François Diederich
Luxembourgian chemist and professor at the Swiss Federal Institute of Technology in Zurich
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Chemistry
François Diederich's Degrees
- PhD Chemistry University of Strasbourg
Why Is François Diederich Influential?
(Suggest an Edit or Addition)According to Wikipedia, François Diederich was a Luxembourgian chemist specializing in organic chemistry. Education He obtained both his diploma and PhD from the University of Heidelberg in 1977 and 1979, respectively. Career and research After postdoctoral studies with Orville L. Chapman at the University of California, Los Angeles and habilitation at the Max Planck Institute for Medical Research in Heidelberg, he became Full Professor of Organic and Bioorganic Chemistry at UCLA in 1989. In 1992 he was appointed Professor of Organic Chemistry at ETH Zurich. He retired on 31 July 2017, and remained a research-active professor at ETH Zurich. On 16 March 2019, the German Chemical Society bestowed him with their highest recognition, Honorary Membership.
François Diederich's Published Works
Published Works
- Fluorine in Pharmaceuticals: Looking Beyond Intuition (2007) (4379)
- Metal-catalyzed cross-coupling reactions (2004) (3642)
- Interactions with aromatic rings in chemical and biological recognition. (2003) (2789)
- Aromatic rings in chemical and biological recognition: energetics and structures. (2011) (1006)
- All-optical high-speed signal processing with silicon–organic hybrid slot waveguides (2009) (793)
- Linear Monodisperse π-Conjugated Oligomers: Model Compounds for Polymers and More. (1999) (689)
- Supramolecular fullerene chemistry (1999) (532)
- Modern acetylene chemistry (1995) (500)
- Metal-Catalyzed Cross-Coupling Reactions: Diederich/Metal (2007) (471)
- Covalent Fullerene Chemistry (1996) (457)
- Synthetic approaches toward molecular and polymeric carbon allotropes (1992) (432)
- Wechselwirkungen mit aromatischen Ringen in chemischen und biologischen Erkennungsprozessen (2003) (419)
- Orthogonal multipolar interactions in structural chemistry and biology. (2005) (408)
- Molecular recognition in chemical and biological systems. (2015) (395)
- Systematic investigation of halogen bonding in protein-ligand interactions. (2011) (394)
- Structural aspects of fullerene chemistry--a journey through fullerene chirality. (2006) (374)
- Predicting and Tuning Physicochemical Properties in Lead Optimization: Amine Basicities (2007) (350)
- Carbon scaffolding: building acetylenic all-carbon and carbon-rich compounds (1994) (341)
- Acetylene-derived strong organic acceptors for planar and nonplanar push-pull chromophores. (2009) (325)
- All‐Carbon Scaffolds by Rational Design (2010) (279)
- Phosphate recognition in structural biology. (2007) (233)
- Improved purification of C60 and formation of σ- and π-homoaromatic methano-bridged fullerenes by reaction with alkyl diazoacetates (1993) (233)
- Non-planar push-pull chromophores. (2010) (226)
- Allenes in molecular materials. (2012) (222)
- Acetylenkupplungen: eine leistungsfähige Methode für den Aufbau von Molekülen (2000) (221)
- Determination of End-to-End Distances in a Series of TEMPO Diradicals of up to 2.8 nm Length with a New Four-Pulse Double Electron Electron Resonance Experiment. (1998) (221)
- Supramolecular [60]fullerene chemistry on surfaces. (2007) (219)
- Functional Dendrimers: Unique Biological Mimics (1998) (219)
- 1,1‐Dicyano‐4‐[4‐(diethylamino)phenyl]buta‐1,3‐dienes: Structure–Property Relationships (2012) (216)
- Acetylene chemistry : chemistry, biology and material science (2004) (213)
- Donor-substituted 1,1,4,4-tetracyanobutadienes (TCBDS): new chromophores with efficient intramolecular charge-transfer interactions by atom-economic synthesis. (2006) (213)
- Steroids in Molecular Recognition. (1997) (205)
- A new class of organic donor-acceptor molecules with large third-order optical nonlinearities. (2005) (202)
- Structure−Property Relationships in Third-Order Nonlinear Optical Chromophores (1998) (201)
- Templated Regioselective and Stereoselective Synthesis in Fullerene Chemistry (1999) (192)
- Aromatische Ringe in chemischer und biologischer Erkennung: Energien und Strukturen (2011) (183)
- Aromatic Rings in Chemical and Biological Recognition: Energetics and Structures (2011) (183)
- Syntheses, structures, and properties of methanofullerenes (1994) (176)
- Dendritic Porphyrins: Modulating Redox Potentials of Electroactive Chromophores with Pendant Multifunctionality (1994) (176)
- Enthalpically driven cyclophane-arene inclusion complexation: solvent-dependent calorimetric studies (1991) (174)
- Conjugated oligoenynes based on the diethynylethene unit. (2005) (170)
- Strength of molecular complexation of apolar solutes in water and in organic solvents is predictable by linear free energy relationships: a general model for solvation effects on apolar binding (1990) (166)
- Regio‐ and Diastereoselective Bisfunctionalization of C60 and Enantioselective Synthesis of a C60 Derivative with a Chiral Addition Pattern (1996) (165)
- A fluorine scan of thrombin inhibitors to map the fluorophilicity/fluorophobicity of an enzyme active site: evidence for C-F...C=O interactions. (2003) (165)
- Silicon Organic Hybrid Technology—A Platform for Practical Nonlinear Optics (2009) (161)
- Lineare monodisperse π-konjugierte Oligomere: mehr als nur Modellverbindungen für Polymere (1999) (156)
- Dendritic vectors for gene transfection (2007) (153)
- Structures and vibrational frequencies of the carbon molecules C2-C18 calculated by density functional theory (1994) (152)
- A weak attractive interaction between organic fluorine and an amide group. (2004) (151)
- Tether-Directed Remote Functionalization of Buckminsterfullerene: Regiospecific Hexaadduct Formation† (1994) (151)
- Strategien zum Aufbau molekularer und polymerer Kohlenstoffallotrope (1992) (149)
- Supramolecular patterned surfaces driven by cooperative assembly of C60 and porphyrins on metal substrates. (2004) (147)
- Macrocyclization on the fullerene core: Direct regio‐ and diastereoselective multi‐functionalization of [60]fullerene, and synthesis of fullerene‐dendrimer derivatives (1997) (138)
- Fullerene Sugars: Preparation of Enantiomerically Pure, Spiro‐Linked C‐Glycosides of C60 (1992) (134)
- A High‐Optical Quality Supramolecular Assembly for Third‐Order Integrated Nonlinear Optics (2008) (134)
- Amphiphilic dendrimers: novel self-assembling vectors for efficient gene delivery. (2003) (133)
- Carbon-rich acetylenic scaffolding: rods, rings and switches (2001) (131)
- Fluorine Interactions at the Thrombin Active Site: Protein Backbone Fragments HCαCO Comprise a Favorable CF Environment and Interactions of CF with Electrophiles (2004) (129)
- Modern Supramolecular Chemistry: Strategies for Macrocycle Synthesis (2008) (128)
- Benzenoid versus Annulenoid Aromaticity: Synthesis and Properties of Kekulene (1978) (125)
- Synthesis of a Fullerene Derivative of Benzo[18]crown‐6 by Diels‐Alder Reaction: Complexation Ability, Amphiphilic Properties, and X‐Ray Crystal Structure of a Dimethoxy‐1,9‐(methano[1,2]benzenomethano)fullerene[60] Benzene Clathrate (1993) (125)
- A Novel Three-Way Chromophoric Molecular Switch: pH and Light Controllable Switching Cycles. (1999) (125)
- Water‐Soluble Dendritic Iron Porphyrins: Synthetic Models of Globular Heme Proteins (1996) (124)
- Cycloarenes, a New Class of Aromatic Compounds, I. Synthesis of Kekulene (1983) (123)
- Halogen bonding molecular capsules. (2015) (119)
- A new pyridyl-substituted methanofullerene derivative. Photophysics, electrochemistry and self-assembly with zinc(II) meso-tetraphenylporphyrin (ZnTPP) (1999) (115)
- A new water-soluble macrocyclic host of the cyclophane type: host-guest complexation with aromatic guests in aqueous solution and acceleration of the transport of arenes through an aqueous phase (1984) (114)
- A supramolecular multiposition rotary device. (2007) (113)
- Optical properties of highly nonlinear silicon-organic hybrid (SOH) waveguide geometries. (2009) (112)
- A New Family of Chiral Binaphthyl‐Derived Cyclophane Receptors: Complexation of Pyranosides (1995) (111)
- Solution-spray flash vacuum pyrolysis: a new method for the synthesis of linear poliynes with odd numbers of C.tplbond.C bonds from substituted 3,4-dialkynyl-3-cyclobutene-1,2-diones (1991) (110)
- Cyclophane zur Komplexierung von Neutralmolekülen (1988) (109)
- Stable Langmuir and Langmuir-Blodgett films of fullerene-glycodendron conjugates (1998) (108)
- Halogen Bonding at the Active Sites of Human Cathepsin L and MEK1 Kinase: Efficient Interactions in Different Environments (2011) (106)
- Organic super-acceptors with efficient intramolecular charge-transfer interactions by [2+2] cycloadditions of TCNE, TCNQ, and F4-TCNQ to donor-substituted cyanoalkynes. (2009) (105)
- Charge-transfer chromophores by cycloaddition-retro-electrocyclization: multivalent systems and cascade reactions. (2007) (104)
- Orthogonal dipolar interactions between amide carbonyl groups (2008) (103)
- Cyclophane-arene inclusion complexation in protic solvents: solvent effects versus electron donor-acceptor interactions (1991) (102)
- A novel reaction of 7,7,8,8-tetracyanoquinodimethane (TCNQ): charge-transfer chromophores by [2 + 2] cycloaddition with alkynes. (2007) (102)
- Structures and Chemistry of Methanofullerenes: A Versatile Route into N-[(Methanofullerene)carbonyl]-Substituted Amino Acids (1993) (101)
- Property tuning in charge-transfer chromophores by systematic modulation of the spacer between donor and acceptor. (2007) (100)
- Halogen bonding of (iodoethynyl)benzene derivatives in solution. (2014) (98)
- Exceptional redox and photophysical properties of a triply fused diporphyrin-C60 conjugate: novel scaffolds for multicharge storage in molecular scale electronics. (2003) (98)
- C60 and C70 in a Basket? – Investigations of Mono‐ and Multilayers from Azacrown Compounds and Fullerenes (1992) (98)
- Helicene quinones: redox-triggered chiroptical switching and chiral recognition of the semiquinone radical anion lithium salt by electron nuclear double resonance spectroscopy. (2014) (95)
- Structure-based drug design: exploring the proper filling of apolar pockets at enzyme active sites. (2008) (94)
- Prospective Evaluation of Free Energy Calculations for the Prioritization of Cathepsin L Inhibitors. (2017) (94)
- Origin of intense intramolecular charge-transfer interactions in nonplanar push-pull chromophores. (2009) (93)
- Triply fused Zn(II)-porphyrin oligomers: synthesis, properties, and supramolecular interactions with single-walled carbon nanotubes (SWNTs). (2006) (93)
- Molecular torsion balances: evidence for favorable orthogonal dipolar interactions between organic fluorine and amide groups. (2007) (91)
- Foldamers : structure, properties, and applications (2007) (91)
- Tetraethynylethenes: Fully cross-conjugated π-electron chromophores and molecular scaffolds for all-carbon networks and carbon-rich nanomaterials (1995) (89)
- Quantification of cation-pi interactions in protein-ligand complexes: crystal-structure analysis of Factor Xa bound to a quaternary ammonium ion ligand. (2005) (88)
- Modification of supramolecular binding motifs induced by substrate registry: formation of self-assembled macrocycles and chain-like patterns. (2009) (88)
- A Copper(I)‐Complexed Rotaxane with Two Fullerene Stoppers: Synthesis, Electrochemistry, and Photoinduced Processes (1998) (88)
- Development of redox-switchable resorcin[4]arene cavitands. (2014) (88)
- The Impact of Antiaromatic Subunits in [4n+2] π-Systems: Bispentalenes with [4n+2] π-Electron Perimeters and Antiaromatic Character. (2015) (87)
- Lewis acidic catalysts for olefin epoxidation by iodosylbenzene (1991) (86)
- Redox-Active Self-Assembled Monolayers for Solid-Contact Polymeric Membrane Ion-Selective Electrodes (2002) (85)
- Chemistry of the Higher Fullerenes: Preparative isolation of C76 by HPLC and synthesis, separation, and characterization of Diels-Alder monoadducts of C70 and C76 (1994) (85)
- Supramolecular Dendrimer Chemistry: A Journey Through the Branched Architecture (2000) (84)
- Redox-active self-assembled monolayers as novel solid contacts for ion-selective electrodes (2000) (84)
- Extended conjugation and donor-acceptor substitution to improve the third-order optical nonlinearity of small molecules (2007) (83)
- Orthogonale multipolare Wechselwirkungen in chemischen und biologischen Strukturen (2005) (83)
- Geometrically precisely defined multinanometer expansion/contraction motions in a resorcin[4]arene cavitand based molecular switch. (2005) (82)
- The [2+2] Cycloaddition-Retroelectrocyclization (CA-RE) Click Reaction: Facile Access to Molecular and Polymeric Push-Pull Chromophores. (2018) (82)
- Container molecules with portals: Reversibly switchable cycloalkane complexation. (2007) (82)
- Preparation of Enantiomerically Pure C76 with a General Electrochemical Method for the Removal of Di(alkoxycarbonyl)methano Bridges from Methanofullerenes: The Retro-Bingel Reaction (1998) (81)
- Dendrimers with Porphyrin Cores: Synthetic Models for Globular Heme Proteins (1997) (81)
- Synthesis, and Optical and Electrochemical Properties of Cyclophane-Type Molecular Dyads Containing a Porphyrin in Close, Tangential Orientation Relative to the Surface oftrans-1 Functionalized C60. Preliminary Communication (1998) (80)
- Analysis of Isomers of the Higher Fullerenes by 3He NMR Spectroscopy (1995) (80)
- Supramolecular chemistry of dendrimers with functional cores (2002) (80)
- New strong organic acceptors by cycloaddition of TCNE and TCNQ to donor-substituted cyanoalkynes. (2007) (78)
- Donor-substituted cyanoethynylethenes: pi-conjugation and band-gap tuning in strong charge-transfer chromophores. (2005) (78)
- Bis- through Tetrakis-Adducts of C60 by Reversible Tether-Directed Remote Functionalization and systematic investigation of the changes in fullerene properties as a function of degree, pattern, and nature of functionalization (1997) (77)
- Molecular Recognition with Resorcin[4]arene Cavitands: Switching, Halogen-Bonded Capsules, and Enantioselective Complexation. (2018) (77)
- Halogen-Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase. (2017) (77)
- Starving the malaria parasite: inhibitors active against the aspartic proteases plasmepsins I, II, and IV. (2006) (77)
- Electrochemistry of Mono‐ through Hexakis‐adducts of C60 (1995) (77)
- A fluorine scan of the phenylamidinium needle of tricyclic thrombin inhibitors: effects of fluorine substitution on pKa and binding affinity and evidence for intermolecular C-F...CN interactions. (2004) (76)
- Methanofullerene Molecular Scaffolding: Towards C60-substituted poly(triacetylenes) and expanded radialenes, preparation of a C60–C70 hybrid derivative, and a novel macrocyclization reaction (1997) (75)
- Supramolecular Capsules: Strong versus Weak Chalcogen Bonding. (2018) (75)
- Fullerene–Acetylene Hybrids: On the Way to Synthetic Molecular Carbon Allotropes (1994) (75)
- The Covalent Chemistry of Higher Fullerenes: C70 and Beyond (1997) (74)
- 1,2,3-triazoles as conjugative pi-linkers in push-pull chromophores: importance of substituent positioning on intramolecular charge-transfer. (2008) (73)
- Nanoscale engineering of molecular porphyrin wires on insulating surfaces. (2008) (73)
- An enantiomerically pure alleno-acetylenic macrocycle: synthesis and rationalization of its outstanding chiroptical response. (2009) (73)
- Stable [12]‐ and [18]Annulenes Derived from Tetraethynylethene (1993) (72)
- Self-assembly and two-dimensional spontaneous resolution of cyano-functionalized [7]helicenes on Cu111. (2011) (72)
- Molekulare Erkennung in chemischen und biologischen Systemen (2015) (72)
- Optically Active Cyclophane Receptors for Mono- and Disaccharides: The Role of Bidentate Ionic Hydrogen Bonding in Carbohydrate Recognition (2001) (72)
- Pentafluorosulfanyl as a Novel Building Block for Enzyme Inhibitors: Trypanothione Reductase Inhibition and Antiprotozoal Activities of Diarylamines (2009) (71)
- Cation-pi interactions at the active site of factor Xa: dramatic enhancement upon stepwise N-alkylation of ammonium ions. (2009) (71)
- Synthesis and crystal structure of a stable hexacobalt complex of cyclo[18] carbon (1990) (70)
- Cycloarenes, a New Class of Aromatic Compounds, II. Molecular Structure and Spectroscopic Properties of Kekulene (1983) (69)
- Conformational Switching of Resorcin[4]arene Cavitands by Protonation, Preliminary Communication (2001) (69)
- Molecular Clefts Derived from 9,9′‐spirobi[9H‐fluorene] for enantioselective complexation of pyranosides and dicarboxylic acids (1995) (69)
- Selective Extraction of C70 by a Tetragonal Prismatic Porphyrin Cage. (2018) (69)
- Systematische Untersuchung von Halogenbrücken in Protein‐Ligand‐ Wechselwirkungen (2011) (68)
- Regioselective Synthesis of trans-1 Fullerene Bis-Adducts Directed by a Crown Ether Tether: Alkali Metal Cation Modulated Redox Properties of Fullerene-Crown Ether Conjugates. (1998) (67)
- A New Helicopodand: Molecular Recognition of Dicarboxylic Acids with High Diastereoselectivity (1993) (67)
- Amplification of chirality in monodisperse, enantiopure alleno-acetylenic oligomers. (2010) (66)
- Chemistry of C84 : Separation of Three Constitutional Isomers and Optical Resolution of D2 -C84 by Using the "Bingel-Retro-Bingel" Strategy. (1999) (66)
- Substituent Effects in Parallel-Displaced π-π Stacking Interactions: Distance Matters. (2017) (66)
- Tetrakis(phenylamidinium)-Substituted Resorcin[4]arene Receptors for the Complexation of Dicarboxylates and Phosphates in Protic Solvents (2000) (66)
- Efficient Stacking on Protein Amide Fragments (2013) (65)
- Synthetic routes to the cyclo[n]carbons (1994) (65)
- Highly efficient third-order optical nonlinearities in donor-substituted cyanoethynylethene molecules. (2005) (65)
- Donor-substituted cyanoethynylethenes: powerful chromophores for opto-electronic applications. (2003) (65)
- Conformational behavior of pyrazine-bridged and mixed-bridged cavitands: a general model for solvent effects on thermal "vase-kite" switching. (2006) (65)
- Thiazolopyrimidine Inhibitors of 2‐Methylerythritol 2,4‐Cyclodiphosphate Synthase (IspF) from Mycobacterium tuberculosis and Plasmodium falciparum (2010) (65)
- Molecular recognition at the thrombin active site: structure-based design and synthesis of potent and selective thrombin inhibitors and the X-ray crystal structures of two thrombin-inhibitor complexes. (1997) (65)
- Electronic Characteristics of Arylated Tetraethynylethenes: A Cooperative Computational and Electrochemical Investigation (1997) (64)
- Dramatically Enhanced Fluorescence of Heteroaromatic Chromophores upon Insertion as Spacers into Oligo(triacetylene)s (2002) (64)
- NMR Investigations into the Vase-Kite Conformational Switching of Resorcin[4]arene Cavitands (2004) (64)
- Redox-switchable resorcin[4]arene cavitands: molecular grippers. (2012) (64)
- Precursors to the cyclo[n]carbons: from 3,4-dialkynyl-3-cyclobutene-1,2-diones and 3,4-dialkynyl-3-cyclobutene-1,2-diols to cyclobutenodehydroannulenes and higher oxides of carbon (1990) (63)
- Allene in molekularen Materialien (2012) (63)
- One-pot synthesis of aromatic methyl esters by electrochemical oxidation of aldehydes mediated by biscoenzyme catalysis (1992) (63)
- Spacer‐kontrollierte Fernfunktionalisierung von Buckminsterfulleren: regiospezifische Bildung eines Hexaadduktes (1994) (63)
- A supramolecular approach for the formation of fullerene–phthalocyanine dyads (2002) (63)
- Multiple Cyclopropanations of C70. Synthesis and characterization of bis‐, tris‐, and tetrakis‐adducts and chiroptical properties of bis‐adducts with chiral addends, including a recommendation for the configurational description of fullerene derivatives with a chiral addition pattern (1995) (63)
- Solubilized Derivatives of C195 and C260: The First Members of a New Class of Carbon Allotropes Cn(60 + 5) (1995) (62)
- Fullerene-acetylene hybrids: Towards a novel class of molecular carbon allotropes (1996) (62)
- Structure‐property relationships in nonlinear optical tetraethynylethenes (1996) (62)
- Supramolecular synthons on surfaces: controlling dimensionality and periodicity of tetraarylporphyrin assemblies by the interplay of cyano and alkoxy substituents. (2008) (62)
- A COPPER(I)-COMPLEXED ROTAXANE WITH TWO FULLERENE STOPPERS (1995) (61)
- Donor/Acceptor‐Substituted Tetraethynylethenes: Systematic Assembly of Molecules for Use as Advanced Materials (1996) (61)
- The Higher Fullerenes: Covalent Chemistry and Chirality (1999) (61)
- Bucky Ligands: Synthesis, Ruthenium(II) Complexes, and Electrochemical Properties (1998) (61)
- Oligoporphyrin arrays conjugated to [60] fullerene: Preparation, NMR analysis, and photophysical and electrochemical properties (2005) (61)
- Strong enthalpically driven complexation of neutral benzene guests in aqueous solution (1988) (60)
- Dendrophanes: Water‐Soluble Dendritic Receptors. Preliminary communication (1995) (60)
- Structural, optical, and electrochemical properties of three-dimensional push-pull corannulenes. (2012) (59)
- Dendritic Iron(II) Porphyrins as Models for Hemoglobin and Myoglobin: Specific Stabilization of O2 Complexes in Dendrimers with H-Bond-Donor Centers (2002) (59)
- PTII-DIRECTED SELF-ASSEMBLY OF A DINUCLEAR CYCLOPHANE CONTAINING TWO FULLERENES (1998) (59)
- Dendritic hydrogen bonding receptors: enantiomerically pure dendroclefts for the selective recognition of monosaccharides (1998) (58)
- Synthesis of trans-1, trans-2, trans-3, and trans-4 bisadducts of C60 by regio- and stereoselective tether-directed remote functionalization. (2005) (58)
- Redox Characteristics of Covalent Derivatives of the Higher Fullerenes C70, C76, and C78 (1998) (58)
- Solvatochromism as an efficient tool to study N,N-dimethylamino- and cyano-substituted π-conjugated molecules with an intramolecular charge-transfer absorption (2011) (58)
- Self-assembly, DNA complexation, and pH response of amphiphilic dendrimers for gene transfection. (2007) (58)
- Regio- and stereoselective tether-directed remote functionalization of C60 with derivatives of the Tröger base. (2004) (58)
- Multiple Adducts of C60 by Tether‐Directed Remote Functionalization and synthesis of soluble derivatives of new carbon allotropes Cn(60+5) (1997) (57)
- Shape-persistent chiral alleno-acetylenic macrocycles and cyclophanes by acetylenic scaffolding with 1,3-diethynylallenes. (2005) (57)
- Expanded Radialenes: A Novel Class of Cross‐Conjugated Macrocycles (1994) (56)
- New Push‐Pull Chromophores Featuring TCAQ (11,11,12,12‐Tetracyano‐ 9,10‐anthraquinodimethane) and Other Dicyanovinyl Acceptors (2008) (56)
- Sub-Picosecond Singlet Exciton Fission in Cyano-Substituted Diaryltetracenes. (2015) (56)
- Photoswitchable Tetraethynylethene‐Dihydroazulene Chromophores (2001) (56)
- Crystal structures of tRNA-guanine transglycosylase (TGT) in complex with novel and potent inhibitors unravel pronounced induced-fit adaptations and suggest dimer formation upon substrate binding. (2007) (56)
- Catalytic Dendrophanes as Enzyme Mimics: Synthesis, Binding Properties, Micropolarity Effect, and Catalytic Activity of Dendritic Thiazolio‐cyclophanes (1999) (55)
- Synthesis of the helicopodands: novel shapes for chiral clefts (1991) (55)
- Redox-dependent binding ability of a flavin cyclophane in aqueous solution: hydrophobic stacking versus cavity-inclusion complexation (1990) (55)
- Stable Soluble Conjugated Carbon Rods with a Persilylethynylated Polytriacetylene Backbone (1994) (55)
- 61,61‐Bis(trimethylsilylbutadiynyl)‐1,2‐dihydro‐1,2‐methanofullerene[60]: Crystal Structure at 100 K and Electrochemical Conversion to a Conducting Polymer (1994) (55)
- Dioxygen and carbon monoxide binding in dendritic iron(ii)porphyrins (1997) (54)
- Homochiral [2]Catenane and Bis[2]catenane from Alleno-Acetylenic Helicates - A Highly Selective Narcissistic Self-Sorting Process. (2015) (54)
- 1,3-Diethynylallenes (DEAs): enantioselective synthesis, absolute configuration, and chiral induction in 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs). (2008) (54)
- The hit-and-return system enables efficient time-resolved serial synchrotron crystallography (2018) (54)
- X-ray Crystal Structure of a Bisubstrate Inhibitor Bound to the Enzyme Catechol-O-methyltransferase: A Dramatic Effect of Inhibitor Preorganization on Binding Affinity. (2001) (54)
- Photophysical and electrochemical properties of meso, meso-linked oligoporphyrin rods with appended fullerene terminals. (2005) (54)
- Donor-acceptor (D-A)-substituted polyyne chromophores: modulation of their optoelectronic properties by varying the length of the acetylene spacer. (2013) (52)
- Dendroclefts: Optically Active Dendritic Receptors for the Selective Recognition and Chiroptical Sensing of Monosaccharide Guests (1999) (52)
- New donor-acceptor chromophores by formal [2+2] cycloaddition of donor-substituted alkynes to dicyanovinyl derivatives. (2009) (52)
- Highly-Nonlinear Silicon Photonics Slot Waveguide (2008) (52)
- Modeling the Supramolecular Properties of Aliphatic-Aromatic Hydrocarbons with Convex-Concave Topology. (1998) (52)
- Diaryl sulfide-based inhibitors of trypanothione reductase: inhibition potency, revised binding mode and antiprotozoal activities. (2008) (52)
- Regio‐ und diastereoselektive Bisfunktionalisierung von C60‐Fulleren und enantioselektive Synthese eines C60‐Fullerenderivates mit chiralem Additionsmuster (1996) (52)
- Chalcogen Bonding "2S-2N Squares" versus Competing Interactions: Exploring the Recognition Properties of Sulfur. (2018) (51)
- Poly(triacetylene) Oligomers: Synthesis, Characterization, and Estimation of the Effective Conjugation Length by Electrochemical, UV/Vis, and Nonlinear Optical Methods (1997) (51)
- The self-assembly of fullerene-containing [2]pseudorotaxanes: formation of a supramolecular C60 dimer (1999) (51)
- Molecular Recognition of Pyranosides by a Family of Trimeric, 1,1′‐Binaphthalene‐Derived Cyclophane Receptors (1998) (51)
- Pseudilins: halogenated, allosteric inhibitors of the non-mevalonate pathway enzyme IspD. (2014) (51)
- Molecular recognition at the active site of factor Xa: cation-π interactions, stacking on planar peptide surfaces, and replacement of structural water. (2012) (50)
- Dendritische Porphyrine: Modulation des Redoxpotentials elektroaktiver Chromophore durch periphere Multifunktionalität (1994) (50)
- Chirality transfer in 1D self-assemblies: influence of H-bonding vs metal coordination between dicyano[7]helicene enantiomers. (2013) (50)
- Synthesis of Novel Nonpeptidic Thrombin Inhibitors (2000) (50)
- Structure-based design, synthesis, and in vitro evaluation of bisubstrate inhibitors for catechol O-methyltransferase (COMT). (2000) (50)
- Macrocyclic Tetraethynylethene Molecular Scaffolding: Perethynylated aromatic dodecadehydro[18]annulenes, antiaromatic octadehydro[12]annulenes, and expanded radialenes (1995) (49)
- Dendrophanes: Novel Steroid‐Recognizing Dendritic Receptors. Preliminary Communication (1996) (49)
- SYNTHESIS OF A FULLERENE[60] CRYPTATE AND SYSTEMATIC LANGMUIR-BLODGETT AND THIN-FILM INVESTIGATIONS OF AMPHIPHILIC FULLERENE DERIVATIVES (1995) (49)
- Switching the regioselectivity in cycloaddition-retro-electrocyclizations between donor-activated alkynes and the electron-accepting olefins TCNE and TCNQ. (2011) (49)
- Tetrakis(trialkylsilylethynyl)butatriene and 1,1,4,4‐Tetrakis(trialkylsilylethynyl)‐1,3‐butadiene: Novel Cross‐Conjugated Chromophores (1993) (49)
- Donor‐Substituted Perethynylated Dehydroannulenes and Radiaannulenes: Acetylenic Carbon Sheets Featuring Intense Intramolecular Charge Transfer (2004) (48)
- Self-Assembly of the First Fullerene-Containing [2]Catenane† (1997) (48)
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- Aromaticity and Electron Affinity of Carbok‐[3]radialenes, k = 0, 1, 2. (2004) (0)
- Donor-Acceptor Systems Derived from Tetraethynylethene (1995) (0)
- Synthesis of a Macrocyclic Thiazolium Host and Supramolecular Catalysis of the Benzoin Condensation. (1987) (0)
- TRIAZINE CATHEPSIN INHIBITOR COMPLEX (2013) (0)
- Crystal structure of Trypanothione Reductase from Trypanosoma brucei in complex with inhibitor 3-(2-{1-[2-(Piperidin-4-yl)ethyl]-1H-indol-5-yl}-5-[1-(pyrrolidin-1-yl)cyclohexyl]-1,3- thiazol-4-yl)-N-(2,2,2-trifluoroethyl)prop-2-yn-1-amine (2019) (0)
- Reaction with Tetrachlorothiophene 1,1-Dioxide (2008) (0)
- Reduction of Fulleroids C71H2: Probing the Magnetic Properties of C706‐. (2001) (0)
- Further Titles of Interest (2004) (0)
- Synthesis of Product Subclass 1 (2008) (0)
- Stepwise Synthesis under Oxygen-Free Conditions (2008) (0)
- PL-12 A Multi-dimensional Approach to Molecular Recognition in Chemistry and Biology (2006) (0)
- Catalytic Cyclophanes. Part 5. A Porphyrin-Bridged Cyclophane as a Model for Cytochrome P-450 Enzymes. (1990) (0)
- Starving the Malaria Parasite: A New Class of Inhibitors Active Against the Aspartic Proteases Plasmepsins I, II, and IV (2006) (0)
- Extremely Efficient Two-Photon Absorption in Small Donor-Acceptor Substituted Organic Molecules (2015) (0)
- Pirrolderivados of dioxopirrolo. (1996) (0)
- CCDC 295279: Experimental Crystal Structure Determination (2006) (0)
- Frontispiece: The Quest for Molecular Grippers: Photo‐Electric Control of Molecular Gripping Machinery (2019) (0)
- Regioselectivity in the Functionalization of Higher Fullerenes and Chiroptical Properties of Fullerenes with a Chiral Addition Pattern (1997) (0)
- Molecular structure and spectroscopic properties of kekulene (Cycloarenes, a new class of aromatic compounds ; 2) (1983) (0)
- Crystal structure of Trypanothione Reductase from Trypanosoma brucei in complex with inhibitor (+)-5-{5-[1-(Pyrrolidin-1-yl)cyclohexyl]-1,3-thiazol-2-yl}-1-{[(2S)-pyrrolidin-2-yl]methyl}-1H-indole (2019) (0)
- Plasmodium vivax SHMT bound with PLP-glycine and GS363 (2017) (0)
- Structure-based drug design in HIV protease- and tRNA-guanine transglycosylase inhibitor development (2008) (0)
- PM3 geometry optimization and CNDO/S-CI computation of UV/Vis spectra of large organic structures: Program description and application to poly(triacetylene) hexamer and taxotere (1999) (0)
- Synthesis of 1,2,5-Thiadiazolidin-3-one 1,1-Dioxide Derivatives and Evaluation of Their Affinity for MHC Class-II Proteins. (2000) (0)
- Dimerization under Copper Catalysis (2008) (0)
- Conjugates Exceptional Redox and Photophysical Properties of a Triply Fused Diporphyrin – C 60 Conjugate : Novel Scaffolds for Multicharge Storage in Molecular Scale Electronics * * (2003) (0)
- Synthesis, Separation, and Characterization of Optically Pure C76 Mono- Adducts. (1997) (0)
- Signal Processing with Silicon-Organic Hybrid Waveguides (2010) (0)
- Vapor Deposited Small Molecule Materials for Integrated Nonlinear Optics (2010) (0)
- Reaction of Sodium Acetylides with Alkyl Bromides (2008) (0)
- Crystal structure of Trypanothione Reductase from Trypanosoma brucei in complex with inhibitor EP127 (5-{5-[1-(PYRROLIDIN-1-YL)CYCLOHEXYL]-1,3-THIAZOL-2-YL}-1H-INDOLE) (2014) (0)
- CCDC 729039: Experimental Crystal Structure Determination (2010) (0)
- New Strong Organic Acceptors by Cycloaddition of TCNE and TCNQ to Donor‐Substituted Cyanoalkynes. (2008) (0)
- CCDC 295281: Experimental Crystal Structure Determination (2006) (0)
- CYCLOARENES, A NEW CLASS OF AROMATIC COMPOUNDS. II. MOLECULAR STRUCTURE AND SPECTROSCOPIC PROPERTIES OF KEKULENE (1983) (0)
- CONJUGATION IN MACROCYCLIC BOND SYSTEMS. 27. BENZENOID VS. ANNULENOID AROMATICITY- SYNTHESIS AND PROPERTIES OF KEKULENE (1978) (0)
- Time-resolved serial synchrotron crystallography: an efficient interlacing system enables milliseconds to seconds time delays (2018) (0)
- CCDC 295282: Experimental Crystal Structure Determination (2006) (0)
- Synthesis of Multiple Adducts of C60 with Specific Addition Patterns by Simple and Reversible (Templated) Tether‐Directed Remote Functionalization (1997) (0)
- Supramolecular Fullerene Chemistry: A Comprehensive Study of Cyclophane-Type Mono- and Bis-Crown Ether Conjugates of C70. (2002) (0)
- De novo Disign, Synthesis, and in vitro Evaluation of a New Class of Nonpeptidic Inhibitors of the Malarial Enzyme Plasmepsin II. (2003) (0)
- Biomimetic Oxidation of Aromatic Aldehydes Catalyzed by a Bis(Coenzyme)-Cyclophane (1998) (0)
- Crystal Structure of C70×6(S8) at 100 K. (1993) (0)
- EPR and Photochemical Studies on Organic Super-Acceptors (2009) (0)
- Plasmodium vivax SHMT(C346A) bound with PLP-glycine and GS395 (2017) (0)
- Dendritic Rods with a Poly(triacetylene) Backbone: Insulated Molecular Wires. (1998) (0)
- Photophysical and Electron Paramagnetic Resonance Investigations on Organic Acceptors and their Precursors (2009) (0)
- Walk on the Sphere: Electrochemically Induced Isomerization of C60 Bis‐adducts by Migration of Di(alkoxycarbonyl)methano Bridges. (2010) (0)
- Plasmodium vivax SHMT bound with PLP-glycine and S-GS849 (2018) (0)
- On-Surface Supramolecular Chemistry with Porphyrins and Phthalocyanines: An Architectural Concept Leading to Engineered Quantum-Functional Nanostructures (2020) (0)
- Cover Picture: Synthesis and Characteristics of a Nonaggregating Tris(tetrathiafulvaleno)dodecadehydro[18]annulene (Chem. Eur. J. 33/2006) (2006) (0)
- CONJUGATION IN MACROCYCLIC BOND SYSTEMS. 30. MOLECULAR STRUCTURE AND SPECTROSCOPIC PROPERTIES OF KEKULENE (1979) (0)
- Plasmodium vivax SHMT bound with PLP-glycine and GS657 (2018) (0)
- Non-Planar Push—Pull Chromophores (2010) (0)
- Factor Xa - cation inhibitor complex (2011) (0)
- Precursors to the Cyclo(n)carbons: (4n + 2)- and (4n)Annulenes with Unusual Stabilities. (1989) (0)
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