David P Goldberg
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Computer Science
David P Goldberg's Degrees
- PhD Computer Science Stanford University
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(Suggest an Edit or Addition)David P Goldberg's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective. (2016) (201)
- Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes. (2017) (182)
- Valence tautomerism in a high-valent manganese-oxo porphyrinoid complex induced by a Lewis acid. (2012) (146)
- Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: evidence for a "third oxidant" in high-valent porphyrinoid oxidations. (2004) (135)
- Unprecedented rate enhancements of hydrogen-atom transfer to a manganese(V)-oxo corrolazine complex. (2010) (125)
- Hydrogen atom abstraction by a high-valent manganese(V)-oxo corrolazine. (2006) (115)
- Corrolazines: new frontiers in high-valent metalloporphyrinoid stability and reactivity. (2007) (114)
- EPR SPECTRA FROM EPR-SILENT SPECIES : HIGH-FIELD EPR SPECTROSCOPY OF MANGANESE(III) PORPHYRINS (1997) (104)
- Recent advances in the chemistry of corroles and core-modified corroles (2004) (103)
- Synthesis and characterization of trinuclear iron(II) and manganese(II) carboxylate complexes : structural trends in low valent iron and manganese carboxylates (1992) (98)
- High-Frequency and -Field Electron Paramagnetic Resonance of High-Spin Manganese(III) in Porphyrinic Complexes. (1999) (92)
- A stable manganese(V)-oxo corrolazine complex. (2002) (91)
- O2 activation by bis(imino)pyridine iron(II)-thiolate complexes. (2011) (89)
- A Balancing Act: Stability versus Reactivity of Mn(O) Complexes. (2015) (84)
- Secondary Coordination Sphere Influence on the Reactivity of Nonheme Iron(II) Complexes: An Experimental and DFT Approach (2013) (81)
- Syntheses, Structures, and Magnetic Properties of Two Dinuclear Iron(III) Citrate Complexes (1994) (74)
- Catalytic reactivity of a meso-N-substituted corrole and evidence for a high-valent iron-oxo species. (2009) (71)
- A Decanuclear Manganese Cluster with Oxo and Halide Bridging Ligands: Magnetic Behavior of an S .gtoreq. 12 System (1995) (69)
- Iron(II)-thiolate S-oxygenation by O2: synthetic models of cysteine dioxygenase. (2010) (67)
- An example of O2 binding in a cobalt(II) corrole system and high-valent cobalt-cyano and cobalt-alkynyl complexes. (2004) (67)
- A manganese(V)-oxo π-cation radical complex: influence of one-electron oxidation on oxygen-atom transfer. (2011) (66)
- Synthesis, characterization, and physicochemical properties of manganese(III) and manganese(V)-oxo corrolazines. (2005) (66)
- Synthesis of the first corrolazine: a new member of the porphyrinoid family. (2001) (66)
- Octalkoxy-substituted phosphorus(V) triazatetrabenzcorroles via ring contraction of phthalocyanine precursors. (2003) (65)
- Singlet versus Triplet Reactivity in an Mn(V)-Oxo Species: Testing Theoretical Predictions Against Experimental Evidence. (2016) (62)
- Addition of dioxygen to an N4S(thiolate) iron(II) cysteine dioxygenase model gives a structurally characterized sulfinato-iron(II) complex. (2012) (62)
- Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex. (2017) (62)
- Generation of an isolable, monomeric manganese(V)-oxo complex from O2 and visible light. (2012) (61)
- A high-valent iron-oxo corrolazine activates C-H bonds via hydrogen-atom transfer. (2012) (60)
- Electron- and hydride-transfer reactivity of an isolable manganese(V)-oxo complex. (2011) (57)
- Preparation of non-heme {FeNO}7 models of cysteine dioxygenase: sulfur versus nitrogen ligation and photorelease of nitric oxide. (2013) (55)
- Direct Observation of a Nonheme Iron(IV)–Oxo Complex That Mediates Aromatic C–F Hydroxylation (2014) (54)
- H2O2 oxidations catalyzed by an iron(III) corrolazine: avoiding high-valent iron-oxido species? (2007) (53)
- Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes. (2008) (53)
- Factors Affecting Hydrogen Atom Transfer Reactivity of Metal-Oxo Porphyrinoid Complexes. (2018) (53)
- Oxygen-Atom Transfer Reactivity of Axially Ligated Mn(V)–Oxo Complexes: Evidence for Enhanced Electrophilic and Nucleophilic Pathways (2014) (52)
- Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres (2014) (51)
- A decanuclear mixed-valent manganese complex with a high spin multiplicity in the ground state (1993) (50)
- Characterization of the first N2S(alkylthiolate)lead compound: a model for three-coordinate lead in biological systems. (2006) (49)
- New monomeric cobalt(II) and zinc(II) complexes of a mixed N,S(alkylthiolate) ligand: model complexes of (His)(His)(Cys) metalloprotein active sites. (2002) (49)
- Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex. (2015) (46)
- Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid (2014) (46)
- Epoxidations catalyzed by manganese(V) oxo and imido complexes: role of the oxidant-Mn-oxo (imido) intermediate. (2010) (45)
- Sulfur oxygenation in biomimetic non-heme iron-thiolate complexes. (2012) (44)
- A Reactive Manganese(IV)-Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds. (2018) (43)
- Generation of a high-valent iron imido corrolazine complex and NR group transfer reactivity. (2013) (42)
- Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction. (2015) (42)
- High-valent transition metal corrolazines. (2006) (41)
- Influence of the nitrogen donors on nonheme iron models of superoxide reductase: high-spin Fe(III)-OOR complexes. (2010) (40)
- Strong Inhibition of O-Atom Transfer Reactivity for Mn(IV)(O)(π-Radical-Cation)(Lewis Acid) versus Mn(V)(O) Porphyrinoid Complexes. (2015) (40)
- Aromatic C-F Hydroxylation by Nonheme Iron(IV)-Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations. (2016) (38)
- High-Valent Manganese-Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C-H Bond Cleavage. (2016) (38)
- Star porphyrazines and related multimetallic macrocycles (1998) (37)
- Mechanism of S-oxygenation by a cysteine dioxygenase model complex. (2012) (36)
- Metal Ion Binding to Octakis(dimethylamino)porphyrazine: Core Coordination of Mn(III) and Peripheral Coordination of Pd(II) (1998) (35)
- A Nonheme, High-Spin {FeNO}8 Complex that Spontaneously Generates N2O. (2017) (33)
- Slow Magnetic Relaxation of [Et3NH]2Mn(CH3CN)4(H2O)2] [Mn10O4(biphen)4Br12] (biphen=2,2′-biphenoxide) at Very Low Temperature (1999) (31)
- Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2 with Manganese Porphyrins (2014) (31)
- Solitaire and gemini metallocene porphyrazines. (2001) (31)
- A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: implications for the mechanism of superoxide reductase. (2006) (31)
- Photochemical oxidation of a manganese(III) complex with oxygen and toluene derivatives to form a manganese(V)-oxo complex. (2013) (30)
- Copper(III) and vanadium(IV)-oxo corrolazines. (2004) (30)
- Hydrolysis of 4-nitrophenyl acetate by a (N2S(thiolate))zinc hydroxide complex: a model of the catalytically active intermediate for the zinc form of peptide deformylase. (2003) (28)
- Molybdocene Porphyrazines: A Peripheral Dithiolene Metallacycle Fused to a Porphyrinic Core. (1998) (26)
- Activation of Dioxygen by a Mononuclear Nonheme Iron Complex: Sequential Peroxo, Oxo, and Hydroxo Intermediates. (2019) (26)
- Model complexes of the active site in peptide deformylase: a new family of mononuclear N2S-M(II) complexes. (2001) (24)
- Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex. (2018) (24)
- A Nonheme Thiolate-Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity. (2019) (23)
- Dramatic Influence of an Anionic Donor on the Oxygen-Atom Transfer Reactivity of a MnV–Oxo Complex (2014) (23)
- Structures, Spectroscopic Properties, and Dioxygen Reactivity of 5- and 6-Coordinate Nonheme Iron(II) Complexes: A Combined Enzyme/Model Study of Thiol Dioxygenases. (2018) (22)
- Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere. (2014) (22)
- An isolable, nonreducible high-valent manganese(V) imido corrolazine complex. (2006) (22)
- Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals. (2019) (21)
- Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}(7) Complex with Dioxygen. (2016) (21)
- Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine. (2016) (21)
- Ferromagnetic versus Antiferromagnetic Exchange in Five Structurally Analogous Carboxylate-Bridged Trinuclear Ferrous Complexes (1995) (20)
- Synthesis, structures, and properties of a series of four-, five-, and six-coordinate cobalt(III) triazacorrole complexes: the first examples of transition metal corrolazines. (2002) (20)
- Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases. (2020) (20)
- X-ray absorption spectroscopy and reactivity of thiolate-ligated Fe(III)-OOR complexes. (2010) (20)
- A model complex of a possible intermediate in the mechanism of action of peptide deformylase: first example of an (N2S)zinc(II)-formate complex. (2001) (20)
- High-frequency and -field electron paramagnetic resonance of high-spin manganese(III) in tetrapyrrole complexes. (2002) (20)
- Synthesis and ligand non-innocence of thiolate-ligated (N4S) Iron(II) and nickel(II) bis(imino)pyridine complexes. (2013) (19)
- Inverse axial-ligand effects in the activation of H(2)O(2) and ROOH by an Mn(III) corrolazine. (2006) (18)
- The MCD spectroscopy of corrolazines and triazatetrabenzocorroles (2008) (16)
- Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies. (2019) (16)
- Mononuclear, dinuclear, and pentanuclear [[N,S(thiolate)]iron(II)] complexes: nuclearity control, incorporation of hydroxide bridging ligands, and magnetic behavior. (2005) (16)
- Phosphate triester hydrolysis promoted by an N2S(thiolate)Zn complex: mechanistic implications for the metal-dependent reactivity of peptide deformylase. (2005) (16)
- Hydroxyl Transfer to Carbon Radicals by Mn(OH) vs Fe(OH) Corrole Complexes. (2020) (15)
- Axial and equatorial ligand effects on biomimetic cysteine dioxygenase model complexes. (2012) (15)
- A (.mu.-Oxo)bis(.mu.-carboxylato)diiron(III) Complex with a Tethered Phenoxyl Radical as a Model for the Active Site of the R2 protein of Ribonucleotide Reductase (1995) (14)
- Geometric preferences in iron(II) and zinc(II) model complexes of peptide deformylase. (2006) (14)
- Evidence for the formation of a mononuclear ferric-hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(II) complex. (2009) (14)
- A Nonheme Sulfur-Ligated {FeNO}6 Complex and Comparison with Redox-Interconvertible {FeNO}7 and {FeNO}8 Analogues. (2018) (13)
- Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity. (2016) (13)
- Mechanistic Investigation of Oxygen Rebound in a Mononuclear Nonheme Iron Complex. (2019) (11)
- Complexes of a pendant phenoxyl radical ligand, including a new model for the ribonucleotide reductase R2 protein (1993) (11)
- Mononuclear, Nonheme, High-Spin {FeNO}7/8 Complexes Supported by a Sterically Encumbered N4S-Thioether Ligand. (2019) (10)
- A new bis(imidazolyl)(alkylthiolate) tripodal ligand and the spontaneous formation of a disulfide-linked, hydroxo-bridged dinuclear zinc complex. (2002) (10)
- The Influence of Peripheral Substituent Modification on P(V), Mn(III), and Mn(V)(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities. (2016) (10)
- 66 Synthesis and Reactivity of High-Valent Transition Metal Corroles and Corrolazines (2011) (10)
- A combinatorial approach to minimal peptide models of a metalloprotein active site. (2006) (9)
- A Nonheme Mononuclear {FeNO}7 Complex that Produces N2 O in the Absence of an Exogenous Reductant. (2021) (9)
- Preparation, size control, surface deposition, and catalytic reactivity of hydrophobic corrolazine nanoparticles in an aqueous environment. (2010) (9)
- Revisiting and re-engineering the classical zinc finger peptide: consensus peptide-1 (CP-1). (2016) (9)
- Sulfide Oxidation by O2: Synthesis, Structure and Reactivity of Novel Sulfide-Incorporated Fe(II) Bis(imino)pyridine Complexes. (2013) (9)
- Temperature-Dependent Reactivity of a Non-heme FeIII(OH)(SR) Complex: Relevance to Isopenicillin N Synthase. (2020) (8)
- Multiple bonding modes exhibited by heteroscorpionate N2S(alkylthiolate) ligands with Zn(II) and Fe(II) (2004) (6)
- CHAPTER 1:Dioxygen Binding and Activation Mediated by Transition Metal Porphyrinoid Complexes (2018) (6)
- Modeling Phenoxyl Radical Metalloenzyme Active Sites (1996) (6)
- A Mononuclear, Nonheme FeII-Piloty's Acid (PhSO2NHOH) Adduct: An Intermediate in the Production of {FeNO}7/8 Complexes from Piloty's Acid. (2019) (6)
- What Drives Radical Halogenation versus Hydroxylation in Mononuclear Nonheme Iron Complexes? A Combined Experimental and Computational Study (2022) (5)
- The hydrogen atom transfer reactivity of a porphyrinoid cobalt superoxide complex. (2019) (5)
- Sulfur Oxygenation in Biomimetic Non-Heme Iron-Thiolate Complexes (2012) (4)
- Methane Monooxygenase: Models and Mechanism (1993) (4)
- Oxidation of an indole substrate by porphyrin iron(iii) superoxide: relevance to indoleamine and tryptophan 2,3-dioxygenases. (2020) (4)
- Catalytic Function and Mechanism of Heme and Nonheme Iron(IV)–Oxo Complexes in Nature (2015) (3)
- A Reactive, Photogenerated High-Spin (S = 2) FeIV(O) Complex via O2 Activation. (2021) (3)
- A model complex of a possible intermediate in the mechanism of action of peptide deformylase: first example of an (N2S)zinc(ii)–formate complexElectronic supplementary information (ESI) available: synthesis and characterisation of compounds 1–3. See http://www.rsc.org/suppdata/cc/b1/b106865m/ (2001) (3)
- Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4). (2012) (3)
- Corrolazines: Novel porphyrinoid compounds capable of oxygen binding, stabilization of high-valent metal-oxo species, and more☆ (2003) (2)
- Evaluation of the Physicochemical Properties of the Iron Nanoparticle Drug Products: Brand and Generic Sodium Ferric Gluconate. (2021) (2)
- Halogen Transfer to Carbon Radicals by High-Valent Iron Chloride and Iron Fluoride Corroles. (2021) (2)
- Proton-Coupled Electron-Transfer Reactivity Controls Iron versus Sulfur Oxidation in Nonheme Iron-Thiolate Complexes. (2021) (1)
- An Iron(III) Superoxide Corrole from Iron(II) and Dioxygen. (2021) (1)
- Nonheme Iron(III) Azide and Iron(III) Isothiocyanate Complexes: Radical Rebound Reactivity, Selectivity, and Catalysis. (2022) (1)
- meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine. (2017) (1)
- Sulfur-Ligated, Oxidative Nonheme Iron Enzymes and Related Complexes (2020) (1)
- Iron Insertion at the Assembly Site of the ISCU Scaffold Protein Is a Conserved Process Initiating Fe-S Cluster Biosynthesis. (2022) (1)
- CCDC 1507912: Experimental Crystal Structure Determination (2016) (0)
- An Iron(III) Superoxide Corrole from Iron(II) and Dioxygen (2021) (0)
- H2O2 Oxidations Catalyzed by an Iron(III) Corrolazine: Avoiding High‐Valent Iron—Oxido Species? (2007) (0)
- Synthetic protobiology: the chemistry of life-like objects (2019) (0)
- CCDC 1510757: Experimental Crystal Structure Determination (2017) (0)
- High-Valent Transition-Metal Corrolazines (2006) (0)
- Synthesis and magnetochemistry of a new decanuclear manganese complex. (1993) (0)
- Synthetic Models of Peptide Deformylase (2005) (0)
- A Balancing Act: Stability Versus Reactivity of Mn(O) Complexes (2015) (0)
- Oxygen versus Sulfur Coordination in Cobalt Superoxo Complexes: Spectroscopic Properties, O2 Binding, and H-Atom Abstraction Reactivity. (2022) (0)
- Polynuclear iron and manganese complexes as models for biological systems (1995) (0)
- The Selective Monobromination of a Highly Sterically Encumbered Corrole: Structural and Spectroscopic Properties of Fe(Cl)(2-Bromo-5,10,15-tris(triphenyl)phenyl corrole). (2021) (0)
- Corrolazines: New Frontiers in High-Valent Metalloporphyrinoid Stability and Reactivity (2007) (0)
- Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex. (2022) (0)
- A Nonheme Mononuclear {FeNO} 7 Complex that Produces N 2 O in the Absence of an Exogenous Reductant (2021) (0)
- Hydrolysis of 4-nitrophenyl acetate by a novel (N2S)zinc-hydroxide complex: A kinetic and thermodynamic study of a reactive peptide deformylase model (2003) (0)
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