Christopher C. Cummins
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American chemist
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Christopher C. Cumminschemistry Degrees
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Inorganic Chemistry
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Chemistry
Why Is Christopher C. Cummins Influential?
(Suggest an Edit or Addition)According to Wikipedia, Christopher "Kit" Colin Cummins is an American chemist, currently the Henry Dreyfus Professor at the Massachusetts Institute of Technology. He has made contributions to the coordination chemistry of transition metal nitrides, phosphides, and carbides.
Christopher C. Cummins's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex (1995) (377)
- Towards uranium catalysts (2008) (328)
- Early-transition-metal-mediated activation and transformation of white phosphorus. (2010) (310)
- Dinitrogen cleavage by three-coordinate molybdenum(III) complexes: Mechanistic and structural data (1996) (248)
- Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3 (1988) (236)
- Arene-Bridged Diuranium Complexes: Inverted Sandwiches Supported by δ Backbonding (2000) (206)
- Triple-Bond Reactivity of Diphosphorus Molecules (2006) (136)
- Cleavage of the Nitrous Oxide NN Bond by a Tris(amido)molybdenum(III) Complex (1995) (127)
- Tri-tert-butylsilyl)imido complexes of titanium: benzene carbon-hydrogen activation and structure of [(tert-Bu3SiNH)Ti]2(.mu.-NSi-tert-Bu3)2 (1991) (118)
- Reductive cleavage and related reactions leading to molybdenum–element multiple bonds: new pathways offered by three-coordinate molybdenum(III) (1998) (110)
- Phosphinidenetantalum(V) Complexes of the Type [(N3N)TaPR] as Phospha‐Wittig Reagents (1993) (110)
- Heterodinuclear Uranium/Molybdenum Dinitrogen Complexes (1998) (109)
- A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling. (2006) (108)
- Shining light on dinitrogen cleavage: structural features, redox chemistry, and photochemistry of the key intermediate bridging dinitrogen complex. (2008) (101)
- A terminal molybdenum carbide prepared by methylidyne deprotonation (1997) (94)
- Diuranium inverted sandwiches involving naphthalene and cyclooctatetraene. (2002) (94)
- Uranium-nitrogen multiple bonding: the case of a four-coordinate uranium(VI) nitridoborate complex. (2009) (94)
- Uranium-nitrogen multiple bonding: isostructural anionic, neutral, and cationic uranium nitride complexes featuring a linear U=N=U core. (2010) (93)
- A cycle for organic nitrile synthesis via dinitrogen cleavage. (2006) (91)
- Atomic carbon as a terminal ligand: studies of a carbidomolybdenum anion featuring solid-state (13)C NMR data and proton-transfer self-exchange kinetics. (2001) (90)
- Formation of cyclo-E4(2-) units (E4 =P4, As4, AsP3) by a complex with a Cr-Cr quintuple bond. (2011) (89)
- Isolation and Structural Characterization of the Terminal Mesityl Azide Complex V(N3Mes)(I)(NRArF)2 and Its Conversion to a Vanadium(V) Imido Complex (1995) (88)
- The niobaziridine-hydride functional group: synthesis and divergent reactivity. (2003) (86)
- Facile Synthesis of AsP3 (2009) (86)
- A Molybdenum–Phosphorus Triple Bond: Synthesis, Structure, and Reactivity of the Terminal Phosphido (P3−) Complex [Mo(P)(NRAr)3] (1995) (84)
- Synthesis of Terminal Vanadium(V) Imido, Oxo, Sulfido, Selenido, and Tellurido Complexes by Imido Group or Chalcogenide Atom Transfer to Trigonal Monopyramidal V[N3N] (N3N = [(Me3SiNCH2CH2)3N]3-) (1994) (83)
- On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes. (2001) (81)
- Synthesis of zinc sulfide and cadmium sulfide within ROMP block copolymer microdomains (1992) (78)
- Four-Coordinate Molybdenum Chalcogenide Complexes Relevant to Nitrous Oxide N−N Bond Cleavage by Three-Coordinate Molybdenum(III): Synthesis, Characterization, Reactivity, and Thermochemistry (1998) (78)
- Reversible Reduction of Oxygen to Peroxide Facilitated by Molecular Recognition (2012) (74)
- Dinitrogen Cleavage Stemming from a Heterodinuclear Niobium/Molybdenum N2 Complex: New Nitridoniobium Systems Including a Niobazene Cyclic Trimer (2000) (74)
- An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple. (2007) (74)
- Redox-Catalyzed Binding of Dinitrogen by Molybdenum N-tert-Hydrocarbylanilide Complexes: Implications for Dinitrogen Functionalization and Reductive Cleavage (1999) (73)
- Ligand-based reduction of CO(2) to CO mediated by an anionic niobium nitride complex. (2010) (73)
- Small PbS clusters prepared via ROMP block copolymer technology (1990) (73)
- Synthesis and characterization of P2N3−: An aromatic ion composed of phosphorus and nitrogen (2015) (73)
- Revisiting CO2 Reduction with NaBH4 under Aprotic Conditions: Synthesis and Characterization of Sodium Triformatoborohydride (2015) (72)
- Photochemical incorporation of diphosphorus units into organic molecules. (2010) (70)
- Investigations of the Electronic Structure of Arene-Bridged Diuranium Complexes (2013) (70)
- A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. (2006) (69)
- A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites (2008) (69)
- Terminal, anionic carbide, nitride, and phosphide transition-metal complexes as synthetic entries to low-coordinate phosphorus derivatives. (2006) (69)
- A Cyclometalated Resting State for a Reactive Molybdenum Amide: Favorable Consequences of β-Hydrogen Elimination Including Reductive Cleavage, Coupling, and Complexation (1999) (67)
- Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N] (1992) (66)
- Facile Synthesis of Trialkoxymolybdenum(VI) Alkylidyne Complexes for Alkyne Metathesis (2000) (62)
- μ-η6,η6-Arene-bridged diuranium hexakisketimide complexes isolable in two states of charge. (2012) (62)
- Trigonal-Monopyramidal MIII Complexes of the Type [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N)† (1992) (62)
- Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene. (2012) (62)
- Carbon–phosphorus triple bond formation through multiple bond metathesis of an anionic niobium phosphide with carbon dioxide (2012) (61)
- Diorganophosphanylphosphinidenes as complexed ligands: synthesis via an anionic terminal phosphide of niobium. (2004) (59)
- Triple-bond reactivity of an AsP complex intermediate: synthesis stemming from molecular arsenic, As(4). (2009) (59)
- Phosphoric acid as a precursor to chemicals traditionally synthesized from white phosphorus (2018) (59)
- Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-phosphanorbornadiene Compounds. (2017) (57)
- Nitric Oxide Cleavage: Synthesis of Terminal Chromium(VI) Nitrido Complexes via Nitrosyl Deoxygenation (1995) (57)
- Complexes obtained by electrophilic attack on a dinitrogen-derived terminal molybdenum nitride: electronic structure analysis by solid state CP/MAS 15N NMR in combination with DFT calculations (2004) (57)
- Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P₄ (2010) (56)
- Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: a recyclable niobium phosphide (P(3-)) reagent that effects C-P triple-bond formation. (2004) (55)
- Nitrogen Atom Transfer Coupled with Dinitrogen Cleavage and Mo−Mo Triple Bond Formation (1996) (54)
- Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex. (2002) (54)
- Spontaneous and Selective Formation of HSNO, a Crucial Intermediate Linking H2S and Nitroso Chemistries. (2016) (54)
- A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO2. (2015) (53)
- Unusual 31P Chemical Shielding Tensors in Terminal Phosphido Complexes Containing a Phosphorus−Metal Triple Bond (1996) (53)
- Properties and reactivity patterns of AsP(3): an experimental and computational study of group 15 elemental molecules. (2009) (53)
- On the molecular and electronic structures of AsP3 and P4. (2010) (52)
- Two-electron reduction of a vanadium(V) nitride by CO to release cyanate and open a coordination site. (2009) (52)
- A retro Diels-Alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of P2 transfer to 1,3-dienes, and detection of P2 by molecular beam mass spectrometry. (2014) (51)
- Carbon dioxide reduction by terminal tantalum hydrides: formation and isolation of bridging methylene diolate complexes. (2010) (51)
- Enediynes via Sequential Acetylide Reductive Coupling and Alkyne Metathesis: Easy Access to Well-Defined Molybdenum Initiators for Alkyne Metathesis (2003) (49)
- Atom‐Bridged Intermediates in N‐ and P‐Atom Transfer Reactions (1997) (48)
- Cobalt and Vanadium Trimetaphosphate Polyanions: Synthesis, Characterization, and Electrochemical Evaluation for Non-aqueous Redox-Flow Battery Applications. (2018) (48)
- P2 addition to terminal phosphide M[triple bond]P triple bonds: a rational synthesis of cyclo-P3 complexes. (2008) (47)
- Assembly of Molybdenum/Titanium μ-Oxo Complexes via Radical Alkoxide C−O Cleavage (1996) (46)
- Carbonylation of zirconium complex [tert-Bu3SiNH]3ZrH and x-ray structural study of [tert-Bu3SiNH]3ZrCH3 (1991) (45)
- Radical Synthesis of a Heterobinuclear .mu.-Oxo Complex: Reaction of V(O)(O-i-Pr)3 with Ti(NRAr)3 (R = C(CD3)2CH3, Ar = 3,5-C6H3Me2) (1995) (44)
- Uranium−Group 14 Element Single Bonds: Isolation and Characterization of a Uranium(IV) Silyl Species (2001) (44)
- Reactions of Organic Nitriles with a Three-Coordinate Molybdenum(III) Complex and with a Related Molybdaziridine-Hydride (2003) (41)
- Coordination chemistry of a chelating amidoximato ligand. (2001) (39)
- Organometallic Complexes of Tantalum That Contain the Triamidoamine Ligand, [(Me3SiNCH2CH2)3N]3-, Including an Ethylidene Complex Formed via a Phosphine-Catalyzed Rearrangement of an Ethylene Complex (1994) (39)
- A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions. (2008) (37)
- Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX- (E = As, P, and N; X = S and O) Anions. (2017) (36)
- Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. (2008) (35)
- A reactive niobium phosphinidene P8 cluster obtained by reductive coupling of white phosphorus. (2008) (34)
- Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex. (2004) (34)
- A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation (1997) (34)
- SYNTHESIS OF NORBORNENES CONTAINING TIN(II), TIN(IV), LEAD(II), AND ZINC(II) AND THEIR POLYMERIZATION TO GIVE MICROPHASE-SEPARATED BLOCK COPOLYMERS (1991) (33)
- Let’s Make White Phosphorus Obsolete (2020) (32)
- Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds: C−C Bond Cleavage with Titanium(IV) Enolate Formation and Related Reactions (2002) (32)
- A terminal molybdenum arsenide complex synthesized from yellow arsenic. (2009) (31)
- Family of cofacial bimetallic complexes of a hexaanionic carboxamide cryptand. (2011) (30)
- A Chromium(VI) Nitrido−Silylmethyl Complex and a Chromium(V) μ-Nitrido Dimer: Synthetic and Structural Details (1996) (30)
- Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: a thermochemical, kinetic, and quantum chemical investigation. (2005) (29)
- A Molecular Precursor to Phosphaethyne and Its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion. (2016) (29)
- Synthesis of an iron(IV) cyanide complex that contains the triamido amine ligand [(tert-BuMe2SiNCH2CH2)3N]3- (1994) (29)
- Binding, release, and functionalization of CO2 at a nucleophilic oxo anion complex of titanium (2011) (29)
- Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide. (2002) (28)
- Phosphorus monoxide as a terminal ligand (1997) (28)
- Morphology of diblock copolymers of norbornene and organometallic derivatives of norbornene (1991) (28)
- Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide. (2013) (27)
- Synthesis of Titanium Complexes That Contain Triamido−Amine Ligands (1996) (27)
- Three‐Coordinate Complexes of “Hard” Ligands: Advances in Synthesis, Structure and Reactivity (1998) (27)
- LOW-COORDINATE IRON COMPLEXES STABILIZED BY N-(TERT-HYDROCARBYL)ANILIDE LIGATION : ADDUCT FORMATION, CHEMICAL OXIDATION, AND NITRIC OXIDE COMPLEXATION (1996) (27)
- Phosphinidene Reactivity of a Transient Vanadium P≡N Complex. (2016) (27)
- Terminal phosphinidene formation via tantalaziridine complexes. (2012) (26)
- Nitrogen fixation to cyanide at a molybdenum center. (2011) (26)
- A terminal nitride-to-phosphide conversion sequence followed by tungsten phosphide functionalization using a diphenylphosphenium synthon. (2007) (26)
- Terminal phosphide and dinitrogen molybdenum compounds obtained from pnictide-bridged precursors. (2001) (26)
- An unusual P-P double bond formed via phospha-Wittig transformation of a terminal PO complex. (2009) (25)
- Niobium and vanadium iminophosphinimide complexes. (2001) (25)
- Synthesis of a diniobium tetraphosphorus complex by a 2(3−1) process (2012) (25)
- Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide. (2014) (25)
- Ethylenebis(triphenylphosphine)platinum as a probe for niobium-mediated diphosphorus chemistry. (2007) (25)
- A Sterically Demanding Enolate Ligand: Tantalum Ligation and Pyridine Coupling (2004) (24)
- White phosphorus activation at a metal-phosphorus triple bond: a new route to cyclo-triphosphorus or cyclo-pentaphosphorus complexes of niobium. (2011) (24)
- Bimetallic μ-cyanoimide complexes prepared by NCN group transfer (2001) (24)
- Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex. (1998) (23)
- TITANIUM COMPLEXES STABILIZED BY N-(TERT-HYDROCARBYL)ANILIDE LIGATION : A SYNTHETIC INVESTIGATION (1996) (23)
- Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate. (2005) (23)
- Relaxation and dissociation following photoexcitation of the (μ-N2)[Mo(N[t-Bu]Ar)3]2 dinitrogen cleavage intermediate. (2013) (23)
- A diamagnetic dititanium(III) paddlewheel complex with no direct metal-metal bond. (2006) (22)
- Cleavage of Titanium Dimethylamides with Methyl Iodide (1994) (22)
- PIP-DB: the Protein Isoelectric Point database (2015) (22)
- Shuttling P3 from niobium to rhodium: the synthesis and use of Ph3SnP3(C6H8) as a P3- synthon. (2010) (22)
- Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. (2008) (22)
- Breaking chemistry's strongest bond: can three-coordinate [M{N(R)Ar}3] complexes cleave carbon monoxide? (2007) (21)
- Isolation of an elusive phosphatetrahedrane (2020) (21)
- Synthesis of cadmium pentamethylcyclopentadienyl complexes (1991) (21)
- Cofacial dicobalt complex of a binucleating hexacarboxamide cryptand ligand. (2010) (21)
- CHROMIUM(VI) NITRIDO COMPLEXES : REACTIONS WITH BRONSTED ACIDS AND SYNTHESIS OF ORGANOMETALLIC DERIVATIVES (1998) (21)
- A homoleptic molybdenum(IV) enolate complex: synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI). (2004) (21)
- Uptake of one and two molecules of CO2 by the molybdate dianion: a soluble, molecular oxide model system for carbon dioxide fixation (2014) (21)
- Terminal tungsten pnictide complex formation through pnictaethynolate decarbonylation. (2017) (21)
- Tin N-tert-Butylanilide Compounds (1995) (20)
- Functionalization of Intact Trimetaphosphate: A Triphosphorylating Reagent for C, N, and O Nucleophiles. (2019) (20)
- Anion-Receptor Mediated Oxidation of Carbon Monoxide to Carbonate by Peroxide Dianion. (2015) (20)
- Dihydrogen tetrametaphosphate, [P4O12H2]2-: synthesis, solubilization in organic media, preparation of its anhydride [P4O11]2- and acidic methyl ester, and conversion to tetrametaphosphate metal complexes via protonolysis. (2014) (19)
- Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus-Sulfur Material Having the Composition P2S, a Vulcanized Red Phosphorus That Is Yellow. (2018) (19)
- In pursuit of the molybdenum(III) tris(thiolate) fragment: unusual structure of a dimolybdenum mu-nitrido complex. (2000) (19)
- Bacterial Phosphate Granules Contain Cyclic Polyphosphates: Evidence from 31P Solid-State NMR. (2020) (19)
- Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate. (2009) (19)
- Trigonal-monopyramidale MIII-Komplexe des Typs [M(N3N)] (M = Ti, V, Cr, Mn, Fe; N3N = [(tBuMe2Si)CH2CH2]3N) (1992) (19)
- Orthophosphate and Sulfate Utilization for C-E (E = P, S) Bond Formation via Trichlorosilyl Phosphide and Sulfide Anions. (2019) (19)
- Dimolybdenum–μ-cyanide complexes supported by N - tert -butylanilide ligation: in pursuit of cyanide reductive cleavage (1999) (18)
- Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex. (2003) (18)
- Triatomic EP2 Triangles (E=Ge, Sn, Pb) as μ2:η3,η3‐Bridging Ligands (2005) (18)
- Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex. (2012) (18)
- Elucidation of a Sc(I) complex by DFT calculations and reactivity studies. (2003) (18)
- Base-catalyzed dinitrogen cleavage by molybdenum amides (2003) (17)
- Probing the Niobium Metallaaziridine Functionality (2001) (17)
- Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. (2011) (17)
- Small-Molecule Activation by Molybdaziridine Hydride Complexes: Mechanistic Sequence of the Small-Molecule Binding and Molybdaziridine Ring-Opening Steps (2004) (16)
- A bimetallic uranium mu-dicarbide complex: synthesis, X-ray crystal structure, and bonding. (2010) (16)
- Bicyclic dinuclear tris-(ditopic diphosphane) complexes of zerovalent group 10 metals (2012) (16)
- Rationalizing the different products in the reaction of N2 with three-coordinate MoL3 complexes. (2007) (16)
- A Nucleophilic Chromium(V) Dioxo Radical Anion. (1999) (15)
- Radical anionic versus neutral 2,2'-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands. (2014) (15)
- Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone. (2005) (14)
- Cleavage of CO by Mo[N(R)Ar]3 Complexes (2007) (14)
- The stannylphosphide anion reagent sodium bis(triphenylstannyl) phosphide: synthesis, structural characterization, and reactions with indium, tin, and gold electrophiles. (2014) (14)
- Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. (2005) (14)
- Phosphaalkenes as long-lived phosphorus cluster surface functional groups: intramolecular P=C addition to a niobium-supported P7 cage. (2008) (14)
- Functionalization reactions characteristic of a robust bicyclic diphosphane framework. (2013) (14)
- Synthesis and reversible reductive coupling of cationic, dinitrogen-derived diazoalkane complexes. (2009) (14)
- Phosphorus: From the Stars to Land & Sea (2014) (14)
- Nucleoside Tetra- and Pentaphosphates Prepared Using a Tetraphosphorylation Reagent are Potent Inhibitors of Ribonuclease A. (2019) (14)
- A tungstenVI nitride having a W2(mu-N)2 core. (2008) (13)
- Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity (2018) (13)
- Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. (2006) (13)
- Investigating CN- cleavage by three-coordinate M[N(R)Ar]3 complexes. (2008) (13)
- N‐Tert‐Alkyl‐anilides as Bulky Anciliary Ligands (2007) (13)
- Crystalline Metaphosphate Acid Salts: Synthesis in Organic Media, Structures, Hydrogen-Bonding Capability, and Implication of Superacidity. (2016) (13)
- The titanium tris-anilide cation [Ti(N[(t)Bu]Ar)3](+) stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4'-bipyridine dititanium complexes. (2015) (13)
- 6-Coordinate tungsten(VI) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles. (2008) (12)
- A pathway to diphosphorus from the dissociation of photoexcited tetraphosphorus (2013) (12)
- Synthesis of mer-trichlorotris(tetrahydrofuran) tungsten(III) by intermetal chlorine atom transfer (1998) (12)
- Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex. (2017) (11)
- An Oxide Ion Encapsulating Tetraholmium Tetrahedron Stabilized by Complexation with the “Carbons Apart” C2B4-Carborane Ligands (2003) (11)
- A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines (2018) (11)
- Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4-) and cyclo-trimetaphosphate ([P3O9]3-. (2014) (11)
- Cyclophosphates as ligands for cobalt(III) in water. (2011) (11)
- A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex. (2005) (11)
- Chemistry of C-Trimethylsilyl-Substituted Heterocarboranes. 30. Synthetic and Structural Studies on Oxide Ion Encapsulating Tetralanthanide Tetrahedra Surrounded by “Carbons Apart” C2B4-Carborane Ligands (Ln(III) = La, Nd, Gd, Tb, Ho, Lu) (2004) (11)
- Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes (2019) (10)
- Terminal Titanyl Complexes of Tri- and Tetrametaphosphate: Synthesis, Structures, and Reactivity with Hydrogen Peroxide. (2017) (10)
- Ultrafast Photoinduced Electron Transfer from Peroxide Dianion. (2015) (10)
- Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene (2015) (10)
- Coordination-mode control of bound nitrile radical complex reactivity: intercepting end-on nitrile-Mo(III) radicals at low temperature. (2009) (10)
- Cobalt Complexes Supported by cis-Macrocyclic Diphosphines: Synthesis, Reactivity, and Activity toward Coupling Carbon Dioxide and Ethylene (2017) (10)
- Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors. (2018) (9)
- Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer (2019) (9)
- Lost in Condensation: Poly-, Cyclo-, and Ultraphosphates. (2021) (9)
- An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom. (2017) (7)
- Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes. (2014) (7)
- Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙– (2016) (7)
- Facile synthesis of zero-, one-, and two-dimensional vanadyl pyrophosphates. (2011) (7)
- Molecular gallium arsenide phosphide clusters prepared from AsP(3), P(4), and [{GaC(SiMe(3))(3)}(4)]. (2010) (6)
- An Azophosphine Synthetic Equivalent of Mesitylphosphaazide and Its 1,3-Dipolar Cycloaddition Reactions. (2021) (6)
- Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction. (2006) (6)
- Portability of the RNNMo(3+) core : Application to the synthesis of dinitrogen-derived trialkoxymolybdenum organodiazenido complexes (2005) (6)
- Iconography : Six-coordinate uranium complexes featuring a bidentate anilide ligand (2010) (5)
- Dihydrogen Tetrametaphosphate, [P4O12H2]2—: Synthesis, Solubilization in Organic Media, Preparation of Its Anhydride [P4O11]2— and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via Protonolysis. (2015) (5)
- A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-triazolate Anion, HCPN3(.). (2016) (5)
- Pushing Single-Oxygen-Atom-Bridged Bimetallic Systems to the Right: A Cryptand-Encapsulated Co-O-Co Unit. (2015) (5)
- A highly reduced cyanogen ligand derived from cyanide reductive coupling. (2012) (5)
- Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh (E = S, Se, and Te) elimination. (2003) (5)
- Assembly and stabilization of {E(cyclo-P3)2} (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units. (2016) (5)
- A trigonal and hindered tertiary phosphine ligand rendered anionic by a niobate anchor: Formation of zwitterionic M(I) (M = Cu, Ag, Au, Rh) complexes (2011) (4)
- Frustrated Lewis Pair Stabilized Phosphoryl Nitride (NPO), a Monophosphorus Analogue of Nitrous Oxide (N2O). (2021) (4)
- Synthesis and characterization of the trimetaphosphate molybdenum tricarbonyl anion [(P3O9)Mo(CO)3]3- as its tris(bis(triphenylphosphine)iminium) salt (2012) (4)
- Electron-transfer studies of a peroxide dianion. (2014) (4)
- 3,5-Diphenyl-2-phosphafuran: Synthesis, Structure, and Thermally Reversible [4 + 2] Cycloaddition Chemistry. (2020) (4)
- Magnetic-Bottle and velocity-map imaging photoelectron spectroscopy of APS− (A=C14H10 or anthracene): Electron structure, spin-orbit coupling of APS•, and dipole-bound state of APS− (2018) (3)
- Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent (2017) (3)
- Taming phosphorus mononitride (2022) (3)
- Understanding the Nature and Properties of Hydrogen-Hydrogen Bonds: The Stability of a Bulky Phosphatetrahedrane as a Case Study. (2021) (3)
- Countercation Effect on CO2 Binding to Oxo Titanate with Bulky Anilide Ligands. (2018) (3)
- Methane and Benzene Activation via Transient (tBu3SiNH)2Zr=NSi-tBu3. (1989) (3)
- SYNTHETIC ROUTE TO WHITE PHOSPHORUS (P4 ) AND ARSENIC TRIPHOSPHIDE (AsP3 ) (2018) (3)
- Alleviating Strain in Organic Molecules by Incorporation of Phosphorus: Synthesis of Triphosphatetrahedrane. (2021) (3)
- Synthesis and Characterization of an Organochromium Compound Bearing Three Sterically Demanding Alkenyl Ligands (1999) (3)
- Reactions of Tri-tert-Butylphosphatetrahedrane as a Spring-Loaded Phosphinidene Synthon Featuring Nickel-Catalyzed Transfer to Unactivated Alkenes. (2022) (2)
- Taming Phosphorus Mononitride (PN) (2021) (2)
- Sustainable Production of Reduced Phosphorus Compounds: Mechanochemical Hydride Phosphorylation Using Condensed Phosphates as a Route to Phosphite (2021) (2)
- As–P vs. P–P Insertion in AsP 3 : Kinetic Control of the Formation of [AsP 3 NO] + (2019) (2)
- Microwave spectrum of arsenic triphosphide (2012) (2)
- 31P NMR Chemical Shift Tensors: Windows into Ruthenium Phosphinidene Complex Electronic Structures. (2021) (2)
- Photochemical Alkene Hydrophosphination with Bis(trichlorosilyl)phosphine. (2022) (2)
- Dimerization and Cycloaddition Reactions of Transient Tri-tert-butylphosphacyclobutadiene Generated by Lewis Acid Induced Isomerization of Tri-tert-butylphosphatetrahedrane. (2021) (2)
- Contrasting cyclo‐P3 Ligand Transfer Reactivity of Valence‐Isoelectronic Aryloxide Complexes [(P3)Nb(ODipp)3]– and [(P3)W(ODipp)3] (2014) (2)
- Beyond Triphosphates: Reagents and Methods for Chemical Oligophosphorylation. (2022) (2)
- Chemical Challenges that the Peroxide Dianion Presents to Rechargeable Lithium–Air Batteries (2022) (1)
- Terminal, Anionic Carbide, Nitride, and Phosphide Transition‐Metal Complexes as Synthetic Entries to Low‐Coordinate Phosphorus Derivatives (2006) (1)
- Supporting Information for the paper entitled , Multi-electron reactivity of a cofacial di-tin ( II ) cryptand : Partial reduction of sulfur and selenium and reversible generation of S 3 • − (2016) (1)
- Retraction: Pushing single-oxygen-atom-bridged bimetallic systems to the right: A cryptand-encapsulated Co-O-Co unit (Journal of the American Chemical Society (2015) 137:49 (15354-15357) DOI: 10.1021/jacs.5b09827) (2020) (1)
- A Niobaziridine Hydride System for White Phosphorus or Dinitrogen Activation and N- or P-Atom Transfer (2006) (1)
- A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO{subscript 2]/ethylene coupling (2016) (1)
- N-donor Base Adducts of P2O5 as Diphosphorylation Reagents (2021) (1)
- Reductive Cleavage and Related Reactions Leading to Molybdenum-Element Multiple Bonds: New Pathways Offered by Three-Coordinate Molybdenum(III) (1998) (1)
- Synthesis of α,δ-Disubstituted Tetraphosphates and Terminally-Functionalized Nucleoside Pentaphosphates. (2020) (1)
- Staudinger Reactivity and Click Chemistry of Anthracene (A)-Based Azidophosphine N3PA. (2022) (1)
- SYNTHESIS OF SELECTED TRANSITION METAL AND MAIN GROUP COMPOUNDS WITH SYNTHETIC APPLICATIONS (2018) (1)
- Synthesis and Characterization of P2N3‐: An Aromatic Ion Composed of Phosphorus and Nitrogen. (2015) (1)
- Synthetic investigations featuring amidometallic complexes (1993) (1)
- RNase A in complex with p5U (2019) (0)
- Pushing MOM to the right: a cryptand-encapsulated Co–O–Co unit (2015) (0)
- Retraction of "Pushing Single-Oxygen-Atom-Bridged Bimetallic Systems to the Right: A Cryptand-Encapsulated Co-O-Co Unit". (2020) (0)
- Uptake of one and two molecules of CO[subscript 2] by the molybdate dianion: a soluble, molecular oxide model system for carbon dioxide fixation (2014) (0)
- UTILIZATION OF MICROWAVE SPECTROSCOPY TO IDENTIFY AND PROBE REACTION DYNAMICS OF HSNO, A CRUCIAL BIOLOGICAL SIGNALING MOLECULE (2016) (0)
- Dihydrogen cleavage by a dimetalloxycarbene-borane frustrated Lewis pair. (2021) (0)
- Bis(μ[subscript 2]-η[superscript 2]:η[superscript 2]-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo-Mo) (2011) (0)
- An Anthracene-based Precursor for Sulfur Monoxide Delivery: Thermal Release, Spectroscopic Identification and Transfer Reactivity (2020) (0)
- CCDC 297821: Experimental Crystal Structure Determination (2006) (0)
- Identification of Reactive Intermediates Relevant to Dimethylgermylene Group Transfer Reactions of an Anthracene-Based Precursor (2019) (0)
- Introducing N-Heterocyclic Iminophosphoranes (NHIPs): Synthesis by [3 + 2] Cycloaddition of Azophosphines with Alkynes and Reactivity Studies. (2022) (0)
- On the incompatibility of lithium – O 2 battery technology with CO 2 † (2017) (0)
- Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide Q 1 † (2014) (0)
- The titanium tris-anilide cation [Ti(N[[superscript t]Bu]Ar)[subscript 3]][superscript +] stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4'-bipyridine dititanium complexes (2015) (0)
- Shuttling P(3) [P subscript 3] from Niobium to Rhodium: The Synthesis and Use of Ph(3)SnP(3)(C(6)H(8)) [Ph subscript 3 Sn P subscript 3 (C subscript 6 H subscript 8)] as a P(3) (-) [P subscript 3 superscript 1-] Synthon (2010) (0)
- Inside Cover: An Isolable and Monomeric Phosphorus Radical That Is Resonance‐Stabilized by the Vanadium(IV/V) Redox Couple (Angew. Chem. Int. Ed. 17/2007) (2007) (0)
- RNase A in complex with p5A (2019) (0)
- Lithium superoxide encapsulated in a benzoquinone anion matrix. (2021) (0)
- Supplementary material from "Alan Davison. 24 March 1936 — 14 November 2015" (2017) (0)
- A LIGAND FIELD THEORY VIEW OF THE ELECTRONIC STRUCTURE OF CaX (X=F, Cl, Br, I, AND O) (2020) (0)
- Bis(μ2-η2:η2-2,4,6-trimethylbenzonitrile)bis[(N-isopropyl-3,5-dimethylanilido)molybdenum(III)](Mo—Mo) (2011) (0)
- Multi-electron reactivity of a cofacial di-tin(I) cryptand: partial reduction of sulfur and selenium and reversible generation of S[subscript 3][superscript ˙−] (2016) (0)
- Synthesis of an Anthracene-Based Macrocyclic Diphosphine Ligand (2020) (0)
- Hydrocarbon Activation via Reversible 1,2-RH-Elimination from ( tBu3SiNH)3ZrR: Synthetic, Structural, and Mechanistic Investigations. (2010) (0)
- Who's who in Chemical Science (2011) (0)
- Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins (2022) (0)
- ( Tri-tert-butylsily 1 ) imido Complexes of Titanium : Benzene C-H Activation and Structure of (2001) (0)
- RNase A in complex with cp4pA (2019) (0)
- Negative ion photoelectron spectroscopy of P 2 N 3 (cid:1) : electron a ffi nity and electronic structures of P 2 N 3 c † (2016) (0)
- CCDC 710857: Experimental Crystal Structure Determination (2010) (0)
- Innentitelbild: An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IV/V) Redox Couple (Angew. Chem. 17/2007) (2007) (0)
- 2 ] – : Synthesis , Solubilization in Organic Media , Preparation of Citation (2014) (0)
- Triatomic EP2 triangles (E=Ge, Sn, Pb) as mu2:eta3,eta3-bridging ligands. (2005) (0)
- RNase A in complex with hexametaphosphate (2019) (0)
- MIT Open Access Articles A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-Triazolate Anion, HCPN₃ (2022) (0)
- Generation of Vibrationally Excited HCP from a Stable Synthetic Precursor (2015) (0)
- Stabilized Molecular Diphosphorus Pentoxide, P2O5L2 (L = N-Donor Base), in the Synthesis of Condensed Phosphate-Organic Molecule Conjugates. (2023) (0)
- CCDC 1524850: Experimental Crystal Structure Determination (2017) (0)
- Atom-abstraction as a synthetic tool (1997) (0)
- Synthesis and characterization of the trimetaphosphate molybdenum tricarbonyl anion (2012) (0)
- Dihydrogen Tetrametaphosphate, [P[subscript 4]O][subscript 12]H[subscript 2]][superscript 2] –: Synthesis, Solubilization in Organic Media, Preparation of its Anhydride [P[subscript 4]O[subscript 11]][superscript 2] – and Acidic Methyl Ester, and Conversion to Tetrametaphosphate Metal Complexes via (2014) (0)
- Alan Davison. 24 March 1936 — 14 November 2015 (2017) (0)
- Reductive trapping of dinitrogen by molybdenum tris anilide to form a dinitrogen anion and chemistries thereof (1999) (0)
- Facile synthesis of mononuclear early transition-metal complexes of κ[superscript 3]cyclo-tetrametaphosphate ([P[subscript 4]O[subscript 12]][superscript 4−]) and cyclo-trimetaphosphate ([P[subscript 3]O[subscript 9]][superscript 3−]) (2014) (0)
- Negative ion photoelectron spectroscopy of P[subscript 2]N[subscript 3]−: electron affinity and electronic structures of P[subscript 2]N[subscript 3]˙ (2016) (0)
- On the Incompatibility of lithium – O Battery Technology with CO (2017) (0)
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