Francesco Minisci
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Francesco Miniscichemistry Degrees
Chemistry
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Organic Chemistry
#713
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Chemistry
Francesco Minisci's Degrees
- PhD Chemistry University of Salerno
- Masters Chemistry University of Salerno
- Bachelors Chemistry University of Salerno
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(Suggest an Edit or Addition)Francesco Minisci's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- ELECTRON-TRANSFER PROCESSES: PEROXYDISULFATE, A USEFUL AND VERSATILE REAGENT IN ORGANIC CHEMISTRY (2002) (323)
- Recent developments of free-radical substitutions of heteroaromatic bases (1989) (301)
- Nucleophilic character of alkyl radicals—VI : A new convenient selective alkylation of heteroaromatic bases (1971) (243)
- Free-radical additions to olefins in the presence of redox systems (1975) (217)
- Substitutions by nucleophilic free radicals: A new general reaction of heteroaromatic bases (1990) (184)
- Homolytic acylation of protonated pyridines and pyrazines with .alpha.-keto acids: the problem of monoacylation (1991) (160)
- Diazo Chemistry I. Aromatic and Heteroaromatic Compounds (1995) (145)
- Fine Chemicals from Lignosulfonates. 1. Synthesis of Vanillin by Oxidation of Lignosulfonates (1999) (145)
- Efficient Mn–Cu and Mn–Co–TEMPO-catalysed oxidation of alcohols into aldehydes and ketones by oxygen under mild conditions (2001) (139)
- Novel Applications of Free-Radical Reactions in Preparative Organic Chemistry (2002) (139)
- Recent aspects of homolytic aromatic substitutions. (1976) (118)
- Mechanisms of the Aerobic Oxidation of Alcohols to Aldehydes and Ketones, Catalysed under Mild Conditions by Persistent and Non‐Persistent Nitroxyl Radicals and Transition Metal Salts − Polar, Enthalpic, and Captodative Effects (2004) (116)
- Kharasch and Metalloporphyrin Catalysis in the Functionalization of Alkanes, Alkenes, and Alkylbenzenes by t-BuOOH. Free Radical Mechanisms, Solvent Effect, and Relationship with the Gif Reaction (1995) (105)
- Polar effects in free-radical reactions. Rate constants in phenylation and new methods of selective alkylation of heteroaromatic bases. (1986) (90)
- Aerobic oxidation of N-alkylamides catalyzed by N-hydroxyphthalimide under mild conditions. Polar and enthalpic effects. (2002) (84)
- Nucleophilic character of alkyl radicals. 18. Absolute rate constants for the addition of primary alkyl radicals to conjugated olefins and 1,4-benzoquinone (1979) (84)
- New Methods of Free-Radical Perfluoroalkylation of Aromatics and Alkenes. Absolute Rate Constants and Partial Rate Factors for the Homolytic Aromatic Substitution by n-Perfluorobutyl Radical. (1997) (82)
- A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions. Polar and enthalpic effects. (2002) (78)
- Transition metal salts catalysis in the aerobic oxidation of organic compounds: Thermochemical and kinetic aspects and new synthetic developments in the presence of N-hydroxy-derivative catalysts (2003) (78)
- Nucleophilic character of the alkyl radicals. 16. Absolute rate constants and the reactivity-selectivity relationship in the homolytic aromatic alkylation (1977) (78)
- Polar effects in free-radical reactions. New synthetic developments in the functionalization of heteroaromatic bases by nucleophilic radicals (1985) (75)
- Nucleophilic character of alkyl radicals—V: Selective homolytic α-oxyalkylation of heteroaromatic bases☆ (1971) (74)
- Free Radicals in Biology and Environment (1997) (74)
- Polar effects in free-radical reactions. Solvent and isotope effects and effects of base catalysis on the regio- and chemoselectivity of the substitution of protonated heteroaromatic bases by nucleophilic carbon-centered radicals (1987) (69)
- Ingold−Fischer “Persistent Radical Effect”, Solvent Effect, and Metal Salt Oxidation of Carbon-Centered Radicals in the Synthesis of Mixed Peroxides from tert-Butyl Hydroperoxide (1997) (66)
- Homolytic alkylation of protonated heteroaromatic bases by alkyl iodides, hydrogen peroxide, and dimethyl sulfoxide (1989) (65)
- Nucleophilic character of alkyl radicals—II (1970) (64)
- Free radicals in synthesis and biology (1989) (63)
- Nucleophilic character of alkyl radicals: new syntheses by alkyl radicals generated in redox processes (1968) (59)
- Radical versus “Oxenoid” Oxygen Insertion Mechanism in the Oxidation of Alkanes and Alcohols by Aromatic Peracids. New Synthetic Developments (1996) (55)
- A novel and mild source of carbon-centered radicals by iodosobenzene diacetate (IBDA) and sodium azide from alcohols, ethers, aldehydes, amides and alkyl iodides (1993) (52)
- Nucleophilic character of alkyl radicals—VII : Substituent effects on the homolytic alkylation of protonated heteroaromatic bases with methyl, primary, secondary and tertiary alkyl radicals (1972) (51)
- Advances in Homolytic Substitution of Heteroaromatic Compounds (1974) (49)
- Homolytic acylation of protonated pyridine and pyrazine derivatives (1972) (47)
- Mechanism of the Gif-Barton type alkane functionalization by halide and pseudohalide ions (1994) (47)
- A general, selective, and convenient procedure of homolytic formylation of heteroaromatic bases (1986) (46)
- Solvent and Temperature Effects in the Free Radical Aerobic Oxidation of Alkyl and Acyl Aromatics Catalysed by Transition Metal Salts and N-Hydroxyphthalimide: New Processes for the Synthesis of p-Hydroxybenzoic Acid, Diphenols, and Dienes for Liquid Crystals and Cross-Linked Polymers (2004) (46)
- Polar effects in free radical reactions. Homolytic aromatic amination by the amino radical cation, •+NH3: reactivity and selectivity (1984) (44)
- Polar effects in free radical reactions. Induced decompositions of peroxo compounds in the substitution of heteroaromatic bases by nucleophilic radicals (1984) (43)
- Polar effects in reactions of carbon-centered radicals with diazonium salts: free-radical diazo coupling (1992) (43)
- Molecule-Induced Homolysis versus “Concerted Oxenoid Oxygen Insertion” in the Oxidation of Organic Compounds by Dimethyldioxirane (1998) (40)
- Molecule-induced homolysis of N-hydroxyphthalimide (NHPI) by peracids and dioxirane. A new, simple, selective aerobic radical epoxidation of alkenes (2006) (40)
- Oxidation of organic sulfides by Br(2) and H(2)O(2). Electrophilic and free-radical processes. (2001) (40)
- Polar effects in free-radical reactions. Selectivity and reversibility in the homolytic benzylation of protonated heteroaromatic bases (1986) (39)
- Influence of the electrophilic character on the reactivity of free radicals in solution reactivity of alkoxy, hydroxy, alkyl and azido radicals in presence of olefins (1962) (39)
- High Selectivity in the Oxidation of Mandelic Acid Derivatives and in O-Methylation of Protocatechualdehyde: New Processes for Synthesis of Vanillin, iso-Vanillin, and Heliotropin (2000) (39)
- A new general method of homolytic alkylation of protonated heteroaromatic bases by carboxylic acids and iodosobenzene diacetate (1989) (38)
- Polar effects in free-radical reactions. Homolytic heteroaromatic substitutions by alkyl bromides (1993) (37)
- Facile and convenient syntheses of quinones from phenols (1989) (36)
- Free-radicals in the oxidation and halogenation of alkanes by dimethyldioxirane: an oxygen rebound mechanism (1995) (34)
- Nucleophilic character of alkyl radicals—XIII: Absolute rate constants for the addition of alkyl radicals to acrylonitrile and methyl acrylate (1977) (34)
- A novel, selective free-radical carbamoylation of heteroaromatic bases by Ce(IV) oxidation of formamide, catalysed by N-hydroxyphthalimide (2002) (33)
- Steric, polar, and resonance effects in reactivity and regioselectivity of aryl radical addition to .alpha.,.beta.-unsaturated carbonyl compounds (1982) (32)
- New general and convenient sources of alkyl radicals, useful for selective syntheses (1987) (32)
- Nucleophilic character of alkyl radicals—XII : Mechanism and new syntheses in the oxidation of alcohols by peroxydisulphate (1976) (30)
- Selective functionalisation of hydrocarbons by nitric acid and aerobic oxidation catalysed by N-hydroxyphthalimide and iodine under mild conditions (2003) (30)
- A novel radical reaction of alkyl xantates useful for the selective substitution of heteroaromatic bases (1992) (30)
- Nucleophilic character of acyl radicals: a new selective type of aromatic acylation (1969) (29)
- Reactivity of Carbamoyl Radicals. A New, General, Convenient Free-Radical Synthesis of Isocyanates from Monoamides of Oxalic Acid (1995) (29)
- Polar effects in free-radical reactions. Carbamoylation and .alpha.-N-amidoalkylation of heteroaromatic bases by amides and hydroxylamine-O-sulfonic acid (1984) (28)
- Polar effects in free-radical reactions. A novel homolytic acylation of heteroaromatic bases by aerobic oxidation of aldehydes, catalysed by N-hydroxyphthalimide and Co salts (2003) (27)
- A new selective free radical synthesis of aromatic aldehydes by aerobic oxidation of tertiary benzylamines catalysed by N-hydroxyimides and Co(II) under mild conditions. Polar and enthalpic effects (2002) (26)
- Free-radical diazocoupling. A new general reaction of diazonium salts (1982) (26)
- Nucleophilic character of acyl radicals. Substituent effects on the homolytic acylation of protonated heteroaromatic bases (1972) (26)
- Nucleophilic character of acyl radicals. Homolytic acylation of quinoxaline (1970) (25)
- Homolytic amidation of heteroaromatic bases: a new selective process (1971) (25)
- A new selective type of aromatic substitution: homolytic amidation (1970) (25)
- Homolytic alkylation of heteroaromatic bases: the problem of monoalkylation (1990) (25)
- Intra- and intermolecular free radical reactions of alcohols and olefines with peroxydisulphate. New homolytic aromatic alkylations. (1978) (24)
- A Convenient Nitroxyl Radical Catalyst for the Selective Oxidation of Primary and Secondary Alcohols to Aldehydes and Ketones by O2 and H2O2 under Mild Conditions (2003) (24)
- New Selective Metal-Free Oxidations of Primary Alcohols by HNO3 or HNO3 and O2, Catalyzed by Br2 (2004) (24)
- NUCLEOPHILIC CHARACTER OF THE ALKYL RADICALS. 19. 1A ABSOLUTE RATE CONSTANTS IN THE HOMOLYTIC ALKYLATION OF PROTONATED HETEROAROMATIC BASES BY N-BUTYL AND TERT-BUTYL RADICALS (1980) (24)
- Nucleophilic character of carbon free radicals. A new convenient, selective carboxylation of heteroaromatic bases. (1973) (23)
- Photoinitiated electron transfer-substitution reaction of diphenyl ketyl with protonated 4-cyanopyridine (1975) (22)
- A Facile, Convenient and Selective Homolytic Carbamolylation of Heteroaromatic Bases (1993) (21)
- A novel substitution reaction by photoinduced electron-transfer between pyridine derivatives and alkyltin compounds (1992) (21)
- A new modified montanari oxidation process by means of chlorine dissolved in the reaction solvent as oxidant and TEMPO as catalyst: Oxidation of 3-S-quinuclidinol to 3-quinuclidinone (2002) (21)
- Oxidation of alkyl and aryl iodides, phenylacetaldehyde and alkenes by dimethyldioxirane. Reaction products and mechanism. (1995) (21)
- New syntheses of mixed peroxides under Gif–Barton oxidation of alkylbenzenes, conjugated alkenes and alkanes; a free-radical mechanism (1994) (21)
- Nucleophilic character of alkyl radicals generated in redox processes—III (1970) (20)
- Metal ion initiated halogenation reaction of N-haloamines (1970) (20)
- Electron-transfer processes: oxidation of naphthalene and p-cymene by peroxydisulfate (1979) (20)
- A novel convenient and selective alkoxycarbonylation of heteroaromatic bases by oxalic acid monoesters (1992) (19)
- A new direct homolytic iodination reaction of alkanes by perfluoroalkyl iodides (1997) (19)
- Homolytic acylation of benzothiazole. A diagnostic criterion for the presence of acyl radicals (1971) (19)
- Steric and polar effects in free-radical reactions. - An unusual type of azocoupling by free radical decomposition of diazonium salts (1980) (19)
- Enhanced nucleophilic character of the 1-adamantyl radical in chlorine atom abstraction and in addition to electron-poor alkenes and to protonated heteroaromatic bases. Absolute rate constants and relationship with the Gif reaction (1997) (19)
- Electrophilic Aromatic Alkylation by Hydroperoxides. Competition between Ionic and Radical Mechanisms with Phenols. (1999) (19)
- New types of amination of olefinic, acetylenic and aromatic compounds by hydroxylamine-o-sulfonic acid and hydroxylamines/ metal salts redox systems. (1965) (18)
- Enthalpic and polar effects in the reactions of perfluoroalkyl radicals: New selective synthetic developments with alkenes and heteroaromatic bases (2004) (18)
- Regio- and chemo-selectivity of adamantane halogenation by Gif-Barton and metalloporphyrin catalysis and by classical free-radical reactions (1994) (18)
- TRAPPING OF FREE-RADICALS IN THE OXIDATION OF ETHERS, ALDEHYDES AND ALKANES BY DIMETHYLDIOXIRANE (1995) (17)
- New free-radical syntheses under Gif-Barton oxidation conditions (1994) (17)
- A new, highly selective, type of radical chlorination (1967) (17)
- Nucleophilic character of alkyl radicals—VIII : Kinetics and mechanism of induced decomposition of decanoyl peroxide in the homolytic alkylation of protonated quinoline (1972) (17)
- Redox-chain decomposition of hydroxylamine-O-sulphonic acid. A novel general source of nucleophilic radicals for the functionalization of heteroaromatic bases (1983) (17)
- Free-radical mechanisms in the oxidation and halogenation of alkanes, alkenes and alkylbenzenes by t-BuOOH under Gif-Barton catalysis (1996) (17)
- Electron-transfer processes: metal salt catalysed oxidation of olefins by peroxydisulphate (1983) (16)
- A new general method of homolytic alkylation of protonated heteroaromatic bases (1985) (16)
- New free-radical halogenations of alkanes, catalysed by N-hydroxyphthalimide. Polar and enthalpic effects on the chemo- and regioselectivity (2004) (16)
- Reactivity of carbohydrate radicals derived from iodo sugars and dibenzoyl peroxide. Homolytic heteroaromatic and aromatic substitution, reduction, and oxidation (1993) (15)
- A New Selective Method for the Homolytic Alkylation and Carboxylation of Quinones by Monoesters of Oxalic Acid (1992) (15)
- Nucleophilic character of alkyl radicals—IX : The benzyl radical (1973) (15)
- ‘Oxenoid’ oxygen insertion vs. a radical mechanism in the oxidation of alkanes and alcohols: the case of aromatic peracids (1996) (14)
- Selective aromatic chlorination and bromination with N-halogeno amines in acidic solution (1989) (14)
- Redox catalysis in free-radical reactions: New, simple, convenient intramolecular homolytic aromatic substitutions (1995) (14)
- Highly Selective and Efficient Conversion of Alkyl Aryl and Alkyl Cyclopropyl Ketones to Aromatic and Cyclopropane Carboxylic Acids by Aerobic Catalytic Oxidation: A Free-radical Redox Chain Mechanism. (2002) (14)
- Polar effects in free-radical reactions. A new type of homolytic aromatic alkylation by silver catalyzed oxidation of acetone by peroxydisulphate in the presence of olefins. (1982) (13)
- A new convenient, highly selective free-radical hydroxymethylation of heteroaromatic bases by persulfate oxidation of ethylene glycol and glycerol, catalysed by AgNO3 (2004) (13)
- An electron spin resonance reinvestigation of dihydropyridyl radicals (1977) (13)
- Electronic configuration and nucleophilicity of carbon free radicals. α-Alkoxyalkyl, α-alkoxycarbonyl, and cycloalkyl radicals (1974) (13)
- Induced homolysis of dimethyldioxirane by alkanes and alkyl radicals in oxidation processes. The dramatic role of molecular oxygen and radical inhibitors (1995) (13)
- Silver-mediated oxidative decarboxylation of carboxylic acids by peroxocompounds new sources of carbon-centered radicals for heteroaromatic substitution (1985) (12)
- α-Hydroxyalkylation of heteroaromatic bases by alcohols and hydroxylamine-O-sulphonic acid (1985) (12)
- New syntheses by amino radicals from N-chloroamines in the presence of olefins and oxidation-reduction systems. (1964) (12)
- A new, highly selective, free-radical aerobic oxidation of silanes to silanols catalysed by N-hydroxyphthalimide under mild conditions. (2002) (12)
- Minisci Reaction: A Friedel-Crafts Type Process with Opposite Reactivity and Selectivity. Selective Homolytic Alkylation, Acylation, Carboxylation and Carbamoylation of Heterocyclic Aromatic Bases. (2008) (12)
- Intramolecular homolytic amination by N-chloroamines: New syntheses of indolines and tetrahydroquinolines. (1966) (12)
- A bromine-catalysed free-radical oxidation of acetamides from primary and secondary alkylamines by H2O2 (2001) (12)
- A Novel, Simple and Cheap Source of Alkyl Radicals from Alcohols, Useful for Heteroaromatic Substitution (1992) (12)
- Polar and steric effects in hydrogen abstraction by dialkylamine cation radicals (1968) (12)
- Polar effects in free-radical reactions: new selective alkylations of heteroaromatic bases by benzoylperoxide and olefins (1986) (11)
- Nucleophilic character of alkyl radicals—X : Polar and steric effects in the alkylation of 3-substituted pyridines by t-butyl radical (1974) (11)
- Homolytic amination of aromatic compounds by redox systems. Reactivity and orientation. (1965) (11)
- Nucleophilic character of alkyl radicals. Part 15. Selective homolytic alkylation of quinoxaline by N-chloro-amines; influence of medium acidity (1977) (11)
- Reactivity of carbamoyl radicals: the first general and convenient free-radical synthesis of isocyanates (1994) (11)
- New syntheses by amino radicals and oxygen. Conversion of olefins into α-aminoketones. (1964) (11)
- Polar effects in the homolytic methylation of pyrimidine: orientation and polysubstitution (1984) (11)
- A new, highly selective, type of aromatic substitution. Homolytic amination of phenolic ethers. (1965) (11)
- New, Simple and Selective Synthesis of Perfluoroalkylquinones by Perfluoroalkyl Radicals – Enthalpic and Polar Effects (2005) (10)
- Nucleophilic character of alkyl radicals generated in redox processes—I : Reactivity of the 5-(methoxycarbonyl)-pentyl radical towards conjugated olefins (1969) (10)
- Nucleophilic character of alkyl radicals. XIV. Homolytic δ‐aminoalkylation of protonated quinoxaline (1976) (9)
- New General Processes of Homolytic Alkylation of Heteroaromatic Bases by t-BuOOH or (t-BuO)2 and Alkyl Iodides. (1990) (9)
- Electron-transfer processes: New synthesis of γ-lactones by peroxydisulfate oxidation of isopropylbenzenes and aliphatic carboxylic acids (1980) (8)
- A new general method for selective homolytic alkylation of heteroaromatic bases (1976) (8)
- New Selective Oxidation Reactions by Nitroarenes in Basic Medium Involving Electron-Transfer Processes (2001) (8)
- Stereochemistry of reduction of cyclic ketones by alkali metals and by sodium dithionite. (1983) (8)
- Radical addition of protonated N-chloroamines to olefins (1966) (8)
- Chemistry of the amino radical ions. A new chain process of the protonated N-chloramines (1984) (8)
- Nucleophilic character of acyl radicals. Absolute rate constant for the acylation of protonated benzothiazole by pivaloyl radical (1977) (8)
- Free radical reactivity of nitriloxides. 1,3-addition. (1970) (7)
- Addition reaction of nitrile oxides on aromatic nitrosoderivatives. A novel synthesis of the benzimidazole ring (1963) (7)
- Reactivity of hydroxy and alkoxy radicals in presence of olefins and oxidation-reduction systems. Introduction of azido, chloro and acyloxy groups in allylic position and azido-chlorination of olefins (1963) (7)
- A FREE-RADICAL MECHANISM IN A NOVEL METALLOPORPHYRIN-CATALYZED OXIDATION OF PHENOLS BY T-BUOOH (1996) (7)
- Electron-transfer processes: oxidation of arylacetic acids by peroxydisulphate in acetic acid (1981) (7)
- Polar Effects in Free-Radical Reactions. The Paradox of Reduction of Alkyl Iodides and Reductive Alkylation of Alkenes by Strong Oxidants (t-BuOOH, Pb(OAc)4) (1999) (7)
- New free-radical chain processes involving substitution of vinyl and aryl chlorides by alkanes, alkenes, esters and ethers (1996) (6)
- Homolytic Acylation of Protonated Pyridines and Pyrazines with α‐ Keto Acids: The Problem of Monoacylation. (1991) (6)
- Polar and steric effects in the homolytic amination of alkylbenzenes and biphenyl (1974) (6)
- Hydroperoxides as pseudohalides: oxidation, oxidative alkylation, acylation and arylation of acrylonitrile (1995) (6)
- Homolytic δ-aminoalkylation of protonated quinoxaline by N-chloroamine (1976) (6)
- POLAR EFFECTS IN FREE RADICAL REACTIONS. HOMOLYTIC AROMATIC AMINATION BY THE AMINO RADICAL CATION, .CNTDOT.+NH3: REACTIVITY AND SELECTIVITY (1985) (6)
- A NEW PROCEDURE FOR THE SELECTIVE α-OXYALKYLATION OF HETEROAROMATIC BASES BY CYCLIC ETHERS AND HYDROGEN PEROXIDE (1988) (6)
- The chemistry of acyl radicals (1973) (5)
- Polar and Enthalpic Effects in Free‐Radical Reactions. Free‐Radical Diazo Coupling and Reactivity of Carbohydrate Radicals (1993) (5)
- A new selective free-radical synthesis of γ-lactone and β-scission of γ-phenylpropyl radical (1974) (5)
- Polar Effects in Free-Radical Reactions in Synthetic Chemistry (1984) (5)
- Polar effects in radical reactions: a new selective type of radical bromination (1967) (5)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS. PART 17. ABSOLUTE RATE CONSTANTS AND THE ALTERNATING EFFECT IN THE ADDITION OF ALKYL RADICALS TO STYRENE AND ACRYLIC MONOMERS (1978) (5)
- Selective Aerobic Radical Epoxidation of α-Olefins Catalyzed by N-Hydroxyphthalimide (2008) (4)
- A New Photochemical Method of Homolytic Alkylation of Heteroaromatic Bases by Alkyl Iodides and Iodosobenzene Diacetate. (1992) (4)
- Synthetic and Mechanistic Organic Chemistry (2013) (4)
- The Invention of Radical Chain Reactions of Value in Organic Synthesis (1990) (3)
- Steric influence on the reactivity of amino radical ions. New type of benzylic chlorination (1966) (3)
- Synthetic Applications of the Polar Effects of the Substituents in Free-Radical Reactions (1986) (3)
- Electron-transfer process with pyridinium, quinolinium, and pyrazinium salts; an electron spin resonance study (1977) (3)
- Oxidation of Organic Sulfides by Br2 and H2O2. Electrophilic and Free-Radical Processes. (2010) (2)
- ELECTRON-TRANSFER PROCESSES : MECHANISMS OF OXIDATION OF ETHERS AND ESTERSBY SILVER-CATALYZED PEROXYDISULPHATE (1993) (2)
- Highly Selective and Efficient Conversion of Alkyl Aryl and Alkyl Cyclopropyl Ketones to Aromatic and Cyclopropane Carboxylic Acids by Aerobic Catalytic Oxidation: A Free‐Radical Redox Chain Mechanism. (2002) (2)
- Reactivity of Carbamoyl Radicals. A New, General, Convenient Free- Radical Synthesis of Isocyanates from Monoamides of Oxalic Acid. (1996) (2)
- Alternating addition of carbon-centered radicals to unsaturated systems. Novel homolytic aromatic substitutions (1996) (2)
- ELECTRON-TRANSFER PROCESSES: OXIDATION OF ARYLACETIC ACIDS BY PEROXYDISULFATE IN ACETIC ACID (1981) (2)
- POLAR EFFECTS IN FREE-RADICAL REACTIONS. CARBAMOYLATION AND α-N-AMIDOALKYLATION OF HETEROAROMATIC BASES BY AMIDES AND HYDROXYLAMINE-O-SULFONIC ACID (1985) (2)
- Catalytic Processes of Oxidation by Hydrogen Peroxide in the Presence of Br2 or HBr. Mechanism and Synthetic Applications. (1998) (2)
- NEW SYNTHESES OF POLYFUNCTIONAL LONG-CHAIN COMPOUNDS BY ALTERNATING FREE RADICAL ADDITIONS TO CONJUGATED OLEFINS (1969) (2)
- CATECHOL AND HYDROQUINONE FROM CATALYTIC HYDROXYLATION OF PHENOL BY HYDROGEN PEROXIDE (1977) (2)
- New Methods of Free‐Radical Perfluoroalkylation of Aromatics and Alkenes. Absolute Rate Constants and Partial Rate Factors for the Homolytic Aromatic Substitution by n‐Perfluorobutyl Radical. (1998) (1)
- A General, Selective and Convenient Procedure of Homolytic Formylation of Heteroaromatic Bases. (1986) (1)
- Transition Metal Salts Catalysis in the Aerobic Oxidation of Organic Compounds: Thermochemical and Kinetic Aspects and New Synthetic Developments in the Presence of N‐Hydroxy Derivative Catalysts (2004) (1)
- BASE CATALYSIS AND SOLVENT EFFECT IN THE SYNTHESIS OF ASPARTAME (1985) (1)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS. XII. MECHANISM AND NEW SYNTHESES IN N THE OXIDATION OF ALCOHOLS BY PEROXYDISULFATE (1977) (1)
- Redox Catalysis in Free-Radical Reactions: New, Simple, Convenient Intramolecular Homolytic Aromatic Substitutions. (1995) (1)
- Additions and Corrections - Polar Effects in Free-Radical Reactions. Selectivity and Reversibility in the Homolytic Benzylation of Protonated Heteroaromatic Bases. (1986) (1)
- Polar Effects in Free-Radical Reactions. Homolytic Heteroaromatic Substitutions by Alkyl Bromides. (1993) (1)
- Aerobic oxidation of alcohols to aldehydes and ketones catalysed by nitroxyl radicals (2003) (1)
- Homolytic Alkylation of Protonated Heteroaromatic Bases by Alkyl Iodides, Hydrogen Peroxide, and Dimethyl Sulfoxide. (1990) (1)
- PREPARATION AND REACTIVITY OF THE 2-NITROSO-2-NITROCYCLOHEXANONE (1969) (1)
- REACTIVITY OF HYDROXY AND ALKOXY RADICALS IN PRESENCE OF OLEFINS AND OXIDATION-REDUCTION SYSTEMS. (1963) (1)
- A NEW TYPE OF α-N-AMIDOALKYLATION OF HETEROAROMATIC BASES. MECHANISM OF THE OXIDATION OF THE N-ACYLAMINOETBANOLS BY PEROXYDISULFATE (1985) (1)
- Free Radicals in Oxidation Processes (1999) (1)
- The Role of Transition Metal Salts in One Electron Transfer Organic Reactions (1984) (1)
- Homolytic Alkylation of Naphthoquinone and Methylnaphthoquinone. Enthalpic, Steric and Polar Effects. (1992) (1)
- Polar Effects in Reactions of Carbon-Centered Radicals with Diazonium Salts: Free-Radical Diazocoupling. (1992) (1)
- A Novel Substitution Reaction by Photoinduced Electron-Transfer Between Pyridine Derivatives and Alkyltin Compounds. (2010) (1)
- New Selective Oxidation Reactions by Nitroarenes in Basic Medium Involving Electron-Transfer Processes. (2001) (1)
- A Facile, Convenient, and Selective Homolytic Carbamoylation of Heteroaromatic Bases. (2010) (1)
- Polar Effects in Free-Radical Reactions. New Homolytic Substitutions of Heteroaromatic Bases and Quinones by Ethyl Vinyl Ether and Hydroperoxides. (1996) (1)
- A process for the production of quinones. (1987) (0)
- Reactivity of Carbohydrate Radicals Derived from Iodo Sugars and Dibenzoyl Peroxide. Homolytic Heteroaromatic and Aromatic Substitution, Reduction, and Oxidation. (1994) (0)
- Solvent and temperature effects in free radicals aerobic oxidations catalysed by n-Hydroxyphtalimide. Practical applications (2004) (0)
- New General and Convenient Sources of Alkyl Radicals, Useful for Selective Syntheses. (1988) (0)
- A NEW CONVENIENT ALKYLATION OF HETEROAROMATIC BASES (1974) (0)
- A Bromine‐Catalyzed Free‐Radical Oxidation of Acetamides from Primary and Secondary Alkylamines by H2O2. (2001) (0)
- A New General Method of Homolytic Alkylation of Protonated Heteroaromatic Bases (I), (IV), (VI), (VIII), (X) by Carboxylic Acids (II) and Iodosobenzene Diacetate. (1990) (0)
- Polar Effects in Free-Radical Reactions. Selectivity and Reversibility in the Homolytic Benzylation of Protonated Heteroaromatic Bases. (1986) (0)
- ELECTRON-TRANSFER PROCESS WITH PYRIDINIUM, QUINOLINIUM, AND PYRAZINIUM SALTS, AN ELECTRON SPIN RESONANCE STUDY (1977) (0)
- A process for the manufacture of hydroquinone-mono ethers. (1988) (0)
- SIR DEREK BARTON AND FREE RADICAL CHEMISTRY: A TESTIMONY (2000) (0)
- ELECTRON-TRANSFER PROCESSES BY PEROXYDISULFATE: A NOVEL APPROACH TO THE IMIDAZOLE MOIETY OF CIMETIDINE (1982) (0)
- Reactivity of Carbamoyl Radicals: The First General and Convenient Free‐Radical Synthesis of Isocyanates. (1994) (0)
- ELECTRON-TRANSFER PROCESSES. NEW SYNTHESIS OF Γ-LACTONES BY PEROXYDISULFATE OXIDATION OF ISOPROPYLBENZENES AND ALIPHATIC CARBOXYLIC ACIDS (1981) (0)
- New selective metal-free oxidations of primary alcohols by nitric acid or nitric acid and oxygen, catalyzed by bromine (2005) (0)
- ELECTRONIC CONFIGURATION AND NUCLEOPHILICITY OF CARBON FREE RADICALS, ALPHA‐ALKOXYALKYL, ALPHA‐ALKOXYCARBONYL, AND CYCLOALKYL RADICALS (1975) (0)
- N-METHYLTETRAHYDROCHINOLIN UND N-METHYLINDOLIN (1970) (0)
- N,N-DIALKYLAMINOPHENOLE (1970) (0)
- A New Direct Homolytic Iodination Reaction of Alkanes by Perfluoroalkyl Iodides. (1997) (0)
- Efficient Mn—Cu and Mn—Co—TEMPO Catalyzed Oxidation of Alcohols into Aldehydes and Ketones by Oxygen under Mild Conditions. (2001) (0)
- Free-Radical Mechanisms in the Oxidation and Halogenation of Alkanes, Alkenes, and Alkylbenzenes by t-BuOOH under Gif-Barton Catalysis (1996) (0)
- Molecule‐Induced Homolysis of N‐Hydroxyphthalimide (NHPI) by Peracids and Dioxirane. A New, Simple, Selective Aerobic Radical Epoxidation of Alkenes. (2006) (0)
- THE CHEMISTRY OF ORGANIC FREE-RADICALS (1974) (0)
- NUCLEOPHILIC CHARACTER OF CARBON FREE RADICALS, NEW CONVENIENT SUBSTITUTIONS OF HETEROAROMATIC BASES, THE HOMOLYTIC AMIDATIONS (1973) (0)
- Hydroperoxides as Pseudohalides: Oxidation, Oxidative Alkylation, Acylation and Arylation of Acrylonitrile. (1995) (0)
- ELECTRON-TRANSFER PROCESSES. SELECTIVE SYNTHESES OF AROMATIC ALDEHYDES OF INDUSTRIAL INTEREST BY CATALYZED PEROXYDISULFATE OXIDATION (1979) (0)
- Mechanisms of the Aerobic Oxidations Catalyzed by N‐Hydroxy Derivatives (2006) (0)
- New selective metal-free aerobic of primary alcohols by HNO3 or HNO3 and O2 catalysed by Br2 (2004) (0)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS. XIV. HOMOLYTIC Δ-AMINOALKYLATION OF PROTONATED QUINOXALINE (1977) (0)
- Departmental Data Foreword by the Director of the Department (2009) (0)
- A Convenient Nitroxyl Radical Catalyst for the Selective Oxidation of Primary and Secondary Alcohols to Aldehydes and Ketones by O2 and H2O2 under Mild Conditions. (2004) (0)
- A Novel, Simple, and Cheap Source of Alkyl Radicals from Alcohols, Useful for Heteroaromatic Substitution. (1993) (0)
- Methode de preparation de composes aliphatiques organiques bifonctionnels (1979) (0)
- A New, Highly Selective, Free‐Radical Aerobic Oxidation of Silanes to Silanols Catalyzed by N‐Hydroxyphthalimide under Mild Conditions. (2002) (0)
- Polar Effects in Free‐Radical Reactions. New Selective Alkylations of Heteroaromatic Bases by Benzoylperoxide and Olefins. (1986) (0)
- Redox Catalysis and Electron-Transfer Processes in Selective Organic Syntheses (1989) (0)
- A New Selective Method for the Homolytic Alkylation and Carboxylation of Quinones by Monoesters of Oxalic Acid. (1993) (0)
- ErratumA new, highly selective type of radical chlorination (1967) (0)
- Process for the preparation of monoethers of hydroquinones (1987) (0)
- Facile and Convenient Syntheses of Quinones from Phenols. (1989) (0)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS PART 9, THE BENZYL RADICAL (1973) (0)
- REARRANGEMENT OF BETA-KETOALKYL RADICALS (1974) (0)
- Production of 5-(2,4-difluorophenyl)-salicylic acid (1991) (0)
- Selective Synthesis Mediated by Radical Reaction (1989) (0)
- Polar Effects in Free-Radical Reactions. A Novel Homolytic Acylation of Heteroaromatic Bases by Aerobic Oxidation of Aldehydes, Catalyzed by N-Hydroxyphthalimide and Co Salts. (2003) (0)
- INTRA- AND INTERMOLECULAR FREE RADICAL REACTIONS OF ALCOHOLS AND OLEFINES WITH PEROXYDISULFATE. NEW HOMOLYTIC AROMATIC ALKYLATIONS (1978) (0)
- REAKTIVITAET DER RADIKALE VON NITRILOXIDEN, 1,3-ADDITION (1970) (0)
- A NEW SELECTIVE FREE-RADICAL SYNTHESIS OF GAMMA-LACTONE AND BETA-SCISSION OF GAMMA-PHENYLPROPYL RADICAL (1975) (0)
- A Novel Convenient and Selective Alkoxycarbonylation of Heteroaromatic Bases by Oxalic Acid Monoesters. (1992) (0)
- New aerobic oxidation and new selective mono-etherification of hydroquinones under mild conditions (2005) (0)
- New Procedures of Homolytic Alkylation of Heteroaromatic Bases: Synthesis of C-Nucleosides (1988) (0)
- Alternating Addition of Carbon‐Centered Radicals to Unsaturated Systems. Novel Homolytic Aromatic Substitutions. (1997) (0)
- Book Review, Diazo Chemistry II (1996) (0)
- THE POLAR CHARACTER OF THE PHENYL RADICAL (1973) (0)
- Polar Effects in Free-radical Reactions. New Synthetic Developments in the Functionalization of Heteroaromatic Bases by Nucleophilic Radicals. (1986) (0)
- A Novel, Selective Free‐Radical Carbamoylation of Heteroaromatic Bases by Ce(IV) Oxidation of Formamide, Catalyzed by N‐Hydroxyphthalimide. (2003) (0)
- Homolytic Alkylation of Heteroaromatic Bases: The Problem of Monoalkylation. (1990) (0)
- A Novel Radical Reaction of Alkyl Xanthates Useful for the Selective Substitution of Heteroaromatic Bases. (1992) (0)
- New Selective Metal‐Free Oxidations of Primary Alcohols by HNO3 or HNO3 and O2, Catalyzed by Br2. (2005) (0)
- STERIC AND POLAR EFFECTS IN FREE-RADICAL REACTIONS. AN UNUSUAL TYPE OF AZO COUPLING BY FREE RADICAL DECOMPOSITION OF DIAZONIUM SALTS (1980) (0)
- A NEW TYPE OF α-N-AMIDOALKYLATION OF HETEROAROMATIC BASES. MECHANISM OF THE OXIDATION OF THE N-ACYLAMINOETHANOLS BY PEROXYDISULFATE (1985) (0)
- A New, Highly Selective Synthesis of Aromatic Aldehydes by Aerobic Free-Radical Oxidation of Benzylic Alcohols, Catalyzed by N-Hydroxyphthalimide under Mild Conditions. Polar and Enthalpic Effects. (2002) (0)
- NUCLEOPHILIC AND RADICAL REACTIVITY OF HYDROGEN PEROXIDE (1984) (0)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS. 18. ABSOLUTE RATE CONSTANTS FOR THE E ADDITION OF PRIMARY ALKYL RADICALS TO CONJUGATED OLEFINS AND 1,4-BENZOQUINONE (1979) (0)
- Synlett 2002 silanes3 (2015) (0)
- A Novel and Mild Source of Carbon-Centered Radicals by Iodosobenzene Diacetate (IBDA) and Sodium Azide from Alcohols, Ethers, Aldehydes, Amides, and Alkyl Iodides. (1993) (0)
- A process for preparing o-isopropoxiphenol. (1988) (0)
- NUCLEOPHILIC CHARACTER OF THE ALKYL RADICALS. 16. ABSOLUTE RATE CONSTANTS AND D THE REACTIVITY-SELECTIVITY RELATIONSHIP IN THE HOMOLYTIC AROMATIC ALKYLATION (1978) (0)
- A method for the preparation of quaternary ammonium halides and products obtained (1966) (0)
- New Syntheses of Mixed Peroxides Under Gif-Barton Oxidation of Alkylbenzenes, Conjugated Alkenes and Alkanes; a Free-Radical Mechanism. (2010) (0)
- Enthalpic and polar effects in the reactions of perfluoroalkyl radicals. New, selective synthetic developments with alkenes and electronpoor substrates (2003) (0)
- Selective Functionalization of Hydrocarbons by Nitric Acid and Aerobic Oxidation Catalyzed by N-Hydroxyphthalimide and Iodine under Mild Conditions. (2003) (0)
- POLAR EFFECTS IN FREE RADICAL REACTIONS. A NEW TYPE OF HOMOLYTIC AROMATIC ALKYLATION BY SILVER-CATALYZED OXIDATION OF ACETONE BY PEROXYDISULFATE IN THE PRESENCE OF OLEFINS (1983) (0)
- A process for the preparation of carboxylic acids (2001) (0)
- Polar Effects in Free-Radical Reactions. Solvent and Isotope Effects and Effects of Base Catalysis on the Regio- and Chemoselectivity of the Substitution of Protonated Heteroaromatic Bases by Nucleophilic Carbon- Centered Radicals. (1987) (0)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS PART 10, POLAR AND STERIC EFFECTS IN THE ALKYLATION OF 3-SUBSTITUTED PYRIDINES BY TERT.-BUTYL RADICAL (1975) (0)
- New Free‐Radical Chain Processes Involving Substitution of Vinyl and Aryl Chlorides by Alkanes, Alkenes, Esters, and Ethers. (1997) (0)
- Metal free aerobic oxidation reactions catalyzed by N-hydroxyphthalimide in the presence of aldehydes (2008) (0)
- STERIC, POLAR, AND RESONANCE EFFECTS IN REACTIVITY AND REGIOSELECTIVITY OF ARYL RADICAL ADDITION TO α,β-UNSATURATED CARBONYL COMPOUNDS (1982) (0)
- Silver-Mediated Oxidative Decarboxylation of Carboxylic Acids by Peroxocompounds. (1986) (0)
- A method for the production of caprolactam from esters of 5-cyano-acid (3) -penténoïque (1959) (0)
- ELECTRON-TRANSFER PROCESSES: METAL SALT CATALYZED OXIDATION OF OLEFINS BY PEROXYDISULFATE (1983) (0)
- Enthalpic and Polar Effects in the Reactions of Perfluoroalkyl Radicals. New Selective Synthetic Developments with Alkenes and Heteroaromatic Bases. (2004) (0)
- NUCLEOPHILIC CHARACTER OF ALKYL RADICALS. PART 15. SELECTIVE HOMOLYTIC ALKYLATION OF QUINOXALINE BY N-CHLORO-AMINES, INFLUENCE OF MEDIUM ACIDITY (1977) (0)
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