Dimitri Coucouvanis

Dimitri Coucouvanis's AcademicInfluence.com Rankings

Dimitri Coucouvanis

Chemistry

#4050

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#5109

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#877

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Chemistry

Dimitri Coucouvanis's Degrees

PhD Chemistry Stanford University
Masters Chemistry Stanford University
Bachelors Chemistry University of California, Berkeley

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Dimitri Coucouvanis's Published Works

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Published Works

Molybdenum Enzymes, Cofactors, and Model Systems. (1993) (157)
Fe-M-S complexes derived from MS42- anions (M = molybdenum, tungsten) and their possible relevance as analogs for structural features in the molybdenum site of nitrogenase (1981) (153)
Tetrahedral mercaptide complexes. Crystal and molecular structures of [(C6H5)4P]2M(SC6H5)4 complexes (M = cadmium(II), zinc(II), nickel(II), cobalt(II), and manganese(II)) (1978) (151)
The Chemistry of the Dithioacid and 1,1‐Dithiolate Complexes (2007) (147)
Square-planar sulfur complexes. VI. Reactions of bases with xanthates, dithiocarbamates, and dithiolates of nickel(II) (1967) (125)
Sulfur Chelates. III. Metal Complexes of the 1,1-Dithiolato Anions S2CS2-, S2CNCN2-, and S2CC(CN)22- (1966) (124)
Use of preassembled iron/sulfur and iron/molybdenum/sulfur clusters in the stepwise synthesis of potential analogs for the Fe/Mo/S site in nitrogenase (1991) (122)
TETRAHEDRAL COMPLEXES CONTAINING THE FE(II)S4 CORE. THE SYNTHESES, GROUND-STATE ELECTRONIC STRUCTURES AND CRYSTAL AND MOLECULAR STRUCTURES OF THE BIS(TETRAPHENYLPHOSPHONIUM) TETRAKIS (THIOPHENOLATO)FERRATE (II) AND BIS (TETRAPHENY LPHOSPHONIUM) BIS(DITHIOSQUARATO)FERRATE (II) COMPLEXES. AN ANALOG FO (1981) (84)
Metastable Fe/S clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3' clusters (L=Cl', Br', I', RS', RO') and the structure of [(C2H5)4N]3[Fe6S6Cl6] (1985) (81)
Metal-mercaptide chemistry. The synthesis and structural characterization of the [Cu(SC6H5)3]2- anion. A rational synthesis and the structure of the [Cu4(SC6H5)6]2- cluster (1980) (80)
Synthesis, interconversions, and structural characterization of the [(S4)2MoS]2-, [(S4)2MoO]2-, (Mo2S10)2-, and (Mo2S12)2- anions (1982) (80)
Kinetic Lability, Structural Diversity, and Oxidation Reactions of New Oligomeric, Anionic Carboxylate-Pyridine Complexes. (1998) (77)
Metal complexes as ligands. IV. Structures of bis[bis(triphenylphosphine)silver(I)]bis[1,2-dicyano-1,2-ethylenedithiolato)nickelate(II), and of the bis[bis(triphenylphosphine)silver(I)] bis(1,1-dicyano-2,2-ethylenedithiolato)nickelate(II) (1974) (75)
Catalytic Reduction of Hydrazine to Ammonia with MoFe(3)S(4)-Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase. (1996) (74)
A new metal cluster system containing a cube of metal atoms (1968) (73)
Catalytic Reduction of Hydrazine to Ammonia by the VFe3S4 Cubanes. Further Evidence for the Direct Involvement of the Heterometal in the Reduction of Nitrogenase Substrates and Possible Relevance to the Vanadium Nitrogenases (1995) (72)
Density functional theory calculations and exploration of a possible mechanism of N2 reduction by nitrogenase. (2004) (71)
Syntheses, Structures, and Reactions of Binary and Tertiary Thiomolybdate Complexes Containing the (O)Mo(Sx) and (S)Mo(Sx) Functional Groups (x = 1, 2, 4) (1998) (65)
Normal-mode analysis of FeCl4- and Fe2S2Cl42- via vibrational mössbauer, resonance Raman, and FT-IR spectroscopies. (2005) (65)
Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten). First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site (1980) (64)
Successful isolation of a reduced tetrathiometallate complex. Synthesis and structural characterization of the [(MoS4)2Fe]3- trianion (1980) (62)
Studies of the reactivity of binary thio- and tertiary oxothiomolybdates toward electrophiles. Reactions with dicarbomethoxyacetylene and the synthesis and structures of the [Et4N2[MoO(L)2], anti-[Et4N]2[Mo2O2S2(L)2]], syn-[Ph4P]2[Mo2O2S2(L)2].cntdot.2DMF, Ph4P]2[Mo(L)3]DMF.cntdot.C6H6, and [Ph4P]2[ (1991) (61)
Metal complexes as ligands. II. Synthesis, structure determination, and bonding characteristic of certain tin(IV) halide adducts of the nickel(II) and palladium(II) dithiooxalato complexes (1973) (58)
Synthesis and reactions of binary metal sulfides. Structural characterization of the [(S4)2Zn]2-, [(S4)2Ni]2-, [(S5)Mn(S6)]2-, and [(CS4)2Ni]2- anions (1985) (57)
Synthesis, structural characterization, and properties of new single and double cubanes containing the MoFe3S4 structural unit and molybdenum-bound polycarboxylate ligands. Clusters with a molybdenum-coordination environment similar to that in the iron-molybdenum cofactor of nitrogenase (1995) (57)
Sulfur Chelates. IV.1Sulfur Addition to Dithiolato Complexes of Nickel(II) (1967) (56)
Iron EXAFS of Azotobacter vinelandii nitrogenase Mo-Fe and V-Fe proteins (1993) (55)
Transition metal hydroborate complexes. V. Crystal structure of tetrahydroboratobis(cyclopentadienyl)titanium(III) (1973) (54)
Binucleating Macrocyclic (14)N4 Ligands and Their Complexes. Synthesis of the Free Ligand 2,3-Dioxo-5,6:13,14-dibenzo-9,10-(4′,5′-dimethylbenzo)-1,4,8,11-tetraazacyclotetradeca-7,11-diene (L) and of the 7,12-Me2-L Metal Complexes and (1990) (54)
Synthesis and characterization of a new series of first row element tetrahedral mercaptide complexes (1975) (53)
Sulfur chelates. VIII. Oxidative addition of sulfur to dithioaryl acid complexes of nickel(II) and zinc(II) (1968) (53)
Metal dithiosquarates. II. Synthesis and characterization of bis(dithiosquarato) tetrahedral and planar complexes. Crystal and molecular structure of potassium bis(dithiosquarato)nickelate(II) dihydrate (1975) (50)
Useful Reagents and Ligands (2002) (49)
Synthesis, molecular structure, and reactions of bis(tetraphenylphosphonium) hexakis(.mu.-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2[Fe4(SPh)6Cl4]. Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S4(Cl)2(SC6H5)2]2- "Cubane"-type clusters (1982) (47)
Metal complexes as ligands. III. Bonding interactions of the anionic metal dithiooxalate complexes with the coordinately unsaturated bis(triphenylphosphine)copper(I) and bis(triphenylphosphine)silver(I) complex cations (1973) (47)
Synthesis and Characterization of a New Class of Asymmetric Aqua-Acetate Bridged Dimers. Solid State Molecular Structures of the [M2(.mu.-H2O)(.mu.-OAc)2(OAc)3(Py)2]- Anions (M = Mn(II), Fe(II), Co(II)). A Structural Model for the Fe2 Site in Methane Monooxygenase (1995) (47)
Unique reactivity characteristics of Mo-coordinated S2−2 and S2−4 ligands (1986) (46)
Synthesis of 1,2-dithiosquarate salts and x-ray crystal structure of potassium bis(dithiosquarato)nickelate(II) (1974) (44)
The catalytic reduction of hydrazine to ammonia by the MoFe3S4 cubanes and implications regarding the function of nitrogenase. Evidence for direct involvement of the molybdenum atom in substrate reduction (1993) (44)
A new Mo(IV) thioanion containing the Mo=S, unit. Synthesis and structural characterization of (Et4N)2MoS9 (1981) (43)
THE CHEMISTRY OF THE DITHIOACID AND 1,1‐DITHIOLATE COMPLEXES, 1968‐1977 (2007) (42)
Metallocubanes. Crystal and molecular structures of tetrakis(tetraphenylphosphonium) hexakis(dithiosquarato)octacuprate(I) and tetrakis(tetrabutylammonium) hexakis(1,1-dicarboethoxyethylene-2,2-dithiolato) octacuprate(I) clusters with a common Cu8S12 core (1977) (40)
Dinuclear iron-molybdenum-sulfur complexes containing the FeS2Mo core. Syntheses, ground-state electronic structures and crystal and molecular structures of the [(C6H5)4P]2[(C6H5S)2FeS2MoS2], [(C2H5)4N]2[(C6H5S)2FeS2WS2], and [(C6H5)4P]2[(S5)FeS2MS2] (M = Mo, W) complexes (1983) (39)
Synthesis, structural characterization, and electronic structures of the mixed terminal ligand iron-sulfur cubanes [Fe4S4Cl2(XPh)2]2- (X = S, O) and [Fe4S4(SPh)2(OC6H4Me-p)2]2-. The first examples of [Fe4S4]2+ cores with a noncompressed D2d idealized geometry (1984) (39)
Catalytic Reduction of cis-Dimethyldiazene by the [MoFe3S4]3+ Clusters. The Four-Electron Reduction of a NN Bond by a Nitrogenase-Relevant Cluster and Implications for the Function of Nitrogenase (1997) (39)
HETERODINUCLEAR DI-μ-SULFIDO BRIDGED DIMERS CONTAINING IRON AND MOLYBDENUM OR TUNGSTEN. STRUCTURES OF (PH4P)2(FEMS9) COMPLEXES (M = MOLYBDENUM, TUNGSTEN) (1980) (38)
Letter: The crystal and molecular structures of [(C6H5)4P]2Fe(S2C4O2)2 and [(C6H5)4P]2Fe(SC6H5)4, a structural analogue of reduced rubredoxin. (1976) (38)
Use of [MoFe3S4]3+ Single Cubanes in the Catalytic Reduction of Acetylene to Ethylene and Ethane. Identification of Molybdenum and Iron Atoms as Catalytic Sites during Substrate Reduction and Implications for Nitrogenase Action (1995) (37)
Synthesis, Structural Characterization, and Electronic Properties of the Ph4P+ Salts of the Mixed Terminal Ligand Cubanes Fe4S4(Et2Dtc)n(X)4-n 2-(X = Cl-, PhS-) (n = 1, 2). Two Different Modes of Ligation on the [Fe4S4]2+ Core (1985) (36)
Metal complexes as ligands—VI: Bonding interactions of anionic nickel dithiolate complexes with the coordinately unsaturated bis(triphenylphosphine)copper(I) and bis(triphenylphosphine)silver(I) complex cations (1975) (35)
Functional analogs for the reduction of certain nitrogenase substrates. Are multiple sites within the Fe/Mo/S active center involved in the 6e– reduction of N2? (1996) (35)
New .mu.2-S2--coupled, singly bridged double cubane with the [(Fe4S4Cl3)2S]4- core. The stepwise synthesis and structural characterization of (n-Bu4N)2(Ph4P)2[(Fe4S4Cl3)2S] (1990) (35)
Synthesis and Structural Characterization of the New Mo2Fe6S8(PR3)6(Cl4-cat)2 Clusters. Double Cubanes Containing Two Edge-Linked [MoFe3S4]2+ Reduced Cores (1995) (34)
Catalytic and stoichiometric multielectron reduction of hydrazine to ammonia and acetylene to ethylene with clusters that contain the MFe3S4 cores (MMo, V). Relevance to the function of nitrogenase (1996) (34)
Rational Synthesis of High Nuclearity Mo/Fe/S Clusters: The Reductive Coupling Approach in the Convenient Synthesis of (Cl4-cat)2Mo2Fe6S8(PR3)6 [R = Et, nPr, nBu] and the New [(Cl4-cat)2Mo2Fe2S3O(PEt3)3Cl]·1/2(Fe(PEt3)2(MeCN)4) and (Cl4-cat)2Mo2Fe3S5(PEt3)5 Clusters (2001) (34)
Chemistry of [Fe6S6]3+ prismatic cages. Synthesis, structural characterization, and electronic structures of the [Et4N]3[Fe6S6L6] clusters (L=p-CH3C6H4O−, Br−) (1986) (33)
Metal complexes as ligands. V. Crystal and molecular structures of tris(bis(triphenylphosphine)silver(I)) tris(dithiooxalato)iron(III) and -aluminum(III) (1974) (33)
Mixed Carboxylate/Catecholate Polynuclear Complexes. Integral Association of Trivalent Lanthanide Ions with Mn4 Units in the Pentanuclear Mn4LaCl and Mn4Tb Clusters (1998) (32)
The Chemistry of Synthetic Fe–Mo–S Clusters and their Relevance to the Structure and Function of the Fe–Mo–S Center in Nitrogenase (2007) (32)
Crystallographic evidence for copper-copper bonding at 2.8 Ang. Crystal and molecular structure of tetrakis(tetraphenylphosphonium) hexakis(1,2-dithiosquarato)octacuprate(I) (1974) (32)
Oxidative transformation of the [Fe4S4X4]2- "cubanes" to the [Fe6S6X6]2- "prismane" clusters (X = Cl, Br). The crystal and molecular structure of [(C6H5)4P]2Fe6S 6Cl6 (1984) (32)
Synthesis of thiomolybdenyl complexes with [Mo2(S)2(O)2]2+ cores and substitutionally labile ligands. Crystal and molecular structure of the tris(dimethylformamide)dioxotetrasulfidodimolybdenum complex (1988) (32)
Reaction of MoS/sub 9//sup 2 -/ with Bis(carboxymethyl)acetylene. Crystal and molecular structure of (Ph/sub 4/P)/sub 2/Mo(S/sub 2/C/sub 2/(COOMe)/sub 2/)/sub 3/: a trigonal prismatic complex with a new dithiolene ligand (1983) (31)
A new class of bis(.mu.-aryloxy)-bridged dimers with first-row divalent transition-metal ions. Synthesis and structural characterization of the (Et4N)2[M2Cl4(O-C6H4-p-CH3)2] complexes (M = Mn(II), Fe(II), Co(II), Zn(II), and Cd(II)) (1988) (31)
Dimeric complexes containing the disulfidodiron(2+) cores coordinated by non-sulfur terminal ligands. Synthesis, structural characterization, and spectroscopic properties of [Et4N]2[Fe2S2(o,o'-C12H8O2)2], [Et4N]2[Fe2S2(C4H4N)4], and [Et4N]2[Fe2S2(O-o-C6H4CH(n-C4H9)NHC6H4-o-S)2] and the structure of (1988) (31)
Trinuclear Fe―M―S complexes containing a linear Fe―M―Fe array and a bridging S2MS2 unit. Electronic structures and crystal and molecular structures of the [(C6H5)4P]2[Cl2FeS2MS2FeCl2] (M=Mo, W) complexes (1984) (30)
Synthesis and characterization of sulfur-voided cubanes. Structural analogues for the MoFe(3)S(3) subunit in the nitrogenase cofactor. (2002) (30)
Nitrogenase substrates as intercluster bridging units between the molybdenum atoms in doubly bridged, double cubanes. The synthesis and characterization of the [MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-L)]n- anions (L = N2H4, n = 4; L = CN-, n = 5) (1990) (29)
Dimeric complexes containing the disulfidodiiron(2+) cores coordinated by non-sulfur containing terminal ligands. The crystal and molecular structures of the tetraethylammonium salts of the [Fe2S2(o,o'-C12H8O2)2]2- and [Fe2S2(C4H4N)4]2- anions (1984) (29)
Coordination unsaturation in the iron tetrahiometalate complexes. Synthesis and structural characterization of the [Fe(WS4)2(HCON(CH3)2)2]2- complex anion (1981) (28)
Dynamics of an [Fe4S4(SPh)4]2- cluster explored via IR, Raman, and nuclear resonance vibrational spectroscopy (NRVS)-analysis using 36S substitution, DFT calculations, and empirical force fields. (2006) (27)
SYNTHETIC ANALOGS FOR THE MOFE3S3 SUBUNIT OF THE NITROGENASE COFACTOR : STRUCTURAL FEATURES ASSOCIATED WITH THE TOTAL NUMBER OF VALENCE ELECTRONS AND THE POSSIBLE ROLE OF M-M AND MULTIPLE M-S BONDING IN THE FUNCTION OF NITROG ENASE (1999) (27)
The formation of perthiocarbonate ligands following the addition of CS2 to binary molybdenum-sulfur complexes. The crystal and molecular structures of the (Ph4P)2[(CS4)2MoS].DMF and (Ph4P)2[(CS4)Mo2S4(CS4)].1/2DMF complexes (1982) (26)
New members of the [Mo2(S)n(S2)6−n]2− series. Synthesis, structural characterization, and properties of the [Mo2S9]2−, [Mo2S7]2−, and [Mo2S6]2− thio anions (1987) (26)
Crystal and molecular structure of bis(ethyl thioxanthato)-.mu.-bis(ethyl thioxanthato)-.mu.'-bis(ethylthio)diiron(III) (1970) (25)
Metal complexes as ligands. New Class of polynuclear dithiolate complexes (1970) (25)
Addition of activated acetylenes to coordinated polysulfide ligands. 2. Synthesis of the Fe2[S2C2(COOCH3)2]42- dithiolene complex by the addition of CH3OOCC.tplbond.CCOOCH3 to the (Fe2S12)2- anion. The crystal and molecular structure of (Ph4P)2Fe2[S2C2(COOCH3)2]4 (1984) (25)
Sulfur-Bridged Dimeric Complexes of Iron (III) (1970) (25)
STRUCTURAL CHARACTERIZATION AND REACTIVITY PROPERTIES OF A NEW CLASS OF MO/FE/S DOUBLE CUBANES WITH MO-BOUND S-MU 2-ETA 1,O-ETA 1 MERCAPTO CARBOXYLATE LIGANDS. NEW CATALYSTS FOR THE REDUCTION OF HYDRAZINE TO AMMONIA AND IMPLI CATIONS REGARDING THE FUNCTION OF NITROGENASE (1995) (25)
Synthesis, structural characterization, and properties of the [Mo2O2S9]2- thio anion and the [Mo4O4S18]2-, [Mo2O2S8(SCH3)]-, and [Mo2O2S8Cl]- derivatives (1989) (24)
Synthesis and structural characterization of the tetraethylammonium salts of the new tetrakis(disulfido)dioxo-.mu.-sulfidodimolybdate(2-) and bis[.mu.-sulfidobis[bis(disulfido)oxomolybdate](2-) oxo-disulfido-molybdate(VI) anions (1987) (24)
Further on the Myth of Nickel(IV)-Sulfur Chelates. V (1967) (24)
Synthesis, characterization, and reactivity of new clusters that contain the [MFe3S4]0 core, M = molybdenum, tungsten. A weakly perturbed [MFe3S4]0 unit structurally and electronically analogous to the reduced three-ion centers in ferredoxins (1992) (23)
Single and double MoFe3S4 cubanes with molybdenum-coordinated polycarboxylate ligands. Syntheses and structural characterization of (Et4N)4{[MoFe3S4Cl4]2(.mu.-C2O4)} and (Et4N)3([MoFe3S4Cl4(C2O4)] clusters (1993) (23)
Preparation and structural characterization of six-coordinate iron(III) complexes containing the Fe-S-S linkage (1968) (23)
Reaction of [Fe(SC6H5)4]2- with organic trisulfides and implications concerning the biosynthesis of ferredoxins. Synthesis and structure of the [(C6H5)4P]2Fe2S12 complex (1979) (23)
Borohydride anions as terminal ligands on a Fe/Mo/S cluster. Synthesis, structure, and characterization of the [(Cl4-cat)(PPr3)MoFe3S4(BH4)2]2(Bu4N)4 double-fused cubane. (2004) (22)
Reactivity and kinetic studies of (NH4)2(MoS4) in acidic aqueous solution: possible relevance to the angiostatic function of the MoS4(2-) ligand. (2009) (22)
ESR of spin 5/2 systems with axial symmetry and moderately large zero‐field splittings. Application of line‐shape calculations to the interpretation of randomly oriented microcrystallite spectra (1973) (22)
CROWN-ETHER-FUNCTIONALIZED NICKEL SALICYLALDIMINE COMPLEXES. STRUCTURAL CHARACTERIZATION OF THEIR POTASSIUM, CESIUM, AND HEXYLAMMONIUM DERIVATIVES AND THEIR USE IN THE TRANSPORT OF AMINO ACIDS (1998) (21)
Crystal and molecular structure of bis[bis(diphenylethylphosphine)silver(I)] bis(1,2-dicyano-1,2-ethylenedithiolato)nickelate(II), [Ag(P(C6H5)2(C2H5))2]2Ni(S2C2(CN)2)2. Steric effects on the phosphorus-silver-phosphorus angle (1976) (21)
First examples of polynuclear, sulfur-containing, zirconium compounds. Synthesis and structural characterization of the trinuclear Zr3S3(S-tert-Bu)2(BH4)4(THF)2 and the hexanuclear Zr6S6(S-tert-Bu)4(BH4)8(THF)2 clusters (1985) (21)
Syntheses and Structural Characterization of a New Class of Double Cubanes That Contain MoFe3S4 Subunits and Molybdenum-Coordinated, Bridging Mercapto-Carboxylate Ligands. Effective Catalysts for the Reduction of Hydrazine to Ammonia (1994) (20)
Zirconium-Sulfur Chemistry. Synthesis and Structural Characterization of the Zr3S3(tBuS)2(BH4)4(THF)2, Zr6S6(tBuS)4(BH4)8(THF)2, Zr3(S)(tBuS)10, and (Mg(THF)6)[Zr2(SPh)7.2(CH2Ph)1.8]2.cntdot.3THF Clusters. Activation and Cleavage of the C-S bond in Zirconium-Coordinated Alkanethiolate Ligands (1994) (20)
Mössbauer effect in synthetic analogs of rubredoxin (1976) (20)
An inorganic functional group approach to the systematic synthesis and reactivity studies of binuclear Mo/S and Mo/S/O complexes (1989) (20)
First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2 (1990) (20)
A Dimeric Iron(III) Complex Containing Two Ethyl Mercaptide and Two Ethyl Thioxanthate Groups as Bridging Ligands (1969) (19)
Synthesis, Structural Characterization, and Electronic Properties of the [Fe6S6X6(M(CO)3)2]n-Anions (M = Mo, W; n = 3, 4; X = Cl, Br, I). Heteronuclear Clusters of Possible Structural Relevance to the Fe/Mo/S Center in Nitrogenase (1988) (19)
Activation and cleavage of the carbon-sulfur bond in niobium tert-butanethiolato complexes. Syntheses and structural characterizations of the tetrahedral and trigonal bipyramidal [Ph4P][NbV(S)2(tert-BuS)2] and [Et4N][NbV(S)(tert-BuS)4] complexes (1992) (18)
New [Fe6S6Cl6(Mo(CO)3)2]n- (n = 3, 4) clusters. Derivatives of either [Fe6S6Cl6]3- or [Fe4S4Cl4]2- with possible relevance to the iron-molybdenum-sulfide center in nitrogenase (1986) (18)
Lipophilic Metal−Salicylideneimine−Crown Ether Hybrids — Ditopic Carriers in the Facilitated Transport of Amphiphilic Molecules Across Bulk Liquid Membranes (2001) (18)
Synthesis, structural characterization, and properties of singly bridged double molybdenum-iron cubanes containing two [(Cl4-cat)MoFe3S4Cl3]2- subunits and hydrazine or pyrazine bridges (1993) (18)
Transition metal ions in high formal oxidation states. Structural characterization of the nickel and copper complexes of the 1,1-dicarboethoxy-2,2-ethylenedithiolate ligand (1976) (18)
Mixed Carboxylate/Catecholate Bridged Polynuclear Complexes. Tetranuclear Linear Arrays and Pentanuclear Clusters with [M4M‘O8]3+ Cores (M = Fe2+, Mn+2; M‘ = Fe3+, Mn+3). Rare Examples of Dodecahedrally Coordinated, First Row, Trivalent Metal Ions (1998) (18)
Synthesis and characterization of a new Fe/Mo/S cluster containing the [Fe6Mo2S6]3+ core. A precursor to a possible structural analogue for the Fe/Mo site of nitrogenase (2002) (18)
Crystal structure determination of bis(tetraphenylphosphonium) heptasulfide, (Ph4P)2S7 (1983) (18)
Molybdenum enzymes, cofactors, and model systems : developed from a symposium sponsored by the Division of Inorganic Chemistry at the 204th National Meeting of the American Chemical Society, Washington, DC, August 23-28, 1992 (1993) (17)
Synthesis and structure of singly bridged and doubly bridged [MoFe(3)S(4)] double cubanes with bidentate phosphine ligands. (2002) (17)
A New Cubane Cluster with the [MoFe3S4]0 Core and Possible Relevance to the Fe3‐Centers in Ferredoxins. The Synthesis, Structure and Properties of the [Fe3S4(SEt)3Mo(CO)3]3⊖ Anion (1988) (17)
Crystal and molecular structure of thio-p-toluoyldisulfidobis (dithio-p-toluato)iron(III) (1969) (17)
A new iron–sulphide cluster containing the ‘prismane’[Fe6(µ-S)6]3+ core. Synthesis, structure, and properties of [Et4N]3[Fe6S6Cl6] (1984) (16)
Synthesis and reactivity of a new octanuclear iron-sulfur nitrosyl cluster. (2006) (16)
New Fe/Mo/S Clusters with MoFe3S3 Cuboidal Cores Similar to the One in the Fe/Mo Cofactor of Nitrogenase. Synthesis and Structural Characterization of the (C14-cat)MoFe3S3(PEt3)2(CO)6 and (C14-cat)Mo(O)Fe3S3(PEt3)3(CO)5 Clusters (1997) (16)
Crystal and Molecular Structures of the Copper(II) and Copper(III) Dithiooxalate Complexes (18-crown-6)2K2Cu(S2C2O2)2 and ([(C6H5)3P]2N)Cu(S2C2O2)2 (1985) (16)
Stepwise synthesis and structural characterization of the molybdenum-iron-sulfur {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)2}6- and {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-OH}5- doubly bridged double cubanes obtained by the coupling of [MoFe3S4] clusters (1989) (16)
Thioxanthate complexes. Carbon disulfide eliminations to form bridged mercaptide dimers of nickel(II) and palladium(II) (1972) (16)
Chalcogenometalate Complexes of NbV and TaV. Synthesis and Structural Characterization of the Et4N+ Salts of the[(E)3M(StBu)]2- Complexes (E = S, M = Nb, Ta; E = Se, M = Nb) and of (Ph4P)2[(S)3M(OMe)] (1994) (15)
A new function of the (mu(3)-S) ligand in an Fe(4)S(4) cluster: synthesis and structure of the high-nuclearity Mo/Fe/S cluster, Fe(DMF)Cl(Cl(4)-cat)(2)-Mo(2)Fe(2)S(4)(PEt(3))(2)ClFe(4)S(4)(PEt(3))(3)(CO)(6)Cl. (2001) (15)
Synthesis and molecular structure of a six-coordinate iron(IV) complex with a new 1,1-dithiolate ligand (1974) (15)
Crown-Ether-Functionalized Mn(III) Salicylaldimine Complexes as Ditopic Carriers. Efficient Transport of Tryptophan and Serotonin across a CHCl3 Barrier (1998) (15)
Mössbauer, magnetic susceptibility, and EPR studies of intermediate spin iron (III) dithiooxalato halides (1978) (15)
Synthesis, structural characterization and electronic structures of the [Fe6S6(X)6(Mo(CO)3)2]3- clusters (X = Cl, Br) (1987) (15)
Synthesis and Structural Characterization of the [Nb(O)(S2)2SH]2-, [Nb(S)3SH]2-, and {[Nb(S)3]2O}4- anions. New elementary Thio- and Oxothioniobates (1995) (15)
Chemistry of the copper-dithiooxalate complexes. Synthesis of a new carbonyl sulfide complex (1971) (14)
Transition metal ions in high formal oxidation states. Synthesis and structural characterization of the six-coordinate iron(IV) complex of the 1,1-dicarboethoxy-2,2-ethylenedithiolate chelating ligand (1977) (14)
Uncharged Mixed-Ligand Clusters with the [Fe4S4]+ and [Fe4S4]2+ Cores. Synthesis, Structural Characterization, and Properties of the Fe4S4X(tBu3P)3 (X = Cl, Br, I) and Fe4S4(SPh)2(tBu3P)2 Cubanes (1995) (14)
Superclusters: a host-guest complex with a cyclic array of three bridged MoFe3S4 clusters. (2004) (14)
Metal complexes as ligands. 9. Crystal and molecular structure of potassium bis(tri-p-tolylphosphine)copper(I) bis(dithiooxalato-O,O')stannate(IV)-2-acetone, KSn[S2C2O2)3Cu(P(C7H7)3)2].2C3H6O (1977) (13)
Spectroscopic and structural evidence of temperature dependent charge localization and structural differentiation of the iron sites within the [Fe6S6X6]2- clusters (X = chloro, bromo) (1987) (13)
A new Fe/S cluster with the (Fe6S6)3+ prismatic core and p-methylphenolate terminal ligands: the synthesis, structure, and properties of (Et4N)3Fe6S6(OC6H4-p-CH3)6 (1985) (13)
Synthesis, electronic structure, and structural characterization of the new, "non-innocent" 4,5-dithio-catecholate ligand, its metal complexes, and their oxidized 4,5-dithio-o-quinone derivatives. (2009) (13)
Mixed-valence coinage metal clusters with 1,1-thioperthio ligands. Syntheses and molecular structures of the copper and gold [Cu4L3]2-, [Cu5L4]-, and [AuCu4L4]- anions (L = 1,1-dicarbo-tert-butoxyethylene-2,2-thioperthiolate). A geometrically-locked, charge-separated valence state in the [Cu5L4]- an (1993) (13)
The synthesis and structural characterization of the [Nb(Se)3StBu]2−, [Nb(O)(Se2)SeH]2−, [(Nb(O)(Se2)2)2Se4]4− and {[Nb(Se)3]2O}4− anions. New elementary selenoniobates (1997) (13)
Ground-state electronic and magnetic properties of MS2−4 derived trinuclear M-Fe-S complexes (M = Mo, W) (1981) (13)
Acid-base reactions of the metallocubanes. Synthesis and structural characterization of Cu10[S2CCH(COO-t-C4H9)2]6[S2CC(COO-t-C4H9)2]2, a ten copper atom aggregate (1977) (13)
Chemistry of the iron-dithiooxalate complexes (1970) (13)
Synthesis and structural characterization of [(NO)2 FeS2MoS2]2− a dinitrosyl complex containing the FeS2MoS2 core (1981) (12)
Volatile Rare‐Earth Chelates of 2,2,6,6‐Tetramethylheptane‐3,5‐Dione (2007) (12)
A New Class of Complexes Possessing Cofacially-Oriented, Planar, Metal-Containing Subunits. Synthesis, Characterization, and Reactivity of [(MoO(2))(2)(&mgr;-O)](2+)-Linked, Catechol-Functionalized, Tetraazamacrocyclic and Salicylideneamine Complexes. (1998) (12)
Kinetics of the chemical and electrochemical, reversible oxidation of bis(dithiooxalato-S,S')cuprate(II), [Cu(Dto)2]2-. A facile, light-activated, intramolecular electron transfer and cleavage of the carbon-carbon bond in the coordinated Dto ligands in the [Cu(Dto)2]- anion (1984) (12)
Synthesis and structural characterization of the tetraphenylphosphonium salts of the sulfido(tetrasulfido(2-))(tetrathiomolybdate)molybdate(2-) anion and its hexathiodimolybdate(2-) and heptathiodimolybdate(2-) desulfurized derivatives (1986) (11)
Molybdenum‐Sulfur Clusters (2007) (11)
Protonation of the 1,1-dithiolene ligands in the [Cu8(L)6]4- cubanes (L = [S2C:C(COOR)2]2-) and synthesis of the [Cu8(L)6-n(H-L)n]-(4-n) clusters. Synthesis and structural characterization of the [Cu10(H-L)6(L)2] decanuclear cluster (1989) (11)
X-Ray crystal structure of bis(tetraethylammonium)di-µ-thio-[bis(phenylthio)ferrate(III)[dithiomolybdate(V)], [Et4N]2[(PhS)2FeMoS4]: a dinuclear complex with the FeMoS2 core (1979) (11)
Synthesis and characterization of new heterometallic iron sulfur nitrosyl clusters (2007) (11)
Oxidation by elemental sulfur and coupling of iron/sulfur complexes. Synthesis and structural characterization of tetrakis(tetraethylammonium) tetrakis(ethanethiolato)hexasulfidotetraferrate, a new Fe/S cluster with a linear Fe4 backbone (1991) (11)
Rational synthesis of monooxo thioanions from tetrakis(benzenethiolato)oxomolybdate(1-). Structural characterization of the [Ph4P]+ salts of the [(.eta.2-S2)MoO(.mu.-S)2MoS(.eta.2-S2)]2-, [(.eta.2-S2)MoO(MoS4)]2-, [(S4)MoX(.mu.-S)2MoSX(.eta.2-S2)]2- (X = S, O), and [(S4)MoO(MoS4)]2- anions (1989) (10)
METASTABLE IRON/SULFUR CLUSTERS. THE SYNTHESIS, ELECTRONIC STRUCTURE, AND TRANSFORMATIONS OF THE (FE6S6(L)6)3- CLUSTERS (L = CL-, BR, I-, RS-, RO-) AND THE STRUCTURE OF ((C2H5)4N)3(FE6S6CL6) (1985) (10)
Borohydride, azide, and chloride anions as terminal ligands on Fe/Mo/S clusters. Synthesis, structure and characterization of [(Cl4-cat)(PPr3) MoFe3S4(X)2]2(Bu4N)4 and [(Cl4-cat)(PPr3)MoFe3S4 (PPr3)(X)]2(Bu4N)2 (X = N3-, BH4-, Cl-) double-fused cubanes. NMR reactivity studies of [(Cl4-cat)(PPr3) MoF (2006) (10)
Isolation and Characterization of Single and Sulfide-Bridged Double [4Fe–4S] Cubane Clusters with 4-Pyridinethiolato Ligands (2013) (10)
Systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a pentlandite-like M8S6 core. (2005) (9)
New heteronuclear Mo/Fe/S clusters. The syntheses and structures of (Cl4-cat)Mo(PEt3)Fe3S4(SPEt3)2Cl and (Cl4-cat)2MoFe2S2(PEt3)2(CO)4 clusters (2002) (9)
A NEW MOLYBDENUM(IV) THIOANION CONTAINING THE MO:ST UNIT. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF BIS(TETRAETHYLAMMONIUM) NONATHIOMOLYBDATE (1981) (9)
Dimerization of the molybdenum complex [(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)]2- dianions stabilized by a quadruply bridging sulfate ligand and intramolecular hydrogen bonding by the [(CH3)2NH2]+ cations. Structures of the [(CH3)2NH2]6-x(Et4N)x[{(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)}2(SO4)] aggregates (x = 1, 2, 2. (1993) (9)
SYNTHESIS, INTERCONVERSIONS, AND STRUCTURAL CHARACTERIZATION OF THE MOLYBDENUM SULFIDE ANIONS, ((S4)2MOS)2-, ((S4)2MOO)2-, (MO2S10)2- AND (MO2S12)2- (1982) (9)
Synthesis and structural characterization of the nickel(II) and copper(III) complexes of the 1,1-dicarboethoxy-2,2-ethylenedithiolate ligand (1974) (9)
Synthesis and Characterization of MoFe3S4 and Mo2Fe2S4 Single Cubanes (2008) (9)
Reactions of the molybdenum-sulfur double bond in the [(Cp)Mo(O)(.mu.-S)2Mo(O)(S)]- complex with sulfur dioxide. An proton NMR study and the synthesis and structural characterization of [(Cp)Mo(O)(.mu.-S)2Mo(O)(L)]- complexes containing SO2-derived sulfite, thiosulfate, and sulfate bidentate chelati (1993) (9)
Sulfur‐Bridged Dinuclear Molybdenum(V) Complexes with Mo2O3S and Mo2O2S2 Cores (2007) (9)
REACTION OF (FE(SC6H5)4)2- WITH ORGANIC TRISULFIDES AND IMPLICATIONS CONCERNING THE BIOSYNTHESIS OF FERREDOXINS. SYNTHESIS AND STRUCTURE OF THE ((C6H5)4P)2FE2S12 COMPLEX (1979) (9)
Structure of bis(tetraethylammonium) tetrathiomolybdate(VI), 2C8H20N+.MoS42− (1983) (8)
A tetrahedral complex of nickel(II) with the pseudo-halide cyanate (1964) (8)
CRYSTALLOGRAPHIC EVIDENCE FOR COPPER-COPPER BONDING AT 2,8 A, THE CRYSTAL AND MOLECULAR STRUCTURE OF TETRAKIS(TETRAPHENYLPHOSPHONIUM) HEXAKIS(1,2-DITHIOSQUARATO)OCTACUPRATE(I) (1974) (8)
Heterodinuclear Di-.mu.-sulfido bridged dimers containing iron and molybdenum or tungsten. Structures of (Ph4P)2(FeMS9) complexes (M = molybdenum, tungsten) (1980) (8)
Synthesis and structure of the organometallic MFe2(mu3-S)2 clusters (M = Mo or Fe). (2005) (8)
Multifunctional macrocyclic ligands. Synthesis and characterization of nickel(II) and cobalt(II) macrocyclic-catechol complexes and their dimeric, antiferromagnetically coupled, semiquinone derivatives (1993) (8)
Compounds of General Interest (2002) (8)
Synthesis and structures of perthio- and polymeric metal complexes with the tetrathio- and dithioterephthalate ligands (2013) (8)
Metal complexes as ligands. 8. Synthesis and characterization of polynuclear dithiooxalate copper(I)-tin(IV) complexes of the general type M[(O2C2S2)CuL2]n (1977) (7)
Macrocyclic catechol complexes as ligands in the synthesis of heterometallic supramolecules (1993) (7)
TRINUCLEAR FE-M-S COMPLEXES CONTAINING A LINEAR FEMFE ARRAY AND A BRIDGING S2MS2 UNIT. ELECTRONIC STRUCTURES AND CRYSTAL AND MOLECULAR STRUCTURES OF THE ((C6H5)4P)2(CL2FES2MS2FECL2) (M = MO, W) COMPLEXES (1984) (7)
Recognition and transport of amphiphilic molecules by a new class of inorganic ditopic receptors. The synthesis of M-t Bu4-salphen-3n-cr-n complexes and their use (M = Mn,Fe, n = 6) in the transport of tryptophan and serotonin across bulk liquid membranes (2003) (7)
The synthesis and structural characterization of Zr3(S)(ButS)10. A Zr–S cluster that contains thiolate ligands in three different modes of co-ordination (1985) (7)
Metal clusters as ligands. Substitution of fe ions in Fe/Mo/S clusters by thiophilic CuI ions. (2006) (7)
Catalytic Multielectron Reduction of Hydrazine to Ammonia and Acetylene to Ethylene with Clusters That Contain the MFe3S4Cores (M = Mo, V): Relevance to the Function of Nitrogenase (1996) (7)
Macrocyclic catecholate complexes as ligands. Synthesis, structural characterization and properties of the [MH2ETC] and {[Ni(ETC)]Cu}– complexes (M = Co, Ni; H4ETC = the macrocyclic catechol, 2,3-ethylene-5,6:13,14-di(5′-methylbzo)-9,10-(4′,5′-diolbzo)-[14]-1,4,8,11-[N4]-7, 12-diene) (1996) (7)
Oxidative decoupling of the molybdenum-iron-sulfur MoFe3S4 clusters and possible relevance to the oxidative degradation of the nitrogenase cofactor. Isolation and structural characterization of the [(Cl4cat)Mo(O)(.mu.-S)2FeCl2]2- anion (1993) (7)
Normal-Mode Analysis of FeCl 4-and Fe 2 S 2 Cl 42-via Vibrational Mo 1 ssbauer , Resonance Raman , and FTIR Spectroscopies (2005) (6)
Synthesis and Characterization of [Mo(2)O(5)](2+)-Bridged Complexes Containing Cofacially-Oriented, Catechol-Functionalized Macrocyclic and SALPHEN Ligands. (1996) (6)
IUPAC Glossary of Terms Used in Bioinorganic Chemistry (2000) (6)
The synthesis, and properties of Fe/Mo/S clusters with MoFe3S4 cubane subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} (1994) (6)
6. Tetrakis(Benzenethiolato)Metallate(2–) Complexes, [M(SPh)4]2‐, of Manganese, Iron, Cobalt, Zinc, and Cadmium and Derivatives of the [Fe(SPh)4]2‐ Complex (2007) (4)
EXAFS model for the iron-molybdenum cofactor of nitrogenase: molybdenum, tungsten, and iron EXAFS of the [Cl2FeS2MS2FeCl2]2- (M = molybdenum or tungsten) dianions. A comparison with the Mo EXAFS of nitrogenase (1983) (4)
Sulfur addition to the 1,1-dithiolate ligands in the [Cu8L6]4- cubanes (L = 1,1-dicarbo-tert-butoxy-2,2-ethylene dithiolate). Reversible Cu8(LS)64- to Cu4(LS)32- transformations (1982) (4)
Recent Structure Determinations of the Molybdenum—Iron Protein of Nitrogenase: Impact on Design of Synthetic Analogs for the Iron-Molybdenum-Sulfur Active Site and the Iron—Molybdenum Cofactor (1993) (4)
Connecting [4Fe–4S] Clusters and Hemes – Towards Modeling the Active Site of Sulfite Reductase (2013) (4)
Enzyme electrode with enhanced specificity using outer polymeric membrane doped with substrate selective ditopic carrier (2000) (4)
Extended X-ray Absorption Fine Structure and L-Edge Spectroscopy of Nitrogenase Molybdenum—Iron Protein (1993) (4)
Metal clusters as ligands: substitution of Fe ions in Fe/Mo/S clusters by thiophilic Cu(I) ions to give clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ cores. (2005) (4)
Syntheses of Selected Supramolecules (2002) (3)
Bernstein's bond length-bond order relation is applied to carbon-nitrogden, carbon-oxygen, and nitrogen-oxygen bonds in metal complexes (1968) (3)
Sulfur‐Bridged Cubane‐Type (Mo4S4) and Incomplete Cubane‐Type (Mo3O4 – nSn; n = 1–4) Molybdenum Aqua Ions (2007) (3)
A synthetic iron-containing prismane complex: peculiar electron-delocalization and spin-coupling properties deduced from Mössbauer and magnetization studies (1998) (3)
Fe-Mo complexes of cysteinyl peptides (1982) (3)
Density functional theory calculations on the nitrogenase cofactor and synthetic analogs (2003) (3)
The synthesis and structural characterization of [Et4N]3[Fe6S6(p-MeC6H4O)6{W(CO)3}2]. A hetero-polynuclear aggregate that contains the [W2Fe6S6]3+ core (1986) (3)
REACTION OF MOS92- WITH BIS(CARBOXYMETHYL)ACETYLENE. THE CRYSTAL AND MOLECULAR STRUCTURE OF (PH4P)2MO(S2C2(COOME)2)3: A TRIGONAL PRISMATIC COMPLEX WITH NEW DITHIOLENE LIGAND (1983) (3)
Solid-State Materials and Clusters (2002) (2)
The Synthesis Structures and Electronic Properties of Fe-Mo-S Polynuclear Aggregates. Molecules of Elementary Structural Compliance with the Fe-Mo-S Aggregate of Nitrogenase (1984) (2)
Bis[cis-1,2-dicyanoethene-1,2-dithiolato(1- or 2-)] Complexes of Cobalt and Iron (2007) (2)
An evaluation by density functional theory of M-M interactions in organometallic clusters with the [Fe(3)MoS(3)](2+) cores. (2004) (2)
New μ2‐S2‐‐Coupled, Singly Bridged Double Cubane with the ((Fe4S4Cl3)2S)4‐ Core. The Stepwise Synthesis and Structural Characterization of (n‐Bu4N)2(Ph4P)2((Fe4S4Cl3)2S). (1990) (2)
TETRAHEDRAL MERCAPTIDE COMPLEXES. CRYSTAL AND MOLECULAR STRUCTURES OF ((C6H5)4P)2M(SC6H5)4 COMPLEXES (M = CADMIUM(II), ZINC(II), NICKEL(II), COBALT(II), AND MANGANESE(II)) (2002) (2)
Nucleophilic substitution reactions of co-ordinated xanthates and dithiocarbamates (1967) (1)
Metal complexes as ligands—VII: The chemistry of the monothiooxalate complexes (1977) (1)
Bioinorganic chemistry. (2003) (1)
COORDINATION UNSATURATION IN THE IRON TETRAHIOMETALATE COMPLEXES. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE (FE(WS4)2(HCON(CH3)2)2)2‐ COMPLEX ANION (2002) (1)
SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTRONIC PROPERTIES OF THE TETRAPHENYLPHOSPHONIUM SALTS OF THE MIXED TERMINAL LIGAND CUBANES FE4S4(ET2DTC)N(X)4-N2- (X = CL-, PHS-) (N = 1, 2). TWO DIFFERENT MODES OF LIGATION ON THE (FE4S (1985) (1)
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE (PH4P)2(CL2FES2MS2FECL2) COMPLEXES (M = MOLYBDENUM, TUNGSTEN). FIRST EXAMPLE OF A DOUBLY BRIDGING THIOMOLYBDATE (MOS4) UNIT AND ITS POSSIBLE RELEVANCE AS A STRUCTURAL FEATURE IN THE NIT (1980) (1)
Synthesis and Structural Characterization of the Ph4P+ Salts of the (MoS(MoS4)(S4))2- Anion and Its (Mo2S6)2- and (Mo2S7)2- Desulfurized Derivatives. (1987) (1)
Catalytic Reduction of Hydrazine and Acetylene to Ammonia and Ethylene and Stoicfflometric Reduction of Cn to Ammonia and Methane By Fe/M/S Clusters (M =MO, V) with Structural Features Similar to Those of the Fe/Mo/S Site in Nitrogenase (1995) (1)
The first structurally characterized monoalkylthioborane. Structure of 1,3,5-tri(tert-butyl)cyclotriborathiane (1987) (1)
METAL COMPLEXES AS LIGANDS PART 2. THE SYNTHESIS, STRUCTURE DETERMINATION AND BONDING CHARACTERISTICS OF CERTAIN TIN(IV) HALIDE ADDUCTS OF THE NICKEL(II) AND PALLADIUM(II) DITHIOOXALATO COMPLEXES (1973) (1)
Theoretical study on the electronic structure and properties of synthetic MoFe3S3 compounds (2001) (1)
Synthetic Analogs for the Fe-Mo-S Site in Nitrogenase: Chemistry of the [Fe6S6(L)6(M(CO)3)2]n-Clusters (1988) (1)
The Chemistry of the Fe-M-S Complexes (M = Mo, W) (1983) (1)
Fe/S and Fe/Mo/S clusters as speculative models for the metal centers in uncommon Fe/S proteins and the Fe/Mo protein of the nitrogenases. (1994) (1)
SYNTHESIS AND REACTIONS OF BINARY METAL SULFIDES. STRUCTURAL CHARACTERIZATION OF THE ((S4)2ZN)2-, ((S4)2NI)2-, ((S5)MN(S6))2-, AND ((CS4)2NI)2- ANIONS (1985) (1)
A NEW IRON/SULFUR CLUSTER WITH THE (FE6S6)3+ PRISMATIC CORE AND P-METHYLPHENOLATE TERMINAL LIGANDS. THE SYNTHESIS, STRUCTURE, AND PROPERTIES OF (ET4N)3FE6S6(OC6H4-P-CH3)6 (1985) (1)
Anionic complexes of dithiocarboxylates (1965) (1)
Dimeric Complexes Containing the (Fe2S2)2+ Cores Coordinated by Non-Sulfur Terminal Ligands. Synthesis, Structural Characterization, and Spectroscopic Properties of (Et4N)2(Fe2S2(o,o′-C12H8O2)2), (Et4N)2(Fe2S2(C4H4N)4), and (Et4N)2(Fe (1989) (1)
A New Class of Bis(μ-aryloxy)-Bridged Dimers with First-Row Divalent Transition-Metal Ions. Synthesis and Structural Characterization of the (Et4N)2(M2Cl4(O-C6H4-p-CH3)2) Complexes (M: Mn(II), Fe(II), Co(II), Zn(II), and Cd(II)). (1988) (1)
Determination of fine and hyperfine structure in Fe−Mo(W) dinuclear clusters (1986) (1)
Activation and Cleavage of the CS Bond in Nb-StBu Complexes . Syntheses and Structural Characterizations of the Tetrahedral and Trigonal Bipyramidal (2001) (0)
First Examples of Six‐Coordinate Homoleptic Complexes with Monodentate Arenethiolate Ligands. Synthesis and Structural Characterization of ( Ph4P)2(Nb(SPh)6), Na(THF)3Nb(SPh‐pMe)6, ((15‐crown‐5)Na)(Ta(SPh)6), and Nb2(μ2‐SPh)4(SPh)2Cl2(C2H5CN)2. (1991) (0)
Synthesis, Structural Characterization, and Electronic Structures of the (Fe6S6(X)6(Mo(CO)3)2)3- Clusters (X: Cl, Br). (1987) (0)
EXAFS MODEL FOR THE IRON‐MOLYBDENUM COFACTOR OF NITROGENASE: MOLYBDENUM, TUNGSTEN, AND IRON EXAFS OF THE (CL2FES2MS2FECL2)2‐ (M = MOLYBDENUM OR TUNGSTEN) DIANIONS. A COMPARISON WITH THE MO EXAFS OF NITROGENASE (1983) (0)
Thiomolybdate salts and their uses (2003) (0)
SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTRONIC STRUCTURES OF THE MIXED TERMINAL LIGAND IRON-SULFUR CUBANES (FE4S4CL2(XPH)2)2- (X = S, O) AND (FE4S4(SPH)2(OC6H4ME-P)2)2-. THE FIRST EXAMPLES OF (FE4S4)2+ CORES WITH A NONCOMPRESS (1984) (0)
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF BIS(TETRAPHENYLPHOSPHONIUM) BIS(DIETHYLDITHIOCARBAMATO)BIS(THIOPHENOLATO)TETRAKIS(μ3-SULFIDO)TETRAFERRAT# E(2II, 2III), (PH4P)2(FE4S4(SPH)2(ET2DTC)2). A “CUBANE” TYPE CLUSTER WITH MIXED TER (1983) (0)
Tetraphenylphosphonium Salts of [Mo2(S)N(s2)6‐N]2‐ Thioanions and Derivatives (2007) (0)
METAL COMPLEXES AS LIGANDS. 9. CRYSTAL AND MOLECULAR STRUCTURE OF POTASSIUM BIS(TRI-P-TOLYLPHOSPHINE)COPPER(I) BIS(DITHIOOXALATO-O,O′)STANNATE(IV)-2-ACETONE, KSN(S2C2O2)3CU(P(C7H7)3)2).2C3H6O (1977) (0)
The use of MFe3S4 clusters (M = Mo, V) and derivatives in the reduction of nitrogenase substrates (1995) (0)
DIMERIC COMPLEXES CONTAINING THE DISULFIDODIIRON(2+) CORES COORDINATED BY NON-SULFUR CONTAINING TERMINAL LIGANDS. THE CRYSTAL AND MOLECULAR STRUCTURES OF THE TETRAETHYLAMMONIUM SALTS OF THE (FE2S2(O,O′-C12H8O2)2)2- AND (FE2S2(C4H4N)4) (1985) (0)
New Members of the (Mo2(S)n(S2)6-n)2- Series. Synthesis, Structural Characterization, and Properties of the (Mo2S9)2-, (Mo2S7)2-, and (Mo2S6)2- Thio Anions. (1987) (0)
Synthesis and Structural Characterization of the Et4N+ Salts of the New (((S2)2MoO)2S)2‐ and (((S2)2MoO)2S)2‐ 2 Oxo‐Disulfido‐Molybdate(VI) Anions. (1987) (0)
METAL COMPLEXES AS LIGANDS. 8. SYNTHESIS AND CHARACTERIZATION OF POLYNUCLEAR DITHIOOXALATE COPPER(I)-TIN(IV) COMPLEXES OF THE GENERAL TYPE M((O2C2S2)CUL2)N (1977) (0)
ADDITION OF ACTIVATED ACETYLENES TO COORDINATED POLYSULFIDE LIGANDS. 2. SYNTHESIS OF THE FE2(S2C2(COOCH3)2)42- DITHIOLENE COMPLEX BY THE ADDITION OF CH3OOCCCCOOCH3 TO THE (FE2S12)2- ANION. THE CRYSTAL AND MOLECULAR STRUCTURE OF (PH4P (1984) (0)
Sulfido bridged Fe/S and Fe/Mo/S clusters. A new proposed model for the Fe/Mo/S center in nitrogenase (1989) (0)
SULFUR ADDITION TO THE 1,1-DITHIOLATE LIGANDS IN THE (CU8L6)4- CUBANES (L = 1,1-DICARBO-TERT-BUTOXY-2,2-ETHYLENE DITHIOLATE). REVERSIBLE CU8(LS)64- TO CU4(LS)32- TRANSFORMATIONS (1982) (0)
METAL COMPLEXES AS LIGANDS PART 5, CRYSTAL AND MOLECULAR STRUCTURES OF TRIS(BIS(TRIPHENYLPHOSPHINE)SILVER(I)) TRIS(DITHIOOXALATO)IRON(III) AND -ALUMINIUM(III) (1974) (0)
ACID-BASE REACTIONS OF THE METALLOCUBANES. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF CU10(S2CCH(COO-T-C4H9)2)6(S2CC(COO-T-C4H9)2)2, A TEN COPPER ATOM AGGREGATE (1978) (0)
CRYSTAL AND MOLECULAR STRUCTURES OF THE COPPER(II) AND COPPER(III) DITHIOOXALATE COMPLEXES (18-CROWN-6)2K2CU(S2C2O2)2 AND ((C6H5)3P)2N)CU(S2C2O2)2 (1985) (0)
DINUCLEAR IRON-MOLYBDENUM-SULFUR COMPLEXES CONTAINING THE FES2MO CORE. SYNTHESES, GROUND-STATE ELECTRONIC STRUCTURES AND CRYSTAL AND MOLECULAR STRUCTURES OF THE ((C6H5)4P)2((C6H5S)2FES2MOS2), ((C2H5)4N)2((C6H5S)2FES2WS2), AND ((C6H5)4 (1983) (0)
Additions and Corrections - Sulfur Chelates. VIII. Oxidative Addition of Sulfur to Dithioaryl Acid Complexes of Nickel(II) and Zinc(II) (1969) (0)
Mo/S Chemistry and Its Importance in Enzymatic Catalysis (1995) (0)
IRON-MOLYBDENUM COMPLEXES OF CYSTEINYL PEPTIDES (1982) (0)
METAL COMPLEXES AS LIGANDS PART 4, STRUCTURES OF (AG(P(C6H5)3))2 , BIS(1,2-DICYANO-1,2-ETHYLENEDITHIOLATO)NICKELATE(II) (AG(P(C6H5)3)2)2NI(S2C2(CN)2)2, AND OF (AG(P(C6H5)3))2, BIS(1,1-DICYANO-2,2-ETHYLENEDITHIOLATO)NICKELATE(II), (AG( (1974) (0)
Magnetic properties of [(CO)3MoFe3S4(SR)3]3− (R=Bz,Et,Ph), a synthetic cubane-type cluster simulating three-iron centers in proteins. (1991) (0)
MÖSSBAUER STUDIES OF A SYNTHETIC ANALOG FOR THE ACTIVE SITE IN REDUCED RUBREDOXIN (1976) (0)
KINETICS OF THE CHEMICAL AND ELECTROCHEMICAL, REVERSIBLE OXIDATION OF BIS(DITHIOOXALATO-S,S′)CUPRATE(II), (CU(DTO)2)2-. A FACILE, LIGHT-ACTIVATED, INTRAMOLECULAR ELECTRON TRANSFER AND CLEAVAGE OF THE CARBON-CARBON BOND IN THE COORDINA (1984) (0)
Rational Synthesis of Monooxo Thioanions from (OMo(SPh)4)-. Structural Characterization of the (Ph4P)+ Salts of the ((η2-S2)MoO(μ-S)2MoS(η2-S2))2-, ((η2-S2)MoO(MoS4))2-, ((S4)MoX(μ-S)2MoX(η2-S2))2- (X: S, O), and ((S4)MoO(MoS4))2- Ani (1989) (0)
LIGAND FIELD ANALYSIS OF MÖSSBAUER DATA FOR A SIX COORDINATE Fe(IV) COMPLEX WITH DITHIOLATE LIGANDS (1976) (0)
A Cubane Cluster with the (MoFe3S4)0 Core and Its Possible Relevance Concerning the Fe3 Centers in Ferredoxins: The (Fe3S4(SEt)3Mo(CO)3)3- Ion. (1989) (0)
Mossbauer Studies of Synthetic Analogues Simulating Building Blocks of Nitrogenase Reactions (1986) (0)
Additions and Corrections - Synthesis and Characterization of a New Fe/Mo/S Cluster Containing the [Fe6Mo2S6]3+ Core. A Precursor to a Possible Structural Analouge for the Fe/Mo Site in Nitrogenase. (1985) (0)
MoFe Cofactor of nitrogenase: Extraction, purification, and characterization (1989) (0)
Possible structural analogs for the Fe/M/S sites in the nitrogenases. The[Fe6S6(L)6(M(CO)3)2]n- clusters and the [(MFe3S4)2(μ2-S)(μ2-L)]n- singly- and doubly-bridged double cubanes (1990) (0)
New [Fe6S6Cl6(Mo(CO)3)2]n‐ Clusters (n: 3, 4). Derivatives of Either [Fe6S6Cl6]3‐ or [Fe4S4Cl4]2‐ with Possible Relevance to the Fe/Mo/S Center in Nitrogenase. (1986) (0)
Thiomolybdatsalte and uses thereof (2003) (0)
KRISTALL- UND MOLEKULARSTRUKTUR VON BIS-(AETHYLTHIOXANTHATO)-MY-BIS-(AETHYLTHIOXANTHATO)-MY′-BIS-(AETHYLMERCAPTO)-DIEISEN(III) (1971) (0)
Synthesis, Structural Characterization, and Properties of the (Mo2O2S9)2- Thio Anion and the (Mo4O4S18)2-, (Mo2O2S8(SCH3))-, and (Mo2O2S8Cl)- Derivatives. (1989) (0)
Protonation of the 1,1-Dithiolene Ligands in the (Cu8(L)6)4- Cubanes (L: (S2C=C(COOR)2)2-) and Synthesis of the (Cu8(L)6-n(H-L)n)-(4-n) Clusters. Synthesis and Structural Characterization of the (Cu10(H-L)6(L)2) Decanuclear Cluster. (1989) (0)
SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF ((NO)2FES2MOS2)2- A DINITROSYL COMPLEX CONTAINING THE FES2MOS2 CORE (1981) (0)
UNIQUE REACTIVITY CHARACTERISTICS OF MO-COORDINATED !&- AND S$- LIGANDS (1986) (0)
Reactivity of the Mo ( S , ) Functional Groups in Thio-and Oxothiomolybdate Complexes toward Carbon Disulfide . Synthesis and Reactivity of Trithio-and Perthiocarbonate Complexes of Mo ( 1 V ) and Mo ( V ) and Structural Characterization (2001) (0)
Synthesis and Reactivity of a New Octanuclear Iron—Sulfur Nitrosyl Cluster. (2007) (0)
Synthesis and characterization of a new iron/molybdenum/sulfur cluster containing the [Fe6Mo2S6]3+ core. A precursor to a possible structural analog for the iron/molybdenum site of nitrogenase (1985) (0)
First Examples of Polynuclear, Sulfur-Containing, Zirconium Compounds. (1986) (0)
Synthesis, Structural Characterization, and Electronic Properties of the (Fe6S6X6(M(CO)3)2)n- Anions (M: Mo, W; n = 3, 4; X: Cl, Br, I). Heteronuclear Clusters of Possible Structural Relevance to the Fe/Mo/S Center in Nitrogenase. (1989) (0)
Erratum: Synthesis and characterization of a new Fe/Mo/S cluster containing the [Fe6Mo2S6]3+ core. A precursor to a possible structural analogue for the Fe/Mo site in nitrogenase (Journal of the American Chemical Society (1985) 107, (5005-5006)) (1985) (0)
Synthesis and Characterization of MoFe 3 S 4 and Mo 2 Fe 2 S 4 Single Cubanes (2007) (0)
Stepwise Synthesis and Structural Characterization of the ((MoFe3S4Cl2(Cl4cat))2(μ2-S)2)6- and ((MoFe3S4Cl2(Cl4cat))2(μ2-S)(μ2-OH))5- Doubly Bridged Double Cubanes Obtained by the Coupling of (MoFe3S4) Clusters. (1990) (0)
Chemistry of (Fe6S6)3+Prismatic Cages. Synthesis, Structural Characterization, and Electronic Structures of the (Et4N)3(Fe6S6L6) Clusters (L: p-CH3C6H4O-, Br-). (1986) (0)
Thiomolybdatanaloger and uses thereof (2005) (0)
SYNTHESIS, MOLECULAR STRUCTURE, AND REACTIONS OF BIS(TETRAPHENYLPHOSPHONIUM) HEXAKIS(μ-THIOPHENOLATO)-TETRACHLOROTETRAFERRATE(II), (PH4P)2(FE4(SPH)6CL4). ITS REACTIONS WITH DIBENZYL TRISULFIDE AND THE SYNTHESIS OF THE (FE4S4CL4)2 AND (1982) (0)
Erratum: Synthesis, structural characterization, and electronic structures of the [Fe6S6(X)6(Mo(CO)3) 2]3- clusters (X = Cl, Br) (Journal of the American Chemical Society (1987) 109, (3807)) (1987) (0)
Rational synthesis of high nuclearity Mo/Fe/S clusters: the reductive coupling approach in the convenient synthesis of (Cl(4)-cat)(2)Mo(2)Fe(6)S(8)(PR(3))(6) [R = Et, (n)Pr, (n)Bu] and the new [(Cl(4)-cat)(2)Mo(2)Fe(2)S(3)O(PEt(3))(3)Cl]-1/2(Fe(PEt(3))(2)(MeCN)(4)) and (Cl(4)-cat)(2)Mo(2)Fe(3)S(5)(P (2001) (0)
Additions and Corrections - Sulfur Chelates. III. Metal Complexes of the 1,1-Dithiolato Anions S2CS2-, S2CNCN2-, and S2CC(CN)22- (1969) (0)
Spectroscopic and Structural Evidence of Temperature Dependent Charge Localization and Structural Differentiation of the Fe Sites within the (Fe6S6X6)2‐ Clusters (X: Cl, Br). (1988) (0)
METAL COMPLEXES AS LIGANDS PART 3, BONDING INTERACTIONS OF THE ANIONIC METAL DITHIOOXALATE COMPLEXES WITH THE COORDINATELY UNSATURATED BIS(TRIPHENYLPHOSPHINE)COPPER(I) AND BIS(TRIPHENYLPHOSPHINE)SILVER(I) COMPLEX CATIONS (1973) (0)

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What Schools Are Affiliated With Dimitri Coucouvanis?

Dimitri Coucouvanis is affiliated with the following schools:

Karlsruhe Institute of Technology
University of California, Berkeley
University of Michigan
Stanford University
Case Western Reserve University