Carlos Andrés Osorio Murillo
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Carlos Andrés Osorio Murillochemistry Degrees
Chemistry
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Inorganic Chemistry
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Chemistry
Carlos Andrés Osorio Murillo's Degrees
- PhD Chemistry Stanford University
- Masters Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Carlos Andrés Osorio Murillo Influential?
(Suggest an Edit or Addition)Carlos Andrés Osorio Murillo's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Multiple bonds between metal atoms (1982) (1320)
- Supramolecular arrays based on dimetal building units. (2001) (637)
- Square and Triangular Arrays Based on Mo24+ and Rh24+ Units (1999) (133)
- The use of dimetal building blocks in convergent syntheses of large arrays (2002) (112)
- Vibrational excitations in single trimetal-molecule transistors. (2005) (106)
- Non-trivial behavior of palladium(II) acetate. (2005) (102)
- Molecular and electronic structures by design: tuning symmetrical and unsymmetrical linear trichromium chains. (2004) (99)
- SYMMETRICAL AND UNSYMMETRICAL COMPOUNDS HAVING A LINEAR CO36+ CHAIN LIGATED BY A SPIRAL SET OF DIPYRIDYL ANIONS (1997) (99)
- Linear tricobalt compounds with Di-(2-pyridyl)amide (dpa) ligands : temperature dependence of the structural and magnetic properties of symmetrical and unsymmetrical forms of Co{sub 3}(dpa){sub 4}Cl{sub 2} in the solid state. (2000) (98)
- A trinickel dipyridylamido complex with metal-metal bonding interaction: prelude to polynickel molecular wires and devices? (2002) (92)
- FURTHER STUDY OF THE LINEAR TRINICKEL(II) COMPLEX OF DIPYRIDYLAMIDE (1999) (91)
- The simplest supramolecular complexes containing pairs of Mo(2)(formamidinate)(3) units linked with various dicarboxylates: preparative methods, structures, and electrochemistry. (2001) (89)
- Closed-Shell Molecules That Ionize More Readily Than Cesium (2002) (89)
- Additional steps toward molecular scale wires: Further study of Ni(5)(10/11+) chains embraced by polypyridylamide ligands. (2003) (83)
- Oxidation of Ni3(dpa)4Cl2 and Cu3(dpa)4Cl2: nickel-nickel bonding interaction, but no copper-copper bonds. (2003) (82)
- Synthesis and characterization of four vanadium(II) compounds, including vanadium(II) sulfate hexahydrate and vanadium(II) saccharinates (1986) (80)
- Supramolecular squares with Mo2(4+) corners. (2001) (78)
- Hexaaqua dipositive ions of the first transition series: new and accurate structures; expected and unexpected trends (1993) (77)
- High yield syntheses of stable, singly bonded Pd2(6+) compounds. (2006) (75)
- Polyunsaturated dicarboxylate tethers connecting dimolybdenum redox and chromophoric centers: syntheses, structures, and electrochemistry. (2003) (74)
- Modifying electronic communication in dimolybdenum units by linkage isomers of bridged oxamidate dianions. (2003) (71)
- Comparative study of structures, including Jahn-Teller effects, in the saccharinate complexes, [M(C7H4NO3S)2(H2O)4]•2H2O, of chromium and zinc, as well as other divalent metal ions (1984) (68)
- The molybdenum-molybdenum triple bond. 2. Hexakis(alkoxy)dimolybdenum compounds: preparation, properties and structural characterization of hexakis(neopentoxy)dimolybdenum (1977) (66)
- Molecular squares with paramagnetic diruthenium corners: synthetic and crystallographic challenges. (2003) (65)
- The designed ‘self-assembly’ of a three-dimensional molecule containing six quadruply-bonded Mo24+ units (1999) (63)
- A Calix[4]arene Carceplex with Four Rh24+ Fasteners (2004) (62)
- Modeling spin interactions in a cyclic trimer and a cuboidal Co4O4 core with Co(II) in tetrahedral and octahedral environments. (2005) (61)
- A neutral triangular supramolecule formed by Mo2(4+) units. (2001) (60)
- Linear trichromium complexes with direct Cr to Cr contacts. 1. Compounds with Cr3(dipyridylamide)4(2+) cores. (2000) (58)
- THE CRYSTAL PACKING OF BIS(2,2'-DIPYRIDYLAMIDO)COBALT(II), CO(DPA)2, IS STABILIZED BY C-H...N BONDS: ARE THERE ANY REAL PRECEDENTS? (1997) (58)
- Further structural and magnetic studies of tricopper dipyridylamido complexes. (2003) (54)
- The extraordinary ability of guanidinate derivatives to stabilize higher oxidation numbers in dimetal units by modification of redox potentials: structures of Mo(2)(5+) and Mo(2)(6+) compounds. (2002) (53)
- New linear tricobalt complex of di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2][PF6]2. (2000) (53)
- Transition metal (Mn, Co) and zinc formamidinate compounds having the basic beryllium acetate structure, and unique isomeric iron compounds (1997) (53)
- The lengths of molybdenum to molybdenum quadruple bonds: correlations, explanations, and corrections. (2002) (53)
- Supramolecular squares with Rh24+ corners (2001) (52)
- A systematic approach in the preparation of compounds with .sigma.2.pi.4 vanadium-to-vanadium triple bonds: synthesis, reactivity, and structural characterization (1993) (51)
- Triply Bonded Nb24+ Tetragonal Lantern Compounds: Some Accompanied by Novel B−H···Na+ Interactions (1998) (51)
- The first dirhodium tetracarboxylate molecule without axial ligation: new insight into the electronic structures of molecules with importance in catalysis and other reactions. (2002) (49)
- Highly distorted diiron(II, II) complexes containing four amidinate ligands. A long and short metal-metal distance (1997) (49)
- A Trinuclear EMAC-Type Molecular Wire with Redox-Active Ferrocenylacetylide “Alligator Clips” Attached (2004) (48)
- Structural studies of formamidine compounds: from neutral to anionic and cationic species (1997) (48)
- Four compounds containing oxo-centered trivanadium cores surrounded by six .mu.,.eta.2-carboxylato groups (1986) (47)
- Compounds with symmetrical tricobalt chains wrapped by dipyridylamide ligands and cyanide or isothiocyanate ions as terminal ligands. (2001) (47)
- Trigonal-lantern dinuclear compounds of diiron(I,II): the synthesis and characterization of two highly paramagnetic Fe2(amidinato)3 species with short metal-metal bonds ☆ (1997) (47)
- A New Type of Divalent Niobium Compound: The First Nb−Nb Triple Bond in a Tetragonal Lantern Environment (1997) (47)
- Tuning the metal-metal bonds in the linear tricobalt compound Co3(dpa)(4)Cl2: bond-stretch and spin-state isomers. (2001) (47)
- Connecting pairs of dimetal units to form molecular loops. (2001) (47)
- Making connections with molecular wires: extending tri-nickel chains with axial cyanide, dicyanamide, and phenylacetylide ligands (2003) (46)
- Reactions of metal-to-metal multiple bonds. 1. .mu.-Allene-bis(cyclopentadienyl)tetracarbonyldimolybdenum and -ditungsten compounds. Preparation, properties, and structural characterization (1978) (46)
- Chiral organometallic triangles with Rh-Rh bonds. 2. Compounds prepared from enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and their catalytic potentials. (2005) (45)
- Enhancing the stability of trinickel molecular wires and switches: Ni(3)(6+)/Ni(3)(7+). (2003) (44)
- Remarkable Effects of Axial π* Coordination on the Cr−Cr Quadruple Bond in Dichromium Paddlewheel Complexes (1999) (44)
- Polyunsaturated dicarboxylate tethers connecting dimolybdenum redox and chromophoric centers: absorption spectra and electronic structures. (2003) (44)
- The exceptional structural versatility of 2,2′-dipyridylamine (Hdpa) and its ions [dpa]− and [H2dpa]+ (1998) (44)
- The exceptional structural versatility of 2,2′-dipyridylamine (Hdpa) and its ions [dpa]− and [H2dpa]+ (1998) (44)
- Linear tri- and tetra-chromium(II) chains supported by four bis(2-pyridyl)formamidinium ligands (1998) (44)
- Expeditious access to the most easily ionized closed-shell molecule, W2(hpp)4. (2005) (43)
- Filling a void: isolation and characterization of tetracarboxylato dimolybdenum cations. (2002) (43)
- An Efficient Reduction Process Leading to Titanium(II) and Niobium(II): Preparation and Structural Characterization of trans-MCl2(py)4 Compounds, M = Ti, Nb, and Mn (1995) (42)
- Structure and magnetism of [M3](6/7+) metal chain complexes from density functional theory: analysis for copper and predictions for silver. (2006) (42)
- A fractional bond order of 1/2 in Pd(2)(5+)--formamidinate species; the value of very high-field EPR spectra. (2007) (41)
- An efficient synthesis of acetylide/trimetal/acetylide molecular wires. (2004) (40)
- From end-on coordination of acetonitrilemoleculestocrosswise bridging ; formation ofiminophosphinoandacetamidate ligands in adimolybdenum complex byfurther reactions withnucleophiles fn2 fn2 Dedicatedto Lord Lewis on theoccasion of his 70th birthday. (1998) (39)
- Dynamic equilibrium between cyclic oligomers. Thermodynamic and structural characterization of a square and a triangle. (2006) (39)
- Chiral organometallic triangles with Rh-Rh bonds. 1. Compounds prepared from racemic cis-Rh2(C6H4PPh2)2(OAc)2. (2004) (39)
- Di- and trinuclear complexes with the mono- and dianion of 2,6-bis(phenylamino)pyridine: high-field displacement of chemical shifts due to the magnetic anisotropy of quadruple bonds. (2001) (39)
- Structural and Magnetic Evidence Concerning Spin Crossover in Formamidinate Compounds with Ru25+ Cores (2005) (39)
- A new class of dinuclear compounds: The synthesis and x-ray structural characterization of tris(μ-diphenyl-formamidinato) diiron (1994) (39)
- Extended metal atom chains (EMACs) of five chromium or cobalt atoms: symmetrical or unsymmetrical? (2004) (38)
- Homologues of the easily ionized compound Mo2(hpp)4 containing smaller bicyclic guanidinates. (2006) (38)
- Metal-metal bonding in mixed valence Ni2(5+) complexes and spectroscopic evidence for a Ni2(6+) species. (2006) (37)
- Searching for precursors to metal-metal bonded dipalladium species: a study of Pd2(4+) complexes. (2005) (37)
- Divalent metal chloride amidine complexes—2. Compounds of Mn, Co and Ni (1997) (36)
- Neutral dodecanuclear supramolecular complexes containing dimetal units linked by the trimesate anion. (2001) (36)
- Completion of the series of M2(hpp)4Cl2 compounds from W to Pt: the W, Os, and Pt compounds. (2000) (35)
- Structure of tetraphenylarsonium tetrachloroferrate(III) (1975) (35)
- New chemistry of the triply bonded divanadium (V2 4+) unit and reduction to an unprecedented V2 3+ core. (2003) (35)
- Proof of large positive zero-field splitting in a Ru2 5+ paddlewheel. (2005) (34)
- Uniquely strong electronic communication between [Mo2] units linked by dioxolene dianions. (2006) (33)
- Supramolecular structures based on dimetal units: simultaneous utilization of equatorial and axial connections (2001) (33)
- Facilitating access to the most easily ionized molecule: an improved synthesis of the key intermediate, W2(hpp)4Cl2, and related compounds. (2006) (32)
- Synthesis and Structural Studies of Platinum Complexes Containing Monodentate, Bridging, and Chelating Formamidine Ligands. (1996) (32)
- Cyclic polyamidato dianions as bridges between Mo(2)(4+) units: synthesis, crystal structures, electrochemistry, absorption spectra, and electronic structures. (2003) (32)
- Divalent metal chloride formamidine complexes, M11 = Fe, Co and Pt. syntheses and structural characterization (1994) (31)
- The First Complex with a σ2π4 Triple Bond between Vanadium Atoms in a Ligand Framework of Fourfold Symmetry—[V2{(p‐CH3C6H4)NC(H)N(p‐C6H4CH3)}4] (1992) (31)
- Systematic preparation of Mo 2 4+ building blocks for supramolecular assemblies. (2004) (30)
- A chain of five chromium(II) atoms: a desired compound with an undesired, unsurprising, but important structure (1999) (30)
- Tuning metal-to-metal distances in linear trichromium units (1998) (29)
- Tuning metal-to-metal distances in linear trichromium units (1998) (29)
- The first dirhodium-based supramolecular assemblies with interlocking lattices and double helices (2001) (29)
- Paramagnetic precursors for supramolecular assemblies: selective syntheses, crystal structures, and electrochemical and magnetic properties of Ru2(O2CMe)4-n(formamidinate)nCl complexes, n = 1-4. (2004) (29)
- Bonding implications of the resistance of dimolybdenum(II) to attach axial ligands. Structures of two polypyrazolylborate complexes (1976) (28)
- The First Structurally Confirmed Paddlewheel Compound with an M27+ Core: [Os2(hpp)4Cl2](PF6) (2003) (28)
- REACTIONS OF TICL4 WITH PHOSPHINES AND ALKYLATING REAGENTS : AN ORGANOMETALLIC ROUTE TO A TITANIUM(II) CLUSTER COMPOUND (1999) (28)
- Maximum communication between coupled oxidations of dimetal units. (2001) (28)
- Linear Tricobalt Compounds with Di-(2-pyridyl)amide (dpa) Ligands: Studies of the Paramagnetic Compound Co(3)(dpa)(4)Cl(2) in Solution. (1999) (28)
- Dinuclear and heteropolynuclear complexes containing Mo2(4+) units. (2001) (27)
- Effects of weak intermolecular interactions on the molecular isomerism of tricobalt metal chains. (2009) (27)
- Divalent iron formamidinato complexes: a highly distorted dinuclear compound (1994) (27)
- Dicarboxylato-bridged diruthenium units in two different oxidation states: The first step towards the synthesis of Creutz-Taube analogs with dinuclear Ru2n+ species (2004) (27)
- Increasing solubility and stability of linear tricobalt(II) chains with depa (diethyldipyridylamide) ligands. (2003) (27)
- Resolving conformational ambiguities in M2(hpp)4Cl2 paddlewheel compounds: M=Mo, W, Re, Ru, Os, Ir, Pd, Pt (2003) (27)
- Exceptionally strong electronic coupling between [Mo2] units linked by substituted dianionic quinones. (2008) (26)
- Dimolybdenum-containing molecular triangles and squares with diamidate linkers: structural diversity and complexity. (2006) (26)
- Chromium(II) complexes bearing 2-substituted N,N′-diarylformamidinate ligands (2000) (26)
- Can crystal structure determine molecular structure? For Co3(dpa)4Cl2, yes (1999) (26)
- A hardwon dirhodium paddlewheel with guanidinate type (hpp) bridging ligands. (2005) (26)
- Coupling Mo2n+ units via dicarboxylate bridges (1998) (26)
- How small variations in crystal interactions affect macroscopic properties. (2007) (26)
- Linear trichromium complexes with the anion of 2,6-di(phenylimino)piperidine. (2000) (25)
- Mononuclear-dinuclear equilibrium for the pyridine adducts of chromium(II) saccharinates (1992) (25)
- Two chromium(II) complexes with amidato-like ligands: a compound with the longest CrCr bond and a mononuclear compound with D2d symmetry (1991) (24)
- Completion of the series of Pt2 (ArNC(H)NAr)4n, n = 0, +1, +2, compounds, with PtPt sigma bond orders of , respectively (1997) (24)
- Dinuclear TiIV and TiIII complexes supported by calix[4]arene ligands. Binding alkali-metal cations inside and outside the cavity of calix[4]arenes (2002) (24)
- Fitting the pieces of the puzzle: the δ bond. (2014) (24)
- Strong electronic coupling between dimolybdenum units linked by the N,N'-dimethyloxamidate anion in a molecule having a heteronaphthalene-like structure. (2004) (24)
- Structural variations in the ligands around a simple oxo-centered building block, the tetrahedral [M4O]6+ unit, M=Mn and Fe (2000) (24)
- Transition metal complexes with amidinato ligands: the ubiquitous tris-chelated structural motif☆ (1996) (24)
- The Tungsten-to-Tungsten Triple Bond. 7. Replacement of Dimethylamido by Chloro Groups in Hexakis (dimethylamido)ditungsten and -dimolybdenum Compounds; the Preparation, Properties and Structure of Dichlorotetrakis-(dimethylamido)ditungsten and -dimolybdenum. (1977) (24)
- Quadridentate bridging EO(4)(2-) (E = S, Mo, W) ligands and their role as electronic bridges. (2001) (24)
- Strong electronic interaction between two dimolybdenum units linked by a tetraazatetracene. (2006) (23)
- Compounds in which the Mo24+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands (1999) (23)
- Bis(pyrazolylborato)allyldicarbonylmolybdenum complex with a 16-electron configuration (1975) (23)
- Quadruply Bonded Dichromium Complexes with Variously Fluorinated Formamidinate Ligands. (1999) (23)
- The first designed syntheses of bis-dimetal molecules in which the bridges are diamidate ligands. (2002) (23)
- Getting the right answer to a key question concerning molecular wires (1999) (23)
- Modulating Electronic Coupling Using O- and S-donor Linkers. (2007) (22)
- PREPARATION AND STRUCTURE OF CRYSTALLINE TETRAKIS(D-MANDELATO)DIMOLYBDENUM(II) BIS(TETRAHYDROFURANATE) (1983) (22)
- A diamagnetic dititanium(III) paddlewheel complex with no direct metal-metal bond. (2006) (22)
- Dicobalt trigonal lanterns: compounds containing the Co23+ core Co2[RC(NPh)2]3 (R H, C6H5) and an oxidized compound {Co2[HC(NPh)2]3(CH3CN)2}PF6 (1997) (22)
- Paramagnetism at ambient temperature, diamagnetism at low temperature in a Ru2(6+) core: structural evidence for zero-field splitting. (2004) (22)
- Fully localized mixed-valence oxidation products of molecules containing two linked dimolybdenum units: an effective structural criterion. (2003) (22)
- Strong reducing agents containing dimolybdenum Mo2(4+) units and their oxidized cations with Mo2(5+/6+) cores stabilized by bicyclic guanidinate anions with a seven-membered ring. (2006) (22)
- Bis(N,N′-diphenylformamidine)silver(I) triflate: a three-coordinate silver formamidine compound stabilized by intramolecular hydrogen bonds (1997) (22)
- Metal-assisted unorthodox reactions of formamidines: coupling, cleavage and insertions (1997) (21)
- Steps on the way to the first dirhodium tetracarboxylate with no axial ligation: synthetic lessons and a plethora of Rh2(O2CR)4L2−n compounds, n=0, 1, 2 (2002) (21)
- Tri-bridged amidinato compounds of dicobalt 1: Co2[PhNC(R)NPh]3 with R H and C6H5 (1996) (21)
- Better understanding of the species with the shortest Re2(6+) bonds and related Re2)(7+) species with tetraguanidinate paddlewheel structures. (2007) (21)
- New .sigma.-ethyl compounds of dimolybdenum (M.tplbond.M) and evidence for dinuclear reductive elimination with a concomitant metal-metal triple to quadruple bond transformation: Et-M.tplbond.M-Et .fwdarw. M::M + C2H4 + C2H6 (1978) (21)
- Electronic structure of dinuclear trigonal-lantern amidinato compounds of iron and cobalt☆ (1997) (20)
- Chiral Molecules Containing Metal–Metal Bonds (2006) (20)
- Mono-, di-, and tri-ruthenium complexes with the ligand 2,2′-dipyridylamide (dpa): insights into the formation of extended metal atom chains (2004) (20)
- .mu.-Allene-bis(cyclopentadienyl)tetracarbonyldimolybdenum; a bridging allene ligand (1977) (20)
- A refinement of the crystal structure of tetraphenylmethane: three independent redeterminations (1975) (20)
- Structural and magnetic properties of Co3(dpa)4Br2 (2001) (19)
- Tetranuclear Complexes Containing Quadruply Bonded Dimolybdenum Units Joined by μ-Hydride Ions (1998) (19)
- Effect of axial anthracene ligands on the luminescence of trinickel molecular wires (2008) (19)
- A highly oxidized Re27+ species with an electron-poor bond of order 3.5 (2003) (19)
- A highly reduced v(2)(3+) unit with a metal-metal bond order of 3.5. (2003) (19)
- Applications of high-field (W-band) EPR to M-M bonded units (M = Cr, Mo): the first confirmed oxidation of a Cr2 4+ paddlewheel complex to a stable isostructural Cr2 5+ product. (2003) (18)
- Manipulating magnetism: Ru₂⁵⁺ paddlewheels devoid of axial interactions. (2014) (18)
- A complete series of compounds (2002) (18)
- Photoelectron spectroscopy and DFT calculations of easily ionized quadruply bonded Mo2(4+) compounds and their bicyclic guanidinate precursors. (2006) (18)
- Large changes in electronic structures of Ru2(6+) species caused by the variations of the bite angle of guanidinate ligands: tuning magnetic behavior. (2010) (18)
- Hexakis(neopentoxy)dimolybdenum. Preparation, characterization, and reactions with Lewis bases and carbon dioxide (1977) (18)
- Experimental and theoretical evidence of aromatic behavior in heterobenzene-like molecules with metal-metal multiple bonds. (2011) (18)
- A deliberate approach for the syntheses of heterometallic supramolecules containing dimolybdenum Mo(2)4+ species coordinated to other metal units. (2007) (18)
- A re-evaluation of the two-step spin crossover in the trinuclear cation [Co3(dipyridylamido)4Cl2]+. (2008) (18)
- Increasing the solubility of strong reducing agents containing Mo(2)(4+) units and alkyl-substituted guanidinate ligands. (2007) (18)
- The first oxidation of a Cr(2)(4+) paddlewheel complex to an isostructural stable product. (2002) (17)
- Synthesis and reactivity of a very strong reducing agent containing a quadruple bond: structures of W2(hpp)4 and W2(hpp)4Cl2·4CH2Cl2 (2003) (17)
- Detailed structure of bis(.mu.-trimethylsilylmethylidyne)-tetrakis(trimethylsilylmethyl)ditungsten(W-W) (1978) (17)
- Single crystal x‐ray study of solid solutions of a Jahn‐Teller compound in an undistorted host: The Cr, Zn Saccharinate Hexahydrate System (1986) (17)
- Very large difference in electronic communication of dimetal species with heterobiphenylene and heteroanthracene units. (2008) (17)
- A trimetal chain cocooned by two heptadentate polypyridylamide ligands. (2006) (17)
- Metalmetal versus metalligand bonding in dimetal compounds with tridentate ligands (2000) (17)
- Deliberate synthesis of the preselected enantiomer of an enantiorigid molecule with pure rotational symmetry T. (2005) (17)
- An uncommon highly oxidized multiple bonded Re2(8+) species. (2011) (17)
- A dichromium(II,II) compound with a strong antiferromagnetic coupling but little or no Cr-Cr bonding. (2000) (17)
- Synthesis of unsymmetrical formamidines and benzamidines: structural studies of copper, cobalt and chromium complexes (2003) (16)
- Nature of bonding in complexes containing "supershort" metal-metal bonds. raman and theoretical study of M2(dmp)4 [M = Cr (natural abundance Cr, 50Cr, and 54Cr) and Mo; dmp = 2,6-dimethoxyphenyl]. (2010) (16)
- FIRST PADDLEWHEEL COMPLEX WITH A DOUBLY-BONDED IR26+ CORE (1999) (16)
- Preparation of several polypyrazolylborato compounds. Structures of two phenyltrispyrazolylborato complexes (1977) (16)
- Crystal-to-crystal oxidative deprotonation of a di(μ-hydroxo) to a di(μ-oxo) dimer of dimolybdenum units (2007) (16)
- Electronic localization versus delocalization determined by the binding of the linker in an isomer pair. (2007) (16)
- Unusual Magnetism of an Unsymmetrical Trinickel Chain (2008) (16)
- Trapping tetramethoxyzincate and -cobaltate(II) between Mo24+ units. (2003) (16)
- Proof by EPR spectroscopy that the unpaired electron in an Os(2)(7+) species is in a delta* metal-based molecular orbital. (2010) (16)
- CRYSTALLOGRAPHIC PROOF OF THE STABILITY OF A QUADRUPLE BOND BETWEEN TUNGSTEN ATOMS (1977) (15)
- Solubilizing the most easily ionized molecules and generating powerful reducing agents. (2013) (15)
- A Reliable Method of Preparation of Diiridium Paddlewheel Complexes: Structures of the First Compounds with Ir25+ Cores (2000) (15)
- Heteronuclear chains of four metal atoms including one quadruply bonded dimetal unit. Dichromium and dimolybdenum compounds with appended copper(I) atoms. (2000) (15)
- Dependence of metal-to-metal distances on Mo–Mo multiple bond orders; a new triple bond (1997) (15)
- Ligand Exchange or Reduction at Multiply Bonded Dimetal Units of Molybdenum and Rhenium by 2,6-Bis(diphenylphosphino)pyridine. (1998) (15)
- A completely suppressed Jahn-Teller effect in the structure of hexaaquachromium(II) hexafluorosilicate (1992) (14)
- Preparation of anhydrous vanadium(II) sulfate compounds from aqueous solutions: the synthesis and characterization of [V(en)3]SO4, V(bpy)2SO4 and V(py)4SO4 (1995) (14)
- A very short Re26+ quadruple bond: first DFT calculations on a paddlewheel complex with an element of the third transition series (1999) (14)
- Experimental and theoretical study of a paradigm Jahn-Teller molecule, all-trans-CrCl2(H2O)2(pyridine)2, and the related trans-CrCl2(pyridine)4·acetone (1995) (14)
- The usefulness of EPR spectroscopy in the study of compounds with metal-metal multiple bonds. (2014) (14)
- Trinuclear complexes of copper, cobalt and iron with N,N′-di(2-pyridyl) formamidinate ligands, [M3(DPyF)4][PF6]2 (1998) (14)
- A molecular propeller with three quadruply-bonded blades (2001) (14)
- A pseudo-jahn-teller distortion in an Mo2(μ2-O)2 ring having the shortest MoIV-MoIV double bond (2002) (14)
- Calixarenes as ligands for dimetal units: the state of the art. Structure of a new quadruply-bonded dimolybdenum compound (2003) (13)
- A WONDERFUL BOND THAT WASN'T THERE : REFORMULATION OF A COMPOUND CONTAINING A TA-TA BOND WITHOUT BRIDGING LIGANDS AS (CY2N)2CITA(MU -H)2 (1996) (13)
- Trinuclear complexes of four-coordinate iron and cobalt: (1998) (13)
- The first supramolecular assemblies comprised of dimetal units and chiral dicarboxylates (2002) (13)
- In search of metal-metal metathesis in the chemistry of compounds containing metal-to-metal triple bonds between molybdenum and tungsten atoms (1978) (13)
- A compound containing two tantalum atoms in oxidation states separated by six units (2000) (13)
- The effect of divergent-bite ligands on metal–metal bond distances in some paddlewheel complexes (2000) (13)
- Reaction products of W(CO)(6) with formamidines; electronic structure of a W(2)(mu-CO)(2) core with unsymmetric bridging carbonyls. (2004) (12)
- Molecular pairs and a propeller containing quadruply bonded dimolybdenum units linked by polyamidate ligands. (2006) (12)
- Neutron and X-ray Structural Characterization of the Hexaaquavanadium(II) Compound VSO4.cntdot.7H2O (1994) (12)
- Supramolecular Arrays Based on Dimetal Building Units (2001) (12)
- An equilibrium between a loop and a triangle containing Mo24+ species and perfluorodicarboxylate linkers (2006) (12)
- Controlling the dimensionality of metal-metal bonded Rrh(2)(4+) polymers by the length of the linker. A disciplined example of crystal engineering. (2001) (12)
- Strong electronic communication by direct metal-metal interaction in molecules with halide-bridged dimolybdenum pairs. (2006) (12)
- Strong Electronic Coupling between Mo2n+ Units: The Oxidation Products of [Mo2(DAniF)3]2(μ−H)2 and Mo2(DAniF)4 (2005) (12)
- Solid solutions of a Jahn-Teller compound in an undistorted host. 3. The chromium/zinc Tutton salt system (1993) (12)
- Solid Solutions of a Jahn-Teller Compound in an Undistorted Host. 4. Neutron and X-ray Single-Crystal Structures of Two Cr/Zn Tutton Salt Solid Solutions and the Observation of Disorder by Low-Temperature Neutron Diffraction (1994) (12)
- The molybdenum-to-molybdenum triple bond. 5. Preparation and structure of dimethyltetrakis(dimethylamido)dimolybdenum (1978) (11)
- X-ray crystallographic structural studies of the quadruply bonded octamethylditungsten anion and a related species containing a mixture of chloro and methyl ligands (1978) (11)
- Isomerization by ligand shuffling along a Cr24+ unit: further reactions leading to cleavage of a quadruple bond (2003) (11)
- Syntheses of very soluble alkylated bicyclic guanidinate ligands and structural characterization of a dipalladium paddlewheel (2013) (11)
- Relatively Air‐Stable M(II) saccharinates, M = V, or Cr (2007) (11)
- Structural studies of nickel complexes of the unsymmetrical tridentate ligand N-phenyl-N-(2-pyridyl)formamidinate (2003) (11)
- STRUCTURE OF TETRAKIS(BENZOATO)DIMOLYBDENUM(II) (1976) (11)
- Exploring the Reactivity of Rh2 (OAc)4 with 2, 2′ -Dipyridylamine (2004) (11)
- The structure of bis(diphenyldipyrazolylborato)nickel(II) (1976) (10)
- Linear trichromium(II) chains wrapped by unsymmetrical formamidinates (2003) (10)
- Chiral supramolecules: organometallic molecular loops made from enantiopure R-[cis-Rh2(C6H4PPh2)2(CH3CN)6](BF4)2. (2005) (10)
- Novel η3-allyl complexes of titanium (2000) (10)
- Enhancement in electronic communication upon replacement of Mo-O by Mo-S bonds in tetranuclear clusters of the type [Mo2]2(mu-E-E)2 (E = O or S). (2007) (10)
- Solid solutions of a Jahn‐Teller compound in an undistorted host. 2. High‐Spin, Six‐Coordinate Cr2+ without Jahn‐Teller Distortion (1991) (10)
- First water soluble Mo24+ compounds spanned by four α-hydroxycarboxylate anions (2002) (10)
- An infrequent geometry for an element of the first transition series: structural characterization of a distorted eight-coordinate compound TiCl4[C2H4(PMe2)2]2 (1998) (10)
- Inserting sulfur donor ligands in axial positions of an extended trinickel chain (2007) (9)
- A Tetragonal and an Uncommon Trigonal Dicobalt Paddlewheel Compound (2008) (9)
- A mixed-valence compound with one unpaired electron delocalized over four molybdenum atoms in a cyclic tetranuclear ion. (2003) (9)
- Synthesis and structural characterization of the molecular loop [cis-Mo2(N,N′-di-p-anisylformamidinate)2]2(O2C–CHCCH–CO2)2 (2005) (9)
- Preparation of vanadium(II) compounds. Structures of a carboxylato and a 3-pyridinesulphonate compound (1992) (8)
- Direct evidence from electron paramagnetic resonance for additional configurations in uncommon paddlewheel Re2(7+) units surrounded by an unsymmetrical bicyclic guanidinate. (2012) (8)
- A strong metal-to-metal interaction in an edge-sharing bioctahedral compound that leads to a very short tungsten-tungsten double bond. (2014) (8)
- Tuning the electrochemistry of Re2(6+) species with divergent bicyclic guanidinate ligands and by modification of axial π interactions. (2011) (8)
- Synthesis and X-ray structure of two relatively air-stable chromium(II) 3-pyridinesulphonate compounds (1992) (8)
- Influence of bonding mode of the linkers in the electronic communication of molecular pairs having dimolybdenum units linked by pseudohalides. (2009) (8)
- An efficient synthetic route to tribridged dimolybdenum compounds: synthesis and structural characterization of dichlorotris (μ-N,N′-diarylformamidinato)-dimolybdenum(II,III), Aryl = phenyl and p-tolyl (1997) (8)
- Trivalent mononuclear mer-trichlorotris (pyridine) tantalum (III): preparation and structure in three crystalline forms (1996) (8)
- An iron complex with an unsupported Fe-Fe bond. (2009) (7)
- A remarkable Cr(III) organometallic compound formed by an unprecedented rearrangement of a formamidinate anion (2001) (7)
- X-ray structural characterization of a pair of isotypic tetraaqua compounds of the Jahn-Teller species chromium(II) and copper(II) (1993) (7)
- The δ Bond and Trigonal Paddlewheels Before the Dawn of the Quintuple Bond (2015) (7)
- Symmetrical linear Co36+ chains cocooned by two polypyridylamide ligands: How do they compare to open chains? (2010) (7)
- A molecular loop with interstitial channels in a chiral environment: exploration of the chemistry of Mo24+ species with chiral and non-chiral dicarboxylate anions (2003) (7)
- Precursors for Assembly of Supramolecules Containing Quadruply Bonded Cr24+ Units: Systematic Preparation of Cr2(formamidinate)n(acetate)4–n (n = 2–4) (2007) (7)
- An unusual binding mode of a guanidinate ligand in a species with a short metal–metal single bond (2008) (7)
- An isomeric pair of fluoride-bridged cyclic dimolybdenum triads. (2006) (6)
- An unprecedented quadruply bonded compound with a bridging chlorine atom: Cr2[(o-ClC6H4N)2CH]3(μ-Cl) (1999) (6)
- An unusual iron-oxo tetranuclear species: Li2(HDPhF)2Fe4O4(DPhF)6·4toluene. A ubiquitous side product in the chemistry of iron/formamidine compounds (1996) (6)
- Evidence of disruption of conjugation involving delta bonds in intramolecular electronic coupling. (2009) (6)
- Lewis- or Brønsted-acid assisted formation of open-chain vinamidinium salts from N,N′-diarylformamidines and acetone (1996) (6)
- Transition from a nonbonding to a bonding interaction in a tetranuclear [Mo2]2(mu-OR)4 cluster. (2006) (6)
- A Magic Equation: Delta Bonds Plus Bicyclic Guanidinates Equals Strong Reducing Agents (2014) (6)
- How to make a major shift in a redox potential: ligand control of the oxidation state of dimolybdenum units. (2002) (5)
- A paramagnetic trigonal paddlewheel complex with iron-dithiolato ligand paddles: {[(C9H18N2S2)Fe(NO)]3Ag2}(BF4)2 (2008) (5)
- Linear trichromium complexes with direct Cr to Cr contacts. 2. Compounds with Cr3(dipyridylamide)4(3+) cores. (2000) (5)
- Iron, Cobalt and Iridium Compounds (2005) (5)
- An unusual o-metallated pyridyl dirhodium(II) complex: [Rh2{μ-(C5H3N)NH(C5H4N)}2{η2-(C5H4N)NH(C5H4N}2]Cl2·CH3OH (1999) (5)
- Oxidative scission of a Mo-Mo quadruple bond. (2000) (5)
- A double-bonded niobium(III) compound with a formamidinate core: Nb2(μ-SMe)2(μ-DTolF)2 (η2-DTolF)2.2 toluene, DToIF= di-p-tolylformamidinate (1996) (5)
- Substitution on a methyl group of an acetylacetonate ligand: synthesis and structural characterization of oxobis[6-(phenylamino)hexane-2,4-dionato-O,O′]vanadium(IV), VO(Phad)2 (1996) (5)
- A rare and highly oxidized Mo(2)5.5+ unit stabilized by oxo anions and supported by formamidinate bridges. (2006) (5)
- The aqueous chromium sulfate-pyridine system: X-ray structural characterization of chain- and tetranuclear compounds (1994) (5)
- Introduction and Survey (2005) (5)
- Four Compounds Containing Oxo-Centered Trivanadium Cores Surrounded by Six μη2-Carboxylato Groups. (1987) (5)
- A rare dimer of dimers having four hydride linkers joining two quadruply bonded dimolybdenum units. (2007) (5)
- An unprecedented tetranuclear complex containing two quadruply bonded Mo24+ units joined by two μ-OH groups (1998) (4)
- An unprecedented tetranuclear complex containing two quadruply bonded Mo24+ units joined by two μ-OH groups (1998) (4)
- Diruthenium Formamidinato Complexes (2014) (3)
- Linear Trichromium, Tricobalt, Trinickel, and Tricopper Complexes of 2,2′‐Dipyridylamide (2014) (3)
- A dinuclear cation with both four- and five-coordinate cobalt(II). (2000) (3)
- Exploring the Intricacies of Weak Interactions in Metal-Metal Bonds Using an Unsymmetrical Carbonyl Precursor and a Triple-Bonded W2(6+) Paddlewheel. (2016) (3)
- Soluble paramagnetic Ru 2 6+ paddlewheels with alkyl-substituted bicyclic guanidinates (2016) (3)
- The Magic of the Delta Bonds: How to Modulate Electronic Communication in Pairs-of-Pairs Containing Multiple Bonded Mo2 Species (2015) (3)
- An unusual trigonal D3 assembly composed of molybdate anions and multiply bonded dimolybdenum units. (2008) (3)
- Acetonitrile Activation Promoted by Divalent Nickel Species with Bicyclic Guanidinate Ligands (2012) (3)
- A molecular pair having two quadruply bonded dimolybdenum units linked by a terephthalate dianion (2002) (3)
- Neutron and X-Ray Structural Characterization of the Hexaaquavanadium( II) Compound VSO4×7 H2O. (1995) (2)
- The Use of Dimetal Building Blocks in Convergent Syntheses of Large Arrays. (2002) (2)
- Complexes of the Group 5 Elements (2005) (2)
- Metal-metal bonded compounds and metal clusters (2015) (2)
- μ-ALLENE-BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM, A BRIDGING ALLENE LIGAND (1977) (2)
- A pseudo-Jahn-Teller distortion in an Mo(2)(mu(2)-O)(2) ring having the shortest Mo(IV)-Mo(IV) double bond. (2002) (2)
- Adventures in divalent early transition metal coordination chemistry: On the way to metal–metal bonded species (2017) (2)
- Trishomobarrelenedicarboxylate dianion as a bridge between dimolybdenum units: Comparison to similar compounds (2006) (2)
- In Memoriam — Malcolm H. Chisholm (1945–2015) (2016) (1)
- 12. Syntheses of Dimethylamido Compounds Containing Metal‐to‐Metal Triple Bonds Between Molybdenum and Tungsten Atoms (2007) (1)
- A tetranuclear nickel(II) cluster: bis[μ3‐2,6‐bis(methylamino)pyridine(2−)‐κ4N2:N1,N6:N6]bis[μ3‐2,6‐bis(methylamino)pyridine(1−)‐κ3N1:N2:N2]dichloridotetranickel(II) (2007) (1)
- A calix[4]arene carceplex with four Rh2 4+ fasteners. (2004) (1)
- Tetra(Acetato)Dimolybdenum(II) (2014) (1)
- A paramagnetic precursor for polymeric supramolecular assemblies based on multiply bonded dimetal units: mu-acetato-acetonitriletris(mu-N,N'-diphenylformamidinato)diruthenium tetrafluoroborate dichloromethane hemisolvate. (2005) (1)
- Nickel, Palladium and Platinum Compounds (2005) (1)
- Tetrakis(1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidin-9-ido-κ2 N 1,N 9)niobium(V) hexafluoridophosphate (2008) (1)
- Correction to Proof by EPR Spectroscopy that the Unpaired Electron in an Os27+ Species Is in a δ* Metal-based Molecular Orbital (2014) (1)
- Trinuclear Palladium(II) Acetate (2014) (1)
- An Asymmetric Edge-Sharing Bioctahedral Complex: (η2-DAniF)MoIII(μ-DAniF)2(μ-O,Cl)MoVCl2 (DAniF=N,N′-di-p-anisylformamidinate) (2003) (1)
- The first structurally confirmed paddlewheel compound with an M(2)(7+) core: [Os(2)(hpp)(4)Cl(2)](PF(6)). (2003) (0)
- Chiral Molecules Containing Metal—Metal Bonds (2007) (0)
- Single Crystal X-Ray Study of Solid Solutions of a Jahn-Teller Compound in an Undistorted Host: The Cr, Zn Saccharinate Hexahydrate System. (1987) (0)
- Structural and magnetic evidence concerning spin crossover in formamidinate compounds with ru2 5+ cores. (2005) (0)
- Erratum to “Reactions of TiCl4 with phosphines and alkylating reagents: an organometallic route to a titanium(II) cluster compound” ☆ ☆☆: [Journal of Organometallic Chemistry 573 (1999) 78–86] (1999) (0)
- A Rare Cyclic Dimolybdenum Triad with Three Weakly Interacting Unpaired Electrons (2010) (0)
- New Sigma-Ethyl Compounds of Dimolybdenum and Evidence for Dinuclear Reductive Elimination with a Concomitant Metal-Metal Triple to Quadruple Bond Transformation. (1978) (0)
- The Tungsten-to-Tungsten Triple Bond. Part 7. Replacement of Dimethylamido by Chloro Groups in Hexakis(dimethylamido)ditungsten and dimolybdenum Compounds. Preparation, Properties, and Structure of Dichlorotetrakis(dimethylamido)ditun (1977) (0)
- X‐Ray Structural Characterization of a Pair of Isotypic Tetraaqua Compounds of the Jahn‐Teller Species Chromium(II) and Copper(II). (1994) (0)
- Oxygen in a box: an oxygen atom surrounded by a cube of 8 lithium atoms (1999) (0)
- A Novel Cluster Consisting of Seven Fused MX6 Octahedra, Li14(THF)8[Ni7Cl17(μ-formamidinate)3(μ-Cl)]2 (2000) (0)
- Crystal-to-crystal oxidative deprotonation of a di(micro-hydroxo) to a di(micro-oxo) dimer of dimolybdenum units. (2007) (0)
- COMPARATIVE STUDY OF STRUCTURES, INCLUDING JAHN-TELLER EFFECTS, IN THE SACCHARINATE COMPLEXES, (M(C7H4NO3S)2(H2O)4).2H2O, OF CHROMIUM AND ZINC, AS WELL AS OTHER DIVALENT METAL IONS (1985) (0)
- Synthesis and Characterization of Four Vanadium(II) Compounds, Including Vanadium(II) Sulfate Hexahydrate and Vanadium(II) Saccharinates. (1987) (0)
- Tetra-mu-acetato-kappa8O:O'-bis[(N(1),N2-di-p-anisylformamidine-kappaN2)ruthenium(II)](Ru-Ru): an example of an axial bis-adduct of {Ru2}4+ tetracarboxylate with N-donor ligands. (2005) (0)
- CCDC 113165: Experimental Crystal Structure Determination (1999) (0)
- Spotlights on Recent JACS Publications. (2018) (0)
- Quantum carpets in a one-dimensional tilted optical lattices (2017) (0)
- Parallelization of web processing services on cloud computing: A case study of Geostatistical Methods (2011) (0)
- Supramolecular Arrays Based on Dimolybdenum Building Blocks (2014) (0)
- New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co 3 (dpa) 4 (CH 3< (2000) (0)
- Detailed Structure of Bis-micron-(trimethylsilylmethylidyne)tetrakis-(trimethylsilylmethyl) ditungsten(W-W). (1977) (0)
- CCDC 648935: Experimental Crystal Structure Determination (2007) (0)
- CCDC 648933: Experimental Crystal Structure Determination (2007) (0)
- CCDC 603499: Experimental Crystal Structure Determination (2006) (0)
- NEW Σ-ETHYL COMPOUNDS OF DIMOLYBDENUM (MM) AND EVIDENCE FOR DINUCLEAR REDUCTIVE ELIMINATION WITH A CONCOMITANT METAL-METAL TRIPLE TO QUADRUPLE BOND TRANSFORMATION: ET-MM-ET → M::M + C2H4 + C2H6 (1978) (0)
- Oxidative Scission of a MoMo Quadruple Bond (0)
- The reduction of pentavalent group 5 compounds with KC 8 or LiBH 4 : a potpourri of oxidation states (1996) (0)
- Lewis- or Broensted-Acid Assisted Formation of Open-Chain Vinamidinium Salts from N,N′-Diarylformamidines and Acetone. (1997) (0)
- CCDC 603498: Experimental Crystal Structure Determination (2006) (0)
- A BISPYRAZOLYLBORATOALLYLDICARBONYLMOLYBDENUM COMPLEX WITH A 16-ELECTRON CONFIGURATION (1975) (0)
- The Molybdenum-to-Molybdenum Triple Bond. 5. Preparation and Structure of Dimethyltetrakis(dimethylamido)dimolybdenum. (1978) (0)
- CCDC 648934: Experimental Crystal Structure Determination (2007) (0)
- An Unusual Organometallic Supramolecule Composed of Chiral Dirhodium Units and Sulfato Bridging Ligands (2011) (0)
- F. Albert Cotton (1930–2007) (2008) (0)
- CCDC 113170: Experimental Crystal Structure Determination (1999) (0)
- Erratum to “A molecular propeller with three quadruply-bonded blades” [Inorg. Chem. Commun. 4 (2001) 130–133] (2001) (0)
- Synthesis and Structure of an Enantiopure Dirhodium Loop with Unusual Axial Coordination (2011) (0)
- Molybdenum-to-molybdenum triple bond. 5. preparation and structure of dimethyltetrakis(dimethylamido)dimolybdenum. Technical report (1978) (0)
- Tetra‐μ‐acetato‐κ8O:O′‐bis[(N1,N2‐di‐p‐anisylformamidine‐κN2)ruthenium(II)](Ru—Ru): an example of an axial bis‐adduct of {Ru2}4+ tetracarboxylate with N‐donor ligands (2005) (0)
- Robust entangled states in a non-hermitian periodically driven two-band Bose-Hubbard Hamiltonian (2017) (0)
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