Barry Trost
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American chemist
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Chemistry
Barry Trost's Degrees
- Bachelors Chemistry University of Pennsylvania
Why Is Barry Trost Influential?
(Suggest an Edit or Addition)According to Wikipedia, Barry M. Trost is an American chemist who is the Job and Gertrud Tamaki Professor Emeritus in the School of Humanities and Sciences at Stanford University. The Tsuji-Trost reaction and the Trost ligand are named after him. He is prominent for advancing the concept of atom economy.
Barry Trost's Published Works
Published Works
- Asymmetric Transition Metal-Catalyzed Allylic Alkylations. (1996) (2131)
- Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis. (2003) (1970)
- Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way (1995) (1952)
- On inventing reactions for atom economy. (2002) (967)
- Asymmetric Syntheses of Oxindoleand Indole Spirocyclic Alkaloid Natural Products (2009) (868)
- Catalytic enantioselective construction of all-carbon quaternary stereocenters (2006) (760)
- Green chemistry for chemical synthesis (2008) (659)
- The direct catalytic asymmetric aldol reaction. (2010) (585)
- Non-metathesis ruthenium-catalyzed C-C bond formation. (2001) (547)
- Atomökonomische Synthesen – eine Herausforderung in der Organischen Chemie: die Homogenkatalyse als wegweisende Methode (1995) (483)
- On the use of the O-methylmandelate ester for establishment of absolute configuration of secondary alcohols (1986) (462)
- Ruthenium-catalyzed reactions--a treasure trove of atom-economic transformations. (2005) (412)
- New synthetic reactions. Sulfenylations and dehydrosulfenylations of esters and ketones (1976) (403)
- Palladium-catalyzed enantioselective C-3 allylation of 3-substituted-1H-indoles using trialkylboranes. (2006) (383)
- Asymmetric allylic alkylation, an enabling methodology. (2004) (381)
- Predicting the stereochemistry of diphenylphosphino benzoic acid (DPPBA)-based palladium-catalyzed asymmetric allylic alkylation reactions: a working model. (2006) (374)
- New rules of selectivity: allylic alkylations catalyzed by palladium (1980) (366)
- The Enantioselective Addition of Alkyne Nucleophiles to Carbonyl Groups. (2009) (365)
- A modular approach for ligand design for asymmetric allylic alkylations via enantioselective palladium-catalyzed ionizations (1992) (358)
- Chemoselective oxidation of sulfides to sulfones with potassium hydrogen persulfate (1981) (337)
- .alpha.-Sulfenylated carbonyl compounds in organic synthesis (1978) (334)
- Palladium-catalyzed cycloisomerizations of enynes and related reactions (1990) (325)
- Enantioselective construction of spirocyclic oxindolic cyclopentanes by palladium-catalyzed trimethylenemethane-[3+2]-cycloaddition. (2007) (322)
- [3+2] Cycloaddition Approaches to Five‐Membered Rings via Trimethylenemethane and Its Equivalents [New Synthetic Methods (55)] (1986) (317)
- Organopalladium intermediates in organic synthesis (1977) (314)
- Transition Metal Catalyzed Cycloisomerizations (1998) (287)
- Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation (2010) (285)
- Addition of Metalloid Hydrides to Alkynes: Hydrometallation with Boron, Silicon, and Tin (2005) (278)
- New synthetic reactions. Allylic alkylation (1973) (275)
- A dinuclear Zn catalyst for the asymmetric nitroaldol (Henry) reaction. (2002) (268)
- Comprehensive organic synthesis : selectivity, strategy & efficiency in modern organic chemistry (1991) (265)
- DESIGNING A RECEPTOR FOR MOLECULAR RECOGNITION IN A CATALYTIC SYNTHETIC REACTION : ALLYLIC ALKYLATION (1996) (265)
- Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition. (2005) (254)
- A direct catalytic asymmetric mannich-type reaction to syn-amino alcohols. (2003) (252)
- Asymmetric Aldol Reaction via a Dinuclear Zinc Catalyst: α-Hydroxyketones as Donors (2001) (236)
- Palladium-Catalyzed Additions of Terminal Alkynes to Acceptor Alkynes (1997) (235)
- A model for metal-templated catalytic asymmetric induction via .pi.-allyl fragments (1985) (232)
- Selectivity: A Key to Synthetic Efficiency (1983) (219)
- Palladium-catalyzed decarboxylative asymmetric allylic alkylation of enol carbonates. (2009) (217)
- Regio- and enantioselective Pd-catalyzed allylic alkylation of ketones through allyl enol carbonates. (2005) (207)
- Pd asymmetric allylic alkylation (AAA). A powerful synthetic tool. (2002) (206)
- Cyclizations via Palladium-Catalyzed Allylic Alkylations [New Synthetic Methods (79)] (1989) (206)
- Effect of ligand structure on the zinc-catalyzed Henry reaction. Asymmetric syntheses of (-)-denopamine and (-)-arbutamine. (2002) (205)
- Allylic alkylation. Palladium-catalyzed substitutions of allylic carboxylates. Stereo- and regiochemistry (1980) (198)
- Total synthesis of bryostatin 16 using atom-economical and chemoselective approaches (2008) (198)
- Chemoselectivity in the ruthenium-catalyzed redox isomerization of allyl alcohols (1993) (195)
- Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes. (2001) (192)
- Dynamic Kinetic Asymmetric Transformation of Diene Monoepoxides: A Practical Asymmetric Synthesis of Vinylglycinol, Vigabatrin, and Ethambutol (2000) (190)
- Dinuclear Zn-catalyzed asymmetric alkynylation of unsaturated aldehydes. (2006) (188)
- Atom economy. Palladium-catalyzed formation of coumarins by addition of phenols and alkynoates via a net C-H insertion. (2003) (181)
- Palladium-Catalyzed Asymmetric Alkylation of Ketone Enolates (1999) (179)
- New strategies for the synthesis of vitamin D metabolites via palladium-catalyzed reactions (1992) (179)
- The palladium catalyzed asymmetric addition of oxindoles and allenes: an atom-economical versatile method for the construction of chiral indole alkaloids. (2011) (177)
- Development of chiral sulfoxide ligands for asymmetric catalysis. (2015) (174)
- Neutral alkylations via palladium(0) catalysis (1981) (173)
- Chemical Chameleons. Organosulfones as Synthetic Building Blocks (1988) (171)
- A chemoselective reduction of alkynes to (E)-alkenes. (2002) (171)
- Nucleophilic α-Addition to Alkynoates. A Synthesis of Dehydroamino Acids (1997) (170)
- Asymmetric induction in catalytic allylic alkylation (1977) (170)
- Palladium-catalyzed asymmetric allylation of prochiral nucleophiles: synthesis of 3-allyl-3-aryl oxindoles. (2005) (168)
- Elaboration of Conjugated Alkenes Initiated by Insertion into a Vinylic C-H Bond (1995) (165)
- Asymmetric induction in allylic alkylations of 3-(acyloxy)cycloalkenes (1994) (165)
- Molybdenum-catalyzed asymmetric allylation of 3-alkyloxindoles: application to the formal total synthesis of (-)-physostigmine. (2006) (164)
- Internal redox catalyzed by triphenylphosphine (1992) (164)
- Palladium-catalyzed dynamic kinetic asymmetric transformations of vinyl aziridines with nitrogen heterocycles: rapid access to biologically active pyrroles and indoles. (2010) (163)
- Metal-mediated approach to enynes (1987) (161)
- Palladium-catalyzed diastereo- and enantioselective synthesis of substituted cyclopentanes through a dynamic kinetic asymmetric formal [3+2]-cycloaddition of vinyl cyclopropanes and alkylidene azlactones. (2011) (159)
- Pd and Mo Catalyzed Asymmetric Allylic Alkylation. (2012) (158)
- Novel "Umpolung" in C-C Bond Formation Catalyzed by Triphenylphosphine (1994) (157)
- Ruthenium-Catalyzed Intramolecular [5 + 2] Cycloadditions (2000) (155)
- Centenary Lecture. Cyclopentanoids: a challenge for new methodology (1982) (154)
- Modern alkyne chemistry : catalytic and atom-economic transformations (2014) (153)
- A total synthesis of racemic and optically active ibogamine. Utilization and mechanism of a new silver ion assisted palladium catalyzed cyclization (1978) (152)
- A stereospecific ruthenium-catalyzed allylic alkylation. (2002) (152)
- Asymmetric Friedel-Crafts alkylation of pyrroles with nitroalkenes using a dinuclear zinc catalyst. (2008) (152)
- A Direct Catalytic Asymmetric Mannich-type Reaction via a Dinuclear Zinc Catalyst: Synthesis of Either anti- or syn-α-Hydroxy-β-Amino Ketones (2006) (151)
- Metal vinylidenes as catalytic species in organic reactions. (2008) (150)
- Palladium-Catalyzed Asymmetric Allylicα-Alkylation of Acyclic Ketones (2005) (150)
- New conjunctive reagents. 2-Acetoxymethyl-3-allyltrimethylsilane for methylenecyclopentane annulations catalyzed by palladium(0) (1979) (147)
- Direct asymmetric Michael addition to nitroalkenes: vinylogous nucleophilicity under dinuclear zinc catalysis. (2009) (146)
- DESULFONYLATION OF ARYL ALKYL SULFONES (1976) (144)
- Phosphine-Catalyzed Isomerization-Addition of Oxygen Nucleophiles to 2-Alkynoates (1994) (143)
- Divergent enantioselective synthesis of (-)-galanthamine and (-)-morphine. (2005) (143)
- SOME ASPECTS OF ORGANOSULFUR-MEDIATED SYNTHETIC METHODS (1978) (143)
- Transition-metal-controlled synthesis of (.+-.)-aristeromycin and (.+-.)-2',3'-diepi-aristeromycin. An unusual directive effect in hydroxylations (1988) (142)
- Callipeltoside a: total synthesis, assignment of the absolute and relative configuration, and evaluation of synthetic analogues. (2002) (142)
- Direct catalytic asymmetric aldol additions of methyl ynones. Spontaneous reversal in the sense of enantioinduction. (2004) (141)
- Mo-catalyzed regio-, diastereo-, and enantioselective allylic alkylation of 3-aryloxindoles. (2007) (140)
- Asymmetric Catalysis. (2004) (140)
- A general synthetic strategy toward aminocyclopentitol glycosidase inhibitors. Application of palladium catalysis to the synthesis of allosamizoline and mannostatin A (1993) (139)
- Rhodium-catalyzed cycloisomerization: formation of indoles, benzofurans, and enol lactones. (2007) (139)
- Enol thioethers as enol substitutes. An alkylation sequence (1983) (138)
- Exercising regiocontrol in palladium-catalyzed asymmetric prenylations and geranylation: unifying strategy toward flustramines A and B. (2011) (137)
- An unusual mechanism of a palladium-catalyzed intramolecular carbametalation. A novel palladium-catalyzed rearrangement (1988) (137)
- Synthesis of chiral chromans by the Pd-catalyzed asymmetric allylic alkylation (AAA): scope, mechanism, and applications. (2004) (137)
- New synthetic reactions. Sulfenylation-dehydrosulfenylation as a method for introduction of unsaturation (1973) (134)
- A Ru catalyzed divergence: oxidative cyclization vs cycloisomerization of bis-homopropargylic alcohols. (2002) (134)
- Ruthenium-catalyzed vinylsilane synthesis and cross-coupling as a selective approach to alkenes: benzyldimethylsilyl as a robust vinylmetal functionality. (2003) (132)
- Palladium asymmetric allylic alkylation of prochiral nucleophiles: horsfiline. (2006) (131)
- Enantioselective Allylations of Azlactones with Unsymmetrical Acyclic Allyl Esters (1999) (131)
- Strategy for employing unstabilized nucleophiles in palladium-catalyzed asymmetric allylic alkylations. (2008) (130)
- Cyclization via isomerization: a palladium(2+)-catalyzed carbocyclization of 1,6-enynes to 1,3- and 1,4-dienes (1985) (129)
- Tetra-n-butylammonium oxone. Oxidations under anhydrous conditions (1988) (128)
- Asymmetric alkylation of beta-ketoesters (1997) (128)
- Concise total synthesis of (+/-)-marcfortine B. (2007) (128)
- Palladium-mediated cycloaddition approach to cyclopentanoids. Introduction and initial studies (1983) (127)
- Palladium-catalyzed diastereo- and enantioselective formal [3 + 2]-cycloadditions of substituted vinylcyclopropanes. (2012) (127)
- Palladium-catalyzed asymmetric addition of pronucleophiles to allenes. (2003) (126)
- Synthesis of novel quaternary amino acids using molybdenum-catalyzed asymmetric allylic alkylation. (2002) (125)
- Allylic alkylation: preparation of .pi.-allylpalladium complexes from olefins (1978) (125)
- Metal Catalyzed Allylic Alkylation: Its Development in the Trost Laboratories. (2015) (125)
- Applications of transition metal catalysis in drug discovery and development : an industrial perspective (2012) (125)
- ProPhenol-Catalyzed Asymmetric Additions by Spontaneously Assembled Dinuclear Main Group Metal Complexes (2015) (122)
- Asymmetric Ligands for Transition‐Metal‐Catalyzed Reactions: 2‐Diphenylphosphinobenzoyl Derivatives of C2‐Symmetric Diols and Diamines (1992) (122)
- Total syntheses of furaquinocin A, B, and E. (2003) (119)
- Steric steering with supported palladium catalysts (1978) (118)
- Dynamic kinetic asymmetric allylic alkylations of allenes. (2005) (118)
- Palladium-catalyzed asymmetric construction of vicinal all-carbon quaternary stereocenters and its application to the synthesis of cyclotryptamine alkaloids. (2013) (117)
- New class of nucleophiles for palladium-catalyzed asymmetric allylic alkylation. Total synthesis of agelastatin A. (2006) (116)
- Allyl sulfones as synthons for 1,1- and 1,3-dipoles via organopalladium chemistry (1980) (115)
- Asymmetric allylic alkylation of cyclic vinylogous esters and thioesters by Pd-catalyzed decarboxylation of enol carbonate and beta-ketoester substrates. (2006) (115)
- A theoretical study on the mechanism, regiochemistry, and stereochemistry of hydrosilylation catalyzed by cationic ruthenium complexes. (2003) (115)
- Direct asymmetric aldol reactions of acetone using bimetallic zinc catalysts. (2001) (114)
- Fünfgliedrige Ringe durch [3+2]-Cycloaddition mit Trimethylenmethan und Syntheseäquivalenten (1986) (114)
- Transition metal-catalyzed couplings of alkynes to 1,3-enynes: modern methods and synthetic applications. (2016) (114)
- Pd-Catalyzed Cycloisomerization to 1,2-Dialkylidenecycloalkanes .1. (1994) (114)
- Palladium-catalyzed asymmetric benzylation of 3-aryl oxindoles. (2010) (113)
- A model for asymmetric induction in the Diels-Alder reaction (1980) (113)
- Enolstannanes as electrofugal groups in allylic alkylation (1980) (112)
- Deracemization of Baylis−Hillman Adducts (2000) (112)
- DYKAT of Baylis-Hillman adducts: concise total synthesis of furaquinocin E. (2002) (111)
- gem-Diacetates as carbonyl surrogates for asymmetric synthesis. Total syntheses of sphingofungins E and F. (2001) (111)
- Chemoselectivity in molybdenum catalyzed alcohol and aldehyde oxidations (1984) (110)
- Reaction of olefins with palladium trifluoroacetate (1980) (109)
- Cis hydroxyamination equivalent. Application to the synthesis of (-)-acosamine (1987) (109)
- New synthetic reactions. X. Versatile cyclobutanone (spiroannelation) and .gamma.-butyrolactone (lactone annelation) synthesis (1973) (108)
- Dynamic kinetic asymmetric cycloadditions of isocyanates to vinylaziridines. (2003) (108)
- Allylic alkylation: nucleophilic attack on .pi.-allylpalladium complexes (1978) (106)
- Palladium-catalyzed regio-, diastereo-, and enantioselective benzylic allylation of 2-substituted pyridines. (2009) (106)
- A simple synthesis of dienones via isomerization of alkynones effected by palladium catalysts (1988) (105)
- Palladium-catalyzed dearomative trimethylenemethane cycloaddition reactions. (2014) (104)
- Palladium-mediated vicinal cleavage of allyl epoxides with retention of stereochemistry: a cis hydroxylation equivalent (1985) (104)
- Desymmetrization of meso 1,3- and 1,4-diols with a dinuclear zinc asymmetric catalyst. (2003) (103)
- An atom-economic synthesis of nitrogen heterocycles from alkynes. (2011) (103)
- Group-transfer polymerization. 3. Lewis acid catalysis (1984) (102)
- A novel palladium-catalyzed cycloalkylation to isoxazoline 2-oxides. Application for the asymmetric synthesis of carbanucleosides. (1992) (102)
- A concise synthesis of (-)-oseltamivir. (2008) (100)
- Ruthenium‐katalysierte Reaktionen – eine Schatzkiste für atomökonomische Umwandlungen (2005) (100)
- Magnesium-catalyzed asymmetric direct aldol addition of ethyl diazoacetate to aromatic, aliphatic, and alpha,beta-unsaturated aldehydes. (2009) (100)
- Tungsten-catalyzed allylic alkylations. New avenues for selectivity (1983) (99)
- Palladium-catalyzed DYKAT of butadiene monoepoxide: enantioselective total synthesis of (+)-DMDP, (-)-bulgecinine, and (+)-broussonetine G. (2006) (99)
- Pd-Catalyzed Cycloisomerization to 1,2-Dialkylidenecycloalkanes. 2. Alternative Catalyst System (1994) (97)
- Contemporaneous dual catalysis by coupling highly transient nucleophilic and electrophilic intermediates generated in situ. (2011) (97)
- Die Struktur des Juvenilhormons (1967) (97)
- A Rh(I)-catalyzed cycloisomerization of homo- and bis-homopropargylic alcohols. (2003) (97)
- 57 – Organopalladium Compounds in Organic Synthesis and in Catalysis (1982) (96)
- A Pd-Catalyzed (2 + 2) Cycloaddition. Mechanism of a Pd-Catalyzed Enyne Metathesis. (1993) (96)
- Asymmetric Total Synthesis of (+)-Pancratistatin (1995) (96)
- An enantiodirected cyclopentenone annulation. Synthesis of a useful building block for condensed cyclopentanoid natural products (1980) (95)
- Dinuclear asymmetric Zn aldol additions: formal asymmetric synthesis of fostriecin. (2005) (95)
- Syntheses of seven-membered rings: ruthenium-catalyzed intramolecular [5+2] cycloadditions. (2005) (95)
- Enantioselective ProPhenol-catalyzed addition of 1,3-diynes to aldehydes to generate synthetically versatile building blocks and diyne natural products. (2010) (95)
- Catalytic Asymmetric Alkylation of Nucleophiles: Asymmetric Synthesis of α‐Alkylated Amino Acids (1997) (94)
- ON THE QUESTION OF ASYMMETRIC INDUCTION WITH ACYCLIC ALLYLIC SUBSTRATES. AN ASYMMETRIC SYNTHESIS OF (+)-POLYOXAMIC ACID (1996) (94)
- Ruthenium-catalyzed cycloisomerizations of diynols. (2005) (94)
- Access to a welwitindolinone core using sequential cycloadditions. (2009) (93)
- Asymmetric synthesis of allylic sulfones useful as asymmetric building blocks. (1995) (93)
- New synthetic methods. Transfer of chirality from sulfur to carbon (1973) (93)
- Palladium-catalyzed asymmetric allylic alkylation of ketone enolates. (2004) (93)
- Stereocontrolled approach to steroid side chain via organopalladium chemistry. Partial synthesis of 5.alpha.-cholestanone (1978) (93)
- Development of aliphatic alcohols as nucleophiles for palladium-catalyzed DYKAT reactions: total synthesis of (+)-hippospongic acid A. (2005) (93)
- A ruthenium-catalyzed reconstitutive condensation of acetylenes and allyl alcohols (1990) (92)
- Allylic substitutions with retention of stereochemistry (1976) (92)
- Asymmetric catalysis: an enabling science. (2004) (92)
- Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions. (2006) (92)
- 5H-oxazol-4-ones as building blocks for asymmetric synthesis of alpha-hydroxycarboxylic acid derivatives. (2004) (92)
- Palladium-catalyzed enantioselective allylic alkylations through C-H activation. (2013) (92)
- Benzylic phosphates as electrophiles in the palladium-catalyzed asymmetric benzylation of azlactones. (2012) (91)
- Palladium-Catalyzed Enyne Cycloisomerization Reaction in an Asymmetric Approach to the Picrotoxane Sesquiterpenes. 2. Second-Generation Total Syntheses of Corianin, Picrotoxinin, Picrotin, and Methyl Picrotoxate (1999) (91)
- Asymmetric synthesis of bicyclo[4.3.1]decadienes and bicyclo[3.3.2]decadienes via [6 + 3] trimethylenemethane cycloaddition with tropones. (2008) (91)
- New synthetic reactions. Asymmetric induction in allylic alkylations (1973) (91)
- Palladium-catalyzed asymmetric allylic alkylations of polynitrogen-containing aromatic heterocycles. (2011) (90)
- MOLYBDENUM CATALYSTS FOR ALLYLIC ALKYLATION (1982) (90)
- New synthetic methods. Secoalkylative approach to grandisol (1975) (90)
- A new palladium catalyst for intramolecular carbametalations of enynes (1989) (90)
- An alkyne hydrosilylation-oxidation strategy for the selective installation of oxygen functionality. (2005) (90)
- Intramolecular endo-dig hydrosilylation catalyzed by ruthenium: evidence for a new mechanistic pathway. (2003) (89)
- New synthetic reactions. A chemoselective approach to cleavage .alpha. to a carbonyl group via .beta.-keto sulfides. Preparation of 1,2-diketones (1977) (89)
- Unusual effects in the pd-catalyzed asymmetric allylic alkylations: synthesis of chiral chromans. (2003) (89)
- Total synthesis of (-)-pseudolaric acid B. (2007) (88)
- A highly enantio- and diastereoselective molybdenum-catalyzed asymmetric allylic alkylation of cyanoesters. (2011) (88)
- A catalytic asymmetric Wagner-Meerwein shift. (2001) (88)
- New synthetic reactions. Synthesis of cyclobutanes, cyclobutenes, and cyclobutanones. Applications in geminal alkylation (1977) (87)
- Chemoselectivity of the ruthenium-catalyzed hydrative diyne cyclization: total synthesis of (+)-cylindricine C, D, and E. (2003) (87)
- Palladium catalyzed kinetic and dynamic kinetic asymmetric transformations of gamma-acyloxybutenolides. Enantioselective total synthesis of (+)-Aflatoxin B1 and B2a. (2003) (86)
- Annulation via alkylation-Alder ene cyclizations. Palladium-catalyzed cycloisomerization of 1,6-enynes (1991) (86)
- Structure and reactivity of late transition metal η³-benzyl complexes. (2014) (86)
- Total synthesis of (+)-frondosin A. Application of the Ru-catalyzed [5+2] cycloaddition. (2007) (86)
- Direct asymmetric Zn-aldol reaction of methyl vinyl ketone and its synthetic applications. (2005) (86)
- Cyclization catalyzed by palladium(0). Initial studies and macrolide formation (1980) (85)
- Sequential Ru-Pd catalysis: a two-catalyst one-pot protocol for the synthesis of N- and O-heterocycles. (2006) (85)
- Dinuclear zinc catalyzed asymmetric spirannulation reaction: an umpolung strategy for formation of α-alkylated-α-hydroxyoxindoles. (2012) (85)
- Enantioselective synthesis of alpha-tertiary hydroxyaldehydes by palladium-catalyzed asymmetric allylic alkylation of enolates. (2007) (85)
- Palladium-catalyzed cyclizations of polyenynes. A palladium zipper (1993) (84)
- New synthetic reactions. IX. Facile synthesis of oxaspiropentanes, versatile synthetic intermediates (1973) (84)
- Synthesis of a ring-expanded bryostatin analogue. (2007) (84)
- A palladium-catalyzed zipper reaction (1991) (84)
- Dimethylmethylthiosulfonium fluoroborate. A chemoselective initiator for thionium ion induced cyclizations (1981) (84)
- On the mechanism of the ruthenium-catalyzed reconstitutive condensation of allylic alcohols and terminal alkynes (1992) (84)
- The Chemistry of Carbanions. X. The Selective Alkylation of Unsymmetrical Ketones1 (1965) (84)
- Rapid access to spirocyclic oxindole alkaloids: application of the asymmetric palladium-catalyzed [3 + 2] trimethylenemethane cycloaddition. (2013) (84)
- Additions and Corrections - A Stereocontrolled Total Synthesis of (±)-Hirsutic Acid C (1979) (83)
- Atom economic asymmetric creation of quaternary carbon: regio- and enantioselective reactions of a vinylepoxide with a carbon nucleophile. (2001) (83)
- Ru-catalyzed alkene-alkyne coupling. Total synthesis of amphidinolide P. (2005) (83)
- Palladium-catalyzed asymmetric ring expansion of allenylcyclobutanols: an asymmetric Wagner-Meerwein shift. (2006) (83)
- Ligand dependence of molybdenum-catalyzed alkylations. Molybdenum-isonitrile complexes as a new class of highly reactive alkylation catalysts (1990) (82)
- A Two-Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles (1998) (82)
- Biomimetic enantioselective total synthesis of (-)-siccanin via the Pd-catalyzed asymmetric allylic alkylation (AAA) and sequential radical cyclizations. (2004) (82)
- On the Use of O-Methylmandelic Acid for the Establishment of Absolute Configuration of .alpha.-Chiral Primary Amines (1994) (81)
- Intramolecular enyne metathesis reaction. Route to bridged bicycles with bridgehead olefins (1991) (81)
- Enantioselective synthesis of (-)-codeine and (-)-morphine. (2002) (81)
- Enantioselective construction of pyrrolidines by palladium-catalyzed asymmetric [3 + 2] cycloaddition of trimethylenemethane with imines. (2008) (81)
- Palladium-catalyzed asymmetric allylic alkylation of 2-acylimidazoles as ester enolate equivalents. (2010) (81)
- A [3+2] cycloaddition and [4+3] cycloaddition approach to N-heterocycles via palladium-catalyzed TMM reactions with imines (1993) (81)
- Asymmetric Synthesis of (−)-Anatoxin-a via an Asymmetric Cyclization Using a New Ligand for Pd-Catalyzed Alkylations (1999) (81)
- Two-Metal Catalyst System for Redox Isomerization of Propargyl Alcohols to Enals and Enones. (1995) (81)
- Ruthenium Catalyzed Synthesis of Butenolides and Pentenolides via Contra-Electronic .alpha.-Alkylation of Hydroxyalkynoates (1995) (80)
- Palladium-catalyzed DYKAT of vinyl epoxides: enantioselective total synthesis and assignment of the configuration of (+)-Broussonetine G. (2003) (80)
- On asymmetric induction in allylic alkylation via enantiotopic facial discrimination (1996) (80)
- A RU CATALYZED ADDITION OF ALKENES TO ALKYNES (1995) (80)
- Directing Tandem Catalyzed Reactions as an Approach to Furans and Butenolides (1995) (80)
- Reductive cyclization of 1,6- and 1,7-enynes (1987) (80)
- Dinuclear zinc-catalyzed enantioselective Aza-Henry reaction. (2007) (79)
- Palladium-catalyzed asymmetric [3+2] cycloaddition of trimethylenemethane with imines. (2007) (79)
- Ruthenium-catalyzed cycloisomerization-6pi-cyclization: a novel route to pyridines. (2007) (79)
- Sulfur ylides : emerging synthetic intermediates (1975) (78)
- Nitrogen Pronucleophiles in the Phosphine-Catalyzed γ-Addition Reaction (1997) (78)
- Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis. (2009) (78)
- Juvenile hormone. V. Synthesis of the racemic juvenile hormone (1967) (77)
- 4-Aryloxybutenolides as "chiral aldehyde" equivalents: an efficient enantioselective synthesis of (+)-brefeldin a. (2002) (77)
- Palladium-Catalyzed Addition of Pronucleophiles to Allenes (1995) (77)
- Sulfones as chemical chameleons. Cyclization via 1,1-dipole synthons (1984) (77)
- Regio- and Enantioselective Molybdenum-Catalyzed Alkylations of Polyenyl Esters (1999) (77)
- An atom-economic and selective ruthenium-catalyzed redox isomerization of propargylic alcohols. An efficient strategy for the synthesis of leukotrienes. (2008) (76)
- A novel ruthenium-catalyzed tandem cyclization-reconstitutive addition of propargyl alcohols with allyl alcohols (1992) (76)
- Novel allene-acetylene cross-condensation catalyzed by palladium complexes (1990) (75)
- Palladium-catalyzed diastereo- and enantioselective Wagner-Meerwein shift: control of absolute stereochemistry in the C-C bond migration event. (2008) (75)
- Stereocontrolled total synthesis of (+)-streptazolin by a palladium-catalyzed reductive diyne cyclization. (2004) (75)
- Palladium-catalyzed asymmetric allylic alkylation of meso- and dl-1,2-divinylethylene carbonate. (2006) (75)
- Palladium-Catalyzed Asymmetric Allylic Alkylation of 3-Substituted 1 H-Indoles and Tryptophan Derivatives with Vinylcyclopropanes. (2018) (75)
- Contemporaneous dual catalysis: chemoselective cross-coupling of catalytic vanadium-allenoate and π-allylpalladium intermediates. (2011) (75)
- When Is a Proton Not a Proton (1998) (74)
- An unusual oxidative cyclization. A synthesis and absolute stereochemical assignment of (-)-rocaglamide (1990) (74)
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- Origin of enhanced axial attack by sterically undemanding nucleophiles on cyclohexenones (1987) (50)
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- A convenient chemoselective semihydrogenation of acetylenes using homogeneous catalysis (1989) (48)
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- A Practical Synthesis of Rosefuran. Furans from Acetylenes and Allyl Alcohols (1994) (46)
- Methods in alkaloid synthesis. Imino ethers as donors in the Michael reaction (1975) (45)
- A Versatile Enantioselective Strategy Toward L-C-Nucleosides: A Total Synthesis of L-Showdomycin. (1999) (45)
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- A short and concise asymmetric synthesis of hamigeran B. (2005) (42)
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- A 1,3-O- to -C-alkyl shift catalyzed by palladium (1980) (42)
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- Enantioselective palladium-catalyzed [3 + 2] cycloadditions of trimethylenemethane with nitroalkenes. (2012) (41)
- Enol thioethers in synthesis. Regiocontrolled arylation via organopalladium chemistry (1979) (41)
- Asymmetric synthesis of oxygen heterocycles via Pd-catalyzed dynamic kinetic asymmetric transformations: application to nucleosides. (2003) (41)
- The juvenile hormone. IV. Stereochemistry of juvenile hormone and biological activity of some of its isomers and related compounds. (1968) (41)
- A formal synthesis of (-)-mycalamide A. (2004) (40)
- The Effect of Acetylene Substituents on a PdII‐Catalyzed Cycloisomerization. Total Synthesis of (–)‐Sterepolide and Assignment of Absolute Stereochemistry (1989) (40)
- Nucleophilic attack on olefins initiated by dimethylmethylthiosulfonium fluoroborate (DMTSF). Cyanosulfenylation and oxy- and oxosulfenylation (1982) (40)
- An efficient one-pot enantio- and diastereoselective synthesis of heterocycles. (2002) (40)
- Stereochemistry of desulfurization of thietane derivatives (1971) (40)
- Thionium ions as carbonyl substitutes. Synthesis of cyclic imino thioethers and lactams (1980) (40)
- Cyclizations initiated by a palladium(2+)-silver(1+) mixed-metal system (1982) (40)
- New stereocontrolled approach to spirosesquiterpenes. Synthesis of acorenone B (1975) (40)
- New synthetic methods. Stereocontrolled bicycloannulation: an approach to gibberellins (1978) (40)
- 2,3-Bis[(trimethylsilyl)methyl]-1,3-butadiene. A conjunctive reagent for tandem Diels-Alder reactions (1982) (39)
- Asymmetric induction in a palladium-catalyzed TMM cycloaddition. Mechanistic implications regarding the reactive intermediate (1989) (39)
- Cyclizations via organopalladium intermediates. Macrolide formation (1977) (39)
- Stereocontrolled synthesis of the ecdysone side chain via organopalladium chemistry. (1977) (39)
- Chemistry of .alpha.,.alpha.'-bis(diazo)ketones (1974) (39)
- Readily accessible chiral diene ligands for Rh-catalyzed enantioselective conjugate additions of boronic acids. (2011) (39)
- Asymmetric Transition Metal‐Catalyzed Allylic Alkylations (1996) (39)
- Molecular Gymnastics of Alkynes Orchestrated by Ruthenium Complexes (1996) (39)
- Unusual chemoselectivity using difunctional allylic alkylating agents (1987) (39)
- On the Effect of a Cation Binding Site in an Asymmetric Ligand for a Catalyzed Nucleophilic Substitution Reaction (1997) (38)
- AAA in KAT/DYKAT processes: first- and second-generation asymmetric syntheses of (+)- and (-)-cyclophellitol. (2001) (38)
- Sulfur as a regiochemical control element. Synthesis of 2-alkoxy(acyloxy)-3-alkyl(aryl)thiobuta-1,3-dienes (1980) (38)
- New synthetic methods. Ring expansion approach to .alpha.-methylene .delta.-lactones (1975) (38)
- A novel palladium-catalyzed reductive cyclization (1987) (38)
- THIONIUM IONS AS REACTIVE CARBONYL EQUIVALENTS IN CYCLIZATION REACTIONS (1979) (38)
- A new strategy for the synthesis of chiral β-alkynyl esters via sequential palladium and copper catalysis. (2011) (38)
- Zn-ProPhenol Catalyzed Enantio- and Diastereoselective Direct Vinylogous Mannich Reactions between α,β- and β,γ-Butenolides and Aldimines. (2017) (38)
- A regioselective Ru-catalyzed alkene-alkyne coupling. (2000) (38)
- Migratory hydroamination: a facile enantioselective synthesis of benzomorphans. (2003) (38)
- Regio- and stereoselectivity of allylic alkylation (1975) (38)
- Ligand-accelerated enantioselective propargylation of aldehydes via allenylzinc reagents. (2011) (38)
- Desulfurization of episulfides, a sulfurane reaction (1973) (38)
- A STEREOCONTROLLED APPROACH TOWARD VITAMIN D METABOLITES. A SYNTHESIS OF THE INHOFFEN-LYTHGOE DIOL (1979) (37)
- Atom economy. A simple Pd catalyzed addition of pronucleophiles with dienes (1992) (37)
- Enantio- and Diastereoselective Synthesis of Chiral Allenes by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition Reactions. (2018) (37)
- Alkene-alkyne coupling as a linchpin: an efficient and convergent synthesis of amphidinolide P. (2004) (37)
- Regiochemical diversity in allylic alkylations via molybdenum catalysts (1987) (37)
- A metal-catalyzed cyclization of enallenes (1988) (37)
- On the diastereoselectivity of ru-catalyzed [5 + 2] cycloadditions. (2003) (37)
- Regiocontrolled synthesis of hydroxyphthalides. Synthesis of (.+-.)-isoochracinic acid and a zealeranone intermediate (1980) (37)
- Redox cycloisomerization approach to 1,2-dihydropyridines. (2015) (37)
- On an (oxatrimethylenemethane)palladium(0) complex. An unusual palladium(0)-catalyzed cyclopropanation (1989) (37)
- New synthetic reactions. Stereochemistry of allylic alkylation (1975) (37)
- Ruthenium-catalyzed alkene-alkyne coupling of disubstituted olefins: application to the stereoselective synthesis of trisubstituted enecarbamates. (2015) (37)
- Geminal alkylation: substitutions of allyl sulfones. Regiocontrol via molybdenum catalysis (1990) (37)
- A flexible approach toward trans-fused polycyclic tetrahydropyrans. A synthesis of prymnesin and yessotoxin units. (2004) (37)
- A SIMPLE DIVERGENCE FROM ASYMMETRIC CYCLOPROPANE TO LACTONE ANNULATION (1997) (37)
- Cyclic 1,2-diketones as core building blocks: a strategy for the total synthesis of (-)-terpestacin. (2010) (36)
- Asymmetric synthesis of alpha-substituted aldehydes by Pd-catalyzed asymmetric allylic alkylation-alkene isomerization-Claisen rearrangement. (2006) (36)
- A concise synthesis of (-)-lasonolide A. (2014) (36)
- Broad Spectrum Enolate Equivalent for Catalytic Chemo-, Diastereo-, and Enantioselective Addition to N-Boc Imines. (2015) (36)
- New synthetic reactions. Geminal alkylation via .alpha.-trimethylenedithiocyclobutanones (1975) (36)
- By-products of the Robinson Annelation Reaction with Cyclohexanone, Cyclopentanone, and Cyclopentane-1,2-dione1 (1965) (36)
- Preparation of Some Cyclopropanes and Stable Sulfoxonium Ylides from Dimethylsulfoxonium Methylide (1965) (36)
- On the palladium-catalyzed alkylation of silyl-substituted allyl acetates with enolates (1984) (36)
- Enantioselective construction of highly substituted vinylidenecylopentanes by palladium-catalyzed asymmetric [3+2] cycloaddition reaction. (2013) (36)
- Tandem palladium(0) and palladium(II)-catalyzed allylic alkylation through complementary redox cycles. (2012) (35)
- Pyracylene. Pentalenoid system (1967) (35)
- ACTIVATION IN TRANSITION-METAL CATALYSIS BY CATALYST RELAY. A SYNTHETIC APPROACH TO (-)-DENDROBINE (1991) (35)
- Formation of vinyl halides via a ruthenium-catalyzed three-component coupling. (2002) (35)
- Catalyst controlled diastereoselective N-alkylations of α-amino esters (1998) (35)
- Alkanyl sulfenylation. A direct approach for nucleophilic addition and substitution of olefins by carbanions (1984) (35)
- Syntheses of the picrotoxane skeleton via the palladium (II) - catalyzed carbacyclization reaction (1987) (35)
- Total synthesis of verrucarol (1982) (35)
- Lipid droplets can promote drug accumulation and activation (2019) (35)
- Chemoselectivity in palladium-mediated cycloadditions of substituted trimethylenemethanes (1985) (35)
- An unusual dichotomy in the regioselectivity of a metal catalyzed versus thermal ene reaction (1985) (35)
- Palladium-catalyzed asymmetric benzylation of azlactones. (2013) (34)
- Dinuclear Metal-ProPhenol Catalysts: Development and Synthetic Applications. (2020) (34)
- Palladium-catalyzed asymmetric allylic alkylation of barbituric acid derivatives: enantioselective syntheses of cyclopentobarbital and pentobarbital. (2000) (34)
- Theoretical studies of stereoselectivities of nucleophilic 1,2-additions to cyclohexenones. Transition structures and force-field models for metal hydride and keteniminate additions to ketones (1991) (34)
- A stereospecific palladium mediated [3+2] cycloaddition (1986) (34)
- The unusual role of CO transfer in molybdenum-catalyzed asymmetric alkylations. (2002) (34)
- Tandem alkylation-cycloadditions. Control by transition-metal templates (1984) (34)
- Dinuclear zinc-ProPhenol-catalyzed enantioselective α-hydroxyacetate aldol reaction with activated ester equivalents. (2013) (34)
- Regioselectivity control in a ruthenium-catalyzed cycloisomerization of diyne-ols. (2004) (34)
- Asymmetric induction of conduritols via AAA reactions: synthesis of the aminocyclohexitol of hygromycin A. (2001) (34)
- Vanadium-catalyzed anti-selective additions of allenols to imines. (2003) (34)
- Alkylative eliminations. Scope of the activating group (1975) (33)
- Tris(trimethylsilyl)aluminum and transition-metal catalysts. Silylation of allyl acetates (1983) (33)
- Palladium-mediated cycloaddition approach to loganin aglucon (1985) (33)
- Palladium-catalyzed asymmetric allylic alkylation of 3-aryloxindoles with allylidene dipivalate: a useful enol pivalate product. (2013) (33)
- A new diene synthesis via organopalladium chemistry (1980) (33)
- A RUTHENIUM-CATALYZED ALKYLATIVE CYCLOETHERIFICATION (1999) (33)
- Regiochemistry of the cycloaddition of a substituted trimethylenemethanepalladium complex (1981) (33)
- Diphenylsulfonium cyclopropylide. Useful spiroalkylation reagnet (1971) (32)
- Regiochemical control in the molybdenum-catalyzed reactions of trimethylsilyl- and ester-substituted allylic acetates (1983) (32)
- Tin mediated palladium catalyzed regiocontrolled alkylations of vinyl epoxides (1988) (32)
- 2-[(Trimethylsilyl)methyl]-1-(trimethylsilyl)propen-3-yl carboxylates in cycloaddition. Novel approach for substitutive cyclopentannulation (1988) (32)
- Effect of High Pressure on a Transition-Metal-Catalyzed Cycloaddition (1995) (32)
- General Strategy for the Asymmetric Synthesis of the Picrotoxanes (1996) (32)
- The Chemistry of Carbanions. XI. Michael Reactions with 2-Methylcyclopentanone and 2-Methylcyclohexanone1a (1966) (32)
- .alpha.-Elimination of .alpha.-acetoxysilanes induced by palladium: evidence for the intermediacy of a vinylcarbene-palladium complex (1983) (32)
- Template-directed synthesis of (.+-.)-allosamizoline and its 3,4-epimers (1990) (32)
- Enantioselective synthesis of 2,2-disubstituted tetrahydrofurans: palladium-catalyzed [3+2] cycloadditions of trimethylenemethane with ketones. (2013) (32)
- Computational modeling of stereoselectivity in the Diels-Alder reactions of dienol esters of O-methylmandelic acid and the question of .pi.-stacking (1990) (32)
- Transition metals and olefins. A promising land: A personal account (1986) (32)
- Palladium-catalyzed chemo- and enantioselective oxidation of allylic esters and carbonates. (2006) (32)
- On the regioselectivity of Pd catalyzed intramolecular carbametalations (1993) (31)
- Flexible strategy to polyfunctional cyclopentanes. A synthesis of mannostatin A (1991) (31)
- KINETICS OF THE SILOXYVINYLCYCLOPROPANE REARRANGEMENT USING A MICRO STIRRED FLOW REACTOR (1981) (31)
- The acyl effect on intramolecular palladium-catalyzed trimethylenemethane cycloadditions (1992) (31)
- Studies directed toward taxanes. Preparation of α-ketols by oxidative ring-opening of epoxides (1988) (31)
- Pd Catalyzed kinetic resolution of conduritol B. Asymmetric synthesis of (+)-cyclophellitol (1999) (31)
- Forging Odd-Membered Rings: Palladium-Catalyzed Asymmetric Cycloadditions of Trimethylenemethane. (2020) (31)
- New synthetic reactions. Geminal and reductive alkylations (1975) (31)
- New approach for the stereocontrolled synthesis of acyclic terpenes (1975) (31)
- Pyrones as Substrates for Palladium–Catalyzed [4 + 3] Cycloadditions (1989) (31)
- Palladium-catalyzed cycloisomerizations of alkynyl N-acyl enamines (1992) (31)
- Controlling Regioselectivity in the Enantioselective N-Alkylation of Indole Analogues Catalyzed by Dinuclear Zinc-ProPhenol. (2017) (31)
- ON PD-CATALYZED CYCLOISOMERIZATION VERSUS CYCLOREDUCTION. A GENERAL STRATEGY FOR DRIMANE SYNTHESIS AND A SHORT TOTAL SYNTHESIS OF SICCANIN (1996) (31)
- A selectivity control element for palladium-catalyzed trimethylenemethane cycloaddition (1991) (31)
- Molecular orbital study of substituted trimethylenemethane-bis(phosphine)palladium complexes (1981) (31)
- An unusual selectivity in Pd catalyzed cross-coupling of terminal alkynes with “Unactivated” alkynes (1997) (31)
- Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Trimethylenemethane and Fluorinated Ketones. (2018) (31)
- Total Synthesis of (-)-Lasonolide A. (2016) (31)
- A Total Synthesis of ( + )‐2′S, 3′R‐Zoapatanol (1994) (31)
- Synthetic Strategies Employed for the Construction of Fostriecin and Related Natural Products. (2016) (31)
- A two catalyst system for cycloadditlon of a trimethylenemethane fragment to aldehydes (1986) (30)
- A synthesis of the spiroketal subunit of (−)-calyculin A (1994) (30)
- An unusual ruthenium-catalyzed dimerization of propargyl alcohols. (2001) (30)
- Catalytic palladium-oxyallyl cycloaddition (2018) (30)
- Asymmetric catalytic synthesis of the proposed structure of trocheliophorolide B. (2012) (30)
- An Enantioselective Synthesis of cis‐4‐tert‐Butoxycarbamoyl‐1‐methoxycarbonyl‐2‐cyclopentene—A Useful, General Building Block (1995) (30)
- New synthetic reactions. Oxidative decarboxylation (1975) (30)
- Palladium-Catalyzed Ring Opening of Isoprene Monoxide with Nitrogen Nucleophiles - Asymmetric Synthesis of Branched Amino Sugars (2005) (30)
- Pd-catalyzed carbonylative lactamization: a novel synthetic approach to FR900482. (2004) (30)
- Rotational selectivity in cyclobutene ring openings. Model studies directed toward a synthesis of verrucarin A (1984) (30)
- A convenient synthesis of .gamma.-hydroxy .alpha.,.beta.-unsaturated sulfones (1991) (30)
- Molybdenum Catalyzed Reactions Selectivity in Oxidations with Hydrogen Peroxide and Ammonium Molybdate (1984) (30)
- The effect of tether substituents on the selectivity of Pd catalyzed enyne cyclizations. A total synthesis of chokol C (1993) (30)
- New synthetic reactions. Stereoreversed cyclobutanone formation utilizing selenoxide as a leaving group (1977) (29)
- A three-component coupling approach to cyclopentanoids. (2001) (29)
- A catalytic asymmetric total synthesis of (–)-perophoramidine (2014) (29)
- Regiochemistry of cycloaddition of (trimethylenemethane)palladium intermediates to muconic esters (1982) (29)
- A FACILE CYCLOISOMERIZATION FOR THE FORMATION OF MEDIUM AND LARGE RINGS VIA ALLENES (1997) (29)
- Ruthenium- and palladium-catalyzed enyne cycloisomerizations: differentially stereoselective syntheses of bicyclic structures. (2008) (29)
- New synthetic methods. A stereocontrolled approach to cyclopentane annelation (1976) (29)
- New Synthetic reactions. Alkylative elimination (1974) (29)
- An intramolecular carbocyclic [3 + 2] cycloaddition via organopalladium intermediates (1982) (29)
- An enantio- and diastereo-controlled synthesis of (−) neplanocin A and its 2,3-di-epi isomer (1997) (29)
- A chemoselective desulfurization method via homogeneous nickel catalysis (1982) (29)
- Asymmetrische Liganden für übergangsmetall‐katalysierte Reaktionen: 2‐Diphenylphosphino‐benzoylderivate C2‐symmetrischer Diole und Diamine (1992) (29)
- Sulfur activation of azides toward addition of organometallics. Amination of aliphatic carbanions (1983) (29)
- Branched aldehydes as linchpins for the enantioselective and stereodivergent synthesis of 1,3-aminoalcohols featuring a quaternary stereocentre (2018) (29)
- A Ru-Catalyzed Three-Component Addition To Form 1,5-Diketones (1997) (29)
- Nature of a trimethylenemethane-palladium complex (1980) (28)
- A Ruthenium-Catalyzed Three-Component Coupling to Form E-Vinyl Chlorides (1999) (28)
- Asymmetric cis - Hydroxylation via Epoxidation-Carboxylation: A Formal Synthesis of (+)-Citreoviral (1987) (28)
- Total syntheses of bryostatins: synthesis of two ring-expanded bryostatin analogues and the development of a new-generation strategy to access the C7-C27 fragment. (2011) (28)
- The Palladium-Catalyzed Enyne Cycloisomerization Reaction in a General Approach to the Asymmetric Syntheses of the Picrotoxane Sesquiterpenes. Part I. First-Generation Total Synthesis of Corianin and Formal Syntheses of Picrotoxinin and Picrotin (1999) (28)
- Vanadium-Catalyzed Synthesis of Geometrically Defined Acyclic Tri- and Tetrasubstituted Olefins from Propargyl Alcohols (2019) (28)
- A Synthesis of β-necrodol via a palladium catalyzed reductive enyne cyclization (1988) (28)
- Diastereoselectivity control elements. Acyclic diastereocontrol in formation and reactions of .gamma.-hydroxy sulfones (1988) (28)
- Thermal and photochemical decomposition of 7,8-diazatetracyclo[3.3.0.02,4.03.6]oct-7-ene. 1,2-Diazacycloocta-2,4,5,8-tetraene (1971) (27)
- Applications of sulfenylations of ester enolates. Synthesis of pheromones of the honey bee. (1975) (27)
- Cyclocontraction - spiroannulation: a stereoselective approach to spirocycles (1983) (27)
- Cyclization terminators. Vinylcyclopropanol as a composite functional group (1988) (27)
- Preparation of Dienylstannanes Via Pd Catalyzed Regio- and Stereocontrolled Addition Reactions (1994) (27)
- An example of axial selectivity in nucleophilic additions to cyclohexanones and cyclohexenones (1987) (27)
- Zum Mechanismus der TCPCHFB‐katalysierten Metathese von 1,6‐Eninen ‐ Nachweis von Alkylidenpalladium‐Zwischenstufen (1993) (27)
- Development of Non-C2-symmetric ProPhenol Ligands. The Asymmetric Vinylation of N-Boc Imines. (2015) (27)
- Juvenile hormone of Hyalophora cecropia (1970) (27)
- Asymmetric induction in a [2,3] sigmatropic rearrangement. Biogenetic model (1973) (27)
- Intramolecular palladium-catalyzed allylic alkylation: enantio- and diastereoselective synthesis of [2.2.2] bicycles. (2002) (27)
- Chirality transfer in acyclic systems via organocopper chemistry (1980) (27)
- Criteria for concertedness in cycloadditions (1988) (27)
- Synthesis of 7-Epi +-FR900482: an epimer of comparable anti-cancer activity. (2008) (26)
- Coordinative cocatalysis via indium(3+). A chemoselectivity switch for palladium-catalyzed cycloadditions (1992) (26)
- Total synthesis of laulimalide: assembly of the fragments and completion of the synthesis of the natural product and a potent analogue. (2012) (26)
- Synthesis of (±)‐Phyllanthocin via a Metal‐Catalyzed Cycloreduction (1990) (26)
- Chiral Recognition for Control of Alkene Geometry in a Transition Metal Catalyzed Allylic Alkylation (1999) (26)
- Synthesis of Allosamidin (1992) (26)
- A RUTHENIUM-CATALYZED TWO-COMPONENT ADDITION TO FORM 1,3-DIENES (1999) (26)
- Chirale Sulfoxidliganden für die asymmetrische Katalyse (2015) (26)
- Synthesis of 4-(dimethylphenylsilyl)buta-2,3-dien-1-ol and its use in alkylation (1989) (26)
- Struktur und Reaktivität später Übergangsmetall‐ η3‐Benzylkomplexe (2014) (26)
- Methyl 2-pyridinesulfinate. A convenient reagent for sulfinylation-dehydrosulfinylation (1993) (26)
- cis‐5‐Amino‐6‐hydroxycyclohexadiene as a Chiral Building Block: An Asymmetric Synthesis of (−)‐Swainsonine (1999) (26)
- 2-Alkoxybenzo-1,3-dithiole 1,1,3,3-tetraoxide, a carbonyl 1,1-dipole synthon (1984) (26)
- Synthesis of trichonine via double elimination reaction and its structural reinvestigation (1986) (26)
- Use of α-trifluoromethyl carbanions for palladium-catalysed asymmetric cycloadditions (2020) (25)
- Tuning the Reactivity of Ketones through Unsaturation: Construction of Cyclic and Acyclic Quaternary Stereocenters via Zn-ProPhenol Catalyzed Mannich Reactions (2019) (25)
- A Highly Convergent Total Synthesis of Leustroducsin B (2015) (25)
- AN ASYMMETRIC SYNTHESIS OF (+)-PHYLLANTHOCIN (1991) (25)
- THEORETICAL AND EXPERIMENTAL STUDIES OF THE DIELS-ALDER DIMERIZATIONS OF SUBSTITUTED CYCLOPENTADIENES (1995) (25)
- A synthesis of trisubstituted alkenes by a Ru-catalyzed addition. (2002) (25)
- Asymmetric Carbon–Carbon Bond‐Forming Reactions: Asymmetric Allylic Alkylation Reactions (2005) (25)
- Palladium‐Catalyzed Additions of Alkenyl Epoxides to Pronucleophiles: A Synthesis of the Macrolactam Aglycone of Fluviricin B1 (1997) (25)
- Ruthenium-catalyzed diyne hydrative cyclization: synthesis of substituted 1,3-diene synthons. (2005) (25)
- Intramolecular palladium-catalyzed cycloadditions with a cleavable tether (1991) (25)
- On the nucleophilic nature of a TMM-PdL2 intermediate: a direct palladium catalyzed addition of trimethylenemethane to heteroatom unsaturation (1985) (25)
- Synthesis of 4-methylene-1-cyclopentenes (1986) (25)
- Oxasecoalkylation via cyclobutanone intermediates (1978) (24)
- Umpolung of .pi.-allylpalladium intermediates. A chemoselective reductive elimination of diols (1988) (24)
- New synthetic methods. VIII. Spiropentanes (1973) (24)
- Enantioselective Divergent Synthesis of C19-Oxo Eburnane Alkaloids via Palladium-Catalyzed Asymmetric Allylic Alkylation of an N-Alkyl-α,β-unsaturated Lactam. (2019) (24)
- Total synthesis of aeruginosin 98B. (2012) (24)
- Cycloisomerization approach to tetrahydrofurans (1989) (24)
- Triphenylsilanol as a water surrogate for regioselective Pd catalyzed allylations (1993) (24)
- Transition-Metal-Catalyzed Cycloaddition Reactions to Access Seven-Membered Rings. (2020) (24)
- Dibenzopentalenyl dianion. A perturbed [12] annulene dianion (1970) (24)
- An unusual regioselectivity in the Pd-catalyzed cross coupling of alkynes. A correction (2001) (24)
- Reactions of .pi.-sulfuranes (ylides) with aromatic carbonium ions (1973) (24)
- An asymmetric synthesis of vigabatrin (1996) (24)
- Intermolecular 1,3-dipolar cycloadditions of muchnones with acetylenic dipolarophiles: Sorting out the regioselectivity (1994) (24)
- An Asymmetric Synthesis of the Vitamin E Core by Pd Catalyzed Discrimination of Enantiotopic Alkene Faces (1999) (24)
- On the synthesis of Z-gamma-amino-alpha,beta-unsaturated esters via Ru-catalyzed coupling. (1999) (23)
- A Ru-Catalyzed Four-Component Coupling (2000) (23)
- An asymmetric approach to 2-deoxynucleosides via organosulfur building blocks as chemical chameleons. (1990) (23)
- A regioselective Ru-catalyzed alkene-alkyne coupling to form (Z,Z)-1,3-dienes. (2009) (23)
- Polymer-supported C2-symmetric ligands for palladium-catalyzed asymmetric allylic alkylation reactions. (2002) (23)
- On the mechanism of allylic alkylations catalyzed by palladium (1981) (23)
- A three carbon intercalation of an enediol silyl ether; a short entry to the bicyclo[5.3.1]undecyl system of taxanes (1984) (22)
- Stereocontrolled approach to 1,4-disubstituted 1,3-dienes (1978) (22)
- A tandem cycloaddition-ene strategy for the synthesis of (.+-.)-verrucarol and (.+-.)-4,11-diepi-12,13-deoxyverrucarol (1984) (22)
- An atom-economical access to β-heteroarylated ketones from propargylic alcohols via tandem ruthenium/indium catalysis. (2011) (22)
- A palladium mediated reductive cyclization (1985) (22)
- Selectivity in the design of the total synthesis of natural products (1979) (22)
- Ruthenium-catalyzed alkylative lactonization and carbocyclization. (2006) (22)
- Katalytische asymmetrische Alkylierung von Nucleophilen - asymmetrische Synthese α-alkylierter Aminosäuren† (1997) (22)
- Vinylcyclobutanols: A Composite Functional Group? (1996) (22)
- Diastereoselective formation of tetrahydrofurans via Pd-catalyzed asymmetric allylic alkylation: synthesis of the C13-C29 subunit of amphidinolide N. (2012) (22)
- Atom-economic and stereoselective syntheses of the ring a and B subunits of the bryostatins. (2011) (22)
- Intermolekulare Additionen und Cycloisomerisierungen durch eine Pd‐katalysierte Sequenz aus intramolekularer Redoxreaktion und Addition (1992) (22)
- New synthetic reactions. Geminal alkylation (1973) (21)
- A concise enantioselective synthesis of (-)-ranirestat. (2010) (21)
- A new strategy for cyclopentenone synthesis. (2000) (21)
- Synthesis and reactivity of unique heterocyclic structures en route to substituted diamines. (2011) (21)
- BROMOMALONATES AS SYNTHETIC REAGENTS. TRANSFER ALKYLATIONS (1976) (21)
- Exploring the unique reactivity of diazoesters: an efficient approach to chiral β-amino acids. (2013) (21)
- New synthetic reactions. New approach to geminal alkylation (1973) (21)
- New synthetic reactions. Chemospecificity of allylic alkylation (1974) (21)
- A general synthesis of π-allyl palladium chloride dimers from cycloalkenes and alkylidenecycloalkanes (1974) (21)
- Chemoselectivity in the Pd‐Catalyzed Cyclization of 1,6‐Enynes and Proof of the Relative Configuration of the New Stereogenic Centers (2001) (21)
- Propene as an Atom-Economical Linchpin for Concise Total Synthesis of Polyenes: Piericidin A. (2018) (21)
- Acetoxy Meldrum's acid: a versatile acyl anion equivalent in the Pd-catalyzed asymmetric allylic alkylation. (2011) (21)
- Total synthesis of bryostatin 3 (2020) (21)
- A synthesis of the naphthalene core of streptovaricin D via A synthon of NH2 (1983) (21)
- A carbonyl 1,1-zwitterion synthon for ester and macrolide synthesis (1991) (21)
- Palladium-catalyzed C-H activation of N-allyl imines: regioselective allylic alkylations to deliver substituted aza-1,3-dienes. (2015) (21)
- New synthetic reactions. 12. Dimethylsulfonium 2-oxotetrahydrofuryl-3-ylide as an annelating reagent (1973) (21)
- New synthetic methods. Allylic alkylation of enol thioethers (1979) (21)
- 1,2-Diaza-2,4,6,8-cyclooctatetraene (1979) (20)
- An atom-economical three-carbon chain extension of alkynes to form E-enol silanes. (2001) (20)
- Palladium-Catalyzed Asymmetric Allylic Fluoroalkylation/Trifluoromethylation. (2019) (20)
- Synthetic strategy toward verrucarins. An approach toward verrucarol (1978) (20)
- Useful approach for determination of the structure of organosulfur compounds: sulfur-33 high-resolution FT-NMR (1985) (20)
- On palladium catalyzed cyclizations to medium sized carbocycles (1992) (20)
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- A Convenient Chemoselective Semihydrogenation of Acetylenes Using Homogeneous Catalysis. (1990) (0)
- A Novel‐Ru‐Catalyzed Tandem Cyclization‐Reconstitutive Addition of Propargyl Alcohols with Allyl Alcohols. (2010) (0)
- Synthesis of Trichonine via Double Elimination Reaction and Its Structural Reinvestigation. (1987) (0)
- Palladium‐Catalyzed Alkylative Cyclization of 1,6‐ and 1,7‐Enynes. (1992) (0)
- Synthesis of (+)-Spirolaxine Methyl Ether (2008) (0)
- Development of Diamidophosphite Ligands and Their Application to the Palladium‐Catalyzed Vinyl‐Substituted Trimethylenemethane Asymmetric [3 + 2] Cycloaddition. (2013) (0)
- Ru-Catalyzed Selective Redox Isomerization of PropargylicAlcohols (2008) (0)
- Zinc-Catalyzed Direct Asymmetric Vinylogous Michael Addition (2009) (0)
- A Heterodinuclear Asymmetric Catalyst for Conjugate Additions of α-Hydroxyketones to β-Substituted Nitroalkenes. (2007) (0)
- Stereochemical Control in Palladium Templated Reactions (1987) (0)
- Ring Expansion of Alkynylcyclopropanols Catalyzed by Ruthenium (2009) (0)
- A Facile Cycloisomerization for the Formation of Medium and Large Rings via Allenes. (1997) (0)
- Constructing Tricyclic Compounds Containing a Seven-Membered Ring by Ruthenium-Catalyzed Intramolecular (2001) (0)
- Palladium-Catalyzed Trimethylenemethane Reaction to Form Methylenetetrahydrofurans. Aldehyde and Ketone Substrates and the Tin Effect. (1989) (0)
- Pd-Catalyzed Chemoselective Cyclization to Cyclic Ethers. (1988) (0)
- A Palladium Mediated Reductive Cyclization. (1986) (0)
- Asymmetric Synthesis of N- and O-Heterocycles Using Sequential Ru-Pd Catalysis (2006) (0)
- Catalytic Asymmetric Allylic Alkylation Employing Heteroatom Nucleophiles: A Powerful Method for C—X Bond Formation (2011) (0)
- Enhancing the Efficiency of a Synthetic Reaction: Palladium-Catalyzed Allylic Alkylation (1999) (0)
- BIFUNCTIONAL CYCLOPROPYL REAGENTS: A TOTAL SYNTHESIS OF 7-E,9-Z METHYL TRISPORATE B (1983) (0)
- Zinc-Catalyzed Asymmetric Friedel-Crafts Alkylation of Pyrroles (2008) (0)
- Novel Silicon-Directed Alkylative Cyclization. (1990) (0)
- Readily Accessible Chiral Diene Ligands for Rh‐Catalyzed Enantioselective Conjugate Additions of Boronic Acids. (2012) (0)
- Alkene—Alkyne Coupling as a Linchpin: An Efficient and Convergent Synthesis of Amphidinolide P (IV). (2005) (0)
- A Two‐Component Catalyst System for Asymmetric Allylic Alkylations with Alcohol Pronucleophiles. (1999) (0)
- 2-METHYLTHIOACETIC ACID AND DIETHYL MALONATE AS ACYL ANION EQUIVALENTS SYNTHESIS OF JUVABIONE (1976) (0)
- Enhanced Synthetic Efficiency Towards Natural Products via Transition Metal Catalyzed Reactions. (1995) (0)
- Transition metal templates cy cl oadd i t i o ns as guides for (1988) (0)
- A Synthesis of β-Necrodol via a Palladium Catalyzed Reductive Enyne Cyclization. (1988) (0)
- A THREE CARBON INTERCALATION OF AN ENEDIOL SILYL ETHER; A SHORT ENTRY TO THE BICYCLO(5.3.1)UNDECYL SYSTEM OF TAXANES (1985) (0)
- A Pd‐Catalyzed Zipper Reaction. (1991) (0)
- An Efficient One‐Pot Enantio‐ and Diastereoselective Synthesis of Heterocycles. (2003) (0)
- ALLYL STANNANES AS ELECTROFUGAL PARTNERS IN ALLYLIC ALKYLATION (1980) (0)
- A Biomimetic Synthesis of (.+-.)-Petiodial. A Novel Palladium-Catalyzed Enallene Cyclization. (1988) (0)
- ON THE REGIO- AND STEREOSELECTIVITY OF ALLYLIC ALKYLATION (1975) (0)
- STEREOCONTROLLED SYNTHESIS OF THE ECDYSONE SIDE CHAIN VIA ORGANOPALLADIUM CHEMISTRY (1977) (0)
- Synthesis of Chiral Cyclopentanones via Asymmetric Ring Expansion (2006) (0)
- Total Synthesis of (+)-(2′S,3′R)-Zoapatanol. (1995) (0)
- 2-((Trimethylsilyl)methyl)-1-(trimethylsilyl)propen-3-yl Carboxylates in Cycloaddition. A Novel Approach for Substitutive Cyclopentannulation. (1988) (0)
- NEW SYNTHETIC REACTIONS, ON THE REGIOSELECTIVITY AND CHEMOSPECIFICITY OF THE CYCLOPENTANE ANNELATION-CYCLOPENTENONE ANNELATION (1974) (0)
- The Acyl Effect on Intramolecular Palladium‐Catalyzed Trimethylenemethane Cycloadditions. (1992) (0)
- MOLYBDENUM CATALYZED REACTIONS. SELECTIVITY IN OXIDATIONS WITH HYDROGEN PEROXIDE AND AMMONIUM MOLYBDATE (1984) (0)
- Chiral Recognition for Control of Alkene Geometry in a Transition Metal Catalyzed Allylic Alkylation. (2000) (0)
- PREPARATION OF CYCLOPROPYLDIPHENYLSULFONIUM AND 2-METHYLCYCLOPROPYLDIPHENYLSULFONIUM FLUOROBORATE AND THEIR YLIDES, STEREOCHEMISTRY OF SULFUR YLIDES (1973) (0)
- NEW SYNTHETIC REACTIONS, FACILE SYNTHESIS OF OXASPIROPENTANES, VERSATILE SYNTHETIC INTERMEDIATES (2002) (0)
- Asymmetric Induction in Allylic Alkylations of 3-(Acyloxy)cycloalkenes. (1994) (0)
- Counterion Can Reverse Enantioselection of Pd-AAA (2011) (0)
- Stereoelectronic Requirements of a Pd(0)-Catalyzed Cyclization. A Synthesis of allo-Pumiliotoxin 339B. (1989) (0)
- Ruthenium‐Catalyzed Diyne Hydrative Cyclization: Synthesis of Substituted 1,3‐Diene Synthons. (2005) (0)
- Vicinal Alkynylation-Alkylation via a Tandem Michael Addition. Transition Metal Catalyzed Alkylation Reaction. (2010) (0)
- ON THE CHEMISTRY OF ALPHA,ALPHA′-BIS(DIAZO) KETONES (1975) (0)
- A direct catalytic asymmetric Mannich-type reaction via a dinuclear zinc catalyst: synthesis of either anti- or syn-alpha-hydroxy-beta-amino ketones. (2006) (0)
- Pyrones as Substrates for Palladium-Catalyzed (4 + 3) Cycloadditions. (1989) (0)
- Atom Economical Syntheses of Oxygen Heterocycles via Tandem Palladium-Catalyzed Reactions. (2001) (0)
- Enantioselective Synthesis of Cyanohydrins by a Novel Aluminum Catalyst. (2005) (0)
- The structure and reactivity of enolate anions. (1965) (0)
- Pd-Catalyzed Cycloaddition of Vinylcyclopentenes with Trimethylenemethane. Substituent Effect on (4 + 3) vs (3 + 2) Selectivity. (2010) (0)
- Hydroxy Group as a Regio- and Stereochemical Control Element for Sequential Metal-Catalyzed and Thermal Cyclizations. (1989) (0)
- TANDEM ANNULATIONS. 2-BROMOMETHYL-3-(TRIMETHYLSILYLMETHYL)BUTA-1,3-DIENE AS A SYNTHON FOR A ZWITTERION OF 2,2′-BIALLYL (1983) (0)
- Inventing Reactions for Atom Economy (2002) (0)
- Synthesis of Chiral Tetrahydrofurans by a Palladium-CatalyzedCycloaddition (2011) (0)
- Convergent Asymmetric Alkylation from meso and dl Carbonates (2006) (0)
- ISOMERIZATION OF ALLYLIC ACETATES CATALYZED BY PALLADIUM. NEW METHOD FOR STEREOCONTROL (1979) (0)
- Tris(triphenylsiloxy)vanadium Oxide (2009) (0)
- Internal Redox Catalyzed by Triphenylphosphine. (1993) (0)
- A Practical Asymmetric Synthesis of a 1,7-Enyne A-Ring Synthon en route Toward the Total Synthesis of Vitamin D3 Analogues. (1995) (0)
- Total Syntheses of Bryostatins: Synthesis of Two Ring-Expanded Bryostatin Analogues and the Development of a New-Generation Strategy to Access the C7—C27 Fragment. (2012) (0)
- Metal-Catalyzed Syntheses of cis-or trans-Fused Bicyclic Compounds (2009) (0)
- Readily Accessible Diene Ligands for Enantioselective ConjugateAdditions (2011) (0)
- Highly Substituted Enantioenriched Cyclopentane Derivatives by Palladium‐Catalyzed [3 + 2] Trimethylenemethane Cycloadditions with Disubstituted Nitroalkenes. (2014) (0)
- A Carbonyl 1,1-Zwitterion Synthon for Ester and Macrolide Synthesis. (1991) (0)
- Opinions on review system [4] (1976) (0)
- A Two Catalyst System for Cycloaddition of a Trimethylenemethane Fragment to Aldehydes. (1987) (0)
- Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters (2006) (0)
- NEUE SYNTH.-RK., TRANSFER-ALKYLIERUNGEN (1972) (0)
- Synthesis of Communiol A (2007) (0)
- Synthesis and Palladium‐Catalyzed Cycloaddition of the Bifunctional Conjunctive Reagent Methyl Z‐1‐Methyl‐2‐trimethylsilylmethyl‐2‐butenyl Carbonate. (1992) (0)
- Coupling of Alkenes and Alkynes: Synthesis of the C1—C11 (IVb) and C18—C28 (XV) Fragments of Miyakolide. (2008) (0)
- THE DEVELOPMENT OF NEW SYNTHETIC METHODS AS APPLIED TO THE SYNTHESIS OF NATURAL PRODUCTS (1978) (0)
- Additions and Corrections - On the Regioselectivity of the Catalyzed and Uncatalyzed Diels-Alder Reaction (1978) (0)
- Asymmetric Synthesis of Oxygen Heterocycles via Pd‐Catalyzed Dynamic Kinetic Asymmetric Transformations: Application to Nucleosides. (2004) (0)
- Geminal Alkylation: Substitutions of Allyl Sulfones. Regiocontrol via Molybdenum Catalysis. (1990) (0)
- A Reactivity Control Substituent in the Pd‐Catalyzed Cycloisomerization of 1,7‐Enynes. (1994) (0)
- Criteria for Concertedness in Cycloadditions. (1988) (0)
- Synthesis and Alkylation of Cyclopentane β‐Ketoxime Sulfones. . alpha.,α‐Methylation‐Alkynylation of Cyclopentanone. (2010) (0)
- Heterocyclic Acceptors in Diastereoselective Palladium Mediated (3 + 2) Cycloadditions. (1987) (0)
- ALLYLIC ALKYLATION- PREPARATION OF Π-ALLYLPALLADIUM COMPLEXES FROM OLEFINS (1978) (0)
- A Novel Nickel-Chromium Catalyst System for Cyclization via Intramolecular Carbametalation. (1987) (0)
- Atom‐Economical Synthesis of Functionalized Cycloalkanes via Catalytic Redox Cycloisomerization of Propargyl Alcohols. (2012) (0)
- Formation of Vinyl Halides via a Ruthenium‐Catalyzed Three‐Component Coupling. (2002) (0)
- Some Synthetic Implications of the Concept of Cyclopropyl Units as Pseudo-Functional Groups (1989) (0)
- Transition Metal Catalyzed Cycloisomerizations of Enynes (1991) (0)
- Asymmetric catalytic alkynylation of acetaldehyde and its application to the synthesis of (+)-tetrahydropyrenophorol (2012) (0)
- Intermolecular Additions and Cycloisomerizations by a Pd-Catalyzed Sequence of an Intramolecular Redox Reaction and an Addition. (1993) (0)
- Oral History Interview: Barry Trost (0319) (1986) (0)
- Synthetic Dehydrogenation of Carbonyl and Related Compounds (2001) (0)
- Convenient Alternative Approach to 2-(Acetoxymethyl)-3-(trimethylsilyl)propene. (1989) (0)
- Regiochemical control elements (1981) (0)
- THE DI-TERT-BUTYLSILYLENE PROTECTING GROUP FOR DIOLS (1982) (0)
- Palladium-Catalyzed Enyne Cycloisomerization Reaction in an Asymmetric Approach to the Picrotoxane Sesquiterpenes. Part 2. Second-Generation Total Syntheses of Corianin, Picrotoxinin, Picrotin, and Methyl Picrotoxate. (1999) (0)
- A Chemoselective Internal Redox of Allyl Alcohols to Saturated Aldehydes or Ketones. (1992) (0)
- Cyclic 1,2‐Diketones as Core Building Blocks: A Strategy for the Total Synthesis of (‐)‐Terpestacin. (2010) (0)
- Palladium‐Catalyzed Asymmetric Benzylation of Azlactones. (2014) (0)
- On 1,4-Diastereoselectivity in the Aldol Condensation of Methyl Ketones. (1990) (0)
- A (3 + 2)Cycloaddition Strategy to the Phyllanthocin Ring System. (1989) (0)
- AN APPROACH TO THE PHENANTHRENE NUCLEUS VIA THIONIUM IONS AND EPOXY KETONE CYCLIZATIONS (1982) (0)
- Vinylidenecyclopentane Synthesis by Palladium-Catalyzed [3+2] Cycloaddition (2013) (0)
- Activation in Transition‐Metal Catalysis by Catalyst Relay. A Synthetic Approach to (‐)‐Dendrobine. (1991) (0)
- An Unusual Regioselectivity in the Pd‐Catalyzed Cross Coupling of Alkynes. A Correction. (2001) (0)
- Palladium‐Catalyzed Regio‐ and Enantioselective Allylic Alkylation of Bis Allylic Carbonates Derived from Morita—Baylis—Hillman Adducts. (2008) (0)
- MOLYBDENUM-CATALYZED ELIMINATIONS OF ALLYLIC ACETATES. NEW DIENE SYNTHESIS (1984) (0)
- Unusual Chemoselectivity Using Difunctional Allylic Alkylating Agents. (1987) (0)
- ORGANOPALLADIUM AND -MOLYBDENUM INTERMEDIATES: CHEMICAL CHAMELEONS (1984) (0)
- From the Blogosphere (2008) (0)
- Tandem Pd-Catalyzed Elimination-Cyclization. (1987) (0)
- ProPhenol‐Catalyzed Asymmetric Additions by Spontaneously Assembled Dinuclear Main Group Metal Complexes (2015) (0)
- An Unusual Stereochemical Directing Effect of Propargylic Oxygen Substituents on an Intramolecular Diels-Alder Reaction. (1990) (0)
- Enantioselective Allylations of Azlactones with Unsymmetrical Acyclic Allyl Esters. (2010) (0)
- NEUE SYNTH., DIE ANNELLIERUNG VON LACTONEN (1973) (0)
- PRAEPARATIV INTERESSANTE SCHWEFEL‐YLID‐RK. (1970) (0)
- EIN SCHWEFEL-YLID, THETIN-ANIONEN (1970) (0)
- ORGANOKUPFER-CHEMIE, DIE DECARBOXYLIERUNG EINER BENZHYDRYLCARBONSAEURE (1972) (0)
- ELIMINIERUNGSRK. AN ANHYDRIDEN UND THIOANHYDRIDEN DURCH UEBERGANGSMETALLE (1971) (0)
- STEREOCHEMIE DER DESULFURIERUNG VON THIETAN-DERIVATEN (1971) (0)
- DESULFURIERUNG VON EPISULFIDEN, EINE SULFURAN-RK. (1973) (0)
- EIN UNGEWOEHNLICHER STEREOELEKTRONISCHER EFFEKT BEI DER UMLAGERUNG DES DIELS‐ALDER‐ADDUKTS VON CYCLOPROPEN UND FURAN (1971) (0)
- PHOTOLYTISCHE UND KATALYTISCHE ZERS. EINES ALPHA,ALPHA′-BIS-DIAZO-KETONS UEBER CYCLOPROPENON (1970) (0)
- 1-LITHIOCYCLOPROPYL-PHENYLSULFID, EIN NEUES SPIROANELLIERENDES REAGENZ (1973) (0)
- NEUE SYNTH.-RK., CYCLOPENTANANELLIERUNG (1973) (0)
- GESTOERTE (12)ANNULENE, SYNTH. VON PYRACYLENEN (1971) (0)
- NEUER ELEKTROCYCLISCHER PROZESS, EINFACHE BLDG. EINES DIAZACYCLOPENTADIENONS (1973) (0)
- THERMISCHE UND PHOTOCHEMISCHE ZERS. VON 7,8-DIAZATETRACYCLO(3,3,0,0(2,4),0(3,6))OCTEN-(7), 1,2-DIAZACYCLOOCTATETRAEN-(2,4,6,8) (1971) (0)
- STEREOCHEMIE DER DURCH N-BUTYLLITHIUM INDUZIERTEN FRAGMENTIERUNG VON DIHYDROTHIOPHENIUM HEXAFLUOROPHOSPHATEN, NEUE SULFURANREAKTION (1971) (0)
- NEUE SYNTH.-METHODEN, UEBERTRAGUNG VON CHIRALITAET VOM SCHWEFEL AUF DEN KOHLENSTOFF (1973) (0)
- PHOTOLYSE VON SCHWEFELYLIDEN, DIPHENYLSULFONIUMALLYLID (1970) (0)
- RK. VON PI-SULFURANEN (YLIDEN) MIT AROMATISCHEN CARBONIUMIONEN (1973) (0)
- DIE RK. VON DICHLORCARBEN MIT TRIMETHYLCYCLOPROPEN (1972) (0)
- KATALYTISCHE UND PHOTOLYTISCHE ZERS. VON 1-CHLOR-4-DIAZOALKENEN (1973) (0)
- HERSTELLUNG UND PHOTOLYSE VON SPIRO(2,3-BENZONORBORNADIEN-7,1′-CYCLOPROPAN) (1970) (0)
- ADDUKTE VON FULVEN UND 6-ACETOXY-FULVEN MIT AZODICARBONSAEUREESTER (1972) (0)
- HERST. UND CHEMIE VON VINYLSULFONIUM-YLIDEN, NEUE SYNTH.-ZWISCHENSTUFEN (1971) (0)
- DIBENZO(CD,GH)PENTALENOCHINON‐(4,8) UND SEIN SEMICHINONRADIKALANION, MODELL FUER PLANARE (12)ANNULENE (1971) (0)
- NEUE SYNTH.‐RK., GEMINALE ALKYLIERUNG (1973) (0)
- DIBENZOPENTALEN‐DIANION, EIN GESTOERTES (12)ANNULEN‐DIANION (1970) (0)
- STRUKTUR VON 4,8‐DIHYDRO‐DIBENZO(CD,GH)PENTALEN (1972) (0)
- NEUE SYNTH.-RK., ALLYLALKYLIERUNG (1973) (0)
- DIPHENYLSULFONIUMCYCLOPROPYLID, EIN BRAUCHBARES SPIROALKYLIERUNGS-REAGENZ (1971) (0)
- NEUE SYNTHETISCHE RK., SECOALKYLIERUNG (1972) (0)
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