Don Tilley
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American chemistry professor
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Chemistry
Don Tilley's Degrees
- PhD Chemistry Stanford University
- Bachelors Chemistry University of California, Berkeley
Why Is Don Tilley Influential?
(Suggest an Edit or Addition)According to Wikipedia, T. Don Tilley is a professor of chemistry at the University of California, Berkeley. Career In 1977, Tilley received his B.S. degree in chemistry from the University of Texas. In 1982, he earned his Ph.D. degree from the University of California, Berkeley for his research on organolanthanide chemistry with Professor Richard A. Andersen.
Don Tilley's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Size-Dependent Activity of Co 3 O 4 Nanoparticle Anodes for Alkaline Water Electrolysis (2009) (472)
- Synthetic development and chemical reactivity of transition-metal silylene complexes. (2007) (253)
- The coordination polymerization of silanes to polysilanes by a ".sigma.-bond metathesis" mechanism. Implications for linear chain growth (1993) (252)
- Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts (2015) (227)
- Probing the chemistry of molecular heterojunctions using thermoelectricity. (2008) (224)
- Electrocatalytic Water Oxidation at Neutral pH by a Nanostructured Co(PO3)2 Anode (2013) (208)
- Identifying the length dependence of orbital alignment and contact coupling in molecular heterojunctions. (2009) (196)
- Comparison of cobalt-based nanoparticles as electrocatalysts for water oxidation. (2011) (194)
- Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for a new hydrosilylation mechanism. (2003) (170)
- Charge-Transfer Interaction of Poly(vinylpyrrolidone) with Platinum and Rhodium Nanoparticles (2007) (169)
- Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica. (2002) (168)
- Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2]. (2010) (163)
- Radial anisotropic growth of rhodium nanoparticles. (2005) (163)
- N-heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices. (2009) (161)
- Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations. (2017) (142)
- Iridium-catalyzed H/D exchange into organic compounds in water. (2002) (133)
- Divalent lanthanide chemistry. Bis (pentamethylcyclopentadienyl) europium(II) and -ytterbium(II) derivatives: crystal structure of bis (pentamethylcyclopentadienyl) (tetrahydrofuran ytterbium(II) -hemitoluene at 176 K (1980) (129)
- Coordination of 2,2'-bipyridyl and 1,10-phenanthroline to substituted ytterbocenes: An experimental investigation of spin coupling in lanthanide complexes (2002) (123)
- Metal-Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular Weight Polystannanes (1995) (122)
- Synthesis and Study of Cyclic π-Systems Containing Silicon and Germanium. The Question of Aromaticity in Cyclopentadienyl Analogues (1996) (120)
- Platinum-based catalysts for the hydroamination of olefins with sulfonamides and weakly basic anilines. (2005) (119)
- Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium (1984) (117)
- .sigma.-Bond metathesis mechanism for dehydropolymerization of silanes to polysilanes by d0 metal catalysts (1992) (112)
- Versatile synthesis of pentalene derivatives via the Pd-catalyzed homocoupling of haloenynes. (2009) (110)
- Pentamethylcyclopentadienyl derivatives of the trivalent lanthanide elements neodymium, samarium, and ytterbium (1981) (107)
- Rhodium nanoparticles from cluster seeds: control of size and shape by precursor addition rate. (2007) (106)
- Divalent lanthanide chemistry. Preparation and crystal structures of sodium tris[bis(trimethylsilyl)amido]europate(II) and sodium tris[bis(trimethylsilyl)amido]ytterbate(II), NaM[N(SiMe3)2]3 (1984) (105)
- Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation. (2015) (102)
- The nature of transport variations in molecular heterojunction electronics. (2009) (101)
- Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction (1982) (98)
- Oxidative Dehydrogenation of Propane over Vanadia–Magnesia Catalysts Prepared by Thermolysis of OV(OtBu)3 in the Presence of Nanocrystalline MgO (2002) (97)
- Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium. (2003) (97)
- Preparation, characterization, and x-ray crystal structure of an acetonitrile-complexed ruthenium silylene (1987) (97)
- Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer. (2008) (96)
- Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. (2006) (95)
- SILYLENE EXTRUSION FROM A SILANE : DIRECT CONVERSION OF MES2SIH2 TO AN IRIDIUM SILYLENE DIHYDRIDE (1999) (95)
- Molecular and polymer precursor routes to manganese-doped zinc orthosilicate phosphors (1996) (95)
- Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. (2005) (94)
- A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition. (2013) (93)
- Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4 (2004) (91)
- Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions (1990) (91)
- Activated Boron Nitride Derived from Activated Carbon (2004) (90)
- Synthesis and structure of PNP-supported iridium silyl and silylene complexes: catalytic hydrosilation of alkenes. (2009) (90)
- A Versatile, Transition-Metal Mediated Route to Blue-Light-Emitting Polymers with Chemically Tunable Luminescent Properties (1997) (89)
- Titania−Silica Materials from the Molecular Precursor Ti[OSi(OtBu)3]4: Selective Epoxidation Catalysts (2000) (89)
- Spectroscopic characterization of highly dispersed vanadiasupported on SBA-15 (2003) (89)
- Alkoxy and aryloxy derivatives of (pentamethylcyclopentadienyl)ruthenium. X-ray crystal structures of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2, [(.eta.5-C5Me5)(CO)Ru(.mu.-OEt)]2, and (.eta.5-C5Me5)Ru(.eta.5-2,6-tBu2C6H3O) and molecular orbital analysis of [(.eta.5-C5H5)Ru(.mu.-OMe)]2 (1989) (88)
- Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes. (2014) (85)
- Mechanism of the Decomposition of Aqueous Hydrogen Peroxide over Heterogeneous TiSBA15 and TS-1 Selective Oxidation Catalysts: Insights from Spectroscopic and Density Functional Theory Studies (2011) (85)
- Design and synthesis of heterogeneous catalysts: the thermolytic molecular precursor approach (2003) (83)
- Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex. (2012) (83)
- Tris(tert-butoxy)siloxy Complexes as Single-Source Precursors to Homogeneous Zirconia- and Hafnia-Silica Materials. An Alternative to the Sol-Gel Method (1997) (82)
- Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes of Yttrium (1999) (82)
- Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst. (2003) (81)
- POLY(FERROCENYLENEVINYLENE) FROM RING-OPENING METATHESIS POLYMERIZATION OFANSA-(VINYLENE)FERROCENE (1997) (80)
- An efficient, single-source molecular precursor to silicoaluminophosphates. (2001) (79)
- Silolyl Anions and Silole Dianions: Structure of [K([18]crown‐6)+]2[C4Me4Si2−] (1996) (78)
- Synthesis and Characterization of MO[OSi(OtBu)3]4 and MO2[OSi(OtBu)3]2 (M = Mo, W): Models for Isolated Oxo-Molybdenum and -Tungsten Sites on Silica and Precursors to Molybdena− and Tungsta−Silica Materials (2005) (78)
- The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination (2000) (77)
- Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N]2- ([Ar*N]2-). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO2CF3)], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand (2002) (77)
- Multiple bonding between silicon and molybdenum: a transition-metal complex with considerable silylyne character. (2003) (77)
- Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex. (2008) (76)
- 2,7-Substituted hexafluoroheterofluorenes as potential building blocks for electron transporting materials. (2009) (75)
- Base-free silylene complexes [(.eta.5-C5Me5)(PMe3)2Ru:Si(SR)2]BPh4 (R = Et, p-MeC6H4) (1990) (74)
- Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. (2015) (74)
- Inverse rectification in donor-acceptor molecular heterojunctions. (2011) (74)
- Pt-Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins (2004) (73)
- Platinum-mediated reactions of hydrosilanes. Isolation of a complex with bridging disilene and silylene ligands (1992) (73)
- Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst. (2005) (72)
- Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. (2009) (70)
- A Fischer-type silylene complex of platinum : [trans-(Cy3P)2(H)Pt=Si(SEt)2]BPh4 (1993) (70)
- Coordination Networks Based on Tetrahedral Silane Building Blocks: Influence of the Anion on Structures Adopted by Ag+−Si(p-C6H4CN)4 Arrays (1997) (70)
- Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates. (2014) (70)
- Activations of silanes with [PhB(CH2PPh2)3]Ir(H)(η3-C8H13). Formation of iridium silylene complexes via the extrusion of silylenes from secondary silanes R2SiH2 (2002) (69)
- Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition. (2017) (68)
- Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex. (2015) (67)
- Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH2PiPr2)3]-. Activation of H-H, Si-H, and ligand B-C bonds (2004) (67)
- .sigma.-Bond metathesis reactions for d0 metal-silicon bonds that produce zirconocene and hafnocene hydrosilyl complexes (1992) (67)
- Yttrium Complexes of the Chelating, C2-Symmetric, Bis(silylamido)biphenyl Ligand [DADMB]2- (={[6,6‘-Me2-(C6H3)2](2,2‘-NSiMe2tBu)2}2-) (1999) (66)
- A new mechanism for metal-catalyzed stannane dehydrocoupling based on alpha-H-elimination in a hafnium hydrostannyl complex. (2002) (65)
- New Zirconocene-Coupling Route to Large, Functionalized Macrocycles (2000) (65)
- .sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes (1989) (65)
- Bis(triisopropylsilyl)-o-phenylenediamido Complexes of Titanium and Zirconium: Investigation of a New Ancillary Ligand (1996) (64)
- Synthesis and electronic properties of extended, fused-ring aromatic systems containing multiple pentalene units. (2010) (64)
- Base-Free Silylene Complexes without .pi.-Donor Stabilization. Molecular Structure of [Cp*(PMe3)2Ru:SiMe2][B(C6F5)4] (1994) (63)
- Silyl Derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) Complexes: Catalytic Redistribution of Arylsilanes and Dehydrogenative Arene Silylation (2007) (63)
- Kinetics and mechanism of olefin epoxidation with aqueous H2O2 and a highly selective surface-modified TaSBA15 heterogeneous catalyst. (2008) (62)
- Isolation and Characterization of Neutral Platinum Silylene Complexes of the Type (R3P)2PtSiMes2 (Mes = 2,4,6-Trimethylphenyl) (1998) (60)
- Stable Silacyclopentadienyl Complexes of Ruthenium: (.eta.5-C5Me5)Ru[.eta.5-Me4C4SiSi(SiMe3)3] and X-ray Structure of Its Protonated Form (1994) (60)
- Beta-Phosphinoethylboranes as Ambiphilic Ligands in Nickel-Methyl Complexes (2008) (60)
- Influence of surface modification of Ti-SBA15 catalysts on the epoxidation mechanism for cyclohexene with aqueous hydrogen peroxide. (2005) (59)
- Structure and Reactivity of Chelating Imido−Amido Complexes of Tantalum. Mechanistic Studies on the Addition of Silanes to Ta−N Multiple Bonds (1997) (59)
- Silyl and diphenylsilylene derivatives of (.eta.5-C5Me5)(PMe3)2Ru. Evidence for the base-free silylene complex [(.eta.5-C5Me5)(PMe3)2Ru:SiPh2]+ (1990) (58)
- Reactions of carbon monoxide with trimethylsilyl and tris(trimethylsilyl)silyl derivatives of group 4 metals. Synthesis, characterization, and reactivity of silaacyl complexes (1987) (58)
- Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3: A Model for Isolated Vanadyl Sites on Silica and a Precursor to Vanadia−Silica Xerogels† (1999) (57)
- Synthesis and Reactivity of η5-Silolyl, η5-Germolyl, and η5-Germole Dianion Complexes of Zirconium and Hafnium (2000) (57)
- Preparation and reactivity of 16-electron ‘half-sandwich’ ruthenium complexes; X-ray crystal structure of (η5-C5Me5)Ru(PPri3)Cl (1988) (57)
- Dinucleating naphthyridine-based ligand for assembly of bridged dicopper(I) centers: three-center two-electron bonding involving an acetonitrile donor. (2011) (57)
- Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches (2005) (56)
- Synthesis and characterization of perfluoroaryl-substituted siloles and thiophenes : A series of electron-deficient blue light emitting materials (2006) (56)
- Catalytic antimony-antimony bond formation through stibinidene elimination from zirconocene and hafnocene complexes. (2006) (55)
- Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior. (2017) (55)
- Preparation and characterization of tris(trimethylsilyl)silyl derivatives of zinc, cadmium, and mercury. X-ray crystal structure of Zn[Si(SiMe3)3]2 (1987) (54)
- Synthesis and reactions of silyl and germyl derivatives of scandocene. Structure of Cp2Sc[Si(SiMe3)3](THF) (1993) (54)
- Thermolytic molecular precursor route to site-isolated vanadia–silica materials and their catalytic performance in methane selective oxidation (2006) (54)
- General, Efficient Route to Thiophene-1-Oxides and Well-Defined, Mixed Thiophene-Thiophene-1-Oxide Oligomers (1999) (54)
- High oxidation state rhodium and iridium bis(silyl)dihydride complexes supported by a chelating pyridyl-pyrrolide ligand. (2009) (54)
- CRYSTAL STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL)BIS(PYRIDINE)YTTERBIUM(II) (1982) (54)
- High molecular mass polystannanes via dehydropolymerization of di(n-butyl)stannane (1993) (53)
- Zinc di(tert-butyl)phosphate complexes as precursors to zinc phosphates. Manipulation of zincophosphate structures (1997) (53)
- Generation of a Silylene Complex by the 1,2-Migration of Hydrogen from Silicon to Platinum. (1998) (53)
- Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes. (2006) (53)
- Poly(2,5-diphenylgermole): Incorporation of a Germole Ring into a Conjugated Polymer (2000) (51)
- Silylene Hydride Complexes of Molybdenum with Silicon−Hydrogen Interactions: Neutron Structure of (η5-C5Me5)(Me2PCH2CH2PMe2)Mo(H)(SiEt2) (2004) (50)
- Block Copolymer-Assisted Synthesis of Mesoporous, Multicomponent Oxides by Nonhydrolytic, Thermolytic Decomposition of Molecular Precursors in Nonpolar Media (2001) (50)
- Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation. (2011) (49)
- Stoichiometric and Catalytic Arene Activations by Platinum Complexes Containing Bidentate Monoanionic Nitrogen-Based Ligands (2006) (49)
- Preparation, isolation, and characterization of transition-metal .eta.2-silene complexes. X-ray crystal structure of (.eta.5-C5Me5)[P(iso-Pr)3]Ru(H)(.eta.2-CH2SiPh2) (1988) (49)
- Regioselective coupling of pentafluorophenyl substituted alkynes: mechanistic insight into the zirconocene coupling of alkynes and a facile route to conjugated polymers bearing electron-withdrawing pentafluorophenyl substituents. (2003) (49)
- Poly(diaryl)stannanes: Influence of Substituents on the σ−σ* Transition Energy (2000) (49)
- ETA 5-SILOLYL AND ETA 5-GERMOLYL COMPLEXES OF D HAFNIUM. STRUCTURAL CHARACTERIZATION OF AN ETA 5-SILOLYL COMPLEX (1998) (48)
- Stoichiometric and Catalytic Reactions Involving Si-H Bond Activations by Rh and Ir Complexes Containing a Pyridylindolide Ligand (2006) (48)
- The osmium-silicon triple bond: synthesis, characterization, and reactivity of an osmium silylyne complex. (2013) (48)
- Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. (2003) (48)
- Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes (2009) (48)
- Preparation and crystal structure of bis[bis(pentamethylcyclopentadienyl)ytterbium(III)] undecacarbonyltriferrate, [(C5Me5)2Yb]2 [Fe3(CO)11]; a compound with four isocarbonyl (iron-carbonyl-ytterbium) interactions (1982) (48)
- Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride. (2002) (47)
- Mechanistic aspects of samarium-mediated sigma-bond activations of arene C-H and arylsilane Si-C bonds. (2001) (47)
- A hydrogen-substituted osmium stannylene complex: isomerization to a metallostannylene complex via an unusual alpha-hydrogen migration from tin to osmium. (2009) (47)
- Transition metal complexes containing donor-stabilized silylyne ligands. Reductive dimerization to a silylene complex (1992) (47)
- Reversible Cycloaddition of Isocyanates to Ruthenium Silylene Complexes (1997) (46)
- Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. (2001) (46)
- Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation (2013) (46)
- A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. (2013) (45)
- New Route to Unsaturated Organosilicon Polymers and Macrocycles Based on Zirconocene Coupling of 1,4-MeC.tplbond.C(Me2Si)C6H4(SiMe2)C.tplbond.CMe (1995) (45)
- Tertiary phosphine complexes of the f-block metals. Preparation of pentamethylcyclopentadienyl-tertiary phosphine complexes of ytterbium(II), ytterbium(III), and europium(II). Crystal structure of Yb(Me/sub 5/C/sub 5/)/sub 2/Cl(Me/sub 2/PCH/sub 2/PMe/sub 2/) (1983) (45)
- Trialkoxysiloxy complexes as precursors to MO2.cntdot.4SiO2 (M = Ti, Zr, Hf) materials (1991) (45)
- High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation. (2001) (44)
- Photocatalytic water oxidation by very small cobalt domains on a silica surface (2013) (44)
- Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and Mixed-Valence μ-Aryl Dicopper(I,II) Complexes. (2016) (44)
- Synthesis and characterization of the neutral lanthanide silyl complexes (.eta.5-C5Me5)2LnSiH(SiMe3)2 (Ln = Nd, Sm) (1992) (43)
- Efficient, high-yield route to long, functionalized p-phenylene oligomers containing perfluorinated segments, and their cyclodimerizations by zirconocene coupling. (2001) (43)
- Rhodium(III) and Rhodium(II) Complexes of Novel Bis(oxazoline) Pincer Ligands (2003) (43)
- Synthesis and structure of a transition-metal-substituted silylene complex, (CO)4OsSi(STol-p)[Ru(.eta.5-C5Me5)(PMe3)2] (1993) (43)
- Structural and Chemical Properties of Zwitterionic Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PPh2)3]- (2002) (43)
- A dimeric molecular precursor [(tBuO)2Ti{μ-O2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation (2005) (41)
- Synthons for coordinatively unsaturated complexes of tungsten, and their use for the synthesis of high oxidation-state silylene complexes. (2004) (41)
- Iridium(III) complexes of the new tridentate bis(8-quinolyl)silyl (‘NSiN’) ligand (2001) (41)
- Thermolytic molecular precursor route to active and selective vanadia-zirconia catalysts for the oxidative dehydrogenation of propane (2000) (41)
- Synthesis and Reactivity of (Pentamethylcyclopentadienyl)ruthenium Complexes of the Stable Neutral Silylene Si(tBuNCHCHNtBu) (2000) (41)
- Iridium(III) and Rhodium(III) Complexes Bearing Chelating Cyclopentadienyl−Phosphine Ligands as C−H Activation Catalysts for the Deuteration of Hydrocarbons in D2O (2002) (41)
- Atomic level control over surface species via a molecular precursor approach: isolated Cu(I) sites and Cu nanoparticles supported on mesoporous silica. (2004) (41)
- Enhancement of the Catalytic Activity of Titanium-Based Terminal Olefin Epoxidation Catalysts via Surface Modification with Functionalized Protic Molecules (2011) (41)
- Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds. (2003) (40)
- Samarium-mediated redistribution of silanes and formation of trinuclear samarium–silicon clusters (1996) (40)
- General Route to Homogeneous, Mesoporous, Multicomponent Oxides Based on the Thermolytic Transformation of Molecular Precursors in Non‐polar Media (2001) (40)
- High electrophilicity at silicon in η3-silane σ-complexes: Lewis base adducts of a silane ligand, featuring octahedral silicon and three Ru-H-Si interactions. (2011) (40)
- Trimethylsilyl derivatives of bis(cyclopentadienyl)zirconium and -hafnium. Crystal structure of (.eta.5-C5H5)2Zr(SiMe3)(S2CNEt2) (1985) (40)
- Highly selective olefin epoxidation with aqueous H2O2 over surface-modified TaSBA15 prepared via the TMP method. (2007) (40)
- Synthesis and Study of Ruthenium Silylene Complexes of the Type [(η5-C5Me5)(Me3P)2RuSiX2]+(X = Thiolate, Me, and Ph) (1998) (40)
- New tris(tert-butoxy)siloxy complexes of aluminum and their transformation to homogeneous aluminosilicate materials via low-temperature thermolytic pathways (2002) (39)
- New Fe/SiO2 Materials Prepared using Diiron Molecular Precursors: Synthesis, Characterization and Catalysis (2005) (39)
- Synthesis, characterization, and reactivity of triphenylsilyl, triphenylgermyl, and triphenylstannyl derivatives of zirconium and hafnium (1992) (39)
- Reactions of alkynes with coordinatively unsaturated (.eta.5-C5Me5)Ru derivatives. X-ray crystal structures of (.eta.5-C5Me5)Cl2Ru(.eta.2:.eta.4-.mu.2-C4H4)Ru(.eta.5-C5Me5) and (.eta.5-C5Me5)3Ru3(.mu.2-Cl)2(.mu.3-Cl)(.eta.2-.mu.2-HC.tplbond.CSiMe3) (1990) (39)
- Synthesis of Polysilanylmagnesium Compounds (2006) (38)
- Reactions of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]X (X Cl, Me) complexes with carbon monoxide and the isocyanide 2,6-Me2C6H3NC. Crystal structure of (η5-C5H5)(η5-C5Me5)Zr[η2-C(N-2,6-Me2C6H3)Si(SiMe3)3]Cl (1988) (38)
- Thermolytic conversion of a bis(alkoxy)tris(siloxy)tantalum(V) single-source molecular precursor to catalytic tantala-silica materials (2005) (38)
- Synthesis and chemical functionalization of high surface area dendrimer-based xerogels and their use as new catalyst supports (2000) (38)
- Synthesis, Structure, and Reactivity of Osmium Silyl and Silylene Complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5)4] (R = Me, iPr; X = Cl, OTf) (2004) (38)
- Transition‐metal silyl derivatives (2004) (38)
- Synthesis and reactivity of η5-germacyclopentadienyl complexes of iron (2002) (37)
- The Influence of Catalyst Structure on the Dehydropolymerization of Phenylsilane (1994) (37)
- Preparation and characterization of the monomeric copper(II) siloxide complex Cu[OSi(OCMe3)3]2(py)2 (1989) (37)
- Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts. (2017) (37)
- Efficient C–H bond activations via O2 cleavage by a dianionic cobalt(ii) complex (2014) (37)
- EFFICIENT ZIRCONOCENE-COUPLING OF SILICON-SUBSTITUTED DIYNES TO POLYMERS AND MACROCYCLES (1998) (37)
- C–H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes (2015) (37)
- Molecular design and synthesis of heterogeneous and single-site, supported catalysts (2002) (37)
- 9,10-Dichlorooctafluoroanthracene as a building block for n-type organic semiconductors. (2007) (37)
- Low-temperature pyrolytic transformations of tri-tert-butoxysiloxy derivatives of aluminum to aluminosilicate materials (1992) (36)
- Evidence for the Existence of Group 3 Terminal Methylidene Complexes (2017) (36)
- Thermolytic Transformation of Tris(alkoxy)siloxychromium(IV) Single-Source Molecular Precursors to Catalytic Chromia−Silica Materials (2001) (36)
- Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. (2012) (36)
- Reactions of Cationic PNP-Supported Iridium Silylene Complexes with Polar Organic Substrates (2010) (36)
- Synthesis and Structure of a Free Germacyclopentadienide Ion: [Li([12]crown‐4)2][C4Me4GeSi(SiMe3)3] (1995) (36)
- Dimesitylsilyl derivatives of zirconium (1989) (36)
- A Zirconocene-Coupling Route to Substituted Poly(p-phenylenedienylene)s: Band Gap Tuning via Conformational Control (1998) (36)
- Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(µ-CCPh)4 and Eu2(C5Me5)2(µ-CCPh)2(tetrahydrofuran)4 (1984) (35)
- Cp*(PiPr3)RuOTf: A Reagent for Access to Ruthenium Silylene Complexes (2011) (35)
- Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN)Ta (Cp* = η5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3) (2004) (35)
- Tris(tert-butoxy)siloxy derivatives of boron, including the boronous acid HOB[OSi(O(t)Bu)(3)](2) and the metal (siloxy)boryloxide complex Cp(2)Zr(Me)OB[OSi(O(t)Bu)(3)](2): a remarkable crystal structure with 18 independent molecules in its asymmetric unit. (2003) (35)
- Perfluoropentaphenylborole: a new approach to Lewis acidic, electron-deficient compounds. (2009) (35)
- Neutral and anionic silyl hydride derivatives of the tantalum imido fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-bonds and intramolecular C-H bond activations involving the silyl ligands (2002) (35)
- Organolutetium Complexes in σ-Bond Metathesis Reactions Involving Silicon. Catalysts for the Hydrogenolysis of Si−C Bonds (2001) (35)
- Coordinatively unsaturated tris(trimethylsilyl)silyl complexes of chromium, manganese, and iron (1987) (34)
- Alkyl and Hydrido Complexes of Platinum(IV) Supported by the Bis(8-quinolyl)methylsilyl Ligand (2008) (34)
- Synthesis, Structure, and α-Elimination Chemistry of Hafnocene Triarylstannyl Complexes (2005) (34)
- Reactivity of an Osmium Silylene Complex toward Chlorocarbons: Promotion of Metal Redox Chemistry by a Silylene Ligand and Relevance to the Mechanism of the Direct Process (2000) (34)
- Carbosilane Dendrimers as Nanoscopic Building Blocks for Hybrid Organic–Inorganic Materials and Catalyst Supports (2001) (34)
- Hypercoordinate ketone adducts of electrophilic η3-H2SiRR' ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation. (2014) (33)
- Low-Band-Gap, σ-Conjugated Polymers: Poly(diarylstannanes) (1996) (33)
- Partial Oxidation of Methanol Over Highly Dispersed Vanadia Supported on Silica SBA-15 (2005) (32)
- Preparation and crystal structure of µ-carbonyl-OC-bis(pentamethylcyclopentadienyl)(tetrahydrofuran)ytterbium(III)tricarbonylcobalt(I); A Yb–OC–Co linkage (1981) (32)
- Dendrimers as Building Blocks for Nanostructured Materials: Micro- and Mesoporosity in Dendrimer-Based Xerogels (1999) (32)
- Preparation of the first stable formylsilane, (Me3Si)3SiCHO, from a zirconium .eta.2-silaacyl complex (1988) (32)
- A stable .eta.2-silene complex of iridium: (.eta.5-C5Me5)(PMe3)Ir(.eta.2-CH2:SiPh2) (1990) (32)
- Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane (2003) (32)
- Regioselective, Transition Metal-Free C-O Coupling Reactions Involving Aryne Intermediates. (2016) (32)
- Spatial resolution of a type II heterojunction in a single bipolar molecule. (2009) (31)
- Terminal hafnium phosphinidene complexes and phosphinidene ligand exchange (2011) (31)
- Control of Selectivity in the Hydromethylation of Olefins via Ligand Modification in Scandocene Catalysts (2005) (31)
- Synthesis of Highly Charged Organometallic Dendrimers and Their Characterization by Electrospray Mass Spectrometry and Single-Crystal X-ray Diffraction (1998) (31)
- Preparation and reaction chemistry of trimethylsilyl derivatives of niobium. Redox chemistry of (.eta.5-C5H5)2Nb(SiMe3)Cl and x-ray structures of (.eta.5-C5H5)2Nb(SiMe3)(.eta.2-C2H4) and [(.eta.5-C5H5)2Nb(CH2SiMe3)Cl]PF6 (1987) (31)
- Carbon dioxide activation by a transition metal-silicon bond. Formation of silanecarboxylate complexes [Cp2Sc[.mu.-O2CSiR3)]2 (1990) (31)
- Preparation and characterization of tris(trimethylsilyl)silyl and tris(trimethylsilyl)germyl derivatives of zirconium and hafnium. X-ray crystal structures of (.eta.5-C5Me5)Cl2HfSi(SiMe3)3 and (.eta.5-C5Me5)Cl2HfGe(SiMe3)3 (1988) (31)
- Divalent lanthanide chemistry. Preparation of some four- and six-coordinate bis[(trimethylsilyl)amido] complexes of europium(II). Crystal structure of bis[bis(trimethylsilyl)amido]bis(1,2-dimethoxyethane)europium(II) (1981) (31)
- A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts. (2014) (31)
- Enhancement of epoxidation efficiencies for Ta-SBA15 catalysts. The influence of modification with -EMe3 (E = Si, Ge, Sn) groups. (2011) (30)
- Site-Isolated Pt-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pt(II) and Pt(IV) (2008) (30)
- Dehydropolymerization of bis- and tris(silyl)arenes to highly crosslinked disilanylenearylene polymers, catalyzed by [(.eta.5-C5H5)(.eta.5-C5Me5)ZrH2]2 (1991) (30)
- Reactions of hafnocene stannyl complexes with stannanes: implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes (2004) (30)
- Isolation of the First d0 Metalloxy Ketene Complexes via "Double Insertion" of Carbon Monoxide into Thorium-Silicon Bonds (1995) (30)
- Synthesis and Reactivity of Silyl and Silylene Ligands in the Coordination Sphere of the 14-Electron Fragment Cp*(iPr3P)Os+ (2004) (30)
- Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism (2016) (30)
- Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H σ-complexes. (2012) (30)
- Efficient diastereoselective syntheses of chiral macrocycles via zirconocene coupling. Synthetic control of size and geometry. (2001) (30)
- Reversible 1,2-Migration of Hydrogen between Platinum and Silicon via Intermediate Silylene Complexes (1998) (30)
- Reactions of Cp*(PMe3)Ir(Me)OTf with Silanes: Role of Base-Free Silylene Complexes in Rearrangements of the Resulting Silicon-Based Ligands (2002) (29)
- Synthesis and study of the ruthenium-silene complexes (.eta.5-C5Me5)(PR3)RuH(.eta.2-CH2:SiR'2) (R = CHMe2, Cy; R' = Me, Ph) (1993) (29)
- Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand. (2010) (29)
- ALKOXY(SILOXY) COMPLEXES OF TIN, LEAD AND BISMUTH (1998) (29)
- Effects of Precursor Composition on the Local Structure of Cu Dispersed on Mesoporous Silica: A Detailed X-ray Absorption Spectroscopy Study (2004) (29)
- Di-tert-butyl Phosphate Complexes of Titanium (1998) (29)
- Neutral lanthanide silyl complexes via σ-bond metathesis reactions (1996) (29)
- Disambiguation of Metal and Brønsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts (2011) (29)
- Enhanced Reactivity of Cationic Hafnocene Complexes toward σ-Bond Metathesis Reactions. Si−H and Si−C Bond Activations in Stoichiometric and Catalytic Organosilane Conversions (2003) (29)
- Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene)-Catalyzed Proton Reduction. (2016) (28)
- Synthesis and characterization of fluorinated heterofluorene-containing donor-acceptor systems. (2010) (28)
- AUTOCATALYTIC MECHANISM FOR SIGMA -BOND METATHESIS REACTIONS OF (ETA 5-C5ME5)2SMCH(SIME3)2 WITH SILICON-HYDROGEN BONDS (1995) (28)
- Synthetic control and empirical prediction of redox potentials for Co 4 O 4 cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation † (2017) (28)
- Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.5-C5Me5)Cl3Ta(.eta.2-COSiMe3) and derivatives (1989) (28)
- Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects. (2008) (28)
- Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6-iPr2-C6H3)]2} (2014) (28)
- Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). (2012) (28)
- Osmium Alkyl and Silyl Derivatives with Cyclopentadienyl(phosphine) and Pentamethylcyclopentadienyl(phosphine) Ligand Sets (1997) (28)
- Bond Activations of PhSiH3 by Cp2SmH: A Mechanistic Investigation by the DFT Method (2009) (27)
- Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons. (2017) (27)
- Synthesis of Sm−SiH3 Complexes via σ-Bond Metathesis of the Si−C Bond of Phenylsilane (2000) (27)
- Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation (2000) (27)
- Unsymmetrical Zirconacyclopentadienes from Isolated Zirconacyclopropenes with 1-Alkynylphosphine Ligands (2009) (27)
- Dimolybdenum(III) Complexes of −OSi(OtBu)3, −O2P(OtBu)2, and −OB[OSi(OtBu)3]2 as Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials (2004) (27)
- Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf. (2014) (26)
- Artificial Metalloproteins Containing Co4O4 Cubane Active Sites. (2018) (26)
- Germylene and silylene complexes of molybdenum via E-H (E = Ge, Si) bond activations: steric influences on intramolecular MoH...E interactions. (2009) (26)
- Synthesis, structure and dynamic studies on base-stabilized silylene complexes (1995) (26)
- A Molecular Precursor Route to Active and Selective Vanadia−Silica−Zirconia Heterogeneous Catalysts for the Oxidative Dehydrogenation of Propane (1998) (26)
- Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes. (2002) (26)
- Five-Coordinate Dihydridosilyl Platinum(IV) Complexes Supported by a Chelating Monoanionic Nitrogen-Based Ligand (2009) (26)
- Pt-catalyzed C-C activation induced by C-H activation. (2013) (26)
- Trityl tetraphenylborate as a reagent in organometallic chemistry (1989) (26)
- 9,10-Disubstituted octafluoroanthracene derivatives via palladium-catalyzed cross-coupling. (2008) (26)
- Synthesis and study of platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl) (2003) (26)
- Synthesis and structure of [(η5-C5Me5Ru(μ-NHPh)]2,an electron-deficient ruthenium amide complex (1992) (26)
- New vanadium tris(tert-butoxy)siloxy complexes and their thermolytic conversions to vanadia-silica materials (2002) (25)
- Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling. (2001) (25)
- 1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion. (2014) (25)
- Titanocene-Mediated Dinitrile Coupling: A Divergent Route to Nitrogen-Containing Polycyclic Aromatic Hydrocarbons. (2018) (25)
- Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity (2006) (25)
- A Simple, Efficient Route to Cage Compounds via Zirconocene Coupling (1998) (25)
- POLYSILYL GROUP ISOMERIZATION VIA MIGRATIONS IN RHODIUM AND IRIDIUM DERIVATIVES (ME3P)3MSI(SIME3)3 (1995) (25)
- Silabenzene and Disilabenzene Complexes of Ruthenium (2001) (25)
- Synthetic, structural and reactivity studies with new group 4 transition-metal silyl complexes (1995) (25)
- Di‐μ‐Chloro‐Bis[(η5‐Pentamethylcyclopentadienyl) Chlororuthenium(III)], [Cp*RuCl2]2 and Di‐μ‐methoxo‐Bis(η5‐Pentamethylcyclopentadienyl)diruthenium(II), [Cp*RuOMe]2 (2007) (25)
- Reactions of Zirconacyclopentadienes with Nitrosobenzene. Characterization of Zirconacycle Intermediates and Formation of N-Phenylpyrroles (2001) (25)
- Organometallics Roundtable 2013–2014 (2014) (24)
- Hafnium−Rhodium and Hafnium−Iridium Heterobimetallic Complexes Featuring the Bridging Germole Dianion Ligand [GeC4Me4]2- (2000) (24)
- Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications (2009) (24)
- Cuprous tris(tert-butoxy)siloxy complexes and their thermolytic conversion to copper-silica and copper oxide-silica nanocomposites (1996) (23)
- Highly Dispersed Pd-SBA15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II) (2011) (23)
- Bis(pentamethylcyclopentadienyl)carboxylato and -dithiocarbamato derivatives of neodymium(III) and ytterbium(III). Crystal structure of bis(pentamethylcyclopentadienyl)(diethyldithiocarbamato)ytterbium(III) (1982) (23)
- Titanium–Germoxy Precursor Route to Germanium-Modified Epoxidation Catalysts with Enhanced Activity (2013) (23)
- Silane-isocyanide coupling involving 1,1-insertion of XylNC into the Si-H bond of a σ-silane ligand. (2013) (23)
- Interconversion of η3-H2SiRR' σ-complexes and 16-electron silylene complexes via reversible H-H or C-H elimination. (2014) (23)
- Tantalum–Polyhedral Oligosilsesquioxane Complexes as Structural Models and Functional Catalysts for Epoxidation (2017) (23)
- Reactivity of a scandium-silicon bond toward carbon monoxide and CN(2,6-Me2C6H3). Generation and reactivity of an apparent silene intermediate resulting from isocyanide coupling at scandium (1990) (22)
- Tris(trimethylsilyl)silyl derivatives of tri-tert-butoxyzirconium and tri-tert-butoxyhafnium. X-ray crystal structure of (Me3CO)3ZrSi(SiMe3)3 (1989) (22)
- Enhanced Reactivity of Cationic vs Neutral Hafnocene Complexes in Stoichiometric and Catalytic σ-Bond Metathesis Reactions Involving Si−H and Si−C Bonds (2001) (22)
- Reverse micelle synthesis of rhodium nanoparticles. (2007) (22)
- Nickel Complexes with Bis(8-quinolyl)silyl Ligands. An Unusual Ni3Si2 Cluster Containing Six-Coordinate Silicon† (2010) (22)
- Efficient, Zirconocene-Mediated Cyclotrimerization and Cyclotetramerization of Me3SiC.tplbond.CC6H4C6H4C.tplbond.CSiMe3 to Unsaturated Macrocycles (1995) (22)
- Disulfide passivation of the Ge(100)-2 × 1 surface. (2011) (21)
- Ruthenium(IV) silyl hydride complexes via reaction of silanes with 16-electron [Ru(η5-C5Me5)(PPri3)X](X = Cl, CH2SiHPh2, SiMePh2) complexes. Hydride migrations to an η2-silene ligand (1992) (21)
- Nonaqueous, Molecular Precursor Route to Hybrid Inorganic/Organic Zirconia−Silica Materials Containing Covalently Linked Organic Bridges (2003) (21)
- Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons. (2020) (21)
- Disilanylenearylene oligomers and polymers from dehydropolymerization of 1,4-RH2SiC6H4SiH2R (R = methyl, ethyl, and hexyl) (1993) (21)
- Olefin Hydroarylation Catalyzed by (pyridyl-indolate)Pt(II) Complexes: Catalytic Efficiencies and Mechanistic Aspects (2017) (20)
- Activation of Arene C−H Bonds by a Cationic Hafnium Silyl Complex Possessing an α-Agostic Si−H Interaction (2002) (20)
- A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states. (2014) (20)
- Insertion of ethylene into zirconium-silicon and hafnium-silicon bonds (1989) (20)
- Preparation and properties of tris(trimethylstannyl)silyl complexes of chromium, molybdenum, and tungsten. X-ray structure of [NEt4][(CO)5WSi(SnMe3)3] (1990) (20)
- Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+. (2012) (20)
- Synthesis and Reactivity of d0 Alkyl, Silyl, and Hydride Complexes of Titanium and Zirconium Featuring an Aryl-Substituted Tripodal Triamido Ligand Derived from cis,cis-1,3,5-Triaminocyclohexane (2004) (20)
- Zirconium amide, halide, and alkyl complexes supported by tripodal amido ligands derived from cis, cis-1,3,5-triaminocyclohexane (2002) (20)
- DFT Investigation of the Catalytic Hydromethylation of α-Olefins by Metallocenes. 1. Differences between Scandium and Lutetium in Propene Hydromethylation (2006) (20)
- Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N)Ta[Si(SiMe3)3]H: The Unexpected Formation of a Ta(V) Carbonyl Complex and the Complete Reduction of CO (1999) (20)
- Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis (2015) (20)
- Mesityl alkyne substituents for control of regiochemistry and reversibility in zirconocene couplings: new synthetic strategies for unsymmetrical zirconacyclopentadienes and conjugated polymers. (2009) (19)
- Chromium(II) and chromium(III) tri-tert-butoxysiloxy complexes (1993) (19)
- Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand. (2015) (19)
- Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands. (2020) (19)
- Stabilization of reactive Co4O4 cubane oxygen-evolution catalysts within porous frameworks (2019) (19)
- Reactions of the ruthenium silylene derivative [(η5-C5Me5)(PMe3)2RuSiPh2(NCMe)]BPh4 with alcohols, ketones and acetic acid (1991) (19)
- Synthesis and reactivity of bis(heptamethylindenyl) yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: crystal structure of Ind*2YCl(THF) (2004) (19)
- Molecular cobalt electrocatalyst for proton reduction at low overpotential. (2014) (19)
- Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 Di(phosphine) Complexes of Rhodium and Iridium (2013) (19)
- Synthesis and characterization of scandium complexes with reduced ligands: Crystal structures of Cp∗ScI2, [Cp∗ScI(bpy)]2, and [Cp∗ScCl(bpy)]2 (2005) (18)
- Order−Disorder Phase Transition in Poly(di-n-butylstannane) Observed by UV−Vis and Raman Spectroscopy (2002) (18)
- Migrations in a Polysilyl Complex of Rhodium. Trapping of an Apparent Silylene Intermediate and Observation of Reversible Si−Si Bond Reductive Elimination (1996) (18)
- Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. (2004) (18)
- BIPYRIDINE-CONTAINING CYCLOPHANES VIA ZIRCONOCENE COUPLING (1998) (18)
- Coordinatively and Electronically Unsaturated Zwitterionic Iron Silyl Complexes Featuring the Tripodal Phosphine Ligand [PhB(CH2PiPr2)3]- (2003) (18)
- Insertion of carbon monoxide into a transition metal-silicon bond. X-ray structure of the silaacyl chloro(trimethylsilyl-.eta.2-carbonyl)bis(.eta.5-cyclopentadienyl)zirconium (1985) (18)
- Synthesis and Reactivity of d0 Bis(imido) Silyl and Germyl Complexes of Molybdenum and Tungsten (1997) (18)
- Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing. (2018) (18)
- Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium. (2017) (18)
- Molecular Routes to Metal Oxides and Metal Silicates. Synthesis and Thermal Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3 and W2(NHMe2)2[O2Si(OtBu)2]2[OSi(OH)(OtBu)2]2 (1997) (18)
- The Influence of Surface Modification on the Epoxidation Selectivity and Mechanism of TiSBA15 and TaSBA15 Catalysts with Aqueous Hydrogen Peroxide (2008) (18)
- Influence of a "Dangling" Co(II) Ion Bound to a [MnCo3O4] Oxo Cubane. (2018) (18)
- Trialkoxysiloxy complexes of nickel. Molecular structures of Na3(.mu.3-I){Ni[.mu.3-OSi(O-tert-Bu)3]3I}.cntdot.0.5THF.cntdot.0.5C5H12 and {(.eta.3-C3H5)Ni[.mu.2-OSi(O-tert-Bu)3]}2 (1990) (17)
- Insertion of organic carbonyls into the tantalum-silicon bond of (.eta.5-C5Me5)Cl3TaSiMe3. Preparation and characterization of the .alpha.-silylalkoxides (.eta.5-C5Me5)Cl3TaOCRR'SiMe3 (1987) (17)
- TRANSITION-METAL-MEDIATED REDISTRIBUTION AT SILICON : A BIMOLECULAR MECHANISM INVOLVING SILYLENE COMPLEXES (1994) (17)
- Mechanistic Interrogation of Alkyne Hydroarylations Catalyzed by Highly Reduced, Single-Component Cobalt Complexes. (2020) (17)
- Electrocatalytic water oxidation by single site and small nuclearity clusters of cobalt (2018) (16)
- Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV-Oxo with Significant Oxyl Radical Character. (2019) (16)
- Sterically controlled functionalization of carbon surfaces with -C6H4CH2X (X = OSO2Me or N3) groups for surface attachment of redox-active molecules. (2015) (16)
- Dehydrogenative polymerization of silanes to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism (1989) (16)
- Antimony-antimony bond formation by reductive elimination from a hafnium bis(stibido) complex. (2006) (16)
- Hydrogen Migrations in Rhodium Silyl Complexes: Silylene Intermediates vs Oxidative Addition/Reductive Elimination† (1998) (16)
- Nucleophilic Attack of Amides onto Coordinated Ethylene in Platinum Complexes Supported by a Chelating Pyridyl−Pyrrolide Ligand: Azaplatinacyclobutane and Vinylamine Complexes (2010) (16)
- Convenient, zirconocene-coupling routes to germole- and thiophene-containing macrocycles with triangular geometries (2003) (15)
- Bis(triisopropylsilyl)-o-phenylenediamido complexes of tantalum. X-ray structure of (η5-C5Me5)[o-C6H4(NSiPri3)2]TaCl2 (1996) (15)
- Stoichiometric Reaction Chemistry of Cationic Ruthenium Silylene Complexes toward Polar and Nonpolar Organic Substrates (2012) (15)
- Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp∗(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium (2014) (15)
- Scalable, Divergent Synthesis of a High Aspect Ratio Carbon Nanobelt. (2021) (15)
- Oxygen-atom transfer chemistry and thermolytic properties of a di-tert-butylphosphate-ligated Mn4O4 cubane. (2015) (15)
- Strained, ring tilted dicarbon-bridged [2]ferrocenophanes and ferrocene revisited: 57Fe Mössbauer spectroscopic study of bonding, hyperfine interactions, and lattice dynamics (1999) (15)
- Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne. (2006) (15)
- Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and iron (2002) (15)
- Synthesis and Study of Heterobimetallic Complexes Supported by a Ferrocene-Based Bisphosphine−Diamine Ligand (2003) (14)
- Cross-conjugated polymers via condensation of a zirconocene alkynyl(benzyne) derivative generated by thermolysis of Cp2ZrMe(C6H4CCSiMe3) (1996) (14)
- Generation and Reactivity of {(Ethane-1,2-diyl)bis[diisopropylphosphine-κP]}-{[2,4,6-tri(tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(tBu3C6H2)}(iPr2PCH2CH2PiPr2)]): Catalytic C−P Bond Formationvia Intramolecular C−H/P−H Dehydrogenative Cross-Coupling (2001) (14)
- A new molecular precursor for magnesia-silica materials (2001) (14)
- Ether cleavage following insertion of carbon monoxide into the tantalum-silicon bond of (.eta.5-C5Me5)Ta(SiMe3)Cl3 (1985) (14)
- The Silicon-Heteroatom Bond (1991) (1991) (14)
- SYNTHESIS AND REACTIVITY OF 16-ELECTRON HAFNOCENE SILYL HYDRIDE COMPLEXES (1997) (14)
- Tetrahedral Lewis base adducts of an acyl. Preparation and x-ray structure of the pyridine adduct (.eta.5-C5Me5)Cl3Ta[.eta.2-OC(SiMe3)(NC5H5)] (1986) (14)
- Lanthanide–tungsten heterobimetallic complexes viaσ-bond metathesis (1994) (14)
- Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization of the Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n (M = Zr, Hf; n = 1, 2) (1998) (14)
- The [(η5-C5Me5)(2,2‘-bipyridine)Ru]- Anion and Its Use in the Synthesis of Alkyl, Gallyl, and Stannyl Complexes of Ruthenium (2004) (14)
- Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. (2016) (14)
- Silylene-bridged ruthenium dimers via reactions of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2 with silanes. Structure of {[(.eta.5-C5Me5)Ru]2(.mu.-SiPhOMe)(.mu.-OMe)(.mu.-H)} (1992) (13)
- The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes. (2015) (13)
- (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): an unusual δ-agostic iron complex containing an η1-SiH interaction (2010) (13)
- Tantalum-Mediated Substitution at Germanium: A Germolyl-to-Germole Transformation Leading to η4-C4Me4GeMeCl Complexes (2000) (13)
- Monomeric, Divalent Vanadium Bis(arylamido) Complexes: Linkage Isomerism and Reactivity (2019) (12)
- Dicopper Alkyl Complexes: Synthesis, Structure, and Unexpected Persistence (2018) (12)
- Tricoordinate Organochromium(III) Complexes Supported by a Bulky Silylamido Ligand Produce Ultra-High-Molecular Weight Polyethylene in the Absence of Activators (2016) (12)
- A coordination network based on d0 transition-metal centers: synthesis and structure of the [2,4]-connected layered compound [(TiCl4)2Si(C6H4CN-p)4]·1.5C7H8 (1998) (12)
- Facile interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(mu-H)SnH2]: DFT investigations of hafnocene stannyl complexes as masked stannylenes. (2010) (12)
- Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica. (2013) (12)
- Bis(pentamethylcyclopentadienyl)bis(pyridine)ytterbium(II) (1982) (12)
- Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoroheterofluorenes: new materials with high electron affinities. (2008) (12)
- Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. (2016) (12)
- Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate Complex in Organic Solvents (1998) (11)
- Epoxidation catalysts derived from introduction of titanium centers onto the surface of mesoporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica (2013) (11)
- Site-selective [2 + 2 + n] cycloadditions for rapid, scalable access to alkynylated polycyclic aromatic hydrocarbons† (2019) (11)
- Synthesis and characterization of [(diene)Rh[mu-OSi(OtBu)3]]2, a precursor to silica-bound rhodium. (2004) (11)
- Elucidation of Diverse Solid‐State Packing in a Family of Electron‐Deficient Expanded Helicenes via Microcrystal Electron Diffraction (MicroED)** (2020) (11)
- Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a Bipyridine Ligand (2009) (11)
- DFT Investigation of the Catalytic Hydromethylation of Olefins by Scandocenes. 2. Influence of the Ansa Ligand on Propene and Isobutene Hydromethylation (2008) (11)
- Paramagnetic Vanadium Silyl Complexes: Synthesis, Structure, and Reactivity (2008) (11)
- Early-Transition-Metal Complexes of Functionalized Nonagermanide Clusters: Synthesis and Characterization of [Cp2(MeCN)Ti(η1-Ge9{Si(TMS)3}3)] and K3[Cp2Ti(η1-Ge9{Si(TMS)3}2)2]. (2019) (11)
- Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide. (2016) (11)
- Selective Synthesis of a Series of Isostructural MII CuI Heterobimetallic Complexes Spontaneously Assembled by an Unsymmetrical Naphthyridine-Based Ligand. (2018) (11)
- Bis[Bis(Trimethylsilyl)Amido]Bis(Diethyl Ether)Ytterbium and (Diethyl Ether)Bis(η5‐Pentamethylcyclopentadienyl)Ytterbium (2007) (10)
- Preparation and reaction chemistry of trimethylsilyl derivatives of tantalum. X-ray structures of d0 (.eta.5-C5Me5)Ta(SiMe3)Cl3 and d1 (.eta.5-C5Me5)Ta(SiMe3)(PMe3)Cl2 (1986) (10)
- Artificial Metalloproteins Containing Co (2018) (10)
- Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload. (2011) (9)
- Octa- and Nonamethylfluorenyl Complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of Steric and Electronic Effects (2008) (9)
- Silylene Complexes of Late 3d Transition Metals Supported by tris-Phosphinoborate Ligands (2018) (9)
- Silane–Allyl Coupling Reactions of Cp*(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp*(iPr2MeP)FeH(N2) (2015) (9)
- Insertions of nitriles and pyridine into the ZrSi bond of (η5-C5H5)(η5-C5Me5)Zr[Si(SiMe3)3]Me (1990) (9)
- Sigma-Bond Metathesis Reactions Involving Lanthanide-Silicon and Lanthanide-Hydrogen Bonds (1994) (9)
- Reaction of an early-transition metal .eta.2-silaacyl complex with pyridine. Diastereoselectivity in the formation of a (2-pyridyl)silylmethoxy ligand (1988) (9)
- Zirconocene-coupling routes to conjugated polymers: soluble poly(arylenedienylene)s (1998) (9)
- Synthesis and Chemistry of the 16‐Electron Osmium Complex [OsBr(η5‐C5Me5)(PiPr3)] (2001) (9)
- Selective Catalytic Cyclohexene Oxidation Using Titanium-Functionalized Silicone Nanospheres (2007) (9)
- Octa- and Nonamethylfluorene and an Electron-Rich Permethylfluorenyl Ruthenocene Derivative (2006) (9)
- Organosilicon nitrogen compounds (2010) (9)
- Synthesis and Structure of the (tetrahydroxy)oligosiloxane [(tBuO)3SiOSi(OH)2]2O (2000) (9)
- Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes. (2015) (9)
- A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes. (2020) (8)
- Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes. (2004) (8)
- Octa- and Nonamethylfluorenyl Complexes of Zirconium(IV): Reactive Hydride Derivatives and Reversible Hydrogen Migration between the Metal and the Fluorenyl Ligand (2009) (8)
- Synthesis of chelating, C2-symmetric bis(silylamido) complexes of zirconium, and their activities as olefin polymerization catalysts (2003) (8)
- The Coordination Polymerization of Silanes to Polysilanes by a “σ ‐Bond Metathesis” Mechanism. Implications for Linear Chain Growth (1993) (8)
- Synthesis, characterization and reactivity of tetramethylphospholyl complexes of scandium (2006) (8)
- Polymers with Linked Macrocyclic Rings in the Main Chain. Zirconocene Coupling of 1,8-Cyclotetradecadiyne (1996) (8)
- Multifunctional silicon surfaces: reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces. (2014) (8)
- Chapter 1. Hypervalent silicon compounds (2010) (8)
- Bimetallic Mechanism for Alkyne Cyclotrimerization with a Two-Coordinate Fe Precatalyst (2020) (7)
- Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores. (2019) (7)
- Functionalization of an iridium–diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources (2016) (7)
- Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine. (2011) (7)
- Concerted Proton-Electron Transfer Reactivity at a Multimetallic Co4O4 Cubane Cluster. (2020) (7)
- Mechanistic Aspects of Cobalt-Oxo Cubane Clusters in Oxidation Chemistry. (2022) (7)
- An Arbuzov-like reaction in the trimethyl phosphite-.eta.2-silaacyl adduct (.eta.5-C5Me5)Cl3Ta[.eta.2-OC(SiMe3)[P(OMe)3]] (1987) (7)
- Appendix to ‘Transition‐metal silyl derivatives’ (2010) (7)
- Catalytic Olefin Hydrosilations Mediated by Ruthenium η3-H2Si σ Complexes of Primary and Secondary Silanes (2018) (7)
- Chapter 9. Transition-metal silyl derivatives (2010) (7)
- Group 8 Transition Metal Complexes of the Tripodal Triphosphino Ligands PhSi(CH2PR2)3 (R = Ph, iPr) (2013) (7)
- Hafnium imido complexes containing silyl ligands (2002) (6)
- Synthesis and Reactivity of Ti(III) Tris(tert-butoxy)siloxy Complexes (2004) (6)
- A two-coordinate Ni(i) silyl complex: CO2 insertion and oxidatively-induced silyl migrations. (2019) (6)
- Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific Blue™) succinimidyl ester under acidic and basic conditions (2013) (6)
- Synthesis and characterization of tantalum silsesquioxane complexes. (2013) (6)
- Heavy Tetrel Complexes of Ru Featuring Ru═E(R)X and Ru–E–R (E = Sn, Pb) Linkages (2019) (6)
- Element–Hydrogen Bond Activations at Cationic Platinum Centers To Produce Silylene, Germylene, Stannylene, and Stibido Complexes (2019) (6)
- Zirconium bent sandwich complex with a dicarbahexaborate ligand: [Li(THF)3]{[η5-C2B4H4(SiMe3)2](η5-C5Me5)ZrCl2} (1997) (6)
- Isolation of a Dicationic Platinum Complex with Two Accessible Coordination Sites (2013) (6)
- Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex (2019) (6)
- TERPHENYL LIGANDS AND COMPLEXES (2018) (5)
- Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission. (2020) (5)
- Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium(ii) complexes. (2019) (5)
- Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium. (2018) (5)
- Adsorption and Stability of π-Bonded Ethylene on GaP(110) (2013) (5)
- C-H Activation by RuCo3O4 Oxo Cubanes: Effects of Oxyl Radical Character and Metal-Metal Cooperativity. (2021) (5)
- Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes. (2009) (4)
- Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center (2020) (4)
- General, Efficient Route to Thiophene‐1‐oxides and Well‐Defined, Mixed Thiophene‐Thiophene‐1‐oxide Oligomers. (2000) (4)
- Ether Cleavage Following Insertion of Carbon Monoxide into the Tantalum - Silicon Bond of (η5-C5Me5)Ta(SiMe3)Cl3. (1986) (4)
- An Anionic Ruthenium Dihydride [Cp*(iPr2MeP)RuH2]− and Its Conversion to Heterobimetallic Ru(μ-H)2M (M = Ir or Cu) Complexes (2019) (4)
- Olefin Hydroarylation Catalyzed by a Single-Component Cobalt(-I) Complex. (2021) (4)
- Dehydrogenative polymerization of silane to polysilanes by zirconocene and hafnocene catalysts. A new polymerization mechanism [Erratum to document cited in CA111(20):174712j] (1990) (4)
- Switchable Product Selectivity in Diazoalkane Coupling Catalyzed by a Two-Coordinate Cobalt Complex (2021) (4)
- Covalent Functionalization of GaP(110) Surfaces via a Staudinger-Type Reaction with Perfluorophenyl Azide (2016) (3)
- TERTIARY PHOSPHINE COMPLEXES OF THE F‐BLOCK METALS. CRYSTAL STRUCTURE OF YB(N(SIME3)2)2(ME2PCH2CH2PME2): EVIDENCE FOR A YTTERBIUM‐Γ‐CARBON INTERACTION (1982) (3)
- Zirconocene-mediated macrocyclizations of diynes containing di-o-methylphenylene spacers. (2009) (3)
- Structure of trans‐(ethanenitrile)(hydrido)bis(tricyclohexylphosphine)platinum tetraphenylborate dichloromethane solvate (1991) (3)
- Interligand H⋯Si interactions in tungsten silyl trihydride complexes (2011) (3)
- Identification of Second Shell Coordination in Transition Metal Species Using Theoretical XANES: Example of Ti-O-(C, Si, Ge) Complexes. (2017) (3)
- Metal‐Catalyzed Dehydropolymerization of Secondary Stannanes to High Molecular Weight Polystannanes. (1996) (3)
- Water oxidation catalysis via immobilization of the dimanganese complex [Mn 2 ( μ -O) 2 Cl( μ -O 2 CCH 3 )-(bpy) 2 (H 2 O)](NO 3 ) 2 onto silica † (2013) (3)
- Versatile Fe-Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C-H Bond Activation. (2021) (3)
- σ-Bond Metathesis Reactions of Si-H and M-Si Bonds. New Routes to d0 Metal Silyl Complexes. (1989) (2)
- Unsymmetrical Naphthyridine-Based Dicopper(I) Complexes: Synthesis, Stability, and Carbon–Hydrogen Bond Activations (2021) (2)
- Two-Coordinate Iron(I) Complexes on the Edge of Stability: Influence of Dispersion and Steric Effects (2021) (2)
- Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially-Hydrolyzed Framework Sites in Zeolites and Zeotypes. (2020) (2)
- Preparation and Characterization of Tris(trimethylsilyl)silyl Derivatives of Zinc, Cadmium, and Mercury. X-Ray Crystal Structure of Zn(Si(SiMe3)3)2. (1987) (2)
- Pt—Ag Catalyst System for Hydroarylations with Unactivated Arenes and Olefins. (2004) (2)
- Expanded [23]-Helicene with Exceptional Chiroptical Properties via an Iterative Ring-Fusion Strategy. (2022) (2)
- Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)). (2004) (2)
- Zirconocene‐Mediated, High‐Yielding Macrocyclizations of Silyl‐Terminated Diynes. (2002) (2)
- C—H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen—Deuterium Exchange and C—C Bond‐Forming Reactions (2005) (2)
- Pentamethylcyclopentadienyl and bis(trimethylsilyl)amido complexes of the di- and trivalent lanthanides (1982) (2)
- Appendix to ‘Organosilicon derivatives of phosphorus, arsenic, antimony and bismuth’ (2010) (2)
- Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers (2017) (1)
- Coordinatively Unsaturated Tris(trimethylsilyl)silyl Complexes of Chromium, Manganese, and Iron. (1987) (1)
- Low-valent iron and cobalt complexes supported by a rigid xanthene-based disilylamido ligand (2020) (1)
- Efficient alkene hydrosilation with bis(8-quinolyl)phosphine (NPN) nickel catalysts. The dominant role of silyl-over hydrido-nickel catalytic intermediates† (2020) (1)
- Synthesis, Characterization, and Reactivity of Low-Coordinate Titanium(III) Amido Complexes (2022) (1)
- Intramolecular rearrangements on ultrafast timescales: femtosecond infrared studies of ring slip in (eta(1)-C(5)Cl(5))Mn(CO)(5). (2001) (1)
- Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. (2020) (1)
- Oxidative dehydrogenation of propane over vanadia-based cataly supported on high-surface-area mesoporous MgAl 2 O 4 (2004) (1)
- Synthesis and Characterization of Et2NM{OB[OSi(OtBu)3]2}3 (M = Zr, Hf) Molecular Precursors to Zr/B/Si/O and Hf/B/Si/O Materials (2005) (1)
- Unusual ruthenium hydride complexes supported by the [N(2-PPh2-4-Me-C6H3)2] pincer ligand (2010) (1)
- Platinum-Mediated Reactions of Hydrosilanes. Isolation of a Complex with Bridging Disilene and Silylene Ligands. (1992) (1)
- Appendix to ‘Siloxane polymers and copolymers’ (2010) (1)
- Preparation, Isolation, and Characterization of Transition-Metal η2-Silene Complexes. X-Ray Crystal Structure of (η5-C5Me5)(P(iPr)3)Ru(H)(η2-CH2SiPh2). (1989) (1)
- EFFECTS OF PERCURSOR COMPOSTION ON THE LOCAL STRUCTURE OF CU DISPERSED ON MESOPOROUS SILICA: A DETAILED X-RAY ABSORPTION SPECTROSCOPY STUDY (2004) (1)
- Tris(trimethylstannyl)silyl Complexes of Ruthenium and Platinum (1996) (1)
- Synthesis and Reactivity of a Dimeric Ni(I) Methyl Complex (2022) (1)
- Correction: Ga[OSi(OtBu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. (2016) (1)
- Preparation of the First Stable Formylsilane, (Me3Si)3SiCHO, from a Zirconium η2-Silaacyl Complex. (1988) (1)
- Carbonylation chemistry of the tantalum silyl (.eta.5-C5Me5)Cl3TaSiMe3. Synthesis, characterization, and reaction chemistry of (.eta.2-COSiMe3) and derivatives [Erratum to document cited in CA110(9):75695d] (1990) (1)
- Ein stabiler ?5-Germacyclopentadienyl-Komplex: [(?5-C5Me5)Ru{?5-C4Me4GeSi(SiMe3)3}] (1993) (1)
- The influence of Michael Lappert on the chemistry landscape. (2014) (1)
- Silyl and Diphenylsilylene Derivatives of (η5-C5Me5)(PMe3)2Ru. Evidence for the Base-Free Silylene Complex ((η5-C5Me5)(PMe3)2Ru=SiPh2)+. (1990) (1)
- Reactions of Carbon Monoxide with Trimethylsilyl and Tris(trimethylsilyl)silyl Derivatives of Group 4 Metals. Synthesis, Characterization, and Reactivity of Silaacyl Complexes. (1987) (1)
- Copper(III) Metallacyclopentadienes via Zirconocene Transfer and Reductive Elimination to an Isolable Phenanthrocyclobutadiene. (2022) (1)
- Formation of the novel benzophenone sila-acylhydrazonato complex (η5-C5Me5)Cl3Ta[OC(SiMe3)NNCPh2] following addition of diphenyldiazomethane to an η2-sila–-acyl ligand (1987) (1)
- A sequential cyclization/π-extension strategy for modular construction of nanographenes enabled by stannole cycloadditions (2022) (1)
- An enigmatic trailblazer on the frontier of discovery: Richard A. Andersen. (2018) (0)
- An Efficient, Single‐Source Molecular Precursor to Silicoaluminophosphates. (2001) (0)
- Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane (2004) (0)
- Reaction of an Early-Transition-Metal η2-Silaacyl Complex with Pyridine. Diastereoselectivity in the Formation of a (2-Pyridyl)silylmethoxy Ligand. (1989) (0)
- CCDC 837240: Experimental Crystal Structure Determination (2012) (0)
- New Chemistry for Reactive Transition‐Metal Silicon Bonds (2008) (0)
- DIVALENT LANTHANIDE CHEMISTRY. PREPARATION OF SOME FOUR- AND SIX-COORDINATE BIS((TRIMETHYLSILYL)AMIDO) COMPLEXES OF EUROPIUM(II). CRYSTAL STRUCTURE OF BIS(BIS(TRIMETHYLSILYL)AMIDO)BIS(1,2-DIMETHOXYETHANE)EUROPIUM(II) (1981) (0)
- Revealing Transmission in Metal-Molecule Junctions Using Length Dependant Thermopower Measurements (2009) (0)
- An Arbuzov-like Reaction in the Trimethyl Phosphite-η2-Silaacyl Adduct (η5-C5Me5)Cl3Ta(η2-OC(SiMe3)(P(OMe)3)). (1987) (0)
- Zirconium complexes supported by a new class of tripodal amide ligands. (2001) (0)
- Synthesis and reactivity of new yttrium and lanthanide silyl complexes (1993) (0)
- Title Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron ( Oxy ) Hydroxide Catalysts Permalink (2015) (0)
- Homocoupling for Pentalenes Synthesis (2009) (0)
- Appendix to ‘Organosilicon nitrogen compounds’ (2010) (0)
- TERTIARY PHOSPHINE COMPLEXES OF THE f-BLOCK METALS; PREPARATION OF PENTAMETHYLCYCLOPENTADIENYL-TERTIARY PHOSPHIEN COMPLEXES OF YTTERBIUM(II AND III) AND EUROPIUM(II). THE CRYSTAL STRUCTURE OF Yb(Me5C5)2Cl (Me2PCH2PMe2) (1982) (0)
- Early-Transition-Metal Silicon Compounds and Their Roles in the Synthesis of New Polymeric and Ceramic Materials (1991) (0)
- Tailoring Properties of Silicon‐Containing Oxide Catalysts Via the Thermolytic Molecular Precursor Route (2008) (0)
- Carbonylation Chemistry of the Tantalum Silyl (η5-C5Me5)Cl3TaSiMe3. Synthesis, Characterization, and Reaction Chemistry of (η5-C5Me5)Cl3Ta(η2-COSiMe3) and Derivatives. (1989) (0)
- Pt‐Catalyzed C—C Activation Induced by C—H Activation. (2014) (0)
- Exploring the reactivity of (dippe)Rh(eta(3)-benzyl) with (2,4,6-tri-tert-butylphenyl)PH2:Stoichiometric and catalytic dehydrogenative P-H/C-H cross-coupling. (2002) (0)
- Hybrid organic-inorganic gels based on dendrimeric buildingblocks: high surface area xerogels as catalyst supports (2000) (0)
- DIVALENT LANTHANIDE CHEMISTRY; PREPARATION AND CRYSTAL STRUCTURES OF SODIUM TRIS[BIS(TRIMETHYLSILYL) AMIDO] -EURDPATE(II) AND -YTTERBATE (II), NaM[NSiMe3)2]3 (1983) (0)
- a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry Permalink (2016) (0)
- Electronic Transport in Molecular Diode Heterojunctions (2010) (0)
- Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X-Ray Structures of d0 (η5-C5Me5)Ta(SiMe3)Cl3 and d1 (η5-C5Me5)Ta(SiMe3)(PMe3)Cl2. (1987) (0)
- Transition-Metal Complexes of Reactive Silicon Intermediates (2010) (0)
- Probing the structure of the silylene complex (Cy3P)2PtSiMes2. (2004) (0)
- Alkene epoxidation by fluorinated-alcohol modified Ti-SBA15 (2014) (0)
- Appendix to ‘Chemistry of compounds with silicon–sulphur, silicon–selenium and silicon–tellurium bonds’ (2010) (0)
- Pyridine-derived dinuclear copper complexes: Synthesis, structure, characterization, and reactivity with small molecules (2014) (0)
- E ffi cient C – H bond activations via O 2 cleavage by a dianionic cobalt( II ) complex † Chemistry 2014 (0)
- Tuning the Thermoelectric Properties of Metal-Molecule-Metal Junctions (2008) (0)
- STM Study of Donor-Bridge-Acceptor Molecules Having Different Bridge Structure (2010) (0)
- Mono(η5‐Pentamethylcyclopentadienyl) Complexes of Osmium (2014) (0)
- Synthesis, structure, and alpha-elimination chemistry of hafnocene triarylstannyl complexes. (2005) (0)
- Additions and Corrections - Preparation and Reaction Chemistry of Trimethylsilyl Derivatives of Tantalum. X-ray Structures of d0 (n5-C5Me5)Ta(SiMe3)Cl3 and d1 (n5-C5Me5)Ta-(SiMe3)(PMe3)Cl2 (1987) (0)
- DURIP Synthesis and Study of Preceramic Polymers/Ceramic Precursors, Metal Silicides, and Polymers with Unique Optical and Electronic Properties (1991) (0)
- Trialkoxysiloxy Complexes as Precursors to MO2×4 SiO2 (M: Ti, Zr, Hf) Materials. (1992) (0)
- Activation of arene C[bond]H bonds by a cationic hafnium silyl complex possessing an alpha-agostic Si[bond]H interaction. (2002) (0)
- Preparation, Characterization, and X-Ray Crystal Structure of an Acetonitrile-Complexed Ruthenium Silylene. (1988) (0)
- Reactivity of a Sc-Si Bond Toward CO and CN(2,6-Me2C6H3). Generation and Reactivity of an Apparent Silene Intermediate Resulting from Isocyanide Coupling at Scandium. (1990) (0)
- Tertiary phosphine complexes of the f-block metals. Preparation of pentamethylcyclopentadienyl-tertiary phosphine complexes of ytterbium(II), ytterbium(III) and europium(II). Crystal structure of Yb(Me5C5)2Cl(Me2PCH2PMe2) (2002) (0)
- Effect of bridge on energy transfer and photoinduced charge separation in perylene-diimide-naphthalene-bisimide- hexathiophene based donor-bridge-acceptor triads (2013) (0)
- Robust dicopper(i) μ-boryl complexes supported by a dinucleating naphthyridine-based ligand (2022) (0)
- PREPARATION AND CRYSTAL STRUCTURE OF Bis[BIS (PENTAMETHYLCYCLOPENTADIENYL) YTTERBIUM(III)] UNDECACARBONYLTRIFERRATE, [(C5Me5)2Yb]2 [Fe3(CO)11]; A COMPOUND WITH POUR ISOCARBONYL (Fe-CO-Yb) INTERACTIONS (1981) (0)
- Base-Free Silylene Complexes ((η5-C5Me5)(PMe3)2Ru=Si(SR)2)BPh4 (R: Et, p-MeC6H4). (1991) (0)
- REACTION OF M(C5Me5)2(OEt2),M = Eu OR Yb, WITH PHENYLRCETYLENE; FORMATION OF MIXED-VALENCE Yb3(C5Me5)4(u-=CPh)4 AND Eu2(C5Me5)2(u-C=CPH)2(thf)4 (1984) (0)
- A Stable η2-Silene Complex of Iridium: (η5-C5Me5)(PMe3)Ir(η2-CH2=SiPh2). (1990) (0)
- Synthesis, Characterization and Reactivity ofTetramethylphospholyl Complexes of Scandium (2007) (0)
- Dimesitylsilyl Derivatives of Zirconium. (1989) (0)
- CCDC 1473704: Experimental Crystal Structure Determination (2016) (0)
- New molecular precursors for low-temperature routes to new oxide materials. Final progress report (1997) (0)
- Perfluoropentaphenylborole: A New Approach to Lewis Acidic, Electron-Deficient Compounds (2009) (0)
- Insertions of Nitriles and Pyridine into the Zr-Si Bond of (η5-C5H5)(η5-C5Me5)Zr(Si(SiMe3)3)Me. (1990) (0)
- Cubanes Oxygen-Atom Transfer Chemistry and Thermolytic Properties of a Di-tert-Butylphosphate-Ligated Mn 4 O 4 Cubane (2015) (0)
- Zirconocene “Molecular Zippers”: Implements for Construction of Well-defined Polymers and Macrocycles (1999) (0)
- Hydrosilylation Catalysis by C2-Symmetric Bis(silylamido) Complexes of Yttrium. (2000) (0)
- First-Principles Studies of Single-Molecule Photovoltaics (2009) (0)
- PREPARATION AND CRYSTAL STRUCTURE OF BIS(PENTAMETHYLCYCLOPENTADIENYL) YTTERBIUM (III) TETRACARBONYLCOBALTATE) (-I) (TETRAHYDROFURAN); A YTTERBIUM ISOCARBONYL (Yb-OC-Co) BOND (1981) (0)
- Title Artificial Metalloproteins Containing Co 4 O 4 Cubane Active Sites Permalink (2018) (0)
- Direct Transformation of SiH4 to a Molecular L(H)2Co═Si═Co(H)2L Silicide Complex. (2023) (0)
- Preparation and Characterization of the Monomeric Copper(II) Siloxide Complex Cu(OSi(OCMe3)3)2(py)2. (1990) (0)
- Alkoxy and Aryloxy Derivatives of (Pentamethylcyclopentadienyl)ruthenium. X-Ray Crystal Structures of ((η5-C5Me5)Ru(μ-OMe))2, ((η5-C5Me5)(CO)Ru(μ-OEt))2, and (η5-C5Me5)Ru(η5-2,6-tBu2C6H3O) and Molecular Orbital Analysis of ((η5-C5H5)R (1989) (0)
- CRYSTAL STRUCTURE OF BIS (PENTAMETHYLCYCLOPENT-ADIENYL)BIS(PYRIDINE)YTTERBIUtl(II) (1981) (0)
- Transition Metals in Organosilicon Chemistry (2009) (0)
- Insertion of Organic Carbonyls Into the Tantalum-Silicon Bond of (η5-C5Me5)Cl3TaSiMe3. Preparation and Characterization of the α-Silylalkoxides (η5-C5Me5)Cl3TaOCRR′SiMe3. (1987) (0)
- A Dicopper Nitrenoid by Oxidation of a CuICuI Core: Synthesis, Electronic Structure, and Reactivity. (2021) (0)
- Gauging aromatic conjugation and charge delocalization in the aryl silanes PhnSiH4-n (n = 0-4), with silicon K-edge XAS and TDDFT. (2020) (0)
- .sigma.-Bond metathesis reactions of silicon-hydrogen and metal-silicon bonds. New routes to d0 metal silyl complexes [Erratum to document cited in CA110(25):231799y] (1990) (0)
- Covalent Attachment to GaP(110) - Engineering the Chemical Functionalization of a III-V Semiconductor (2014) (0)
- A molecular precursor route to oxide networks and nanocomposite materials. An alternative to the sol-gel method (1997) (0)
- Tris(trimethylstanny1)silyl Complexes of Ruthenium (1996) (0)
- The Reactivity of Transition Metal-Silicon Compounds (1988) (0)
- Late 3d-Transition Metal Complexes Bearing a Bis-Phosphine Borane Ligand, PhB(CH2PtBu2)2 (2022) (0)
- CCDC 1840185: Experimental Crystal Structure Determination (2018) (0)
- Trityl Tetraphenylborate as a Reagent in Organometallic Chemistry. (1989) (0)
- CCDC 751173: Experimental Crystal Structure Determination (2010) (0)
- MicroED Elucidation of Diverse Solid-State Packing in a Family of Electron-Deficient Expanded Helicenes. (2020) (0)
- A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes (2020) (0)
- Preparation and Characterization of Tris(trimethylsilyl)silyl and Tris(trimethylsilyl)germyl Derivatives of Zirconium and Hafnium. X-Ray Crystal Structures of (η5-C5Me5)Cl2HfSi(SiMe3)3 and (η5-C5Me5)Cl2HfGe(SiMe3)3. (1989) (0)
- Synthetic Development and Chemical Reactivity of Transition-Metal Silylene (2007) (0)
- DIVALENT LANTHANIDE CHEMISTRY. PREPARATION OF BASE-FREE DIMERIC BIS [BIS(TRIMETHYLSILYL) AMIDO] -YTTERBIUM(II) AND SOME OF ITS REACTIONS WITH PROTIC ACIDS (1986) (0)
- Silylene extrusion from silanes: Direct conversion of R2SiH2 to iridium silylene dihydride complexes (2000) (0)
- Controlled monodefluorination and alkylation of C(sp3)–F bonds by lanthanide photocatalysts: importance of metal–ligand cooperativity (2022) (0)
- DIVALENT LANTHANIDE CHEMISTRY. PREPARATION AND CRYSTAL STRUCTURES OF SODIUM TRIS(BIS(TRIMETHYLSILYL)AMIDO)EUROPATE(II) AND SODIUM TRIS(BIS(TRIMETHYLSILYL)AMIDO)YTTERBATE(II), NAM(N(SIME3)2)3 (1984) (0)
- INSERTION OF CARBON MONOXIDE INTO A TRANSITION METAL‐SILICON BOND. X‐RAY STRUCTURE OF THE SILAACYL CHLORO(TRIMETHYLSILYL‐η2‐CARBONYL)BIS(η5‐CYCLOPENTADIENYL)ZIRCONIUM (1985) (0)
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