Claudio Bianchini

Claudio Bianchini's AcademicInfluence.com Rankings

Claudio Bianchini

Chemistry

#3941

World Rank

#4991

Historical Rank

Physical Chemistry

#580

World Rank

#632

Historical Rank

chemistry Degrees

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Chemistry

Claudio Bianchini's Degrees

Bachelors Chemistry University of California, Berkeley

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Claudio Bianchini's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. (2009) (1365)
Pd and Pt–Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with an anion-exchange membrane (alcohol = methanol, ethanol, glycerol) (2009) (402)
Ethylene oligomerization, homopolymerization and copolymerization by iron and cobalt catalysts with 2,6-(bis-organylimino)pyridyl ligands (2006) (290)
Olefin oligomerization, homopolymerization and copolymerization by late transition metals supported by (imino)pyridine ligands (2010) (254)
Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis (2002) (237)
Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines (2004) (177)
Selective oxidation of ethanol to acetic acid in highly efficient polymer electrolyte membrane-direct ethanol fuel cells (2009) (155)
An in situ Fourier transform infrared spectroelectrochemical study on ethanol electrooxidation on Pd in alkaline solution (2010) (152)
Hydrogenation, Hydrogenolysis, and Desulfurization of Thiophenes by Soluble Metal Complexes: Recent Achievements and Future Directions (1998) (126)
Electrooxidation of ethylene glycol and glycerol on Pd-(Ni-Zn)/C anodes in direct alcohol fuel cells. (2013) (125)
Enantioselective Hydrogenation of 2-Methylquinoxaline to (−)-(2S)-2-Methyl-1,2,3,4-tetrahydroquinoxaline by Iridium Catalysis (1998) (114)
First-Principles Considerations on Catalytic Activity of Pd toward Ethanol Oxidation (2009) (108)
A ruthenium(II) enynyl complex mediates the catalytic dimerization of 1-alkynes to Z-1,4-disubstituted enynes (1991) (108)
Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands (1992) (108)
Oligomerisation of Ethylene to Linear α‐Olefins by new Cs‐ and C1‐Symmetric [2,6‐Bis(imino)pyridyl]iron and ‐cobalt Dichloride Complexes (2003) (103)
Ethanol oxidation on electrocatalysts obtained by spontaneous deposition of palladium onto nickel-zinc materials. (2009) (103)
Catalysis for sustainable energy production. (2009) (102)
Selective Oligomerization of Ethylene to Linear α-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands: Influence of the Heteroatom in the Organyl Group on the Catalytic Activity (2003) (101)
The Mechanism of the Ru-Assisted C−C Bond Cleavage of Terminal Alkynes by Water (1996) (100)
PREPARATION, CHARACTERIZATION, AND PERFORMANCE OF TRIPODAL POLYPHOSPHINE RHODIUM CATALYSTS IMMOBILIZED ON SILICA VIA HYDROGEN BONDING (1999) (100)
Self-sustainable production of hydrogen, chemicals, and energy from renewable alcohols by electrocatalysis. (2010) (96)
Chemoselective hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones catalyzed by isostructural iron(II), ruthenium(II), and osmium(II) cis-hydride (.eta.2-dihydrogen) complexes (1993) (96)
REGIO- AND STEREOSELECTIVE DIMERIZATION OF PHENYLACETYLENE TO (Z)-1,4-DIPHENYLBUT-3-EN-1-YNE BY RUTHENIUM(II) CATALYSIS. REACTION MECHANISM INVOLVING INTERMOLECULAR PROTONATION OF SIGMA -ALKYNYL BY 1-ALKYNE (1994) (92)
Single-site and nanosized Fe–Co electrocatalysts for oxygen reduction: Synthesis, characterization and catalytic performance (2011) (91)
Energy efficiency enhancement of ethanol electrooxidation on Pd-CeO(2)/C in passive and active polymer electrolyte-membrane fuel cells. (2012) (90)
Tripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3 (1990) (86)
Tripodal polyphosphine ligands control selectivity of organometallic reactions (1992) (85)
Recent Aspects of Asymmetric Catalysis by Immobilized Chiral Metal Catalysts (2002) (80)
A biologically inspired organometallic fuel cell (OMFC) that converts renewable alcohols into energy and chemicals. (2010) (68)
A comparison between silica-immobilized ruthenium(II) single sites and silica-supported ruthenium nanoparticles in the catalytic hydrogenation of model hetero- and polyaromatics contained in raw oil materials (2003) (68)
Methoxycarbonylation of Ethene by Palladium(II) Complexes with 1,1‘-Bis(diphenylphosphino)ferrocene (dppf) and 1,1‘-Bis(diphenylphosphino)octamethylferrocene (dppomf) (2003) (67)
In situ FTIR spectroelectrochemical study on the mechanism of ethylene glycol electrocatalytic oxidation at a Pd electrode. (2011) (65)
A deceptively simple case of selective hydrogenation of phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complex (1992) (65)
Classical and nonclassical polyhydride ruthenium(II) complexes stabilized by the tetraphosphine P(CH sub 2 CH sub 2 PPh sub 2 ) sub 3 (1991) (64)
Palladium Nanoparticles Supported on Hyperbranched Aramids: Synthesis, Characterization, and Some Applications in the Hydrogenation of Unsaturated Substrates (2003) (64)
SYNTHETIC MODELS FOR CATECHOL 1,2-DIOXYGENASES. INTERCEPTION OF A METAL CATECHOLATE-DIOXYGEN ADDUCT (1991) (63)
Electrochemical milling and faceting: size reduction and catalytic activation of palladium nanoparticles. (2012) (63)
Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis (2003) (63)
HDS Model Systems. Coordination, Opening, and Hydrogenation of Benzo[b]thiophene at Iridium (1994) (63)
Opening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phase (1993) (62)
Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneacetone and Benzonitrile (2000) (62)
Ruthenium-promoted Z-selective head-to-head dimerization of terminal alkynes in organic and aqueous media (2005) (62)
C−C Bond Formation between Vinylidene and Alkynyl Ligands at Ruthenium(II) Leading to either Enynyl or Dienynyl Complexes† (1996) (59)
Electronic influence of the thienyl sulfur atom on the oligomerization of ethylene by cobalt(II) 6-(thienyl)-2-(imino)pyridine catalysis (2007) (59)
Synthesis of New Polydentate Nitrogen Ligands and Their Use in Ethylene Polymerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides and Methylaluminoxane (2007) (57)
Rhodium complexes with tripodal polyphosphines as excellent precursors to systems for the activation of H-H and C-H bonds (1988) (57)
A homogeneous iron(II) system capable of selectivity catalyzing the reduction of terminal alkynes to alkenes and buta-1,3-dienes (1989) (57)
Hydrogenation and hydrogenolysis of thiophenic molecules catalysed by soluble metal complexes (1996) (56)
Palladium(II) Complexes with 1,1‘−Bis(diphenylphosphino)ferrocenes [Fe(η5-C5R4PPh2)2]n+ (dppf, R = H, n = 0; dppomf, R = Me, n = 0; dppomf+, R = Me, n = 1). Synthesis, Characterization, and Catalytic Activity in Ethene Methoxycarbonylation (2002) (56)
A stable .eta.2-dihydrogen complex of cobalt. Role of the hydrogen-hydrogen interaction in hydrogen transfer from metal to alkene (1988) (55)
Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes. (2010) (55)
Metal-hydride alkynyl .fwdarw. metal-vinylidene rearrangements occurring in both solid state and solution. Role of the 1-alkyne substituent in determining the relative stability of .pi.-alkyne, hydride alkynyl, and vinylidene forms at cobalt (1991) (55)
In Situ High-Pressure 31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3 (2000) (53)
Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles: evidence for substrate activation on Rh(single-site)-Pd(metal) moieties. (2006) (53)
Activation of molecular hydrogen over a binuclear complex with Rh2S2 core: DFT calculations and NMR mechanistic studies. (2004) (50)
Reversible double addition of hydrogen on a bis(.mu.-sulfido) binuclear rhodium complex (1986) (50)
Renewable H2 from glycerol steam reforming: effect of La2O3 and CeO2 addition to Pt/Al2O3 catalysts. (2010) (50)
Electron-rich iridium complexes with mixed-donor polydentate ligands. Chemoselective catalysts in hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones (1990) (50)
Improvement in the efficiency of an OrganoMetallic Fuel Cell by tuning the molecular architecture of the anode electrocatalyst and the nature of the carbon support (2012) (49)
An .eta.4-benzene species mediates acetylene cyclotrimerization (1991) (49)
Oligomerisation of ethylene to linear α-olefins by tetrahedral cobalt(II) precursors stabilised by benzo[b]thiophen-2-yl-substituted (imino)pyridine ligands ☆ (2004) (49)
Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis. (2007) (49)
Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Olefins by Palladium−Diphosphine Catalysis (2002) (49)
Functionalization of Multiwalled Carbon Nanotubes with Cyclic Nitrones for Materials and Composites: Addressing the Role of CNT Sidewall Defects (2011) (48)
Selective σ-Bond Metathesis in Alkyl−Aryl and Alkyl−Benzyl Yttrium Complexes. New Aryl− and Benzyl−Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands (2009) (48)
Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands (1997) (46)
A novel oxygen-carrying and activating system of rhodium(III). Oxidation and oxygenation reactions of 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complex (1990) (46)
Liquid-Biphase Hydrogenolysis of Benzo[b]thiophene by Rhodium Catalysis (1997) (46)
Asymmetric Hydroformylation of Olefins with Rh Catalysts Modified with Chiral Phosphine−Phosphite Ligands (2007) (45)
STYRENE CYCLOPROPANATION AND ETHYL DIAZOACETATE DIMERIZATION CATALYZED BY RUTHENIUM COMPLEXES CONTAINING CHIRAL TRIDENTATE PHOSPHINE LIGANDS (1999) (45)
Water-Soluble Palladium(II) Catalysts for the Alternating Co- and Terpolymerization of CO and Olefins in Aqueous Phase (1999) (45)
In-depth NMR and IR study of the proton transfer equilibrium between ({(MeC(CH 2 PPh 2 ) 3 }Ru(CO)H 2 ) and hexafluoroisopropanol (2001) (45)
Simultaneous Polymerization and Schulz−Flory Oligomerization of Ethylene Made Possible by Activation with MAO of a C1-Symmetric [2,6-Bis(arylimino)pyridyl]iron Dichloride Precursor (2004) (45)
Embedded Ru@ZrO2 Catalysts for H2 Production by Ammonia Decomposition (2010) (44)
Evidence for a molecular hydrogen complex of rhodium. Some factors affecting cis-dihydride .tautm. .eta.2-dihydrogen exchange (1987) (44)
Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)−P3 or −P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone (1997) (44)
Hydrodesulfurization (HDS) Model Systems. Opening, Hydrogenation, and Hydrodesulfurization of Dibenzothiophene (DBT) at Iridium. First Case of Catalytic HDS of DBT in Homogeneous Phase (1995) (43)
Novel diphosphine-modified palladium catalysts for oxidative carbonylation of styrene to methyl cinnamate (2001) (43)
Bis-alkoxycarbonylation of styrene by pyridinimine palladium catalysts (2002) (43)
Transition metal complexes with the C1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in different phase systems (2001) (43)
Reactivity of copper(I) tetrahydroborates toward CO2 and COS. Structure of (triphos)Cu(μ1−O2CH) (1985) (43)
Reactivity of copper(I) tetrahydroborates toward carbon dioxide and carbonyl sulfide. Structure of (triphos)Cu(.eta.1-O2CH) (1985) (42)
Isomerization of allylic alcohols to carbonyl compounds by aqueous-biphase rhodium catalysis (2001) (42)
A Synthetic Nickel Electrocatalyst with a Turnover Frequency above 100 000 s−1 for H2 Production (2012) (42)
Zwitterionic Metal Complexes of the New Triphosphine NaO3S(C6H4)CH2C(CH2PPh2)3 in Liquid Biphasic Catalysis: An Alternative to Teflon "Ponytails" for Facile Catalyst Separation without Water (1995) (41)
Modelling the Hydrodenitrogenation of Aromatic N‐Heterocycles in the Homogeneous Phase (2001) (41)
Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis-Hydride-eta(2)-Dihydrogen Complexes [{P(CH(2)CH(2)PPh(2))(3)}M(H)(eta(2)-H(2))](+) (M = Fe, Ru). (1997) (41)
Molecular solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. Catalytic hydrogenation of ethylene at iridium (1993) (41)
Immobilization of Optically Active Rhodium‐Diphosphine Complexes on Porous Silica via Hydrogen Bonding (2001) (40)
Synthesis, characterization, and electrochemical properties of a family of dinuclear rhodium complexes containing two terminal hydride ligands and two hydride (or chloride) bridges. Stoichiometric and catalytic hydrogenation reactions of alkynes and alkenes (1988) (40)
Electrochemistry as a diagnostic tool to discriminate between classical M-(H)2 and nonclassical M-(H2) structures within a family of dihydride and dihydrogen metal complexes (1990) (40)
Chemoselective oxidation of 3,5-Di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct (1992) (40)
Synthesis, characterization, and reactivity of 1,1 '-bis(diphenylphosphino)osmocene: Palladium(II) complexes and their use as catalysts in the methoxycarbonylation of olefins (2003) (39)
New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene (2000) (39)
Low-temperature IR and NMR studies of the interaction of group 8 metal dihydrides with alcohols. (2003) (38)
The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis (1994) (38)
Solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. Carbon-hydrogen activation reactions at cobalt(I) encapsulated into the tetraphosphine P(CH2CH2PPh2)3 (1991) (37)
Synthesis, Characterization, and Reactivity of Neutral and Cationic Pd–C,N,N Pincer Complexes (2005) (37)
Activation of Dioxygen by Cobalt Group Metal Complexes (1997) (37)
Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies (1997) (36)
Classical, nonclassical, and mixed-metal osmium(II) polyhydrides stabilized by the tetraphosphine P(CH2CH2PPh2)3. Hydrogen/deuterium isotope exchange reactions promoted by a strongly bound dihydrogen ligand (1993) (36)
Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides (2007) (36)
Dioxygen and carbon monoxide uptake by iridium(I) complexes stabilized by mixed N,P-donor ligands (1994) (36)
Mimicking the HDS Activity of Ruthenium-Based Catalysts 2: The Hydrogenation of Benzo[b]thiophene to 2,3-Dihydrobenzo[b]thiophene (1999) (36)
Nickel Complexes with Phosphinito-Oxazoline Ligands: Temperature-Controlled Formation of Mono- or Dinuclear Complexes and Catalytic Oligomerization of Ethylene and Propylene (2009) (35)
Homogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation of the Hydrodesulfurization Mechanism and an Effective Method for the Synthesis of Unusual Organosulfur Compounds (1995) (35)
Activation of 1-alkynes at tripodal (polyphosphine)rhodium systems. Regioselective synthesis of enol esters from 1-alkynes and carboxylic acids catalyzed by rhodium(I) monohydrides (1990) (35)
Methoxycarbonylation of styrene to methyl arylpropanoates catalyzed by palladium(II) precursors with 1,1'-bis(diphenylphosphino)metallocenes (2004) (35)
Ethylene carbonylation in methanol and in aqueous media by palladium(II) catalysts modified with 1,1'-bis(dialkylphosphino)ferrocenes (2005) (35)
Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(.alpha.-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of .alpha.,.beta.-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis (1995) (35)
An exceptionally stable cis-(hydride)(η2-dihydrogen) complex of iron (1988) (34)
Amorphous Polyethylene by Tandem Action of Cobalt and Titanium Single‐Site Catalysts (2005) (34)
Comprehensive experimental and interpretational study of the complex formation and transformations involving o-quinoid molecules and an L3M-type metal fragment (M = cobalt) (1987) (34)
Reactions of the Rhenium(I) Fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and Characterization of a Stable Cationic .eta.2-H2 Complex of Rhenium (1995) (34)
Hydrogenation of Quinoline by Rhodium Catalysts Modified with the Tripodal Polyphosphine Ligand MeC(CH2PPh2)3 (2001) (33)
Hydrogenation of arenes over catalysts that combine a metal phase and a grafted metal complex: role of the single-site catalyst. (2003) (33)
Aminocarbene Complexes as Intermediates in the Ruthenium-Assisted Aminolysis of Phenylacetylene to Isonitriles and Toluene (1999) (33)
Electrochemical synthesis of the σ-aryl complex [NiBr(Mes)(bpy)] and its use as catalyst precursor for the oligomerization of ethylene (Mes = 2,4,6-trimethylphenyl, bpy = 2,2'-bipyridine) (2006) (33)
A family of stable iron(I) .sigma.-alkynyl complexes. Synthesis, characterization, structure, and electron-transfer chemistry (1993) (33)
Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes (1992) (32)
First Examples of Rhenium-Assisted Activation of Propargyl Alcohols: Allenylidene, Carbene, and Vinylidene Rhenium(I) Complexes (1999) (32)
Mimicking the HDS Activity of Ruthenium-Based Catalysts. Homogeneous Hydrogenolysis of Benzo[b]thiophene (1998) (32)
Yttrium‐Amidopyridinate Complexes: Synthesis and Characterization of Yttrium‐Alkyl and Yttrium‐Hydrido Derivatives (2010) (32)
Studies of ligand and solvent effects in the alternating copolymerization of carbon monoxide and ethene by palladium-diphosphine catalysis (2002) (31)
Multiple Re−C Bonds at the [{MeC(CH2PPh2)3}Re(CO)2]+ Auxiliary (1996) (31)
Reactions of the trigonal-bipyramidal cobalt(I) hydride [{P(CH2CH2PPH2)3}CoH] with 1-alkynes. Synthesis and reactivity of acethylide, alkenyl, and vinylidene complexes (1990) (31)
Hydrogenation of indole by phosphine-modified rhodium and ruthenium catalysts (2002) (31)
Tandem Action of Early−Late Transition Metal Catalysts for the Surface Coating of Multiwalled Carbon Nanotubes with Linear Low-Density Polyethylene (2008) (31)
Selective Cα–Cβ bond cleavage by water in allenylidene and alkenylvinylidene ruthenium complexes (1999) (30)
Schulz–Flory oligomerisation of ethylene by the binuclear nickel(II) complex Ni2Cl4[cis,trans,cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane] (2003) (30)
Homogeneous Hydrogenation of Benzo[b]thiophene by Use of Rhodium and Iridium Complexes as the Catalyst Precursors: Kinetic and Mechanistic Aspects† (1997) (30)
Dioxomolybdenum(VI) Complexes Stabilized by Polydentate Ligands with NO3, N2O2, and NS2 Donor-Atom Sets (1994) (30)
Copolymerization of Carbon Monoxide with Ethene Catalyzed by Palladium(II) Complexes of 1,3-Bis(diphenylphosphino)propane Ligands Bearing Different Substituents on the Carbon Backbone (1999) (29)
The Catalytic Transformation of Benzo[b]thiophene to 2-Ethylthiophenol by a Soluble Rhodium Complex: The Reaction Mechanism Involves Ring Opening Prior to Hydrogenation (1995) (29)
Copolymerization of carbon monoxide with ethene catalyzed by bis-chelated palladium(II) complexes containing diphosphine and dinitrogen ligands (1999) (29)
Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH2PPh2)3}Ir(H2)(H)2]BPh4 (1997) (29)
In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [{MeC(CH2PPh2)3}Re (CO)2H]. ReH…H bonding and proton-transfer pathways (1998) (28)
Sodium borohydride as an additive to enhance the performance of direct ethanol fuel cells (2010) (28)
Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(II) complex (1994) (28)
Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts (2004) (28)
Reversible uptake of hydrogen and nitrogen at cobalt in the solid state. Influence of the counter anion on the formation of classical dihydride vs. nonclassical .eta.2-dihydrogen forms of [(PP3)CoH2]+ (1992) (28)
Genesis of tetrathiooxalate-like C2S4 and C2Se4 units. A multiform experimental study and the relevant theoretical implications for the role of transition-metal fragments (1987) (27)
Addition of E-H bonds (E = S, N) across the Cα=Cβ bond of the allenylidene ligand in [Re{C=C=CPh2}(CO)2(triphos)](OSO2CF3) (triphos = MeC(CH2PPh2)3) (2002) (27)
Palladium acetate complexes bearing chelating N-heterocyclic carbene (NHC) ligands: Synthesis and catalytic oxidative homocoupling of terminal alkynes (2009) (27)
Specific and non-specific influence of the environment on dihydrogen bonding and proton transfer to [RuH2{P(CH2CH2PPh2)3}] (2007) (27)
Interaction of monohydrido complexes of rhodium(I) with 1-alkynes. Experimental study on deceptively simple reactions (1990) (27)
Catalytic polymerisation of ethylene with tris(pyrazolyl)borate complexes of late transition metals (2005) (26)
Coupling of two ethyne molecules at rhodium versus coupling of two rhodium atoms at ethyne. 2. Implications for the reactivity. Catalytic and stoichiometric functionalization reactions of ethyne (1991) (26)
The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality. (2002) (26)
Synthesis, redox properties, and reactivity of a novel family of electron-rich vinylidene and vinylphosphonium complexes of rhodium(I) (1990) (26)
CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups (2007) (26)
Synthesis of the first polymer-supported tripodal triphosphine ligand and its application in the heterogeneous hydrogenolysis of benzo[b]thiophene by rhodium catalysis (2001) (25)
Reactivity of copper(I) tetrahydroborates toward CS2 and SCNPh. structures of (PPh3)2Cu(μ-S2CSCH2SCS2)Cu(PPh3)2, (PPh3)2Cu(S2COEt), and (PPh3)2Cu(S2CNHPh).CHCl3 (1985) (25)
Oxidative addition/reductive elimination of aldehydes and ketones at rhodium (1989) (25)
Synthesis and crystal structure of two isomorphous rhodium and iridium complexes with cyclo-triphosphorus and 1,1,1,-tris(diphenylphosphinomethyl)-ethane (1979) (25)
Can nitrones functionalize carbon nanotubes? (2010) (25)
New alkyl derivatives phosphine sulfonate (P-O) ligands. Catalytic activity in Pd-catalysed Suzuki-Miyaura reactions in water. (2007) (25)
Facile activation of hydrogen on 1,1- and 1,2-dithio complexes of rhodium(III). An experimental study (1987) (25)
SYNTHESIS AND CHARACTERIZATION OF AN IRON(II) CIS-HYDRIDE(ETA 2-DIHYDROGEN) COMPLEX STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 (1991) (25)
Homo- and heterometal triple-decker complexes of cyclo-triphosphorus with mixed triphosphine ligands. Crystal structure of [[MeC(CH2PPh2)3]Co[.mu.-(.eta.3-P3)]Fe[MeC(CH2PEt2)3]](PF6)2.cntdot.CH2Cl2 (1981) (24)
Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene (1993) (24)
Operando High-Pressure NMR and IR Study of the Hydroformylation of 1-Hexene by 1,1'-Bis(Diarylphosphino)metallocene-Modified Rhodium(I) Catalysts (2005) (24)
Mono- and dinuclear carbon disulfide metal complexes with 1,1,1-tris((diphenylphosphino)methyl)ethane (1980) (24)
Oxidation of primary alcohols to carboxylic acids made easy at iridium (1990) (23)
Preparation of models and oligomers of metal alkynyls: NMR, GPC and X-ray structural characterization of building blocks for the construction of molecular devices (2003) (23)
Assembling ethylene, alkyl, hydride, and carbon monoxide ligands at iridium (1991) (23)
Synthesis of Polymer-Supported Rhodium(I)−1,3-Bis(diphenylphosphino)propane Moieties and Their Use in the Heterogeneous Hydrogenation of Quinoline and Benzylideneacetone (2001) (23)
Hydrodesulfurization model systems. Homogeneous and heterogeneous (solid-gas) hydrogenation of benzothiophene at iridium (1993) (23)
Reactions of ethyl cyanoformate with (np3)Ni, (np3)CoH [np3 = N(CH2CH2PPh2)3], and (triphos)Ni [triphos = MeC(CH2PPh2)3]. Crystal structures of the ethoxycarbonyl complexes [(np3)Ni(CO2Et)]BPh4 and (triphos)Ni(CN)(CO2Et) (1986) (22)
Chemistry of Et3P.CS2 metal complexes: synthesis of 1,1-dithiolate complexes via nucleophilic attacks on [(triphos)Co(S2CPEt3)](BPh4)2. X-ray structure of [(triphos)Co(S2CO)] (1982) (22)
Palladium(II) Complexes with Phosphanylferrocenecarboxylate Ligands and Their Use as Catalyst Precursors for Semialternating CO–Ethylene Copolymerization (2008) (22)
Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions (1999) (22)
"Triple-decker" sandwich complexes of cyclo-triphosphorus with 4d and 5d metals (1981) (22)
Metal-promoted transformation of CO2, into CO. X-ray crystal structure of the nickel−carbonate complex [O = PPh2CH2C(CH3)(CH2PPh2)2]Ni(O2CO)•0.5H2O•C6H6 (1984) (22)
The barrier to rotation of the dihydrogen ligand in the complexes [MH(.eta.2-H2)PP3]BPh4 (M = iron, ruthenium): evidence for stronger back-donation in the iron complex (1992) (22)
In Situ and Reactor Study of the Enantioselective Hydrogenation of Acetylacetone by Ruthenium Catalysis with the New Chiral Diphosphine Ligand (R)-(R)-3-Benzyl-2,4-bis(diphenylphosphino)pentane (2000) (22)
Taking Too Many Precautions in Making a Catalyst Is Never a Loss of Time: A Lesson We Learned at Our Own Expense (2003) (21)
HDS model systems. 2,3-Dihydrothiophene as an intermediate in the homogeneous hydrogenation of thiophene to tetrahydrothiophene at iridium (1994) (21)
C−H Bond Cleavage in Thiophenes by [P(CH2CH2PPh2)3Ru]. UV Flash Kinetic Spectroscopy Discloses the Ruthenium−Thiophene Adduct Which Precedes C−H Insertion (1997) (21)
Structural comparison of cobalt and nickel complexes with CS2 and SCNPh molecules stabilized by tripodal polyphosphine ligands. Implications for the nature of the chemical bonding in compounds containing C−S linkages #7B-N2 coordinated to L3M fragments (1984) (21)
Nucleophilic attack on .eta.2-coordinated dithio acids by hydride ion. A preliminary step in the formation of a variety of nickel complexes (1983) (20)
Diastereoselective Alkylation−Vinylation of Norbornene Catalyzed by a Tetrahedral Cobalt(II) Pyridinimine Complex (2007) (20)
Reactivity of the triethylphosphinecarbon disulfide adduct Et3PCS2 toward iron(II) cations in the presence of the bis(tertiary phosphines), depe, and diphos, x-ray crystal structures of the complexes [(depe)2Fe(S2CPEt3)](BPh4)2 and [(depe)2Fe(S2CH)](BPh4) (1982) (20)
Imine Hydrogenation by Tribenzylphosphine Rhodium and Iridium Complexes (2006) (20)
C−S Bond Cleavage of Benzo[b]thiophene at Ruthenium (1998) (20)
Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resins. (2004) (20)
2‐Oxacyclopentylidene, 2‐Oxacyclohexylidene, and 2‐Oxacycloheptylidene Rhenium Complexes by Reaction of ω‐Alkynols with the [{MeC(CH2PPh2)3}Re(CO)2]+ Auxiliary (1998) (20)
Simultaneous coordination of hydrides and .eta.1-S thiophenes made possible at iridium (1993) (20)
Synthesis, characterization, and molecular structure of the first metal complex containing thallium chloride as a ligand. A novel carrier of thallium(I) (1992) (20)
Anodically-induced metal deprotonation of the hydrido complexes [{PCH2CH2PPh2)3}M (H) Cl ] (M = Fe, Ru, Os) : the first step to the electrogeneration of Fe(I),u(I) and Os(I) five-coordinate complexes (1997) (20)
Synthesis and characterization of the tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-diacetic acid (H2Me2DO2A) and of its neutral copper(II) complex [Cu(Me2DO2A)]. A new 64Cu-labeled macrocyclic complex for positron emission tomography imaging (2000) (20)
Bifunctional activation of carbon dioxide: a case where the basic and acidic sites are not held in the same structure (1984) (19)
Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites (2008) (19)
Mononuclear ruthenium complexes containing two different phosphines in trans position: II. Catalytic hydrogenation of CC and CO bonds (2007) (19)
Opening and Hydrogenation of Dinaphtho[2,1-b:1‘,2‘-d]thiophene (DNT) by Soluble Rhodium and Iridium Complexes. Homogeneous Hydrogenolysis of DNT to 1,1‘-Binaphthalene-2-thiol by Rhodium Catalysis (1996) (19)
Crystal structure of the cis hydride acetyl complex [{N(CH2CH2PPh2)3}Rh(H)(COMe)]BPh4. One-pot synthesis of (.sigma.-acyl)metal complexes from aldehydes (1991) (19)
Metal-promoted transformation of carbon dioxide into carbon monoxide. X-ray crystal structure of the nickel-carbonate complex [O:PPh2CH2C(CH3)(CH2PPh2)2]Ni(O2CO).0.5H2O.C6H6 (1984) (19)
Reactivity of copper(I) tetrahydroborates toward carbon disulfide and phenyl isothiocyanate. Structures of (PPh3)2Cu(.mu.-S2CSCH2SCS2)Cu(PPh3)2, (PPh3)2Cu(S2COEt), and (PPh3)2Cu(S2CNHPh).CHCl3 (1985) (18)
C-S Bond Scission of Substituted Thiophenes at Rhodium. Factors Influencing the Regioselectivity of the Insertion and the Stability of the Resulting Metalathiacycles (1995) (18)
Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC=N-heterocyclic carbene) complexes (2010) (18)
Synthesis, characterization and aqueous-biphase catalysis of the ruthenium dimer Na[(O3S(C6H4)CH2C(CH2PPh2)3Ru)2(μ-Cl)3] (1999) (18)
Reactivity of [N(CH2CH2PPh2)3]CoH toward carbon disulfide, SCNPh, OCNPh, and carbon oxide sulfide (COS) (1983) (18)
Like on Heterogeneous Hydrodesulfurization (HDS) Catalysts, the Homogeneous HDS of Benzo[b]thiophene Is Achived by the Concomitant Action of a Metal Promoter (Rh) and an Active HDS Component (W) (1996) (18)
Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se). Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2 (1987) (18)
Chemoselective methoxycarbonylation of terminal alkynes catalyzed by Pd(II)-TROPP complexes. (2010) (18)
Factors affecting the metal-promoted head-to-head dimerization of carbon disulfide, CS2 to C2S4. Synthesis, chemistry, structure, and MO analysis of [(triphos)Rh(.mu.-C2S4)Rh(triphos)](BPh4)2.CH2Cl2 (1984) (18)
Synthesis, Characterization, and Interconversion of the Rhenium Polyhydrides [ReH3(η4‐NP3)] and [ReH4(η4‐NP3)]+ {NP3 = tris[2‐(diphenylphosphanyl)ethyl]amine} (2002) (18)
Facile reduction of carbon dioxide, carbonyl sulfide, and carbon disulfide by copper(I) borohydride. X-ray crystal structure of the complex [(triphos)Cu(O2CH)] (1983) (17)
Low density polyethylene by tandem catalysis with single site Ti(IV)/Co(II) catalysts (2006) (17)
Intramolecular sigma-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: exploring unexpected reactivity paths. (2010) (17)
Hydrogen-transfer reactions of the trihydride [(MeC(CH2PPh2)3RhH3]: a simple route to rhodium cis hydride .eta.2-alkene complexes (1990) (17)
Nucleophilic addition of phosphines to rhenium allenylidenes. Unprecedented double P?H bond activation to give an ?1-P-phospha-1-butadienyl ligandBased on the presentation given at Dalton Discussion No. 6, 9?11th September 2003, University of York, UK. (2003) (17)
Activation of 1-alkynes at 16-electron rhodium fragments. Some examples of thermodynamically favored rearrangements [M(.pi.-HC.tplbond.CR)] .fwdarw. [M(H)(C.tplbond.CR)] (1989) (17)
Chemoselective Aerobic Diol Oxidation by Palladium(II)–Pyridine Catalysis (2011) (17)
Control of the Bridgehead Donor Atom in the Tripodal Ligand over Oxidative Addition of Au(PPh3)+ to [X(CH2CH2PPh2)3RhH] (X = N, P). X-ray Diffraction and Multinuclear (103Rh, 31P, 1H) NMR Studies (1995) (17)
Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase (1997) (17)
Stepwise metal-assisted conversion of carbon diselenide to diselenium and carbon dioxide. Novel bonding mode of the diselenium molecule in the double-Se2-bridged complex [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.2DMF (1985) (16)
Metal-assisted reaction of carbon disulfide with the tris(tertiary phosphine) 1,1,1-tris(diethylphosphinomethyl)ethane. Synthesis and structure of the complex [MeC(CH2PEt2)3Fe{S2C(PEt2CH2)2CMe2}](BF4)2 (1981) (16)
Dioxomolybdenum(VI) Complexes with New Enantiomerically Pure Amino Diol Ligands. (1996) (16)
Thiophene, Benzo[b]thiophene and Dibenzo[b,d]thiophene as Precursors to Highly Conjugated Organosulfur Compounds (1997) (16)
Reactivity of the triethylphosphine-carbon disulfide adduct toward metal carbonyls. X-ray structures of the complexes [Cr(CO)5(S2CPEt3)] and [Mo(CO)2(PEt3)(.mu.-S2CPEt3)]2 (1982) (16)
How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study (2003) (16)
Backward synthesis of rhenium(I) γ-hydroxyvinylidene and γ-methoxyvinylidene complexes and their conversion to the allenylidene [Re{CCCPh2}(CO)2(MeC(CH2PPh2)3)](OSO2CF3) (2001) (16)
1H- and 2H-T1 relaxation behavior of the rhodium dihydrogen complex [(triphos)Rh(eta 2-H2)H2]+. (2000) (16)
Homo- and heterobimetallic trihydride complexes stabilized by the tripodal phosphine ligand MeC(CH2PPh2)3: experimental and theoretical studies (1989) (16)
Tandem Copolymerization: An Effective Control of the Level of Branching and Molecular Weight Distribution (2006) (16)
Chemoselective reduction of α,β-unsaturated ketones catalyzed by transition metal complexes with polydentate ligands (1995) (16)
Reactive Blending of Polyamides with Different Carbonyl Containing Olefin Polymers (2003) (16)
Reactivity of the triethylphosphine-carbon disulfide adduct (Et3P.CS2) toward cobalt(II) cations in the presence of the tris (tertiary phosphines) triphos and etriphos. X-ray crystal structure of the complex [(etriphos)Co(S2C(H)PEt3)](BPh4)2 (1982) (16)
High-pressure investigations under CO/H2 of rhodium complexes containing hemispherical diphosphites. (2010) (16)
Ruthenium(II)-Mediated Reaction of Phenylacetylene with Primary Amines To Give Ruthenium(II)-Isonitrile Complexes (1995) (15)
Redox-Induced Conversion Pathways in Rhodium and Iridium Complexes Containing C-S Bond Cleaved Benzo[b]thiophene (1995) (15)
Synthesis, characterization and reactivity of tribenzylphosphine rhodium and iridium complexes (2006) (15)
Intra- and intermolecular activation of sp2 carbon-hydrogen bonds at rhodium(I) and iridium(I) metal centers. X-ray structure of the cis .sigma.-cyclooctadienyl hydride [{N(CH2CH2PPh2)3}IrH(.sigma.-C8H11)]BPh4.cntdot.CH3COCH3 (1986) (15)
Unraveling the o-methoxy effect in the CO/ethene copolymerization reaction by diphosphanepalladium(II) catalysis (2007) (15)
Ruthenium(II) Complexes with Triphosphane Ligands Combining Planar, Phosphorus, and Carbon Chirality: Application to Asymmetric Reduction of Trifluoroacetophenone (2003) (15)
Effects of the conformational rearrangement of the (np3)M fragment in the course of the reaction between (np3)MH hydrides [M = Co, Rh; np3 = N(CH2CH2PPh2)3] and carbon disulfide (1985) (15)
Activation of 2-propyn-1-ols by the rhenium(I) fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and characterization of cationic Re(I) complexes containing unsaturated η1-carbon ligands (2001) (15)
Asymmetric hydrogen-transfer reduction of prochiral and α,β-unsaturated ketones by iridium complexes containing optically pure aminodiphosphine ligands (1998) (15)
Synthesis of neutral rhodium(I) complexes containing a rigid P–O ligand and their use as catalyst precursors for the hydroformylation of 1-hexene (2008) (14)
Reactivity of (triphos)Ni(η2-CS2) towards group VIB elements, HBF4, and MeOSO2F. Crystal structure of the dithiocarbonate complex [OPPh2CH2C(CH3)(CH2PPh2)2]Ni(S2CO)· 0.5THF (1985) (14)
.sigma.-Acetylide complexes of rhodium(I), rhodium(II), and rhodium(III). Correlation between electrochemical (E0') and spectroscopic (.DELTA..nu.(C.tplbond.C)) parameters and d.pi.(metal) .fwdarw. .pi.*(acetylide) transfer (1990) (14)
Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. (2011) (14)
Metal Activation of Dibenzo[b,d]thiophene. Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(.eta.2(C,S)-C12H8S) (1995) (14)
Synthesis and characterization of rhenium polyhydrides stabilized by the tripodal ligand MeC(CH2PPh2)3 (1993) (14)
Rhenium(III) and rhenium(V) complexes stabilized by the potentially tetradentate ligand tris(2-diphenylphosphinoethyl)amine (2002) (14)
Cobalt monolayer islands on Ag(111) for ORR catalysis. (2011) (14)
Rhodium complexes with the tripodal triphosphine MeC(CH2PPh2)3 as highly reactive systems for hydrogenation and hydroformylation of alkenes (1988) (14)
Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules (1989) (14)
X-ray structural analyses of copper(I) and silver(I) adducts of the Rh(III) trihydride [(triphos)RhH3], with triphos=CH3C(CH2PPh2)3 (1993) (14)
The Energy Profile of Proton Transfer from Brønsted Acids to Terminal Hydrides in Transition Metal Complexes Can Be Estimated by Combining in situ IR and NMR Spectroscopy (2000) (13)
MIMICKING THE HDS ACTIVITY OF PROMOTED TUNGSTEN CATALYSTS. A HOMOGENEOUS MODELING STUDY USING A TWO-COMPONENT TUNGSTEN/RHODIUM SYSTEM (1997) (13)
A double CS2-bridged nickel complex. New synthesis and crystal structure of [(PPh3)Ni(µ-CS2)2Ni(PPh3)] (1983) (13)
Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation. (2006) (13)
Oxidative addition/reductive elimination of aldehydes and ketones at rhodium. Synthesis and characterization of cis hydrido acyl complexes of rhodium(III) (1987) (13)
Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt. (2003) (13)
Synthesis and characterization of new rhodium and iridium complexes with trianisylphosphine, PAn3, and evaluation of their catalytic behavior in the homogeneous hydrogenation of cinnamaldehyde (2009) (13)
Selective hydrogenation of 1.10-phenanthrolines by silica-supported palladium nanoparticles (2008) (13)
Reactions of HC.tplbond.CCO2Et with (np3)CoH and (np3)Ni [np3 = N(CH2CH2PPh2)3]. Crystal structures of the alkenyl complexes [(np3)CoC(CO2Et):CH2]BPh4.cntdot.0.5THF and [(np3)NiCH:CHC(O)OEt]BPh4 (1986) (13)
A new P-chiral aminophosphine ligand containing a 2,2′-coupled pyrrolidine–phospholane ring system. Synthesis and coordination properties with rhodium(I) and iridium(I) fragments (1995) (13)
MECHANISTIC STUDY OF IR(H)2-ASSISTED TRANSFORMATIONS OF ETHYNE : CYCLOTRIMERIZATION, COOLIGOMERIZATION WITH ETHENE, AND REDUCTIVE COUPLING (1995) (13)
CH bond activation of thiophenes at iridium: a lower energy process than CS bond scission (1995) (13)
Cobalt(II) and nickel(II) trithiocarbonate complexes as nucleophilic reagents. Reactivity and X-ray structure of the trithiocarbonate complex [Co(tppme)(S2CSCH3)][BPh4]·1.5thf (1982) (13)
Triple‐Decker Sandwich Complexes of 4d and 5d Metals with cyclo‐Triphosphorus as μ,η3‐Ligand: Structural and Magnetic Properties (1980) (13)
Synthesis and Characterization of Trimetallic Complexes Containing M−Pd−M Arrays (M = Mo, W) and Their Relevance in Palladium-Catalyzed Metal−Carbon Bond Formation (2002) (12)
LLDPE with Exclusively Ethyl Branches by Tandem Catalysis with Single-Site Zr(IV)/Co(II) Catalysts (2008) (12)
Alternative routes to the synthesis of the cobalt thiocarbonyl complex [(np3)Co(CS)]BPh4. Influence of the CoH dissociation pathway on the reaction of the hydride (np3)CoH with heterocumulenes (np3 = tris(2-diphenylphosphinoethyl)amine) (1984) (12)
Synthesis of a novel palladium(0) carbonyl complex containing a tridentate phosphorus ligand. X-ray crystal structure of [Pd(CO)(CH3C(CH2PPh2)3)] (1993) (12)
Redox-induced reversible migration of hydrogen from metal to alkene (1988) (12)
Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric iridium-assisted C-C bond-forming reactions involving ethyne and ethene (1994) (12)
Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric transformations of ethyne at iridium (1993) (12)
Synthesis and x-ray structure of the dinuclear cobalt(0) complex (PhCCPh)Co2(CO)4(triphos) (1979) (12)
Migration of hydrogen from metal to alkene promoted by dioxygen addition. Oxygen atom transfer from a cis-(alkyl)(η2-dioxygen) complex of rhodium to organic and inorganic substrates (1989) (12)
Unprecedented transformation of a vinylidene ligand. Synthesis and ESR characterization of a paramagnetic .sigma.-acetylide complex of rhodium(II) (1988) (11)
Regioselective propylene dimerization by tetrahedral (imino)pyridine CoII dichloride complexes activated by MAO (2007) (11)
Soft matter nanocomposites by grafting a versatile organogelator to carbon nanostructures (2011) (11)
New enantiomerically pure aminoalcohols from (R)-α-methylbenzylamine and cyclohexene oxide (1996) (11)
Stepwise metal-assisted conversion of .eta.2-carbon diselenide to .eta.1-phosphoniodiselenoformate, .eta.2-diselenocarbonate, and .eta.2-diselenium. Crystal structure of the rhodium complexes [(triphos)Rh(Se2CO)]BPh4.cntdot.0.5CH2Cl2.cntdot.0.5C4H9OH and [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.cn (1988) (11)
Efficient Catalysis of Ammonia Borane Dehydrogenation (2009) (11)
A novel linkage-isomeric pair of dinuclear Pd(II) complexes bearing a bis-bidentate tetraphos ligand. (2009) (11)
Reactivity of [N(CH2CH2PPh2)3]Ni toward CS2, SCNPh, and COS. Structure of the η2S,C-bonded phosphoniodithiomethyl ester complex [Ph2S2Me)]BPh4 (1984) (11)
A New Bridging Mode of Carbon Disulfide in a Dinuclear Cobalt(I) Complex (1979) (11)
Stoichiometric and catalytic functionalization reactions of alkynes at transition metal complexes stabilized by tripodal polyphosphine ligands (1991) (11)
COUPLING OF TWO ETHYNE MOLECULES AT RHODIUM VERSUS COUPLING OF TWO RHODIUMATOMS AT ETHYNE. I, ELECTRONIC CONTROL ON THE INTERCONVERSION OF (MU -ETA 2 ,ETA 2-ETHYNE)- AND (MU -ETA 1,ETA 1-ETHYNE)DIRHODIUM COMPLEXES (1991) (11)
Synthesis of the New Chiral (R)- and (S)-Aminodiphosphine Ligands sec-Butylbis(2-(diphenylphosphino)ethyl)amine, sec-Butylbis(2-(dicyclohexylphosphino)ethyl)amine, and (α-Methylbenzyl)bis(2-(dicyclohexylphosphino)ethyl)amine and Their Organometallic Chemistry When Combined with Iridium (1997) (11)
Reactivity of the tetrahydroborate copper(I) complexes [(PR3)2Cu(η2-BH4)] (R = Ph, Cy) toward CO2, COS, and SCNPh (1983) (11)
2H-T1 Relaxation and Deuterium Quadrupole Coupling Constants in Transition Metalη2-D2 Complexes (1999) (10)
Metal‐Assisted Reaction of Carbon Disulfide with the “Etriphos” Phosphane Ligand: Synthesis and Structure of [(Etriphos)Fe{S2C(Et2PCH2)2CMe2}](BF4)2 (1980) (10)
Stepwise metal-assisted reduction of .eta.4-coordinated benzene to cyclohexene (1992) (10)
Synthesis and x-ray structure of the binuclear complex [(MeC(CH2PEt2)3)Fe(.mu.-Cl)3Fe(MeC(CH2PEt2)3)]BPh4.cntdot.CH2Cl2. Interpretation of the geometrical and electronic features through a recent MO approach for M2L9 complexes (1982) (10)
Mixed iridium-gold hydrides as model compounds for elucidating the interconversion between classical and nonclassical polyhydrides (1992) (10)
Reactions of coordinated ligands exemplified by the formation and transformation of the dithiocarbonate ligand in the rhodium (III) complex [(triphos) Rh(S2CO)] BPh4 (1988) (10)
A FIVE-COORDINATE RUTHENIUM(I) COMPLEX (1994) (10)
Potential application of (1,3-dithiol-2-ylidene)metal complexes to the synthesis of tetrathiafulvalene derivatives (1985) (10)
Nucleophilic properties and electrochemistry of five-coordinate rhodium(I) .sigma.-cyanide complexes. Synthesis and characterization of stable cis hydride cyanide complexes of rhodium(III) (1989) (10)
Stepwise metal-promoted conversion of η2-CS2 into η2-SO. Synthesis and crystal structure of the complex [(triphos)Rh(µ-SO)2Rh(triphos)][BPh4]2·HCONMe2[triphos = MeC(CH2PPh2)3] (1985) (10)
Nucleophilic attack on metal dithioformates by tertiary phosphines: preparation and structure of [(dppe)Fe{S2C(H)dppe}]BPh4 · CH2Cl2 (1982) (9)
4 Palladium-Based Electrocatalysts for Alcohol Oxidation in Direct Alcohol Fuel Cells (2011) (9)
1,3-Cycloaddition of pyrazole to the allenylidene ligand in [Re{CCCPh2}(CO)2{MeC(CH2PPh2)3}]+ (2003) (9)
Reactivity of carbon disulfide and triethylphosphine.carbon disulfide toward copper(I)-phosphine complexes. X-ray crystal structure of the complex [(PPh3)2Cu(S2CPEt3)]BPh4 (1983) (9)
Insertion of iridium into C-H and C-S bonds of 2,5-dimethylthiophene 2-methylbenzothiophene and 4,6-dimethyldibenzothiophene (1997) (9)
Alkyl, aryl and cis-dihydride complexes of iridium with the tripodal phosphine P(CH2CH2PPh2)3 as excellent precursors of active systems for the activation of hydrocarbon CH bonds (1987) (9)
Synthesis and Characterisation of a Novel Copper(II) Azamacrocycle‐Phosphonate 3D Polymeric Network (2005) (9)
Adduct of two 1,8‐naphthyridine molecules (one protonated) with tetrachloroferrate (III) (1992) (9)
π-Polyolefin and π-acetylene cobalt(I) complexes with the tris(tertiary phosphine) 1,1,1-tris(diphenylphosphinomethyl)ethane. X-ray structure of [(triphos)Co(η4-C7H8)]ClO4 · O.5 CH2Cl2 (1980) (9)
Metal-assisted three-fragment demolition of the dithiocarbonate ligand: a new synthetic route to homo- and heterobinuclear bis(.mu.-sulfido)metal complexes. Chemical, electrochemical, and spectroscopic characterization of a family of complexes of iron, cobalt, rhodium, and platinum with bridging sul (1988) (9)
CHEMISTRY OF ET3P.CS2 METAL COMPLEXES: SYNTHESIS OF 1,1-DITHIOLATE COMPLEXES VIA NUCLEOPHILIC ATTACKS ON ((TRIPHOS)CO(S2CPET3))(BPH4)2. X-RAY STRUCTURE OF ((TRIPHOS)CO(S2CO)) (1983) (9)
Activation of CH bonds in acetylene and terminal alkynes by rhodium(I) species. Crystal structure of cis-(ethynyl)hydride [(NP3)Rh(H)(CCH)]BPh4·1.5C4H8O (NP3 = N(CH2CH2PPh2)3) (1988) (8)
Enthalpy and entropy studies with some copper(II) bis(diamine) complexes and some comments on solvation energy and gas-phase enthalpies (1975) (8)
Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides (1995) (8)
Reactivity of formaldehyde and acetaldehyde toward [N(CH2CH2PPh2)3]Ni and [N(CH2CH2PPh2)3]CoH (1985) (8)
Reactivity of η2-CS3Me metal complexes as electrophiles (1983) (8)
Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride (1991) (8)
Ruthenium-assisted synthesis of gem-deuterated alkenes from monosubstituted propargyl alcohols and D2O (2000) (7)
From vegetable residues to hydrogen and electric power: Feasibility of a two step process operating with purple non sulfur bacteria (2007) (7)
Combinations of Transition Metal Catalysts for Reactor Blending (2004) (7)
DESIGNING HOMOGENEOUS CATALYSTS. RU(II) COMPLEXES WITH POLYDENTATE MIXED-P,N-DONOR LIGANDS (1992) (7)
1-Hexene Hydroformylation with the Rhodium (I) Triphosphane Complex [Rh(CO){PhP(CH2CH2PPh2)2}]PF6: An In Situ Study Using High-Pressure NMR Spectroscopy (1997) (7)
First example of opening and hydrogenation of 2,3-dihydrobenzo[b]thiophene to 2-ethylthiophenol assisted by a soluble metal complex (1999) (7)
Reactivity of η2-trithiocarbonate metal complexes as nucleophiles. Intramolecular mobility of the trithiocarbonate group in µ-CS3 binuclear complexes (1983) (7)
Characterization and reactivity of the tetrametallic Pd2-Mo2 complex Ph(Bu)P(η5-C5H4)Mo(CO)3Pd(μ-I)2PdMo(CO)3(η5-C5H4)P(Ph)Bu and its use to model Pd-catalyzed cross-coupling reactions leading to M-C≡C bonds (2004) (7)
Synthesis and chemistry of 2-oxacyclocarbene and 2-cyclovinyl ether ligands supported by the [{MeC(CH2PPh2)3}Re(CO)2]+ auxiliary (2002) (7)
Synthesis and crystal structure of the 2bonded CSe2 complex [(triphos )RhCl(2CSe2)]C6H6triphos =(Ph2PCH2)3CMe]. Metal-promoted head-to-head dimerization of CSe2 to C2Se4 (1984) (7)
A New Way to both Oligothiophene-Spaced Bimetallic Complexes and Functionalized Oligothiophenes (1997) (6)
Solid-gas reactions of molecular organometallic complexes. Detection of a metastable intermediate in the carbonylation of a nickel(0) complex (1993) (6)
[(Triphos)Co(CS2)Cr(CO)5]. A dinuclear heterometal complex containing a CS2 bridging group (1979) (6)
Synthesis and characterisation of κ1-P and κ2-P,N palladium(II) complexes of the open cage water soluble aminophosphine PTN (2008) (6)
Photochemistry of metal dithio- and diselenocarbonates. A new route to sulfido, disulfur, and diselenium complexes (1987) (6)
Cover Picture: Ethanol Oxidation on Electrocatalysts Obtained by Spontaneous Deposition of Palladium onto Nickel-Zinc Materials (ChemSusChem 1/2009) (2009) (6)
Unprecedented bridging mode of the triethylphosphine–carbon disulphide adduct PEt3·CS2. X-Ray crystal structure of the binuclear silver(I) complex [{Ag(S2CPEt3)(µ-S2CPEt3)}2][ClO4]2 (1983) (6)
New Functionalized Vinyl Monomers by Ethylene‐(Functionalized)‐Norbornene Hetero‐Trimerization Catalyzed by Cobalt(II)‐(Imino)pyridine Complexes (2008) (6)
Cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane, atriphos, and 1,1,1-tris(diethylphosphinomethyl)ethane, etriphos. Crystal structures of the trinuclear complexes [Co3(atriphos)2Cl6] and [Ni3(etriphos)2Cl6] · 2 CHCl3 (1981) (6)
Direct alcohol fuel cells as chemical reactors for the sustainable production of energy and chemicals: Energy and chemicals from renewables by electrocatalysis (2010) (6)
Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)‐P3 or ‐P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone. (1997) (5)
Cobalt(II) and nickel(II) complexes with tris(2-diethylphosphinoethyl)amine. Crystal and molecular structure of the trinuclear complex [Ni3(Etnp3)2Cl4](BPH4)2 (1980) (5)
Flow microcalorimetry in stepwise equilibria of metal complexes. Reactions of NN′- and NN-diethylethylenediamine with hydrogen and copper(II) ions (1975) (5)
Confined electrodeposition using a template-assisted procedure based on the selective desorption of a short chain thiol from a binary self-assembled monolayer formed on Ag( 1 1 1) (2010) (5)
Synthesis and reactivity toward reducing agents of the ethoxycarbonyl complex [(np3)Ni(CO2Et)]BPh4(np3=tris(2-diphenylphosphinoethyl)amine) (1984) (5)
Synthesis and structure of a rhodacyclobutene complex formed by addition of two F3CC.tplbond.CCF3 molecules to a Rh-.eta.2-CS2 moiety (1985) (5)
Chemoselective hydrogenation of α,β-unsaturated ketones to allylic alcohols, catalyzed by a mononuclear ruthenium complex containing trans PnBu3 and PPh3 ligands (2007) (5)
Large-scale synthesis of chiral ferrocenyl imino-phosphines (2005) (5)
Synthesis and crystal structure of the dihapto-bonded phenylisothiocyanate complex [(triphos)Ni(η2-SCNPh)]·0.5 CH2Cl2 (1983) (5)
Dihydrogen Metal Complexes in Catalysis (2001) (5)
A family of hydride complexes of rhodium. Crystal structure of the paramagnetic rhodium(III)–rhodium(II) complex [(triphos)Rh(µ-H)3Rh(triphos)](BPh4)2·DMF [triphos = MeC(CH2PPh2)3, DMF = dimethylformamide] (1986) (5)
Electrooxidation in Alkaline Media of Ethylene Glycol and Glycerol on Pd‐(Ni‐Zn)/C Anodes in Direct Alcohol Fuel Cells (2013) (5)
Iridium-Catalyzed C=O Hydrogenation (2010) (4)
Homogeneous decarbonylation of ethyl formate at rhodium. Evidence for the formation of a cis-hydride(ethoxycarbonyl) intermediate through CH bond cleavage (1988) (4)
Triethylphosphine—carbgn disulfide zwitterion as a bridging six-electron donor ligand in [Mo(CO)2(PEt3)(μ-S2CPEt3)]2; synthesis and x-ray crystal structure (1981) (4)
REACTIVITY OF THE TRIETHYLPHOSPHINE‐CARBON DISULFIDE ADDUCT (ET3P.CS2) TOWARD COBALT(II) CATIONS IN THE PRESENCE OF THE TRIS (TERTIARY PHOSPHINES) TRIPHOS AND ETRIPHOS. X‐RAY CRYSTAL STRUCTURE OF THE COMPLEX ((ETRIPHOS)CO(S2C(H)PET3))(BPH4)2 (1983) (4)
New metal-assisted synthesis of tetrakis(trifluoromethyl)tetrathiafulvalene (1984) (4)
Synthesis of palladium(II) complexes containing a new alpha-D-xylofuranose-modified diphosphine and their application as catalyst precursors in the co- and terpolymerization of CO-ethene and propene. (2008) (4)
Unprecedented intramolecular attack by a phosphine on a η2-dithiomethyl ester group. X-ray crystal structure of the complex [Ph2S2Me)]BPh4 (1983) (4)
Hydrogenation of Arenes and Heteroaromatics (2008) (4)
Thiophene C–S bond cleavage by rhodium and iridium. An unprecedented bridging mode of the open C4H4S fragment (1995) (4)
Confined electrodeposition of CdS in the holes left by the selective desorption of 3-mercapto-1-propionic acid from a binary self-assembled monolayer formed with 1-octanethiol. (2010) (4)
A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a η1-thioaldehyde (1994) (4)
Metathesis of CS2‐Like Heteroallenes on 1,1‐Dithio Complexes of Rhodium(III) (1987) (4)
Reversible Double Addition of H2 on a Bis(μ-sulfido) Binuclear Rhodium Complex. (1987) (4)
Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II) (1998) (4)
Enantioselective hydrogenation of prochiral substrates in catalytic membrane reactors (2011) (4)
Palladium‐Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells (2010) (4)
Cover Picture: Self-Sustainable Production of Hydrogen, Chemicals, and Energy from Renewable Alcohols by Electrocatalysis (ChemSusChem 7/2010) (2010) (3)
Hydrogenation, Hydrogenolysis and Desulphurization of Thiophenes by Soluble Metal Complexes (1998) (3)
Pulsed laser photolysis of Os(pp3)H2[pp3= P(CH2CH2PPh2)3]: kinetic selectivity for reaction with methane (1994) (3)
Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH(2)PPh(2))(3)}Ir(H(2))(H)(2)]BPh(4). (1997) (3)
Distinct reaction pathways for some classical and nonclassical transition metal dihydrides (1990) (3)
Chemoselective Hydrogen-Transfer Reduction of α,β-Unsaturated Ketones Catalyzed by Isostructural Iron(II), Ruthenium(II), and Osmium(II) cis Hydride η2-Dihydrogen Complexes. (1993) (3)
Classical and Nonclassical Polyhydride Ruthenium(II) Complexes Stabilized by the Tetraphosphine P(CH2CH2PPh2)3. (1991) (3)
mer,trans‐[Bis(2‐diphenylphosphinoethyl)(n‐propyl)amine‐N,P,P']dichloro(triphenylphosphine)ruthenium(II) 0.5‐Dichloromethane Solvate (1995) (3)
Metal-promoted trimerization of carbon disulphide. Synthesis and structure of the dinuclear copper(I) complex [(PPh3)2Cu(µ-S2CSCH2SCS2)Cu(PPh3)2] (1983) (3)
Hydrogen Energy. Challenges and Prospects. By D. A. J. Rand and R. M. Dell. (2008) (3)
Synthesis and characterization of heterobimetallic complexes containing C-S cleaved thiophenes (1998) (3)
Radial trinuclear complexes of cobalt(II) and nickel(ll) with tris(2-dimethylphosphinoethyl)- amine (1978) (3)
Synthesis and electrochemistry of some homo- and hetero-dinuclear trihydride complexes of rhodium, iron, cobalt, and nickel (1986) (3)
Electron‐Rich Iridium Complexes with Mixed‐Donor Polydentate Ligands. Chemoselective Catalysts in Hydrogen‐Transfer Reduction of α,. beta.‐Unsaturated Ketones. (1991) (2)
Synthesis and Reactivity of Metal Complexes with the Zwitterionic Et3P—CS2 Ligand. Structure of the Dithiocarbonato Complex [(triphos)Co(S2CO)] (1982) (2)
Synthesis of New Hydride-Carbyne and Hydride-Vinylcarbyne Complexes of Osmium(II) by Reaction of OsH2Cl2(iPr3P)2 with Terminal Alkynes (1995) (2)
A Stable η2-H2 Complex of Cobalt. Role of the H-H Interaction in Hydrogen Transfer from Metal to Alkene. (1989) (2)
Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μ-S2 Groups Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3 (1990) (2)
Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Triphosphines Combining Phosphorus, Planar, and Carbon Chirality (2004) (2)
Polyketone Nanocomposites by Palladium-Catalyzed Ethylene-Carbon Monoxide-(Propene) Co(Ter)polymerization Inside an Unmodified Layered Silicate (2006) (2)
REGIO- AND STEREOSELECTIVE DIMERIZATION OF 1-ALKYNES CATALYZED BY CLASSICAL AND NONCLASSICAL RUTHENIUM AND OSMIUM POLYHYDRIDO COMPLEXES (1996) (2)
Cycloaddition of dimethylacetylene dicarboxylate to η2-coordinated trithiocarbonate (1982) (2)
REACTIVITY OF COPPER(I) TETRAHYDROBORATES TOWARD CARBON DIOXIDE AND CARBONYL SULFIDE. STRUCTURE OF (TRIPHOS)CU(η1-O2CH) (1985) (2)
Chloro[o-(diphenylphosphino)benzaldehyde]{N-[o-(diphenylphosphino)benzylidene]ethylamine}(tetrachloro-o-catecholato)iridium(III) (1994) (2)
Hydrogenation of Benzene over Silica-Supported Catalysts (2006) (2)
Thiophene, Benzo(b)thiophene and Dibenzo(b,d)thiophene as Precursors to Highly Conjugated Organosulfur Compounds. (2010) (2)
Bis(cyclopentadienyl)phenylphosphine as Ligand Precursor for Assembling Heteropolymetal Complexes (2008) (2)
STRUCTURAL COMPARISON OF COBALT AND NICKEL COMPLEXES WITH CARBON DISULFIDE AND ISOTHIOCYANATOBENZENE MOLECULES STABILIZED BY TRIPODAL POLYPHOSPHINE LIGANDS. IMPLICATIONS FOR THE NATURE OF THE CHEMICAL BONDING IN COMPOUNDS CONTAINING C (1984) (2)
Rhodium Complexes with the Tripodal Triphosphine MeC(CH2PPh2)3 as Highly Reactive Systems for Hydrogenation and Hydroformylation of Alkenes. (1988) (1)
Typical Reactions: Sections 6.3–6.4 (2005) (1)
Domino Rhodium/Palladium‐Catalyzed Dehydrogenation Reactions of Alcohols to Acids by Hydrogen Transfer to Inactivated Alkenes. (2010) (1)
anti,mer‐[Bis(2‐diphenylphosphinoethyl)(n‐propyl)amine‐N,P,P'](phenylethynyl)[(Z)‐1‐p‐tolyl‐4‐phenyl‐η3‐but‐1‐en‐3‐ynyl]ruthenium(II) Chloroform Solvate (1996) (1)
Catalytic Hydrogenolysis of Thiophenic Molecules to Thiols by Soluble Metal Complexes (1996) (1)
Synthesis, reactivity and X-ray structure of the complex [(depe)2Fe(S2CPEt3)](BPh4)2 (depe = 1,2-bis(diethylphosphino)ethane) (1981) (1)
Structure of (4-pentynoato-O,O'){tris[2-(diphenylphosphino)ethyl]phosphine}iron(II) tetraphenylborate (1992) (1)
fuel cell membrane electrode assemblies for fuel cells, their manufacture, use and containing them (2005) (1)
Evidence for a Molecular Hydrogen Complex of Rhodium. Some Factors Affecting cis-Dihydride ←→ η2-Dihydrogen Exchange. (1987) (1)
Facile Activation of H2 on 1,1- and 1,2-Dithio Complexes of Rhodium(III). An Experimental Study. (1988) (1)
A Novel Oxygen-Carrying and Activating System of Rhodium(III). Oxidation and Oxygenation Reactions of 3,5-Di-tert.-butylcatechol Catalyzed by a Rhodium(III) Catecholate Through Its (η1-Superoxo) (η2-semiquinonato)rhodium(III) Complex. (1990) (1)
Modified multi-walled carbon nanotubes potentially suitable for intracellular pH measurements (2010) (1)
FACILE REDUCTION OF CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE BY COPPER(I) BOROHYDRIDE. X-RAY CRYSTAL STRUCTURE OF THE COMPLEX ((TRIPHOS)CU(O2CH)) (1983) (1)
Intramolecular, reversible C–H oxidative addition–reductive elimination at rhodium. Reaction of the intermediate with different types of C–H bonds and dihydrogen (1987) (1)
Immobilization of Optically Active Rhodium‐Diphosphine Complexes on Porous Silica via Hydrogen Bonding. (2001) (1)
Formation and X-ray Structure of Unusual Doubly and Triply Condensed Cyclic Systems Complexes . 1 . The [ 2 + 21 Condensation of an Alkyne on a (2001) (0)
Metathesis of CS2-Like Heteroallenes on 1,1-Dithio Complexes of Rhodium(III). (1987) (0)
Oxazolidonderivate, methods for their manufacture and pharmaceutical compositions containing them (1978) (0)
Homo- and Heterobimetallic Trihydride Complexes Stabilized by the Tripodal Phosphine Ligand MeC(CH2PPh2)3: Experimental and Theoretical Studies. (1989) (0)
Photochemistry of Metal Dithio- and Diselenocarbonates. A New Route to Sulfido, Disulfur, and Diselenium Complexes. (1987) (0)
Catalysts for fuel cell electrodes based on platinum and its alloys, making and using these catalysts and fuel cells containing the same (2005) (0)
ENTHALPY AND ENTROPY STUDIES WITH COPPER(II)-BIS(DIAMINE) COMPLEXES AND SOME COMMENTS ON SOLVATION ENERGY AND GAS-PHASE ENTHALPIES (1975) (0)
Utilisation de catalyseurs metalliques a nanostructures pour la production de gaz de synthese et de melanges gazeux riches en hydrogene (2005) (0)
Nucleophilic Properties and Electrochemistry of Five-Coordinate Rhodium(I) σ-Cyanide Complexes. Synthesis and Characterization of Stable cis Hydride Cyanide Complexes of Rhodium(III). (1989) (0)
Carbon monoxide-olefins co-(ter-)polymerization in the presence of GTR (Ground Tyre Rubber) microparticles (2007) (0)
Hydrogenation and Hydrogenolysis of Thiophenic Molecules (2010) (0)
COBALT(II) AND NICKEL(II) COMPLEXES WITH TRIS(2-DIETHYLPHOSPHINOETHYL)AMINE. CRYSTAL AND MOLECULAR STRUCTURE OF THE TRINUCLEAR COMPLEX (NI3(ETNP3)2CL4)(BPH4)2 (1981) (0)
Polymerization of conjugated dienes in the presence of iron-based complex catalysts (2002) (0)
Rhodium Complexes with Tripodal Polyphosphines as Excellent Precursors to Systems for the Activation of H-H and C-H Bonds. (1988) (0)
Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Triphosphines Combining Phosphorus, Planar, and Carbon Chirality Synthesis of New Diastereomerically Pure Ferrocenyl Triphosphines (2004) (0)
Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μS2 Groups, Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3 (1990) (0)
NEW DIASTEREOMERICALLY PURE AMINODIOL LIGANDS FROM (R)-(-)-PHENYLGLYCINOL AND CYCLOHEXENE OXIDE. SYNTHESIS AND CHARACTERIZATION OF THE LIGANDS AND OF THEIR DIOXOMOLYBDENYL COMPLEXES (1996) (0)
Device for handling and / or processing of objects. (2007) (0)
REACTIVITY OF η2-S-METHYL TRITHIOCARBONATOMETAL COMPLEXES AS ELECTROPHILES (1984) (0)
Synthesis, Characterization, and Electrochemical Properties of a Family of Dinuclear Rhodium Complexes Containing Two Terminal Hydride Ligands and Two Hydride (or Chloride) Bridges. Stoichiometric and Catalytic Hydrogenation Reactions (1989) (0)
Electrophilic addition of oxygen, sulphur, and selenium to η2-CS2 and η2-CS2Me cobalt complexes (1983) (0)
Iridium‐Catalyzed CO Hydrogenation (2009) (0)
COBALT(II) AND NICKEL(II) TRITHIOCARBONATE COMPLEXES AS NUCLEOPHILIC REAGENTS. REACTIVITY AND X-RAY STRUCTURE OF THE TRITHIOCARBONATE COMPLE S,S-(METHYLTRITHIOCARBONATO)(1,1,1,-TRIS(DIPHENYLPHOSPINOMETHYL)ETHANE)COBAL TETRAPHENYLBORATE TETRAHYDROFURAN (1/1.5) (1982) (0)
Stepwise Metal-Assisted Conversion of η2-CSe2 to η1-Se2CPEt3, η2-Se2CO, and η2-Se2. Crystal Structures of the Complexes ((triphos)Rh(Se2CO))BPh4·0.5 CH2Cl2·0.5 C4H9OH and ((triphos)Rh(μ-Se2)2Rh(triphos))(BPh4)2·2 DMF (triphos: MeC(CH2 (1989) (0)
METAL-PROMOTED TRANSFORMATION OF CARBON DIOXIDE INTO CARBON MONOXIDE. X-RAY CRYSTAL STRUCTURE OF THE NICKEL-CARBONATE COMPLEX (O:PPH2CH2C(CH3)(CH2PPH2)2)NI(O2CO).0.5H2O.C6H6 (1984) (0)
Chemical and Electrochemical Oxidation of the Phosphoniodichalcogenoformate Complexes (triphos)RhCl(X2CPEt3) (triphos: MeC(CH2PPh2)3; X: S, Se). Synthesis of Metal Dichalcogenocarbonates from O2 and Phosphonium-Betaine-Like Complexes. (1988) (0)
A New P-Chiral Aminophosphine Ligand Containing a 2,2′-Coupled Pyrrolidine-Phospholane Ring System. Synthesis and Coordination Properties with Rhodium(I) and Iridium(I) Fragments (1995) (0)
(Dithiocarbonato) [1,1,1-Tris(Diphenylphosphinomethyl)Ethane]Rhodium (III) Tetraphenylborate Solvate (2007) (0)
Hydrogenation, Hydrolysis, and Desulfurization of Thiophenes by Soluble Metal Complexes: Recent Achievements and Future Directions (1998) (0)
A CARBON DISULFIDE BRIDGE OF A NEW TYPE IN A BINUCLEAR COBALT(I) COMPLEX (1979) (0)
Energy and Chemicals from Renewables by Electrocatalysis (2009) (0)
A Homogeneous Iron(II) System Capable of Selectively Catalyzing the Reduction of Terminal Alkynes to Alkenes and Buta-1,3-dienes. (1989) (0)
Platinum-free electro-catalyst (2003) (0)
Membrane-electrode assembly for a fuel cell, their manufacture and use and fuel cells that incorporate them. (2005) (0)
Isomerization of Allylic Alcohols to Carbonyl Compounds by Aqueous‐Biphase Rhodium Catalysis. (2001) (0)
Cover Picture: Electrooxidation of Ethylene Glycol and Glycerol on Pd‐(Ni‐Zn)/C Anodes in Direct Alcohol Fuel Cells (ChemSusChem 3/2013) (2013) (0)
First Example of Opening and Hydrogenation of 2,3-Dihydrobenzo[b]thiophene to 2-Ethylthiophenol Assisted by a Soluble Metal Complex. (1999) (0)
Alkene/CO Copolymerisation (2005) (0)
Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides. (1996) (0)
SYNTHESIS AND CRYSTAL STRUCTURE OF TWO ISOMORPHOUS RHODIUM AND IRIDIUM COMPLEXES WITH CYCLO-TRIPHOSPHORUS AND 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE (1980) (0)
TRIPLE-DECKER COMPLEXES OF 4D AND 5D METALS WITH CYCLO-TRIPHOSPHORUS AS μ,η3 LIGAND: STRUCTURE AND MAGNETIC PROPERTIES (1980) (0)
Activation of 1-Alkynes at Tripodal (Polyphosphine)rhodium Systems. Regioselective Synthesis of Enol Esters from 1-Alkynes and Carboxylic Acids Catalyzed by Rhodium(I) Monohydrides. (1990) (0)
Rücktitelbild: Electrochemical Milling and Faceting: Size Reduction and Catalytic Activation of Palladium Nanoparticles (Angew. Chem. 34/2012) (2012) (0)
Special Catalysts and Processes: Sections 3.2.6–3.2.14 (2008) (0)
TRIPHOS)CO(CS2)CR(CO)5). A DINUCLEAR HETEROMETAL COMPLEX CONTAINING A CARBON DISULFIDE BRIDGING GROUP (1979) (0)
Synthesis of the New Chiral Aminodiphosphine Ligands (R)‐ and (S)‐(. alpha.‐Methylbenzyl)bis(2‐(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of α,β‐Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis. (1995) (0)
Aqueous-Phase Catalysis: Typical Reactions (2008) (0)
Synthesis, Redox Properties, and Reactivity of a Novel Family of Electron‐Rich Vinylidene and Vinylphosphonium Complexes of Rhodium(I). (1990) (0)
Hydrogenation, Hydrogenolysis, and Hydrodesulfurization of Thiophenes (2006) (0)
Palladium-Catalyzed Arylation of Malonates and Cyanoesters Using Sterically Hindered Trialkyl- and Ferrocenyldialkylphosphine Ligands: A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate (2003) (0)
HYDROGENATION, HYDROGENOLYSIS DES ULPHURIZATIO N 0 F THIO PHENES S 0 LUBLE METAL C 0 MPLEXES (1998) (0)
Genesis of Tetrathiooxalate‐like C2S4 and C2Se4 Units. A Multiform Experimental Study and the Relevant Theoretical Implications for the Role of Transition‐Metal Fragments. (1987) (0)
Metal-Assisted Three-Fragment Demolition of the Dithiocarbonate Ligand: A New Synthetic Route to Homo- and Heterobinuclear Bis(μ-sulfido)metal Complexes. Chemical, Electrochemical, and Spectroscopic Characterization of a Family of Com (1988) (0)
THIOPHENE, BENZOBTHIOPHENE AND DIBENZOB,DTHIOPHENE AS PRECURSORS TO HIGHLYCONJUGATED ORGANOSULFUR COMPOUNDS (1997) (0)
Transition Metal Complexes with the C1‐Symmetric Diphosphines (R)‐(R)‐3‐Benzyl‐2,4‐bis(diphenylphosphino)pentane and (R)‐(R)‐3‐Benzyl(p‐sulfonate)‐2,4‐bis(diphenylphosphino)pentane Sodium Salt. Applications to Enantioselective Catalysis in Different Phase Systems. (2001) (0)
Bifunctional activation of CO2: a case where the basic and acidic sites are not held in the same structure (1984) (0)
FLOW MICROCALORIMETRY IN STEPWISE EQUILIBRIA OF METAL COMPLEXES, REACTIONS OF NN′- AND NN-DIETHYLETHYLENEDIAMINE WITH HYDROGEN AND COPPER(II) IONS (1975) (0)
CCDC 195274: Experimental Crystal Structure Determination (2003) (0)
Novel Reactions of the (BPh4)‐ Salt of the Bifunctional Complex ((triphos)Rh(S2CO))+ (triphos: MeC(CH2PPh2)3): One‐Electron Reduction, Cleavage of B‐H and B‐C Bonds, and Metathesis of CS2‐like Heteroallene Molecules. (1989) (0)
Comprehensive Experimental and Interpretational Study of the Complex Formation and Transformations Involving o-Quinoid Molecules and an L3M-Type Metal Fragment (M: Cobalt). (1988) (0)
RADIAL TRINUCLEAR COMPLEXES OF COBALT(II) AND NICKEL(II) WITH TRIS(2-DIMETHYLPHOSPHINOETHYL)AMINE (1979) (0)
Few layer graphene decorated with Pd nanoparticles: synthesis, characterisation and catalytic applications in the electrochemical oxidation of alcohols (2012) (0)
SYNTHESIS AND REACTIVITY OF METAL COMPLEXES WITH ZWITTERION LIGANDS ET3P-CS2; STRUCTURE OF THE DITHIOCARBONATO COMPLEX ((TRIPHOS)CO(S2CO)) (1982) (0)
Synthesis and Reactivity of Metal Complexes with the Zwitterionic Et3PCS2 Ligand. X‐Ray Structure of the Dithiocarbonate Complex [(triphos) CoS2CO] (1982) (0)
SMOOTH MUSCLE RELAXANT PROPERTIES OF 2-NAPHTHYL-OXYACETIC ACID ESTERS (1978) (0)
Confined Electrodeposition of Metals and Semiconductors (2009) (0)
Asymmetric Alkylation or Amination of Allylic Esters (2005) (0)
REACTIVITY OF η2-TRITHIOCARBONATE METAL COMPLEXES AS NUCLEOPHILES. INTRAMOLECULAR MOBILITY OF THE TRITHIOCARBONATE GROUP IN μ-CS3 BINUCLEAR COMPLEXES (1983) (0)
Tripodal Polyphosphine Ligands in Homogeneous Catalysis. Part 1. Hydrogenation and Hydroformylation of Alkynes and Alkenes Assisted by Organorhodium Complexes with MeC(CH2PPh2)3. (1990) (0)
UNPRECENDENTED BRIDGING MODE OF THE TRIETHYLPHOSPHINE-CARBON DISULFIDE ADDUCT PET3.CS2. X-RAY CRYSTAL STRUCTURE OF THE BINUCLEAR SILVER(I) COMPLEX BIS(μ-(PHOSPHONIODITHIOCARBOXYLATO-S,S′))(PHOSPHONIODITHIOCARBOXYLATO-S,S′)S# ILVER)BIS (1983) (0)
Use of nanostructured metallic catalysts for the production of syngas and gassous mixtures rich in H2 (2005) (0)
IRON-ASSISTED REACTION OF CARBON DISULFIDE WITH TRIETHYLPHOSPHINE. SYNTHESIS AND STRUCTURE OF THE COMPOUND [Et3PCH2S2CH2PEt3](BPh4)2 (1981) (0)
Modelling the Hydrodenitrogenation of Aromatic N-Heterocycles in the Homogeneous Phase. (2001) (0)

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What Schools Are Affiliated With Claudio Bianchini?

Claudio Bianchini is affiliated with the following schools:

University of Trieste
University of York
University of Milan
University of Rovira i Virgili
University of Strasbourg
University of Mons-Hainaut
University of Teramo
University of Florence