David Hodgson
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British chemist
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David Hodgson chemistry Degrees
Chemistry
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Organic Chemistry
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Chemistry
David Hodgson 's Degrees
- PhD Chemistry University of Oxford
- Masters Chemical Engineering Imperial College London
Why Is David Hodgson Influential?
(Suggest an Edit or Addition)According to Wikipedia, David Michael Hodgson is the Todd Fellow and Tutor in Chemistry at Oriel College, Oxford. Hodgson achieved his Bachelor of Science at the University of Bath and gained his Doctor of Philosophy from the University of Southampton. His research interests are in synthesis, broadly encompassing studies directed towards the design and development of new methods, reagents and strategies for the synthesis of biologically active molecules.
David Hodgson 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Enantioselective desymmetrisation of achiral epoxides (1996) (264)
- Catalytic enantioselective rearrangements and cycloadditions involving ylides from diazo compounds (2001) (247)
- Organolithiums in enantioselective synthesis (2003) (78)
- Development of dirhodium(II)-catalyzed generation and enantioselective 1,3-dipolar cycloaddition of carbonyl ylides. (2001) (77)
- Recent Developments in the Chemistry of Lithiated Epoxides (2002) (70)
- Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition (1997) (67)
- The scope of catalytic enantioselective tandem carbonyl ylide formation-intramolecular [3 + 2] cycloadditions. (2003) (66)
- Intramolecular cyclopropanation of unsaturated terminal epoxides and chlorohydrins. (2007) (58)
- Highly chemo- and stereoselective intermolecular coupling of diazoacetates to give cis-olefins by using Grubbs second-generation catalyst. (2007) (57)
- Lithiation-electrophilic substitution of N-thiopivaloylazetidine. (2010) (54)
- Intramolecular cyclopropanation of unsaturated terminal epoxides. (2004) (52)
- Catalytic enantioselective [3 + 2]-cycloadditions of diazoketone-derived aryl-substituted carbonyl ylides. (2003) (51)
- Stereoselective synthesis of β-(hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones. (2011) (47)
- Catalytic enantioselective intermolecular cycloadditions of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkene dipolarophiles. (2004) (46)
- Widening the usefulness of epoxides and aziridines in synthesis (2007) (46)
- Efficient RhII binaphthol phosphate catalysts for enantioselective intramolecular tandem carbonyl ylide formation–cycloaddition of α-diazo-β-keto esters (1999) (46)
- Isomerisations of cycloalkene- and bicycloalkene-derived achiral epoxides by enantioselective α-deprotonation (1998) (45)
- Functionalised bicyclic alcohols by enantioselective α-deprotonation–rearrangement of meso-epoxides (2001) (43)
- Rh(II)-binaphthol phosphate catalysts in the enantioselective intramolecular oxonium ylide formation–[3,2] sigmatropic rearrangement of α-diazo-β-ketoesters (2001) (42)
- 2-Ene-1,4-diols by dimerization of terminal epoxides using hindered lithium amides. (2005) (41)
- Consecutive alkene cross-metathesis/oxonium ylide formation-rearrangement: synthesis of the anti-HIV agent hyperolactone C. (2008) (40)
- Selectivity in the cycloadditions of carbonyl ylides with glyoxylates: an approach to the zaragozic acids—squalestatins (2000) (40)
- Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. (2007) (38)
- Recent applications in natural product synthesis of dihydrofuran and -pyran formation by ring-closing alkene metathesis. (2016) (38)
- Enamines from terminal epoxides and hindered lithium amides. (2004) (37)
- First Direct Deprotonation−Electrophile Trapping of Simple Epoxides: Synthesis of α,β-Epoxysilanes from Terminal Epoxides (2001) (36)
- Dimerization and Isomerization Reactions of α-Lithiated Terminal Aziridines (2007) (35)
- Concise racemic and highly enantioselective approaches to key intermediates for the syntheses of carbocyclic nucleosides and pseudo-ribofuranoses: formal syntheses of carbovir (1994) (35)
- Stereocontrolled syntheses of the nemorensic acids using 6-diazoheptane-2,5-dione in carbonyl ylide cycloadditions. (2004) (35)
- Stereocontrolled syntheses of (-)-cubebol and (-)-10-epicubebol involving intramolecular cyclopropanation of alpha-lithiated epoxides. (2010) (35)
- Substituted aziridines by lithiation-electrophile trapping of terminal aziridines. (2005) (34)
- Maleates from diazoacetates and dilactones from head-to-head dimerisation of alkenyl diazoacetates using Grubbs' 2nd-generation ruthenium carbene catalyst. (2005) (34)
- Methods for direct generation of α-alkyl-substituted aldehydes (2014) (34)
- Concise, stereoselective syntheses of cis-nemorensic acid and 4-hydroxy-cis-nemorensic acid via tandem carbonyl ylide formation-cycloaddition. (2002) (33)
- Amine protection/α-activation with the tert-butoxythiocarbonyl group: application to azetidine lithiation-electrophilic substitution. (2015) (32)
- Synthesis of the anti-HIV agent (-)-hyperolactone C by using oxonium ylide formation-rearrangement. (2011) (32)
- A CYCLOADDITION-REARRANGEMENT APPROACH TO THE SQUALESTATINS (1996) (31)
- Catalytic enantioselective intermolecular cycloadditions of a 2-diazo-3,6-diketoester-derived carbonyl ylide with alkyne and strained alkene dipolarophiles (2003) (30)
- Chromium(II)-based methods for carbon-carbon bond formation (1994) (29)
- The reactivity of epoxides with lithium 2,2,6,6-tetramethylpiperidide in combination with organolithiums or grignard reagents. (2007) (28)
- Expanding the Utility of Lithiated Epoxides and Aziridines in Synthesis (2006) (28)
- Enantioselective alkylative double ring opening of epoxides: synthesis of enantioenriched unsaturated diols and amino alcohols. (2002) (28)
- 6-Substituted 2-azabicyclo[2.2.1]hept-5-enes by nitrogen-directed radical rearrangement: synthesis of an epibatidine analogue with high binding affinity at the nicotinic acetylcholine receptor (2001) (28)
- Synthesis of alpha-kainic acid from a 7-azabicyclo[2.2.1]heptadiene by tandem radical addition-homoallylic radical rearrangement. (2005) (28)
- Chromium(II)-mediated synthesis of E-alkenylstannanes from aldehydes and Bu3SnCHBr2 (1992) (27)
- Asymmetric synthesis of alpha-alkylated aldehydes using terminal epoxide-derived chiral enamines. (2008) (27)
- Synthesis and C-alkylation of hindered aldehyde enamines. (2009) (26)
- Enantioselective α-deprotonation–rearrangement of meso-epoxides (1996) (26)
- Scope of the chromium(II)-mediated synthesis of E-alkenylstannanes from aldehydes and Bu3SnCHBr2 (1995) (26)
- [3+2] Cycloaddition reactions of arylacetylenes with carbonyl ylides derived from 1-aryl-1-diazohexane-2,5-diones (2002) (26)
- Mechanism and applications of lithium amide-induced asymmetric rearrangements of 4-substituted and 4,4-disubstituted cyclopentene oxides to cyclopentenols (1999) (26)
- One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester. (2006) (26)
- Enantioselective access to isoquinuclidines by tropenone desymmetrization and homoallylic radical rearrangement: synthesis of (+)-ibogamine. (2005) (26)
- A Stille cyclisation approach to (–)-periplanone-B: studies in alkene-selective ring-closing metathesis and an improved chromium(II)-mediated synthesis of (E)-alkenylstannanes from aldehydes (1999) (25)
- Functionalized bicyclo[3.3.0]octanes by enantioselective transannular desymmetrization. (2001) (25)
- Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Subsequent Rearrangement (2003) (25)
- Catalytic enantioselective tandem carbonyl ylide formation—intramolecular cycloaddition with unsaturated α-diazo-β,ε-diketo sulfones (2009) (25)
- Chromium( II )-mediated synthesis of vinylbis(silanes) from aldehydes and a study of acid- and base-induced reactions of the derived epoxybis(silanes): a synthesis of acylsilanes (1997) (24)
- Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine. (2008) (24)
- Regio- and stereo-selective reactions of trimethylsilyl-substituted allyl-chromium reagents with aldehydes (1992) (24)
- Convergent and stereoselective synthesis of trisubstituted E-alkenyl bromides and iodides via beta-oxido phosphonium ylides. (2008) (24)
- Generation and Electrophile Trapping of N-Boc-2-lithio-2-azetine: Synthesis of 2-Substituted 2-Azetines (2014) (24)
- One-carbon homologation of N-sulfonylaziridines to allylic amines using dimethylsulfonium methylide. (2005) (24)
- Studies towards a stereocontrolled synthesis of the tricarboxylate core of the zaragozic acids–squalestatins by a cycloaddition–rearrangement strategy (2000) (24)
- Highly enantioselective rearrangement of a meso-epoxide to an allyl alcohol for carbocyclic nucleoside synthesis: An internal alkoxide effect (1994) (23)
- Oxapolycycles from One-Pot Cross-Metathesis/Carbonyl Ylide Formation-Intramolecular Cycloaddition of α-Diazo-β-keto Esters (2006) (23)
- On the mechanism of base-induced rearrangements of epoxides to ketones: a formal synthesis of (S)-physoperuvine (1999) (23)
- Alkenes from terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide and organolithiums or grignard reagents. (2004) (23)
- ENANTIOSELECTIVE REARRANGEMENT OF EXO-NORBORNENE OXIDE TO NORTRICYCLANOL (1996) (23)
- Development of two processes for the synthesis of bridged azabicyclic systems: intermolecular radical addition-homoallylic rearrangements leading to 2-azanorborn-5-enes and neophyl-type radical rearrangements to 2-azabenzonorbornanes. (2003) (23)
- α-Lithiation-electrophile trapping of N-thiopivaloylazetidin-3-ol: stereoselective synthesis of 2-substituted 3-hydroxyazetidines. (2013) (23)
- Synthesis of (−)-xialenon A by enantioselective α-deprotonation-rearrangement of a meso-epoxide (2003) (23)
- Use of allene in 1,3-dipolar addition to a carbonyl ylide: syntheses of 3-hydroxy-cis-nemorensic acid and nemorensic acid. (2004) (23)
- ENANTIOSELECTIVE REARRANGEMENT OF EXO-NORBORNENE OXIDE TO NORTRICYCLANOL (1996) (23)
- Dimerization of lithiated terminal aziridines. (2006) (22)
- Improved Cr(II)-mediated synthesis of E-alkenyl-stannanes from aldehydes using Bu3SnCHI2 in DMF (1998) (22)
- Chemoselectivity in the chromium(II)-mediated synthesis of E-alkenylstannanes from aldehydes and Bu3SnCHBr2 (1994) (22)
- Terminal Aziridinesby Addition of Grignard Reagents or Organoceriums to an (α-Chloro)sulfinylimine (2009) (22)
- Chiral epoxides by desymmetrizing deprotonation of meso-epoxides. (2002) (22)
- Asymmetric synthesis of terminal N-tert-butylsulfinyl aziridines from organoceriums and an alpha-chloroimine. (2008) (21)
- Asymmetric rearrangement of N-Boc 7-azanorbornene oxide: use of aryllithiums for enantioselective deprotonation (1999) (21)
- Palladium-catalysed isomerisation of vinyldisilanes to allyldisilanes (2001) (21)
- 2-azabenzonorbornanes from 7-azabenzonorbornanols by a nitrogen-directed neophyl-type radical rearrangement. (2002) (21)
- An Epoxide Rearrangement - Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue (1998) (20)
- Stereocontrolled syntheses of kainoid amino acids from 7-azabicyclo[2.2.1]heptadienes using tandem radical addition-homoallylic radical rearrangement. (2005) (20)
- An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin (1997) (20)
- α- and α'-Lithiation-Electrophile Trapping of N-Thiopivaloyl and N-tert-Butoxythiocarbonyl α-Substituted Azetidines: Rationalization of the Regiodivergence Using NMR and Computation. (2015) (20)
- Organolithium-induced alkylative ring opening of aziridines: synthesis of unsaturated amino alcohols and ethers. (2006) (20)
- Pd/Cu Co-catalysed Cross-coupling Reactions of Methyl (Z)-2-Tributylstannyl-3-methoxypropenoate: a Method for Direct Introduction of the Agrochemically Important β-Methoxyacrylate Toxophore (1995) (20)
- Enantioselective alkylative double ring-opening of epoxides derived from cyclic allylic ethers: synthesis of enantioenriched unsaturated diols. (2003) (19)
- Chromium(II)-mediated nickel(II)-catalysed cyclisations of (iodoaryl)-substituted alkynes and alkynals (1994) (19)
- Organic Syntheses Based on Name Reactions and Unnamed Reactions (1995) (19)
- A new and enantioselective indolizidine synthesis by meso-epoxide α-deprotonation–transannular N–C insertion (1999) (19)
- Catalytic asymmetric synthesis of (+)-anthecotulide using enyne and Meyer-Schuster rearrangements. (2011) (19)
- Substituted alkenediols by alkylative double ring opening of dihydrofuran and dihydropyran epoxides. (2001) (19)
- Unsaturated 1,2-amino alcohols and ethers from aziridines and organolithiums. (2004) (19)
- Convergent synthesis of trisubstituted Z-allylic esters by Wittig-Schlosser reaction. (2010) (19)
- Ligand effects in the organolithium-mediated enantioselective α-deprotonation of achiral epoxides (1997) (19)
- Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides. (2003) (18)
- Metalated Epoxides and Aziridines in Synthesis (2006) (18)
- Synthesis of azabicyclic systems using nitrogen-directed radical rearrangements. (2007) (18)
- Intramolecular cyclopropanation of unsaturated terminal aziridines. (2006) (17)
- Synthesis and evaluation of 4,4', 6,6'-tetrasubstituted binaphtholphosphate dirhodium(II) complexes as catalysts in enantioselective carbonyl ylide formation-cycloaddition reactions (2003) (17)
- HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF QUATERNARY CARBON-CONTAINING MESO-EPOXIDES TO ALLYLIC ALCOHOLS (1996) (16)
- 3-Hydroxypyrrolidines from epoxysulfonamides and dimethylsulfoxonium methylide. (2006) (16)
- Straightforward synthesis of α,β-epoxysilanes from terminal epoxides by lithium 2,2,6,6-tetramethylpiperidide-mediated deprotonation-in situ silylation (2002) (16)
- On the possibility of carbamate-directed hydroboration. An approach to the asymmetric synthesis of 1-aminocyclopentane-1,3-dicarboxylic acid (1999) (16)
- HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF QUATERNARY CARBON-CONTAINING MESO-EPOXIDES TO ALLYLIC ALCOHOLS (1996) (16)
- Deprotonation-electrophile trapping of terminal epoxides. (2005) (15)
- syn-β-Hydroxyallylic silanes from terminal epoxide α-lithiation-silylation and alkenylation: application to the tetrahydrofuran portion of the lytophilippines. (2012) (15)
- Alkene Chemoselectivity in Ring-Closing Metathesis: A Formal Synthesis of (-)-Periplanone-B (1999) (15)
- Anomalous Nuclear Overhauser Effects in Carbon-Substituted Aziridines: Scalar Cross-Relaxation of the First Kind** (2015) (15)
- Epoxide opening-induced tandem 8-azabicyclo[3.2.1]octane to 6-azabicyclo[3.2.1]octane rearrangement-iminium allylation: synthesis of (+/-)-peduncularine. (2010) (14)
- Synthesis of (-)-6,7-Dideoxysqualestatin H5 by Carbonyl Ylide Cycloaddition-Rearrangement and Cross-electrophile Coupling. (2017) (14)
- Unsymmetrical maleates from stereoselective decomposition of diazoesters using Grubbs’ 2nd-generation Ru carbene catalyst (2006) (14)
- Cycloadditions of Carbonyl Ylides Derived from Diazocarbonyl Compounds (2013) (14)
- Carbamate-directed hydroboration: enantioselective synthesis of the excitatory amino acid 1-aminocyclopentane-1,3-dicarboxylic acid (1998) (14)
- Total Synthesis and Structural Revision of the Cytotoxin Aruncin B. (2016) (13)
- Overview of Organolithium-Ligand Combinations and Lithium Amides for Enantioselective Processes (2003) (13)
- Organolithium-induced synthesis of acyclic unsaturated amino alcohols from epoxides of dihydropyrroles and tetrahydropyridines (2003) (13)
- Organolithium-induced enantioselective alkylative double ring-opening of epoxides: synthesis of enantioenriched unsaturated amino alcohols (2004) (13)
- Substituted epoxides by lithiation of terminal epoxides. (2004) (13)
- C-alkylation of chiral tropane- and homotropane-derived enamines. (2013) (12)
- Synthetic and computational studies on the tricarboxylate core of 6,7-dideoxysqualestatin H5 involving a carbonyl ylide cycloaddition-rearrangement. (2010) (12)
- Unsaturated 1,2-Amino Alcohols from Dihydropyrrole Epoxides and Organolithiums (2002) (12)
- Chromium(II)-mediated synthesis of 1,1-bis(trimethylsilyl)alkenes from aldehydes and (Me3Si)2CBr2 (1994) (12)
- Radical deoxygenation of 3-azatricyclo[2.2.1.02,6]heptan-5-ols to 2-azabicyclo[2.2.1]hept-5-enes and 1,2-dihydropyridines (2009) (11)
- On the mechanism of lithium amide-induced rearrangements of 4-substituted cyclopentene oxides to cyclopentenols (1997) (11)
- Synthesis of the anti-trypanosomal agent (±)-hydroxyanthecotulide by Cr(ii)-catalysed allylation and Meyer-Schuster rearrangement. (2012) (11)
- Intramolecular cyclopropanation of epichlorohydrin-derived unsaturated chlorohydrins (2005) (10)
- α,β-Aziridinylphosphonates by lithium amide-induced phosphonyl migration from nitrogen to carbon in terminal aziridines (2010) (10)
- Intramolecular oxonium ylide formation-[2,3] sigmatropic rearrangement of diazocarbonyl-substituted cyclic unsaturated acetals: a formal synthesis of hyperolactone C. (2014) (10)
- Disubstituted Z-allylic esters by Wittig-Schlosser reaction using methylenetriphenylphosphorane. (2011) (10)
- One-step chromium(II)-mediated homologation of aldehydes to methyl ketones using Me3SiCBr3 (1994) (9)
- Studies on organolithium-induced alkylative desymmetrisation of epoxides: synthesis of enantioenriched β-amino cycloheptenols from 6,7-epoxy-8-azabicyclo[3.2.1]octanes ☆ (2004) (9)
- A remarkable base-induced rearrangement of epoxydisilanes (1996) (9)
- Synthesis and Homologation of an Azetidin-2-yl Boronic Ester with α-Lithioalkyl Triisopropylbenzoates. (2019) (9)
- Enantioselective total synthesis of (-)-xialenon A. (2002) (9)
- AN EFFICIENT MEDIUM-RING CYCLISATION APPROACH TO THE GERMACRANES (1995) (9)
- A short and efficient synthesis of the C-3 to C-10 portion of the maytansinoids (1991) (9)
- Enantioselective intramolecular 1,3-dipolar cycloadditions of diazocarbonyl-derived oxidopyryliums (2003) (8)
- 2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition—homoallylic radical rearrangement (2001) (8)
- Enantioselective rearrangements of bicyclo[2.2.1]- and bicyclo[2.2.2]alkene-derived achiral epoxides to ketones (1997) (7)
- Syntheses of (±)-α-Isokainic Acid and (±)-α-Dihydroallokainic Acid Using a Decarboxylative Ramberg-Bäcklund Reaction (2005) (7)
- On the ozonolysis of unsaturated tosylhydrazones as a direct approach to diazocarbonyl compounds. (2018) (7)
- An approach to hyperolactone C and analogues using late stage conjugate addition on an oxonium ylide-derived spirofuranone. (2013) (7)
- Synthesis and reactivity of lithiated γ-functionalised ketene dithioacetals. Generation of a flexible β-lithioacrylate equivalent (1988) (7)
- Asymmetric Induction in C-Alkylation of Tropane-Derived Enamines: Congruence Between Computation and Experiment. (2017) (6)
- Transition states and origins of 1,4-asymmetric induction in alkylations of 2,2,6-trialkylpiperidine enamines. (2010) (6)
- Highly Enantioenriched 2-Azabenzonorbornenes from 7-Azabenzonorbornadienes by Asymmetric Hydroboration-Oxidation and Tandem Deoxygenation-Rearrangement-Electrophile Trapping (2006) (6)
- Regio- and stereo-specific synthesis of cis-(±)-1-acetoxy-4-(acetoxymethyl)cyclopent-2-ene : a key intermediate in the synthesis of carbocyclic nucleosides and pseudo-ribofuranoses (1993) (5)
- BASE-INDUCED REARRANGEMENTS OF BICYCLO2.2.1 AND BICYCLO2.2.2ALKENE-DERIVEDEPOXIDES TO KETONES AND ALCOHOLS (1997) (5)
- Vinyldisilanes as masked acylsilanes (1996) (5)
- Alkene protection against acid using a bromide substituent: application in a total synthesis of (-)-6,7-dideoxysqualestatin H5. (2018) (5)
- Radical deoxygenation of 3-azatricyclo[2.2.1.02,6]heptan-5-ols to 1,2-dihydropyridines (2005) (5)
- Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis (2008) (4)
- Extended Scope of Dirhodium(II)-Catalysed Enantioselective Intramolecular 1,3-Dipolar Cycloadditions of Carbonyl Ylides with Alkene and Alkyne Dipolarophiles (2002) (4)
- Convergent and Stereoselective Synthesis of Trisubstituted (E)-Alkenyl Bromides and Iodides via β-Oxido Phosphonium Ylides. (2009) (4)
- Thieme Chemistry Journal Awardees - WhereAre They Now? Synthesis of (-)-Cubebol by IntramolecularCyclopropanation of a Terminal Epoxide (2009) (4)
- The Scope of Catalytic Enantioselective Tandem Carbonyl Ylide Formation—Intramolecular [3 + 2] Cycloadditions. (2003) (4)
- UNUSUAL BASE-INDUCED REARRANGEMENT OF EXO-9-OXABICYCLO〔4.2.1〕NON-7-ENE OXIDE TO EXO-8-HYDROXYBICYCLO〔3.3.0〕OCTAN-2-ONE (Dedicated to Dr. Albert Padwa on his 75th birthday) (2012) (4)
- Aruncin B: Synthetic Studies, Structural Reassignment and Biological Evaluation (2017) (4)
- Epoxydisilanes by direct double silylation of terminal epoxides (2004) (4)
- Aldehyde and Ketone Functions Further Substituted on Oxygen (2005) (3)
- Enantioselective Desymmetrization of Achiral Epoxides (1997) (3)
- Organolithium-Induced Synthesis of Unsaturated Diols from Epoxides of Dihydrofurans and Dihydropyrans (2002) (3)
- Scope of the Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2. (1995) (2)
- Alkylation of lithiated dimethyl tartrate acetonide with unactivated alkyl halides and application to an asymmetric synthesis of the 2,8-dioxabicyclo[3.2.1]octane core of squalestatins/zaragozic acids (2019) (2)
- 1.04 – Oxiranes and Oxirenes: Fused-ring Derivatives (2008) (2)
- Stereospecific α-Deprotonation of N-ProtectedAziridines (2008) (2)
- On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid (2018) (2)
- Convergent synthesis of conjugated 1,2-disubstituted E-allylic alcohols from two aldehydes and methylenetriphenylphosphorane. (2012) (2)
- Generation and Electrophile Trapping of N‐Boc‐2‐lithio‐2‐azetine: Synthesis of 2‐Substituted 2‐Azetines. (2014) (2)
- Electrophile dependent mechanisms in the asymmetric trapping of α-lithio-N-(tert-butoxythiocarbonyl)azetidine. (2020) (2)
- Organolithiums and Lithium 2,2,6,6-Tetramethylpiperidide in Reductive Alkylation of Epoxides: Synthesis of (E)-Alkenes [(E)-2-Methyltetradeca-1,3-Diene] (2008) (2)
- Squarate desymmetrisation–ozonolysis as an approach to β-substituted-α-ketosuccinates and squalestatin synthesis (2019) (2)
- Oxiranes and Oxirenes: Fused-Ring Derivatives (2021) (2)
- Enantioselective desymmetrisation of an epoxytropinone for peduncularine synthesis (2020) (2)
- Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine (2012) (2)
- A short and efficient synthesis of a key intermediate for maytansinoid construction (1988) (1)
- Terminal Aziridines by α-Deprotonation/Electrophile Trapping of N-Protected Aziridine. (2008) (1)
- Chromium(II)‐Mediated and ‐Catalyzed C‐C Coupling Reactions (2008) (1)
- Asymmetric Synthesis of Terminal N-tert-Butylsulfinyl Aziridines from Organoceriums and an α-Chloroimine. (2008) (1)
- Reactions involving metallocarbenes (1991) (1)
- Evolution of a Cycloaddition–Rearrangement Approach to the Squalestatins: A Quarter-Century Odyssey (2020) (1)
- Alkene Ozonolysis in the Presence of Diazo Functionality: Accessing an Intermediate for Squalestatin Synthesis (2019) (1)
- Convergent Synthesis of Trisubstituted Z-Allylic Esters by Wittig—Schlosser Reaction. (2011) (1)
- Chromium(II)-Mediated Nickel(II)-Catalyzed Cyclizations of (Iodoaryl)- Substituted Alkynes and Alkynals (1994) (1)
- Oxidation with Selenium Reagents (2008) (1)
- An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin. (1997) (1)
- The Reactivity of Epoxides with Lithium 2,2,6,6‐Tetramethylpiperidide in Combination with Organolithiums or Grignard Reagents. (2007) (1)
- A Remarkable Base-Induced Rearrangement of Epoxydisilanes. (1996) (1)
- Alkene Chemoselectivity in Ring-Closing Metathesis: A Formal Synthesis of (-)-Periplanone-B. (1999) (1)
- CCDC 817384: Experimental Crystal Structure Determination (2011) (0)
- Deprotonation—Electrophile Trapping of Terminal Epoxides. (2005) (0)
- Comment on gc-2021-37 (2021) (0)
- Enantioselective α-Deprotonation-Rearrangement of meso-Epoxides. (1996) (0)
- Addition of Other Organometallic Reagents (2008) (0)
- Selectivity in the Cycloadditions of Carbonyl Ylides with Glyoxylates: An Approach to the Zaragozic Acids—Squalestatins. (2001) (0)
- A Stille Cyclization Approach to (‐)‐Periplanone‐B: Studies in Alkene‐Selective Ring‐Closing Metathesis and an Improved Chromium(II)‐Mediated Synthesis of (E)‐Alkenylstannanes from Aldehydes. (2000) (0)
- Addition of Organometallic Reagents to Vinyl Epoxides (2008) (0)
- Enantioselective Rearrangements of Bicyclo(2.2.1)- and Bicyclo(2.2.2) alkene-Derived Achiral Epoxides to Ketones. (1997) (0)
- Rearrangement of Sulfoxides (2008) (0)
- With Less Than a Stoichiometric Amount of Selenium Dioxide (2008) (0)
- 1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Other Reagents (2008) (0)
- Extended Scope of Dirhodium(II)-Catalyzed Enantioselective Intramolecular 1,3-Dipolar Cycloadditions of Carbonyl Ylides with Alkene and Alkyne Dipolarophiles. (2003) (0)
- Additions to α-Epoxy Hydrazones (2008) (0)
- Cr- and Ti-Mediated Synthesis of Alkenes from Carbonyl Compounds (1997) (0)
- Substituted Aziridines by Lithiation—Electrophile Trapping of Terminal Aziridines. (2005) (0)
- Cr(II)-Mediated C-C Coupling Reactions (1999) (0)
- With a Catalytic Amount of Selenium Dioxide (2008) (0)
- Unusual Base‐Induced Rearrangement of exo‐9‐Oxabicyclo[4.2.1]non‐7‐ene Oxide to exo‐8‐Hydroxybicyclo[3.3.0]octan‐2‐one. (2012) (0)
- Highly Chemo- and Stereoselective Intermolecular Coupling of Diazoacetates to Give cis-Olefins by Using Grubbs′ Second-Generation Catalyst. (2007) (0)
- New process for production of beta-alkoxyacrylic (1994) (0)
- Reduction of Unactivated Epoxy Alcohols (2008) (0)
- Hodgson Review (2018) (0)
- Towards the development of direct methodology to enantioenriched α-alkylated aldehydes (2013) (0)
- Nonenzymatic Resolution of Allylic Alcohols (2008) (0)
- Rearrangement of Epoxides Using Lithium Amides (2008) (0)
- Terminal Aziridines by Addition of Grignard Reagents or Organoceriums to an (α-Chloro)sulfinylimine. (2009) (0)
- Concise Racemic and Highly Enantioselective Approaches to Key Intermediates for the Syntheses of Carbocyclic Nucleosides and pseudo- Ribofuranoses: Formal Syntheses of Carbovir. (1995) (0)
- Asymmetric Copper-Catalyzed Alkenylations of Carbonyl Compounds (2008) (0)
- A process for the preparation of compounds derived from beta-alkoxy-acrylic acid (1994) (0)
- 1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Boron Reagents (2008) (0)
- Dibromomethyl(tributyl)stannane (2004) (0)
- Asymmetric Iridium-Catalyzed Substitutions of Allylic Carbonates (2008) (0)
- Synthesis of β-(Hydroxymethylaryl/alkyl)-α-methylene-γ-butyrolactones (2011) (0)
- Synthesis and Reactivity of Lithiated γ-Functionalized Ketene Dithioacetals. Generation of a Flexible β-Lithioacrylate Equivalent. (1989) (0)
- Mechanism and Applications of Lithium Amide‐Induced Asymmetric Rearrangements of 4‐Substituted and 4,4‐Disubstituted Cyclopentene Oxides to Cyclopentenols. (2000) (0)
- Enantioselective Rearrangement of exo‐Norbornene Oxide to Nortricyclanol. (1996) (0)
- Alkenes from Terminal Epoxides Using Lithium 2,2,6,6‐Tetramethylpiperidide and Organolithiums or Grignard Reagents. (2005) (0)
- Regio- and Stereoselective Reactions of Trimethylsilyl-Substituted Allyl-Chromium Reagents with Aldehydes. (2010) (0)
- Transition-Metal-Catalyzed Alkenylation of Carbonyl Compounds (2008) (0)
- Disubstituted Z‐Allylic Esters by Wittig—Schlosser Reaction Using Methylenetriphenylphosphorane. (2011) (0)
- A Short and Efficient Synthesis of the C‐3 to C‐10 Portion of the Maytansinoids. (1991) (0)
- Highly Enantioenriched 2-Azabenzonorbornenes from 7-Azabenzonorbornadienes by Asymmetric Hydroboration—Oxidation and Tandem Deoxygenation—Rearrangement—Electrophile Trapping. (2007) (0)
- Corrigendum to: “Studies on organolithium-induced alkylative desymmetrisation of epoxides: synthesis of enantioenriched β-amino cycloheptenols from 6,7-epoxy-8-azabicyclo[3.2.1]octanes” [Tetrahedron 60 (2004) 5185] (2004) (0)
- Correction to: On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid (2018) (0)
- Synthesis of Azabicyclic Systems Using Nitrogen‐Directed Radical Rearrangements (2008) (0)
- Synthesis of 2-Substituted 2-Azetines by Lithiation of N-Boc-2-azetines (2014) (0)
- Methods for Direct Generation of α‐Alkyl‐substituted Aldehydes (2014) (0)
- Reactions of Epoxides with LiTMP and Organolithium or Grignard Reagents (2007) (0)
- Synthesis of Product Class 5 (2008) (0)
- Highly Enantioselective Rearrangement of Quaternary Carbon-Containing meso-Epoxides to Allylic Alcohols. (1996) (0)
- An Epoxide Rearrangement — Radical Rearrangement Approach to 6‐Substituted 2‐Azabicyclo[2.2.1]‐5‐heptenes: Synthesis of an Epibatidine Analogue. (1999) (0)
- Addition of Organolithium Reagents to Epoxides (2008) (0)
- Efficient Medium‐Ring Cyclization Approach to the Germacranes. (1995) (0)
- Chromium(II)‐Mediated CC Coupling Reactions (2008) (0)
- Reduction of Sulfonylated Epoxy Alcohols (2008) (0)
- Using Catalytic Chiral Lithium Amides (2008) (0)
- Highly Enantioselective Rearrangement of a meso‐Epoxide to an Allyl Alcohol for Carbocyclic Nucleoside Synthesis: An Internal Alkoxide Effect. (1994) (0)
- Allylic alcohols and amines by carbenoid eliminative cross-coupling using epoxides or aziridines (2021) (0)
- 6-Substituted 2-Azabicyclo[2.2.1]hept-5-enes by Nitrogen-Directed Radical Rearrangement: Synthesis of an Epibatidine Analogue (VIII) with High Binding Affinity at the Nicotinic Acetylcholine Receptor. (2010) (0)
- Rh(II)-Binaphthol Phosphate Catalysts in the Enantioselective Intramolecular Oxonium Ylide Formation—[3,2] Sigmatropic Rearrangement of α-Diazo-β-ketoesters. (2001) (0)
- Chromium(II)‐Mediated Synthesis of 1,1‐Bis(trimethylsilyl)alkenes from Aldehydes and (Me3Si)2CBr2. (1995) (0)
- Organolithium‐Ligand Combinations and Lithium Amides for Enantioselective Processes (2003) (0)
- Reduction of α-Halo Epoxides (2008) (0)
- Using Nonenantioselective Boron Reagents (2008) (0)
- Unsaturated 1,2‐Amino Alcohols from Dihydropyrrole Epoxides and Organolithiums. (2002) (0)
- Convergent Synthesis of Conjugated 1,2‐Disubstituted E‐Allylic Alcohols from Two Aldehydes and Methylenetriphenylphosphorane. (2013) (0)
- Sharpless Asymmetric Epoxidation (2008) (0)
- Stereoselective Synthesis of β-(Hydroxymethylaryl/alkyl) -α-methylene-γ-butyrolactones. (2011) (0)
- Epoxydisilanes by Direct Double Silylation of Terminal Epoxides. (2004) (0)
- Isomerizations of Cycloalkene- and Bicycloalkene-Derived Achiral Epoxides by Enantioselective α-Deprotonation. (1998) (0)
- Efficient RhII Binaphthol Phosphate Catalysts for Enantioselective Intramolecular Tandem Carbonyl Ylide Formation—Cycloaddition of α‐Diazo‐β‐keto Esters. (2000) (0)
- Using Organotitanium Reagents (2008) (0)
- Dimerization and Isomerization Reactions of α-Lithiated Terminal Aziridines. (2008) (0)
- 1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Aluminum Hydride Reagents (2008) (0)
- One‐Carbon Homologation of N‐Sulfonylaziridines to Allylic Amines Using Dimethylsulfonium Methylide. (2005) (0)
- Palladium‐Catalyzed Isomerization of Vinyldisilanes to Allyldisilanes. (2001) (0)
- 2-Azabicyclo[2.2.1]hept-5-enes from 7-Azabicyclo[2.2.1]heptadienes by Tandem Intermolecular Radical Addition—Homoallylic Radical Rearrangement. (2001) (0)
- Use of Allene in 1,3‐Dipolar Addition to a Carbonyl Ylide: Syntheses of 3‐Hydroxy‐cis‐nemorensic Acid and Nemorensic Acid. (2004) (0)
- Rearrangement of Epoxides Using Other Reagents (2008) (0)
- 1,2-Reduction of α,β-Unsaturated Carbonyl Compounds Using Ruthenium Catalysts (2008) (0)
- Substitution of Allylic Halides (2008) (0)
- Carbamate-Directed Hydroboration: Enantioselective Synthesis of the Excitatory Amino Acid 1-Aminocyclopentane-1,3-dicarboxylic Acid. (2010) (0)
- Synthesis of the Antitrypanosomal Agent (.+-.)-Hydroxyanthecotulide by Cr(II)-Catalyzed Allylation and Meyer—Schuster Rearrangement. (2012) (0)
- Vinyldisilanes as Masked Acylsilanes. (1996) (0)
- Recent Applications in Natural Product Synthesis of Dihydrofuran and ‐pyran Formation by Ring‐Closing Alkene Metathesis (2016) (0)
- Diiodomethyl(tri‐N‐butyl)stannane (2004) (0)
- Using Nonenantioselective Aluminum Hydride Reagents (2008) (0)
- 3‐Hydroxypyrrolidines from Epoxysulfonamides and Dimethylsulfoxonium Methylide. (2006) (0)
- Using Grignard Reagents (2008) (0)
- Asymmetric Synthesis of α‐Alkylated Aldehydes Using Terminal Epoxide‐Derived Chiral Enamines. (2009) (0)
- Consecutive Alkene Cross-Metathesis/Oxonium Ylide Formation—Rearrangement: Synthesis of the anti-HIV Agent Hyperolactone C. (2009) (0)
- Straightforward Synthesis of α,β-Epoxysilanes from Terminal Epoxides by Lithium 2,2,6,6-Tetramethylpiperidide-Mediated Deprotonation-in situ Silylation. (2003) (0)
- Lithiation—Electrophilic Substitution of N-Thiopivaloylazetidine. (2010) (0)
- Lithiated azetidine and azetine chemistry (2014) (0)
- Studies towards the stereoselective synthesis of alkenes (2011) (0)
- Oxapolycycles from One‐Pot Cross‐Metathesis/Carbonyl Ylide Formation—Intramolecular Cycloaddition of α‐Diazo‐β‐keto Esters. (2007) (0)
- Addition of Organozinc Reagents (2008) (0)
- A Cycloaddition-Rearrangement Approach to the Squalestatins. (1996) (0)
- Rich Chemistry of α-Lithiated Epoxides and Aziridines (2011) (0)
- Elimination Reactions of Iodo Ketals (2008) (0)
- Other Methods of Nonenzymatic Resolution (2008) (0)
- First direct deprotonation-electrophile trapping of simple epoxides: synthesis of alpha,beta-epoxysilanes from terminal epoxides. (2001) (0)
- First Direct Deprotonation—Electrophile Trapping of Simple Epoxides: Synthesis of α,β‐Epoxysilanes from Terminal Epoxides. (2001) (0)
- A New and Enantioselective Indolizidine Synthesis by meso‐Epoxide α‐Deprotonation—Transannular N—C Insertion. (1999) (0)
- Amine Protection/α-Activation with the tert-Butoxythiocarbonyl Group: Application to Azetidine Lithiation—Electrophilic Substitution. (2015) (0)
- Addition of Grignard Reagents (2008) (0)
- Chromium(II)-Mediated Synthesis of E-Alkenylstannanes from Aldehydes and Bu3SnCHBr2. (1993) (0)
- NOUVEAU PROCEDE DE PREPARATION D'ACIDE β-ALCOXY ACRYLIQUE (1994) (0)
- Using Stoichiometric Chiral Lithium Amides (2008) (0)
- Using Achiral Lithium Amides (2008) (0)
- One-Step Chromium(II)-Mediated Homologation of Aldehydes to Methyl Ketones Using Me3SiCBr3. (1994) (0)
- Using Organolithium Reagents (2008) (0)
- Asymmetric synthesis of α-alkylated aldehydes using chiral enamines (2008) (0)
- Synthesis of (-)-Cubebol (2010) (0)
- Chiral Epoxides by Desymmetrizing Deprotonation of meso‐Epoxides. (2002) (0)
- 2‐Ene‐1,4‐diols by Dimerization of Terminal Epoxides Using Hindered Lithium Amides. (2005) (0)
- One‐Pot Cross‐Metathesis/Tandem Carbonyl Ylide Formation — Intramolecular Cycloaddition of an Unsaturated 2‐Diazo‐3,6‐diketoester. (2006) (0)
- Using Chiral Boron Reagents (2008) (0)
- Epoxide Opening‐Induced Tandem 8‐Azabicyclo[3.2.1]octane to 6‐Azabicyclo[3.2.1]octane Rearrangement—Iminium Allylation: Synthesis of (.+‐.)‐Peduncularine. (2010) (0)
- Rhenium-Catalyzed Rearrangements (2008) (0)
- Correction to Synthesis of (-)-6,7-Dideoxysqualestatin H5 by Carbonyl Ylide Cycloaddition-Rearrangement and Cross-electrophile Coupling. (2018) (0)
- Synthesis of (-)-Xialenon A (I) by Enantioselective α-Deprotonation-Rearrangement of a meso-Epoxide. (2004) (0)
- Additions of Metalated Selenoxides (2008) (0)
- The chromium(II)-mediated synthesis of E-alkenylstannanes from aldehydes and their application in synthesis (1995) (0)
- Base‐Induced Rearrangements of Bicyclo(2.2.1) and Bicyclo(2.2.2)alkene‐ Derived Epoxides to Ketones and Alcohols. (1997) (0)
- Palladium-Catalyzed Eliminations (2008) (0)
- A One-Pot Protocol for the Divergent Synthesis of Dihydrofuranones (2009) (0)
- Improved Cr(II)‐Mediated Synthesis of E‐Alkenylstannanes from Aldehydes Using Bu3SnCHI2 in DMF. (1998) (0)
- Catalytic Enantioselective [3 + 2]‐Cycloadditions of Diazoketone‐Derived Aryl‐Substituted Carbonyl Ylides. (2003) (0)
- Oxidation of Chiral Allylic Selenides (2008) (0)
- Asymmetric Nickel-Catalyzed Alkenylation of Carbonyl Compounds (2008) (0)
- Organolithium‐Induced Synthesis of Acyclic Unsaturated Amino Alcohols from Epoxides of Dihydropyrroles and Tetrahydropyridines. (2004) (0)
- Alkenylation of Carbonyl Compounds (2008) (0)
- Carbenes and Nitrenes (2005) (0)
- Using Chiral Ruthenium Catalysts (2008) (0)
- Catalytic Enantioselective Intermolecular Cycloadditions of a 2-Diazo-3,6-diketoester-Derived Carbonyl Ylide with Alkyne and Strained Alkene Dipolarophiles. (2003) (0)
- Pd/Cu Co-Catalyzed Cross-Coupling Reactions of Methyl (Z)-2- Tributylstannyl-3-methoxypropenoate: A Method for Direct Introduction of the Agrochemically Important β-Methoxyacrylate Toxophore. (1995) (0)
- Elimination of Allylic Cyclic Carbonates (2008) (0)
- Towards the synthesis of anthecularin and anthecotulides (2011) (0)
- Using Organozinc Reagents (2008) (0)
- Using Chiral Aluminum Reagents (2008) (0)
- Addition of Organolithium Reagents (2008) (0)
- Chemoselectivity in the Chromium(II)-Mediated Synthesis of E- Alkenylstannanes from Aldehydes and Bu3SnCHBr2. (2010) (0)
- Reduction of 2,3-Epoxy Alcohols (2008) (0)
- α-Lithiation—Electrophile Trapping of N-Thiopivaloylazetidin-3-ol: Stereoselective Synthesis of 2-Substituted 3-Hydroxyazetidines. (2013) (0)
- Chromium(II)-Mediated Synthesis of Vinylbis(silanes) from Aldehydes and a Study of Acid- and Base-Induced Reactions of the Derived Epoxybis(silanes): A Synthesis of Acylsilanes. (2010) (0)
- Elimination of β-Hydroxy Selenides (2008) (0)
- With Transition Metals (2008) (0)
- CCDC 612535: Experimental Crystal Structure Determination (2017) (0)
- Reduction of Propargylic Alcohols to -Alk-2-enols (2008) (0)
- Dimerization and isomerization reactions of alpha-lithiated terminal aziridines. (2007) (0)
- Using Organochromium Reagents (2008) (0)
- Acid-Mediated Rearrangements (2008) (0)
- Using Nonenantioselective Ruthenium Catalysts (2008) (0)
- Reduction of Epoxides with Samarium(II) Iodide (2008) (0)
- Maleates from Diazoacetates and Dilactones from Head-to-Head Dimerization of Alkenyl Diazoacetates Using Grubbs′ 2nd-Generation Ruthenium Carbene Catalyst. (2006) (0)
- Functionalized Bicyclic Alcohols by Enantioselective α‐Deprotection—Rearrangement of meso‐Epoxides. (2002) (0)
- Correction to: On the Prins reaction of terminal olefins and formaldehyde in trifluoroacetic acid (2018) (0)
- Elimination of α-Epoxystannanes (2008) (0)
- Additions of Organometallic Reagents to α,β-Unsaturated Carbonyl Compounds (2008) (0)
- Regio- and Stereospecific Synthesis of cis-(.+-.)-1-Acetoxy-4-( acetoxymethyl)cyclopent-2-ene: A Key Intermediate in the Synthesis of Carbocyclic Nucleosides and pseudo-Ribofuranoses. (1993) (0)
- Achiral Catalytic Alkenylations of Carbonyl Compounds (2008) (0)
- An Approach to Hyperolactone C and Analogues Using Late Stage Conjugate Addition on an Oxonium Ylide‐Derived Spirofuranone. (2013) (0)
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