Carol J. Burns

Q: What Schools Are Affiliated With Carol J. Burns

Carol J. Burns is affiliated with the following schools: Rice University, Federal University of Toulouse Midi-Pyrénées, University of California, Berkeley, Autonomous University of Barcelona, California Institute of Technology, Howard University, Stanford University, University of New Mexico, University of Washington

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Carol J. Burns

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Chemistry

Carol J. Burns's Degrees

Bachelors Chemistry University of California, Berkeley
PhD Chemistry Stanford University

Why Is Carol J. Burns Influential?

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According to Wikipedia, Carol Jean Burns is an American chemist who is Deputy Director of Research at Lawrence Berkeley National Laboratory. Her research is in actinide coordination and organometallic chemistry. She spent a term at the White House Office of Science and Technology Policy, and is a Fellow of the American Chemical Society. She was awarded the American Chemical Society Garvan–Olin Medal in 2021.

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Carol J. Burns's Published Works

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Published Works

Synthesis and Properties of High-Valent Organouranium Complexes Containing Terminal Organoimido and Oxo Functional Groups. A New Class of Organo-f-Element Complexes (1995) (148)
Trends in covalency for d- and f-element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy and time-dependent density functional theory. (2009) (145)
Synthesis and structure of high-valent organouranium complexes containing terminal monooxo functional groups (1993) (117)
Thorium(IV) and Uranium(IV) Ketimide Complexes Prepared by Nitrile Insertion into Actinide−Alkyl and −Aryl Bonds (2004) (111)
Synthesis and structure of the first uranium(VI) organometallic complex (1992) (101)
Synthesis and Crystal Structure of UO2Cl2(THF)3: A Simple Preparation of an Anhydrous Uranyl Reagent (1999) (92)
Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes. (2008) (90)
A trigonal bipyramidal uranyl amido complex: synthesis and structural characterization of [Na(THF)2][UO2(N(SiMe3)2)3]. (2000) (88)
A Simple Preparative Route to Bis(imido)uranium(VI) Complexes by the Direct Reductions of Diazenes and Azides. (1998) (88)
Convenient Synthesis, Structure, and Reactivity of (C5Me5)U(CH2C6H5)3: A Simple Strategy for the Preparation of Monopentamethylcyclopentadienyl Uranium(IV) Complexes (2002) (85)
Synthesis and Structural Characterization of the First Uranium Cluster Containing an Isopolyoxometalate Core (2001) (84)
Preparation of actinide phosphinidene complexes: Steric control of reactivity (1996) (75)
First example of a neutral homoleptic uranium alkyl. Synthesis, properties, and structure of U[CH(SiMe3)2]3 (1989) (75)
Oxidation Chemistry of a Uranium(III) Aryloxide (1994) (74)
Electron-transfer reactions of divalent ytterbium metallocenes. Synthesis of the series [(Me5C5)2Yb]2[.mu.-E] (E = oxygen, sulfur, selenium, or tellurium) and crystal structure of [(Me5C5)2Yb]2[.mu.-Se] (1989) (73)
Uranium(VI) organoimido complexes (1990) (72)
Uranium alkoxide chemistry. 1. Synthesis and the novel dimeric structure of the first homoleptic uranium(III) aryloxide complex (1988) (67)
Organometallic coordination complexes of the bis(pentamethylcyclopentadienyl)-alkaline earth compounds, (Me5C5)2MLn, where M is Mg, Ca, Sr, OR Ba and Me5C5BeCl (1987) (64)
The First f-Element Ketimido Complex: Synthesis and Characterization of (C5Me5)2U(−NCPh2)2 (2002) (64)
Reaction of the uranyl(VI) ion (UO(2)(2+)) with a triamidoamine ligand: preparation and structural characterization of a mixed-valent uranium(V/VI) oxo-imido dimer. (2001) (63)
Synthesis of the First Examples of Transition Metal .eta.2-SiH4 Complexes, cis-Mo(.eta.2-SiH4)(CO)(R2PC2H4PR2)2, and Evidence for an Unprecedented Tautomeric Equilibrium between an .eta.2-SiH4 Complex and a Hydridosilyl Species: A Model for Methane Coordination and Activation (1995) (61)
Preparation of the first n2-olefin complex of a 4f-transition metal, (Me5C5)2Yb(.mu.-C2H4)Pt(PPh3)2 (1987) (61)
Basicity of uranyl oxo ligands upon coordination of alkoxides. (2000) (61)
Neutron structure and inelastic-neutron-scattering and theoretical studies of molybdenum complex Mo(CO)(H2)[(C6D5)2PC2H4P(C6D5)2]2.cntdot.4.5C6D6, a complex with an extremely low barrier to hydrogen rotation. Implications on the reaction coordinate for H-H cleavage to dihydride (1993) (59)
Solid-State Structures of Base-Free Ytterbocenes and Inclusion Compounds of Bis(pentamethylcyclopentadienyl)ytterbium with Neutral Carboranes and Toluene: The Role of Intermolecular Contacts (2000) (56)
Covalency in f-element organometallic complexes: theory and experiment (1989) (56)
Uranium-Mediated Ring Opening of Tetrahydrofuran. Crystal Structure of UI(2)(OCH(2)CH(2)CH(2)CH(2)I)(2)(Ph(3)P=O)(2). (1996) (50)
Enhancing the reactivity of uranium(VI) organoimido complexes with diazoalkanes. (2002) (50)
Mono(pentamethylcyclopentadienyl)uranium(III) Complexes: Synthesis, Properties, and X-ray Structures of (η-C5Me5)UI2(THF)3, (η-C5Me5)UI2(py)3, and (η-C5Me5)U[N(SiMe3)2]2 (2000) (49)
.eta.2-Coordination of Si-H .sigma. Bonds to Transition-Metal Fragments That Also Bind .eta.2-Dihydrogen Ligands and Agostic C-H Bonds: Synthesis and Characterization of .eta.2-Silane Complexes cis-Mo(.eta.2-H-SiHR'2)(CO)(R2PC2H4PR2)2 (1994) (49)
The Thermal Average Molecular Structures of Bis(pentamethylcyclopentadienyl)magnesium(II), -calcium(II) and -ytterbium(II) in the Gas Phase. (1987) (49)
Experimental and Theoretical Studies of Bonding and Oxidative Addition of Germanes and Silanes, EH4-nPhn (E = Si, Ge; n = 0−3), to Mo(CO)(diphosphine)2. The First Structurally Characterized Germane σ Complex (2003) (47)
Synthesis and characterization of bis(pentamethylcyclopentadienyl)uranium(IV) and -thorium(IV) compounds containing the bis(trimethylsilyl)phosphide ligand (1993) (47)
Dihydrogen : a better ligand than water ? IR and X-ray evidence for aquo coordination in W(CO)3(PR3)2(H2O), thermodynamics of H2O versus η2-H2 binding, and H2O/D2 isotopic exchange. Implications on the biological activation of hydrogen (1992) (46)
The catalytic reduction of azides and hydrazines using high-valent organouranium complexes (1999) (46)
The complex (Me5C5)2Yb(.mu.-Me)Be(C5Me5): a model for methane coordination? (1987) (46)
Synthesis of mixed-ring organoactinide complexes. 2. (Cyclooctatetraene)(pentamethylcyclopentadienyl)(THF)uranium [(C8H8)(C5Me5)U(THF)] and its 4,4'-dimethyl-2,2'-bipyridine derivative (1993) (45)
The molecular structures of bis(pentamethylcyclopentadienyl)-calcium and -ytterbium in the gas phase; two bent metallocenes (1986) (45)
Preparation of the first molecular .eta.2-acetylene complex of a 4f transition metal, (Me5C5)2Yb(.eta.2-MeC.tplbond.CMe) (1987) (43)
Fission Product Data Measured at Los Alamos for Fission Spectrum and Thermal Neutrons on 239Pu, 235U, 238U (2010) (43)
C−H Bond Activation with Actinides: The First Example of Intramolecular Ring Bite of a Pentamethylcyclopentadienyl Methyl Group (1999) (42)
Synthesis of Neutral and Anionic Uranyl Aryloxide Complexes from Uranyl Amide Precursors: X-ray Crystal Structures of UO2(O-2,6-i-Pr2C6H3)2(py)3 and [Na(THF)3]2[UO2(O-2,6-Me2C6H3)4] (1995) (42)
Reaction of (C5Me5)2Yb with fluorocarbons: formation of (C5Me5)4Yb2(µ-F) by intermolecular C–F activation (1989) (42)
Covalency trends in group IV metallocene dichlorides. chlorine K-edge X-ray absorption spectroscopy and time dependent-density functional theory. (2008) (41)
[(C5Me5)2U(Me)(OTf)]2: A New Reagent for Uranium Metallocene Chemistry. Preparation of the First Actinide Hydrazonato Complexes (2002) (40)
Approaching zero discharge in uranium reprocessing: photochemical reduction of uranyl. (2001) (38)
Steric control of substituted phenoxide ligands on product structures of uranyl aryloxide complexes. (2002) (38)
Effects of temperature on the crystal and molecular structure of the mixed-valence linear chain bis(ethylenediamine)platinum bis(ethylenediamine)dihaloplatinum tetraperchlorate (halo = chloro, bromo) (1993) (33)
Synthesis and structural characterization of uranium ansa-metallocene complexes containing organoimido functional groups; electronic effects of ancillary ligands (1999) (33)
Fission Product Yields from Fission Spectrum n+239Pu for ENDF/B-VII.1 (2010) (31)
Synthesis and reactivity of technetium(VII) imido complexes (1993) (30)
Experimental and theoretical comparison of the O K-edge nonresonant inelastic X-ray scattering and X-ray absorption spectra of NaReO4. (2010) (29)
Bridging a Gap in Actinide Chemistry (2005) (26)
Monomeric uranyl alkoxide and amide complexes (1992) (24)
Uranium(VI) oxo-alkoxide cluster synthesis via ligand redistribution (1988) (22)
Preparation and crystal structure of the mixed-valence (YbIII,II) tetranuclear complex, (Me5C5)6Yb(µ-F)4 (1987) (22)
Synthesis and thermal average gas phase molecular structures of bis(pentamethylcyclopentadienyl)-strontium and -barium; the first organo-strontium and -barium structures (1987) (22)
Zirconium complexes involving 2-phosphorus-substituted indenyl fragments (2005) (21)
Uranium (III) scorpionates: synthesis and structure of [(TpMe2)2U[N(C6H5)2]] and [(TpMe2)2U[N(SiMe3)2]]. (2004) (20)
Bonding of H2, N2, ethylene, and acetylene to bivalent lanthanide metallocenes: Trends from DFT calculations on Cp2M and Cp*2 M (M = Sm, Eu, Yb) and experiments with Cp*2Yb (2003) (19)
Metal-Metal Multiply Bonded Complexes of Technetium. 1. Synthesis and Structural Characterization of Phosphine Complexes That Contain a Tc-Tc Multiple Bond (1994) (19)
Synthesis and X-ray Crystal Structures of {Mo(CO)(Et2PC2H4PEt2)2}2(.mu.-N2) with an End-On Bridging Dinitrogen Ligand and Mo(CO)(Bui2PC2H4PBui2)2 Containing an Agostic Mo.cntdot..cntdot..cntdot.H-C Interaction (1995) (18)
Synthesis, characterization, and x-ray structure of {[K(THF)2]2[U(NH-2,6-iso-Pr2C6H3)5]}.cntdot.THF (1992) (18)
Generation of spirotricyclic site-differentiated cyclotriphosphazenes: a solvent-free approach to multidentate N/O donor ligand systems. (2004) (18)
Coordination of Carbon Monoxide and Isocyanides to Bis(pentamethylcyclopentadienyl)ytterbium and Related Bivalent Ytterbocenes (2001) (17)
Carbon−Hydrogen Bond Activation of Aromatic Imines by (Cp*2SmH)2 (1996) (17)
Novel synthetic route to molybdenum hydrido-thiocarbamoyl and hydrosulfido-carbyne complexes by reactions of trans-Mo(N{sub 2}){sub 2}(R{sub 2}PC{sub 2}H{sub 4}PR{sub 2}){sub 2} with N,N-dimethylthioformamide (1995) (16)
Electronic structure of bis(cyclopentadienyl) lanthanide compounds: photoelectron spectra and molecular orbital calculations (1986) (16)
Synthesis and Characterization of Thorium a nsa -Cyclopentadienyl-Amido Complexes (2003) (15)
Halide Effects in the Synthesis of Mixed Uranium(IV) Aryloxide-Halide Compounds. (1998) (14)
Mixed-halide MX chain solids: effect of chloride doping on the crystal structure and resonance Raman spectra of [Pt(en)2Br2][Pt(en)2](ClO4)4 (1991) (14)
Synthesis and Characterization of Molybdenum Complexes Containing Diphosphine Ligands of the Type (ArCH2)2PC2H4P(CH2Ar)2 (Ar = C6H4X). Electronic Control of .eta.2-Dihydrogen versus Dihydride Coordination in MoH2(CO){(RCH2)2PC2H4P(CH2R)2}2 (R = Me, Pri, C6H4X) and Implications on the Reaction Coordi (1994) (14)
First rhenium complexes based on cyclotriphosphazene scaffolds with exocyclic pyrazolyl substituentsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b203254f/ (2002) (14)
Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study. (2015) (14)
Research program to investigate the fundamental chemistry of technetium - eScholarship (2003) (12)
Organoactinide Chemistry: Synthesis and Characterization (2010) (12)
Final Report, Research Program to Investigate the Fundamental Chemistry of Technetium (2000) (12)
New Syntheses of Cp*2Th(Ph)2 and Cp*2Th(Me)(aryl) Derivatives (1994) (12)
Synthesis and Reactions of [Cp*2Yb]2(μ-Me) and [Cp*2Yb]2(μ-Me)(Me) and Related Yb2(II, III) and Yb2(III, III) Compounds (2017) (12)
Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdo (1992) (12)
Possible heavy-fermion behavior and field-induced transitions in new R-Pt-Ga compounds☆ (1992) (11)
Plutonium(III)-catalyzed Meerwein–Ponndorf–Verley reactions (2000) (11)
New chain materials from binuclear metal complexes (1991) (11)
Characterization of the bisphosphonate recognition site on hydroxyapatite using radioligand binding techniques with [14C]citric acid (1993) (11)
Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5‐Pentamethylcyclopentadienyl)Ytterbium (2007) (10)
Low-temperature Chemical Vapor Deposition of Rhodium and Iridium thin Films (1989) (9)
The crystal structure of mercury (I, II) bromide oxide, Hg8O4Br3 (1987) (8)
Synthesis and Physical Properties of Pentamethylmanganocene, (C5Me5)Mn(C5H5), and the Inclusion Compounds [(C5Me5)2Yb]2[(C5H5)2M] (Where M = V, Cr, Fe, Co) (2016) (8)
Syntheses, solution properties and crystal structures of peroxo- and superoxo-bridged dinuclear ammine rhodium(III) complexes (1987) (8)
Reactions of ReH3(CO)(PMe2Ph)3 with Metallic Lewis Acids. Synthesis and Structural Characterization of Hydrido-Bridged Heterometallic Rhenium-Gold, Rhenium-Silver, and Rhenium-Copper Complexes (2000) (7)
Chloro(p-chloroanilido-N)bis(η5-pentamethylcyclopentadienyl)uranium(IV) (1999) (7)
Actinide complexes with the Kläui tripodal oxygen ligand – crystal structure of [{η4-C5H5(CH2C(CH3)3)}Co{P(O)(OC2H5)2}3]2U (2005) (6)
Los Alamos National Laboratory Fission Basis (2012) (6)
Preparation and characterization of high-Tc oxides. YBa2Cu3O7 and REBa2Cu3O7 (1987) (5)
Organometallic and Coordination Complexes (2004) (4)
The Catalytic Reduction of Azides and Hydrazines Using High-Valent Organouranium Complexes. (2010) (4)
Homogeneous and Heterogeneous Catalytic Processes Promoted by Organoactinides (2010) (4)
A sulphur and uranium fiesta! Synthesis, structure, and characterization of neutral terminal uranium(vi) monosulphide, uranium(vi) η2-disulphide, and uranium(iv) phosphine sulphide complexes. (2018) (4)
The Crystal Structure at 105 K of Two Compounds Derived from Tryptamine, 1-Trifluoroacetyl-3-(2-trifluoroacetamidoethyl)indole and Tryptamine 3,4-Dimethoxybenzoate. (1987) (4)
Synthesis and Properties of Novel Low-Dimensional Ruthenium Materials: Self-Assembled Multilayers and Mixed Inorganic—Organic Polymers (1992) (3)
Tetrachlorotetrakis(propan-2-ol)uranium(IV) and tetrachlorotetrakis(propan-2-ol)thorium(IV) (1999) (2)
Los Alamos fission basis (2009) (2)
On the origin of the resonance Raman γ1 dispersion and fine structure of PtBr (1991) (1)
Nanoscale Science and Technology at Los Alamos National Laboratory (2000) (1)
Uranium Alkoxide Chemistry. Part 1. Synthesis and the Novel Dimeric Structure of the First Homoleptic Uranium(III) Aryloxide Complex. (1988) (1)
THE COORDINATION CHEMISTRY OF DIVALENT BIS(PENTAMETHYLCYCLOPENTADIENYL)LANTHANIDE COMPLEXES WITH NON-CLASSICAL LIGANDS (1987) (1)
(Me5C5)2Yb(μ-Me)Be(C5Me5): A Model for Methane Coordination? (1988) (1)
Synthesis and structure of tetrakis(2,6-dichlorophenoxide) bis(THF) uranium(IV) (2000) (1)
Chemistry. Bridging a gap in actinide chemistry. (2005) (1)
Preparation of the First η2-Olefin Complex of a 4f-Transition Metal, (Me5C5)2Yb(μ-C2H4)Pt(PPh3)2. (1987) (1)
Steric vs electronic effects in binary uranyl alkoxides: A spectroscopic perspective (2000) (1)
Research program to investigate the fundamental chemistry of technetium. 1998 annual progress report (1998) (1)
Actinides: Organometallic Chemistry (2006) (1)
Structure of μ-hydrido-bis(hydrido)bis(pentamethylcyclopentadienyl)bis(trimethylphosphino)diiridium hexafluorophosphate (1987) (1)
Lewis base binding affinities and redox properties of plutonium complexes (2001) (1)
Eu3+and UO22+Surface Complexes on SiO2and TiO2: Models for Testing Mediated Electrochemical Methods for the Treatment of Actinide Processing Residues (2000) (0)
DIVALENT LANTHANIDE CHEMISTRY. REACTION OF BASE-FREE BIS |BIS(TRIMETHYLSILYL)AMIDE] YTTERBIUM (II) WITH SUBSITUTED CYCLOPENTADIENES; PREPARATIONS OF BASE-FREE BIS(PENTAMETHYLCYCLOPENTADIENYL) YTTERBIUM (II) (1986) (0)
Los Alamos National Laboratory -- FY18 Science Accomplishments (2018) (0)
Uranium(VI)-Oxo-Alkoxide Cluster Synthesis via Ligand Redistribution. (1989) (0)
2018 Capabilities Awareness Workshop Presentations (2018) (0)
Nuclear forensics: the science and role in enhancing global security (2011) (0)
2001 Gordon Research Conference on Organometallic Chemistry. Final progress report [agenda and attendee list] (2001) (0)
Non-aqueous chemistry of uranyl complexes with tripodal ligands (2001) (0)
Chemistry contributing to radionuclide monitoring and measurement (2011) (0)
Preparation of the first eta/sup 2/-olefin complex of a 4f-transition metal, (Me/sub 5/C/sub 5/)/sub 2/Yb(. mu. -C/sub 2/H/sub 4/)Pt(PPh/sub 3/)/sub 2/ (1987) (0)
Preparation of the first molecular eta/sup 2/-acetylene complex of a 4f transition metal, (Me/sub 5/C/sub 5/)/sub 2/Yb(eta/sup 2/-MeC identical with CMe) (1987) (0)
Nuclear Forensics at Los Alamos National Laboratory (2012) (0)
Thorium benzyne: Reactivity of the Cp*{sub 2}Th(C{sub 6}H{sub 4}) moiety with Lewis bases (1993) (0)
Aqueous electrochemical mechanisms in actinide residue processing. 1998 annual progress report (1998) (0)
Weapons Science Program Integration Nuclear Physics (2013) (0)
PREPARATION AND CRYSTAL STRUCTURE OF THE MIXED-VALENCE Yb(III,II) TETRANUCLEAR COMPLEX, (Me5C5)6Yb4(u-F)4 (1986) (0)
Los Alamos National fission basis (2011) (0)
LANL Analytical and Radiochemistry Capabilities (2012) (0)
Metal-ligand ``multiple`` bonding: Revelations in the electronic structure of complexes of high-valent f-elements (1997) (0)
Reductions of technetium imido complexes (1993) (0)
Preparation of the First Molecular η2-Acetylene Complex of a 4f Transition Metal, (Me5C5)2Yb(η2-MeCCMe). (1987) (0)
Synthesis and structure of uranyl compounds containing sterically demanding alkoxide ligands (1997) (0)
Nuclear and radiochemistry supporting national security (2011) (0)
Weapons radiochemistry and nuclear forensics (2012) (0)
The synthesis and characterization of mixed fluoroaryloxides of uranium(V) (1993) (0)
Possible heavy fermion behavior and field-induced transitions in new rare earth platinum gallium compounds (1991) (0)
Kinetic and mechanistic studies of the reduction of uranium(VI) bis(imido) complexes (1997) (0)
Technetium Chemistry (2008) (0)
Synthesis and Structure of the First Uranium(VI) Organometallic Complex. (1993) (0)
needs to sustain nuclear forensics capabilities (2007) (0)
CCDC 135488: Experimental Crystal Structure Determination (1999) (0)
Uranium and thorium alkyne complexes (1997) (0)
Photocatalytic oxidation by uranyl (1995) (0)
(ME[SUB]5 C[SUB]5) [SUB]2 YB(MU-H[SUB]3 B)(PME[SUB]3 ): A COMPLEX WITH A NEAR-LINEAR BH[SUB]3 BRIDGING GROUP (1988) (0)
Identification and forensic characterization of nuclear materials (2010) (0)
Synthesis and properties of (bis)pentamethylcyclo-pentadienyl actinide complexes containing terminal organoimido and oxo functional groups (1993) (0)
REACTION OF (ME[SUB]5 C[SUB]5 )[SUB]2 YB WITH FLUOROCARBONS: FORMATION OF (ME[SUB]5 C[SUB]5 )[SUB]4 YB[SUB]2 (MU-F) BY INTRAMOLECOLAR C-F ACTIVATION (1988) (0)
Structural Preferences and Reactivity of Uranyl Alkoxide Complexes Prepared in Non-Protic Media (2001) (0)

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