A. L. J. Van Der Spek
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(Suggest an Edit or Addition)A. L. J. Van Der Spek's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Structure validation in chemical crystallography (2009) (11978)
- Single-crystal structure validation with the program PLATON (2003) (10529)
- BYPASS: an effective method for the refinement of crystal structures containing disordered solvent regions (1990) (2871)
- PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors. (2015) (2009)
- PLATON, An Integrated Tool for the Analysis of the Results of a Single Crystal Structure Determination (1990) (609)
- Determination of absolute structure using Bayesian statistics on Bijvoet differences (2008) (569)
- STRONG DIMERIZATION OF UREIDOPYRIMIDONES VIA QUADRUPLE HYDROGEN BONDING (1998) (565)
- Electrocatalytic CO2 Conversion to Oxalate by a Copper Complex (2010) (440)
- Organoplatinum crystals for gas-triggered switches (2000) (398)
- checkCIF validation ALERTS: what they mean and how to respond (2020) (349)
- Crystal Structure Refinement (2006) (319)
- NMR study on the coordination behavior of dissymmetric terdentate trinitrogen ligands on methylpalladium(II) compounds (1993) (257)
- Origin of the Bite Angle Effect in Rhodium Diphosphine Catalyzed Hydroformylation. (2000) (257)
- Cyclic Bis‐Urea Compounds as Gelators for Organic Solvents (1999) (239)
- Self‐Complementarity Achieved through Quadruple Hydrogen Bonding (1998) (236)
- Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution (2009) (191)
- Dimethyl(N,N,N',N'-tetramethylethanediamine)palladium(II) and dimethyl[1,2-bis(dimethylphosphino)ethane]palladium(II): syntheses, x-ray crystal structures, and thermolysis, oxidative-addition and ligand-exchange reactions (1989) (182)
- Hydrogen-Bonded Complexes of Diaminopyridines and Diaminotriazines: Opposite Effect of Acylation on Complex Stabilities. (1996) (181)
- End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry. (2003) (179)
- IPr* an easily accessible highly hindered N-heterocyclic carbene. (2010) (162)
- Zn(II)-salphen complexes as versatile building blocks for the construction of supramolecular box assemblies. (2005) (154)
- Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines. (2003) (153)
- New neutral and ionic methyl and chloro palladium and platinum complexes containing hemilabile phosphorus-nitrogen ligands. Study of the insertion of carbon monoxide into the metal-methyl bond (1992) (150)
- Synthesis and characterization of rigid bidentate nitrogen ligands and some examples of coordination to divalent palladium. X-ray crystal structures of bis(p-tolylimino)acenaphthene and methylchloro[bis(o,o'-diisopropylphenyl-imino)acenaphthene]palladium (1994) (147)
- Capsule-controlled selectivity of a rhodium hydroformylation catalyst (2013) (146)
- Cyclometalated ruthenium complexes for sensitizing nanocrystalline TiO2 solar cells. (2007) (139)
- A two-step spin crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase. (2008) (135)
- Consequences of N,C,N'- and C,N,N'-coordination modes on electronic and photophysical properties of cyclometalated aryl ruthenium(II) complexes. (2009) (134)
- A novel isomerization on interaction of antitumor-active azole-bridged dinuclear platinum(II) complexes with 9-ethylguanine. Platinum(II) atom migration from N2 to N3 on 1,2,3-triazole. (2002) (132)
- Iron Chemistry of a Pentadentate Ligand That Generates a Metastable Fe(III)-OOH Intermediate. (1999) (128)
- Synthesis, Characterization, Spectroscopy, and Magnetism of Dinuclear Azido- and Alkoxo-Bridged Copper(II) Complexes of Bis(2-benzimidazolyl)alkanes. X-ray Structures of [Cu2(tbz)2(CH3O)2](ClO4)2(CH3OH)2, [Cu2(tbz)2(NO3)(CH3O)2](NO3)(CH3OH)2, and [Cu(tbz)(N3)2]2(CH3OH)2 (tbz = Bis(2-benzimidazolyl)p (1995) (121)
- Synthesis and properties of isostructural transition-metal (copper, nickel, cobalt, and iron) compounds with 7,7',8,8'-tetracyanoquinodimethanide(1-) in an unusual monodentate coordination mode: crystal structure of bis(3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole)bis(7,7',8,8'-tetracyanoquinodimeth (1992) (121)
- Triorganotin cations stabilized by intramolecular SnN coordination; synthesis and characterization of { C , N , N ′-2,6-bis[(dimethylamino)methyl]phenyl}diorganotin bromides (1978) (119)
- Efficient Catalytic Phosphate Diester Cleavage by the Synergetic Action of Two Cu(II) Centers in a Dinuclear Cis-Diaqua Cu(II) Calix[4]arene Enzyme Model (1998) (118)
- Bulky diphosphite modified rhodium catalyst; Hydroformylation and characterization (1996) (115)
- Conformational control in the cyclization of hydrogen-bonded supramolecular polymers. (2004) (112)
- Construction of adjacent quaternary and tertiary stereocenters via an organocatalytic allylic alkylation of Morita-Baylis-Hillman carbonates (2007) (110)
- High Superoxide Dismutase Activity of a Novel, Intramolecularly Imidazolato-Bridged Asymmetric Dicopper(II) Species. Design, Synthesis, Structure, and Magnetism of Copper(II) Complexes with a Mixed Pyrazole-Imidazole Donor Set. (1997) (108)
- The coordination behaviour of large natural bite angle diphosphine ligands towards methyl and 4-cyanophenylpalladium(II) complexes † (2002) (108)
- Dinuclear and Trinuclear Zn(II) Calix[4]arene Complexes as Models for Hydrolytic Metallo-Enzymes. Synthesis and Catalytic Activity in Phosphate Diester Transesterification (1999) (108)
- A novel type of Pt–C interaction and a model for the final stage in reductive elimination processes involving C–C coupling at Pt; synthesis and molecular geometry of [1,N,N′-η-2,6-bis{(dimethylamino)methyl}-toluene]iodoplatinum(II) tetrafluoroborate (1978) (106)
- Synthesis of Monomeric Permethylyttrocene Derivatives. The Crystal Structures of Cp*2YN(SiMe3)2 and Cp*2YCH(SiMe3)2 (1986) (105)
- Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one [2-[1-(S)-(dimethylamino)ethyl]phenyl]methylphenyltin bromide diastereomer (1978) (104)
- Phenanthroline Derivatives with Improved Selectivity as DNA‐Targeting Anticancer or Antimicrobial Drugs (2008) (104)
- Rigid five- and six-membered C,N,N' bound aryl, benzyl, and alkyl organopalladium complexes : sp2 vs. sp3 C-H activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halides (1993) (103)
- Two Examples of Novel and Unusual Double-Layered, Two-Dimensional CuII Compounds with Bridging 1,3-Bis(1,2,4-triazol-1-yl)propane (2000) (97)
- Crystal and Molecular Structures of Asymmetric cis- and trans-Platinum(II/IV) Compounds and Their Reactions with DNA Fragments (1997) (96)
- Zerovalent palladium and platinum complexes containing rigid bidentate nitrogen ligands and alkenes: synthesis, characterization, alkene rotation and substitution reactions. X-ray crystal structure of [Bis((2,6-diisopropylphenyl)imino)acenaphthene](maleic (1994) (96)
- Long-range magnetic ordering in a TbIII-MoV cyanido-bridged quasi-one-dimensional complex. (2007) (94)
- Catecholase activity of a copper(II) complex with a macrocyclic ligand: unraveling catalytic mechanisms. (2006) (93)
- Models for the Initial Stages of Oxidative Addition : Synthesis, Characterization and Mechanistic Investigation of N1-I2 Organometallic 'Pincer' Complexes of Platinum : X-ray Crystal Structures of [Ptl(C6H3{CH2NMe2}2-2,6)(N1-I2)] and exo-meso-[Pt(N1-I3)(N1-I2)(C6H3{CH2N-(t-Bu)Me}2-2,6) (1999) (91)
- Cooperative Dynamics in Duplexes of Stacked Hydrogen-Bonded Moieties (1999) (91)
- Novel multicomponent reaction for the combinatorial synthesis of 2-imidazolines. (2003) (91)
- Design and Performance of Rigid Nanosize Multimetallic Cartwheel Pincer Compounds as Lewis-Acid Catalysts (2001) (91)
- Fluorous Versions of Wilkinson's Catalyst : Activity in Fluorous Hydrogenation of 1-Alkenes and Recycling by Fluorous Biphasic Separation (2000) (91)
- Stable palladium(0), palladium(II) and platinum(II) complexes containing a new, multifunctional and hemilabile phosphino-imino-pyridyl ligand: Synthesis, characterization and reactivity (1996) (90)
- Molecular recognition in a thermoplastic elastomer. (2005) (90)
- G-quadruplex self-assembly regulated by Coulombic interactions. (2009) (90)
- "Click" 1,2,3-triazoles as tunable ligands for late transition metal complexes. (2007) (89)
- A New Class of Organocopper and Organocuprate Compounds Derived from Copper( I) Arenethiolates (1992) (85)
- Highly selective hydrocyanation of butadiene toward 3-pentenenitrile. (2007) (84)
- Trans 2,6-bis[(dimethylamino)methyl]phenyl-N,N,C complexes of Pd(II) and Pt(II). Crystal structure of [PtI(MeC6H3(CH2NMe2)2-o,o)]BF4: A cyclohexadienyl carbonium ion with a s-bonded metal substituent, (1982) (84)
- Bulky monodentate phosphoramidites in palladium-catalyzed allylic alkylation reactions: aspects of regioselectivity and enantioselectivity. (2004) (84)
- Dinuclear Paddle-Wheel Copper(II) Carboxylates in the Catalytic Oxidation of Carboxylic Acids. Unusual Polymeric Chains Found in the Single-Crystal X-ray Structures of [Tetrakis(&mgr;-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-Poly[[bis(&mgr;-diphenylacetato-O:O') (1997) (84)
- Dinuclear Ruthenium Complexes Bearing Dicarboxylate and Phosphine Ligands. Acceptorless Catalytic Dehydrogenation of 1-Phenylethanol (2006) (83)
- Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS)2] (2009) (83)
- Insertion Chemistry of Cp*2Y(2-pyridyl) and Molecular Structure of the Unexpected CO Insertion Product (Cp*2Y)2(μ-η2: η2-OC(NC5H4)2) (1994) (83)
- Supramolecular zinc(II)salphen motifs: Reversible dimerization and templated dimeric structures (2006) (81)
- Iron(II) complexes with bio-inspired N,N,O ligands as oxidation catalysts: olefin epoxidation and cis-dihydroxylation. (2008) (81)
- Sulfonamido-phosphoramidite ligands in cooperative dinuclear hydrogenation catalysis. (2009) (81)
- Redox Properties and Electrocatalytic Activity of the Oxo/Aqua System [Ru(terpy)(bpz)(O)]2+/[Ru(terpy)(bpz)(H2O)]2+. X-ray Crystal Structure of [Ru(terpy)(bpz)Cl]PF6.cntdot.MeCN (terpy = 2,2',2''-Terpyridine; bpz = 2,2'-Bipyrazine) (1995) (80)
- Synthesis and properties of para-substituted NCN-pincer palladium and platinum complexes. (2004) (79)
- Using the t‐distribution to improve the absolute structure assignment with likelihood calculations (2010) (77)
- Synthesis, spectroscopic properties and X-ray crystal structures of two dinuclear alkoxo-bridged copper(II) compounds with the ligand bis(1-methyl-2-benzimidazolyl) propane. A unique alkoxo-bridged Cu(II) dinuclear compound with an additional bidentate bridging triflate anion (1997) (76)
- Modeling the 2-His-1-carboxylate facial triad: iron-catecholato complexes as structural and functional models of the extradiol cleaving dioxygenases. (2007) (75)
- New antitumor-active azole-bridged dinuclear platinum(II) complexes: synthesis, characterization, crystal structures, and cytotoxic studies. (2000) (75)
- Transcyclometalation Processes with Late Transition Metals: CarylH Bond Activiation via Noncovalent CHCl Interactions (2000) (75)
- Synthesis, Structure, Magnetic Behavior, and Mössbauer Spectroscopy of Two New Iron(II) Spin-Transition Compounds with the Ligand 4-Isopropyl-1,2,4-triazole. X-ray Structure of [Fe(3)(4-isopropyl-1,2,4-triazole)(6)(H(2)O)(6)](tosylate)(6).2H(2)O. (1997) (75)
- Mixed Alkali Systems: Structure and 29Si MASNMR of Li2Si2O5 and K2Si2O5 (1998) (74)
- Toward a switchable molecular rotor. Unexpected dynamic behavior of functionalized overcrowded alkenes (1997) (73)
- Cu(I) complexes with a noninnocent PNP ligand: selective dearomatization and electrophilic addition reactivity. (2009) (73)
- Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor (1999) (71)
- Bifunctional pincer-type organometallics as substrates for organic transformations and as novel building blocks for polymetallic materials. (2002) (71)
- Structure-dependent in vitro cytotoxicity of the isomeric complexes [Ru(L)2Cl2] (L=o-tolylazopyridine and 4-methyl-2-phenylazopyridine) in comparison to [Ru(azpy)2Cl2] (2004) (71)
- Replacement of a cyclometalated terdentate diamino ligand by a phosphorus analogue. Isolation and crystallographic characterization of an intermediate in aryl C-H bond activation in models of dendrimer-bound organometallic catalysts (1997) (70)
- Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'} (h1-I2)] containing a linear Pt-I-I arrangement (1986) (70)
- New cytotoxic and water-soluble bis(2-phenylazopyridine)ruthenium(II) complexes. (2003) (70)
- Crystal and molecular structure of C, N-{2-[(dimethylamino)methyl]phenyl} diphenyltin bromide (1976) (70)
- Synthesis, magnetic properties, and X-ray structure of catena-µ3-nitrato-O,O′,O″-[µ3-hydroxo-1-nitrato-1,2;1,3;2,3-tris(µ-pyrazolato-N,N′)-2,3-bis(pyrazole-N2)tricopper(II) monohydrate]. An unusual chain of trinuclear copper clusters (1983) (70)
- New isomeric azine-bridged dinuclear platinum(II) complexes circumvent cross-resistance to cisplatin. (2003) (69)
- A Bis(ortho-amine)aryl-Gold(I) Compound as an Efficient, Nontoxic, Arylating Reagent (2002) (69)
- Catalyst selection based on intermediate stability measured by mass spectrometry (2010) (69)
- A highly flexible dinuclear ruthenium(II)-platinum(II) complex: crystal structure and binding to 9-ethylguanine. (2004) (69)
- Encapsulated transition metal catalysts comprising peripheral Zn(II)salen building blocks: template-controlled reactivity and selectivity in hydroformylation catalysis. (2005) (68)
- Structural investigations of silver(I) and copper(I) complexes with neutral N4 donor ligands; the X-ray crystal and molecular structure of the dimer [Ag2{m-(R,S)-1,2-(py-2-CH=N)2cyclohexane}2][O3SCF3]2 and 1H and 13C and INEPT 109Ag and 15N NMR solution studies (1984) (68)
- Donor-functionalized polydentate pyrylium salts and phosphinines: synthesis, structural characterization, and photophysical properties. (2007) (68)
- FORMATION OF A NOVEL ETA-3-ETA-4-1,2,3-TRIMETHYL-4,5-DIMETHYLENECYCLOPENTENYL LIGAND BY HYDROGEN ABSTRACTION FROM A PERMETHYLCYCLOPENTADIENYL GROUP IN PERMETHYLTITANOCENE CARBYL AND RELATED SYSTEMS (1985) (68)
- Methoxycarbonylation of Ethene by Palladium(II) Complexes with 1,1‘-Bis(diphenylphosphino)ferrocene (dppf) and 1,1‘-Bis(diphenylphosphino)octamethylferrocene (dppomf) (2003) (67)
- An unprecedented 1D ladder coordination polymer based on a pentanuclear copper(II) 2,4,6-tris(dipyridin-2-ylamino)-1,3,5-triazine building block. (2002) (67)
- Monomeric Bis(pentamethylcyclopentadienyl)titanium(III) Complexes with Halide, Borohydride, Amide, Alkoxide, and Carboxylate Ligands: X-ray Structure of Bis(pentamethylcyclopentadienyl)titanium(III) Chloride (1987) (66)
- Stereospecific Reaction of Molecular Halogens with Palladacyclopentadienes Containing Bidentate Nitrogen Ligands To Give 1,4-Dihalo-1,3-dienes via Palladium(IV) Intermediates. (2003) (66)
- New Antitumor-Active Azole-Bridged Dinuclear Platinum(II) Complexes: Synthesis, Characterization, Crystal Structures, and Cytotoxic Studies. (2000) (66)
- T-shaped cationic CuI complexes with hemilabile PNP-type ligands. (2008) (66)
- Monomeric bis(h2-alkyne) complexes of copper(I) and silver(I) with h1-bonded alkyl, vinyl, and aryl ligands (1996) (65)
- Organonickel(II) complexes of the terdentate monoanionic ligand o,o'-bis[(dimethyl-amino)methyl] phenyl (N-C-N). Syntheses and X-ray crystal structure of the stable nickel(II) formate [Ni(N-C-N)O2CH] (1984) (65)
- Unique ligand-based oxidative DNA cleavage by zinc(II) complexes of hpyramol and hpyrimol. (2007) (65)
- Crystal engineering of melamine - imide complexes: tuning the stoichiometry by steric hindrance of the imide carbonyl groups (1997) (65)
- Synthesis, X-ray structure, spectroscopy and magnetism of polymeric bis(μ-dicyanamido)(μ-pyrimidine)copper(II) monoacetonitrile; a 3D compound with bridging dicyanamide anions in two dimensions (2001) (64)
- Rigid bis-zinc(II) salphen building blocks for the formation of template-assisted bidentate ligands and their application in catalysis. (2007) (64)
- Sterically demanding diphosphonite ligands - synthesis and application in nickel-catalyzed isomerization of 2-methyl-3-butenenitrile (2004) (64)
- Synthesis and Characterization of the Bis-Cyclometalating Ligand 3,3‘,5,5‘-Tetrakis[(dimethylamino)methyl]biphenyl and Its Use in the Preparation of Bimetallic M(II), M(IV) (M = Pt, Pd), and Mixed-Valence Pt(II)−Pt(IV) Complexes via a Dilithio-Derivative. Crystal Structure of the Pd Dimer [ClPd{2,6- (1998) (64)
- A Cationic AgI(PNPtBu) Species Acting as PNP Transfer Agent: Facile Synthesis of Pd(PNPtBu)(alkyl) Complexes and Their Reactivity Compared to PCPtBu Analogues (2009) (63)
- Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene (2006) (63)
- Chiral platinum and palladium complexes containing functionalized C2-symmetric bisaminoaryl ‘Pincer’ ligands (2001) (62)
- Synthesis, Molecular Structure, and Reactivity of a Half-Sandwich Vanadium(III) Imido Complex: The First Vanadium(V) Alkylidene (1994) (62)
- Copper(II)-Mediated Oxidative Coupling of Bis(dimethylaminomethyl)arylruthenium Complexes to give [(terpy)RuIII(pincer-pincer)-RuIII(terpy)](CuCl2)4 (1994) (62)
- Cationic and neutral Ni(II) complexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species. (2009) (62)
- The Stepwise Successive Insertion of carbon Monoxide and Allenes into Palladium-carbon Bonds of complexes Containing the Rigid Bidentate Nitrogen Ligand bis(p-anisylimino)acenaphthene. (1996) (61)
- Titanium dichloro, bis(carbyl), aryne, and alkylidene complexes stabilized by linked cyclopentadienyl-amido auxiliary ligands (1997) (61)
- Aggregation of [Cu${{\bf }{{{\bf II}\hfill \atop \bf 4\hfill}}}$] Building Blocks into [Cu${{\bf }{{{\bf II}\hfill \atop \bf 8\hfill}}}$] Clusters or a [Cu${{\bf }{{{\bf II}\hfill \atop \bf 4\hfill}}}$]∞ Chain through Subtle Chemical Control (2004) (61)
- Titanium dichloro, bis(carbyl), aryne, and alkylidene complexes stabilized by linked cyclopentadienyl-amido auxiliary ligands (1997) (61)
- Palladium and platinum diphenoxide and aryl phenoxide complexes with amine donors : Effect of hydrogen bonding on structure and properties (1992) (61)
- Synthesis of novel chelating benzimidazole-based carbenes and their nickel(II) complexes: activity in the Kumada coupling reaction (2009) (60)
- A Convenient Synthetic Route for the Preparation of Nonsymmetric Metallo- salphen Complexes (2005) (60)
- Comparative Rates of Ligand Substitution Reactions of Pt-C-Bonded Complexes in Aqueous Solution and the X-ray Crystal Structure of (Pt{C6H3(CH2NMe2)2-2,6}(OH2))(OSO2CF3) (1996) (59)
- Oxidative Addition of Carbon−Chloride Bonds to Rhodium(I) Complexes Containing Terdentate Nitrogen Ligands. X-ray Analyses of Rhodium(I) Chloride and Rhodium(III) Chloromethyl Complexes (1997) (59)
- Selective self-organization of guest molecules in self-assembled molecular boxes. (2005) (59)
- Stoichiometric and Catalytic Conversion of Alkynes to Conjugated (Z,Z)-Dienes and Cyclopentadienes via Palladacyclopentadienes and 1,3-Dienylpalladium(II) Halide and Triorganopalladium(IV) Halide Compounds Containing Chelating Nitrogen Ligands† (1998) (59)
- Crystal and molecular structure, spectroscopy, and magnetism of diaquobis(imidazole)catena-.mu.-(squarato-1,3)-nickel(II). A one-dimensional polymer (1979) (58)
- Bimetallic Sesquifulvalene Complexes–Compounds with Unusually Large Hyperpolarizability β (1996) (58)
- Isocyanide Insertion into the Palladium−Carbon Bond of Complexes Containing Bidentate Nitrogen Ligands: A Structural and Mechanistic Study (1997) (58)
- Counterion effect on the spin-transition properties of the cation [Fe(btzx)3]2+ (btzx=m-Xylylenebis(tetrazole)). (2008) (58)
- Organoplatinum building blocks for one-dimensional hydrogen bonded polymeric structures (1996) (58)
- Coordination compounds from 1,3,5-triazine-derived multi-directional ligands: application in oxidation catalysis. (2003) (57)
- Synthesis and properties of trimeric ortho-chelated (arenethiolato)copper(I) complexes (1991) (57)
- N-Heterocyclic carbene functionalized iridium phosphinidene complex [Cp*(NHC)Ir=PMes*]: comparison of phosphinidene, imido, and carbene complexes. (2003) (57)
- The binding mode of the ambidentate ligand dicyanamide to transition metal ions can be tuned by bisimidazoline ligands with H-bonding donor property at the rear side of the ligand (2003) (57)
- Hydrogen-bonded porous solid derived from trimesic amide (1997) (57)
- A new 3-D polymeric spin transition compound: [tris(1,4-bis(tetrazol-1-yl)butane-N1,N1′)iron(II)] bis(perchlorate) (2001) (57)
- Synthesis and characterization of volatile, thermally stable bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)barium-, -strontium- and -calcium · polyether complexes, suitable as precursors in chemical vapour deposition (1991) (57)
- Metal-directed self-assembly of a Zn(II)-salpyr complex into a supramolecular vase structure. (2007) (57)
- Rhenium(V)-Salen Complexes: Configurational Control and Ligand Exchange. (1998) (57)
- 2,6-Bis(oxazolinyl)phenylnickel(II) bromide and 2,6-bis(ketimine)phenylnickel(II) bromide: Synthesis, structural features, and redox properties (2007) (57)
- Self-assembled Organoplatinum(II) Supermolecules as Crystalline, SO2 Gas-triggered Switches (2000) (57)
- Activation of ethers and sulfides by organolanthanide hydrides - molecular-structures of (cp-asterisk(2)y)(2)(mu- och(2)ch(2)0)(thf)(2) and (cp-asterisk-ce-2)(2)(mu-o)(thf)(2) (1995) (56)
- Enantioselective cyclization of racemic supramolecular polymers. (2003) (55)
- X-Ray Structural Analyses of Organomagnesium Compounds (1993) (55)
- Ionic 4,4‘-Biphenylene-Bridged Bis-ruthenium Complexes [Ru2(4,4‘-{C6H2(CH2NMe2)2-2,6}2)(terpy)2]n+ (n = 2 and 4) and Their Reversible Redox Interconversion: A Molecular Switch (1998) (55)
- Steric and electronic ligand perturbations in catalysis: asymmetric allylic substitution reactions using C2-symmetrical phosphorus-chiral (bi)ferrocenyl donors. (2001) (55)
- A hydrogen atom in an organoplatinum-amine system. 1. Synthesis and spectroscopic and crystallographic characterization of novel zwitterionic complexes with a Pt(II)[sup [minus]][center dot][center dot][center dot]H-N[sup +] unit (1992) (55)
- A model structure for the resting state of cyanocuprate reagents R2Cu(CN)Li2. The X-ray Crystal Structure of [Ar2Cu(CN)Li2(THF)4] (1998) (55)
- Terminal phosphinidene complexes Cp-R(L)M=PAr of the group 9 transition metals cobalt, rhodium, and iridium. Synthesis, structures, and properties (2003) (54)
- Development of the First P‐Stereogenic PCP Pincer Ligands, Their Metallation by Palladium and Platinum, and Preliminary Catalysis (2001) (54)
- 5-HT1A-versus D2-receptor selectivity of flesinoxan and analogous N4-substituted N1-arylpiperazines. (1997) (54)
- Diphosphinine derivatives of terpyridine: a new class of neutral pi-accepting PNP-pincer ligands. (2008) (54)
- A Unique Asymmetric [Mn$\rm{^{II}_{3}}$] Triple-Stranded Helicate from a Symmetric Pentadentate Ligand Financial support by the European Union, under contract HPMF-CT-1999-00113 (Marie Curie Fellowship to G.A.), the WFMO (J.R.), and the CW-NOW (A.L.S.) is thankfully acknowledged. (2001) (54)
- Increase in coordination number of lanthanide complexes with 2,2′-bipyridine and 1,10-phenanthroline by using β-diketonates with electron-withdrawing groups (2001) (54)
- Modular Synthesis of Bidentate Triazolyl-Functionalized N-Heterocyclic Carbenes and Their Palladium Complexes (2010) (54)
- Substituted 4,4′-Stilbenoid NCN-Pincer Platinum(II) Complexes. Luminescence and Tuning of the Electronic and NLO Properties and the Application in an OLED (2008) (53)
- 16- 18-electron ruthenium(II) complexes of the neutral, potentially tridentate triamine logand 2,6-[bis(dimethylamino)methyl]pyridine (NN'N) (1998) (53)
- SIAPhos: Phosphorylated Sulfonimidamides and their Use in Iridium-Catalyzed Asymmetric Hydrogenations of Sterically Hindered Cyclic Enamides (2012) (53)
- Photocontrolled release and uptake of a porphyrin guest by dithienylethene-tethered beta-cyclodextrin host dimers. (2004) (53)
- Tripodal Tris‐Urea Derivatives as Gelators for Organic Solvents (2000) (52)
- Oxygenation of cyclopalladated N,N-dimethylbenzylamine complexes by inorganic and organic peroxides : Oxygen insertion into the palladium-carbon bond (1993) (52)
- Catalytic enantioselective Michael addition reactions of α-nitroesters to α,β-unsaturated ketones (1997) (52)
- Novel P-Stereogenic PCP Pincer-Aryl Ruthenium(II) Complexes and Their Use in the Asymmetric Hydrogen Transfer Reaction of Acetophenone (2005) (52)
- Nickel and palladium complexes of pyridine-phosphine ligands as ethene oligomerization catalysts (2009) (52)
- Activity of SPANphos rhodium dimers in methanol carbonylation. (2005) (52)
- A Mixed-Valence Tetranuclear Copper Cluster with Localized Valencies. (1997) (51)
- Cyclopalladation of 2-[(Dimethylamino)methyl]-Substituted Naphtalenes : 1- vs 3-Palladation. Crystal Structures of [Hydrotris(pyrazoly)borato][2-[(dimethylamino)methyl]-3-naphthyl]palladium and trans-[4,4-Dimethyl-2-(2-naphthyl)oxazoline]palladium Dichloride (1994) (51)
- Solid state organisation of C60 by inclusion crystallisation with triptycenes (1999) (51)
- Dithiacrown Ether Substituted Porphyrazines: Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions. (1996) (51)
- Low-temperature structure of lithium nesosilicate, Li4SiO4, and its Li1s and O1s X-ray photoelectron spectrum (1994) (50)
- Carbanions as Intermediates in the Formation of Grignard Reagents (2002) (50)
- 1,2-Methyl shift between Pt and coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of Pt(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(Me C6H3(CH2NMe2)2-o,o')]I (1985) (50)
- Comparison between SiMe2 and CMe2 spacers as sigma-bridge for photoinduced charge transfer (1996) (50)
- N-donor functionalized N-heterocyclic carbene nickel(II) complexes in the Kumada coupling. (2009) (49)
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- Versatile N,C,N Coordiantion Behaviour of a Monoanionic Aryldiamine Ligand in Ruthenium(II) Complexes: Syntheses and Crystal structures of [RuII{C6H3(CH2NMe2)2-2,6}X(L)](L=Norbornadiene, X=Cl, SO3CF3; L=PPh3, X=I) and [RuII{C6H3(CH2NMe2)2-2,6}(2,2':6',2'-terpyridine)]Cl (1996) (49)
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- Dynamic configurational isomerism of a stable pentaorganosilicate. (2004) (49)
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- Crystal structure of (benzotriazolato)thallium(I) and its relation with the mechanism of corrosion inhibition by benzotriazole (1979) (48)
- N6,C8-distributed adenosine derivatives as partial agonists for adenosine A1 receptors. (1996) (48)
- Probing the mer- to fac-isomerization of tris-cyclometallated homo- and heteroleptic (C,N)3 iridium(III) complexes. (2008) (48)
- Synthesis and Binding-Properties of Basket-Shaped Hosts (1989) (48)
- The homoleptic sandwich anion [Co(P2C2tBu2)2]-: a versatile building block for phosphaorganometallic chemistry. (2008) (48)
- Phosphorous-chiral analogues of 1,1'-Bis(diphenylphosphino)ferrocene: Asymmetric synthesis and application in highly enantioselective rhodium-catalyzed hydrogenation reactions (1999) (47)
- A novel pentadentate ligand 2,6-bis[methoxybis(2-pyridyl)methyl]pyridine L for mononuclear iron(II) and manganese(II) compounds; Synthesis and crystal structures of [FeL(MeCN)][ClO4](2) and [(MnL(H2O)][ClO4](2) (1997) (47)
- The structure of the grignard reagent : IX. The crystal structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex (1974) (47)
- Coordinational behavior of solvent-free diorganylzinc compounds: the remarkable x-ray structure of dimeric diphenylzinc (1990) (47)
- Developing a new class of axial chiral phosphorus ligands: preparation and characterization of enantiopure atropisomeric phosphinines. (2008) (46)
- Chiral bidentate phosphabenzene-based ligands: synthesis, coordination chemistry, and application in Rh-catalyzed asymmetric hydrogenations (2006) (46)
- A pyrazole ligand yielding both chloro-bridged dinuclear and tetranuclear copper(II) compounds. The crystal and molecular structure of bis[μ-chloro-chloro(3,4-dimethyl-5-phenylpyrazole)(4,5-dimethyl-3-phenylpyrazole)copper(II)] and of (μ4-oxo)hexakis(μ-chloro)tetrakis(3,4-dimethyl-5-phenylpyrazole)t (1991) (46)
- Calix[4]arene based monophosphites, identification of three conformations and their use in the rhodium-catalysed hydroformylation of 1-octene (2000) (45)
- DNA cleavage and antitumour activity of platinum(II) and copper(II) compounds derived from 4-methyl-2-N-(2-pyridylmethyl)aminophenol: spectroscopic, electrochemical and biological investigation. (2009) (45)
- Redox chemistry and electronic properties of 2,3,5,6-tetrakis(2-pyridyl)pyrazine-bridged diruthenium complexes controlled by N,C,N'-biscyclometalated ligands. (2009) (45)
- What makes a crystal structure report valid (2018) (45)
- A novel three-component reaction toward dihydrooxazolopyridines. (2009) (45)
- INDOLPhosphole and INDOLPhos palladium−allyl complexes in asymmetric allylic alkylations (2009) (45)
- Structure of a second monoclinic polymorph of triphenylphosphine oxide (1987) (45)
- The mechanism of ureido-pyrimidinone:2,7-diamido-naphthyridine complexation and the presence of kinetically controlled pathways in multicomponent hydrogen-bonded systems. (2008) (45)
- Phosphepines: convenient access to phosphinidene complexes. (2005) (45)
- [Fe(mu-btzmp)2(btzmp)2](ClO4)2: a doubly-bridged 1D spin-transition bistetrazole-based polymer showing thermal hysteresis behaviour. (2007) (45)
- Trigonal-Prismatic vs. Octahedral Geometry for Mn(II) Complexes with Innocent Didentate Ligands: A Subtle Difference as Shown by XRD and DFT on [Mn(acac)2(bpy)]. (2005) (44)
- Methyl-, acetyl- and allyl-palladium and -platinum complexes containing the novel chiral phosphorus-imine 2-(diphenylphosphino)- benzylidene-S( - )-a-methyl-benzylamine ligand (1996) (44)
- X-ray Structures and Redox Properties of Copper(II) Bis(pyrazole) Complexes (1995) (44)
- Diastereoselective Ortho-Metalation of Stereogenic Ferrocenylphosphine Oxides. Asymmetric Synthesis of the First Enantiopure Phosphorus-Chiral 2,2‘-Bis(diarylphosphino)-1,1‘-biferrocenyls (2000) (44)
- Intramolecularly Stabilized 1,4-Phenylene-Bridged Homo- and Heterodinuclear Palladium and Platinum Organometallic Complexes Containing N,C,N-Coordination Motifs (1998) (44)
- Silver complexes containing an Ag4O8 core imposed by multidentate ligands having fixed geometry. Crystal structure of**[bis(1,8-naphthalenedicarboxylato)] [tetrakis(triphenylphosphine)silver(I)] dibenzene (1979) (43)
- Bimetallic η6,η1 SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity (2010) (43)
- Macrocycle synthesis by olefin metathesis on a nanosized, shape-persistent tricationic platinum template. (2003) (43)
- X-Ray and NMR Study of the Structural Features of SCS-Pincer Metal Complexes of the Group 10 Triad (2008) (43)
- Concerning the localization of end groups in dendrimers (1998) (43)
- Highly Selective Cobalt-Catalyzed Hydrovinylation of Styrene (2009) (43)
- Dichlorobis(2-phenylazopyridine)ruthenium(II) complexes: characterisation, spectroscopic and structural properties of four isomers. (2004) (43)
- Extended structures in crystalline phyllosilicates: silica ring systems in lithium, rubidium, cesium, and cesium/lithium phyllosilicate (1994) (43)
- A Homologous Series of Homoleptic Zinc Bis(1,4-di-tert-butyl-1,4-diaza-1,3-butadiene) Complexes: K(x)[Zn(t-BuNCHCHN-t-Bu)(2)], Zn(t-BuNCHCHN-t-Bu)(2), and [Zn(t-BuNCHCHN-t-Bu)(2)](OTf)(x) (x = 1, 2). (1998) (43)
- Insertions of Allenes into Palladium-Carbon Bonds of Complexes Containing Bidentate Nitrogen Ligands. Structural and Mechanistic Studies (1997) (42)
- Novel Concave Building Block for the Synthesis of Organic Hosts (1987) (42)
- para-Functionalized NCN-Pincer Palladium(II) Complexes: Synthesis, Catalysis and DFT Calculations (2003) (42)
- Characterization by NMR Spectroscopy, X‐ray Analysis and Cytotoxic Activity of the Ruthenium(II) Compounds [RuL3](PF6)2(L = 2‐Phenylazopyridine or o‐Tolylazopyridine) and [RuL'2L''](PF6)2(L', L'' = 2‐Phenylazopyridine, 2,2'‐Bipyridine) (2005) (42)
- Polycationic (mixed) core-shell dendrimers for binding and delivery of inorganic/organic substrates. (2001) (42)
- New Ruthenium(II) Complexes of Functionalized Monoanionic Aryldiamine N,C,N'‐Terdentate Ligands: Syntheses of [RuII{2,6‐(Me2NCH2)2‐4‐R‐C6H2}‐(terpy)]+Cl‐; X‐ray Structure of a Dimeric Organolithium Compound, [Li{2,6‐(Me2NCH2)2‐4‐Ph‐C6H2}]2 (1996) (42)
- A Unique Mononuclear Nickel Disulfonato Complex Obtained by Oxidation of a Mononuclear Nickel Dithiolate Complex. (1997) (42)
- Synthesis of cyclic bifunctional organomagnesium compounds. X-ray crystal structures of tetrameric organomagnesium clusters (1993) (42)
- Regulatory strategies in the complexation and release of a noncovalent guest trimer by a self-assembled molecular cage. (2003) (42)
- The crystal and molecular structure of cyclopentadienyltin(II) chloride. The bonding of the cyclopentadienyl group in tin(II) compounds (1975) (42)
- Synthesis and resolution of planar-chiral ruthenium-palladium complexes with ECE' pincer ligands. (2009) (41)
- Selective Formation of Four-Membered Metallacyclic Pt-N-P-C Compounds from Reactions of Bis((N-arylimino)phosphoranyl)methanes with Halide-Bridged Platinum(II) Phosphine Dimers. X-ray Crystal Structures of [PtCl(PMe2Ph){CH(PPh2:NC6H4-4-CH3)(PPh2N'HC6H4-4-CH3)}]+Cl- and [PtCl(PEt3){CH(PPh2:NC6H4-4-CH (1995) (41)
- Synthesis of Novel Terminal Iridium Phosphinidene Complexes (2002) (41)
- Designing Ionic Liquids: 1-Butyl-3-Methylimidazolium Cations with Substituted Tetraphenylborate Counterions (2003) (41)
- Reactions of Sodium Bis(N-aryliminophosphoranyl)alkanides with Halide-Bridged Platinum(II) and Palladium(II) Phosphine Dimers Affording Four-Membered M−N−P−C Metallacycles and Orthometalated Platinum(II) and Palladium(II) Complexes (1996) (41)
- Binaphthol‐Based Diphosphite Ligands in Asymmetric Nickel‐Catalyzed Hydrocyanation of Styrene and 1,3‐Cyclohexadiene: Influence of Steric Properties (2007) (41)
- Vanadium(IV) and -(V) complexes with O,N-chelating aminophenolate and pyridylalkoxide ligands. (2000) (41)
- Diorganoruthenium complexes incorporating noninnocent [C(6)H(2)(CH(2)ER(2))(2)-3,5](2)(2-) (E = N, P) bis-pincer bridging ligands: synthesis, spectroelectrochemistry, and DFT studies. (2007) (41)
- Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination (2006) (41)
- Halide-Assisted Macrocyclic Ring Formation in Cyclometalated Carbosilane Dendrimers with 1-[C6H3(CH2NMe2)-4-(PdCl)-3] Peripheral Groups: Application as Aldol Condensation Catalysts (2001) (41)
- Rhodium Complexes of Sterically Demanding Diphosphonites: Coordination Chemistry and Catalysis. (2004) (41)
- Crystallization and Characterization of a New Magnesium Sulfate Hydrate MgSO4·11H2O (2007) (41)
- Synthesis, characterization, crystal structures and magnetic properties of di- and polynuclear bis(μ-3-pyridin-2-yl-1,2,4- triazolato)copper(II) compounds containing N-methylimidazole, pyrazole or 4,4′-bipyridine as co-ligands (1993) (40)
- 2,4,6-Triisopropylphenylcopper, a new tetranuclear organocopper aggregate with unsymmetrically bridging s-p bonded aryl ligands (1989) (40)
- Synthesis and Characterisation of New Nickel-Iron Complexes with an S4 Coordination Environment around the Nickel Centre (2003) (40)
- Synthesis and molecular structures of novel α-amino organoaluminum ester enolates. Key intermediates in the selective formation of trans-3-amino-2-azetidinones (1991) (40)
- Organozinc α-diimine radicals. Synthesis and reactivity toward alkyl halides (1994) (40)
- Template-assisted ligand encapsulation; the impact of an unusual coordination geometry on a supramolecular pyridylphosphine-Zn(II)porphyrin assembly. (2005) (40)
- Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents (2008) (40)
- Strongly isolated ferromagnetic layers in poly-trans-mu-dichloro- and poly-trans-mu-dibromobis(1-(2-chloroethyl)-tetrazole-N4)copper(II) complexes. (2002) (40)
- X-ray structure of (1,3-xylyl-18-crown-5)diphenylmagnesium: an organometallic rotaxane (1988) (39)
- Versatility in phenolate bonding in organoaluminum complexes containing Mono- and Bis(ortho)-chelating phenolate ligands. X-ray structures of Al{OC6H2(CH2NMe2)2-2,6-Me-4}3, Al(Me)2{OC6H2(CH2NMe2-2,6-Me-4} N-AlMe3, and Al(Me)2{OC6H2(CH2NMe2)2-2,6-Me-4} N-AlMe3O-AlMe3 (1995) (39)
- Synthesis and Structure-Activity Relationships of Conformationally Constrained Histamine H3 Receptor Agonists. (2003) (39)
- Synthesis, Characterization, and Reactions of Rhodium(I) and Iridium(I) Bis(Iminophosphoranyl)Methanide Complexes in Which the Ligand Acts as a Sigma-N,Sigma-C Chelate - X-Ray Crystal-Structure of [Ir(CH(PPh2=N-C6H4-CH3-4)2)(COD)] (1993) (39)
- Oligo(cyclohexylidenes): Parent Compounds and End-Functionalized Derivatives (1995) (39)
- Sulfur dioxide gas detection by reversible η1-SO2–Pt bond formation as a novel application for periphery functionalised metallo-dendrimers‡ (1998) (39)
- Phospha-scorpionate complexes by click chemistry using phenyl azide and ethynylphosphine oxides (2008) (39)
- Synthesis, crystal structure, studies in solution and cytotoxicity of two new fluorescent platinum(II) compounds containing anthracene derivatives as a carrier ligand. (2008) (39)
- Monomeric Bis(eta(2)-alkyne)copper(I) and -silver(I) Halides, Pseudohalides, and Arenethiolates. (1996) (38)
- Chiral bidentate aminophosphine ligands: synthesis, coordination chemistry and asymmetric catalysis. (2005) (38)
- N-Heterocyclic Carbene Functionalized Group 7-9 Transition Metal Phosphinidene Complexes (2009) (38)
- Reactions of bis(iminophosphoranes) with palladium(II) dichloride: Metal-induced tautomerization orthopalladation and unexpected platinum-assisted [2 + 2] cycloaddition of an aryl-nitrile with a phosphinimine moiety (1997) (38)
- Synthesis and structural studies of phenyl( iodo) - and methyl( phenyl) palladium( II) complexes of bidentate nitrogen donor ligands (1994) (38)
- Mono(NCN-pincer palladium)-metalloporphyrin catalysts: evidence for supramolecular bimetallic catalysis. (2010) (38)
- Application of S,N-Chelating Chiral Zinc Bis(aminoarenethiolates) as New Precursor Catalysts in the Enantioselective Addition of Dialkylzincs to Aldehydes† (1997) (38)
- Chiral Amino Alcohol Derived Bis-phosphoramidite Pincer Palladium Complexes and Their Applications in Asymmetric Allylation of Aldimines (2010) (38)
- Orthometalation of m-bis(dimethylaminomethyl)benzene: crystal structure and chemistry of trans-Rh(III)Cl2[C6H3(CH2NMe2)2-o,o'](H2O) (1988) (38)
- Chemistry of P,N-Ligated Methylpalladium(II) Alkoxide Complexes: Syntheses, Structural Features in the Solid State and in Solution, and Hydrogen-Bond Formation (1996) (38)
- 3H-benzophosphepine complexes: versatile phosphinidene precursors. (2005) (38)
- Synthesis, spectroscopic and electrochemical properties and X-ray studies of bis(2,2′-bipyridyl)(3-(2-hydroxy-phenyl)-5-(pyridin-2-yl)- 1,2,4-triazole)-ruthenium(II)hexafluorphosphate (1990) (38)
- Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(η6‐Ar)(L)MPMes*] (2003) (38)
- Structural and Magnetic Characterization of a Linear Trinuclear Copper Complex Formed through Ligand Sharing (2003) (38)
- A solvent-controlled switch of manganese complex assemblies with a beta-diketonate-based ligand. (2002) (37)
- Dinuclear CuII Complexes with a New Phenol-Based Ligand Bearing Pyridine and Thiophene Substituents: Synthesis, Characterization and Interaction with Catechol Substrates (2004) (37)
- Rodlike bimetallic ruthenium and osmium complexes bridged by phenylene spacers. Synthesis, electrochemistry, and photophysics. (2005) (37)
- Diastereoselective multicomponent synthesis of dihydropyridones with an isocyanide functionality. (2006) (37)
- Hypothetical Crystal Structures of Benzene at 0 and 30 kbar (1998) (37)
- Two pyrazolato-bridged, linear trinuclear Cu(II) complexes. Crystal structures and magnetic properties (2003) (37)
- The structure of dicyclopentadienylzinc (1985) (37)
- A phosphorus analogue of Bis(eta4-cyclobutadiene)iron(0). (2009) (37)
- Mono- and dinuclear platinum(II) compounds with 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine. Structure, cytotoxic activity and reaction with 5'-GMP. (2009) (37)
- Well-Defined 2:1 and 2:2 Arylcopper−Copper Bromide Aggregates and Selective Biaryl Formation (1996) (37)
- Iron(III)-catecholato complexes as structural and functional models of the intradiol-cleaving catechol dioxygenases. (2007) (37)
- Wide-bite-angle diphosphinines: design, synthesis, and coordination properties (2008) (36)
- Three dinuclear copper(II) carboxylates with the paddle-wheel cage structure as intermediates in cop (1998) (36)
- Copper(II) Coordination Compounds with Bis(imidazol-2-yl)methylamine and Bis(imidazol-2-yl)methylaminomethane in Relation to Bis(imidazol-2-yl)methylamine-Modified Poly(glycidyl methacrylate) Polymers and Other Bis(imidazol-2-yl)-Containing Ligands (1996) (36)
- New cis- and trans-Arylplatinum(II) Acetylide Compounds Containing a Bis(imino)aryl [NCN] Ligand (2001) (36)
- Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5 (1991) (36)
- New aspects of chiral heteroorganocuprates and an x-ray crystal structure with unprecedented magnesium-sulfur bonds (1990) (36)
- NCN-Pincer Metal Complexes (Ti, Cr, V, Zr, Hf, and Nb) of the Phebox Ligand (S,S)-2,6-Bis(4′-isopropyl-2′-oxazolinyl)phenyl (2011) (36)
- PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions (2010) (36)
- Zero-valent palladium complexes with monodentate nitrogen sigma-donor ligands. (2003) (36)
- Synthesis, spectroscopic, magnetic properties and X-ray crystal structure of di-μ-hydroxo-bis(μ-perchlorato- O , O ′)-bis-[bis(2-amino-4-methylpyrimidine)copper(II)]: bridging perchlorate results in significant deviation from the predicted magnetic exchange (1999) (36)
- Atropisomeric phosphinines: design and synthesis. (2007) (36)
- Autoionization of homogeneous nickel(II) diphosphane hydrogenation catalysts. An NMR study and crystal structures of [Ni(o-MeO-dppe)I2] and [Ni(o-MeO-dppe)I2](PF6)2. (2001) (36)
- Synthesis, characterisation and crystal structures of new nickel complexes in S4 coordination spheres; an unprecedented rearrangement during ligand synthesis (2002) (36)
- Dinuclear five-coordinate diorgano[(2-pyridyl)methoxyl]aluminum compounds: dynamic behaviour in solution (1H-, 13C- and 27Al-NMR) and molecular geometry of [i-Bu2AlOCH2-2-C5H4N]2 (X-ray) (1985) (36)
- Ligand-templated four-metal chains dimerize into a unique [Cu(II)(8)] cluster. (2002) (35)
- N-heterocyclic carbene-functionalized ruthenium phosphinidenes: what a difference a twist makes. (2009) (35)
- Synthesis, magnetism and X-ray structures of [Cu(2-aminopyrimidine)2(μ-OH)(CF3SO3)]2(2-aminopyrimidine)2, a new hydroxo-bridged dinuclear Cu(II) compound generating extremely small antiferromagnetism (2002) (35)
- Vanadium(III) and -(IV) Complexes with O,N-Chelating Aminophenolate Ligands: Synthesis, Characterization and Activity in Ethene/Propene Copolymerization (2001) (35)
- Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2)2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4) (1993) (35)
- The use of dimethyl sulfide in organocopper chemistry; X-ray crystal structures of cyclo-tetrakis-(m-2-methylphenyl)bis(dimethylsulphide)tetracopper(I) and of the polymeric copper bromide adduct bromo(dimethyl sulphide)-copper(I) (1991) (35)
- The new multi-directional polydentate ligand 2,4,6-(di-pyridin-2-yl-amino)-[1,3,5]triazine (dpyatriz) can discriminate between Zn(II) and Co(II) nitrate. (2003) (35)
- General Approach for Template‐Directed Synthesis of Macroheterocycles by Ring‐Closing Metathesis (RCM) (2005) (35)
- Chemistry of Diamino Ligated Methylpalladium(II) Alkoxide Complexes: Syntheses, X-Ray Crystal Structures and Hydrogen-Bond Formation (1995) (35)
- Group 11 Metal ions in poly(donor atom) environments: X-ray crystal and molecular structure of[M((R,S)-1,2-(5-R-thio-2-CH=N)2-c-Hx)2](O3SCF3) (M = Ag(I) R = Me, thio = thiophene, c-Hx = cyclohexane) and silver(I) and copper(I) coordination properties in solution (1H, 109Ag and 15N NMR) (1985) (34)
- Single-crystal structure validation with the program (2003) (34)
- Centrosymmetric and pseudo-centrosymmetric structures refined as non-centrosymmetric. (2006) (34)
- Nickel and palladium complexes of new pyridine-phosphine ligands and their use in ethene oligomerization (2009) (34)
- Asymmetric hydrogenation with highly active IndolPhos-Rh catalysts: kinetics and reaction mechanism. (2010) (34)
- Linkage isomers of dibromobis(1-(2-methoxyethyl)tetrazole)- copper(II) containing either a bromide or a unique tetrazole bridge (2003) (34)
- The synthesis of a calix[6]arene derived diphosphate, its palladium and platinum complexes and the remarkable activity of (syn-calix[6]arene diphophate)Pd(CH3)(CH3CN)OTf in carbon monoxide and ethene copolymerisation (1999) (34)
- 5'-N-substituted carboxamidoadenosines as agonists for adenosine receptors. (1999) (34)
- Synthesis, Characterization, and Single-Crystal EPR Studies of Three Dinuclear Copper(II) Complexes and One Mixed-Valence Tetranuclear Copper(I)-Copper(II) Cluster with an Asymmetric Imidazole-Containing Tripodal Ligand with Copper(II)-Copper(II) Distances between 3.35 and 3.63 Å (1996) (34)
- Fluorous derivatives of [Rh(COD)(dppe)]BX4 (X=F, Ph): synthesis, physical studies and application in catalytic hydrogenation of 1-alkenes and 4-alkynes (2002) (34)
- Improved syntheses, structures, spectral and electrochemical properties of [Mn2III(µ-O)(µ-O2CMe)2L2]2+ and [Mn2IV(µ-O)3L2]2+ complexes. Two homologous series derived from eight N-substituted 1,4,7-triazacyclononanes (1996) (34)
- Synthesis of Pt compounds containing chiral (2S,4S)-pentane-2,4-diyl-bis(5H-dibenzo[b]phosphindole) as ligand and their use in asymmetric hydroformylation of styrene derivatives (1997) (33)
- Group 1B organometallic chemistry. Part 25. Crystal and molecular structure of 1,2,3;1,4,5;2,3,6;4,5,6-tetrakis-µ3-2-dimethylaminophenyl-2,5;3,4-bis-µ2-4-tolylethynyl-octahedro-hexacopper(I) (1978) (33)
- Multiple ionic interactions for noncovalent synthesis of molecular capsules in polar solvents (2005) (33)
- Alkylation Reactions of dialkylzinc Compounds with 1,4-Diaza-1,3-butadienes : Cationic and Radical Anionic Organozinc intermediates. Molecular Structure of the Cationic Organozinc Species [MeZn(t-BuN=CHCH=N-t-Bu)]O3SCF3 and Me2Zn(bpy)(bpy = 2,2-Bipyridine) (1994) (33)
- Multicomponent Synthesis of N-Heterocyclic Carbene Complexes (2007) (33)
- Influence of the amino substituents of potentially bis ortho chelating aryl ligands (2,6-{R1R2NCH2}2C6H3)- on the synthesis and properties of their organonickel(II) complexes (1991) (33)
- Three new asymmetric trans-amine(azole)dichloridoplatinum complexes that overcome cisplatin resistance and their reactions with 5'-GMP. (2006) (33)
- A novel heteroditopic terpyridine-pincer ligand as building block for mono- and heterometallic Pd(II) and Ru(II) complexes. (2006) (33)
- A chiral coordination polymer of silver(I) and a polydentate ligand with one asymmetric centre: X-ray structure of the (1:1) complex of AgO3SCF3 and [N-(5-methyl-2-thienylmethylidene)-L-methionyl]histamine (1989) (33)
- A STABLE BIMETALLIC COPPER(I) TITANIUM ACETYLIDE (1995) (33)
- The synthesis and properties of novel (organo)zinc enoaltes of N,N-disubstituted glycine esters : Molecular structure of [EtZnOC(OMe)=C(H)N(t-Bu)Me]4 (1991) (32)
- Dimetallic complexes derived from a novel dinucleating chelating symmetric triazole ligand; crystal structure, magnetic properties and ESR study of bis[µ-3,5-diacetylamino-1,2,4-triazolato-O′,N 1,N 2,O″]bis[(nitrato)(aqua)copper(II)]‡ (1999) (32)
- Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H (1995) (32)
- Effect of acyl chain length and branching on the enantioselectivity of Candida rugosa lipase in the kinetic resolution of 4-(2-difluoromethoxyphenyl)-substituted 1,4-dihydropyridine 3,5-diesters. (2002) (32)
- New palladium, patinum and nickel complexes based on rigid phosphorus and nitrogen containing ligands (1997) (32)
- Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: A gem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation (2009) (32)
- Cationic Ruthenium‐Cyclopentadienyl‐Diphosphine Complexes as Catalysts for the Allylation of Phenols with Allyl Alcohol; Relation between Structure and Catalytic Performance in O‐ vs. C‐Allylation (2009) (32)
- A new family of Ru(II) complexes with a tridentate pyridine Schiff-base ligand and bidentate co-ligands: synthesis, characterization, structure and in vitro cytotoxicity studies (2013) (32)
- Oxidative-addition reactions of cyclometallated platinum(II) compounds with mercury(II) carboxylates. X-ray, crystal and molecular structure of rac-[a-(m-MeCO2)-cf,de-(2-Me2NCH2C6H4)2PtHg(O2CMe)] (1982) (32)
- Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: tantalum-mediated alkene synthesis via reductive rearrangements and Wittig-type reactions (1992) (32)
- Bis(imino)aryl)rhodium(III) Halide and Methyl Compounds (2004) (32)
- Coordination chemistry of 1,1'-bis(2-pyridyl)ferrocene in palladium(II) and platinum(II) Complexes and Reaction of (BPF)Pd(Me)Cl with CO. X-Ray Structure of (1,1'-bis(2-pyridyl)ferrocene)Pd(Me)Cl and (1,1'-bis(2-pyridyl)ferrocene)[PtCl2(CH2=CH2)]2 (1996) (32)
- Catalytic and electrochemical properties of new manganese(III) compounds of 2-(2′-hydroxyphenyl)-oxazoline (Hphox or HClphox). Molecular structures of [Mn(Clphox)2(MeOH)2](ClO4) and [Mn(phox)2(MeOH)2][Mn(phox)2(ClO4)2](H2O)2 (2001) (32)
- Bimetallic η6,η1 NCN-pincer ruthenium palladium complexes with η6-RuCp coordination: synthesis, X-ray structures, and catalytic properties (2009) (32)
- Triruthenium dodecacarbonyl/triphenylphosphine catalyzed dehydrogenation of primary and secondary alcohols (2004) (31)
- Insertion reactions into palladium–carbon bonds of complexes containing new rigid bidentate nitrogen ligands (1998) (31)
- Efficient catalytic oxidation of primary and secondary alcohols using a non-heme dinuclear iron complex (2001) (31)
- Synthesis of the Dibenzofuran‐Based Diphosphine Ligand BIFAP and Its Water‐Soluble Derivative BIFAPS and Their Use in Ruthenium‐Catalyzed Asymmetric Hydrogenation.[≠] (1999) (31)
- New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(mu4-O)4(phpz)8(thf)4]. (2005) (31)
- Homoleptic diphosphacyclobutadiene complexes [M(η(4)-P2C2R2)2]x- (M = Fe, Co; x = 0, 1). (2010) (31)
- Formation and molecular structure of permethylyttrocene methyl tetrahydrofuranate (1987) (31)
- Tuning the coordination mode in mononuclear manganese complexes by changing the steric bulk of the carboxylates (2001) (31)
- The unusual solid state structures of the pentasubstituted bis(cyclopentadienyl)zinc compounds bis(pentamethylcyclopentadienyl)zinc and bis(tetramethylphenylcyclopentadienyl)zinc (1989) (31)
- New dinuclear Co(II) and Mn(II) complexes of the phenol-based compartmental ligand containing formyl and amine functions: structural, spectroscopic and magnetic properties (2004) (31)
- Monodentate sigma-N and Bidentate sigma-N,sigma-N' Coordination of 1,1-Bis((N-p-tolylimino)diphenylphosphoranyl)ethane, CHCH(3)(PPh(2)=NC(6)H(4)-4-CH(3))(2), to Platinum(II). (1996) (31)
- Copper-mediated selective oxidation of a C-H bond. (2005) (31)
- Unusual isomerization of ortho chelated aryliridum(I) complexes, involving a unique sequence of intramolecular C-H bond making and breaking processes. X-ray structure of IrI[C6H3(CH2NMe2)2-2,4](COD) (1988) (31)
- Crystal structure and molecular geometry of a square-pyramidal platinum(II) complex,[{2,6-(Me2NCH2)2C6H3}Pt(m-{(p-tol)NC(H)N(i-Pr)}HgBrCl], containing a PtII- to HgII donor bond (1982) (31)
- A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes. (2009) (31)
- Ortho-chelated arylrhodium(I) complexes. X-ray structure of RhI[C6H3(CH2NMe2)2-o,o'-C,N](COD) (1988) (31)
- Fluctuations between square-planar and tetrahedral coordination geometry with bis(2-benzimidazolyl)alkane ligands. Synthesis, spectroscopic properties and X-ray crystal structure of four representative examples (1999) (31)
- The role of neutral and radical anionic organozinc complexes in the alkylation reactions of 1,4-diaza-1,3-butadienes with diorganozinc compounds (1997) (31)
- SYNTHESIS, CHARACTERIZATION, SPECTROSCOPY, MAGNETISM AND X-RAY STRUCTURES OF RED AND GREEN CU(II) CHLORIDE ADDUCTS WITH BIS(2-BENZIMIDAZOLYL)PROPANE (1999) (31)
- Reactions of Rh- and Ir-bis(iminophosphoranyl)methanide compounds with electrophiles; a trapped cation-anion complex in the oxidative addition of iodine to a d8 metal centre and X-ray crystal structure of IrI{CH(PPh2NC6H4CH3-4)2}(COD)]I, containing two fused four-membered metallacycles (1995) (30)
- Diastereopure Fe(II) and Zn(II) complexes derived from a tridentate N,N',N-bis(methyl-L-prolinate)-substituted pyridine ligand. (2006) (30)
- Chiral (Diphosphonite)platinum Complexes in Asymmetric Hydroformylation (2006) (30)
- 2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i) (2010) (30)
- Separation of actinides and lanthanides: crystal and molecular structures of N,N ′-bis(3,5-di- t -butylsalicylidene)-4,5-dimethyl-1,2-phenylenediamine and its uranium complex (2004) (30)
- Coordination Chemistry of SCS PdII Pincer Systems (2000) (30)
- Rhodium complexes based on phosphorus diamide ligands: Catalyst structure versus activity and selectivity in the hydroformylation of alkenes. (2000) (30)
- Mononuclear diastereopure non-heme Fe(II) complexes of pentadentate ligands with pyrrolidinyl moieties: Structural studies, and alkene and sulfide oxidation (2007) (30)
- TRANS-2,6-BIS((DIMETHYLAMINO)METHYL)PHENYL-N,N′,C COMPLEXES OF PALLADIUM(II) AND PLATINUM(II). CRYSTAL STRUCTURE OF (PTI(MEC6H3(CH2NME2)2-O,O′))BF4: A CYCLOHEXADIENYL CARBONIUM ION WITH A Σ-BONDED METAL SUBSTITUENT (1983) (30)
- Crystal structure, magnetic properties and spectroscopic studies of bis[1,3-bis(pyrazol-3-yl)triazenido]dicopper(II) trihydrate: a dinuclear complex with an asymmetric double pyrazolate bridge (1996) (30)
- Synthesis and Structural Characterization of Lithium and Trimethyltin Complexes of 2,6-Bis(oxazolinyl)phenyl (2005) (30)
- C(arenium)-C(alkyl) bond making and breaking: key process in the platinum-mediated C(aryl)-C(alkyl) bond formation. Analogies to organic electrophilic aromatic substitution. (2001) (30)
- Synthesis and characterization of antitumor-active platinum 2,2-dimethyl-1,3-diaminopropane compounds. Crystal and molecular structure of (malonato)(2,2-dimethyl-1,3-diaminopropane)platinum(II) (1980) (30)
- High-nuclearity manganese and iron complexes with the anionic ligand methyl salicylimidate. (2006) (30)
- Olefin Cycloadditions of the Electrophilic Phosphinidene Complex [iPr2N−P=Fe(CO)4] (1999) (30)
- Coordination of 9-ethylguanine to the mixed-ligand compound alpha-[Ru(azpy)(bpy)Cl2] (azpy = 2-phenylazopyridine and bpy = 2,2'-bipyridine). An unprecedented ligand positional shift, correlated to the cytotoxicity of this type of [RuL2Cl2] (with L = azpy or bpy) complex. (2004) (30)
- STABLE PALLADIUM(0) AND PALLADIUM(II) COMPLEXES CONTAINING A NEW, MULTIFUNCTIONAL AND SEMI-LABILE PHOSPHORUS-BISNITROGEN LIGAND (1995) (30)
- Metal-Mediated C-C Bond Making and Breaking : First Direct Evidence for a Reversible Migration of a Benzyl Group Along a Metal-Carbon Bond (1999) (30)
- Phenoxaphosphine-Based Diphosphine Ligands. Synthesis and Application in the Hydroformylation Reaction (2010) (29)
- Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes (2005) (29)
- Metal Coordination and Aggregation Properties of Chiral Polythiophenes and Polythienylethynylenes (2007) (29)
- Activation of sp3-CH Bonds in a Mono(pentamethylcyclopentadienyl)yttrium Complex. X-ray Crystal Structures and Dynamic Behavior of Cp*Y(o-C6H4CH2NMe2)2 and Cp*Y[o-C6H4CH2NMe(CH2-μ)][μ-o-C6H4CH2NMe(CH2-μ)]YCp*[THF] (1989) (29)
- New mono- and di-nuclear complexes of PdII, PtII and NiII of PNNP ligands with a 2,2′-biaryl bridging unit (1998) (29)
- Formation of mixed aryl-, alkyl-lithium aggregates in the heteroatom assisted lithiation of a,a'-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene (1998) (29)
- Ruthenium-catalyzed isomerization of allylic alcohols: oxidation state determines resistance against diene inhibition. (2002) (29)
- Arylpalladium compounds containing an alcohol functionality : Hindered rotation around the Pd-C bond and reactivity towards styrene and carbon monoxide : Comments on C-O bond shortening in late transition metal alkoxides (1993) (29)
- Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes (2009) (29)
- Synthesis of cyclometalated (8-methoxynaphthyl)- and [8-(dimethylamino)naphthyl]platinum compounds and their reactivity toward electrophiles. X-ray molecular structures of square-planar (8-methoxynaphthyl)platinum(II) chloride bis(diethyl sulfide) and bis(8-methoxynaphthyl)platinum(II) diethyl sulfi (1988) (29)
- Dinuclear silver(I) and copper(I) complexes with neutral N2S2 donor ligands and their reactivities towards CO. Structures in solution (1H and INEPT 109Ag NMR) and in the solid (X-ray) of [Ag2{μ-(R)(S)-1,2-(thiophene-2–CHN)2cyclohexane}2](O3SCF3)2 (1985) (29)
- Synthesis and molecular structure of copper(I) and organozinc(II) arylthiolates with chelating amino and ether groups: X-ray structure of [CuSC6H4(CH2N(Me)-CH2CH2OMe)-2]4 and [Zn(Me){SC6H4(R)-CH(Me)NMe2}]2 (1991) (29)
- Chemistry of Bis(aryloxo)palladium(II) Complexes with N-Donor Ligands: Structural Features of the Palladium-to-Oxygen Bond and Formation of O-H.O Bonds. (1996) (29)
- Bis-ortho-chelated Diaminoaryl Platinum Compounds with s-Acetylene Substituents : Investigations into Their Stability and Subsequent Construction of Multimetallic Systems : The Crystal Structure of [(m2-[h2-NCN)Pt(h1-CO)C=CSiMe3])Co2(CO)6] (NCN=2,6-Bis[(dimethylamino),ethyl]phenyl) (2000) (29)
- Structure of calcium acetate monohydrate, Ca(C2H3O2)2.H2O (1984) (29)
- Synthesis and characterization of ruthenium(II) complexes with the new ligand 2-phenylazopyridine-5-sulfonic acid (HSAZPY): in search for new anticancer agents (2004) (29)
- Tungsten(VI) Phenylimido Alkylidene complexes containing a Monoanionic O,N-Chelating Ligand and Their Isolated Precursor Complexes: X-ray Structures of W(CH2SiMe3)3(=NPh)[OCPh2(2-py)] and W(=CHSiMe3)(CH2SiMe3)(=NPh)[OCPh2(2-py)] (1994) (29)
- BINUCLEAR ZIRCONIUM(III) AND ZIRCONIUM(IV) COMPLEXES - MILD OXIDATION OF LOW-VALENT ZIRCONIUM AS A SYNTHETIC PATHWAY TO A CLASS OF TRIVALENT AND TETRAVALENT ZIRCONIUM FULVALENE COMPLEXES - MOLECULAR-STRUCTURES OF [ETA-5-ETA-5-C10H8][CPZRSPH]2, [ETA-5-ETA-5-C10H8][CPZR(CH3)2]2, AND [ETA-5-ETA-5-C10H8 (1990) (29)
- Synthesis, Spectroscopy, and Magnetic Properties of Transition‐Metal Complexes with the Diethyl 2‐Quinolylmethylphosphonate (2‐qmpe) Ligand − Crystal Structures of [Ni(2‐qmpe)4(H2O)2](ClO4)2 and [Mn(2‐qmpe)4(H2O)2](ClO4)2 Showing Unexpected O‐Binding of the qmpe Ligands (1998) (28)
- ALKYLATION AND REDUCTIVE DIMERIZATION OF HALF-SANDWICH IMIDO VANADIUM DICHLORIDES (1995) (28)
- Crown ether Grignard reagents; x-ray structure of 2-(bromomagnesio)-1,3-xylyl-15-crown-4 (1988) (28)
- The coordination modes of simple diarylmagnesium species: Some representative X-ray crystal structures (1990) (28)
- Electron delocalization in cross-conjugated p-phenylenevinylidene oligomers. (2003) (28)
- Sulfato-bridged ECE-pincer palladium(II) complexes: structures in the solid-state and in solution, and catalytic properties. (2009) (28)
- Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands. (2010) (28)
- Novel ruthenium(II)2 carboxylates as catalysts for alkene metathesis. (2001) (28)
- New nickel-containing homogeneous hydrogenation catalysts: Structures of [Ni(o-MeO-dpppol)Cl2] and [Ni(dcpe)Cl2] (2003) (28)
- Ferromagnetic and antiferromagnetic spin coupling in Ni4O4 cubane-type clusters with 4-amino-3,5-bis(hydroxymethyl)-1,2,4-triazole as a ligand. The x-ray structure of a new dumbbell-like double cubane cluster (1987) (28)
- The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates, and -aurates; MLi(2)XAr(2) (M = Cu(I), Ag(I), Au(I); X = Br, C(triple bond)N; Ar = [C(6)H(4)CH(2)N(Et)CH(2)CH(2)NEt(2)-2]-). (2002) (28)
- Tetraalkylammonium pentaorganosilicates: the first highly stable silicates with five hydrocarbon ligands. (2002) (28)
- Separation of actinides and lanthanides: Synthesis and molecular structure of a new di-μ-phenoxo-bridged dinuclear bis(dioxouranium(VI)) complex (2006) (28)
- Organotin(IV) compounds derived from 2-Me2NC6H4CH2Li and its chiral a-Me3Si-derivative. X-ray structure of penta-coordinate [{2-(dimethylamino)phenyl}(trimethyl-silyl)methyl-C,N]methylphenyltin bromide having a chiral Sn center (1986) (28)
- Complexes of a novel multinucleating poly-β-diketonate ligand (2004) (28)
- Crystal structure and spectroscopy of a most unusual Cu(II) coordination compound containing an infinite chain of lattice ligand interwoven with stacked sheets of neutral bis(2-aminopyrimidine-bridged) copper ions: X-ray structure of [Cu(ampym)2(H2O)2(CF3SO3)2](ampym)2(ampym)2 (2000) (28)
- Palladium(0)-Alkene Bis(triarylphosphine) Complexes as Catalyst Precursors for the Methoxycarbonylation of Styrene (2005) (28)
- A Zig‐Zag [MnII4] Cluster from a Novel Bis(β‐diketonate) Ligand (2006) (28)
- Strained, stable 2-aza-1-phosphabicyclo[n.1.0]alkane and -alkene Fe(CO)4 complexes with dynamic phosphinidene behavior. (2005) (27)
- Heterolytic activation of dihydrogen by platinum and palladium complexes. (2013) (27)
- Synthesis and conformational evaluation of p-tert-butylthiacalix[4]arene-crowns. (2004) (27)
- Reactivity of 1-aza-4-oxo-1,3-butadienes (a-iminoketones) towards diorganozinc reagents: Regio- and chemoselective transfer of organo groups in the ZnR2/R1N=C(R2)C(R3)=O system and X-ray structure of [EtZn(Et)(t-Bu)NC(H)= =C(Me)O]2 (1987) (27)
- Ruthenium(III) chloride complex with a tridentate bis(arylimino)pyridine ligand: synthesis, spectra, X-ray structure, 9-ethylguanine binding pattern, and in vitro cytotoxicity. (2008) (27)
- Anion dependent deprotection of a thioether group in Schiff base NS2 ligands results in new mononuclear and dinuclear thiolato nickel complexes (1998) (27)
- The autoxidation activity of new mixed-ligand manganese and iron complexes with tripodal ligands (2007) (27)
- High-presure NMR and ab initio computational studies on the insertion mechanism of carbon monoxide into cationic monoorganopalladium(II) complexes bearing tridentate nitrogen donor ligands (1995) (27)
- .alpha.-, .beta.-, and .delta.-Hydrogen abstraction in the thermolysis of paramagnetic vanadium(III) dialkyl complexes (1993) (27)
- Synthesis, characterization, and DNA-binding studies of nitro(oligopyridine)ruthenium(II) complexes. (2006) (27)
- Solution-stable trinuclear zinc(II) cluster from 4-methyl-2-N-(2-pyridylmethylene)aminophenol (HPyrimol). (2004) (27)
- Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions. (2009) (27)
- An aryllithium complex with intramolecular coordination of an ortho-diamine substituent : X-ray and solution NMR structure of dimeric [Li{C6H4(Ch2N(Me)CH2CH2NMe2)-2}]2 (1994) (27)
- VERSATILE COORDINATION BEHAVIOR OF (N-ARYLIMINOPHOSPHORANYL)(THIOPHOSPHORANYL) METHANE AND ITS ANION TO PLATINUM(II) (1997) (27)
- Organonickel(II) complexes containing aryl ligands with chiral pyrrolidinyl ring systems; syntheses and use as homogeneous catalysts for the Kharasch addition reaction (1994) (27)
- Ruthenium(III) Coordination to the Exocyclic Nitrogen of 9‐Methyladenine and Stabilisation of the Rare Imine Tautomer by Intramolecular Hydrogen Bonding (2001) (27)
- Luminescent and Electronic Properties of Stilbenoid NCN‐Pincer PtII Compounds (2007) (27)
- Synthesis and Structural Studies of Ionic Monoorganopalladium(II) Complexes with Tridentate Nitrogen-Donor Ligands (1994) (27)
- Synthesis of conformationally constrained peptidomimetics using multicomponent reactions. (2009) (27)
- Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity. (2010) (27)
- Synthesis, structure, and metathesis activity of ruthenium carbene complexes containing diphosphines (2001) (27)
- Monocyclopentadienyl yttrium chemistry : incorporation of alkoxides as supporting ligands and synthesis of [Y(C5Me5)(OC6H3But2)(μ-H)]2 (1991) (27)
- Phosphinoureas: cooperative ligands in rhodium-catalyzed hydroformylation? On the possibility of a ligand-assisted reductive elimination of the aldehyde (2010) (26)
- Pincer-porphyrin hybrids. (2004) (26)
- Probability plots based on Student's t-distribution. (2009) (26)
- Group 1B organometallic chemistry XXVII. Complex forming reactions of polynuclear arylcopper compounds; Calk-P bond cleavage in 1,2-bis(diphenylphosphino)ethane (Diphos) by (2-Me2NCH2C6H4)4Cu4 and crystal structure of [(C6H5)2PCu.Diphos]2 -C6H6 (1978) (26)
- Coordination compounds with 4-aminopyridine. An unusual in situ formation of a bridging formato compound. The structure of catena -poly[bis(4-amino-pyridine)(formato- O )copper(II)-μ-formato( O,O′ )] (1999) (26)
- Calix[4]arene rhenium(V) complexes as potential radiopharmaceuticals. (2000) (26)
- Coordination chemistry and X-ray studies with novel sterically constrained diphosphonite ligands (2003) (26)
- Crystal structures, spectroscopy and magnetism of Cu(II) bromide adducts with bis(2-benzimidazolyl)alkanes: influence of alkyl bridge on the degree of distortion from tetrahedral (2000) (26)
- The assembly of supramolecular boxes and coordination polymers based on bis-zinc-salphen building blocks. (2009) (26)
- Sequential C-H and C-Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with (1998) (26)
- METHYL-, ACETYL- AND ALLYL-PALLADIUM AND -PLATINUM COMPLEXES CONTAINING NOVEL TERDENTATE PNS AND NN'S LIGANDS (1996) (26)
- Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'. (2009) (26)
- Novel phosphite palladium complexes and their application in C–P cross-coupling reactions (2010) (26)
- (Perfluoro)alkylsilyl-Substituted 2-[Bis(4-aryl)phosphino]pyridines: Synthesis and Comparison of Their Palladium Complexes in Methoxycarbonylation of Phenylacetylene in Regular Solvents and Supercritical CO2 (2005) (26)
- New mono- and tricyclopalladated dendritic systems with encapsulated catalytic sites. (2002) (26)
- Synthesis and characterization of Pd(II)-methyl complexes with N-heterocyclic carbene-amine ligands. (2009) (26)
- Dentritic Carbosilanes Containing Silicon-Bonded 1-[C6H2(CH2NMe2)2-3,5-Li-4] or 1-[C6H3(CH2NMe2)-4-Li-3] Mono-and Bis(amino)aryllithium End Groups: Structure of {[CH2SiMe2C6H3(CH2NMe2)-4-Li-3]2}2 (1999) (26)
- The formation of a mixed organolithium aggregate Li4R2nBu2 during the heteroatom assisted lithiation of 1,3-bis(dimethylaminomethyl)-2,4,6-trimethylbenzene(R=2,6- (CH2NMe2)2-3,5 Me2C6HCH2) (1995) (25)
- Activation of H2 by a highly distorted Rh(II) complex with a new C3-symmetric tripodal tetraphosphine ligand. (2010) (25)
- Novel Linear Transition Metal Clusters of a Heptadentate Bis-β-diketone Ligand (2007) (25)
- SYNTHESIS AND STRUCTURAL FEATURES OF NOVEL VANADIUM(II) AMIDES - X-RAY STRUCTURES OF OCTAHEDRAL [(2-C5H4N)(CH3)N]2V(TMEDA) (TMEDA=N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE) AND SQUARE-PYRAMIDAL [2,5-(CH3)2C4H2N]2V(PY)3 (PY=PYRIDINE) (1991) (25)
- Carbon–hydrogen and C–X (X = Cl or SiMe3) bond activation. 1-Cyclopalladation and oxidation of some derivatives of 2-[(dimethylamino)methyl]naphthalene (1994) (25)
- Ruthenium polypyridyl complexes containing the bischelating ligand 2,2′-azobispyridine. Synthesis, characterization and crystal structures (2006) (25)
- Calix salophen crown ethers as receptors for neutral molecules (1994) (25)
- Mono- and dinuclear iron complexes of bis(1-methylimidazol-2-yl)ketone (bik): structure, magnetic properties, and catalytic oxidation studies. (2011) (25)
- Organozinc complexes with monoanionic chelating phenolates or 2-pyridylmethanolates. Molecular structure of [Zn(CH2SiMe3){OCH2(2-Py)}]4 (1993) (25)
- X-ray crystal structures, spectroscopic and magnetic measurements of copper(II) and cobalt(II) halide compounds with bis(2-benzimidazolyl)alkane ligands (2001) (25)
- Unusual CuII and MnII Complexes of Phenol-Based Ligands Containing Amine, Pyridine and Formyl Functions: Unexpected Structural Features and Solution Studies (2004) (25)
- Efficient synthesis and molecular structure of 2-hydroxyisophthaldehyde (1997) (25)
- Strong Binding of Paraquat and Polymeric Paraquat Derivatives by Basket‐Shaped Hosts (1995) (25)
- New antitumour active platinum compounds containing carboxylate ligands in trans geometry: synthesis, crystal structure and biological activity. (2006) (25)
- Molecular structures of bis[3-(dimethylamino)propyl]zinc, Zn[(CH2)3N(CH3)2]2, by x-ray and gas electron diffraction and bis[3-(methylthio)propyl]zinc, Zn[(CH2)3SCH3]2, by gas electron diffraction (1987) (25)
- A novel ruthenium carbene dimer that is active in the metathesis of internal alkenes; the crystal structure of Ru2(CHPh)2(CF3CO2)2(μ-CF3CO2)2(PCy3)2(μ-H2O) (1999) (25)
- The synthesis, structures and characterisation of new mixed-ligand manganese and iron complexes with tripodal, tetradentate ligands (2008) (25)
- Circumambulatory rearrangement with characteristics of a 2:1 covalent molecular bevel gear. (2006) (25)
- Coordination Dependence of Magnetic Properties within a Family of Related [FeII2] Complexes of a Triazine-Based Ligand (2006) (25)
- Chromium(II) amides: synthesis and structures (1993) (24)
- 1:1 and 2:1 Lithium Zincates with Intramolecular Coordination. Structures of Li(thf)Zn(C6H4CH2NMe2-2)3 and Li2Zn(C6H4CH2NMe2-2)4 (1997) (24)
- Carbosilane Molecules with Mono- and Bis(amino)arylmetal End Groups: Structures of {NiI(C6H2(CH2NMe2)2-2,6-SiMe3-4)} and Tetranuclear {(CH2Si(Me)2C6H3(CH2NMe2)-4-(PdCl)-3)2}2 (1999) (24)
- A Novel Trimeric Chiral Copper(I) Thiophenolate with Intramolecular Coordination (1989) (24)
- Synthesis and crystal structure of the novel transition metal substituted tin hydride H2Sn2 [Mn(CO)5]4 (1974) (24)
- The crystal structure and IR spectra of μ-(bipyrimidine-N1,N1′,N5,N5′)-bis[(azido-N1)(methanol)(bipyrimidine-N1,N1′)copper(II)] bis(triflate) bis(methanol) (1998) (24)
- Electron transfer in the reactions of titanocene-bis(trimethylsilyl) acetylene complexes with 2,2'-bipyridine and 4,5-diazafluorene. The crystal structure of (4,5-diazafluorenyl) bis(pentamethylcyclopentadienyl) titanium(III) (1996) (24)
- Synthesis and reactivity of tantalum alkylidene complexes containing the C,N,N'-chelating aryldiamine ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2- (CNN). X-ray structurs of [TaCl2(=CH-t-Bu) (CNN)], [Ta{CH2)3-1,3}(CNN)(O-t-Bu)2], and [Ta(CNN)(O-t-Bu)2(H2C=CH2)] (1997) (24)
- The influence of intramolecular coordination on the aggregation of sodium phenolate complexes. X-ray structures of [NaOC6H4(CH2NMe2)-2]6 and [Na(OC6H2(CH2NMe2)2-2,6-Me-4)(HOC6H2NMe2)2-2,6-Me-4)]2 (1996) (24)
- Novel zigzag 1D coordination polymer from copper(II) chloride and N,N'-{2,4-di[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine exhibiting ferromagnetic interactions. (2003) (24)
- Synthesis, Structure and Properties of a Mixed Mononuclear/Dinuclear Iron(II) Spin‐Crossover Compound with the Ligand 4‐(p‐Tolyl)‐1,2,4‐triazole (1999) (24)
- Calix[4]arene dimers; self-assembly via hydrogen bonding at the upper rim (1997) (24)
- A Simple Procedure for the Preparation of 1,8-BIS(Diphenylphosphino)Naphthalene (1995) (24)
- Double Cyclometalation via Carbon−Silicon Bond Cleavage by Palladium(II) Acetate. X-ray Structure of a Cationic 1,4-Dipalladated Benzene Ring and Selective Synthesis of Heterobimetallic 1,4-Phenylene-Bridged Platinum(II)−Palladium(II) Complexes (1997) (24)
- Nickel N-heterocyclic carbene complexes in the vinyl polymerization of norbornene (2011) (24)
- Synthesis and Crystal Structures of Zerovalent Platinum η2-Fumarate Bis(norbornene) Complexes and Their Application as Hydrosilylation Catalysts (2004) (24)
- Coordination Chemistry and Asymmetric Catalysis with a Chiral Diphosphonite (2004) (24)
- Structure and Reactivity of Mono(cyclopentadienyl)vanadium Alkynyl and Aryne Complexes (1996) (24)
- Selective para-halogenation and dimerization of N,C,N'-arylruthenium(II) and -(III) 2,2':6',2''-terpyridine cations. (2010) (23)
- Preparation and electrochemical behaviour of dinuclear platinum complexes containing NCN ligands (NCN=[C6H3(Me2NCH2)2-2,6]−). The crystal structure of [C6H3(Me2NCH2)2-1,3-(CC)-5]2 (2001) (23)
- Effect of Intramolecular Coordination on Tantalum‐Alkylidene‐Centered Reactions: Synthesis and Structure of a Tantalum‐Olefin Adduct and a Tantalum‐Zinc‐Alkylidene Complex (1991) (23)
- Structure of bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(2,5,8,11,14-pentaoxapentadecane)barium(II) (1990) (23)
- Synthesis and Characterization of [Acridinium][Ni(dmit)2]3 and [Phenazinium][Ni(dmit)2]3 (dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate) (1997) (23)
- NOVEL ARYLTITANIUM(IV) COMPLEXES CONTAINING ETA 3-NCN-PSEUDOFACIAL- AND ETA 3-NCN-MERIDIONAL-BONDED C6H3(CH2NME2)2-2,6- (ABBREVIATED AS NCN) LIGANDS. THE CRYSTAL STRUCTURES OF TICL2(ETA 3-FAC-NCN)(O-I-PR), TICL(ETA 3-MER-NCN) (O-I-PR)(OTF) CONTAINING AN ETA 1-O-BONDED TRIFLATE ANION, AND THE SEVEN-C (1997) (23)
- A new, easily recyclable arylating agent based on a diphosphino-digold(I) complex. (2007) (23)
- Crystallization and Characterization of Magnesium Methanesulfonate Hydrate Mg(CH3SO3)2·12H2O (2010) (23)
- Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4‐1,2,4,5 − X‐ray Structure of a Dinuclear Ruthenium(II)‐Bridged Complex: [{RuCl2(PPh3)}2{C6H2(CH2PPh2)4‐1,2,4,5‐P,P′,P′′,P′′′}] (1998) (23)
- Acid-Base Self-Assembly Chemistry and Hydrogen Bonding Interactions Resulting in the Formation of a Tetranuclear Aggregate Containing Four Crystallographically Non-Equivalent FeIII Centers (2004) (23)
- One-dimensional, cofacial porphyrin polymers formed by self-assembly of meso-tetrakis(ERE donor) zinc(II) porphyrins. (2007) (23)
- Vanadium(V) complexes based on a bis(pyridine)-imine ligand (HL); synthesis and crystal structure of a dioxovanadium(V) complex involving a ligand cyclisation (1999) (23)
- NMR spectra and crystal structure of a regioselective hydroformylation catalyst complex RhH(diphosphite)(CO)2 (1995) (23)
- Construction of Supported Organometallics Using Cycloplatinated Arylamine Ligands (2002) (23)
- Synthesis and characterization of the new complex tris[(2-oxazolinyl)phenolato] manganese (III) and its use as a catalyst in oxidation reactions (1998) (23)
- Homogeneous Models for Chemically Tethered Silica-Supported Olefin Polymerization Catalysts (2002) (23)
- Copper(I) arenethiolates with intramolecular coordination and the formation of mixed organo(arenethiolate) copper(I) aggregates. X-ray structures of trimeric [Cu(S-1-C10H6NMe2-8)]9, and hexanuclear [Cu3(S-1-C10H6NMe2-8)2(C_CtBu)]2 (1996) (23)
- Synthesis, solid state and DFT structure and olefin polymerization capability of a unique base-free dimeric methyl titanium dication. (2010) (23)
- Palladium(0)–tetracyanoethylene complexes ofdiphosphines and a dipyridine with large bite angles, and their crystalstructures (1997) (23)
- Zinc(II)‐Catalyzed Disproportionation in Rubber: The mechanism of Sulfur Vulcanization Revisited (1997) (23)
- Ortho-metalation of m-(Me2NCH2)2C6H4; crystal structure and chemistry of trans-RhIIICl2(C6H3(CH2NMe2)2-o,o')(H2O) (1988) (23)
- Modular diphosphine ligands based on bisphenol A backbones (2003) (23)
- Novel trinuclear and hexanuclear heteroorganocopper compounds with phosphine ligands, bridging alkynyls, and intramolecularly coordinating bridging arylthiolates : X-ray structures of [Cu3{SC6H4(CH(R)NMe2)-2}2-(C_Ct-Bu)]2 (R = H, Me) (1992) (23)
- A DIMERIC TETRANUCLEAR COPPER(II) COMPOUND ASSEMBLED THROUGH PENTACOORDINATING CARBONATE ANIONS (1999) (23)
- Complexation of diphenylzinc with simple ethers. Crystal structures of the complexes Ph2Zn · glyme and Ph2Zn · diglyme (1992) (23)
- Palladium catalyzed cyclization reactions of acetylenic lactams (2001) (22)
- Formation of Dinuclear Copper(II) Complexes from a Macrocycle with Built-in Pyrazole Groups. (1999) (22)
- Alkene insertion reactions of nitrogen-coordinated acylpalladium(II) complexes. The crystal structure of the dicyclopentadiene insertion product [Pd(C10H12COMe)(bpy)]SO3CF3 (1992) (22)
- Synthesis, Structure, and Magnetic Properties of a Tris[3‐(2‐pyridyl)‐1,2,4‐triazole]iron(II) Spin‐Crossover Complex (2000) (22)
- Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems (1998) (22)
- Versatile Phosphite Ligands Based on Silsesquioxane Backbones (2004) (22)
- A Structural Model for [Fe]-Only Hydrogenases. (1998) (22)
- Efficient near-UV photosensitization of the Tb(III) green luminescence by use of 2-hydroxyisophthalate ligands. (2008) (22)
- The crystal structure of 2-methoxy-1,4-benzoquinone: molecular recognition involving intermolecular dipole–dipole- and C–H ⋯ O hydrogen bond interactions (1994) (22)
- Organometallic polymers: an infinite organoplatinum chain in the solid state formed by (CCH⋯ClPt) hydrogen bonds (1996) (22)
- Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions (2010) (22)
- η6-Coordination of a Ruthenium(II) Organometallic Fragment to the Arene Ring of N,C,N-Pincer Metal Complexes (2008) (22)
- Selective copper(II)-mediated oxidative coupling of a nucleophilic reagent to the para-methyl group of 2,4,6-trimethylphenol. (2005) (22)
- Dinuclear copper(II) complexes of four new pyrazole-containing macrocyclic ligands are active catalysts in the oxidative coupling of 2,6-dimethylphenol (2003) (22)
- A Ruthenium(II) Complex Stabilized by a Highly Fluorinated PCP Pincer Ligand (2005) (22)
- Facile access to key reactive intermediates in the Pd/PR3-catalyzed telomerization of 1,3-butadiene. (2010) (22)
- New manganese-based catalyst systems for alkyd paint drying (2007) (22)
- The crystal structure of a 2,2-diphenyl-1-picrylhydrazyl (DPPH) modification (1976) (22)
- Bifunctional and cyclic organomagnesium compounds: III. The crystal and molecular structure of the dimer of magnesiacyclohexane, 1,7-dimagnesiacyclododecane (1969) (22)
- Synthesis and characterization of 9,10‐bis(arylimino)‐9,10‐dihydrophenanthrenes, the structure of (Z,Z)‐9,10‐bis(phenylimino)‐9,10‐dihydrophenanthrene and PdCl2‐[(E,E)‐9,10‐bis(phenylimino)‐9,10‐dihydrophenanthrene] in the solid state and in solution (1996) (22)
- Electron-Poor Pentafluorophenyl-substituted PCP-Palladium Pincer Complexes (2005) (22)
- Quadridentate nitrogen donor ligands acting as bridging di-bidentates; X-ray crystal and molecular structure of [Ag2{µ-(R)(S)-1,2-[(2-C5H4N)-C(H)N]2-cyclohexane}2][O3SCF3]2 and the observation of 3J(107,109Ag-1H) in the 1H n.m.r. spectrum of the dinuclear [Ag2L2]2+ cation (1980) (22)
- A novel hemilabile calix[4],quinoline-based P,N-ligand: coordination chemistry and complex characterisation. (2009) (22)
- Iron complexes of chiral phenol-oxazoline ligands: Structural studies and oxidation catalysis (2007) (21)
- 4-(p-Methylthio)phenyl-2,6-diphenyl phosphinine: The first X-ray crystal structure of a λ3-triaryl-phosphabenzene (2006) (21)
- Scope and limitations of an efficient four-component reaction for dihydropyridin-2-ones. (2010) (21)
- Synthesis of new bis(cyclopentadienyl)yttrium complexes with ether functionalized cyclopentadienyl ligands. Crystal structure of [(C5H4CH2CH2OMe)2Y(μ-H)2BH2] (1993) (21)
- Insertion of Unsaturated Hydrocarbons into the Palladium−Carbon Bond of Complexes (N⌒N)Pd(C(N-2,6-Me2Ph)Me)X (N⌒N = bpy, phen; X = Cl, Br, I, BF4): A Structural and Mechanistic Study (1997) (21)
- Synthesis, characterization and reactivity of ionic palladium(II) complexes contaiing bidentate nitrogen ligands in a unidentate coordination mode (1999) (21)
- Complex formation between nickel(0) and a phosphaalkene: Influence of the second ligand on the η1- and η2-coordination mode (1983) (21)
- Reactions of [RhCl(diene)]2 with Bi- and Terdentate Nitrogen Ligands. X-ray Structures of Five-Coordinate Complexes (1997) (21)
- Novel silicon bisalkoxy complexes with a pseudo-atrane structure. Synthesis and molecular structures of 2,6-di(2-hydroxy(2-adamantyl)) ethylpyridine and 2,6-di(2-oxy(2-adamantylidine))ethylpyridine dimethylsilicon (1994) (21)
- Reversible carbonylation of cationic palladium 2,6‐bis[(dimethylamino)methyl]pyridine complexes: The first X‐ray structure of a cationic aroyl‐palladium complex (1991) (21)
- Synthesis of novel terdentate N,C,N′-coordinated butyltin(IV) complexes and their redistribution reactions with SnCl4 (2006) (21)
- A Simple One‐Step Synthesis of Symmetrical Thiocrown Ethers and the Molecular Structure of an Unusual Sandwich‐like Tetrametallic Silver Thiocrown Ether Complex (1993) (21)
- Synthetic strategies towards new para-functionalised NCN-pincer palladium(II) and platinum(II) complexes (2002) (21)
- Influence of the size of upper and lower rim substituents on the fluxional and complexation behaviour of calix[5]arenes (1998) (21)
- Self-Organization of 2,5-Di-n-Alkoxy-1,4-benzoquinones in the Solid State: Molecular Recognition Involving Intermolecular Dipole−Dipole, Weak C−H···OC Hydrogen Bond and van der Waals Interactions (1996) (21)
- The synthesis, chemical and biological properties of dichlorido(azpy)gold(III) chloride (azpy=2-(phenylazo)pyridine) and the gold-induced conversion of the azpy ligand to the chloride of the novel tricyclic pyrido[2,1-c][1,2,4]benzotriazin-11-ium cation. (2007) (21)
- A multicomponent reaction towards N-(cyanomethyl)amides. (2009) (21)
- Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. (2011) (21)
- Unexpected formation of derivatives of cyclobutene and thiacyclobutane from the reaction between dilithiated benzylacetylene and isothiocyanates (2001) (21)
- The determination of pore volumes, pore shapes and diffusion paths in microporous crystals (2006) (21)
- Intramolecularly coordinated arylmagnesium compounds: effects on the Schlenk equilibrium (1991) (21)
- The stereoselective synthesis of cis- and trans-b-lactams via α-amino ester enolates and 1-aza-4-hetero-1,3-butadiene systems. Molecular structure of EtOC(O)C(H)Net2)C(H)(NH)(-t-Bu)C(H)=N(t-Bu)ZnCl2: an unexpectedly isolated intermediate (1991) (21)
- Five-Coordinate Tungsten(VI) Phenylimido Alkylidene Complexes, and Isolated Precursors, Containing a Chelating Arylamine Ligand as Active ROMP Catalysts : Molecular Structure of W(C6H4CH2NMe2-2)(-CHSiMe3)(CH2SiMe3)(=NPh) (1993) (20)
- One-pot synthesis and immobilisation of sulfonate-tethered N-heterocyclic carbene complexes on polycationic dendrimers. (2009) (20)
- LIGAND AND ALKALI-METAL CATION CONTROL ON THE MOLECULAR COMPLEXITY OF ANIONIC CHROMIUM(II) ARYLOXIDES - PREPARATION AND CRYSTAL-STRUCTURE OF DIMERIC (PHO)10CR2LI6(THF)6 AND (2,6-ME2C6H3O)6CR2LI2(THF)4 AND TRIMERIC (GUO)14CR3NA9CL [GUO = (ORTHO-CH3O)C6H4O] WITH AN ENCAPSULATED CHLORIDE-ION (1991) (20)
- Addition of a phosphinidene complex to C=N bonds: P-ylides, azaphosphiridines, and 1,3-dipolar cycloadditions. (2001) (20)
- A novel enantiopure proline-based organonickel(III) halide monocation with a pentadentate C, N2, O2-bonded bis(ortho-chelating) aryldiamine ligand☆ (1995) (20)
- A 12-Membered inorganic heterocycle: synthesis and structural characterization of a bimetallic chromium (VI) siloxane complex (1997) (20)
- Metathesis of olefin-substituted pyridines: the metalated NCN-pincer complex in a dual role as protecting group and scaffold. (2002) (20)
- Role of Cation-Anion Interactions in Ionic Complexes Containing [Pd{C6H3(CH2NMe2)2-2,6}(OH2)]+ and [{Pd(C6H3(CH2NMe2)2-2,6)}2(m-C1)]+ Cations (2004) (20)
- Reaction of a terminal phosphinidene complex with azulenes: eta1-complexes, C--H bond insertions, and 1,4-adducts. (2004) (20)
- Resolution of a tetrahydrofuran ester by Candida rugosa lipase (CRL) and an examination of CRL's stereochemical preference in organic media (1996) (20)
- Structural investigations of benzocyclopentadienylzinc compounds. Crystal structure of the bis(tetrahydrofuran) complex of difluorenylzinc (1989) (20)
- Phosphorus coordination of di- and tri-azaphospholes in platinum(0) complexes: x-ray molecular structure of tris(triphenylphospine)-1,5-dimethyl-1,2,4,3-triazaphosphole platinum(0) [Pt(PPh3)3] (1983) (20)
- Ring closing metathesis employing organometallic substrates and the templated synthesis of macrocycles (2006) (20)
- Pyrenoxy-Based NCN-Pincer Palladium(II) Molecular Tweezers: Synthesis, Properties in Solution and Catalysis (2003) (20)
- Carbonylation of the ruthenium-methyl bond of Ru(Me)(I)(CO)2(i-Pr-N:CHCH:N-i-Pr) catalyzed by Ru(CO)4(PR3), ZnCl2, and H+ (1992) (20)
- Self-complementary hydrogen bonding of 1,1′-bicyclohexylidene-4,4′-dione dioxixe. Formation of a non-covalent polymer. (1996) (20)
- The first x-ray structure of a 1,1-di-Grignard compound: bis(bromomagnesio)bis(trimethylsilyl)methane (1992) (20)
- Investigations on organoantimony compounds: XI. Triorganoantimony(V) compounds containing potentially tridentate ligands⋆ (1974) (20)
- Alkene and Alkyne Reactivity Towards a Bisruthenium (II) µ2-Dinitrogen Complex Containing the 'Pincer' ligand 2,6-Bis[(dimethylamino)methyl]pyridine(NN'N). The X-ray Crystal Structures of [Ru(=C=CHPh)Cl2(NN'N)] and [Ru(=C=CHPh)(OTf)(NN'N)(PPh3)][OTf] (OTf =Trifluoromethane Sulfonate) (1999) (20)
- Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. (2006) (20)
- Monomeric arylchromium(II) complexes: the crystal structures of [cis-Mes2Cr(THF)2](THF), [cis-Mes2Cr(bipy)](THF), [Mes4CrLi2(THF)2](THF) and Ph4CrLi2(THF)4 (Mes = 2,4,6-mesityl; bipy = 2,2′-bipyridine) (1990) (20)
- Syntheses and characterization of dinuclear palladium and platinum complexes with a single unsupported bridging group. Crystal structure of [{C6H3(CH2NMe2)2-o,o′}Pd(µ-Cl)Pd{C6H3(CH2NMe2)2-o,o′}]BF4 (1987) (20)
- A novel octanuclear Mn(III) aggregate as a single-molecule magnet. (2005) (20)
- Synthesis and molecular structures of palladium and platinum complexes of PTFA: models of Grignard cross-coupling catalysts (1996) (20)
- Synthesis, spectroscopy, and X-ray structure of the polymer catena-[bis(azido-N)-copper(II)-μ-bis(2-benzimidazolyl)butane] (2000) (20)
- The circumambulation of a phosphirane: taking 9-phenyl-9-phosphabicyclo[6.1.0]nona-2,4,6-triene for a "walk". (2004) (20)
- Non-Tethered Organometallic Phosphonate Inhibitors for Lipase Inhibition: Positioning of the Metal Center in the Active Site of Cutinase (2008) (20)
- Amine-thioether and amine-pyridine complexes of palladium(II) and the reactivity of the methyl complexes towards CO and allenes (1996) (19)
- A pyrazole-containing verdazyl radical ligand Meprv: structure of its precursor prvH3 and its bis(2,2′-bipyridine)ruthenium(II) complex (2003) (19)
- Spontaneous Assembly of a Novel Tetranuclear Ni–Fe Complex by Complete Reshuffling of Ligands and Oxidation States (1999) (19)
- XPdCl (X = Cl, Me, Ac) (1997) (19)
- Synthesis, Crystal Structure, and Redox and Photophysical Properties of Novel Bisphosphinoaryl RuII-Terpyridine Complexes (2004) (19)
- A dinuclear copper(II) macrocyclic pyrazole compound catalyses the oxidative polymerisation of 2,6-dimethylphenol (2001) (19)
- Determination of the Absolute Configuration of 3-Pyrrolin-2-ones (1999) (19)
- A multiple hydrogen-bond scaffold based on dipyrimidin-2-ylamine. (2001) (19)
- A bimetallic tantalum-zinc complex with an ancillary aryldiamine ligand as precursor for a reactive alkylidyne species : Alkylidyne-mediated C-H activation and a palladium-mediated alkylidyne functionalizing (1993) (19)
- Highly Efficient Disproportionation of Dihydrogen Peroxide: Synthesis, Structure, and Catalase Activity of Manganese Complexes of the Salicylimidate Ligand (2005) (19)
- Generation of molecular diversity using a complexity-generating MCR-platform towards triazinane diones. (2008) (19)
- Oxidative double dehalogenation of tetrachlorocatechol by a bio-inspired CuII complex: formation of chloranilic acid. (2008) (19)
- Cp6Ni2Zn4 ― an unusually electron-rich octahedral cluster (1985) (19)
- Cation control on the synthesis of p-t-butylthiacalix[4](bis)crown ethers (2002) (19)
- Zinc enolates: C- or O-metallation? (1987) (19)
- Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the N-Thienylidene-L/D-methionine Methyl Ester Ligand (1996) (19)
- Synthesis and characterization of platinum(II)-terminated dendritic carbosilanes: X-ray crystal structure of the model species [PtCl(C6H3{CH2NMe2}-2-SiMe3-5)(PPh3)] (2001) (19)
- Scope, mechanism and diene inhibition of isomerization of allylic alcohols to saturated ketones catalyzed by ruthenium(II)-cyclopentadienyl complexes (2005) (19)
- The first lithium phenolate with a trinuclear structure and the tetranuclear product of 1 : 1 addition of lithium iodide; X-ray structures of [LiOAr]3 and [Li2(OAr)I]2[OAr = OC6H2(CH2NMe2)2-2,6-Me-4] (1992) (19)
- Synthesis and Spectroscopy of Coordination Compounds of a Versatile Bridging Ligand. Molecular Structures of the Dinuclear Compounds [Co2(bdnol)(NCS)3], [Zn2(bdnol)Cl(NCS)2], and [Cu2(bdnol)(NO3)3] and of the Polymeric Copper(I) Compound [Cu2(Hbdnol)(NCS)2] (1995) (19)
- Comparing structures and reactivity in analogous Fe- and Ru-Complexes (iPr-DAB)Fe(CO)2I2 and (iPr-DAB)FeI2: A perfectly reversible CO-crrier system (R-DAB=N,N,'-R2-1,4-diaza-1,3-butadiene) (1999) (19)
- Complexation and (templated) synthesis of rhenium complexes with cyclodextrins and cyclodextrin dimers in water. (2001) (19)
- Reactivity of 1-aza-4-oxo-1,3-butadienes (a-iminoketones) towards triorganoaluminum reagents I. X-ray crystal structures of [(AlMe3)2{s,s-N,O-(MeN=C(Ph)C(Ph)=O}],with a N,O-bridge bonded a-iminoketone, and of Me2Al(t-Bu)N= CHC(Me)2OAlMe3, a carbonyl alkylated product which is O-coordinated to AlMe3 (1986) (19)
- The crystal and molecular structure of copper(I) trifluoromethanesulphonate cyclohexene complex (1984) (18)
- Self-assembly of para-OH functionalized ECE-metalated pincer complexes (2008) (18)
- Formation of organolithium hetero-aggregates [Li4Ar2(nBu)2] (Ar=C6H4CH(Me)NMe2-2) during the directed ortho-lithiation of [1-(dimethylamino)ethyl]benzene. (2004) (18)
- A hydrogen atom in an organoplatinum-amine system: tautomers having either a bridging hydrogen with platinum(II) or a hydride on platinum(IV). The X-ray crystal structure at 100 K of [Pt{C10H6(NMe2)-8-C,N}{C10H6(NHMe2)-8-C}(Br)] (1990) (18)
- Configurational Preferences and Alkylidene-Centered Reactivity of Tantalum Alkoxide Complexes Containing an Aryldiamine Spectator Ligand? (1994) (18)
- Strongly Nucleophilic RhI Centre in Square-Planar Complexes with Terdentate (κ3) 2,2':6',2''-Terpyridine ligands: Crystallographic, Electrochemical and Density Functional Theoretical Studies (2004) (18)
- Synthesis and Crystal Structure of [guanidinium][Ni(dmit)2]2 and [1,1-dimethylguanidinium][Ni(dmit)2]2 (dmit = 2-Thioxo-1,3-dithiole-4,5-dithiolate). Intermolecular Orbital Overlap Calculations and Electrical Conductivities (1995) (18)
- The First Low‐Spin Nickel Complex with Two Coordinated Water Molecules, [Ni(o‐MeO‐dppp)(H2O)2](PF6)2 − Synthesis and Structural Characterization (2001) (18)
- The synthesis and characterization of 1,1-bis(aminomethyl)cyclohexaneplatinum(II) compounds and the crystal structure determination of 1,1-bis(aminomethyl)-cyclohexaneaquosulphatoplatinum(II) monohydrate (1986) (18)
- Induction of higher coordination states in phenyl Grignard reagents by intramolecular coordination. Crystal structures of O-CH2(OCH2CH2)*OCH3-substituted phenylmagnesium bromides (n = 0-3) (1991) (18)
- Introduction of Bulky Substituents at the Bridgehead Position of a 9-Silatriptycene: Pentacoordinate Hydridoorganylsilicates as Intermediates (2000) (18)
- Dualistic Reactivity of Lithium and Zinc Dienolates with Imines: Effects of Counter Ion, Termperature and Substituents on a- and g-Coupling (1994) (18)
- Structure of aqua-bis(ethylenediamine)copper(II) bis(2,6-dimethylphenolate) (2000) (18)
- Effect of conformation of cyclic sulfide ligands on the mode of complexation to silver salts (1993) (18)
- Construction of a monoanionic S,N,S-pincer ligand with a pyrrole core by sequential [1,2] phospho-Fries rearrangement. Characterization of palladium and silver coordination complexes. (2010) (18)
- Towards Organometallic Polymers with High Directionality Containing Bis-ortho-Chelating Ligands (2001) (18)
- Coordination Behaviour of the New Multidentate Ligand 3,5‐Bis(dimethylaminomethyl)pyridine with Palladium(II) and Platinum(II) Metal Centres (1998) (18)
- Kinetic and thermodynamic products in the reaction of poly(dichlorodicarbonylruthenium) with pyridinecarbaldimine ligands and the crystal structure of trans-Cl2Ru(CO)2(N-(pyrid-2-ylmethoxymethyl)(3-isopropoxypropyl)amine) (1993) (18)
- Structure and Electronic Properties of (Ni(dsdm){Fe(CO) 3 } 2 ), an Unusual, Triangular Nickel Diiron Compound (2003) (18)
- In vitro antitumor activity and interaction with DNA model bases of cis-[PtCl2(iPram)(azole)] complexes and comparison with their trans analogues (2006) (18)
- POLYMETALLIC CHROMIUM ALKOXIDES - SYNTHESIS AND CRYSTAL-STRUCTURES OF (I-PRO)8CR2NA4(THF)4 AND (MU-3-OPH)10CR4(MU-3-O)3NA4(TMEDA)4 (1991) (18)
- Ureidobenzotriazine multiple H-bonding arrays: the importance of geometrical details on the stability of H-bonds. (2008) (18)
- Spectro-electrochemical and DFT studies of a planar Cu(II)-phenolate complex active in the aerobic oxidation of primary alcohols (2011) (18)
- INSERTION REACTIONS INTO PALLADIUM-CARBON BONDS OF COMPLEXES CONTAINING TERDENTATE NITROGEN LIGANDS; EXPERIMENTAL AND AB INITIO MO STUDIES (1998) (18)
- Mononuclear tungsten(VI) phenylimido phenoxide and alkoxide complexes with intramolecular amine coordination : molecular structure of WCl3(=NPh)(OC6H2(CH2NMe2)2-2,6-Me-4] (1993) (18)
- A modular approach to potential synthetic receptors with large surfaces based on crown[n]cavitands (1998) (17)
- Bridging of Resorcin[4]arenes in the Chair Conformation to Cavitands Having Two Pairs of Axial and Equatorial Substituents (1998) (17)
- Haloalkane C-X Bond Activation by a Ruthenium(II) Complex: X-ray Characterization of a Ruthenium(III) Intermediate Species in the Atom Transfer Radical Polymerization of Methyl Methacrylate (2000) (17)
- Increasing the Lipophilic Character of Tetraphenylborate Anions through Silyl Substituents (2001) (17)
- (Tetraazadiene)platinum complexes. X-ray crystal and molecular structure of thetriethylphosphine nucleophilic addition product [Pt{1,4-(4-NO2C6H4)2N4} {CHC(PEt3)H(CH2CH=CHCH2CH2}(PEt3)]; a novel five-coordinate blue mononuclear platinum species (1982) (17)
- Organopalladium-Functionalized Dendrimers: Insertion of Palladium(0) into Peripheral Carbon−Iodine Bonds of Carbosilane Dendrimers Derived from Polyols. Crystal Structure of Si{(CH2)3O2CC6H4I-4}4 (1997) (17)
- Synthesis, reactivity and crystal structure of [1,4-bis(4-tolyl)tetraazadiene] (h5-cyclopentadienyl)nickel (1982) (17)
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- THE CONTROVERSY OVER THE THERMAL-STABILITY OF BIS(CYCLOPENTADIENYL)ZIRCONIUM(III) HALIDES - SYNTHESIS OF CP2ZRCL, C5H4ME2ZRBR, CP'2ZRI VIA PHOTOLYSIS OF CP'2ZR(I-BU)X - THE X-RAY STRUCTURES OF [(C5H4ME)2ZR(MU-I)]2 AND [ETA-5-ETA-5-C10H8][CPZR(MU-I)]2 (1989) (17)
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- Synthesis and Characterization of O,N-Chelated Vanadium (IV) Oxo Phenolate Complexes : the Electronic Effect of meta- and para Substituents on the Vanadium Center (1999) (17)
- Homogeneous hydrogenation of 1-octene: effect of anion, solvent and ligand on hydrogenation activity and selectivity: Crystal structure of the catalyst precursor [Ni(o-MeO-dppp)(tfa)2] (2002) (17)
- Intramolecular rearrangements of sulfines coordinated to platinum. A unique equilibrium between oxidative-addition stereoisomers cis-(E)- and cis-(Z)-bis(triphenyl-phosphine) (methylthio)(arylsulfine)platinum(II) and the two stereoisomers of the reductive coupling product. Bis(triphenylphosphine) [a (1981) (17)
- Crystal Structure and Silver Ion Complexation of a Novel Porphyrazine Substituted with Four Dithiacrown Ether Rings (1994) (17)
- Anion-controlled oligomerization of carbon monoxide and norbornene on a palladium(II) centre (1993) (17)
- Synthesis of Novel Phosphaalkene-Based Bidentate Ligands Mes*(Me)P=CH(3-R-Ar) (R = Pyridyl, Carbaldimino) and Formation of Three-Membered Palladacycles Mes*(Me)P-CH(3-R-Ar)-PdCl by Carbapalladation of the P=C Double Bond (1999) (17)
- A proposal for positive cooperation in anion-cation binding in yttrium and lutetium complexes based on o-amino-substituted phenolate ligands. On the way to coordination polymers by self-assembly. Molecular structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR) (1996) (17)
- Intramolecular oxidation of the ligand 4-methyl-2-N-(2-pyridylmethyl)aminophenol (Hpyramol) upon coordination with iron(II) chloride and manganese(II) perchlorate (2004) (17)
- Synthesis and structural characterisation of platinum silasesquioxane complexes (1998) (17)
- The Activation of Phenylmagnesium Compounds by Crown Ethers (1988) (17)
- Structure of a second polymorph of calcium acetate monohydrate (1987) (17)
- C,N-2-((Dimethylamino)methyl)phenylplatinum Complexes Functionalized with C60 as Macromolecular Building Blocks (2001) (17)
- Another silver complex of 1,3-dibenzylimidazol-2-ylidene: Solution and solid-state structures (2009) (17)
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- Palladium(0) mediated coupling of bromophosphaalkenes with Grignard reagents. (1997) (17)
- Mono N,C,N-pincer complexes of titanium, vanadium and niobium. Synthesis, structure and catalytic activity in olefin polymerisation. (2011) (17)
- Organomolybdenum(VI) and Lithium Organomolybdate(VI) and -(V) Complexes with C,N-Chelating Aminoaryl Ligands (1999) (17)
- NMR Spectroscopic Studies of Palladium(II) Complexes of Bidentate Diphenylphosphane Ligands with Acetate and Tosylate Anions: Complex Formation and Structures (2010) (17)
- Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks. (2007) (16)
- Internally coordinated organozinc-transition metal compounds. Crystal structure of (CH3)2N(CH2)3ZnW(ν-C5H5)(CO)3 (1983) (16)
- Silsesquioxane-bonded zirconocene complexes; soluble models for silica-tethered olefin polymerization catalysts. (2003) (16)
- Organometallic benzylidene anilines: donor-acceptor features in NCN-pincer Pt(ii) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent. (2014) (16)
- Asymmetric chlorine-bridged zig-zag Cu(II) chains linked together in 2D sheets by strong Watson–Crick type intermolecular double hydrogen bonds of bis(pyrimidin-2-yl)amine ligands: synthesis, structure and antiferromagnetism (2004) (16)
- Branched phospha[7]triangulanes. (2004) (16)
- Two phases of [Me4N][Ni(dmise)2]2: syntheses, crystal structures, electrical conductivities, and intermolecular orbital overlap calculations of .alpha.- and .beta.-tetramethylammonium bis[bis(2-selenoxo-1,3-dithiole-4,5-dithiolato)nickelate], the first conductors based on the M(C3S4Se)2 system (1993) (16)
- Molecular-weight-enlarged multiple-pincer ligands: synthesis and application in palladium-catalyzed allylic substitution reactions. (2009) (16)
- 1,4-Addition of a Terminal Phosphinidene Complex to [5]Metacyclophane. (1998) (16)
- [(Ph2P(CH2)3]2Zn: X-ray crystal structure determination and reaction with group 11 metal salts (1987) (16)
- A dinuclear copper(II) and a mononuclear cobalt(II) compound of the didentate N,O-donor ligand 1-(2-hydroxyethyl)-3,5-dimethylpyrazole (2000) (16)
- Reactivity of [2,6-Bis((dimethylamino)methyl)phenyl]gold(I), an Unusual Intermolecularly Stabilized Bis(amino)aryl−Gold(I) Dimer, toward Alkyl Halides. X-ray Crystal Structures of Its Iodomethane and Methylene Diiodide Adducts† (2000) (16)
- Group IB organometallic Chemistry. XXXV. Crystal and molecular structure of [Cu4{4-MeC6H4)MeC=C(C6H4NMe2-2)}2(C6H4NMe2-2)2], a tetranuclear organo-copper compound containing bridging alkenyl and aryl groups (1982) (16)
- Preparation of novel alkylated ruthenium {alpha}-diimine complexes: Reactivity toward carbon monoxide and phosphines (1992) (16)
- Induction of Chirotopicity in the Self-Assembly Process of Heterocuprates: Structual and Stereochemical Aspects of Neutral Culi2BrAryl2 Aggregates (2002) (16)
- Synthesis of and evidence for electronic communication within heteromultimetallic tetrakis(NCN-pincer metal)-(metallo)porphyrin hybrids. (2010) (16)
- A calix[6]arene derived diphosphite, synthesis and complexation behaviour; X-ray structure of a palladium(II) chloride complex (1996) (16)
- Cyclopentadienylzinc-transition metal compounds. Structure of (C5H5Zn)2Co(C5H5)P(C6H5)3 (1982) (16)
- New Coordinatively Unsaturated Lutetium Mono- and Bis(alkyl) Complexes with a Bis(ortho)-Chelating Aryldiamine Ligand—Crystal Structures of [LuCl2{2,6-(Me2NCH2)2C6H3}(μ-Cl)(μ-Li(thf)2)]2 and [Lu(μ-Cl){2,6-(Me2NCH2)2C6H3}(CH2SiMe3)]2 (1995) (16)
- Iridium phosphinidene complexes: a comparison with iridium imido complexes in their reaction with isocyanides. (2009) (16)
- Cyclic 1,8-napththalenediyl compounds containing group 14 hetero atoms (1994) (16)
- Phospha[3]radialenes. Synthesis, Structures, Strain Energies, and Reactions (2000) (16)
- New diphosphane ligands based on Bisphenol A backbones - synthesis and coordination chemistry (2003) (16)
- Gentiogenal, a conversion product of gentiopicrin (gentiopicroside)*. (1983) (16)
- SYNTHESIS OF METHYLTRIOXORHENIUM(VII) ARYLAMINE COMPLEXES AND MONO-AND BIS(ORTHO)-CHELATED ARYLAMINORHENIUM(VII) TRIOXIDES (1997) (15)
- trans-Arylplatinum(II) methyl compounds containing a bis(imino)aryl [NCN] ligand (2004) (15)
- 2-Phospha-4-silabicyclo[1.1.0]butane as a reactive intermediate. (2004) (15)
- Electronic and second-order nonlinear optical properties ofconformationally locked benzylideneanilines and biphenyls. The effect ofconformation on the first hyperpolarizability (1997) (15)
- Two New Dinuclear Sterically Crowded CuII Complexes as Catalyst Precursors for the Oxidative Coupling of 2,6‐Dimethylphenol (2003) (15)
- Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies. (2010) (15)
- The crystal structure of a hexanuclear mixed thiophenolato-alkynyl copper(I) complex: [Cu3{SC6H4(CH2NMe2)-2}2(CCBut)]2: a model for electron deficient organocopper(I) complexes with cuprate reactivity (1989) (15)
- The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes (2011) (15)
- (2,2'-Biquinoline-κ2N,N')chloro(2,2':6',2''-terpyridine-κ3N,N',N'')ruthenium(II) hexafluorophosphate, [RuCl(C18H12N2)(C15H11N3)][PF6] (1994) (15)
- The First Case of Local cis versus trans Coordination as the Controlling Factor for the Overall Structure in Dinuclear Assemblies (2002) (15)
- Directed ortho-lithiation: observation of an unexpected 1-lithio to 3-lithio conversion of 1-lithio-naphthyllithium compounds with an ortho-directing 2-(dimethylamino)methyl group. (2013) (15)
- Bis(μ-alkoxo)-bridged dinuclear iron(III) complexes of pyrazole-based ligands as models for iron-oxo proteins (2005) (15)
- Monomeric bis(η2-alkyne) complexes of (η1-mesityl)copper(I) and (η1-mesityl)silver(I) obtained from a bis(alkynyl)titanocene; X-ray structure of [(η5-C5H4SiMe3)2Ti(CCSiMe3)2]Cu(η1-Mes)(Mes = C6H2Me3-2,4,6) (1995) (15)
- Synthesis and structure of phosphaalkenylmercury compounds (1992) (15)
- Periphery-Palladated Carbosilane Dendrimers: Synthesis and Reactivity of Organopalladium(II) and -(IV) Dendritic Complexes. Crystal Structure of (PdMe(C6H4(OCH2Ph)-4)(bpy)) (bpy ) 2,2'-Bipyridine) (1999) (15)
- Bis-(thiosemicarbazonato) Zn(II) complexes as building blocks for construction of supramolecular catalysts. (2012) (15)
- A new mixed alkoxo aryloxo palladium complex with a bidentate nitrogen donor system (1993) (15)
- 2,3,5,6,-Tetraalkoxy-1,4-benzoquinones and structurally related tetraalkoxy benzene derivatives: synthesis, properties and solid state packing motifs (1996) (15)
- Kupfer(II)‐vermittelte oxidative Kupplung eines Bis(dimethylaminomethyl)arylruthenium‐komplexes zu [(terpy)RuIII(pincer‐pincer)‐RuIII(terpy)] (CuCl2)4 (1994) (15)
- X-ray crystal structure and hydrocarbon solution dynamics of tetrameric 1-(dimethylamino)-3-lithiopropane (1985) (15)
- Four‐Membered 1,8‐Naphthalenediyl Transition Metallacycles (1994) (15)
- Synthesis of the ligand N,N′-bis(2-tert-butylthiobenzenylidene)-diethylenetriamine; its reactivity with nickel(II) salts (1999) (15)
- Ladderlike oligomers; intramolecular hydrogen bonding, push-pull character, and electron affinity. (2000) (15)
- Synthesis of novel trialkyl(trichlorostannyl)platinum(IV) complexes through SnCl2 insertion into the Pt-Cl bond (2003) (15)
- 8,11-Dichloro-N-tosyl-3-aza[5]metacyclophane: A Highly Strained Aromatic System (1997) (15)
- Metal-binding affinity of a series of bis-benzimidazolesimmobilised on silica (1997) (14)
- Century-known copper salt Cu(OAc)(OMe) proven to be a unique magnetic lattice composed of tetranuclear copper(II) species with a rare binding mode of the acetate anion. (2003) (14)
- Cavities for Binding Two Metal Atoms: A Novel Pentanuclear Copper(I) Complex with an Anionic, Pentadentate Aryl Ligand with Two ortho-Chelating Diamine Substituents† (1993) (14)
- Dinuclear palladium, nickel, and rhodium complexes based on 1,3-bis[(2-(diphenylphosphino)benzylidene)-amino]propan-2-ol (1998) (14)
- Cooperative binding of Na+ and Cl- in Na{M[OC6H2(CH2NMe2)2-2,6-Me-4]3Cl}: Synthesis (M = Lu, Y) and X-Ray Structure (M = Lu) of New Heterometallic Complexes of Lutetium and Yttrium Containing bis(ortho)-Amino Phenolate Ligands (1994) (14)
- Synthesis of a bis-(Cyclopentadienyl)lanthanum aryl complex with a pseudofacially, bis(ortho)-chelating aryldiamine ligand. X-ray structure of (h5-C5H5)2La(C6H3{CH2NMe2}2-2,6) (1996) (14)
- Synthesis of a complexed 2,2-bisphosphirane (2000) (14)
- The structure of the three‐dimensional polymer poly[μ‐hexakis(2‐methylimidazolato‐N,N')‐triiron(II)], [Fe3(C4H5N2)6]n (1983) (14)
- Unexpected Carbon-Carbon Coupling between Organic Cyanides and an Isopropyl β-Carbon in a Hafnium Ene Diamide Complex (1992) (14)
- Structure–Activity Relationships of Oligocationic, Ammonium‐Functionalized Triarylphosphines as Ligands in the Pd‐Catalyzed Suzuki–Miyaura Reaction (2010) (14)
- Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(μ-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy = 2,2'-bipyridine) (2002) (14)
- Diamino-ligated platinum(II) and platinum(IV) phenoxide complexes; syntheses and crystal structures (1997) (14)
- Synthesis of ruthenium-phosphine complexes with heterodiene ligands (1993) (14)
- Coordination Chemistry in Water of a Free and a Lipase-Embedded Cationic NCN-Pincer Platinum Center with Neutral and Ionic Triarylphosphines (2012) (14)
- Structure of (−)‐epicatechin: (2R,3R)‐2‐(3,4‐dihydroxyphenyl)‐3,4‐dihydro‐2H‐1‐benzopyran‐3,5,7‐triol, C15H14O6 (1984) (14)
- Bidentate phosphorus baskets by intramolecular phosphinidene addition. (2006) (14)
- A novel synthetic route to tantalum-zinc neophylidyne complexes stabilized by ortho-chelating arylamine ligands : The X-ray structure of [TaCl2(m-C6H4CH2NMe2-2)(m-CCMe2Ph)ZnCl(THF)] (1997) (14)
- Alkylidene-centered rearrangement of a tantalum alkylidene alkoxide species with the N,C,N,-bis-ortho-chelated 1,2,6-trisubstituted aryldiamine ligand [C6H3(CH2NMe2)2-2,6]- to a product with a C,N-mono-ortho-chelated 1,2,4-trisubstituted aryldiamine ligand. X-ray molecular structure of [TaCl(=Ch-t-B (1997) (14)
- A Novel Phenol for Use in Convergent and Divergent Dendrimer Synthesis: Access to Core Functionalisable Trifurcate Carbosilane Dendrimers—The X‐ray Crystal Structure of [1,3,5‐Tris{4‐(triallylsilyl)phenylester}benzene] (1999) (14)
- The Absolute Configuration and Crystal Structure of the Anticholinergic Drug Dexbenzetimide (1971) (14)
- Structure, Dynamic Behavior, and Catalytic Activity of a Novel Ruthenium Cyclopentadienyl Complex with a Tridentate P,P,O Ligand (2002) (14)
- Quinoxaline-2-carboxamide as a carrier ligand in two new platinum(II) compounds: Synthesis, crystal structure, cytotoxic activity and DNA interaction. (2010) (14)
- Coordination complexes of bis(2,2-dimethyl-3,5-hexanedionato) zinc with organozinc-oxygen and -nitrogen compounds. Crystal structure of the complex formed with phenylzinc phenoxide (1974) (14)
- Hydrogenation of the two diastereomers of the 66-electron linear cluster Ru4(CO)10[R1C:C(H)C(H):NR2]2. Hydrogen-transfer reactions and the molecular structure of the only isolable diastereomer of the 64-electron butterfly cluster (.mu.-H)2Ru4(CO)8[CH3C:C(H)C(H):N-iso-Pr]2 (1992) (14)
- Diastereopure Cationic NCN-Pincer Palladium Complexes with Square Planar η4-N,C,N,O Coordination (2006) (14)
- Syntheses, structures and spectroscopic properties of a novel series of metalmetal bonded complexes Ru(E)(E′)(CO)2(iPrDAB): (E Br, E′ Mn(CO)5; E SnPh3, E′ Mn(CO)5, Re(CO)5, CO(CO)4; E Me, E′ Re(CO)5; E E′ Mn(CO)5, Re(CO)5; iPrDAB N,N′-diisopropyl-1,4-diaza-1,3-butadiene) (1997) (14)
- Structure of m-[1,2-bis(tert-butylamino-1:2kN)-1,2-di(2-pyridyl-kN)ethane]-bis (ethylzinc) (1987) (13)
- Ionic core–shell dendrimers with a polycationic core: structural aspects and host–guest binding properties (2007) (13)
- Intramolecular alkoxycobaltation: a novel route to the cobalt–carbon bond in a coenzyme B12 model (1993) (13)
- Synthesis and X-ray crystal structures of a dinuclear and a trinuclear nickel complex with mixed N,O,S ligand environments (2001) (13)
- Synthesis and crystal structure of a dinuclear rhodium complex. Catalytic activity of mono- and di-nuclear rhodium phosphite complexes in hydroformylation. (1996) (13)
- Synthesis and characterization of two isomers of Os3(CO)10(C5H4N-2-C(H)NR) and the conversion to ortho-metallated HOs3(C5H3N-2-C(H)NR)(CO)9. Part III. X-ray Structure of HOs3(C5H3N-2-C(H)Ni-Pr)(CO)9 (1988) (13)
- Electronic properties, redox behavior, and interactions with H2O2 of pH-sensitive hydroxyphenyl-1,2,4-triazole-based oxovanadium(V) complexes. (2006) (13)
- Supramolecular Hydrogen-Bonding Tautomeric Sulfonamido–Phosphinamides: A Perfect P-Chirogenic Memory (2012) (13)
- Direct phase determination of triple products from Bijvoet inequalities. II. A probabilistic approach (1978) (13)
- C–H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN ‘pincer’ ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)] (1999) (13)
- Synthesis and x-ray crystal structure of 11-bromo-endo-9-chloro-7-ethoxybicyclo[5.3.1]undec-1(11)-ene. A stable highly strained anti-Bredt olefin (1992) (13)
- Norbornadiene-Quadricyclane Valence Isomerism for a Tetraphosphorus Derivative The Netherlands Organization for Scientific Research (NOW/CW) is acknowledged for partial support (A.L.S., M.L., K.L.), as are the NSERC of Canada for a scholarship (S.B.C.), and EPSRC for funding phosphaorganometallic ch (2001) (13)
- Structural Aspects of Lithium Arenethiolate Complexes with Intramolecular Coordinating Amine Donors. (1996) (13)
- Bridged (β-alkoxyalkyl)CoIII(salen) complexes by intramolecular alkoxycobaltation of unactivated alkenes: new models for coenzyme B12 (2000) (13)
- Crystal structure of zinc[bis[3-(dimethylamino)propyl-C,N]tin]bis(dibenzoylmethanato)-(SnZn). The first example of a dialkyltin(II) compound stabilized by SnZn coordination (1990) (13)
- Neutral pyridyl-functionalized C,N-ortho-chelated aminoaryl platinum(II) corner building blocks for application in coordination reactions. (2005) (13)
- A Mixed (Arenethiolato)copper(I)/Copper Bromide Aggregate: X-ray Structure of Octanuclear [Cu(8){SC(6)H(3)(CH(2)NMe(2))(2)-2,6}(3)Br(5)]. (1996) (13)
- Reaction of a complexed phosphinidene with 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene. (2001) (13)
- {2,6-Bis[(dimethylamino-κN)methyl]phenyl-κC}iodopalladium(II) bis(diiodine) (2002) (13)
- A novel type of tetranuclear cluster with the trinucleating ligand 1,2-Bis(benzimidazol-2-yl)-1-hydroxyethane. Crystal and molecular structure of Ni(HRSL)2(CF3SO3)2 and [Cu4(SL)4(NO3)2(EtOH)] (NO3)2(EtOH)3(H2O)2; spectroscopy and magnetism of these and related transition metal compounds (1989) (13)
- Tricarbonylchromium complexes of [5]- and [6]metacyclophane: an experimental and theoretical study (2008) (13)
- A new homobimetallic arenediyl diplatinum(II) unit as building block for macromolecular synthesis. X-ray crystal structure of [C6H2{CH2NMe2}2-1,5-{PtCl(PPh3)}2-2,4] (2001) (13)
- Metal-template-directed synthesis of diphosphorus compounds through intramolecular phosphinidene additions. (2002) (13)
- Supramolecular Dendriphores: Anionic Organometallic Phosphors Embedded in Polycationic Dendritic Species (2009) (13)
- Unusual conformational aspects of some novel chiral non-racemic pyridinyl-2-phosphonates (1998) (13)
- O,N-Chelated boron aminophenolate complexes. Crystal structure of BPh2(OC6H4(CH2NMe2)-2) (2000) (13)
- Synthesis and structure-activity relationships of conformationally constrained histamine H(3) receptor agonists. (2003) (13)
- Cyclic Bis-Urea Compounds as Gelators for Organic Solvents (1999) (13)
- Reactions of monoaza dienes with metal carbonyl complexes. 15. Heteronuclear monoaza dienyl complexes, isolobally related to cyclopentadienyl compounds (1993) (13)
- Intra-versus inter-molecular azine formation in thiocrown ether chemistry (1992) (13)
- Synthesis and structural characterization of the homoleptic magnesium bis zinc ate complex Mg(thf) 6[Zn(CH2Ph)3]2 (1997) (13)
- Mechanistic Study of the Pd/TOMPP‐Catalyzed Telomerization of 1,3‐Butadiene with Biomass‐Based Alcohols: On the Reversibility of Phosphine Alkylation (2011) (13)
- Intramolecular CH activation and oxidative addition reactions of iridium complexes containing arylamines with bulky substituents on n itrogen; X-ray structures of [IrI(C6H4CH2NEt2-2-C,C)] and [IrIII(C6H4CH2Net(CHMe)-2-C,N,C′)I(cod)] (cod = cycloocta-1,-5-diene) (1996) (13)
- Molybdenum(VI) Bisimidoaryl Phenoxide and Alkoxide Complexes: Molecular Structures of [Mo(NAr)2(OCMe2‐2‐py)(CH2SiMe3)] and [{Mo(NAr)2Me(OMe)}2] (1999) (13)
- Synthesis and Characterization of β‐Phosphaenones An Investigation on the Conjugative Properties of the PC Bond (1995) (12)
- (R)-2-phenylglycine as a chiral auxiliary in the asymmetric synthesis of 2-azetidinones (1993) (12)
- A PCP‐Pincer RuII–Terpyridine Building Block as a Potential “Antenna Unit” for Intramolecular Sensitization (2007) (12)
- Valence isomerization of 2-phosphabicyclo[1.1.0]butanes. (2005) (12)
- Synthesis, structures, and strain energies of dispirophosphiranes. Comparisons with dispirocyclopropanes. (2002) (12)
- 1,3-Dipolar cycloaddition to the Fe-S=C fragment 20. Preparation and properties of carbonyliron complexes of di-thiooxamide. Reactivity of the mononuclear (di-thiooxamide)Fe(CO)3 towards dimethyl acetylenedicarboxylate (2002) (12)
- Reinvestigation of the structure of calcium copper acetate hexahydrate, CaCu(C2H3O2)4.6H2O (1983) (12)
- X-Ray crystal structure of tetrameric 3-lithio-1-methoxybutane (1983) (12)
- Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium. (2008) (12)
- Addition of a phenylphosphinidene complex to conjugated diynes (1999) (12)
- Synthesis, structure and magnetic properties of a linear-chain manganese(II) complex [Mn(μ-Cl)2(mppma)]n, where mppma is N-(3-methoxypropyl)-N-(pyridin-2-ylmethyl)amine (2003) (12)
- The crystal and molecular structure of prostaglandin E1 (1977) (12)
- Reactivity of a binuclear Ru(II) N2-bridged complex towards phosphines: facile access to novel mono and binuclear phosphorous derivatives. X-ray structural characterization of two unusual binuclear complexes containing ‘pincer’ ligands: [{RuCl2(η3-NN′N)}2(μ-η2-P2)] (NN′N=2,6-bis[(dimethylamino)methy (1999) (12)
- Functionalized Homoleptic cis- and trans-C,N-ortho-Chelated Aminoaryl Platinum(II) Complexes (2005) (12)
- α-Tris(2,4-pentanedionato-κ2O,O')cobalt(III) at 240, 210, 180, 150 and 110 K (2007) (12)
- X-Ray Structures of Mononuclear and Dinuclear Cu(Ii) Complexes of Novel Pyridine Crown-Ether Ligands (1994) (12)
- A Silsesquioxane-Based Diphosphinite Ligand: Synthesis, DFT Study, and Coordination Chemistry (2003) (12)
- Conformational studies of ligand-template assemblies and the consequences for encapsulation of rhodium complexes and hydroformylation catalysis (2013) (12)
- P-chirogenic benzo-fused phenoxaphosphane: Synthesis, resolution and study of the stereochemical properties of the corresponding palladium complexes (2008) (12)
- Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene (2000) (12)
- The synthesis and crystal structure of a remarkable binuclear, double Pd–Cl–H–O–Pd bridged palladium alcohol complex. Catalytic oxidations with molecular oxygen mediated by [{[Me2C(OH)CH2CONMe2]Pd(Cl)NO2}2] (1992) (12)
- Manganese Oxidation Catalysts with 2-(2'-Hydroxyphenyl)oxazoline Ligands: Catalyst Intermediates and Degradation Products - Crystal Structure of Bis[{2,(2'-oxazolinyl)phenolato}bis(1-methylimidazole)manganese(III)] Perchlorate. (2002) (12)
- New ring-opening metathesis polymerization catalyst based on a five-coordinate tungsten(VI) alkylidene complex containing an ortho-chelating arylamine ligand; X-ray structure of [W{C6H4(CH2NMe2)-2}(NPh)(CHSiMe3)(CH2SiMe3)] (1992) (12)
- An alternating chain of spider-like tris(peptides) stabilized by stacking and by N-H...N and N-H...O=C hydrogen bonding (2005) (12)
- CRYSTAL-STRUCTURE AND REACTIVITY OF C4PH4TICL3.MG2CL3(THF)6, A NEW TYPE OF ORGANOMETALLIC COMPLEX (1984) (12)
- A reversible solid-solid phase transition Z '=1 to Z '=6 in [Ni(OAc)(PNPtBu)]OTf (2009) (12)
- DIMERIC AND MONOMERIC CHROMIUM(II) AND MONOMERIC CHROMIUM(III) ARYLS - CRYSTAL-STRUCTURE OF PYRAMIDAL MZ2CR(PY) (MZ = ORTHO-ME2NCH2C6H4, PY = PYRIDINE), DIMERIC [(ME2NC6H4)2CR]2, AND OCTAHEDRAL (ME2NC6H4)3CR (1992) (12)
- Open-shell organometallic [MII(dbcot(bislutidylamine)]2+ complexes (M = Rh, Ir): unexpected base-assisted reduction of the metal instead of amine ligand deprotonation (2011) (11)
- 1,3-Dipolar cycloaddition to the Fe-N:C fragment. 11. Isocyanide-controlled change between a reversible molecular self-assembly of three components, including a unique isocyanide deinsertion, and dimethyl maleate coupling reactions (1993) (11)
- Glycine coupled to a bis(imidazole): a tetradentate ligand rendering dinuclear copper(II) compounds through ligand sharing (1998) (11)
- The twinned structure of the μ-isopropoxidodiisopropoxido(p-tolylimido)vanadium(V) dimer, twin refinement against CCD area-detector data (1999) (11)
- A Unique Asymmetric [Mn] Triple-Stranded Helicate from a Symmetric Pentadentate Ligand (2001) (11)
- A novel aryllithium · lithium bromide complex containing an anionic pentadentate organylpolyamine system enfolding two lithium centres (1993) (11)
- Structure of {2,6‐bis[(dimethylamino)methyl]phenyl}dichloroiron(III), [Fe(C12H19N2)Cl2] (1985) (11)
- Preparation and Properties of Carbonyliron Complexes of 1-Aza-4-oxa-1,3-butadiene (α-Imino Ester). X-ray Crystal Structures of Fe(CO)2(σ(N): σ(C)-i-PrN(H)C(H)C(O)OEt)2 and Fe(CO)2(σ(N): σ(C)-i-PrN(H)C(H)C(O)OMe)(i-PrNC(H)C(O)O) (2000) (11)
- HYDROGEN BONDING AND CONFORMATIONAL ANALYSIS OF CHELATE-STABILIZED ALKOXOPALLADIUM(II) COMPLEXES DERIVED FROM AMINO ALCOHOL LIGANDS (1997) (11)
- SYNTHESIS AND X-RAY STRUCTURE OF THE 1ST DINUCLEAR HOMOLEPTIC CHROMIUM(II) AMIDE, ([I-PR)2N]CR[MU-(I-PR)2N])2 (1989) (11)
- Application of a base-induced [1,2]-rearrangement to synthesize thiophosphonate bidentate S(sp2)–N monoanionic ligand: Characterization of its silver and palladium complexes (2009) (11)
- The coordination of divalent transition metal ions to a sterically constrained chelating pyrazole derivative. The crystal and molecular structure of bis(azido)(2,5-bis(3′,5′-dimethylpyrazol-1′-ylmethyl)-2,5-diazahexane)nickel(II), [Ni(C16H28N12)] (1985) (11)
- MONOCYCLOPENTADIENYLZIRCONIUM AND MONOCYCLOPENTADIENYLHAFNIUM ALKYLS - SYNTHESIS, HYDROGEN-TRANSFER REACTIONS, AND CATALYTIC FEATURES IN THE REACTIVITY WITH ALPHA-OLEFINS - X-RAY STRUCTURE OF CPZR(ETA-4-BUTADIENE) (1,2-BIS(DIMETHYLPHOSPHINO)ETHANE CL (1990) (11)
- 1,3-Dipolar Cycloaddition to the Fe-O=C Fragment 19. Synthesis and Properties of Fe(CO)2(PR3)(R1N=C(R2)-C(R3)=O) and Fe(CO)(Ph2PCH2CH2PPh2)-(R1N=C(R2)-C(R3)=O) and their Reactivity towards Dipolarophiles. X-ray Crystal Structure of the Initial Bicyclo[2.2.1] Adduct. (2002) (11)
- New nickel complexes with an S4 coordination sphere; synthesis, characterization and reactivity towards nickel and iron compounds (2004) (11)
- Oxime-substituted NCN-pincer palladium and platinum halide polymers through non-covalent hydrogen bonding (NCN = [C6H2(CH2NMe2)2-2,6]−) (2008) (11)
- Diastereoselective self-assembly of chiral diamine-chelated aryllithiums to dimeric aggregates. (2004) (11)
- Self-assembly of a [2 x 2] hydrogen bonded grid (1999) (11)
- Linear and branched phospha[n]triangulanes. (2005) (11)
- Generating and dimerizing the transient 16-electron phosphinidene complex [Cp*Ir=PAr]: a theoretical and experimental study. (2004) (11)
- The Presence of [Ar2Cu]- and [(RC⋮C)2Cu]- Homocuprate Moieties in the Neutral Mixed Cuprate [Cu2Li2(C⋮CR)2Ar2] (Ar = C6H4{CH2N(Me)CH2CH2NMe2}-2; R = C6H4Me-4 or C6H4SiMe3-4) (2003) (11)
- X-ray crystal structure and hydrocarbon solution dynamics of dimeric 1,1-bis[(dimethylamino)methyl]-2-propyllithium (1989) (11)
- Trapping of three-center Ir-Sn-X intermediates in the reaction of IrI(C6H4(CH2NMe2))-2(COD) with (organo)tin(IV) halides. X-ray structure of [2-(Me2NCH2)C6H4](COD)Ir(Br)SnMe2Br (1988) (11)
- Synthesis of Arylplatinum(II) Complexes with Chiral Monoanionic Aryldiamine ligands. The X-ray Crystal Structure of)[(1R)2,6bis{1(dimethylamino)propyl}phenyl]chloroplatinum, (1998) (11)
- Unique chains of alternating octahedral and tetrahedral cobalt(II) sites: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH)2]n and [{Co4(μ-Cl)6Cl2(thf)4(H2O)2}·2THF]n (2000) (11)
- On the structure of cross-conjugated 2,3-diphenylbutadiene (2007) (11)
- Reactions of metal carbonyl complexes with monoazadienes. 8. Regio- and diastereoselective carbon-carbon coupling of two .eta.3-allyl fragments on a tetranuclear ruthenium chain complex (1991) (11)
- Phosphinidene reactivity toward unsaturated phosphorus heterocycles (2001) (11)
- Changes in magnetic properties from solid state to solution in a trinuclear linear copper(II) complex (2007) (11)
- 9,10-Dimetallatriptycenes of group 14: a novel synthetic approach from ortho-phenylenemagnesium. (1996) (11)
- Organometallic Zwitterions: Arylpalladium(II) (Pincer) Complexes with a Tethered Sulfato Group as para-Substituent (2005) (11)
- Reactivity of mixed cyclometallated palladium compounds containing the [2-Me2NC6H4C(H)SiMe3] monoanion. Transmetallation reactions and formation of a novel m-alkylidene compound (X-ray) (di-m-chloro)bis{m-C,s-N-[2-(dimethylamino) benzylidene](m-chloro)(diethyl sulfide)dipalladium(II)} (1986) (11)
- NOVEL ASYMMETRIC TRIPODAL IMIDAZOLE-CONTAINING LIGANDS FORMING DINUCLEAR COPPER COMPOUNDS THROUGH LIGAND SHARING (1995) (11)
- THIOCROWN ETHERS CONTAINING THE THIOACETAL LINKAGE - TOWARD FUNCTIONALIZATION OF THE MOLECULAR PERIPHERY - MOLECULAR-STRUCTURE OF 1,3,6,10-TETRATHIACYCLODODECANE - A NOVEL MACROCYCLIC THIOETHER CONTAINING METHYLENE, PROPYLENE, AND ETHYLENE BRIDGES (1993) (11)
- alpha-Tris(2,4-pentanedionato-kappa(2)O,O')aluminum(III) at 240, 210, 180, 150 and 110 K: a new delta phase at 110 K. (2007) (10)
- Stereochemical Aspects of Enantiopure and Racemic Organolithium Aggregates Li4Ar4 {Ar=C6H4[CH(Me)NMe2]-2} (2004) (10)
- X‐ray Crystal Structures and Some Solution Structures of Lithium Amides with Intramolecular Complexation of Lithium by Tertiary Amide Groups (1999) (10)
- Molybdenum (VI) Bis(imidoaryl) Complexes Containing the Bis (amonimethyl)aryl 'Pincer' Ligand (1999) (10)
- Structure of N,N'-di-tert-butylethanediimine, C10H20N2, at 98 K and comparison with the geometry calculated by molecular mechanics (1985) (10)
- CC coupling and CH activation occurring in reactions of FeRu(CO)6(iPr-Pyca) (ipr-PycaC5H4N-2-CHN-iPr) with activated alkynes RCCR′ (RR′C(O)OMe; RH, R′C(O)Me) (1993) (10)
- Palladium(II) Arenethiolates with Chelating Diamines: Formation of N-H.S Hydrogen Bonds with Protonated N,N,N',N'-Tetramethylethylenediamine. (1996) (10)
- Stereochemical influence of the ligand on the structure of manganese complexes: implications for catalytic epoxidations. (2005) (10)
- Interaction of diphenylzinc with 1,3-xylyl crown ethers. Crystal structures of three 1:1 complexes (1991) (10)
- New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization. (2005) (10)
- Stereoselective oxidative-addition reactions of dihalogens and copper(II) halides to square-planar organoplatinum(II) complexes containing hard N and C donor atoms. Molecular structures of [bc,de-bis(8-dimethylamino-1-naphthyl)]-af-diiodoplatinum(IV) and ab-dibromo[cf,de-bis(8-dimethylamino-1-naphth (1991) (10)
- Synthesis of cyclometalated aryltantalum(V) complexes: Amine C-H activation via [sigma]-bond metathesis (1993) (10)
- Low-temperature triphenylmethane (1996) (10)
- Self-Assembly of p-Nitro NCN-Pincer Palladium Complexes into Dimers through Electron Donor−Acceptor Interactions (2003) (10)
- 1,3-Dipolar Cycloaddition Reactions to the C:X-M Fragment. 15. Reaction of Ru(CO)3(i-Pr-DAB) with the Electron-Deficient Alkenes Dimethyl Maleate and Dimethyl Fumarate. CO Substitution versus 1,3-Dipolar Cycloaddition (1995) (10)
- Synthesis and crystal structure of the tetranuclear organozinc compound diethyltetrazinc hexakis(N-phenylmethylcarbamate).2 benzene (1978) (10)
- Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue (2014) (10)
- CRYSTAL AND MOLECULAR STRUCTURE OF 1,1,2,2-TETRAKIS(PENTACARBONYLMANGANIO)-1,2-DIBROMODITIN, A TRANSITION METAL SUBSTITUTED DITIN COMPOUND (1976) (10)
- C-C bond insertion of a complexed phosphinidene into 1,6-methano[10]annulene. (2004) (10)
- The structure of bis[(R,S)-N,N'-bis(5-methyl-2-thienylmethylene)-1,2-cyclohexanediamine]copper(I) trifluoromethanesulfonate, C36H44CuN4S4+.CF3SO3− (1985) (10)
- Synthesis of Alkynyl-Substituted 9,10-Dimetallatriptycenes of Group 14 and Their Application in the Preparation of a Novel Class of Organometallic Oligomers. (1998) (10)
- catena-Poly[[dicyanamido(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)copper(II)]-μ-dicyanamido-κ2N1:N5] (2002) (10)
- A triclinic modification of triphenylphosphine (1998) (10)
- Synthesis and Structure of ortho‐Phenylenezinc (1996) (10)
- 1,3-Dipolar cycloaddition to the FePN=C fragment. 17. Diastereoselectivity with C2- and non-C2-symmetric chirally N-substituted a-diimine ligands, R*PN=C(H)PC(R')=NPR* and C5H4N-2-C(R')=N-R*, with dimethyl acetylenedicarboxylate (DMAD) and methyl propios (1996) (10)
- Ligand substitution reactions in new square-planar iridium, rhodium and platinum complexes containing a potentially terdentate C,N,N′ ligand system; crystal structure of [Ir{C6H4CH2N(Me)CH2CH2NMe2-2-C,N,N′}(cod)](cod = cycloocta-1,5-diene) (1994) (10)
- Ruthenium-to-Platinum Interactions in η6,η1 NCN-Pincer Arene Heterobimetallic Complexes: An Experimental and Theoretical Study (2010) (10)
- Reinvestigation of the Structure of Ammonium Hydrogen D-Tartrate (1987) (10)
- 1,3-Dipolar cycloaddition reactions to the C=X-M fragment. IX: Synthesis and characterization of mononuclear imino ketone complexes Fe(CO)3(t-Bu-N=C(H)-C(R)=O) and their use in chemoselective cycloaddition reactions with dimethyl acetylenedicarboxylate resulting in the formation of Fe(CO)3(butenolid (1993) (10)
- (2,2'-Bipyridyl-N,N')dibromopalladium(II) (1997) (10)
- Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate (2007) (10)
- Novel Complexes cis,cis-[Rh(R2)(I)(dmb)] (R=Me, iPr; dmb=4,4'-dimethyl-2,2'-bipyridine): Synthesis, Structure and Photoreactivity (2001) (9)
- Linear homobimetallic 4-thioacetyl-substituted NCN pincer palladium(II) and platinum(II) complexes with N-bidentate connecting units (NCN = [C6H2(CH2NMe2)2-2,6-R-4]-) (2008) (9)
- Insertion of norbornene into aryl–palladium(II) bonds: mechanistic aspects of the subsequent C–H activation (1992) (9)
- Chiroptical properties of 12,15-dichloro[3.0]orthometacyclophane—correlations between molecular structure and circular dichroism spectra of a biphenylophane (1999) (9)
- Synthesis and crystal structure of the new mixed metal mixed ligand cluster compound Zn4Ni2(C5H5)4(C5Me5)2 (1989) (9)
- Transmetalation reactions with nitrogen-containing 'pincer' -class ligands on platinum(II) centers (2001) (9)
- (μ‐Methylene)bis(methylzirconocene): Preparation, Molecular Structure, and Thermal Disproportionation (2004) (9)
- Extended structures based on hydrogen bonding and π-π interactions: [synthesis and characterization of two zinc complexes: [Zn(dap)Cl2] and [Zn(dap)2Cl2]. (2004) (9)
- Dimethyl fumarate (2004) (9)
- Synthesis and properties of complexes Fe(Co)2(CNR)(1, 4-diaza-1, 3-butadiene) obtained by heterogeneously (Pd/C) catalyzed substitution of a CO by an isocyanide ligand. Crystal structure of Fe(Co)2(t-BuNC)(N, N′-p-tolyl- 1, 4-diaza- 1,3-butadiene) (1992) (9)
- The Chelating Ligand 1,3‐Bis(pyrazol‐1′‐yl)propane (Bpp) Enforces a Tetrahedral Geometry in Both CuII and CuI Species (2003) (9)
- Langmuir-Blodgett mono- and multilayers of rodlike oligo(cyclohexylidene) derivatives bearing an oxime headgroup. (1996) (9)
- Oxidative addition reactions of bis-aryl cyclometallated platinum(II) compounds with mercury(II) carboxylates. X-Ray crystal and molecular structure of the binuclear platinum–mercury compound rac-a-(µ-acetato-O,O′)-b-(O-acetatomercurio)-cf,de-bis[2-(dimethylaminomethyl)-phenyl-N,C]platinum (1980) (9)
- Rhodium aryloxide complexes containing terdentate nitrogen ligands, C-O bond formation, hydrogen bonding with phenol and oxidative addition reactions. Molecular structure of an Rh(III)-acetyl complex (1998) (9)
- Mixed alkali systems: Dietzels theorem, X-ray structure, hygroscopicity, and 29-Si MAS NMR of NaRbSi2O5 and NaCsSi2O5 (2000) (9)
- Synthesis and dynamic behaviour of new metallo-based sterically overcrowded alkenes (1996) (9)
- Isocyanide Insertion into the Palladium-Carbon Bond of [PdMe(L-L)Cl] Complexes and the Reactivity of the Products toward Norbornadiene; X-Ray Crystal Structure of [Pd{C(=NCC6HC3MeC2-2,6)Me}(bpy)Cl] {L-L = bpy or phen] (1995) (9)
- Synthesis, Crystal Structure, Spectroscopic and Magnetic Properties of an Unprecedented Three-Dimensional CuII Coordination Compound of 1,2-Bis(1,2,4-triazol-4-yl)ethane (2000) (9)
- α-Tris(2,4-pentanedionato-κ2O,O’)-chromium(III) at 290 and 110 K: a new δ phase at 110 K (2007) (9)
- Synthesis of a tri(organoplatinum) complex via the double directed lithiation of a mono(organoplatinum) precursor (1996) (9)
- Study on the isomerism in meso-amavadin and an amavadin analogue. (2007) (9)
- A thermally stable nickel(II) metalloformate and its platinum(II) analogue (1984) (9)
- Reactions of monoazadienes with metal carbonyl complexes. 13b. Influence of heteronuclearity on the dimerization of HFeRu(CO)5{RC:C(H)C(H):NPr-iso+} and the synthesis of heterotetranuclear chain complexes (1993) (9)
- A Unique Dinuclear CuII Compound with Two Phase Transitions Clearly Visible from Thermal and Magnetic Behaviour; Synthesis, Magnetism and X-ray Structures at Three Temperatures of Bis(di-2-pyridylamine)bis(μ-hydroxo)bis(μ-perchlorato-O,O)dicopper(II) (2002) (9)
- ISOLATION AND X-RAY STUDY OF A HOST-GUEST COMPLEX OF AN AMINO-ACID ESTER SALT AND A SIMPLE ACYCLIC LIGAND DERIVED FROM TRIPHENYLPHOSPHINE OXIDE (1979) (9)
- FUNCTIONALIZATION OF 1,3-PHENYLENE-16-CROWN-5 VIA DIRECT LITHIATION (1996) (9)
- Pyridinediols as HCI receptors; formation of an unusual pyridine·HCI complex in conjunction with the preparation of Lewis acidic titanium(IV) centres (1993) (9)
- Reactions of monoazadienes with metal carbonyl complexes. 17. Photochemically induced reversible carbon monoxide insertion into ruthenium-amido bonds (1993) (9)
- A Simple Building‐Block Route to (Phosphanyl‐carbene)palladium Complexes via Intermolecular Addition of Functionalised Phosphanes to Isocyanides (2009) (9)
- 1,4-Addition eines terminalen Phosphiniden-Komplexes an [5]Metacyclophan. (1998) (9)
- The crystal and molecular structure of polymeric [(dineopentylmagnesium)2 · (neopentylmagnesium bromide)2]n: an unsolvated alkylmagnesium species (1989) (9)
- Isolation and crystal structure (130 K) of the first example of an η1-O coordinated sulphine-metal complex: SnMe2Cl2[η1-O-{Me(Ph)NC(Ph)SO}] (1985) (9)
- Self-assembling of bis-ortho chelated diaminobenzyl- (NC′N) and butyl-lithium units to give 2:2 mixed alkyllithium aggregates (NC′N)Li2Bu2Li2(NC′N) with a ladder structure (1997) (9)
- Towards organometallic conducting polymers containing bis-cyclometallating bridging ligands (1994) (9)
- Hydrogenation of [5]- and [6]Metacyclophane: Reactivity and Thermochemistry (2000) (9)
- Synthesis and X-ray crystal structures of two novel dinuclear methoxo-bridged hexafluoropentanedionato Er(III) complexes with 1,10-phenanthroline and 2,2′-bipyridine (2000) (9)
- Cobalt(II) aldoxime complexes stabilised by halide hydrogen bonding: crystal structures of [Co{HONC(H)(Me)}4X2] (X = Cl or Br) and [Co{HONC(H)(Pr)}4Cl2] (2001) (9)
- Heterosite Effects in Novel Heteronuclear Clusters [Os2Ru(CO)11(PPh3)] and [Os2Ru(CO)10(2‐acetylpyridine‐N‐isopropylimine)] (2005) (8)
- Crystal structure and magnetic properties of a μ-halogeno-bridged copper(II) chain with neutral planar [Cu(batt)Cl] units (Hbatt = 1,3-bis[3-(5-amino-1,2,4-triazolyl)]triazene) (1997) (8)
- Structure of {2,3,5,6‐tetrakis[(dimethylamino)methyl]phenyl‐C,N,N'}lithium dimer (1987) (8)
- The occurrence of through-bond orbital interactions in an α,ω donor–acceptor substituted bi(cyclohexylidene) and bi(cyclohexyl). X-Ray diffraction, UV–Vis absorption and photoelectron spectroscopy, ab initio SCF-MO and natural bond orbital analyses (2001) (8)
- Structure of dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II) dichloromethane solvate (1987) (8)
- Preparation and crystal structure of [μ-Ni(C5H5)P(C6H5)3] [μ-C5H5] [ZnC5H5]2, a nickel-bridged cyclopentadienylzinc dimer (1985) (8)
- ISOLATION AND X-RAY STUDY OF A HOST-GUEST COMPLEX OF AN AMINO ACID ESTER SALT AND A SIMPLE ACYCLIC LIGAND DERIVED FROM TRIPHENYLPHOSPHINE OXIDE (1979) (8)
- Investigations of a highly crowded phosphino‐substituted biphenyl: A precursor for a λ3, λ5‐diphosphaphenanthrene (1991) (8)
- The synthesis and properties of Pt2→M (M=Ag(I), Hg(II)) adducts of Pt2{o-C6H4P(Ph)(CH2)3PPh2}2 with Ag(O2CCF3), HgCl2 and Hg(O2CCF3)2. X-ray crystal structure of [Pt2{o-C6H4P(Ph) (CH2)3PPh2}2Hg(O2CCF3)2] (1992) (8)
- Chiral ortho-Palladated and -Platinated Arylphosphite Complexes (2009) (8)
- Synthesis and structure of side chain haloallenes in the steroid series (1984) (8)
- Crystal structures, electrical conductivity and band-structure calculations of three new [cation][Ni(C3S5)2]2 compounds (1992) (8)
- Thermally stable aryltungsten(VI) oxo and phenylimido complexes containing phenyl ligands with ortho-chelating tertiary amine substituents: molecular structures of W[(R)-C6H4CH(Me)NMe2-2]Cl3(:O) and W(C6H4CH2NMe2-2)Cl2(:NPh)(OCMe3) (1993) (8)
- Crystallographic and NMR evidence of the unusual N6,N7-didentate chelation of 3-methyladenine coordinated to the cytotoxic -dichlorobis(2-phenylazopyridine)ruthenium(II) complex † (2002) (8)
- A new type of tungsten(VI) phenylimido alkylidene complex and its triorganotungsten precursor with an O,N-chelating ligand; molecular structures of [W(CH2SiMe3)3(NPh){OCPh2(2-py)}] and [W{CHSiMe3(CH2SiMe3)(NPh){OCPh2(2-py)}](py = pyridine) (1993) (8)
- cis, trans - or both: Steric bulk determines coordination mode of dimeric palladium complexes with bridging pyridine-phosphane ligands (2008) (8)
- Structure of the luminescent Ca4K2(CrO4)5 · 2H2O crystal (1996) (8)
- 2,6-Bis[(dimethylamino) methyl]phenylsodium: the first trimeric organosodium compound (1995) (8)
- Synthesis, Structure, and Properties of an Intramolecularly Coordinated Diindacycle: 9,10-Dihydro-9,10-bis[2,6-bis((dimethylamino)methyl)- phenyl]-9,10-diindaanthracene (1997) (8)
- Synthesis, Solid-state and Solution Structures of Bis{N,NE'-bis[2-thienyl)methylene]-1,2-diaminoethane}-silver(I) and -copper(I) Trifluoromthanesulfonate Complexes (1995) (8)
- {1,2‐Bis[N‐(4‐methylphenyl)imino‐N]acenaph‐thene}(η2‐maleic anhydride)palladium(0) (1997) (8)
- Synthesis of electron-rich platinum centers: Platinum0(carbene)(alkene)2 complexes (2005) (8)
- 1,3-Dipolar cycloaddition to a FeN=C fragment XII °. Reactivity of Fe(2,6-xylyl-isocyanide)3 (iPr-α-diimine) towards heteroallenic C=S bonds (1994) (8)
- Structure of KLiSi2O5 and the hygroscopicity of glassy mixed alkali disilicates (1996) (8)
- Copper(I) and silver(I) ions in unusual poly donor-atom environments; X-ray crystal and molecular structures of [M{(R)(S)-1,2-(5-Me-thiophene-2-CHz.dbnd;N)2-cyclohexane}2](O3SCF3), M = CuI or AgI (1983) (8)
- Magnetism and structure of copper(II) co-ordination compounds. X-Ray structure determination of trans-dichlorobis(N-methylimidazole)copper(II) (1979) (8)
- An unexpected dinuclear zwitterionic PtII cation [Pt2{C6H3(CH2NHMe2)2-2,6}2I4]2+ and alcohols from the reaction of an aryl(diamine)(aquo)PtII complex with alkyl iodides; X-ray and n.m.r. studies (1989) (8)
- Olefin‐Cycloaddition des elektrophilen Phosphinidenkomplexes [iPr2N−P=Fe(CO)4] (1999) (8)
- Structure of a,b,c,j,k,l-hexaaqua-d,e,f,g,h,i-hexakis[μ-(4-ethyl-1,2,4-triazole-N1,N2)]trizinc(II) hexakis(trifluoromethanesulphonate), [Zn3(C4H7N3)6(H2O)6][CF3SO3]6 (1983) (8)
- Bis(cyclooctene)copper(I) trifluoromethanesulfonate (1987) (8)
- TANTALACYCLOBUTANE COMPLEXES CONTAINING THE POTENTIALLY C,N,N'-COORDINATING LIGAND C6H4(CH2N(ME)CH2CH2NME2)-2- (CNN) AND THEIR REACTIVITY WITH CARBON MONOXIDE AND TERT-BUTYL ISOCYANIDE. X-RAY MOLECULAR STRUCTURES OF TACH2CH(M E)CH2-1,3(CNN)(O-T-BU)2, TACH2CH(PH)CH2-1,3(CNNO)(O-T-BU)2, AND TAC(=N-T-B (1997) (8)
- Reactivity of the linear tetranuclear ruthenium cluster Ru{sub 4}(CO){sub 10}[CH{sub 3}C=C(H)C(H)=NC(H)(CH{sub 3}){sub 2}]{sub 2} toward CO. Regioselective aliphatic C-H activation processes and the X-ray crystal structure of Ru{sub 2}(CO){sub 6}[CH{sub 3}CC(H)C(H)N=C(CH{sub 3}){sub 2}] (1992) (8)
- 1,2-Dimetalated Benzene Derivatives (1,2-C6H4MCH3)n of Group 13 (M = Al, Ga, ln) (1999) (8)
- The nickel(II) complex of a new multidentate ligand containing both imidazole and pyrazole moieties (1999) (8)
- Synthesis, coordination chemistry, and metal complex reactivity of (dimethylamino)methyl-substituted triarylphosphanes; X-ray study on [AuCl(PPh3-nArn)] (Ar = 1-C6H3(CH2NMe2)2-3,5, n = 1, 3; Ar = 1-C6H4(CH2NMe2)-4, n = 3) (2006) (8)
- Methylene-azaphosphirane as a reactive intermediate. (2005) (8)
- Intra-annular reactions of the (1,3-xylylene)-18-crown-5 system: synthesis and crystal structure of [2-(bromomagnesio)-1,3-xylylene]-18-crown-5, [2-(bromomercurio)-1,3-xylylene]-18-crown-5 and bis[(1,3-xylylene-18-crown-5)-2-yl]mercury (1993) (8)
- Novel reactions of substituted 1-aza-4-oxobutadienes )(a-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuN=C(H)-C(Me)=O system and X-ray crystal structure of [EtZn(Et)(t-Bu)NC(H)=C(Me)O]2 (1983) (8)
- Crystal and molecular structure of SnMePh[C10H5(OMe-5)(CH2NMe2-8)]Br and proton nuclear magnetic resonance study of the puckering of the chelate ring in five-co-ordinate triorganotin halides SnRR′-[C10H5(OMe-5)(CH2NMe2-8)]X and SnRR′[CH2C6H4(CH2NMe2-2)]X (1980) (8)
- Self-assembling chiral metallo-clefts; synthesis and molecular structure of N,N′-bis(12H-benzo[α]xanthen-12-ylidene)-1,2-ethanediamine zinc(II)-dichloride complex (1993) (8)
- Template-Directed Synthesis of Macroheterocycles by Ring-Closing Metathesis of Olefin-Substituted Pyridines in the Coordination Sphere of a Triplatinum Complex (2003) (8)
- Enantioselective synthesis of a chiral intermediate for aztreonam and related monobactam antibiotics (1990) (8)
- Structure of dioxo[2‐(salicylidenamino)phenolato(2‐)‐O,N,O'][tris(dimethylamino)phosphine oxide]tungsten(VI) (1990) (7)
- Synthesis and characterisation of ruthenium carbonyl complexes with cyclometallated ligands derived from senecialdimine (1997) (7)
- Acetylene-Substituted Phosphane Oxides: Building Blocks for Macrocycles (2007) (7)
- Structure of merohedrally twinned di-μ-fluoro-bis[tris(3,5-dimethylpyrazole-N2)coppper(II)] bis(tetrafluoroborate) (1987) (7)
- Synthesis and Anomalous Structure-Reactivity Relationship of 8,11-Dichloro[5]metacyclophan-3-one (2001) (7)
- 1,3-Dipolar cycloaddition to the FeNC fragment XVI. Reactivity of Fe(alkyl-NC)3(iPr-DAB) complexes towards aromatic isothiocyanates as dipolarophiles. Insertion of isothiocyanate into the FeN bond (1996) (7)
- Reactions of monoazadienes with metal carbonyl complexes. 13a. Carbon-hydrogen bond-making and -breaking processes in heteronuclear monoazadienyl complexes: reactivity of HFeRu(CO)5{RC:C(H)C(H):NPr-iso} toward CO (1993) (7)
- Diastereoselective Condensation Reactions with an Easily Accesible Intramolecularly Coordinated Zinc-Enamine : Molecular Structure of a Self-Assembled Polymer of Diethylzinc and Zinc-Aldolates (1993) (7)
- 9,10-Dimetallatriptycenes of Group 14: a structural study. (1998) (7)
- Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [NC-4-C6H2(CH2NMe2)2-2,6]−) (2008) (7)
- Alkylation of the SCS linkage. Towards lipophilic mono‐ and ditopic heavy‐metal receptors containing trithiane building blocks. Molecular structure of cis‐2,4,6‐tribenzyl‐1,3,5‐trithiane (1993) (7)
- 1,3-Dipolar cycloaddition to the CXM fragment 13. Regioselectivity in the reactions of mononuclear iminoketone complexes Fe(CO)3(tBu-NC(H)C(R)O) (R Ph, Me) with the asymmetric alkyne methyl propynoate (1994) (7)
- Synthesis and X-ray structure of the chiral, polydentate cation binder N-[N-[(5-methyl-2-thienyl)methylidene]-L-methionyl]histamine (1991) (7)
- Infinite, undulating chains of intermolecularly hydrogen bonded (E,E)-2,2-dimethylcyclohexane-1,3-dione dioximes in the solid state. A single crystal X-ray, charge density distribution and spectroscopic study (2000) (7)
- 1,4-Addition of a Phosphinidene Complex to Cisoid 1,3-Dienes (2000) (7)
- Synthesis, structure and Co–C bond homolysis of an intramolecularly bridged (tetrahydrofurfuryl)cobalt(salen) complex: a simple model of enzyme-bound coenzyme B12 (1998) (7)
- Synthesis of the monohydride complexes HRu2(X)(CO)5(iPr-NCHCHN-iPr) (X=Cl, I); hydrogenation of the central CC bond of the coordinated α-diimine ligands. X-ray. single crystal structure of HRu2(Cl)(CO)5(iPr-NCHCHN-iPr) (1993) (7)
- Eta3-diphosphavinylcarbene: a P2 analogue of the Dötz intermediate. (2009) (7)
- Synthesis and Structural Studies of Two New Base Adducts of Bis(2,4‐pentanedionato)cobalt(II) (2004) (7)
- A novel ruthenium(III) complex with a tridentate dianionic P,O,O-ligand showing high cytotoxic activity. (2009) (7)
- Synthesis and X-ray crystal structure of 2-(methoxymethyl) phenyldicyclopentadienyltitanium(III) (1997) (7)
- Structure of tetrakis[μ3‐(4‐methoxy‐2‐butyl)‐O,μ3‐C2]tetralithium, [Li4(C5H11O)4] (1984) (7)
- Fused tricyclic phosphiranes--analysis of phosphorus chemical shieldings. (2008) (7)
- Facial triad modelling using ferrous pyridinyl prolinate complexes: synthesis and catalytic applications. (2014) (7)
- Synthesis, spectroscopy, magnetism, and X-ray structures of hexakis(1-(2-chloroethyl)-tetrazole-N4)copper(II) salts (2001) (7)
- Heterobimetallic Fe-Pd and Fe-Pt NCN pincer complexes (NCN = [C6H2 (CH2NMe2)2-2,6]-) (2006) (7)
- Bridged (alkoxo)CoIII(salen) complexes: synthesis and structure (2002) (7)
- Bis[bis(2-pyridylcarbonyl)aminato]iron(III) perchlorate acetonitrile disolvate. (2006) (7)
- Reactions of monoazadienes with metal carbonyl complexes. 6. Synthesis, separation, and structural characterization (x-ray) of the two diastereomers of Ru3(CO)6[CH3C:C(H)C(H):N-iso-Pr]2, an acyclic trinuclear complex that is isolobally related to Cp2Ru. (1991) (7)
- Toward poly(aminophthalimide), structures of dimers and trimers (2007) (7)
- The intriguing substitution behavior of CO with bidentate phosphine ligands induced by a gem-dialkyl effect (2011) (7)
- Directed anisotropy in bis(acetato-kappa2O,O')diaquazinc(II) at 110 and 250 K. (2009) (6)
- Mixed Alkali Systems: Structure and ^29^Si MASNMR of Li~2~Si~2~O~5~ and K~2~Si~2~O~5~ (1998) (6)
- Synthesis and characterization of two new "pincer" complexes of zinc(II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{η3-NN'N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me) (2000) (6)
- Synthesis, crystal structure and magnetic properties of [Cu6(tidah)2Cl10(H2O)4]·6H2O [Htidah = 1,1,6,6-tetrakis-(imidazol-2-yl)-2,5-diazahexane], a unique imidazolato- and chloro-bridged hexanuclear copper(II) compound (1993) (6)
- Synthesis and crystal structure of [1,1,2,2-tetramethylguanidinium][Ni(dmit)2]2 and [hexamethylguanidinium][Ni(dmit)2]2 (dmit = 1,3-dithiole-2-thione-4,5-dithiolate). Intermolecular orbital overlap integral calculations and electrical conductivities (1996) (6)
- Synthesis and Characterization of Bis(arenethiolato)magnesium Complexes with Intramolecular Coordination. X-ray Structure of (Mg{S(C6H4-2-CH2NMe2)}2)2 (1996) (6)
- PHOTOINDUCED INTRAMOLECULAR CHARGE TRANSFER IN 4-DONOR, 4'-ACCEPTOR SUBSTITUTED DIMETHYLDIPHENYLSILANES (1995) (6)
- Binuclear metal carbonyl R-DAB complexes. Synthesis and spectroscopic properties of novel heterodinuclear a-diimine (R-DAB and R-Pyca) complexes, containing an asymmetric bridging hydride. Molecular structure of [(m-H)FeMn(CO)6 C5H4N-2-CH=N-t-Bu)] (1985) (6)
- Synthesis, crystal structure and electrochemical properties of [NBu4][Ni(mdt)2]: a potential precursor for new materials (mdt = 1,3-dithiole-4,5-dithiolate) (1998) (6)
- Structure of 1,2,5,6-tetramethyltricyclo[3.1.0.02,6]hexane-3,4-dione (1990) (6)
- A novel dinuclear ruthenium-1,8-naphthyridine catalyst for the oxidation of alcohols and the epoxidation of alkenes (1995) (6)
- Solid state structures in spin-coated assemblies of oligo(cyclohexylidene) oxime derivatives and (partly) saturated analogues : an atomic force microscopy study (1998) (6)
- Trapping of the highly strained [5](2,4)quinolinophane system (2007) (6)
- Transition metal complexes of ligands containing 3,5-dimethylpyrazolyl groups and thioether functions. The crystal and molecular structure of (1,12-bis(3,5-dimethylpyrazol-1-yl)-2,11-diaza-5,8-dithiadodecane)nickel(II)-bis(tetrafluoroborate) (1988) (6)
- Synthesis and Structure of cis-1,4-Di(1-pyrenyl)decamethylcyclohexasilane (2003) (6)
- X-ray structure of a molecular basket. Origin of its poor binding properties (1993) (6)
- Triple Proton Abstraction from a 1‐Methylallyl Ligand on Thermolysis: Formation of a Hf3(C4H4) Cluster (1988) (6)
- CRYSTAL STRUCTURE OF SOLVENT FREE [2-(DIMETHYLAMINOMETHYL)PHENYL]ALUMINIUM DICHLORIDE (1995) (6)
- Synthesis of the diphenylacetylene-based, tetra-amine ligand 1,2-bis(3,5-bis[(dimethylamino)methyl]phenyl)acetylene by palladium-catalysed cross-coupling: isolation and crystal structure of the catalyst trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide (2000) (6)
- Twinning by merohedry in cyclohexanone oxime: a revised structure. (2004) (6)
- 1,3-Dipolar Cycloaddition to the Fe¿X=C Fragment. 18. Chemoselectivity in the Addition of Activated Alkynes across the Fe¿O=C vs. the Fe¿N=C Fragment in Chelate (a-Iminoester)-tricarbonyliron Complexes. (2000) (6)
- Boric acid mediated preparation of mesocyclic thiocrown ethers containing xylylene units. Molecular structures of 3,8-dibenzo-1,6-di-thiacyclodecane and 2,5,8-trithia-(9)-p-benzenophane (1993) (6)
- O-Phenylenemagnesium tetramer: the first organomagnesium cluster (1991) (6)
- Structure and Magnetism of a New Dodecanuclear CuII Complex with Acetato and Imidazolato Bridges, Formed by Oxidation of the Chelating Ligand 1,1,7,7‐Tetrakis(imidazol‐2‐yl)‐2,6‐diazaheptane (2003) (6)
- Crystal and molecular structure of bis[(μ-benzotriazolato-N1,N2)methylmercury(II)] (1985) (6)
- Formation of Diphosphates. A NMR Study on the Mechanism and Stereochemistry of Diphosphate Formation from Chiral Dioxaphosphorinanes (2000) (6)
- Self‐assembly of a Novel trans‐Oxamidato‐bridged Copper(II) Compound with a Neutral Oxamidate‐Ester Ligand as a Spacer. Crystal Structure, Spectroscopy, and Magnetism of a Chain of Dinuclear Units (2003) (6)
- Structure of bis[N-(2-pyrrolylmethylene)-tert-butylamine]zinc(II), Zn(C9H13N2)2 (1983) (6)
- Synthesis, crystal structure, and spectroscopy of (azido-N1)bis(2,2′-bi-imidazoline)copper(II) perchlorate (2004) (6)
- Direct phase determination of triple products from Bijvoet inequalities (1977) (6)
- Dinuclear iron complexes of the tridentate ligand N ,N-bis(2-ethyl-5-methyl-imidazol-4-ylmethyl)aminopropane (biap) (2002) (6)
- C−N Bond Insertion of a Complexed Phosphinidene into a Bis(imine) − A Novel 2,3‐Sigmatropic Shift (2002) (5)
- Preparation and Properties of Carbonyliron Complexes of 1-Aza-4-oxa-1,3-butadiene (α-Imino Ketone) – X-ray Crystal Structures of Fe(CO)3[MeNC(Ph)C(Ph)=O] and Fe2(CO)4[tBuNC(H)(Me)C(O)(O)C(Me)C(H)=NtBu] (2000) (5)
- Resorcinarene cavitands as building blocks for cation receptors (1997) (5)
- Structure of iodo(methylthiomethylphenyl)bis(triphenylphosphine)palladium(II) (1987) (5)
- Synthesis and X-Ray Structure of a Novel Cavity-Containing Dinuclear Nickel(Ii) Complex (1993) (5)
- Titelbild: A Phosphorus Analogue of Bis(η4-cyclobutadiene)iron(0) (Angew. Chem. 17/2009) (2009) (5)
- Complex of (−)‐Morphine with β‐Phenylhydracrylic Acid (1998) (5)
- Tris[2-(2-oxazolin-2-yl)phenolato]iron(III). (2002) (5)
- γ-Tris(2,4-pentanedionato-k2O,O')aluminium(III) at 110 K (2006) (5)
- [η2-(E)-But-2-enedinitrile](N,N′-diphenyl-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-diimine-N,N′)palladium(0) (2001) (5)
- Palladium arenethiolates with intramolecularly coordinating nitrogen lewis bases (1996) (5)
- Absolute structure determination: pushing the limits. (2016) (5)
- Synthesis, X - ray crystal structure and reactions of dimethyl(N,N,N′,N′- tetramethylethanediamine)palladium† (2010) (5)
- The Extended PLATON/SQUEEZE Tool in the Context of Twinning and SHELXL2014 (2014) (5)
- The structure of the pyridine complex of dicylopentadienylcadmium (1987) (5)
- (3R,4S)-3-phenyl-1-[(R)-1-phenylethyl]-4-[(R)-1-phenylethyliminomethyl] azetidin-2-one. (2000) (5)
- Structure of bis(isothiocyanato)[N,N,N‐tris(1‐pyrazolylmethyl)amine]zinc(II) (1988) (5)
- Hydrogenation of the central carbon-carbon bond of coordinated .alpha.-diimine ligands of H2Ru2(CO)5(iso-PrN:C(H)C(R):Niso-Pr) (R = hydrogen, methyl), involving carbon-hydrogen and ruthenium-hydrogen bond-making and -breaking processes (1992) (5)
- Cobalt‐Assisted Condensation of 2‐Butanone Oxime and Acetone: Synthesis and X‐ray Structure of the Novel Acetaldiimine Complex [CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}] (2000) (5)
- X-ray crystal structure and hydrocarbon solution behaviour of tetrameric 2,2-Bis(methoxymethyl)-1-propyllithium (1990) (5)
- X‐Ray crystal structure of the ethylzinc enolate of 1‐(2,4‐cyclopentadienyl)‐2‐(diethylamino)‐1‐ethanone, the unexpected reaction product from cyclopentadienyl(ethyl)zinc and ethyl N,N‐diethylglycinate (2010) (5)
- Structure of di-μ-bromo-bis-μ-{1-[2-(dimethylamino)phenyl]-2-(4-methylphenyl)-1-propenyl-N,C}-tetracopper(I) (1987) (5)
- Nickel Thiolate Complexes as Ligands for Copper and Zinc: Novel Additions to a Library of Binding Modes (2006) (5)
- 3-(1-Hydroxyethylidene)-1-phenylpyrrolidine-2,4-dione (2001) (5)
- Structure of bis[N,N-bis(1-pyrazolylmethyl)amine]nickel(II) bis(tetrafluoroborate) (1988) (5)
- Synthesis and characterisation of muramic acid 1′,2-lactam-β-(1→4)-d-glucosamine derivatives related to repeating units of bacterial spore cortex (1998) (5)
- Synthesis and reactivity towards Ni(COD)2 of substituted dicyclopentadienylzinc compounds; crystal structures of zinc-nickel clusters Zn4Ni2(h5-C5H4t-Bu)4 (h1-C5H4t-Bu)2 and Zn4Ni2(h5-C5H4SiMe3)2(h3-C5H4SiMe3)2(h1-C5H4SiMe3)2 (1989) (5)
- The crystal and molecular structure of tricarbonyl(2,5-dihydrothiophene 1-oxido)iron, (CO)3Fe(C4H6OS) (1977) (5)
- Intraannular functionalization of the 1,3-phenylene-19-crown-6 system via bromine–lithium exchange (1999) (5)
- Bisphenolate iron(II) complexes with intramolecularly coordinating nitrogen Lewis bases (1999) (5)
- Palladium-Mediated Intramolecular C-N bond Formation between Tertiary amines and Alkenes (1994) (5)
- 2,6-di-tert-butylphenol revisited at 110 K. (2005) (5)
- The influence of chirality in the amide side chain on the carbonyl orientation in rotational isomers of 3-carbamoylpyridinium halides (1988) (5)
- Low-temperature structure of bicyclohexylidene, C12H20 (1994) (5)
- Synthesis, X‐ray Crystal Structure and Magnetism of [NiCl2{(bis(2‐benzimidazolyl)propane}]2 · (C2H5OH)2 – A Second Example of a Ferromagnetically Coupled Five‐Coordinated High‐Spin Dichloro‐Bridged Nickel(II) Dimer (1998) (5)
- A Tin(IV) Porphyrin with Two Axial Organometallic NCN-Pincer Platinum Units† (2007) (5)
- The solid state structures of ortho-lithio-β-(N,N-dimethylamino)ethoxybenzene and the corresponding sodium compound: a new type of organolithium tetramer and a first example of an organosodium hexamer (1996) (5)
- Structure of 2-hydroxy-(5-{[4-(2-pyridinylamino)sulfonyl]phenyl}azo)benzoic acid–N,N-dimethylformamide–H2O (1/0.5/n)(n∝2.25) (1990) (5)
- Selectivity in reductive elimination from dialkyl(aryl)palladium(IV) complexes, and the observation of benzyl halide transfer from palladium(IV) to palladium(II). The X‐ray structure of methyl(phenyl)(2,2′‐bipyridyl)palladium(II) (2010) (4)
- In Quest of the Double Rotaxane Formation of the Bis(coronand) (1,5),(2,4)‐Durenetetrayl‐bis(18‐crown‐5) with Organomagnesium Compounds (2004) (4)
- Synthesis and characterization of ruthenium ‘pincer’ complexes containing sulfur atom donor ligands. The X-ray crystal structure of [RuCl2(η3-NN′N)(SMe2)] (NN′N={2,6-(Me2NCH2)2C5H3N}) (1999) (4)
- Structure of bromo(trimethylsilylethynyl)bis(triphenylphosphine)palladium(II)–chloroform–dichloromethane (2/2/1) solvate (1987) (4)
- Bis[mu-3,3',5,5'-tetra-tert-butylbiphenyl-2,2'-diyl phosphonato(1-)]bis(acetonitrile)carbonylrhodium(I)] dichloromethane sesquisolvate (2004) (4)
- Bis[μ‐2‐hydroxy‐5‐methyl‐1,3‐bis(3‐oxido‐κO‐3‐phenylprop‐2‐enonyl‐κO)benzene]bis[(N,N‐dimethylformamide‐O)copper(II)] bis(N,N‐dimethylformamide) solvate (2002) (4)
- Bis[bis(pyrimidin-2-yl-κN)amine](dicyanamido-κN1)(trifluoromethanesulfonato-κO)copper(II) ethanol hemisolvate forms a hydrogen-bonded chain (2004) (4)
- The first intramolecularly co-ordinated aryl tantalum compounds with amine donors: synthesis and X-ray crystal structure of [Ta{C6H4CH(R)NMe2-2}(CH2Ph)2Cl2](R = H, Me) (1989) (4)
- A remarkable halogen‐zinc exchange reaction; X‐ray crystal structure of (2‐iodozincio‐1,3‐xylylene)‐15‐crown‐4 (1993) (4)
- Tetrakis(triphenylphosphine)silver(I) tetraphenylborate acetonitrile solvate (2000) (4)
- Structural Features and Dynamical Behavior of Heteroleptic trans-C,C-Bisaryl-Platinum(II) and -Palladium(II) Complexes (2005) (4)
- [N,N'‐Bis(2‐thiobenzylidene)‐1,2‐phenylenediaminato]nickel(II) (1997) (4)
- Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of 1 -I2 Organometallic "Pincer" Complexes of Platinum. X-ray Crystal (1999) (4)
- A Dinuclear Nickel(II) Compound: μ‐{N,N,N',N'‐Tetrakis[2‐(3,5‐dimethyl‐1‐pyrazolyl)ethyl]‐1,2‐ethylenediamine}‐bis[aqua(nitrato‐O,O')nickel(II)] Dinitrate Dimethanol Solvate (1996) (4)
- The remarkable crystal structure of the dimeric species [bis(ortho-anisyl)magnesium · THF]2 (1991) (4)
- Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents (2010) (4)
- Cover Picture: A Phosphorus Analogue of Bis(η4‐cyclobutadiene)iron(0) (Angew. Chem. Int. Ed. 17/2009) (2009) (4)
- SYNTHESIS OF 9, 10-DIMETALLATRIPTYCENES CONTAINING GROUP 15 ELEMENTS FROM ortho-PHENYLENEMAGNESIUM (1999) (4)
- Structure of 1,1,1,2,2-pentacarbonyl-μ-hydrido-μ-2η-[(Z,s-cis,Z)-N-isopropylcinnamylideneamino-μ-N,μ-Cγ]-diruthenium(Ru-Ru), HRu2(CO)5(C12H14N) (1991) (4)
- Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5. [Erratum to document cited in CA115(21):232313a] (1992) (4)
- Aggregation of [Cu(II)4] building blocks into [Cu(II)8] clusters or a [Cu(II)4]infinity chain through subtle chemical control. (2004) (4)
- Structure of calcium hydrogen triacetate monohydrate, CaH(C2H3O2)3.H2O (1984) (4)
- Diastereoselective formation of complexed methylenediphosphiranes (2008) (4)
- Crystal structure and spectroscopic study of bis{1,3-bis[3-(5-amino-1,2,4-triazolyl)]triazenido-N′4,N2,N″4}nickel(II) tetrahydrate (1999) (4)
- The isolation and X-ray structure determination of an active intermediate in the accelerated sulfur vulcanization of alkenes (1993) (4)
- Lipase-mediated resolution of octahydro-3,3,8a-trimethyl-1-naphthalenol, a key intermediate in the total synthesis of lactaranes and marasmanes (1999) (4)
- Bisxantphos: stereoselective synthesis and coordination behaviour of a new class of cyclic double bridged diphosphines (2011) (4)
- 2-(1-(Dimethylamino)ethyl)phenylpalladium(II) complexes 5-functionalized with fluorous silyl tails (2006) (4)
- Caesium–Lithium Phyllosilicate, Cs1.33Li0.67Si2O5 (1995) (4)
- Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)33](CF3SO3)2 (2000) (4)
- (5S)-3-oxo-4-oxa-endo-tricyclo[5.2.1.0(2,6)]dec-8-en-5-yl acetate. (2000) (3)
- cyclo‐Decakis(μ‐2,2‐diphenylacetato‐O,O′)dodecakis(μ‐methoxo)decairon(III)) mixed solvate (2002) (3)
- Reactivity of a cyclothiaphosphazene towards Grignard reagents. Crystal structure of the 1 : 1 adduct of the Bi(cyclothiaphosphazene)[NPMe(NSOPh)2]2 and benzene (1990) (3)
- Crystal structure of the mononuclear complex (Mn(mesalim)2Cl) and electrochemical studies of manganese complexes of the ligand Hmesalim (2005) (3)
- Hydrogen bonding in andrographolide: 3-{2-[decahydro-6-hydroxy-5-(hydroxymethyl)-5,8a-dimethyl-2-methylene-1-naphthalenyl]ethylidene}dihydro-4-hydroxy-2(3H)-furanone (1987) (3)
- Potassium sodium phyllosilicate, K1.33Na0.67Si2O5 (2005) (3)
- Reaction of (1,8-naphtalenediyl)magnesium with group 5 and 6 metallocene dichlorides. Formation and crystal structure of (ethasup5-Cp)Mo(PMEsub3)(ethasup3-6b-H-7,9a-dihydrocyclopent[a]acenaphtylen-7-yl) (1994) (3)
- Triphenylsilanol-4,4'-bipyridyl (4/1): the Z' = 4 polymorph revisited. (2013) (3)
- Trans-4,5-bis(2-pyridyl)norbornane: a bidentate nitrogen ligand with a potentially large bite angle (1998) (3)
- CRYSTAL AND MOLECULAR STRUCTURE, SPECTROSCOPY, AND MAGNETISM OF DIAQUOBIS(IMIDAZOLE)CATENA-μ-(SQUARATO-1,3)-NICKEL(II). A ONE-DIMENSIONAL POLYMER (1979) (3)
- Synthesis and reactivity of (thioamido S-oxide)(diene)rhodium(I) complexes. X-ray structure of Rh(I)[(p-Tol)(p-TolN)CSO](NBD) (1987) (3)
- {2,6-Bis[(dimethylamino-κN)methyl]-4-{[(2,5-dioxo-1-pyrrolidinyl)oxy]carbonyl}phenyl-κC1}(diiodine)iodidoplatinum(II) dichloromethane hemisolvate (2007) (3)
- Structure of a-chloro-b-dichloromethylstannio-[dc,ef-bis(8-dimethylamino-1-naphthyl)]platinum(IV) (1992) (3)
- The crystal and molecular structure of N‐mesitylbenzophenoneimine [N‐(diphenylmethylene)mesitylamine] (1979) (3)
- Phosphaspiropentene as a Transient Intermediate (2005) (3)
- A new monoclinic crystal phase of [Bu4N][Ni(dmit)2] (2002) (3)
- Structure elucidation of the unprecedented asymmetric bis-chelate complex [Pd(1,3-bis(di(o-methoxy-m-methylphenyl)phosphino)propane)2]2+ in the solid state and in solution. (2010) (3)
- cis‐Bis[N1,N2‐bis(trimethylsilyl)benzamidinato‐κ2N1,N2]chloro(4‐tolylimido‐κN)vanadium(V) (2001) (3)
- Aryltitanium(IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]−. The X-ray crystal structure of [TiCl2(CNN)(O-i-Pr)] (1997) (3)
- Zwitterionic pyrrolidine-2,2-diylbis(phosphonic acid) at 100, 150 and 293 K. (2000) (3)
- Nucleic acids in two dimensions : layers of base pairs linked by carboxylate (2007) (3)
- Phosphinidene Addition to Conjugated Allenes (2009) (3)
- Structure of bis[1,3‐bis(5‐methyl‐4‐imidazolyl)‐2‐thiapropane‐N,N,S]nickel(II) hexafluorosilicate pentahydrate (1988) (3)
- Polymorphs and pseudo-polymorphs of μ-oxo-bis{[N,N′-bis(salicylidene)propane-1,3-diamine]oxorhenium(V)} (2000) (3)
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- (2R,3R,5R)-2-[(2R,3aS,6aR)-2,3,3a,4,5,6a-Hexahydrofuro[2,3-b]furan-2-yl]-5-isopropenyl-2,3-dimethylcyclohexanone and (4aR,5S,7R)-5-isopropenyl-7,8,8-trimethyl-2,3,4,4a,5,6,7,8-octahydronaphthalene-4a-carbonitrile (2000) (2)
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- Copper(II) Bipyridine and Crown Ether-Bipyridine Complexes: X-ray Structures, Characterization, and Properties as Histamine Receptors (1996) (2)
- A Novel Type of Pt-C Interaction and a Model for the Final Stage in Reductive Elimination Processes Involving C-C Coupling at Pt; Synthesis and Molecular Geometry of [1,N,N′-η-2,6-Bis((dimethylamino)methyl)-toluene]iodoplatinum(II) Te (1978) (2)
- trans-Dichlorobis(tris{4-((dimethylamino)- methyl)phenyl}phosphine)platinum(II) (2005) (2)
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- Formation and isolation of huge cyclic oligomers: posycondensation of 1,5-bis(1-hydroxy-3,6,9-trioxanonyl) naphthalene and terephthaloyl chloride (1995) (2)
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- Non-merohedrally twinned mer-trichloro(dimethyl sulfoxide-κS)(1,10-phenanthroline)ruthenium(III) chloroform solvate, with Z′ = 6 (2005) (1)
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- Bis(μ-N-tert-butyl-2-{N-[2-(dimethylamino)ethyl]-N-methylamino}ethanaminato)dilithium(I) (2007) (1)
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- 17-Isopropyl-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthrene (2005) (1)
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- [2,6-bis(N-tert-butyliminomethyl)pyridine-κ3N](phenolato-κO)rhodium(I) (1999) (1)
- Unexpected dynamic behavior of functionalized overcrowded (1997) (1)
- Chloro(P-{2-[N-(2,6-diisopropylphenyl)iminomethyl]phenyl}-P,P-diphenylphosphine-κ2N,P)methylpalladium(II) (2003) (1)
- Tuning of tantalum alkylidene reactivity with a terdentate aryl amine ligand: Synthesis structure and reactivity of [TaCl2{C6H3(CH2NMe2)2-2,6}(CHBut)] (2010) (1)
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- CRYSTAL STRUCTURE AND SPECTROSCOPIC PROPERTIES OF A POLYMERIC (μ-1, 3-AZIDO) COPPER(H) COMPOUND, catena-[Cu(BIPYRIMIDINE)(μ-l,3-N3)(N3)]n (1999) (1)
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- (1R,4bS,8aR)-(1,2,3,4b,5,6,7,8,8a,9a-Decahydro-4,9a-diazafluoren-1-yl)methanol (2000) (0)
- Thermally Stable Arylpalladium Diamine Complexes as Versatile Precursors in Organopalladium Chemistry. Synthesis and X-Ray Molecular Structure of PdIPh(tmeda) and Its Conversion to PdMePh(tmeda) (tmeda: Me2N(CH2)2NMe2). (1989) (0)
- Computer Graphics and Chemical Structures. Stanley V. Kasparek. John Wiley & Sons, Chicester, 1990, XXVIII + 798 pp. £47.00. ISBN 0‐471‐62822‐0 (2010) (0)
- Caesium‐Lithium Phyllosilicate, Cs1.33Li0.67Si2O5. (1996) (0)
- On the Two Closely Related Phases of [Ru(C5Me5)(η6-1,3-(Me2NCH2)2C6H4)](BF4) and the Reversible Solid–Solid Order–Disorder Phase Transition (2010) (0)
- Transition Metal Complexes of Ligands Containing 3,5-Dimethylpyrazolyl Groups and Thioether Functions. The Crystal and Molecular Structure of (1,12-Bis(3,5-dimethylpyrazol-1-yl)-2,11-diaza-5,8-dithiadodecane)nickel(II)-bis(tetrafluoro (1988) (0)
- Self-assembling of bis- ortho chelated diaminobenzyl- (NC A N) and butyl-lithium units to give 2 : 2 mixed alkyllithium aggregates (NC A N)Li 2 Bu 2 Li 2 (NC A N) with a ladder structure (1996) (0)
- [4-(Diphenylphosphino)-9,9-dimethylxanthen-5-yl]diphenylphosphine oxide toluene hemisolvate (2001) (0)
- (3S)-3-benzyloxymethyl-1,4-dioxane-2,5-dione (2005) (0)
- CCDC 614029: Experimental Crystal Structure Determination (2006) (0)
- Arylpalladium Compounds Containing an Alcohol Functionality: Hindered Rotation around the Pd-C Bond and Reactivity toward Styrene and Carbon Monoxide (2001) (0)
- 1:1 and 2:1 Lithium Zincates with Intramolecular Coordination. Structures of Li(thf)Zn(C 6 H 4 CH 2 NMe 2 -2) 3 and Li 2 Zn(C 6 H 4 CH 2 NMe 2 -2) 4 (1997) (0)
- Crystal Structure of Zinc(bis(3-(dimethylamino)propyl-C,N)tin)bis(dibenzoylmethanato)-(Sn-Zn). The First Example of a Dialkyltin(II) Compound Stabilized by Sn-Zn Coordination. (1990) (0)
- Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands.: The X-ray crystal structure of (−)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}phenyl]chloroplatinum(II)1Dedicated to Professor Peter Maitlis in admiration of his contributions to organometallic and homogeneous catal (1998) (0)
- Enantioselective Synthesis of a Chiral Intermediate for Aztreonam and Related Monobactam Antibiotics. (1990) (0)
- Synthesis and X-Ray Crystal Structure of 11-Bromo-endo-9-chloro-7- ethoxybicyclo(5.3.1)undec-1(11)-ene. A Stable, Highly Strained anti- Bredt Olefin. (1993) (0)
- Stereoselective Synthesis of cis- and trans-β-Lactams via α-Amino Ester Enolates and 1-Aza-4-hetero-1,3-butadiene Systems. Molecular Structure of EtOC(O)C(H)(NEt2)C(H)(N(H)-t-Bu)(C(H)=N(t-Bu)ZnCl2): An Unexpectedly Isolated Aldolate. (1992) (0)
- Efficient Catalytic Oxidation of Primary and Secondary Alcohols Using a Non‐heme Dinuclear Iron Complex. (2001) (0)
- Unpredictable Structural Features of Chromium(II) Pyrrolyls: Synthesis and X-Ray Structures of Monomeric Square-Planar (η1-2,5-Me2C4H2N)2Cr(py)2, Square-Pyramidal (η1-C4H4N)2Cr(py)3, Dimeric ((7-azaindolyl)2Cr(DMF))2, and Polymeric (( (1990) (0)
- Structure of lodo(methylthiomethylphenyl)bis(triphenylphosphine)palladium(lI) (1987) (0)
- Syntheses and coordination behavior of di- and poly-nucleating imidazole containing ligands (1993) (0)
- Tuning of Tantalum Alkylidene Reactivity with a Terdentate Aryl Amine Ligand: Synthesis, Structure and Reactivity of (TaCl2(C6H3(CH2NMe2)2-2,6)(CHtBu)). (1990) (0)
- A Simple One‐Step Synthesis of Symmetrical Thiocrown Ethers and the Molecular Structure of an Unusual Sandwich‐Like Tetrametallic Silver Thiocrown Ether Complex. (1993) (0)
- Crystal structure of (5S,4R)-5-(2-oxo-2-phenylethyl)-4-(phenylsulfanyl)- 2(3H)-dihydrofuranone, C18H16O3S (1997) (0)
- Oxidative addition of carbon-chloride bonds by Rh(I)-complexes containing terdentate nitrogen ligands. X-ray analyses of Rh(I) chloride and Rh(III) chloromethyl complexes (1997) (0)
- Intramolecular Amine Coordination versus NMe C-H Activation: The Stereoselective Synthesis of a Tantala(V)azacyclopropane Complex. (1990) (0)
- COORDINATION COMPLEXES OF BIS(2,2‐DIMETHYL‐3,5‐HEXANE‐DIONATO)ZINC WITH ORGANOZINC‐OXYGEN AND ‐NITROGEN COMPOUNDS, CRYSTAL STRUCTURE OF THE COMPLEX FORMED WITH PHENYLZINC PHENOXIDE (1975) (0)
- Coordination Dependence of Magnetic Properties within a Family of Related [FeII2] Complexes of a Triazine‐Based Ligand (Eur. J. Inorg. Chem. 7/2006) (2006) (0)
- What makes a structure report valid (2017) (0)
- Table 1. Fractional atomic coordinates and equivalent isotropic displacement parameters (~2) (1995) (0)
- (2R,3R,5R)-2-[(2R,3aS,6aR)-2,3,3a,4,5,6a-Hexahydrofuro [2,3-b]furan-2-yl]-5-isopropenyl-2,3-dimethylcyclohexanone and (4aR,5S,7R) -5-isopropenyl-7,8,8-trimethyl-2,3,4,4a,5,6,7,8-octahydronaphthalene-2-o xo-4a-carbonitrile. (2001) (0)
- Synthesis and Structural Studies of Ionic Monoorganopalladium(I1) Complexes with Tridentate Nitrogen-Donor Ligands (2001) (0)
- (5α,7α)-7-Hydroxy-4,4,7-trimethylcholestan-3-one (2002) (0)
- Communications to the Editor (1986) (0)
- New Mono‐ and Tricyclopalladated Dendritic Systems with Encapsulated Catalytic Sites. (2002) (0)
- Structure of gentiopicrin hemihydrate: (−)‐(5R,6S)‐5‐ethenyl‐6‐(β‐d‐glucopyranosyloxy)‐5,6‐dihydro‐1H,3H‐pyrano[3,4‐c]pyran‐1‐one hemihydrate, C16H20O9.1/2H2O (1985) (0)
- Long-Range σ-π Interactions in Tetrahydro-4 H-thiopyran End-Capped Oligo ( cyclohexylidenes ) (0)
- A Novel, Trimeric, Chiral Copper(I) Thiophenolate with Intramolecular Coordination. (1989) (0)
- Crystal structure of bis[(1,2,3,4,5-pentamethylcyclopentadienyl)(1,2-methylene-3,4,5-trimethylcyclopentadiene)zirconium(IV)], C40H56Zr2 (1996) (0)
- Pyridyl-functionalized posphabenzenes - design, synthesis and coordination properties (2009) (0)
- Cover Picture: Regulatory Strategies in the Complexation and Release of a Noncovalent Guest Trimer by a Self‐Assembled Molecular Cage (Angew. Chem. Int. Ed. 46/2003) (2003) (0)
- Monocyclopentadienylzirconium and ‐hafnium Alkyls: Synthesis, Hydrogen‐Transfer Reactions, and Catalytic Features in the Reactivity with α‐Olefins. X‐Ray Structure of CpZr(η4‐butadiene)(dmpe)Cl (dmpe: 1,2‐Bis(dimethylphosphino)ethane). (1990) (0)
- Synthesis and Characterization of 1,1-Bis(aminomethyl)cyclohexaneplatinum) Compounds and the Crystal Structure Determinatian of 1,1-Bis(aminomethyl)cyclohexaneaquosulphatoplatinum(II) Monohydrate. (1986) (0)
- TRIORGANOTIN CATIONS STABILIZED BY INTRAMOLECULAR TIN-NITROGEN COORDINATION, SYNTHESIS AND CHARACTERIZATION OF (C,N,N′-2,6-BIS((DIMETHYLAMINO)METHYL)PHENYL)DIORGANOTIN BROMIDES (1978) (0)
- "Pincer" Ligand 2,6-Bis((dimethylamino)methyl)pyridine (NNN). The X-ray Crystal Structures of (Ru(dCdCHPh)- Cl2(NNN)) and (Ru(dCdCHPh)(OTf)(NNN)(PPh3))(OTf) (OTf ) Trifluoromethane Sulfonate) (1999) (0)
- The absolute structure of 3-[N-methyl-N-(S)-α-methylbenzyl]carbamoyl-2,4-dimethylpyridinium chloride monohydrate (1988) (0)
- 2,6-BIS(DIMETHYLAMINO)METHYLPHENYLSODIUM : THE FIRST TRIMERIC ORGANOSODIUMCOMPOUND (1995) (0)
- Crystal and Molecular Structure of Bis((~-benzotci- azolato-Nl ,N2)methyhnercury(II)) (2014) (0)
- Isocyanide Insertion into the Palladium-Carbon Bond of (N-N)Pd(Me)Cl Complexes and the Reactivity of the Products toward Norbornadiene; X-ray Structure of (Bipy)Pd(C=N-2,6-MeC2CC6HC4)Me)Cl (1995) (0)
- New Diphosphane Ligands Based on Bisphenol A Backbones (cid:1) Synthesis and Coordination Chemistry (2003) (0)
- The SYSTEM-S approach to automated structure determination: problems and solutions (2004) (0)
- A Homologous Series of Homoleptic Zinc Bis(1,4-di- tert-butyl-1,4-diaza-1,3-butadiene) Complexes: Kx[Zn( t-BuNCHCHN- t-Bu)2], Zn(t-BuNCHCHN- t-Bu)2, and [Zn( (1998) (0)
- A Chiral Ag(I) Coordination Polymer with a Polydentate Chiral Ligand; Crystal Structure of the 1:1 Complex of CF3SO3Ag and N-(N-(5-Methylthenylidene)-L-methionyl)histamine. (1990) (0)
- Reactivity of Mixed Cyclometalated Palladium Compounds Containing the [2-Me2NC6H4C(H)SiMe3] Monoanion. (1986) (0)
- Efficient Synthesis and Molecular Structure of 2‐ Hydroxyisophthaldehyde. (1997) (0)
- 1H nuclear magnetic resonance and x-ray study of dihedral bond angles in the gauche O·CH2·CH2·O moiety of cyclic 7,8-dihydrodibenzo[f,h]-[1,4]dioxecin (1977) (0)
- 1,1'-Bis(ferrocenylphenylphosphino)-ferrocene (2007) (0)
- SYNTHESIS AND STRUCTURE OF 6-EXO-HYDROXY-1,2-DIPHENYL-1-PHOSPHONIATRICYCLO(3.3.1.13,7)DECANE IODIDE, A DERIVATIVE OF 1-PHOSPHAADAMANTANE (1983) (0)
- trans‐transoid‐trans‐transoid‐trans‐Tetracyclo[16.4.0.02,9.010,17]docosa‐5,13‐diene (1994) (0)
- MAGNETISM AND STRUCTURE OF COPPER(II) COORDINATION COMPOUNDS. X-RAY STRUCTURE DETERMINATION OF TRANS-DICHLOROBIS(N-METHYLIMIDAZOLE)COPPER(II) (1979) (0)
- New Classes of Monomeric and Dimeric Square-Planar Chromium(II) Aryloxides: Syntheses and Structures. (1989) (0)
- MONOMERIC BIS(ETA 2-ALKYNE) COMPLEXES OF (ETA 1-MESITYL)COPPER(I) AND (ETA1-MESITYL)SILVER(I) OBTAINED FROM A BIS(ALKYNYL)TITANOCENES ; X-RAY STRUCTU RE OF (ETA 5-C5H4SIME3)2TI(CCSIME3)2CU(ETA 1-MES) (MES = C6H2ME3-2,4,6) (1995) (0)
- 2,6-Bis(oxazolinyl)phenylnickel(II) Bromide and 2,6-Bis(ketimine)phenylnickel(II) Bromide: Synthesis, Structural Features, and Redox Properties g (0)
- SYNTHESIS AND CRYSTAL STRUCTURE OF THE NOVEL TRANSITION METAL SUBSTITUTED TIN HYDRIDE H2SN2(MN(CO)5)4 (1974) (0)
- The Mechanism of Complexation and the Presence of Kinetically Controlled Pathways in Multicomponent Hydrogen-Bonded Systems (2009) (0)
- Palladium(0)-Mediated Coupling of Bromophosphaalkenes with Grignard Reagents. (2010) (0)
- Metal-catalysed olefin polymerisation into the new millennium : a perspective outlook (2009) (0)
- Cover Picture: Mechanistic Study of the Pd/TOMPP‐Catalyzed Telomerization of 1,3‐Butadiene with Biomass‐Based Alcohols: On the Reversibility of Phosphine Alkylation (ChemCatChem 5/2011) (2011) (0)
- A second polymorph of 2,2'-bipyridyl-(methyl)(phenyl)palladium(II) (1996) (0)
- University of Groningen Synthesis and crystal structure of a dinuclear rhodium complex. Catalytic activity of mono- and di-nuclear rhodium phosphite complexes in hydroformylation Beuken, (2002) (0)
- ortho Metalation of m-(Me2NCH2)2C6H4: Crystal Structure and Chemistry of trans-Rh(III)Cl2(C6H3(CH2NMe2)2-o,o′)(H2O). (1988) (0)
- Structure of Bis(eyelopentadienyl)bis(pyridine)eadmium(II) (1987) (0)
- Structure of (+)‐(2S,3S,5S)‐3‐hydroxy‐5‐isopropenyl‐2‐methylcyclohexanone (1990) (0)
- Bis(benzyltrimethylammonium) tetrachloronickelate(II) N-methylpyrrolidin-2-one solvate (2004) (0)
- Counterion Effect on the Spin-Transition Properties of the Cation ACHTUNGTRENNUNG [ Fe ACHTUNGTRENNUNG ( btzx ) 3 ] 2 + ACHTUNGTRENNUNG ( btzx = m-Xylylenebis ( tetrazole ) ) (2008) (0)
- THE COORDINATION OF DIVALENT TRANSITION METAL IONS TO A STERICALLY CONSTRAINED CHELATING PYRAZOLE DERIVATIVE. THE CRYSTAL AND MOLECULAR STRUCTURE OF BIS(AZIDO)(2,5-BIS(3′,5′-DIMETHYLPYRAZOL-1′-YLMETHYL)-2,5-DIAZAHEXANE)NICKEL(II), (NI (1985) (0)
- Alcohols and an unexpected dinuclear Zwitterionic Pt(II) cation [Pt2 {C6H3 (CH2NHMe2)2-2,6}2I4-]2+ from the reaction of alkyl halides with an aryl(diamine)(aquo)Pt(II) complex; X-ray and N.M.R. Studies (1989) (0)
- Synthesis of a New Multidentate Phosphane Ligand C6H2 (CH2PPh2)4-1,2,4,5 — X-Ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: [{RuCl2(PPh3)}2{C6H2 (CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′}]. (1998) (0)
- X-RAY STRUCTURE OF THE INHERENTLY DISSYMMETRIC OLEFIN D,L-TRANS-1,2,3,4,1',2',3',4'-OCTAHYDRO-4,4'-BIPHENANTHRYLIDENE (2010) (0)
- Direct Structural Comparison of a Rigid Cyclic Peptidic Scaffold Using Crystallography and NMR in Strained PH Polymer Gels (2010) (0)
- A Novel Dinuclear Ruthenium-1,8-Naphthyridine Catalyst for the Oxidation of Alcohols and the Epoxidation of Alkenes. (1996) (0)
- X-Ray Crystal Structure of the Ethylzinc Enolate of 1-(2,4-Cyclopentadienyl)-2-(diethylamino)-1-ethanone, the Unexpected Reaction Product from Cyclopentadienyl(ethyl)zinc and Ethyl N,N-Diethylglycinate. (1988) (0)
- Dimethyl fumarate (2016) (0)
- Lithium Amides with Intramolecularly Coordinated Lithium. (1997) (0)
- Structure of 1,3-xylyl-18-crown-5 (1989) (0)
- Alkylation of the S-C-S Linkage. Towards Lipophilic Mono- and Ditopic Heavy-Metal Receptors Containing Trithiane Building Blocks. Molecular Structure of cis-2,4,6-Tribenzyl-1,3,5-trithiane. (2010) (0)
- Synthesis and Crystal Structure of the New Mixed-Metal, Mixed-Ligand Cluster Compound Zn4Ni2(C5H5)4(C5Me5)2. (1989) (0)
- Comparative Rates of Ligand Substitution Reactions of Pt - C-Bonded Complexes in Aqueous Solution and the X-ray Crystal Structure of [Pt { C 6 H 3 (CH NMe ) -2,6 } (OH 2 )][OSO CF 3 ] (1997) (0)
- A n Aryllithium Complex with Intramolecular Coordination of an o-Diamine Substituent. X-ray and Solution NMR Structures of Dimeric [Li( CsH4(CH2N(Me)CH2CH2Ne2)=2}12 (2001) (0)
- Synthesis and Characterization of β-Phosphaenones. An Investigation on the Conjugative Properties of the P=C Bond. (1995) (0)
- UvA-DARE (Digital Academic Repository) Insertions of Allenes into Palladium-Carbon Bonds of Complexes Containing Bidentate Nitrogen Ligands. Structural and Mechanistic Studies (1997) (0)
- University of Groningen Electronic properties , redox behavior , and interactions with H 2 O 2 of pH-sensitive hydroxyphenyl-1 , 2 , 4-triazole-based oxovanadium ( V ) complexes (2017) (0)
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