Claudio Bianchini
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Claudio Bianchinichemistry Degrees
Chemistry
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Physical Chemistry
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Chemistry
Claudio Bianchini's Degrees
- Bachelors Chemistry University of California, Berkeley
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(Suggest an Edit or Addition)Claudio Bianchini's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Palladium-based electrocatalysts for alcohol oxidation in half cells and in direct alcohol fuel cells. (2009) (1365)
- Pd and Pt–Ru anode electrocatalysts supported on multi-walled carbon nanotubes and their use in passive and active direct alcohol fuel cells with an anion-exchange membrane (alcohol = methanol, ethanol, glycerol) (2009) (402)
- Ethylene oligomerization, homopolymerization and copolymerization by iron and cobalt catalysts with 2,6-(bis-organylimino)pyridyl ligands (2006) (290)
- Olefin oligomerization, homopolymerization and copolymerization by late transition metals supported by (imino)pyridine ligands (2010) (254)
- Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis (2002) (237)
- Progress in stereoselective catalysis by metal complexes with chiral ferrocenyl phosphines (2004) (177)
- Selective oxidation of ethanol to acetic acid in highly efficient polymer electrolyte membrane-direct ethanol fuel cells (2009) (155)
- An in situ Fourier transform infrared spectroelectrochemical study on ethanol electrooxidation on Pd in alkaline solution (2010) (152)
- Hydrogenation, Hydrogenolysis, and Desulfurization of Thiophenes by Soluble Metal Complexes: Recent Achievements and Future Directions (1998) (126)
- Electrooxidation of ethylene glycol and glycerol on Pd-(Ni-Zn)/C anodes in direct alcohol fuel cells. (2013) (125)
- Enantioselective Hydrogenation of 2-Methylquinoxaline to (−)-(2S)-2-Methyl-1,2,3,4-tetrahydroquinoxaline by Iridium Catalysis (1998) (114)
- First-Principles Considerations on Catalytic Activity of Pd toward Ethanol Oxidation (2009) (108)
- A ruthenium(II) enynyl complex mediates the catalytic dimerization of 1-alkynes to Z-1,4-disubstituted enynes (1991) (108)
- Selective hydrogenation of 1-alkynes to alkenes catalyzed by an iron(II) cis-hydride .eta.2-dihydrogen complex. A case of intramolecular reaction between .eta.2-H2 and .sigma.-vinyl ligands (1992) (108)
- Oligomerisation of Ethylene to Linear α‐Olefins by new Cs‐ and C1‐Symmetric [2,6‐Bis(imino)pyridyl]iron and ‐cobalt Dichloride Complexes (2003) (103)
- Ethanol oxidation on electrocatalysts obtained by spontaneous deposition of palladium onto nickel-zinc materials. (2009) (103)
- Catalysis for sustainable energy production. (2009) (102)
- Selective Oligomerization of Ethylene to Linear α-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands: Influence of the Heteroatom in the Organyl Group on the Catalytic Activity (2003) (101)
- The Mechanism of the Ru-Assisted C−C Bond Cleavage of Terminal Alkynes by Water (1996) (100)
- PREPARATION, CHARACTERIZATION, AND PERFORMANCE OF TRIPODAL POLYPHOSPHINE RHODIUM CATALYSTS IMMOBILIZED ON SILICA VIA HYDROGEN BONDING (1999) (100)
- Self-sustainable production of hydrogen, chemicals, and energy from renewable alcohols by electrocatalysis. (2010) (96)
- Chemoselective hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones catalyzed by isostructural iron(II), ruthenium(II), and osmium(II) cis-hydride (.eta.2-dihydrogen) complexes (1993) (96)
- REGIO- AND STEREOSELECTIVE DIMERIZATION OF PHENYLACETYLENE TO (Z)-1,4-DIPHENYLBUT-3-EN-1-YNE BY RUTHENIUM(II) CATALYSIS. REACTION MECHANISM INVOLVING INTERMOLECULAR PROTONATION OF SIGMA -ALKYNYL BY 1-ALKYNE (1994) (92)
- Single-site and nanosized Fe–Co electrocatalysts for oxygen reduction: Synthesis, characterization and catalytic performance (2011) (91)
- Energy efficiency enhancement of ethanol electrooxidation on Pd-CeO(2)/C in passive and active polymer electrolyte-membrane fuel cells. (2012) (90)
- Tripodal polyphosphine ligands in homogeneous catalysis. 1. Hydrogenation and hydroformylation of alkynes and alkenes assisted by organorhodium complexes with MeC(CH2PPh2)3 (1990) (86)
- Tripodal polyphosphine ligands control selectivity of organometallic reactions (1992) (85)
- Recent Aspects of Asymmetric Catalysis by Immobilized Chiral Metal Catalysts (2002) (80)
- A biologically inspired organometallic fuel cell (OMFC) that converts renewable alcohols into energy and chemicals. (2010) (68)
- A comparison between silica-immobilized ruthenium(II) single sites and silica-supported ruthenium nanoparticles in the catalytic hydrogenation of model hetero- and polyaromatics contained in raw oil materials (2003) (68)
- Methoxycarbonylation of Ethene by Palladium(II) Complexes with 1,1‘-Bis(diphenylphosphino)ferrocene (dppf) and 1,1‘-Bis(diphenylphosphino)octamethylferrocene (dppomf) (2003) (67)
- In situ FTIR spectroelectrochemical study on the mechanism of ethylene glycol electrocatalytic oxidation at a Pd electrode. (2011) (65)
- A deceptively simple case of selective hydrogenation of phenylacetylene to styrene catalyzed by a cis-hydrido(.eta.2-dihydrogen)ruthenium(II) complex (1992) (65)
- Classical and nonclassical polyhydride ruthenium(II) complexes stabilized by the tetraphosphine P(CH sub 2 CH sub 2 PPh sub 2 ) sub 3 (1991) (64)
- Palladium Nanoparticles Supported on Hyperbranched Aramids: Synthesis, Characterization, and Some Applications in the Hydrogenation of Unsaturated Substrates (2003) (64)
- SYNTHETIC MODELS FOR CATECHOL 1,2-DIOXYGENASES. INTERCEPTION OF A METAL CATECHOLATE-DIOXYGEN ADDUCT (1991) (63)
- Electrochemical milling and faceting: size reduction and catalytic activation of palladium nanoparticles. (2012) (63)
- Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis (2003) (63)
- HDS Model Systems. Coordination, Opening, and Hydrogenation of Benzo[b]thiophene at Iridium (1994) (63)
- Opening, desulfurization, and hydrogenation of thiophene at iridium. An experimental study in a homogeneous phase (1993) (62)
- Preparation, Characterization, and Performance of the Supported Hydrogen-Bonded Ruthenium Catalyst [(sulphos)Ru(NCMe)3](OSO2CF3)/SiO2. Comparisons with Analogous Homogeneous and Aqueous-Biphase Catalytic Systems in the Hydrogenation of Benzylideneacetone and Benzonitrile (2000) (62)
- Ruthenium-promoted Z-selective head-to-head dimerization of terminal alkynes in organic and aqueous media (2005) (62)
- C−C Bond Formation between Vinylidene and Alkynyl Ligands at Ruthenium(II) Leading to either Enynyl or Dienynyl Complexes† (1996) (59)
- Electronic influence of the thienyl sulfur atom on the oligomerization of ethylene by cobalt(II) 6-(thienyl)-2-(imino)pyridine catalysis (2007) (59)
- Synthesis of New Polydentate Nitrogen Ligands and Their Use in Ethylene Polymerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides and Methylaluminoxane (2007) (57)
- Rhodium complexes with tripodal polyphosphines as excellent precursors to systems for the activation of H-H and C-H bonds (1988) (57)
- A homogeneous iron(II) system capable of selectivity catalyzing the reduction of terminal alkynes to alkenes and buta-1,3-dienes (1989) (57)
- Hydrogenation and hydrogenolysis of thiophenic molecules catalysed by soluble metal complexes (1996) (56)
- Palladium(II) Complexes with 1,1‘−Bis(diphenylphosphino)ferrocenes [Fe(η5-C5R4PPh2)2]n+ (dppf, R = H, n = 0; dppomf, R = Me, n = 0; dppomf+, R = Me, n = 1). Synthesis, Characterization, and Catalytic Activity in Ethene Methoxycarbonylation (2002) (56)
- A stable .eta.2-dihydrogen complex of cobalt. Role of the hydrogen-hydrogen interaction in hydrogen transfer from metal to alkene (1988) (55)
- Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes. (2010) (55)
- Metal-hydride alkynyl .fwdarw. metal-vinylidene rearrangements occurring in both solid state and solution. Role of the 1-alkyne substituent in determining the relative stability of .pi.-alkyne, hydride alkynyl, and vinylidene forms at cobalt (1991) (55)
- In Situ High-Pressure 31P{1H} NMR Studies of the Hydroformylation of 1-Hexene by RhH(CO)(PPh3)3 (2000) (53)
- Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles: evidence for substrate activation on Rh(single-site)-Pd(metal) moieties. (2006) (53)
- Activation of molecular hydrogen over a binuclear complex with Rh2S2 core: DFT calculations and NMR mechanistic studies. (2004) (50)
- Reversible double addition of hydrogen on a bis(.mu.-sulfido) binuclear rhodium complex (1986) (50)
- Renewable H2 from glycerol steam reforming: effect of La2O3 and CeO2 addition to Pt/Al2O3 catalysts. (2010) (50)
- Electron-rich iridium complexes with mixed-donor polydentate ligands. Chemoselective catalysts in hydrogen-transfer reduction of .alpha.,.beta.-unsaturated ketones (1990) (50)
- Improvement in the efficiency of an OrganoMetallic Fuel Cell by tuning the molecular architecture of the anode electrocatalyst and the nature of the carbon support (2012) (49)
- An .eta.4-benzene species mediates acetylene cyclotrimerization (1991) (49)
- Oligomerisation of ethylene to linear α-olefins by tetrahedral cobalt(II) precursors stabilised by benzo[b]thiophen-2-yl-substituted (imino)pyridine ligands ☆ (2004) (49)
- Ligand effects in the non-alternating CO-ethylene copolymerization by palladium(II) catalysis. (2007) (49)
- Ligand and Solvent Effects in the Alternating Copolymerization of Carbon Monoxide and Olefins by Palladium−Diphosphine Catalysis (2002) (49)
- Functionalization of Multiwalled Carbon Nanotubes with Cyclic Nitrones for Materials and Composites: Addressing the Role of CNT Sidewall Defects (2011) (48)
- Selective σ-Bond Metathesis in Alkyl−Aryl and Alkyl−Benzyl Yttrium Complexes. New Aryl− and Benzyl−Hydrido Yttrium Derivatives Supported by Amidopyridinate Ligands (2009) (48)
- Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands (1997) (46)
- A novel oxygen-carrying and activating system of rhodium(III). Oxidation and oxygenation reactions of 3,5-di-tert-butylcatechol catalyzed by a rhodium(III) cathecolate through its (.eta.1-superoxo)(.eta.2-semiquinonato)rhodium(III) complex (1990) (46)
- Liquid-Biphase Hydrogenolysis of Benzo[b]thiophene by Rhodium Catalysis (1997) (46)
- Asymmetric Hydroformylation of Olefins with Rh Catalysts Modified with Chiral Phosphine−Phosphite Ligands (2007) (45)
- STYRENE CYCLOPROPANATION AND ETHYL DIAZOACETATE DIMERIZATION CATALYZED BY RUTHENIUM COMPLEXES CONTAINING CHIRAL TRIDENTATE PHOSPHINE LIGANDS (1999) (45)
- Water-Soluble Palladium(II) Catalysts for the Alternating Co- and Terpolymerization of CO and Olefins in Aqueous Phase (1999) (45)
- In-depth NMR and IR study of the proton transfer equilibrium between ({(MeC(CH 2 PPh 2 ) 3 }Ru(CO)H 2 ) and hexafluoroisopropanol (2001) (45)
- Simultaneous Polymerization and Schulz−Flory Oligomerization of Ethylene Made Possible by Activation with MAO of a C1-Symmetric [2,6-Bis(arylimino)pyridyl]iron Dichloride Precursor (2004) (45)
- Embedded Ru@ZrO2 Catalysts for H2 Production by Ammonia Decomposition (2010) (44)
- Evidence for a molecular hydrogen complex of rhodium. Some factors affecting cis-dihydride .tautm. .eta.2-dihydrogen exchange (1987) (44)
- Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)−P3 or −P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone (1997) (44)
- Hydrodesulfurization (HDS) Model Systems. Opening, Hydrogenation, and Hydrodesulfurization of Dibenzothiophene (DBT) at Iridium. First Case of Catalytic HDS of DBT in Homogeneous Phase (1995) (43)
- Novel diphosphine-modified palladium catalysts for oxidative carbonylation of styrene to methyl cinnamate (2001) (43)
- Bis-alkoxycarbonylation of styrene by pyridinimine palladium catalysts (2002) (43)
- Transition metal complexes with the C1-symmetric diphosphines (R)-(R)-3-benzyl-2,4-bis(diphenylphosphino)pentane and (R)-(R)-3-benzyl(p-sulphonate)-2,4-bis(diphenylphosphino)pentane sodium salt. Applications to enantioselective catalysis in different phase systems (2001) (43)
- Reactivity of copper(I) tetrahydroborates toward CO2 and COS. Structure of (triphos)Cu(μ1−O2CH) (1985) (43)
- Reactivity of copper(I) tetrahydroborates toward carbon dioxide and carbonyl sulfide. Structure of (triphos)Cu(.eta.1-O2CH) (1985) (42)
- Isomerization of allylic alcohols to carbonyl compounds by aqueous-biphase rhodium catalysis (2001) (42)
- A Synthetic Nickel Electrocatalyst with a Turnover Frequency above 100 000 s−1 for H2 Production (2012) (42)
- Zwitterionic Metal Complexes of the New Triphosphine NaO3S(C6H4)CH2C(CH2PPh2)3 in Liquid Biphasic Catalysis: An Alternative to Teflon "Ponytails" for Facile Catalyst Separation without Water (1995) (41)
- Modelling the Hydrodenitrogenation of Aromatic N‐Heterocycles in the Homogeneous Phase (2001) (41)
- Ab Initio and Experimental Studies on the Structure and Relative Stability of the cis-Hydride-eta(2)-Dihydrogen Complexes [{P(CH(2)CH(2)PPh(2))(3)}M(H)(eta(2)-H(2))](+) (M = Fe, Ru). (1997) (41)
- Molecular solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. Catalytic hydrogenation of ethylene at iridium (1993) (41)
- Immobilization of Optically Active Rhodium‐Diphosphine Complexes on Porous Silica via Hydrogen Bonding (2001) (40)
- Synthesis, characterization, and electrochemical properties of a family of dinuclear rhodium complexes containing two terminal hydride ligands and two hydride (or chloride) bridges. Stoichiometric and catalytic hydrogenation reactions of alkynes and alkenes (1988) (40)
- Electrochemistry as a diagnostic tool to discriminate between classical M-(H)2 and nonclassical M-(H2) structures within a family of dihydride and dihydrogen metal complexes (1990) (40)
- Chemoselective oxidation of 3,5-Di-tert-butylcatechol by molecular oxygen. Catalysis by an iridium(III) catecholate through its dioxygen adduct (1992) (40)
- Synthesis, characterization, and reactivity of 1,1 '-bis(diphenylphosphino)osmocene: Palladium(II) complexes and their use as catalysts in the methoxycarbonylation of olefins (2003) (39)
- New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene (2000) (39)
- Low-temperature IR and NMR studies of the interaction of group 8 metal dihydrides with alcohols. (2003) (38)
- The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis (1994) (38)
- Solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. Carbon-hydrogen activation reactions at cobalt(I) encapsulated into the tetraphosphine P(CH2CH2PPh2)3 (1991) (37)
- Synthesis, Characterization, and Reactivity of Neutral and Cationic Pd–C,N,N Pincer Complexes (2005) (37)
- Activation of Dioxygen by Cobalt Group Metal Complexes (1997) (37)
- Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies (1997) (36)
- Classical, nonclassical, and mixed-metal osmium(II) polyhydrides stabilized by the tetraphosphine P(CH2CH2PPh2)3. Hydrogen/deuterium isotope exchange reactions promoted by a strongly bound dihydrogen ligand (1993) (36)
- Synthesis of a New Polydentate Ligand Obtained by Coupling 2,6-Bis(imino)pyridine and (Imino)pyridine Moieties and Its Use in Ethylene Oligomerization in Conjunction with Iron(II) and Cobalt(II) Bis-halides (2007) (36)
- Dioxygen and carbon monoxide uptake by iridium(I) complexes stabilized by mixed N,P-donor ligands (1994) (36)
- Mimicking the HDS Activity of Ruthenium-Based Catalysts 2: The Hydrogenation of Benzo[b]thiophene to 2,3-Dihydrobenzo[b]thiophene (1999) (36)
- Nickel Complexes with Phosphinito-Oxazoline Ligands: Temperature-Controlled Formation of Mono- or Dinuclear Complexes and Catalytic Oligomerization of Ethylene and Propylene (2009) (35)
- Homogeneous Reactions of Thiophenes with Transition Metals: A Modeling Approach for Elucidation of the Hydrodesulfurization Mechanism and an Effective Method for the Synthesis of Unusual Organosulfur Compounds (1995) (35)
- Activation of 1-alkynes at tripodal (polyphosphine)rhodium systems. Regioselective synthesis of enol esters from 1-alkynes and carboxylic acids catalyzed by rhodium(I) monohydrides (1990) (35)
- Methoxycarbonylation of styrene to methyl arylpropanoates catalyzed by palladium(II) precursors with 1,1'-bis(diphenylphosphino)metallocenes (2004) (35)
- Ethylene carbonylation in methanol and in aqueous media by palladium(II) catalysts modified with 1,1'-bis(dialkylphosphino)ferrocenes (2005) (35)
- Synthesis of the New Chiral Aminodiphosphine Ligands (R)- and (S)-(.alpha.-Methylbenzyl)bis(2-(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of .alpha.,.beta.-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis (1995) (35)
- An exceptionally stable cis-(hydride)(η2-dihydrogen) complex of iron (1988) (34)
- Amorphous Polyethylene by Tandem Action of Cobalt and Titanium Single‐Site Catalysts (2005) (34)
- Comprehensive experimental and interpretational study of the complex formation and transformations involving o-quinoid molecules and an L3M-type metal fragment (M = cobalt) (1987) (34)
- Reactions of the Rhenium(I) Fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and Characterization of a Stable Cationic .eta.2-H2 Complex of Rhenium (1995) (34)
- Hydrogenation of Quinoline by Rhodium Catalysts Modified with the Tripodal Polyphosphine Ligand MeC(CH2PPh2)3 (2001) (33)
- Hydrogenation of arenes over catalysts that combine a metal phase and a grafted metal complex: role of the single-site catalyst. (2003) (33)
- Aminocarbene Complexes as Intermediates in the Ruthenium-Assisted Aminolysis of Phenylacetylene to Isonitriles and Toluene (1999) (33)
- Electrochemical synthesis of the σ-aryl complex [NiBr(Mes)(bpy)] and its use as catalyst precursor for the oligomerization of ethylene (Mes = 2,4,6-trimethylphenyl, bpy = 2,2'-bipyridine) (2006) (33)
- A family of stable iron(I) .sigma.-alkynyl complexes. Synthesis, characterization, structure, and electron-transfer chemistry (1993) (33)
- Dioxygen uptake and transfer by Co(III), Rh(III) and Ir(III) catecholate complexes (1992) (32)
- First Examples of Rhenium-Assisted Activation of Propargyl Alcohols: Allenylidene, Carbene, and Vinylidene Rhenium(I) Complexes (1999) (32)
- Mimicking the HDS Activity of Ruthenium-Based Catalysts. Homogeneous Hydrogenolysis of Benzo[b]thiophene (1998) (32)
- Yttrium‐Amidopyridinate Complexes: Synthesis and Characterization of Yttrium‐Alkyl and Yttrium‐Hydrido Derivatives (2010) (32)
- Studies of ligand and solvent effects in the alternating copolymerization of carbon monoxide and ethene by palladium-diphosphine catalysis (2002) (31)
- Multiple Re−C Bonds at the [{MeC(CH2PPh2)3}Re(CO)2]+ Auxiliary (1996) (31)
- Reactions of the trigonal-bipyramidal cobalt(I) hydride [{P(CH2CH2PPH2)3}CoH] with 1-alkynes. Synthesis and reactivity of acethylide, alkenyl, and vinylidene complexes (1990) (31)
- Hydrogenation of indole by phosphine-modified rhodium and ruthenium catalysts (2002) (31)
- Tandem Action of Early−Late Transition Metal Catalysts for the Surface Coating of Multiwalled Carbon Nanotubes with Linear Low-Density Polyethylene (2008) (31)
- Selective Cα–Cβ bond cleavage by water in allenylidene and alkenylvinylidene ruthenium complexes (1999) (30)
- Schulz–Flory oligomerisation of ethylene by the binuclear nickel(II) complex Ni2Cl4[cis,trans,cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane] (2003) (30)
- Homogeneous Hydrogenation of Benzo[b]thiophene by Use of Rhodium and Iridium Complexes as the Catalyst Precursors: Kinetic and Mechanistic Aspects† (1997) (30)
- Dioxomolybdenum(VI) Complexes Stabilized by Polydentate Ligands with NO3, N2O2, and NS2 Donor-Atom Sets (1994) (30)
- Copolymerization of Carbon Monoxide with Ethene Catalyzed by Palladium(II) Complexes of 1,3-Bis(diphenylphosphino)propane Ligands Bearing Different Substituents on the Carbon Backbone (1999) (29)
- The Catalytic Transformation of Benzo[b]thiophene to 2-Ethylthiophenol by a Soluble Rhodium Complex: The Reaction Mechanism Involves Ring Opening Prior to Hydrogenation (1995) (29)
- Copolymerization of carbon monoxide with ethene catalyzed by bis-chelated palladium(II) complexes containing diphosphine and dinitrogen ligands (1999) (29)
- Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH2PPh2)3}Ir(H2)(H)2]BPh4 (1997) (29)
- In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [{MeC(CH2PPh2)3}Re (CO)2H]. ReH…H bonding and proton-transfer pathways (1998) (28)
- Sodium borohydride as an additive to enhance the performance of direct ethanol fuel cells (2010) (28)
- Regio- and stereoselective dimerization of 1-alkynes catalyzed by an Os(II) complex (1994) (28)
- Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts (2004) (28)
- Reversible uptake of hydrogen and nitrogen at cobalt in the solid state. Influence of the counter anion on the formation of classical dihydride vs. nonclassical .eta.2-dihydrogen forms of [(PP3)CoH2]+ (1992) (28)
- Genesis of tetrathiooxalate-like C2S4 and C2Se4 units. A multiform experimental study and the relevant theoretical implications for the role of transition-metal fragments (1987) (27)
- Addition of E-H bonds (E = S, N) across the Cα=Cβ bond of the allenylidene ligand in [Re{C=C=CPh2}(CO)2(triphos)](OSO2CF3) (triphos = MeC(CH2PPh2)3) (2002) (27)
- Palladium acetate complexes bearing chelating N-heterocyclic carbene (NHC) ligands: Synthesis and catalytic oxidative homocoupling of terminal alkynes (2009) (27)
- Specific and non-specific influence of the environment on dihydrogen bonding and proton transfer to [RuH2{P(CH2CH2PPh2)3}] (2007) (27)
- Interaction of monohydrido complexes of rhodium(I) with 1-alkynes. Experimental study on deceptively simple reactions (1990) (27)
- Catalytic polymerisation of ethylene with tris(pyrazolyl)borate complexes of late transition metals (2005) (26)
- Coupling of two ethyne molecules at rhodium versus coupling of two rhodium atoms at ethyne. 2. Implications for the reactivity. Catalytic and stoichiometric functionalization reactions of ethyne (1991) (26)
- The first tridentate phosphine ligand combining planar, phosphorus and carbon chirality. (2002) (26)
- Synthesis, redox properties, and reactivity of a novel family of electron-rich vinylidene and vinylphosphonium complexes of rhodium(I) (1990) (26)
- CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups (2007) (26)
- Synthesis of the first polymer-supported tripodal triphosphine ligand and its application in the heterogeneous hydrogenolysis of benzo[b]thiophene by rhodium catalysis (2001) (25)
- Reactivity of copper(I) tetrahydroborates toward CS2 and SCNPh. structures of (PPh3)2Cu(μ-S2CSCH2SCS2)Cu(PPh3)2, (PPh3)2Cu(S2COEt), and (PPh3)2Cu(S2CNHPh).CHCl3 (1985) (25)
- Oxidative addition/reductive elimination of aldehydes and ketones at rhodium (1989) (25)
- Synthesis and crystal structure of two isomorphous rhodium and iridium complexes with cyclo-triphosphorus and 1,1,1,-tris(diphenylphosphinomethyl)-ethane (1979) (25)
- Can nitrones functionalize carbon nanotubes? (2010) (25)
- New alkyl derivatives phosphine sulfonate (P-O) ligands. Catalytic activity in Pd-catalysed Suzuki-Miyaura reactions in water. (2007) (25)
- Facile activation of hydrogen on 1,1- and 1,2-dithio complexes of rhodium(III). An experimental study (1987) (25)
- SYNTHESIS AND CHARACTERIZATION OF AN IRON(II) CIS-HYDRIDE(ETA 2-DIHYDROGEN) COMPLEX STABILIZED BY THE TETRAPHOSPHINE P(CH2CH2PPH2)3 (1991) (25)
- Homo- and heterometal triple-decker complexes of cyclo-triphosphorus with mixed triphosphine ligands. Crystal structure of [[MeC(CH2PPh2)3]Co[.mu.-(.eta.3-P3)]Fe[MeC(CH2PEt2)3]](PF6)2.cntdot.CH2Cl2 (1981) (24)
- Thermal and photochemical carbon-hydrogen bond activation reactions at iridium. .pi.-Coordination vs. C-H cleavage of ethene, styrene, and phenylacetylene (1993) (24)
- Operando High-Pressure NMR and IR Study of the Hydroformylation of 1-Hexene by 1,1'-Bis(Diarylphosphino)metallocene-Modified Rhodium(I) Catalysts (2005) (24)
- Mono- and dinuclear carbon disulfide metal complexes with 1,1,1-tris((diphenylphosphino)methyl)ethane (1980) (24)
- Oxidation of primary alcohols to carboxylic acids made easy at iridium (1990) (23)
- Preparation of models and oligomers of metal alkynyls: NMR, GPC and X-ray structural characterization of building blocks for the construction of molecular devices (2003) (23)
- Assembling ethylene, alkyl, hydride, and carbon monoxide ligands at iridium (1991) (23)
- Synthesis of Polymer-Supported Rhodium(I)−1,3-Bis(diphenylphosphino)propane Moieties and Their Use in the Heterogeneous Hydrogenation of Quinoline and Benzylideneacetone (2001) (23)
- Hydrodesulfurization model systems. Homogeneous and heterogeneous (solid-gas) hydrogenation of benzothiophene at iridium (1993) (23)
- Reactions of ethyl cyanoformate with (np3)Ni, (np3)CoH [np3 = N(CH2CH2PPh2)3], and (triphos)Ni [triphos = MeC(CH2PPh2)3]. Crystal structures of the ethoxycarbonyl complexes [(np3)Ni(CO2Et)]BPh4 and (triphos)Ni(CN)(CO2Et) (1986) (22)
- Chemistry of Et3P.CS2 metal complexes: synthesis of 1,1-dithiolate complexes via nucleophilic attacks on [(triphos)Co(S2CPEt3)](BPh4)2. X-ray structure of [(triphos)Co(S2CO)] (1982) (22)
- Palladium(II) Complexes with Phosphanylferrocenecarboxylate Ligands and Their Use as Catalyst Precursors for Semialternating CO–Ethylene Copolymerization (2008) (22)
- Synthesis and characterization of chiral bis-ferrocenyl triphosphine Ni(II) and Rh(III) complexes and their use as catalyst precursors for acetalization reactions (1999) (22)
- "Triple-decker" sandwich complexes of cyclo-triphosphorus with 4d and 5d metals (1981) (22)
- Metal-promoted transformation of CO2, into CO. X-ray crystal structure of the nickel−carbonate complex [O = PPh2CH2C(CH3)(CH2PPh2)2]Ni(O2CO)•0.5H2O•C6H6 (1984) (22)
- The barrier to rotation of the dihydrogen ligand in the complexes [MH(.eta.2-H2)PP3]BPh4 (M = iron, ruthenium): evidence for stronger back-donation in the iron complex (1992) (22)
- In Situ and Reactor Study of the Enantioselective Hydrogenation of Acetylacetone by Ruthenium Catalysis with the New Chiral Diphosphine Ligand (R)-(R)-3-Benzyl-2,4-bis(diphenylphosphino)pentane (2000) (22)
- Taking Too Many Precautions in Making a Catalyst Is Never a Loss of Time: A Lesson We Learned at Our Own Expense (2003) (21)
- HDS model systems. 2,3-Dihydrothiophene as an intermediate in the homogeneous hydrogenation of thiophene to tetrahydrothiophene at iridium (1994) (21)
- C−H Bond Cleavage in Thiophenes by [P(CH2CH2PPh2)3Ru]. UV Flash Kinetic Spectroscopy Discloses the Ruthenium−Thiophene Adduct Which Precedes C−H Insertion (1997) (21)
- Structural comparison of cobalt and nickel complexes with CS2 and SCNPh molecules stabilized by tripodal polyphosphine ligands. Implications for the nature of the chemical bonding in compounds containing C−S linkages #7B-N2 coordinated to L3M fragments (1984) (21)
- Nucleophilic attack on .eta.2-coordinated dithio acids by hydride ion. A preliminary step in the formation of a variety of nickel complexes (1983) (20)
- Diastereoselective Alkylation−Vinylation of Norbornene Catalyzed by a Tetrahedral Cobalt(II) Pyridinimine Complex (2007) (20)
- Reactivity of the triethylphosphinecarbon disulfide adduct Et3PCS2 toward iron(II) cations in the presence of the bis(tertiary phosphines), depe, and diphos, x-ray crystal structures of the complexes [(depe)2Fe(S2CPEt3)](BPh4)2 and [(depe)2Fe(S2CH)](BPh4) (1982) (20)
- Imine Hydrogenation by Tribenzylphosphine Rhodium and Iridium Complexes (2006) (20)
- C−S Bond Cleavage of Benzo[b]thiophene at Ruthenium (1998) (20)
- Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resins. (2004) (20)
- 2‐Oxacyclopentylidene, 2‐Oxacyclohexylidene, and 2‐Oxacycloheptylidene Rhenium Complexes by Reaction of ω‐Alkynols with the [{MeC(CH2PPh2)3}Re(CO)2]+ Auxiliary (1998) (20)
- Simultaneous coordination of hydrides and .eta.1-S thiophenes made possible at iridium (1993) (20)
- Synthesis, characterization, and molecular structure of the first metal complex containing thallium chloride as a ligand. A novel carrier of thallium(I) (1992) (20)
- Anodically-induced metal deprotonation of the hydrido complexes [{PCH2CH2PPh2)3}M (H) Cl ] (M = Fe, Ru, Os) : the first step to the electrogeneration of Fe(I),u(I) and Os(I) five-coordinate complexes (1997) (20)
- Synthesis and characterization of the tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-diacetic acid (H2Me2DO2A) and of its neutral copper(II) complex [Cu(Me2DO2A)]. A new 64Cu-labeled macrocyclic complex for positron emission tomography imaging (2000) (20)
- Bifunctional activation of carbon dioxide: a case where the basic and acidic sites are not held in the same structure (1984) (19)
- Benzene Hydrogenation by Silica-Supported Catalysts Made of Palladium Nanoparticles and Electrostatically Immobilized Rhodium Single Sites (2008) (19)
- Mononuclear ruthenium complexes containing two different phosphines in trans position: II. Catalytic hydrogenation of CC and CO bonds (2007) (19)
- Opening and Hydrogenation of Dinaphtho[2,1-b:1‘,2‘-d]thiophene (DNT) by Soluble Rhodium and Iridium Complexes. Homogeneous Hydrogenolysis of DNT to 1,1‘-Binaphthalene-2-thiol by Rhodium Catalysis (1996) (19)
- Crystal structure of the cis hydride acetyl complex [{N(CH2CH2PPh2)3}Rh(H)(COMe)]BPh4. One-pot synthesis of (.sigma.-acyl)metal complexes from aldehydes (1991) (19)
- Metal-promoted transformation of carbon dioxide into carbon monoxide. X-ray crystal structure of the nickel-carbonate complex [O:PPh2CH2C(CH3)(CH2PPh2)2]Ni(O2CO).0.5H2O.C6H6 (1984) (19)
- Reactivity of copper(I) tetrahydroborates toward carbon disulfide and phenyl isothiocyanate. Structures of (PPh3)2Cu(.mu.-S2CSCH2SCS2)Cu(PPh3)2, (PPh3)2Cu(S2COEt), and (PPh3)2Cu(S2CNHPh).CHCl3 (1985) (18)
- C-S Bond Scission of Substituted Thiophenes at Rhodium. Factors Influencing the Regioselectivity of the Insertion and the Stability of the Resulting Metalathiacycles (1995) (18)
- Chemoselective aerobic oxidation of unprotected diols catalyzed by Pd-(NHC) (NHC=N-heterocyclic carbene) complexes (2010) (18)
- Synthesis, characterization and aqueous-biphase catalysis of the ruthenium dimer Na[(O3S(C6H4)CH2C(CH2PPh2)3Ru)2(μ-Cl)3] (1999) (18)
- Reactivity of [N(CH2CH2PPh2)3]CoH toward carbon disulfide, SCNPh, OCNPh, and carbon oxide sulfide (COS) (1983) (18)
- Like on Heterogeneous Hydrodesulfurization (HDS) Catalysts, the Homogeneous HDS of Benzo[b]thiophene Is Achived by the Concomitant Action of a Metal Promoter (Rh) and an Active HDS Component (W) (1996) (18)
- Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos)RhCl(X2CPEt3) (triphos = MeC(CH2PPh2)3; X = S, Se). Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos)Rh(S2CH(PEt3))](BPh4)2 (1987) (18)
- Chemoselective methoxycarbonylation of terminal alkynes catalyzed by Pd(II)-TROPP complexes. (2010) (18)
- Factors affecting the metal-promoted head-to-head dimerization of carbon disulfide, CS2 to C2S4. Synthesis, chemistry, structure, and MO analysis of [(triphos)Rh(.mu.-C2S4)Rh(triphos)](BPh4)2.CH2Cl2 (1984) (18)
- Synthesis, Characterization, and Interconversion of the Rhenium Polyhydrides [ReH3(η4‐NP3)] and [ReH4(η4‐NP3)]+ {NP3 = tris[2‐(diphenylphosphanyl)ethyl]amine} (2002) (18)
- Facile reduction of carbon dioxide, carbonyl sulfide, and carbon disulfide by copper(I) borohydride. X-ray crystal structure of the complex [(triphos)Cu(O2CH)] (1983) (17)
- Low density polyethylene by tandem catalysis with single site Ti(IV)/Co(II) catalysts (2006) (17)
- Intramolecular sigma-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: exploring unexpected reactivity paths. (2010) (17)
- Hydrogen-transfer reactions of the trihydride [(MeC(CH2PPh2)3RhH3]: a simple route to rhodium cis hydride .eta.2-alkene complexes (1990) (17)
- Nucleophilic addition of phosphines to rhenium allenylidenes. Unprecedented double P?H bond activation to give an ?1-P-phospha-1-butadienyl ligandBased on the presentation given at Dalton Discussion No. 6, 9?11th September 2003, University of York, UK. (2003) (17)
- Activation of 1-alkynes at 16-electron rhodium fragments. Some examples of thermodynamically favored rearrangements [M(.pi.-HC.tplbond.CR)] .fwdarw. [M(H)(C.tplbond.CR)] (1989) (17)
- Chemoselective Aerobic Diol Oxidation by Palladium(II)–Pyridine Catalysis (2011) (17)
- Control of the Bridgehead Donor Atom in the Tripodal Ligand over Oxidative Addition of Au(PPh3)+ to [X(CH2CH2PPh2)3RhH] (X = N, P). X-ray Diffraction and Multinuclear (103Rh, 31P, 1H) NMR Studies (1995) (17)
- Efficient rhodium catalysts for the hydrogenolysis of thiophenic molecules in homogeneous phase (1997) (17)
- Stepwise metal-assisted conversion of carbon diselenide to diselenium and carbon dioxide. Novel bonding mode of the diselenium molecule in the double-Se2-bridged complex [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.2DMF (1985) (16)
- Metal-assisted reaction of carbon disulfide with the tris(tertiary phosphine) 1,1,1-tris(diethylphosphinomethyl)ethane. Synthesis and structure of the complex [MeC(CH2PEt2)3Fe{S2C(PEt2CH2)2CMe2}](BF4)2 (1981) (16)
- Dioxomolybdenum(VI) Complexes with New Enantiomerically Pure Amino Diol Ligands. (1996) (16)
- Thiophene, Benzo[b]thiophene and Dibenzo[b,d]thiophene as Precursors to Highly Conjugated Organosulfur Compounds (1997) (16)
- Reactivity of the triethylphosphine-carbon disulfide adduct toward metal carbonyls. X-ray structures of the complexes [Cr(CO)5(S2CPEt3)] and [Mo(CO)2(PEt3)(.mu.-S2CPEt3)]2 (1982) (16)
- How can the metal affect the proton transfer to the dihydrides [{P(CH2CH2PPh2)3}MH2] (M = Fe, Ru, Os)? A low-temperature electronic spectroscopy study (2003) (16)
- Backward synthesis of rhenium(I) γ-hydroxyvinylidene and γ-methoxyvinylidene complexes and their conversion to the allenylidene [Re{CCCPh2}(CO)2(MeC(CH2PPh2)3)](OSO2CF3) (2001) (16)
- 1H- and 2H-T1 relaxation behavior of the rhodium dihydrogen complex [(triphos)Rh(eta 2-H2)H2]+. (2000) (16)
- Homo- and heterobimetallic trihydride complexes stabilized by the tripodal phosphine ligand MeC(CH2PPh2)3: experimental and theoretical studies (1989) (16)
- Tandem Copolymerization: An Effective Control of the Level of Branching and Molecular Weight Distribution (2006) (16)
- Chemoselective reduction of α,β-unsaturated ketones catalyzed by transition metal complexes with polydentate ligands (1995) (16)
- Reactive Blending of Polyamides with Different Carbonyl Containing Olefin Polymers (2003) (16)
- Reactivity of the triethylphosphine-carbon disulfide adduct (Et3P.CS2) toward cobalt(II) cations in the presence of the tris (tertiary phosphines) triphos and etriphos. X-ray crystal structure of the complex [(etriphos)Co(S2C(H)PEt3)](BPh4)2 (1982) (16)
- High-pressure investigations under CO/H2 of rhodium complexes containing hemispherical diphosphites. (2010) (16)
- Ruthenium(II)-Mediated Reaction of Phenylacetylene with Primary Amines To Give Ruthenium(II)-Isonitrile Complexes (1995) (15)
- Redox-Induced Conversion Pathways in Rhodium and Iridium Complexes Containing C-S Bond Cleaved Benzo[b]thiophene (1995) (15)
- Synthesis, characterization and reactivity of tribenzylphosphine rhodium and iridium complexes (2006) (15)
- Intra- and intermolecular activation of sp2 carbon-hydrogen bonds at rhodium(I) and iridium(I) metal centers. X-ray structure of the cis .sigma.-cyclooctadienyl hydride [{N(CH2CH2PPh2)3}IrH(.sigma.-C8H11)]BPh4.cntdot.CH3COCH3 (1986) (15)
- Unraveling the o-methoxy effect in the CO/ethene copolymerization reaction by diphosphanepalladium(II) catalysis (2007) (15)
- Ruthenium(II) Complexes with Triphosphane Ligands Combining Planar, Phosphorus, and Carbon Chirality: Application to Asymmetric Reduction of Trifluoroacetophenone (2003) (15)
- Effects of the conformational rearrangement of the (np3)M fragment in the course of the reaction between (np3)MH hydrides [M = Co, Rh; np3 = N(CH2CH2PPh2)3] and carbon disulfide (1985) (15)
- Activation of 2-propyn-1-ols by the rhenium(I) fragment [{MeC(CH2PPh2)3}Re(CO)2]+. Synthesis and characterization of cationic Re(I) complexes containing unsaturated η1-carbon ligands (2001) (15)
- Asymmetric hydrogen-transfer reduction of prochiral and α,β-unsaturated ketones by iridium complexes containing optically pure aminodiphosphine ligands (1998) (15)
- Synthesis of neutral rhodium(I) complexes containing a rigid P–O ligand and their use as catalyst precursors for the hydroformylation of 1-hexene (2008) (14)
- Reactivity of (triphos)Ni(η2-CS2) towards group VIB elements, HBF4, and MeOSO2F. Crystal structure of the dithiocarbonate complex [OPPh2CH2C(CH3)(CH2PPh2)2]Ni(S2CO)· 0.5THF (1985) (14)
- .sigma.-Acetylide complexes of rhodium(I), rhodium(II), and rhodium(III). Correlation between electrochemical (E0') and spectroscopic (.DELTA..nu.(C.tplbond.C)) parameters and d.pi.(metal) .fwdarw. .pi.*(acetylide) transfer (1990) (14)
- Steric control on the redox chemistry of (η5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. (2011) (14)
- Metal Activation of Dibenzo[b,d]thiophene. Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(.eta.2(C,S)-C12H8S) (1995) (14)
- Synthesis and characterization of rhenium polyhydrides stabilized by the tripodal ligand MeC(CH2PPh2)3 (1993) (14)
- Rhenium(III) and rhenium(V) complexes stabilized by the potentially tetradentate ligand tris(2-diphenylphosphinoethyl)amine (2002) (14)
- Cobalt monolayer islands on Ag(111) for ORR catalysis. (2011) (14)
- Rhodium complexes with the tripodal triphosphine MeC(CH2PPh2)3 as highly reactive systems for hydrogenation and hydroformylation of alkenes (1988) (14)
- Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules (1989) (14)
- X-ray structural analyses of copper(I) and silver(I) adducts of the Rh(III) trihydride [(triphos)RhH3], with triphos=CH3C(CH2PPh2)3 (1993) (14)
- The Energy Profile of Proton Transfer from Brønsted Acids to Terminal Hydrides in Transition Metal Complexes Can Be Estimated by Combining in situ IR and NMR Spectroscopy (2000) (13)
- MIMICKING THE HDS ACTIVITY OF PROMOTED TUNGSTEN CATALYSTS. A HOMOGENEOUS MODELING STUDY USING A TWO-COMPONENT TUNGSTEN/RHODIUM SYSTEM (1997) (13)
- A double CS2-bridged nickel complex. New synthesis and crystal structure of [(PPh3)Ni(µ-CS2)2Ni(PPh3)] (1983) (13)
- Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation. (2006) (13)
- Oxidative addition/reductive elimination of aldehydes and ketones at rhodium. Synthesis and characterization of cis hydrido acyl complexes of rhodium(III) (1987) (13)
- Synthesis, characterization and coordination chemistry of the new tetraazamacrocycle 4,10-dimethyl-1,4,7,10-tetraazacyclododecane-1,7-bis(methanephosphonic acid monoethyl ester) dipotassium salt. (2003) (13)
- Synthesis and characterization of new rhodium and iridium complexes with trianisylphosphine, PAn3, and evaluation of their catalytic behavior in the homogeneous hydrogenation of cinnamaldehyde (2009) (13)
- Selective hydrogenation of 1.10-phenanthrolines by silica-supported palladium nanoparticles (2008) (13)
- Reactions of HC.tplbond.CCO2Et with (np3)CoH and (np3)Ni [np3 = N(CH2CH2PPh2)3]. Crystal structures of the alkenyl complexes [(np3)CoC(CO2Et):CH2]BPh4.cntdot.0.5THF and [(np3)NiCH:CHC(O)OEt]BPh4 (1986) (13)
- A new P-chiral aminophosphine ligand containing a 2,2′-coupled pyrrolidine–phospholane ring system. Synthesis and coordination properties with rhodium(I) and iridium(I) fragments (1995) (13)
- MECHANISTIC STUDY OF IR(H)2-ASSISTED TRANSFORMATIONS OF ETHYNE : CYCLOTRIMERIZATION, COOLIGOMERIZATION WITH ETHENE, AND REDUCTIVE COUPLING (1995) (13)
- CH bond activation of thiophenes at iridium: a lower energy process than CS bond scission (1995) (13)
- Cobalt(II) and nickel(II) trithiocarbonate complexes as nucleophilic reagents. Reactivity and X-ray structure of the trithiocarbonate complex [Co(tppme)(S2CSCH3)][BPh4]·1.5thf (1982) (13)
- Triple‐Decker Sandwich Complexes of 4d and 5d Metals with cyclo‐Triphosphorus as μ,η3‐Ligand: Structural and Magnetic Properties (1980) (13)
- Synthesis and Characterization of Trimetallic Complexes Containing M−Pd−M Arrays (M = Mo, W) and Their Relevance in Palladium-Catalyzed Metal−Carbon Bond Formation (2002) (12)
- LLDPE with Exclusively Ethyl Branches by Tandem Catalysis with Single-Site Zr(IV)/Co(II) Catalysts (2008) (12)
- Alternative routes to the synthesis of the cobalt thiocarbonyl complex [(np3)Co(CS)]BPh4. Influence of the CoH dissociation pathway on the reaction of the hydride (np3)CoH with heterocumulenes (np3 = tris(2-diphenylphosphinoethyl)amine) (1984) (12)
- Synthesis of a novel palladium(0) carbonyl complex containing a tridentate phosphorus ligand. X-ray crystal structure of [Pd(CO)(CH3C(CH2PPh2)3)] (1993) (12)
- Redox-induced reversible migration of hydrogen from metal to alkene (1988) (12)
- Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric iridium-assisted C-C bond-forming reactions involving ethyne and ethene (1994) (12)
- Molecular solid-gas organometallic chemistry. Catalytic and stoichiometric transformations of ethyne at iridium (1993) (12)
- Synthesis and x-ray structure of the dinuclear cobalt(0) complex (PhCCPh)Co2(CO)4(triphos) (1979) (12)
- Migration of hydrogen from metal to alkene promoted by dioxygen addition. Oxygen atom transfer from a cis-(alkyl)(η2-dioxygen) complex of rhodium to organic and inorganic substrates (1989) (12)
- Unprecedented transformation of a vinylidene ligand. Synthesis and ESR characterization of a paramagnetic .sigma.-acetylide complex of rhodium(II) (1988) (11)
- Regioselective propylene dimerization by tetrahedral (imino)pyridine CoII dichloride complexes activated by MAO (2007) (11)
- Soft matter nanocomposites by grafting a versatile organogelator to carbon nanostructures (2011) (11)
- New enantiomerically pure aminoalcohols from (R)-α-methylbenzylamine and cyclohexene oxide (1996) (11)
- Stepwise metal-assisted conversion of .eta.2-carbon diselenide to .eta.1-phosphoniodiselenoformate, .eta.2-diselenocarbonate, and .eta.2-diselenium. Crystal structure of the rhodium complexes [(triphos)Rh(Se2CO)]BPh4.cntdot.0.5CH2Cl2.cntdot.0.5C4H9OH and [(triphos)Rh(.mu.-Se2)2Rh(triphos)](BPh4)2.cn (1988) (11)
- Efficient Catalysis of Ammonia Borane Dehydrogenation (2009) (11)
- A novel linkage-isomeric pair of dinuclear Pd(II) complexes bearing a bis-bidentate tetraphos ligand. (2009) (11)
- Reactivity of [N(CH2CH2PPh2)3]Ni toward CS2, SCNPh, and COS. Structure of the η2S,C-bonded phosphoniodithiomethyl ester complex [Ph2S2Me)]BPh4 (1984) (11)
- A New Bridging Mode of Carbon Disulfide in a Dinuclear Cobalt(I) Complex (1979) (11)
- Stoichiometric and catalytic functionalization reactions of alkynes at transition metal complexes stabilized by tripodal polyphosphine ligands (1991) (11)
- COUPLING OF TWO ETHYNE MOLECULES AT RHODIUM VERSUS COUPLING OF TWO RHODIUMATOMS AT ETHYNE. I, ELECTRONIC CONTROL ON THE INTERCONVERSION OF (MU -ETA 2 ,ETA 2-ETHYNE)- AND (MU -ETA 1,ETA 1-ETHYNE)DIRHODIUM COMPLEXES (1991) (11)
- Synthesis of the New Chiral (R)- and (S)-Aminodiphosphine Ligands sec-Butylbis(2-(diphenylphosphino)ethyl)amine, sec-Butylbis(2-(dicyclohexylphosphino)ethyl)amine, and (α-Methylbenzyl)bis(2-(dicyclohexylphosphino)ethyl)amine and Their Organometallic Chemistry When Combined with Iridium (1997) (11)
- Reactivity of the tetrahydroborate copper(I) complexes [(PR3)2Cu(η2-BH4)] (R = Ph, Cy) toward CO2, COS, and SCNPh (1983) (11)
- 2H-T1 Relaxation and Deuterium Quadrupole Coupling Constants in Transition Metalη2-D2 Complexes (1999) (10)
- Metal‐Assisted Reaction of Carbon Disulfide with the “Etriphos” Phosphane Ligand: Synthesis and Structure of [(Etriphos)Fe{S2C(Et2PCH2)2CMe2}](BF4)2 (1980) (10)
- Stepwise metal-assisted reduction of .eta.4-coordinated benzene to cyclohexene (1992) (10)
- Synthesis and x-ray structure of the binuclear complex [(MeC(CH2PEt2)3)Fe(.mu.-Cl)3Fe(MeC(CH2PEt2)3)]BPh4.cntdot.CH2Cl2. Interpretation of the geometrical and electronic features through a recent MO approach for M2L9 complexes (1982) (10)
- Mixed iridium-gold hydrides as model compounds for elucidating the interconversion between classical and nonclassical polyhydrides (1992) (10)
- Reactions of coordinated ligands exemplified by the formation and transformation of the dithiocarbonate ligand in the rhodium (III) complex [(triphos) Rh(S2CO)] BPh4 (1988) (10)
- A FIVE-COORDINATE RUTHENIUM(I) COMPLEX (1994) (10)
- Potential application of (1,3-dithiol-2-ylidene)metal complexes to the synthesis of tetrathiafulvalene derivatives (1985) (10)
- Nucleophilic properties and electrochemistry of five-coordinate rhodium(I) .sigma.-cyanide complexes. Synthesis and characterization of stable cis hydride cyanide complexes of rhodium(III) (1989) (10)
- Stepwise metal-promoted conversion of η2-CS2 into η2-SO. Synthesis and crystal structure of the complex [(triphos)Rh(µ-SO)2Rh(triphos)][BPh4]2·HCONMe2[triphos = MeC(CH2PPh2)3] (1985) (10)
- Nucleophilic attack on metal dithioformates by tertiary phosphines: preparation and structure of [(dppe)Fe{S2C(H)dppe}]BPh4 · CH2Cl2 (1982) (9)
- 4 Palladium-Based Electrocatalysts for Alcohol Oxidation in Direct Alcohol Fuel Cells (2011) (9)
- 1,3-Cycloaddition of pyrazole to the allenylidene ligand in [Re{CCCPh2}(CO)2{MeC(CH2PPh2)3}]+ (2003) (9)
- Reactivity of carbon disulfide and triethylphosphine.carbon disulfide toward copper(I)-phosphine complexes. X-ray crystal structure of the complex [(PPh3)2Cu(S2CPEt3)]BPh4 (1983) (9)
- Insertion of iridium into C-H and C-S bonds of 2,5-dimethylthiophene 2-methylbenzothiophene and 4,6-dimethyldibenzothiophene (1997) (9)
- Alkyl, aryl and cis-dihydride complexes of iridium with the tripodal phosphine P(CH2CH2PPh2)3 as excellent precursors of active systems for the activation of hydrocarbon CH bonds (1987) (9)
- Synthesis and Characterisation of a Novel Copper(II) Azamacrocycle‐Phosphonate 3D Polymeric Network (2005) (9)
- Adduct of two 1,8‐naphthyridine molecules (one protonated) with tetrachloroferrate (III) (1992) (9)
- π-Polyolefin and π-acetylene cobalt(I) complexes with the tris(tertiary phosphine) 1,1,1-tris(diphenylphosphinomethyl)ethane. X-ray structure of [(triphos)Co(η4-C7H8)]ClO4 · O.5 CH2Cl2 (1980) (9)
- Metal-assisted three-fragment demolition of the dithiocarbonate ligand: a new synthetic route to homo- and heterobinuclear bis(.mu.-sulfido)metal complexes. Chemical, electrochemical, and spectroscopic characterization of a family of complexes of iron, cobalt, rhodium, and platinum with bridging sul (1988) (9)
- CHEMISTRY OF ET3P.CS2 METAL COMPLEXES: SYNTHESIS OF 1,1-DITHIOLATE COMPLEXES VIA NUCLEOPHILIC ATTACKS ON ((TRIPHOS)CO(S2CPET3))(BPH4)2. X-RAY STRUCTURE OF ((TRIPHOS)CO(S2CO)) (1983) (9)
- Activation of CH bonds in acetylene and terminal alkynes by rhodium(I) species. Crystal structure of cis-(ethynyl)hydride [(NP3)Rh(H)(CCH)]BPh4·1.5C4H8O (NP3 = N(CH2CH2PPh2)3) (1988) (8)
- Enthalpy and entropy studies with some copper(II) bis(diamine) complexes and some comments on solvation energy and gas-phase enthalpies (1975) (8)
- Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides (1995) (8)
- Reactivity of formaldehyde and acetaldehyde toward [N(CH2CH2PPh2)3]Ni and [N(CH2CH2PPh2)3]CoH (1985) (8)
- Reactivity of η2-CS3Me metal complexes as electrophiles (1983) (8)
- Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride (1991) (8)
- Ruthenium-assisted synthesis of gem-deuterated alkenes from monosubstituted propargyl alcohols and D2O (2000) (7)
- From vegetable residues to hydrogen and electric power: Feasibility of a two step process operating with purple non sulfur bacteria (2007) (7)
- Combinations of Transition Metal Catalysts for Reactor Blending (2004) (7)
- DESIGNING HOMOGENEOUS CATALYSTS. RU(II) COMPLEXES WITH POLYDENTATE MIXED-P,N-DONOR LIGANDS (1992) (7)
- 1-Hexene Hydroformylation with the Rhodium (I) Triphosphane Complex [Rh(CO){PhP(CH2CH2PPh2)2}]PF6: An In Situ Study Using High-Pressure NMR Spectroscopy (1997) (7)
- First example of opening and hydrogenation of 2,3-dihydrobenzo[b]thiophene to 2-ethylthiophenol assisted by a soluble metal complex (1999) (7)
- Reactivity of η2-trithiocarbonate metal complexes as nucleophiles. Intramolecular mobility of the trithiocarbonate group in µ-CS3 binuclear complexes (1983) (7)
- Characterization and reactivity of the tetrametallic Pd2-Mo2 complex Ph(Bu)P(η5-C5H4)Mo(CO)3Pd(μ-I)2PdMo(CO)3(η5-C5H4)P(Ph)Bu and its use to model Pd-catalyzed cross-coupling reactions leading to M-C≡C bonds (2004) (7)
- Synthesis and chemistry of 2-oxacyclocarbene and 2-cyclovinyl ether ligands supported by the [{MeC(CH2PPh2)3}Re(CO)2]+ auxiliary (2002) (7)
- Synthesis and crystal structure of the 2bonded CSe2 complex [(triphos )RhCl(2CSe2)]C6H6triphos =(Ph2PCH2)3CMe]. Metal-promoted head-to-head dimerization of CSe2 to C2Se4 (1984) (7)
- A New Way to both Oligothiophene-Spaced Bimetallic Complexes and Functionalized Oligothiophenes (1997) (6)
- Solid-gas reactions of molecular organometallic complexes. Detection of a metastable intermediate in the carbonylation of a nickel(0) complex (1993) (6)
- [(Triphos)Co(CS2)Cr(CO)5]. A dinuclear heterometal complex containing a CS2 bridging group (1979) (6)
- Synthesis and characterisation of κ1-P and κ2-P,N palladium(II) complexes of the open cage water soluble aminophosphine PTN (2008) (6)
- Photochemistry of metal dithio- and diselenocarbonates. A new route to sulfido, disulfur, and diselenium complexes (1987) (6)
- Cover Picture: Ethanol Oxidation on Electrocatalysts Obtained by Spontaneous Deposition of Palladium onto Nickel-Zinc Materials (ChemSusChem 1/2009) (2009) (6)
- Unprecedented bridging mode of the triethylphosphine–carbon disulphide adduct PEt3·CS2. X-Ray crystal structure of the binuclear silver(I) complex [{Ag(S2CPEt3)(µ-S2CPEt3)}2][ClO4]2 (1983) (6)
- New Functionalized Vinyl Monomers by Ethylene‐(Functionalized)‐Norbornene Hetero‐Trimerization Catalyzed by Cobalt(II)‐(Imino)pyridine Complexes (2008) (6)
- Cobalt(II) and nickel(II) complexes with 1,1-bis(diphenylphosphinomethyl)-1-diphenylphosphino-ethylethane, atriphos, and 1,1,1-tris(diethylphosphinomethyl)ethane, etriphos. Crystal structures of the trinuclear complexes [Co3(atriphos)2Cl6] and [Ni3(etriphos)2Cl6] · 2 CHCl3 (1981) (6)
- Direct alcohol fuel cells as chemical reactors for the sustainable production of energy and chemicals: Energy and chemicals from renewables by electrocatalysis (2010) (6)
- Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)‐P3 or ‐P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone. (1997) (5)
- Cobalt(II) and nickel(II) complexes with tris(2-diethylphosphinoethyl)amine. Crystal and molecular structure of the trinuclear complex [Ni3(Etnp3)2Cl4](BPH4)2 (1980) (5)
- Flow microcalorimetry in stepwise equilibria of metal complexes. Reactions of NN′- and NN-diethylethylenediamine with hydrogen and copper(II) ions (1975) (5)
- Confined electrodeposition using a template-assisted procedure based on the selective desorption of a short chain thiol from a binary self-assembled monolayer formed on Ag( 1 1 1) (2010) (5)
- Synthesis and reactivity toward reducing agents of the ethoxycarbonyl complex [(np3)Ni(CO2Et)]BPh4(np3=tris(2-diphenylphosphinoethyl)amine) (1984) (5)
- Synthesis and structure of a rhodacyclobutene complex formed by addition of two F3CC.tplbond.CCF3 molecules to a Rh-.eta.2-CS2 moiety (1985) (5)
- Chemoselective hydrogenation of α,β-unsaturated ketones to allylic alcohols, catalyzed by a mononuclear ruthenium complex containing trans PnBu3 and PPh3 ligands (2007) (5)
- Large-scale synthesis of chiral ferrocenyl imino-phosphines (2005) (5)
- Synthesis and crystal structure of the dihapto-bonded phenylisothiocyanate complex [(triphos)Ni(η2-SCNPh)]·0.5 CH2Cl2 (1983) (5)
- Dihydrogen Metal Complexes in Catalysis (2001) (5)
- A family of hydride complexes of rhodium. Crystal structure of the paramagnetic rhodium(III)–rhodium(II) complex [(triphos)Rh(µ-H)3Rh(triphos)](BPh4)2·DMF [triphos = MeC(CH2PPh2)3, DMF = dimethylformamide] (1986) (5)
- Electrooxidation in Alkaline Media of Ethylene Glycol and Glycerol on Pd‐(Ni‐Zn)/C Anodes in Direct Alcohol Fuel Cells (2013) (5)
- Iridium-Catalyzed C=O Hydrogenation (2010) (4)
- Homogeneous decarbonylation of ethyl formate at rhodium. Evidence for the formation of a cis-hydride(ethoxycarbonyl) intermediate through CH bond cleavage (1988) (4)
- Triethylphosphine—carbgn disulfide zwitterion as a bridging six-electron donor ligand in [Mo(CO)2(PEt3)(μ-S2CPEt3)]2; synthesis and x-ray crystal structure (1981) (4)
- REACTIVITY OF THE TRIETHYLPHOSPHINE‐CARBON DISULFIDE ADDUCT (ET3P.CS2) TOWARD COBALT(II) CATIONS IN THE PRESENCE OF THE TRIS (TERTIARY PHOSPHINES) TRIPHOS AND ETRIPHOS. X‐RAY CRYSTAL STRUCTURE OF THE COMPLEX ((ETRIPHOS)CO(S2C(H)PET3))(BPH4)2 (1983) (4)
- New metal-assisted synthesis of tetrakis(trifluoromethyl)tetrathiafulvalene (1984) (4)
- Synthesis of palladium(II) complexes containing a new alpha-D-xylofuranose-modified diphosphine and their application as catalyst precursors in the co- and terpolymerization of CO-ethene and propene. (2008) (4)
- Unprecedented intramolecular attack by a phosphine on a η2-dithiomethyl ester group. X-ray crystal structure of the complex [Ph2S2Me)]BPh4 (1983) (4)
- Hydrogenation of Arenes and Heteroaromatics (2008) (4)
- Thiophene C–S bond cleavage by rhodium and iridium. An unprecedented bridging mode of the open C4H4S fragment (1995) (4)
- Confined electrodeposition of CdS in the holes left by the selective desorption of 3-mercapto-1-propionic acid from a binary self-assembled monolayer formed with 1-octanethiol. (2010) (4)
- A novel reaction of coordinated vinylidenes: coupling with hydrogen sulfide to give a η1-thioaldehyde (1994) (4)
- Metathesis of CS2‐Like Heteroallenes on 1,1‐Dithio Complexes of Rhodium(III) (1987) (4)
- Reversible Double Addition of H2 on a Bis(μ-sulfido) Binuclear Rhodium Complex. (1987) (4)
- Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II) (1998) (4)
- Enantioselective hydrogenation of prochiral substrates in catalytic membrane reactors (2011) (4)
- Palladium‐Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells (2010) (4)
- Cover Picture: Self-Sustainable Production of Hydrogen, Chemicals, and Energy from Renewable Alcohols by Electrocatalysis (ChemSusChem 7/2010) (2010) (3)
- Hydrogenation, Hydrogenolysis and Desulphurization of Thiophenes by Soluble Metal Complexes (1998) (3)
- Pulsed laser photolysis of Os(pp3)H2[pp3= P(CH2CH2PPh2)3]: kinetic selectivity for reaction with methane (1994) (3)
- Synthesis and Reactivity of the Labile Dihydrogen Complex [{MeC(CH(2)PPh(2))(3)}Ir(H(2))(H)(2)]BPh(4). (1997) (3)
- Distinct reaction pathways for some classical and nonclassical transition metal dihydrides (1990) (3)
- Chemoselective Hydrogen-Transfer Reduction of α,β-Unsaturated Ketones Catalyzed by Isostructural Iron(II), Ruthenium(II), and Osmium(II) cis Hydride η2-Dihydrogen Complexes. (1993) (3)
- Classical and Nonclassical Polyhydride Ruthenium(II) Complexes Stabilized by the Tetraphosphine P(CH2CH2PPh2)3. (1991) (3)
- mer,trans‐[Bis(2‐diphenylphosphinoethyl)(n‐propyl)amine‐N,P,P']dichloro(triphenylphosphine)ruthenium(II) 0.5‐Dichloromethane Solvate (1995) (3)
- Metal-promoted trimerization of carbon disulphide. Synthesis and structure of the dinuclear copper(I) complex [(PPh3)2Cu(µ-S2CSCH2SCS2)Cu(PPh3)2] (1983) (3)
- Hydrogen Energy. Challenges and Prospects. By D. A. J. Rand and R. M. Dell. (2008) (3)
- Synthesis and characterization of heterobimetallic complexes containing C-S cleaved thiophenes (1998) (3)
- Radial trinuclear complexes of cobalt(II) and nickel(ll) with tris(2-dimethylphosphinoethyl)- amine (1978) (3)
- Synthesis and electrochemistry of some homo- and hetero-dinuclear trihydride complexes of rhodium, iron, cobalt, and nickel (1986) (3)
- Electron‐Rich Iridium Complexes with Mixed‐Donor Polydentate Ligands. Chemoselective Catalysts in Hydrogen‐Transfer Reduction of α,. beta.‐Unsaturated Ketones. (1991) (2)
- Synthesis and Reactivity of Metal Complexes with the Zwitterionic Et3P—CS2 Ligand. Structure of the Dithiocarbonato Complex [(triphos)Co(S2CO)] (1982) (2)
- Synthesis of New Hydride-Carbyne and Hydride-Vinylcarbyne Complexes of Osmium(II) by Reaction of OsH2Cl2(iPr3P)2 with Terminal Alkynes (1995) (2)
- A Stable η2-H2 Complex of Cobalt. Role of the H-H Interaction in Hydrogen Transfer from Metal to Alkene. (1989) (2)
- Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μ-S2 Groups Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3 (1990) (2)
- Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Triphosphines Combining Phosphorus, Planar, and Carbon Chirality (2004) (2)
- Polyketone Nanocomposites by Palladium-Catalyzed Ethylene-Carbon Monoxide-(Propene) Co(Ter)polymerization Inside an Unmodified Layered Silicate (2006) (2)
- REGIO- AND STEREOSELECTIVE DIMERIZATION OF 1-ALKYNES CATALYZED BY CLASSICAL AND NONCLASSICAL RUTHENIUM AND OSMIUM POLYHYDRIDO COMPLEXES (1996) (2)
- Cycloaddition of dimethylacetylene dicarboxylate to η2-coordinated trithiocarbonate (1982) (2)
- REACTIVITY OF COPPER(I) TETRAHYDROBORATES TOWARD CARBON DIOXIDE AND CARBONYL SULFIDE. STRUCTURE OF (TRIPHOS)CU(η1-O2CH) (1985) (2)
- Chloro[o-(diphenylphosphino)benzaldehyde]{N-[o-(diphenylphosphino)benzylidene]ethylamine}(tetrachloro-o-catecholato)iridium(III) (1994) (2)
- Hydrogenation of Benzene over Silica-Supported Catalysts (2006) (2)
- Thiophene, Benzo(b)thiophene and Dibenzo(b,d)thiophene as Precursors to Highly Conjugated Organosulfur Compounds. (2010) (2)
- Bis(cyclopentadienyl)phenylphosphine as Ligand Precursor for Assembling Heteropolymetal Complexes (2008) (2)
- STRUCTURAL COMPARISON OF COBALT AND NICKEL COMPLEXES WITH CARBON DISULFIDE AND ISOTHIOCYANATOBENZENE MOLECULES STABILIZED BY TRIPODAL POLYPHOSPHINE LIGANDS. IMPLICATIONS FOR THE NATURE OF THE CHEMICAL BONDING IN COMPOUNDS CONTAINING C (1984) (2)
- Rhodium Complexes with the Tripodal Triphosphine MeC(CH2PPh2)3 as Highly Reactive Systems for Hydrogenation and Hydroformylation of Alkenes. (1988) (1)
- Typical Reactions: Sections 6.3–6.4 (2005) (1)
- Domino Rhodium/Palladium‐Catalyzed Dehydrogenation Reactions of Alcohols to Acids by Hydrogen Transfer to Inactivated Alkenes. (2010) (1)
- anti,mer‐[Bis(2‐diphenylphosphinoethyl)(n‐propyl)amine‐N,P,P'](phenylethynyl)[(Z)‐1‐p‐tolyl‐4‐phenyl‐η3‐but‐1‐en‐3‐ynyl]ruthenium(II) Chloroform Solvate (1996) (1)
- Catalytic Hydrogenolysis of Thiophenic Molecules to Thiols by Soluble Metal Complexes (1996) (1)
- Synthesis, reactivity and X-ray structure of the complex [(depe)2Fe(S2CPEt3)](BPh4)2 (depe = 1,2-bis(diethylphosphino)ethane) (1981) (1)
- Structure of (4-pentynoato-O,O'){tris[2-(diphenylphosphino)ethyl]phosphine}iron(II) tetraphenylborate (1992) (1)
- fuel cell membrane electrode assemblies for fuel cells, their manufacture, use and containing them (2005) (1)
- Evidence for a Molecular Hydrogen Complex of Rhodium. Some Factors Affecting cis-Dihydride ←→ η2-Dihydrogen Exchange. (1987) (1)
- Facile Activation of H2 on 1,1- and 1,2-Dithio Complexes of Rhodium(III). An Experimental Study. (1988) (1)
- A Novel Oxygen-Carrying and Activating System of Rhodium(III). Oxidation and Oxygenation Reactions of 3,5-Di-tert.-butylcatechol Catalyzed by a Rhodium(III) Catecholate Through Its (η1-Superoxo) (η2-semiquinonato)rhodium(III) Complex. (1990) (1)
- Modified multi-walled carbon nanotubes potentially suitable for intracellular pH measurements (2010) (1)
- FACILE REDUCTION OF CARBON DIOXIDE, CARBONYL SULFIDE, AND CARBON DISULFIDE BY COPPER(I) BOROHYDRIDE. X-RAY CRYSTAL STRUCTURE OF THE COMPLEX ((TRIPHOS)CU(O2CH)) (1983) (1)
- Intramolecular, reversible C–H oxidative addition–reductive elimination at rhodium. Reaction of the intermediate with different types of C–H bonds and dihydrogen (1987) (1)
- Immobilization of Optically Active Rhodium‐Diphosphine Complexes on Porous Silica via Hydrogen Bonding. (2001) (1)
- Formation and X-ray Structure of Unusual Doubly and Triply Condensed Cyclic Systems Complexes . 1 . The [ 2 + 21 Condensation of an Alkyne on a (2001) (0)
- Metathesis of CS2-Like Heteroallenes on 1,1-Dithio Complexes of Rhodium(III). (1987) (0)
- Oxazolidonderivate, methods for their manufacture and pharmaceutical compositions containing them (1978) (0)
- Homo- and Heterobimetallic Trihydride Complexes Stabilized by the Tripodal Phosphine Ligand MeC(CH2PPh2)3: Experimental and Theoretical Studies. (1989) (0)
- Photochemistry of Metal Dithio- and Diselenocarbonates. A New Route to Sulfido, Disulfur, and Diselenium Complexes. (1987) (0)
- Catalysts for fuel cell electrodes based on platinum and its alloys, making and using these catalysts and fuel cells containing the same (2005) (0)
- ENTHALPY AND ENTROPY STUDIES WITH COPPER(II)-BIS(DIAMINE) COMPLEXES AND SOME COMMENTS ON SOLVATION ENERGY AND GAS-PHASE ENTHALPIES (1975) (0)
- Utilisation de catalyseurs metalliques a nanostructures pour la production de gaz de synthese et de melanges gazeux riches en hydrogene (2005) (0)
- Nucleophilic Properties and Electrochemistry of Five-Coordinate Rhodium(I) σ-Cyanide Complexes. Synthesis and Characterization of Stable cis Hydride Cyanide Complexes of Rhodium(III). (1989) (0)
- Carbon monoxide-olefins co-(ter-)polymerization in the presence of GTR (Ground Tyre Rubber) microparticles (2007) (0)
- Hydrogenation and Hydrogenolysis of Thiophenic Molecules (2010) (0)
- COBALT(II) AND NICKEL(II) COMPLEXES WITH TRIS(2-DIETHYLPHOSPHINOETHYL)AMINE. CRYSTAL AND MOLECULAR STRUCTURE OF THE TRINUCLEAR COMPLEX (NI3(ETNP3)2CL4)(BPH4)2 (1981) (0)
- Polymerization of conjugated dienes in the presence of iron-based complex catalysts (2002) (0)
- Rhodium Complexes with Tripodal Polyphosphines as Excellent Precursors to Systems for the Activation of H-H and C-H Bonds. (1988) (0)
- Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Triphosphines Combining Phosphorus, Planar, and Carbon Chirality Synthesis of New Diastereomerically Pure Ferrocenyl Triphosphines (2004) (0)
- Synthesis and Characterization of Dirhodium Complexes Containing μ-SO, μ-SH, and μS2 Groups, Stabilized by the Tripodal Ligand CH3C(CH2PPh2)3 (1990) (0)
- NEW DIASTEREOMERICALLY PURE AMINODIOL LIGANDS FROM (R)-(-)-PHENYLGLYCINOL AND CYCLOHEXENE OXIDE. SYNTHESIS AND CHARACTERIZATION OF THE LIGANDS AND OF THEIR DIOXOMOLYBDENYL COMPLEXES (1996) (0)
- Device for handling and / or processing of objects. (2007) (0)
- REACTIVITY OF η2-S-METHYL TRITHIOCARBONATOMETAL COMPLEXES AS ELECTROPHILES (1984) (0)
- Synthesis, Characterization, and Electrochemical Properties of a Family of Dinuclear Rhodium Complexes Containing Two Terminal Hydride Ligands and Two Hydride (or Chloride) Bridges. Stoichiometric and Catalytic Hydrogenation Reactions (1989) (0)
- Electrophilic addition of oxygen, sulphur, and selenium to η2-CS2 and η2-CS2Me cobalt complexes (1983) (0)
- Iridium‐Catalyzed CO Hydrogenation (2009) (0)
- COBALT(II) AND NICKEL(II) TRITHIOCARBONATE COMPLEXES AS NUCLEOPHILIC REAGENTS. REACTIVITY AND X-RAY STRUCTURE OF THE TRITHIOCARBONATE COMPLE S,S-(METHYLTRITHIOCARBONATO)(1,1,1,-TRIS(DIPHENYLPHOSPINOMETHYL)ETHANE)COBAL TETRAPHENYLBORATE TETRAHYDROFURAN (1/1.5) (1982) (0)
- Stepwise Metal-Assisted Conversion of η2-CSe2 to η1-Se2CPEt3, η2-Se2CO, and η2-Se2. Crystal Structures of the Complexes ((triphos)Rh(Se2CO))BPh4·0.5 CH2Cl2·0.5 C4H9OH and ((triphos)Rh(μ-Se2)2Rh(triphos))(BPh4)2·2 DMF (triphos: MeC(CH2 (1989) (0)
- METAL-PROMOTED TRANSFORMATION OF CARBON DIOXIDE INTO CARBON MONOXIDE. X-RAY CRYSTAL STRUCTURE OF THE NICKEL-CARBONATE COMPLEX (O:PPH2CH2C(CH3)(CH2PPH2)2)NI(O2CO).0.5H2O.C6H6 (1984) (0)
- Chemical and Electrochemical Oxidation of the Phosphoniodichalcogenoformate Complexes (triphos)RhCl(X2CPEt3) (triphos: MeC(CH2PPh2)3; X: S, Se). Synthesis of Metal Dichalcogenocarbonates from O2 and Phosphonium-Betaine-Like Complexes. (1988) (0)
- A New P-Chiral Aminophosphine Ligand Containing a 2,2′-Coupled Pyrrolidine-Phospholane Ring System. Synthesis and Coordination Properties with Rhodium(I) and Iridium(I) Fragments (1995) (0)
- (Dithiocarbonato) [1,1,1-Tris(Diphenylphosphinomethyl)Ethane]Rhodium (III) Tetraphenylborate Solvate (2007) (0)
- Hydrogenation, Hydrolysis, and Desulfurization of Thiophenes by Soluble Metal Complexes: Recent Achievements and Future Directions (1998) (0)
- A CARBON DISULFIDE BRIDGE OF A NEW TYPE IN A BINUCLEAR COBALT(I) COMPLEX (1979) (0)
- Energy and Chemicals from Renewables by Electrocatalysis (2009) (0)
- A Homogeneous Iron(II) System Capable of Selectively Catalyzing the Reduction of Terminal Alkynes to Alkenes and Buta-1,3-dienes. (1989) (0)
- Platinum-free electro-catalyst (2003) (0)
- Membrane-electrode assembly for a fuel cell, their manufacture and use and fuel cells that incorporate them. (2005) (0)
- Isomerization of Allylic Alcohols to Carbonyl Compounds by Aqueous‐Biphase Rhodium Catalysis. (2001) (0)
- Cover Picture: Electrooxidation of Ethylene Glycol and Glycerol on Pd‐(Ni‐Zn)/C Anodes in Direct Alcohol Fuel Cells (ChemSusChem 3/2013) (2013) (0)
- First Example of Opening and Hydrogenation of 2,3-Dihydrobenzo[b]thiophene to 2-Ethylthiophenol Assisted by a Soluble Metal Complex. (1999) (0)
- Alkene/CO Copolymerisation (2005) (0)
- Rhodium-Assisted Transformations of Substituted Thiophenes into Butadienyl Methyl Sulfides. (1996) (0)
- SYNTHESIS AND CRYSTAL STRUCTURE OF TWO ISOMORPHOUS RHODIUM AND IRIDIUM COMPLEXES WITH CYCLO-TRIPHOSPHORUS AND 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE (1980) (0)
- TRIPLE-DECKER COMPLEXES OF 4D AND 5D METALS WITH CYCLO-TRIPHOSPHORUS AS μ,η3 LIGAND: STRUCTURE AND MAGNETIC PROPERTIES (1980) (0)
- Activation of 1-Alkynes at Tripodal (Polyphosphine)rhodium Systems. Regioselective Synthesis of Enol Esters from 1-Alkynes and Carboxylic Acids Catalyzed by Rhodium(I) Monohydrides. (1990) (0)
- Rücktitelbild: Electrochemical Milling and Faceting: Size Reduction and Catalytic Activation of Palladium Nanoparticles (Angew. Chem. 34/2012) (2012) (0)
- Special Catalysts and Processes: Sections 3.2.6–3.2.14 (2008) (0)
- TRIPHOS)CO(CS2)CR(CO)5). A DINUCLEAR HETEROMETAL COMPLEX CONTAINING A CARBON DISULFIDE BRIDGING GROUP (1979) (0)
- Synthesis of the New Chiral Aminodiphosphine Ligands (R)‐ and (S)‐(. alpha.‐Methylbenzyl)bis(2‐(diphenylphosphino)ethyl)amine and Their Use in the Enantioselective Reduction of α,β‐Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis. (1995) (0)
- Aqueous-Phase Catalysis: Typical Reactions (2008) (0)
- Synthesis, Redox Properties, and Reactivity of a Novel Family of Electron‐Rich Vinylidene and Vinylphosphonium Complexes of Rhodium(I). (1990) (0)
- Hydrogenation, Hydrogenolysis, and Hydrodesulfurization of Thiophenes (2006) (0)
- Palladium-Catalyzed Arylation of Malonates and Cyanoesters Using Sterically Hindered Trialkyl- and Ferrocenyldialkylphosphine Ligands: A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate (2003) (0)
- HYDROGENATION, HYDROGENOLYSIS DES ULPHURIZATIO N 0 F THIO PHENES S 0 LUBLE METAL C 0 MPLEXES (1998) (0)
- Genesis of Tetrathiooxalate‐like C2S4 and C2Se4 Units. A Multiform Experimental Study and the Relevant Theoretical Implications for the Role of Transition‐Metal Fragments. (1987) (0)
- Metal-Assisted Three-Fragment Demolition of the Dithiocarbonate Ligand: A New Synthetic Route to Homo- and Heterobinuclear Bis(μ-sulfido)metal Complexes. Chemical, Electrochemical, and Spectroscopic Characterization of a Family of Com (1988) (0)
- THIOPHENE, BENZOBTHIOPHENE AND DIBENZOB,DTHIOPHENE AS PRECURSORS TO HIGHLYCONJUGATED ORGANOSULFUR COMPOUNDS (1997) (0)
- Transition Metal Complexes with the C1‐Symmetric Diphosphines (R)‐(R)‐3‐Benzyl‐2,4‐bis(diphenylphosphino)pentane and (R)‐(R)‐3‐Benzyl(p‐sulfonate)‐2,4‐bis(diphenylphosphino)pentane Sodium Salt. Applications to Enantioselective Catalysis in Different Phase Systems. (2001) (0)
- Bifunctional activation of CO2: a case where the basic and acidic sites are not held in the same structure (1984) (0)
- FLOW MICROCALORIMETRY IN STEPWISE EQUILIBRIA OF METAL COMPLEXES, REACTIONS OF NN′- AND NN-DIETHYLETHYLENEDIAMINE WITH HYDROGEN AND COPPER(II) IONS (1975) (0)
- CCDC 195274: Experimental Crystal Structure Determination (2003) (0)
- Novel Reactions of the (BPh4)‐ Salt of the Bifunctional Complex ((triphos)Rh(S2CO))+ (triphos: MeC(CH2PPh2)3): One‐Electron Reduction, Cleavage of B‐H and B‐C Bonds, and Metathesis of CS2‐like Heteroallene Molecules. (1989) (0)
- Comprehensive Experimental and Interpretational Study of the Complex Formation and Transformations Involving o-Quinoid Molecules and an L3M-Type Metal Fragment (M: Cobalt). (1988) (0)
- RADIAL TRINUCLEAR COMPLEXES OF COBALT(II) AND NICKEL(II) WITH TRIS(2-DIMETHYLPHOSPHINOETHYL)AMINE (1979) (0)
- Few layer graphene decorated with Pd nanoparticles: synthesis, characterisation and catalytic applications in the electrochemical oxidation of alcohols (2012) (0)
- SYNTHESIS AND REACTIVITY OF METAL COMPLEXES WITH ZWITTERION LIGANDS ET3P-CS2; STRUCTURE OF THE DITHIOCARBONATO COMPLEX ((TRIPHOS)CO(S2CO)) (1982) (0)
- Synthesis and Reactivity of Metal Complexes with the Zwitterionic Et3PCS2 Ligand. X‐Ray Structure of the Dithiocarbonate Complex [(triphos) CoS2CO] (1982) (0)
- SMOOTH MUSCLE RELAXANT PROPERTIES OF 2-NAPHTHYL-OXYACETIC ACID ESTERS (1978) (0)
- Confined Electrodeposition of Metals and Semiconductors (2009) (0)
- Asymmetric Alkylation or Amination of Allylic Esters (2005) (0)
- REACTIVITY OF η2-TRITHIOCARBONATE METAL COMPLEXES AS NUCLEOPHILES. INTRAMOLECULAR MOBILITY OF THE TRITHIOCARBONATE GROUP IN μ-CS3 BINUCLEAR COMPLEXES (1983) (0)
- Tripodal Polyphosphine Ligands in Homogeneous Catalysis. Part 1. Hydrogenation and Hydroformylation of Alkynes and Alkenes Assisted by Organorhodium Complexes with MeC(CH2PPh2)3. (1990) (0)
- UNPRECENDENTED BRIDGING MODE OF THE TRIETHYLPHOSPHINE-CARBON DISULFIDE ADDUCT PET3.CS2. X-RAY CRYSTAL STRUCTURE OF THE BINUCLEAR SILVER(I) COMPLEX BIS(μ-(PHOSPHONIODITHIOCARBOXYLATO-S,S′))(PHOSPHONIODITHIOCARBOXYLATO-S,S′)S# ILVER)BIS (1983) (0)
- Use of nanostructured metallic catalysts for the production of syngas and gassous mixtures rich in H2 (2005) (0)
- IRON-ASSISTED REACTION OF CARBON DISULFIDE WITH TRIETHYLPHOSPHINE. SYNTHESIS AND STRUCTURE OF THE COMPOUND [Et3PCH2S2CH2PEt3](BPh4)2 (1981) (0)
- Modelling the Hydrodenitrogenation of Aromatic N-Heterocycles in the Homogeneous Phase. (2001) (0)
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What Schools Are Affiliated With Claudio Bianchini?
Claudio Bianchini is affiliated with the following schools: