David Milstein
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Israeli chemist
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Inorganic Chemistry
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Chemistry
David Milstein's Degrees
- Bachelors Chemistry Tel Aviv University
- PhD Chemistry Tel Aviv University
Why Is David Milstein Influential?
(Suggest an Edit or Addition)According to Wikipedia, David Milstein is an Israeli chemist studying homogeneous catalysis. Education and early life Milstein was born in 1947 in Ulm, Germany where his family took refuge after being displaced during the Holocaust. With his family, he immigrated to the newly founded state of Israel at the age of two. Milstein was first fascinated by chemistry when attending high school in the town of Rehovot where “an enthusiastic, old-fashioned chemistry teacher who didn’t care much about orbitals” inspired him “with vivid, thought-provoking experiments”. Pursuing his interest, Milstein received B.Sc., M.Sc., and Ph.D. degrees in chemistry from the Hebrew University of Jerusalem.
David Milstein's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Cyclometalated phosphine-based pincer complexes: mechanistic insight in catalysis, coordination, and bond activation. (2003) (1231)
- Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2 (2007) (982)
- Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis (2013) (938)
- Metal-ligand cooperation by aromatization-dearomatization: a new paradigm in bond activation and "green" catalysis. (2011) (825)
- Metal-ligand cooperation. (2015) (732)
- Bond activation and catalysis by ruthenium pincer complexes. (2014) (653)
- A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium (1978) (630)
- Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes. (2005) (615)
- Metal Insertion into C-C Bonds in Solution. (1999) (504)
- Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO (2011) (486)
- Efficient homogeneous catalytic hydrogenation of esters to alcohols. (2006) (441)
- Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity. (2011) (432)
- Selective synthesis of primary amines directly from alcohols and ammonia. (2008) (417)
- Consecutive Thermal H2 and Light-Induced O2 Evolution from Water Promoted by a Metal Complex (2009) (404)
- Hydrogenation and dehydrogenation iron pincer catalysts capable of metal-ligand cooperation by aromatization/dearomatization. (2015) (404)
- Direct synthesis of imines from alcohols and amines with liberation of H2. (2010) (383)
- Direct hydrogenation of amides to alcohols and amines under mild conditions. (2010) (336)
- Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction (1997) (335)
- Palladium-catalyzed coupling of tetraorganotin compounds with aryl and benzyl halides. Synthetic utility and mechanism (1979) (296)
- Efficient hydrogenation of ketones catalyzed by an iron pincer complex. (2011) (295)
- Manganese-Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study. (2016) (295)
- Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes (2018) (292)
- Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation (2010) (252)
- Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source (2013) (251)
- Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes. (2013) (242)
- Electron-Rich, Bulky Ruthenium PNP-Type Complexes. Acceptorless Catalytic Alcohol Dehydrogenation (2004) (235)
- Direct conversion of alcohols to acetals and H(2) catalyzed by an acridine-based ruthenium pincer complex. (2009) (223)
- Synthesis of amides from esters and amines with liberation of H2 under neutral conditions. (2011) (216)
- Catalytic Activation of Carbon-Fluorine Bonds by a Soluble Transition Metal Complex (1994) (208)
- Rational design in homogeneous catalysis. Iridium(I)-catalyzed addition of aniline to norbornylene via nitrogen-hydrogen activation (1988) (202)
- Organometallic Pincer Chemistry (2013) (199)
- N-H activation of amines and ammonia by Ru via metal-ligand cooperation. (2010) (193)
- Selective Hydrogenation of Nitriles to Primary Amines Catalyzed by a Cobalt Pincer Complex. (2015) (192)
- Iron pincer complex catalyzed, environmentally benign, E-selective semi-hydrogenation of alkynes. (2013) (187)
- Activation of a carbon–carbon bond in solution by transition-metal insertion (1993) (185)
- Efficient hydrogen liberation from formic acid catalyzed by a well-defined iron pincer complex under mild conditions. (2013) (183)
- Metal-ligand cooperation in C-H and H2 activation by an electron-rich PNP Ir(I) system: facile ligand dearomatization-aromatization as key steps. (2006) (183)
- Electron-Rich PNP- and PNN-Type Ruthenium(II) Hydrido Borohydride Pincer Complexes. Synthesis, Structure, and Catalytic Dehydrogenation of Alcohols and Hydrogenation of Esters (2011) (181)
- Evidence for a terminal Pt(iv)-oxo complex exhibiting diverse reactivity (2008) (165)
- Ru-catalyzed oxidative coupling of arenes with olefins using O(2). (2001) (163)
- Iron borohydride pincer complexes for the efficient hydrogenation of ketones under mild, base-free conditions: synthesis and mechanistic insight. (2012) (159)
- New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of Esters (2011) (159)
- HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS (1995) (159)
- Unprecedented iron-catalyzed ester hydrogenation. Mild, selective, and efficient hydrogenation of trifluoroacetic esters to alcohols catalyzed by an iron pincer complex. (2014) (156)
- Manganese-Catalyzed Hydrogenation of Esters to Alcohols. (2017) (155)
- Unprecedented catalytic hydrogenation of urea derivatives to amines and methanol. (2011) (153)
- Mild, selective, general method of ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium (1979) (148)
- Highly active PdII cyclometallated imine catalyst for the Suzuki reaction (1999) (143)
- Highly active PdII cyclometallated imine catalysts for the Heck reaction (1999) (143)
- Manganese-Catalyzed N-Formylation of Amines by Methanol Liberating H2 : A Catalytic and Mechanistic Study. (2017) (141)
- Metallinsertion in C-C-Bindungen in Lösung (1999) (141)
- Chelate-assisted, Pd-catalyzed efficient carbonylation of aryl chlorides (1989) (138)
- Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes. (2013) (138)
- Metall‐Ligand‐Kooperation (2015) (134)
- Synthesis of peptides and pyrazines from β-amino alcohols through extrusion of H2 catalyzed by ruthenium pincer complexes: ligand-controlled selectivity. (2011) (133)
- Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes. (2016) (133)
- Gd3+ complexes as potential spin labels for high field pulsed EPR distance measurements. (2007) (132)
- Mechanism of aryl chloride oxidative addition to chelated palladium(0) complexes (1993) (132)
- Cobalt-catalyzed hydrogenation of esters to alcohols: unexpected reactivity trend indicates ester enolate intermediacy. (2015) (131)
- Reusable Homogeneous Catalytic System for Hydrogen Production from Methanol and Water (2014) (131)
- Electron-rich, bulky PNN-type ruthenium complexes: synthesis, characterization and catalysis of alcohol dehydrogenation. (2007) (130)
- Combining Low-Pressure CO2 Capture and Hydrogenation To Form Methanol (2015) (122)
- Alkyl− and Aryl−Oxygen Bond Activation in Solution by Rhodium(I), Palladium(II), and Nickel(II). Transition-Metal-Based Selectivity (1998) (117)
- H/D exchange at aromatic and heteroaromatic hydrocarbons using D2O as the deuterium source and ruthenium dihydrogen complexes as the catalyst. (2007) (116)
- Aldehyde binding through reversible C-C coupling with the pincer ligand upon alcohol dehydrogenation by a PNP-ruthenium catalyst. (2012) (116)
- Nitrogen-hydrogen activation. 1. Oxidative addition of ammonia to iridium(I). Isolation, structural characterization and reactivity of amidoiridium hydrides (1987) (115)
- Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols. (2017) (114)
- "Long-range" metal-ligand cooperation in H2 activation and ammonia-promoted hydride transfer with a ruthenium-acridine pincer complex. (2010) (114)
- Bond Activation by Metal-Ligand Cooperation: Design of “Green” Catalytic Reactions Based on Aromatization-Dearomatization of Pincer Complexes (2011) (113)
- Direct Synthesis of Benzimidazoles by Dehydrogenative Coupling of Aromatic Diamines and Alcohols Catalyzed by Cobalt (2017) (112)
- Aspects of intermediacy of carbalkoxymetal complexes in carbon monoxide reactions (1988) (111)
- A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature. (2012) (110)
- Selective N-Formylation of Amines with H2 and CO2 Catalyzed by Cobalt Pincer Complexes (2017) (108)
- Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst. (2017) (107)
- Catalytic coupling of nitriles with amines to selectively form imines under mild hydrogen pressure. (2012) (105)
- Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex. (2017) (105)
- Metal-ligand cooperation in the trans addition of dihydrogen to a pincer Ir(I) complex: a DFT study. (2009) (105)
- Transition-metal-catalyzed carbon-carbon bond formation via carbon-hydrogen activation. Intermolecular hydroacylation: the addition of aldehydes to alkenes (1988) (105)
- Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex. (2016) (104)
- Efficient hydrogenation of biomass-derived cyclic di-esters to 1,2-diols. (2012) (103)
- Palladium-catalyzed vinylation of aryl chlorides. Chelate effect in catalysis (1992) (103)
- Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols. (2018) (102)
- Formation of η2 C−H Agostic Rhodium Arene Complexes and Their Relevance to Electrophilic Bond Activation (1998) (101)
- Ruthenium Pincer‐Catalyzed Cross‐Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions (2012) (99)
- Synthesis and reactivity of iron complexes with a new pyrazine-based pincer ligand, and application in catalytic low-pressure hydrogenation of carbon dioxide. (2015) (99)
- System with potential dual modes of metal-ligand cooperation: highly catalytically active pyridine-based PNNH-Ru pincer complexes. (2014) (98)
- Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols (2018) (98)
- Reactions of electron-rich arylpalladium complexes with olefins. Origin of the chelate effect in vinylation catalysis (1994) (97)
- Advances in metal chemistry of quinonoid compounds: new types of interactions between metals and aromatics. (2001) (94)
- Highly Efficient Process for Production of Biofuel from Ethanol Catalyzed by Ruthenium Pincer Complexes. (2016) (92)
- Activation of nitriles by metal ligand cooperation. Reversible formation of ketimido- and enamido-rhenium PNP pincer complexes and relevance to catalytic design. (2013) (92)
- Synthesis and reactivity of an iridium(I) acetonyl PNP complex. Experimental and computational study of metal-ligand cooperation in H-H and C-H bond activation via reversible ligand dearomatization (2010) (91)
- N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System. (2018) (91)
- Mechanism of reductive elimination. Reaction of alkylpalladium(II) complexes with tetraorganotin, organolithium, and Grignard reagents. Evidence for palladium(IV) intermediacy (1979) (91)
- Oxidant-free conversion of cyclic amines to lactams and H2 using water as the oxygen atom source. (2014) (87)
- Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(I) PNP pincer-type complex and the reaction with dihydrogen (2014) (87)
- Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes (2018) (86)
- Synthesis, Structure, and Reactivity of New Rhodium and Iridium Complexes, Bearing a Highly Electron-Donating PNP System. Iridium-Mediated Vinylic C−H Bond Activation (2002) (86)
- A Room Temperature Direct Metal Insertion into a Nonstrained Carbon−Carbon Bond in Solution. C−C vs C−H Bond Activation (1996) (85)
- Rechargeable Hydrogen Storage System Based on the Dehydrogenative Coupling of Ethylenediamine with Ethanol. (2016) (82)
- Complexation of N2, H2, CO2, and Ethylene to a T-Shaped Rhodium(I) Core (1996) (80)
- Silanol-based pincer Pt(II) complexes: synthesis, structure, and unusual reactivity. (2008) (80)
- Z-Selective (Cross-)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex. (2016) (80)
- ortho C-H Activation of Haloarenes and Anisole by an Electron-Rich Iridium(I) Complex: Mechanism and Origin of Regio- and Chemoselectivity. An Experimental and Theoretical Study (2006) (80)
- Pincer “Hemilabile” Effect. PCN Platinum(II) Complexes with Different Amine “Arm Length” (2005) (79)
- N–H Activation by Rh(I) via Metal–Ligand Cooperation (2012) (78)
- Selective ortho C-h activation of haloarenes by an Ir(I) system. (2003) (78)
- Mechanism of a Directly Observed Beta-Hydride Elimination Process of Iridium Alkoxo Complexes (1995) (77)
- Metallacarbenes from diazoalkanes: an experimental and computational study of the reaction mechanism. (2003) (77)
- A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation (2015) (76)
- Aromatic vs aliphatic C-H bond activation by rhodium(I) as a function of agostic interactions: catalytic H/D exchange between olefins and methanol or water. (2003) (76)
- Metal–ligand cooperation by aromatization–dearomatization as a tool in single bond activation (2015) (75)
- Formation, structures, and reactivity of cis-hydroxy-, cis-methoxy-, and cis-mercaptoiridium hydrides. Oxidative addition of water to Ir(I) (1986) (75)
- Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation (2018) (75)
- The cis-alkyl and cis-acylrhodium and iridium hydrides. Model intermediates in homogeneous catalysis (1984) (73)
- A PCN Ligand System. Exclusive C−C Activation with Rhodium(I) and C−H Activation with Platinum(II) (1997) (72)
- Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics (2021) (72)
- Formation of Stable trans-Dihydride Ruthenium(II) and 16-Electron Ruthenium(0) Complexes Based on Phosphinite PONOP Pincer Ligands. Reactivity toward Water and Electrophiles (2009) (72)
- Transition-metal-catalyzed cyclization of alkynoic acids to alkylidene lactones (1987) (72)
- Anionic nickel(II) complexes with doubly deprotonated PNP pincer-type ligands and their reactivity toward CO2 (2013) (71)
- Cationic, neutral, and anionic PNP Pd(II) and Pt(II) complexes: dearomatization by deprotonation and double-deprotonation of pincer systems. (2010) (70)
- Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols with Secondary Amines Catalyzed by Ruthenium Bipyridine‐Based Pincer Complexes (2013) (70)
- Catalytic selective cleavage of a strong C–C single bond by rhodium in solution (1998) (69)
- Reductive Cleavage of CO2 by Metal-Ligand-Cooperation Mediated by an Iridium Pincer Complex. (2016) (68)
- Chelate effect on the structure and reactivity of electron-rich palladium complexes and its relevance to catalysis (1993) (67)
- Ethylene Glycol as an Efficient and Reversible Liquid Organic Hydrogen Carrier (2019) (66)
- Direct observation of reductive elimination of methyl iodide from a rhodium(III) pincer complex: the importance of sterics. (2006) (66)
- Transfer of methylene groups promoted by metal complexation (1994) (66)
- UNEXPECTED ISOMERIZATION OF A CIS- INTO A TRANS-DIHYDRIDE COMPLEX. A NEUTRAL LATE TRANSITION METAL COMPLEX AS A HYDRIDE DONOR (1997) (66)
- Comparison of steric and electronic requirements for C-C and C-H bond activation. Chelating vs nonchelating case. (2001) (65)
- How Innocent are Potentially Redox Non-Innocent Ligands? Electronic Structure and Metal Oxidation States in Iron-PNN Complexes as a Representative Case Study. (2015) (65)
- Iron-Catalyzed Mild and Selective Hydrogenative Cross-Coupling of Nitriles and Amines To Form Secondary Aldimines. (2017) (64)
- Ruthenium Pincer-Catalyzed Acylation of Alcohols Using Esters with Liberation of Hydrogen under Neutral Conditions (2010) (64)
- Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols (2017) (63)
- Exclusive C-C activation and an apparent α-H elimination with a rhodium phosphinite pincer complex (2006) (63)
- Iron(II) complexes based on electron-rich, bulky PNN- and PNP-type ligands (2006) (63)
- Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex (2017) (62)
- Selective hydrogenation of nitriles to primary amines catalyzed by a novel iron complex. (2016) (61)
- Clarification of a remarkable chelate effect leads to palladium-catalyzed base-free olefin arylation (1993) (61)
- Directly Observed Oxidative Addition of a Strong Carbon-Carbon Bond to a Soluble Metal Complex (1995) (60)
- Synthesis of polyamides from diols and diamines with liberation of H2 (2012) (59)
- Formal loss of an H radical by a cobalt complex via metal-ligand cooperation. (2013) (59)
- A Dearomatized Anionic PNP Pincer Rhodium Complex: C–H and H–H Bond Activation by Metal–Ligand Cooperation and Inhibition by Dinitrogen (2011) (58)
- Unprecedented iron-catalyzed selective hydrogenation of activated amides to amines and alcohols. (2016) (57)
- Highly efficient, general hydrogenation of aldehydes catalyzed by PNP iron pincer complexes (2015) (57)
- A binuclear palladium(I) hydride. Formation, reactions, and catalysis (1994) (56)
- Hydride elimination from an iridium(III) alkoxide complex: a case in which a vacant cis coordination site is not required (2000) (56)
- The first isolated, stable cis-hydridoalkylrhodium complexes and their reductive elimination reaction (1982) (56)
- Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives. (2019) (56)
- Unsaturated Pd(0), Pd(I), and Pd(II) complexes of a new methoxy-substituted benzyl phosphine. Aryl-X (X = Cl, I) oxidative addition, C-O cleavage, and Suzuki-Miyaura coupling of aryl chlorides (2004) (55)
- Synthesis and characterisation of nonclassical ruthenium hydride complexes containing chelating bidentate and tridentate phosphine ligands. (2007) (55)
- C–F bond activation by iridium(I). A unique process involving P–C bond cleavage, P–F bond formation and net retention of oxidation state (1991) (55)
- The unexpected role of CO in C--H oxidative addition by a cationic rhodium(I) complex. (2007) (54)
- Mechanism of the Manganese-Pincer-Catalyzed Acceptorless Dehydrogenative Coupling of Nitriles and Alcohols. (2019) (53)
- Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier (2018) (53)
- Selective sp3 C-H activation of ketones at the beta position by Ir(I). Origin of regioselectivity and water effect. (2006) (53)
- Mononuclear Rh(II) PNP-type complexes. Structure and reactivity. (2007) (52)
- Methanol reduces an organopalladium(II) complex to a palladium(I) hydride. Crystallographic characterization of a hydrido-bridged palladium complex (1991) (52)
- Nickel promoted C–H, C–C and C–O bond activation in solution (2004) (51)
- Oxidative addition of unactivated epoxides to iridium(I) complexes. Formation of stable cis-hydridoformylmethyl and -acylmethyl complexes (1982) (51)
- Mechanism of Coupling of Alcohols and Amines To Generate Aldimines and H2 by a Pincer Manganese Catalyst (2019) (51)
- Formylation of aryl chlorides catalysed by a palladium complex (1989) (51)
- Oxidative addition of water and aliphatic alcohols by IrCl(trialkylphosphine)(3). (2002) (50)
- Iron dicarbonyl complexes featuring bipyridine-based PNN pincer ligands with short interpyridine C-C bond lengths: innocent or non-innocent ligand? (2014) (50)
- Direct Synthesis of Secondary Amines From Alcohols and Ammonia Catalyzed by a Ruthenium Pincer Complex (2014) (50)
- Redox-induced collapse and regeneration of a pincer-type complex framework: a nonplanar coordination mode of palladium(II). (2005) (48)
- Metal-Stabilized Methylene Arenium and σ-Arenium Compounds: Synthesis, Structure, Reactivity, Charge Distribution, and Interconversion (1999) (48)
- Simple and efficient catalytic reaction for the selective deuteration of alcohols (2013) (48)
- Cobalt-catalyzed carbalkoxylation of olefins: a new mechanism (1982) (48)
- General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2. (2016) (48)
- CARBON-CARBON VS CARBON-HYDROGEN BOND ACTIVATION BY RUTHENIUM(II) AND PLATINUM(II) IN SOLUTION (1999) (47)
- Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi-acceptors. (2004) (47)
- Hydrogenative Depolymerization of Nylons (2020) (47)
- Mechanistic investigations of the catalytic formation of lactams from amines and water with liberation of H2. (2015) (47)
- Concept of the H(δ+)⋯ H(δ–) interaction. A low-temperature neutron diffraction study of cis-[IrH(OH)(PMe3)4]PF6 (1990) (47)
- The First Observation and Kinetic Evaluation of a Single Step Metal Insertion into a C−C Bond (2000) (46)
- Selective C - C vs C - H bond activation by rhodium(I) PCP pincer complexes. A computational study (2000) (46)
- Cationic, Neutral, and Anionic Platinum(II) Complexes Based on an Electron-Rich PNN Ligand. New Modes of Reactivity Based on Pincer Hemilability and Dearomatization (2008) (46)
- Direct catalytic olefination of alcohols with sulfones. (2014) (46)
- Synthesis, structures, and dearomatization by deprotonation of iron complexes featuring bipyridine-based PNN pincer ligands. (2013) (45)
- Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium (2018) (45)
- Direct coupling of alcohols to form esters and amides with evolution of H2 using in situ formed ruthenium catalysts (2012) (44)
- Stepwise metal-ligand cooperation by a reversible aromatization/deconjugation sequence in ruthenium complexes with a tetradentate phenanthroline-based ligand. (2013) (44)
- C-C versus C-H activation and versus agostic C-C interaction controlled by electron density at the metal center. (2003) (44)
- Evidence for an unprecedented Ir(H)(NH3) ⇄ Ir(H2)(NH2) equilibrium and hydrogen exchange between NH and CH bonds (1991) (44)
- Selective Acceptorless Conversion of Primary Alcohols to Acetals and Dihydrogen Catalyzed by the Ruthenium(II) Complex Ru(PPh3)2(NCCH3)2(SO4) (2012) (43)
- Effect of CO on the oxidative addition of arene C-H bonds by cationic rhodium complexes. (2010) (43)
- Facile NH Cleavage of Ammonia (1991) (43)
- B-C bond cleavage of BArF anion upon oxidation of rhodium(I) with AgBArF. Phosphinite rhodium(I), rhodium(II), and rhodium(III) pincer complexes (2008) (43)
- DFT study of the structure and reactivity of the terminal Pt(IV)-oxo complex bearing no electron-withdrawing ligands. (2010) (43)
- Isolation of cis-hydridoacylrhodium(III) complexes not stabilized by chelation. Reductive elimination and decarbonylation (1982) (43)
- Challenging metal-based transformations. From single-bond activation to catalysis and metallaquinonoids (2003) (43)
- Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese. (2018) (43)
- PNS-Type Ruthenium Pincer Complexes (2012) (42)
- A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol-Ethylenediamine and Ethylene Urea. (2019) (42)
- SELECTIVE ACTIVATION OF ALKYL- AND ARYL-OXYGEN SINGLE BONDS IN SOLUTION WITH TRANSITION METAL COMPLEXES (1997) (42)
- Catalytic system for Heck reactions involving insertion into Pd-(perfluoro-organyl) bonds. (2001) (42)
- Dehydrogenative Cross-Coupling of Primary Alcohols To Form Cross-Esters Catalyzed by a Manganese Pincer Complex (2018) (42)
- B–H Bond Cleavage via Metal–Ligand Cooperation by Dearomatized Ruthenium Pincer Complexes (2014) (42)
- Highly Efficient Additive-Free Dehydrogenation of Neat Formic Acid (2021) (42)
- CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism (2018) (41)
- Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex (2017) (41)
- C-Metalated Diazoalkane Complexes of Platinum Based on PCP- and PCN-Type Ligands (2005) (41)
- Bottom-Up Construction of a CO2-Based Cycle for the Photocarbonylation of Benzene, Promoted by a Rhodium(I) Pincer Complex. (2016) (40)
- A general method for preparation of metal carbenes via solution- and polymer-based approaches. (2005) (40)
- Dimethylsulfoxide as a ligand for RhI and IrI complexes--isolation, structure, and reactivity towards X-H bonds (X=H, OH, OCH3). (2003) (40)
- Noninnocent behavior of PCP and PCN pincer ligands of late metal complexes (2013) (39)
- The Methylene-Transfer Reaction: Synthetic and Mechanistic Aspects of a Unique C−C Coupling and C−C Bond Activation Sequence (2000) (39)
- RHODIUM AND PALLADIUM COMPLEXES OF A 3,5-LUTIDINE-BASED PHOSPHINE LIGAND (1996) (39)
- Mild, low-pressure carbonylation of (.pi.-allyl)palladium complexes (1982) (38)
- Rhodium complexes with chiral counterions: achiral catalysts in chiral matrices (2004) (38)
- Discovery of the First Metallaquinone (2000) (37)
- sp3 C–H and sp2 C–H agostic ruthenium complexes: a combined experimental and theoretical study ☆ (2004) (37)
- Direct observation of reductive elimination of MeX (X = Cl, Br, I) from Rh(III) complexes: mechanistic insight and the importance of sterics. (2013) (37)
- Direct Synthesis of Amides by Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and Ammonia Catalyzed by a Manganese Pincer Complex: Unexpected Crucial Role of Base. (2019) (37)
- Synthesis and Structure of New Osmium−PCP Complexes. Osmium-Mediated C−C Bond Activation (2001) (37)
- Facial (methyl)(hydrido)(silyl) Complexes of Iridium: Synthesis, X-ray Structures, and Reductive Elimination Reactions. Facile Formation of Silametalacycles by Metalation of Silyl Ligands (1995) (36)
- O2 activation by metal-ligand cooperation with Ir(I) PNP pincer complexes. (2015) (36)
- Homogeneously catalyzed, chelate assisted hydrogenolysis of an amine C–N bond (2000) (36)
- Formation of difluoromethylene-arenium complexes by consecutive Aryl- CF3 C-C bond activation and C-F bond cleavage (1999) (35)
- Ruthenium dihydrogen complex for C-H activation: Catalytic H/D exchange under mild conditions (2008) (35)
- Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding (2016) (35)
- Interplay between solvent and counteranion stabilization of highly unsaturated rhodium(III) complexes: facile unsaturation-induced dearomatization. (2003) (35)
- C-H vs. O-H reductive elimination of methanol from a metal complex. Which is a more likely process? (1986) (35)
- Solvent-controlled selectivity toward exclusive C-C or C-H bond activation by a cationic metal center (1999) (34)
- Ligand-Controlled Formation of a Low-Valent Pincer Rhodium(I)-Dioxygen Adduct Bearing a Very Short O O Bond (2006) (34)
- Pi-accepting-pincer rhodium complexes: an unusual coordination mode of PCP-type systems. (2005) (34)
- PNN Ruthenium Pincer Complexes Based on Phosphinated 2,2′-Dipyridinemethane and 2,2′-Oxobispyridine. Metal–Ligand Cooperation in Cyclometalation and Catalysis (2013) (34)
- N–Hvis. C–H activation; a major ligand size effect (1993) (34)
- Low‐Pressure Hydrogenation of Nitriles to Primary Amines Catalyzed by Ruthenium Pincer Complexes. Scope and mechanism (2017) (34)
- Reductive dechlorination of aryl chlorides catalyzed by palladium complexes containing basic, chelating phosphines (1992) (33)
- Reactivity of rhodium-triflate complexes with diphenylsilane: evidence for silylene intermediacy in stoichiometric and catalytic reactions. (2005) (33)
- Oxidative addition of water to novel Ir(I) complexes stabilized by dimethyl sulfoxide ligands. (2002) (33)
- Competitive C-I versus C-CN reductive elimination from a Rh(III) complex. Selectivity is controlled by the solvent. (2008) (33)
- Formamides as Isocyanate Surrogates: A Mechanistically-Driven Approach to the Development of Atom-Efficient, Selective Catalytic Syntheses of Ureas, Carbamates and Heterocycles. (2019) (32)
- Direct Synthesis of Thermally Stable PCP-Type Rhodium Carbenes (2000) (32)
- SELECTIVE TRANSFORMATION OF VICINAL-DISUBSTITUTED EPOXIDES INTO KETONES BY HOMOGENEOUS RHODIUM CATALYSTS (1977) (32)
- Novel azine reactivity: facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. (2003) (31)
- Reaction of Aryl Iodides with (PCP)Pd(II)—Alkyl and Aryl Complexes: Mechanistic Aspects of Carbon—Carbon Bond Formation (2001) (31)
- Stable Carbene and Diazoalkane Complexes of the Same Complex System. Synthesis, Structure, and Reactivity of PNP−Ru(II) Fluorenylidene and Diazofluorene Complexes (2008) (30)
- Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes (2020) (30)
- CARBON-CARBON BOND ACTIVATION BY RHODIUM(I) IN SOLUTION. COMPARISON OF SP2-SP3 VS SP3-SP3 C-C, C-H VS C-C, AND AR-CH3 VS AR-CH2CH3 ACTIVATION (1998) (30)
- The product-forming step in palladium-catalysed methoxycarbonylation of organic halides (1986) (29)
- Isolation and direct observation of intramolecular hydroacylation of a cis-hydridopent-4-enoylrhodium(III) complex (1982) (29)
- Rh(I) and Rh(III) silyl PMe3 complexes. Syntheses, reactions and 103Rh NMR spectroscopy (1998) (29)
- Exclusive C–C Oxidative Addition in a Rhodium Thiophosphoryl Pincer Complex and Computational Evidence for an η3-C–C–H Agostic Intermediate (2012) (29)
- Direct deamination of primary amines by water to produce alcohols. (2013) (29)
- Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal‐Ligand Cooperation by Aromatization/Dearomatization (2015) (29)
- Formation and X-ray Structures of PCP Ligand Based Platinum(II) and Palladium(II) Macrocycles. (1996) (28)
- Synthesis, Structure, and Reactivity of Nitrosyl Pincer-Type Rhodium Complexes (2009) (28)
- Palladium-catalyzed cross-methylation of aryl chlorides by stabilized dimethylaluminium and -gallium reagents (2000) (28)
- Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2 (2018) (28)
- Directly Observed β-H Elimination of Unsaturated PCP-Based Rhodium(III)−Alkyl Complexes (1999) (28)
- Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2 and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl (1987) (28)
- Osmium-mediated C--H and C--C bond cleavage of a phenolic substrate: p-quinone methide and methylene arenium pincer complexes. (2007) (27)
- Water-soluble contrast agents targeted at the estrogen receptor for molecular magnetic resonance imaging. (2007) (27)
- Metal-Stabilized Quinone and Thioquinone Methides (1997) (27)
- A pincer-type anionic platinum(0) complex. (2008) (27)
- Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics. (2007) (26)
- Metal-stabilized phenoxonium cation. (2003) (26)
- Catalytic System for the Heck Reaction of Fluorinated Haloaryls (2005) (26)
- Rhodaoxetane: synthesis, structure, and theoretical evaluation (1993) (26)
- Facile Oxidative Addition of C−Cl Bonds to New Neutral and Cationic Rhodium(I)‐Bipyridine Complexes (2002) (25)
- Evidence for Direct trans Insertion in a Hydrido-Olefin Rhodium Complex-Free Nitrogen as a Trap in a Migratory Insertion Process. (1997) (25)
- The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity (2017) (24)
- New Tridentate Phosphine Rhodium and Iridium Complexes, Including a Stable Rhodium(I) Silyl. Si−S Activation and a Strong Effect of X in (PP2)M−X (X = H, Cl, Me) on Si−H Activation (2002) (24)
- Pyridine-Based PCP-Ruthenium Complexes: Unusual Structures and Metal-Ligand Cooperation. (2019) (24)
- Hydrogenation of Polar Bonds Catalysed by Ruthenium-Pincer Complexes (2014) (24)
- Ru(0) and Ru(II) nitrosyl pincer complexes: structure, reactivity, and catalytic activity. (2013) (24)
- A unique dioxo alkene hydride metal complex: [RhH(O2){CH2C(CH2CH2PBut2)2}] (1996) (24)
- Reversible Aromaticity Transfer in a Bora-Cycle: Boron-Ligand Cooperation. (2016) (24)
- Unsaturated Rh(I) and Rh(III) Naphthyl-Based PCP Complexes. Major Steric Effect on Reactivity (2009) (24)
- Ligand‐Controlled Chemoselectivity in the Classical Oxidative Addition Reactions of MeI and Aldehydes to Rhodium(I) Complexes (2001) (24)
- Methylene Arenium Cations via Quinone Methides and Xylylenes Stabilized by Metal Complexation (1998) (23)
- CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. (2019) (23)
- Pyridine-Based Sulfoxide Pincer Complexes of Rhodium and Iridium (2008) (23)
- Direct Observation of OH Reductive Elimination from IrIII Complexes (1995) (23)
- A new ligand system based on a bipyridine-functionalized calix[4]arene backbone leading to mono- and bimetallic complexes. (2003) (23)
- Structure and Reactivity of Rhodium(I) Complexes Based on Electron-Withdrawing Pyrrolyl-PCP-Pincer Ligands (2009) (23)
- Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight (2020) (23)
- Competitive generation of C-H and C-Si bonds by reductive elimination: Formation of silametallacycles by metalation of silyl ligands (1994) (22)
- Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols (2018) (22)
- Reactivity of [Ir(COE)2(solvent)2]PF6 Complexes toward Alkylphosphines: Room-Temperature C−H Activation (Cyclometalation) and Isolation of a 14-Electron Alkyl−Iridium(III) Complex (2003) (22)
- Carbon–carbon activation by rhodium in solution; sp2–sp3 is preferred over sp3–sp3 bond cleavage (1995) (21)
- C-H rather than O–H activation: synthesis and molecular structure of a cationic cis-hydrido-σ-acetylide complex of rhodium (1987) (21)
- Reversible Cyclometalation of Silyl Ligands. First X-ray Structure of an Iridium(I) Silyl That Is Not Stabilized by Chelation (1996) (20)
- Mechanistic studies of the rhodium-catalysed cyclization of α,ω-alkynoci acids to alkylidene lactones. Crystals structures of two iridium model catalytic intermediates (1987) (20)
- The reactions of tridentate cationic palladium(II) complexes with olefins and nucleophiles (1995) (20)
- Transition metal-catalyzed silanone generation (1996) (20)
- Activation of a non-strained C–C bond with plantinum(II) (1996) (20)
- (Hydroxyacetyl)iridium and -rhodium complexes: model compounds for CO hydrogenation (1986) (19)
- Synthesis and x-ray structure of a simple metallaoxetane. Metal-based selectivity in oxidative addition (1990) (19)
- Oxidative addition of Si–Cl bonds to electron-rich IrI complexes (1989) (19)
- The first fully characterized neutral and cationic rhodium(I)-complexes containing DMSO as the only dative ligand; S-, O- and bridging S,O-bidentate binding modes. (2002) (19)
- POLYMERIC SUPPORTS FOR CATALYSTS. (1983) (18)
- PALLADIUM‐CATALYZED COUPLING OF TETRAORGANOTIN COMPOUNDS WITH ARYL AND BENZYL HALIDES. SYNTHETIC UTILITY AND MECHANISM (1979) (17)
- Methyl-to-Double Bond Migration in Methylene Arenium Rhodium Complexes (2000) (17)
- METAL-MEDIATED GENERATION, STABILIZATION, AND CONTROLLED RELEASE OF A BIOLOGICALLY RELEVANT, SIMPLE PARA QUINONE METHIDE : BHT-QM (1998) (17)
- Naphthyl-Based PCP Platinum Complexes. Nucleophilic Activation of Coordinated CO and Synthesis of a Pt(II) Formyl Complex (2007) (17)
- Pyridine-based SNS-iridium and -rhodium sulfide complexes, including d8-d8 metal-metal interactions in the solid state. (2008) (17)
- Homogeneous catalytic transformation of aryl-substituted epoxides by some complexes of the platinum metals (1974) (17)
- CO-Induced Methyl Migration in a Rhodium Thiophosphoryl Pincer Complex and Its Comparison with Phosphine-Based Complexes: The Divergent Effects of S and P Donor Ligands (2013) (17)
- Cyclometalated Phosphine‐Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation (2003) (16)
- Methylene transfer from SnMe groups mediated by a rhodium(I) pincer complex: Sn-C, C-C, and C-H bond activation. (2007) (16)
- Formation of transition metal carbenes using haloalkylzinc reagents. (2007) (16)
- Oxidation of Alkenes by Water with H2 Liberation (2020) (16)
- Chelation versus Cyclometalation in a Cationic Dppn−RhI Complex − A Unique Rearrangement of Norbornadiene via C−H Activation of the Pyridazine Ring (2003) (15)
- Solvent-dependent interconversions between Rh(I), Rh(II), and Rh(III) complexes of an aryl-monophosphine ligand. (2007) (15)
- Formation of thioesters by dehydrogenative coupling of thiols and alcohols with H2 evolution (2020) (15)
- Dimerization of terminal epoxides by homogeneous transition-metal complexes. A novel synthesis of carboxylic esters (1978) (15)
- C-C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism. (2019) (15)
- Consecutive cyclometalation by platinum(II) (1996) (15)
- Pd Catalyzed, Acid Accelerated, Rechargeable, Liquid Organic Hydrogen Carrier System Based on Methylpyridines/Methylpiperidines (2019) (15)
- Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles. (2017) (15)
- Exclusive C-Si bond formation upon reaction of a platinum(II) alkyl with silanes (1998) (14)
- Catalytic Oxidative Deamination by Water with H2 Liberation (2020) (14)
- Template catalysis by manganese pincer complexes: oxa- and aza-Michael additions to unsaturated nitriles (2019) (14)
- Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C–C Bond Formation (2020) (14)
- Synthesis and reactivity of the methylene arenium form of a benzyl cation, stabilized by complexation. (2006) (14)
- Isolation and chemical properties of ruthenium and iron hydroxymethyl complexes (η5-C5H5)M(CO)2CH2OH (1983) (14)
- Catalytic transformation of benzoic anhydrides into fluorenones and biphenyls (1970) (14)
- Efficient Base-Free Aqueous Reforming of Methanol Homogeneously Catalyzed by Ruthenium Exhibiting a Remarkable Acceleration by Added Catalytic Thiol (2021) (13)
- Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. (2004) (13)
- Heterogeneously catalyzed selective hydrogenation of amides to alcohols and amines (2018) (13)
- Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents. (2015) (13)
- Homogeneous Reforming of Aqueous Ethylene Glycol to Glycolic Acid and Pure Hydrogen Catalyzed by Pincer-Ruthenium Complexes Capable of Metal-Ligand Cooperation. (2020) (13)
- Metal—Ligand Cooperation (2015) (13)
- Synthesis, structure, and reactivity of rhodium and iridium complexes of the chelating bis-sulfoxide tBuSOC2H4SOtBu. Selective O-H activation of 2-hydroxy-isopropyl-pyridine. (2008) (12)
- New ruthenium nitrosyl pincer complexes bearing an O2 ligand. Mono-oxygen transfer. (2015) (12)
- Catalytic Furfural/5-Hydroxymethyl Furfural Oxidation to Furoic Acid/Furan-2,5-dicarboxylic Acid with H2 Production Using Alkaline Water as the Formal Oxidant (2022) (12)
- Metal-dependent stabilization of Si-S bonds to hydrolysis in iridium and rhodium silyls. Hydrolyzability as a probe for Si-H reductive elimination (1996) (12)
- Polarizable stilbazole-based organometallic complexes and polymers (1993) (12)
- Metal-Controlled Reactivity of a Pincer-type, σ-Coordinated Naphthyl Radical Anion (2006) (12)
- Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides (2020) (12)
- Formation of iridalactones by CH2-O oxidative addition of propiolactone to iridium(I) (1990) (11)
- Ketone hydrogenation catalyzed by a new iron(II)–PNN complex (2016) (11)
- Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine-based Pincer Ligands: Isolation of a Photochemical Hofmann-Martius-type Intermediate. (2020) (10)
- Lanthanide-organic framework of a rigid bis-Gd complex: Composed by carbonate ions spacers (2010) (10)
- Formation of P,C-chelated palladium complexes by phosphine-assisted oxidative addition of an aliphatic CCl bond (1995) (10)
- The impact of weak C-H...Rh interactions on the structure and reactivity of trans-[Rh(CO)2(phosphine)2]+: an experimental and theoretical examination. (2008) (10)
- Mechanistic Investigations of Ruthenium Catalyzed Dehydrogenative Thioester Synthesis and Thioester Hydrogenation (2021) (9)
- Processes Involved in the Reduction of a Cyclometalated Palladium(II) Complex (2008) (9)
- A Reversible Liquid Organic Hydrogen Carrier System Based on Methanol‐Ethylenediamine and Ethylene Urea (2019) (9)
- CO2 activation by metal−ligand-cooperation mediated by iridium pincer complexes (2018) (9)
- Iridium-silanol complexes from direct oxidative addition of silanols to Ir(I). Synthesis and X-ray structure of the metallosilanolate [(Et3P)2Ir(H)(Cl)(SiiPr2OLi)] 2 (1995) (9)
- Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis. (2013) (9)
- Is Rh(PMe3)3+ formed upon anion exchange of Rh(PMe3)4+CI−? Crystal and molecular structure of Rh(PMe3)4+BPh4− and Ir(PMe3)4+PF6− (1990) (8)
- Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines (2020) (8)
- Electron Transfer Behavior of Pincer-Type {RhNO}8 Complexes: Spectroscopic Characterization and Reactivity of Paramagnetic {RhNO}9 Complexes (2013) (8)
- Near-Ambient-Temperature Dehydrogenative Synthesis of the Amide Bond: Mechanistic Insight and Applications (2021) (8)
- Benzyl Cation Stabilized by Metal Complexation. Relative Stability of Coordinated Methylene Arenium, π-Benzylic, and σ-Benzylic Structures (2013) (7)
- Bond Activation and Catalysis by Ruthenium Pincer Complexes (2015) (7)
- Manganese-Pincer-Catalyzed Nitrile Hydration, α-Deuteration, and α-Deuterated Amide Formation via Metal Ligand Cooperation (2021) (7)
- NO˙ disproportionation by a {RhNO}9 pincer-type complex. (2017) (6)
- Anionic d8 Alkyl Hydrides – Selective Formation and Reactivity of Anionic cis‐PtII Methyl Hydride (2010) (6)
- A Reversible Liquid-to-Liquid Organic Hydrogen Carrier System Based on Ethylene Glycol and Ethanol. (2020) (6)
- Electron-rich siloxane-platinum complexes - Synthesis, structures, and reactivity (2005) (6)
- DIMERIZATION OF TERMINAL EPOXIDES BY HOMOGENEOUS TRANSITION METAL COMPLEXES. A NOVEL SYNTHESIS OF CARBOXYLIC ESTERS (1978) (6)
- Synthesis of oxalamides by acceptorless dehydrogenative coupling of ethylene glycol and amines and the reverse hydrogenation catalyzed by ruthenium† (2020) (6)
- Quinone Methide Generation Based on a cis-(N,N) Platinum Complex (2007) (6)
- New ligand systems incorporating two and three 4,4'-bipyridine units. Characterization of bi- and trimetallic rhodium and iridium complexes. (2004) (6)
- Iridium- and rhodium-silanol complexes: Synthesis and reactivity (2003) (5)
- Hexamethylenetetramine formation by Ru-catalyzed methanol hydrogen transfer (1986) (5)
- Highly Active Pd(II) PCP-Type Catalysts for the Heck ReactionJ. Am. Chem. Soc.1997,119, 11687−11688 (1998) (5)
- Rational Design in Homogeneous Catalysis. Ir(I)-Catalyzed Addition of Aniline to Norbornylene via N-H Activation. (1989) (5)
- Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium–hydrogen bond (1988) (5)
- Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction. (1998) (5)
- ISOLATION, CHARACTERIZATION, AND INTERCONVERSIONS OF (ET3P)2IR(C2H4)NCL (N 1,2) (1996) (5)
- Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese (2018) (5)
- Magnesium Pincer Complexes and Their Applications in Catalytic Semihydrogenation of Alkynes and Hydrogenation of Alkenes: Evidence for Metal–Ligand Cooperation (2022) (5)
- Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes (2022) (5)
- Unprecedented Iron‐Catalyzed Selective Hydrogenation of Activated Amides to Amines and Alcohols. (2016) (5)
- Pincer Systems as Models for the Activation of Strong Bonds: Scope and Mechanism (2007) (4)
- Electrophilic ligand abstraction from electron-rich iridium(I) complexes with Me3SiOTf; evidence for direct ligand attack (1994) (4)
- Formal oxidative addition of a C-H bond by a 16e iridium(i) complex involves metal-ligand cooperation. (2018) (4)
- Synthesis, structure and reactivity of NO+, NO˙ and NO- pincer PCN-Rh complexes. (2020) (4)
- Sustainable catalysis with fluxional acridine-based PNP pincer complexes (2022) (4)
- Conversion of alcohols to carboxylates using water and base with H 2 liberation (2018) (4)
- Synthesis and Reactivity of Cationic Boron Complexes Distorted by Pyridine‐based Pincer Ligands: Isolation of a Photochemical Hofmann–Martius‐type Intermediate (2020) (4)
- Aliphatic and aromatic C–H activation of benzo[h]quinolines by Rh(I). Unique precursor dependent formation of mono-, di- and trinuclear complexes (2011) (4)
- Catalysis by Pincer Complexes: Synthesis of Esters, Amides, and Peptides (2014) (4)
- ‘Caging’ of and catalysis by a complex inside a polymer matrix (1990) (3)
- Recent Topics in Cooperative Catalysis: Asymmetric Catalysis, Polymerization, Hydrogen Activation, and Water Splitting (2012) (3)
- Why Does the Tetrakis(trimethylphosphine)iridium(III) Hydridochloride Cation Adopt the Sterically and Electronically Unfavorable Cis Geometry (2000) (3)
- C−C Bond Formation of Benzyl Alcohols and Alkynes Using a Catalytic Amount of KOt Bu: Unusual Regioselectivity through a Radical Mechanism (2019) (3)
- Transition‐Metal‐Catalyzed C‐C Bond Formation via C‐H Activation. Intermolecular Hydroacylation: The Addition of Aldehydes to Alkenes. (1988) (3)
- Preparation and Characterization of Poly(styrene-divinylbenzene)-Supported Catalysts (1982) (3)
- Catalytic System for the Heck Reaction of Fluorinated Haloaryls. (2005) (3)
- Rhodaoxetane: Synthesis, Structure, and Theoretical Evaluation. (1993) (2)
- Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia (2022) (2)
- Ruthenium Pincer‐Catalyzed Acylation of Alcohols Using Esters with Liberation of Hydrogen under Neutral Conditions. (2011) (2)
- Ru‐Catalyzed Oxidative Coupling of Arenes with Olefins Using O2. (2001) (2)
- Cover Picture: Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex (Angew. Chem. Int. Ed. 9/2011) (2011) (2)
- Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes (2022) (2)
- Manganese Catalyzed Hydrogenation of Azo (N=N) Bonds to Amines (2021) (2)
- C—C versus C—H Bond Oxidative Addition in PCX (X = P,N,O) Ligand Systems: Facility, Mechanism, and Control (2005) (2)
- Quinone Methide Stabilization by Metal Complexation (2009) (2)
- Formation, Structures, and Reactivity of cis-Hydroxy-, cis-Methoxy-, and cis-Mercaptoiridium Hydrides. Oxidative Addition of Water to Ir(I). (1987) (2)
- C-F Bond Activation by Iridium(I). A Unique Process Involving P-C Bond Cleavage, P-F Bond Formation, and Net Retention of Oxidation State. (1991) (2)
- Palladium‐Catalyzed Cross‐Methylation of Aryl Chlorides by Stabilized Dimethylaluminum and ‐Gallium Reagents. (2000) (2)
- Iron-catalysed ring-opening metathesis polymerization of olefins and mechanistic studies (2022) (2)
- Activation of a Non‐Strained C‐C Bond with Platinum(II). (1997) (1)
- Electrification of a Milstein-type catalyst for alcohol reformation (2022) (1)
- Frontiers in Bond Activation by Electron‐Rich Metal Complexes (1996) (1)
- Manganese‐Catalyzed Environmentally Benign Dehydrogenative Coupling of Alcohols and Amines to Form Aldimines and H2: A Catalytic and Mechanistic Study. (2016) (1)
- Ruthenium Pincer-Catalyzed Cross-Dehydrogenative Coupling of Primary Alcohols with Secondary Alcohols under Neutral Conditions. (2013) (1)
- N-H Activation. Part 1. Oxidative Addition of Ammonia to Iridium(I). Isolation, Structural Characterization, and Reactivity of Amidoiridium Hydrides. (1987) (1)
- Catalytic Selective Cleavage of a Strong C—C Single Bond by Rhodium in Solution. (1998) (1)
- Aspects of Intermediacy of Carbalkoxymetal Complexes in CO Reactions (1989) (1)
- Organometallic chemistry of enols (2010) (1)
- Palladium‐Catalyzed Vinylation of Aryl Chlorides. Chelate Effect in Catalysis. (1992) (1)
- [2,6‐Bis[(bis(1‐methylethyl)phosphino‐P]methyl]‐3,5 dimethylphenyl]methyl‐C]tri‐fluoroacetato‐O)palladium (2002) (1)
- Titelbild: Efficient Hydrogenation of Ketones Catalyzed by an Iron Pincer Complex (Angew. Chem. 9/2011) (2011) (1)
- Dehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy (2022) (1)
- Efficient Hydrogenation of Biomass‐Derived Cyclic Di‐Esters to 1,2‐Diols. (2012) (1)
- Substituent effects on the McLafferty rearrangement of ionized 2‐(aryl)ethyl arylacetates (1981) (1)
- The Chemistry of Enols. Organometallic Chemistry of Enols (1991) (0)
- Sustainable amidation through acceptorless dehydrogenative coupling by pincer-type catalysts: recent advances (2023) (0)
- Homogeneously Catalyzed, Chelate Assisted Hydrogenolysis of an Amine C—N Bond. (2000) (0)
- New process for production of metal-carbene complex (2002) (0)
- Highly Active PdII Cyclometalated Imine Catalysts for the Heck Reaction. (2010) (0)
- Advances in Metal Chemistry of Quinonoid Compounds: New Types of Interactions Between Metals and Aromatics (2001) (0)
- Synthesis and Molecular Structures of a Rhoda-Lactone and Its Alkylation Product. Insertion of a Pendant Alkyne into a Rhodium-Hydrogen Bond. (1989) (0)
- Clarification of a Remarkable Chelate Effect Leads to Palladium- Catalyzed Base-Free Olefin Arylation. (1994) (0)
- Discovery of the first metalloquinone (2000) (0)
- Occurrence of redwing Warbler Heliolais Erythroptera and some other observations from the Northern Kruger National Park (1981) (0)
- Designing New Magnesium Pincer Complexes for Catalytic Hydrogenation of Imines and N-Heteroarenes: H2 and N–H Activation by Metal–Ligand Cooperation as Key Steps (2023) (0)
- System with Potential Dual Modes of Metal‐Ligand Cooperation: Highly Catalytically Active Pyridine‐Based PNNH—Ru Pincer Complexes. (2015) (0)
- Formation of Iridalactones by CH2-O Oxidative Addition of Propiolactone to Iridium(I). (1990) (0)
- Synthesis and X-Ray Structure of a Simple Metallaoxetane. Metal-Based Selectivity in Oxidative Addition. (1990) (0)
- Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal-Ligand Cooperation (2011) (0)
- Formylation of Aryl Chlorides Catalyzed by a Palladium Complex. (1990) (0)
- Recent Advances in the Applications of Metal-Ligand Cooperation via Dearomatization and Aromatization of Pincer Complexes (2020) (0)
- Ruthenium, [6‐[[Bis(1,1‐dimethylethyl)phosphino‐κP] methylene]‐N,N‐diethyl‐1,6‐dihydro‐2‐pyridinemethanaminato‐κN1,κN2]carbonylhydride (2009) (0)
- Chelate-Assisted, Pd-Catalyzed Efficient Carbonylation of Aryl Chlorides. (1990) (0)
- BIRDS ASSOCIATED WITH PAFURI GALLERY FOREST (1989) (0)
- Formation of Tertiary Amides and Dihydrogen by Dehydrogenative Coupling of Primary Alcohols with Secondary Amines Catalyzed by Ruthenium Bipyridine‐Based Pincer Complexes. (2014) (0)
- Nitric oxide disproportionation mediated by a Rh complex with an asymmetric pincer ligand: spectroscopic detection of a dinitrosyl intermediate (2023) (0)
- Highly Active PdII Cyclometalated Imine Catalyst for the Suzuki Reaction. (2000) (0)
- Foreword by the Guest Editor of this Issue (1990) (0)
- Oxidationof Alkenes by Water with H2 Liberation (2020) (0)
- CCDC 211933: Experimental Crystal Structure Determination (2003) (0)
- Lanthanide-organic frameworks of bis-Gd complexes: composed by carbonate ions spacers (2011) (0)
- POLY(STYRENE-DIVINYLBENZENE)-SUPPORTED CATALYSTS: PREPARATION AND CHARACTERIZATION. (1981) (0)
- Metal Isertion into C—C Bonds in Solution (1999) (0)
- Transformations in Chemical Synthesis Applications of Acceptorless Dehydrogenation and Related (2014) (0)
- (Hydroxyacetyl)iridium and -rhodium Complexes: Model Compounds for CO Hydrogenation. (1986) (0)
- Transition-Metal-Catalyzed Cyclization of Alkynoic Acids to Alkylidene Lactones. (1988) (0)
- Selective Activation of Alkyl- and Aryl-Oxygen Single Bonds in Solution with Transition-Metal Complexes. (1997) (0)
- Z‐Selective (Cross‐)Dimerization of Terminal Alkynes Catalyzed by an Iron Complex. (2016) (0)
- Mononuclear Rh(II) PNP-type complexes. Structure and reactivity (2008) (0)
- Direct Synthesis of Primary Amines from Alcohols and Ammonia (2009) (0)
- Manganese(I)-Pincer Catalyzed α-Alkylation of Sulfones by Alcohols (2023) (0)
- Metal-controlled reactivity of a pincer-type, sigma-coordinated naphthyl radical anion. (2006) (0)
- Bond activation by metal complexes. The desing of new catalysis (1997) (0)
- Bond Activation by Metal Complexes: Special Issue in Honor of the 2017 Wolf Prize Laureate in Chemistry, Professor Robert G. Bergman (2017) (0)
- Easy Cleavage of the N-H Bond of Ammonia. (2010) (0)
- Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with Alcohols or Esters Catalysed by a Manganese Pincer Complex (2017) (0)
- Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines (2022) (0)
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