPE-INGOLD EFFECT IN THE INTRAMOLECULAR CARBOXYL-CATALYZED HYDROLYSIS OF SULFONAMIDES (1984) (6)
Bond length and reactivity: structures of five dialkyl aryl phosphates: 2-phenoxy-1,3,2-dioxaphosphorinane 2-oxide, C9H11O4P, (2a); 2-(3-nitrophenoxy)-1,3,2-dioxaphosphorinane 2-oxide, C9H10NO6P, (2b); 2-(2-nitrophenoxy)-1,3,2-dioxaphosphorinane 2-oxide, C9H10NO6P, (2c); 2-(4-chloro-2-nitrophenoxy)- (1984) (5)
Crystal structure of phenyl-β-D-glucopyranoside dihydrate (1982) (5)
Intramolecular catalysis by the ionised carboxy-group of the hydrolysis of enol esters, and of the general acid catalysed ketonisation of the enols produced (1972) (5)
N-(3,4-Dichlorophenyl)cyclopropanecarboxamide and N-(3,4-dichlorophenyl)acetamide (1990) (5)
The Electronic Basis of the Effects (1983) (5)
A very large stereoelectronic effect on acetal cleavage (1982) (5)
The crystal structure of l,2,3,4,6-penta-0-acetyl-β-D-glucopyranose (1982) (5)
The crystal structure of 4-nitrophenyl-α-D-glucopyranoside (1982) (5)
Enzymatic Reaction Mechanisms. By Perry A. Frey and Adrian D. Hegeman. (2007) (5)
On the disappearance of the gem-dimethyl effect: the base-catalysed cyclization of ethyl hydantoates† (1998) (5)
Bond length and reactivity: the Beckmann rearrangement. 5. Structure of 4‐phenylcyclohexanone oxime O‐4‐nitrobenzoate ester at 290 K (1987) (5)
Illuminating the Ancient Retainer (1996) (5)
Addition of amine nitrogen to an unactivated double bond. The mechanisms of the reverse Hofmann elimination (1978) (5)
The crystal structure of 2-(2′,5′-dinitrophenoxy)-tetrahydropyran1 (1982) (5)
2α-Phenoxy-trans-1-oxadecalin (1978) (4)
STRUCTURE AND REACTIVITY IN INTRAMOLECULAR CATALYSIS. CATALYSIS OF SULFONAMIDE HYDROLYSIS BY THE NEIGHBORING CARBOXYL GROUP (1980) (4)
Conformational equilibria involving 2-amino-1,3-dioxans: steric control of the anomeric effect (2001) (4)
INTRAMOLECULAR CATALYSIS OF SULFONAMIDE HYDROLYSIS .2. CIS-2-CARBOXY-N-METHYL-N-PHENYLETHENESULFONAMIDE (1976) (4)
Multiple changes in rate-determining step in the acid and base catalyzed cyclizations of ethyl N-(p-nitrophenyl)hydantoates caused by methyl substitution (1999) (4)
Turning lysozyme upside down (1995) (4)
Stabilisation of the thromboxane ring system by electron-withdrawing substituents. Mechanism and reactivity in the hydrolysis of alkyl and aryl oxetane acetals (1990) (4)
INTRAMOLECULAR CARBOXYL-CATALYZED HYDROLYSIS OF SULFONAMIDE .4. SALT EFFECTS ON THE INTRAMOLECULAR CARBOXYL-CATALYZED HYDROLYSIS OF SULFONAMIDES (1981) (4)
The crystal structure of l-(2′,4′-Dinitrophenoxy)-bicyclo[3.3. l]-9-oxanonane (1982) (4)
Stereoelectronic effects on anilide conformation (1988) (4)
HAPTEN DESIGN FOR ANTIBODY-CATALYZED DECARBOXYLATION AND RING-OPENING REACTIONS OF BENZISOXAZOLES (1996) (4)
An Expedient and Practical Approach to Functionalized 3-Aza-, 3-Oxa-, and 3-Thiabicyclo[3.3.1]nonane Systems (2014) (4)
Crystal structure of phenyl-β-d-glucopyranoside dihydrate1 (1982) (4)
Intramolecular general acid catalysis of ester hydrolysis by the carboxylic acid group (1967) (4)
The x-ray structure of a bis-alkylidene-1,2,4,5-tetrathiin (1966) (4)
NUCLEOPHILIC ADDITION OF PHENOLATE OXYGEN TO AN UNACTIVATED CARBON-CARBON DOUBLE BOND (1982) (4)
The crystal structure of 3,4-dinitrophenyl-β-D-glucopyranoside hydrate (1982) (4)
Rate-determining proton transfer in intramolecular catalysis of amide hydrolysis by the carboxylic acid group (1972) (4)
2,4-Dioxaadamantane (1988) (4)
Intramolecular catalysis of sulfonamide hydrolysis by a neighbouring carboxyl group (1975) (4)
Intramolecular general base catalysis of intramolecular nucleophilic catalysis of ester hydrolysis (1974) (4)
Intramolecular nucleophilic catalysis of ester hydrolysis by the carboxylate group (1967) (3)
The anomeric effects of aryloxy groups (1992) (3)
Intramolecular nucleophilic catalysis of glucoside hydrolysis by the 2-phosphate group (1994) (3)
The Role of the Sun in Climatic Change (2003) (3)
The crystal structure of 2-(2',5'-dinitropheiioxy)-tetrahydropyran (1982) (3)
Nucleophilic attack by amine nitrogen on the ionised carboxy group (1978) (3)
Nucleophilic catalysis of glycoside hydrolysis. The hydrolysis of 4-nitrophenyl α- and β-D-glucopyranoside tetraphosphates (1994) (3)
The introduction of P–F bonds using aqueous fluoride ion and a water soluble carbodiimide: a convenient alternative synthesis of phosphorofluoridates and phosphonofluoridates (2015) (3)
Efficient intramolecular general acid catalysis: a preview from a crystal structure. (2001) (3)
A normal gem-dimethyl effect in the base-catalyzed cyclization of ω-(p-nitrophenyl)hydantoic acids: evidence for hindered proton transfer in the permethylated esters (2000) (3)
The crystal structure of 2,3,4,6-tetra-O-acetyI- 3,4-dinitrophenyl-β-D-glucopyranoside (1982) (3)
Stereoelectronic Effects on Reactivity: The Kinetic Anomeric Effect (1983) (3)
The crystal structures of 1-(3′,5′-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3′,5′-dinitrobenzoyloxy)-cyclooctanone1 (1983) (3)
The role of hydrophobicity in supramolecular polymer/surfactant catalysts: An understandable model for enzymatic catalysis. (2020) (3)
2-Methoxymethoxybenzoic acid, C9H10O4 (1984) (3)
Bond length and reactivity. The pinacol rearrangement. 1. Redetermination of the structure of trans-cyclohexane-1,2-diol (1989) (3)
Intramolecular catalysis of sulfonamide hydrolysis. 3. Intramolecular acid-catalyzed hydrolysis of (Z)-2-carboxy-N-methyl-N-phenylethenesulfonamide and N-methyl-N-phenylmaleamic acid under conditions of varying water ordering effects (1977) (3)
Bis(cyclohexylammonium) propargyl phosphate dihydrate, 2C6H14N+.C3H3O4P2−.2H2O (1984) (3)
Bis(cyclohexylammonium) 4‐nitrophenyl phosphate dihydrate, 2C6H14N+.C6H4NO6P2−.2H2O (1984) (2)
Bond length and reactivity: the Beckmann rearrangement. 3. Structure of 4-phenylcyclohexanone O-(2-naphthalenesulfonyl)oxime at 233 K (1986) (2)
The crystal structure of 2-(3′,5′-dinitrobenzoyloxy)-tetrahydropyran Cyclohexane Solvate1 (1983) (2)
The crystal structure of 2-(3',5'-dinitrobenzoyloxy)-tetrahydropyran Cyclohexane Solvate (1983) (2)
Absence of stereoelectronic control in the hydrolysis of a conformationally locked acetal (1978) (2)
Bond length and reactivity. Structure of 2-(4-nitrophenoxy)tetrahydrofuran (1989) (2)
General Acid–Base Catalysis in Model Systems (2007) (2)
Base catalysis of nucleophilic aromatic substitution. The reactions of primary and secondary amines with nitrophenyl phosphates (1970) (2)
Bond length and reactivity: the Beckmann rearrangement. 2. Structure of a protonated lactam: 5‐tert‐butylhexahydro‐2H‐azepin‐2‐onium p‐toluensulfonate monohydrate (1986) (2)
Bond length and reactivity. Structure of 1-methoxymethoxy-3,5-dinitrobenzene, C8H8N2O6 (1985) (2)
Reactions of substituted aspirins with amino acids (2012) (2)
A measure of stereoelectronic control in the hydrolysis of an orthoester (1982) (2)
peri-Dimethylamino substituent effects on proton transfer at carbon in α-naphthylacetate esters: a model for mandelate racemase. (2012) (2)
Crystal structure of phenyl-α-D-glucopyranoside (1982) (2)
Bond length and reactivity. The pinacol rearrangement. 4. Structures of trans‐2‐hydroxycyclohexyl benzenesulfonate, p‐toluenesulfonate and 2‐naphthalenesulfonate (1989) (2)
The crystal structure of 2-(N-phthalimidomethoxy)-tetrahydropyran (1983) (2)
The reaction of hydroxylamine with aspirin (2011) (2)
Stereoelectronic Effects on Structure (1983) (2)
A Study of the Structure and Chiral Selectivity of Micelles of Two Isomeric D‐Glucopyranoside‐Based Surfactants. (1998) (2)
The crystal structure of 2-nitrophenyl-β-d-glucopyranoside1 (1982) (2)
The crystal structure of methoxymethoxy-2,4-dinitrobenzene1 (1983) (2)
Electronic effects on conformational preferences: A-values for aryloxy groups (1992) (2)
Intramolecular proton transfer catalysis of ether hydrolysis (1987) (2)
Bond length and reactivity: the Beckmann rearrangement. 4. Structure of 4‐phenylcyclohexanone oxime O‐triphenylmethyl ether at 233 K (1986) (2)
Bond length and reactivity. Structure of 1-indanol 4-nitrobenzoate ester (1989) (2)
The hydrogen bond as a key factor in efficient intramolecular proton transfer catalysis (1987) (2)
The organic chemistry of phosphate transfer. (1977) (2)
Intramolecular general acid catalysis of sulfate transfer Nucleophilic attack by oxyanions on the SO3 group (2005) (2)
Pentacyclohexyloxyphosphorane (2001) (2)
Intramolecular displcement of methoxide by the ionised carboxy-group (1972) (2)
Efficient intramolecular general acid catalysis of the hydrolysis of a dialkyl acetal (1996) (1)
STRUCTURE AND MECHANISM OF INTRAMOLECULAR CATALYSIS (1974) (1)
Bond length and reactivity: 1‐arylethyl ethers and esters. 6. Structure of 1‐(4‐nitrophenyl)ethyl 2‐naphthalenesulfonate (1986) (1)
On the biosynthesis of sinomenine (1965) (1)
Phosphorus chemistry and technology (1978) (1)
Bond length and reactivity: 1‐arylethyl ethers and esters. 4. Structures of two p‐nitrophenyl ethers of 1‐arylethanols. 1‐Phenylethyl and 1‐(4‐methoxy)phenylethyl 4‐nitrophenyl ethers (1986) (1)
The crystal structure of 2-nitrophenyl-β-D-glucopyranoside (1982) (1)
Bond length and reactivity. Structure of the 4‐phenylbenzoate ester of trans‐3‐tert‐butylcyclohexanol (1992) (1)
(2SR,6RS)-6-Phenyl-2-phenylmethoxy-6-trifluoromethyltetrahydropyran-4-one (1989) (1)
Bond length and reactivity. Structure of a tetraalkyl pyrophosphate, bis(2-oxo-1,3,2λ5-dioxaphosphorinan-2-yl) oxide, C6H12O7P2 (1985) (1)
A cationic zinc(II) complex of a new ligand based on N,N,N′,N′‐tetramethylstreptamine 2,4,6‐orthoformate as the trichloro(pyridine)zincate(II) salt (2003) (1)
The E1cb mechanism for ester hydrolysis. Evidence for a dianion intermediate in the hydrolysis of aryl malonate anions (1977) (1)
INTRAMOLECULAR NUCLEOPHILIC CATALYSIS OF ANILIDE HYDROLYSIS BY PYRIMIDINE NITROGEN (1985) (1)
Bond length and reactivity. Structure of 2‐phenylethyl p‐toluenesulfonate (1992) (1)
Estimating p Ka Values for Pentaoxyphosphoranes (1)
Synthesis, Structure and Reactions of the Most Twisted Amide. (2001) (1)
Evidence from crystal structures for an incipient fragmentation reaction (1982) (1)
The crystal structure of 9-oxabicyclo[3.3.1]non-1-yl diphenyl phosphate (1983) (1)
Bond length and reactivity. Structure of two alkyl oxadecalin acetals: 2α-[2-(4-carboxyphenyl)ethoxy]-trans-1-oxadecalin, C18H24O4 (3), and 2α-[2,2-bis(4-chlorophenyl)ethoxy]-trans-1-oxadecalin, C23H26Cl2O2 (4) (1985) (1)
Steric assistance for intramolecular catalysis. (1970) (1)
N,N,N′,N′‐Tetramethylstreptamine 2,4,6‐orthoformate hydrochloride (2003) (1)
3-Acetoxy-2-naphthoic acid (2010) (1)
Steric assistance for intramolecular catalysis. (1970) (1)
2‐Allyloxy‐5‐chlorobenzoic acid (2007) (1)
Bond length and reactivity. Structure of 2-endo-bornyl p-toluenesulfonate (1992) (1)
Bond length and reactivity: 1-arylethyl ethers and esters. 3. Structures of three trityl ethers of 1-arylethanols: 1-phenylethyl, 1-(4-chlorophenyl)ethyl and 1-(4-nitrophenyl)ethyl triphenylmethyl ethers (1986) (1)
Intramolecular Nucleophilic Addition of Phenolate Oxygen to Double Bonds Activated by Carboxyl and Carboxylate Groups. Relative Reactivity, Stereochemistry, and Mechanism. (1988) (1)
Model systems — Artificial models of protein function (2001) (1)
The crystal structure of methoxymethoxy-2,4-dinitrobenzene (1983) (1)
Physical Organic Chemistry: A Personal Reflection (2016) (1)
INTRAMOLECULAR CATALYSIS OF SULFONAMIDE HYDROLYSIS. II. CIS-2-CARBOXY-N-METHYL-N-PHENYLETHENESULFONAMIDE (1976) (1)
The crystal structures of l-(3',5'-dinitrobenzoyloxy)-bicyclo[3.3.1]-9-oxanonane and 5-(3',5'-dinitrobenzoyloxy)-cyclooctanone1 (1983) (1)
2,2,2-Tris(cyclohexyloxy)-4,5-(2′,2′'-biphenylo)-1,3,2-dioxaphospholene (2002) (1)
The crystal structure of 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose (1982) (1)
Bond length and reactivity. Structures of the triphenylmethyl and 4-nitrophenyl ethers and the 3,5-dinitrobenzoate ester of 2,6-dichlorobenzyl alcohol (1989) (1)
Intramolecular general base catalysis by the ionised carboxy-group of the hydrolysis of aryl hydrogen malonates (1971) (1)
Bond length and reactivity. Structure of a Grob fragmentation substrate, 4aα,5β,8aβ‐1‐methyldecahydroquinolin‐5‐yl 3,5‐dinitrobenzoate (1986) (1)
Electrostatic catalysis of the hydrolysis of a phosphate diester in water (1992) (1)
Thermodynamics of Biochemical Reactions. By Robert A. Alberty. (2003) (0)
Crystal Structures of Acetals. Part 27.(2SR,6RS)-6-Phenyl-2-phenylmethoxy-6-trifluoromethyltetrahydropyran-4-one (1989) (0)
Disappearance of the gem-Dimethyl Effect: The Base-Catalyzed Cyclization of Ethyl Hydantoates. (1999) (0)
Bond length and reactivity. The effect of β-silicon. Structure of the 4-phenylbenzoate ester of 2-trimethylsilylethanol (1992) (0)
Bond length and reactivity. The effect of β‐fluorine. Structures of the 4‐phenylbenzoate and methanesulfonate esters of trans,cis‐4‐tert‐butyl‐2‐fluorocyclohexanol (1992) (0)
Structure‐Activity Studies on Amides Inhibiting Photosystem II. (1992) (0)
THE PHOSPHATE TRANSFER PROCESS (1980) (0)
INTRAMOLECULAR NUCLEOPHILIC ATTACK ON CARBOXYLATE BY UREIDE ANION. GENERAL ACID-BASE CATALYSIS OF THE ALKALINE CYCLIZATION OF 2,2,3,5-TETRAMETHYLHYDANTOIC ACID (1984) (0)
Bond length and reactivity. The pinacol rearrangement. 2. Structure of trans-2-phenoxycyclohexanol (1989) (0)
ANILIDE FORMATION FROM AN ALIPHATIC ESTER. THE MECHANISM OF CYCLIZATION OF METHYL 3-(2-AMINOPHENYL)PROPIONATE (1980) (0)
Stabilization of the Thromboxane Ring System by Electron-Withdrawing Substituents: Synthesis and Attempted Cyclization of Substituted Tetrahydropyran-2,4-diols. (1990) (0)
Off-the-Shelf Proteins that Rival Tailor-Made Antibodies as Catalysts. (1997) (0)
Bond length and reactivity. Structures of the methanesulfonate esters of cis- and trans-4-tert-butylcyclohexanol (1992) (0)
Kinetics and mechanism of the cyclization of ω-(p-nitrophenyl)-hydantoic acid amides: steric hindrance to proton transfer causes a 104-fold change in rateElectronic supplementary information (ESI) available: Observed first-order rate coefficients, constants for solvent and buffer catalysis for the c (2003) (0)
NUCLEOPHILIC ATTACK BY AMINE NITROGEN ON THE IONIZED CARBOXY GROUP (1979) (0)
Bond length and reactivity. Structures of the triphenylmethyl ether and the 4-nitrobenzoate ester of benzyl alcohol (1989) (0)
Additions and Corrections - Structure and Reactivity in Intramolecular Catalysis. Catalysis of Sulfonamide Hydrolysis by the Neighboring Carboxyl Group (1980) (0)
Bond length and reactivity. The effect of β‐silicon. Structure of the 3,5‐dinitrobenzoate ester of trans‐2‐(dimethylphenylsilyl)cyclohexanol (1992) (0)
Bond length and reactivity: the Beckmann rearrangement. 1. Structure of cyclopentanone O-(3,5-dinitrobenzoyl)oxime n-hexane solvate (4:1) (1986) (0)
CCDC 100711: Experimental Crystal Structure Determination (1998) (0)
ACID-CATALYZED HYDROLYSIS OF BENZENESULFONAMIDES - RATE ENHANCEMENTS BY ORTHO-ALKYL SUBSTITUENTS (2010) (0)
INTRAMOLECULAR CARBOXYL-CATALYZED HYDROLYSIS OF SULFONAMIDES. 5. SALT EFFECTS S ON THE INTRAMOLECULAR CARBOXYL-CATALYZED HYDROLYSIS OF SULFONAMIDES (1981) (0)
The efficiency of intramolecular general base catalysis in nonaqeous solvents (1978) (0)
A cationic zinc(II) complex of a new ligand based on N,N,N′,N′-tetramethylstreptamine 2,4,6-orthoformate as the chloride salt (2003) (0)
Bond length and reactivity. The effect of β-fluorine. Structures of the 9-(9-phenylxanthenyl) ether, and the 4-phenylbenzoate, diphenyl phosphate and methanesulfonate esters of cis,trans-4-tert-butyl-2-fluorocyclohexanol (1992) (0)
Bond length and reactivity. The effect of β-fluorine. Structures of the 4-nitrophenyl ether and the 4-nitrobenzoate ester of 2-fluoro-2-phenylethanol (1992) (0)
Stabilisation of the Thromboxane Ring System by Electron-Withdrawing Substituents. Mechanism and Reactivity in the Hydrolysis of Alkyl and Aryl Oxetane Acetals. (1990) (0)
(E)-3-Methoxymethoxybut-2-enoic acid (1978) (0)
Phosphorylation of 1,3‐Di(N‐alkyl)Azoles by Phosphorus(V) Acid Chlorides ‐ A Route to Potential Haptens Derived from Phosphinic Acids. (1996) (0)
Bond length and reactivity. The effect of β-fluorine. Structure of the methanesulfonate ester of trans,trans-5-tert-butyl-2-fluorocyclohexanol (1992) (0)
The crystal structure of 2-(N-phthalimidomethoxy)-tetrahydropyran1 (1983) (0)
Der Mechanismus der Perkow-Reaktion (1963) (0)
There is no evidence for electrostatic catalysis of vinyl ether hydrolysis in water (1991) (0)
Bond length and reactivity. Structures of the triphenylmethyl ether and the 4-nitrobenzoate ester of anti-7-norbornenol (1992) (0)
The Synthesis and Aggregation Properties of a Novel Anionic Gemini Surfactant (I). (1999) (0)
EFFICIENCY AND MECHANISM IN INTRAMOLECULAR CATALYSIS (1979) (0)
Intramolecular nucleophilic catalysis of amide hydrolysis by pyrimidine nitrogen (1978) (0)
Supplementary Material The Reaction of Hydroxylamine with Aspirin (2011) (0)
Hydroxylamine as an oxygen nucleophile . Direct evidence from its reaction with a phosphate triester (2008) (0)
Equatorial 2-phenoxy-trans-1-oxadecalin: erratum (1979) (0)
Bond length and reactivity: 1‐arylethyl ethers and esters. 2. Structure of 1‐(4‐nitrophenyl)ethyl chloroacetate (1986) (0)
Bond Length and Reactivity: The gauche Effect. A Combined Crystallographic and Theoretical Investigation of the Effects of β -Substituents on C-OX Bond Length. (1992) (0)
Exceptional Reactivity of the Aromatic Ring in 8-Substituted 1-Naphthol Derivatives. Ready Reduction to Tetralins. (1989) (0)
Bond length and reactivity. The effect of β-fluorine. Structures of the 4-phenylbenzoate, the diphenyl phosphate and the 2-naphthalenesulfonate esters of trans-2-fluorocyclohexanol (1992) (0)
Enzymatic Reaction Mechanisms. Von Perry A. Frey und Adrian D. Hegeman. (2007) (0)
Latin America as a fertile ground for advances in Physical Organic Chemistry: the contribution of Professor Faruk Jose Nome Aguilera (2019) (0)
THE SPONTANEOUS HYDROLYSIS OF ACETALS- SENSITIVITY TO THE LEAVING GROUP (1978) (0)
[Preparation and characteristics of antibodies to a sulfur-containing hapten, mimicking the transition state in lactamization reactions]. (1997) (0)
Syntheses and Structures of Anomeric Quaternary Ammonium β-Glucosides and Comments on the Anomeric C—N Bonds Lengths. (2009) (0)
Bond length and reactivity: 1-arylethyl ethers and esters. 7. Structure of 1-[3,5-bis(trifluoromethyl)phenyl]ethyl 4-nitrobenzoate (1989) (0)
N,N,N′,N′‐Tetramethylstreptamine 2,4,6‐orthoformate (2003) (0)
NH-ACIDITIES OF SOME STERICALLY HINDERED UREAS (1997) (0)
Bond length and reactivity. The pinacol rearrangement. 3. Structures of trans-2-hydroxycyclohexyl 4-nitrobenzoate and 2,4-dinitrobenzoate esters (1989) (0)
Bond length and reactivity: 1‐arylethyl ethers and esters. 5. Structure of 1‐(4‐nitrophenyl)ethyl diphenyl phosphate (1986) (0)
Bond length and reactivity. Structure of 3,5‐bis(trifluoromethyl)benzyl 4‐nitrobenzoate (1989) (0)
The chemistry of functional group series. Supplement A: The chemistry of double-bonded functional groups. Volume 2. Part 1 (1990) (0)
Bond length and reactivity. The effect of β-fluorine. Structures of the 4-methyl-, 4-chloro- and 4-nitrobenzenesulfonate esters of 2-fluoro-2-phenylethanol (1992) (0)
The Potential of Catalytic Antibodies (1996) (0)
Synthesis of B2,5 Type Conformationally Constrained Glucopyranosides. (2003) (0)
INTRAMOLECULAR CATALYSIS OF AMIDE HYDROLYSIS BY THE CARBOXY-GROUP, RATE DETERMINING PROTON TRANSFER FROM EXTERNAL GENERAL ACIDS IN THE HYDROLYSIS OF SUBSTITUTED MALEAMIC ACIDS (1974) (0)
Reactions of Acids and Their Derivatives (419 Literaturangaben). (1982) (0)
STRUCTURE AND EFFICIENCY IN INTRAMOLECULAR AND ENZYMIC CATALYSIS- INTRAMOLECULAR GENERAL BASE CATALYSIS. HYDROLYSIS OF MONOARYL MALONATES (1977) (0)
Bond length and reactivity. The effect of β-fluorine. Structures of the 4-nitrobenzenesulfonate esters of 2-fluoroethanol and 2,2,2-trifluoroethanol (1992) (0)
Intramolecular Nucleophilic Attack by Urea Nitrogen. Reactivity‐Selectivity Relationships for the General Acid‐Base Catalyzed Cyclizations of Ureido Acids and Esters (1989) (0)
Rapid intramolecular and C‐O cleavage reactions of a phosphate triester catalysed by a neighbouring hydroxyl group (2010) (0)
Bond length and reactivity. Structure of the diphenyl phosphate ester of 2,6-dichlorobenzyl alcohol (1992) (0)
The Case of the Missing Acetylene. The Mechanism of an Intramolecular SN(V) Reaction and a New Route to 1-Methylbenzo[de]quinolines. (2010) (0)
Intramolecular Hydride Transfer from a 1,4-Dihydropyridine to an α-Ketoester in Aqueous Solution. A Model for Lactate Dehydrogenase. (1987) (0)
2‐Methoxymethoxycyclopentene‐1‐carboxylic acid (1978) (0)
INTRAMOLECULARLY CATALYZED SULFONAMIDE HYDROLYSIS. 8. INTRAMOLECULAR NUCLEOPHILIC CATALYSIS BY A NEIGHBORING HYDROXYL GROUP IN ACID-CATALYZED BENZENESULFONAMIDE HYDROLYSIS (1985) (0)
Intramolecular Catalysis of Sulphate Diester Hydrolysis by One and Two Carboxy Groups. (1986) (0)
Bond length and reactivity: 1-aryl ethers and esters. 1. Three 3,5-dinitrobenzoate esters of 1-arylethanols: 1-(4-methoxyphenyl)ethyl, 1-phenylethyl and 1-(3-fluorophenyl)ethyl 3,5-dinitrobenzoates (1986) (0)
Bond length and reactivity. Structures of the triphenylmethyl ethers of 1‐indanol and 5‐methoxy‐1‐indanol (1989) (0)
The chemistry of functional group series. Supplement A: The chemistry of double-bonded functional groups. Volume 2. Part 2 (1990) (0)
THE ROLE OF THE CARBOXY-GROUP IN INTRAMOLECULAR CATALYSIS OF ACETAL HYDROLYSIS, THE HYDROLYSIS OF SUBSTITUTED 2-METHOXYMETHOXYBENZOIC ACIDS (1974) (0)
ACID-CATALYZED HYDROLYSIS OF BENZENESULFONAMIDES. RATE ENHANCEMENTS BY ORTHO-ALKYL SUBSTITUENTS (1985) (0)
INTRAMOLECULAR DISPLACEMENT OF ALKOXIDE IONS BY THE IONISED CARBOXY-GROUP, HYDROLYSIS OF ALKYL HYDROGEN DIALKYLMALEATES (1974) (0)
2,4-Dioxaadamantane. (1988) (0)
DNA Pharmaceuticals: Formulation and Delivery in Gene Therapy, DNA Vaccination and Immunotherapy. Edited by Martin Schleef. (2006) (0)
Anatomy of an SN1 Reaction. Crystal Structure-Reactivity Correlations for 1-Arylethanol Derivatives. (1987) (0)
Reactions of Acids and their Derivatives (2007) (0)

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