Daniel S. Kemp
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American chemist
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Chemistry
Daniel S. Kemp's Degrees
- PhD Chemistry California Institute of Technology
- Masters Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is Daniel S. Kemp Influential?
(Suggest an Edit or Addition)According to Wikipedia, Daniel Schaeffer Kemp was an American organic chemist, an emeritus professor of chemistry at the Massachusetts Institute of Technology. Kemp's work was focused on the synthesis and conformational analysis of peptides. He developed several chemical ligation strategies and methods for templating the formation of helices and sheets. The eponymous and the reaction are among his developments. He was the author of an organic chemistry textbook. He died from COVID-19 during the COVID-19 pandemic in Massachusetts.
Daniel S. Kemp's Published Works
Published Works
- Mechanism of Stabilization of Helical Conformations of Polypeptides by Water Containing Trifluoroethanol (1996) (185)
- Synthesis and conformational analysis of cis,cis-1,3,5-trimethylcyclohexane-1,3,5-tricarboxylic acid (1981) (128)
- Physical organic chemistry of benzisoxazoles. I. Mechanism of the base-catalyzed decomposition of benzisoxazoles (1973) (117)
- Physical organic chemistry of benzisoxazoles. III. Mechanism and the effects of solvents on rates of decarboxylation of benzisoxazole-3-carboxylic acids (1975) (117)
- Physical organic chemistry of benzisoxazoles. IV. Origins and catalytic nature of the solvent rate acceleration for the decarboxylation of 3-carboxybenzisoxazoles (1975) (94)
- The helical s constant for alanine in water derived from template-nucleated helices (1991) (93)
- Physical organic chemistry of benzisoxazoles. II. Linearity of the Broensted free energy relation for the base-catalyzed decomposition of benzisoxazoles (1973) (84)
- Synthesis of a 39-peptide and a 25-peptide by thiol capture ligations : observation of a 40-fold rate acceleration of the intramolecular O,N-acyl-transfer reaction between peptide fragments bearing only cysteine protective groups (1993) (74)
- Synthesis and conformational analysis of epindolidione-derived peptide models for .beta.-sheet formation (1990) (71)
- Dual wavelength parametric test of two-state models for circular dichroism spectra of helical polypeptides: anomalous dichroic properties of alanine-rich peptides. (2003) (67)
- The amine capture strategy for peptide bond formation—an outline of progress (1981) (66)
- Studies of N-terminal templates for .alpha.-helix formation. Synthesis and conformational analysis of peptide conjugates of (2S,5S,8S,11S)-1-acetyl-1,4-diaza-3-keto-5-carboxy-10-thiatricyclo[2.8.1.04,8]tridecane (Ac-Hel1-OH) (1991) (64)
- The N-ethylbenzisoxazolium cation—I (1965) (58)
- Immunochemical studies of angiotensin. (1966) (56)
- Boc-L-Dmt-OH as a fully N,S-blocked cysteine derivative for peptide synthesis by prior thiol capture. Facile conversion of N-terminal Boc-L-Dmt-peptides to H-Cys(Scm)-peptides (1989) (55)
- Peptidomimetics and the template approach to nucleation of β-sheets and α-helices in peptides (1990) (55)
- 2-Amino-2′-carboxydiphenylacetylenes as β-turn mimetics. synthesis and conformational properties (1995) (54)
- Decarboxylation of benzisoxazole-3-carboxylic acids. Catalysis by extraction of possible relevance to the problem of enzymic mechanism (1970) (53)
- Studies of N-terminal templates for .alpha.-helix formation. Synthesis and conformational analysis of (2S,5S,8S,11S)-1-acetyl-1,4-diaza-3-keto-5-carboxy-10-thiatricyclo[2.8.1.04,8]tridecane (Ac-Hel1-OH) (1991) (53)
- Peptide synthesis by prior thiol capture. 6. Rates of the disulfide-bond-forming capture reaction and demonstration of the overall strategy by synthesis of the C-terminal 29-peptide sequence of BPTI (1989) (51)
- A convenient preparation of derivatives of 3(s)-amino-10(r)-carboxy-1,6-diaza-cyclodeca-2,7-dione the dilactam of L-α, γ-diaminobutyric acid and d-glutamic acid: A β-turn template (1988) (45)
- Peptide synthesis by prior thiol capture. 1. A convenient synthesis of 4-hydroxy-6-mercaptodibenzofuran and novel solid-phase synthesis of peptide-derived 4-(acyloxy)-6-mercaptodibenzofurans (1986) (44)
- Peptide synthesis by prior thiol capture. 2. Design of templates for intramolecular O,N-acyl transfer. 4,6-Disubstituted dibenzofurans as optimal spacing elements (1986) (44)
- Template-nucleated alanine-lysine helices are stabilized by position-dependent interactions between the lysine side chain and the helix barrel. (1996) (42)
- Sequence- and strand-specific cleavage in oligodeoxyribonucleotides and DNA containing 3'-thiothymidine. (1992) (42)
- Microanalysis by successive isotopic dilution. A new assay for racemic content. (1970) (40)
- Base catalysis of thiazolium salt hydrogen exchange and its implications for enzymatic thiamine cofactor catalysis. (1970) (39)
- A new peptide coupling reagent. (1967) (39)
- Large Circular Dichroism Ellipticities for N-Templated Helical Polypeptides Are Inconsistent with Currently Accepted Helicity Algorithms. (1999) (38)
- Solubilized, spaced polyalanines: a context-free system for determining amino acid alpha-helix propensities. (2002) (38)
- The Energetics of Helix Formation by Short Templated Peptides in Aqueous Solution. 1. Characterization of the Reporting Helical Template Ac-Hel1 (1995) (38)
- Synthesis of peptide-functionalized diacylaminoepindolidiones as templates for β-sheet formation (1988) (37)
- A short β-sheet containing proline nucleated by a 2,2′-substituted tolan β-turn mimetic (1995) (37)
- Conformationally restricted cyclic nonapeptides derived from L-cysteine and LL-3-amino-2-piperidone-6-carboxylic acid (LL-Acp), a potent .beta.-turn-inducing dipeptide analog (1985) (36)
- Amino acids derivatives that stabilize secondary structures of polypeptides (1982) (35)
- Conformational analysis of peptide-functionalized diacylaminoepindolidiones 1H NMR evidence for β-sheet formation (1988) (33)
- High Helicities of Lys-Containing, Ala-Rich Peptides Are Primarily Attributable to a Large, Context-Dependent Lys Stabilization (1998) (32)
- Consistent helicities from CD and template t/c data for N-templated polyalanines: progress toward resolution of the alanine helicity problem. (2002) (32)
- Temperature- and length-dependent energetics of formation for polyalanine helices in water: assignment of w(Ala)(n,T) and temperature-dependent CD ellipticity standards. (2006) (32)
- Rate constants for peptide p-nitrophenyl ester coupling reactions in dimethylformamide. A model for steric interactions in the peptide bond forming transition state. (1974) (31)
- Optimal N-caps for N-terminal helical templates: effects of changes in H-bonding efficiency and charge. (2001) (31)
- Peptide racemization mechanism. A kinetic isotope effect as a means of distinguishing enolization from oxazolone formation. (1970) (29)
- Models that demonstrate peptide bond formation by prior thiol capture I. Capture by disulfide formation (1981) (29)
- Pluripotential amino acids I. ()--dihydroxyborylphenylalanine (-Bph) as a precursor of -Phe and -Tyr containing peptides; specific tritiation of -Phe-containing peptides at a final step in synthesis (1980) (29)
- The Structure and Energetics of Helix Formation by Short Templated Peptides in Aqueous Solution. 2. Characterization of the Helical Structure of Ac-Hel1-Ala6-OH (1996) (28)
- Context-independent, temperature-dependent helical propensities for amino acid residues. (2009) (28)
- Convenient routes to 4,4''-functionalized o-terphenyls and 2,2'-functionalized biphenyls (1981) (28)
- INTRAMOLECULAR O,N-ACYL TRANSFER VIA CYCLIC INTERMEDIATES OF NINE AND TWELVE MEMBERS. MODELS FOR EXTENSIONS OF THE AMINE CAPTURE STRATEGY FOR PEPTIDE SYNTHESIS (1981) (28)
- THE STRUCTURE AND ENERGETICS OF HELIX FORMATION BY SHORT TEMPLATED PEPTIDES IN AQUEOUS SOLUTION. 3. CALCULATION OF THE HELICAL PROPAGATION CONSTANT S FROM THE TEMPLATE STABILITY CONSTANTS T/C FOR AC-HEL1-ALAN-OH, N = 1-6 (1996) (27)
- An addition-elimination mechanism for CH/CD exchange in thiazole (1970) (26)
- Letter: Peptide bond formation by the amine capture principle. (1975) (25)
- Short, solubilized polyalanines are conformational chameleons: exceptionally helical if N- and C-capped with helix stabilizers, weakly to moderately helical if capped with rigid spacers. (2001) (25)
- Rapid intramolecular acyl transfer from phenol to carbinolamine--progress toward a new class of peptide coupling reagent. (1975) (24)
- Peptide synthesis with benzisoxazolium salts—III : Utility of 7-hydroxy-2-ethylbenzisoxazolium fluoroborate in the synthesis of peptides (1974) (24)
- Base-catalyzed epimerization behavior and unusual reactivity of N-substituted derivatives of 2,5-dicarbalkoxypyrrolidine. Preparation of a novel mixed carbamic carbonic anhydride by a 4-(dimethylamino)pyridine-catalyzed acylation (1988) (24)
- Rational design of templates for intramolecular O,N-acyl transfer via medium-sized cyclic intermediates derived from L-cysteine. Definition of an experimental maximum in effective molarity through the study of "tunable" templates (1989) (23)
- Peptide synthesis by prior thiol capture. IV: Amide bond formation: the effect of a side-chain substituent on the rates of intramolecular O,N-acyl transfer (1986) (23)
- (2S,5S,8S,11S)-1-Acetyl-1,4-diaza-3-keto-5-carboxy-10-thia-tricyclo-[2.8.04,8]-tridecane, 1 synthesis of prolyl-proline-derived, peptide-functionalized templates for α-helix formation (1988) (23)
- Racemization during peptide couplings using the mixed anhydride, N-hydroxysuccinimide ester, 8-hydroxyquinoline ester, and acyl azide methods. (1970) (23)
- Water-solubilized, cap-stabilized, helical polyalanines: calibration standards for NMR and CD analyses. (2005) (23)
- An Improved Synthesis of a Template for .alpha.-Helix Formation (1995) (21)
- (2S,5S,8S,11S)-1-Acetyl-1,4-diaza-3-keto-5-carboxy-10-thia-tricyclo -[2.8.04,8]-tridecane, 1 the preferred conformation of 1 (1 ≡ αTemp-OH) and its peptide conjugates αTemp-L-(Ala)n-OR (n=1 to 4) and α-Temp-L-Ala-L-Phe-L-Lys(εBoc)-L-Lys(ε-Boc)-NHMe studies of templates for α-helix formation (1988) (21)
- Amino acid derivatives that stabilize secondary structures of polypeptides : II. The most stable conformation of peptides containing 3-amino-2-piperidone-6-carboxylic acid (Acp) (1982) (21)
- New protective groups for peptide synthesis—II the Dobz group boron-derived affinity protection with the p-dihydroxyborylbenzyloxycarbonylamino function (1975) (20)
- Models that demonstrate peptide bond formation by prior thiol capture--II capture by organomercury derivatives (1981) (20)
- Amino acid derivatives that stabilize secondary structures of polypeptides. 4. Practical synthesis of 4-(alkylamino)-3-cyano-6-azabicyclo[3.2.1]oct-3-enes (ben derivatives) as .gamma.-turn templates (1989) (19)
- New protective groups for peptide synthesis--III the maq ester group mild reductive cleavage of 2-acyloxymethyleneanthraquinones (1977) (19)
- New templates for prior thiol capture from xanthene, dibenzo[c,h]xanthen-7-one and 2-methylenedihydrobenzofuran (1991) (18)
- Relative ease of 1,2-proton shifts. Origin of the formyl proton of salicylaldehyde obtained by the Reimer-Tiemann reaction (1971) (18)
- The N-ethylbenzisoxazolium cation—II: The mechanism of reactions of the cation with nucleophiles (1967) (17)
- Synthetic routes to 1,5-diazacyclooctanes via 2,6-dioxo-1,5-diazabicyclo[3.3.1]octanes (1979) (17)
- New protective groups for peptide synthesis—I the Bic group base and solvent lability of the 5-benzisoxazolylmetheleneoxycarbonylamino function (1975) (17)
- Peptide synthesis with benzisoxazolium salts—II : Activation chemistry of 2-ethyl-7-hydroxybenzisoxazolium fluroborate; Coupling chemistry of 3-acyloxy-2-hydroxy-N-ethylbenzamides (1974) (17)
- An efficient synthesis of ethyl LL-3-amino-2-piperidone-6-carboxylate (1984) (16)
- Resolution of the histidine problem for thiol capture--synthesis of a 39-peptide (1991) (16)
- Calibrated calculation of polyalanine fractional helicities from circular dichroism ellipticities. (2004) (15)
- Specific base catalysis of azlactone formation. (1967) (15)
- Efficient helix nucleation by a macrocyclic triproline-derived template (1995) (14)
- Energetic characterization of short helical polyalanine peptides in water: analysis of 13C=O chemical shift data. (2005) (14)
- Chemistry of acylsalicylamides. I. Base-catalyzed decomposition of o-benzyloxycarbonylglycyl-n-ethylsalicylamide (1971) (14)
- Peptide synthesis by prior thiol capture—V. The scope and control of disulfide interchange during the acyl transfer step (1987) (13)
- How to promote proton transfer (1995) (13)
- New S-protection from known N-protection: thio esters of N-urethanyl-N-methyl-.gamma.-aminobutyric acid as a class of protective groups for thiols in peptide synthesis (1985) (13)
- Chaotropic Anions Strongly Stabilize Short, N-Capped Uncharged Peptide Helicies: A New Look at the Perchlorate Effect. (2001) (13)
- Racemization in Peptide Synthesis (1979) (12)
- Amino acid derivatives that stabilize secondary structures of polypeptides—IV. Practical synthesis of 4-alkyamino-3-cyano-azabicyclo[3.2.1.]oct-3-enes (Ben derivatives) as γ-turn templates (1987) (11)
- Antithrombogenic cellulose film (1968) (11)
- Letter: Anomalously large steric inhibition of intramolecular O,N-acyl transfer to amino acid esters. (1975) (10)
- Highly enantioselective amide ligation by prior thiol capture (1991) (10)
- Peptide synthesis with benzisoxazolium salts—III (1974) (10)
- A macrocyclic triproline-derived template for helix nucleation (1995) (9)
- Peptides containing β-turns I-- -(gly--cys-gly)3 triply bridged by 1,3,5--(thiomethyl)benzene (1981) (9)
- Anderson test assessment of racemization for the hydroxybenzotriazole-dicyclohexylcarbodiimide peptide coupling procedure☆ (1974) (9)
- High Helicities of Lys-Containing, Ala-Rich Peptides Are Primarily Attributable to a Large, Context-Dependent Lys Stabilization. (1999) (9)
- Hydrazinolysis of salicyloylsalicylic acid. Irrelevance of an anhydride intermediate (1968) (9)
- Synthesis and analysis of a macrocyclic triproline-derived template containing a local conformational constraint (1995) (9)
- Indenes via fulvene intermediates (1994) (9)
- Nucleophilic reactivity of peptides toward 2-acyloxy-N-ethylbenzamides. The utility of free peptides as nucleophiles in amide bond forming reactions. (1974) (9)
- Peptide synthesis by prior thiol capture…III. Assessment of levels of racemization during two typical thiol capture coupling reactions (1987) (9)
- New protective groups for peptide synthesis. 4. Chromone-derived protection for amine and carboxyl functions (1981) (8)
- Peptide Synthesis by Prior Thiol Capture. Part 1. A Convenient Synthesis of 4-Hydroxy-6-mercaptodibenzofuran and Novel Solid-Phase Synthesis of Peptide-Derived 4-(Acyloxy)-6-mercaptodibenzofurans. (1986) (7)
- Synthesis of 1-methoxy-9-mercaptophenoxathiin and the resolved 1-[[N-[(benzyloxy)carbonyl]-L-alanyl]oxy]-9-[(methoxycarbonyl)dithio]phenoxathiin 10-oxide diastereomers. Comments on improved methods for sulfone reduction (1989) (7)
- Mild reductive cleavage of the 9-anthracenesulfonamido function. The 9-anthracenesulfonyl (Ans) group: a new approach to the protection of the guanidino function of arginine residues in peptide synthesis (1988) (7)
- Stereoselective decarboxylation of a geminal dicarboxylic acid. Synthesis of cis-5-(hydroxymethyl)-D-proline derivatives (1986) (7)
- CATECHOL AND SUBSTITUTED CATECHOL-DERIVED ORTHO ESTERS, MODELS FOR PROTECTED ACTIVE ESTERS IN PEPTIDE SYNTHESIS (1981) (7)
- Construction and Analysis of LifsonRoig Models for the Helical Conformations of α‐Peptides (2002) (6)
- An amino acid that controls polypeptide helicity: β-amino alanine, the first strongly stabilizing C-terminal helix stop signal (2000) (6)
- Amino acid derivatives that stabilized secondary structures of polypeptides—III. β-Enaminonitriles as analogs of secondary amides. The MCC group—1-acylamino-2-aminoalkyl-3-cyano-2-cyclopentenes as amino acid analogs. (1987) (6)
- Practical preparation and deblocking conditions for N-α-2-(p-biphenylyl)-2-propyloxycarbonyl)-amino acid(N-α-Bpoc-Xxx-OH) derivatives (2009) (5)
- Synthesis of cyclophanes derived from 1-amino-3,7-dialkyl-4-methylnaphthalenes (1980) (5)
- Conformational analysis of a triproline-derived helical template and its peptide conjugates (1995) (5)
- PHYSICAL ORGANIC CHEMISTRY OF BENZISOXAZOLES PART 2, LINEARITY OF THE BRONSTED FREE ENERGY RELATIONSHIP FOR THE BASE-CATALYSED DECOMPOSITION OF BENZISOXAZOLES (1973) (5)
- Structure of anhydroacetylsalicylamide (1981) (5)
- Resolution of proline acylation problem for thiol capture strategy by use of a chloro-dibenzofuran template. (2009) (5)
- Templates for intramolecular O,N-acyl transfer via cyclic intermediates derived from mercury derivatives of L-cysteine: progress toward a mercury-based thiol capture strategy (1989) (5)
- The reaction of dialkylmalonyl dichlorides with 1,3-diaminopropanes a new route to macrocyclic polyamides and polyamines (1977) (5)
- Progress toward a novel C-terminal helix capping principle: Synthesis and properties of (S)-α-(2-aminoethyl)-methionine (1994) (4)
- Novel class of silicon-based protective groups for the side chain of tyrosine. (1993) (4)
- Anomalous Neber reaction. General method for the preparation of 3-carboxy-1-naphthylamines (1975) (4)
- PLURIPOTENTIAL AMINO ACIDS. I. (L)-P-DIHYDROXYBORYLPHENYLALANINE (L-BPH) AS A A PRECURSOR OF L-PHE AND L-TYR CONTAINING PEPTIDES. SPECIFIC TRITIATION OF L-PHE-CONTAINING PEPTIDES AT A FINAL STEP IN SYNTHESIS (1980) (4)
- A Permutation Test for Stabilization of Polypeptide Helices by Sequence-Dependent Side Chain Interactions: Characterization of a Helix Initiation Site within the Myohemerythrin Sequence 76-87 (1997) (4)
- C-terminal helix capping propensities in a polyalanine context for amino acids bearing nonpolar aliphatic side chains (2001) (4)
- For Short Alanine-Lysine Peptides the Helical Propensities of Lysine Residues (s Values) Are Strongly Temperature Dependent (1996) (4)
- Peptidomimetics and the template approach to nucleation of beta-sheets and alpha-helices in peptides. (1990) (4)
- CONVENIENT ROUTES TO 4,4′′-FUNCTIONALIZED O-TERPHENYLS AND 2,2′-FUNCTIONALIZED BIPHENYLS (1982) (3)
- Synthesis of 1,5-diazacyclooctanes from 2,4,6,8-tetraketo-1,5-diazabicyclo[3,3,0]octanes (1978) (3)
- The irrelevance of an intramolecular salt bridge for solvent-catalyzed decarboxylation-solvent catalysis of the decarboxylation of 4 and6-(2′,4′,6′-trimethylpyridinium)-benzisoxazole-3-carboxylates (1978) (3)
- O-(2-Acetoxycyclohexyl)-N-isopropylhydroxylamine: a striking inertness of acyl carbon toward an intramolecular hydroxylamine function (1980) (3)
- STUDIES TOWARD PRACTICAL THIOXANTHENE-DERIVED PROTECTIVE GROUPS. 9,10-PROPANOTHIOXANTHYLIUM SALTS (1981) (3)
- Helix‐coil energetics for helix formers and breakers reflect context and temperature: Mutants of helically robust, guest‐sensitive homopeptide hosts (2009) (2)
- NUCLEOPHILIC REACTIVITY OF PEPTIDES TOWARD 2‐ACYLOXY‐N‐ETHYLBENZAMIDES, THE UTILITY OF FREE PEPTIDES AS NUCLEOPHILES IN AMIDE BOND FORMING REACTIONS (1974) (2)
- ANOMALOUSLY LARGE STERIC INHIBITION OF INTRAMOLECULAR O,N-ACYL TRANSFER TO AMINO ACID ESTERS (1976) (2)
- MODELS THAT DEMONSTRATE PEPTIDE BOND FORMATION BY PRIOR THIOL CAPTURE. I. CAPTURE BY DISULFIDE FORMATION (1981) (2)
- Applications of new peptide protective groups 1-- a synthesis of -s-acetamidomethyl dihydrosomatostatin (1981) (2)
- The synthesis of 3,11-dimethyl-1,5,9,13-tetraazatricyclo[9.5.1.13,9]octadecane, , a novel tetradentate cage structure (1978) (2)
- Conformationally Restricted Cyclic Nonapeptides Derived from L-Cysteine and LL-3-Amino-2-piperidone-6-carboxylic Acid (LL-Acp), a Potent β-Turn-Inducing Dipeptide Analogue. (1986) (1)
- Studies on the Nucleation in DMSO and Water of Beta-Sheet Structures with Peptide-Epindolidione Conjugates, (1992) (1)
- AMINO ACID DERIVATIVES THAT STABILIZE SECONDARY STRUCTURES OF POLYPEPTIDES. I. YNTHESIS OF L,L-3-AMINO-2-PIPERIDONE-6-CARBOXYLIC ACID (L,L-ACP), A NOV L BETA-TURN-FORMING AMINO ACID (1983) (1)
- Criterion for catalytically active intermediates (1968) (1)
- Correction. Structure of Anydroacetylsalicylamide (1981) (1)
- PEPTIDES CONTAINING β-TURNS. I. CYCLO-(GLY-L-CYS-GLY)3 TRIPLY BRIDGED BY Y 1,3,5-TRIS-(THIOMETHYL)BENZENE (1982) (1)
- Development of a 3-State Equilibrium Model for the Helix-Nucleation Template Ac-Hel1-OH, (1992) (1)
- RAPID INTRAMOLECULAR ACYL TRANSFER FROM PHENOL TO CARBINOLAMINE. PROGRESS TOWARD A NEW CLASS OF PEPTIDE COUPLING REAGENT (1976) (1)
- PEPTIDE BOND FORMATION BY THE PRIOR AMINE CAPTURE PRINCIPLE (1976) (1)
- Synthesis and Analysis of a Macrocyclic Triproline‐Derived Template (I) Containing a Local Conformational Constraint. (1995) (0)
- PEPTIDE SYNTHESIS WITH BENZISOXAZOLIUM SALTS PART 2, ACTIVATION CHEMISTRY OF 2-ETHYL-7-HYDROXYBENZISOXAZOLIUM FLUOROBORATE, COUPLING CHEMISTRY OF 3-ACYLOXY-2-HYDROXY-N-ETHYLBENZAMIDES (1975) (0)
- New Protective Groups for Peptide Synthesis. Part l. The Bic Group.Base and Solvent Lability of the 5-Benzisoxazolylmethyleneoxycarbonylamino Function. Part 2. The Dobz Group. Boron-derived Affinity Protection with the p-Dihydroxybory (1976) (0)
- An improved template for the initiation of peptide helices (2002) (0)
- ADDITIONS-ELIMINIERUNGS-MECHANISMUS BEI C-H/C-D-AUSTAUSCH VON THIAZOL (PH-ABHAENGIGE KINETIK) (1970) (0)
- Base-Catalyzed Epimerization Behavior and Unusual Reactivity of N-Substituted Derivatives of 2,5-Dicarbalkoxypyrrolidine. Preparation of a Novel Mixed Carbamic Carbonic Anhydride by a 4-(Dimethylamino)pyridine-Catalyzed Acylation. (1989) (0)
- APPLICATIONS OF NEW PEPTIDE PROTECTIVE GROUPS. I. A SYNTHESIS OF BIS-S-ACETAMIDOMETHYL DIHYDROSOMATOSTATIN (1982) (0)
- AMINO ACID DERIVATIVES THAT STABILIZE SECONDARY STRUCTURES OF POLYPEPTIDES. II. THE MOST STABLE CONFORMATION OF PEPTIDES CONTAINING 3-AMINO-2-PIPERIDONE-6-CARBOXYLIC ACID (ACP) (1983) (0)
- Peptide Synthesis by Prior Thiol Capture. Part 4. Amide Bond Formation: The Effect of a Side-Chain Substituent on the Rates of Intramolecular O,N-Acyl Transfer. (1987) (0)
- Indenes via Fulvene Intermediates. (1995) (0)
- Utilization of a reporting conformational template in probing the Phe-His interaction in the short alanine-rich peptide helices (2002) (0)
- Synthesis of 1-Methoxy-9-mercaptophenoxathiin and the Resolved 1-((N-(Benzyloxycarbonyl)-L-alanyl)oxy)-9-((methoxycarbonyl)dithio)phenoxathiin 10-Oxide Diastereomers. Comments on Improved Methods for Sulfone Reduction. (1990) (0)
- Practical Preparation and Deblocking Conditions for N-α-(2-p-Biphenylyl-2-propyloxycarbonyl)amino Acid (N-α-Bpoc-Xxx-OH) Derivatives. (1988) (0)
- THE REACTION OF DIALKYLMALONYL DICHLORIDES WITH 1,3-DIAMINOPROPANES. A NEW ROUTE TO MACROCYCLIC POLYAMIDES AND POLYAMINES (1977) (0)
- NEW PROTECTIVE GROUPS FOR PEPTIDE SYNTHESIS. III. THE MAQ ESTER GROUP. MILD REDUCTIVE CLEAVAGE OF 2-ACYLOXYMETHYLENEANTHRAQUINONES (1977) (0)
- PROGRESS TOWARD A NOVAL C-TERMINAL HELIX CAPPING PRINCIPE : SYNTHESIS AND PROPERTIES OF (S)-ALPHA -(2-AMINOETHYL)-METHIONINE (1994) (0)
- Amino Acid Derivatives That Stabilize Secondary Structures of Polypeptides. Part 4. Practical Synthesis of 4‐(Alkylamino)‐3‐cyano‐6‐azabicyclo(3.2.1)oct‐3‐enes (Ben Derivatives) as γ‐Turn Templates. (1989) (0)
- THE PHYSICAL ORGANIC CHEMISTRY OF BENZISOXAZOLES, THE MECHANISM OF THE BASE-CATALYZED DECOMPOSITION OF BENZISOXAZOLES (1973) (0)
- MODELS THAT DEMONSTRATE PEPTIDE BOND FORMATION BY PRIOR THIOL CAPTURE. II. CAPTURE BY ORGANOMERCURY DERIVATIVES (1981) (0)
- A Convenient Preparation of Derivatives of 3(S)-Amino-10(R)-carboxy-1,6-diazacyclodeca-2,7-dione, the Dilactam of L-α,γ-Diaminobutyric Acid and D-Glutamic Acid: A β-Turn Template. (1989) (0)
- Abstract of papers for future publicationImmunochemical studies of angiotensin (1966) (0)
- Workbook to accompany organic chemistry (1980) (0)
- PEPTIDE SYNTHESIS WITH BENZISOXAZOLIUM SALTS PART 3, UTILITY OF 7-HYDROXY-2-ETHYLBENZISOXAZOLIUM FLUOROBORATE IN THE SYNTHESIS OF PEPTIDES (1975) (0)
- PEPTIDE SYNTHESIS WITH BENZISOXAZOLIUM SALTS PART 1, PROPERTIES OF SUBSTITUTED 2-ETHYL-BENZISOXAZOLIUM SALTS (1975) (0)
- THE SYNTHESIS OF 3,11‐DIMETHYL‐1,5,9,13‐TETRAAZATRICYCLO(9.5.1.13,9)OCTADECANE (1978) (0)
- Peptide Synthesis by Prior Thiol Capture. Part 2. Design of Templates for Intramolecular O,N-Acyl Transfer. 4,6-Disubstituted Dibenzofurans as Optimal Spacing Elements. (1986) (0)
- 310 Helix Nucleation with a Macrocyclic Triproline Template (1992) (0)
- Catalytic antibodies. How to promote proton transfer. (1995) (0)
- Stereoselective Decarboxylation of a Geminal Dicarboxylic Acid. Synthesis of cis-5-(Hydroxymethyl)-D-proline Derivatives. (1987) (0)
- Mild Reductive Cleavage of the 9-Anthracenesulfonamido Function. The 9-Anthracenesulfonyl (Ans) Group: A New Approach to the Protection of the Guanidino Function of Arginic Residues in Peptide Synthesis. (1988) (0)
- Practical preparation and deblocking conditions for N-alpha-(2-(p-biphenylyl)-2-propyloxycarbonyl)-amino acid (N-a-Bpoc-Xxx-OH) derivatives. (1988) (0)
- Amino Acid Derivatives that Stabilize Secondary Structures of Polypeptides. Part 3. β-Enaminonitriles as Analogs of Secondary Amides. The Mcc Group. 1-Acylamino-2-aminoalkyl-3-cyano-2-cyclopentenes as Amino Acid Analogs. (1988) (0)
- Antihrombogenic cellulose film. (1968) (0)
- NEW S-PROTECTION FROM KNOWN N-PROTECTION: THIO ESTERS OF N-URETHANYL-N-METHYL-Γ-AMINOBUTYRIC ACID AS A CLASS OF PROTECTIVE GROUPS FOR THIOLS IN PEPTIDE SYNTHESIS (1985) (0)
- THE JOURKAL OF Organic Chemistry (1979) (0)
- Qualitative organic microanalysis: by Frank L. Schneider. 535 pages, diagrams, 612 × 912 in. New York, Academic Press, Inc., 1964. Price, $22.50 (1966) (0)
- AN ANOMALOUS NEBER REACTION, A GENERAL METHOD FOR THE PREPARATION OF 3-CARBOXY-1-NAPHTHYLAMINES (1975) (0)
- RATE CONSTANTS FOR PEPTIDE P-NITROPHENYL ESTER COUPLING REACTIONS IN DIMETHYLFORMAMIDE, A MODEL FOR STERIC INTERACTIONS IN THE PEPTIDE BOND FORMING TRANSITION STATE (1975) (0)
- SYNTHESIS OF 1,5‐DIAZACYCLOOCTANES FROM 2,4,6,8‐TETRAKETO‐1,5‐DIAZABICYCLO(3,3,0)OCTANES (1978) (0)
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