Antonio Tiripicchio

Antonio Tiripicchio's AcademicInfluence.com Rankings

Antonio Tiripicchio

Chemistry

#3640

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#4676

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Inorganic Chemistry

#180

World Rank

#192

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Chemistry

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Antonio Tiripicchio's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads (1983) (281)
Selective metal-ligand interactions in hetero-metallic transition metal clusters (1985) (127)
The crystal and molecular structure of mono-(N,N-diethylnicotinamide)cadmium dithiocyanate (1972) (85)
Topologically unique heterometallic Cu(II)/Li coordination polymers self-assembled from N,N-bis(2-hydroxyethyl)-2-aminoethanesulfonic acid biobuffer: versatile catalyst precursors for mild hydrocarboxylation of alkanes to carboxylic acids. (2012) (73)
Pyrazolate bridged dinuclear rhodium complexes. X-ray structure of [Rh(Pz)(CO)P(OPh) 3 ] 2 (1981) (69)
Chiral Phosphoramidite Ligands Based on 8‐Chloroquinoline and Their Rhodium(III), Palladium(II), and Platinum(II) Complexes (1999) (68)
Binuclear copper(I) complexes containing bis(diphenylphosphino)methane bridging ligands: crystal structure of [Cu2(-dppm)2(MeCN)4][ClO4]2 (1987) (66)
Steric Crowding and Redox Reactivity in Platinum(II) and Platinum(IV) Complexes Containing Substituted 1,10-Phenanthrolines. (1996) (61)
Electron-deficient (pentamethylcyclopentadienyl)titanium trialkyls: evidence of [cyclic] Ti.cntdot..cntdot..cntdot.H-C and [cyclic] Ti.cntdot..cntdot..cntdot.C-C interactions. Crystal and molecular structure of .mu.-[o-(CH2)2C6H4]{(.eta.5-C5Me5)Ti[o-(CH2)2C6H4]}2 (1989) (59)
Nucleophilic attack of amine and hydroxide to platinum dibenzonitrile dichloride. Crystal structure of [Pt(NH:CPhN-tert-BuCH2CH2NH-tert-Bu)Cl(NHCOPh)] and cis-[PtNH:CPhN-tert-BuCH2CH2NH-tert-Bu)Cl2(NCPh)] (1986) (59)
Synthetic, Structural, Spectroscopic, and Theoretical Studies of Structural Isomers of the Cluster Pt(3)(&mgr;-PPh(2))(3)Ph(PPh(3))(2). A Unique Example of Core Isomerism in Phosphine Phosphido-Rich Clusters. (1996) (58)
Synthesis, characterization, and transistor response of tetrathia-[7]-helicene precursors and derivatives (2009) (57)
Complexes with an η2‐μ2‐SiO Bridge. Structure of the Bimetallic Complex (1989) (53)
Platinum(II) Complexes with Monocoordinated 2,9-Dimethyl-1,10-phenanthroline and Phosphine Ligands. Exchange of the Donor Nitrogen and Rotation about the Pt-P and P-C Bonds Studied by NMR Spectroscopy: Arene Stacking as an Intramolecular Brake (1994) (51)
Four-versus five-co-ordination in palladium(II) and platinum(II) complexes containing 2,9-dimethyl-1,10-phenanthroline (dmphen). Crystal structures of [PtCl2(dmphen)] and [Pt(η2-C2H4)Cl2(dmphen)] (1991) (50)
Skeletal Isomerization of the [Pt3(μ‐PPh2)3Ph(PPh3)2] Cluster by Recrystallization in Various Solvents (1985) (48)
Tetrathiaheterohelicene Phosphanes as Helical‐Shaped Chiral Ligands for Catalysis (2011) (48)
Steric effects of the 2-(diphenylphosphino)pyridine bridging ligand in the synthesis of binuclear rhodium-palladium complexes. Crystal structures of [(CN-tert-Bu)2Cl2Rh(.mu.-Ph2PPy)Pd(.mu.-Cl)]2 and [(C8H12)Rh(.mu.-Cl)(.mu.-Ph2PPy)PdCl2] (1991) (48)
Nitrosyl, Nitro, and Nitrato Complexes of Palladium(IV). The First Structurally Characterized Mononuclear Nitrosyl Complex of Palladium (2003) (47)
Spectral properties and crystal structure of bis(μ-thiocyanato-N,S)bis-(thiocyanato-N)tetrakis(5,7-dimethyl[1,2,4]triazolo[1,5-α]pyrimidine-N3)dicopper(II) and of tetrakis(5,7-dimethyl[1,2,4]triazolo[1,5-α]pyrimidine-N3)platinum(II) hexa(thiocyanato-S)platinate(IV) (1983) (47)
Synthesis and insertion reactions of the cyclometalated palladium-alkyl complexes Pd(CH(2)CMe(2)-o-C(6)H(4))L(2). Observation of a pentacoordinated intermediate in the insertion of SO(2). (2001) (47)
Five-coordination in platinum(II) species: when and why (1992) (47)
Chiral modification of trinuclear ruthenium clusters with proline and cysteine derivatives. Synthesis, crystal structure, and catalytic properties of [(μ2-H)Ru3(CO)10- (μ2,η2-OCHCH2OCH3)] and [(μ2-H)Ru3(CO)9(μ3,η2-HCH2OCH3)] (1989) (43)
Novel Bonding Mode for a Cyanometalate Ligand: Synthesis and Crystal Structure of the Mn4Pd4 Cluster [(OC)Pd(μ‐NC)Mn(η‐C5H4Me)(CO)2]4 Containing an Orthogonal Arrangement of Helical Units (1990) (42)
The reactions of ruthenium carbonyl and alkyne-carbonyl complexes with nickelocene, [(η-C5H5)Ni(CO)]2 and (η-C5H5)2Ni2(RC2R′). Cyrstal structures of two isostructural heterometallic trinuclear clusters, (η-C5H5)2Ni2Ru(CO)3(C2Ph2) and (η-C5H5)2Ni2Fe(CO)3(C2Ph2) (1981) (42)
Crystal and molecular structure of thiosemicarbazide hydrochloride (1977) (40)
The Reactivity of HRu3(CO)9C2BUt. The Synthesis and crystal structure of (PPH3)AuRu3(CO)9C2BUt, a new ruthenium-gold cluster (1982) (40)
Simple, high-yields syntheses of nickel-osmium clusters. spectroscopic characterization of the new (η-C5H5)NiOs3(CO)9(μ2-H)3. The reactivity of (η-C5H5)NiOs3(CO)9(μ2-H)3 and (η-C5H5)3Ni3Os3(CO)9 towards H2, CO, alkynes and alkenes (1983) (40)
Tetranuclear Complexes as Intermediates in Transannular Oxidative‐Addition Reactions. Structure of the First Tetrairidium Linear Cluster (1988) (40)
Synthesis, structure, and reactivity of mercurial derivatives of an organoruthenium cluster (1980) (38)
Fast ortho-metalation reactions in binuclear dirhodium compounds. Syntheses and molecular structures of a monometalated compound and two doubly metalated compounds with head-to-head configurations (1992) (38)
Reactivity of phosphonodithioato NiII complexes: solution equilibria, solid state studies and theoretical calculations on the adduct formation with some pyridine derivatives (2001) (37)
Ring‐Opening of Lawesson’s Reagent: New Syntheses of Phosphono‐ and Amidophosphono‐Dithioato Complexes − Structural and CP‐MAS 31P‐NMR Characterization of [p‐CH3OPh(X)PS2]2M (X = MeO, iPrNH; M = NiII, PdII, and PtII) (2000) (37)
The crystal structure of tris-μ-[(ethoxy)(N-p-tolylimino)methyl-N, C]trigold(I), [(EtO)(MeC6H4N)CAu]3 (1979) (36)
The crystal structures of nitrates of divalent hexaaquocations. III. Hexaaquonickel nitrate (1971) (36)
Competing metal-metal bonding in heterometallic complexes of gold and mercury. Synthesis of contrasting iron-gold-gold-iron and iron-mercury-iron complexes (1992) (34)
Synthesis and properties of rhodium(I) chloranilate and 2,5-dihydroxy-1,4-benzoquinonate complexes. Crystal structures of the binuclear [Rh2(.mu.-CA)(cod)2] and tetranuclear [Rh4(.mu.-CA)2(cod)4] complexes (CA = chloranilate anion) (1993) (34)
Ph3PSe as a convenient synthon for one-step syntheses of Ph3P-substituted selenido carbonyl iron and ruthenium clusters. Crystal structures of Fe3(μ3-Se)(μ-CO)(CO)7(PPh3)2, M3(μ3-Se)2(CO)7(Pph3)2 (MFe or Ru) and Ru4(μ4-Se)2(μ-CO)2(CO)7(PPh3)2☆ (1995) (34)
Synthesis and characterization of novel σ-alkynyl cyclopentadienyl iron(II) complexes [Fe(CCR)L2(η-C5H5)] [L CO; L2 bis(diphenylphosphino)methane (dppm)]. Crystal structure of [Fe(CCC6H5)(dppm)(η-C5H5)] (1991) (34)
The reactions of [Ru3(CO)12] with nitrogen-containing heterocycles. Crystal structures of [Ru3(µ-H)(µ3-ppy)(CO)9] and [Ru3(µ-napy)(µ-CO)3(CO)7] (1988) (34)
Synthesis and Crystal Structures of Ru(II) Complexes Containing Chelating (Phosphinomethyl)oxazoline P,N-Type Ligands and Asymmetric Catalytic Transfer Hydrogenation of Acetophenone in Propan-2-ol† (2000) (34)
Pyrazolate thiocarbonylrhodium complexes. X-ray structure of [Rh(μ-3,5-Me2Pz)(CS)(PPh3)]2 (1982) (33)
Monomeric Alkoxo and Amido Methylnickel(II) Complexes. Synthesis and Heterocumulene Insertion Chemistry (2007) (33)
Anchoring rhodium(I) on benzoylthiourea-functionalized silica xerogels. Production of recyclable hydroformylation catalysts and the crystal structure of the model compound [Rh(cod)(Hbztu)Cl] (1995) (33)
Preparation, spectroscopic and magnetic characterization of a new series of two-dimensional transition metal compounds. The x-ray structure of poly-bis(thiocyanato-N)-bis-μ- [1,2,4] triazolo [1,5-a] pyrimidine-N1,N3)iron(II) (1987) (32)
Alkyne trimerization on carbonyl ruthenium clusters. Synthesis and crystal structure of Ru3(CO)8(HC2But)3 (1980) (32)
Electrochemical activity of thiahelicenes: Structure effects and electrooligomerization ability (2009) (32)
Extensive substitution, protonation, and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (.mu.3-ampy) as a face-bridging ligand. X-ray structures of [Ru3(.mu.-H)(.mu.3-ampy)(CO)7(PPh3)2] and [Ru3(.mu.-H)2(.mu.3-ampy)(CO2Me)(CO)6(PPh3)2].cntdot.MeOH (1991) (31)
Crystal structures of nitrates of divalent hexaquocations. I. Hexaquozinc nitrate (1967) (31)
Synthesis and Dynamic Behavior of (Pentamethylcyclopentadienyl)azatantalacyclopropane Complexes. Crystal Structures of TaCp*Cl4[C(Me)(NHR)] and TaCp*Me2(.eta.2-Me2CNR) (1995) (31)
Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] (2007) (31)
Butterfly cluster complexes of the group VIII transition metals (1988) (31)
Novel cationic vinylidene complexes of iron(II) containing Fe(.eta.-C5H5)L2 as metal auxiliary [L2 = bis(diphenylphosphino)methane (dppm) and bis(dimethylphosphino)methane (dmpm)]. Crystal structure of [Fe[:C:C(Me)Ph](.eta.-C5H5)(dppm)]I (1992) (31)
The synthesis, reactivity and structure of functionally substituted trimetallic clusters of ruthenium (1980) (30)
Preparation of titanium pentamethylcyclopentadienyl trialkyls and crystal structure of tribenzylpentamethylcyclopentadienyltitanium, showing some evidence of a CH2⋯ Ti interaction (1986) (30)
A New Type of Doubly Silylamido-Bridged Cyclopentadienyl Group 4 Metal Complexes. (2001) (30)
Transition-metal Chelates of Hydrazincarboxylic Acid (1966) (30)
A Versatile and Unprecedented Triply Bonded Dimolybdenum Carbonyl Anion (2003) (30)
Reversible addition of protic molecules to co-ordinated di-2-pyridyl ketone in palladium(II), platinum(II), and gold(III) complexes. X-Ray crystal structures of dichloro(dihydroxy-di-2-pyridylmethane)palladium(II) and dichloro(dihydroxy-di-2-pyridylmethane)gold(III) chloride (1981) (29)
The reactions of iron-carbonyl and alkyne-carbonyl complexes with nickelocene, [(η-C5H5)Ni(CO)]2 and (η-C5H5)2Ni2(RC2R'). crystal structures of two heterometallic tetranuclear clusters (1980) (29)
Synthesis and crystal structure of mercury-bridged transition-metal clusters: Hg[Ru3(CO)9(C2-tert-Bu)]2 and [(C2-tert-Bu)Ru3(CO)9HgMo(.eta.-C5H5)(CO)3] (1983) (29)
Silyl-Substituted Tetrathia[7]helicenes: Synthesis, X-ray Characterization and Reactivity (2007) (29)
One-step syntheses of Ph3P-substituted selenido carbonyl iron and ruthenium clusters Part 2. Crystal structures of Fe2(μ2-Se2)(CO)6-n(PPh3)n(n=1 or 2) Fe3(μ3-Se)2(CO)8(PPh3) and Ru4(μ4-Se)2(μ-CO)2(CO)8(PPh3), and HPLC behaviour of the iron derivatives (1996) (29)
Rapid inversion versus stable chiral center formation. Different behavior of coordinated nitrogens in four- and five-coordinate platinum(II) complexes with N,N'-disubstituted ethylenediamines (1988) (29)
A Triply Bonded Dimolybdenum Hydride Complex with Acid, Base and Radical Activity (2005) (29)
Fluoride Displacement by Lithium Reagents. An Improved Method for the Synthesis of Nickel Hydroxo, Alkoxo, and Amido Complexes (2005) (28)
Binuclear copper(I) complexes containing two or three 2-(diphenylphosphine) pyridine (dppy) bridging ligands: X-ray crystal structure of [Cu2(µ-dppy)3(MeCN)][BF4]2 and variable-temperature 1H and 31P-{1H} nuclear magnetic resonance studies (1989) (28)
Insertion of CNAr into Ta-Me bonds of TaCp*ClnMe4-n (n=0-3) : intramolecular rearrangements, dynamic behavior, and X-ray crystal structure of TaCp*Cl2(NAr) (Ar=2,6-Me2C6H3) (1994) (28)
Cyclic enolates of Ni and Pd: equilibrium between C- and O-bound tautomers and reactivity studies. (2005) (28)
Synthesis and crystal structure of the mixed cluster (η-C5H5)NiFe2(CO)6C2-t-Bu (1980) (28)
Products of the reaction of Ru3(CO)12 with 1,3-cyclohexadiene. X-ray structure of (η-benzene)nonacarbonyl-1-cyclohexen-1,2-ylenetetraruthenium, Ru4(CO)9(C6H6)(C6H8) (1979) (28)
CH bond functionalization of aromatic heterocycles with chelating dicarbene palladium(II) and platinum(II) complexes (2009) (28)
Formation of Diiridium(II) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex (1987) (27)
Insertion of Isocyanides into Tantalum-Carbon Bonds of Azatantalacyclopropane Complexes. Crystal Structures of TaCp*Cl3(.eta.2-NRCMe2CNHR), TaCp*Me(NR)(NRCMe:CMe2), and TaCp*Me(NR)(.eta.2-NR:CCMe2CMe:NR) (R = 2,6-Me2C6H3) (1995) (27)
Reactivity of 1-alkynes at dimanganese carbonyl centers. Synthesis and structural characterization of alkenyl-, alkenylidene-, alkynyl-, and 5-oxo-2-furanylidene-bridged dimanganese compounds (1992) (27)
The synthesis and crystal structure of (η5-C5H5)NiOs3(μ-H)3(CO)8(Ph2PCCPri) and of (η5-C5H5)NiOs3(μ-H)3(CO)8{(Ph2PCCPri)Co2(CO)6}(σ-P,η2-C2). The reaction of unsaturated “linear” ligands on clusters with metal carbonyl species (1985) (27)
The crystal structure of tetrasodium tetramminecopper(II) di-catena-di-μ-thiosulphatocuprate(I) (1966) (27)
Synthesis and reactivity of phosphine-substituted hydrido silyl complexes mer-[FeH(SiR3)(CO)3{Ph2P(CH2)nPPh2}](n= 1 or 4), mer-[FeH{Si(OMe)3}(CO)3(PPh2H)] and mer-[FeH{Si(OMe)3}(CO)3{Ph2PCH2C(O)Ph}]. Synthesis of bimetallic complexes and crystal structure of mer-[(Ph3P)Cu(µ-dppm)Fe{Si(OMe)3}(CO)3] (1991) (27)
Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes part II. Matrix effects on the selectivity in the hydroformylation of styrene (1997) (27)
TRINUCLEAR OSMIUM AND RUTHENIUM CLUSTERS CONTAINING LIGANDS FORMED BY DEHYDRATION AND REARRANGEMENT OF 1,4-DIHYDROXYBUT-2-YNE (1981) (27)
Reactivity of the heterometallic clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) toward phosphine selenides, including selenium transfer. Crystal structures of [HRuCo3(CO)7(μ-CO)3(μ-dppy)], [MCo2(μ3-Se)(CO)7(μ-dppy)], and [RuCo2(μ3-Se)(CO)7(μ-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2PCH2PP (2002) (27)
Reaction between cyanate ion and ethylene coordinated to platinum: a new route to carbamoyl complexes (1982) (26)
Reactions of unsaturated dihydrido carbonyl complexes of manganese(I) with nitriles and isonitriles. Preparation and characterization of the first binuclear .mu.,.eta.1,.eta.2-NCR derivatives (1992) (26)
Imidazolate bridged polynuclear rhodium(I) complexes. X-ray structure of [Rh(2-Meimidazolate)(CO)2]4 (1982) (26)
A Molecular Tool for Measuring the Electron-Acceptor Ability of Ligands from Crystallographic Data (2004) (26)
Synthesis of diphosphine-substituted selenido carbonyl iron clusters: Progressive deformation of the Fe3Se2 core in the nido clusters [Fe3Se2(CO)7μ-(Ph2P)2R] by widening the bite of the bridging ligand (1997) (26)
Insertion of Isocyanides into Tantalum−Methyl and Tantalum−Amido Bonds (2000) (26)
Synthesis of the First Pt-Au Cluster by an Unexpected H⊕-Substitution at trans-PtH(Cl)L2† (1984) (25)
Reactions of di-2-pyridyl sulfide with the palladium(II) and platinum(II) diene or methoxydiene complexes. Dynamic behaviour of the cationic compounds. Crystal structure of Pd(di-2-pyridyl sulfide)Cl2 (1992) (25)
Synthesis of copper(I) bis(3,5-dimethylpyrazolyl)methane olefin complexes and their reactivity towards carbon monoxide (2006) (25)
Iron−Gold (or −Mercury) Carbide Clusters Derived from [Fe6C(CO)16]2-. X-ray Crystal Structures of (NEt4)[Fe6C{AuPPh3}(CO)16] and [Fe4C{AuPPh3}(CO)11(NO)] (1997) (25)
Reactions of [Pd2(μ‐dppm)2Cl2] with Electrophilic Complexes of Copper and Gold. Synthesis of the Pd4 Cluster [Pd4(μ‐Cl)2(μ‐dppm)4](PF6)2·2(CH3)2CO (1987) (25)
A New Type of Iron‐Molybdenum‐Sulfur Cluster: Synthesis and Structure of [Fe2Mo2(η5‐C5H5)2(μ3‐S)2(μ3‐CO)2(CO)6] (1982) (25)
Chemoselective Reactions of the Phosphino Enolate Li[Ph2PCH C( O)NPh2] with Ph2P−Cl and M−Cl Bonds (M = Pd, Pt). Coordination Properties of the New Functional Diphosphine Ligand (Ph2P)2CHC(O)NPh2. Hemilabile Behavior of [Cu2{(Ph2P)2CHC(O)NPh2-P,P,O}2](BF4)2. Reactivity and Molecular Structure of [(8 (1996) (25)
CO activation in the reactions of iron carbonyls and alkynes. Syntheses, crystal structures, and nuclear magnetic resonance studies on hydroxyferrole and maleoyliron derivatives (1979) (24)
Multisite-bound vinylidenes on heterometallic clusters. Reformulation of (.eta.5-C5H5Ni)Ru3(CO)9(.mu.4-.eta.2-C:CHR) (R = tert-Bu) as hydrido-bridged (.mu.-H)(.eta.5-C5H5Ni)Ru3(CO)9(.mu.4-.eta.2-C:CHR). Molecular structure of the isopropyl derivative (R = iso-Pr) and an improved synthetic method (1983) (24)
Formation of metallacycles from terminal diynes with geminal methyl groups α to the triple bonds. Synthesis and crystal structure of Co2(CO)5[(HCCCMe2)2NMe], an intermediate in cobalt-catalyzed organic syntheses (1992) (24)
Synthesis and spectroscopic characterization of a new class of heterotetranuclear compounds with thiocyanate groups as bridging ligands. The X-ray structure of bis-(μ-tetrakis(thiocyanato-S)mercury(II)-N,N′)diaquahexakis(5.7-dimethyl[1,2,4] triazolo[1,5-a] pyrimidine-N3) dicobalt(II) (1984) (24)
Synthesis of MMoO4/SiO2 catalysts (M=Ni or Co) by a sol–gel route via silicon alkoxides: Stabilization of β-NiMoO4 at room temperature (1999) (24)
Benzamidinatorhodium complexes. X-Ray structures of [Rh{CPh(NPh)2}(cod)] and [Rh2{µ-CPh(NPh)2}2(tfbb)2] (1985) (23)
Synthesis and crystal structure of Ru3(CO)8(C16H22). The insertion of isopropenylacetylene into RuC bonds and the opening of a stable closed triruthenium cluster (1979) (23)
Syntheses, structures, and bonding of heteropentametallic clusters [MCo3(CO)12{µ3-M′(EPh3)}](M = Fe or Ru; M′= Cu or Au; E = P or As): X-ray crystal structures of [RuCo3(CO)12{µ3-M′(PPh3)}](M′= Cu or Au) (1986) (23)
Steric effects of the 2-(diphenylphosphino)-6-methoxypyridine short-bite bridging ligand in the synthesis of binuclear complexes. Crystal and molecular structure of [Rh2Cu(CO)2(Ph2PPyOMe)2(.mu.-Cl)2]BF4.cntdot.CH2Cl2 (1992) (23)
Crystal and molecular structure of bis(amidoxalato-O,O)cobalt(II) tetrahydrate (1972) (23)
Trinuclear angular aggregates of rhodium: synthesis and crystal structures of [Rh3(µ3-SC5H4N)2(CO)6][ClO4](SC5H4N = pyridine-2-thiolate) and [Rh3(µ3-C7H4NS2)2(CO)2(PPh3)2(tfbb)][ClO4](C7H4NS2= benzothiazole-2-thiolate, tfbb = tetrafluorobenzobarrelene) (1990) (23)
Reactions of alkynes with HFeCO3(CO)12. Crystal structure of FeCO3(CO)9[PhC2(H)Ph] (PhC2Ph) (1983) (22)
Hydrocarbyl derivatives of dppm- or dppa-bridged alkoxysilyl heterobimetallic Fe–Pd complexes and CO insertion reactions. Crystal structures of [(OC)3{(MeO)3Si}Fe(μ-dppm)Pd(8-mq)] (dppm = Ph2PCH2PPh2), [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdCl] and [(OC)3Fe{μ-Si(OMe)2(OMe)}(μ-dppa)PdPh] (dppa = Ph2PNHPP (1999) (22)
Complexes of rhodium(I) with 1,8-naphthyridine and related ligands. Crystal structure of [Rh2(µ-napy)2(nbd)2][ClO4]2·H2O (1984) (22)
Anchoring metal species on a thiourea-functionalized silica xerogel. In situ production of colloidal palladium particles (1992) (22)
Structure of ferrocenium hexafluorophosphate (1990) (22)
Five-coordinate platinum (II) alkyne complexes: synthesis, ab initio calculations and crystal and molecular structure of [PtI2(Me2phen)η2PhCCPh]·CHCl3 (1998) (22)
Multi-site bound hydrocarbyls on osmium clusters. The reactions of t-butylacetylene with Os3(CO)12 and H2Os3(CO)10. Characterization of the products and crystal structure of HOs3(CO)10(HCCHBut) (1983) (22)
Chemistry of multi-site bound unsaturated ligands on metal carbonyl clusters. Intramolecular reductive coupling in the conversion of [Ru3(µ-H)(CO)9(µ3,η2-CCBut)] to the butadienyl cluster [Ru3(CO)8{µ3,η4C(But)CC(H)C(Ph)(PPh2)}], and its crystal structure. An example of ligand isomerism on metal clus (1989) (22)
Dimerization of isopropenylacetylene on Ru3(CO)12. Synthesis and crystal structure of Ru3(CO)8(C10H12) (1979) (22)
Rhodium(I), Palladium(II), and Platinum(II) Complexes Containing New Mixed Phosphane−Phosphite Ligands − Effect of the Catalytic System Stability on the Enantioselective Hydroformylation of Styrene (2002) (22)
Structures and properties of bis(thiocyanato-N)bis(6-methyl[1,2,4]triazolo[1,a]pyrimidine-N3)copper(II), a distorted tetrahedral copper(II) thiocyanate compound, and bis(thiocyanato-N)bis(5-methyl[1,2,4]triazolo[1,5-a]pyrimidine-N3)copper(II), a polynuclear pseudo-layered system (1989) (21)
Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis-μ-(3,5-dimethylpyrazolate)bis(tricarbonyl-ruthenium(I)) (RuRu) (1987) (21)
Oxidative Addition of Ammonium and Iminium Tetraphenylborates to Low-Valent Metal Complexes. Evidence of Selective N−C and N−H Activation. A New, Easy Route to Cationic Allyl- and Hydridonickel Complexes (1997) (21)
Synthesis, characterization and X-ray structure of hetero-polynuclear thiocyanates of iron(II) and mercury(II) with 5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine-N3 and water as ligands (1985) (21)
Phosphido-bridged, heterodi-, heterotri-, and heterotetranuclear complexes of palladium and platinum with transition metals. Crystal structure of [{(OC)4Mn(.mu.-PPh2)}2Pt(PPh3)] (Mn-Mn, 2 Mn-Pt) (1992) (21)
A homoleptic mononuclear iridium(II) organometallic complex : synthesis and X-ray structure of [Ir(C6Cl5)4]2- (1993) (21)
Copper(I) complexes containing 1,1′-bis(diphenylphosphino) ferrocene (dppf) as a chelate ligand. X-ray crystal structures of [Cu2(μ-Cl)2(κ2-P,P-dppf)2] and [Cu(CNtBu)2(κ2-P,P-dppf)][BF4] (2001) (21)
Influence of the alkaline cation on the structures of polymeric o-phthalatocuprate(II). I. The crystal structures of dilithium catena-di-μ-(o-phthalato)-cuprate(II) tetrahydrate and dirubidium catena-di-μ-(o-phthalato)-cuprate(II) dihydrate (1977) (21)
Synthesis and molecular structure of bis(µ4-but-1-yne)-undecacarbonyl-quadro-tetrairon (4 Fe–Fe) (1978) (21)
Oxidation of Substrates by an Iridium Dioxygen Complex: Intramolecular Oxidation of Carbon Monoxide and Activation of a Carbonyl Group by Attack of a Heterocyclic Nitrogen (1995) (20)
Heterotrinuclear angular aggregates of rhodium, iridium, palladium and Group 11 metals. X-Ray structure of the complex [(cod)2Rh2(µ3-C7H4NS2)2Ag(O2ClO2)](cod = cycloocta-1,5-diene) (1991) (20)
GROUP 4 ANSA-METALLOCENES IN OXIDATION STATE III : SYNTHESIS CHARACTERIZATION, AND CHEMICAL BEHAVIOR. CRYSTAL STRUCTURE OF ETA 5:ETA 5-(C5H4)2SI(CH3)2 TICL(PME2PH) (1991) (20)
The crystal structures of nitrates of divalent hexaaquocations. II. Hexaaquomagnesium nitrate (1969) (20)
Perthiocarboxylate complex: synthesis, structure and spectroscopic characterization of the tetrameric copper(I) o-tolylperthiocarboxylate, [Cu(S)SSCC7H7]4 (1988) (20)
Direct synthesis and crystal structure of a new pentanuclear heterotrimetallic Cu/Co/Ni complex with 2-(dimethylamino)ethanol. Discussion of possible “butterfly-like” molecular structure types (2011) (20)
the reactivity of HRu3(CO)9C2But. Synthesis and crystal structure of (η5-C5H5)NiRu3(CO)9CsdC(H)But, a new mixed ruthenium-nickel cluster (1980) (20)
Preparation, spectroscopic and magnetic characterization of two pseudo layered copper(II) systems. The x-ray structures of bis(thiocyanato-N)bis([1,2,4] triazolo[1,5-a]pyrimidine-N3)copper(II) and dichlorobis([1,2,4]triazolo[1,5-a]pyrimidine-N3)copper(II) (1987) (20)
Chelating versus bridging behaviour and NMR fluxionality of dppf in the nido clusters [M3Se2(CO)7(dppf)] [M = Fe or Ru, dppf = Fe(η5-C5H4PPh2)2]. Crystal structure of the chelated ruthenium derivative† (1999) (20)
METAL-ASSISTED SYNTHESIS OF NEW AND HIGHLY FUNCTIONALIZED DIPHOSPHINES (1998) (20)
Cationic complexes of dirhodium(II) with 1,8-naphthyridine : Catalysis of reactions involving silanes (2006) (20)
Influence of the alkaline cation on the structures of polymeric o-phthalatocuprate(II). II. The crystal structures of disodium di-o-phthalatocuprate(II) dihydrate and dipotassium catena-di-μ-(o-phthalato)-cuprate(II) dihydrate (1978) (20)
ISOLATION OF A POSTULATED INTERMEDIATE IN THE STILLE REACTION. SYNTHESIS OF 2-ARYLAZOARYLPHOSPHONIUM SALTS VIA C-P COUPLING. SYNTHESIS OF ACETONE COMP LEXES OF PALLADIUM(II). CRYSTAL AND MOLECULAR STRUCTURE OF PD(C6H4N=NPH-2)( PPH3)(ACETONE), PH3PC6H3(N2C6H4ME-4')-2-ME-5CLO4 AND PD(O,O-ACAC)(PPH3)2C (1996) (20)
[CpTi(μ3-S)3{Rh(tfbb)}3]: An early-late heterometallic complex as molecular model for the deactivation of metal sulphide catalysts (1996) (20)
Novel High‐Nuclearity HgCoRu and HgCoFe Sandwich Complexes. Synthesis and Structure of [Hg{RuCo3(μ‐CO)3(CO)9}2] (1985) (20)
Fulvalene derivatives of titanium: x-ray structures of [(TiCl2)2(.mu.-O)(.mu.-.eta.5:.eta.5-C10H8)] and [{Ti(CH2C6H5)3}2(.mu.-.eta.5:.eta.5-C10H8)] (1992) (20)
Synthesis and structural characterization of the isomeric ruthenium-nickel derivatives (η-C5H5)NiRu3(CO)8(C6H9) and related complexes (1980) (20)
Chemical transformations on phosphido-bridged clusters. Methyne, methylene transfer, and ketene forming reactions involving the μ-methylene cluster Ru3(CO)7(μ-CH2){μ3-η3-CH2=C=C(i-Pr)}(μ-PPh2). X-ray structures of (μ-H)Ru3(CO)7{μ3-η4-CH=C(i-Pr)C=CH2}(μ-PPh2) and Ru3(CO)6(μ-CO){μ3-η4-CH2=C(i-Pr)C=CH2 (1988) (19)
Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-Electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters (2007) (19)
The oxidation of ethane-1,2-diol resulting from molecular oxygen activation by copper: formation of an oxoethanoate complex precedes carbon–carbon bond cleavage (1993) (19)
Aminocarbyne coupling reactions at M(Ph2PCH2CH2PPh2)2(M = Mo or W) sites. Synthesis and properties of the diaminoacetylene complexes trans-[MX(η2-MeHNCCNHMe)-(Ph2PCH2CH2PPh2)2]A (X = F, Cl or ClO4; A = BF4′PF6′HCl2or ClO4) and of their di(aminocarbyne)-type precursors (1995) (19)
Synthesis of Phosphonito,N and Phosphito,N ligands based on quinolines and (R)-binaphthol or substituted biphenol and of their rhodium(I), palladium(II) and platinum(II) complexes (2002) (19)
Chain Core Isomerism in dppm-Bridged Polymetallic Complexes. Synthesis, Reactivity, and Structure of Fe-Hg-Pt, Fe-Sn-Pt, and Fe-Pd-Sn Arrays (dppm = Ph2PCH2PPh2) (1994) (19)
Reaction of CH2(Ph2PSe)2 (dppmSe2) with [Ru3(CO)12]. Fluxional behaviour of [Ru3(µ3-Se)2(CO)7(µ-dppm)] and crystal structures of [Ru4(µ4-Se)2(µ-CO)(CO)8(µ-dppm)]·MeOH and [Ru6(µ3-Se)4(CO)12(µ-dppm)2]·CH2Cl2 (1999) (19)
Synthesis of dppm-stabilized Si–Fe–M (M = Zn, Cd, Hg or Tl) complexes and crystal structure of a heterotetranuclear Fe2Cd2 complex (dppm = Ph2PCH2PPh2) (1992) (19)
New trisubstituted cyclopentadienyl ligands: synthesis, characterisation and catalytic properties of mono and dinuclear cobalt, rhodium, iron and ruthenium complexes (2001) (19)
The crystal and molecular structure of bis(hydrazinecarboxylato-N',O)manganese(II) dihydrate (1967) (19)
Organometallic models for the hydrodesulphurisation (HDS) reaction: synthesis of [(η-thiophene)M(PPh3)2]+ (M = Rh, Ir) and x-ray structure of the Rh derivative, the first example of a fully characterised π-thiophene complex of an HDS-active metal (1986) (18)
Synthesis and reactivity of bimetallic iron-rhenium silyl complexes: crystal structures of [(OC)3{(MeO)3Si}Fe(μ-dppm)Re(CO)4] and (1996) (18)
Synthesis and Crystal Structure of a trans-Diaquabis(amidato) Complex of Platinum(II). (1996) (18)
Manganese−Gold and −Silver Mixed-Metal Clusters Derived from the Unsaturated Binuclear Complex [Mn2(CO)6(μ-Ph2PCH2PPh2)]2-(MnMn) and Related Anions (2003) (18)
Oxidative Addition of Phosphorus Ylides to Ru3(CO)12 (1990) (18)
X-Ray and infrared structural studies on the methyl ester of dithiocarbazic acid and its N-substituted derivatives (1977) (18)
Reactions of HC.tplbond.CCMe2NHCOR alkynes with M3(CO)12 carbonyl (M = Ru, R = C6H9, Ph; M = Os, R = C6H9). Synthesis and crystal structure of Ru4(CO)11(HC.tplbond.CCMe2NHCOC6H9), a butterfly cluster showing an interaction between a wingtip metal and the amide CO (1990) (18)
Homogeneous catalysis on metal clusters. The isomerization and selective hydrogenation of dienes, alkenes, and alkynes in the presence of [(η-C5H5)NiOs3(µ-H)3(CO)9] and [(η-C5H5)NiOs3(µ-H)3(CO)8L][L = PPh2H or P(C6H4Me-o)3]. Spectroscopic identification of the reaction intermediates and X-ray struct (1986) (18)
Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[-(3,5-dimethylpyrazolato-NN?)-tricarbonylruthenium(I)](Ru?Ru) and bis[-(3,5-dimethylpyrazolato-NN?)]--iodo-bis[tricarbonylruthenium(II)]tri-iodide (1989) (18)
Polynuclear .eta.2-benzophenone methylhydrazonato(1-) complexes from the insertion of diphenyldiazomethane into Ti-CH3 bonds of electron-deficient organotitanium oxides. X-ray structure of [Ti(C5Me5)Me(.eta.2-MeNNCPh2)][Ti(C5Me5)Me2](.mu.-O) (1989) (18)
Electrophilic additions to phosphido-bridged palladium- and platinum-transition-metal bonds. Synthesis and crystal structure of the heterotetranuclear cluster [cyclic] [{Cp(OC)2W(.mu.-CO)(.mu.-PPh2)}{Cp(OC)2W(.mu.-AuPPh3)(.mu.-PPh2)}Pt][PF6].cntdot.2THF (Au-Pt, Au-W, 2W-Pt) (1992) (18)
Chelating and bridging behaviour of bidentate P,P or P,As ligands (LL) in HRu3(CCBut)(CO)7(LL) as indicated by 1H, 13C and 31P NMR spectroscopy (1989) (18)
The reactivity of HRu3(CO)9C2But. Synthesis and crystal structure of Ru3(CO)7{(C2But)[PhC2(H)Ph](C2Ph2)} (1982) (18)
Reaction of 4-methylpent-2-yne with dodecacarbonyltriruthenium. The structure of a novel alkyne dimerization dehydrogenation product (1982) (18)
dppm-Assisted synthesis and reactivity of bimetallic M-molybdenum, M-tungsten, M-cobalt, and M-manganese (M = platinum, palladium) complexes. Crystal structure of [cyclic] [(.eta.2-dppm)Pt(.mu.-dppm)W(CO)2CpPt,W][PF6].cntdot.CH2Cl2 (dppm = bis(diphenylphosphino)methane) (1993) (18)
Synthesis, crystal structures and reactivity of ruthenium-(II) and -(III) complexes containing β-ketophosphine or phosphino enolate ligands (1995) (17)
The coordination of alkynes to four metal atoms in square planar clusters. Crystal structure and cluster contraction and expansion reactions of (η5-C5H5)2Ni2Fe2(CO)6(μ4,η2-C2Ph2) (1985) (17)
Trifluoromethyl-substituted Bis(Pyrazolyl)Methanes as Ligands for Copper and Silver: Synthesis and Spectroscopic and Structural Characterization (2007) (17)
Di- and tetra-nuclear mixed-valence complexes of rhodium(III,I) and rhodium(III)–iridium(I) with the 2,2′-bi-imidazolate(2–) anion (bim) as bridging ligand. Crystal structure of [{(η-C5Me5)[P(OEt)3]Rh(bim)Rh(nbd)}2][ClO4]2 (1986) (17)
Reactions of phosphine ligands with iridium complexes leading to C(sp3)-H bond activation (2005) (17)
Cyclopentadienyl dithiocarbamate and dithiophosphate molybdenum and tungsten complexes (1999) (17)
A flexible framework obtained from oxidative additions upon the binuclear complex [Ir2(-pz)(-SBut)(CO)2{P(OMe)3}2]: preparation and X-ray structures of [Ir2(-pz)(-SBut)(-L)(CO)2{P(OMe)3}2] and [Ir2(-pz)(-SBut)(-L)I2(CO)2-{P(OMe)3}2](Hpz = pyrazole, L = dimethyl acetylenedicarboxylate) (1990) (17)
Synthesis and crystal structure of (η-C5H5)2Ru2Ni(CO)3(μ3CO)(C2Ph2). Facile, one step synthesis of a chiral complex (1981) (17)
A re-examination of the reaction between 1,1′-bis(diphenylphosphino)ferrocene (dppf) diselenide and [Ru3(CO)12]. Electrochemical behaviour of the isomeric nido-clusters [Ru3(μ3-Se)2(dppf)(CO)7] and [Ru3(μ3-Se)2(μ-dppf)(CO)7] and crystal structure of [Ru3Se{μ-P(Ph)C5H4FeC5H4PPh2}(μ-OCPh)(CO)6] (2001) (17)
Reversible C-H Bond Activation of a Bifunctional Phosphine Bridging Ligand across Two Unbonded Metal Centers. (2000) (17)
The crystal structure of tetrapotassium dihydrogendecaoxodiiodate(VII) octahydrate (1965) (17)
First heterobimetallic complexes with bridging and chelating Ph2PCH2PPh2 (dppm): crystal structure of [(.eta.-C5H4Me)Mo(CO)2(.mu.-dppm)Pt(dppm)]2[Mo2O7]. Air oxidation of the anions [(.eta.-C5H4R)Mo(CO)3]- into [Mo2O7]2- (1984) (17)
Synthesis, crystal structure, and stereochemical non-rigidity of µ-[1-σ:1–2-η-2-carboxylato-1-ethylbut-1-enyl-O(2Fe)]-bis(tricarbonyl-iron)(Fe–Fe), a new complex obtained from iron carbonyls under apolar conditions (1979) (17)
CHEMISTRY OF HIGHLY ELECTROPHILIC BINUCLEAR CATIONS. 1. OXIDATION REACTIONS OF M2(ETA 5-C5H5)2(CO)4(MU -PH2PCH2PPH2) (M = MO, W) WITH FECP2X (X = BF4, PF6) (1999) (17)
Reactivity of the methylcyclopentadienylmanganese cyanometalate Na[Cp'Mn(CO)2CN] with titanium, zirconium, and hafnium halides. Crystal and molecular structure of the .mu.-cyano .mu.-oxo tetranuclear complex [Cp2Zr{(.mu.-NC)MnCp'(CO)2}]2(.mu.-O) (Cp = .eta.-C5H5; Cp' = .eta.-MeC5H4) (1993) (17)
Synthesis, structure, and ligand dynamics of the organometallic anion [Ru3(CO)9C2-tert-Bu]- (1981) (17)
Polymeric chains of tetranuclear hydroxo-o-phthalatocuprate(II) units and silver(I)–aromatic interactions in the crystal structure of Ag[Cu2(C8H4O4)2(OH)].5H2O (1979) (17)
Activation of the carbon—nitrogen triple bond of benzonitrile in the presence of triosmium clusters and acetic acid. Crystal structure of (μ-H)Os3(CO)10(μ-O2CCH3), a product of the reaction (1985) (17)
Reaction of CH2(Ph2PSe)2 with [Ru3(CO)12]. Crystal structure of [Ru4Se4(CO)10(Ph2PCH2PPh2)], a missing link in the [M4E4L12] cubane series (M = Group 8 metal, E = chalcogenido ligand) (1995) (17)
Crystal structure and stereochemical non-rigidity of octacarbonyl-(η-1,3-dimethyl-2-vinylcyclopentadienyl)-µ3-propylidyne-triangulo-tri-iron (1977) (17)
The replacement of one hydrido-ligand in [(η-C5H5)NiOs3(µ-H)3(CO)9] by MPPh3+(M = Cu or Au). Crystal structure of [(η-C5H5)NiOs3(µ-H)2-(µ-AuPPh3)(CO)9], the first gold–nickel–osmium cluster (1984) (17)
Complexes of functional phosphines. 23. PPh3 and .beta.-ketophosphine complexes of cobalt(II). Crystal and molecular structures of CoCl2[Ph2PCH2C(O)Ph]2 and Co2(CO)6[Ph2PCH2C(O)Ph]2 and of the trinuclear, mixed-metal complex [(Ph3P)2Ag(.mu.-Cl)2Co(.mu.-Cl)2Ag(PPh3)2].cntdot.0.50Et2 (1994) (17)
Square Fe2Au2 and triangular Fe2Au clusters: A reversible transformation. X-ray crystal structure of [Fe2Au2(CO)8(.mu.-dppm)] [dppm = bis(diphenylphosphino)methane] (1991) (16)
Reactivity of α-Phosphino Enolate Complexes of Nickel(II) and Palladium(II) toward Electrophilic Metal Centers. Synthesis and Crystal Structures of the Bimetallic Palladium(II)−Gold(I) Complex [(dmba)Pd{Ph2PCH(AuPPh3)C(O)Ph}](BF4) and of the Nickel(II)−Cobalt(II) Paramagnetic Complexcis-[Ni{Ph2PCH C (1996) (16)
Systematic synthesis of triply bridged binuclear copper(I) complexes containing bis(diphenylphosphino)methane (dppm) bridging ligands: X-ray crystal structures of [Cu2(µ-dppm)2(µ-mpyO)]BF4 and [Cu2(µ-dppm)(µ-mpyO)2](mpyO = 6-methylpyridin-2-olate) (1990) (16)
The crystal and molecular structure of o-phthalatocopper(II) dihydrate (1978) (16)
(η6-Arene)ruthenium(II) complexes containing enantiomerically pure (β-aminoalkyl)phosphines or a (β-aminoalkyl) phosphinite: synthesis, stereochemical and kinetic studies (2000) (16)
Synthesis and x-ray structure of (η-C5H5)2Ni2Fe(CO)3S, the first iron-nickel cluster with a sulphur atom nearly symmetrically bridging three metal atoms (1980) (16)
Synthesis and spectroscopic characterization of heterobimetallic (α-alkynyl)iron-cobalt hexacarbonyl complexes, μ-(1-σ, 2-3, η2-R2C-CCR′)][(CO)3Fe-Co(CO)3] and [μ-(1-σ, 2-3, η2-H2C-CCCH2OH)] [(CO)3Fe-Co(CO)2(PPh3)] (1983) (16)
Reactivity of [Mn2(.mu.-H)2(CO)6(.mu.-tedip)] (tedip = (EtO)2POP(OEt)2) with Group 11 Alkynyl Compounds. X-ray Structures of [Ag2Mn4(.mu.-H)6(CO)12(.mu.-tedip)2] and [AuMn4(.mu.-H)5(CO)12(.mu.-tedip)2] (1994) (16)
Synthesis, Structural Characterisation and Electrochemical Studies of Neutral Alkenylcarbyne Tungsten Complexes Bearing Chelating Bidentate and Tridentate Phosphanes (2000) (16)
Manganese-Group 11 elements and -zinc mixed-metal clusters derived from the unsaturated hydride [Mn2(.mu.-H)2(CO)6(.mu.-tedip)][tedip = (EtO)2POP(OEt)2]. X-ray structures of [Mn2(.mu.-AuPPh3)(.mu.-H)(CO)6(.mu.-tedip)] and [Mn2[.mu.-Zn(N,N'-Me2NCH2CH2NMe2)](.mu.-H)2(CO)6(.mu.-tedip)] (1993) (16)
2,2′-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)–rhodium(I) complexes. Crystal structure of [(Ph3P)2Au2(µ-bbzim)Rh(cod)][ClO4]·CHCl3 (1983) (16)
The crystal and molecular structure of bis(amidoxalato-O,O)-zinc dihydrate (1971) (16)
Low-temperature N-O bond cleavage in nitrosyl ligands induced by the unsaturated dimolybdenum anion [Mo2(eta(5)-C5H5)2(mu-PPh2)(mu-CO)2]-. (2009) (16)
Synthesis of organic molecules from functionalized alkynes and metal carbonyls. Reaction pathways and intermediates. Crystal structure of Fe3(CO)6(μ-CO)2[(HC ≡ CCMe2)2NH] (1993) (16)
Synthesis, Structure, and Reactivity of [Mn2(μ‐H)2(CO)6(μ‐Ph2PCH2PPh2)] (1988) (16)
Reactivity of molybdenum-platinum bonds toward PPh2H: Synthesis of phosphido-bridged, heterometallic complexes. Molecular structures of [(.eta.-C5H5)2Mo2Pt(.mu.-PPh2)2(CO)5].cntdot.1/2C7H8 and of the hydrido, tetranuclear, bent-chain complex [(.eta.-C5H5)MoPt(H) (.mu.-PPh2)2(CO)2]2 (Ph = C6H5) (1989) (16)
Aminocarbyne and isocyanide complexes of rhenium. Crystal structures of trans-[ReCl(CNR)(Ph2PCH2CH2PPh2)2] (R = H or SiMe3) (2000) (16)
Heterometallic complexes containing a μ-PCy2 bridge: synthesis and crystal structure of the tungsten-platinum-gold complex [Cp(OC)2W(μ-PCy2)(μ-AuPP3)Pt(CO)(PCy2H)][PF6] (Cy=c-C6H11; Cp=η-CH5) (1988) (16)
Preparation of carbonyl, halogeno, and alkyl niobocene complexes and their reactions with oxygen. Crystal structures of [Nb(η-C5H4SiMe3)2Cl2], [Nb(η-C5H4SiMe3)2(O)Me], and [Nb(η-C5H4SiMe3)2(C6F5)(CO)] (1988) (16)
Synthesis and structural characterization of a new chromium-iron-sulfur cluster, (.eta.5-C5H5)2Cr2Fe2(.mu.3-CO)2(.mu.3-S)2(CO)6 (1981) (16)
Stereoselective hetero Diels–Alder reactions of chiral tricarbonyl (η6-benzaldehyde)chromium complexes (2001) (16)
STRUCTURE EXPANSION OF THE IR4 CLUSTER CORE INDUCED BY THE SHORT BITE OF THE 2-(BIPHENYLPHOSPHINO)PYRIDINE LIGAND. REACTION OF IR4(CO)10(PH2PPY)2 WITH CU(NCCH3)4BF4 AND AGPF6 LEADING TO HIGHER-NUCLEARITY IR4CU AND IR4AG CLUST ER COMPOUNDS (1996) (16)
Synthesis of mixed metal clusters from binuclear precursors: X-ray structure of (η5-C5H5)2(CO)5(μ-PPh72)(μ4-η2-CCPh a molecule with a μ4-acetylide on a spiked triangular metal framework (1985) (16)
The crystal and molecular structure of tris(thiourea)copper(I) hydrogen-o-phthalate. A monomeric trigonal planar copper(I) complex (1977) (16)
Deprotonation reactions of the aminocarbyne complex trans-[ReCl(CNH2)(dppe)2][BF4](dppe = Ph2PCH2CH2PPh2). Synthesis and properties of the cyano-complexes trans-[Re(CN)L(dppe)2](L = NCR, N2, CO or CCHPh) and crystal structure of trans-[Re(CN)(NCMe)(dppe)2]PriOH (1996) (16)
Stepwise Construction of Polynuclear Complexes of Rhodium and Iridium Assisted by Benzimidazole-2-thiol. NMR and X-ray Diffraction Studies. (1996) (16)
Reactivity of unsaturated clusters. Phosphoruscarbon bond activation, hydrogen migration and acetylene interconversion in the reactions of 46-electron (H)Ru3(CO)9(μ-PPh2) with Ph2PCCR (R = Ph, But, Pri). X-ray structure of Ru3(CO)9(μ-PPh2)2(μ3-η2-HCCPh): a new type of 5-vertex, 7-skeletal pair clust (1987) (16)
Crystal structure and fluxionality of the chiral cluster [HRu3(CCBut)(CO)7(dppm)] (dppm Ph2PCH2PPh2). A novel racemization mechanism (1988) (16)
Synthesis and crystal structure of (η5-C5H5)NiFe3(CO)7(μ-PPh2)(μ4,η2-HCCPri): a butterfly cluster with an unprecedented metal core stoichiometry (1989) (15)
The crystal and molecular structure of diaquadichlorotheophyllinecopper(II) (1979) (15)
Notes. Synthesis and characterization of monocyclopentadienyl niobium derivatives. X-Ray crystal structure of di-µ-chloro-µ-oxo-bis[dichloro(η-trimethylsilylcyclo-pentadienyl)niobium(V)], [{Nb(η-C5H4SiMe3)Cl2}2(µ-O)(µ-Cl)2] (1987) (15)
Synthesis of homo and hetero palladium–platinum bimetallic complexes; X-ray crystal structure of Pt2Cl2(µ-CO)(PPh3)3 (1984) (15)
SPECTROSCOPIC STUDY AND X‐RAY STRUCTURE OF BIS(N‐METHYLIMIDAZOLE)BIS(2,4,6‐TRICHLOROPHENOLATO)COBALT(II) (1980) (15)
Reactivity of Ph2P(Se)CH2C6H4CH2P(Se)Ph2 with [M3(CO)12] (M=Ru or Fe). Synthesis and characterization of the new carbene cluster [Ru3(mu3-Se)(mu3-H)(mu2-PPh2)(CO)6(mu2-CHC6H4CH2PPh2)]. (2003) (15)
An inspection into the class of bis(alkyne)-undecacarbonyl-quadro-tetraruthenium complexes. Crystal structure and dynamic behaviour of Ru4(CO)11 (μ4, η2-MeC2Ph)2 (1984) (15)
Acid−Base Reactions of Methylnickel Hydroxo, Alkoxo, and Amide Complexes with Carbon Acids. Studies on the Reactivity of Noncyclic Nickel Enolates (2007) (15)
Alkyne oligomerization and CO activation on ruthenium clusters. Synthesis and crystal structure of Ru3(CO)5(C12H20)(C19H30O). The stepwise formation of a heterocyclic ring without cluster degradation (1983) (15)
The crystal and molecular structure of hydrazinium tris(hydrazincarboxylato-N′,O)niccolate(II) monohydrate (1967) (15)
Zwitterionic metalates of group 11 elements and their use as metalloligands for the assembly of multizwitterionic clusters. (2006) (15)
Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Catalysts for Silane Alcoholysis under Homogeneous and Liquid-Liquid Biphasic Conditions (2007) (15)
Activation of a carbon—nitrogen triple bond in the presence of Ru3(CO)12 and H4Ru4(CO)12 (1984) (15)
Complexes of functional phosphines. 22. Cobalt(II) complexes with .beta.-keto phosphines and corresponding cobalt(III) enolates. Crystal and molecular structures of the fac and mer isomers of [Co{Ph2PCHC(O)Ph}3] (1993) (15)
Iridium(I) insertion into an aromatic carbon-hydrogen bond. Synthesis and structure of [Ir(H)(CO)(bq)(PPh3)2]PF6 (bq = 7,8-benzoquinolinato) (1989) (15)
Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes. (1998) (15)
The structure of (o‐phthalato)bis(pyridine)copper(II) with bridging and chelating o‐phthalate anions (1981) (15)
Low Oxidation Dinuclear Titanium Complexes with the Bridging .mu.-(Dimethylsilyl)biscyclopentadienyl Ligand. Crystal Structure of [{Ti(.eta.5-C5H5)}2(.mu.-Cl)2{.mu.-Me2Si(C5H4)2}] (1995) (15)
Nitrosyl derivatives of the unsaturated dihydrides [Mn2(μ-H)2(CO)6(μ-L2)] (L2 = Ph2PCH2PPh2, (EtO)2POP(OEt)2) (2011) (15)
The crystal and molecular structure of barium diaquadi(o-phthalato)cuprate(II) dihydrate. An example of the chelating behaviour of the o-phthalate anion (1978) (14)
[(Allylsilyl)(η-amidosilyl)-η5-cyclopentadienyl] Group 4 Metal Complexes: Synthesis, Reactivity, and Olefin Polymerization (2007) (14)
Carbon-hydrogen cleavage versus nitrogen-nitrogen cleavage in .mu.3-.eta.2 azoalkane ligands on the M3(CO)9 clusters of iron, ruthenium, and osmium (1991) (14)
Metal clusters as models of intermediates in organic syntheses. Reactions of the terminal dialkynes NR(CMe2CCH)2(R = H or Me) with [Ru3(CO)12] (1992) (14)
Polyfunctional ligands: comparative oxidative coupling of [E(PPh2)2]–(E = CH, N) with iodine (1995) (14)
Anionic (nitrophenyl)palladium(II) carbonyls. Crystal structure of cis-[PPh3(CH2Ph)][Pd(C6H3Me-2,NO2-6)Cl2(CO)] (1991) (14)
The influence of molecular hydrogen on the reaction between [Ru3(CO)12] and [Ni2(η-C5H5)(C2Ph2)]. Synthesis and crystal structure of the new heteropentametallic cluster [Ni2Ru3(η-C5H5)2(CO)6(µ-CO)2(µ4,η2-C2Ph2)] (1984) (14)
A novel reaction of CS2 with organocopper(I) complexes. Synthesis and structure of {tetra[µ-bis(diphenylphosphino)methane]di-µ4-trithio-carbonato}tetracopper(I)–toluene (1983) (14)
Addition reactions of O-bound cyclic nickel enolates to ?,?-unsaturated ketonesElectronic supplementary information (ESI) available: Further experimental and crystallographic details. See http://www.rsc.org/suppdata/cc/b3/b303062h/ (2003) (14)
Synthesis and Characterization of Tungsten Alkenyl−Carbyne Complexes [(dppe)(CO)2LW⋮CCHCCH2(CH2)nCH2CH2][BF4] (L = CO, MeCN, PMe3) and [(dppe)(CO)2XW⋮CCHCCH2(CH2)nCH2CH2] (X = Cl, Br, I). X-ray Crystal Structure of [(dppe)(CO)2ClW⋮CCHCCH2CH2CH2CH2] and 183W NMR Studies (1996) (14)
Synthesis and crystal structure of the new near-linear Rh2Mo trinuclear complex [(η5-C5H5)Rh(μ-CO)-(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)] (1990) (14)
Comparison of the closo trigonal-bipyramidal structures of .mu.3-.eta.2-.perp.-acetylene and -acetylide clusters: synthesis of (.eta.5-C5H5)NiFe2(CO)6(.mu.3-.eta.2-C.tplbond.CPr-iso) and x-ray structures of (.eta.-C5H5)NiFe2(CO)5(L)(.mu.3-.eta.2-C.tplbond.CR) (R = Pr-iso, L = CO; R = Bu-tert, L = PP (1991) (14)
1H-Pyrrolo[2,3-b]pyridine (HL) ligands in rhodium(I) and iridium(I) chemistry. Crystal and molecular structures of [Rh2(µ-L)2(nbd)2] and [Rh4(µ-Cl)2(µ-L)2(µ-CO)2(CO)2(nbd)2] (1985) (14)
Oxidative Addition of Allylammonium BPh4- to Nickel(0): Synthesis, Crystal Structure, Fluxional Behavior, and Catalytic Activity of Chiral [(η3-allyl)(NH3)(PCy3)Ni]BPh4 (2000) (14)
[Mo2(η5-C5H5)2(μ-PPh2)(CO)4], a Reactive 33-Electron Binuclear Radical (1999) (14)
Trinuclear iridium and rhodium complexes: the solution to a puzzle involving the multiple coordination possibilities of 1,8-naphthyridine-2-one ligands (1996) (14)
Phosphane-Substituted Selenido−(carbonyl)iron and −(carbonyl)ruthenium Clusters: Structures, Fluxionality and Reactivity (2003) (14)
Crystal structure of 2:1 molecular complexes of caffeine with hexaaquamagnesium(II) bromide and hexaaquamanganese(II) triiodide iodide (1981) (14)
Easy Access to Phosphido-Selenido Clusters. Reaction of [Ru3(CO)12] with Ph2(pyth)PSe {pyth=5-(2-Pyridyl)-2-Thienyl} and Crystal Structure of [Ru3(μ3-Se)(μ-PPh2)(μ-pyth)(CO)6{P(pyth)Ph2}] (2001) (14)
Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion. (2004) (14)
Occurrence of a µ-SiF interaction in bimetallic trifluorosilyl complexes (1992) (13)
Multiple oxidative addition of diphenyl-2-thienylphosphine selenide to [Ru3(CO)12]: crystal and molecular structure of [Ru3(μ3-Se)(μ-PPh2)(μ-η1:η2-C4H3S)(CO)6{P(C4H3S)Ph2}] (2000) (13)
Synthesis, crystal structure, and stereochemical non-rigidity of octacarbonyl-µ3-(1,3,6-trimethylhexa-1,3,5-triene-1,5-diyl)-triangulo-tri-iron (1976) (13)
The hydrogenation of cis- and trans-1,3-pentadiene in the presence of (η5-C5H5)NiOs3(μ-H)3(CO)9. A new method to carry out homogeneous or heterogeneous catalysis and the analysis of the products in a gas-chromatographic apparatus (1984) (13)
Reactions of the ‘ferrole’ complex [Fe2(CO)6(C2Et2)2] with group 15 donor ligands and with alkynes. Stepwise formation and disengagement of tropones. Crystal and molecular structure of [Fe2(CO)5{(CEt)2 CO(CEt)2 CHCPh}] (1996) (13)
The ruthenium cluster anion [HRu3(CO)8(.mu.-PPh2)2]- as a building block for the assembly of bimetallic tetranuclear clusters: synthesis, structure, fluxionality, and reactivity. Syntheses and structures of [H2Ru3Rh(.mu.-CO)(CO)6(PPh3)2(.mu.-PPh2)(PPhC6H4)] and [H2Ru3Ir(.mu.-CO)(CO)7(PPh3)(.mu.-PPh2 (1990) (13)
Preparation and X-ray structure of a trinuclear rhodium complex with the polydentate 1,8-naphthyridine-2-one (onapy) ligand: [Rh3(μ3-onapy)2(CO)2(cod)2](ClO4)·1.5C2H4Cl2 (1986) (13)
Multi-site bonded hydrocarbyls on osmium clusters. The reactions of hydridoacetylide and hydridovinylidene-osmium clusters with [(η-C5H5)Ni(CO)]2 and of (η-C5H5)2Ni2(HC2But) with osmium carbonyls. Synthesis and crystal structure of (η-C5H5)Ni(μ-H)Os3(CO)9(μ4-η2-CCHBut) (1983) (13)
Reactivity of double thioureas towards metal complexes. Synthesis and crystal structure of [{(μ-H)Ru3(CO)9}2{SC(NPh)N (Et)(CH2) 2NH(PhN) CS}] (1993) (13)
Multiple Oxidative Addition of Ph2(C5H4N)PSe to [Ru3(CO)12] − Structural Characterization of [Ru3(µ3‐Se)(µ‐PPh2)2(µ‐C5H4N)(µ3‐C5H4N)(CO)6] Containing Two Differently Metalated 2‐Pyridyl Fragments (2001) (13)
Synthesis and reactivity of a novel unsaturated dimanganese hydride complex, [Mn2H2(CO)6{(OEt)2POP(OEt)2}]. X-Ray Structure of [Mn4Cu2H6(CO)12{(OEt)2-POP(OEt)2}2] (1985) (13)
Synthesis and Crystal Structure of (η-C5H5)2Ni2Ru2(CO)6[C2(H)C(=CH2)CH3]. A new heterometallic cluster with an uncommon metal atom framework (1982) (13)
NiRu4(CO)9(µ-PPh2)2(µ4-CCPri)2: a pentanuclear mixed metal cluster with a novel metal framework (1982) (13)
The reactions of (η5-C5H5)NiO(s)3(μ-H)3(CO)9 with group V donor ligands. Spectroscopic characterization of the disubstituted derivatives, and crystal structure of (η5-C5H5)NiO(s)3(μ-H)3(CO)7(PMe2Ph)2 (1986) (13)
Sulfido–carbonyl ruthenium clusters derived from tertiary phosphine sulfides (2003) (13)
Crystal and molecular structure of thiocarbohydrazide (1969) (13)
μ-Amido complexes of ruthenium carbonyl. Asymmetric versus symmetric bridging preference of the monodeprotonated derivatives of 1,2-arenediamines. Crystal structure of [Ru3(μ-H)(μ-H3N2-4,5-Me2-1,2-phenylene)] (1989) (13)
Crystal structure of a novel tetranuclear dithiocarboxylato copper(I) complex, [{Cu(S2CC6H4Me-p)}4(PPh3)2] (1989) (13)
Platinum(II) complexes containing a cationic amine ligand: crystal structure of [(2-aminoethyl)ammonium]trichloroplatinum(II) (1985) (13)
A novel class of nitrosyl A-frames. Crystal and molecular structure of [Pt2Cl2(.mu.-NO)(.mu.-dppm)2]BPh4.cntdot.CH2Cl2 (1992) (13)
Dynamic behaviour of carbon-metallated palladium hydrazone complexes. Crystal structures of [{Pd[CH2CMe2C(N–NMePh)Me]Cl}2] and [{Pd[CH2C(N–NMePh)But]Cl}2] (1985) (13)
The reaction of (ηC5-C5H5NiOs(μ-H)3(CO)9 with group V donor ligands: spectroscopic characterization of the monosubstituted derivatives. An example of monodentate bis(diphenylphosphino)methane on a heterometallic cluster. (1984) (13)
Phosphido-phosphinidene transformations. Ru3(CO)6-[P(Ph)C(Ph)C(Ph)](μ-PPh2)2: A novel six vertex nido-pentagonal bipyramidal structure via reductive elimination and acetylene insertion at a triruthenium centre (1990) (12)
Ring-expansion reactions of ligand-bridged dinuclear cobalt complexes with alkynes and with allene: crystal and molecular structures of [Co2{.mu.-PPh2CHCHC(O)CHCHPPh2}(CO)4] and [Co2{.mu.-PPh2CHCHC(O)C(CH2)2}(.mu.-PPh2)(CO)3] (1993) (12)
Synthesis and Characterization of Tungsten Alkenyl−Carbyne and Alkenyl−Ketenyl Complexes Containing Dithio Ligands. X-ray Crystal Structure and MO Analyses of [(dppe){κ3(S,C,S)-S2CPCy3}W⋮CCHC(CH2)3CH2][BF4] (1997) (12)
Reaction of [Pt{Fe(CO)3(NO)}2(PhCN)2] with diphenyl(2-pyridyl)phosphine selenide. Crystal structure of [(CO)3Fe(μ3-Se) {Pt(CO)P(2-C5H4N)Ph2}2]and its theoretical study (2002) (12)
Fast orthometalation reactions at a binuclear dirhodium(II) complex. Synthesis, crystal structure and reactivity of Rh2(O2CCH3)3[(C6H4)PPh2]·(HO2CCH3)2 (1989) (12)
Unexpected and then rational synthesis of a new class of anionic phosphino–oxazoline ligands; structure and catalytic properties of a ruthenium complex (2000) (12)
Platinum(IV) complexes containing a cationic amine ligand: crystal structure of [(2-aminoethyl)ammonium]pentachloroplatinum(IV) monohydrate (1984) (12)
Bi-imidazole (H2bim) and bibenzimidazole η3-allylic complexes of palladium(II). Mono- and tetra-nuclear palladium(II) and heteronuclear palladium(II)–rhodium(I) complexes. Crystal structure of [Pd4(η3-C3H5)4(µ-bim)2]·CH2Cl2 (1983) (12)
Insertion reactions of alkynes and organic isocyanides into the palladium-carbon bond of dimetallic Fe-Pd alkoxysilyl complexes. (2006) (12)
Synthesis, characterization, and reactivity of ruthenium diene/diamine complexes including catalytic hydrogenation of ketones. (2007) (12)
New approach to the chemistry of polysulfides using diphosphanylmethanide complexes of manganese(I). (2001) (12)
A ten year stroll in the chemistry of nickel-containing heterometallic clusters of the iron triad synthesis, structure and catalytic activity (1988) (12)
Synthesis and Structure of [(Ph3P)3Ir(μ3‐H)(μ‐H)2Ag2(OSO2CF3)(H2O)]‐(CF3SO3), a Complex with a Bent Ag‐Ir‐Ag Chain (1986) (12)
The crystal and molecular structure of bis(thiocarbohydrazide-N,S)cadmium dichloride (1971) (12)
Polynuclear pentamethylcyclopentadienyl chloro, oxo, and hydroxo zirconium(IV) complexes; X-ray structure of [{(η5-C5Me5)ZrCl}3(µ-Cl)4(µ3-O)] and [{(η3-C5Me5)ZrCl2(H2O)(µ-OH)}2] (1990) (12)
Heteronuclear rhodium, palladium, platinum, and gold organoimido complexes from dinuclear organoamido rhodium precursors. (2004) (12)
Synthesis and crystal structure of heptacarbonyl-µ3-(pent-1 -en-1 -yl-3-ylidene)-(η-1,2,3-triethylcyclopentadienyl)-triangulo-tri-iron (3 Fe–Fe) : the cleavage of an acetylenic triple bond on a metal-atom cluster (1978) (11)
Cluster Growth Reactions with Selenido-Carbonyl Clusters − Synthesis, Characterisation and Theoretical Study of the Dimetallic closo Clusters [WRu3(μ4-Se)2(μ-CO)4(CO)6(L)2] (L = Phosphane) and of the Donor-Acceptor Adduct [(CO)5W(μ4-Se)Ru3(μ3-Se)(CO)7{P(CH2Ph)Ph2}2] (2004) (11)
Syntheses of 1,2-diamidobenzene complexes of molybdenum. Crystal structure of the complex cis-dicarbonyl 1,2-diamidobenzenebis(triphenylphosphine)molybdenum [Mo{(NH)2C6H4}(CO)2(PPh3)2] (1993) (11)
Synthesis and crystal structure of heptacarbonyl-Hydrido-(t-butylethynyl)-(2,4-hexadiene)-triangulo-triruthenium, HRu3(CO)7(C6H9)(C6H10) (1979) (11)
Preparation and X-ray structure of a rhodium(III)–rhodium(I) pyrazolate complex with a mercury atom asymmetrically bridging the metal atoms (1984) (11)
Notes. Crystal structure of [Ni2Ru3(η-C5H5)2(CO)9(µ5-PPh)], an open square-pyramidal cluster obtained via condensation of co-ordinatively unsaturated [Ru3(µ-H)(CO)9(µ-PPh2)] with [Ni2(η-C5H5)2(CO)2] (1986) (11)
Olefin trifluoroacetato derivatives of copper(I) and their olefin/CO exchange reactions (2005) (11)
Facile benzene ring contraction to cyclopentene derivatives during the copper promoted oxidation of phenol with dioxygen (1995) (11)
Nickel nitrosyl complexes with diphosphines. The crystal and molecular structure of [(dppe)(ON)Ni(µ-dppe)Ni(NO)(dppe)][BF4]2(dppe = Ph2PCH2CH2PPh2) (1990) (11)
Manganese(I) carbonyls with σ-bonded alkynyl ligands. The crystal structure of [Co2 (CO)6][PhCCMn(CO)4{P(C6H11)3}] (1984) (11)
Half‐Sandwich η5‐Indenyl‐ and η6‐Areneruthenium(II) Complexes Bearing the Chiral Ligand (4S)‐2‐[(Sp)‐2‐(Diphenylphosphanyl)ferrocenyl]‐4‐(methylethyl)oxazoline (FcPN) (2007) (11)
Polynuclear Rhenium and Manganese Selenido‐Carbonyl Complexes − Reversible Square to Butterfly Conversion of the Re4Se2 Core by CO Loss in [Re4(µ3‐Se)2(CO)16(PPh3)2], and the Crystal Structure of [Mn2(µ2‐Se2)(CO)5(PPh3)2] (2004) (11)
Formation of Metallamacrocycles from Palladium(II), Platinum(II) and Copper(I) Complexes and the Ditopic Ligands [{p‐(Ph2PO)C6H4}2CMe2], [{2‐Ph2PO‐3,5‐(Me3C)2C6H2}2S], [{p‐[(C10H6O)2PO]C6H4}2CMe2] (2001) (11)
Iron/gold carbide clusters containing Fe5Au or Fe5Au2 skeletons: X-ray crystal structure of [Fe5CAu2(CO)14(dppm)] (1998) (11)
Oxidative-addition reactions on planar chloranilate rhodium systems. Crystal structure of [Rh2(µ-C6Cl2O4)Me2I2(CO)2(PPh3)2] (1996) (11)
Competitive Insertion of Isocyanide into Tantalum−Amido and Tantalum−Methyl Bonds (2002) (11)
Notes. Nuclear magnetic resonance evidence for three different isomers of [Ru3(µ-H)(µ-bzim)(CO)9(PPh3)](bzim = benzimidazolate). Crystal structure of [Ru3(µ-H)(µ-bzim)(CO)10]·Me2CO (1990) (10)
[(ClAu)3(triphos)] as a Building Block for the Synthesis of Heterometallic Clusters. Crystal Structure of [{Fe2(μ-CO)(CO)6(μ-HCCPhH)Au}3(triphos)]: A Compound Containing Three Independent Cluster Units Linked by a Triphosphine Ligand (1997) (10)
Degradation and Oxidation of 1,1,1-Trichloroethane-Mediated Rhodium Compounds. A New Entry in the Synthesis of Bridging Vinylidene and .eta.1-Chlorovinyl Complexes (1994) (10)
Reactions of cationic vinylidene complexes [Fe{=C=C(R1)R2}(η-C5H5)(dppm)]+ [dppm=bis(diphenylphosphino)methane] with nucleophiles : stereoselective synthesis and crystal structure of the alkenyl complex (E)-[Fe{C(H)=C(Me)Ph}(η-C5H5)(dppm)] (1992) (10)
Niobium(III) monocyclopentadienyl isocyanide, acetylene, and diene complexes. X-ray crystal structures of Nb(.eta.5-C5Me5)Cl4(CN-2,6-Me2C6H3) and Nb(.eta.5-C5Me5)Cl2(CN-2,6-Me2C6H3)3.1/2MeC6H5 (1994) (10)
Oxidative Addition von Phosphor‐Yliden an Ru3(CO)12 (1990) (10)
Intramolecular dealkylation of chelating diamines with Ru(II) complexes. (2002) (10)
Octahedral ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(isopropyl)oxazoline (FcPN). X-Ray crystal structures of fac-[RuCl2(PMe3)2(FcPN)] and fac-[RuCl2(dppm)(FcPN)] (dppm=bis(diphenylphosphino)methane) (2001) (10)
The oxidative addition of a vinylic CH bond of divinyl(phenyl)phosphine at M3(CO)12 carbonyls (M Ru, Os). Stepwise formation and crystal structure of [(μ-H)Ru3(CO)8{PPh(CHCH2)2}{μ3-PPh(CHCH2) (CHCH)}] (1997) (10)
Reaction of triphenylphosphine with the anionic cluster [HRu3(CO)11]- revisited: isolation, crystal structure, and isomerization of [NEt4][HRu3(CO)8(PPh3)(PPhC6H4)] (1989) (10)
Identification of a surface organometallic species anchored on a thiourea-functionalized silica xerogel. Crystal structure of the model ruthenium compound [(.mu.-H)Ru3{.mu.3-SC(NHPr)NPh}(CO)9] (1992) (10)
Preparation and properties of thiophosphinito-bridged rhodium complexes. Crystal structure of [Rh2(μ-SPPh2)2(COD)2] (1988) (10)
Some insertion reactions into the Ti–Me bond of [Ti(η5-C5Me5)MeCl2]; crystal structures of [Ti(η5-C5Me5)(η2-COMe)Cl2] and [{Ti(η5-C5Me5)}2(µ-Cl)2{µ-η4-CH2-(2,6-me2C6H3N)CC(NC6H3Me2-2,6)CH2}] (1993) (10)
Hexaaquanickel(II) dipotassium tetrahydrogen tetra-o-phthalate tetrahydrate, K2[Ni(H2O)6][C8H5O4]4.4H2O (1984) (10)
Reactivity of metallic copper with acidic organic compounds in the presence of molecular oxygen. Crystal structure of [{Cu(NCO)(py)2}2]·H2O (1989) (10)
The crystal and molecular structure of di‐μ‐(N,N‐diethylnicotinamide‐O,N)‐diisothiocyanatomanganese(II) (1973) (10)
Unprecedented trimetallic cluster with an in-plane .mu.3-hydride ligand. X-ray crystal structure of [Mo2(CO)8(.mu.-dppm)(.mu.3-H)(.mu.-AuPPh3)] (1992) (10)
Electrophilic Attack of Group 11 and 12 Metal Fragments on the Dinuclear Anions [M2(.mu.-.sigma.:C2Ph)(CO)4(.eta.-C5H5)2]- (M = Mo, W). Crystal Structure of the Transversally Bridged Alkyne Complex [W2(.mu.-PhC2AuPPh3)(CO)4(.eta.-C5H5)2] (1995) (10)
Reaction of diphenyl(vinyl)phosphine with carbonyls [M3(CO)12](M = Ru or Os); oxidative addition at [Ru3(CO)12]. Spectroscopic characterization and crystal structure of [Ru3(µ-H)(CO)8(Ph2PCHCH2)(µ3-Ph2PCHCH)] (1990) (10)
Activation of the CN Triple Bond of Substituted Benzonitriles in the Presence of Ru3(CO)12, Acetic Acid and Molecular Hydrogen. Crystal Structure of (μH)2Ru3-(CO)9(μ3NCH2C6H4OMe) (1986) (10)
Low-temperature N-O bond cleavage of nitrogen monoxide in heterometallic carbonyl complexes. An experimental and theoretical study. (2008) (10)
Synthesis and structure of chlorobis[3,6-di(2-pyridyl)pyridazine]copper(II) chloride pentahydrate (1982) (10)
The first ruthenium-alkyne-dihydride reported is now recognized as an intermediate in the homogeneous hydrogenation of diphenylacetylene: Crystal structure of (μ-H)2Ru3(CO)9(μ3-η2-∥-C2Ph2) (1993) (10)
Halogenation of Alkenes in Five‐Coordinate Platinum(II) Complexes – A Route to Stable (β‐Haloalkyl)platinum(IV) Species (1999) (9)
Stepwise selenium transfer from tertiary phosphine selenides to [Ru3(CO)12]. Structural characterization of the primary product [Ru3(μ3-Se)(μ3-CO)(CO)7(PPh3)2] (2002) (9)
Synthesis of [Co2(µ-PPh2C3H4)(µ-PPh2)(CO)4]; its reactions with P(OMe)3 and with alkynes (1993) (9)
(PPh4)[Mn3(CO)12(.mu.3-H)(.mu.-Hg{Mo(CO)3(.eta.5-C5H5)})]: The First Example of a Mercury-Containing Planar Triangulated Rhomboidal Metal Cluster (1994) (9)
Hexa- and nona-nuclear heterometallic clusters based on mercury-capped MCo3(M = Fe or Ru) tetrahedral units (1992) (9)
Trinuclear osmium clusters containing aminophosphine and phosphinoamido ligands, synthesis and molecular structure of Os3(CO)11(PPh2NHPh) and HOs3(CO)8(PPh2NHPh)(PPh2NPh) (1987) (9)
Synthesis and crystal structure of the mixed iridium(III) and copper(II) complex, [IrCl(PPh3)2(µ-dppn)(µ-NO)CuCl][PF6]2, [dppn = 3,6-bis(2′-pyridyl)pyridazine], with a nitrosyl group bridging two different metals (1983) (9)
Reactivity of the iridium nitrosyl complex [Ir(NO)(paa)(PPh3)2][PF6]2(paa = 2-pyridinecarbaldehyde azine) with nucleophiles: insertion of NO into a methinic C–H bond; crystal structure of [Ir{(2-C5H4N)CHN–NC(NOH)(2-C5H4N)}{Me-(EtO)CNH}(PPh3)2][PF6]2 (1989) (9)
Preparation of imido pentamethylcyclopentadienyl molybdenum(IV) complexes X-ray molecular structure of cis-[MoCp* Cl(μ-NtBu)]2 · C6H6 (1997) (9)
New rhodium(I) complexes with the bridging 1,8-naphthyridine-2-one ligand (1984) (9)
MONONUCLEAR AND BINUCLEAR O-XYLYLENE DERIVATIVES OF PD(II) (1998) (9)
Synthesis, Characterization and Olefin/CO Exchange Reactions of Copper(I) Derivatives Containing Bidentate Oxygen Ligands (2005) (9)
Fischer-type alkyl(hydrazino)carbene complexes: new synthetic potential in comparison with aminocarbene complexes (2001) (9)
Syntheses of low-valent nitrosyl complexes of rhenium and X-ray structure oftrans-[ReCl(NO)(Ph2PCH2CH2PPh2)2][NO3]2 with nitrosyl derived nitrates (1992) (9)
Kinetics and mechanism of the reaction between dimethyl sulphoxide and dichloro(pyridine-2-carboxylato)platinate(II) anion and the cis-trans isomerization of the products. X-Ray crystal structure of trans-(O,S)chloro(dimethyl sulphoxide)(pyridine-2-carboxylato)platinum(II) (1986) (9)
Iridium(III)cis-dihydrido complexes with 3,6-bis(2′-pyridyl)pyridazine. Crystal structure of the pyridazinyl complex [{IrH2(PPh3)2}2{µ-C4HN2(C5H4N)2-3,6}]PF6 (1988) (9)
Iridium nitrosyl complexes: insertion of NO into a methinic C–H bond promoted by nitriles. X-Ray crystal structure of [Ir{(2-C5H4N)–CHN–NC(NOH)–(2-C5H4N)}-{Me(EtO)CNH}(PPh3)2][PF6]2 (1987) (9)
A dinuclear bis(1,3-diene) complex of titanium: crystal and molecular structure of .mu.-[o-(CH2)2C6H4] (.mu.-Cl)2[(.eta.5-C5Me5)Ti]2, containing an unprecedented "o-xylidene" bridging group (1988) (9)
Cluster growth reactions with selenido–carbonyl clusters. Synthesis and structural characterization of [M2Ru2(µ4-Se)2(µ-CO)4(CO)6(PPh3)2] (M = Mo or W)‡ (1998) (9)
Synthesis and crystal structure of a new mixed-metal cluster, (η-C5H5)3Ni3Os3(CO)9. An example of a high yield pyrolytic synthesis (1981) (9)
Iodo Derivatives of Bimetallic Fe—Pd and Fe—Pt Complexes. Crystal Structures of (2001) (9)
Synthesis and crystal structure of [Ru2(CO)6(µ-PPh2)(µ-PCHCHC6H4)], a complex with an unprecedented phospha-bicyclic ligand, obtained from [Ru3(µ-H)(CO)8(Ph2PCHCH2)(µ3-Ph2PCHCH)]via reductive elimination reactions (1990) (9)
New 2,4,6-trinitrophenylpalladium(II) complexes. Crystal and molecular structure of trans-2,4,6-trinitrophenyl(chloro)bis(triphenylarsine)palladium(II) (1990) (9)
Aminocarbyne coupling reactions leading to the bis(amino)acetylene complexes trans-[MF(η2-MeHNCCNHMe)-(Ph2PCH2CH2PPh2 (1993) (9)
Polynuclear acetylide chemistry: acetylide to acetylene transformation at a binuclear center via carbon-carbon and carbon-nitrogen bond-forming reactions. X-ray structure of Os2(CO)6[.mu.-.eta.2-.dblvert.-C[C(NHBu-tert)(NEt2)]CPh](.mu.-PPh2) (1990) (9)
Synthesis, crystal structure, electrochemistry and molecular-orbital analysis of the piano-stool dimer [Mo2(η-C5H5)2(CO)4(NC5H4PPh2-2)2] (1992) (9)
Asymmetric Induction and Configurational Stability at the Metal Center in Half-Sandwich (η6-p-Cymene)ruthenium(II) and (η5-Pentamethylcyclopentadienyl)rhodium(III) Complexes Containing Chiral Phosphito-N and Phosphonito-N Ligands (2002) (9)
Preparation and reactivity of halide-bridged binuclear carbonyl manganese and rhenium anions, [M2(µ-X)(CO)8–2n{(EtO)2POP(OEt)2}n]–(X = halide; M = Mn, n= 1 or 2; M = Re, n= 1). X-Ray crystal structure of [Mn2Au(µ-Br)(CO)6–(µ-tedip)(PPh3)] (1987) (9)
Rhodium(I), Palladium(II) and Platinum(II) Coordination Chemistry of the Short-Bite Chiral Ligands (Sc)-N,N-Bis(diphenylphosphanyl)-sec-butylamine, (Ra,Ra)-N,N-Bis(binaphthylphosphonito)phenylamine and (Ra,Sc)-N-(Diphenylphosphanyl)-N-(binaphthylphosphonito)-sec-butylamine (2004) (9)
Stereoselective oxidative-addition reaction of molecular iodine and mercury(II) halides to rhodium dithiolate compounds. Crystal structure of [Rh2{µ-S(CH2)2S}Cl2(CO)2(PPh3)2] (1994) (8)
Program for crystal setting and data reduction on a PW 1100 diffractometer using a simple method based on real space (1980) (8)
Synthesis, characterization and olefin/CO exchange reactions of pyrazolylborato complexes of copper(I). (2006) (8)
Polynuclear selenido–carbonyl manganese complexes derived from tertiary phosphine selenides (2003) (8)
Mixed cobalt/gold clusters based on octahedral or prismatic Co6C skeletons (2000) (8)
The Anion of the Pentacarbonyl[(trans‐2,6‐dimethylmorpholino)(methyl)carbene]chromium Complex in the Reactions with Nitroalkenes (1998) (8)
Crystal and molecular structure of thiocarbohydrazide dihydrochloride dihydrate (1971) (8)
Isolation of polynuclear platinum complexes in the ammination reaction of activated olefins. X-Ray crystal structure of a diplatinum(II) perchlorate salt bridged by an ammoniodiethylide group (1982) (8)
Synthesis of the pseudohalide-dinitrogen complexes trans-[ReX(N2)(Ph2PCH2CH2PPh2)2] (X = NCS, NCO or N3) and crystal structures of the isothiocyanate and azide complexes (1993) (8)
A Study on the Coordinative Versatility of the Zwitterionic S,N,S Ligand EtNHC(S)Ph2P=NPPh2C(S)NEt in Its Anionic, Neutral and Cationic Forms – Determination of Absolute pKa Values in CH2Cl2 of RhI Complexes (2008) (8)
Reactivity of rhodium(III) complexes containing chelating pentachlorophenyl ligands. Molecular structures of fac-[Rh(C6Cl5)3(py)] and mer-[Rh(C6Cl5)3(tBuNC)3] (2000) (8)
New synthesis of Fischer-type hydrazino(alkyl) complexes. First X-ray characterisation of a chelate hydrazino derivative (1998) (8)
The crystal structure of strontium diiodate(V) monohydrate (1972) (8)
New electron rich Ru3P4 and Ru4P3 phosphido clusters: synthesis and molecular structures of the expanded triangular and butterfly clusters (μ-H)Ru3(CO)6(μ-PPh2)3[μ-P(Ph)C6H4] and (μ-H)2Ru4(CO)10(μ3-PPh)(μPPh2)2 (1993) (8)
Novel co-ordination modes for bimetallic HgCo and HgMo fragments when bonded to clusters; X-ray crystal structure of RuCo3(µ-CO)3(CO)9[µ3-HgCo(CO)4] (1984) (8)
Conversion of a .mu.-.eta.2-acetylide to a .mu.-.eta.2-.dblvert.-acetylene via successive nucleophilic additions. X-ray structure of Os2(CO)6[.mu.-.eta.2-C{C(NH-tert-Bu)(S-n-Bu)}CPh](.mu.-PPh2) (1987) (8)
Reorientation of the alkyne moiety in the heterometallic cluster [FeCo2(CO)9(EtC2Et)], induced by phosphine, phosphite, or isonitrile substitution for CO. Crystal structure of [FeCo2(CO)8(PPh3)(EtC2Et)] (1988) (8)
Binuclear complexes of ruthenium with diphosphines and bridging benzene-1,2-diamide. X-Ray crystal structure of [Ru2{µ-1,2-(NH)2C6H4}{µ-(Ph2P)2CH2}(CO)2(PPh3)2]·C6H5Me (1991) (8)
The crystal and molecular structure of diaquobis(N,N-diethylnicotinamide)diisothiocyanatozinc (1973) (8)
Synthesis and characterization of an unusual tetranuclear rhodium complex; X-ray molecular structure of [Rh4(µ-Cl)2(µ-az)2(µ-CO)2(CO)2(nbd)2](az = 7-azaindolate; nbd = norborna-2,5-diene) (1984) (8)
The crystal structure of dipotassium hydrogen diiodate(V) chloride (1972) (8)
Reactions of [Ni2(η-C5H5)2{HC2C(CH2)CH3}] with [M3(CO)12](M = Ru or Os) in the presence of hydrogen. Synthesis and crystal structure of the new heterotetrametallic complex [Ni2Fe2(η-C5H5)2(CO)6{C2(H)C(CH2)CH3}] and spectroscopic characterization of a planar isomer (1984) (8)
Synthesis of trinuclear complexes with mixed bridging ligands. X-Ray structure of [Pd{Rh(µ-pz)(µ-SBut)(CO)2}2](pz = pyrazolate) (1991) (8)
Reactions of the unsaturated hydroxo complex [W2Cp2(OH)(μ-PPh2)2(CO)]BF4 with mono- and bidentate ligands having E-H bonds (E = O, S, N). (2012) (8)
From Methyl to Acetyl Complexes. An Example of Alkyl Migration in Heterotrinuclear Systems. Crystal and Molecular Structure of [{Rh(.mu.-pz)(.mu.-StBu)I(COMe)P(OMe)3}2Pd] (1995) (8)
Synthesis and crystal structure of (η-C5H5)NiRu3(CO)6(C6H9). A new complex obtained by insertion of a nickel atom into a Ru3 cluster (1979) (8)
Reactions of NiX2(dppe) (X Cl, Br) with Na[Co(CO)4]. Synthesis and crystal structure of Co2(μ-CO)2(CO)4(dppe) (dppe = Ph2PCH2CH2PPh2) (1983) (8)
The crystal and molecular structure of bis(hydrazinecarboxylato-N',O)-nickel dihydrate and comparisons with other complexes of the ligand (1970) (8)
Behaviour of thiocarbonohydrazidium cation as a ligand. Crystal and molecular structure of dichloro(1H+-thiocarbonohydrazidium-NS)-copper(II) chloride (1975) (8)
Carbonyl clusters with a capping methylidyne phosphonate ligand crystal structure of [CO3(CO)9{η1-μ3-[CP(O) (OEt)2]}] (1997) (8)
Metal complexes of P(Ph2)CH2(Ph2)PSe. Crystal structure of [Ni{P(Ph2)CH2(Ph2)PSe}2]Cl2·2EtOH (1998) (8)
On the reaction of Ph2PNHPPh2 with RNCS (R=Et, Ph, p-NO2C6H4): preparation of the zwitterionic ligand EtNHC(S)Ph2P==NPPh2C(S)NEt (HSNS) and the zwitterionic metalate [(SNS)Rh(CO)]. (2005) (8)
Synthesis and crystal structure of [NiOs3(η-C5H5)(µ-H)2{µ-Cu(PPh3)}(CO)9]. Hydrogenation–dehydrogenation reactions of dienes and alcohols with heterogeneous catalysts derived from [NiM3(η-C5H5)(µ-H)2(µ-X)(CO)9][M = Ru, X = H; M = Os, X = Cu(PPh3)] (1989) (8)
Studies on chelates of hydrazinecarboxylic acid with bivalent metals. The crystal and molecular structure of bis(hydrazinecarboxylato‐N',O)cadmium monohydrate (1969) (8)
The crystal structure and reactivity of [(η-C5H5)NiOs3(µ-H)3(CO)8(PPh2H)]; 1H and 31P nuclear magnetic resonance spectroscopic characterization of [(η-C5H5)NiOs3(µ-H)2(µ-HgBr)(CO)8(PPh2H)] and related complexes (1986) (8)
An unusual mixed-valence palladium(I)-palladium(II) cluster: crystal structure of [Pd4(μ-Cl)3(μ-dppm)2Cl2][BF4] (dppm=Ph2PCH2PPh2) (1988) (8)
New synthetic approaches to Mn2(CO)10-n Ln derivatives (L = phosphines): Their catalytic activity in the homogeneous hydrogenation of diphenylacetylene and the crystal structure of Mn2(CO)9(PPh2H) (1989) (8)
The crystal structure ofbis(hydrazincarboxylato-N',O) cadmium (1968) (7)
Tris(pentafluorophenyl) neutral and anionic five-co-ordinate complexes of rhodium(III). Crystal structures of [Rh(C6F5)3(PEt3)2] and [Rh(C6F5)3(AsPh3)2] (1990) (7)
Crystal and molecular structure of calcium hydrazinecarboxylate monohydrate (1971) (7)
Thiocarbonylrhodium complexes with pyrazolate-type ligands (1981) (7)
Synthesis and X-ray characterization of [RhCl(C2H4)(PiPr3)]2. Multinuclear NMR and DFT investigation of its solid-state and solution reaction with dihydrogen. Ethene and propene hydrogenation by the solid Rh-hydrides. (2009) (7)
Synthesis and characterization of [N(PPh3)2]+ cyanometallates. Crystal structure of [N(PPh3)2]3[Fe(CN)6]·2H2O (1993) (7)
Syntheses, crystal structures, and Raman and resonance Raman spectroscopy of platinum(II), platinum(IV), and halogen-bridged chain platinum(II,IV) complexes involving the terdentate ligand 3-methyl-3-azapentane-1,5-diamine(4Me-dien) (1989) (7)
Crystal and molecular structure of carbohydrazide (1972) (7)
[Pt2(μ-NO)(μ-dppm)2Cl2]BF4: the first A-frame complex with a nitrosyl bridgehead (1990) (7)
Tetra- and tri-nuclear rhodiumpalladium complexes with the 1,2,4-triazolate ligand. Crystal structure of (η3-C3H5)2Pd2Rh2(μ3-tz)2Cl2(CO)4 (1985) (7)
β-Elimination and insertion of CNR in transient pentamethylcyclopentadienyl-imido-tantalum dialkyl complexes. X-ray structure of [TaCp*{N(2,6-Me2C6H3)}(CH2CH2)(PMe3)] (1998) (7)
Synthesis of mixed-metal trinuclear complexes. X-Ray crystal structure of [(cod)2Rh2(µ3-C7H4NS2)2AgO2ClO2](cod = cyclo-octa-1,5-diene; C7H4NS2= benzothiazole-2-thiolate) (1986) (7)
Diolefin cationic rhodium complexes with sulfur donors. X-ray structure of [Rh(NBD)2(SEt2)]CIO4 (1983) (7)
Synthesis and characterization of an unusual heterobridged di-rhodium complex. X-ray molecular structure of [Rh2(μ-pz)2I2(CO)2(μ-dppm)] (1985) (7)
Heterobinuclear nitrosyl complexes. Part 2. Crystal structures of [(Ph3P)2(NO)Ir(µ-dppn)(µ-Cl)PdCl][PF6]2 and [(Ph3P)Cl2Ir(µ-NO)(µ-dppn)PdCl]PF6[dppn = 3,6-bis(2′-pyridyl)pyridazine] (1990) (7)
Reactions of the tetrafluoroborate complex [Mo2Cp2(κ(2)-F2BF2)(μ-PPh2)2(CO)]BF4 with mono- and bidentate ligands having E-H bonds (E = O, S, Se, N, P). (2012) (7)
Oxidative Addition of Iodomethane to Charge-Tuned Rhodium(I) Complexes (2009) (7)
Unexpected formation of a “flyover-bridged” complex by reaction of a “ferrole” derivative with Ph2PCH2PPh2 (dppm) and Me3NO. Crystal structure of [Fe2(CO)5(P-dppm){C2Et2(CO)C2Et2}] (1991) (7)
Mixed iron–silicon–tin complexes stabilized by a phosphinoenolate bridging ligand. Crystal structure of [(OC)3{(MeO)3Si}-Fe{µ-Ph2PCHC(O)Ph}SnBun2] (1996) (7)
Enantiomeric discrimination in coordination of sulfoxides to platinum(II): X-ray structure of the kinetically over thermodynamically favoured erythro cis-dichloro-bis(methyl-p-tolylsulfoxide)platinum(II) (1997) (7)
Structure of bis(3-acetylamino-1,2,4-triazole-O,N4)diaquacopper(II) sulfate pentahydrate (1989) (7)
The crystal and molecular structure of trichloro(1H+-thiocarbonohydrazidium-N,S)copper(II) monohydrate (1978) (7)
Studies of the stereoselective allylation of chiral benzaldimine chromium tricarbonyl complexes (2000) (7)
Pyrazolate A-frame rhodium complexes. Crystal structures of [Rh2(µ-dmpz)(CO)2(µ-dppm)2][ClO4] and [Rh2(µ-dmpz)I2(CO)2(µ-dppm)2][ClO4] (1985) (6)
Iridium(III) hydrido complexes with 2-pyridinaldazines. Crystal structure of [IrH2(mpaa)(PPh3)2]SbF6. Synthesis and characterization of homo- and hetero-nuclear complexes (1989) (6)
Reconsideration of the crystal structure refinement of the complex [Nb(η-C5H4SiMe3)2Cl2] (1990) (6)
Synthesis and crystal structure of trans-Pt[Fe(CO)3(NO)]2 (NCPh)2, a complex containing a linear metal chain (1985) (6)
Experimental and computational studies on the solvent-controlled cluster isomerism of Ru3(H)(CO)9(NPPh3) and related dynamics. (2006) (6)
Reactivity of binuclear pyrazolate-bridged rhodium complexes with isocyanides. Molecular structure of [Rh2(µ-pz)I2(CNBut)2–(µ-Ph2PCH2PPh2)2]BF4(pz = pyrazolate) (1989) (6)
Tetrachloroplatinate(II) and hexachloroplatinate(IV) salts of N,N,N′,N′-tetramethylethylenediammonium: significant differences in the conformation of the cation, as shown by infrared and x-ray diffraction data (1984) (6)
Formation of an anchored copper(II) complex on a thiourea-functionalized silica gel by in situ modification of the tethered ligating function (1994) (6)
Trapping a pseudo-Hofmann rearrangement on a ruthenium cluster. (2007) (6)
The crystal and molecular structure of di-μ-(N,N-diethylnicotinamide-O,N)-tetraisothiocyanatodizinc (1973) (6)
Carbonhalogen bond activation at Ru3(CO)12 (1983) (6)
Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru2(µ-C10H8N2)(CO)6]. Crystal structure of [Ru2(µ-C10H8N2)(CO)4{P(OPh)3}2](C10H10N2= 1,8-diaminonaphthalene) (1991) (6)
Reactivity of Ph2(2-C5H4N)PSe towards Ru3(CO)12 and mononuclear MCl2(PhCN)2 (M=Pd or Pt) complexes (2003) (6)
Composition-tunable metal–alkyl xerogels as precursors for homogeneously dispersed metals in amorphous silica matrix (1995) (6)
Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2]BF4 (2013) (6)
The crystal and molecular structure of aquabis[l‐(+)‐threo‐2‐amino‐1‐phenyl‐1,3‐propanediolato‐N,O1]copper(II) tetrahydrate (1979) (6)
Structures of chelates of hydrazinecarboxylic acid: bis(hydrazinecarboxylato-N',O)-zinc (1971) (6)
LIGAND BEHAVIOUR OF SUBSTITUTED THIOUREAS. CRYSTAL STRUCTURE OF A DINUCLEAR SULPHUR-BRIDGED RHODIUM(I) COMPLEX RHCL(CO)22MU -SC(NHPH)(NHPRN) (1993) (6)
The synthesis, using hexamethyldialuminium, and reactivity of new (1–5-η-cyclopentadienyl)methyl(nitrosyl)molybdenum complexes. Crystal structure of bromo(η5-cyclopentadienyl)methyl(nitrosyl)(triphenylphosphine)-molybdenum (1988) (6)
New tetraethyldiphosphite-bridged dinuclear manganese(I) carbonyl complexes; Synthesis of μ-hydride-bromide compounds Mn2(μ-H)(μ-Br)(CO)8-2n(tedip)n (n = 1, 2; tedip = (Eto)2pop(OEt)2). Crystal structures of Mn2(μ-Br)2(CO)4(tedip)2 and Mn2(μ-H)(μ-Br)(CO)4(tedip)2 (1984) (6)
The crystal structure of tris(acetonitrile)nitrosylbis(triphenylphosphine)iridium(III) dihexafluorophosphate. An unusual iridium nitrosyl hexacoordinate complex (1980) (6)
An anhydrous theophylline–copper(I) chloride compound, [Cu(C7H8N4O2)2Cl2] (1983) (5)
Synthesis and characterization of novel neutral σ-alkynylcarbonylnitrosyl molybdenum(0) and tungsten(0) complexes. Crystal structure of [Mo(CCnPr) (CO)2 (dppe) (NO)] [dppe = 1,2-bis(diphenylphosphino) ethane] (1996) (5)
The synthesis and crystal structure of two new heterometallic clusters: (η-C5H5)2Ni2Fe2(CO)6(μ3CO) and (η-C5H5)2Ni2Fe2(CO)6(C2Et2) (1980) (5)
A New Type of Doubly Silylamido-Bridged Cyclopentadienyl Group 4 Metal Complexes We thank the Dirección General de Enseñanza Superior e Investigación Científica (DGESEIC) for financial support of this work (Project PB97-0776). J.C. thanks the CAM for a Postgraduate Fellowship. (2001) (5)
A new, mixed ruthenium–nickel cluster. Synthesis and X-ray crystal structure of (η5-C5H5)NiRu3(CO)9C·C(H)But (1979) (5)
Zirconium and Hafnium Complexes with (Allylsilyl)(η‐amidosilyl)‐η5‐cyclopentadienyl Ligands: Synthesis, Structure and Reactivity (2005) (5)
Ligand substitution and growth reactions with Ru3Se2 nido clusters. Coordination isomerism in [WRu3(μ4-Se)2(μ-CO)4(CO)7(L)] (L = phosphine ligand) and electrochemical behaviour of the Ru3MSe2 core clusters (M = Ru, W) in solution (2005) (5)
Crystal and molecular structure of anhydrous calcium hydrazinecarboxylate (1971) (5)
Synthesis of new halogen-bridged cationic dimanganese carbonyl compounds. X-ray structure of [Mn2(μ-I)(CO)8(μ-Ph2PCH2PPh2)][BF4] (1986) (5)
Crystal and molecular structure of ennea‐ammonium dichloride tetrathiosulphatoargenate, (NH4)9Cl2[Ag(S2O3)4] (1972) (5)
The structure of cis,trans,cis‐diaquabis(5‐methyl[1,2,4]triazolo[1,5‐a]pyrimidine‐N3)bis (thiocyanato‐N)iron(II) (1986) (5)
The crystal and molecular structures of magnesium di-o-phthalatocuprate(II) tetrahydrate and strontium di-o-phthalatocuprate(II) trihydrate: errata (1978) (5)
The unexpected formal insertion of a carbonyl group into a heterocyclic NIr bond (1994) (5)
Synthesis and Structure of [(CO)4Mn{(PPh2)2C−S6−C(PPh2)2}Mn(CO)4]: A Unique Tetraphosphinobis(methanide) Complex of Manganese(I) with a Hexasulfur Bridge (1996) (5)
N-indolyltriarylphosphinegold(I) derivatives as η6-arene ligands in pentamethylcyclopentadienylrhodium(III) complexes. X-ray structure of [(C5Me5)Rh(μ-In)AuP(C6H5)3](ClO4)2·CH2Cl2 (1983) (4)
Coordination properties of the multifunctional S,N,S zwitterionic ligand EtNHC(S)Ph2PNPPh2C(S)NEt (2010) (4)
The crystal and molecular structure of sulphatobis(thiocarbonohydrazide-N,S)copper(II) tetrahydrate (1975) (4)
The syntheses, structures, and electronic and resonance-Raman spectroscopy of halogen-bridged platinum(II,IV) chain complexes involving equatorially co-ordinated terdentate amines: X- ray crystal structure of [PtII(Me-dien)I][PtIV(Me-dien)I3]I2, and spectroscopy of [PtII(dien)(NO2)][PtIV(dien)(NO2)B (1986) (4)
High diastereoselective Michael and aldol additions of Fischer-type alkyl(hydrazino)carbene complexes: synthesis of new hydrazides (2003) (4)
Synthesis and reactivity studies of Pd(II) complexes of the bulky CH(SiMe3)2 group. X ray structure of the indenyl derivative (η-Ind)Pd[CH(SiMe3)2](PMe3) (1999) (4)
[PPh4][Fe3(CO)9(μ-CO)2{PbPh3}]: A Metal Cluster Containing an Open Fe−Fe−Pb Array (1996) (4)
Crystal and molecular structure of hexaaquomagnesium trihydrogenhexaoxoiodate(VII) (1970) (4)
Crystal and molecular structure of nitrosyl(1,10-phenanthroline)-bis(triphenylphosphine)iridium(I) Dihexafluorophosphate, [Ir(NO)(phen)(PPh3)2][PF6]2 (1980) (4)
The crystal srtucture of calcium diiodate(V) hexahydrate (1971) (4)
Synthesis of trans-[Re(NO)2-(Ph2PCH2CH2PPh2)2][BF4], a formal dinitrosyl complex of rhenium(-I) and its protic denitrosylation. X-Ray structure of trans-[ReF(NO)-(Ph2PCH2CH2PPh2)2][BF4] (1994) (4)
Synthesis of the first chiral phosphorous chelate aminophosphino-carbene complex and its applications in stereoselective addition reactions (1999) (4)
Carbonylcyanometalates as building blocks: heterometallic complexes containing Mn(μ-CN)M (M = Cu, Au, Ni, Pd or Pt), Mn(μ-CN)Pd(μ-dppm)2Mn and Mn(μ-CN)M(μ-dppm)2Pd(μ-NC)Mn (M = Pt or Pd) chains of atoms and crystal structure of the mixed-metal cluster [Ru3{(μ3-NC)MnCp(CO)2}(μ-AuPPh3)(CO)10] (2000) (4)
Reactivity of the zwitterionic ligand EtNHC(S)Ph2P[double bond, length as m-dash]NPPh2C(S)NEt towards [Ru3(CO)12]. Sulfur transfer and ligand fragmentation leading to the methideylamide [-N(Et)-CH(R)-] micro3-bridging moiety. (2009) (4)
Single-strand polymer in catena-poly{[trans-bis(6,8-dimethyl[1,2,4]triazolo[3,4-b]pyridazine-N2)cadmium]-μ-(thiocyanato-N:S)-μ-(thiocyanato-S:N)} (1986) (4)
New ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). X-ray structures of mer–trans-[RuCl2(dppm)(FcPN)] (dppm=bis(diphenylphosphino)methane) and cis-[RuCl2(CO)(py)(FcPN)] (2002) (4)
Synthesis of the Diazadisilatitanacyclopentane RSi(NH2)NHTiMe(cp*)NHSi(NH2)R (R =PhNSiMe3, cp *=η5‐C5Me5 (1997) (4)
tert-Butylsilylcyclopentadienyl Group 4 metal complexes (2003) (4)
Methylation of (pentamethylcyclopentadienyl)trichloro(diphenyldimethylenephosphoranyl-C,C)tantalum(V). Crystal structures of [TaCp*Cl3((CH2)2PPh2)] and [TaCp*Me2((CH)(CH2)PPh2)] (1992) (4)
Synthesis and X-ray structure of a two-dimensional thiocyanato-bridged mercury(II)-copper(I) complex with 5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine, [CuHg(μ-SCN)3(dmtp)2] (1986) (3)
Phosphonate−Stannylene Coupling in the Reactions of the Anion [Mn2{μ-OP(OEt)2}{μ-P(OEt)2}(CO)6]2- with SnR2Cl2 (R = Bu, Ph) (2005) (3)
Synthesis of (pentamethylcyclopentadienyl)nitrosylmolybdenum complexes containing halide, methyl, or cyclopentadienyl ligands. Crystal structures of [MoMe(η-C5H5)(η-C5Me5)(NO)] and [{Mo(η-C5Me5)O(µ-O)}2] (1990) (3)
[Methoxy(p‐tolylimino)methyl](triphenylphosphine)gold(I), C27H25AuNOP (1985) (3)
Sulfur ligand-stabilized palladium aggregates produced on the surface of benzoylthiourea-functionalized silica xerogels (1995) (3)
Crystal and molecular structure of thiocarbonohydrazide hemihydrochloride (1972) (3)
Synthesis and Crystal Structure of a Heteronuclear Fe–Ru Silyl Complex* (2007) (3)
The crystal and molecular structure of 6-acetyl-8-(acetyloxyimino)-2-phenyl-4-oxo-4,8-dihydro-2H,6H-pyrazolo[3,4-f]-1,2,3-benzotriazole–dioxane (2:1) (1977) (3)
Redox-Induced P-O and Mn-Mn Bond Cleavages at Dimanganese Carbonyl Centers. Synthesis and Oxidation Reactions of the Dianion [Mn2{.mu.-P(OEt)2}{.mu.,.eta.2-OP(OEt)2}(CO)6]2- (1994) (3)
Spectroscopic and structural studies on cobalt complexes of the methyl esters of dithiocarbazic and 2-methyldithiocarbazic acids. Crystal structure of [Co{NH2NHC(S)SMe}{NH2NC(S)SMe}2]Cl·H2O (1979) (3)
Synthesis of orthometallated rhodium(III) compounds. Crystal structures of [RhCl2{η2(C6H4)PPh2}(η2-dppm)] and [RhCl{η2(C6H4)PPh2}(η1-PCCl)(phen)] (SbF6)·CH2Cl2 (dppm=bis(diphenylphosphino)methane; PCCl=P(o-ClC6H4)Ph2; phen=1,10 phenanthroline) (1993) (3)
A BIS-TETRAALKYLDIAMMONIUM ION BRIDGING, VIA CARBON BOND, TWO METAL ATOMS. X-RAY CRYSTAL STRUCTURE OF DICHLORO(3,3,6,6-TETRAMETHYL-3,6-DIAZAOCTANE-1,8-DIYL)BIS(N,N,-N′,N′-TETRAMETHYLETHYLENEDIAMINE)DIPLATINUM(II) DIPERCHLORATE (1979) (3)
Evidence for multiple palldiumhydrogen shortrange interactions in dichlorobis(1,3-dimethyl-1,4,5,6-tetrahydopyridazine) palladium(II) (1980) (2)
SYNTHESIS, STRUCTURE, AND LIGAND DYNAMICS OF THE ORGANOMETALLIC ANION (RU3(CO)9C2-TERT-BU)- (1982) (2)
A seven-membered platinum-amino-amidine metallacycle. X-ray structure of cis-[Pt(NH=CPhNButCH2CH2NHBUt)Cl2•1/2Me2CO (1990) (2)
COPPER-PROMOTED INTRAMOLECULAR SELENIUM TRANSFER FROM A P=SE GROUP TO A P-CH2-P METHYLENE CARBON PRODUCING AN UNUSUAL METHANESELONE LIGAND (1995) (2)
Thermal behaviour and crystal structure of dichlorobis(methyl 2-methyldithiocarbazate-N3S)cobalt(II)–methyl 2-methyldithiocarbazate (2/1), [Co{NH2NMeC(S)SMe}2Cl2]·0.5[NH2NMeC(S)SMe] (1980) (2)
Crystal and molecular structure of thiocarbonohydrazide sulphate (1972) (2)
Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru2(μ-C10H8N2)(CO)4{P(OPh)3}2] (C10H10N2=1,8-diaminonaphthalene) (1991) (2)
Chemistry of polynuclear allenyl complexes: The μ-η1 : η2-allenyl diruthenium system Ru2(CO)6(μ-PPh2)(μ-η1 :η2-C(Ph)CCH2). Dimetallocycles via CC, CN and CS bond forming reactions and the X-ray structure of Ru2(CO)6(μ-PPh2)[μ-η1 : η1-PhCC{C(EtS)N(H)tBu}CH2] (1994) (2)
Pentaco-ordination in bis(hydrazinecarboxylato-N′O)-zinc (1970) (2)
NEW DITHIOUREA LIGANDS AS MODELS OF THIOUREA-FUNCTIONALIZED SILICA XEROGELS. CRYSTAL STRUCTURES OF PHNHC(S)N(ET)(CH2)2NHC(S)NHPH AND OF THE DERIVED CO MPLEX CUCL2(C7H4NS)N(CH2)2N(ET)C=NPH, CONTAINING A NOVEL N,N-CHELATING LIGA ND (1992) (2)
Preparation of Ti(IV), Zr(IV) and Sn(IV) metal alkyls containing the (PriO)3SiCH2 fragment (2002) (2)
High co-ordination numbers in the crystal structures of calcium hydrazinecarboxylates (1970) (2)
Nucleophilic Attack of Amine and Hydroxide to Platinum Dibenzonitrile Dichloride. (1986) (1)
REVERSIBLE ADDITION OF PROTIC MOLECULES TO COORDINATED DI-2-PYRIDYL KETONE IN PALLADIUM(II), PLATINUM(II), AND GOLD(III) COMPLEXES. X-RAY CRYSTAL STRUCTURES OF DICHLORO(DIHYDROXYDI-2-PYRIDYLMETHANE)PALLADIUM(II) AN DICHLORO(DIHYDROXYDI-2-PYRIDYLMETHANE)GOLD(III) CHLORIDE (1982) (1)
Leaching of anchored Rh and Pd species from thiourea-functionalized monolithic silica xerogel catalysts (2003) (1)
Crystal and molecular structure of cadmium trihydrogenhexaoxoiodate(VII) trihydrate (1970) (1)
Dinitrosylbis(trimethyl phosphite)cobalt(–I) tetraphenylborate, [Co(NO)2{P(OMe)3}2][BPh4] (1983) (1)
SYNTHESIS AND REACTIVITY OF BIMETALLIC IRON-RHENIUM SILYL COMPLEXES : CRYSTAL STRUCTURES OF (OC)3(MEO)3SIFE(MU -DPPM)RE(CO)4 AND (OC)3FE(MU -BR)(MU -D PPM)RE(CO)3 (1996) (1)
Tris(pentafluorophenyl) Neutral and Anionic Five‐Coordinate Complexes of Rhodium(III). Crystal Structures of (Rh(C6F5)3(PEt3)2) and (Rh(C6F5)3(AsPh3)2). (1990) (1)
Crystal and molecular structure of carbonohydrazide sulphate (1974) (1)
Novel High-Nuclearity HgCoRu and HgCoFe Sandwich Complexes. Synthesis and Structure of [Hg{RuCo3(μ-CO)3(CO)9}2]. (1986) (1)
Binuclear Copper(I) Complexes Containing Bis(diphenylphosphino)methane Bridging Ligands: Crystal Structure of (Cu2(μ‐dppm)2(MeCN)4) (ClO4)2. (1987) (1)
Silica-supported bismuth molybdate catalysts obtained by the sol-gel process via silicon alkoxides (1998) (1)
Structures and Properties of Bis(thiocyanato-N)bis(6-methyl(1,2,4)triazolo(1,5-a)pyrimidine-N3)copper(II), a Distorted Tetrahedral Copper(II) Thiocyanate Compound, and Bis(thiocyanato-N)bis(5-methyl(1,2,4)triazolo(1,5-a)pyrimidine-N3) (1990) (1)
Reactivity of the heterometallic clusters [HMCo3(CO)12] and [Et4N][MCo3(CO)12] (M = Fe, Ru) toward phosphine selenides, including selenium transfer. Crystal structures of [HRuCo3(CO)7(mu-CO)3(mu-dppy)], [MCo2(mu3-Se)(CO)7(mu-dppy)], and [RuCo2(mu3-Se)(CO)7(mu-dppm)] [dppy = Ph2(2-C5H4N)P, dppm = Ph2 (2002) (1)
Reactivity of the methylcyclopentadienylmanganese cyanometalate Na[Cp'Mn(CO)2CN] with titanium, zirconium, and hafnium halides. Crystal and molecular structure of the .mu.-cyano .mu.-oxo tetranuclear complex [Cp2Zr{(.mu.-NC)MnCp'(CO)2}]2(.mu.-O) (Cp = .eta.-C5H5; Cp' = .eta.-MeC5H4). [Erratum to doc (1994) (1)
The calculation of absorption factors for highly absorbing crystals with rectangular cross-sections (1961) (1)
Formation of Metallacycles from Terminal Diynes with Geminal Methyl Groups α to the Triple Bonds. Synthesis and Crystal Structure of Co2(CO)5((HCCCMe2)2NMe), an Intermediate in Cobalt-Catalyzed Organic Syntheses. (1992) (1)
Calculation of transmission factors in crystals with any polygonal cross-section and high absorption power (1965) (1)
Low‐Nuclearity Iron and Ruthenium Selenido‐Carbonyl Clusters Derived from Phosphine and Diphosphine Selenides (2008) (1)
Synthesis of coordinated carbon monoxide from isocyanide iron(II) compounds. Crystal structure of [Fe(dppe)(CO)(CN-p-tol)(p-tolNCN-p-tolC;N-p-tol)] (1987) (1)
Anchoring selenido-carbonyl ruthenium clusters to functionalised silica xerogels (2003) (1)
Thiocarbonohydrazide dihydrochloride hemihydrate, CH8N4S2+.2Cl−.0.5H2O (1984) (0)
Copper(I) olefin complexes and their CO/olefin exchange equilibria (2005) (0)
Phosphane‐Substituted Selenido‐(carbonyl)iron and ‐(carbonyl)ruthenium Clusters: Structures, Fluxionality and Reactivity (2003) (0)
Trinuclear Angular Aggregates of Rhodium: Synthesis and Crystal Structures of (Rh3(μ3‐SC5H4N)2(CO)6)(ClO4) (SC5H4N: pyridine‐2‐thiolate) and (Rh3(μ3‐C7H4NS2)2(CO)2(PPh3)2(tfbb))(ClO4) (C7H4NS2: benzothiazole‐2‐thiolate, tfbb: tetrafluorobenzobarrelene). (1990) (0)
THE SYNTHESIS AND CRYSTAL STRUCTURE OF TWO NEW HETEROMETALLIC CLUSTERS: (η‐C5H5)2NI2FE2(CO)6(μ3‐CO) AND (η‐C5H5)2NI2FE2(CO)6(C2ET2) (1980) (0)
PRODUCTS OF THE REACTION OF RU3(CO)12 WITH 1,3-CYCLOHEXADIENE. X-RAY STRUCTURE OF (η-BENZENE)NONACARBONYL-1-CYCLOHEXEN-1,2-YLENETETRARUTHENIUM RU4(CO)9(C6H6)(C6H8) (1979) (0)
CARBON MONOXIDE ACTIVATION IN THE REACTIONS OF IRON CARBONYLS AND ALKYNES. SYNTHESES, CRYSTAL STRUCTURES, AND NUCLEAR MAGNETIC RESONANCE STUDIES ON HYDROXYFERROLE AND MALEOYLIRON DERIVATIVES (1980) (0)
Group 4 ansa-metallocenes in oxidation state (III): synthesis, characterization, and chemical behavior. Crystal structure of {[.eta.5:.eta.5-(C5H4)2Si(CH3)2]TiCl(PMe2Ph)} [Erratum to document cited in CA114(23):229076z] (1991) (0)
Addition Reactions of O-bound Cyclic Nickel Enolates to alpha,beta-Unsaturated Ketones. (2003) (0)
Reactivity of Metallic Copper with Acidic Organic Compounds in the Presence of Molecular Oxygen. Crystal Structure of ((Cu(NCO)(py)2)2)·H2O. (1989) (0)
Structure of the Ionic Polynuclear Tantalum(V) Derivative Bis{tri-g-chloro-bis(dichloro- (1985) (0)
REACTIONS OF ((η‐C5H5)2NI2(HCCCME:CH2)) WITH TRIOSMIUM OR TRIRUTHENIUM DODECACARBONYLS IN THE PRESENCE OF HYDROGEN. SYNTHESIS AND CRYSTAL STRUCTURE OF THE NEW HETEROTETRAMETALLIC COMPLEX ((η‐C5H5)2NI2FE2(CO)6(:C:CHCME:CH2)) AND SPECTROSCOPIC CHARACTERIZATION OF A PLANAR ISOMER (1984) (0)
2,2′-BIBENZIMIDAZOLATE ANIONS AS BRIDGING LIGANDS IN CATIONIC HETERONUCLEAR GOLD(I)-RHODIUM(I) COMPLEXES. CRYSTAL STRUCTURE OF (1,1′-BIS(TRIPHENYLPHOSPHINEAURIO)-2,2′-DIBENZIMIDAZOLE-N3,N3′)(η-CYCLOOCTA# -1,5-DIENE)RHODIUM PERCHLORATE (1983) (0)
COMPLEXES OF RHODIUM(I) WITH 1,8-NAPHTHYRIDINE AND RELATED LIGANDS. CRYSTAL STRUCTURE OF BIS(μ-1,8-NAPHTHYRIDINE-N,N′)BIS((η-2,5-NORBORNADIENE)RHODIUM(I))(RH-RH) DIPERCHLORATE MONOHYDRATE (1984) (0)
Reaction of Triphenylphosphine with the Anionic Cluster (HRu3(CO)11)Revisited: Isolation, Crystal Structure, and Isomerization of (NEt4)(HRu3(CO)8(PPh3)(PPhC6H4)). (1989) (0)
Nuclear recoil synthesis of metallorganic compounds and crystal structure of Co3(CO)9(C6H7) (1990) (0)
DIMERIZATION OF ISOPROPENYLACETYLENE ON DODECACARBONYLTRIRUTHENIUM. SYNTHESIS AND CRYSTAL STRUCTURE OF RU3(CO)8(C10H12) (1980) (0)
Influence of the R Group in [Mo2(μ-R)(μ-PCy2)(CO)2Cp2], R=H, CH3, Ph, Bz (2005) (0)
Crystal Structure and Reactivity of [(η-C5H5)NiOs3(μ-H)3(CO)8(PPh2H)].1H and31P Nuclear Magnetic Resonance Spectroscopic Characterization of [(η- C5H5)NiOs3(μ-H)2(μ-HgBr)(CO)8(PPh2)H) and Related Complexes. (1986) (0)
(Pt2(μ-NO)(μ-dppm)2Cl2)BF4: The First A-Frame Complex with a Nitrosyl Bridgehead. (1991) (0)
SYNTHESIS OF THE FIRST PLATINUM-GOLD CLUSTER BY UNEXPECTED PROTON EXCHANGE ON TRANS-PTH(CL)L2 (1984) (0)
Unexpected Formal Insertion of a Carbonyl Group into a Heterocyclic N‐ Ir Bond. (1994) (0)
SYNTHESIS, CRYSTAL STRUCTURE, AND STEREOCHEMICAL NON-RIGIDITY OF OCTACARBONYL-μ3-(1,3,6-TRIMETHYLHEXA-1,3,5-TRIENE-1,5-DIYL)-TRIANGULO-TRI-IR# ON (1977) (0)
Synthesis and Crystal Structure of (NiOs3(η-C5H5)(μ-H)2(μ-Cu(PPh3))(CO)9). Hydrogenation-Dehydrogenation Reactions of Dienes and Alcohols with Heterogeneous Catalysts Derived from (NiM3(η-C5H5)(μ-H)2(μ-X)(CO)9) (M: Ru, X: H; M: Os, X: (1989) (0)
Crystal data of `three-pyraphene' and of some derivatives of `dipyraphene' (1965) (0)
Silyl-Substituted Tetrathia[7]helicenes: Synthesis, X-ray Characterization and Reactivity (Eur. J. Org. Chem. 27/2007) (2007) (0)
SPECTROSCOPIC STUDY AND X-RAY STRUCTURE OF BIS(N-METHYLIMIDAZOLE)BIS(2,4,6-TRICHLOROPHENOLATO)COBALT(II) (1980) (0)
New 2,4,6-Trinitrophenylpalladium(II) Complexes. Crystal and Molecular Structure of trans-2,4,6-Trinitrophenyl(chloro)bis(triphenylarsine) palladium(II). (1991) (0)
Synthesis and Structure of ((Ph3P)3Ir(μ3‐H)(μ‐H)2Ag2(OSO2CF3)(H2O))(CF3SO3), a Complex with a Bent Ag‐Ir‐Ag Chain. (1987) (0)
BISIMIDAZOLE (H2BIM) AND BIBENZIMIDAZOLE η3-ALLYLIC COMPLEXES OF PALLADIUM(II). MONO- AND TETRANUCLEAR PALLADIUM(II) AND HETERONUCLEAR PALLADIUM(II)-RHODIUM(I) COMPLEXES. CRYSTAL STRUCTURE OF (PD4(η3-C3H5)4(μ-BIM)2).CH2CL2 (1983) (0)
SYNTHESIS AND MOLECULAR STRUCTURE OF BIS(μ4-BUT-1-YNE)-UNDECACARBONYL-QUADRO-TETRAIRON (4 FE-FE) (1978) (0)
Synthesis and Crystal Structure of the New Near-Linear Rh2Mo Trinuclear Complex ((η5-C5H5)Rh(μ-CO)(μ-Ph2PC5H4N)Rh(CO)Mo(CO)3(η5-C5H5)). (1990) (0)
SPECTROSCOPIC AND STRUCTURAL STUDIES ON COBALT COMPLEXES OF THE METHYL ESTERS OF DITHIOCARBAZIC AND 2-METHYLDITHIOCARBAZIC ACIDS. CRYSTAL STRUCTURE OF (METHYL DITHIOCARBAZATE-N3S)BIS(METHYL DITHIOCARBAZATO(1-)-N3S)COBALT(III) CHLORIDE (1980) (0)
Iridium(I) Insertion into an Aromatic C-H Bond. Synthesis and Structure of (Ir(H)(CO)(bq)(PPh3)2)PF6 (bq: 7,8-Benzoquinolinato). (1989) (0)
TETRA- AND TRINUCLEAR RHODIUM-PALLADIUM COMPLEXES WITH THE 1,2,4-TRIAZOLATE (TZ) LIGAND. CRYSTAL STRUCTURE OF (η3-C3H5)2PD2RH2(μ3-TZ)2CL2(CO)4 (1985) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF (η-C5H5)NIRU3(CO)8(C6H9). A NEW COMPLEX OBTAINED BY INSERTION OF A NICKEL ATOM INTO A RU3 CLUSTER (1979) (0)
Syntheses and crystal structures of Co2Rh2(η5-C5Me5)2(μ3-CO)2(μ-CO)(CO)4 and Rh(η5-C5Me5)(CO)2 (1985) (0)
Reactions of Alkynes with HFeCo3(CO)12. Crystal Structure of FeCo3(CO)9[PhC2· (H)Ph](PhC2Ph). (1983) (0)
Comparative chemistry of - ? 1 : ? 2-allenyl and - ? 1 : ? 2-acetylide complexes: ? 5-cyclopentadi (1996) (0)
PLATINUM(IV) COMPLEXES CONTAINING A CATIONIC AMINE LIGAND: CRYSTAL STRUCTURE OF ((2-AMINOETHYL)AMMONIUM)PENTACHLOROPLATINUM(IV) MONOHYDRATE (1984) (0)
THE REACTION OF (η5-C5H5)NIOS3(μ-H)3(CO)9 WITH GROUP V DONOR LIGANDS: SPECTROSCOPIC CHARACTERIZATION OF THE MONOSUBSTITUTED DERIVATIVES. AN EXAMPLE OF MONODENTATE BIS(DIPHENYLPHOSPHINO)METHANE ON A HETEROMETALLIC CLUSTER (1984) (0)
CCDC 246736: Experimental Crystal Structure Determination (2009) (0)
The Reactivity of HRu3(CO)9C2But. The Synthesis and Crystal Structure of (PPh3) AuRu3(CO)9C2But, a New Ruthenium-Gold Cluster. (1983) (0)
BEHAVIOR OF THIOCARBONOHYDRAZIDIUM CATION AS A LIGAND. CRYSTAL AND MOLECULAR STRUCTURE OF DICHLORO(1H+-THIOCARBONOHYDRAZIDIUM-NS)COPPER(II) CHLORIDE (1976) (0)
Activation of the CN Triple Bond of Substituted Benzonitriles in the Presence of Ru3(CO)12, Acetic Acid and Molecular Hydrogen. Crystal Structure of (μ-H)2Ru3(CO)9(μ3-NCH2C6H4OMe). (1987) (0)
AN INSPECTION INTO THE CLASS OF BIS(ALKYNE)UNDECACARBONYL-QUADRO-TETRARUTHENIUM COMPLEXES. CRYSTAL STRUCTURE AND DYNAMIC BEHAVIOR OF RU4(CO)11(μ4,η2-MEC2PH)2 (1984) (0)
Complexes of functional phosphines. Manganese(II) complexes containing β-keto- and 2-pyridylphosphine ligands. The molecular structure of MnI2(Ph2Ppy)2 (1995) (0)
CCDC 815740: Experimental Crystal Structure Determination (2012) (0)
Complexes with an η2-μ2-SiO Bridge. Structure of the Bimetallic Cyclic Complex (Fe(CO)3(μ-Si(OMe)2OMe)(μ-dppm)PdCl) (Fe-Pd). (1990) (0)
PLATINUM(II) COMPLEXES CONTAINING A CATIONIC AMINE LIGAND: CRYSTAL STRUCTURE OF ((2-AMINOETHYL)AMMONIUM)TRICHLOROPLATINUM(II) (1985) (0)
BENZAMIDINATORHODIUM COMPLEXES. X-RAY STRUCTURES OF (RH(CPH(NPH)2)(COD)) AND (RH2(μ-CPH(NPH)2)2(TFBB)2) (1985) (0)
Di- and Tetra-nuclear Mixed-valence Complexes of Rhodium(III,I) and Rhodium(III) (1986) (0)
Chemistry of Multi-Site Bound Unsaturated Ligands on Metal Carbonyl Clusters. Intramolecular Reductive Coupling in the Conversion of (Ru3(μ-H)(CO)9(μ3,η2-CCtBu)) to the Butadienyl Cluster (Ru3(CO)8(μ3,η4-C(tBu)CC(H)C(Ph)(PPh2))), and (1989) (0)
CRYSTAL STRUCTURE AND STEREOCHEMICAL NONRIGIDITY OF OCTACARBONYL(η-1,3-DIMETHYL-2-VINYLCYCLOPENTADIENYL)-μ3-PROPYLIDYNE-TRIA# NGULO-TRIIRON (1977) (0)
Preparation of Titanium Pentamethylcyclopentadienyl Trialkyls and Crystal Structure of Tribenzylpentamethylcyclopentadienyltitanium, Showing Some Evidence of a CH2...Ti Interaction. (1986) (0)
Synthesis and characterization of heterometallicbl] clusters (1980) (0)
Synthesis and Crystal Structure of (η-C5H5)2Ni2Ru2(CO)6[C2(H)C(=CH2)CH3]. A New Heterometallic Cluster with an Uncommon Metal Atom Framework. (1982) (0)
Reconsideration of the Crystal Structure Refinement of the Complex (Nb(η-C5H4SiMe3)2Cl2). (1990) (0)
Spectral Properties and Crystal Structure of Bis(μ-thiocyanato-N,S)bis(thiocyanato-N)-tetrakis(5,7-dimethyl[1,2,4]triazolo[1,5-α]pyrimidine-N3)dicopper(II) and of Tetrakis(5,7-dimethyl[1,2,4]triazolo[1,5-α]pyrimidine-N3)platinum(II)he (1983) (0)
Metal Clusters as Models of Intermediates in Organic Syntheses. Reactions of the Terminal Dialkynes NR(CMe2CCH)2 (R: H or Me) with (Ru3(CO)12). (1992) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF HEPTACARBONYL-HYDRIDO-(TERT-BUTYLETHYNYL)-(2,4-HEXADIENE)-TRIANGULO-TRIRUTHENIUM, HRU3(CO)7(C6H9)(C6H10) (1979) (0)
Reaction of Diphenyl(vinyl)phosphine with Carbonyls (M3(CO)12) (M: Ru or Os); Oxidative Addition at (Ru3(CO)12). Spectroscopic Characterization and Crystal Structure of (Ru3(μ-H)(CO)8(Ph2PCH=CH2)(μ3-Ph2PCH=CH)). (1990) (0)
Reactions of (Pd2(μ-dppm)2Cl2) with Electrophilic Complexes of Copper and Gold. Synthesis of the Pd4 Cluster (Pd4(μ-Cl)2(μ-dppm)4)(PF6)2·2 (CH3)2CO. (1987) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF HEPTACARBONYL-μ3-(PENT-1-EN-1-YL-3-YLIDENE)-(η-1,2,3-TRIETHYLCYCLOPENTAD# IENYL)-TRIANGULO-TRI-IRON (3 FE-FE): THE CLEAVAGE OF AN ACETYLENIC TRIPLE BOND ON A METAL-ATOM CLUSTER (1978) (0)
Alkyne Oligomerization and CO Activation on Ruthenium Clusters. Synthesis and Crystal Structure of Ru3(CO)5(C12H20)(C19H30O). The Stepwise Formation of a Heterocyclic Ring without Cluster Degradation. (1983) (0)
Crystal Structure of a Novel Tetranuclear Dithiocarboxylato Copper(I) Complex, ((Cu(S2CC6H4Me-p))4(PPh3)2) (1989) (0)
PYRAZOLATE A-FRAME RHODIUM COMPLEXES. CRYSTAL STRUCTURES OF BIS-μ-(BIS(DIPHENYLPHOSPHINO)METHANE)-μ-(3,5-DIMETHYLPYRAZOLATO-N,N′)BIS(# CARBONYLRHODIUM(I)) PERCHLORATE AND BIS-μ-(BIS(DIPHENYLPHOSPHINO)METHANE)-μ-(3,5-DIMETHYLPYRAZOLATO (1985) (0)
Mixed iron and cobalt acetylenic carbonyl derivatives (1980) (0)
Syntheses, Structures, and Bonding of Heteropentametallic Clusters [MCo3(CO)12{μ3-M′(EPh3)}] (M: Fe or Ru; M′: Cu or Au; E: P or As). (1986) (0)
THE REACTIVITY OF HRU3(CO)9C2BUT. SYNTHESIS AND CRYSTAL STRUCTURE OF (η5-C5H5)NIRU3(CO)9C.C(H)BUT, A NEW MIXED RUTHENIUM-NICKEL CLUSTER (1980) (0)
Kinetics and Mechanism of the Reaction Between Dimethyl Sulphoxide and Dichloro(pyridine-2-carboxylato)platinate(II) Anion and the cis-trans Isomerization of the Products. X-Ray Crystal Structure of trans-(O,S)-Chloro(dimethyl sulphox (1986) (0)
Preparation of Carbonyl, Halogeno, and Alkyl Niobocene Complexes and Their Reactions with Oxygen. Crystal Structures of (Nb(η-C5H4SiMe3)2Cl2), (Nb(η-C5H4SiMe3)2(O)Me), and (Nb(η-C5H4SiMe3)2(C6F5)(CO)). (1989) (0)
Synthesis and Characterization of Novel σ‐Alkynyl Cyclopentadienyl Iron(II) Complexes (Fe(CCR)L2(η‐C5H5)) ( L: CO; L2: bis(diphenylphosphino)methane (dppm)). Crystal Structure of (Fe(CCC6H5)(dppm)(η‐C5H5)). (1991) (0)
Reactivity of Binuclear Pyrazolate-Bridged Rhodium Complexes with Isocyanides. Molecular Structure of (Rh2(μ-pz)I2(CNtBu)2(μ-Ph2PCH2PPh2)2)BF4 (pz: pyrazolate). (1989) (0)
Synthesis and Crystal Structure of Cyclic (Ru2(CO)6(μ-PPh2)(μ-PCH=CHC6H4)), a Complex with an Unprecedented Phospha-Bicyclic Ligand, Obtained from (Ru3(μ-H)(CO)8(Ph2PCH=CH2)(μ3-Ph2PCH=CH)) via Reductive Elimination Reactions. (1990) (0)
SYNTHESIS AND CHARACTERIZATION OF AN UNUSUAL HETEROBRIDGED DIRHODIUM COMPLEX. X-RAY MOLECULAR STRUCTURE OF (RH2(μ-PZ)2I2(CO)2(μ-DPPM)) (1985) (0)
MULTISITE-BOUND VINYLIDENES ON HETEROMETALLIC CLUSTERS. REFORMULATION OF (η5-C5H5NI)RU3(CO)9(μ4-η2-C:CHR) (R = TERT-BU) AS HYDRIDO-BRIDGED (μ-H)(η5-C5H5NI)RU3(CO)9(μ4-η2-C:CHR). MOLECULAR STRUCTURE OF THE ISOPROPYL DERIVATIVE (R = ISO (1983) (0)
CCDC 294808: Experimental Crystal Structure Determination (2006) (0)
THERMAL BEHAVIOR AND CRYSTAL STRUCTURE OF DICHLOROBIS(METHYL 2-METHYLDITHIOCARBAZATE-N3S)COBALT(II)-METHYL 2-METHYLDITHIOCARBAZATE (2/1), (CO(NH2NMEC(=S)SME)2CL2).CNTDOT.0.5(NH2NMEC(=S)SME) (1981) (0)
Reactivity of Chelating Dicarbene Metal Complex Catalysts. Part V. C—H Bond Functionalization of Aromatic Heterocycles with Chelating Dicarbene Palladium(II) and Platinum(II) Complexes. (2010) (0)
Conversion of a .mu±eta.2-Acetylide to a .mu±eta.2-||-Acetylene via Successive Nucleophilic Additions. X-Ray Structure of Os2(CO)6(.mu±eta.2-C(C(NH-t-Bu)(S-n-Bu))-CPh)(μ-PPh2). (1988) (0)
Metal‐Assisted Synthesis of New and Highly Functionalized Diphosphines. (1999) (0)
Heterotrinuclear Angular Aggregates of Rhodium, Iridium, Palladium and Group 11 Metals. X-Ray Structure of the Complex ((cod)2Rh2(μ3- C7H4NS2)2Ag(O2ClO2)) (cod: cycloocta-1,5-diene). (1991) (0)
Binuclear Copper(I) Complexes Containing Two or Three 2-(Diphenylphosphine)pyridine (dppy) Bridging Ligands: X-Ray Crystal Structure of (Cu2(μ-dppy)3(MeCN))(BF4)2 and Variable-Temperature 1H and 31P-(1H) NMR Studies. (1989) (0)
Addition Reactions of O‐Bound Cyclic Nickel Enolates to α,β‐Unsaturated Ketones. (2003) (0)
New Rhodium(I) Complexes with the Bridging 1,8-Naphthyridine-2-one Ligand. (1984) (0)
Rapid Inversion versus Stable Chiral Center Formation. Different Behavior of Coordinated Nitrogens in Four- and Five-Coordinate Platinum(II) Complexes with N,N′-Disubstituted Ethylenediamines. (1988) (0)
Syntheses and X-ray structures of [Rh2(μ-SC5H4N)2(tfb)2]•Me2CO and [Rh3(μ-SC5H4N)2(CO)6][ClO4]•1/2CH2Cl2(tfb=tetrafluorobenzobarrelene: 5,6,7,8-tetrafluoro-1,4-dihydro-1,4-ethenonaphthalene): two unusual Bi- and trinuclear complexes of the pyridine-2-thiolato ligand showing three different co-ordina (1986) (0)
Erratum: Nucleophilic attack of amine and hydroxide to platinum dibenzonitrile dichloride. Crystal structure of [Pt(NH=CPhN-t-BuCH2CH2NH-t-Bu)Cl(NHCOPh)] (2) and cis-[Pt(NH= CPhN-t-BuCH2CH2NH-t-Bu)Cl(NCPh)] (3) (Journal of the American Chemical Society (1986) 108, (1180)) (1986) (0)
Nickel Nitrosyl Complexes with Diphosphines. The Crystal and Molecular Structure of ((dppe)(ON)Ni(μ-dppe)Ni(NO)(dppe))(BF4)2 (dppe: Ph2PCH2CH2PPh2). (1990) (0)
CCDC 295832: Experimental Crystal Structure Determination (2006) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF (η‐C5H5)2RU2NI(CO)3(μ3‐CO)(C2PH2). FACILE, ONE STEP SYNTHESIS OF A CHIRAL COMPLEX (1981) (0)
Perthiocarboxylate Complex. Synthesis, Structure and Spectroscopic Characterization of the Tetrameric Copper(I) o-Tolylperthiocarboxylate, (Cu(S)SSCC7H7)4. (1988) (0)
Preparation and Reactivity of Halide-Bridged Binuclear Carbonyl Manganese and Rhenium Anions, (M2(μ-X)(CO)8-2n((EtO)2POP(OEt)2)n)- (X: halide; M: Mn, n = 1 or 2; M: Re, n = 1). X-Ray Crystal Structure of (Mn2Au(μ-Br)(CO)6(μ-tedip)(PPh (1987) (0)
Homogeneous Catalysis on Metal Clusters. The Isomerization and Selective Hydrogenation of Dienes, Alkenes, and Alkynes in the Presence of [(η-C5H5)NiOs3(μ-H)3(CO)9] and [(η-C5H5)NiOs3(μ-H)3(CO)8L] (L: PPh2H or P(C6H4Me-o)3). (1986) (0)
Oxidative Addition of Phosphorus Ylides to Ru3(CO)12. (1990) (0)
A Novel Type of Bonding of a Cyanometalate Ligand. Synthesis and Structure of the Mn4Pd4 Cluster ((OC)Pd(μ-NC)Mn(η-C5H4Me)(CO)2) 4 with Orthogonal Helical Units. (1991) (0)
Frame Isomerization of the Cluster [Pt3(μ‐PPh2)3Ph(PPh3)2] by Recrystallization in Different Solvents. (1986) (0)
Formation of Diiridium(II) Complexes by Photoassisted Oxidative‐Addition Reactions: Structure of a Stable Binuclear Iodo(iodomethyl)iridium(II) Complex. (1987) (0)
THE REPLACEMENT OF ONE HYDRIDO LIGAND IN ((η-C5H5)NIOS3(μ-H)3(CO)9) BY MPPH3+ (M = COPPER OR GOLD). CRYSTAL STRUCTURE OF NONACARBONYL-μ3-(η-CYCLOPENTADIENYL)NICKELIODI-μ-HYDRIDO-μ-TRIPHEN# YLPHOSPHINEAURIO-TRIANGULO-TRIOSMIUM, THE FIR (1984) (0)
Tetrachloroplatinat(II) and Hexachloroplatinat(IV) Salts of N,N,N′,N′-Tetramethylethylenediammonium: Significant Differences in the Conformation of the Cation, as Shown by Infrared und X-Ray Diffraction Data. (1985) (0)
High Diastereoselective Michael and Aldol Additions of Fischer‐Type Alkyl(hydrazino)carbene Complexes: Synthesis of New Hydrazides. (2004) (0)
Rhodium Complexes of the Binucleating Ligands Pyridine-2-thiolate and Benzothiazole-2-thiolate. Crystal Structures of ((Rh(μ-SC5H4N)(CO)2)2) and ((Rh(μ-SC5H4N)(tfbb))2)·Me2CO (tfbb: tetrafluorobenzobarrelene). (1989) (0)
Cationic Carboxylato Complexes of Dirhodium(II) with Oxo Thioethers: Catalysts for Silane Alcoholysis under Homogeneous and Liquid—Liquid Biphasic Conditions. (2008) (0)
Syntheses, Crystal Structures, and Raman and Resonance Raman Spectroscopy of Platinum(II), Platinum(IV), and Halogen-Bridged Chain Platinum(II,IV) Complexes Involving the Terdentate Ligand 3-Methyl-3-azapentane-1,5-diamine (4Me-dien). (1989) (0)
The intermolecular interactions in the crystal structure of dipotassium hydrogen di-iodate chloride (1967) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF RU3(CO)8(C16H22). THE INSERTION OF ISOPROPENYLACETYLENE INTO RUTHENIUM‐CARBON BONDS AND THE OPENING OF A STABLE CLOSED TRIRUTHENIUM CLUSTER (1980) (0)
lH-Pyrrolo[2,3-b]pyridine (HL) Ligands in Rhodium(I) and Iridium(I) Chemistry. (1986) (0)
Structure of 2‐carboxypyridinium trichloro(dimethyl sulfoxide)platinate(II) (1991) (0)
Stereoselective Hetero Diels—Alder Reactions of Chiral Tricarbonyl (η6-Benzaldehyde)chromium Complexes. (2002) (0)
Synthesis, Characterization and X-Ray Structure of Hetero-polynuclear Thiocyanates of Iron(II) and Mercury(II) with 5,7-Dimethyl[1,2,4]triazolo[1,5-a]-pyrimidine-N3 and Water as Ligands. (1985) (0)
Preparation, Spectroscopic and Magnetic Characterization of Two Pseudo Layered Copper(II) Systems. The X-Ray Structures of Bis(thiocyanato-N)bis((1,2,4)triazolo(1,5-a)pyrimidine-N3)copper(II) and Dichlorobis((1,2,4)triazolo(1,5-a)pyri (1987) (0)
The Reactivity of HRu3(CO)9C2But. Synthesis and Crystal Structure of Ru3(CO)7· {(C2But)[PhC2(H)Ph](C2Ph)}. (1982) (0)
Preparation and X-Ray Structure of a Trinuclear Rhodium Complex with the Polydentate 1,8-Naphthyridine-2-one (Onapy) Ligand: [Rh3(μ3-Onapy)2(CO)2(cod)2](ClO4)·1.5 C2H4Cl2. (1986) (0)
Silica-dispersed vanadium and niobium mixed-oxide catalysts obtained by non-hydrolytic condensation (poster) (2000) (0)
Synthesis, Structure, and Reactivity of Mn2(μ-H)2(CO)6(μ-Ph2PCH2PPh2). (1988) (0)
Crystal Structure of (Ni2Ru3(η-C5H5)2(CO)9(μ5-PPh)), an Open Square-Pyramidal Cluster Obtained via Condensation of Coordinatively Unsaturated (Ru3(μ-H)(CO)9(μ-PPh2)) with (Ni2(η-C5H5)(CO)2). (1987) (0)
The Synthesis, Using Hexamethyldialuminum, and Reactivity of New (1-5-η-Cyclopentadienyl)methyl(nitrosyl)molybdenum Complexes. Crystal Structure of Bromo(η5-cyclopentadienyl)methyl(nitrosyl)(triphenylphosphine)molybdenum. (1988) (0)
SYNTHESIS, CRYSTAL STRUCTURE, AND STEREOCHEMICAL NONRIGIDITY OF μ-(1-Σ:1-2-η-2-CARBOXYLATO-1-ETHYLBUT-1-ENYL-O(2FE))BIS(TRICARBONY# LIRON)(FE-FE), A NEW COMPLEX OBTAINED FROM IRON CARBONYLS UNDER APOLAR CONDITIONS (1979) (0)
Iridium(III) cis-Dihydrido Complexes with 3,6-Bis(2′-pyridyl)pyridazine. Crystal Structure of the Pyridazinyl Complex ((IrH2(PPh3)2)2(μ-C4HN2(C5H4N)2-3,6))PF6. (1988) (0)
Calculation of exact transmission factors for crystals with constant cross‐section (1965) (0)
Tetranuclear Complexes as Intermediates in Transannular Oxidative Addition Reactions. Structure of the First Linear Tetrairidium Cluster. (1988) (0)
SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF A NEW CLASS OF HETEROTETRANUCLEAR COMPOUNDS WITH THIOCYANATE GROUPS AS BRIDGING LIGANDS. THE X-RAY STRUCTURE OF BIS(μ-TETRAKIS(THIOCYANATO-S)MERCURY(II)-N,N′)DIAQUAHEXAKIS(5,7-DIMETHYL(1 (1984) (0)
THE INFLUENCE OF MOLECULAR HYDROGEN ON THE REACTION BETWEEN (RU3(CO)12) AND (NI2(η-C5H5)(C2PH2)). SYNTHESIS AND CRYSTAL STRUCTURE OF THE NEW HETEROPENTAMETALLIC CLUSTER (NI2RU3(η-C5H5)2(CO)6(μ-CO)2(μ4,η2-C2PH2)) (1984) (0)
The Syntheses, Structures, and Electronic and Resonance-Raman Spectroscopy of Halogen-bridged Platinum(II,IV) Chain Complexes Involving Equatorially Coordinated Terdentate Amines: X-Ray Crystal Structure of [Pt(II)(Me-dien)I][Pt(IV)(M (1986) (0)
New Synthetic Approaches to Mn2(CO)10-nLn Derivatives (L: Phosphines): Their Catalytic Activity in the Homogeneous Hydrogenation of Diphenylacetylene and the Crystal Structure of Mn2(CO)9(PPh2H). (1989) (0)
Reorientation of the Alkyne Moiety in the Heterometallic Cluster (FeCo2(CO)9(EtC2Et)), Induced by Phosphine, Phosphite, or Isonitrile Substitution for CO. Crystal Structure of (FeCo2(CO)8(PPh3)(EtC2Et)). (1988) (0)
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ISOMERIC RUTHENIUM-NICKEL DERIVATIVES (η-C5H5)NIRU3(CO)8(C6H9) (1981) (0)
Reactivity of the Iridium Nitrosyl Complex (Ir(NO)(paa)(PPh3)2) (PF6)2 (paa: 2-Pyridinecarbaldehyde Azine) with Nucleophiles: Insertion of NO into a Methinic C-H Bond; Crystal Structure of (Ir((2-C5H4N)CH=N-N=C(NOH)(2-C5H4N))(Me(EtO)C (1989) (0)
Phosphido-bridged heterodinuclear complexes of CrPd, MoPd, WPd, and MnPd. X-Ray crystal structures of [Cp(CO)2Mo(μ-PCy2)Pd(PCy2H)2] and [(CO)4Mn(μ-PCy2)Pd(PCy1H)2] (1989) (0)
Reactions of (Ru3(CO)12) with Nitrogen-Containing Heterocycles. Crystal Structures of (Ru3(μ-H)(μ3-ppy)(CO)9) and (Ru3(μ-napy)(μ-CO)3(CO)7). (1988) (0)
DYNAMIC BEHAVIOR OF CARBON-METALLATED PALLADIUM HYDRAZONE COMPLEXES. CRYSTAL STRUCTURES OF BIS(CHLORO(2,2,3-TRIMETHYL-5-PHENYL-4,5-DIAZAHEX-3-ENYL)PALLADIUM(II)) AND BIS(CHLORO(2-TERT-BUTYL-4-PHENYL-3,4-DIAZAPENT-2-ENYL)PALLADIUM(II)) (1985) (0)
Synthesis and Characterization of Monocyclopentadienyl Niobium Derivatives. X-Ray Crystal Structure of Di-μ-chloro-μ-oxo-bis(dichloro(η-trimethylsilylcyclopentadienyl)niobi# um(V)), ((Nb(η-C5H4SiMe3)Cl2)2(μ-O)(μ-Cl)2). (1987) (0)
Aminocarbyne coupling reactions leading to the bis(amino)acetylene complexes trans-[MF(η2-MeHNC≡CNHMe)-(Ph2PCH2CH2PPh2)2][BF4] (M = Mo or W) and cleavage of the acetylenic-triple bond. A reformulation, and X-ray structure of the Mo compound (1993) (0)

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