Bernhard Breit

Bernhard Breit's AcademicInfluence.com Rankings

Bernhard Breit

Chemistry

#3440

World Rank

#4458

Historical Rank

Organic Chemistry

#544

World Rank

#628

Historical Rank

chemistry Degrees

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Chemistry

Bernhard Breit's Degrees

PhD Chemistry University of Bonn
Masters Chemistry University of Bonn
Bachelors Chemistry University of Bonn

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Bernhard Breit's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Removable directing groups in organic synthesis and catalysis. (2011) (407)
Recent Advances on Chemo-, Regio- and Stereoselective Hydroformylation (2001) (231)
Hydrogen bonding as a construction element for bidentate donor ligands in homogeneous catalysis: regioselective hydroformylation of terminal alkenes. (2003) (225)
Supramolecular approaches to generate libraries of chelating bidentate ligands for homogeneous catalysis. (2005) (220)
Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis. (2013) (210)
Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes. (2016) (202)
Synthetic aspects of stereoselective hydroformylation. (2003) (174)
A supramolecular catalyst for regioselective hydroformylation of unsaturated carboxylic acids. (2008) (160)
Self-assembled bidentate ligands for Ru-catalyzed anti-Markovnikov hydration of terminal alkynes. (2006) (139)
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenation. (2006) (137)
Allylation of N-heterocycles with allylic alcohols employing self-assembling palladium phosphane catalysts. (2008) (129)
Phosphabenzenes as monodentate pi-acceptor ligands for rhodium-catalyzed hydroformylation. (2001) (127)
Redox-neutral atom-economic rhodium-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters. (2011) (120)
Phosphorylation of Tip60 by GSK-3 determines the induction of PUMA and apoptosis by p53. (2011) (113)
Asymmetric rhodium-catalyzed addition of thiols to allenes: synthesis of branched allylic thioethers and sulfones. (2015) (112)
Cuticular Hydrocarbon Pheromones for Social Behavior and Their Coding in the Ant Antenna. (2015) (108)
Iron Nanoparticles Supported on Chemically‐Derived Graphene: Catalytic Hydrogenation with Magnetic Catalyst Separation (2011) (105)
Catalytic hydrogenation of amides to amines under mild conditions. (2013) (104)
A combinatorial approach to the identification of self-assembled ligands for rhodium-catalysed asymmetric hydrogenation. (2010) (103)
Direct transformation of terminal alkynes to branched allylic sulfones. (2014) (102)
Rhodium-catalyzed chemo- and regioselective decarboxylative addition of β-ketoacids to allenes: efficient construction of tertiary and quaternary carbon centers. (2014) (100)
Paraformaldehyde and methanol as C1 feedstocks in metal-catalyzed C-C couplings of π-unsaturated reactants: beyond hydroformylation. (2015) (100)
Supramolecular catalyst for aldehyde hydrogenation and tandem hydroformylation-hydrogenation. (2009) (100)
Enantioselective rhodium-catalyzed synthesis of branched allylic amines by intermolecular hydroamination of terminal allenes. (2012) (97)
Dual palladium- and proline-catalyzed allylic alkylation of enolizable ketones and aldehydes with allylic alcohols. (2009) (94)
Alkynes as Electrophilic or Nucleophilic Allylmetal Precursors in Transition-Metal Catalysis. (2017) (94)
Tandem rhodium-catalyzed hydroformylation-hydrogenation of alkenes by employing a cooperative ligand system. (2012) (94)
Branched-regioselective hydroformylation with catalytic amounts of a reversibly bound directing group. (2008) (94)
Mechanistic investigations of the rhodium catalyzed propargylic CH activation. (2014) (91)
Bidentate Ligands by Self‐Assembly through Hydrogen Bonding: A General Room Temperature/Ambient Pressure Regioselective Hydroformylation of Terminal Alkenes (2005) (89)
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base-pair model. (2005) (89)
Directed reactions of organocopper reagents. (2008) (84)
A supramolecular catalyst for the decarboxylative hydroformylation of alpha,beta-unsaturated carboxylic acids. (2008) (82)
Unlocking the N(2) selectivity of benzotriazoles: regiodivergent and highly selective coupling of benzotriazoles with allenes. (2014) (82)
Enantioselective synthesis of branched allylic esters via rhodium-catalyzed coupling of allenes with carboxylic acids. (2011) (80)
Supramolecular bidentate ligands by metal-directed in situ formation of antiparallel beta-sheet structures and application in asymmetric catalysis. (2008) (80)
Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids (2012) (79)
All-carbon quaternary centers via ruthenium-catalyzed hydroxymethylation of 2-substituted butadienes mediated by formaldehyde: beyond hydroformylation. (2009) (78)
Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution. (2015) (77)
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: methanol-stable platforms analogous to the adenine-thymine base pair. (2007) (77)
Self-assembled bidentate ligands for the nickel-catalyzed hydrocyanation of alkenes. (2009) (76)
Domino Hydroformylation/Enantioselective Cross‐Aldol Addition (2007) (73)
Regio- and Enantioselective Rhodium-Catalyzed Addition of 1,3-Diketones to Allenes: Construction of Asymmetric Tertiary and Quaternary All Carbon Centers. (2017) (72)
Atom-economic, regiodivergent, and stereoselective coupling of imidazole derivatives with terminal allenes. (2014) (72)
Highly regioselective hydroformylation under mild conditions with new classes of π-acceptor ligands (1996) (72)
Supramolecular PhanePhos-analogous ligands through hydrogen-bonding for asymmetric hydrogenation. (2008) (71)
Self-Assembled Bidentate Ligands for Ruthenium-Catalyzed Hydration of Nitriles (2007) (70)
Rhodium-catalyzed chemo-, regio-, and enantioselective addition of 2-pyridones to terminal allenes. (2014) (69)
Inter- and intramolecular hydroacylation of alkenes employing a bifunctional catalyst system. (2011) (69)
Transition-state stabilization by a secondary substrate-ligand interaction: a new design principle for highly efficient transition-metal catalysis. (2010) (69)
Enantioselective redox-neutral Rh-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters. (2015) (68)
Recent Advances in Alkene Hydroformylation (2007) (67)
Remote control of regio- and diastereoselectivity in the hydroformylation of bishomoallylic alcohols with catalytic amounts of a reversibly bound directing group. (2010) (66)
Regio- and enantioselective synthesis of N-substituted pyrazoles by rhodium-catalyzed asymmetric addition to allenes. (2015) (65)
Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines (2015) (62)
Rhodium-catalyzed selective anti-Markovnikov addition of carboxylic acids to alkynes. (2010) (61)
Probing new classes of π-acceptor ligands for rhodium catalyzed hydroformylation of styrene (1999) (59)
Zinc-catalyzed enantiospecific sp3-sp3 cross-coupling of alpha-hydroxy ester triflates with Grignard reagents. (2008) (59)
Mechanistic insights into a supramolecular self-assembling catalyst system: evidence for hydrogen bonding during rhodium-catalyzed hydroformylation. (2012) (59)
Enantioselective hydrogenation with self-assembling rhodium phosphane catalysts: influence of ligand structure and solvent. (2007) (58)
Stereospecific and stereodivergent construction of quaternary carbon centers through switchable directed/nondirected allylic substitution. (2004) (56)
Reagent Directing Group Controlled Organic Synthesis: Total Synthesis of (R,R,R)‐α‐Tocopherol (2007) (55)
PHOSPHABENZENE-RHODIUM CATALYSTS FOR THE EFFICIENT HYDROFORMYLATION OF TERMINAL AND INTERNAL OLEFINS (1997) (54)
Selective Hydrogenation of Carboxylic Acids to Alcohols or Alkanes Employing a Heterogeneous Catalyst (2017) (54)
Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system (2013) (54)
Rhodium-Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers. (2016) (53)
Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes. (2016) (53)
Regiodivergent Hydroaminoalkylation of Alkynes and Allenes by a Combined Rhodium and Photoredox Catalytic System. (2019) (53)
Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization. (2006) (53)
Total synthesis of (+)-clavolonine, (-)-deacetylfawcettiine, and (+)-acetylfawcettiine. (2010) (52)
Spirocyclization of a Stable Phosphaalkyne with Aluminum Trichloride—Key Reaction for the Production of Triphospha Dewar Benzene Derivatives (1992) (50)
A New Platform for Designing Ligands for Asymmetric Induction in Allylic Alkylations (1995) (50)
Divergent regioselectivity in the synthesis of trisubstituted allylic alcohols by nickel- and ruthenium-catalyzed alkyne hydrohydroxymethylation with formaldehyde. (2011) (49)
4-Acyl Pyrrole Derivatives Yield Novel Vectors for Designing Inhibitors of the Acetyl-Lysine Recognition Site of BRD4(1). (2016) (49)
Hexaphosphapentaprismane: a new gateway to organophosphorus cage compound chemistry. (2002) (48)
Phosphabarrelene-rhodium complexes as highly active catalysts for isomerization free hydroformylation of internal alkenes. (2004) (47)
Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Triazoles with Internal Alkynes and Terminal Allenes. (2018) (47)
Short access to (+)-lupinine and (+)-epiquinamide via double hydroformylation. (2010) (47)
Regioconvergent and Enantioselective Rhodium-Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles. (2016) (46)
Hydroformylation of homoallylic azides: a rapid approach toward alkaloids. (2009) (45)
On the nature of the asymmetric induction in a palladium catalyzed allylic alkylation (1994) (45)
Iterative deoxypropionate synthesis based on a copper-mediated directed allylic substitution. (2004) (45)
Domino Hydroformylation-Wittig Reactions. (1999) (42)
Substrate‐Directed Diastereoselective Hydroformylation of Methallylic Alcohols (1996) (41)
Enantioselective and Regiodivergent Addition of Purines to Terminal Allenes: Synthesis of Abacavir. (2017) (41)
Desymmetrizing hydroformylation with the aid of a planar chiral catalyst-directing group. (2004) (41)
o-DPPB-directed copper-mediated and -catalyzed allylic substitution with Grignard reagents. (2006) (39)
Rhodium-Catalyzed Diastereoselective Cyclization of Allenyl-Sulfonylcarbamates: A Stereodivergent Approach to 1,3-Aminoalcohol Derivatives. (2016) (39)
Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines. (2016) (39)
Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification. (2015) (39)
Copper‐Mediated and ‐Catalyzed o‐DPPB‐Directed Allylic Substitution (2001) (39)
Ligand self-assembling through complementary hydrogen-bonding in the coordination sphere of a transition metal center: the 6-diphenylphosphanylpyridin-2(1H)-one system. (2011) (38)
Iterative synthesis of (oligo)deoxypropionates via zinc-catalyzed enantiospecific sp3-sp3 cross-coupling. (2009) (38)
Stereoselective hydroformylation: key step for the assembly of polypropionate subunits. (1999) (38)
Domino Hydroformylation/Knoevenagel/Hydrogenation Reactions (2001) (37)
Enantioselective Pd-catalyzed allylic amination with self-assembling and non-assembling monodentate phosphine ligands (2007) (37)
Rhodium-Catalyzed Enantioselective Decarboxylative Alkynylation of Allenes with Arylpropiolic Acids. (2018) (37)
Enantioselective total synthesis of the unnatural and the natural stereoisomers of vittatalactone. (2010) (37)
Self-assembly of bidentate ligands for combinatorial homogeneous catalysis based on an A-T base pair model (2006) (36)
Catalysts through self-assembly for combinatorial homogeneous catalysis (2008) (35)
Practical Synthesis of Enantiomerically Pure 2-(Diphenylphosphanyl)ferrocene Carboxylic Acid (2005) (35)
Iterative deoxypropionate synthesis based on a copper-mediated directed allylic substitution: formal total synthesis of borrelidin (C3-C11 fragment). (2006) (35)
Stereospecific and stereodivergent construction of tertiary and quaternary carbon centers through switchable directed/nondirected allylic substitution. (2006) (35)
Development of an improved rhodium catalyst for z-selective anti-markovnikov addition of carboxylic acids to terminal alkynes. (2013) (34)
Rhodium-catalyzed chemo- and regioselective decarboxylative addition of β-ketoacids to alkynes. (2016) (34)
Enantioselective total synthesis and determination of the absolute configuration of the 4,6,8,10,16,18-hexamethyldocosane from Antitrogus parvulus. (2007) (34)
Regioselective Rhodium‐Catalyzed Addition of β‐Keto Esters, β‐Keto Amides, and 1,3‐Diketones to Internal Alkynes (2016) (33)
Cooperative effect of a classical and a weak hydrogen bond for the metal-induced construction of a self-assembled beta-turn mimic. (2009) (33)
Combined transition-metal- and organocatalysis: an atom economic C3 homologation of alkenes to carbonyl and carboxylic compounds. (2010) (33)
Enantioselective Rhodium-Catalyzed Atom-Economical Macrolactonization. (2016) (32)
Palladium- and Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles. (2018) (31)
1,3‐Asymmetric Induction in Stereoselective Rhodium‐Catalyzed Hydroformylation of Homomethallylic Alcohols☆ (1998) (31)
A systematic investigation of coinage metal carbonyl complexes stabilized by fluorinated alkoxy aluminates. (2013) (31)
Online Monitoring of Hydroformylation Intermediates by ESI-MS (2010) (30)
Rhodium-catalyzed addition of sulfonyl hydrazides to allenes: regioselective synthesis of branched allylic sulfones. (2017) (30)
Development of an axial chirality switch. (2007) (29)
Asymmetric synthesis of allylic amines via hydroamination of allenes with benzophenone imine† †Electronic supplementary information (ESI) available: Experimental procedures and detailed characterization data of all new compounds. See DOI: 10.1039/c5sc04984a (2016) (28)
Diastereoselective hydroformylation of 2,5-cyclohexadienyl-1-carbinols with catalytic amounts of a reversibly bound directing group. (2011) (28)
Easily Accessible TADDOL-Derived Bisphosphonite Ligands: Synthesis and Application in the Asymmetric Hydroformylation of Vinylarenes (2015) (27)
Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to enones with new peptidyl phosphane ligands (2003) (27)
Direct assignment of the relative configuration in 1,3,n-methyl-branched carbon chains by (1)H NMR spectroscopy. (2010) (27)
Substrate-Directed Diastereoselective Hydroformylations, 1. Substrate-Directed Diastereoselective Hydroformylation of Methallylic Alcohols – Development of an Efficient Catalyst-Directing Group for Rhodium-Catalyzed Hydroformylation (1997) (27)
Rhodium-Catalyzed Regioselective Domino Azlactone-Alkyne Coupling/Aza-Cope Rearrangement: Facile Access to 2-Allyl-3-oxazolin-5-ones and Trisubstituted Pyridines. (2017) (27)
Domino‐Hydroformylierungs‐Wittig‐ Reaktionen (1999) (27)
Enantioselective total synthesis and determination of absolute configuration of vittatalactone. (2009) (26)
Metal catalyzed reductive C-C bond formation : a departure from preformed organometallic reagents (2007) (26)
Enantioselective Total Synthesis and Determination of the Absolute Configuration of the 4,6,8,10,16,18‐Hexamethyldocosane from Antitrogus parvulus (2005) (26)
Mechanistic insight into the ruthenium-catalysed anti-Markovnikov hydration of alkynes using a self-assembled complex: a crucial role for ligand-assisted proton shuttle processes. (2014) (25)
Organophosphorus Compounds, 112. Lewis Acid Mediated Spirocyclotrimerization of Kinetically Stabilized Phosphaalkynes – Key Step for the Selective Generation and Trapping of Triphospha Dewar Benzenes (1996) (25)
Enantioselective formation of tertiary and quaternary allylic C-N bonds via allylation of tetrazoles. (2015) (25)
Formation of quaternary carbon centers by highly regioselective hydroformylation with catalytic amounts of a reversibly bound directing group. (2011) (25)
o-DPPB-Directed Stereoselective Conjugate Addition of Organocuprates (2000) (25)
Tandem Regioselective Hydroformylation-Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst. (2018) (24)
Total synthesis of (18S)- and (18R)-homolargazole by rhodium-catalyzed hydrocarboxylation. (2014) (24)
Diastereoselective hydroformylation of acyclic olefins: Efficient construction of an all-anti stereotriade building block for polyketide synthesis (1998) (24)
Preparation of alkylmagnesium reagents from alkenes through hydroboration and boron-magnesium exchange. (2012) (24)
Chiral Phosphabarrelene Ligands: Synthesis and Evaluation in Rhodium-Catalyzed Asymmetric Hydrogenation (2006) (24)
A unified strategy for the stereospecific construction of propionates and acetate-propionates relying on a directed allylic substitution. (2009) (24)
Rhodium-Catalyzed Asymmetric N-H Functionalization of Quinazolinones with Allenes and Allylic Carbonates: The First Enantioselective Formal Total Synthesis of (-)-Chaetominine. (2017) (24)
Substrate-directed diastereoselective hydroaminomethylation of methallylic alcohols (1998) (24)
Assignment of relative configuration of desoxypropionates by 1H NMR spectroscopy: method development, proof of principle by asymmetric total synthesis of xylarinic acid A and applications. (2012) (23)
Substrate directed diastereoselective hydroformylation of acyclichomomethallylic alcohols (1997) (23)
Structural characterization of O- and C-glycosylating variants of the landomycin glycosyltransferase LanGT2. (2015) (22)
Rhodium-Catalyzed Hydroformylation of 1,1-Disubstituted Allenes Employing the Self-Assembling 6-DPPon System. (2015) (22)
Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Allenes. (2019) (22)
Desymmetrizing Hydroformylation of Dialkenylcarbinols with the Aid of a Planar‐Chiral, Catalyst‐Directing Group (2005) (22)
Stereodivergent and Protecting-Group-Free Synthesis of the Helicascolide Family: A Rhodium-Catalyzed Atom-Economical Lactonization Strategy. (2016) (22)
Rhodium-Catalyzed Asymmetric Allylation of Malononitriles as Masked Acyl Cyanide with Allenes: Efficient Access to β,γ-Unsaturated Carbonyls. (2018) (21)
Beyond the BET Family: Targeting CBP/p300 with 4-Acyl Pyrroles. (2017) (21)
Palladium-Catalyzed Direct C-H Allylation of Electron-Deficient Polyfluoroarenes with Alkynes. (2018) (21)
Chemo-, Regio-, and Enantioselective Rhodium-Catalyzed Allylation of Pyridazinones with Terminal Allenes. (2017) (20)
From Central to Axial to Central Chirality: Enantioselective Construction of the trans‐4,5,9,10‐Tetrahydroxy‐9,10‐dihydrophenanthrene System (2007) (20)
Room Temperature Ambient Pressure (RTAP)‐Hydroformylation in Water Using a Self‐Assembling Ligand (2013) (20)
One-pot desymmetrizing hydroformylation/carbonyl ene cyclization process: straightforward access to highly functionalized cyclohexanols. (2008) (19)
Realistic energy surfaces for real-world systems: an IMOMO CCSD(T):DFT scheme for rhodium-catalyzed hydroformylation with the 6-DPPon ligand. (2013) (19)
Practical Synthesis of (E)‐α,β‐Unsaturated Carboxylic Acids Using a One‐Pot Hydroformylation/Decarboxylative Knoevenagel Reaction Sequence (2008) (19)
Dithioacetals as an Entry to Titanium-Alkylidene Chemistry: A New and Efficient Carbonyl Olefination. (1998) (19)
Tetraphosphasemibullvalene: First Valence Isomerizations in the Phosphaalkyne Cyclotetramer System†‡ (1997) (19)
Transition-Metal-Catalyzed Regiodivergent and Stereoselective Access to Branched and Linear Allylated 4-Pyridones. (2017) (19)
The Total Synthesis of Epothilone D as a Yardstick for Probing New Methodologies. (2017) (19)
Directed Branched‐Regioselective Hydroformylation of 2‐Substituted Allylic o‐DPPB Esters (2007) (19)
Rhodium-Catalyzed Enantioselective Cyclization of 3-Allenyl-indoles: Access to Functionalized Tetrahydrocarbazoles. (2019) (19)
Domino‐Hydroformylierungs/Knoevenagel/Hydrierungs‐Reaktion (2001) (18)
Enantioselective copper-mediated allylic substitution with Grignard reagents employing a chiral reagent-directing leaving group (2004) (18)
Directed regio- and stereoselective hydroformylation of mono- and 1,3-disubstituted allylic alcohols: a catalytic approach to the anti-aldol-retron. (2004) (18)
Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution. (2009) (18)
Rhodium-Catalyzed Regio- and Enantioselective Addition of N-Hydroxyphthalimide to Allenes: A Strategy To Synthesize Chiral Allylic Alcohols. (2018) (18)
Diastereoselective hydroformylation of 2-substituted allylic o-DPPB-esters-on the origin of 1,2-asymmetric induction. (2003) (18)
Copper‐mediated Diastereoselective Conjugate Addition and Allylic Substitution Reactions (2002) (18)
Enantioselective Rhodium-Catalyzed Dimerization of ω-Allenyl Carboxylic Acids: Straightforward Synthesis of C2 -Symmetric Macrodiolides. (2018) (17)
Hydrogen-bond and solvent dynamics in transition metal complexes: a combined simulation and NMR-investigation. (2012) (17)
A New Method for the Synthesis of Chiral -Branched a-Amino Acids (2007) (16)
Inducing Axial Chirality in a Supramolecular Catalyst. (2018) (16)
Potent inhibitors of malarial aspartic proteases, the plasmepsins, by hydroformylation of substituted 7-azanorbornenes. (2013) (16)
ortho-Diphenylphosphanylbenzoyl-Directed Cuprate Addition to Acyclic Enoates. (1998) (15)
Domino hydroformylation–Wittig olefination–hydrogenation (2005) (15)
Palladium-Catalyzed Stereoselective Cyclization of in Situ Formed Allenyl Hemiacetals: Synthesis of Rosuvastatin and Pitavastatin. (2018) (15)
Bis alkoxytitanacyclopropanes and -propenes (Kulinkovich reagents): Versatile reagents for carbon—carbon bond formation (2000) (14)
Tandem decarboxylative hydroformylation-hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system. (2013) (14)
Enantioselective synthesis of 2,6-dideoxy carbasugars based on a desymmetrizing hydroformylation-carbonyl ene cyclization process. (2008) (14)
The First Carbon–Phosphorus–Aluminum Cage Compounds: Cyclooligomerization of Phosphaalkynes with Trialkylaluminum Compounds (1994) (13)
Organophosphorus Compounds; 52.1 Phosphatriafulvenes and Their Reactions with Electrophiles (1991) (13)
1,2-Diastereoselective C–C Bond-Forming Reactions for the Synthesis of Chiral β-Branched α-Amino Acids (2010) (12)
Full kinetic analysis of a rhodium-catalyzed hydroformylation: beyond the rate-limiting step picture (2015) (12)
Rhodium-Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3-Diketones. (2019) (12)
4-Acyl Pyrrole Capped HDAC Inhibitors: A New Scaffold for Hybrid Inhibitors of BET Proteins and Histone Deacetylases as Antileukemia Drug Leads. (2021) (11)
Visible‐Light‐Driven Intermolecular Reductive Ene–Yne Coupling by Iridium/Cobalt Dual Catalysis for C(sp3)−C(sp2) Bond Formation (2019) (11)
Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes (2021) (11)
Functional Characterization of Three Specific Acyl-Coenzyme A Synthetases Involved in Anaerobic Cholesterol Degradation in Sterolibacterium denitrificans Chol1S (2018) (11)
Rhodium‐Catalyzed Cyclization of Terminal and Internal Allenols: An Atom Economic and Highly Stereoselective Access Towards Tetrahydropyrans (2020) (11)
Concise Total Synthesis of (-)-Vermiculine through a Rhodium-Catalyzed C2 -Symmetric Dimerization Strategy. (2019) (10)
Ligand‐Mediated Regioselective Rhodium‐Catalyzed Benzotriazole–Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis (2019) (10)
Efficient synthesis of new fluorinated building blocks by means of hydroformylation. (2014) (10)
Synthesis of 2-(Isoquinolin-1-yl)prop-2-en-1-ones via Silver(I)-Catalyzed One-Pot Tandem Reaction of ortho-Alkynylbenzaldoximes with Propargylic Alcohols. (2019) (10)
Total Synthesis of (-)-Cylindrocyclophane F: A Yardstick for Probing New Catalytic C-C Bond-Forming Methodologies. (2018) (10)
The Mediated Cyclooligomerization of Phosphaalkynes-New Aspects in the Synthesis of Polycyclic Phosphorus Compounds [1] (1993) (9)
Rhodium-Catalyzed Diastereo- and Enantioselective Tandem Spirocyclization/Reduction of 3-Allenylindoles: Access to Functionalized Vinylic Spiroindolines. (2019) (9)
Stereoselective hydroformylation, cuprate addition and domino reactions with the aid of a catalyst directing group (2000) (9)
Asymmetric Total Syntheses of (-)-Angustureine and (-)-Cuspareine via Rhodium-Catalyzed Hydroamination. (2019) (9)
Cobalt-Catalyzed Hydroboration of Terminal and Internal Alkynes. (2021) (8)
Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes (2016) (8)
A Supramolecular Catalyst for the Decarboxylative Hydroformylation of α,β-Unsaturated Carboxylic Acids. (2008) (8)
Tofacitinib and analogs as inhibitors of the histone kinase PRK1 (PKN1). (2016) (8)
New phosphorus self-assembling ligands for the tandem hydroformylation–Wittig olefination reaction of homoallylic alcohols — A key step for stereoselective pyran synthesis (2014) (8)
4-Acyl Pyrroles as Dual BET-BRD7/9 Bromodomain Inhibitors Address BETi Insensitive Human Cancer Cell Lines. (2020) (7)
Rhodium(I)-Catalyzed Allylation with Alkynes and Allenes (2019) (7)
Ionic-liquid-modified CMK-3 as a support for the immobilization of molybdate ions (MoO42-): Heterogeneous nanocatalyst for selective oxidation of sulfides and benzylic alcohols. (2020) (7)
4.18 Hydroformylation and Related Carbonylation Reactions of Alkenes, Alkynes, and Allenes (2014) (7)
A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis (2019) (7)
Rhodium‐Catalyzed Asymmetric Intramolecular Hydroamination of Allenes (2019) (7)
Rhodium-Catalyzed Stereoselective Cyclization of 3-Allenylindoles and N-Allenyltryptamines to Functionalized Vinylic Spiroindolenines. (2021) (7)
Chemo-, regio-, and enantioselective synthesis of allylic nitrones via rhodium-catalyzed addition of oximes to allenes. (2019) (7)
Organophosphorus Compounds, 114. Tetracyclic Phosphorus‐Aluminium‐Carbon Compounds – Synthesis by Cooligomerization of Kinetically Stabilized Phosphaalkynes with Trialkylaluminium Compounds (1997) (6)
Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Allylation of 2-Aminothiazoles with Terminal Allenes (2019) (6)
Catalyst-free hydrothiolation of alkynes with dithiocarbamic acids. (2019) (6)
Probing o-diphenylphosphanyl benzoate (o-DPPB)-directed C-C bond formation: total synthesis of dictyostatin. (2015) (6)
Tandem Regioselective Rhodium-Catalyzed Hydroformylation–Enantioselective Aminocatalytic anti-Mannich Reaction (2014) (6)
Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy. (2011) (6)
Directed Rhodium-Catalyzed Hydroformylation of Alkenes (2009) (5)
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines. (2011) (5)
Directed Synthesis of Phosphorus-Carbon Cage Compounds - A Challenge in Organophosphorus Chemistry (1996) (5)
Tandem Regioselective Hydroformylation-Hydrogenation of Internal Alkynes Using a Supramolecular Catalyst (2018) (5)
Syntheses of Thailandepsin B Pseudo‐Natural Products: Access to New Highly Potent HDAC Inhibitors via Late‐Stage Modification (2020) (5)
Metal-Free Domino Oligocyclization Reactions of Enynals and Enynones with Molecular Oxygen. (2021) (5)
Removable Directing Groups in Organic Synthesis and Catalysis (2011) (5)
Tandem Hydroformylation–Biginelli Reaction (2013) (5)
Enantioselective Synthesis of Branched Allylic Esters via Rhodium‐Catalyzed Coupling of Allenes with Carboxylic Acids. (2012) (5)
Cu-Catalyzed C-H Allylation of Benzimidazoles with Allenes. (2021) (5)
Transition metal catalyzed stereodivergent synthesis of syn- and anti-δ-vinyl-lactams: formal total synthesis of (–)-cermizine C and (–)-senepodine G† †Electronic supplementary information (ESI) available. CCDC 1840179–1845388. For ESI and crystallographic data in CIF or other electronic format see (2019) (5)
Rhodium(I)-Catalyzed 1,4-Additionof Arylboronic Acids to Acrylic Acid in Water: One-Step Preparationof 3-Arylpropionic Acids (2011) (4)
Corrigendum: Removable Directing Groups in Organic Synthesis and Catalysis (2011) (4)
Amino Acid‐Based Dithiocarbamates as Efficient Intermediates for Diversity‐Oriented Synthesis of Thiazoles (2020) (4)
Paraformaldehyde and Methanol as C1 Feedstocks in Metal‐Catalyzed C—C Couplings of π‐Unsaturated Reactants: Beyond Hydroformylation (2015) (4)
Organophotoredox/Ni-Cocatalyzed Allylation of Allenes: Regio- and Diastereoselective Access to Homoallylic Alcohols (2022) (4)
Metabolic reprogramming of inner ear cell line HEI-OC1 after dexamethasone application (2021) (4)
Tandem Photocatalysis Protocol for Hydrogen Generation/Olefin Hydrogenation Using Pd-g-C3N4-Imine/TiO2 Nanoparticles. (2021) (4)
Tandem Decarboxylative Hydroformylation—Hydrogenation Reaction of α,β-Unsaturated Carboxylic Acids Toward Aliphatic Alcohols under Mild Conditions Employing a Supramolecular Catalyst System. (2014) (4)
Addition of Chloroprene Grignards to Aromatic Aldehydes: Synthesis of Homoallenyl Alcohols. (2021) (4)
Rhodium‐Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3‐Diketones (2019) (4)
Needle ball-like nanostructured mixed Cu-Ni-Co oxides: Synthesis, characterization and application to the selective oxidation of sulfides to sulfoxides. (2019) (4)
Self‐Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis: Asymmetric Rhodium‐Catalyzed Hydrogenation. (2006) (3)
Palladium-catalyzed trisallylation of benzoxazoles and 2-aryl-1,3,4-oxadiazoles with alkyne. (2019) (3)
Aliphatic and Alicyclic Aldehydes: Synthesis by Hydroformylation of Alkenes (2009) (3)
Enantioselective Formation of Tertiary and Quaternary Allylic C—N Bonds via Allylation of Tetrazoles. (2015) (3)
Titelbild: A Supramolecular Catalyst for Regioselective Hydroformylation of Unsaturated Carboxylic Acids (Angew. Chem. 2/2008) (2008) (3)
Regio‐, Diastereo‐, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis (2022) (3)
Hydrofunctionalization of Propadiene – New Life for a Previously Unwanted Product (2022) (3)
Asymmetric Synthesis of Allylic Amines via Hydroamination of Allenes with Benzophenone Imine. (2016) (3)
Zinc-Catalyzed Enantiospecific sp3—sp3 Cross-Coupling of α-Hydroxy Ester Triflates with Grignard Reagents. (2008) (3)
Rhodium-Catalyzed Addition of Carboxylic Acids to Terminal Alkynes towards Z-Enol Esters (2016) (3)
Ruthenium-Catalyzed Enantioselective Addition of Carboxylic Acids to Allenes (2021) (3)
Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acrylic Acid in Water: One-Step Preparation of 3-Arylpropionic Acids. (2012) (3)
Organophosphorus Compounds; 65. The Phospha-Ane Reaction: An Unusual Dimerization of Phosphaalkenes (1993) (3)
Self-Assembly of Ligands for Combinatorial Homogeneous Catalysis (2006) (2)
Regio‐ and Enantioselective Synthesis of N‐Substituted Pyrazoles by Rhodium‐Catalyzed Asymmetric Addition to Allenes. (2015) (2)
Domino Hydroformylation/Enantioselective Cross‐Aldol Addition. (2007) (2)
Zinc-Catalyzed Cross-Coupling of Triflates with GrignardReagents (2008) (2)
Phosphine-Directed Diastereoselective Allylic Substitutions (2007) (2)
μ-Bromido-dibromido-μ-hydroxido-bis[(4S)-2-halo-6-(4-isopropyl-4,5-dihydrooxazol-2-yl)pyridine]dicopper(II) (halo: Cl/Br = 3:1) (2007) (2)
Tandem-Directed RegioselectiveHydroformylation/β-Elimination: A PracticalMethod for the Synthesis of Enals (2008) (2)
Synthesis of (−)‐( R )‐Sitagliptin by Rh I ‐Catalyzed Asymmetric Hydroamination (2021) (2)
A Convenient Allylic Functionalizationof Bis(prop-2-enyl)methanol by Direct Trimetalation (2008) (2)
Pharmacokinetic study of the novel phosphocholine derivative 3-dibutylaminopropylphosphonic acid by LC-MS coupling. (2021) (2)
o‐DPPB‐Directed Copper‐Mediated and ‐Catalyzed Allylic Substitution with Grignard Reagents. (2006) (2)
Rhodium‐Catalyzed Hydroformylation of Alkynes Employing a Self‐Assembling Ligand System. (2013) (2)
Structure-Based Design, Docking and Binding Free Energy Calculations of A366 Derivatives as Spindlin1 Inhibitors (2021) (2)
Copper‐Catalyzed Enantioselective Conjugate Addition of Dialkylzinc Reagents to Enones with New Peptidyl Phosphane Ligands. (2004) (2)
Supramolecular Approaches to Generate Libraries of Chelating Bidentate Ligands for Homogeneous Catalysis (2006) (2)
Stereodivergent Palladium- and Rhodium-Catalyzed Intramolecular Addition of Tosylureas to Allenes: Diastereoselective Synthesis of Tetrahydropyrimidinones. (2021) (2)
Reagent directing group controlled organic synthesis: total synthesis of (R,R,R)-alpha-tocopherol. (2007) (1)
Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti‐Markovnikov Hydration of Terminal Alkynes. (2006) (1)
Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis (2008) (1)
A Convenient Allylic Functionalization of Bis(prop‐2‐enyl)methanol by Direct Trimetallation. (2009) (1)
Urea‐Substituted Tetramethylcyclopentadienyl Ligands for Supramolecularly Accelerated RhIII‐Catalyzed ortho‐C−H Olefination of Benzoic Acid Derivatives (2020) (1)
Total Syntheses of Cylindrocyclophanes Exemplifying the Power of Transition-Metal Catalysis in Natural-Product Synthesis (2020) (1)
Unlocking the N2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes. (2014) (1)
Self-Assembly of Bidentate Ligands for Combinatorial Homogeneous Catalysis Based on an A—T Base Pair Model (2006) (1)
Catalyst Deactivation During Rhodium Complex‐Catalyzed Propargylic C−H Activation (2021) (1)
Asymmetric hydroalkylation of alkynes and allenes with imidazolidinone derivatives: α-alkenylation of α-amino acids† (2021) (1)
Cover Picture: Bidentate Ligands by Self‐Assembly through Hydrogen Bonding: A General Room Temperature/Ambient Pressure Regioselective Hydroformylation of Terminal Alkenes (Adv. Synth. Catal. 11‐13/2005) (2005) (1)
Copper-Catalyzed Cycloisomerization of Unactivated Allene-Tethered O-Propargyl Oximes: A Domino Reaction Sequence toward the Synthesis of Hexahydropyrrolo[3,4-b]azepin-5(4H)-ones. (2021) (1)
Economic Large-Scale Synthesisof o- and m-DiphenylphosphinobenzoicAcids (2010) (1)
Copper-Mediated and -Catalyzed o-DPPB-Directed Allylic Substitution. (2001) (1)
Practical Synthesis of Chlorosilyl-Functionalized Triphenylphosphanes. (2004) (1)
Dicarbonyl(acetylacetonato) Rhodium (I) (2013) (1)
o-DPPB-Directed Copper-Mediated Allylic Substitution. Part 3. Stereospecific and Stereodivergent Construction of Tertiary and Quaternary Carbon Centers Through Switchable Directed/Nondirected Allylic Substitution. (2007) (1)
ortho‐Diphenylphosphanylbenzoyl‐Directed Cuprate Addition to Acyclic Enoates. (1998) (1)
Rhodium‐Catalyzed Selective anti‐Markovnikov Addition of Carboxylic Acids to Alkynes. (2011) (1)
Palladium‐ and Rhodium‐Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes Towards Chiral Pyrazoles (2018) (1)
Preparation data of the bromodomains BRD3(1), BRD3(2), BRD4(1), and BRPF1B and crystallization of BRD4(1)-inhibitor complexes (2016) (1)
Rhodium-catalyzed asymmetric intramolecular hydroarylation of allenes: access to functionalized benzocycles† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc03894a (2019) (1)
Rhodium-Catalyzed Asymmetric Hydrogenation (2006) (1)
Practical Synthesis of (E)‐α,β‐Unsaturated Carboxylic Acids Using a One‐Pot Hydroformylation/Decarboxylative Knoevenagel Reaction Sequence. (2008) (1)
Branched Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group. (2009) (1)
Domino Hydroformylation/Organocatalytic Aldol Reaction (2007) (1)
Rhodium-Catalyzed Regio- and Diastereoselective Hydroarylation of Allenes: An Unprecedented Ene Reaction (2021) (1)
Chiral Phosphabarrelene Ligands: Synthesis and Evaluation in Rhodium‐Catalyzed Asymmetric Hydrogenation. (2006) (0)
Substrate‐Directed Diastereoselective Hydroformylations. Part 5. Desymmetrizing Hydroformylation of Dialkenylcarbinols with the Aid of a Planar‐Chiral, Catalyst‐Directing Group. (2006) (0)
Diastereoselective Hydroformylation of 2-Substituted Allylic o-DPPB-Esters — On the Origin of 1,2-Asymmetric Induction. (2003) (0)
Chimeric Glycosyltransferase LanGT2S8Ac, TDP complex (2015) (0)
Organophosphorus Compounds. Part 62. The Mediated Cyclooligomerization of Phosphaalkynes - New Aspects in the Synthesis of Polycyclic Phosphorus Compounds (1993) (0)
Mechanism for the Rh-Catalyzed Coupling of Carboxylic Acids with Terminal Alkynes Table 3 . Examples of the Asymmetric Allylation of Carboxylic Acids with Terminal Allenes (2016) (0)
Room Temperature Ambient Pressure (RTAP)-Hydroformylation in Water Using a Self-Assembling Ligand. (2013) (0)
Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes towards Chiral Allylated Triazoles and Tetrazoles (2022) (0)
Chapter 17. Dithioacetals as an Entry to Titanium-Alkylidene Chemistry: New and Efficient Carbonyl Olefination (2008) (0)
Development of an Improved Rhodium Catalyst for Z‐Selective anti‐Markovnikov Addition of Carboxylic Acids to Terminal Alkynes. (2014) (0)
Controlling Regio‐ and Stereochemistry in Metal‐Catalyzed and Metal‐Mediated Reactions with the Aid of Substrate‐Bound Reagent‐Directing Phosphine Groups (2009) (0)
Asymmetric Hydroformylation of Vinylarenes via Rhodium Catalysis (2015) (0)
Synthetic Aspects of Stereoselective Hydroformylation (2003) (0)
Cuticular Hydrocarbon Ph eromones for Social Behavior and Their Coding in the Ant Antenna Graphical (2015) (0)
Rhodium-catalyzed diastereoselective synthesis of highly substituted morpholines from nitrogen-tethered allenols. (2023) (0)
One‐Pot Desymmetrizing Hydroformylation/Carbonyl Ene Cyclization Process: Straightforward Access to Highly Functionalized Cyclohexanols. (2009) (0)
Acyclic and Exocyclic Alkenes (2007) (0)
Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and Their Applications in Organic Synthesis (2013) (0)
Landomycin Glycosyltransferase LanGT2, carbasugar substrate complex (2015) (0)
Synthesis of Vittatalactone (2010) (0)
Rh-Catalyzed Regio- and Diastereoselective Hydroformylationof Bishomoallylic Alcohols (2010) (0)
Practical Synthesis of Chlorosilyl-Functionalized Triphenylphosphanes (2004) (0)
Phosphorus Compounds. Part 77. The First Carbon‐Phosphorus‐Aluminum Cage Compounds: Cyclooligomerization of Phosphaalkynes with Trialkylaluminum Compounds. (1994) (0)
Organo‐Phosphorus Compounds. Part 73. Trapping Reaction of an in situ Generated Silene with tBu‐CP. Formation of a Diphosphatricyclobenzoheptane. (2010) (0)
Self‐Assembled Bidentate Ligands for the Nickel‐Catalyzed Hydrocyanation of Alkenes. (2009) (0)
Desymmetrizing Hydroformylation/Carbonyl Ene Cyclization (2009) (0)
Synthesis of β-Allenylamines by Addition of Chloroprene Grignards to N-Boc Imines. (2022) (0)
Divergent Regioselectivity in the Synthesis of Trisubstituted Allylic Alcohols by Nickel‐ and Ruthenium‐Catalyzed Alkyne Hydrohydroxymethylation with Formaldehyde. (2011) (0)
Titelbild: Inducing Axial Chirality in a Supramolecular Catalyst (Angew. Chem. 18/2018) (2018) (0)
Substrate-Directed Hydroformylation. Part 7. Directed Branched-Regioselective Hydroformylation of 2-Substituted Allylic o-DPPB Esters. (2007) (0)
Stereoselective and Diversity‐Oriented Synthesis of Trisubstituted Allylic Alcohols and Amines. (2012) (0)
Nickel‐Catalyzed Hydrocyanation of Terminal Allenes: Regio‐ and Enantioselective Access towards Branched Allylic Nitriles (2023) (0)
Stereoselective Hydroformylation of Acyclic Olefins with the Aid of a Catalyst Directing Group (1998) (0)
Supramolecular Catalyst for Aldehyde Hydrogenation and Tandem Hydroformylation—Hydrogenation. (2010) (0)
Organophosphorus Compounds. Part 53. Cyclopropenylidene-methylene- diphosphanes - New Cross-Conjugated Phosphapolyenes. (1992) (0)
Cover Picture: A Supramolecular Catalyst for Regioselective Hydroformylation of Unsaturated Carboxylic Acids (Angew. Chem. Int. Ed. 2/2008) (2008) (0)
A new method for the synthesis of chiral beta-branched alpha-amino acids. (2007) (0)
Chimeric Glycosyltransferase LanGT2S8Ac, carbasugar substrate complex (2015) (0)
Organophosphorus Compounds. Part 65. The Phospha-Ane Reaction: An Unusual Dimerization of Phosphaalkenes. (1993) (0)
Domino Hydroformylation/Knoevenagel/Hydrogenation Reactions This work was supported by the Fonds der Chemischen Industrie (Fellowship to S.K.Z.) and the Deutsche Forschungsgemeinschaft, as well as an Alfried Krupp Award for Young University Teachers from the Krupp foundation. We thank the companies (2001) (0)
Atom-Economical Dimerization Strategy by the Rhodium-Catalyzed Addition of Carboxylic Acids to Allenes: Protecting-Group-Free Synthesis of Clavosolide A and Late-Stage Modification. (2016) (0)
Phosphine Ligands with Acylguanidinium Groups as Substrate‐directing Unit (2021) (0)
Phosphabenzene—Rhodium Catalysts for the Efficient Hydroformylation of Terminal and Internal Olefins. (2010) (0)
Direct Reactions of Organocopper Reagents (2008) (0)
Organophosphorus Compounds. Part 52. Phosphatriafulvenes and Their Reaction with Electrophiles. (1992) (0)
Enantioselective Copper‐Mediated Allylic Substitution with Grignard Reagents Employing a Chiral Reagent‐Directing Leaving Group. (2005) (0)
Asymmetric Rhodium‐Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones. (2015) (0)
The Cyclotetramerization of Phosphaalkynes and Its 31P NMR Spectroscopic Consequences (1995) (0)
Dual Palladium and Proline Catalyzed Allylic Allylation with Ketone and Allylic Alcohol (2008) (0)
Supramolecular Construction of Bidentate Ligands Through Self‐assembly by Hydrogen Bonding (2021) (0)
Whole-cell biocatalysis – status and future prospects (2016) (0)
Dithioacetals as an Entry to Titanium‐Alkylidene Chemistry: New and Efficient Carbonyl Olefination (2002) (0)
Diastereoselective Hydroformylation: Passive Substrate Control (2007) (0)
Organophosphorus Compounds. Part 71. Phosphaalkynes and Phosphaalkenes as Trapping Partners for 1,2‐Dehydrobenzene and Phenylium‐2‐ carboxylate. (1994) (0)
Regioconvergent and Enantioselective Rhodium‐Catalyzed Hydroamination of Internal and Terminal Alkynes: A Highly Flexible Access to Chiral Pyrazoles. (2016) (0)
Tandem-Directed Regioselective Hydroformylation/b-Elimination: A Practical Method for the Synthesis of Enals Synthesis of Enals via Regioselective Hydroformylation/b-Elimination (2008) (0)
Substrate‐Directed Diastereoselective Hydroformylation. Part 1. Substrate‐Directed Diastereoselective Hydroformylation of Methallylic Alcohols ‐ Development of an Efficient Catalyst‐Directing Group for Rhodium‐Catalyzed Hydroformylation. (1997) (0)
Chimeric Glycosyltransferase LanGT2S8Ac (2015) (0)
Synthesis of (R,R,R)-α-Tocopherol (2008) (0)
Atom‐Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes. (2014) (0)
Acenaphthoimidazolylidene-Ligated Palladacycle Enabled Suzuki-Miyaura Cross-Coupling Employing Equimolar Organoboron for Tri-Ortho-Substituted Bi(hetero)aryls and Teraryls. (2023) (0)
Phosphorus Compounds. Part 58. Spirocyclization of a Stable Phosphaalkyne with Aluminum Trichloride: Key Reaction for the Production of Triphospha Dewar Benzene Derivatives. (1992) (0)
Asymmetric synthesis process (2003) (0)
Hydrogenation with Iron Nanoparticles Supported on CDG (2011) (0)
Tandem-Directed Regioselective Hydroformylation/β-Elimination: A Practical Method for the Synthesis of Enals. (2008) (0)
Controlling Stereoselectivity with the Aid of a Reagent‐Directing Croup (2003) (0)
Cover Picture: Inducing Axial Chirality in a Supramolecular Catalyst (Angew. Chem. Int. Ed. 18/2018) (2018) (0)
o‐DPPB‐Directed Stereoselective Conjugate Addition of Organocuprates. (2001) (0)
Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions (2005) (0)
Domino Hydroformylation/Knoevenagel/Hydrogenation Reactions. (2001) (0)
Easily Accessible TADDOL-Derived Bisphosphonite Ligands: Synthesis and Application in the Asymmetric Hydroformylation of Vinylarenes. (2015) (0)
Fundamentale Fehler: Name Reactions. A Collection of Detailed Reaction Mechanisms. Von Jie Jack Li. Springer, Heidelberg 2002. 416 Seiten, geb., 79,95 Euro. ISBN 3-540-43024-5 (2002) (0)
Practical Synthesis of Chlorosilyl-Functionalized Triphenylphosphanes Synthesis of Chlorosilyl-Functionalized Triphenylphosphanes (2004) (0)
A New Method for the Synthesis of Chiral β‐Branched α‐Amino Acids. (2008) (0)
Organophosphorus Compounds. Part 51. Phosphatriafulvenes - Phosphaalkenes with Inverse Electron Density. (1992) (0)
A process for preparing phosphabenzene (1998) (0)
Rhodium-Catalyzed Coupling of Terminal Alkynes with CarboxylicAcids (2011) (0)
Stereodivergent and Protecting‐Group‐Free Synthesis of the Helicascolide Family: A Rhodium‐Catalyzed Atom‐Economical Lactonization Strategy. (2016) (0)
Editorial: In celebration of Professor Barry M. Trost's 75th birthday (2017) (0)
Substrate‐Directed Diastereoselective Hydroformylations. Part 2. 1,3‐Asymmetric Induction in Stereoselective Rhodium‐Catalyzed Hydroformylation of Homomethallylic Alcohols. (1998) (0)
Substrate Directed Diastereoselective Hydroformylation of Acyclic Homomethallylic Alcohols. (1997) (0)
Rhodium-catalyzed regioselective addition of thioacids to terminal allenes: enantioselective access to branched allylic thioesters. (2022) (0)
A Diastereoselective Cascade Annulation Approach to Bridged Polycyclic Heterocycles Involving an Unexpected Rearrangement. (2022) (0)
Stereospecific and Stereodivergent Construction of Quaternary Centers Through Switchable Directed/Nondirected Allylic Substitution. (2004) (0)
Diastereoselective Hydroformylation: Catalyst Control (2007) (0)
A process for the decarboxylative hydroformylation alpha, beta-unsaturated carboxylic acids (2008) (0)
Visible-light induced metal-free intramolecular reductive cyclisations of ketones with alkynes and allenes. (2023) (0)
Allylation of N‐Heterocycles with Allylic Alcohols Employing Self‐Assembling Palladium Phosphane Catalysts. (2008) (0)
Regio- and Diastereoselective Decarboxylative Allylation of N-Aryl α-Amino Acids by Dual Photoredox/Nickel Catalysis (2022) (0)
Enantioselective Total Synthesis of the Unnatural and the Natural Stereoisomers of Vittalalactone. (2010) (0)
Substrate-Directed Diastereoselective Hydroformylation of Methallylic Alcohols. (2010) (0)
Landomycin Glycosyltransferase LanGT2 (2015) (0)
Catalysts with Chiral Self‐Assembling P‐Ligands (2009) (0)
Aliphatic Alkenes and Dienes (2007) (0)
A novel pan-selective bromodomain inhibitor for epigenetic drug design. (2023) (0)
Diastereoselective Hydroformylation of Acyclic Olefins: Efficient Construction of an all-anti Stereotriade Building Block for Polyketide Synthesis. (1998) (0)
Regioselective Hydroformylation: Substrate Control (2007) (0)
Total Synthesis of (+)‐Bourgeanic Acid Utilizing o‐DPPB‐Directed Allylic Substitution. (2009) (0)
Domino Hydroformylation—Wittig Reactions. (1999) (0)
Rhodium‐Catalyzed Enantioselective Intermolecular Hydroalkoxylation of Allenes and Alkynes with Alcohols: Synthesis of Branched Allylic Ethers. (2016) (0)
Enantioselective Synthesis of 2,6-Dideoxy Carbasugars Based on a Desymmetrizing Hydroformylation—Carbonyl Ene Cyclization Process. (2009) (0)
Regiodivergent Reductive Coupling of 2‐Substituted Dienes to Formaldehyde Employing Ruthenium or Nickel Catalyst: Hydrohydroxymethylation via Transfer Hydrogenation. (2013) (0)
Organophotoredox/Ni-Cocatalyzed Allylation of Allenes: Regio-, and Diastereoselective Access to Homoallylic Alcohols (2021) (0)
A New Platform for Designing Ligands for Asymmetric Induction in Allylic Alkylations. (1996) (0)
Organophosphorus compounds. 53. Cyclopropylidene-methylene-diphosphines - new cross-conjugated phosphapolyenes. (1992) (0)
ZnCl2-Catalyzed Enantiospecific C(sp³)-C(sp³) Cross-CouplingGiving (Oligo)deoxypropionates (2010) (0)
Enantioselective Rhodium‐Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes. (2013) (0)
Organophosphorus Compounds. Part 108. Directed Synthesis of Phosphorus- Carbon Cage Compounds - A Challenge in Organophosphorus Chemistry (1997) (0)
Regioselective Hydroformylation: Catalyst Control (2007) (0)
Domino Hydroformylation—Wittig Olefination—Hydrogenation. (2005) (0)
Highly Regioselective Hydroformylation under Mild Conditions with New Classes of π-Acceptor Ligands. (2010) (0)
Z‐Selective Hydrothiolation of Racemic 1,3‐Disubstituted Allenes: An Atom‐Economic Rhodium‐Catalyzed Dynamic Kinetic Resolution. (2016) (0)
Catalysts Through Self‐Assembly for Combinatorial Homogeneous Catalysis (2008) (0)

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What Schools Are Affiliated With Bernhard Breit?

Bernhard Breit is affiliated with the following schools:

University of Freiburg
University of Bonn