Brian P. Roberts
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Chemistry
Brian P. Roberts's Degrees
- PhD Chemistry Stanford University
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(Suggest an Edit or Addition)Brian P. Roberts's Published Works
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Published Works
- Polarity-reversal catalysis of hydrogen-atom abstraction reactions: concepts and applications in organic chemistry (1999) (542)
- Rotational spectra and geometries of the gas-phase dimers (CH4,HF) and (CH4,HCl) (1990) (79)
- Bimolecular homolytic substitution at a metal center (1972) (70)
- An extended form of the Evans–Polanyi equation: a simple empirical relationship for the prediction of activation energies for hydrogen-atom transfer reactions (1994) (70)
- Radical chain reduction of alkyl halides, dialkyl sulphides and O-alkyl S-methyl dithiocarbonates to alkanes by trialkylsilanes (1991) (61)
- Free radical chain reactions for the preparation of novel anomeric carbohydrate difluoromethylene -phosphonates and -phosphonothioates (1997) (55)
- Metallic behaviour of boron-containing carbon nanotubes (2000) (54)
- Enantioselective radical-chain hydrosilylation of alkenes using homochiral thiols as polarity-reversal catalysts (1998) (49)
- Dynamic aspects of cyclodextrin host-guest inclusion as studied by an EPR spin-probe technique (1999) (48)
- Radical-chain addition of aldehydes to alkenes catalysed by thiols (1998) (46)
- Electron spin resonance study of dialkoxyphosphonyl radicals, (RO)2PO (1972) (45)
- Peroxides of elements other than carbon. Part XIV. The mechanism of the autoxidation of organic compounds of lithium, magnesium, zinc, cadmium, and aluminium (1968) (45)
- Deoxygenation of alcohols by the reactions of their xanthate esters with triethylsilane: An alternative to tributyltin hydride in the Barton-McCombie reaction (1990) (45)
- Carbohydrate-derived thiols as protic polarity-reversal catalysts for enantioselective radical-chain reactions (2002) (44)
- Polarity-reversal catalysis by thiols of radical-chain hydrosilylation of alkenes (1995) (39)
- Homolytic reactions of ligated boranes. Part 11. Electron spin resonance studies of radicals derived from primary amine–boranes (1989) (36)
- Enantioselective radical-chain hydrosilylation of prochiral alkenes using optically active thiol catalysts (1996) (36)
- Homolytic reactions of ligated boranes. Part 9. Overall addition of alkanes to electron-deficient alkenes by a radical chain mechanism (1988) (33)
- Ligated boryl radicals. Part 2. Electron spin resonance studies of trialkylamin–boryl radicals (1985) (33)
- Thiols as polarity reversal catalysts for hydrogen-atom transfer from organosilanes to alkyl radicals: reduction of alkyl halides by triethylsilane (1989) (33)
- Understanding the rates of hydrogen-atom abstraction reactions: empirical, semi-empirical and ab initio approaches (1996) (32)
- Electron spin resonance studies of radicals derived from organic azides (1980) (31)
- Homolytic reactions of ligated boranes. Part 13. An electron spin resonance study of radical addition to aminoboranes (1989) (29)
- Polarity reversal catalysis of hydrogen atom abstraction reactions (1987) (27)
- Selective radical-chain epimerisation at electron-rich chiral tertiary C–H centres using thiols as protic polarity-reversal catalysts (2001) (27)
- Preparation of some new anomeric carbohydrate difluoromethylenephosphonates via phosphonyl radical addition to gem-difluoroenol ethers (1996) (27)
- A probe for homolytic reactions in solution. Part VIII. An electron spin resonance study of the rates of fragmentation and spin trapping of t-butoxycarbonyl radicals and acyl radicals (1974) (27)
- An electron spin resonance study of radical addition to alkyl isocyanides (1979) (26)
- Homolytic reactions of ligated boranes. Part 15. Comparative studies of amine–boranes as donor polarity reversal catalysts for hydrogen-atom abstraction (1990) (26)
- Homolytic reactions of ligated boranes. Part 12. Amine–alkylboranes as polarity reversal catalysts for hydrogen-atom abstraction by t-butoxyl radicals (1989) (25)
- Deoxygenation of carbohydrates by thiol-catalysed radical-chain redox rearrangement of the derived benzylidene acetals. (2003) (25)
- Homolytic reactions of ligated boranes. Part 10. Electron spin resonance studies of radicals derived from ligated arylboranes (1988) (24)
- Homolytic organometallic reactions. Part II. The kinetics and rate constants for the autoxidation of organoboron compounds in solution (1971) (24)
- A convenient and general preparation of alkyl hydroperoxides and dialkyl peroxides (1977) (24)
- The reaction of N-chlorodimethylamine with tributylborane and with dibutyl(dimethylamino) borane (1970) (23)
- An electron spin resonance study of alkyl radical addition to diethyl vinylphosphonate (1981) (22)
- EPR studies of the additon of 1,1-bis(alkoxycarbonyl)alkyl radicals and tris(ethoxycarbonyl)methyl radicals to alkenes and to alkyl isocyanides (1992) (22)
- Free-radical substitution reactions : bimolecular homolytic substitutions (Sh2 reactions) at saturated multivalent atoms (1971) (22)
- Peroxides of elements other than carbon. Part XII. The autoxidation of optically active 1-phenylethylboronic acid (1967) (22)
- Radical-chain cyclisation of unsaturated acetals and thioacetals in the presence of thiols as polarity-reversal catalysts (1999) (21)
- Radical-chain reductive alkylation of electron-rich alkenes mediated by silanes in the presence of thiols as polarity-reversal catalysts (1999) (21)
- The mechanism of polarity-reversal catalysis as involved in the radical-chain reduction of alkyl halides using the silane–thiol couple (2002) (21)
- Radical-chain redox rearrangement of cyclic benzylidene acetals to benzoate esters in the presence of thiols (2001) (21)
- Homolytic reactions of ligated boranes. Part 3. Electron spin resonance studies of radicals derived from dialkylamine–boranes (1986) (21)
- Radical chain addition to vinyl epoxides catalysed by amine-boranes: Synthesis of allylic alcohols (1992) (20)
- Intramolecular radical-chain hydrosilylation catalysed by thiols: cyclisation of alkenyloxysilanes (1998) (20)
- Homolytic reactions of ligated boranes. Part 4. Electron spin resonance studies of radicals derived from secondary phosphine–boranes (1986) (20)
- Radical-chain deoxygenation of tertiary alcohols, protected as their methoxymethyl (MOM) ethers, using thiols as polarity- reversal catalysts (2000) (19)
- Homolytic organometallic reactions. Part III. An electron spin resonance study of homolytic t-butoxydealkylation of organometallic compounds. Rate constants for the reaction at boron (1971) (18)
- Electron spin resonance study of the fragmentation of some cyclic and acyclic dialkoxyalkyl radicals. The mechanism of 1,2-rearrangement of β-acyloxyalkyl radicals (1975) (18)
- An electron spin resonance study of the electrochemical oxidation of phosphorus(III) compounds (1978) (18)
- Homolytic organometallic reactions. Part VII. An electron spin resonance study of the reaction of t-butoxyl radicals with trialkyl phosphites: kinetics of β-scission of the t-butoxytriethoxyphosphoranyl radical (1972) (18)
- Regioselectivity in the ring-opening β-scission of 2-phenyl-1,3-dioxan-2-yl radicals derived from bicyclic benzylidene acetals (2002) (18)
- An e.s.r. study of amine-boryl radicals (R3N–BH2˙) in solution (1983) (18)
- EPR spectroscopic characterisation of transient organic radicals included in cyclodextrins (1996) (18)
- The electron spin resonance spectra and decarboxylation of alkoxycarbonyl radicals (1972) (17)
- Homolytic reactions of ligated boranes. Part 19. Relationships between structure, reactivity and enantioselectivity for hydrogen-atom abstraction by chiral amine–boryl radicals (1994) (17)
- Electron spin resonance spectra of some phosphonyl radicals and related species (1978) (17)
- An ESR Study of the Oxidation of Triethyl Phosphite by tert-Butoxy Radicals (1971) (17)
- Carbon-13 and proton hyperfine splittings and their variation with temperature for some alkoxyalkyl radicals (1977) (17)
- Mechanism of the reaction of trialkylboranes with α-azidostyrene (1983) (17)
- An electron spin resonance study of phosphine-boryl radicals; their structures and reactions with alkyl halides (1984) (17)
- Deoxygenation of tertiary and secondary alcohols ROH by thiol-catalysed radical-chain redox decomposition of derivatives ROCH2X to give RH and XCHO (2002) (17)
- Radical-chain isomerisation of allyl silyl ethers to silyl enol ethers in the presence of thiols as polarity reversal catalysts (2001) (17)
- Regioselectivity in the ring opening of 2-phenyl-1,3-dioxan-2-yl radicals derived from cyclic benzylidene acetals and comparison with deoxygenation of a carbohydrate diol via its cyclic thionocarbonate (2001) (17)
- Radical-chain reactions of sulfonyl azides and of ethyl azidoformate with allylstannanes: homolytic allylation at nitrogen (1996) (16)
- Carbon-carbon bond formation by radical addition-fragmentation reactions of O-alkylated enols. (2004) (16)
- An electron spin resonance study of the generation and reactions of borane radical anions in solution (1983) (16)
- Rate constants for the formation of oxiranes from .beta.-peroxyalkyl radicals. gem-Dialkyl effect in homolytic ring closure (1974) (16)
- Formation of silanethiols by reaction of silanes with carbonyl sulfide: implications for radical-chain reduction of thiocarbonyl compounds by silanes (2001) (16)
- An E.S.R. study of the structure of phosphorus centred radicals in solution (1973) (16)
- Homolytic reactions of ligated boranes. Part 17. Amine–boranes as polarity reversal catalysts for radical chain reactions of esters with vinylic epoxides and with allylic tert-butyl peroxides (1993) (16)
- Homolytic aldol reactions: thiol-catalysed radical-chain addition of aldehydes to enol esters and to sily enol ethers (1996) (15)
- Bimolecular homolytic substitution by tert-butoxy radicals at metal atoms (1969) (15)
- Enantioselective hydrogen-atom abstraction by optically active amine-boryl radicals: An ESR spectroscopic study (1992) (14)
- Electron spin resonance studies of thiophosphoranyl radicals. The mechanism of ligand permutation in phosphoranyl radicals (1981) (14)
- Homolytic organometallic reactions. Part IV. Homolytic alkylthiyldealkylation of organoboranes (1971) (14)
- EPR studies of the formation and transformation of isomeric radicals [C3H5O]˙. Rearrangement of the allyloxyl radical in non-aqueous solution involving a formal 1,2-hydrogen-atom shift promoted by alcohols (1996) (14)
- An electron spin resonance study of sulphuranyl radicals of the type R2S–SX [X = CF3 or R′C(O)] (1980) (14)
- The effects of β-alkoxy substituents on radical reactions: halogen-atom abstraction from alkyl chlorides (1994) (14)
- Homolytic reactions of ligated boranes. Part 14. ESR studies of ring opening of cycloalkylaminyl–borane radicals and reactions of aminyl–borane radicals with silicon-containing compounds (1990) (14)
- An electron spin resonance study of some sulphonyl radicals in solution (1973) (13)
- Selective radical-chain epimerisation at CH centres α to oxygen under conditions of polarity-reversal catalysis (1999) (13)
- Carboncarbon bond formation by radical addition–fragmentation reactions of O-tert-alkyl enols and O-cyclopropylcarbinyl enols (2003) (13)
- Homolytic organometallic reactions. Part IX. An electron spin resonance study of the mechanism of β-scission of tetra-alkoxyphosphoranyl radicals. Formation of trialkoxy(methyl)phosphoranyl radicals (1972) (13)
- Homolytic displacement at a metal centre by the dimethylamino radical (1970) (13)
- An e.s.r. study of the diborane radical anion in solution (1984) (13)
- Homolytic organometallic reactions. Part VIII. Kinetics of the homolytic reaction between N-halogenosuccinimides and tetra-alkyltins (1972) (12)
- Radical-chain reductive carboxyalkylation of electron-rich alkenes: carbon–carbon bond formation mediated by silanes in the presence of thiols as polarity-reversal catalysts (1998) (12)
- Hydrogen-atom abstraction from dimethylamine in solution: EPR spectroscopic studies and ab initio molecular orbital calculations (1998) (12)
- Bimolecular Homolytic Substitution at a Metal Atom (1971) (12)
- Trialkylsilylaminyl radicals. Part 1. Electron spin resonance studies of the photolysis of silylated hydrazines, hydroxylamines, triazenes, and tetrazenes (1983) (12)
- Electron spin resonance study of iminyl and triazenyl radicals derived from organic azides (1977) (12)
- An electron spin resonance study of the reactions of oxidising radicals with dialkyl sulphides. Radical cations derived from anodic oxidation of R2S, (R2N)2S, and (R2N)2SO (1979) (12)
- Phenylphosphoranyl radicals: are they tetrahedral or trigonal bipyramidal? (1974) (12)
- Long-range proton hyperfine splittings in the epr spectra of cyclohexyl and alkylcyclohexyl radicals: ring inversion in the cyclohexyl radical (1992) (12)
- Radical-chain functionalisation at C–H centres using an O-oxiranylcarbinyl O-silyl ketene acetal (2004) (11)
- Preparation of silanethiols by reaction of silanes with triphenylphosphine sulfide and with alkanethiols (2001) (11)
- Strategy for contra-thermodynamic radical-chain epimerisation of 1,2-diols using polarity-reversal catalysis (2000) (11)
- Homolytic reactions of ligated boranes. Part 18. The scope of enantioselective hydrogen-atom abstraction by chiral amine–boryl radicals for kinetic resolution under conditions of polarity reversal catalysis (1994) (11)
- Amine-boranes as polarity reversal catalysts for radical chain 2,3-epoxypropanation reactions of esters (1992) (11)
- E.s.r. spectra and reactivity of alane radical anions in solution (1981) (10)
- Cyclisation of ω-(isocyanatocarbonyl)alkyl radicals: acyclic precursors of imidyl radicals (1989) (10)
- Laser flash photolysis–electron spin resonance kinetic studies of homolytic reactions in solution (1986) (10)
- RATE CONSTANTS FOR THE FORMATION OF OXIRANES FROM BETA-PEROXYALKYL RADICALS, THE GEM.-DIALKYL EFFECT IN HOMOLYTIC RING CLOSURE (1975) (10)
- Electron spin resonance studies of radicals derived from 1,3,2-benzodioxaboroles (1986) (10)
- The electron spin resonance spectra of alkyl radicals in solution (1969) (10)
- Electrochemical generation of the radical cations [X3PPX3]+ (1975) (10)
- Radical addition to carbenoids. Chain reactions of α-diazo carbonyl compounds with triorganotin hydrides, tris(trimethylsilyl)silane and allyltributylstannane (1996) (10)
- An electron spin resonance study of the structure and reactivity of aminophosphoranyl radicals in solution (1975) (10)
- An ESR study of the reactions of trialkylsiloxyl and trialkylsilyl radicals with dialkyl sulphides (1977) (10)
- Kinetic applications of electron paramagnetic resonance spectroscopy. XII. Self-reactions of some phosphorus centered radicals (1974) (10)
- Homolytic reactions of ligated boranes. Part 5. Spin-trapping and other addition reactions of ligated boryl radicals (1987) (10)
- Photolysis of dialkyl sulphoxylates: formation of alkoxyl and trialkoxysulphuranyl radicals (1976) (10)
- Cyclisation of unsaturated phosphoranyl radicals (1976) (9)
- Homolytic organometallic reactions. Part V. Homolytic bimolecular substitution at boron by the triplet state of ketones (1971) (9)
- Spin-trapping of ligated boryl radicals (1985) (9)
- Addition of silanethiols to aldehydes and ketones: a simple route to homochiral α-siloxyalkanethiols (2001) (9)
- Electron spin resonance studies of the photolysis of trialkylsilyl peroxides (1976) (9)
- EPR spectroscopic studies of N-alkyl-N-trialkylsilylmethylaminyl radicals in solution (1995) (9)
- Enantioselective hydrogen-atom abstraction by homochiral silanethiyl radicals (1995) (9)
- Spirophosphoranyl radicals: Tetra-alkoxyphosphoranyl radicals of remarkable stability towards β-scission (1972) (8)
- Peroxides of elements other than carbon. Part XV. Autoxidation of the epimeric trinorbornylboranes (1969) (8)
- Comments on the structures of phosphoranyl radicals (1983) (8)
- Electron spin resonance studies of the structure and reactivity of some spirophosphoranyl radicals in solution (1973) (8)
- The reaction between azo-compounds and trialkylboranes (1972) (8)
- Homolytic reactions of ligated boranes. Part 6. Electron spin resonance studies of dialkyl sulphide–boryl radicals (1987) (8)
- Peroxides of elements other than carbon. Part XVI. Autoxidation of the epimeric norbornylmagnesium halides (1969) (8)
- An E.S.R. study of the gallane radical anion (1984) (7)
- An ESR study of arsenanyl radicals, As•X4, in solution (1972) (7)
- Enantioselective α-hydrogen-atom abstraction from an ester by an optically active amine-boryl radical (1991) (7)
- Can both cis- and trans-isomers of the 9-decalyl radical be detected in solution by ESR spectroscopy? (1991) (7)
- Radical chain bromination of hydrocarbons using bis(trimethylsilyl)bromamine (1978) (7)
- Homolytic organometallic reactions (1976) (7)
- Homolytic substitution at boron by the triplet state of ketones (1971) (7)
- An electron spin resonance study of radical addition to vinylphosphines (1979) (7)
- Silylaminyl radicals. Part 2. Free radical chain halogenation of hydrocarbons using N-halogenobis(trialkylsilyl)amines (1983) (7)
- A laser flash photolysis study of t-butoxyphosphoranyl radicals. Optical spectra and kinetics of formation, fragmentation, and rearrangement (1981) (6)
- Generation and some reactions of the bis(trimethylsilyl)aminyl radical (1978) (6)
- Thiol-catalysed radical-chain redox rearrangement reactions of benzylidene acetals derived from terpenoid diols. (2003) (6)
- Stereochemical non-rigidity of phosphoranyl radicals: relative ligand apicophilicities (1977) (6)
- Optical resolution and absolute stereochemistry of trans-2,5-dimethyl-1-phenyl-1-silacyclopentane (1995) (6)
- Homolytic organometallic reactions. Part 13. The homolytic reactivity of stannacycloalkanes (1977) (6)
- Organometallic reactions. Part XI. The stereochemistry of the oxidative and hydrolytic cleavage of the 1-phenylethyl–boron bond (1968) (6)
- Homolytic organometallic reactions. Part 14. Homolytic reactivity of β-C–H groups in organotin compounds. An alternative source of trialkyltin radicals (1978) (6)
- The β-sulfur substituent effect in radical reactions. Chlorine-atom abstraction from alkyl 2-chloroethyl sulfides, hydrogen-atom abstraction from dialkyl sulfides and the question of possible 1,4-hydrogen-atom transfer in β-alkylthioethyl radicals (1999) (6)
- The substituent effect of a β-carbon-oxygen bond in radical reactions (1993) (6)
- Formation and electron spin resonance spectra of sulphuranyl radicals of the type [CF3SSR2]˙ (1978) (6)
- Configurational selectivity in the formation of the trimethoxysulphuranyl radical (1977) (6)
- Generation of borane radical anions by photo-induced electron transfer from hydroborate anions (1983) (6)
- Homolytic ring-opening of thietans by oxygen-centred radicals: SH2 attack at sulphur (1976) (5)
- Radical-chain desulfurisation of α-(alkylthiomethyl)acrylates with triphenylphosphine: a new route to α-alkylacrylates (1998) (5)
- EPR and computational studies of the formation and beta-scission of cyclic and acyclic dialkoxyalkyl radicals (2002) (5)
- Polar effects on the addition of alkyl radicals to diethyl vinylphosphonate (1979) (5)
- The reaction of tert-butoxyl radicals with stannic chloride (1972) (5)
- Bimolecular homolytic alkoxydealkylation of organotin compounds (1972) (5)
- Electron spin resonance study of new N-alkoxyphosphoramidyl and N-alkylphosphoramidyl radicals (1980) (5)
- Vicinal alkylation-carboxymethylation of electron-poor alkenes by radical-chain reactions with O-alkyl O-silyl ketene acetals and their [3+2] annulation by reaction with O-cyclopropylcarbinyl O-silyl ketene acetals (2004) (5)
- Electron spin resonance studies of the structures and reactions of trialkoxysilyl radicals (1989) (5)
- An electron spin resonance study of the reactions of alkoxyl and trimethylsiloxyl radicals with dialkyl sulphoxides (1977) (5)
- The bis(trimethylamine)—alanyl radical, (Me3N)2ÅlH2 (1986) (5)
- Hyperconjugation and homoconjugation in alkyl radicals bearing β-phosphorus substituents (1975) (5)
- Radical addition to ethylene sulfite: A trialkoxysulfuranyloxy radical (1977) (5)
- Configurational effects in the α-scission of phosphoranyl radicals (1976) (5)
- Spin-trapping of α-azidoalkyl radicals (1983) (5)
- Homolytic reactions of ligated boranes. Part 16. Enantioselective hydrogen-atom abstraction by chiral amine–boryl radicals: catalytic kinetic resolution of esters and of camphor (1993) (5)
- Liquid xenon as a solvent for e.s.r. studies (1983) (5)
- Homolytic organometallic reactions. Part VI. The reaction of t-butyl hypochlorite with organoboranes. Rate constants for bimolecular t-butoxydealkylation at boron (1972) (4)
- An E.S.R. study of spin-trapping by azodicarboxylates to give hydrazyl radicals (1979) (4)
- Photolysis of di-t-butyl peroxide under acid conditions (1976) (4)
- Absolute rate constants for homolytic alkoxydealkylation at boron (1970) (4)
- The question of isomerization during the alkylation of boron trifluoride etherate with alkylmagnesium halides (1971) (4)
- E.s.r. studies of the bis(triethylsilyl)aminyl radical and trialkylsilyl(t-butyl)aminyl radicals: a reinvestigation (1982) (4)
- An ESR study of the reactions of t-butoxyl radicals with aminophosphines (1972) (4)
- The electron spin resonance spectrum and decarboxylation of the t-butoxycarbonyl-radical in solution (1971) (4)
- Homolytic reactions of ligated boranes. Part 7. An electron spin resonance study of the t-butyl isocyanide–boryl radical (1987) (4)
- The reaction of organoboranes with 2-methyl-2-nitrosopropane and with cis-azobenzene (1971) (4)
- KINETIC APPLICATIONS OF ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY PART 12, SELF-REACTIONS OF SOME PHOSPHORUS CENTERED RADICALS (1974) (4)
- Cyclisation of unsaturated alkoxyphosphoranyl radicals in solution (1974) (3)
- Electron spin resonance studies of radical addition to methylenecycloalkanes (1986) (3)
- Homolytic addition to N-methylene-t-butylamine: a new route to aminyl radicals (1978) (3)
- Memory effects and site selectivity in the β-scission of tetra-alkoxyphosphoranyl radicals (1978) (3)
- Selective Radical‐Chain Epimerization at Electron‐Rich Chiral Tertiary C—H Centers Using Thiols as Protic Polarity‐Reversal Catalysts. (2002) (3)
- An e.s.r. study of some reactions of acylthiyl radicals (1980) (3)
- An electron spin resonance study of fluoroalkoxy- and fluoroalkylphosphoranyl radicals (1977) (3)
- Enantioselective Radical-Chain Hydrosilylation of Prochiral Alkenes Using Optically Active Thiol Catalysts. (1997) (3)
- Site selectivity in the β-scission of alkoxyphosphoranyl radicals. A reinterpretation (1981) (3)
- The autoxidation of optically active 1-phenylethaneboronic acid (1966) (3)
- 3-Bromopropanoyl isocyanate as an acyclic source of the succinimidyl radical (1987) (3)
- Homolytic organometallic reactions. Part XII. An electron spin resonance study of the α-scission of alkoxyalkylphosphoranyl radicals in solution (1974) (3)
- Borylaminyl radicals. N-(9-borabicyclo[3.3.1]nonan-9-yl)-N-t-butylaminyl: a σ-aminyl radical (1985) (3)
- An electron spin resonance study of trialkylsilyl radical addition to alkyl isocyanates (1983) (3)
- Stereochemical non-rigidity of fluorophosphoranyl radicals (1975) (3)
- An electron spin resonance study of the addition of alkoxyl and siloxyl radicals to pyrrolylphosphines (1980) (3)
- Homolytic alkylthiyldealkylation of mixed alkylboranes (1974) (3)
- Silylaminyl radicals. Part 3. Electron spin resonance studies of alkyl(trialkylsilyl)aminyl radicals (1984) (3)
- Homolytic substitution at tin by the succinimidyl radical (1970) (3)
- Polarity‐Reversal Catalysis of Hydrogen‐Atom Abstraction Reactions: Concepts and Applications in Organic Chemistry (1999) (2)
- AN ELECTRON SPIN RESONANCE STUDY OF PHOSPHINE‐BORYL RADICALS: THEIR STRUCTURES AND REACTIONS WITH ALKYL HALIDES (1985) (2)
- Electron spin resonance spectra of selenuranyl radicals R2Se–X (1980) (2)
- Mode of ligand exchange in a cyclic phosphoranyl radical (1979) (2)
- An electron spin resonance study of the photolysis of azide ions in liquid ammonia: formation of imine radical anions in the presence of alkenes (1985) (2)
- Radical-Chain Racemization of Tetrahydrofurfuryl Acetate under Conditions of Polarity-Reversal Catalysis: Possible Implications for the Radical-Induced Strand Cleavage of DNA. (1998) (2)
- THE ELECTRON SPIN RESONANCE SPECTRA AND STRUCTURE OF CHLOROPHOSPHORANYL RADICALS (I) IN SOLUTION (1973) (2)
- An electron spin resonance study of dialkylaminothiyl (R2NS·), dialkylaminosulphinyl (R2NSO), and alkyl(sulphinyl)aminyl [RNS(O)X] radicals. Radical addition to N-sulphinylamines (1978) (2)
- Hydrogen atom transfer to alkenes from aminyl–borane radicals (1988) (2)
- A kinetic study of α- and β-scission of phosphoranyl radicals, RnP(OR)4-n (1972) (2)
- The reaction of 2-methyl-2-nitrosopropane and related species with organoboranes: a ready cis-elimination of alkene from trialkylboranes (1971) (2)
- Electron spin resonance spectra of cyclohexadienyl radicals (1976) (2)
- An e.s.r. study of the triborane(7) radical anion (1983) (2)
- Pseudorotation of trialkoxydimethylaminophosphoranyl radicals in solution (1973) (2)
- Ligand-σ phosphoranyl radicals (1979) (2)
- Electron spin resonance studies of radicals derived from trialkyl phosphorimidates, (RO)3PNR. Phosphazene formation by β-scission of an aminophosphoranyl radical (1979) (2)
- Enantioselective Hydrogen-Atom Abstraction by Homochiral Silanethiyl Radicals. (1995) (1)
- An e.s.r. study of the ring opening of 2-methylaziridine-boryl radicals (1984) (1)
- A PROBE FOR HOMOLYTIC REACTIONS IN SOLUTION PART 8, AN ELECTRON SPIN RESONANCE STUDY OF THE RATES OF FRAGMENTATION AND SPIN TRAPPING OF T-BUTOXYCARBONYL RADICALS AND ACYL RADICALS (1974) (1)
- An e.s.r. study of the generation and reactivity of the borane radical anion (H3B·–) in solution (1981) (1)
- Spin trapping: the rate of addition of t-butoxycarbonyl radicals to 2-methyl-2-nitrosopropane (‘t-nitrosobutane’) (1973) (1)
- Free Radical Chain Reactions for the Preparation of Novel Anomeric Carbohydrate Difluoromethylene-phosphonates and -phosphonothioates. (1998) (1)
- Homolytic Reactions of Ligated Boranes. Part 8. Electron Spin Resonance Studies of Radicals Derived from Ligated Alkylboranes. (1988) (1)
- Preparation of Some New Anomeric Carbohydrate Difluoromethylenephoshonates via Phosphonyl Radical Addition to gem- Difluoroenol Ethers. (1996) (1)
- Radical‐Chain Addition of Aldehydes to Alkenes Catalyzed by Thiols. (1998) (1)
- AN ELECTRON SPIN RESONANCE STUDY OF PHOSPHORANYL RADICALS DERIVED FROM TETRA‐ALKYL ESTERS OF PHOSPHOROUS PHOSPHORIC ANHYDRIDE (RO)2POP(O)(OR)2 (1976) (1)
- CHEMISTRY OF PHOSPHORANYL RADICALS (1981) (1)
- The electronic configuration of 1,3-dialkyltriazenyl radicals (1981) (1)
- The electron spin resonance spectra and structure of chlorophosphoranyl radicals in solution (1973) (1)
- 1,3-Dialkyltriazenyl radicals: their electron spin resonance spectra. Electronic configuration, and addition to trialkyl phosphites (1982) (1)
- Carbohydrate‐Derived Thiols as Protic Polarity‐Reversal Catalysts for Enantioselective Radical‐Chain Reactions. (2002) (1)
- Thiol-catalysed Radical-chain Reduction of Organic Halides by Hexabutylditin in the Presence of Malonic Acid† (1998) (1)
- STEREOCHEMICAL NON-RIGIDITY OF PHOSPHORANYL RADICALS- RELATIVE LIGAND APICOPHILICITIES (1977) (0)
- Homolytic Reactions of Ligated Boranes. Part 7. An ESR Study of the t-Butyl Isocyanide-Boryl Radical (1988) (0)
- Homolytic Reactions of Ligated Boranes. Part 16. Enantioselective Hydrogenatom Abstraction by Chiral Amine‐Boryl Radicals: Catalytic Kinetic Resolution of Esters and of Camphor. (1993) (0)
- Amine‐Boranes as Polarity Reversal Catalysts for Radical Chain 2,3‐ Epoxypropanation Reactions of Esters. (1993) (0)
- Homolytic Reactions of Ligated Boranes. Part 19. Relationships Between Structure, Reactivity and Enantioselectivity for Hydrogen‐Atom Abstraction by Chiral Amine‐Boryl Radicals. (1994) (0)
- PHOTOLYSIS OF DIALKYL SULFOXYLATES- FORMATION OF ALKOXYL AND TRIALKOXYSULFURANYL RADICALS (1977) (0)
- ELECTRON SPIN RESONANCE STUDIES OF RADICALS DERIVED FROM TRIALKYL PHOSPHORIMIDATES, (RO)3P:NR. PHOSPHAZENE FORMATION BY β-SCISSION OF AN AMINOPHOSPHORANYL RADICAL (1979) (0)
- The homolytic reactivity of stannacyclopentanes (1976) (0)
- PHOTOLYSIS OF DI-TERT-BUTYL PEROXIDE UNDER ACID CONDITIONS (1977) (0)
- Homolytic Reactions of Ligated Boranes. Part 17. Amine-Boranes as Polarity Reversal Catalysts for Radical Chain Reactions of Esters with Vinylic Epoxides and with Allylic tert-Butyl Peroxides. (1993) (0)
- 1,3-DIALKYLTRIAZENYL RADICALS: THEIR ELECTRON SPIN RESONANCE SPECTRA, ELECTRONIC CONFIGURATION, AND ADDITION TO TRIALKYL PHOSPHITES (1983) (0)
- Homolytic Reactions of Ligated Boranes. Part 9. Overall Addition of Alkanes to Electron-Deficient Alkenes by a Radical Chain Mechanism. (1988) (0)
- The Bis(trimethylamine)-Alanyl Radical, (Me3N)2H2Al·. (1987) (0)
- Radical‐Chain Isomerization of Allyl Silyl Ethers to Silyl Enol Ethers in the Presence of Thiols as Polarity Reversal Catalysts. (2010) (0)
- Radical Addition to Carbenoids. Chain Reactions of α-Diazo Carbonyl Compounds with Triorganotin Hydrides, Tris(trimethylsilyl) silane and Allyltributylstannane. (1996) (0)
- Enantioselective Radical-Chain Hydrosilylation of Alkenes Using Homochiral Thiols as Polarity-Reversal Catalysts. (1999) (0)
- Laser Flash Photolysis - ESR Kinetic Studies of Homolytic Reactions in Solution. (1986) (0)
- Deoxygenation of Alcohols by the Reactions of Their Xanthate Esters with Triethylsilane: An Alternative to Tributyltin Hydride in the Barton‐McCombie Reaction. (1992) (0)
- Memory effects in the oxidation of trialkyl phosphites by alkoxyl radicals (1975) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF SULFURANYL RADICALS OF THE TYPE R2S-SX (X = CF3 OR R′C(O)) (1981) (0)
- Radical-Chain Reductive Carboxyalkylation of Electron-Rich Alkenes: Carbon—Carbon Bond Formation Mediated by Silanes in the Presence of Thiols as Polarity-Reversal Catalysts. (1998) (0)
- The Chemistry of Phosphoranyl Radicals (1984) (0)
- Carbon—Carbon Bond Formation by Radical Addition—Fragmentation Reactions of O-Alkylated Enols. (2005) (0)
- A LASER FLASH PHOTOLYSIS STUDY OF TERT-BUTOXYPHOSPHORANYL RADICALS. OPTICAL SPECTRA AND KINETICS OF FORMATION, FRAGMENTATION, AND REARRANGEMENT (1981) (0)
- HOMOLYTIC ORGANOMETALLIC REACTIONS. PART 14. HOMOLYTIC REACTIVITY OF β-CH GROUPS IN ORGANOTIN COMPOUNDS. AN ALTERNATIVE SOURCE OF TRIALKYLTIN RADICALS (1978) (0)
- Thiols as Polarity Reversal Catalysts for Hydrogen-Atom Transfer from Organosilanes to Alkyl Radicals: Reduction of Alkyl Halides by Triethylsilane. (1990) (0)
- Electron Spin Resonance Studies of the Structures and Reactions of Trialkoxysilyl Radicals. (1989) (0)
- Homolytic Reactions of Ligated Boranes. Part 4. ESR Studies of Radicals Derived from Secondary Phosphine-Boranes (1987) (0)
- Homolytic Reactions of Ligated Boranes. Part 12. Amine-Alkylboranes as Polarity Reversal Catalysts for Hydrogen-Atom Abstraction by tert.-Butoxyl Radicals. (1990) (0)
- EPR Studies of the Addition of 1,1‐Bis(alkoxycarbonyl)alkyl Radicals and Tris(ethoxycarbonyl)methyl Radicals to Alkenes and to Alkyl Isocyanides. (1993) (0)
- The Effects of β‐Alkoxy Substituents on Radical Reactions: Halogen Atom Abstraction from Alkyl Chlorides. (1995) (0)
- Homolytic Aldol Reactions: Thiol-Catalyzed Radical-Chain Addition of Aldehydes to Enol Esters and to Silyl Enol Ethers. (1997) (0)
- Radical Chain Reduction of Alkyl Halides, Dialkyl Sulfides and O-Alkyl S-Methyl Dithiocarbonates to Alkanes by Trialkylsilanes. (2010) (0)
- Carbon—Carbon Bond Formation by Radical Addition—Fragmentation Reactions of O‐tert‐Alkyl Enols and O‐Cyclopropylcarbinyl Enols. (2003) (0)
- Homolytic Reactions of Ligated Boranes. Part 10. ESR Studies of Radicals Derived from Ligated Arylboranes (1989) (0)
- ELECTRON SPIN RESONANCE STUDIES OF THE STRUCTURE AND REACTIVITY OF SOME SPIROPHOSPORANYL RADICALS IN SOLUTION (1973) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF THE REACTIONS OF OXIDIZING RADICALS WITH DIALKYL SULFIDES. RADICAL CATIONS DERIVED FROM ANODIC OXIDATION OF R2S, (R2N)2S, AND (R2N)2SO (1980) (0)
- Homolytic Reactions of Ligated Boranes. Part 3. ESR Studies of Radicals Derived from Dialkylamine-Boranes (1987) (0)
- ELECTRON SPIN RESONANCE STUDY OF THE FRAGMENTATION OF SOME CYCLIC AND ACYCLIC DIALKOXYALKYL RADICALS, THE MECHANISM OF 1,2-REARRANGEMENT OF BETA-ACYLOXYALKYL RADICALS (1975) (0)
- Enantioselective α-Hydrogenatom Abstraction from an Ester by an Optically Active Amine-Boryl Radical. (2010) (0)
- SILYLAMINYL RADICALS. PART 2. FREE RADICAL CHAIN HALOGENATION OF HYDROCARBONS S USING N-HALOBIS(TRIALKYLSILYL)AMINES (1983) (0)
- Ligated Boryl Radicals. Part 2. ESR Studies of Trialkylamine-Boryl Radicals. (1986) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF THE REACTIONS OF ALKOXYL AND TRIMETHYLSILOXYL RADICALS WITH DIALKYL SULFOXIDES (1978) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF DIALKYLAMINOTHIYL (R2NS·), DIALKYLAMINOSULFINYL (R2N(O)S·), AND ALKYL(SULFINYL)AMINYL (·NRS(O)X) RADICALS. RADICAL ADDITION TO N-SULFINYLAMINES (1978) (0)
- Enantioselective Hydrogen‐Atom Abstraction by Optically Active Amine‐ Boryl Radicals: An ESR Spectroscopic Study. (1993) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF FLUOROAKOXY- AND FLUOROALKYLPHOSPHORANYL RADICALS (1977) (0)
- E.s.r. studies of N-alkyl-N-dialkylborylaminyl radicals in solution (1986) (0)
- Polarity Reversal Catalysis of Hydrogen Atom Abstraction Reactions in Solution (1988) (0)
- Optical Resolution and Absolute Stereochemistry of trans-2,5-Dimethyl- 1-phenyl-1-silacyclopentane. (1995) (0)
- HOMOLYTIC ORGANOMETALLIC REACTIONS PART 12, AN ELECTRON SPIN RESONANCE STUDY OF THE ALPHA-SCISSION OF ALKOXYALKYLPHOSPHORANYL RADICALS IN SOLUTION (1974) (0)
- Ligated boryl radicals. II: Electron spin resonance studies of trialkylamine−boryl radicals (1985) (0)
- Addition of Organosilyl Radicals to Carbon Dioxide: An Electron Spin Resonance Study. (1990) (0)
- Formation of Silanethiols by Reaction of Silanes with Carbonyl Sulfide: Implications for Radical-Chain Reduction of Thiocarbonyl Compounds by Silanes. (2001) (0)
- Homolytic Reactions of Ligated Boranes. Part 14. ESR Studies of Ring Opening of Cycloalkylaminyl-Borane Radicals and Reactions of Aminyl-Borane Radicals with Silicon-Containing Compounds. (1990) (0)
- Preparation of Silanethiols by Reaction of Silanes with Triphenylphosphine Sulfide and with Alkanethiols. (2001) (0)
- Polarity reversal catalysis of radical reactions: hydrogen-atom abstraction from cyclopentadiene and from cycloheptatriene (1989) (0)
- Electron spin resonance studies of the ammonia-boryl radical (H3N→BH2);an inorganic analogue of the ethyl radical (1985) (0)
- AN ELECTRON SPIN RESONANCE STUDY OF RADICAL ADDITION TO BIS(TRIMETHYLSILYL)AMINO(TRIMETHYLSILYLIMINO)PHOSPHINE, (ME3SI)2NP:NSIME3 (1981) (0)
- Single-Crystal 55 Mn NMR Spectra of Two Mn 12 Single-Molecule Magnets (2005) (0)
- Homolytic Reactions of Ligated Boranes. Part 6. ESR Studies of Dialkyl Sulfide-Boryl Radicals. (1987) (0)
- Homolytic Reactions of Ligated Boranes. Part 13. An ESR Study of Radical Addition to Aminoboranes. (1990) (0)
- Radical‐Chain Desulfurization of α‐(Alkylthiomethyl)acrylates with Triphenylphosphine: A New Route to α‐Alkylacrylates. (1998) (0)
- Strategy for Contra‐Thermodynamic Radical‐Chain Epimerization of 1,2‐Diols Using Polarity‐Reversal Catalysis. (2001) (0)
- Deoxygenation of Tertiary and Secondary Alcohols ROH by Thiol‐Catalyzed Radical‐Chain Redox Decomposition of Derivatives ROCH2X to Give RH and XCHO. (2010) (0)
- Radical-Chain Functionalization at C—H Centers Using an O-Oxiranylcarbinyl O-Silyl Ketene Acetal. (2004) (0)
- Absolute rate coefficients of β-scission of amine-boryl radicals in solution (1986) (0)
- Pseudo-rotation of spin-labelled phosphoranes formed by cyclisation of triazenylphosphoranyl radicals (1981) (0)
- Intramolecular Radical-Chain Hydrosilylation Catalyzed by Thiols: Cyclization of Alkenyloxysilanes. (1998) (0)
- Addition of Silanethiols to Aldehydes and Ketones: A Simple Route to Homochiral α-Siloxyalkanethiols. (2010) (0)
- The pronounced differences in reactivity of perfluoro-t-butoxyl and t-butoxyl radicals (1974) (0)
- HOMOLYTIC RING-OPENING OF THIETANES BY OXYGEN-CENTERED RADICALS- SH2 ATTACK AT SULFUR (1976) (0)
- Long‐Range Proton Hyperfine Splittings in the EPR Spectra of Cyclohexyl and Alkylcyclohexyl Radicals: Ring Inversion in the Cyclohexyl Radical. (1993) (0)
- An ESR Study of the Photolysis of Azide Ions in Liquid Ammonia: Formation of Imine Radical Anions in the Presence of Alkenes. (1986) (0)
- Thiol-Catalyzed Radical-Chain Reduction of Organic Halides by Hexabutylditin in the Presence of Malonic Acid. (1999) (0)
- Radical-Chain Deoxygenation of Tertiary Alcohols, Protected as Their Methoxymethyl (MOM) Ethers, Using Thiols as Polarity-Reversal Catalysts. (2000) (0)
- An electron spin resonance study of phosphoranyl radicals derived from tetra-alkyl esters of phosphorous phosphoric anhydride (RO)2POP(O)(OR)2 (1976) (0)
- Polarity‐Reversal Catalysis by Thiols of Radical‐Chain Hydrosilylation of Alkenes. (1995) (0)
- Regioselectivity in the Ring-Opening β-Scission of 2-Phenyl-1,3-dioxan-2-yl Radicals Derived from Bicyclic Benzylidene Acetals. (2003) (0)
- Radical Chain Addition to Vinyl Epoxides Catalyzed by Amine-Boranes: Synthesis of Allylic Alcohols. (2010) (0)
- ESR Studies of Radicals Derived from 1,3,2-Benzodioxaboroles. (1986) (0)
- Radical-Chain Reductive Alkylation of Electron-Rich Alkenes Mediated by Silanes in the Presence of Thiols as Polarity-Reversal Catalysts. (2010) (0)
- Cyclization of ω-(Isocyanatocarbonyl)alkyl Radicals; Acyclic Precursors of Imidyl Radicals. (1990) (0)
- An electron spin resonance study of radical addition to bis(trimethylsilyl)amino(trimethylsilylimino)phosphine, (Me3Si)2NPNSiMe3 (1981) (0)
- Radical‐Chain Cyclization of Unsaturated Acetals and Thioacetals in the Presence of Thiols as Polarity‐Reversal Catalysts. (2000) (0)
- ESR Studies of Radical Addition to Methylenecycloalkanes. (1986) (0)
- CYCLIZATION OF UNSATURATED PHOSPHORANYL RADICALS (1976) (0)
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