Dennis P. Curran
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American chemist
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Chemistry
Dennis P. Curran's Degrees
- Bachelors Chemistry University of Notre Dame
Why Is Dennis P. Curran Influential?
(Suggest an Edit or Addition)According to Wikipedia, Dennis P. Curran is an American organic chemist and a professor of chemistry at University of Pittsburgh known for his research in the fields of organic chemistry, radical chemistry, and fluorous chemistry.
Dennis P. Curran's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Catalysis of Radical Reactions: A Radical Chemistry Perspective. (2016) (724)
- Radical reactions in natural product synthesis (1991) (702)
- Handbook of fluorous chemistry (2004) (610)
- The electron is a catalyst. (2014) (414)
- The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 1 (1988) (387)
- Organocatalysis and C-H activation meet radical- and electron-transfer reactions. (2011) (374)
- Strategy-Level Separations in Organic Synthesis: From Planning to Practice. (1998) (351)
- Fluorous Synthesis: A Fluorous-Phase Strategy for Improving Separation Efficiency in Organic Synthesis (1997) (350)
- Stereochemistry of Radical Reactions (1995) (350)
- Atom transfer cyclization reactions of .alpha.-iodo esters, ketones, and malonates: examples of selective 5-exo, 6-endo, 6-exo, and 7-endo ring closures (1989) (340)
- Chemoselective oxidation of sulfides to sulfones with potassium hydrogen persulfate (1981) (337)
- Tandem Radical Reactions of Carbon Monoxide, Isonitriles, and Other Reagent Equivalents of the Geminal Radical Acceptor/Radical Precursor Synthon. (1996) (315)
- Oxygen switch in visible-light photoredox catalysis: radical additions and cyclizations and unexpected C-C-bond cleavage reactions. (2013) (307)
- Synthesis and reactions of N-heterocyclic carbene boranes. (2011) (305)
- Synthetic applications of fluorous solid-phase extraction (F-SPE). (2006) (271)
- Fluorous Mixture Synthesis: A Fluorous-Tagging Strategy for the Synthesis and Separation of Mixtures of Organic Compounds (2001) (241)
- Acyclic Stereochemical Control in Free-Radical Reactions (1991) (237)
- Reduction of .DELTA.2-isoxazolines. 3. Raney nickel catalyzed formation of .beta.-hydroxy ketones (1983) (225)
- N-heterocyclic carbene boryl radicals: a new class of boron-centered radical. (2009) (202)
- Fluorous chemistry: From biphasic catalysis to a parallel chemical universe and beyond (2002) (188)
- Fluorous Reverse Phase Silia Gel. A New Tool for Preparative Separations in Synthetic Organic and Organofluorine Chemistry (2001) (181)
- Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor. (2008) (181)
- Atroposelective Thermal Reactions of Axially Twisted Amides and Imides (1994) (179)
- EPR studies of the generation, structure, and reactivity of n-heterocyclic carbene borane radicals. (2010) (168)
- Benzotrifluoride: A Useful Alternative Solvent for Organic Reactions Currently Conducted in Dichloromethane and Related Solvents. (1997) (165)
- Fluorous Synthesis: Fluorous Protocols for the Ugi and Biginelli Multicomponent Condensations. (1997) (164)
- Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones. (2001) (161)
- Polarity reversal catalysis in radical reductions of halides by N-heterocyclic carbene boranes. (2012) (159)
- New Mechanistic Insights into Reductions of Halides and Radicals with Samarium(II) Iodide (2010) (150)
- Tris(2-(perfluorohexyl)ethyl)tin Hydride: A New Fluorous Reagent for Use in Traditional Organic Synthesis and Liquid Phase Combinatorial Synthesis (1996) (148)
- Altering the Stereochemistry of Allylation Reactions of Cyclic .alpha.-Sulfinyl Radicals with Diarylureas (1994) (147)
- Effects of temperature on atom transfer cyclization reactions of allylic .alpha.-iodo esters and amides (1991) (146)
- Fluorous synthesis with fewer fluorines (light fluorous synthesis): Separation of tagged from untagged products by solid-phase extraction with fluorous reverse-phase silica gel (1999) (144)
- Transition-Metal Aqua Complexes of 4,6-Dibenzofurandiyl-2,2‘-bis(4-phenyloxazoline). Effective Catalysis in Diels−Alder Reactions Showing Excellent Enantioselectivity, Extreme Chiral Amplification, and High Tolerance to Water, Alcohols, Amines, and Acids (1998) (138)
- The samarium grignard reaction. In situ formation and reactions of primary and secondary alkylsamarium(III) reagents (1992) (137)
- The novel silatecan 7-tert-butyldimethylsilyl-10-hydroxycamptothecin displays high lipophilicity, improved human blood stability, and potent anticancer activity. (2000) (135)
- Asymmetric thermal reactions with oppolzer's camphor sultam (1993) (134)
- Translocation of radical sites by intramolecular 1,5-hydrogen atom transfer (1988) (133)
- Radical translocation reactions of vinyl radicals : substituent effects on 1,5-hydrogen-transfer reactions (1993) (130)
- Additive and solvent effects on samarium diiodide reductions: the effects of water and DMPU (1993) (129)
- Synthesis and Claisen rearrangement of alkoxyallyl enol ethers. Evidence for a dipolar transition state (1987) (127)
- New 4+1 radical annulations. A formal total synthesis of (±)-camptothecin (1992) (127)
- Atom-transfer addition and annulation reactions of iodomalonates (1989) (126)
- Rate constants for halogen atom transfer from representative α-halocarbonyl compounds to primary alkyl radicals (1989) (126)
- Tandem radical approach to linear condensed cyclopentanoids. Total synthesis of (.+-.)-hirsutene (1985) (126)
- A samarium(II) iodide promoted tandem radical cyclization. The total synthesis of (.+-.)-hypnophilin and the formal synthesis of (.+-.)-coriolin (1988) (123)
- Generation and reactions of an unsubstituted N-heterocyclic carbene boryl anion. (2010) (122)
- Stereochemistry of Radical Reactions: Concepts, Guidelines, and Synthetic Applications (1996) (120)
- Thermal Allylations of Aldehydes with a Fluorous Allylstannane. Separation of Organic and Fluorous Products by Solid Phase Extraction with Fluorous Reverse Phase Silica Gel (1997) (118)
- tris(2-perfluorohexylethyl)tin azide: A new reagent for preparation of 5-substituted tetrazoles from nitriles with purification by fluorous/organic liquid-liquid extraction (1999) (117)
- Intramolecular .alpha.-amidoyl-to-aryl 1,5-hydrogen atom transfer reactions. Heteroannulation and .alpha.-nitrogen functionalization by radical translocation (1990) (117)
- 4 + 1 radical annulations with isonitriles : a simple route to cyclopenta-fused quinolines (1991) (115)
- Radical additions of aryl iodides to arenes are facilitated by oxidative rearomatization with dioxygen. (2006) (115)
- Synthesis, reaction, and recycle of light fluorous Grubbs-Hoveyda catalysts for alkene metathesis. (2005) (110)
- Acceleration of a dipolar Claisen rearrangement by Hydrogen bonding to a soluble diaryl^urea (1995) (109)
- Reduction of .DELTA.2-isoxazolines: a conceptually different approach to the formation of aldol adducts (1982) (109)
- A General Synthetic Approach to the (20S)‐Camptothecin Family of Antitumor Agents by a Regiocontrolled Cascade Radical Cyclization of Aryl Isonitriles (1998) (107)
- On the scope of asymmetric nitrile oxide cycloadditions with Oppolzer's chiral sultam. Total syntheses of (+)-hepialone, (-)-(1R,3R,5S)-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane, and (-)-(1S)-7,7-dimethyl-6,8-dioxabicyclo[3.2.1]octane (1990) (107)
- Synergistic Effects of Peloruside A and Laulimalide with Taxoid Site Drugs, but Not with Each Other, on Tubulin Assembly (2006) (106)
- Atom transfer cyclization reactions of hex-5-ynyl iodides: synthetic and mechanistic studies (1989) (104)
- Borenium ion catalyzed hydroboration of alkenes with N-heterocyclic carbene-boranes. (2012) (101)
- Solution-phase preparation of a 560-compound library of individual pure mappicine analogues by fluorous mixture synthesis. (2002) (101)
- The preparation of optically active δ2- isoxazolines. A model for asymmetric induction in the non lewis acid catalyzed reactions of oppolzer's chiral sultam (1988) (100)
- N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization (2010) (100)
- Substitution reactions at tetracoordinate boron: synthesis of N-heterocyclic carbene boranes with boron-heteroatom bonds. (2010) (96)
- Separation-friendly Mitsunobu reactions: a microcosm of recent developments in separation strategies. (2004) (96)
- Fluorous tin hydrides: A new family of reagents for use and reuse in radical reactions (1999) (95)
- An enantiodirected cyclopentenone annulation. Synthesis of a useful building block for condensed cyclopentanoid natural products (1980) (95)
- Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution. (2013) (94)
- Stille Couplings with Fluorous Tin Reactants: Attractive Features for Preparative Organic Synthesis and Liquid-Phase Combinatorial Synthesis. (1996) (94)
- Radical cyclization approach to spirocyclohexadienones. (2005) (93)
- A short total synthesis of (±)-epimeloscine and (±)-meloscine enabled by a cascade radical annulation of a divinylcyclopropane. (2011) (90)
- Separation of "light fluorous" reagents and catalysts by fluorous solid-phase extraction: synthesis and study of a family of triarylphosphines bearing linear and branched fluorous tags. (2000) (90)
- Cascade Radical Reactions of Isonitriles: A Second‐Generation Synthesis of (20S)‐Camptothecin, Topotecan, Irinotecan, and GI‐147211C (1996) (89)
- Radical deoxygenation of xanthates and related functional groups with new minimalist N-heterocyclic carbene boranes. (2010) (88)
- Asymmetric radical addition, cyclization, and annulation reactions with Oppolzer's camphor sultam (1990) (88)
- A new chiral auxiliary for asymmetric thermal reactions: high stereocontrol in radical addition, allylation, and annulation reactions (1992) (86)
- New tandem radical cyclizations directed toward the synthesis of crinipellin A (1990) (86)
- Experimental and theoretical studies of substituent effects in hydrogen bond based molecular recognition of a zwitterion by substituted arylureas (1995) (85)
- Electron paramagnetic resonance and computational studies of radicals derived from boron-substituted N-heterocyclic carbene boranes. (2011) (85)
- A Critical Evaluation of Studies Employing Alkenyl Halide 'Mechanistic Probe' as Indicators of Single Electron Transfer Processes. (1988) (85)
- Tubulin assembly, taxoid site binding, and cellular effects of the microtubule-stabilizing agent dictyostatin. (2005) (84)
- Atom-transfer cyclization. A novel isomerization of hex-5-ynyl iodides to iodomethylene cyclopentanes. (1986) (84)
- Synthesis of carbocyclic and heterocyclic fused quinolines by cascade radical annulations of unsaturated N-aryl thiocarbamates, thioamides, and thioureas. (2003) (84)
- A strategic alternative to solid phase synthesis: Preparation of a small isoxazoline library by “fluorous synthesis” (1997) (83)
- Potassium carbonate-silica: a highly effective stationary phase for the chromatographic removal of organotin impurities. (2010) (83)
- Quasienantiomers and quasiracemates: new tools for identification, analysis, separation, and synthesis of enantiomers. (2005) (83)
- Phase-vanishing reactions that use fluorous media as a phase screen. Facile, controlled bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide. (2002) (82)
- Radical Reactions of N-Heterocyclic Carbene Boranes with Organic Nitriles: Cyanation of NHC-Boranes and Reductive Decyanation of Malononitriles. (2015) (81)
- Rapid Fluorous Stille Coupling Reactions Conducted under Microwave Irradiation (1997) (81)
- Transfer of Chirality in Radical Cyclizations. Cyclization of o-Haloacrylanilides to Oxindoles with Transfer of Axial Chirality to a Newly Formed Stereocenter (1999) (81)
- Total synthesis of (-)-dictyostatin: confirmation of relative and absolute configurations. (2004) (79)
- Preparation of a fluorous benzyl protecting group and its use in fluorous synthesis approach to a disaccharide (1998) (79)
- Cationic Aqua Complexes of the C2-Symmetric trans-Chelating Ligand (R,R)-4,6-Dibenzofurandiyl-2,2′-bis(4-phenyloxazoline). Absolute Chiral Induction in Diels-Alder Reactions Catalyzed by Water-Tolerant Enantiopure Lewis Acids (1997) (78)
- Rotational features of carbon-nitrogen bonds in axially chiral o-tert-butyl anilides and related molecules. Potential substrates for the ‘prochiral auxiliary’ approach to asymmetric synthesis (1997) (76)
- Rate constants for the reactions of primary alkyl radicals with SmI2 in THF/HMPA (1993) (76)
- 4.1 – Radical Addition Reactions (1991) (75)
- ATOM TRANSFER ADDITION, ANNULATION AND MACROCYCLIZATION REACTIONS OF IODOMALONONITRILES (1990) (75)
- Radical-initiated polyolefinic cyclizations in condensed cyclopentanoid synthesis. Total synthesis of (±)-Δ9(12)-capnellene (1985) (74)
- Cyclizations of unsaturated .bul.CR(COX)2 radicals. Manganese(III) acetate oxidative cyclizations of unsaturated acetoacetates and atom-transfer cyclizations of unsaturated haloacetoacetates give the same radicals (1991) (74)
- Boryltrihydroborate: synthesis, structure, and reactivity as a reductant in ionic, organometallic, and radical reactions. (2010) (72)
- Fluorous mixture synthesis of stereoisomer libraries: total syntheses of (+)-murisolin and fifteen diastereoisomers. (2004) (72)
- Tandem radical reactions of isonitriles with 2-pyridonyl and other aryl radicals: Scope and limitations, and a first generation synthesis of (±)-camptothecin (1996) (72)
- Palladium-promoted cascade reactions of isonitriles and 6-iodo-N-propargylpyridones: synthesis of mappicines, camptothecins, and homocamptothecins. (2002) (72)
- High-Speed, Highly Fluorous Organic Reactions (1999) (71)
- Novel A,B,E-ring-modified camptothecins displaying high lipophilicity and markedly improved human blood stabilities. (1999) (71)
- Insertion of reactive rhodium carbenes into boron-hydrogen bonds of stable N-heterocyclic carbene boranes. (2013) (70)
- N-Heterocyclic carbene boranes are good hydride donors. (2012) (70)
- Relaying asymmetry of transient atropisomers of o-iodoanilides by radical cyclizations. (2005) (70)
- Radical translocation reactions of o-iodoanilides: the use of carbon-hydrogen bonds as precursors of radicals adjacent to carbonyl groups (1991) (69)
- Asymmetric induction in nitrile oxide cycloadditions to optically active acrylates. Comparisons of acrylate conformations in thermal and acid-catalyzed 1,3-dipolar and Diels-Alder cycloaddition transition states (1987) (69)
- Selective N-functionalization of 6-substituted-2-pyridones (1995) (68)
- Ionic and organometallic reductions with N-heterocyclic carbene boranes. (2009) (68)
- The parent borylene: betwixt and between. (2012) (68)
- Potent topoisomerase I inhibition by novel silatecans eliminates glioma proliferation in vitro and in vivo. (1999) (67)
- Fluorous Boc ((F)Boc) carbamates: new amine protecting groups for use in fluorous synthesis. (2001) (67)
- N-heterocyclic carbene boranes accelerate type I radical photopolymerizations and overcome oxygen inhibition. (2012) (66)
- Selective mono-Claisen rearrangement of carbohydrate glycals. A chemical consequence of the vinylogous anomeric effect. (1987) (66)
- Quasiracemic synthesis: concepts and implementation with a fluorous tagging strategy to make both enantiomers of pyridovericin and mappicine. (2002) (66)
- Fluorous Mitsunobu reagents and reactions (2002) (65)
- Reduction of substituted .DELTA.2-isoxazolines. Synthesis of .beta.-hydroxy acid derivatives (1984) (64)
- Radical Reactions with Alkyl and Fluoroalkyl (Fluorous) Tin Hydride Reagents in Supercritical CO2 (1997) (64)
- Atom transfer cycloaddition. A facile preparation of functionalized (methylene)cyclopentanes (1987) (64)
- Rotational features of carbon-nitrogen bonds in N-aryl maleimides. Atroposelective reactions of o-tert-butylphenylmaleimides (1999) (64)
- Borenium-Catalyzed Hydroborations of Silyl-Substituted Alkenes and Alkynes with a Readily Available N-Heterocyclic Carbene–Borane (2013) (62)
- Evidence that palladium(0)-promoted cyclizations of unsaturated α-iodocarbonyls occur by an atom transfer mechanism (1990) (62)
- Estimated rate constants for hydrogen abstraction from N-heterocyclic carbene-borane complexes by an alkyl radical. (2010) (62)
- Synthesis of enantioenriched axially chiral anilides from atropisomerically enriched tartarate ortho-anilides. (2001) (61)
- A mild reductive conversion of oximes to ketones (1984) (61)
- Rate constants for chalcogen group transfers in bimolecular substitution reactions with primary alkyl radicals (1993) (60)
- Selective synthesis of (2Z,4E)-dienyl esters by ene-diene cross metathesis. (2007) (60)
- Sequential radical cyclization approach to propellane triquinanes. Total synthesis of (.+-.)-modhephene (1990) (59)
- Studies toward practical synthesis of (20S)-camptothecin family through catalytic enantioselective cyanosilylation of ketones: improved catalyst efficiency by ligand-tuning (2002) (59)
- Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox. (2009) (59)
- A new regioselective Heck vinylation with enamides. Synthesis and investigation of fluorous-tagged bidentate ligands for fast separation. (2003) (59)
- Asymmetric alkylation of aromatic aldehydes with diethylzinc catalyzed by a fluorous BINOL–Ti complex in an organic and fluorous biphase system (2000) (59)
- Total synthesis of a 28-member stereoisomer library of murisolins. (2006) (58)
- Synthesis and applications of a light-fluorous glycosyl donor. (2009) (58)
- Palladium-Catalyzed Stille Couplings with Fluorous Tin Reactants. (1997) (58)
- N-Allylation of anilides with chiral palladium catalysts: the first catalytic asymmetric synthesis of axially chiral anilides (2003) (57)
- Group Transfer Addition-Reactions of Methyl(Phenylseleno)Malononitrile to Alkenes (1994) (56)
- Asymmetric deprotonation of N,N-dihexyl-1-naphthamides to provide atropisomers of N,N-dihexyl-2-alkyl-1-naphthamides (1996) (56)
- Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes. (2011) (55)
- New chiral auxiliaries for thermal cycloadditions (1989) (55)
- Additions of malononitrile radicals to alkenes: new examples of 1,2-asymmetric induction in iodine and phenylselenium transfer reactions (1992) (55)
- Radical trans-Hydroboration of Alkynes with N-Heterocyclic Carbene Boranes. (2018) (54)
- New fluorous/organic biphasic systems achieved by solvent tuning. (2007) (54)
- Discodermolide/Dictyostatin hybrids: synthesis and biological evaluation. (2002) (54)
- Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes. (2017) (54)
- The highly lipophilic DNA topoisomerase I inhibitor DB-67 displays elevated lactone levels in human blood and potent anticancer activity. (2001) (53)
- Tandem radical cyclization approach to angular triquinanes. A short synthesis of (.+-.)-silphiperfol-6-ene and (.+-.)-9-episilphiperfol-6-ene (1986) (53)
- A Water-Compatible NHC-Borane: Photopolymerizations in Water and Rate Constants for Elementary Radical Reactions. (2012) (53)
- A recyclable fluorous organocatalyst for Diels-Alder reactions. (2006) (52)
- Memory of axial chirality in aryl radical phosphanylations. (2010) (52)
- Streamlined syntheses of (-)-dictyostatin, 16-desmethyl-25,26-dihydrodictyostatin, and 6-epi-16-desmethyl-25,26-dihydrodictyostatin. (2010) (52)
- Mechanistic and preparative studies of radical chain homolytic substitution reactions of N-heterocyclic carbene boranes and disulfides. (2013) (52)
- Benzotrifluoride and Derivatives: Useful Solvents for Organic Synthesis and Fluorous Synthesis (1999) (51)
- Fluorous mixture synthesis of (-)-dictyostatin and three stereoisomers. (2006) (51)
- Atom transfer cyclization reactions of α-iodo carbonyls (1987) (51)
- Molecular iodine initiates hydroborations of alkenes with N-heterocyclic carbene boranes. (2013) (51)
- N-Heterocyclic carbene-borane radicals as efficient initiating species of photopolymerization reactions under air (2011) (51)
- Synthesis and some reactions of the first chiral tin hydride containing a C2-symmetric binaphthyl substituent (1996) (51)
- Reactions of Boron-Substituted N-Heterocyclic Carbene Boranes with Triflic Acid. Isolation of a New Dihydroxyborenium Cation (2012) (50)
- Radical Cyclizations of Acylgermanes. New Reagent Equivalents of the Carbonyl Radical Acceptor Synthon (1997) (49)
- Preparation of NHC borane complexes by Lewis base exchange with amine- and phosphine-boranes. (2010) (49)
- Fluorous triphasic reactions: transportative deprotection of fluorous silyl ethers with concomitant purification. (2001) (49)
- Low-temperature heck reactions of axially chiral o-iodoacrylanilides occur with chirality transfer: implications for catalytic asymmetric heck reactions. (2007) (48)
- Amide-based protecting/radical translocating (PRT) groups. Generation of radicals adjacent to carbonyls by 1,5-hydrogen transfer reactions of o-iodoanilides (1994) (47)
- Photoaffinity labeling of the mammalian dopamine transporter (1989) (47)
- Substituent effects on the Claisen rearrangement. The accelerating effect of a 6-donor substituent (1984) (47)
- Organic-Fluorous Phase Switches: A Fluorous Amine Scavenger for Purification in Solution Phase Parallel Synthesis. (1999) (47)
- 7-Silylcamptothecins (silatecans): A new family of camptothecin antitumor agents (1997) (46)
- Synthesis and biological evaluation of (-)-dictyostatin and stereoisomers. (2007) (46)
- Synthesis of perfluoroalkyl-substituted aryl bromides and their purification over fluorous reverse phase silica (1998) (46)
- A versatile prodrug approach for liposomal core-loading of water-insoluble camptothecin anticancer drugs. (2002) (46)
- Fluorous Tags Unstick Messy Chemical Biology Problems (2008) (45)
- Systems cell biology knowledge created from high content screening. (2005) (45)
- Simultaneous preparation of four truncated analogues of discodermolide by fluorous mixture synthesis. (2002) (45)
- Recyclable fluorous chiral ligands and catalysts: asymmetric addition of diethylzinc to aromatic aldehydes catalyzed by fluorous BINOL–Ti complexes (2002) (45)
- Separations with Fluorous Silica Gel and Related Materials (2005) (45)
- Resolution of 1-(2-naphthyl)ethanol by a combination of an enzyme-catalyzed kinetic resolution with a fluorous triphasic separative reaction. (2002) (44)
- o-Bromo-p-methoxyphenyl Ethers. Protecting/Radical Translocating (PRT) Groups That Generate Radicals from C−H Bonds β to Oxygen Atoms (1996) (44)
- New chiral auxiliary for asymmetric thermal reactions: high regio- and .beta.-stereoselectivity in asymmetric radical addition reactions to mixed fumarimides (1991) (44)
- Synthesis and biological assessment of simplified analogues of the potent microtubule stabilizer (+)-discodermolide. (2003) (44)
- Understanding Initiation with Triethylboron and Oxygen: The Differences between Low-Oxygen and High-Oxygen Regimes. (2016) (44)
- Hydroxymethylation of organic halides. Evaluation of a catalytic system involving a fluorous tin hydride reagent for radical carbonylation (1997) (43)
- Iodine atom transfer addition reactions with alkynes. Part 2; α-iodocarbonyls (1991) (43)
- Silica gel promotes reductions of aldehydes and ketones by N-heterocyclic carbene boranes. (2012) (43)
- On the mechanism of the intramolecular samarium Barbier reaction. Probes for formation of radical and organosamarium intermediates (1997) (43)
- On the stereochemistry of the bis-nor-wieland-miescher ketome (1981) (43)
- Synthesis of dl-coriolin (1981) (43)
- Efficient hydroxymethylation reactions of iodoarenes using CO and 1,3-dimethylimidazol-2-ylidene borane. (2013) (42)
- Increasing fluorous partition coefficients by solvent tuning. (2005) (42)
- Synthesis of (S)-mappicine and mappicine ketone via radical cascade reaction of isonitriles (1997) (42)
- Iodine atom transfer addition reactions with alkynes. Part 1: Alkyl iodides (1991) (42)
- Weakly stabilized primary borenium cations and their dicationic dimers. (2013) (42)
- ADDITIVE AND MEDIUM EFFECTS ON LEWIS ACID-PROMOTED CATIONIC PI -CYCLIZATIONS OF ALKENYL- AND ALKYNYLCYCLOPENTANE-1,3-DIONES (1995) (41)
- Radical Reactions and Retrosynthetic Planning (1991) (41)
- Fluorous methods for synthesis and separation of organic molecules (2000) (41)
- Formation of N-heterocyclic carbene-boryl radicals through electrochemical and photochemical cleavage of the B-S bond in N-heterocyclic carbene-boryl sulfides. (2013) (41)
- Structure assignment of lagunapyrone B by fluorous mixture synthesis of four candidate stereoisomers. (2006) (41)
- Approximate absolute rate constants for the reactions of tributyltin radicals with aryl and vinyl halides (1991) (41)
- A Soluble Fluorous Palladium Complex that Promotes Heck Reactions and Can Be Recovered and Reused (2004) (41)
- Fluorous Synthesis of Hydantoin-, Piperazinedione-, and Benzodiazepinedione-Fused Tricyclic and Tetracyclic Ring Systems. (2006) (41)
- Preparation of a Fluorous Chiral BINOL Derivative and Application to an Asymmetric Protonation Reaction (2000) (41)
- Total synthesis and biological evaluation of C16 analogs of (-)-dictyostatin. (2007) (40)
- Radical and Heck cyclizations of diastereomeric o-haloanilide atropisomers. (2011) (40)
- Minimal fluorous tagging strategy that enables the synthesis of the complete stereoisomer library of SCH725674 macrolactones. (2012) (40)
- Use of fluorous silica gel to separate fluorous thiol quenching derivatives in solution-phase parallel synthesis (2002) (40)
- Regiochemical control in dihydrophenanthrene synthesis. A photochemical total synthesis of juncusol (1979) (40)
- Atom transfer cyclization of simple hexenyl iodides. A caution on the use of alkenyl iodides as probes for the detection of single electron transfer processes (1986) (39)
- Stereochemistry of hexenyl radical cyclizations with tert-butyl and related large groups: substituent and temperature effects. (2005) (39)
- Semi-Fluorinated Trialkyltin Fluorides and Fluorinated Telechelic Ionomers as Viscosity-Enhancing Agents for Carbon Dioxide (2001) (39)
- Catalytic enantioselective protonation of a samarium enolate with fluorous chiral and achiral proton sources in fluorous biphasic systems (1998) (39)
- Synthesis and biological evaluation of (-)-16-normethyldictyostatin: a potent analogue of (-)-dictyostatin. (2005) (38)
- Total synthesis of (-)-specionin (1987) (38)
- Recent applications of radical reactions in natural product synthesis (1993) (38)
- Heterocyclic alpha-alkylidene cyclopentenones obtained via a Pauson-Khand reaction of amino acid derived allenynes. A scope and limitation study directed toward the preparation of a tricyclic pyrrole library. (2005) (38)
- Reverse fluorous solid-phase extraction: a new technique for rapid separation of fluorous compounds. (2004) (38)
- Conjugate addition reactions of organosamarium species via in situ transmetalation to copper(I) salts (1992) (37)
- Synthesis and biological evaluation of purealin and analogues as cytoplasmic dynein heavy chain inhibitors. (2006) (37)
- REACTIONS OF TEMPO WITH ALKYLSAMARIUM AND OTHER ORGANOMETALLIC REAGENTS (1996) (37)
- Asymmetric reactions of axially chiral amides: use of removable ortho-substituents in radical cyclizations of o-iodoacrylanilides and N-allyl-N-o-iodoacrylamides (2004) (37)
- Synthesis and reactions of fluorous carbobenzyloxy (FCbz) derivatives of α-amino acids (2003) (37)
- Asymmetric radical cyclization reactions of axially chiral N -allyl- o -iodoanilides to form enantioenriched N -acyl dihydroindoles (2004) (36)
- Altering the Stereochemistry of Allylation Reactions of Cyclic .alpha.-Sulfinyl Radicals: Effects of Solvents and Lewis Acids (1994) (36)
- Synthesis and high content cell-based profiling of simplified analogues of the microtubule stabilizer (+)-discodermolide. (2002) (36)
- Enantioselective conjugate radical addition reactions mediated by chiral Lewis acid complexes of (R,R)-4,6-dibenzofurandiyl-2,2′-bis(4-phenyloxazoline) (DBFOX/Ph) (1999) (36)
- Radical cyclizations of cyclic ene sulfonamides occur with β-elimination of sulfonyl radicals to form polycyclic imines. (2013) (36)
- Regiocontrol in opening of 2H-cyclopenta[b]furanones with organocopper reagents (1986) (35)
- Synthesis of Boriranes by Double Hydroboration Reactions of N-Heterocyclic Carbene Boranes and Dimethyl Acetylenedicarboxylate. (2017) (35)
- 4.2 – Radical Cyclizations and Sequential Radical Reactions (1991) (35)
- Radical annulation reactions of allyl iodomalononitriles (1992) (35)
- How do analogous alpha-chloroenamides and alpha-iodoenamides give different product distributions in 5-endo radical cyclizations? (2008) (35)
- Fluorous techniques for the synthesis and separation of organic molecules (2001) (35)
- Confirmation of the stereostructure of (+)-cytostatin by fluorous mixture synthesis of four candidate stereoisomers. (2008) (34)
- New reagents for radical allylations (1992) (34)
- Synthesis of 1,3-Dialkylimidazol-2-ylidene Boranes from 1,3-Dialkylimidazolium Iodides and Sodium Borohydride. (2015) (34)
- Semisynthesis of DB-67 and other silatecans from camptothecin by thiol-promoted addition of silyl radicals. (2003) (34)
- On the proof and disproof of natural product stereostructures: characterization and analysis of a twenty-eight member stereoisomer library of murisolins and their Mosher ester derivatives. (2006) (34)
- RADICAL CYCLIZATIONS OF ACYLGERMANE OXIME ETHERS AND HYDRAZONES : DIRECT ROUTES TO CYCLIC HYDRAZONES AND OXIMES (1998) (34)
- Synthesis of all 16 stereoisomers of pinesaw fly sex pheromones--tools and tactics for solving problems in fluorous mixture synthesis. (2005) (33)
- Rate constants for reaction of a fluorous tin hydride reagent with primary alkyl radicals (1997) (33)
- Second generation fluorous DEAD reagents have expanded scope in the Mitsunobu reaction and retain convenient separation features. (2004) (33)
- Hydroboration of arynes with N-heterocyclic carbene boranes. (2014) (33)
- [3 + 2]-dipolar cycloaddition reactions of an N-heterocyclic carbene boryl azide. (2012) (33)
- Synthesis of β-mannopyranosides from α-epimers by radical inversion (1994) (33)
- Asymmetric radical and anionic cyclizations of axially chiral carbamates. (2009) (33)
- Oxidative aryl-benzyl coupling. A biomimetic entry to podophyllin lignan lactones. (1977) (33)
- Approximate rate constants for the addition of alkyl radicals to allylstannanes (1990) (33)
- The Tandem Radical Cyclization Approach to Angular Triquinanes (1987) (33)
- Synthesis of highly enantioenriched 3,4-dihydroquinolin-2-ones by 6-exo-trig radical cyclizations of axially chiral alpha-halo-ortho-alkenyl anilides. (2009) (33)
- Radical carbonylations with fluorous allyltin reagents (1999) (33)
- Reduction of Δ2-isoxazolines-2. A facile synthesis of 3(2H)-furanones. (1983) (32)
- Assignment of the structure of petrocortyne A by mixture syntheses of four candidate stereoisomers. (2010) (32)
- Tandem transannular radical cyclizations. Total syntheses of (±)-modhephene and (±)-epi-modhephene (1993) (32)
- A strategy for radical annulation based on allyl and vinyl stannanes (1989) (32)
- Cram's rule for radical reactions (1991) (32)
- Free at last! (2012) (32)
- Ring-closing metathesis approach to dictyostatin. (2005) (32)
- Intramolecular hydrogen transfer reactions of o-(bromophenyl)dialkylsilyl ethers. Preparation of rapamycin-d1 (1992) (32)
- Asymmetric total synthesis of (20R)-homocamptothecin, substituted homocamptothecins and homosilatecans (2002) (31)
- Fluorous dienophiles are powerful diene scavengers in Diels-Alder reactions. (2003) (31)
- Stereoisomer libraries: total synthesis of all 16 stereoisomers of the pine sawfly sex pheromone by a fluorous mixture-synthesis approach. (2004) (31)
- Simplified discodermolide analogues: synthesis and biological evaluation of 4-epi-7-dehydroxy-14,16-didemethyl-(+)-discodermolides as microtubule-stabilizing agents. (2003) (31)
- 1,2-Asymmetric induction in radical reactions. Deuteration and allylation reactions of β-oxy-α-bromo esters (1993) (31)
- DIRECTED NITRILE OXIDE CYCLOADDITION REACTIONS. THE USE OF HYDROGEN BONDING TO DIRECT REGIO- AND STEREOCHEMISTRY IN NITRILE OXIDE CYCLOADDITIONS WITH CYCLOPENTENYLAMIDES (1990) (31)
- Controlling Radical Chain Reactions by Unimolecular Chain Transfer. Intramolecular Hydrogen Transfer Reactions of Silicon Hydrides (1995) (31)
- Asymmetric Induction in [3 + 2] Dipolar Cycloaddition Reactions of Nitrile Oxides with Chiral (α-Oxyallyl)silanes (1988) (31)
- Solution-phase mixture synthesis with fluorous tagging en route: total synthesis of an eight-member stereoisomer library of passifloricins. (2006) (31)
- CBS reductions with a fluorous prolinol immobilized in a hydrofluoroether solvent. (2008) (30)
- Sequential Radical Cyclization/Organometallic Addition. On the Mechanism of the Samarium(II) Mediated Barbier Reaction in the Presence of Hexamethylphosphoric Triamide (1990) (29)
- Stereoselective hydrogen transfer reactions of vinyl radicals: Cyclization of alkynyl iodides by Unimolecular Chain Transfer from silicon hydrides (1997) (29)
- Cell-Based and Biochemical Structure-Activity Analyses of Analogs of the Microtubule Stabilizer Dictyostatin (2008) (29)
- Intramolecular carbozincation of unactivated alkenes occurs through a zinc radical transfer mechanism. (2007) (29)
- The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 2. (1988) (28)
- New Sequential Carbon-Carbon Bond Forming Reactions. A Samarium(II) Iodide Mediated Vinylogous Barbier Reaction Followed by an Aldol Reaction (1991) (28)
- Atom transfer addition and annulation reactions of propargyl iodomalononitrile (1992) (28)
- Radical translocation reactions across amides. 1,5-Hydrogen-transfer reactions of o-iodobenzamides and N-(o-iodobenzyl) amides (1994) (28)
- Esters as Radical Acceptors: β-NHC-Borylalkenyl Radicals Induce Lactonization by C-C Bond Formation/Cleavage on Esters. (2019) (28)
- Synthesis and evaluation of a novel E-ring modified alpha-hydroxy keto ether analogue of camptothecin. (2002) (28)
- Synthesis and Suzuki Reactions of N-Heterocyclic Carbene Difluoro(aryl)-boranes. (2015) (28)
- Solution-phase parallel synthesis with oligoethylene glycol sorting tags. Preparation of all four stereoisomers of the hydroxybutenolide fragment of murisolin and related acetogenins. (2006) (28)
- Binary fluorous tagging enables the synthesis and separation of a sixteen-stereoisomer library of macrosphelides (2011) (27)
- Hydroboration of Arynes Formed by Hexadehydro-Diels-Alder Cyclizations with N-Heterocyclic Carbene Boranes. (2015) (27)
- Selective sulfonylation of 1,2-diols and derivatives catalyzed by a recoverable fluorous tin oxide (2000) (27)
- 1,4-Hydroboration reactions of electron-poor aromatic rings by N-heterocyclic carbene boranes. (2020) (27)
- Radical [3 + 2]-annulation of divinylcyclopropanes: rapid synthesis of complex meloscine analogs. (2014) (27)
- Disulfides and Boryl Sulfides Serve as both Initiators and Precatalysts in Radical Reductions of Halides by an N‐Heterocyclic Carbene⋅Borane (2013) (27)
- One product, two pathways: initially divergent radical reactions reconverge to form a single product in high yield. (2011) (27)
- Fluorous solvent as a new phase-screen medium between reagents and reactants in the bromination and chlorination of alcohols. (2003) (27)
- N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes. (2011) (26)
- 1,2-Asymmetric induction in radical reactions. Deuteration and allylation reactions of β-oxy-o-Iodoanilides. (1993) (26)
- Fluorous parallel synthesis of a piperazinedione-fused tricyclic compound library. (2009) (26)
- Parallel synthesis with fluorous reagents and reactants (1999) (26)
- Synthesis of perfluorinated allylic compounds by radical allylation and their purification over fluorous reverse-phase silica (2001) (26)
- Synthesis and biological assays of E-ring analogs of camptothecin and homocamptothecin. (2006) (26)
- Facile Synthesis of α-N-Heterocyclic Carbene-Boryl Ketones from N-Heterocyclic Carbene-Boranes and Alkenyl Triflates (2019) (26)
- A versatile route to the tulearin class of macrolactones: synthesis of a stereoisomer of tulearin A. (2009) (26)
- Thiol additions to acrylates by fluorous mixture synthesis: relative control of elution order in demixing by the fluorous tag and the thiol substituent (2001) (25)
- 5- Endo Cyclizations of NHC-Boraallyl Radicals Bearing Ester Substituents: Characterization of Derived 1,2-Oxaborole Radicals and Boralactones. (2018) (25)
- Synthesis of 2-functionalized allyl tris(trimethylsilyl)silanes (1996) (25)
- Use of allylic triflones for allylation of C-H bonds (1998) (25)
- Synthesis of Optically Active .alpha.-Hydroxy Lactones by Sharpless Asymmetric Dihydroxylations of Ketene Acetals, Enol Ethers, and Ene Lactones (1994) (25)
- "Propylene spaced" allyl tin reagents: a new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions. (1998) (25)
- UNSATURATED ACYLGERMANES ISOMERIZE BY A CHAIN MECHANISM INVOLVING RADICAL CYCLIZATION TO THE CARBONYL GROUP OF AN ACYLGERMANE (1991) (25)
- Second-generation tags for fluorous chemistry exemplified with a new fluorous Mitsunobu reagent. (2008) (25)
- Axially Chiral Enamides: Substituent Effects, Rotation Barriers, and Implications for their Cyclization Reactions. (2016) (24)
- The Electron is a Catalyst (2015) (24)
- Ring-Enlarging Annulations. A One-Step Conversion of Cyclic Silyl Acyloins and .omega.-Alkynyl Acetals to Polycyclic Enediones (1995) (24)
- Samarium(II) iodide mediated radical/polar crossover reactions of cyclobutenes. An efficient approach to the BCD ring system of the penitrems. (2003) (24)
- Thermolysis of bis[2-[(trimethylsilyl)oxy]propyl]furoxan (TOP-furoxan). The first practical method for intermolecular cycloaddition of an in situ generated nitrile oxide with 1,2-di- and trisubstituted olefins (1985) (24)
- Light, medium, and heavy fluorous triarylphosphines exhibit comparable reactivities to triphenylphosphine in typical reactions of triarylphosphines. (2005) (23)
- 2-Functionalized allyl tris(trimethylsilyl)silanes as radical-based allylating agents (1996) (23)
- Relative Reactivity of Stable Ligated Boranes and a Borohydride Salt in Rhodium(II)-Catalyzed Boron-Hydrogen Insertion Reactions. (2016) (23)
- A Simplified Synthesis of Novel Dictyostatin Analogues with In Vitro Activity against Epothilone B–Resistant Cells and Antiangiogenic Activity in Zebrafish Embryos (2011) (22)
- Total synthesis of (.+-.)-4'-demethyl-4-epipodophyllotoxin by insertion-cyclization (1981) (22)
- Reductive cleavage of highly substituted Δ2-isoxazolines. Synthesis of crispatic acid (1986) (22)
- Improved synthesis of 6-epi-dictyostatin and antitumor efficacy in mice bearing MDA-MB231 human breast cancer xenografts. (2008) (21)
- Nucleophilic additions to and reductiosn of 5-formyl-and 5-acyl-2-isoxazolines (4,5-dihydeoisoxazoles): a stereoselective route to β,γ-dihydroxy ketones (1991) (21)
- The renaissance of organic radical chemistry – deja vu all over again (2013) (21)
- Phase-vanishing methods based on fluorous phase screen: a simple way for efficient execution of organic synthesis. (2008) (21)
- Substrate-Controlled Group-Selective Radical Cyclizations. A New Strategy for Stereocontrolled Transformations of Diastereomeric Reactive Intermediates (1994) (21)
- Enantiomeric resolution by HPLC of axial chiral amides using amylose tris[(S)-1-phenylethylcarbamate]. (1997) (21)
- N-Heterocyclic Carbene Boryl Iodides Catalyze Insertion Reactions of N-Heterocyclic Carbene Boranes and Diazoesters. (2017) (21)
- Reductions of aldehydes and ketones with a readily available N-heterocyclic carbene borane and acetic acid (2013) (21)
- Solution-phase mixture synthesis with double-separation tagging: double demixing of a single mixture provides a stereoisomer library of 16 individual murisolins. (2005) (21)
- The Tin Hydride Reductive Decyanation of Geminal Dinitriles (1991) (21)
- A "shortcut" Mosher ester method to assign configurations of stereocenters in nearly symmetric environments. Fluorous mixture synthesis and structure assignment of petrocortyne A. (2009) (20)
- Tris(trimethylsilyl)silane as mediator in the radical-based allylation reactions of allyl and 2-functionalized allyl phenyl sulfones (1996) (20)
- Towards a tandem-radical macrocyclization-transannular cyclization approach to steroids: Transannular cyclizations of a macrocyclic core (1995) (20)
- Synthesis and spectroscopic analysis of a stereoisomer library of the phytophthora mating hormone α1 and derived bis-Mosher esters. (2011) (20)
- Solution phase synthesis of libraries of polycyclic natural product analogues by cascade radical annulation: synthesis of a 64-member library of mappicine analogues and a 48-member library of mappicine ketone analogues. (2000) (20)
- Reduction of 4,5-Dihydro-1,2-oxazoles (Δ2-Isoxazolines). A Cycloadditive Approach to 2-Alkenyl Ketones. (1986) (20)
- Neutral sulfur nucleophiles: synthesis of thioethers and thioesters by substitution reactions of N-heterocyclic carbene boryl sulfides and thioamides. (2014) (20)
- Light Fluorous Chemistry – A User's Guide (2005) (20)
- Radical and palladium-catalyzed cyclizations to cyclobutenes: an entry to the BCD ring system of penitrem D. (2004) (20)
- The Cascade Radical Annulation Approach to New Analogues of Camptothecins: Combinatorial Synthesis of Silatecans and Homosilatecans (2000) (20)
- Fluorous Reverse Phase Silica Gel. A New Tool for Preparative Separations in Synthetic Organic and Organofluorine Chemistry (2001) (20)
- Control of relative stereochemistry in the cycloadditive route to .beta.-hydroxy carbonyls. Regio- and stereoselective exo alkylation of .DELTA.2-isoxazolines (1987) (20)
- Fluorous diastereomeric mixture synthesis (FDMS) of hydantoin-fused hexahydrochromeno[4,3-b]pyrroles. (2010) (20)
- A general synthetic approach to optically active iridoid aglycones : The total syntheses of β-ethyl descarbomethoxyverbenalol, ethyl catalpol, and (-)-specionin (1988) (20)
- NHC-boranes: air- and water-tolerant co-initiators for type II photopolymerizations. (2012) (20)
- Unimolecular chain transfer (UMCT) reactions: concepts, preliminary results with silicon hydrides, and future potential (1995) (20)
- Additions of electrophilic radicals to electron rich alkenes by the atom transfer method. Surmounting potentially reversible radical atom transfer reactions by irreversible ionic reactions (1998) (19)
- Catalytic enantioselective synthesis of (20s)-camptothecin intermediates using cyanosilylation of ketones promoted by D-glucose-derived lanthanide catalyst (2003) (19)
- Rearrangement Reactions of 1,1-Divinyl-2-phenylcyclopropanes (2014) (19)
- 1,2-Asymmetric Induction in Reactions of Nonconjugated Acyclic Radicals: A New Model for Highly Selective Atom-Transfer Reactions of Alkyl-Substituted Radicals. (1993) (19)
- Microwave Heating Effects Rapid and Selective Decarboalkoxylation of Mono-Alkylated Malonates and β-Ketoesters (2003) (19)
- Formation of cyclopropanes by homolytic substitution reactions of 3- iodopropyl radicals: Preparative and rate studies (1999) (18)
- Stereoselective Synthesis of Alkenes by Using Unimolecular Chain Transfer Reactions of Silicon Hydrides (1995) (18)
- SYNTHESIS OF FUSED BICYCLIC RINGS BY TANDEM RADICAL RING EXPANSION/CYCLIZATION : EVALUATING COMPETING INTRAMOLECULAR REACTIONS (1998) (18)
- Stereoselective synthesis of 1,2-diols by the cycloadditive strategy: total synthesis of (±)-exo-brevicomin and (±)-and (–)-pestalotin (1991) (18)
- Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: slow addition in a test tube. (2004) (18)
- Ring lithiation and functionalization of imidazol-2-ylidene-boranes. (2011) (18)
- Radical trans -Hydroboration of Alkynes with N-Heterocyclic Carbene Boranes (2018) (18)
- Relative rates and approximate rate constants for inter- and intramolecular hydrogen transfer reactions of polymer-bound radicals. (2002) (18)
- Silatecan DB-67 is a novel DNA topoisomerase I-targeted radiation sensitizer. (2005) (18)
- A new class of chiral organogermanes derived from C2-symmetric dithiols: synthesis, characterization and stereoselective free radical reactions. (2003) (17)
- Hydrogen bond directed nitrile oxide cycloaddition reactions of allylic 2°-amides (1993) (17)
- Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC-BF2. ). (2018) (17)
- Amide bond formation with a new fluorous carbodiimide: separation by reverse fluorous solid-phase extraction. (2007) (17)
- Synthetic application of a substituent controlled claisen rearrangement. Preparation of advanced chiral intermediates for the synthesis of pseudomonic acids (1985) (17)
- New Applications of 1,5-Hydrogen Atom Transfer Reactions: Self-Oxidizing Protecting Groups (1992) (17)
- The isobenzofuran route to anthracyclinones (1977) (17)
- Dictyostatin flexibility bridges conformations in solution and in the β-tubulin taxane binding site. (2011) (17)
- Origins of regioselectivity in radical reactions of axially twisted anilides (1993) (16)
- Fluorous mixture synthesis of 4-alkylidene cyclopentenones via a rhodium-catalyzed [2+2+1] cycloaddition of alkynyl allenes. (2005) (16)
- Reductive Coupling and Reductive Demethoxylation of Aromatic Dimethylacetals with SmI2/Trifluoroacetic Acid, SmI2/BF3•Et2O, or SmI2/H2O (1996) (16)
- Fluorous Synthesis: A Fluorous‐Phase Strategy for Improving Separation Efficiency in Organic Synthesis (1997) (16)
- An approach to the enantiocontrolled synthesis of pseudomonic acids via a novel mono—claisen rearrangement (1982) (16)
- A Practical Asymmetric Synthesis of A Pseudomonic Acid Precursor from D-Arabinose or D-Xylose (1996) (16)
- Penultimate group effects in free radical telomerizations of acrylamides (1996) (16)
- Enantioselective α-Chlorination of Aldehydes with Recyclable Fluorous (S)-Pyrrolidine-Thiourea Bifunctional Organocatalyst. (2010) (16)
- Analysis of human topoisomerase I inhibition and interaction with the cleavage site +1 deoxyguanosine, via in vitro experiments and molecular modeling studies. (2004) (16)
- New bis-lactam chiral auxiliaries for nitrile oxide cycloadditions (1993) (16)
- N-Heterocyclic Carbene Boranes are Hydrogen Donors in Masamune-Bergman Reactions of Benzo[3,4]cyclodec-3-ene-1,5-diynes. (2017) (16)
- On the structure of the Phytophthora α1 mating hormone: synthesis and comparison of four candidate stereoisomers. (2007) (16)
- Synthesis of fluorous-FMOC reagents and purification of protected dipeptides with fluorous solid phase extraction (2006) (16)
- Memory of chirality in rebound cyclizations of α-amide radicals (2013) (16)
- Tetrahydrofuran ring opening and related reactions with an N-heterocyclic carbene-boryl trifluoromethanesulfonate. (2013) (16)
- Group selective radical cyclizations with Oppolzer's camphor sultam (1994) (15)
- Platinum catalyzed hydrosilylation and palladium catalyzed cross-coupling: One-pot hydroarylation of 1-heptyne to (E)-1-(1-heptenyl)-4-methoxybenzene :[Benzene, 1-(1e)-1-heptenyl-4-methoxy-] (2005) (15)
- Fluorous mixture synthesis of fused-tricyclic hydantoins. Use of a redundant tagging strategy on fluorinated substrates. (2005) (15)
- CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF3 and BH3 (2010) (15)
- Quantitating the effect of an ortho substituent on cyclization and intramolecular hydrogen-transfer reactions of aryl radicals. (2003) (15)
- Bond rotation dynamics of enamides: the effect of the acyl group and potential for chirality transfer during 5-endo trig radical cyclizations. (2011) (15)
- Carbonylative radical cyclization approaches to tri- and tetra-quinanes: sequential formation of three, four and five carbon-carbon bonds (1998) (15)
- Determination of the absolute configuration of 1,3,5,7-tetramethyl-1,3-dihydroindol-2-one by optical rotation computation (1999) (15)
- Fluorous Chemistry in Pittsburgh: 1996-2008. (2008) (15)
- Group transfer addition reactions of selenomalononitriles to chiral enol ethers. Asymmetric radical addition and selenium transfer reactions (1994) (15)
- Mechanistic studies of atom transfer addition reactions of iodomalononitriles to alkenes. 1,2-asymmetric induction in an iodine atom transfer reaction. (1991) (14)
- Generation and Structure of Unique Boriranyl Radicals. (2017) (14)
- Thiol-Catalyzed Radical Decyanation of Aliphatic Nitriles with Sodium Borohydride. (2018) (14)
- Synthesis of C1-C20 and C21-C40 fragments of tetrafibricin. (2008) (14)
- Controlling stereochemistry in radical addition and cyclization reactions with Oppolzer's camphor sultam (1994) (14)
- Solution-phase parallel synthesis of 115 homosilatecan analogues (2003) (13)
- Total and semisynthesis and in vitro studies of both enantiomers of 20-fluorocamptothecin. (2005) (13)
- Acylsilanes as Geminal Radical Acceptor/Radical Donor Equivalents in Tandem Cyclization/Addition Reactions (1993) (13)
- New 4 + 1 Radical Annulations. A Formal Total Synthesis of (.+-.)- Camptothecin. (1992) (13)
- Annulative ring expansions. Direct conversion of .omega.-alkynyl acetals to polycyclic unsaturated ketones (1992) (13)
- Can an aromatic ring alter the reactions of a nearby unsaturated imide? A study of the rate and selectivity of nitrile oxide cycloaddition reactions of acryloyl derivatives of the Rebek imide benzoxazole (1997) (13)
- Systematic Comparison of Sets of 13C NMR Spectra That Are Potentially Identical. Confirmation of the Configuration of a Cuticular Hydrocarbon from the Cane Beetle Antitrogus parvulus (2014) (13)
- STEREOSELECTION AT THE STEADY STATE. GROUP SELECTIVE RADICAL CYCLIZATIONS OF SUBSTRATES CONTAINING TWO RADICAL PRECURSORS AND ONE RADICAL ACCEPTOR (1998) (12)
- 1-Butyl-3-methylimidazol-2-ylidene Borane: A Readily Available, Liquid N-Heterocyclic Carbene Borane Reagent. (2017) (12)
- Organic/Fluorous Phase Extraction: A New Tool for the Isolation of Organometallic Complexes (1998) (12)
- Bare-minimum fluorous mixture synthesis of a stereoisomer library of 4,8,12-trimethylnonadecanols and predictions of NMR spectra of saturated oligoisoprenoid stereoisomers. (2013) (11)
- Cyclodehydration of o-vinyl anilides. A general synthesis of substituted quinolines (1984) (11)
- The dichlorovinylation of enolates (1980) (11)
- Synthesis and analysis of the all-(S) side chain of phosphomycoketides: a test of NMR predictions for saturated oligoisoprenoid stereoisomers. (2013) (11)
- The Thermal Rearrangement of an NHC-Ligated 3-Benzoborepin to an NHC-Boranorcaradiene. (2019) (11)
- Control of relative stereochemistry in the cycloadditive route to β-hydroxy carbonyls. Stereoselective exo aldol reactions of Δ2-isoxazolines (1990) (11)
- COMBINATION CLAISEN-NITRILE OXIDE ANNULATION. A STRATEGY FOR RING CONSTRUCTION WITH RIGID STEREOCONTROL DICTATED BY AN ALLYLIC HYDROXYL GROUP (1985) (11)
- Bond rotation dynamics of N-cycloalkenyl-N-benzyl alpha-haloacetamide derivatives. (2009) (11)
- Separation tagging with cyclodextrin-binding groups: Mitsunobu reactions with bis-(2-(1-adamantyl)ethyl) azodicarboxylate (BadEAD) and bis-(1-adamantylmethyl) azodicarboxylate (BadMAD) (2004) (11)
- Cram's rule for radicals: Stereoselective hydrogen abstraction reactions of NH substituted radicals (1993) (10)
- 1,3‐Dimethylimidazoyl‐2‐Ylidene Borane (2016) (10)
- Synthesis of deep-cavity fluorous calix[4]arenes as molecular recognition scaffolds (2008) (10)
- Purification of fluorous Mitsunobu reactions by liquid-liquid extraction (2006) (10)
- Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols (2001) (10)
- Synthesis of (R,R)‐4,6‐Dibenzofurandiyl‐2,2′‐Bis (4‐Phenyloxazoline) (DBFOX/PH) – A Novel Tridentate Ligand (2003) (10)
- Fluorous Chemistry: Scope and Definition (2005) (10)
- A new fluorous methoxymethyl ( F MOM) protecting group for alcohols (2006) (10)
- Radical trans-Hydroboration of Substituted 1,3-Diynes with an N-Heterocyclic Carbene Borane. (2021) (10)
- Approximate Absolute Rate Constants for 5-Exo and 6-Exo Cyclizations of 1°-Radicals to Acyl(triphenyl)germanes (1992) (10)
- Rotational isomers of N-methyl-N-arylacetamides and their derived enolates: implications for asymmetric Hartwig oxindole cyclizations. (2013) (10)
- Diverging chemoselective reactions of separable amide rotational isomers. (2010) (10)
- Fluorous Columns are Superior to Cyclodextrin Columns for Demixing in Fluorous Mixture Synthesis: When and Why to Use Fluorous Silica Gel (2004) (10)
- Synthesis, characterization, and applications of fluorous resorcin[4]arenes (2010) (10)
- Iodine Atom Transfer Reactions in Organic Synthesis (1989) (9)
- N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation. (2013) (9)
- Complexes of Borane and N‐Heterocyclic Carbenes: A New Class of Radical Hydrogen Atom Donor. (2008) (9)
- 5.09 – Acyl Silicon, Germanium, or Boron Functions (1995) (9)
- Stereocontrol at the steady state in radical cyclizations of acyclic dihalides. (2002) (9)
- An effect of silicon substitution remote from reactive site (1982) (9)
- The azido acid approach to β-peptides: parallel synthesis of a tri-β-peptide library by fluorous tagging (2007) (8)
- Esters as Radical Acceptors: β‐NHC‐Borylalkenyl Radicals Induce Lactonization by C−C Bond Formation/Cleavage on Esters (2019) (8)
- Fates of imine intermediates in radical cyclizations of N-sulfonylindoles and ene-sulfonamides (2015) (8)
- Ring-Opening Reactions of NHC-Boriranes with In Situ Generated HCl: Synthesis of a New Class of NHC-Boralactones. (2019) (8)
- Efficient syntheses of 25,26-dihydrodictyostatin and 25,26-dihydro-6-epi-dictyostatin, two potent new microtubule-stabilizing agents (2011) (8)
- Total synthesis of luotonin and a small library of AB-ring substituted analogues by cascade radical annulation of isonitriles (2005) (7)
- Altering the Stereochemistry of Allylation Reactions of Cyclic α- Sulfinyl Radicals with Diarylureas. (1994) (7)
- Visible-Light-Induced Radical Cascade Cyclization: Synthesis of (20S )-Camptothecin, SN-38 and Irinotecan (2018) (7)
- Stereoselection at the Steady State by Stereoconvergent Reaction Topography (1998) (7)
- Revisiting Polyfluoroarenes as Radical Acceptors: Radical C-F Bond Borylation of Polyfluoroarenes with N-Heterocyclic Carbene Boranes and Synthesis of Borane-Containing Liquid Crystals. (2020) (7)
- EPR and Preparative Studies of 5- endo Cyclizations of Radicals Derived from Alkenyl NHC-Boranes Bearing tert-Butyl Ester Substituents. (2019) (7)
- Radical Cyclization/Fragmentation Reactions of Dicyanocyclopropanes to Enaminonitriles. A Radical Alternative to the Thorpe-Ziegler Reaction (1999) (7)
- On the reduction of tertiary radicals by samarium diiodide (SmI2) (2000) (7)
- Regioselective Radical Borylation of α,β-Unsaturated Esters and Related Compounds by Visible Light Irradiation with an Organic Photocatalyst. (2021) (7)
- The Camptothecins: A Reborn Family of Antitumor Agents (1993) (7)
- A quantitative analysis of "mechanistic probe" studies of reduction of alkyl iodides by lithium aluminum hydride supports a polar SN2 mechanism (1988) (7)
- On the Alkylation Behavior of 2-(Phenylseleno) Nitriles (1997) (7)
- β-Cyclodextrin Columns for Separation of Fluorous and Non-Fluorous Compounds: How To Use β-Cyclodextrin Columns in Fluorous Mixture Synthesis and Racemic Synthesis (2004) (6)
- Lanthanides in Organic Synthesis (1994) (6)
- Plasma and tissue disposition of non-liposomal DB-67 and liposomal DB-67 in C.B-17 SCID mice (2008) (6)
- Intramolecular α-Amidoyl to Aryl 1,5-Hydrogen Atom Transfer Reactions. Heteroannulation and α-Nitrogen Functionalization by Radical Translocation. (1990) (6)
- Rate constants for the additions of cyclohexyl radicals to acrylamides, imides and sulfonimides (1993) (6)
- Does the Facile Reductive Rearrangement of 2-Allyloxycyclohexenone with Bu3SnH Occur by a Radical-Accelerated Claisen Rearrangement or a Stannyloxy-Accelerated Claisen Rearrangement? (1999) (6)
- Heterocyclic α-Alkylidene Cyclopentenones Obtained via a Pauson—Khand Reaction of Amino Acid Derived Allenynes. A Scope and Limitation Study Directed Toward the Preparation of a Tricyclic Pyrrole Library. (2005) (6)
- Facile synthesis of α-NHC-boryl ketones from NHC-boranes and alkenyl triflates. (2019) (6)
- Inverse Hydroboration of Imines with NHC-Boranes Is Promoted by Diphenyl Disulfide and Visible Light. (2021) (6)
- A short synthesis of ?-hydroxycyclopentemones (1983) (6)
- Synthetic Approaches to Homocamptothecin Antitumor Agents (2008) (6)
- Fluorous Mixture Synthesis of Four Stereoisomers of the C21-C40 Fragment of Tetrafibricin. (2010) (6)
- Total synthesis of juncusol (1978) (6)
- BIMOLECULAR REACTIONS OF ALKYL HALIDES AND ACYLGERMANES : FORMATION OF KETONES, DIKETONES, AND OTHER PRODUCTS BY RADICAL-RADICAL REACTION (1997) (5)
- SULFANYLATION OF 1,3-DITHIANE ANIONS BY 5-(ALKYLSULFANYL)-1-PHENYLTETRAZOLES. (2009) (5)
- REDUCTION OF Δ2-ISOXAZOLINES. 3. RANEY NICKEL CATALYZED FORMATION OF β-HYDROXY KETONES (1983) (5)
- Combinatorial Organic Synthesis and Phase Separation: Back to the Future (1996) (5)
- Radical and Thermal Reactions of N-Heterocyclic Carbene Boranes with Diazo Compounds (2016) (5)
- Radical isomerization and allylation reactions of 2-iodo-3,3-dimethyl-4-pentenoate esters (1992) (5)
- Preparation of a Fluorous Benzyl Protecting Group and Its Use in a Fluorous Synthesis Approach to a Disaccharide. (1998) (5)
- Do α-acyloxy and α-alkoxycarbonyloxy radicals fragment to form acyl and alkoxycarbonyl radicals? (2006) (5)
- Compounding Selectivity in Reactions of Diastereoisomeric Radical Intermediates. An experimental demonstration that the yield of a product from a diastereotopic‐group‐selective reaction can significantly exceed the level of group selectivity (1996) (5)
- Asymmetric Reactions of Axially Chiral Amides: Use of Removable ortho-Substituents in Radical Cyclizations of o-Iodoacrylanilides and N-Allyl-N-o-iodoacrylamides. (2004) (5)
- Stereoselective Reactions of δ2-Isoxazoline Exo-azaenolates. A Model for Construction of the C-Ring of Sesbanimide A (1990) (5)
- Reactions of N-Heterocyclic Carbene Boranes with 5-Diazo-2,2-dimethyl-1,3-dioxane-4,6-dione: Synthesis of Mono- and Bis-hydrazonyl NHC-Boranes. (2018) (5)
- Radical Translocation Reactions of Vinyl Radicals: Substituent Effects on 1,5‐Hydrogen‐Transfer Reactions. (1993) (4)
- Fluorous Techniques for the Synthesis of Organic Molecules: A Unified Strategy for Reaction and Separation (2005) (4)
- Unimolecular Chain Transfer (UMCT) Reactions of Silicon Hydrides: Controlling Relative Configuration in Hydrogen Transfer Reactions of Cyclic Radicals (1997) (4)
- Organic Synthesis with Light-Fluorous Reagents, Reactants, Catalysts, and Scavengers (2006) (4)
- Substituent Effects in NHC–Boranes: Reactivity Switch in the Nucleophilic Fluorination of NHC–Boranes (2013) (4)
- Radical-Initiated Polyolefinic Cyclizations in Condensed Cyclopentanoid Synthesis. (1986) (4)
- Generation and cycloaddition reactions of phenylthionitrile oxide. A preparation of 3-(phenylthio)- and 3-(phenylsulfonyl)-.DELTA.2-isoxazolines (1988) (4)
- Dynamic Behavior of N-Heterocyclic Carbene Boranes: Boron-Carbene Bonds in B,B-Disubstituted N,N-Dimethylimidazol-2-ylidene Boranes Have Substantial Rotation Barriers. (2015) (4)
- (4 + 1) Radical Annulations with Isonitriles: A Simple Route to Cyclopenta‐Fused Quinolines. (2010) (4)
- NHC-Catalyzed Chemo- and RegioselectiveHydrosilylation of Carbonyl Derivatives (2012) (4)
- Comparison of the Relative Reactivities of the Triisopropylsilyl Group With Two Fluorous Analogs. (2009) (4)
- Confirmation of the Stereostructure of (+)‐Cytostatin by Fluorous Mixture Synthesis of Four Candidate Stereoisomers. (2008) (4)
- EPR Studies on the Addition of Ligated Boryl Radicals to Carbonyl Compounds. (2020) (4)
- Radical Reactions in Organic Synthesis (2007) (4)
- Cyclizations of Unsaturated ×CR(COX)2 Radicals. Manganese(III) Acetate Oxidative Cyclizations of Unsaturated Acetoacetates and Atom- Transfer Cyclizations of Unsaturated Haloacetoacetates Give the Same Radicals. (1991) (4)
- Chapter 3. Fluorous Solvents (2007) (4)
- Tris(trimethylsilyl)silane-Mediated Reductive Decyanation and Cyano Transfer Reactions of Malononitriles (2018) (4)
- The Thermal Rearrangement of an NHC‐Ligated 3‐Benzoborepin to an NHC‐Boranorcaradiene (2020) (4)
- Fluorous "racemic" mixture synthesis: polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds. (2008) (4)
- The Role of Electronic and Stereoelectronic Effects on Asymmetric Iodine and Hydrogen Transfer Reactions of Conjugated Radicals (1995) (3)
- REDUCTION OF Δ2-ISOXAZOLINES: A CONCEPTUALLY DIFFERENT APPROACH TO THE FORMATION OF ALDOL ADDUCTS (1982) (3)
- Experimental Techniques in Fluorous Synthesis : A users guide (2000) (3)
- High‐Speed, Highly Fluorous Organic Reactions. (1999) (3)
- Rapid Fluorous Stille Coupling Reactions Conducted under Microwave Irradiation. (1998) (3)
- Quasienantiomers and Quasiracemates: New Tools for Identification, Analysis, Separation, and Synthesis of Enantiomers (2006) (3)
- Synthesis of Highly Enantioenriched 3,4-Dihydroquinolin-2-ones by 6-Exo-trig Radical Cyclizations of Axially Chiral α-Halo-ortho-alkenyl Anilides. (2010) (3)
- Synthesis and Reactions of N-Heterocyclic Carbene Boranes (2012) (3)
- The Cycloadditive Approach to β-Hydroxy Carbonyls: An Emerging Alternative to the Aldol Strategy (1989) (3)
- Ruthenium-catalyzed alkylation of aromatic ketones with olefins: 8-[2-(triethoxysilyl)ethyl]-1-tetralone: [(1(2h)-naphthalenone, 3,4-dihydro-8-[2-(triethoxysilyl)ethyl]-)] (2003) (3)
- Fluorous Boc (FBoc) Carbamates: New Amine Protecting Groups for Use in Fluorous Synthesis. (2001) (3)
- Synthesis and characterization of N-heterocyclic carbene complexes of 1,3,2-dioxaborolane-4,5-dione (NHC-boryl oxalates) (2018) (3)
- Insertion of Reactive Rhodium Carbenes into Boron—Hydrogen Bonds of Stable N‐Heterocyclic Carbene Boranes. (2014) (3)
- Synthesis of tris(2-perfluorohexylethyl)tin hydride: A highly fluorinated tin hydride with advantageous features of easy purification (2003) (3)
- A Bird′s Eye View of Fluorous Reaction and Separation Techniques (2004) (2)
- Organocatalysis and C—H Activation Meet Radical- and Electron-Transfer Reactions (2011) (2)
- Thermal Allylations of Aldehydes with a Fluorous Allylstannane. Separation of Organic and Fluorous Products by Solid Phase Extraction with Fluorous Reverse Phase Silica Gel. (1998) (2)
- TRIS (perfluoroalkylethyl)silyl alkyl amines as calibration standards for electron ionization mass spectrometry in the mass range of 100–3000 Da (2001) (2)
- Synthesis, Structure, and Acidity Constants of Ligated α-Boryl Acetic Acids. (2018) (2)
- Aryl-Csp(3) bond rotation barriers of 2-aryl perhydropyrrolo[3,4-c]pyrrole-1,3-diones. (2009) (2)
- Atom Transfer Cyclization Reactions of α-Iodo Esters, Ketones, and Malonates: Examples of Selective 5-Exo, 6-Endo, 6-Exo, and 7-Endo Ring Closures. (1989) (2)
- Tris(2‐(perfluorohexyl)ethyl)tin Hydride: A New Fluorous Reagent for Use in Traditional Organic Synthesis and Liquid Phase Combinatorial Synthesis. (1996) (2)
- Radical Cyclizations of Acylgermane Oxime Ethers and Hydrazones: Direct Routes to Cyclic Hydrazones and Oximes. (1998) (2)
- Fluorous Mixture Synthesis of Stereoisomer Libraries: Total Syntheses of (+)‐Murisolin (I) and Fifteen Diastereomers. (2004) (2)
- Synthesis, Reaction, and Recycle of Light Fluorous Grubbs′—Hoveyda Catalysts for Alkene Metathesis. (2005) (2)
- Tandem Radical Reactions of Carbon Monoxide, Isonitriles, and Other Reagent Equivalents of the Geminal Radical Acceptor/Radical Precursor Synthon (1996) (2)
- ‘Giese-type’ radical addition reactions to an acceptor that functions by a unimolecular chain transfer reaction of a silicon hydride (1995) (2)
- The Combinatorial Synthesis of Racemic Homosilatecan Libraries via a Cascade Radical Annulation (2000) (2)
- Inside Cover: Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion (Angew. Chem. Int. Ed. 48/2010) (2010) (2)
- Oxygen Switch in Visible-Light Photoredox Catalysis: Radical Additions and Cyclizations and Unexpected C—C-Bond Cleavage Reactions. (2013) (2)
- Radical Cyclization/Fragmentation Reactions of Dicyanocyclopropanes to Enaminonitriles. A Radical Alternative to the Thorpe—Ziegler Reaction. (1999) (2)
- Reactions of NHC‐Boranes with Dibenzoyl Peroxide and Benzoic Acid (2020) (2)
- A Strategic Alternative to Solid Phase Synthesis: Preparation of a Small Isoxazoline Library by “Fluorous Synthesis”. (2010) (2)
- A New Chiral Auxiliary for Asymmetric Thermal Reactions: High Stereocontrol in Radical Addition, Allylation, and Annulation Reactions. (1992) (2)
- Additions of Malononitrile Radicals to Alkenes: New Examples of 1,2- Asymmetric Induction in Iodine and Phenylselenium Transfer Reactions. (1992) (2)
- NHC-Catalyzed Chemo- and Regioselective Hydrosilylation of Carbonyl Derivatives. (2012) (2)
- Fluorescence detection of camptothecin anticancer drugs by two-photon excitation (1998) (2)
- Cascade 4+1 Radical Annulations of 2,6-Disubstituted Phenyl Isonitriles with N-Propargyl-6-Iodopyridones: Scope, Mechanism and Regioselective Synthesis of 7,9-Disubstituted Camptothecin Analogs (2003) (2)
- Enantioselective α-Chlorination of Aldehydes with Recyclable Fluorous (S)-Pyrrolidine—Thiourea Bifunctional Organocatalyst. (2010) (2)
- Synthesis and reactions of fluorous carbobenzyloxy (FCbz) derivatives of alpha-amino acids. (2003) (2)
- Ring-Enlarging Annulations. A One-Step Conversion of Cyclic Silyl Acyloins and ω-Alkynyl Acetals to Polycyclic Enediones. (1995) (2)
- Synthesis of Optically Active α-Hydroxy Lactones by Sharpless Asymmetric Dihydroxylations of Ketene Acetals, Enol Ethers, and Ene Lactones. (1995) (1)
- Suzuki—Miyaura Coupling of NHC—Boranes: A New Addition to the C—C Coupling Toolbox. (2010) (1)
- 7‐Silylcamptothecins (Silatecans): A New Family of Camptothecin Antitumor Agents. (1998) (1)
- New Tandem Radical Cyclizations Directed Toward the Synthesis of Crinipellin A. (1991) (1)
- Fluorous synthesis: an alternative to organic synthesis and solid phase synthesis for the preparation of small organic molecules. (1998) (1)
- Altering the Stereochemistry of Allylation Reactions of Cyclic α- Sulfinyl Radicals: Effects of Solvents and Lewis Acids. (1994) (1)
- Radical Translocation Reactions of o-Iodoanilides: The Use of Carbon- Hydrogen Bonds as Precursors of Radicals Adjacent to Carbonyl Groups. (1991) (1)
- Stereoselective Synthesis of Alkenes by Using Unimolecular Chain Transfer Reactions of Silicon Hydrides. (1996) (1)
- New Radical Allylation Reactions Using 2-Bromo-3-(phenylthio)propene and Their Application to the Synthesis of Carbocyclic Compounds. (1997) (1)
- Innentitelbild: Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion (Angew. Chem. 48/2010) (2010) (1)
- Disulfides and Boryl Sulfides Serve as Both Initiators and Precatalysts in Radical Reductions of Halides by an N‐Heterocyclic Carbene·Borane. (2014) (1)
- Ring‐Closing Metathesis Approach to Dictyostatin. (2005) (1)
- Use of Fluorous Silica Gel to Separate Fluorous Thiol Quenching Derivatives in Solution-Phase Parallel Synthesis. (2010) (1)
- Effects of Temperature on Atom-Transfer Cyclization Reactions of Allylic α-Iodo Esters and Amides. (1991) (1)
- Stille Couplings with Fluorous Tin Reactants: Attractive Features for Preparative Organic Synthesis and Liquid‐Phase Combinatorial Synthesis. (1997) (1)
- tereochemistry of Radical Reactions Concepts , Guidelines , and Synthetic Applications With a Foreword (2017) (1)
- Sequential Radical Cyclization Approach to Propellane Triquinanes. Total Synthesis of (.+-.)-Modhephene. (1990) (1)
- Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion. (2011) (1)
- Can an Aromatic Ring Alter the Reactions of a Nearby Unsaturated Imide? A Study of the Rate and Selectivity of Nitrile Oxide Cycloaddition Reactions of Acryloyl Derivatives of the Rebek Imide Benzoxazole. (1997) (1)
- Atom Transfer Cyclization Reactions of Hex-5-ynyl Iodides: Synthetic and Mechanistic Studies. (1989) (1)
- “Propylene Spaced” Allyl Tin Reagents: A New Class of Fluorous Tin Reagents for Allylations under Radical and Metal-Catalyzed Conditions. (1999) (1)
- Tandem Radical Reactions of Isonitriles with 2‐Pyridonyl and Other Aryl Radicals: Scope and Limitations, and a First Generation Synthesis of (.+‐.)‐Camptothecin (XIII). (1996) (1)
- Advanced Free Radical Reactions for Organic Synthesis (Book) (2004) (1)
- ON THE STEREOCHEMISTRY OF THE BIS-NOR-WIELAND-MIESCHER KETONE (1982) (1)
- Synthesis and Evaluation of a Novel E-Ring Modified α-Hydroxy Keto Ether Analogue of Camptothecin. (2002) (1)
- REDUCTION OF SUBSTITUTED Δ2-ISOXAZOLINES. SYNTHESIS OF β-HYDROXY ACID DERIVATIVES (1985) (1)
- Annulative Ring Expansions. Direct Conversion of ω‐Alkynyl Acetals to Polycyclic Unsaturated Ketones. (1992) (1)
- Reductive Coupling and Reductive Demethoxylation of Aromatic Dimethylacetals with SmI2/Trifluoroacetic Acid, SmI2/BF3×Et2O, or SmI2/H2O. (1996) (1)
- Controlling Radical Chain Reactions by Unimolecular Chain Transfer. Intramolecular Hydrogen Transfer Reactions of Silicon Hydrides. (1995) (1)
- Cationic Aqua Complexes of the C2-Symmetric trans-Chelating Ligand (R,R)-4,6-Dibenzofurandiyl-2,2′-bis(4-phenyloxazoline). Absolute Chiral Induction in Diels—Alder Reactions Catalyzed by Water-Tolerant Enantiopure Lewis Acids. (1998) (1)
- Synthesis of Fused Bicyclic Rings by Tandem Radical Ring Expansion/Cyclization: Evaluating Competing Intramolecular Reactions. (1998) (1)
- Reactions of TEMPO with Alkylsamarium and Other Organometallic Reagents. (1996) (1)
- Cascade Radical Reactions in Organic Synthesis: An Overview (1998) (1)
- Atom transfer cyclization reactions of unsaturated phenylseleno- and iodomalononitriles (1993) (1)
- Total Synthesis of Luotonin (Ia) and a Small Library of AB-Ring Substituted Analogues by Cascade Radical Annulation of Isonitriles. (2006) (1)
- Advanced Free Radical Reactions for Organic Synthesis By Hideo Togo (Chiba University). Elsevier: Amsterdam. 2004. xii + 258 pp. $178.00. ISBN 0-08-044374-5. (2004) (1)
- Group Transfer Addition Reactions of Methyl(phenylseleno)malononitrile to Alkenes. (1994) (1)
- Sequential Radical Ring Expansion and Allylation Reactions Using 2‐Bromo‐3‐(phenylthio)propene: Their Application to the Synthesis of Bridged Ring Systems. (1998) (1)
- Amide Bond Formation with a New Fluorous Carbodiimide: Separation by Reverse Fluorous Solid‐Phase Extraction. (2008) (0)
- Fluorous Dienophiles Are Powerful Diene Scavengers in Diels—Alder Reactions. (2003) (0)
- Hydrogen Bond Directed Nitrile Oxide Cycloaddition Reactions of Allylic 2-Amides. (1993) (0)
- Asymmetric Alkylation of Aromatic Aldehydes with Diethylzinc Catalyzed by a Fluorous BINOL—Ti Complex in an Organic and Fluorous Biphase System. (2000) (0)
- Synthesis of (S)-Mappicine and Mappicine Ketone via Radical Cascade Reaction of Isonitriles. (1997) (0)
- Synthesis of β‐Mannopyranosides from α‐Epimers by Radical Inversion. 1,6‐Hydrogen Transfer Reactions of 2‐O‐(2‐Bromoaryl) dimethylsilyl‐α‐methyl‐D‐mannopyranosides. (1995) (0)
- The Samarium Grignard Reaction. In situ Formation and Reactions of Primary and Secondary Alkylsamarium(III) Reagents. (1992) (0)
- Group Transfer Addition Reactions of Selenomalononitriles to Chiral Enol Ethers. Asymmetric Radical Addition and Selenium Transfer Reactions. (1995) (0)
- Synthesis and Reactions of Fluorous Carbobenzyloxy (FCbz) Derivatives of α‐Amino Acids. (2003) (0)
- Additions of Electrophilic Radicals to Electron‐Rich Alkenes by the Atom Transfer Method. Surmounting Potentially Reversible Radical Atom Transfer Reactions by Irreversible Ionic Reactions. (1998) (0)
- Radical Translocation Reactions Across Amides. 1,5‐Hydrogen‐Transfer Reactions of o‐Iodobenzamides and N‐(o‐Iodobenzyl) Amides. (1994) (0)
- Selective Synthesis of (2Z,4E)‐Dienyl Esters by Ene—Diene Cross Metathesis. (2007) (0)
- Hydroxymethylation of Organic Halides. Evaluation of a Catalytic System Involving a Fluorous Tin Hydride Reagent for Radical Carbonylation. (1998) (0)
- Reductive Cleavage of Highly Substituted 2-Isoxazolines. Synthesis of Crispatic Acid. (1987) (0)
- Camptothecin analogs and methods for their preparation. (2000) (0)
- Palladium‐Promoted Cascade Reactions of Isonitriles and 6‐Iodo‐N‐propargylpyridones: Synthesis of Mappicines, Camptothecins, and Homocamptothecins. (2003) (0)
- Radical-initiated Polyolefinic Cyclizations in Linear Triquinane Synthesis. (1986) (0)
- Chiral Auxiliary Control (2007) (0)
- New Chiral Auxiliary for Asymmetric Thermal Reactions: High Regio- and β-Stereoselectivity in Asymmetric Radical Addition Reactions to Mixed Fumarimides. (1991) (0)
- Substrate Control: Acyclic Systems (2007) (0)
- Asymmetric Thermal Reactions with Oppolzer′s Camphor Sultam (1993) (0)
- Asymmetric Induction in Nitrile Oxide Cycloadditions to Optically Active Acrylates. Comparisons of Acrylate Conformations in Thermal and Acid-Catalyzed 1,3-Dipolar and Diels-Alder Cycloaddition Transition States. (1987) (0)
- Reverse Fluorous Solid‐Phase Extraction: A New Technique for Rapid Separation of Fluorous Compounds. (2004) (0)
- Unimolecular Chain Transfer (UMCT) Reactions: Concepts, Preliminary Results with Silicon Hydrides, and Future Potential. (1996) (0)
- Intermediates for the manufacture of picropodophyllin and related compounds, methods for their preparation and their use (1981) (0)
- Fluorous chemistry in Pittsburgh: 1996-2007 (ISoFT'07特集) (2008) (0)
- Camptotechine analogs and its preparation methods. (1998) (0)
- Synthesis of Perfluorinated Allylic Compounds by Radical Allylation and Their Purification over Fluorous Reverse‐Phase Silica. (2001) (0)
- Studies Toward Practical Synthesis of (20S)-Camptothecin Family Through Catalytic Enantioselective Cyanosilylation of Ketones: Improved Catalyst Efficiency by Ligand-Tuning. (2010) (0)
- Substrate Control: Radical Cyclizations (2007) (0)
- Bimolecular Reactions of Alkyl Halides and Acylgermanes: Formation of Ketones, Diketones, and Other Products by Radical-Radical Reaction. (1997) (0)
- It is better to travel hopefully ... (1996) (0)
- Camptothecinanaloge and their preparation methods (2000) (0)
- Tandem Radical Cyclizations. A General Strategy for the Synthesis of Triquinane Sesquiterpenes (1991) (0)
- Progress in natural products synthesis via free radical reactions (1986) (0)
- Fluorous Mixture Synthesis of 4-Alkylidene Cyclopentenones via a Rhodium-Catalyzed [2 + 2 + 1] Cycloaddition of Alkynyl Allenes. (2005) (0)
- Cover Picture: Total Synthesis and Configurational Assignment of (−)‐Dictyostatin, a Microtubule‐Stabilizing Macrolide of Marine Sponge Origin / Total Synthesis of (−)‐Dictyostatin: Confirmation of Relative and Absolute Configurations (Angew. Chem. Int. Ed. 35/2004) (2004) (0)
- Asymmetric Radical Cyclization Reactions of Axially Chiral N-Allyl-o-iodoanilides to Form Enantioenriched N-Acyl Dihydroindoles. (2004) (0)
- Translocation of Radical Sites by Intramolecular 1,5-Hydrogen Atom Transfer. (1988) (0)
- The Renaissance of Organic Radical Chemistry — Deja Vu All over Again (2014) (0)
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- Difluorination at Boron Leads to the First Electrophilic Ligated Boryl Radical (NHC‐BF 2 . ) (2018) (0)
- Radical Isomerization and Allylation Reactions of 2-Iodo-3,3-dimethyl- 4-pentenoate Esters. (1992) (0)
- Molecular Iodine Initiates Hydroborations of Alkenes with N‐Heterocyclic Carbene Boranes. (2014) (0)
- Tandem Radical Cyclization Approach to Angular Triquinanes. A Short Synthesis of (±)-Silphiperfol-6-ene (VIII) and (±)-9-Episilphiperfol-6-ene (IX). (1986) (0)
- Directed Nitrile Oxide Cycloaddition Reactions. The Use of Hydrogen Bonding to Direct Regio- and Stereochemistry in Nitrile Oxide Cycloadditions with Cyclopentenylamides. (1990) (0)
- Nucleophilic Additions to and Reductions of 5‐Formyl‐ and 5‐Acyl‐2‐ isoxazolines (4,5‐Dihydroisoxazoles): A Stereoselective Route to β ,γ‐Dihydroxy Ketones. (1992) (0)
- Unimolecular Chain Transfer (UMCT) Reactions of Silicon Hydrides: Controlling Relative Configuration in Hydrogen Transfer Reactions of Cyclic Radicals. (1998) (0)
- Microwave Heating Effects Rapid and Selective Decarboalkoxylation of Mono-Alkylated Malonates and β-Ketoesters. (2003) (0)
- A General Synthetic Approach to Optically Active Iridoid Aglycones. The Total Syntheses of β-Ethyl Descarbomethoxyverbenalol, Ethyl Catalpol, and (-)-Specionin. (1988) (0)
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- “Giese‐Type” Radical Addition Reactions to an Acceptor that Functions by a Unimolecular Chain Transfer Reaction of a Silicon Hydride. (1996) (0)
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- A Samarium(II) Iodide Promoted Tandem Radical Cyclization. The Total Synthesis of (.+‐.)‐Hypnophilin and the Formal Synthesis of (.+‐.)‐Coriolin. (1988) (0)
- Unsaturated Acylgermanes Isomerize by a Chain Mechanism Involving Radical Cyclization to the Carbonyl Group of an Acylgermane. (1991) (0)
- Asymmetric Radical Addition, Cyclization, and Annulation Reactions with Oppolzer′s Camphor Sultam. (1990) (0)
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- Radical Anellation Reactions of Allyl Iodomalononitriles. (1992) (0)
- Synthesis of All 16 Stereoisomers of Pinesaw Fly Sex Pheromones — Tools and Tactics for Solving Problems in Fluorous Mixture Synthesis. (2006) (0)
- Solution-Phase Parallel Synthesis of 115 Homosilatecan Analogues. (2004) (0)
- Cover Picture: Fluorous Synthesis of Hydantoin‐, Piperazinedione‐, and Benzodiazepinedione‐Fused Tricyclic and Tetracyclic Ring Systems (Eur. J. Org. Chem. 9/2006) (2006) (0)
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- Cascade Radical Reactions of Isonitriles: A Second-Generation Synthesis of (20S)-Camptothecin, Topotecan, Irinotecan, and GI-147211C. (1996) (0)
- Berichtigung: Radical trans ‐Hydroboration of Alkynes with N‐Heterocyclic Carbene Boranes (2020) (0)
- A Soluble Fluorous Palladium Complex that Promotes Heck Reactions and Can Be Recovered and Reused. (2004) (0)
- Synthesis and Some Reactions of the First Chiral Tin Hydride Containing a C2-Symmetric Binaphthyl Substituent. (2010) (0)
- The azido acid approach to beta-peptides: parallel synthesis of a tri-beta-peptide library by fluorous tagging. (2007) (0)
- New Sequential Carbon-Carbon Bond Forming Reactions. A Samarium(II) Iodide-Mediated Vinylogous Barbier Reaction Followed by an Aldol Reaction. (1992) (0)
- The Role of Electronic and Stereoelectronic Effects on Asymmetric Iodine and Hydrogen Transfer Reactions of Conjugated Radicals. (1995) (0)
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- On the Alkylation Behavior of 2-(Phenylseleno) Nitriles. (2010) (0)
- Preparations: Sections 11.41 – 11.50 (2005) (0)
- Cover Picture: Synthesis and Reactions of N-Heterocyclic Carbene Boranes (Angew. Chem. Int. Ed. 44/2011) (2011) (0)
- OXIDATIVE ARYL-BENZYL COUPLING. A BIOMIMETIC ENTRY TO PODOPHYLLIN LIGNAN LACTONES (1978) (0)
- Formation of Cyclopropanes by Homolytic Substitution Reactions of 3-Iodopropyl Radicals: Preparative and Rate Studies. (1999) (0)
- Atom Transfer Cyclization of Simple Hexenyl Iodides. A Caution on the Use of Alkenyl Iodides as Probes for the Detection of Single Electron Transfer Processes. (1987) (0)
- Frontispiece: Borylative Radical Cyclizations of Benzo[3,4]cyclodec-3-ene-1,5-diynes and N-Heterocyclic Carbene-Boranes (2017) (0)
- A Strategy for Radical Annulation Based on Allyl and Vinyl Stannanes. (1989) (0)
- Carbonylative Radical Cyclization Approaches to Tri‐ and Tetraquinanes: Sequential Formation of Three, Four and Five Carbon—Carbon Bonds. (1998) (0)
- Preparation of a Fluorous Chiral BINOL Derivative and Application to an Asymmetric Protonation Reaction. (2000) (0)
- Fluorous Mitsunobu Reagents and Reactions. (2002) (0)
- Group Selective Radical Cyclizations with Oppolzer′s Camphor Sultam. (1994) (0)
- Asymmetric Induction in (3 + 2) Dipolar Cycloaddition Reactions of Nitrile Oxides with Chiral (α-Oxyallyl)silanes (1988) (0)
- Stereoselective Synthesis of 1,2‐Diols by the Cycloadditive Strategy: Total Synthesis of (.+‐.)‐exo‐Brevicomin and (.+‐.)‐ and (‐)‐ Pestalotin. (1992) (0)
- Radical Carbonylations with Fluorous Allyltin Reagents. (1999) (0)
- Thieme Chemistry Journal Awardees - Where are They Now? Catalytic Transport with an Amine Carrier in a Fluorous Triphasic Reaction. (2009) (0)
- Atom-Transfer Cyclization. A Novel Isomerization of Hex-5-ynyl Iodides to (Iodomethylene)cyclopentanes. (1986) (0)
- Camptothecin analog and process for their manufacture (1998) (0)
- Second Generation Synthesis of (20S)‐Camptothecin and Derivatives via a Cascade Radical Reaction (1996) (0)
- Tris(2‐perfluorohexylethyl)tin Hydride (2003) (0)
- Synthesis via Vinyl Sulfones. Part 76. Triflone Chemistry. Part 11. Use of Allylic Triflones for Allylation of C—H Bonds. (1998) (0)
- Highlights from Two Decades of Synthetic Radical Chemistry (2000) (0)
- Tandem Transannular Radical Cyclizations. Total Syntheses of (.+-.)- Modhephene and (.+-.)-Epi-Modhephene. (2010) (0)
- A SHORT SYNTHESIS OF Γ-HYDROXYCYCLOPENTENONES (1983) (0)
- Fluorous Diastereomeric Mixture Synthesis (FDMS) of Hydantoin‐Fused Hexahydrochromeno[4,3‐b]pyrroles. (2011) (0)
- 1,2-Asymmetric Induction in Radical Reactions. Deuteration and Allylation Reactions of β-Oxy-α-bromo Esters. (1993) (0)
- Towards a Tandem-Radical Macrocyclization-Transannular Cyclization Approach to Steroids: Transannular Cyclizations of a Macrocyclic Core. (1996) (0)
- Selective N‐Functionalization of 6‐Substituted‐2‐pyridones. (1996) (0)
- A New Fluorous Methoxymethyl (FMOM) Protecting Group for Alcohols. (2007) (0)
- Fluorous Chemistry in Pittsburgh: 1996—2008 (2009) (0)
- N‐Allylation of Anilides with Chiral Palladium Catalysts: The First Catalytic Asymmetric Synthesis of Axially Chiral Anilides. (2003) (0)
- Atom Transfer Cycloaddition. A Facile Preparation of Functionalized (Methylene)cyclopentanes. (1988) (0)
- New High Speed New High Speed Regioselective Regioselective Heck Coupling Heck Coupling Reactions Assisted By Reactions Assisted By Microwave Flash Heating (2001) (0)
- Samarium‐Mediated Reactions (2008) (0)
- A General Synthetic Approach to the (20S)‐Camptothecin Family of Antitumor Agents by a Regiocontrolled Cascade Radical Cyclization of Aryl Isonitriles. (1998) (0)
- Thermolysis of Bis[2-[(trimethylsilyl)oxy]prop-2-yl]furoxan (TOP-furoxan). (1986) (0)
- Additive and Medium Effects on Lewis Acid‐Promoted Cationic π‐ Cyclizations of Alkenyl‐ and Alkynylcyclopentane‐1,3‐diones. (1995) (0)
- Stereoselective Hydrogen Transfer Reactions of Vinyl Radicals: Cyclization of Alkynyl Iodides by Unimolecular Chain Transfer from Silicon Hydrides. (1997) (0)
- Atom Transfer Addition and Anellation Reactions of Propargyl Iodomalononitrile. (1992) (0)
- Stereoselective Reactions of δ2‐Isoxazoline exo‐Azaenolates. A Model for Construction of the C‐Ring of Sesbanimide A. (1991) (0)
- Switching Enantiofacial Selectivities Using One Chiral Source: Catalytic Enantioselective Synthesis of the Key Intermediate for (20S)‐Camptothecin Family by (S)‐Selective Cyanosilylation of Ketones. (2002) (0)
- The Tin Hydride Reductive Decyanation of Geminal Dinitriles. (2010) (0)
- Radical Cyclizations of Acylgermanes. New Reagent Equivalents of the Carbonyl Radical Acceptor Synthon. (1997) (0)
- Samarium(II) Iodide Mediated Radical/Polar Crossover Reactions of Cyclobutenes: An Efficient Approach to the BCD Ring System of the Penitrems. (2003) (0)
- Synthesis of Perfluoroalkyl-Substituted Aryl Bromides and Their Purification over Fluorous Reverse Phase Silica. (2010) (0)
- Division of Organic Chemistry (1991) (0)
- Fluorous Tin Hydrides: A New Family of Reagents for Use and Reuse in Radical Reactions. (1999) (0)
- Control of Relative Stereochemistry in the Cycloadditive Route to . beta.-Hydroxy Carbonyls. Stereoselective Exo Aldol Reactions of δ 2-Isoxazolines. (1991) (0)
- On the Scope of Asymmetric Nitrile Oxide Cycloadditions with Oppolzer′ s Chiral Sultam. Total Syntheses of (+)-Hepialone, (1R,3R,5S)-(-)-1,3- Dimethyl-2,9-dioxabicyclo(3.3.1)nonane, and (1S)-(-)-7,7-Dimethyl-6,8- dioxabicyclo(3.2.1)octane. (1991) (0)
- New Reagents for Radical Allylations. (2010) (0)
- Enantioselective Conjugate Radical Addition Reactions Mediated by Chiral Lewis Acid Complexes of (R,R)-4,6-Dibenzofurandiyl-2,2′-bis(4-phenyloxazoline) (DBFOX/Ph). (1999) (0)
- N‐Heterocyclic Carbene‐Catalyzed Hydrosilylation of Styryl and Propargylic Alcohols with Dihydrosilanes. (2012) (0)
- Corrigendum: Radical trans-Hydroboration of Alkynes with N-Heterocyclic Carbene Boranes. (2020) (0)
- Selective Sulfonylation of 1,2-Diols and Derivatives Catalyzed by a Recoverable Fluorous Tin Oxide. (2001) (0)
- New Bis-Lactam Chiral Auxiliaries for Nitrile Oxide Cycloadditions. (1993) (0)
- Cram′s Rule for Radical Reactions. (1992) (0)
- Cascade [4 + 1] Radical Annulations of 2,6‐Disubstituted Phenyl Isonitriles with N‐Propargyl‐6‐iodopyridones: Scope, Mechanism and Regioselective Synthesis of 7,9‐Disubstituted Camptothecin Analogues. (2003) (0)
- Transfer of Chirality in Radical Cyclizations. Cyclization of o-Haloacrylanilides to Oxindoles with Transfer of Axial Chirality to a Newly Formed Stereocenter. (2000) (0)
- Conjugate Addition Reactions of Organosamarium Species via in situ Transmetalation to Cu(I) Salts. (1992) (0)
- Atom Transfer Addition and Annulation Reactions of Iodomalonates. (1990) (0)
- A Practical Asymmetric Synthesis of a Pseudomonic Acid Precursor from D-Arabinose or D-Xylose. (2010) (0)
- Iodine Atom Transfer Addition Reactions with Alkynes. Part 1. Alkyl Iodides. (1991) (0)
- Synthesis and Claisen Rearrangement of Alkoxyallyl Enol Ethers. Evidence for a Dipolar Transition State. (1987) (0)
- Controlling Stereochemistry in Radical Addition and Cyclization Reactions with Oppolzer′s Camphor Sultam. (1994) (0)
- Tris(2-perfluorohexylethyl)tin Azide: A New Reagent for Preparation of 5-Substituted Tetrazoles from Nitriles with Purification by Fluorous/Organic Liquid—Liquid Extraction. (1999) (0)
- The Design and Application of Free Radical Chain Reactions in Organic Synthesis. Part 1. (1988) (0)
- Generation and Cycloaddition Reactions of Phenylthio Nitrile Oxide. A Preparation of 3-(Phenylthio)- and 3-(Phenylsulfonyl)-δ2-isoxazolines. (1989) (0)
- Tris(trimethylsilyl)silane as Mediator in the Radical‐Based Allylation Reactions of Allyl and 2‐Functionalized Allyl Phenyl Sulfones. (1996) (0)
- Pair Reactions, Rearrangements and Formation of Alkenes from Radicals (2007) (0)
- Atom-Transfer Addition, Cyclization, and Annulation (1988) (0)
- Asymmetric Total Synthesis of (20R)‐Homocamptothecin, Substituted Homocamptothecins and Homosilatecans. (2002) (0)
- Rearrangement Reactions of 1,1‐Divinyl‐2‐phenylcyclopropanes. (2015) (0)
- Asymmetric Deprotonation of N,N-Dihexyl-1-naphthamides to Provide Atropisomers of N,N-Dihexyl-2-alkyl-1-naphthamides. (1996) (0)
- EXPERIMENTS TOWARDS THE TOTAL SYNTHESIS OF BREFELDIN A (1978) (0)
- Evidence that Palladium(0)-Promoted Cyclizations of Unsaturated α-Iodo Carbonyls Occur by an Atom Transfer Mechanism. (1990) (0)
- A Critical Evaluation of Studies Employing Alkenyl Halide “Mechanistic Probes” as Indicators of Single-Electron-Transfer Processes (1988) (0)
- Palladium‐Catalyzed Stille Couplings with Fluorous Tin Reactants. (1998) (0)
- New Applications of 1,5‐Hydrogen Atom Transfer Reactions: Self‐ Oxidizing Protecting Groups. (1992) (0)
- REDUCTION OF Δ2-ISOXAZOLINES. 2. A FACILE SYNTHESIS OF 3(2H)-FURANONES (1983) (0)
- The Preparation of Optically Active δ2-Isoxazolines. A Model for Asymmetric Induction in the Non Lewis Acid Catalyzed Reactions of Oppolzer′s Chiral Sultam. (1988) (0)
- Control of Relative Stereochemistry in the Cycloadditive Route to β-Hydroxy Carbonyls. Regio- and Stereoselective Exo Alkylation of δ2-Isoxazolines. (1987) (0)
- Additive and Solvent Effects on SmI2 Reductions: The Effects of Water and DMPU. (1994) (0)
- ChemInform Abstract: Recyclable Fluorous Chiral Ligands and Catalysts: Asymmetric Addition of Diethylzinc to Aromatic Aldehydes Catalyzed by Fluorous BINOL-Ti Complexes. (2002) (0)
- Phase-Vanishing Methods Based on Fluorous Phase Screen: A Simple Way for Efficient Execution of Organic Synthesis (2009) (0)
- Bond Rotation Dynamics of N-Cycloalkenyl-N-benzyl α-Haloacetamide Derivatives (2009) (0)
- 2‐Functionalized Allyl Tris(trimethylsilyl)silanes as Radical‐Based Allylating Agents. (1996) (0)
- Acylsilanes as Geminal Radical Acceptor/Radical Donor Equivalents in Tandem Cyclization/Addition Reactions. (1994) (0)
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