Claude F. Bernasconi

Claude F. Bernasconi's AcademicInfluence.com Rankings

Chemistry

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#6096

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Chemical Engineering

#683

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#703

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Physical Chemistry

#810

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#866

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chemistry Degrees

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Chemistry

Claude F. Bernasconi's Degrees

PhD Chemistry California Institute of Technology
Masters Chemical Engineering Stanford University
Bachelors Chemical Engineering Stanford University

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Claude F. Bernasconi's Published Works

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Published Works

Intrinsic barriers of reactions and the principle of nonperfect synchronization (1987) (177)
The Principle of Non-perfect Synchronization (1992) (145)
Nucleophilic addition to olefins. Kinetics and mechanism (1989) (113)
The principle of nonperfect synchronization: more than a qualitative concept? (1992) (109)
Kinetic and spectral study of some reactions of 2,4,6-trinitrotoluene in basic solution. I. Deprotonation and Janovsky complex formation (1971) (78)
Kinetic behavior of short-lived anionic .sigma. complexes (1978) (72)
The principle of imperfect synchronization: I. Ionization of carbon acids (1985) (71)
Recent advances in our mechanistic understanding of S(N)V reactions. (2009) (57)
Intermediates in nucleophilic aromatic substitution. IV. Kinetic study of the interaction of 1,3,5-trinitrobenzene with the lyate ions of water, methanol, and ethanol in the respective solvents (1970) (49)
Developing the physical organic chemistry of Fischer carbene complexes (1998) (47)
Carbanion Stabilization by Adjacent Sulfur: Polarizability, Resonance, or Negative Hyperconjugation? Experimental Distinction Based on Intrinsic Rate Constants of Proton Transfer from (Phenylthio)nitromethane and 1-Nitro-2-phenylethane (1998) (43)
Influence of the o-nitro group on base catalysis in nucleophilic aromatic substitution. Reactions in Benzene Solution. (1976) (42)
Intermediates in nucleophilic aromatic substitution. 20. Rate-limiting proton transfer in the formation of Meisenheimer complexes between 1,3,5-trinitrobenzene and amines. The effect of dimethyl sulfoxide on proton-transfer rates. Relative leaving-group abilities of amines and alkoxide ions (1979) (42)
Nucleophilic addition to olefins. 18. Kinetics of the addition of primary amines and .alpha.-effect nucleophiles to benzylidene Meldrum's acid (1986) (41)
Stopped-flow kinetic investigations of the activation of soybean lipoxygenase-1 and the influence of inhibitors on the allosteric site. (2003) (38)
Nucleophilic addition to olefins. Part 23. High intrinsic rate constant and large imbalances in the thiolate ion addition to substituted .alpha.-nitrostilbenes (1988) (37)
The role of solvent reorganization in proton transfer and nucleophilic addition reactions (1982) (36)
Kinetics of ionization of nitromethane and phenylnitromethane by amines and carboxylate ions in Me2SO-water mixtures. Evidence of ammonium ion-nitronate ion hydrogen bonded complex formation in Me2SO-rich solvent mixtures (1988) (36)
Magnesium ion catalyzed P-N bond hydrolysis in imidazolide activated nucleotides. Relevance to template-directed synthesis of polynucleotides (1989) (35)
Kinetics of ionization of 1,3-indandione in methyl sulfoxide-water mixtures. Solvent effect on intrinsic rates and Broensted coefficients (1986) (35)
Kinetic dissection of individual steps in the poly(C)-directed oligoguanylate synthesis from guanosine 5'-monophosphate 2-methylimidazolide. (1993) (33)
The Physical Organic Chemistry of Fischer Carbene Complexes (2003) (31)
Kinetics of the Reactions of Methoxybenzylidene Meldrum's Acid with Thiolate Ions, Alkoxide Ions, OH-, and Water in Aqueous DMSO. Detection and Kinetic Characterization of the SNV Intermediate (1998) (31)
Changing views on the mechanism of base catalysis in nucleophilic aromatic substitution. Kinetics of reactions of nitroaryl ethers with piperidine and with n-butylamine in aqueous dioxane (1977) (30)
KINETICS OF THE REACTIONS OF BETA -METHOXY-ALPHA -NITROSILBENE WITH METHOXYAMINE AND N-METHYLMETHOXYAMINE. DIRECT OBSERVATION OF THE INTERMEDIATE IN N UCLEOPHILIC VINYLIC SUBSTITUTION (1995) (29)
Is There a Transition-State Imbalance for Proton Transfers in the Gas Phase? Ab Initio Study of the Carbon-to-Carbon Proton Transfer from Acetaldehyde to Its Enolate Ion (1994) (29)
Tryptophan 500 and arginine 707 define product and substrate active site binding in soybean lipoxygenase-1. (2004) (28)
The Principle of Nonperfect Synchronization: Recent Developments (2011) (27)
Nucleophilic addition to olefins. 16. Unusual substituent effects in the reaction of amines with .beta.-nitrostyrenes. Solvent effect on intrinsic rate constants (1986) (26)
Intermediates in nucleophilic aromatic substitution. XIV. Spiro Meisenheimer complexes derived from N,N-dimethylethylenediamine. Kinetics in aqueous dimethyl sulfoxide (1975) (25)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 16.1 Reactions of (CO)5MC(OR)Ph (M = Cr or W; R = Me or Et) with Thiolate Ions in Aqueous Acetonitrile. Complete Kinetic Dissection of the Two-Step Mechanism (1999) (24)
Intermediates in nucleophilic aromatic substitution. II. Temperature-jump study of the interaction of 1,3,5-trinitrobenzene with aliphatic amines in 10% dioxane-90% water. Concurrent nucleophilic attack on the aromatic carbon and on the nitro group (1970) (24)
INTRINSIC BARRIERS AND TRANSITION STATE STRUCTURES IN THE GAS PHASE CARBON-TO-CARBON IDENTITY PROTON TRANSFERS FROM NITROMETHANE TO NITROMETHIDE ANION AND FROM PROTONATED NITROMETHANE TO ACI-NITROMETHANE. AN AB INITIO STUDY (1997) (24)
Ionization of 9-cyano- and 9-(carbomethoxy)fluorene in dimethyl sulfoxide−water mixtures. How important is solvent reorganization? (1987) (24)
Kinetics of Reactions of Piperidine with Ethers of 2,4-Dinitrophenol in 10% Dioxane-90% Water. Dependence of Base Catalysis on the Group Displaced1 (1965) (24)
Kinetics of amine addition to benzylidenemalonodialdehyde in 50% dimethyl sulfoxide - 50% water (1991) (23)
Intermediates in nucleophilic aromatic substitution. VII. Stopped-flow temperature-jump study of the transient 1,3-methoxide ion adduct of 2,4,6-trinitroanisole in methanol (1971) (23)
Physical organic chemistry of transition metal carbene complexes. 2. Kinetics and mechanism of reactions of [methoxy(phenyl)carbene]pentacarbonylchromium(0) with primary aliphatic amines in aqueous acetonitrile (1993) (21)
Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions (1990) (21)
Nucleophilic addition to olefins. 6. Structure-reactivity relationships in the reactions of substituted benzylidene Meldrum's acids with water, hydroxide ion, and aryloxide ions (1982) (21)
Rate of protonation of 2,6-di-tert-butylpyridine by the hydronium ion. Steric hindrance to proton transfer (1979) (20)
Kinetics of deprotonation of arylnitromethanes by benzoate ions in acetonitrile solution. Effect of equilibrium and nonequilibrium transition state solvation on intrinsic rate constants of proton transfers (1992) (20)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 7.1 Kinetics of Hydrolysis of (CO)5MC(OR)Ph (M = Cr, W; R = Me, Et) and (CO)5Cr(OMe)CHCHPh in Aqueous Acetonitrile (1997) (20)
Rates of deprotonation of (4-nitrophenyl)acetonitrile and (2,4-dinitrophenyl)acetonitrile in 50% dimethyl sulfoxide-50% water (1983) (20)
Intermediates in nucleophilic aromatic substitution. IX. 1:1 and 1:2 Sulfite complexes of 1,3,5-trinitrobenzene. Cis-trans isomerism in the 1:2 complex (1973) (20)
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Cyanamide in 50 DMSO−50 Water. Failure to Detect the SNV Intermediate (1999) (19)
Kinetics of reversible thiolate ion addition to substituted .beta.-nitrostyrenes in water. Radicaloid transition state or principle of nonperfect synchronization? (1992) (19)
Ionization of Acetylacetone in Me2SO—Water Mixtures. Reactivity—Selectivity Principle or Principle of Imperfect Synchronization? (1985) (19)
Intermediates in nucleophilic aromatic substitution. XI. Spiro Meisenheimer complex of N, N'-dimethyl-N-picrylethylenediamine. Partially rate-limiting proton transfer of complex formation. Temperature-jump study (1974) (19)
Nucleophilic addition to olefins. 21. Substituent and solvent effects on the reaction of benzylidene Meldrum's acids with piperidine and morpholine (1987) (18)
Kinetics of the Reactions of Benzylidene Meldrum's Acid with Thiolate and Alkoxide Ions in Aqueous Dimethyl Sulfoxide. (1998) (17)
Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 20: 1 Kinetics and Mechanism of Reactions of (CO) 5 M C(OMe)C 6 H 4 X (M=Cr and W) with Primary Aliphatic Amines in Aqueous Acetonitrile. Substituent Effects (2000) (17)
Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution (1989) (17)
Intermediates in nucleophilic aromatic substitution. 16. Toward a complete characterization of the mechanism of nucleophilic aromatic substitution by an amine. Kinetics of spiro Meisenheimer complexes derived from N-methylethanolamine (1976) (17)
Intermediates in nucleophilic aromatic substitution. I. Temperature jump study of the decomposition of 1,1-dimethoxy- 2,4-dinitrocyclohexadienate in methanol (1968) (17)
Intermediates in nucleophilic aromatic substitution. X. Synthesis of N-methyl-.beta.-aminoethyl nitroaryl ethers via an unusual Smiles rearrangement (1973) (17)
Transition State Imbalances in Gas Phase Proton Transfers. Ab Initio Study of the Carbon-to-Carbon Proton Transfer from the Protonated Acetaldehyde Cation to Acetaldehyde Enol (1996) (16)
Deprotonation of arylnitromethanes. Higher intrinsic rate constants with thiolate ions than with oxyanions or amines as the proton acceptors. Hydrogen bonding in the transition state and desolvation of the base as competing factors in proton transfer at carbon (1993) (16)
Kinetics of the deprotonation of methylnitroacetate by amines: unusually high intrinsic rate constants for a nitroalkane. (2007) (16)
Marcus-grunwald theory and the nitroalkane anomaly (1988) (16)
Nucleophilic addition to olefins. 8. Addition of piperidine, morpholine, and n-butylamine to .alpha.-cyano-4-nitrostilbene and .alpha.-cyano-2,4-dinitrostilbene. Kinetics and equilibria in 50% dimethyl sulfoxide-50% water (1983) (16)
Rate and equilibrium constants of ionization of (.alpha.-cyanodiphenylmethane)bis[tricarbonylchromium(0)] in dimethyl sulfoxide-water mixtures. Unusual solvent effect on the intrinsic rate constant (1988) (16)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 15.1 Kinetic and Thermodynamic Acidities of (Methylthiomethoxycarbene)pentacarbonyl Complexes of Chromium and Tungsten in Aqueous Acetonitrile (1999) (15)
Intermediates in nucleophilic aromatic substitution. 17. Kinetics of spiro Meisenheimer complexes. Effect of ring size (1977) (15)
Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions. (2008) (15)
Kinetic solvent isotope effect and proton inventory study of the carbon protonation of amine adducts of benzylidene Meldrum's acid and other Meldrum's acid derivatives: evidence for concerted intramolecular proton transfer (1987) (15)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 18.1 Kinetics of Reversible Cyclization of the Fischer Carbene Complexes (CO)5MC(SCH2CH2OH)Ph and (CO)5MC(OCH2CH2OH)Ph (M = Cr, W) in Aqueous Acetonitrile (2000) (15)
Nucleophilic addition to olefins. 14. Kinetics of hydrolysis of benzylidene-1,3-indandione (1985) (14)
Physical organic chemistry of transition metal carbene complexes. 3. Thermodynamic and kinetic acidities of chromium carbenes (CO)5Cr:C(OCH3)CH3 and (CO)5Cr:C(OCH3)CH2Ph in aqueous acetonitrile (1993) (14)
Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances (1996) (14)
Nucleophilic addition to olefins. 12. Solvent-induced change in the rate-limiting step of the hydrolysis of benzylidenemalononitrile in acidic dimethyl sulfoxide-water solution (1985) (14)
Nucleophilic additions to olefins. 19. Abnormally high intrinsic barrier in the reaction of piperidine and morpholine with benzylideneacetylacetone. (1986) (14)
Kinetics of the electron transfer reactions of azaviolene radical ions. I (1974) (14)
Kinetics of the reactions of [p-nitrophenoxy(phenyl)carbene]pentacarbonylchromium(0) with aryloxide ions, hydroxide ion, and water in aqueous acetonitrile. Concerted or stepwise? (2007) (14)
The CF3CH2O- Adducts of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene and .beta.-Methoxy-.alpha.-nitrostilbene, and the MeO- Adducts of .beta.-Methoxy-.alpha.-nitrostilbene. Kinetics of Competition between Protonation and Acid Catalyzed Alkoxide Ion Departure (1995) (14)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 9.1 Thermodynamic and Kinetic Acidity of (2-Oxacyclopentylidene)pentacarbonylchromium(0) in Aqueous Acetonitrile (1997) (14)
Nucleophilic addition to olefins. 20. Large transition state imbalances in the reaction of .alpha.-nitrostilbenes with amines (1987) (14)
Nucleophilic addition to olefins. Part 24. Is there a transition-state imbalance in malononitrile anion forming reactions? Kinetics of piperidine and morpholine addition to substituted benzylidenemalononitriles in various Me2SO-water mixtures (1989) (14)
Nucleophilic addition to olefins. 2. Reaction of benzylidene Meldrum's acid with water, hydroxide ion, and aryloxide ions. Complete kinetic analysis of the hydrolytic cleavage of the carbon:carbon double bond (1980) (13)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 8.1 Kinetic and Thermodynamic Acidities of Alkoxyalkylcarbene Pentacarbonyl Complexes of Cr, Mo, and W in Aqueous Acetonitrile. Dependence on Metal, Alkyl Group, and Alkoxy Group (1997) (13)
Nucleophilic addition to olefins. Part 25. Kinetics of hydrolysis of substituted .beta.-nitrostyrenes. Transition-state imbalances and intrinsic rate constants for three different types of nitronate ion forming processes. Relevance to the nitroalkane anomaly (1989) (13)
Chapter 3 – Relaxation Times in Two-Step Systems (1976) (13)
Kinetic and thermodynamic acidities of substituted 1-benzyl-1-methoxy-2-nitroethylenes. Strong reduction of the transition state imbalance compared to other nitroalkanes. (2003) (13)
Reactions that generate aromatic molecules: is aromatic stabilization less or more advanced than bond changes at the transition state? Kinetic and thermodynamic acidities of rhenium carbene complexes. (2003) (13)
Kinetics of amine addition to benzylidene-1,3-indandione and other vinylic .beta.-diketones. Effect of cyclic structure and steric strain on intrinsic rate constants (1991) (13)
REACTION OF ANIONS WITH ACTIVATED OLEFINS IN THE GAS PHASE. A FLOWING AFTERGLOW-SELECTED ION FLOW TUBE STUDY (1990) (13)
Kinetics of reaction of piperidine with substituted phenyl ethers of 2,4-dinitrophenol in 60% dioxane N-40% water. Base catalysis as a function of the group displaced (1970) (12)
Physical organic chemistry of transition metal carbene complexes. 25. Kinetic and thermodynamic acidities of substituted (methylthiophenylcarbene)pentacarbonyl tungsten(0) and (Benzoxymethylcarbene)pentacarbonyl tungsten(0) in aqueous acetonitrile. Evidence for transition state imbalances. (2002) (12)
Free energies of transfer of carbon acids and their conjugate carbanions from water to Me/sub 2/SO-water mixtures (1988) (12)
Kinetic behavior of tetrachlorocyclopentadienyl-type anions. Deprotomation of 1,2,3,4-tetrachloro-1,3-cyclopentadiene and nucleophilic addition to 1,2,3,4-tetrachloro-6-phenylfulvene in 50% Me2SO/50% water (1990) (12)
Physical organic chemistry of transition metal carbene complexes. IV: Kinetics and equilibria of methoxide ion addition to [methoxy(phenyl)carbene]pentacarbonylchromium(0) and [methoxy(phenyl)carbene]pentacarbonyltungsten(0) (1994) (12)
Proton transfer from carbon acids to carbanions. 1. Reactions of various carbon acids with the anions of substituted benzylmalononitriles in 90% Me2SO-10% water. Determination of intrinsic barriers of identity reactions from the Marcus relationship (1993) (12)
Reactions of substituted (methylthio)benzylidene Meldrum's acids with secondary alicyclic amines in aqueous DMSO. Evidence for rate-limiting proton transfer. (2004) (12)
Kinetics of Proton Transfer from Benzoylnitromethane and 1,2-Diphenyl-2-nitroethanone to Various Bases. Resonance, Inductive, Solvation, Steric, and Transition State Hydrogen-Bonding Effects on Intrinsic Rate Constants. (1997) (12)
Nucleophilic addition to olefins. 4. Structure-reactivity relationships in the reactions of amines with substituted benzylidene Meldrum's acids. Evidence for intramolecular proton transfer to carbon (1980) (12)
Intermediates in nucleophilic aromatic substitution. XIII. Normal coordinate analysis of coupled reactions. Application to anionic .sigma. complexes of 1,3,5-trinitrobenzene with hydroxide and alkoxide ions in water, methanol-water, and ethanol-water mixtures (1974) (12)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 5. Kinetics and Mechanism of Hydrolysis of (CO)5Cr:C(OCH3)CH3 and (CO)5Cr:C(OCH2CH3)CH3 in Aqueous Acetonitrile (1995) (12)
Proton transfer from (methoxymethylcarbene)pentacarbonylchromium(0) in aqueous solution (1989) (11)
Kinetics of reactions of hydroxide ion and water with .beta.-X-substituted .alpha.-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution (1991) (11)
Proton transfers in aromatic and antiaromatic systems. How aromatic or antiaromatic is the transition state? An ab initio study. (2008) (11)
Anomalous rates of proton transfer to and from nitrogen and carbon in the reactions of amines with 1,1-dinitro-2,2-diphenylethylene (1979) (11)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION. 18. THE ELUSIVE 1,1‐MEISENHEIMER COMPLEX FROM 2,4,6‐TRINITROANISOLE AND ARYLOXIDE IONS. A STOPPED‐FLOW TEMPERATURE‐JUMP STUDY (1978) (11)
Nucleophilic addition to olefins. 11. Kinetics of the reversible hydrolysis of benzylidenemalononitrile in water (1984) (11)
DETECTION AND KINETIC CHARACTERIZATION OF SNV INTERMEDIATES. REACTIONS OF THIOMETHOXYBENZYLIDENE MELDRUM'S ACID WITH THIOLATE IONS, ALKOXIDE IONS, OH- , AND WATER IN AQUEOUS DMSO (1999) (11)
Physical Organic Chemistry of Transition Metal Complexes. 31. Nucleophilic Attachment of the Malononitrile Anion to Fischer Carbene Complexes (2004) (11)
PHYSICAL ORGANIC CHEMISTRY OF TRANSITION METAL CARBENE COMPLEXES. 14.1 THERMODYNAMIC ACIDITY MEASUREMENTS OF FISCHER CARBENE COMPLEXES IN ACETONITRILE (1998) (11)
Kinetics of Reversible Carbon Deprotonation of 2-Nitroethanol and 2-Nitro-1,3-propanediol by Hydroxide Ion, Water, Amines, and Carboxylate Ions. A Normal Broensted .alpha. Despite an Imbalanced Transition State (1995) (10)
Does aromaticity in a reaction product increase or decrease the intrinsic barrier? Kinetics of the reversible deprotonation of benzofuran-3(2H)-one and benzothiophene-3(2H)-one. (2007) (10)
Reactions of [aryloxy(phenyl)carbene]pentacarbonylchromium(0) complexes with thiolate ions. Decreasing reactivity with increasing basicity of the nucleophile. (2007) (10)
Hydrolysis of α-Alkyl-α-(methylthio)methylene Meldrum's Acids. A Kinetic and Computational Investigation of Steric Effects (2006) (10)
Intermediates in nucleophilic aromatic substitution. 15. Spiro Meisenheimer complex from catechol 2,4,6-trinitrophenyl ether. Rate-limiting proton transfer as a consequence of a very fast intramolecular nucleophilic attack (1976) (10)
Kinetics of proton transfer of 3,5-heptanedione, 2,6-dimethyl-3,5-heptanedione, and dibenzoylmethane with amines in 50% dimethyl sulfoxide-50% water. Effect of steric crowding and .pi.-overlap on intrinsic rate constants (1991) (10)
Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .be (1994) (10)
Nucleophilic addition to activated olefins. 3. Reactions of piperidine and morpholine with benzylidenemalononitrile in 50% dimethyl sulfoxide-50% water. Intrinsic barriers in nucleophilic additions (1980) (10)
Stereoelectronic and conformational effects in Meisenheimer complexes. Intrinsic reactivities of spiro vs. 1,1-dimethoxy and 1-methoxy-1-phenoxy complexes (1982) (9)
Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid. (1999) (9)
Kinetic and Thermodynamic Acidity of [Cp(NO)(PPh3)Re(2,5-dimethyl-3-thienyl)carbene]+. Transition State Imbalance and Intrinsic Barriers† (2006) (9)
PHYSICAL ORGANIC CHEMISTRY OF TRANSITION METAL CARBENE COMPLEXES. 10. OPPOSING EFFECTS OF ALPHA -ALKYL GROUPS ON THE THERMODYNAMIC AND KINETIC ACIDITI ES OF (CO)5CR=C(OME)CHR'R -TYPE FISCHER CARBENE COMPLEXES IN AQUEOUS ACETON ITRILE. ANALOGY TO THE NITROALKANE ANOMALY (1997) (9)
Intermediates in nucleophilic aromatic substitution. 18. The elusive 1,1-Meisenheimer complex from 2,4,6-trinitroanisole and aryloxide ions. A stopped-flow temperature-jump study (1978) (9)
Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile (1993) (9)
Unraveling structure-reactivity relationships in SNV reactions: kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)-1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl beta-methylthio-alpha-nitrocinnamate with OH- and thiolate ions in aqueous DMSO (2001) (9)
Nucleophilic addition to olefins. 9. Kinetics of the reaction of benzylidenemalononitrile with malononitrile anion (1984) (9)
Kinetics of reactions of amines with .alpha.-nitro-.beta.-substituted-stilbenes in 50% dimethyl sulfoxide-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions (1990) (9)
Kinetics of proton transfer from benzo[b]-2,3-dihydrofuran-2-one and benzo[b]-2,3-dihydrothiophene-2-one. Effect of anion aromaticity on intrinsic barriers. (2006) (9)
Nucleophilic addition to olefins. 15. Solvent and substituent effects on the hydrolysis of benzylidenemalononitriles in basic dimethyl sulfoxide-water solutions. (1986) (9)
Kinetics and mechanism of reactions of substituted (methylthio)benzylidene Meldrum's acids with primary amines in aqueous DMSO (2006) (9)
Intrinsic Rate Constants for Proton Transfer from a Monoketone to Amine Bases and Electrostatic Effects on the Intrinsic Rate Constants for the Deprotonation of Cationic Ketones by OH (1999) (8)
Effect of transition state aromaticity and antiaromaticity on intrinsic barriers of proton transfers in aromatic and antiaromatic heterocyclic systems; an ab initio study. (2010) (8)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 26.† Kinetics and Mechanism of the Reactions of [Phenyl(thiomethyl)carbene]pentacarbonylchromium(0) with Amines in Aqueous Acetonitrile (2003) (8)
Intermediates in nucleophilic aromatic substitution. VI. Kinetic evidence of intramolecular hydrogen bonding in Meisenheimer complexes (1971) (8)
Intermediates in nucleophilic aromatic substitution. 22. Kinetics of acid-catalyzed breakdown of spiro Meisenheimer complexes (1983) (8)
Intermediates in nucleophilic aromatic substitution. 19. Multiple structure-reactivity relationships in the acid-catalyzed breakdown of Meisenheimer complexes (1978) (8)
The Principle of Nonperfect Synchronization: How Does It Apply to Aromatic Systems? (2004) (8)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 6. Kinetics and Mechanism of the Thermal and Photochemical Hydrolysis of (CO)5M:C(OMe)CH2Ph (M = Cr, W) in Aqueous Acetonitrile (1995) (8)
Kinetics of reactions of amines with ethers of 2,4-dinitrophenol in 10 percent dioxane-90 percent water. Dependence of base catalysis on the entering amine and the leaving group (1967) (8)
Physical organic chemistry of transition metal carbene complexes. Part11.1 Kinetics and mechanism of the hydrolysis of(2-oxacyclopentylidene)pentacarbonylchromium(0) in aqueous acetonitrile (1997) (8)
Computer simulation in template-directed oligonucleotide synthesis (2005) (8)
Reaction of benzylidenemalonaldehyde with water and hydroxide ion (1986) (8)
Intermediates in nucleophilic aromatic substitution. V. Kinetic study of Meisenheimer complexes of 1,3,5-trinitrobenzene with hydroxide and alkoxide ions in ethanol-water and methanol-water mixtures (1971) (7)
Nucleophilic addition to olefins. 5. Reaction of 1,1-dinitro-2,2-diphenylethylene with water and hydroxide ion in 50% dimethyl sulfoxide-50% water. Complete kinetic analysis of hydrolytic cleavage of the C:C double bond in acidic and basic solution (1981) (7)
Base catalysis of the reaction of morpholine with 2,4-dinitrophenyl phenyl ether in 10 percent dioxane-90 percent water (1967) (7)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 29.† Kinetics of Reactions of [Ethoxy(phenyl)carbene]pentacarbonylchromium(0) and [Ethoxy(phenyl)(Cr(CO)3)carbene]pentacarbonylchromium(0) with Water, OH-, and Amines. Mechanistic Changes Induced by the Cr(CO)3 Group (2004) (7)
RATES OF IONIZATION OF 1,1-DINITROETHANE IN 50% DIMETHYL SULFOXIDE-50% WATER. SOLVENT EFFECT ON PROTON TRANSFER (1979) (7)
Chapter 2 – Relaxation Times in Single-Step Systems (1976) (7)
Intermediates in nucleophilic aromatic substitution. VIII. Temperature-jump and equilibrium study of the spiro Meisenheimer complex of N-2-hydroxyethyl-N-methyl-2,4-dinitroaniline (1973) (7)
Carbon-to-carbon identity proton transfers from propyne, acetimide, thioacetaldehyde, and nitrosomethane to their respective conjugate anions in the gas phase. An ab initio study. (2001) (7)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 13.1 Kinetics of Proton Transfer from (5-Methyl-2-oxacyclopentylidene)pentacarbonylchromium(0) and Hydrolysis of Its Conjugate Anion in Aqueous Acetonitrile (1998) (6)
Broensted coefficients for intramolecularly assisted carbon protonation of amine adducts of benzylidene Meldrum's acid (1986) (6)
Spectroscopic and kinetic evidence for an accumulating intermediate in an SNV reaction with amine nucleophiles. Reaction of methyl beta-methylthio-alpha-nitrocinnamate with piperidine and morpholine. (2007) (6)
Proton transfers from carbon acids activated by pi-acceptors. Changes in intrinsic barriers and transition state imbalances induced by a cyano group. An ab initio study. (2003) (6)
Physical organic chemistry of transition metal carbene complexes. 24. Thermodynamic and kinetic acidities of phenyl-substituted (benzylmethoxycarbene)pentacarbonylchromium(0) complexes. Is there a transition-state imbalance? (2002) (6)
Carbon-to-carbon identity proton transfer from allene, ketene, ketenimine, and thioketene to their respective conjugate anions in the gas phase. An ab initio study. (2001) (6)
Proton Transfer from Carbon Acids to Carbanions. 2. Reaction of Phenylnitromethane with Carbanions, Enolate, and Nitronate Ions in 90% Me2SO-10% Water. Carbon to Carbon or Carbon to Oxygen Proton Transfer? Test of the Marcus Equation (1994) (6)
Nucleophilic addition to olefins. 10. Kinetics of cleavage of the piperidine and morpholine adducts of .alpha.-cyano-4-nitrostilbene and .alpha.-cyano-2,4-dinitrostilbene (1984) (6)
When is intramolecular proton transfer between carbon and nitrogen or oxygen observable (1982) (5)
Complete kinetic analysis of the A-SE2 mechanism of acid-catalyzed addition of methanol to an olefinic double bond (1974) (5)
Additions and Corrections - Kinetics of the Electron Transfer Reactions of Azaviolene Radical Ions. 2. Correlation with the Marcus Theory. The Question of Concerted Acid-Base Catalysis. (1977) (5)
Physical organic chemistry of transition metal carbene complexes. 23. Kinetic and thermodynamic acidities of cationic benzothienyl- and selenylcarbene complexes of rhenium in aqueous acetonitrile. (2001) (5)
Kinetics of hydrolysis of benzylideneacetylacetone (1994) (5)
Kinetic and thermodynamic acidities of pentacarbonyl(cyclobutenylidene)chromium complexes. Effect of antiaromaticity in the conjugate anion. An experimental and computational study. (2004) (5)
PHYSICAL ORGANIC CHEMISTRY OF TRANSITION METAL CARBENE COMPLEXES. 12.1 SPECTROSCOPIC DETECTION AND KINETIC CHARACTERIZATION OF THE INTERMEDIATE IN THE NUCLEOPHILIC SUBSTITUTION REACTION OF (CO)5CR=C(OCH3)PH WITH THIOLATE IONS IN AQUEOUS ACETONITRILE (1998) (5)
Physical Organic Chemistry of Transition Metal Carbene Complexes. 22.1 Substituent Effects on the Reversible Cyclization of Fischer Carbene Complexes (CO)5WC(SCH2CH2OH)C6H4Z in Aqueous Acetonitrile (2001) (5)
MECHANISMS OF NUCLEOPHILIC AROMATIC AND HETERO-AROMATIC SUBSTITUTION. RECENT DEVELOPMENTS (1980) (5)
Ab initio study of the carbon-to-carbon identity proton transfer from ketene to its anion in the gas phase. (2001) (4)
Nucleophilic addition to olefins. 15. Kinetics of the reaction of 1,3-indandione anion with benzylidene-1,3-indandione (1985) (4)
Intermediates in nucleophilic aromatic substitution. Part 23. Kinetics of spiro meisenheimer complex formation from 3,6-dimethylcatechol 2,4,6-trinitrophenyl ether. Competition between a trapping and a preassociation mechanism (1988) (4)
Intermediates in nucleophilic aromatic substitution. XII. Kinetic and equilibrium study of the spiro Meisenheimer complex of 1(.beta.-hydroxyethoxy)-2,4-dinitrobenzene (1974) (4)
Deprotonation of 3(2H)-furanone and 3(2H)-thiophenone by carbanions in the gas phase: disproportionately high aromaticity of the transition state: an ab initio study. (2009) (4)
Intermediates in nucleophilic aromatic substitution. III. Visible absorption spectra of the acid and basic form of the 1,3,5-trinitrobenzene-piperidine Meisenheimer complex in 10% dioxane-90% water (1970) (4)
Recent Advances in Our Mechanistic Understanding of SNV Reactions (2010) (4)
Factors that affect the kinetic and thermodynamic acidities of Fischer carbene complexes: New insights from the study of the cationic (methoxymethylcarbene)dicarbonylpentamethylcyclopentadienyl iron ([Cp*(CO)2FeC(OMe)Me]+) in aqueous acetonitrile ☆ (2005) (4)
Hydrolysis of substituted .alpha.-nitrostilbenes: dissection of rate coefficients for individual steps in the four-step mechanism. Estimates of intrinsic rate constants and transition-state imbalances (1994) (4)
Chapter 15 – Ultrasonic Techniques (1976) (4)
Kinetics of hydroxide and nitromethide ion addition to substituted .beta.-nitrostyrenes in dimethyl sulfoxide-water mixtures. Solvent dependence of .pi.-donor substituent effects and of intrinsic rate constants (1992) (4)
Kinetics of proton transfer from cationic carbon acids in water and aqueous DMSO. Effect of activating groups and solvent on intrinsic rate constants. (2005) (3)
Nucleophilic addition to olefins. 22. Kinetics of hydrolysis of the piperidine and morpholine adducts of benzylideneacetylacetone in 50% dimethyl sulfoxide-50% water (1988) (3)
Transition metal carbene chemistry 6: Kinetic studies of the reactions of hydroxide ion with (CO)5MoC(XCH2CH2OH)(C6H5) (X = O and S) and (CO)5WC(OCH2CH2OH)(C6H4–Z) (2006) (2)
Proton transfers in aromatic systems: How aromatic is the transition state? (2009) (2)
Intermediates in Nucleophilic Aromatic Substitution. Part 23. Kinetics of Spiro Meisenheimer Complex Formation from 3,6-Dimethylcatechol 2,4,6-Trinitrophenyl Ether. Competition Between a Trapping and a Preassociation Mechanism. (1988) (2)
Nucleophilic addition to olefins. 7. Kinetic deuterium isotope effects as criterion for an enforced preassociation mechanism in the hydrolysis of substituted benzylidene Meldrum's acids (1982) (2)
Temperature-jump study of the reversible disproportionation of an azaviolene radical ion (1971) (2)
Gas-phase acidities of acrolein and methyl acrylate (1990) (2)
Kinetics of Reactions of Thiolate Ions with α-Nitro β-Substituted Stilbenes in 50% Me2SO-50% Water. Observation of the Intermediate in Nucleophilic Vinylic Substitution Reactions. (1990) (2)
Reaction of Anions with Activated Olefins in the Gas Phase. A Flowing Afterglow-Selected Ion Flow Tube Study. (1991) (2)
Kinetics of the reactions of phenyl-substituted benzylidenemalonodialdehydes with water and hydroxide ion (1994) (2)
Chapter 9 – Evaluation of Relaxation Times from Experimental Relaxation Curves (1976) (2)
Large Transition State Imbalance in the Expulsion of Arylnitromethane Anions from Aniline Adducts of .alpha.-Nitrostilbenes (1994) (2)
KINETICS OF THE ELECTRON TRANSFER REACTIONS OF AZAVIOLENE RADICAL IONS PART 1 (1974) (2)
Anionic σ-complexes from sulfite ion attack on n-methyl-N-β-hydroxyethyl picramide and its spiro complex. Search for geometric isomerism in 1:2 complexes. An instructive example of complex kinetics† (1979) (2)
Chapter 1 – Basic Principles (1976) (1)
Nucleophilic Addition to Olefins. Part 23. High Intrinsic Rate Constant and Large Imbalances in the Thiolate Ion Addition to Substituted α-Nitrostilbenes. (1989) (1)
Kinetics of the Reaction of β-Methoxy-α-nitrostilbene with Thiolate Ions. First Direct Observation of the Intermediate in a Nucleophilic Vinylic Substitution (1989) (1)
Chapter 6 – Relaxation Amplitudes in Single-Step Systems (1976) (1)
Chapter 7 – Relaxation Amplitudes in Multistep Systems (1976) (1)
Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 14. Thermodynamic Acidity Measurements of Fischer Carbene Complexes in Acetonitrile (1998) (1)
Chapter 14 – The Concentration-Jump Method (1976) (1)
A Textbook Example of Complex Kinetics (1979) (1)
Hydrolysis of Substituted α-Nitrostilbenes (I): Dissection of Rate Coefficients for Individual Steps in the Four-Step Mechanism. Estimates of Intrinsic Rate Constants and Transition-State Imbalances. (1994) (1)
Chapter 5 – What Is a Small Perturbation? (1976) (1)
Kinetics of Proton Transfer from 2-Nitro-4-X-phenylacetonitriles to Piperidine and Morpholine in Aqueous Me2SO. Solvent and Substituent Effects on Intrinsic Rate Constants. Transition State Imbalances. (1997) (1)
Chapter 4 – Relaxation Times in Common Multistep Systems (1976) (1)
Nucleophilic Addition to Olefins. Part 18. Kinetics of the Addition of Primary Amines and α-Effect Nucleophiles to Benzylidene Meldrum′s Acid. (1986) (1)
The Use of the Temperature-Jump Method in the Study of Organic Reaction Mechanisms (1975) (1)
Chapter 11 – The Temperature-Jump Method (1976) (1)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC (1979) (1)
Normal Mode Analysis of Chemical Reactions (1975) (1)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION. 21. STEREOELECTRONIC AND D CONFORMATIONAL EFFECTS IN MEISENHEIMER COMPLEXES. INTRINSIC REACTIVITIES OF SPIRO VS. 1,1-DIMETHOXY AND 1-METHOXY-1-PHENOXY COMPLEXES (1983) (1)
Happy Birthday to Joe Bunnett (2011) (1)
Nonperfect Synchronization in Nucleophilic Additions to Carbon-Carbon Double Bonds (1987) (1)
Kinetics of deprotonation of triphenyl(2-substituted-9-fluorenyl)phosphonium ions in 50% dimethyl sulfoxide-50% water. Intrinsic rate constants, imbalances and evidence for changes in transition state structure (1992) (1)
Kinetics of Amine Addition to Benzylidene‐1,3‐indandione and Other Vinylic β‐Diketones. Effect of Cyclic Structure and Steric Strain on Intrinsic Rate Constants. (1991) (0)
Kinetics of Reactions of Hydroxide Ion and Water with β-X- Substituted α-Nitrostilbenes (X: Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% Water. Search for the Intermediate in Nucleophilic Vinylic Substitution. (1991) (0)
Nucleophilic Addition to Olefins. Part 19. Abnormally High Intrinsic Barrier in the Reaction of Piperidine and Morpholine with Benzylideneacetylacetone (1987) (0)
Chapter 16 – Stationary Electric Field Methods (1976) (0)
A COMPLETE KINETIC ANALYSIS OF THE A‐S(E)2 MECHANISM OF ACID‐CATALYZED ADDITION OF METHANOL TO AN OLEFINIC DOUBLE BOND (1974) (0)
Nucleophilic Addition to Olefins. Part 21. Substituent and Solvent Effects on the Reaction of Benzylidene Meldrum′s Acids with Piperidine and Morpholine. (1987) (0)
General considerations and reactions at coventional rates (1986) (0)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION PART 13, NORMAL COORDINATE ANALYSIS OF COUPLED REACTIONS, APPLICATION TO ANIONIC, SIGMA COMPLEXES OF 1,3,5-TRINITROBENZENE WITH HYDROXIDE AND ALKOXIDE IONS IN WATER, METHANOL-WATER, (1974) (0)
Rate and Equilibrium Constants of Ionization of (α-Cyanodiphenylmethane)bis(tricarbonylchromium(0)) in Me2SO-Water Mixtures. Unusual Solvent Effect on the Intrinsic Rate Constant. (1988) (0)
NUCLEOPHILIC ADDITION TO OLEFINS. 8. ADDITION OF PIPERIDINE, MORPHOLINE, AND N-BUTYLAMINE TO α-CYANO-4-NITROSTILBENE AND α-CYANO-2,4-DINITROSTILBENE. KINETICS AND EQUILIBRIA IN 50% DIMETHYL SULFOXIDE-50% WATER (1983) (0)
Investigation of elementary reaction steps in solution and fast reaction techniques (1986) (0)
NUCLEOPHILIC ADDITION TO OLEFINS. 6. STRUCTURE-REACTIVITY RELATIONSHIPS IN THE REACTIONS OF SUBSTITUTED BENZYLIDENE MELDRUM′S ACIDS WITH WATER, HYDROXIDE ION, AND ARYLOXIDE IONS (1982) (0)
Free Energies of Transfer of Carbon Acids and Their Conjugate Carbanions from Water to Me2SO-Water Mixtures. (1988) (0)
Ionization of 9-cyanofluorene in Me2SO–water mixtures. The role of solvent reorientation in proton tranfers (1986) (0)
Kinetics of Ionization of Nitromethane and Phenylnitromethane by Amines and Carboxylate Ions in Me2SO-Water Mixtures. Evidence of Ammonium Ion-Nitronate Ion Hydrogen Bonded Complex Formation in Me2SO-Rich Solvent Mixtures. (1988) (0)
How do Edge Barriers Affect More O'Ferrall-Jencks Diagrams? (2010) (0)
Chapter 8 – Complete Solution of the Relaxation Equation (1976) (0)
Elementary Steps in the Nucleophilic Addition of Amines to Olefins (1979) (0)
NUCLEOPHILIC ADDITION TO OLEFINS. 10. KINETICS OF CLEAVAGE OF THE PIPERIDINE AND MORPHOLINE ADDUCTS OF α-CYANO-4-NITROSTILBENE AND α-CYANO-2,4-DINITROSTILBENE (1984) (0)
Towards Self-Replicating Chemical Systems Based on Cytidylic and Guanylic Acids (1997) (0)
Chapter 10 – Chemical Relaxation in Complex Systems (1976) (0)
Kinetic Solvent Isotope Effect and Proton Inventory Study of the Carbon Protonation of Amine Adducts of Benzylidene Meldrum′s Acid and Other Meldrum′s Acid Derivatives. Evidence for Concerted Intramolecular Proton Transfer. (1987) (0)
Kinetics of Ionization of 1,3-Indandione in Me2SO - Water Mixtures. Solvent Effect on Intrinsic Rates and Brønsted Coefficients. (1986) (0)
[Catalytic effect in the reaction of 2,4-dinitrofluorobenzene with morpholine in benzene. 7. Communication on nucleophile aromatic substitution reactions]. (1967) (0)
Brönsted Coefficients for Intramolecularly Assisted Carbon Protonation of Amine Adducts of Benzylidene Meldrum′s Acid. (1986) (0)
Nucleophilic Addition of Olefins. Part 20. Large Transition-State Imbalances in the Reaction of α-Nitrostilbenes with Amines. (1987) (0)
Kinetics of the Reaction of beta-Methoxy-alpha-nitrostilbene with Cyanamide in 50 DMSO-50 Water. Failure to Detect the S(N)V Intermediate. (1999) (0)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION PART 12, KINETIK AND EQUILIBRIUM STUDY OF THE SPIRO MEISENHEIMER, COMPLEX OF 1-(BETA-HYDROXYETHOXY)-2,4-DINITROBENZENE (1974) (0)
NUCLEOPHILIC ADDITION TO OLEFINS. 7. KINETIC DEUTERIUM ISOTOPE EFFECTS AS CRITERION FOR AN ENFORCED PREASSOCIATION MECHANISM IN THE HYDROLYSIS OF SUBSTITUTED BENZYLIDENE MELDRUM′S ACIDS (1982) (0)
Nucleophilic Addition to Olefins. Part 22. Kinetics of Hydrolysis of the Piperidine and Morpholine Adducts of Benzylideneacetylacetone in 50% Me2SO-50% Water. (1988) (0)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION PART 9, 1 TO 1 AND 1 TO 2 SULFITE COMPLEXES OF 1,3,5-TRINITROBENZENE, CIS-TRANS ISOMERISM IN THE 1 TO 2 COMPLEX (1973) (0)
Chapter 12 – Pressure-Jump Methods (1976) (0)
Rates of Proton Transfers in 70% DMSO — 30% Water. Mechanism of Deprotonation of Intramolecularly Hydrogen Bonded Species (1975) (0)
Kinetics of the template-directed oligomerization of guanosine 5'-phosphate-2-methylimidazolide: Effect of temperature on individual steps of reactionion (1991) (0)
Physical Organic Chemistry of Transition-Metal Carbene Complexes. Part 10. Opposing Effects of α-Alkyl Groups on the Thermodynamic and Kinetic Acidities of (CO)5Cr=C(OMe)CHR′R′′-Type Fischer Carbene Complexes in Aqueous Acetonitrile. Analogy to the Nitroalkane Anomaly. (2010) (0)
INTERMEDIATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION PART 10, SYNTHESIS OF N-METHYL-BETA-AMINOETHYL NITROARYL ETHERS VIA AN UNUSUAL SMILES REARRANGEMENT (1973) (0)
Nucleophilic Addition to Olefins. Part 13. Kinetics of Hydrolysis of Benzylidene-1,3-indandione (1986) (0)
Product and rate determinations with chemically activated nucleotides in the presence of various prebiotic materials, including other mono- and polynucleotides (1991) (0)
Reactions of substituted benzylidene Meldrum’s acids and methylthiobenzylidene Meldrum’s acids with OH–, CF3CH2O– And HOCH2CH2S– in 50% DMSO-50% water. π-Donor effects, soft acid-base interactions and transition state imbalances (2002) (0)
Nucleophilic Addition to Olefins. Part 16. Unusual Substituent Effects in the Reaction of Amines with β‐Nitrostyrenes. (1986) (0)
Nucleophilic Addition to Olefins. Part 25. Kinetics of Hydrolysis of Substituted β-Nitrostyrenes. Transition-State Imbalances and Intrinsic Rate Constants for Three Different Types of Nitronate Ion Forming Processes. Relevance to the (1989) (0)
Hydrolysis of alpha-alkyl-alpha-(methylthio)methylene Meldrum's acids. A kinetic and computational investigation of steric effects. (2006) (0)
Chapter 13 – The Electric Field-Jump Method (1976) (0)
ANIONIC Σ-COMPLEXES FROM SULFITE ION ATTACK ON N-METHYL-N-β-HYDROXYETHYL PICRAMIDE AND ITS SPIRO COMPLEX. SEARCH FOR GEOMETRIC ISOMERISM IN 1:2 COMPLEXES. AN INSTRUCTIVE EXAMPLE OF COMPLEX KINETICS (1979) (0)
Ionization of 9‐Cyano‐ and 9‐(Carbomethoxy)fluorene in Dimethyl Sulfoxide‐Water Mixtures. How Important Is Solvent Reorganization? (1988) (0)
Kinetics of the Reactions of Benzylidene Meldrum′s Acid with Thiolate and Alkoxide Ions in Aqueous Dimethyl Sulfoxide. (2010) (0)
Physical Organic Chemistry of Transition Metal Carbene Complexes. Part 11. Kinetics and Mechanism of the Hydrolysis of (2‐Oxacyclopentylidene) pentacarbonylchromium(0) in Aqueous Acetonitrile. (1997) (0)
Nucleophilic Addition to Olefins. Part 15. Solvent und Substituent Effects on the Hydrolysis of Benzylidenemalononitriles in Basic Me2SO-Water Solutions. (1986) (0)
The Transition State of the Acid Catalyzed Alkoxide Ion Departure from Meisenheimer Complexes (1) (1979) (0)
Kinetic Behavior of Tetrachlorocyclopentadienyl-Type Anions. Deprotonation of 1,2,3,4-Tetrachloro-1,3-cyclopentadiene and Nucleophilic Addition to 1,2,3,4-Tetrachloro-6-phenylfulvene in 50% Me2SO/50% Water. (1991) (0)
NUCLEOPHILIC ADDITION TO OLEFINS. 5. REACTION OF 1,1-DINITRO-2,2-DIPHENYLETHYLENE WITH WATER AND HYDROXIDE ION IN 50% DIMETHYL SULFOXIDE-50% WATER. COMPLETE KINETIC ANALYSIS OF HYDROLYTIC CLEAVAGE OF THE C:C DOUBLE BOND IN ACIDIC AND (1981) (0)
Kinetics of Deprotonation of Arylnitromethanes by Benzoate Ions in Acetonitrile Solution. Effect of Equilibrium and Nonequilibrium Transition‐State Solvation on Intrinsic Rate Constants of Proton Transfers (1992) (0)
Nucleophilic Addition to Olefins. Part 14. Kinetics of the Reaction of 1,3-Indandione Anion with Benzylidene-1,3-indandione. (1986) (0)

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