Emil T. Kaiser

Q: What Schools Are Affiliated With Emil T. Kaiser

Emil T. Kaiser is affiliated with the following schools: University of California, Berkeley, Wayne State University, Rockefeller University, University of Chicago, Harvard University

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Emil T. Kaiser

Biology

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Biochemistry

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Biology

Emil T. Kaiser's Degrees

PhD Biochemistry University of California, Berkeley
Bachelors Chemistry University of California, Berkeley

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According to Wikipedia, Emil Thomas Kaiser was a Hungarian-born American biochemist. Kaiser was most notable for his research of enzyme modification. He also was noted for developing new types of catalysts and for a more active form of a peptide hormone.

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Emil T. Kaiser's Published Works

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Published Works

Color test for detection of free terminal amino groups in the solid-phase synthesis of peptides. (1970) (3019)
Amphiphilic secondary structure: design of peptide hormones. (1984) (471)
Platelet factor 4 is chemotactic for neutrophils and monocytes. (1981) (417)
The interaction of hemoglobin with the cytoplasmic domain of band 3 of the human erythrocyte membrane. (1984) (272)
Secondary structures of proteins and peptides in amphiphilic environments. (A review). (1983) (239)
Kinetics and mechanism of hemolysis induced by melittin and by a synthetic melittin analogue. (1982) (207)
Helichrome: synthesis and enzymic activity of a designed hemeprotein (1989) (200)
Polymer-bound oxime esters as supports for solid-phase peptide synthesis. The preparation of protected peptide fragments (1980) (193)
Purification and characterization of the principal inhibitor of calcium oxalate monohydrate crystal growth in human urine. (1983) (192)
Chemical mutation of enzyme active sites. (1984) (169)
The mechanism of activation of lecithin:cholesterol acyltransferase by apolipoprotein A-I and an amphiphilic peptide. (1980) (146)
DESIGN, SYNTHESIS, AND CHARACTERIZATION OF A CYTOTOXIC PEPTIDE WITH MELITTIN-LIKE ACTIVITY (1981) (141)
Peptide segment synthesis catalyzed by the semisynthetic enzyme thiolsubtilisin (1987) (132)
Peptide and protein synthesis by segment synthesis-condensation. (1989) (105)
Solid-phase synthesis of protected peptides on a polymer-bound oxime: preparation of segments comprising the sequence of a cytotoxic 26-peptide analog (1982) (105)
Magnetic resonance and kinetic studies of the manganese(II) ion and substrate complexes of the catalytic subunit of adenosine 3',5'-monophosphate dependent protein kinase from bovine heart. (1979) (101)
Purification and characterization of a calcium oxalate monohydrate crystal growth inhibitor from human kidney tissue culture medium. (1981) (87)
[1] Principles of active site titration of proteolytic enzymes (1970) (87)
Idealization of the hydrophobic segment of the alkaline phosphatase signal peptide (1986) (76)
Mechanistic studies of cAMP-dependent protein kinase action. (1984) (75)
Oxidation of dihydronicotinamides by flavopapain (1978) (75)
Design, synthesis, and characterization of a model peptide having potent calcitonin-like biological activity: implications for calcitonin structure/activity. (1985) (73)
The structural characterization of beta-endorphin and related peptide hormones and neurotransmitters. (1986) (71)
Modification of the catalytic subunit of bovine heart cAMP-dependent protein kinase with affinity labels related to peptide substrates. (1982) (71)
The Mechanism of the Periodate Oxidation of Aromatic Systems. III. A Kinetic Study of the Periodate Oxidation of Catechol (1966) (69)
Color test for terminal prolyl residues in the solid-phase synthesis of peptides (1980) (67)
Stereochemical course of the phospho group transfer catalyzed by cAMP-dependent protein kinase (1988) (66)
Protein kinase C phosphorylates the synthetic peptide Arg-Arg-Lys-Ala-Ser-Gly-Pro-Pro-Val in the presence of phospholipid plus either Ca2+ or a phorbol ester tumor promoter. (1984) (66)
A synthetic amphiphilic helical docosapeptide with the surface properties of plasma apolipoprotein A-I (1979) (65)
Design and characterization of peptides with amphiphilic β‐strand structures (1985) (65)
Identification of a mutant human insulin predicted to contain a serine-for-phenylalanine substitution. (1983) (64)
Progress in bioorganic chemistry (1971) (64)
Semisynthesis and biological activity of porcine [LeuB24]insulin and [LeuB25]insulin. (1980) (62)
Flavopapain: synthesis and properties of semi-synthetic enzymes. (1977) (62)
Synthesis of protected peptide segments and their assembly on a polymer-bound oxime: application to the synthesis of a peptide model for plasma apolipoprotein A-I (1983) (61)
The Hydrolysis of Some Cyclic Esters of Sulfuric Acid (1963) (61)
Carboxypeptidase A. Mechanistic analysis (1972) (60)
Catalytic Activity of Enzymes Altered at Their Active Sites (1988) (60)
Studies on the oxidase activity of copper(II) carboxypeptidase A (1976) (59)
Magnetic resonance studies of the effect of the regulatory subunit on metal and substrate binding to the catalytic subunit of bovine heart protein kinase. (1980) (58)
Carbonic anhydrase catalyzed hydrolysis of 2-hydroxy-5-nitro-.alpha.-toluenesulfonic acid sultone (1969) (58)
Syntehsis and structural stability of helichrome as an artificial hemeproteins (1990) (57)
Chain length-function correlation of amphiphilic peptides. Synthesis and surface properties of a tetratetracontapeptide segment of apolipoprotein A-I. (1980) (57)
Studies on the interactions of spin-labeled substrates with chymotrypsin and with cycloamyloses. (1975) (56)
The chemical modification of enzymatic specificity. (1985) (55)
Design of a peptide hormone: synthesis and characterization of a model peptide with calcitonin-like activity (1983) (54)
Characterization of amphiphilic secondary structures in neuropeptide Y through the design, synthesis, and study of model peptides. (1989) (54)
Chlorotrimethylsilane-phenol as a mild deprotection reagent for the tert-butyl based protecting groups in peptide synthesis (1988) (53)
Photoaffinity labeling the substance P receptor using a derivative of substance P containing p-benzoylphenylalanine. (1991) (53)
Structure-function analysis of proteins through the design, synthesis, and study of peptide models. (1987) (51)
Surface properties of an amphiphilic peptide hormone and of its analog: corticotropin-releasing factor and sauvagine. (1983) (50)
3-NITRO-2-PYRIDINESULFENYL GROUP FOR PROTECTION AND ACTIVATION OF THE THIOL FUNCTION OF CYSTEINE (1981) (49)
Sulfhydryl group reactivity of adenosine 3',5'-monophosphate dependent protein kinase from bovine heart: a probe of holoenzyme structure. (1978) (49)
An antipeptide antibody that specifically inhibits insulin receptor autophosphorylation and protein kinase activity. (1985) (48)
The use of polymer-bound oximes for the synthesis of large peptides usable in segment condensation: synthesis of a 44 amino acid amphiphilic peptide model of apolipoprotein A-1 (1985) (47)
ACTIVATION OF LIPOPROTEIN LIPASE BY SYNTHETIC FRAGMENTS OF APOLIPOPROTEIN C‐II * (1980) (46)
Cyclic AMP-dependent ATPase activity of bovine heart protein kinase. (1979) (45)
Nuclear magnetic resonance studies of the conformation of tetraamminecobalt (III)--ATP bound at the active site of bovine heart protein kinase. (1979) (45)
GENERATION OF CATIONIC CARBON BY ANODIC OXIDATION OF CARBOXYLIC ACIDS (1960) (45)
Mechanism of action of carboxypeptidase A in ester hydrolysis. (1976) (44)
The carboxyl-terminal tridecapeptide of platelet factor 4 is a potent chemotactic agent for monocytes. (1982) (43)
Modification of the active site of alkaline phosphatase by site-directed mutagenesis. (1986) (43)
A SYNTHETIC AMPHIPHILIC β-STRAND TRIDECAPEPTIDE: A MODEL FOR APOLIPOPROTEIN B (1984) (42)
Magnetic resonance measurements of intersubstrate distances at the active site of protein kinase using substitution-inert cobalt(III) and chromium(III) complexes of adenosine 5'-(beta, gamma-methylenetriphosphate). (1980) (41)
Synthetic Approaches to Biologically Active Peptides and Proteins Including Enzymes (1989) (40)
Isolation and characterization of calcium oxalate crystal growth inhibitors from human urine. (1978) (39)
Synthesis of enantiomerically pure .gamma.-amino-.beta.-hydroxybutyric acid using malic acid as the chiral precursor (1985) (39)
Nuclear Overhauser effect studies of the conformations of tetraamminecobalt(III)-adenosine 5'-triphosphate free and bound to bovine heart protein kinase. (1983) (38)
Studies of the mechanism of action and regulation of cAMP-dependent protein kinase. (1980) (38)
Nuclear magnetic resonance studies of the conformation and kinetics of the peptide-substrate at the active site of bovine heart protein kinase. (1981) (38)
Evidence against a crucial role for the phenolic hydroxyl of Tyr-248 in peptide and ester hydrolyses catalyzed by carboxypeptidase A: comparative studies of the pH dependencies of the native and Phe-248-mutant forms (1986) (38)
Design and Synthesis of a Model Peptide with β-Endorphin-Like Properties (1982) (38)
Biological properties of two models of calcitonin gene related peptide with idealized amphiphilic alpha-helices of different lengths. (1988) (38)
Probing the peptide binding site of the cAMP-dependent protein kinase by using a peptide-based photoaffinity label. (1988) (37)
Examination of the requirement for an amphiphilic helical structure in beta-endorphin through the design, synthesis, and study of model peptides. (1983) (36)
Physical and conformational properties of a synthetic leader peptide from M13 coat protein (1984) (36)
Detection of a ''Michaelis'' complex by spin labeling in a model enzyme system (1970) (36)
Selective deprotection of the N.alpha.-tert-butyloxycarbonyl group in solid phase peptide synthesis with chlorotrimethylsilane in phenol (1993) (36)
The Mechanism of Trypsin-catalyzed Hydrolyses. The Cinnamoyl-trypsin Intermediate1-3 (1962) (35)
A kinetic study of interactions of (Rp)- and (Sp)-adenosine cyclic 3',5'-phosphorothioates with type II bovine cardiac muscle adenosine cyclic 3',5'-phosphate dependent protein kinase. (1982) (35)
Characterization of an amphiphilic helical structure in beta-endorphin through the design, synthesis, and study of model peptides. (1983) (34)
Use of site-directed mutagenesis to elucidate the role of arginine-166 in the catalytic mechanism of alkaline phosphatase. (1988) (33)
Biological and physical properties of a beta-endorphin analog containing only D-amino acids in the amphiphilic helical segment 13-31. (1984) (33)
Flavohemoglobin: a semisynthetic hydroxylase acting in the absence of reductase (1987) (32)
Evaluation of the oxime resin based segment synthesis-condensation approach using RNase T1 as a model synthetic target (1991) (32)
pH dependence of the nitrotyrosine-248 and arsanilazotyrosine-248 carboxypeptidase A catalyzed hydrolysis of O-(trans-p-chlorocinnamoyl)-L-beta-phenyllactate. (1976) (32)
Enzymic and nonenzymic reactions of cyclic sulfonate and sulfate esters (1970) (31)
NMR studies of the backbone protons and secondary structure of pentapeptide and heptapeptide substrates bound to bovine heart protein kinase. (1984) (29)
Introduction of guest peptides into Escherichia coli alkaline phosphatase. Excision and purification of a dynorphin analogue from an active chimeric protein. (1990) (29)
Synapsin I is a highly surface-active molecule. (1991) (29)
Peptides with affinity for membranes. (1987) (29)
Biological and physical properties of a model calcitonin containing a glutamate residue interrupting the hydrophobic face of the idealized amphiphilic alpha-helical region. (1987) (28)
Design principles in the construction of biologically active peptides (1987) (28)
Semisynthetic enzymes: characterization of isomeric flavopapains with widely different catalytic efficiencies (1984) (28)
A functional decaisoleucine-containing signal sequence. Construction by cassette mutagenesis. (1988) (27)
.alpha.-Chymotrypsin-catalyzed hydrolysis of lactones (1969) (26)
Kinetics and stereochemistry of nucleophilic reactions of phenacyl halide oximes (1972) (26)
STEREOCHEMISTRY OF ELECTRON DELOCALIZATION INVOLVING d-ORBITALS: α-SULFONYL CARBANIONS (1961) (26)
Active-site mutagenesis of E. coli alkaline phosphatase: replacement of serine-102 with nonnucleophilic amino acids (1992) (26)
Phosphorylation of histone catalyzed by a bovine brain protein kinase. (1976) (26)
Mechanism of lipid-protein interaction in lipoproteins. A synthetic peptide-lecithin vesicle model (1978) (25)
A method for probing the affinity of peptides for amphiphilic surfaces. (1985) (25)
The reactions of sultones with chymotrypsin. The pH dependence of sulfonylation and desulfonylation. (1968) (24)
Inactivation of phosphofructokinase by dialdehyde-ATP. (1979) (23)
Purification of recombinant pp60v-src protein tyrosine kinase and phosphorylation of peptides with different secondary structure preference. (1989) (23)
Stereospecificity in the oxidation of NADH by flavopapain (1980) (23)
Design and biological activity of analogs of growth hormone releasing factor with potential amphiphilic helical carboxyl termini. (1986) (23)
The Reaction of Triphenylphosphine with Alkali Metals in Tetrahydrofuran1 (1965) (23)
Binding of amphiphilic peptides to phospholipid/cholesterol unilamellar vesicles: a model for protein--cholesterol interaction. (1981) (22)
Mechanistic studies of carboxypeptidase Y. Kinetic detection of an acyl-enzyme intermediate in trimethylacetate esterase action. (1976) (22)
The Alkaline Hydrolysis of Catechol Cyclic Sulfate. An Extraordinary Rate Acceleration (1965) (22)
Structural characterization of beta-endorphin through the design, synthesis, and study of model peptides. (1982) (22)
Design of biologically active peptides with non-peptidic structural elements. Biological and physical properties of a synthetic analogue of beta-endorphin with unnatural amino acids in the region 6-12. (1986) (22)
Nucleophilic reactions of .alpha.-bromoacetophenone oxime. Preparation of anti-acetophenone oxime (1974) (21)
Protein inhibitors of crystal growth. (1989) (21)
Use of directed mutagenesis to probe the role of tyrosine 198 in the catalytic mechanism of carboxypeptidase A. (1987) (21)
Specificity of bovine heart protein kinase for the Δ‐stereoisomer of the metal—ATP complex (1979) (20)
Alkaline hydrolysis of aromatic esters of phosphoric acid (1967) (20)
Nitrobenzophenone oxime based resins for the solid-phase synthesis of protected peptide segments (1989) (20)
New reagents for the introduction of the thiomethyl group at sulfhydryl residues of proteins with concomitant spectrophotometric titration of the sulfhydryls: methyl 3-nitro-2-pyridyl disulfide and methyl 2-pyridyl disulfide. (1982) (20)
Development of helix-based vasoactive intestinal peptide analogues: identification of residues required for receptor interaction. (1988) (20)
Synthesis and characterization of a pancreatic trypsin inhibitor homologue and a model inhibitor. (1977) (20)
Photolysis of Thiobenzophenone in the Presence of Olefins: A Novel Reaction (1964) (19)
Peptide Segment Coupling Catalyzed by the Semisynthetic Enzyme Thiolsubtilisin. (1987) (19)
The structure and reactivity of cyclic esters. Ethylene sulfate and vinylene sulfate (1968) (19)
Stereochemical and kinetic studies on the action of the catalytic subunit of bovine cardiac muscle adenosine 3',5'-monophosphate dependent protein kinase using metal ion complexes of ATP beta S. (1980) (19)
The use of N-methylated peptides and depsipeptides to probe the binding of heptapeptide substrates to cAMP-dependent protein kinase. (1985) (19)
Semisynthetic enzymes: synthesis of a new flavopapain with high catalytic efficiency (1981) (19)
[LeuB24]insulin and [AlaB24]insulin: altered structures and cellular processing of B24-substituted insulin analogs. (1982) (19)
Effect of D2O on the carboxypeptidase-catalyzed hydrolysis of O-(trans-cinnamoyl)-L-beta-phenyllactate and N-(N-benzoylglycyl)-L-phenylalanine. (1969) (19)
The Mechanism of the Periodate Oxidation of Aromatic Systems. I. A Kinetic Study of the Periodate Oxidation of Hydroquinone and p-Methoxyphenol in Acidic Solution (1964) (18)
INHIBITION OF THE ESTERASE ACTION OF CARBOXYPEPTIDASE A. (1965) (18)
pPH dependence and competitive product inhibition of the carboxypeptidase A catalyzed hydrolysis of O-(trans-cinnamoyl)-L-beta-phenyllactate. (1969) (18)
Structure and enzymatic reactivity of an aromatic five-membered cyclic phosphate diester. Biological implications. (1971) (18)
Synthesis and structure determination of a thermally labile anti-alkyl aryl ketoxime (1972) (18)
The pH dependence of the pepsin-catalyzed hydrolysis of N-acetyl-L-phenylalanyl-L-3,5-dibromotyrosine. (1967) (18)
A Comparative Study of the Alkaline Hydrolysis of o-Hydroxy-α-toluenesulfonic Acid Sultone and Phenyl α-Toluenesulfonate (1966) (18)
Conformation of Leu-Arg-Arg-Ala-Ser-Leu-Gly bound in the active site of adenosine cyclic 3',5'-phosphate dependent protein kinase. (1987) (18)
Carboxypeptidase A catalyzed enolization of a ketonic substrate. A new stereochemical probe for an enzyme-bound nucleophile (1978) (18)
Ionic inhibition of catalytic phosphorylation of histone by bovine brain protein kinase. (1977) (18)
Development of a convenient spectrophotometric assay for peptide phosphorylation catalyzed by adenosine 3',5'-monophosphate dependent protein kinase (1980) (17)
DETERMINATION OF THE ABSOLUTE CONFIGURATION OF (+)-3-CARBOXY-2,2,5,5-TETRAMETHYL-1-PYRROLIDINYLOXY (1973) (17)
Identification of amino acid residues involved in substrate recognition by the catalytic subunit of bovine cyclic AMP dependent protein kinase: peptide-based affinity labels. (1988) (17)
Electrophysiological test of an amphiphilic β-structure in LHRH action (1986) (17)
Semisynthetic enzymes: design of flavin-dependent oxidoreductases. (1987) (17)
Anion Radicals Derived from the Metallic Reduction of Phenylbiphenylenephosphine1 (1966) (17)
Design of DNA-binding peptides: stabilization of .alpha.-helical structure by DNA (1985) (16)
The hydrolysis of O-hippuryglycolate catalyzed by carboxypeptidase A. Evidence for possible allosteric effects. (1965) (16)
The Use of Polymer-Bound Oximes for the Synthesis of Large Peptides Usable in Segment Condensation: Synthesis of a 44 Amino Acid Amphiphilic Peptide Model (I) of Apolipoprotein A-1. (1986) (16)
A study of the binding of two sulfonamides to carbonic anhydrase. (1973) (15)
Multiple forms of carboxypeptidase Y from Saccharomyces cerevisiae. Kinetic demonstration of effects of carbohydrate residues on the catalytic mechanism of a glycoenzyme. (1978) (15)
Multichannel resonance Raman experiments on carboxypeptidase a catalyzed ester hydrolysis under cryoenzymological conditions (1983) (15)
Inhibition in ester hydrolyses catalyzed by carboxypeptidase A (1967) (15)
Studies on the Esterase Action of Carboxypeptidase A. Kinetics of the Hydrolysis of Acetyl-L-mandelate (1964) (15)
Role of enzyme-peptide substrate backbone hydrogen bonding in determining protein kinase substrate specificities. (1987) (15)
Oxidation of dithiols by flavopapain (1981) (15)
A highly active thermophilic semisynthetic flavoenzyme (1988) (14)
Synthesis of the 60 amino acid homeo domain and smaller fragments of the Drosophila gene regulatory protein Antennapedia by a segment synthesis-condensation approach (1993) (14)
Diaryl Sulfone Anion Radicals1,2 (1966) (13)
The mechanism of the periodate oxidation of aromatic systems. II. The formation of an intermediate during the periodate oxidation of catechol (1965) (13)
Catalysis of N-alkyl-1,4-dihydronicotinamide oxidation by a flavopapain: rapid reaction in all catalytic steps (1985) (13)
The Chymotrypsin-Catalyzed Hydrolysis of Sultones (1967) (13)
Heterogeneity of glucagon receptors of rat hepatocytes: a synthetic peptide probe for the high affinity site. (1984) (13)
New semisynthetic flavoenzymes based on a tetrameric protein template, glyceraldehyde-3-phosphate dehydrogenase (1985) (13)
Reaction of a six-membered cyclic sulfonate ester, -(2-hydroxy-3,5-dinitrophenyl)ethanesulfonic acid sultone, with the active site of papain. (1973) (13)
Synthesis and characterization of a new semisynthetic enzyme, flavolysozyme (1986) (13)
The pH dependency of the zinc and cobalt carboxypeptidase catalyzed enolization of (R)-2-benzyl-3-(p-methoxybenzoyl)propionic acid (1983) (12)
Stereochemistry of phospho group transfer catalyzed by a mutant alkaline phosphatase. (1988) (12)
Studies on the Mechanism of Action and Stereochemical Behavior of Semisynthetic Model Enzymes (1980) (12)
Design and synthesis of the pseudo‐EF hand in calbindin D9K: Effect of amino acid substitutions in the α‐helical regions (1991) (12)
[12] Use of NMR and EPR to study cAMP-dependent protein kinase (1983) (12)
Design of an effective mechanism-based inactivator for a zinc protease. (1990) (12)
Studies on the solid-phase synthesis of bovine pancreatic trypsin inhibitor (Kunitz) and the characterization of the synthetic material. (1976) (11)
SULFUR DIOXIDE ELIMINATION IN THE RADIOLYTIC DECOMPOSITION OF SOLID DIARYL SULFONES (1966) (11)
Pepsin-catalyzed hydrolysis of bis-p-nitrophenyl sulfite and its inhibition by diphenyl sulfite at pH 2 (1969) (10)
Modification of the reactive sulfhydryl group in phosphofructokinase. (1976) (10)
[1] Active site titration of cysteine proteases☆ (1976) (10)
The oxidative cleavag of hydroquinone monosulfate ester. A model reaction for sulfate transfer. (1967) (10)
Enantiomeric specificity in the cyclohexa-amylose-catalysed hydrolysis of 3-carboxy-2,2,5,5-tetramethylpyrrolidin-1-oxy m-nitrophenyl ester (1971) (10)
Synthesis, purification, and characterization of the A and B diastereomers of gamma-32P-labeled adenosine 5'-O-(2-thiotriphosphate). (1980) (10)
Kinetics of the reactions of papain with substituted .alpha.-haloacetophenones (1973) (10)
Genetic engineering: Better enzymes by design (1985) (10)
Elucidation of stereochemistry of the carboxypeptidase A catalyzed enolization of 2-benzyl-3-p-methoxybenzoylpropionate, a ketone substrate (1979) (10)
A comparative analysis of single‐ and multiple‐residue substitutions in the alkaline phosphatase signal peptide (1990) (9)
A search for an intermediate in carboxypeptidase A catalyzed ester hydrolyses. (1970) (9)
Solvolyses of five-and six-membered sultones. (1967) (9)
On the question of transesterification in carboxypeptidase-A catalyzed hydrolyses. (1967) (9)
Autoxidation of ascorbic acid catalyzed by a semisynthetic enzyme (1990) (9)
Signal peptide subsegments are not always functionally interchangeable. M13 procoat hydrophobic core fails to transport alkaline phosphatase in Escherichia coli. (1989) (9)
INTERACTIONS OF SPIN‐LABELED SUBSTRATES WITH CHYMOTRYPSIN AND WITH CYCLOAMYLOSES (1975) (9)
Hydrolysis of esters of sulfur-containing acids in oxygen-18 enriched media (1968) (9)
RATIONAL DESIGN OF SYNTHETIC MODELS FOR LIPOPROTEINS * (1980) (9)
The binding of 4-hydroxy-3-nitrobenzenesulfonamide, a reporter group labeled inhibitor, to carbonic anhydrases. (1970) (9)
Model systems for sulfate transfer. Sulfur analogs of 1-phosphoimidazole (1968) (9)
The Reaction of Triphenylamine with Alkali Metals. Observations on the Mechanism (1966) (8)
Electron spin resonance spectra of the dibenzo[b,f]thiepin sulfoxide and thioxanthone sulfoxide anion radicals (1970) (8)
Electron spin resonance studies on the anion radical of dibenzo[b,f]thiepin (1967) (8)
The Pepsin-Catalyzed Hydrolysis of N-Acetyl-L-phenylalanyl-L-3,5-dibromotyrosine at pH 2 (1966) (8)
Evidence for a difference in mechanism between the reactions with carboxypeptidase A of the (-) and (+) - enantiomers of a thiolester substrate. (1975) (8)
Catalytic oxidation of dithiols by a semisynthetic enzyme (1986) (8)
Amphiphilic cationic peptides mediate cell adhesion to plastic surfaces (1985) (8)
NMR studies of the mechanism of action and regulation of protein kinase. (1985) (8)
Studies on the solid-phase synthesis of peptide fragments of apolipoproteins A-I and A-II (1978) (8)
Enantiomeric specificity in the chymotrypsin-catalyzed hydrolysis of 3-carboxy-2,2,5,5-tetramethylpyrrolidin-1-oxy p-nitrophenyl ester. (1972) (8)
Conjugative Effects of Sulfur in Several Aromatic Anion-Radicals (1963) (7)
Readily reversible nucleophilic reaction of imidazole with .beta.-(2-hydroxy-3,5-dinitrophenyl)ethanesulfonic acid sultone (1972) (7)
The binding of thiophenols to bovine carbonic anhydrase. (1971) (7)
Substituent effects in the alkaline hydrolyses of aromatic 5-membered cyclic sulfonates. Hydrolyses of 5-substituted 2-hydroxy-.alpha.-toluenesulfonic acid sultones (1970) (7)
Studies on the desulfonylation of 2-hydroxy-5-nitro-alpha-toluenesulfonyl-alpha-chymotrypsin. (1970) (7)
Selective Deprotection of the Nα‐tert‐Butyloxycarbonyl Group in Solid Phase Peptide Synthesis with Chlorotrimethylsilane and Phenol. (1994) (6)
Distinguishing among protein kinases by substrate specificities. (1987) (6)
Electron paramagnetic resonance spectra of thioxanthone and thioxanthone sulfone anion radicals (1967) (6)
Carboxypeptidase A catalysis of an .alpha.,.beta.-elimination reaction (1981) (6)
Additions and Corrections - A Study of the Binding of Two Sulfonamides to Carbonic Anhydrase (1973) (6)
Inhibition of the pepsin catalyzed hydrolysis of diphenyl sulfite by N-acetyl-L-phenyl-alanine, 3,5-dibromo-L-tryosine and N-acetyl-L-phenylalanyl-3,5-dibromo-L-tyrosine. (1968) (6)
Electron Spin Resonance Study of the Anion Radicals of Cis‐ and Trans‐Thianthrene‐5,10‐Dioxide (1963) (6)
pH dependence of the pepsin-catalyzed hydrolysis of bis-p-nitrophenyl sulfite (1971) (6)
Sulfite esterase activity of pepsin modified at active site carboxyl groups. (1974) (5)
pH dependence of the hydrolysis of O-acetyl-L-mandelate catalyzed by carboxypeptidase A. A critical examination. (1966) (5)
On the mechanism of the pepsin-catalyzed hydrolysis of sulfite esters. (1972) (5)
On the action of carboxypeptidase A on ester substrates in alkaline solution. (1972) (5)
Affinity of nonhomologous amphiphilic peptides toward a monoclonal antibody raised against apolipoprotein A‐I (1986) (5)
Design and characterization of peptides with amphiphilic beta-strand structures. (1985) (5)
Model studies on the hydrolysis of a cyclic ester showing high reactivity toward proteolytic enzymes biological implications (1971) (5)
Solvolysis of five-membered sultones. Methods for determining the intermediacy of carbanions in the hydrolysis of esters with labile .alpha.-protons (1969) (5)
Identification of a sugar-cane sterol antistiffness factor as stigmasterol. (1951) (5)
The x-ray structure of flavohemoglobin. A semisynthetic hydroxylase. (1988) (5)
Nucleophilic reactions of sulfite esters in aqueous media (1974) (5)
The reaction of 4-nitrocatechol cyclic sulfate with alpha-chymotrypsin. (1969) (4)
Inactivation of the catalytic subunit of bovine cAMP‐dependent protein kinase by a peptide‐based affinity inactivator (1990) (4)
Preparation of Flavopapain and Other Semisynthetic Enzymes (1987) (4)
The 1984 nobel prize in chemistry. (1984) (4)
The esterase activity of bovine erythrocyte carbonic anhydrase. Rapid enzyme-catalysed hydrolysis of 2-hydroxy-5-nitro-α-toluenesulphonic acid sultone (1966) (4)
Reaction of p-nitrophenyl trimethylacetate with yeast carboxypeptidase. Evidence for an acyl-enzyme intermediate. (1974) (4)
The reaction of a cyclic sulfonate ester with the sulfhydryl proteolytic enzyme papain (1971) (4)
Transformation of 25-Hydroxycholesterol by Rhizoctonia muneratii (1982) (4)
Hydrolysis and methanolysis of cyclic sulfate and sulfonate esters in strongly basic media. Correlations of rate data with H- and HM (1972) (4)
Studies of peptide conformation in the design of peptide agonists. (1987) (4)
Design and construction of biologically active peptides, including enzymes (1984) (4)
Studies on the Anion Radicals of the Thianthrene Oxides1,2 (1965) (4)
Letter: Detection of covalent intermediates by nucleophile trapping in the hydrolysis of phenyl tetrahydrofurfuryl sulfite catalyzed by pepsin. (1976) (4)
Reactions of Sulfonate and Sulfate Esters (1977) (3)
CuII carboxypeptidase A-catalysed hydrolysis of S-(trans-cinnamoyl)-L-α-mercapto-β-phenylpropionate (1976) (3)
Use of acetylenic substrates in enzyme chemistry. Reaction of the active site of .alpha.-chymotrypsin with N-phenylpropioloylimidazole (1969) (3)
Alcoholysis of Esters with Aluminum Alcoholates1 (1956) (3)
A "Reverse burst" active site titration procedure for human carbonic anhydrase B. (1975) (3)
CATALYTIC VERSATILITY OF ANGIOTENSIN CONVERTING ENZYME: CATALYSIS OF AN α,β-ELIMINATION REACTION (1985) (3)
STUDIES ON THE SOLID-PHASE SYNTHESIS OF BOVINE PANCREATIC TRYPSIN INHIBITOR (KUNITZ) AND THE CHARACTERIZATION OF THE SYNTHETIC MATERIAL (1976) (3)
Carboxypeptidase A catalyzed .alpha.,.beta.-elimination reactions: rapid catalysis of .alpha.,.beta.-elimination of hydrogen chloride from .beta.-chloro ketone substrates (1986) (3)
The intramolecular nucleophilic reaction of a phenolic hydroxyl group at the active site of papain. (1972) (3)
Design of DNA-Binding Peptides: Stabilization of α-Helical Structure by DNA (überwiegend α-helikale Struktur des Peptids (Ia) in Gegenwart von DNS. (1986) (3)
SYNTHESES OF 3-NITRO-2-PYRIDINESULFENATES (1981) (3)
Synthesis and characterization of covalent flavin–papain complexes with sulphur in the sulphide and sulphone oxidation states (1978) (3)
The molecular structures of five- and six-membered cyclic sulphonates (1967) (3)
The synthesis of two strongly electron deficient flavin analogs (1987) (3)
Studies on the desulfonylation of 2-hydroxy-3,5-dinitro-alpha-toluenesulfonyl-alpha-chymotrypsin. (1975) (3)
REACTION OF A SIX-MEMBERED CYCLIC SULFONATE ESTER, BETA-(2-HYDROXY-3,5-DINITRO-PHENYL)ETHANE SULFONIC ACID SULTONE WITH THE ACTIVE SITE OF PAPAIN (1973) (3)
A COMPARISON OF THE ACYL-ENZYME INTERMEDIATES, CINNAMOYL-TRYPSIN AND CINNAMOYL-α-CHYMOTRYPSIN1 (1961) (3)
The Design of Peptides and Proteins Ranging from Hormones to Enzymes (1988) (3)
Isolation of Hyaluronic Acid by means of Buffered Trichloroacetic Acid Solutions (1952) (3)
Design and Construction of Biologically Active Peptides and Proteins Including Enzymes (1988) (3)
Catalytic versatility of angiotensin converting enzyme: catalysis of an .alpha.,.beta.-elimination reaction (1984) (3)
Guide for Studies on Structure and Function Employing Synthetic Polypeptides (1989) (2)
Nucleophilic reactivities toward substituted aryl trimethylacetates: conflicting steric effects of ground-state activation and transition-state crowding (1977) (2)
Active site titration of cysteine proteases. (1976) (2)
Opioid receptor selectivity of peptide models of beta-endorphin. (1989) (2)
Reaction of a mixed anhydride with aqueous hydroxylamine. A model for the trapping by added nucleophiles of anhydride intermediates in carboxypeptidase A action (1978) (2)
NMR studies of the mechanism of cyclic AMP-dependent protein kinase. (1984) (2)
Organic Chemical Models for Proteinase Inhibitors (1974) (2)
Preparation of new derivatives of diethylstilbestrol and hexestrol by the Claisen rearrangement. (1946) (2)
Studies on carboxypeptidase A. (1974) (2)
Specificity of bovine heart protein kinase for the delta-stereoisomer of the metal--ATP complex. (1979) (2)
Detection by low temperature spectrophotometry of a mixed anhydride intermediate in the carboxylate ion-catalysed hydrolysis of a sulphite ester (1979) (2)
Hydrolysis of 1-benzyl-3-bromoacetylpyridinium bromide. Evidence for neighboring group participation (1977) (2)
Preparation of New Derivatives of Diethylstilbestrol and Hexestrol. II. Extension of the Claisen Rearrangement (1948) (2)
Affinity chromatographic purification of papain. (1979) (2)
3-NITRO-2-PYRINEDINESULFENYL GROUP FOR PROTECTION AND ACTIVATION OF THE THIOL FUNCTION OF CYSTEINE (1981) (1)
The Preparation of Isomeric Cholesteryl Malonic Acids. II. Isolation of i-Cholesterylmalonic Acid (1947) (1)
Polymer-supported acidolysis of protecting groups used in the synthesis of large peptides (1991) (1)
Use of NMR and EPR to study cAMP-dependent protein kinase. (1983) (1)
Design and synthesis of the pseudo-EF hand in calbindin D9K: effect of amino acid substitutions in the alpha-helical regions. (1991) (1)
Synthesis and characterization of a metal-binding peptide fragment of human carbonic anhydrase B (1978) (1)
Inhibition of Trypsin by Cholesteryl Malonic Acids and by i-Cholesteryl Acetic Acid (1950) (1)
5 – The Design and Construction of Biologically Active Peptides, Including Hormones (1973) (1)
Effect of External and Intramolecular Nucleophiles on Nature of Products of Carboxypeptidase A-Catalyzed Hydrolysis of Esters. Attempted Trapping of Acyl-Enzyme Intermediate (1978) (1)
Reaction of the active site of papain with a "reporter" group labeled phenacyl halide. (1970) (1)
Better enzymes by design. (1985) (1)
The design of new enzyme active sites for the catalysis of specific chemical reactions. (1985) (1)
Semisynthetic Enzymes a (1984) (1)
The Design of Peptides and Proteins a (1986) (1)
Introduction to electron spin resonance (Assenheim, H. M.) (1968) (1)
STUDIES ON THE DESULFONYLATION OF 2-HYDROXY-3,5-DINITRO-ALPHA-TOLUENESULFONYL-ALPHA-CHYMOTRYPSIN (1975) (1)
Chlorotrimethylsilane-phenol as a selective deprotection reagent for the tert-butyloxycarbonyl group (1988) (1)
Aryl alpha-haloalkyl ketoximes as enzyme modifying agents. The reaction of alpha-haloacetophenone oximes with the active site of papain. (1974) (1)
.alpha. Effect and ring-induced acceleration of hydrolysis at a sulfinyl center. Buffer and nucleophile effects in the hydrolysis of diphenyl sulfite (1976) (1)
Electrophysiological test of an amphiphilic beta-structure in LHRH action. (1986) (1)
Aryl α-haloalkyl ketoximes as enzyme modifying agents. The reaction of α-haloacetophenone oximes with the active site of papain (1974) (1)
Preparation of New Derivatives of Synthetic Estrogens via the Claisen Rearrangement1 (1960) (1)
[Problem of competitive inhibition in hyaluronic acid-hyaluronidase system]. (1955) (1)
The Preparation of Isomeric Cholesteryl Malonic Acids (1945) (1)
Anhydride intermediates in catalysis by pepsin: is pepsin an enzyme with two active sites? (1977) (1)
Semisynthesis andbiological activity ofporcine (LeuB24)insulin and (LeuB25)insulin (solid-phase peptide synthesis/desoctapeptide insulin/insulin analog/insulin antagonist/rat adipocytes) (1980) (0)
Site-Directed Mutagenesis of Alkaline Phosphatase (1988) (0)
Synthetic peptite and a pharmaceutical composition containing then (1986) (0)
Effect of cellulase on the nature of the fermentation process. (1991) (0)
Traegergebundene peptides acth-peptide intermediates and their production (1976) (0)
Nitrobenzophenone Oxime Based Resins for the Solid-Phase Synthesis of Protected Peptide Segments. (1990) (0)
A method for preparing peptides having influence on the function of the pituitary gland in humans and other animals (1986) (0)
NUCLEOPHILIC REACTIVITIES TOWARD SUBSTITUTED ARYL TRIMETHYLACETATES- CONFLICTING STERIC EFFECTS OF GROUND-STATE ACTIVATION AND TRANSITION-STATE CROWDING (1978) (0)
Transport of E. coli alkaline phosphatase containing a mutant signal sequence (1985) (0)
Chlorotrimethylsilane-Phenol, A Mild Deprotection Reagent for the Boc-Group, (1992) (0)
Catalytic Oxidation of Dithiols by a Semisynthetic Enzyme. (1986) (0)
The reactions of nonspecific ester substrates with delta-chymotrypsin. (1971) (0)
The Preparation of Isomeric Cholesterylmalonic Acids. III. Rearrangement of i-Cholesterylacetic Acid and i-Cholesteryl malonamide (1949) (0)
The Synthesis of Two Strongly Electron Deficient Flavin Analogs. (1987) (0)
Synthetic peptides: Approaches to biological problems : proceedings of a Glaxo-UCLA colloquium held at Park City, Utah, January 31-February 4, 1988 (1989) (0)
Titration of the active sites in α-chymotrypsin solutions with 5-nitro-1,2-benzoxathiole 2,2-dioxide (1968) (0)
Synthesis and Characterization of a New Semisynthetic Enzyme, Flavolysozyme. (1986) (0)
[Thin layer chromatography of thalidomide and its hydrolysis products]. (1970) (0)
Base-Catalyzed Rearrangement of Allylphenols and Haloallylphenols1 (1962) (0)
EFFECT OF D 20 ON THE CARBOXYPEPTIDASE-CATALYZED HYDROLYSIS OF O-( TRANS-CINNAMOYL )-L-#-PHENYLLACTA TE AND N-( N-BENZO YLGLYCYL )-L-PHENYLALANINE (0)
PROCESS FOR PREPARING 25-HYDROXYCHOLESTEROL 76 Inventor : (0)
CARBOXYPEPTIDASE A CATALYSIS OF AN α,β-ELIMINATION REACTION (1981) (0)
Notes - Preparation of a Crystalline 22-Bromo-24,24-diphenylchol-23-ene (1956) (0)
Attempt to prepare anti-tyrosine decarboxylase. (1952) (0)
GENERAL DISCUSSION (1980) (0)
Additions and Corrections - pH Dependence of the Nitrotyrosine-248 and Arsanilazotyrosine-248 Carboxypeptidase A Catalyzed Hydrolysis of O-(trans-p-Chlorocinnamoyl) - L-β-phenyllactate (1976) (0)
Studies on the mechanism of action of phosphoryl transferase enzymes. (1987) (0)
THE PH DEPENDENCY OF THE ZINC AND COBALT CARBOXYPEPTIDASE CATALYZED ENOLIZATION OF (R)‐2‐BENZYL‐3‐(P‐METHOXYBENZOYL)PROPIONIC ACID (1983) (0)
b-Lactones as Reagents in Protein Chemsitry. The Inactivation of Pepsin with b-Propiolactone (1976) (0)
Preparation and Properties of Semisynthetic Flavoenzymes (1986) (0)
THE CHEMICAL MODIFICATION OF ENZY"MATIC SPECIFICITY (1985) (0)
Transformation of25-Hydroxycholesterol byRhizoctonia muneratii (1982) (0)
Stereochemical studies on the decomposition of an α-sulfonyl perester (1965) (0)
Biologically active thiocarbamyl derivatives of insulin. (1953) (0)
The carboxypeptidase Y-catalysed hydrolysis of aryl trimethylacetates: the nature of the deacylation reaction of trimethylacetylcarboxypeptidase Y (1975) (0)
Peptide-based photoaffinity label of the catalytic subunit of the cyclic AMP-dependent protein kinase (1986) (0)
Additions and Corrections - Studies on the Esterase Action of Carboxypeptidase A. Kinetics of the Hydrolysis of Acetyl-L-mandelate (1965) (0)
Additions and Corrections - Preparation of a Crystalline 22-Bromo-24,24-diphenylchol-23-ene (1956) (0)
Construction and biological properties of designed peptides (1987) (0)
Carboxypeptidase A Catalyzed α,β-Elimination Reactions: Rapid Catalysis of α,β-Elimination of Hydrogen Chloride from β-Chloro Ketone Substrates. (1986) (0)
Synthetic peptide and the pharmaceutical agent containing the peptide (1986) (0)
SULFITE ESTERASE ACTIVITY OF PEPSIN MODIFIED AT ACTIVE SITE CARBOXYL GROUPS (1974) (0)
β‐LACTONES AS REAGENTS IN PROTEIN CHEMISTRY. THE INACTIVATION OF PEPSIN WITH β‐PROPIOLACTONE (1976) (0)
Secondary structures ofproteins andpeptides inamphiphilic environments (AReview) (amphiphilic surfaces/apolipoproteins/peptide hormones/peptide secondary structure/peptide (1983) (0)
KINETICS OF THE REACTIONS OF PAPAIN WITH SUBSTITUTED ALPHA-HALOACETOPHENONES (1973) (0)
Peptide and Protein Synthesis by Segment Synthesis-Condensation (1989) (0)

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