David MacMillan
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British chemist
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David MacMillanchemistry Degrees
Chemistry
#274
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#547
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Organic Chemistry
#63
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#93
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Chemistry
David MacMillan's Degrees
- Bachelors Chemistry University of Oxford
- PhD Chemistry University of Oxford
Why Is David MacMillan Influential?
(Suggest an Edit or Addition)According to Wikipedia, Sir David William Cross MacMillan is a Scottish chemist and the James S. McDonnell Distinguished University Professor of Chemistry at Princeton University, where he was also the chair of the Department of Chemistry from 2010 to 2015. He shared the 2021 Nobel Prize in Chemistry with Benjamin List "for the development of asymmetric organocatalysis". MacMillan used his share of the $1.14 million prize to establish the May and Billy MacMillan Foundation.
David MacMillan's Published Works
Published Works
- Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis. (2013) (5164)
- The advent and development of organocatalysis (2008) (1691)
- Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes (2008) (1575)
- Photoredox Catalysis in Organic Chemistry (2016) (1463)
- The merger of transition metal and photocatalysis (2017) (1075)
- New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels−Alder Reaction (2000) (1052)
- Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis (2011) (939)
- Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp3-carbons with aryl halides (2014) (832)
- Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development. (2012) (776)
- Enantioselective alpha-trifluoromethylation of aldehydes via photoredox organocatalysis. (2009) (708)
- Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity (2011) (653)
- Modern strategies in organic catalysis: The advent and development of iminium activation (2006) (574)
- Enantioselective organocatalytic reductive amination. (2006) (547)
- Enantioselective organo-cascade catalysis. (2005) (540)
- Collective synthesis of natural products by means of organocascade catalysis (2011) (525)
- The first direct and enantioselective cross-aldol reaction of aldehydes. (2002) (512)
- Enantioselective organocatalytic indole alkylations. Design of a new and highly effective chiral amine for iminium catalysis. (2002) (429)
- Alcohols as alkylating agents in heteroarene C–H functionalization (2015) (426)
- Enantioselective α-benzylation of aldehydes via photoredox organocatalysis. (2010) (411)
- The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes (2003) (393)
- Enantioselective organocatalytic transfer hydrogenation reactions using Hantzsch esters. (2007) (390)
- New strategies in organic catalysis: the first enantioselective organocatalytic Friedel-Crafts alkylation. (2001) (379)
- Enantioselective Organocatalysis Using SOMO Activation (2007) (375)
- Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds. (2011) (373)
- Photoredox Activation for the Direct &bgr;-Arylation of Ketones and Aldehydes (2013) (373)
- Native functionality in triple catalytic cross-coupling: sp3 C–H bonds as latent nucleophiles (2016) (363)
- Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore (2014) (357)
- Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin (2014) (352)
- Enantioselective organocatalytic hydride reduction. (2005) (350)
- Enantioselective organocatalytic construction of pyrroloindolines by a cascade addition-cyclization strategy: synthesis of (-)-flustramine B. (2004) (346)
- New Strategies for Organic Catalysis: The First Enantioselective Organocatalytic 1,3-Dipolar Cycloaddition (2000) (343)
- Switching on Elusive Organometallic Mechanisms with Photoredox Catalysis (2015) (333)
- Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis. (2016) (327)
- The First General Enantioselective Catalytic Diels−Alder Reaction with Simple α,β-Unsaturated Ketones (2002) (323)
- The direct arylation of allylic sp3 C–H bonds via organocatalysis and photoredox catalysis (2015) (315)
- Enantioselective Organocatalytic α-Fluorination of Aldehydes (2005) (313)
- Aryl amination using ligand-free Ni(II) salts and photoredox catalysis (2016) (311)
- The first enantioselective organocatalytic Mukaiyama-Michael reaction: a direct method for the synthesis of enantioenriched gamma-butenolide architecture. (2003) (310)
- Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling. (2016) (309)
- Direct α-arylation of ethers through the combination of photoredox-mediated C-H functionalization and the Minisci reaction. (2015) (307)
- Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides (2014) (297)
- Two-Step Synthesis of Carbohydrates by Selective Aldol Reactions (2004) (288)
- O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols (2015) (284)
- Selective sp3 C–H alkylation via polarity-match-based cross-coupling (2017) (282)
- Visible light photocatalysis in organic chemistry (2018) (281)
- Nine-step enantioselective total synthesis of (+)-minfiensine. (2009) (280)
- Photosensitized, energy transfer-mediated organometallic catalysis through electronically excited nickel(II) (2017) (278)
- Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds (2017) (274)
- Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides (2016) (271)
- Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis (2013) (270)
- The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes. (2010) (268)
- Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines (2014) (266)
- Enantioselective organocatalytic cyclopropanations. The identification of a new class of iminium catalyst based upon directed electrostatic activation. (2005) (265)
- The first Suzuki cross-couplings of aryltrimethylammonium salts. (2003) (263)
- Direct Arylation of Strong Aliphatic C–H Bonds (2018) (260)
- Enantioselective organocatalytic direct aldol reactions of alpha-oxyaldehydes: step one in a two-step synthesis of carbohydrates. (2004) (249)
- Enantioselective organocatalytic singly occupied molecular orbital activation: the enantioselective alpha-enolation of aldehydes. (2007) (249)
- Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis. (2015) (245)
- Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes (2004) (241)
- Enantioselective α-arylation of aldehydes via the productive merger of iodonium salts and organocatalysis. (2011) (233)
- Enantioselective copper-catalyzed construction of aryl pyrroloindolines via an arylation-cyclization cascade. (2012) (229)
- A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes (2018) (224)
- Enantioselective organocatalytic amine conjugate addition. (2006) (218)
- Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids. (2015) (218)
- Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. (2015) (215)
- Cycle-specific organocascade catalysis: application to olefin hydroamination, hydro-oxidation, and amino-oxidation, and to natural product synthesis. (2009) (214)
- Decarboxylative sp3 C–N Coupling via Dual Copper/Photoredox Catalysis (2018) (208)
- The Enantioselective Organocatalytic 1,4-Addition of Electron-Rich Benzenes to α,β-Unsaturated Aldehydes (2002) (204)
- A general strategy for organocatalytic activation of C-H bonds via photoredox catalysis: direct arylation of benzylic ethers. (2014) (191)
- Enantioselective alpha-arylation of aldehydes via organo-SOMO catalysis. An ortho-selective arylation reaction based on an open-shell pathway. (2009) (191)
- Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials (2017) (185)
- Enantioselective Organo-SOMO Catalysis : The α-Vinylation of Aldehydes (2007) (180)
- Enantioselective organocatalytic intramolecular Diels-Alder reactions. The asymmetric synthesis of solanapyrone D. (2005) (178)
- Organocatalytic transfer hydrogenation of cyclic enones. (2006) (178)
- Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis. (2021) (178)
- Activation of C–H Bonds via the Merger of Photoredox and Organocatalysis: A Coupling of Benzylic Ethers with Schiff Bases (2014) (176)
- Enantioselective polyene cyclization via organo-SOMO catalysis. (2010) (175)
- Enantioselective organocatalytic α-fluorination of cyclic ketones. (2011) (172)
- Enantioselective direct α-amination of aldehydes via a photoredox mechanism: a strategy for asymmetric amine fragment coupling. (2013) (171)
- Total synthesis of brasoside and littoralisone. (2005) (167)
- Organocatalytic vinyl and Friedel-Crafts alkylations with trifluoroborate salts. (2007) (156)
- A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions (2017) (154)
- Direct Aldehyde C-H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis. (2017) (151)
- Selective Radical-Radical Cross-Couplings: Design of a Formal β-Mannich Reaction. (2015) (150)
- Direct β-functionalization of cyclic ketones with aryl ketones via the merger of photoredox and organocatalysis. (2013) (149)
- Nine-step enantioselective total synthesis of (-)-vincorine. (2013) (148)
- Enantioselective α-arylation of carbonyls via Cu(I)-bisoxazoline catalysis. (2011) (148)
- The Evolution of High-Throughput Experimentation in Pharmaceutical Development and Perspectives on the Future (2019) (143)
- Enantioselective linchpin catalysis by SOMO catalysis: an approach to the asymmetric alpha-chlorination of aldehydes and terminal epoxide formation. (2009) (142)
- Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis (2014) (138)
- Simple catalytic mechanism for the direct coupling of α-carbonyls with functionalized amines: a one-step synthesis of Plavix. (2013) (134)
- Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis. (2012) (130)
- Merging Photoredox with Nickel Catalysis: Coupling of α‐Carboxyl sp3‐Carbons with Aryl Halides. (2015) (130)
- Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3-sp2 Cross-Coupling of Oxalates with Aryl Halides. (2016) (129)
- The importance of iminium geometry control in enamine catalysis: identification of a new catalyst architecture for aldehyde-aldehyde couplings. (2004) (126)
- The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation (2020) (120)
- C2-SYMMETRIC COPPER(II) COMPLEXES AS CHIRAL LEWIS ACIDS. CATALYTIC ENANTIOSELECTIVE ALDOL ADDITIONS OF ENOLSILANES TO PYRUVATE ESTERS (1997) (120)
- Concerning the mechanism of the FeCl3-catalyzed alpha-oxyamination of aldehydes: evidence for a non-SOMO activation pathway. (2010) (120)
- C2-Symmetric Tin(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Anti Aldol Additions of Enolsilanes to Glyoxylate and Pyruvate Esters (1997) (119)
- Enantioselective organocatalytic epoxidation using hypervalent iodine reagents (2006) (110)
- Enantioselective α-Alkylation of Aldehydes by Photoredox Organocatalysis: Rapid Access to Pharmacophore Fragments from β-Cyanoaldehydes. (2015) (110)
- Enantioselective organo-singly occupied molecular orbital catalysis: the carbo-oxidation of styrenes. (2008) (105)
- Selective Hydrogen Atom Abstraction through Induced Bond Polarization: Direct α-Arylation of Alcohols through Photoredox, HAT, and Nickel Catalysis. (2018) (103)
- Total synthesis of diazonamide A. (2011) (103)
- Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids. (2018) (103)
- Enantioselective organo-SOMO cascade cycloadditions: a rapid approach to molecular complexity from simple aldehydes and olefins. (2010) (100)
- Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway. (2014) (98)
- Enantioselective aldehyde alpha-nitroalkylation via oxidative organocatalysis. (2009) (98)
- Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis. (2018) (97)
- From the Cover: Organocatalysis Special Feature: Organocatalysis (2010) (97)
- Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes. (2010) (96)
- Enantioselective organo-SOMO cycloadditions: a catalytic approach to complex pyrrolidines from olefins and aldehydes. (2012) (95)
- Metallaphotoredox-Catalyzed Cross-Electrophile Csp3-Csp3 Coupling of Aliphatic Bromides. (2018) (95)
- Direct, enantioselective α-alkylation of aldehydes using simple olefins. (2017) (94)
- Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis (2010) (94)
- Metallaphotoredox Difluoromethylation of Aryl Bromides. (2018) (94)
- Microenvironment mapping via Dexter energy transfer on immune cells (2020) (92)
- Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols. (2018) (83)
- Decarboxylative Peptide Macrocyclization through Photoredox Catalysis. (2017) (83)
- Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox. (2015) (83)
- Decarboxylative Hydroalkylation of Alkynes. (2018) (81)
- Copper-Mediated Synthesis of Drug-like Bicyclopentanes (2020) (81)
- Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene (1995) (80)
- A general approach to the enantioselective α-oxidation of aldehydes via synergistic catalysis. (2012) (78)
- Development of a generic activation mode: nucleophilic α-substitution of ketones via oxy-allyl cations (2013) (76)
- A Mechanistic Analysis of Metallaphotoredox C-N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity. (2020) (73)
- Strategies to Bypass the Taxol Problem. Enantioselective Cascade Catalysis, a New Approach for the Efficient Construction of Molecular Complexity (2007) (72)
- Cross-Electrophile Coupling of Unactivated Alkyl Chlorides. (2020) (72)
- Enantioselective Claisen rearrangements: development of a first generation asymmetric acyl-Claisen reaction. (2001) (71)
- A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cladiell-11-ene-3,6,7-triol, sclerophytin A, and the initially purported structure of sclerophytin A. (2001) (70)
- Enantioselective organocatalytic aldehyde-aldehyde cross-aldol couplings. The broad utility of α-thioacetal aldehydes (2004) (70)
- The organocatalytic three-step total synthesis of (+)-frondosin B. (2010) (69)
- Total synthesis and structural revision of callipeltoside C. (2008) (68)
- Copper-Catalyzed Trifluoromethylation of Alkyl Bromides. (2019) (66)
- Transient Absorption Spectroscopy Offers Mechanistic Insights for an Iridium/Nickel Catalyzed C-O Coupling. (2020) (65)
- Enantioselective total synthesis of (-)-minovincine in nine chemical steps: an approach to ketone activation in cascade catalysis. (2013) (65)
- Development of a New Lewis Acid-Catalyzed Claisen Rearrangement (1999) (65)
- The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction. (2011) (62)
- Mechanistic complexity in organo-SOMO activation. (2010) (61)
- Catalyst-controlled oligomerization for the collective synthesis of polypyrroloindoline natural products (2017) (60)
- Enantioselective α-alkenylation of aldehydes with boronic acids via the synergistic combination of copper(II) and amine catalysis. (2013) (58)
- A General and Enantioselective Approach to Pentoses: A Rapid Synthesis of PSI-6130, the Nucleoside Core of Sofosbuvir (2014) (58)
- Enantioselective intramolecular aldehyde α-alkylation with simple olefins: direct access to homo-ene products. (2013) (57)
- Native Functionality in Triple Catalytic Cross‐Coupling: Sp3 C—H Bonds as Latent Nucleophiles. (2016) (56)
- Oxy-Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode. (2016) (55)
- Metallaphotoredox-enabled deoxygenative arylation of alcohols (2021) (52)
- Development of a new Lewis acid-catalyzed [3,3]-sigmatropic rearrangement: the allenoate-Claisen rearrangement. (2002) (51)
- A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of Alpha-Chloro Carbonyls with Aryl Halides. (2019) (48)
- A general method for the enantioselective synthesis of pantolactone derivatives. (2002) (45)
- Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox Organocatalysis. (2010) (44)
- Site-Selective Functionalization of Methionine Residues via Photoredox Catalysis. (2020) (40)
- Static to inducibly dynamic stereocontrol: The convergent use of racemic β-substituted ketones (2020) (39)
- A process for the rapid removal of dialkylamino-substituents from aromatic rings. Application to the expedient synthesis of (R)-tolterodine (2009) (39)
- Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol. (2001) (36)
- Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral. (2000) (35)
- Site-selective tyrosine bioconjugation via photoredox catalysis for native-to-bioorthogonal protein transformation (2021) (34)
- Metallaphotoredox Aryl and Alkyl Radiomethylation for PET Ligand Discovery (2020) (34)
- O—H Hydrogen Bonding Promotes H‐Atom Transfer from α C—H Bonds for C‐Alkylation of Alcohols. (2016) (34)
- New Strategies for Organic Catalysis: The First Highly Enantioselective Organocatalytic Diels—Alder Reaction. (2000) (31)
- Development of a general, enantioselective organocatalytic Mukaiyama-Michael reaction with α,β-unsaturated aldehydes. (2009) (31)
- Photoredox Activation for the Direct β‐Arylation of Ketones and Aldehydes. (2013) (30)
- Decatungstate-Catalyzed C(sp3)-H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality. (2021) (29)
- Open-Shell Fluorination of Alkyl Bromides: Unexpected Selectivity in a Silyl Radical-Mediated Chain Process. (2019) (29)
- The Application of Pulse Radiolysis to the Study of Ni(I) Intermediates in Ni-Catalyzed Cross-Coupling Reactions. (2021) (28)
- Design of a new cascade reaction for the construction of complex acyclic architecture: the tandem acyl-claisen rearrangement. (2001) (25)
- Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor®. (2019) (24)
- Stereoselection in the Prins-pinacol synthesis of acyltetrahydrofurans. (2001) (24)
- A General N-alkylation Platform via Copper Metallaphotoredox and Silyl Radical Activation of Alkyl Halides. (2021) (23)
- Rapid Optimization of Photoredox Reactions for Continuous-Flow Systems Using Microscale Batch Technology (2021) (21)
- HARC as an open-shell strategy to bypass oxidative addition in Ullmann–Goldberg couplings (2020) (21)
- Metallaphotoredox Perfluoroalkylation of Organobromides. (2020) (21)
- A biomimetic SH2 cross-coupling mechanism for quaternary sp3-carbon formation (2021) (20)
- Selective Isomerization via Transient Thermodynamic Control: Dynamic Epimerization of trans to cis Diols. (2021) (20)
- Enantioselective Organocatalytic Direct Aldol Reactions of α-Oxyaldehydes: Step One in a Two-Step Synthesis of Carbohydrates. (2004) (17)
- The First Enantioselective Organocatalytic Mukaiyama—Michael Reaction: A Direct Method for the Synthesis of Enantioenriched γ‐Butenolide Architecture. (2003) (16)
- A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl Carboxylic Acids. (2022) (16)
- Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α‐Chlorination of Aldehydes and Terminal Epoxide Formation. (2009) (15)
- Organocatalysis (2010) (15)
- Nontraditional Fragment Couplings of Alcohols and Carboxylic Acids: C(sp3)-C(sp3) Cross-Coupling via Radical Sorting. (2022) (14)
- Accelerating reaction generality and mechanistic insight through additive mapping (2022) (14)
- History and Perspective of Chiral Organic Catalysts (2006) (13)
- α-Oxidation Reactions (2011) (12)
- Small molecule photocatalysis enables drug target identification via energy transfer (2021) (12)
- Decarboxylative Borylation and Cross-Coupling of (Hetero)aryl Acids Enabled by Copper Charge Transfer Catalysis. (2022) (11)
- Enantioselective Organocatalytic Transfer Hydrogenation Reactions Using Hantzsch Esters (2008) (10)
- Decarboxylative Oxygenation via Photoredox Catalysis (2019) (10)
- Reactive intermediates for interactome mapping. (2021) (10)
- Metallaphotoredox Difluoromethylation of Aryl Bromides (2018) (9)
- New Strategies in Organic Catalysis: The First Enantioselective Organocatalytic Friedel—Crafts Alkylation. (2001) (9)
- Synergistic Catalysis: A Powerful Synthetic Strategy for New Reaction Development (2012) (9)
- A biohybrid strategy for enabling photoredox catalysis with low-energy light (2021) (9)
- μMap-Red: Proximity Labeling by Red Light Photocatalysis. (2022) (8)
- Dual Photoredox Catalysis: The Merger of Photoredox Catalysis with Other Catalytic Activation Modes (2018) (8)
- Decarboxylative sp3 C–N coupling via dual copper and photoredox catalysis (2018) (8)
- Synthesis of Enantiopure Unnatural Amino Acids by Metallaphotoredox Catalysis. (2021) (8)
- Asymmetric Organocatalysis 1 (2012) (8)
- Enantioselective α-Arylation of Aldehydes via Organo-SOMO Catalysis. An ortho-Selective Arylation Reaction Based on an Open-Shell Pathway. (2010) (8)
- New Strategies for Organic Catalysis: The First Enantioselective Organocatalytic 1,3‐Dipolar Cycloaddition. (2001) (7)
- Enantioselective Aldehyde α‐Nitroalkylation via Oxidative Organocatalysis. (2010) (7)
- Photoredox α‐Vinylation of α‐Amino Acids and N‐Aryl Amines. (2015) (7)
- Erratum: Photoredox catalysis: A mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds (Angewandte Chemie - International Edition (2011) 50 (6119-6122)) (2011) (7)
- α-Functionalization of Carbonyl Compounds (2011) (6)
- Enantioselective Organocatalytic Singly Occupied Molecular Orbital Activation: The Enantioselective α‐Enolation of Aldehydes. (2007) (6)
- Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis. (2022) (6)
- Deoxytrifluoromethylation of Alcohols. (2022) (6)
- Radius measurement via super-resolution microscopy enables the development of a variable radii proximity labeling platform (2022) (5)
- Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes. (2008) (5)
- Decarboxylative Arylation of α‐Amino Acids via Photoredox Catalysis: A One‐Step Conversion of Biomass to Drug Pharmacophore. (2014) (5)
- Total Synthesis of (-)-Brasoside and (-)-Littoralisone (2005) (5)
- The direct and enantioselective organocatalytic alpha-oxidation of aldehydes. (2003) (5)
- Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling". (2016) (5)
- The Preparation of (2R,5S)‐2‐t‐Butyl‐3,5‐Dimethylimidazolidin‐4‐One (2012) (4)
- Tracking chromatin state changes using μMap photo-proximity labeling (2021) (4)
- 2. Asymmetric Organocatalysis (2010) (4)
- Rapid Access to 2-Substituted Bicyclo[1.1.1]pentanes. (2023) (4)
- Nickel Catalysis via SH2 Homolytic Substitution: The Double Decarboxylative Cross-Coupling of Aliphatic Acids. (2022) (4)
- Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides. (2015) (4)
- Enantioselective Organocatalytic Intramolecular Diels—Alder Reactions. The Asymmetric Synthesis of Solanapyrone D. (2005) (4)
- Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis. (2014) (4)
- Enantioselective Organocatalytic α‐Fluorination of Cyclic Ketones. (2011) (4)
- Magnitudes and Chemical Consequences of R 3 N +-C-H ‚ ‚ ‚ O d C Hydrogen Bonding (2016) (3)
- The enantioselective organocatalytic 1,4-addition of electron-rich benzenes to alpha,beta-unsaturated aldehydes. (2002) (3)
- Enantioselective organocatalysis involving iminium, enamine, SOMO, and photoredox activation (2010) (3)
- Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α‐Trifluoromethyl Carbonyl Compounds. (2011) (3)
- C2-Symmetric Tin(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective anti Aldol Additions of Enolsilanes to Glyoxylate and Pyruvate Esters. (1998) (3)
- α-Amination Reactions (2011) (3)
- Enantioselective Organo-Cascade Catalysis of α,β-Unsaturated Aldehydes (2005) (3)
- Alcohols as Alkylating Agents: Photoredox-Catalyzed Conjugate Alkylation via In Situ Deoxygenation. (2022) (3)
- Enantioselective organocatalytic alpha-fluorination of aldehydes. (2005) (2)
- Carboxylic Acids as a Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (.+-.)-Pregabalin (XXV). (2015) (2)
- Nine-Step Total Synthesis of (+)-Minfiensine (2009) (2)
- Ligand-to-Copper Charge Transfer: A General Catalytic Approach to Aromatic Decarboxylative Functionalization (2021) (2)
- A Process for the Rapid Removal of Dialkylamino‐Substituents from Aromatic Rings. Application to the Expedient Synthesis of (R)‐Tolterodine. (2009) (2)
- α-Vinylation of Aldehydes (2008) (2)
- Enantioselective Organo‐SOMO Catalysis: a Novel Activation Mode for Asymmetric Synthesis (2013) (2)
- Development of a New Lewis Acid‐Catalyzed Claisen Rearrangement. (2000) (2)
- Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross‐Electrophile Coupling. (2016) (2)
- Direct and Enantioselective Organocatalytic α-Chlorination of Aldehydes. (2004) (2)
- α-Allylation Reactions (2011) (2)
- Bioinspired Supercharging of Photoredox Catalysis for Applications in Energy and Chemical Manufacturing. (2022) (2)
- Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids (2015) (2)
- Photoproximity Labeling of Sialylated Glycoproteins (GlycoMap) Reveals Sialylation-Dependent Regulation of Ion Transport. (2022) (1)
- Enantioselective α-Enolation of Aldehydes by SOMO Activation (2007) (1)
- Enantioselective α-Nitroalkylation of AldehydesUsing SOMO Catalysis (2009) (1)
- A General and Enantioselective Approach to Pentoses: A Rapid Synthesis of PSI-6130, the Nucleoside Core of Sofosbuvir. (2014) (1)
- Development of a Generic Activation Mode: Nucleophilic α-Substitution of Ketones via Oxy-Allyl Cations. (2013) (1)
- Photochemical Identification of Auxiliary Severe Acute Respiratory Syndrome Coronavirus 2 Host Entry Factors Using μMap (2022) (1)
- Fragment Couplings via CO2 Extrusion—Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox. (2016) (1)
- Synthesis of Callipeltoside C (2008) (1)
- Asymmetric Synthesis of (S)-Ketoprofen (2011) (1)
- Enantioselective Organo‐SOMO Cycloadditions: A Catalytic Approach to Complex Pyrrolidines from Olefins and Aldehydes. (2013) (1)
- Enantioselective Copper‐Catalyzed Construction of Aryl Pyrroloindolines via an Arylation—Cyclization Cascade. (2012) (1)
- Enantioselective Total Synthesis of (‐)‐7‐Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene. (1996) (1)
- Selective Radical—Radical Cross-Couplings: Design of a Formal β-Mannich Reaction. (2015) (1)
- α-Enolation of Aldehydes (2012) (1)
- Enantioselective Amine Conjugate Addition (2006) (1)
- The Importance of Iminium Geometry Control in Enamine Catalysis: Identification of a New Catalyst Architecture for Aldehyde—Aldehyde Couplings. (2005) (1)
- Asymmetric Organocatalytic Transfer Hydrogenation of Cyclic Enones (2006) (1)
- Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes. (2009) (1)
- Direct α-Arylation of Ethers Through the Combination of Photoredox-Mediated C—H Functionalization and the Minisci Reaction. (2015) (1)
- α-Alkylation of Aldehydes with Styrenes (2009) (1)
- α-Allylation of Aldehydes (2012) (1)
- Direct and enantioselective organocatalytic alpha-chlorination of aldehydes. (2004) (1)
- Late-Stage C(sp3)-H Methylation of Drug Molecules. (2023) (1)
- Enantioselective α‐Arylation of Carbonyls via Cu(I)‐Bisoxazoline Catalysis. (2012) (1)
- C—C Bond Formation via SOMO Catalysis (2012) (0)
- Iminium-Catalyzed Enantioselective Cyclopropanation, Aziridination, and Epoxidation (2012) (0)
- α-Vinylation Reactions (2011) (0)
- Diels–Alder Processes (2012) (0)
- A General Strategy for the Synthesis of Cladiellin Diterpenes: Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (Deacetoxyalcyonin Acetate) (I), Cladiell-11-ene-3,6,7-triol (II), Sclerophytin A (III), and the Initially Purported Structure (IV) of Sclerophytin A. (2002) (0)
- Homo-Ene Cyclizations by SOMO Catalysis (2013) (0)
- α-Amination Reactions Using Nitrosobenzene (2011) (0)
- Silyl Enol Ether Based Nucleophiles (2012) (0)
- Intramolecular Asymmetric α-Allylation of Aldehydesvia SOMO Umpolung (2011) (0)
- Carbenium Cation Based Catalysts (2012) (0)
- Alkylations of Electron-Deficient Heteroaromatics (2008) (0)
- alpha-Functionalization of carbonyl compounds (2011) (0)
- Aza-Ene Reactions (2012) (0)
- Sulfone-Based Nucleophiles (2012) (0)
- α-Sulfanylation Reactions (2011) (0)
- Direct (Three-Component) Mannich Processes (2011) (0)
- The Enantioselective Organocatalytic 1,4-Addition of Electron-Rich Benzenes to α,β-Unsaturated Aldehydes. (2010) (0)
- α-Oxidation Reactions Using Dibenzoyl Peroxide (2011) (0)
- OrganoSOMO Mediated Enantioselective α-Functionalization (2011) (0)
- Plasmon Mediated Near‐Field Energy Transfer From Solid‐State, Electrically Injected Excitons to Solution Phase Chromophores (2023) (0)
- Enantioselective α‐Alkenylation of Aldehydes with Boronic Acids via the Synergistic Combination of Copper(II) and Amine Catalysis. (2014) (0)
- P-521 Enantioselective Catalytic Synthesis of Platforms of Reactivity : A new and general strategy of broad chemical utility (2006) (0)
- Chemical Science - The best new journal (2012) (0)
- Asymmetric α-Fluorination of Cyclic Ketones (2011) (0)
- Activation of C—H Bonds via the Merger of Photoredox and Organocatalysis: A Coupling of Benzylic Ethers with Schiff Bases. (2015) (0)
- α-Chlorination of Aldehydes (2012) (0)
- Mannich Processes with Preformed Imines (2011) (0)
- Expedient Access to Underexplored Chemical Space: Deoxygenative C(sp3)-C(sp3) Cross-Coupling. (2023) (0)
- α-Substitution of Ketones (2012) (0)
- Ionic Liquid Catalysts (2012) (0)
- α-Amination Reactions Using Azodicarboxylates (2011) (0)
- Azomethine Ylide Based Processes (2012) (0)
- [3 + 2]-Dipolar Cycloaddition Processes (2012) (0)
- Enantioselective Cyclopropanation Reactions (2012) (0)
- The First General Enantioselective Catalytic Diels—Alder Reaction with Simple α,β-Unsaturated Ketones. (2010) (0)
- Total Synthesis of Brasoside (I) and Littoralisone (II). (2005) (0)
- Enantioselective Epoxidation Reactions (2012) (0)
- A General Strategy for Organocatalytic Activation of C—H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers. (2014) (0)
- Phosphoric Acid Catalyzed Enantioselective Reductive Amination (2006) (0)
- Metallaphotoredox aryl and alkyl radiomethylation for PET ligand discovery (2020) (0)
- Iminium-Mediated Enantioselective Cycloaddition Processes (2012) (0)
- Development of a New Lewis Acid Catalyzed [3,3]‐Sigmatropic Rearrangement: The Allenoate‐Claisen Rearrangement. (2003) (0)
- α-Chlorination Reactions (2011) (0)
- Imidazolidinone-acid addition salts as reaction catalysts (2001) (0)
- Enantioselective organo-SOMO catalysis: the alpha-vinylation of aldehydes. (2008) (0)
- α-Enolation Reactions (2011) (0)
- Enantioselective Organocatalytic Aldehyde—Aldehyde Cross‐Aldol Couplings. The Broad Utility of α‐Thioacetal Aldehydes. (2004) (0)
- α-Selanylation Reactions (2011) (0)
- α,α-Dicyanoalkene-Based Nucleophiles (2012) (0)
- Organocatalytic Epoxidation Using Hypervalent Iodine Reagents (2006) (0)
- Ene Reaction Based Processes (2012) (0)
- Photoredox Organocatalysis Mediated Enantioselective α-Functionalization (2011) (0)
- Enantioselective Organocatalysis: Development of New Catalysis Concepts of Broad Utility to Chemical Synthesis (2003) (0)
- Intramolecular Aldol Reactions (2011) (0)
- Redefining the Synthetic Logic of Medicinal Chemistry. Photoredox-Catalyzed Reactions as a General Tool for Aliphatic Core Functionalization. (2023) (0)
- Hypervalent Silicon Catalysts (2012) (0)
- Photoredox Organocatalysis: Asymmetric α-Perfluoroalkylationof Aldehydes (2009) (0)
- 1,3-Dicarbonyl-Based Nucleophiles (2012) (0)
- Direct arylation of strong aliphatic C–H bonds (2018) (0)
- PL-3 New Catalysis Concepts of Broad Utility to Chemical Synthesis (2006) (0)
- Editorial - A flying start! (2011) (0)
- Copper-mediated synthesis of drug-like bicyclopentanes (2020) (0)
- α-Arylation of Aldehydes (2012) (0)
- Synthesis of Diazonamide A (2011) (0)
- Who's who in Chemical Science (2011) (0)
- Editorial Advisory Board Members Progress in Heterocyclic Chemistry 2008-2009 (2009) (0)
- Nitrone-Based Processes (2012) (0)
- SOMO Activation/a-Chlorination: From Aldehydes to Terminal Epoxides (2009) (0)
- Enantioselective 1,4-Addition of Sulfur Nucleophiles (2012) (0)
- Enantioselective 1,4-Addition of Nitrogen Nucleophiles (2012) (0)
- An Expedited Phenotypic Approach Towards Organic Reaction Generality (2021) (0)
- Synthesis of (+)-Frondosin B (2011) (0)
- The Intramolecular Asymmetric Allylation of Aldehydes via Organo‐SOMO Catalysis: A Novel Approach to Ring Construction. (2011) (0)
- Chiral Amine Directed Enantioinduction (2012) (0)
- α-Arylation Reactions (2011) (0)
- Enantioselective Organocatalytic Epoxidation Using Hypervalent Iodine Reagents. (2007) (0)
- α-Alkylation Reactions Using Michael Acceptors (2011) (0)
- Enantioselective 1,4-Addition of Phosphorus Nucleophiles (2012) (0)
- Development of a General Enantioselective Organocatalytic Mukaiyama—Michael Reaction with α,β-Unsaturated Aldehydes. (2009) (0)
- The first general enantioselective catalytic Diels-Alder reaction with simple alpha,beta-unsaturated ketones. (2002) (0)
- Collective, Organocatalytic Syntheses of Natural Products:Strychnos Alkaloids (2011) (0)
- Enamine-Mediated Enantioselective α-Functionalization (2011) (0)
- α-Homobenzylation Reactions (2011) (0)
- Tracking chromatin state changes using nanoscale photo-proximity labelling (2023) (0)
- Arene Nucleophiles: Friedel–Crafts Processes (2012) (0)
- Tracking chromatin state changes using µMap photo-proximity labeling (2021) (0)
- Aldol Processes with Aldehyde Donors (2011) (0)
- Molecular Catalysis Heidelberg Forum of Molecular Catalysis (2005) (0)
- α-Nitroalkylation Reactions (2011) (0)
- Enamine-Mediated Enantioselective Aldol and Mannich Processes (2011) (0)
- The First Direct and Enantioselective Cross‐Aldol Reaction of Aldehydes. (2003) (0)
- α-Halogenation Reactions (2011) (0)
- α-Oxyamination of Aldehydes (2012) (0)
- Cycle-Specific Aminocatalysis Cascades (2009) (0)
- α-Bromination Reactions (2011) (0)
- Go to the Board: A Journey through the Life of Professor David A. Evans. (2022) (0)
- α-Alkylation Reactions (2011) (0)
- α-Alkylation Reactions Using Alkyl Halides (2011) (0)
- Nitroalkane-Based Nucleophiles (2012) (0)
- Cu-Catalyzed Asymmetric α-Arylation of Carbonyls (2011) (0)
- α-Homobenzylation of Aldehydes (2012) (0)
- C2‐Symmetric Copper(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Aldol Additions of Enolsilanes to Pyruvate Esters. (1997) (0)
- Intermolecular Aldol Reactions (2011) (0)
- Iminium-Catalyzed Enantioselective β-Functionalization (2012) (0)
- α-Nitroalkylation of Aldehydes (2012) (0)
- Enantioselective Syntheses of Authentic Sclerophytin A (Ia), Sclerophytin B (Ib), and Cladiell‐11‐ene‐3,6,7‐triol (II). (2001) (0)
- A Closed-Shell Mechanism Alternative for Sibi’s α-Oxyaminationof Aldehydes (2010) (0)
- α-Oxidation Reactions Using Molecular Oxygen (2011) (0)
- SOMO and Radical Chemistry in Organocatalysis (2013) (0)
- P-419 Towards the Synthesis of Diazonamide A (2006) (0)
- Carbon–Carbon Bond Formation by Metallaphotoredox Catalysis (2019) (0)
- Enantioselective Aziridination Reactions (2012) (0)
- Enantioselective 1,4-Hydride Reduction (2012) (0)
- Petasis Reaction Based Processes (2012) (0)
- General Access to Cubanes as Benzene Bioisosteres. (2023) (0)
- Other Bond Formations via SOMO Catalysis (2012) (0)
- Aldol Processes with Ketone Donors (2011) (0)
- [4 + 3]-Cycloaddition Processes (2012) (0)
- Chiral Counteranion Directed Enantioinduction (2012) (0)
- Enantioseletive conversion of alpha, beta-unsaturated ketones using chiral organic catalysts (2002) (0)
- The Application of Photoredox Catalysis to New Transformations in Chemical Synthesis (2015) (0)
- α-Perfluoroalkylation Reactions (2011) (0)
- The Direct and Enantioselective Organocatalytic α-Oxidation of Aldehydes. (2004) (0)
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