Friedrich Matthias Bickelhaupt

Friedrich Matthias Bickelhaupt's AcademicInfluence.com Rankings

Chemistry

#1243

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#1917

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Computational Chemistry

World Rank

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Physical Chemistry

#100

World Rank

#124

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Chemistry

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Friedrich Matthias Bickelhaupt's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Chemistry with ADF (2001) (7213)
Kohn-Sham Density Functional Theory: Predicting and Understanding Chemistry (2007) (837)
Voronoi deformation density (VDD) charges: Assessment of the Mulliken, Bader, Hirshfeld, Weinhold, and VDD methods for charge analysis (2004) (792)
Analyzing Reaction Rates with the Distortion/Interaction‐Activation Strain Model (2017) (672)
The activation strain model of chemical reactivity. (2010) (501)
The activation strain model and molecular orbital theory: understanding and designing chemical reactions. (2014) (381)
Understanding reactivity with Kohn–Sham molecular orbital theory: E2–SN2 mechanistic spectrum and other concepts (1999) (336)
Hydrogen Bonding in DNA Base Pairs: Reconciliation of Theory and Experiment (2000) (330)
Charge transport in columnar stacked triphenylenes: Effects of conformational fluctuations on charge transfer integrals and site energies (2003) (320)
Absolute rates of hole transfer in DNA. (2005) (271)
The Nature of the Hydrogen Bond in DNA Base Pairs: The Role of Charge Transfer and Resonance Assistance (1999) (271)
Hydrogen-hydrogen bonding in planar biphenyl, predicted by atoms-in-molecules theory, does not exist. (2006) (269)
Orbital overlap and chemical bonding. (2006) (246)
The Carbon−Lithium Electron Pair Bond in (CH3Li)n (n = 1, 2, 4) (1996) (227)
The activation strain model and molecular orbital theory (2015) (222)
The case for steric repulsion causing the staggered conformation of ethane. (2003) (194)
A model of the chemical bond must be rooted in quantum mechanics, provide insight, and possess predictive power. (2006) (191)
Halogen Bonding versus Hydrogen Bonding: A Molecular Orbital Perspective (2012) (169)
The Nature of the Transition Metal–Carbonyl Bond and the Question about the Valence Orbitals of Transition Metals. A Bond Energy Decomposition Analysis of TM(CO)6q (TMq = Hf2–, Ta1–, W0, Re1+, Os2+, Ir3+) (2000) (168)
Nucleophilicity and leaving-group ability in frontside and backside S(N)2 reactions. (2008) (166)
Polycyclic benzenoids: why kinked is more stable than straight. (2007) (166)
The many faces of halogen bonding: a review of theoretical models and methods (2014) (159)
Transition-state energy and position along the reaction coordinate in an extended activation strain model. (2007) (145)
Synthesis of mesityldiphenylmethylenephosphine: a stable compound with a localized phosphorus:carbon bond (1978) (138)
Performance of various density functionals for the hydrogen bonds in DNA base pairs (2006) (137)
Central Bond in the Three CN• Dimers NC–CN, CN–CN and CN–NC: Electron Pair Bonding and Pauli Repulsion Effects (1992) (136)
The EDA Perspective of Chemical Bonding (2014) (128)
Nucleophilic substitution at silicon (SN2@Si) via a central reaction barrier. (2007) (128)
Multicomponent synthesis of 2-imidazolines. (2005) (127)
Telomere structure and stability: covalency in hydrogen bonds, not resonance assistance, causes cooperativity in guanine quartets. (2011) (124)
Nucleophilic substitution at phosphorus (S(N)2@P): disappearance and reappearance of reaction barriers. (2006) (122)
Highly accelerated inverse electron-demand cycloaddition of electron-deficient azides with aliphatic cyclooctynes (2014) (120)
Alternatives to the CO Ligand: Coordination of the Isolobal Analogues BF, BNH2, BN(CH3)2, and BO− in Mono‐ and Binuclear First‐Row Transition Metal Complexes (1998) (119)
IS CO A SPECIAL LIGAND IN ORGANOMETALLIC CHEMISTRY? THEORETICAL INVESTIGATION OF AB, FE(CO)4AB, AND FE(AB)5 (AB = N2, CO, BF, SIO) (1998) (117)
Adenine tautomers: relative stabilities, ionization energies, and mismatch with cytosine. (2006) (116)
Adenine versus guanine quartets in aqueous solution: dispersion-corrected DFT study on the differences in π-stacking and hydrogen-bonding behavior (2010) (111)
QUILD: QUantum‐regions interconnected by local descriptions (2008) (109)
A chemist's guide to valence bond theory (2009) (108)
π-π stacking tackled with density functional theory (2007) (107)
Activation of H-H, C-H, C-C and C-Cl Bonds by Pd and PdCl(-). Understanding Anion Assistance in C-X Bond Activation. (2005) (105)
A new all-round density functional based on spin states and S(N)2 barriers. (2009) (104)
Bonding capabilities of imidazol-2-ylidene ligands in group-10 transition-metal chemistry (2009) (104)
Das Distortion/Interaction‐Activation‐Strain‐Modell zur Analyse von Reaktionsgeschwindigkeiten (2017) (103)
Oxidative addition of Pd to C–H, C–C and C–Cl bonds: Importance of relativistic effects in DFT calculations (2001) (102)
Ab initio and DFT benchmark study for nucleophilic substitution at carbon (SN2@C) and silicon (SN2@Si) (2005) (101)
Contiguous metal-mediated base pairs comprising two Ag(I) ions. (2011) (98)
Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent (2018) (97)
Normal-to-abnormal rearrangement and NHC activation in three-coordinate iron(II) carbene complexes. (2013) (96)
Activation of H−H, C−H, C−C, and C−Cl Bonds by Pd(0). Insight from the Activation Strain Model (2004) (96)
Catalytic Carbon-Halogen Bond Activation: Trends in Reactivity, Selectivity, and Solvation. (2007) (90)
Why do cycloaddition reactions involving C60 prefer [6,6] over [5,6] bonds? (2013) (88)
Understanding chemical reactivity using the activation strain model (2020) (88)
Optimization of strong and weak coordinates (2006) (87)
Theoretical study of structure, pKa, lipophilicity, solubility, absorption, and polar surface area of some centrally acting antihypertensives. (2006) (85)
Proton Affinities in Water of Maingroup‐Element Hydrides – Effects of Hydration and Methyl Substitution (2007) (83)
Alder‐ene reaction: Aromaticity and activation‐strain analysis (2012) (83)
Nature of the three-electron bond in H2S∴SH2+ (1998) (82)
2,4,6-Tri-tert-butylphenylphosphene-dimesitylsilene. The first phosphasilaalkene (1984) (81)
Energy landscapes of nucleophilic substitution reactions: A comparison of density functional theory and coupled cluster methods (2007) (79)
Phosphasilenes: synthesis and spectroscopic characterization (1987) (79)
o-Dilithium-benzol (1958) (78)
Synthesis and structure of aryl-substituted phospha-alkenes (1984) (77)
Mapping the sites for selective oxidation of guanines in DNA. (2003) (76)
Aromaticity and activation strain analysis of [3 + 2] cycloaddition reactions between group 14 heteroallenes and triple bonds. (2011) (75)
DFT benchmark study for the oxidative addition of CH4 to Pd. Performance of various density functionals (2005) (75)
Hydrogen bonds of RNA are stronger than those of DNA, but NMR monitors only presence of methyl substituent in uracil/thymine. (2004) (73)
para-Selective C–H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis (2019) (73)
E2 and SN2 Reactions of X(-) + CH3CH2X (X = F, Cl); an ab Initio and DFT Benchmark Study. (2008) (73)
Hypervalent silicon versus carbon: ball-in-a-box model. (2008) (72)
Type-I dyotropic reactions: understanding trends in barriers. (2012) (71)
Orbital interactions in strong and weak hydrogen bonds are essential for DNA replication. (2002) (70)
Catalyst selection based on intermediate stability measured by mass spectrometry (2010) (69)
Origin of the “endo rule” in Diels–Alder reactions (2014) (69)
Chemical basis for the recognition of trimethyllysine by epigenetic reader proteins (2015) (67)
Oxidative Addition of the Chloromethane C-Cl Bond to Pd, an ab Initio Benchmark and DFT Validation Study. (2006) (67)
Organomagnesium chemistry: Nearly hundred years but still fascinating (1994) (66)
Aromaticity: molecular-orbital picture of an intuitive concept. (2007) (66)
Theoretical Investigation on Base-Induced 1,2-Eliminations in the Model System F- + CH3CH2F. The Role of the Base as Catalyst (1993) (65)
Double group transfer reactions: role of activation strain and aromaticity in reaction barriers. (2009) (65)
A ditopic ion-pair receptor based on stacked nucleobase quartets. (2009) (64)
The Effect of Microsolvation on E2 and SN2 Reactions: Theoretical Study of the Model System F− + C2H5F + nHF (1996) (61)
Cyclotrimerization reactions catalyzed by rRhodium(I) half-sandwich complexes: A mechanistic density functional study (2007) (60)
Synthesis of small cyclophanes (1994) (60)
Oxidative Insertion as Frontside SN2 Substitution: Theoretical Investigation of the Model Reaction Systems Pd + CH₃C1. (1995) (58)
Synthesis and structure of pentacarbonyl(mesityldiphenylmethylenephosphine)-chromium(0) (1981) (58)
How Lewis Acids Catalyze Diels–Alder Reactions (2020) (57)
Oxidative addition of the ethane CC bond to Pd. An ab initio benchmark and DFT validation study (2005) (55)
X-Ray Structural Analyses of Organomagnesium Compounds (1993) (55)
Silver(I)-mediated Hoogsteen-type base pairs. (2011) (54)
Synthesis and Reactions of P-Supermesityl-C-halophosphaalkenes (1991) (54)
Nucleophilic Substitution at C, Si and P: How Solvation Affects the Shape of Reaction Profiles (2008) (53)
Controlling the oxidative addition of aryl halides to Au(I) (2014) (53)
A Chemist's Guide to Density Functional Theory, by Wolfram Koch and Max C. Holthausen [Review of: Wolfram Koch and Max C. Holthausen. A Chemist's Guide to Density Functional Theory] (2001) (53)
Ab initio benchmark study for the oxidative addition of CH4 to Pd: importance of basis-set flexibility and polarization. (2004) (53)
PHOSPHASILENE SYNTHESIS AND REACTIVITY : AN IMPROVED ROUTE TO 1-(2,4,6-TRI-TERT-BUTYLPHENYL)-2-TERT-BUTYL-2-(2,4,6-TRI-ISOPROPYLPHENYL)PHOSPHASILENE (1991) (53)
The formation of Grignard compounds—II (1973) (52)
The donor-stabilized silylene bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): synthesis, electronic structure, and reactivity. (2014) (52)
Chemical shifts in nucleic acids studied by density functional theory calculations and comparison with experiment. (2012) (52)
Matrix-isolation infrared investigation of the flash vacuum thermolysis of norbornadienone azine (1989) (51)
CH₃• is planar due to steric H-H repulsion. Theoretical study of MH₃•and MH₃Cl (M=C, Si, Ge,Sn). (1996) (50)
The steric nature of the bite angle. (2009) (50)
Carbanions as Intermediates in the Formation of Grignard Reagents (2002) (50)
Nonlinear d10-ML2 Transition-Metal Complexes (2013) (50)
Nucleophilic substitution at phosphorus centers (SN2@p). (2007) (49)
B-DNA structure and stability: the role of hydrogen bonding, π-π stacking interactions, twist-angle, and solvation. (2014) (49)
Oxidative addition of the fluoromethane C-F bond to Pd. An ab initio benchmark and DFT validation study. (2005) (49)
Intramolecular Coordination in Organometallic Compounds of Groups 2, 12, and 13 (1995) (49)
Oxidation reactions of phosphaalkenes (1983) (48)
Intercalation of Daunomycin into Stacked DNA Base Pairs. DFT Study of an Anticancer Drug (2008) (48)
Orbital interactions in hydrogen bonds important for cohesion in molecular crystals and mismatched pairs of DNA bases (2002) (48)
Ene-ene-yne reactions: activation strain analysis and the role of aromaticity. (2014) (48)
Coordinational behavior of solvent-free diorganylzinc compounds: the remarkable x-ray structure of dimeric diphenylzinc (1990) (47)
Selectivity in DNA replication. Interplay of steric shape, hydrogen bonds, π-stacking and solvent effects. (2011) (47)
The structure of the grignard reagent : IX. The crystal structure of the dimeric ethylmagnesium bromide/diisopropyl ether complex (1974) (47)
On the origin of the steric effect. (2012) (46)
Palladium(II)-catalyzed claisen rearrangement of allyl vinyl ethers (1986) (46)
Role of Steric Attraction and Bite-Angle Flexibility in Metal-Mediated C–H Bond Activation (2015) (46)
Interconversion of [6]paracyclophane and 1,4-hexamethylene(Dewar benzene) (1977) (46)
How Dihalogens Catalyze Michael Addition Reactions (2019) (45)
Bonding of Imidazol-2-ylidene Ligands in Nickel Complexes (2008) (45)
Role of Orbital Interactions and Activation Strain (Distortion Energies) on Reactivities in the Normal and Inverse Electron-Demand Cycloadditions of Strained and Unstrained Cycloalkenes. (2017) (45)
Synthesis and structural investigation of mesityldiphenylmethylenephosphine bis(triphenylphosphine)platinum(0) (1982) (45)
Proton Affinities of Anionic Bases: Trends Across the Periodic Table, Structural Effects, and DFT Validation. (2006) (44)
Frontside versus Backside S(N)2 substitution at group 14 atoms: origin of reaction barriers and reasons for their absence. (2008) (44)
Small cyclophanes: the bent benzene business (1990) (43)
The total synthesis of the antibiotic malonomicin (k16) (1978) (43)
Double CH Activation of a Masked Cationic Bismuth Amide. (2018) (43)
[4]Paracyclophane intercepted (1987) (43)
The formation of grignard compounds—III : The influence of the solvent (1975) (42)
Steric nature of the bite angle. A closer and a broader look. (2011) (42)
Acid-Catalyzed Olefination of Benzaldehyde (1994) (42)
Synthesis of cyclic bifunctional organomagnesium compounds. X-ray crystal structures of tetrameric organomagnesium clusters (1993) (42)
Theoretical and experimental study of charge transfer through DNA: impact of mercury mediated T-Hg-T base pair. (2014) (42)
Di‐Grignard‐Verbindungen und Metallacyclen (1987) (41)
Nucleophilic Substitution in Solution: Activation Strain Analysis of Weak and Strong Solvent Effects (2018) (41)
Di‐Grignard Compounds and Metallacycles (1987) (40)
Hypervalent carbon atom: "freezing" the S(N)2 transition state. (2009) (40)
Understanding the reactivity of endohedral metallofullerenes: C78 versus Sc3N@C78. (2015) (39)
PyFrag—Streamlining your reaction path analysis (2008) (39)
Dibenzo[b,e]phosphorin (1967) (39)
X-ray structure of (1,3-xylyl-18-crown-5)diphenylmagnesium: an organometallic rotaxane (1988) (39)
Stepwise walden inversion in nucleophilic substitution at phosphorus. (2009) (39)
Mechanism of thioredoxin-catalyzed disulfide reduction. Activation of the buried thiol and role of the variable active-site residues. (2008) (38)
Supramolecular switches based on the guanine-cytosine (GC) Watson-Crick pair: effect of neutral and ionic substituents. (2006) (38)
Stable unsymmetrical diphosphenes (1983) (38)
Hydrogen bonding in mimics of Watson-Crick base pairs involving C-H proton donor and F proton acceptor groups: a theoretical study. (2004) (38)
Deeper Insight into the Diels-Alder Reaction through the Activation Strain Model. (2016) (38)
Metallacyclische Vierringsysteme: Zwei unabhängige Wege zu Bis(cyclopentadienyl)titanacyclobutabenzol (1986) (38)
Oxidative addition to main group versus transition metals: Insights from the Activation Strain model (2006) (38)
Reaction Coordinates and the Transition-Vector Approximation to the IRC. (2008) (38)
Formation of the first organometallic catenane (1993) (38)
Activation-strain analysis reveals unexpected origin of fast reactivity in heteroaromatic azadiene inverse-electron-demand diels-alder cycloadditions. (2015) (38)
Alpha-stabilization of carbanions: fluorine is more effective than the heavier halogens. (2006) (37)
Neutral six-coordinate and cationic five-coordinate silicon(IV) complexes with two bidentate monoanionic N,S-pyridine-2-thiolato(-) ligands. (2013) (37)
Radon hydrides: structure and bonding. (2011) (37)
Nuclear versus Side-Chain Bromination of Methyl-Substituted Anisoles by N-Bromosuccinimide (1994) (37)
Inter‐ and intramolecular dispersion interactions (2011) (37)
Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5 (1991) (36)
Model Systems for Initial Stages of Oxidative-Addition Reactions. Theoretical Investigation of η1 and η2 Coordination of F2 and H2 to PtCl42- and Cr(CO)5 (1990) (36)
Reactivity of the Donor-Stabilized Silylenes [iPrNC(Ph)NiPr]2 Si and [iPrNC(NiPr2 )NiPr]2 Si: Activation of CO2 and CS2. (2015) (36)
Bonding of xenon hydrides. (2009) (36)
Proton affinities of maingroup‐element hydrides and noble gases: Trends across the periodic table, structural effects, and DFT validation (2006) (36)
Role of the Chalcogen (S, Se, Te) in the Oxidation Mechanism of the Glutathione Peroxidase Active Site. (2017) (36)
Structural Distortion of Cycloalkynes Influences Cycloaddition Rates both by Strain and Interaction Energies (2019) (35)
Aromaticity and antiaromaticity in 4-, 6-, 8-, and 10-membered conjugated hydrocarbon rings. (2008) (35)
B-DNA Structure and Stability as Function of Nucleic Acid Composition: Dispersion-Corrected DFT Study of Dinucleoside Monophosphate Single and Double Strands (2013) (34)
Might BF and BNR2 Be Alternatives to CO? A Theoretical Quest for New Ligands in Organometallic Chemistry (1998) (34)
[4+2]cycloaddition reactions of triarylphosphaalkene (1984) (34)
Orbital interactions and charge redistribution in weak hydrogen bonds: The Watson-Crick AT mimic adenine-2,4-difluorotoluene (2003) (34)
Ladungstransfer und molekulare Umgebung sind verantwortlich für Eigenschaften von Wasserstoffbrücken in DNA‐Basenpaaren (1999) (34)
Stereodivergent SN2@P reactions of borane oxazaphospholidines: experimental and theoretical studies. (2013) (33)
Dihydrogen bonding: donor-acceptor bonding (AH...HX) versus the H2 molecule (A-H2-X). (2009) (33)
Covalency in Highly Polar Bonds. Structure and Bonding of Methylalkalimetal Oligomers (CH3M)n (M = Li-Rb; n = 1, 4). (2006) (33)
3-Methylenetetrahydrofurans and 3-methylenepyrrolidines by addition of 2-bromozincmethyl-2-propenyl ethers to aldehydes, ketones and imines followed by pd(O)-catalyzed cyclization (1988) (33)
New concepts for designing d10 -M(L)n catalysts: d regime, s regime and intrinsic bite-angle flexibility. (2014) (33)
Synthese von 1,3-Dimetallacyclobutanen mit dem Methylen-di-Grignardreagens (1986) (33)
Hypervalent versus nonhypervalent carbon in noble-gas complexes. (2008) (33)
Bridged valence isomers of benzene and cyclophanes (1988) (32)
Unusual reactivity of small cyclophanes: nucleophilic attack on 11-chloro- and 8,11-dichloro[5]metacyclophane (1990) (32)
Unusual reactivity of small cyclophanes: nucleophilic attack on 11-chloro- and 8,11-dichloro[5]metacyclophane (1990) (32)
Zur Komplexstabilisierung alkalimetall‐organischer Verbindungen in Äther, II (1958) (32)
3-Substituted xanthines as promising candidates for quadruplex formation: Computational, synthetic and analytical studies (2011) (32)
Understanding E2 versus SN2 Competition under Acidic and Basic Conditions (2014) (31)
Oxidative addition versus dehydrogenation of methane, silane, and heavier AH(4) congeners reacting with palladium (2006) (31)
Reactivity in nucleophilic vinylic substitution (S(N)V):S(N)Vπ versus S(N)Vσ mechanistic dichotomy. (2013) (31)
Dibenz[b,e]arsenin (9-Arsaanthracen)† (1969) (31)
n1- and n2-Coordination in a (phosphoalkene)platinum(0) complex (1983) (31)
Origin of Reactivity Trends of Noble Gas Endohedral Fullerenes Ng2@C60 (Ng = He to Xe). (2014) (31)
Origins of the Endo and Exo Selectivities in Cyclopropenone, Iminocyclopropene, and Triafulvene Diels-Alder Cycloadditions. (2018) (30)
Reactivity and Selectivity of Bowl-Shaped Polycyclic Aromatic Hydrocarbons: Relationship to C60. (2016) (30)
Solvent Effects on Hydrogen Bonds in Watson-Crick, Mismatched, and Modified DNA Base Pairs (2012) (30)
1,3-Dilithiopropanes (1982) (30)
Synthesis and structural characterisation of neutral pentacoordinate silicon(IV) complexes with a tridentate dianionic N,N,S chelate ligand. (2012) (30)
PyFrag 2019—Automating the exploration and analysis of reaction mechanisms (2019) (30)
Highly Stable and Selective Tetrazines for the Coordination-Assisted Bioorthogonal Ligation with Vinylboronic Acids (2018) (29)
He(I) photoelectron spectroscopy of diisocyanogen (CNNC) (1989) (29)
The .eta.1- and .eta.2-coordination in a (phosphaalkene)platinum(0) complex (1984) (29)
Factors controlling β-elimination reactions in group 10 metal complexes. (2015) (29)
Theoretical investigation of the relative stabilities of XSSX and X2SS isomers (X = F, Cl, H, and CH3) (1995) (29)
Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl (2019) (29)
Density Functional Calculations of E2 and SN2 Reactions: Effects of the Choice of Method, Algorithm, and Numerical Accuracy. (2010) (28)
Bonding in methylalkalimetals (CH(3)M)(n) (M = Li, Na, K; n = 1, 4). Agreement and divergences between AIM and ELF analyses. (2006) (28)
Rare tautomers of 1-methyluracil and 1-methylthymine: tuning relative stabilities through coordination to PtII complexes. (2009) (28)
Metallacyclic Four-Membered Ring Systems: Two Independent Routes to Bis(cyclopentadienyl)titanacyclobutabenzene† (1986) (28)
Chimeric GNA/DNA metal-mediated base pairs. (2011) (28)
Crown ether Grignard reagents; x-ray structure of 2-(bromomagnesio)-1,3-xylyl-15-crown-4 (1988) (28)
Oxygen and nitrogen heterocycles by intramolecular magnesium- and zinc-ene reactions; Methylenecyclopentanes by Pd(0) - catalyzed isomerization of 5-(bromozincmethyl)-3-methyleneoxacycloalkanes (1987) (28)
The coordination modes of simple diarylmagnesium species: Some representative X-ray crystal structures (1990) (28)
Didehydrophenanthrenes: structure, singlet-triplet splitting, and aromaticity. (2007) (28)
Chemoselectivity of Tertiary Azides in Strain‐Promoted Alkyne‐Azide Cycloadditions (2018) (28)
Evidence for a chemical clock in oscillatory formation of UiO-66 (2016) (28)
Addition-Elimination or Nucleophilic Substitution? Understanding the Energy Profiles for the Reaction of Chalcogenolates with Dichalcogenides. (2016) (27)
Methyl cation affinities of neutral and anionic maingroup-element hydrides: trends across the periodic table and correlation with proton affinities. (2010) (27)
(2,6‐Dimethylphenyl)(9‐fluorenyliden)phosphan (1984) (27)
Thermodynamics of the Cu(II) μ-thiolate and Cu(I) disulfide equilibrium: a combined experimental and theoretical study. (2014) (27)
Substituent Effects on Hydrogen Bonding in Watson–Crick Base Pairs. A Theoretical Study (2005) (27)
Theoretical study of the structure and bonding in ThC2 and UC2. (2012) (27)
The Short N−F Bond in N2F+ and How Pauli Repulsion Influences Bond Lengths. Theoretical Study of N2X+, NF3X+, and NH3X+ (X = F, H) (2002) (27)
Travelling the organometallic road: a Wittig student’s journey from lithium to magnesium and beyond (1999) (27)
Studies on the formation of [5]metacyclophane (1981) (27)
Direct detection of the mercury-nitrogen bond in the thymine-Hg(II)-thymine base-pair with (199)Hg NMR spectroscopy. (2015) (26)
An investigation of the di-Grignard approach to metallabenzocyclobutenes of group 14 (1987) (26)
Multiscale modelling. (2011) (26)
First synthesis of stannacyclobutanes (1983) (26)
Understanding the Reactivity of Ion-Encapsulated Fullerenes. (2017) (26)
Molekülstruktur von 8,11‐Dichlor[5]metacyclophan: Ein stark verbogener Benzolring (1984) (26)
In silico design of heteroaromatic half-sandwich RhI catalysts for acetylene [2+2+2] cyclotrimerization: evidence of a reverse indenyl effect. (2013) (26)
Reactivity of (phosphaalkenyl)metal species: transmetalations and reactions with carbonyl compounds. (1996) (26)
Synthesis and application of precursors of hetero-anthracenes : 2-halo- and 2,2′-dihalodiphenylmethanes and methine substituted derivatives (1976) (25)
Indenyl effect due to metal slippage? Computational exploration of rhodium-catalyzed acetylene [2+2+2] cyclotrimerization. (2014) (25)
Bifunctional and cyclic organomagnesium compounds: I. Pentamethylenebis(magnesium bromide) and magnesiacyclohexane (1969) (25)
[4+2] and [2+2] cycloadditions of benzyne to C60 and zig-zag single walled carbon nanotubes: the effect of the curvature. (2016) (25)
Die Chemie der in 7‐Stellung substituierten Norbornadiene; eine Untersuchung des sterischen Verlaufs einiger Additions‐Reaktionen ungesättigter Bicyclo[2.2.1]heptanderivate und über den Gültigkeitsbereich der Alderschen exo‐Regel (1967) (25)
Radical formation during reactions of Grignard reagents with quinones (1970) (25)
Regioselectivity of Epoxide Ring-Openings via SN 2 Reactions Under Basic and Acidic Conditions (2020) (25)
Rationalizing the structural variability of the exocyclic amino groups in nucleobases and their metal complexes: cytosine and adenine. (2014) (25)
Ion-Pair SN 2 Substitution: Activation Strain Analyses of Counter-Ion and Solvent Effects. (2016) (25)
Synthesis of 2-iodo-4,5-dimethylphosphinine and its conversion to organometallic derivatives (1992) (25)
Aromaticity in Heterocyclic and Inorganic Benzene Analogues (2008) (24)
Structure and bonding of transition metal-boryl compounds. Theoretical study of [(PH3)2(CO)ClOs-BR2] and [(PH3)2(CO)2ClOs-BR2] (BR2 = BH2, BF2, B(OH)2, B(OCH=CHO), Bcat). (2000) (24)
Stable Four-Coordinate Guanidinatosilicon(IV) Complexes with SiN3El Skeletons (El = S, Se, Te) and Si=El Double Bonds. (2015) (24)
Zur herstellung und reaktivität von bis(trimethylsilyl)dilithiomethan (1988) (24)
The reaction of a phosphaalkene with orthoquinones (1983) (23)
Base-induced 1,4-elimination: insights from theory and mass spectrometry. (2001) (23)
Bis[N,N'-diisopropylbenzamidinato(-)]silicon(II): Lewis acid/base reactions with triorganylboranes. (2014) (23)
Bis(bromomagnesio)trimethylsilylmethane (1986) (23)
A direct synthesis of 1,3-bis(bromomagnesio)propane (1982) (23)
Synthesis and conformational analysis of 68,11-dihalo[5]metacyclophanes (1984) (23)
Complexation of diphenylzinc with simple ethers. Crystal structures of the complexes Ph2Zn · glyme and Ph2Zn · diglyme (1992) (23)
1,5-Annelated 4-methylenecyclopentenes by intramolecular type I zinc-ene reactions followed by Pd(0)-catalyzed cyclization (1989) (22)
Some applications of the methylene di-Grignard reagent for the synthesis of main group IV organometallic compounds (1985) (22)
Reaction of photochemically generated dibromocarbene with 1,2-dimethylenecycloalkanes: 1,4 addition is real (1989) (22)
A general synthesis of metallacyclobutanes (1985) (22)
Bifunctional and cyclic organomagnesium compounds: III. The crystal and molecular structure of the dimer of magnesiacyclohexane, 1,7-dimagnesiacyclododecane (1969) (22)
Di-Grignard reagents and metallacycles (1986) (21)
Oxidation of organic diselenides and ditellurides by H2O2 for bioinspired catalyst design. (2018) (21)
Complex formation between nickel(0) and a phosphaalkene: Influence of the second ligand on the η1- and η2-coordination mode (1983) (21)
8,11-dichloro[5]metacyclophane (1983) (21)
Intramolecularly coordinated arylmagnesium compounds: effects on the Schlenk equilibrium (1991) (21)
Scope and limitations of an efficient four-component reaction for dihydropyridin-2-ones. (2010) (21)
Structure and Stability of the Li2CN Molecule. An Experimental and ab Initio Study (1995) (21)
Thermal generation and dimerization of [4]metacyclophane (1987) (21)
Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning (2020) (21)
Investigations on doubly nitrogen-15 labeled isocyanogen (CNCN) (1991) (21)
Bite-angle bending as a key for understanding group-10 metal reactivity of d10-[M(NHC)2] complexes with sterically modest NHC ligands (2014) (21)
Anion Recognition by Organometallic Calixarenes: Analysis from Relativistic DFT Calculations (2018) (21)
Role of s-p orbital mixing in the bonding and properties of second-period diatomic molecules. (2008) (21)
Linkage isomerism of nitriles in rhodium half-sandwich metallacycles (2008) (20)
The 9-mesityl-9-boraanthracene anion (1971) (20)
Reactivity of 8,11-dihalo[5]metacyclophanes (1990) (20)
A Unified Framework for Understanding Nucleophilicity and Protophilicity in the SN2/E2 Competition (2020) (20)
The first x-ray structure of a 1,1-di-Grignard compound: bis(bromomagnesio)bis(trimethylsilyl)methane (1992) (20)
Hypervalence and the delocalizing versus localizing propensities of H3–, Li3–, CH5– and SiH5– (2007) (20)
Koordinationseigenschaften der isolobalen Phosphaniminatound Cyclopentadienyl‐Liganden in TiCl3(NPH3), TiCl3Cp, ReO3(NPH3) und ReO3Cp (1999) (20)
Elucidating the Trends in Reactivity of Aza-1,3-Dipolar Cycloadditions (2018) (20)
Tricyclo[6.1.1.03,9]deca-2,8(10)-diene, the Dewar isomer of [4]metacyclophane (1980) (19)
Diels-Alder-Reaktionen von [5]Metacyclophan (1982) (19)
10‐Phenyldibenzo[b,e]phosphorin (1968) (19)
Mesityl(diphenylmethylen)arsan (1979) (19)
Tuning Heterocalixarenes to Improve Their Anion Recognition: A Computational Approach. (2018) (19)
Zur stabilisierung von [5]paracyclophanen durch substitution am benzolring (1987) (19)
Silicon α-Effect: A Systematic Experimental and Computational Study of the Hydrolysis of Cα- and Cγ-Functionalized Alkoxytriorganylsilanes of the Formula Type ROSiMe2(CH2)nX (R = Me, Et; n = 1, 3; X = Functional Group) (2014) (19)
Reaction Mechanism and Regioselectivity of the Bingel-Hirsch Addition of Dimethyl Bromomalonate to La@C2v -C82. (2016) (19)
XPdCl (X = Cl, Me, Ac) (1997) (19)
Density-Functional Study of (Solvated) Grignard Complexes (2000) (19)
Comment on "The interplay between steric and electronic effects in SN2 reactions". (2010) (19)
Aromaticity of highly bent benzene rings. An investigation by high-field deuterium NMR of [5]metacyclophane and model compounds (1986) (19)
Structural studies on paracyanogen and paraisocyanogen (1994) (19)
Neutral Pentacoordinate Halogeno‐ and Pseudohalogenosilicon(IV) Complexes with a Tridentate Dianionic O,N,O or N,N,O Ligand: Synthesis and Structural Characterization in the Solid State and in Solution (2012) (19)
How the electron-deficient cavity of heterocalixarenes recognizes anions: insights from computation. (2017) (18)
Introduction of Bulky Substituents at the Bridgehead Position of a 9-Silatriptycene: Pentacoordinate Hydridoorganylsilicates as Intermediates (2000) (18)
Induction of higher coordination states in phenyl Grignard reagents by intramolecular coordination. Crystal structures of O-CH2(OCH2CH2)*OCH3-substituted phenylmagnesium bromides (n = 0-3) (1991) (18)
Understanding the Oxidative Addition of σ-Bonds to Group 13 Compounds. (2016) (18)
How Oriented External Electric Fields Modulate Reactivity (2020) (18)
Neutral and positively charged new purine tetramer structures: a computational study of xanthine and uric acid derivatives (2011) (18)
Activation Strain Analysis of SN2 Reactions at C, N, O, and F Centers (2017) (18)
Molecular Structure of 8,11‐Dichloro[5]metacyclophane: A Strongly Bent Benzene Ring (1984) (18)
Deracemization of a Racemic Allylic Sulfoxide Using Viedma Ripening (2017) (18)
A nucleophilic reaction of a phosphaalkene: the methylation of mesityldiphenylmethylenephosphine (1982) (18)
The 2-Vinylphosphirane−3-Phospholene Rearrangement: Biradicaloid and Concerted Features (2000) (18)
Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement (2020) (18)
Neutralization‐Reionization Mass Spectrometry and Matrix Isolation of Some 9‐Silaanthracenes (1991) (18)
On the origin of chemically induced dynamic nuclear polarization [CIDNP] observed during the Grignard formation reaction (1976) (18)
Table salt and other alkali metal chloride oligomers: structure, stability, and bonding. (2007) (18)
Gas-Phase Base-Induced 1,4-Eliminations: Occurence of Single-, Double- and Triple-Well E1cb Mechanisms (1995) (18)
The structure of 1,4-bisorganomagnesium compounds in magnesacyclopentane (1982) (18)
Mesityl(diphenylmethylene)arsane (1979) (18)
Die bildung von titanocen-methylen-komplexen aus 1,3-dititanacyclobutanen (1986) (18)
Activation of C–H, C–C and C–I bonds by Pd and cis-Pd(CO)2I2. Catalyst–substrate adaptation (2005) (18)
The Activation of Phenylmagnesium Compounds by Crown Ethers (1988) (17)
Methylenedimagnesium dibromide as precursor of metal carbene complexes; preparation of titanacyclobutanes. (1983) (17)
Antibiotic A 19009. Structural investigation and synthesis. (1983) (17)
Complexation of bis(p-tert-butylphenyl)magnesium with 1,3-xylylene crown ethers and glymes (1994) (17)
Orbitalwechselwirkungen in starken und schwachen Wasserstoffbrücken sind essentiell für die DNA-Replikation Wir danken der Stiftung Nationale Computerfaciliteiten (NCF) der Nederlandse Organisatie voor Wetenschappelijk Onderzoek (NWO) für finanzielle Unterstützung. C.F.G. dankt der National Research (2002) (17)
Stereoselective Synthesis of 1-Tuberculosinyl Adenosine; a Virulence Factor of Mycobacterium tuberculosis. (2016) (17)
On the nature of the radical pairs involved in the Grignard reaction (1980) (17)
Photoelectron Spectroscopy and Conjugation—Direct Proof of the Unusual Sequence of the Two Highest Occupied π‐Molecular Orbitals in the Phosphorin (Phosphabenzene) and the Arsenin (Arsabenzene) System (1972) (17)
The knoevenagel reaction of malononitrile with some cyclic β-keto-esters—II (1974) (17)
Synthesis of 5-and 6-membered carbon-boron heterocycles by pyrolysis of pyridine-arylboranes (1973) (17)
Preparation and reactivity of bis(bromomagnesio)bis(trimethylsilyl)methane (1989) (17)
Differential stabilization of adenine quartets by anions and cations (2009) (17)
The Pauli Repulsion-Lowering Concept in Catalysis. (2021) (17)
Synthesis of Novel Phosphaalkene-Based Bidentate Ligands Mes*(Me)P=CH(3-R-Ar) (R = Pyridyl, Carbaldimino) and Formation of Three-Membered Palladacycles Mes*(Me)P-CH(3-R-Ar)-PdCl by Carbapalladation of the P=C Double Bond (1999) (17)
THE STRUCTURE OF CHAKSINE, A MONOTERPENE ALKALOID (1958) (17)
Central Bond in the Three CN× Dimers NC‐CN, CN‐CN, and CN‐NC: Electron Pair Bonding and Pauli Repulsion Effects. (1992) (17)
Synthesis of the 9-mesityl-10-phenyl-9-boraanthracene anion (1972) (17)
On the nature of the “free electron pair” on phosphorus in aromatic phosphorus compounds: The photoelectron spectrum of 2-phosphanaphthalene☆ (1975) (17)
Palladium(0) mediated coupling of bromophosphaalkenes with Grignard reagents. (1997) (17)
Allylmetalation of 1-silylalkynes by 2-bromozincmethyl-2-propenyl ethers followed by pd(0)-catalyzed cyclization: A one-pot synthesis of 4-methylenecyclopentenes (1987) (17)
Arylic C–X Bond Activation by Palladium Catalysts: Activation Strain Analyses of Reactivity Trends (2018) (16)
Halogen Bonds in Ligand–Protein Systems: Molecular Orbital Theory for Drug Design (2020) (16)
Multi‐step processes in gas‐phase reactions of halomethyl anions XCH2− (X = Cl,Br) with CH3X and NH3 (1992) (16)
3-methylenetetrahydrofurans and 3-methylenepyrrolidines by addition of 2-(bromozincmethyl)-2-alkenyl ethers or 2-(chloromagnesiomethyl)-2-alkenyl ethers to aldehydes, ketones and imines followed by pd(0)-catalyzed cyclization (1992) (16)
1,4-Addition of a Terminal Phosphinidene Complex to [5]Metacyclophane. (1998) (16)
Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As) (2020) (16)
Synthesis of 1,3-metallatitanacyclobutanes of group 4 (1985) (16)
1,3‐DILITHIOPROPANES (1983) (16)
Nanoswitches based on DNA base pairs: why adenine-thymine is less suitable than guanine-cytosine. (2006) (16)
1,4‐Diphosphabutadiyne: A Realistic Target for Synthesis? A Theoretical Investigation of C2P2, C2N2, [Cr(CO)5PCCP], and [(CO)5Cr(PCCP)Cr(CO)5] (1999) (16)
Supramolecular H-bonded porous networks at surfaces: exploiting primary and secondary interactions in a bi-component melamine-xanthine system. (2013) (16)
Synthesis of deuterium labelled analogues of pristanic acid and phytanic acid for use as internal standards in stable isotope dilution analysis (1988) (16)
Unusual reactivity of highly strained cyclophanes (1998) (16)
How the disulfide conformation determines the disulfide/thiol redox potential (2015) (16)
CIDNP evidence for a radical pathway in the formation of Grignard reagents (1972) (16)
A new stable tricoordinate phosphorus(V) compound: P-2,6-dimethylphenyl-C,C-diphenylselenophosphene (1983) (16)
1,4‐Diphosphabutadiyne: A Realistic Target for Synthesis? A Theoretical Investigation of C2P2, C2N2, [Cr(CO)5PCCP], and [(CO)5Cr(PCCP)Cr(CO)5] (1999) (16)
Remote communication in a DNA-based nanoswitch. (2011) (16)
Scope and Limitations of the Flash Vacuum Thermolysis Approach to Small [n]Paracyclophanes. (1986) (16)
Cyclic 1,8-napththalenediyl compounds containing group 14 hetero atoms (1994) (16)
Base-Induced Imine-Forming 1,2-Elimination Reactions in the Gas Phase (1993) (16)
Synthesis and structure of phosphaalkenylmercury compounds (1992) (15)
Four‐Membered 1,8‐Naphthalenediyl Transition Metallacycles (1994) (15)
Structural interpretation of J coupling constants in guanosine and deoxyguanosine: modeling the effects of sugar pucker, backbone conformation, and base pairing. (2009) (15)
Alkali Metal Complexes of Silyl-Substituted ansa-(Tris)allyl Ligands: Metal-, Co-Ligand- and Substituent-Dependent Stereochemistry (2009) (15)
SYNTHESIS AND VALENCE ISOMERIZATIONS OF 1,1′‐TETRAMETHYLENEBICYCLOPROPENYL (1974) (15)
The constitution of the grignard reagent : VII. The degree of association of ethylmagnesium compounds in diisopropyl ether (1972) (15)
Photoelektronenspektroskopie und Konjugation – Direkter Beweis der ungewöhnlichen Sequenz der beiden obersten besetzten π‐Molekülorbitale im Phosphorin(Phosphabenzol)‐ und Arsenin(Arsabenzol)‐System (1972) (15)
MNDO Calculations on [n]metacyclophanes (1987) (15)
X-ray crystal structures and conformational analysis of bicyclo[5.3.1]undec-1(11)-enes: twisting versus pyradidalization in anti-bredt olefins. (2001) (15)
Rational design of near‐infrared absorbing organic dyes: Controlling the HOMO–LUMO gap using quantitative molecular orbital theory (2018) (15)
Addition of 2-(chloromagnesiomethyl)2-alkenyl ethers to epoxides followed by Pd(0)-catalyzed cyclization: a one-pot synthesis of 3-methylenetetrahydropyrans (1992) (15)
8,11-Dichloro-N-tosyl-3-aza[5]metacyclophane: A Highly Strained Aromatic System (1997) (15)
Formation of 1,3,5-Trilithiobenzene and Its Converson to the Corresponding Magnesium, Mercury, and Tin Derivatives. (1997) (15)
Symmetrical P4 cleavage at cobalt half sandwich complexes [(η5-C5H5)Co(L)] (L = CO, NHC)--a computational case study on the mechanism of symmetrical P4 degradation to P2 ligands. (2013) (15)
Reactions of the 9-mesityl-9-boraanthracene anion (1974) (15)
Hydrogen bonding of 3- and 5-methyl-6-aminouracil with natural DNA bases (2008) (15)
Doppelte CH‐Aktivierung eines maskierten Bismutamid‐Kations (2018) (15)
1,4-Addition of dichlorocarbene to 1,2-bismethylenecycloheptane (1982) (15)
Equilibrium CH-acidity in cyclohexylamine: the aromatic 9-mesityl-9-boraanthracene anion☆ (1974) (15)
Intramolecular zinc-ene reactions of alkynes; preparation of 1,5-annulated 4-methylenecyclopentenes (1992) (15)
Reactions of the donor-stabilized silylene bis[N,N'-diisopropyl-benzamidinato(-)]silicon(II) with Brønsted acids. (2014) (15)
Factors Controlling the Diels–Alder Reactivity of Hetero‐1,3‐Butadienes (2018) (15)
N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence (2020) (15)
A SIMPLE ONE POT SYNTHESIS OF 1-CHLOROPHOSPHOLES (1996) (15)
The first free 7 lambda(3)-phosphanorbornadiene (2000) (15)
Influence of steric factors on the coordination mode (h1 or h2) of phosphaalkenes to zerovalent Pt0L2 centres. X-ray structure of bis(triphenylphosphine){2,6-dimethyl phenyl)-9-fluorenylidenephosphine}platinum(0)-toluene (1986) (15)
A Quantitative Molecular Orbital Perspective of the Chalcogen Bond (2021) (14)
Role of the variable active site residues in the function of thioredoxin family oxidoreductases (2009) (14)
Stabilisation of 2,6-diarylpyridinium cation by through-space polar-π interactions. (2014) (14)
Trifluoromethyl Vinyl Sulfide: A Building Block for the Synthesis of CF3S-Containing Isoxazolidines (2018) (14)
How Mg2+ ions lower the SN2@P barrier in enzymatic triphosphate hydrolysis. (2018) (14)
First Four‐Membered Metallacycles of Rhenium (1987) (14)
Switching between OPTX and PBE exchange functionals (2009) (14)
A novel synthesis of short‐bridged [m]paracyclophanes: Preliminary communication (1977) (14)
Steric effects on alkyl cation affinities of maingroup‐element hydrides (2011) (14)
The synthesis and structure of zinccacyclopentane, zincacyclohexane and zincacycloheptane (1982) (14)
Intermediates in the reaction of a triarylphosphaethene with sulfur (1984) (14)
Nature and strength of chalcogen-π bonds. (2018) (14)
A dual attack on the peroxide bond. The common principle of peroxidatic cysteine or selenocysteine residues (2020) (14)
A donor-functionalized, silyl-substituted pentadienyllithium: structural insight from experiment and theory. (2011) (14)
[5]metacyclophanes a spectroscopic and theoretical investigation of structure and conformation (1983) (14)
A methodology for the photocatalyzed radical trifluoromethylation of indoles: A combined experimental and computational study (2018) (14)
a-Stabilisierung von Carbanionen: Fluor bertrifft die schwereren Halogene (2006) (14)
The formation of grignard compounds—V: The reaction of iodomethane with magnesium in allyl phenyl ether. A second-order cidnp spectrum (1978) (14)
Covalent versus ionic bonding in alkalimetal fluoride oligomers (2007) (14)
Synthesis and Reactivity of 2-Iodophosphinines (1993) (14)
Attempted synthesis of dibenzo[b,e]borin (9-boraanthracene) and its formation under electron impact (1970) (14)
Dibenzo[b,d]phosphorin (1968) (14)
SN2 versus E2 Competition of F– and PH2– Revisited (2020) (14)
Biosynthesis of malonomicin. Part 1. 13C nuclear magnetic resonance spectrum and feeding experiments with 13C-labelled precursors (1979) (14)
One-pot preparation of 3-methylenepyrrolidines with high diastereomeric excess (1993) (13)
Source of Cooperativity in Halogen-Bonded Haloamine Tetramers. (2016) (13)
Aggregation and cooperative effects in the aldol reactions of lithium enolates. (2013) (13)
Halogen versus halide electronic structure (2010) (13)
The structure of delphinine (1959) (13)
Synthesis and x-ray crystal structure of 11-bromo-endo-9-chloro-7-ethoxybicyclo[5.3.1]undec-1(11)-ene. A stable highly strained anti-Bredt olefin (1992) (13)
tert-Butyl cation affinities of maingroup-element hydrides: effect of methyl substituents at the protophilic center. (2011) (13)
Carbanions as Intermediates in the Synthesis of Grignard Reagents (1988) (13)
Conformational behavior of basic monomeric building units of glycosaminoglycans: isolated systems and solvent effect. (2007) (13)
Cesium's Off‐the‐Map Valence Orbital (2017) (13)
Stabilization of 2,6-Diarylanilinum Cation by Through-Space Cation−π Interactions (2017) (13)
B-DNA model systems in non-terran bio-solvents: implications for structure, stability and replication. (2017) (13)
(Ph4P)S6—A Compound Containing the Cyclic Radical Anion S6.− (2000) (13)
The structure of neoline (1960) (13)
Synthesis and properties of 6-acetoxy-1,4-dithiocin (1978) (13)
Zircona‐ and Hafnacyclobutenes—A New Route to Metallacyclobutanes (1983) (13)
Erste Vierring‐Metallacyclen mit Rhenium (1987) (13)
Intramolecular alkoxycobaltation: a novel route to the cobalt–carbon bond in a coenzyme B12 model (1993) (13)
A new type of organometallic spiro compounds: 2,2,6,6-tetracyclopentadienyl-4-sila-2,6-dititanaspiro[3.3]heptane (1986) (13)
Tricarbonylchromium complexes of [5]- and [6]metacyclophane: an experimental and theoretical study (2008) (13)
Addition of 2-(phenoxymethyl)-2-propenylmagnesium chloride to epoxides followed by Pd(0)-catalyzed cyclization: A one-pot synthesis of 3-methylenetetrahydropyrans (1989) (13)
Pentacyclo[4.3.1.01,6.07,908,10]decane. A cyclopropane edge-bridged prismane and its rearrangement to a fulvene (1987) (13)
Kekulene : Structure, stability and nature of H•••H interactions in large PAHs (2017) (13)
Tricarbonylchromium complexes of [5]- and [6]metacyclophane: an experimental and theoretical study (2008) (13)
Bromo-1-ethoxy-7-norbornylmagnesium a stable alicyclic β-alkoxy-substituted grignard compound (1971) (13)
Self-assembly of N3-substituted xanthines in the solid state and at the solid-liquid interface. (2013) (13)
Isolated excited electronic states in the unimolecular gas-phase ion dissociation processes of the radical cations of isocyanogen and cyanogen (1991) (13)
Bond Activation by Group-11 Transition-Metal Cations (2009) (13)
X2Y2 isomers: tuning structure and relative stability through electronegativity differences (X = H, Li, Na, F, Cl, Br, I; Y = O, S, Se, Te). (2013) (13)
Isolated excited electronic states in the unimolecular gas-phase ion dissociation processes of the radical cations of isocyanogen and cyanogen (1991) (13)
Eight-coordinate fluoride in a silicate double-four-ring (2017) (13)
1,2‐Dilithioethane from Ethylene and Lithium (1988) (13)
Asymmetric identity SN2 transition states: Nucleophilic substitution at α-substituted carbon and silicon centers (2017) (13)
Die Aktivierung von Phenylmagnesiumverbindungen durch Kronenether (1988) (13)
Performance of TDDFT Vertical Excitation Energies of Core‐Substituted Naphthalene Diimides (2020) (12)
How Alkali Cations Catalyze Aromatic Diels‐Alder Reactions (2020) (12)
Origin of the α‐Effect in SN2 Reactions (2021) (12)
Properties of Substituted Triarylphosphaalkenes (1987) (12)
Nature of the Ru−NO Coordination Bond: Kohn–Sham Molecular Orbital and Energy Decomposition Analysis (2017) (12)
6,7‐Bis(methoxycarbonyl)‐2,3‐dimethyl‐[5](1,4)naphthalenophane, the First Benzoannelated [5]Paracyclophane (1995) (12)
Ambident Nucleophilic Substitution: Understanding Non‐HSAB Behavior through Activation Strain and Conceptual DFT Analyses (2020) (12)
Dual Activation of Aromatic Diels–Alder Reactions (2019) (12)
A versatile method for the synthesis of 1,3-metallatitanacyclobutanes (1985) (12)
Synthesis and Characterization of β‐Phosphaenones An Investigation on the Conjugative Properties of the PC Bond (1995) (12)
Enhanced π-Back-Donation as a Way to Higher Coordination Numbers in d10 [M(NHC)n ] Complexes: A DFT Study. (2017) (12)
The Substituent Effect of the Phosphaalkenyl Group (2003) (12)
Intramolecularly alkylated Costa complexes: New models for coenzyme B12 with a cobalt-to-ligand carbon bridge (1995) (12)
Easy Preparation of 1,3-Di-tert-Butylbenzene and Some Derivatives Thereof (1996) (12)
Lewis Acid‐Catalyzed Diels‐Alder Reactions: Reactivity Trends across the Periodic Table (2021) (12)
SN2 substitution with inversion at a cyclopropyl carbon atom: formation of 9-oxatetracyclo[6.2.1.01,6.06,10]undecane (1982) (12)
First synthesis of an olefin-coordinated platina(II) cyclobutane and its conversion into diphosphineplatina(II) cyclobutanes (1987) (12)
Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions† (2020) (12)
Total synthesis of c19-diterpene alkaloids: construction of a functionalized bcd-ring system (1986) (12)
The pnictogen bond: a quantitative molecular orbital picture† (2021) (12)
The intermediate formation of [4]metacyclophane on flash vacuum thermolysis (1988) (12)
Homolytic versus heterolytic dissociation of alkalimetal halides: the effect of microsolvation. (2009) (12)
Organomagnesium Clusters: Structure, Stability, and Bonding in Archetypal Models (2011) (12)
A convenient synthesis of germacyclobutanes (1984) (12)
6,7‐Bis(methoxycarbonyl)‐2,3‐dimethyl‐[5](1,4)naphthalinophan, das erste benzoanellierte [5]Paracyclophan (1995) (12)
Synthesis of 1,3,5-tri- and 1,2,4,5-tetrasubstituted tin and mercury derivatives of benzene. Crystal structure of 1,3,5-tris(chloromercurio)benzene (2000) (12)
ATTEMPTED SYNTHESIS OF TRIMESITYLPHOSPHAETHENE; OBSERVATIONS RELATED TO THE MECHANISM OF ACID CATALYZED NUCLEOPHILIC SUBSTITUTIONS AT PHOSPHORUS (III) (1984) (11)
The formation of Grignard compounds - IV Direct proof for the formation of RMgX as primary product in the reaction of organic halides with magnesium (1975) (11)
All-metal aromatic clusters M4(2-) (M = B, Al, and Ga). Are π-electrons distortive or not? (2011) (11)
Diels-Alder Reactions of Trichlorophosphaethene. (1995) (11)
The role of protein plasticity in computational rationalization studies on regioselectivity in testosterone hydroxylation by cytochrome P450 BM3 mutants. (2012) (11)
Synthesis and thermolysis of 1,4-pentamethylene(Dewar benzene) (1976) (11)
9,10-Dimetallatriptycenes of group 14: a novel synthetic approach from ortho-phenylenemagnesium. (1996) (11)
Intramolecular coordination between magnesium and oxygen in cyclic organomagnesium compounds (1982) (11)
1,4-Addition von Dihalogencarbenen an 1,3-Diene† (1985) (11)
Sulfur-sulfur three-electron bond dissociation enthalpies of dialkyl sulfide dimer radical cations (1998) (11)
Carbanionen als Zwischenstufen bei der Synthese von Grignard-Reagentien (1988) (11)
Highly polar bonds and the meaning of covalency and ionicity--structure and bonding of alkali metal hydride oligomers. (2007) (11)
Regioselectivity in Electrophilic Aromatic Substitution: Insights from Interaction Energy Decomposition Potentials (2011) (11)
The substituent effect on benzene dications. (2014) (11)
How Solvation Influences the SN2 versus E2 Competition (2021) (11)
The electronic structure of chichibabin's hydrocarbon (1978) (11)
The Importance of (Intramolecular) Solvation in Organomagnesium Chemistry (1992) (11)
Substituent effects on the optical properties of naphthalenediimides: A frontier orbital analysis across the periodic table (2016) (11)
Chalcogen bonds: Hierarchical ab initio benchmark and density functional theory performance study (2021) (11)
The reaction of grignard reagents with 1,3-dioxolanes. Influence of solvation; kinetics and mechanism (1974) (11)
A convenient synthesis of cyclobutanone (1983) (11)
Computational (DFT) and Experimental (EXAFS) Study of the Interaction of [Ir(IMes)(H)2 (L)3 ] with Substrates and Co-substrates Relevant for SABRE in Dilute Systems. (2015) (11)
Six-coordinate Group 13 complexes: the role of d orbitals and electron-rich multi-center bonding. (2015) (11)
Säurekatalysierte Olefinierung von Benzaldehyd (1994) (10)
1,4‐Addition of Dihalocarbenes to 1,3‐Dienes (1985) (10)
Synthesis of metallacyclobutanes and metallacyclobutabenzenes of molybdenum and tungsten (1988) (10)
Asymmetric addition of B-[2-(phenoxymethyl)-2-propenyl]bis(2-isocaranyl)borane to aldehydes and further cyclization to chiral 3-methylenetetrahydrofurans (1993) (10)
Synthesis and Structure of ortho‐Phenylenezinc (1996) (10)
The synthesis of hetero-bridged [5](3,6)oxepinophanes (1985) (10)
“Forbidden” Four-Center Reactions: Molecular Orbital Considerations for N2 + N2 and N2 + N2+ (1997) (10)
The Gauche Effect in XCH2CH2X Revisited (2021) (10)
Understanding the 1,3‐Dipolar Cycloadditions of Allenes (2020) (10)
Ion-Pair SN 2 Reaction of OH- and CH3 Cl: Activation Strain Analyses of Counterion and Solvent Effects. (2018) (10)
1,2-dimagnesium derivatives of cyclopropane (1981) (10)
Synthesis of Alkynyl-Substituted 9,10-Dimetallatriptycenes of Group 14 and Their Application in the Preparation of a Novel Class of Organometallic Oligomers. (1998) (10)
Watson-crick base pairs with thiocarbonyl groups: How sulfur changes the hydrogen bonds in DNA (2008) (10)
Recent Developments in Phosphasilene Chemistry (1990) (10)
A novel synthesis of 10‐aryl‐9‐arsaanthracenes (1977) (10)
9-Hydroxy [7]metacyclophane (1984) (10)
Ligand‐Mediated Regioselective Rhodium‐Catalyzed Benzotriazole–Allene Coupling: Mechanistic Exploration and Quantum Chemical Analysis (2019) (10)
1,4-trimethylene(Dewar benzene) (1975) (10)
Alkali Metal Cation Affinities of Anionic Main Group-Element Hydrides Across the Periodic Table. (2017) (10)
The reaction of Grignard reagents with 1,3-dioxolanes (1978) (10)
1,4‐Dithiocin‐6‐yl Acetate (1974) (10)
The structure and substitution of the C-D ring system of delphinine (1958) (10)
Wie Dihalogene Michael‐Additionsreaktionen katalysieren (2019) (10)
Recognition of shorter and longer trimethyllysine analogues by epigenetic reader proteins. (2018) (10)
Interconversions of titanocene-methylene complexes (1987) (10)
New Insights into the Reactivity of Cisplatin with Free and Restrained Nucleophiles: Microsolvation Effects and Base Selectivity in Cisplatin-DNA Interactions. (2016) (10)
Interaction of diphenylzinc with 1,3-xylyl crown ethers. Crystal structures of three 1:1 complexes (1991) (10)
Anionic ether cleavage of tetrahydrofuran in the gas phase (1993) (10)
Konjugierte addition von 2-(bromzinkmethyl)-3-phenoxy-1- propen an methylenmalonsäurederivate; weitere umsetzung zu methylencyclopentanen (1992) (10)
Beiträge zur Entwicklung psychotroperStoffe, 2. Mitt.: Basisch substituierte Dibenzo-oxepin-, Dibenzo-thiepin- und Dibenzo-cycloocten-Derivate (1962) (10)
Synthesis of the Mono(Dewar Benzene) Isomer of [1.1]Metacyclophane (1993) (10)
Reactivity of Phosphaalkenes (1983) (10)
Selective C-H and C-C Bond Activation: Electronic Regimes as a Tool for Designing d(10) MLn Catalysts. (2015) (10)
Synthesis of bis(phosphine)-1,2-dihydroplatina(II)cyclobutabenzenes. Molecular structure of the 1,2-dihydroplatina(II)cyclobutabenzene [cyclic] Pt(CH2-o-C6H4)(PMe3)2 (1989) (10)
Synthese des Mono-Dewar-Benzol-Isomers von [1.1]Metacyclophan† (1993) (9)
Group 9 Metallacyclopentadienes as Key Intermediates in [2+2+2] Alkyne Cyclotrimerizations. Insight from Activation Strain Analyses. (2018) (9)
The chemical shift of EtMgBr and Et2Mg as a qualitative measure of the basicity of electron-donating solvents (1978) (9)
Hydrogenation of [5]- and [6]Metacyclophane: Reactivity and Thermochemistry (2000) (9)
12,15-Dichloro[3.0]orthometa- cyclophane: A Highly Strained Biphenylophane. (1998) (9)
The Chemical Bond: When Atom Size Instead of Electronegativity Difference Determines Trend in Bond Strength (2021) (9)
Bifunktionelle und cyclische Organomagnesiumverbindungen, II1) 1‐Oxa‐5‐magnesiacyclooctan (1972) (9)
(μ‐Methylene)bis(methylzirconocene): Preparation, Molecular Structure, and Thermal Disproportionation (2004) (9)
[4]Paracyclophane: MNDO and STO‐3G molecular structure and strain energy (1990) (9)
The constitution of the Grignard reagent: X. Complexes of some organomagnesium compounds with an electron donor in benzene (1978) (9)
Chiroptical properties of 12,15-dichloro[3.0]orthometacyclophane—correlations between molecular structure and circular dichroism spectra of a biphenylophane (1999) (9)
Free Radicals in Grignard Reactions (1974) (9)
The crystal and molecular structure of polymeric [(dineopentylmagnesium)2 · (neopentylmagnesium bromide)2]n: an unsolvated alkylmagnesium species (1989) (9)
Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length (2021) (9)
C-Halophosphaalkenes: Probing the range of stability and reactivity towards bromine† (1994) (9)
1,4-Addition eines terminalen Phosphiniden-Komplexes an [5]Metacyclophan. (1998) (9)
Intramolecularly alkylated Cosalen complexes: thermolysis and photolysis of coenzyme B12 models with a cobalt-to-ligand carbon bridge. (1998) (9)
Photochemical synthesis of arenetricarbonylchromium(0) complexes: scope and limitations (1989) (9)
On the Origin of Regioselectivity in Palladium‐Catalyzed Oxidation of Glucosides (2020) (9)
Trends and anomalies in H–AHn and CH3–AHn bond strengths (AHn = CH3, NH2, OH, F) (2009) (9)
Beiträge zur Entwicklung psychotroper Stoffe, 4. Mitt.: Diphenylamin-Derivate mit piperidylsubstituierten Seitenketten (1962) (9)
Synthetic studies related to 1,4-dithiocin (1977) (9)
FUNCTIONALIZATION OF 1,3-PHENYLENE-16-CROWN-5 VIA DIRECT LITHIATION (1996) (9)
Structure and bonding of methyl alkali metal molecules (2006) (9)
Proton Transfer and SN 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx. (2020) (8)
Flash vacuum thermolysis and mass spectroscopy of 9,10-dihydro-9-silaanthracenes (1990) (8)
Distortion‐Controlled Redshift of Organic Dye Molecules (2019) (8)
A convenient and general synthesis of 1,2-dimethylenecycloalkanes (1978) (8)
10-Phenyldibenz[b,e]arsenin (1970) (8)
The dimerization of some magnesacycloalkanes and benzomagnesacycloalkenes; the relation between ring size, ring strain and degree of association (1982) (8)
Oxidative addition of hydrogen halides and dihalogens to Pd. Trends in reactivity and relativistic effects. (2006) (8)
Intra-annular reactions of the (1,3-xylylene)-18-crown-5 system: synthesis and crystal structure of [2-(bromomagnesio)-1,3-xylylene]-18-crown-5, [2-(bromomercurio)-1,3-xylylene]-18-crown-5 and bis[(1,3-xylylene-18-crown-5)-2-yl]mercury (1993) (8)
8 Energy decomposition analysis in the context of quantitative molecular orbital theory (2021) (8)
Understanding the differences between iron and palladium in cross-coupling reactions (2019) (8)
Investigations of a highly crowded phosphino‐substituted biphenyl: A precursor for a λ3, λ5‐diphosphaphenanthrene (1991) (8)
Synthesis, Structure, and Properties of an Intramolecularly Coordinated Diindacycle: 9,10-Dihydro-9,10-bis[2,6-bis((dimethylamino)methyl)- phenyl]-9,10-diindaanthracene (1997) (8)
Synthesis of 1-phosphaadamantane (1983) (8)
Complexes of 4‐substituted phenolates with HF and HCN: Energy decomposition and electronic structure analyses of hydrogen bonding (2013) (8)
Reactivity of organozinc derivatives of phosphinines. (1996) (8)
The silver(I) catalyzed rearrangement of bicyclopropenyls evidence for a stepwise mechanism (1975) (8)
3-Methyl-2-Ethyl-2-Phosphanaphthalene (1973) (8)
Diels-Alder reactivities of cycloalkenediones with tetrazine (2019) (8)
How metallylenes activate small molecules† (2021) (8)
Dichlorocarbene Addition to [5]Metacyclophane; Experimental and Calculational Evidence for (2000) (8)
Model experiments on the construction of the ABE ring system of hetisine type diterpene alkaloids (1975) (8)
An investigation of the structure of the so-called phenarsazine:Mass spectroscopical evidence for the thermal formation of phenarsazine (1975) (8)
Orbital interactions and charge redistribution in weak hydrogen bonds: Watson–Crick GC mimic involving C ? H proton donor and F proton acceptor groups (2006) (8)
1,2-Dimetalated Benzene Derivatives (1,2-C6H4MCH3)n of Group 13 (M = Al, Ga, ln) (1999) (8)
Mechanism of biomolecular recognition of trimethyllysine by the fluorinated aromatic cage of KDM5A PHD3 finger (2020) (8)
1,4-Addition of a Phosphinidene Complex to Cisoid 1,3-Dienes (2000) (7)
The stereochemistry of the 1,4-addition of dibromocarbene to 1,2-dimethylenecycloheptane (1989) (7)
Note on the solvent dependence of the 1H-NMR coordination chemical shifts of tricarbonyl(η6-[8]paracyclophane)chromium. A caveat concerning its interpretation (1990) (7)
Synthesis and X-ray crystal structure of 2-(methoxymethyl) phenyldicyclopentadienyltitanium(III) (1997) (7)
9,10-Dimetallatriptycenes of Group 14: a structural study. (1998) (7)
The Equilibrium Acidity of A 9,10-Dihydrosilaanthracene on the Degree of Aromaticity of a System with Tetracoordinate Silicon (1974) (7)
Chemical reactivity from an activation strain perspective (2021) (7)
Structures and strain energies of small [n]metacyclophanes (2000) (7)
A Convenient Direct Method for the Preparation of β-Keto-Acids (1979) (7)
Synthesis and Anomalous Structure-Reactivity Relationship of 8,11-Dichloro[5]metacyclophan-3-one (2001) (7)
Probing Through-Space Polar-π Interactions in 2,6-Diarylphenols. (2019) (7)
Addition of alkyl-lithium reagents to alkenylamines and to an alkenyl sulphide (1971) (7)
1-OXA-2-MAGNESIACYCLOHEXANE (1977) (7)
New trends in dimetallic synthons (1990) (7)
[5]Metacyclophane: ab initio STO-3G molecular structure and strain energy (1989) (7)
High-resolution infrared spectroscopy of the charge-transfer complex [Ar-N2]+: a combined experimental/theoretical study. (2005) (7)
Comparison of Molecular Recognition of Trimethyllysine and Trimethylthialysine by Epigenetic Reader Proteins (2020) (7)
The Constitution of the grignard reagent VI. The degree of association of ethylmagnesium compounds in 1-ethoxy-2-methylbutane (1968) (7)
Thermal and electron-impact induced 1,4 aryl migration from phosphorus to carbon (1976) (7)
Biosynthesis of malonomicin-III advanced precursor studies using 2H nuclear magnetic resonance spectroscopy (1982) (6)
The formation of catenanes. The mobius strip approach revisited. (1996) (6)
The reaction of Grignard reagents with 1,3-dioxolanes : III. A novel synthetic route to β-hydroxyalkyl enol ethers (1978) (6)
Mechanism of the unusual ether cleavage of (2-methoxy-1,3-xylylene)-15-crown-4 by organomagnesium reagents (1993) (6)
A computational study on the reactivity enhancement in the free radical polymerization of alkyl α‐hydroxymethacrylate and acrylate derivatives (2013) (6)
Glucose-Nucleobase Pseudo Base Pairs: Biomolecular Interactions within DNA. (2016) (6)
Flash vacuum thermolysis of 5,6,8,9-tetrahydro-4'-methylenespiro[7H-benzocycloheptene-7,1'-cyclohexa-2',5'-diene]. The intermediate formation of [3,2]orthoparacyclophane (1986) (6)
Cope rearrangement of a bicyclopropenyl (1975) (6)
Macrocycles All Aflutter: Substitution at an Allylic Center Reveals the Conformational Dynamics of [13]-Macrodilactones. (2017) (6)
Beiträge zur Entwicklung psychotroper Stoffe, VI. Basisch substituierte Dibenzo[b.e]thiocin‐Derivate (1965) (6)
1,2‐Dilithioethan aus Ethylen und Lithium (1988) (6)
The radical anion of 2-phosphanaphthalene (1974) (6)
CRYSTAL STRUCTURE OF SOLVENT FREE [2-(DIMETHYLAMINOMETHYL)PHENYL]ALUMINIUM DICHLORIDE (1995) (6)
Trapping of the highly strained [5](2,4)quinolinophane system (2007) (6)
Tandem mass spectrometry of silver-adducted ferrocenyl catalyst complexes. (2010) (6)
Palladium(0)-catalyzed non-concerted Cope rearrangement (1992) (6)
Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes (2019) (6)
Silylene‐Induced Reduction of [Mn2(CO)10]: Formation of a Five‐Coordinate Silicon(IV) Complex with an O‐Bound [(OC)4Mn=Mn(CO)4]2– Ligand (2017) (6)
NONCOVALENT INTERACTIONS IN ORGANOMETALLIC COMPOUNDS : FORMATION OF AN INTRAMOLECULAR METAL-CARBON ION PAIR IN ZIRCONIUM BORATE BETAINES (1997) (6)
The structure of the antibiotic K16. I. The dipeptide side chain. (1972) (6)
Radikale bei Grignard‐Reaktionen (1974) (6)
THE MOLECULAR STRUCTURE OF A GERMACYCLOBUTANE BY GAS ELECTRON DIFFRACTION AND AB INITIO MOLECULAR ORBITAL CALCULATIONS (1997) (6)
A 13C NMR investigation of [5]metacyclophanes (1986) (6)
O-Phenylenemagnesium tetramer: the first organomagnesium cluster (1991) (6)
The synthesis and some applications of new 1,3-dilithiopropanes: dimethylbis(α-lithiobenzyl)silane and its germanium analogue (1988) (6)
The structure of the antibiotic K16. II. Chromophore and total structure. (1972) (6)
The optical activity of ethers solvating Grignard compounds. (1966) (5)
Ab Initio and DFT Benchmark Study for Nucleophilic Substitution at Carbon ( SN 2 @ C ) and Silicon ( SN 2 @ Si ) (2005) (5)
Attempted syntheses of 9‐stibaanthracene and 10‐phenyl‐9‐stibaanthracene (1979) (5)
Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (2018) (5)
Toward Transition‐Metal‐Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling (2019) (5)
Carbenoid routes to substituted phosphaalkenes and phosphabenzenes (1993) (5)
The Grignard Reagent Formation Reaction of 2-Chloro-1,1,1-triphenylethane Revisited (2008) (5)
Regioselectivity of the Pauson-Khand reaction in single-walled carbon nanotubes. (2018) (5)
A comparative investigation of 1,4-pentamethylene and 1,4-hexamethylene Dewar benzene: Evidence for the intermediate formation of [5]paracyclophane (2010) (5)
Rotational and rovribrational spectrum of C15NC15N in the region of the bending modes n4, n5, the combination band v4+v5 and the Fermi interacting n3, 2v41. (1996) (5)
(Ph4P)S6 - eine Verbindung mit dem cyclischen Radikalanion S6˙–**. (2000) (5)
Bicyclo[2,2,2]oct-1-ene; formation from 1-ethoxybicyclo[2,2,2]oct-2-yl-lithium and reaction with t-butyl-lithium (1973) (5)
Formation of a Trifluorophosphane Platinum(II) Complex by P-F Bond Activation of Phosphorus Pentafluoride with a Pt0 Complex. (2017) (5)
The silver ion promoted valence isomerization of 1,1′-dimethylbicyclopropenyl. (1972) (5)
Flash vacuum thermolysis of dispiro[2.2.n.2]alkadienes (1987) (5)
2‐alkoxy‐3‐methylenetetrahydrofurans by addition of 2‐(bromozincmethyl)‐3,3‐dialkoxy‐1‐propenes to aldehydes and ketones followed by Pd(0)‐catalyzed cyclization (1990) (5)
Diastereoselective one-pot synthesis of tetrafunctionalized 2-imidazolines. (2014) (5)
The synthesis of substituted bicyclo[3.2.1]octa‐2,6‐dienes (2010) (5)
A convenient synthesis of 2-halo-5-chloro-m-xylenes (1985) (5)
Selective lithiation of 1-bromo-2[(trimethylstannyl)methyl]benzene: synthesis of 1-bromo-2-(lithiomethyl)benzene, 1-lithio-2-[(trimethylstannyl)methyl]benzene, and .alpha.,2-dilithiotoluene (1990) (5)
6-Phenyldibenzo[b,d]phosphinine (2003) (5)
Through‐Space Polar‐π Interactions in 2,6‐Diarylthiophenols (2020) (5)
Intraannular functionalization of the 1,3-phenylene-19-crown-6 system via bromine–lithium exchange (1999) (5)
Mass spectral fragmentation of some phosphaaromatic compounds (1975) (5)
Substituent Effects on Hydrogen Bonds in DNA : A Kohn-Sham DFT Approach (2006) (4)
Blitzvakuumthermolyse von 1‐Chlor‐4‐methylen‐spiro[2.m]alkanen (1986) (4)
Synthese und Struktur von ortho‐Phenylenzink (1996) (4)
o‐Dilithium‐benzol (1957) (4)
Neue heterocyclische Ringsysteme (1962) (4)
Radical Scavenging Potential of the Phenothiazine Scaffold: A Computational Analysis (2021) (4)
Origin of the α‐Effect in S N 2 Reactions (2021) (4)
Unusual Reactions of Halo[5]metacyclophanes (2002) (4)
Synthesis and Properties of Phosphaalkenes (1981) (4)
Synthesis, photochemical behaviour and cis/trans isomerisation of 1-(2,4,6-triisopropylphenyl)-2-(2,4,6-tri-tert-butylphenyl)diphosphene (1993) (4)
Compounds containing localized carbdn—phosphorus double bonds I. Diels-Alder reaction of 3-methyl-2-phosphanaphthalene with hexafluorobutyne-2. (1978) (4)
C(CN)5–: transition state or intermediate? (2010) (4)
Rational design of iron catalysts for C–X bond activation (2022) (4)
Molecular Structure of 1,3,5-Tris (Trimethylstannyl) Benzene: An Electron Diffraction Study (1998) (4)
π‐Electronic communication through mono and multinuclear gold(I) complexes (2009) (4)
The Nature of Nonclassical Carbonyl Ligands Explained by Kohn–Sham Molecular Orbital Theory (2020) (4)
Gas-Phase Base-Induced 1,4-Eliminations: Occurrence of Single-, Double-, and Triple-Well E1cb Mechanisms J. Am. Chem. Soc. 1995, 117, 9889−9899 (1996) (4)
Probing Halogen-π versus CH-π Interactions in Molecular Balance. (2020) (4)
E2 and S(N)2 Reactions of X- + CH3CH2X (X = F, Cl); an ab Initio and OFT Benchmark Study (vol 4, pg 929, 2008) (2008) (4)
10-Heterosubstituted arsaanthracenes (1975) (4)
The Electronic Nature of the P=C Bond (1990) (4)
Supramolecular Ring Structures of 7-Methylguanine: A Computational Study of Its Self-assembly and Anion Binding (2012) (4)
Diastereoselective Synthesis of β-Lactams by Ligand-Controlled Stereodivergent Intramolecular Tsuji–Trost Allylation (2020) (4)
Activation Strain Analyses of Counterion and Solvent Effects on the Ion‐Pair SN2 Reaction of NH2− and CH3Cl (2019) (4)
The mean bond dissociation energy of the carbonmagnesium bond in bis(2,2-dimethylpropyl)magnesium (2010) (4)
Unusual metalation and halogen-metal exchange reactions between 1,3-xylyl crown ethers and organomagnesium reagents. X-ray structure of 2-[(p-tert-butylphenyl)magnesio]-1,3-xylylene-18-crown-5. [Erratum to document cited in CA115(21):232313a] (1992) (4)
A remarkable halogen‐zinc exchange reaction; X‐ray crystal structure of (2‐iodozincio‐1,3‐xylylene)‐15‐crown‐4 (1993) (4)
Book Review: Essentials of Computational Chemistry Theories and Models. By Christopher J. Cramer (2003) (4)
SYNTHESIS OF 9, 10-DIMETALLATRIPTYCENES CONTAINING GROUP 15 ELEMENTS FROM ortho-PHENYLENEMAGNESIUM (1999) (4)
In Quest of the Double Rotaxane Formation of the Bis(coronand) (1,5),(2,4)‐Durenetetrayl‐bis(18‐crown‐5) with Organomagnesium Compounds (2004) (4)
The remarkable crystal structure of the dimeric species [bis(ortho-anisyl)magnesium · THF]2 (1991) (4)
Nucleophilic substitution at di- and triphosphates: leaving group ability of phosphate versus diphosphate (2019) (4)
The rotation barrier in ethane (2004) (4)
7,14-Dichloro[1.1]metacyclophane: A Highly Strained Aromatic Intermediate. (1997) (4)
On the formation of the so-called arsanthrene (1979) (4)
Dynamic stereochemistry of 10-substituted 9-mesityl-9,10-dihydro-9-boraanthracene compounds (1980) (4)
Nonlinear d 10 -ML 2 Transition-Metal Complexes (2013) (4)
Inside Cover: Analyzing Reaction Rates with the Distortion/Interaction-Activation Strain Model (Angew. Chem. Int. Ed. 34/2017) (2017) (4)
Bridged Ring Compounds by Malonic Ester Synthesis (1977) (3)
Selective Synthesis of (unsymmetrical) aromatic biscoronands. (1996) (3)
Watson-Crick hydrogen bonds : Nature and role in DNA replication (2006) (3)
The Knoevenagel condensation of malononitrile with some cyclic β-keto-esters. A correction (1970) (3)
Reaction of (1,8-naphtalenediyl)magnesium with group 5 and 6 metallocene dichlorides. Formation and crystal structure of (ethasup5-Cp)Mo(PMEsub3)(ethasup3-6b-H-7,9a-dihydrocyclopent[a]acenaphtylen-7-yl) (1994) (3)
Beiträge zur Entwicklung psychotroper Stoffe, 5. Mitt. (1964) (3)
d10-ML2 Complexes: Structure, Bonding, and Catalytic Activity (2014) (3)
Synthesis of β-Hydroxy Esters by Lithium/Ammonia Reduction of α,β-Epoxy Esters (1990) (3)
S N 2 versus E2 Competition of F − and PH 2 − Revisited (2020) (3)
Nucleophilic substitution of aromatic bromine in 2‐bromobenzophenone by Grignard reagents (1974) (3)
Alkali-metal-supported bismuth polyhedra-principles and theoretical studies. (2011) (3)
Origin of asynchronicity in Diels–Alder reactions (2021) (3)
Conjugated exocyclic dienes by addition of 2-(benzyloxymethyl)-3-(bromozincmethyl)-1,3-but adiene to aldehydes, ketones and imines followed by Pd(0)-catalyzed cyclization (1989) (3)
A new model for coenzyme B12 with an intramolecular cobalt–carbon bridge (1991) (3)
NICHTKOVALENTE WECHSELWIRKUNGEN BEI ORGANOMETALLVERBINDUNGEN : INTRAMOLEKULARE METALL-KOHLENSTOFF-IONENPAARBILDUNG BEI ZIRCONIUM-BORAT-BETAINEN (1997) (3)
Activation of organomagnesium reagents by crown ethers: unusual ether cleavage of (2-methoxy-1,3-xylylene)-15-crown-4 (1991) (3)
Effects of the protonation state in the interaction of an HIV-1 reverse transcriptase (RT) amino acid, Lys101, and a non nucleoside RT inhibitor, GW420867X (2014) (3)
Anion formation versus nitrile ⇆ ketenimine tautomerism in alkylidene malononitriles and cyanoacetates (1975) (3)
Structures of Organomagnesium Compounds as Revealed by X‐Ray Diffraction Studies (2000) (3)
Arsanthren (9,10-diarsaanthracen) (1970) (3)
Diels‐Alder Reactions of [5]Metacyclophane (1982) (3)
Do sulfonamides interact with aromatic rings? (2020) (3)
Attraktiv und überzeugend (2008) (3)
Alkali Metal Cation versus Proton and Methyl Cation Affinities: Structure and Bonding Mechanism (2016) (3)
The synthesis of four-membered spiro compounds of silicon and germanium: 2,2,6,6-tetramethyl-4-metallaspiro[3.3]heptanes (1986) (3)
Special Collection: Computational Chemistry. (2019) (3)
Outer valence orbital response to proton positions in prototropic tautomers of adenine (2006) (3)
A new approach to 1, 2‐dilithioethane; easy preparation of dilithiomethane (2010) (3)
β-Substituted cyclopropyl radicals (1983) (3)
Proton Transfer and SN 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx. (2021) (3)
The synthesis of 1,1′‐dimethylbicyclopropenyl: (Short Communication) (2010) (2)
Some Investigations on [6]Metacyclophanes (2001) (2)
3-Aza[5]metacyclophanes: Synthesis and Reactions (2001) (2)
B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order (2022) (2)
Palladium‐Catalyzed Activation of Carbon–Halogen Bonds: Electrostatics‐Controlled Reactivity (2022) (2)
Racemization and Deracemization through Intermolecular Redox Behaviour. (2019) (2)
Biosynthesis of malonomicin-II proton and deuteron NMR spectra (1982) (2)
Benchmark Study on the Smallest Bimolecular Nucleophilic Substitution Reaction: H−+CH4 → CH4+H− (2013) (2)
SN2 versus SN2′ Competition (2022) (2)
Phosphasilene Synthesis and Reactivity. An Improved Route to 1‐(2,4,6‐ Tri‐tert.‐butylphenyl)‐2‐tert.‐butyl‐2‐(2,4,6‐tri‐isopropylphenyl) phosphasilene. (1991) (2)
X2Y2 Isomers: Tuning Structure and Relative Stability Through Electronegativity Differences (X: H, Li, Na, F, Cl, Br, I; Y: O, S, Se, Te). (2013) (2)
Attractive and convincing. (2008) (2)
Investigations on the Reactivity of Bis(bromomagnesio)trimethylsilylmethane - Molecular Structure of a Tebbe-Type Spiro-Organomagnesium Compound (2004) (2)
Phosphasilenes: synthesis and spectroscopic characterization [Erratum to document cited in CA107(25):236849n] (1988) (2)
UNEXPECTED FORMATION OF THE FIRST DOUBLY BENZYLIC 1,1-DI-GRIGNARD REAGENT (2001) (2)
Cr(CO)5(CNCN), a complex in which the coordinated CN group of isocyanogen binds and vibrates like a CO ligand (1990) (2)
Synthesis and Reactions of a Diarylphospha-arsaalkene (1987) (2)
1,5-Hydrogen migrations in cyclopentenes (1968) (2)
Synthesis and Hydrolysis of Alkoxy(aminoalkyl)diorganylsilanes of the Formula Type R2(RO)Si(CH2)nNH2 (R = Alkyl, n = 1–3): A Systematic Experimental and Computational Study (2016) (2)
C−X Bond Activation by Palladium: Steric Shielding versus Steric Attraction (2022) (2)
Synthesis of deuterium labelled analogues of very long chain fatty acids C22:0, C24:0 and C26:0 for use as internal standards in stable isotope dilution analysis (1988) (2)
Synthesis of 4,4-dimethyl-3,5-bis(diphenylphosphino)cyclohexanone (2001) (2)
The synthesis of cis- and trans-1,2-dibromocyclopropane (1981) (2)
Buchbesprechung: Essentials of Computational Chemistry Theories and Models. Von Christopher J. Cramer (2003) (2)
Inside Back Cover: Selective C−H and C−C Bond Activation: Electronic Regimes as a Tool for Designing d10 MLn Catalysts (Chem. Asian J. 10/2015) (2015) (2)
Constraining Optimized Exchange (2010) (2)
Rigorous proof of an allylic rearrangement in the pyro-isopyro change in delphinine (1959) (2)
Cover Picture: Hypervalent Silicon versus Carbon: Ball‐in‐a‐Box Model (Chem. Eur. J. 3/2008) (2008) (2)
Cover Picture: Aromaticity: Molecular‐Orbital Picture of an Intuitive Concept (Chem. Eur. J. 22/2007) (2007) (2)
How Lewis Acids Catalyze Ene Reactions (2021) (2)
Regio- and stereoselectivity in 1,3-dipolar cycloadditions: Activation strain analyses for reactions of hydrazoic acid with substituted alkenes (2017) (2)
Investigations on 1-Metallaindanes (2003) (2)
Synthesis of Phosphaadamantane (1983) (2)
Gas-phase base-induced 1,4-eliminations: Occurrence of single-, double-, and triple-well E1cb mechanisms (vol 117, pg 9889, 1995) (1996) (2)
Integrative Theory/Experiment-Driven Exploration of a Multicomponent Reaction towards Imidazoline-2-(thi)ones (2018) (2)
Nucleophilic Substitution at C, Si and P: How Solvation Affects the Shape of Reaction Profiles (Eur. J. Org. Chem. 4/2008) (2008) (2)
Synthesis and silver-ion-catalyzed reactions of 3,3′-ethylenebicyclopropenyl†‡ (2010) (2)
Is there a need to discuss atomic orbital overlap when teaching hydrogen-halide bond strength and acidity trends in organic chemistry? (2015) (2)
Trends and anomalies in H-AH(n) and CH(3)-AH(n) bond strengths (AH(n) = CH3, NH2, OH, F). (2009) (2)
Pericyclic reaction benchmarks: hierarchical computations targeting CCSDT(Q)/CBS and analysis of DFT performance (2022) (2)
Methyl Substitution Destabilizes Alkyl Radicals (2022) (2)
Probing the Lewis Acidity of Boronic Acids through Interactions with Arene Substituents (2021) (2)
New one-pot synthesis of a benzonorcaradiene derivative by reduction of naphthalic anhydride with LiAlH4 (1997) (2)
Polycyclic Aromatic Hydrocarbons (PAHs) in Interstellar Ices: A Computational Study into How the Ice Matrix Influences the Ionic State of PAH Photoproducts (2022) (2)
How Ionization Catalyzes Diels‐Alder Reactions (2022) (1)
Flash vacuum thermolysis of spirocyclohexadienones (1985) (1)
mu2-eta2-2-tert-Butylethyn-1-yl)(mu2-chloro)bis{{eta2-cyclopentadienyl)dimethylsilane]titanium} (2005) (1)
Coming Soon, Volume 37, Issue 1 (2016) (1)
OLIGOMERIC 1,2-DIHYDRO-1-MAGNESACYCLOBUTA[a]NAPHTHALENE (2002) (1)
Total Synthesis of C19-Diterpene Alkaloids: Construction of a Functionalized ABCD-Ring System. (1992) (1)
ANION FORMATION VERSUS NITRILE = KETENIMINE TAUTOMERISM IN ALKYLIDENE MALONONITRILES AND CYANOACETATES (1975) (1)
Reactivity in Nucleophilic Vinylic Substitution (SNV): SNVπ versus SNVσ Mechanistic Dichotomy. (2013) (1)
Alkali Metal Cation Affinities of Neutral Maingroup-Element Hydrides across the Periodic Table (2019) (1)
All-metal aromatic clusters M 4 2 ( M = B , Al , and Ga ) . Are p-electrons distortive or not ? w (2011) (1)
Front Cover: Nucleophilic Substitution (SN2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent (ChemPhysChem 11/2018) (2018) (1)
Tackling DNA with Density Functional Theory: development and application of parallel and order-N DFT methods (2002) (1)
Metallacyclobutanes: Synthons and Catalysts (1989) (1)
Stacked DNA-base quartets: Structure, chemistry and computational intricacies (2010) (1)
Innenrücktitelbild: Six‐Coordinate Group 13 Complexes: The Role of d Orbitals and Electron‐Rich Multi‐Center Bonding (Angew. Chem. 41/2015) (2015) (1)
Coordinational Behavior of Solvent-Free Diorganylzinc Compounds: The Remarkable X-Ray Structure of Dimeric Diphenylzinc. (1990) (1)
Designing Rh(I)-Half-Sandwich Catalysts for Alkyne [2+2+2] Cycloadditions (2020) (1)
The Hydrogenation Problem in Cobalt‐based Catalytic Hydroaminomethylation (2020) (1)
Nature of Alkali‐ and Coinage‐Metal Bonds versus Hydrogen Bonds (2020) (1)
Synthesis of β‐Hydroxy Esters (II) by Lithium/Ammonia Reduction of α,β‐Epoxy Esters (I). (1991) (1)
Tbe chemistry of 7-substituted norbornadienes; 7-cyanonobornadiene and 7-carboxynorbornadiene (1966) (1)
Chapter Four - Cation affinities throughout the periodic table (2019) (1)
Preparation and Hofmann degradation of 1,1′‐dimethyl‐2,2′‐bis(trimethylammonio)‐bicyclopropyl dihydroxide (2010) (1)
The remarkable electron impact mass spectrum of (2-benzyl-1,3-xylylene)-15-crown-4: expulsion of triethylene glycol by double hydrogen transfer (1996) (1)
Synthesis and structure of 6‐exo‐hydroxy‐1,2‐diphenyl‐1‐phosphoniatricyclo [3.3.1.1]decane iodide, a derivative of 1‐phosphaadamantane (2010) (1)
1,8-NAPHTHALENEDIYLZINC (2001) (1)
Influence of Steric Factors on the Coordination Mode (η1 or η2) of Phosphaalkenes to Zerovalent Pt0L2 Centers. X-Ray Structure of Bis(triphenylphosphine)((2,6-dimethylphenyl)-9-fluorenylidenephosphine)platinum(0)-Toluene. (1987) (1)
The synthetic potential of C-halophosphaalkenes. (1996) (1)
Neutralization‐Reionization Mass Spectrometry and Matrix Isolation of Some 9‐Silaanthracenes. (1991) (1)
X 2 Y 2 Isomers : Tuning Structure and Relative Stability through Electronegativity (2013) (1)
Structure of (E)-[(2-isopropylphenyl)(phenyl)methylene](mesityl)phosphine (1987) (1)
Base‐Induced Imine‐Forming 1,2‐Elimination Reactions in the Gas Phase. (1993) (1)
4th International Conference on Chemical Bonding. (2016) (1)
Dilithium diphenylmethanediide ; generation, redox relationship with lithium chlorodiphenylmethanide, implication with regard to aggregation (1991) (1)
Investigations of a Highly Crowded Phosphino-Substituted Biphenyl: A Precursor for a λ3,λ5-Diphosphaphenanthrene. (1991) (1)
Structure and Stability of the Li2CN Molecule. An Experimental and ab Initio Study. (1995) (1)
THE SYNTHESIS AND STRUCTURE OF ZINCACYCLOPENTANE, ZINCACYCLOHEXANE AND ZINCACYCLOHEPTANE (1982) (1)
Small and Strained Cyclophanes (2010) (1)
Cation affinities throughout the periodic table (2019) (1)
Biosynthesis of L-2,3-diaminopropanoic acid (1985) (1)
The First X-Ray Structure of a 1,1-Di-Grignard Compound: Bis( bromomagnesio)bis(trimethylsilyl)methane. (1992) (1)
Synthesis and conformational analysis of halo[n.3.1]propellanes (2010) (1)
A Quantitative Molecular Orbital Perspective of the Chalcogen Bond. (2021) (1)
Zum Mechanismus der pyrolytischen Bildung von 10‐Aryl‐9‐arsaanthracenen (1978) (1)
10-Mesity-9-arsaanthracene (1978) (1)
Hydride affinities of cationic maingroup-element hydrides across the periodic table (2019) (1)
Iodine Gauche Effect Induced by an Intramolecular Hydrogen Bond. (2022) (1)
PHYS 524-A-H bond dissociation energies: Trends across the periodic table and halogen substituent effects (2008) (1)
Switch From Pauli‐Lowering to LUMO‐Lowering Catalysis in Brønsted Acid‐Catalyzed Aza‐Diels‐Alder Reactions (2021) (1)
Intermolecular Covalent Interactions: Nature and Directionality. (2022) (1)
Front Cover: A Quantitative Molecular Orbital Perspective of the Chalcogen Bond (4/2021) (2021) (1)
Reaction of isocyanogen (CNCN) with hydrogen chloride (1993) (1)
C(sp n)−X (n=1–3) Bond Activation by Palladium (2021) (1)
Particle on a Ring Model for Teaching the Origin of the Aromatic Stabilization Energy and the Hückel and Baird Rules (2022) (1)
Stability of alkyl carbocations. (2022) (1)
Bismutamide als einfache Vermittler hochselektiver Pn−Pn‐Radikal‐Kupplungsreaktionen (Pn=N, P, As) (2021) (1)
Inside Cover: New Concepts for Designing d10‐M(L)n Catalysts: d Regime, s Regime and Intrinsic Bite‐Angle Flexibility (Chem. Eur. J. 36/2014) (2014) (1)
Zircona- und Hafnacyclobutane — Ein neuer Weg zu Metallacyclobutanen (1983) (1)
5 Electronic and Steric Effects on Bite-Angle Flexibility and Nonlinearity (2016) (1)
KRISTALLSTRUKTUR UND BINDUNGSVERHALTNISSE VON W(O-T-BU)4(THF) (1998) (1)
Synthesis, Photochemical Behavior and cis/trans Isomerization of 1-(2, 4,6-Triisopropylphenyl)-2-(2,4,6-tri-tert-butylphenyl)diphosphene. (2010) (1)
Properties of Substituted Triarylphosphaalkenes. (1987) (0)
Travelling the Organometallic Road: A Wittig Student′s Journey from Lithium to Magnesium and Beyond (1999) (0)
6,7‐Bis(methoxycarbonyl)‐2,3‐dimethyl‐(5)(1,4)‐naphthalinophane, the First Benzoanellated (5)Paracyclophane. (1996) (0)
1-Bromomercurio-2-(2,5,8,11,14-pentaoxapentadecyl)benzene (1998) (0)
3-METHYL-2-PHOSPHANAPHTHALENE (1973) (0)
1-BROMO-2,6-BIS(CHLOROMAGNESIOMETHYL)BENZENE FROM THE ATTEMPTED SYNTHESIS OF A DOUBLY BENZYLIC 1,3,5-TRI-GRIGNARD REAGENT (2001) (0)
BLDG. VON GRIGNARD-VERBINDUNGEN 2. MITT. (1973) (0)
Inside Cover: Deeper Insight into the Diels–Alder Reaction through the Activation Strain Model (Chem. Asian J. 23/2016) (2016) (0)
Optimization of strong and weak coordinates (vol 106, pg 2536, 2006) (2007) (0)
Easy Preparation of 1,3-Di-tert-butylbenzene and Some Derivatives Thereof. (2010) (0)
ORGN 395-Attractive or repulsive character of the halogen center dot center dot center dot halogen interaction in halogen-substituted biphenyls? (2007) (0)
Structures and Strain Energies of Small [n]Metacyclophanes. (2000) (0)
Synthesis and Reactivity of Bistrimethylsilyl Dilithio Methane. (1989) (0)
1,2‐DIMAGNESIUM DERIVATIVES OF CYCLOPROPANE (1982) (0)
1,5-Annelated 4-Methylenecyclopentenes by Intramolecular Type I Zinc-Ene Reactions Followed by Pd(0)-Catalyzed Cyclization. (1990) (0)
Anion Recognition by Heterocalixarenes : Understanding the Physical Nature of the Interaction (2017) (0)
Extending the "Organic Chemistry" of Phosphaalkenes. (1998) (0)
A NOVEL SYNTHESIS OF 10-ARYL-9-ARSAANTHRACENES (1978) (0)
Front cover. (2017) (0)
Completely enolized carboxylic esters and acids from the knoevenagel condensation of malononitrile with some cyclic β-keto-esters (1968) (0)
ADDITION VON ALKYLLITHIUM-REAGENTIEN AN ALKENYLAMINE UND ALKENYLSULFIDE (1971) (0)
[η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV) (2006) (0)
Steric Attraction and Steric Repulsion : The Effect of Bulky Ligands (2016) (0)
Unusual Reactivity of Small Cyclophanes: Nucleophilic Attack on 11-Chloro- and 8,11-Dichloro(5)metacyclophane (I). (1990) (0)
From the Action of Stable Free Radicals on the Metal (2007) (0)
Preparation and some properties of trimethylaminemethylenetriphenylborane (2010) (0)
Carbanions as Intermediates in the Synthesis of Grignard Reagents. (1988) (0)
Cooperativity in the self-assembly of guanine and xanthine molecules in ribbon structures (2014) (0)
ARSANTHREN (9,10-DIARSA-ANTHRACEN) (1970) (0)
Guanine, Xanthine and Uric Acid Assemblies: Comparative Theoretical and Experimental Studies (2012) (0)
Flash Vacuum Thermolysis of 5,6,8,9-Tetrahydro-4′-methylenespiro(7H- benzocycloheptene-7,1′-cyclohexa-2′,5′-diene). The Intermediate Formation of (3,2)Orthoparacyclophane. (1987) (0)
BIFUNKTIONELLE UND CYCLISCHE ORGANOMAGNESIUMVERBINDUNGEN 2. MITT. 1-OXA-5-MAGNESIACYCLOOCTAN (1973) (0)
THEORY AND APPLICATION OF PHOTOELECTRON SPECTROSCOP PART 40, THE ELECTRONIC STRUCTURE OF A LAMBDA(3)-PHOSPHAPHENANTHRENE, A DIRECT INDICATION OF THE SIMILARITY OF ELECTRONIC EFFECTS PRODUCED BY SP(2) HYBRIDIZED CARBON AND PHOSPHORUS A (1974) (0)
DIE STRUKTUR DES ANTIBIOTICUMS K16 1. MITT. DIE DIPEPTIDKETTE 2. MITT. CHROMOPHOR UNT TOTALSTRUKTUR (1972) (0)
From Organomercury Compounds with The Metal (2007) (0)
Understanding Reactivity with Kohn)Sham Molecular Orbital Theory: E2)S 2 Mechanistic Spectrum and (1999) (0)
Computational Design of Supramolecular Self-Assembling Materials based on a Condensed-Phase Molecular Orbital Theory. (2014) (0)
A new DFT functional based on spin-states and SN2 barriers (2012) (0)
Interconversions of Titanocene-Methylene Complexes. (1988) (0)
On the mechanism of formation and fragmentation of [8]paracyclophane in the gas phase (2010) (0)
BROM-1-AETHOXY-7-NORBORNYL-MAGNESIUM, EINE STABILE ALICYCLISCHE BETA-ALKOXY-SUBSTITUIERTE GRIGNARD-VERBINDUNG (1971) (0)
Theory and modelling of catalytic events (2003) (0)
First Synthesis of an Olefin-Coordinated Platina(II)cyclobutane and Its Conversion into Diphosphineplatina(II)cyclobutanes. (1988) (0)
Special Reactivity of 8,11-Dihalo[5]Metacyclophane (1989) (0)
New Heterocyclic Ring Systems (1962) (0)
Backside and frontside SN2 substitution: Origin of reaction barriers and reasons for their absence (2007) (0)
Attempted Synthesis of a (5)(2,5)pyridinophan-6-one from Its Dewar Isomer. (1988) (0)
Stereospecific Anionic Reduction of gem-Bromohalocyclopropanes by the Dimsyl Anion. (1994) (0)
Reaction of 3-(2,4,6-tri-tert-butylphenylphosphinylidene)quadricyclane with copper(II) chloride (1993) (0)
The Preparation and Reactivity of Bis(bromomagnesio)bis(trimethylsilyl)methane. (1990) (0)
3-Methylenetetrahydrofurans and 3-Methylenepyrrolidines by Addition of 2-(Bromozincmethyl)-2-alkenyl Ethers or 2-(Chloromagnesiomethyl)-2- alkenyl Ethers to Aldehydes, Ketones and Imines Followed by Pd(0)- Catalyzed Cyclization. (1993) (0)
MOLECULAR STRUCTURE OF 8,11‐DICHLORO(5)METACYCLOPHANE: A SEVERELY STRAINED BENZENE RING (1984) (0)
THEORIE UND ANWENDUNG DER PHOTOELEKTRONENSPEKTROSKOPIE 15. MITT. PHOTOELEKTRONENSPEKTROSKOPIE UND KONJUGATION, DIREKTER BEWEIS DER UNGEWOEHNLICHEN SEQUENZ DER BEIDEN OBERSTEN BESETZTEN PI‐MOLEKUELORBITALE IM PHOSPHORIN‐ UND ARSENIN‐SYST. (1972) (0)
ORGN 515-Electronic vs. steric effects in SN2@P reactions (2007) (0)
Inside Cover: Source of Cooperativity in Halogen‐Bonded Haloamine Tetramers (ChemPhysChem 4/2016) (2016) (0)
MECHANISM OF PYROLYTIC FORMATION OF 10-ARYL-9-ARSAANTHRACENES (1978) (0)
ORGN 281-Effects of solvation, pi-stacking, and hydrogen bonding on the selectivity in DNA replication mechanism (2008) (0)
Cover Feature: Half‐Sandwich Metal‐Catalyzed Alkyne [2+2+2] Cycloadditions and the Slippage Span Model (ChemistryOpen 2/2019) (2019) (0)
Back Cover: In Silico Design of Heteroaromatic Half‐Sandwich RhI Catalysts for Acetylene [2+2+2] Cyclotrimerization: Evidence of a Reverse Indenyl Effect (Chem. Eur. J. 40/2013) (2013) (0)
ZIRCONA- AND HAFNACYCLOBUTANES - A NEW WAY TO METALLACYCLOBUTANES (1983) (0)
ORGN 173-Aromaticity and antiaromaticity in annulenes: Origin of the delocalization vs. localization of double bonds (2009) (0)
SYNTHESIS AND STRUCTURE OF ARYL-SUBSTITUTED PHOSPHAALKENES (1984) (0)
Palladium(0)-Mediated Coupling of Bromophosphaalkenes with Grignard Reagents. (2010) (0)
Activation of the C-X bond by palladium: Ab initio benchmarks and evaluation of DFT (2006) (0)
8,11‐Dichloro‐N‐tosyl‐3‐aza(5)metacyclophane (X): A Highly Strained Aromatic System. (1997) (0)
Synthesis of Bis(phosphine)-1,2-dihydroplatina(II)cyclobutabenzenes. Molecular Structure of the Cyclic 1,2-Dihydroplatina(II)cyclobutabenzene Pt(CH2-o-C6H4)(PMe3)2. (1989) (0)
1,2-Dilithioethane from Ethylene and Lithium (1988) (0)
Corrigendum: Inter‐ and intramolecular dispersion interactions (2013) (0)
1,4‐Additionen von Dihalogencarbenen an 1,3‐Diene. (1985) (0)
A New Approach to 1,2‐Dilithioethane; Easy Preparation of Dilithiomethane. (1988) (0)
How do (Exo)Planetary Environments affect Chemistry & Spectra of (Supposed) Biomarkers and Geochemical Processes? (2014) (0)
THERMAL AND ELECTRON-IMPACT INDUCED 1,4-ARYL MIGRATION FROM PHOSPHORUS TO CARBON (1976) (0)
Synthesis of 2‐Iodo‐4,5‐dimethylphosphinine and Its Conversion to Organometallic Derivatives. (2010) (0)
Phosphasilenes: Synthesis and Spectroscopic Characterization. (1987) (0)
Cover Feature: How Oriented External Electric Fields Modulate Reactivity (Chem. Eur. J. 18/2021) (2021) (0)
Book Review: Computational Chemistry. A Practical Guide for Applying Techniques to Real World Problems. By David Young (2002) (0)
THE FORMATION OF GRIGNARD COMPOUNDS PART 3, THE INFLUENCE OF THE SOLVENT (1975) (0)
Metallacyclic Four-Membered Ring Systems: Two Independent Routes to Bis(cyclopentadienyl)titanacyclobutabenzene. (1986) (0)
The steric nature of the bite angle Inspired (2011) (0)
Addition of 2-(Phenoxymethyl)-2-propenylmagnesium Chloride (II) to Epoxides (I) Followed by Pd(0)-Catalyzed Cyclization: A One-Pot Synthesis of 3-Methylenetetrahydropyrans (IV). (1990) (0)
Energy landscapes of bimolecular nucleophilic substitution (SN2) reactions: A comparison of density functional theory and coupled cluster methods (2005) (0)
The First Free 7λ3‐Phosphanorbornadiene. (2000) (0)
BILDUNG VON RADIKALEN BEI DER EINWIRKUNG VON GRIGNARD‐REAGENTIEN AUF CHINONE (1970) (0)
Hypervalent Carbon: Violation of the Octet Rule (2014) (0)
COMP 448-DNA replication: Estimating the effects and interplay of solvation, pi-stacking and hydrogen bonding (2007) (0)
1,2-Bis(halomagnesio)ethane (2010) (0)
(Invited) The Regioselectivity of the Diels-Alder and Bingel-Hirsch Additions to La@ C 2v -C 82 (2016) (0)
ORGN 211-The effect of steric bulk on Pd, PdCl- and Pd(PH3)(2) catalyzed C-C bond activation: Perspectives from an extended activation strain model (2008) (0)
Synthesis of the Mono‐Dewar‐Benzene Isomer of (1.1)Metacyclophane. (1993) (0)
Crown Ether Grignard Reagents. X-Ray Structure of 2-(Bromomagnesio)-1,3-xylyl-15-crown-4. (1988) (0)
Effect of metal variation on oxidative addition: Perspectives from the activation strain model (2013) (0)
Unusual reactivity of small cyclophanes: nucleophilic attack on 11-chloro- and 8,11-dichloro[5]metacyclophane [Erratum to document cited in CA113(13):114434b] (1991) (0)
A NOVEL SYNTHESIS OF SHORT‐BRIDGED (M)PARACYCLOPHANES (1977) (0)
SYNTHESIS AND APPLICATION OF PRECURSORS OF HETERO-ANTHRACENES. 2-HALO- AND 2,2′-DIHALODIPHENYLMETHANES AND METHINE SUBSTITUTED DERIVATIVES (1976) (0)
Conjugate Addition of 2‐(Bromozincmethyl)‐3‐phenoxy‐1‐propene to Derivatives of Methylene Malonic Acid. Further Conversion to Methylenecyclopentanes. (1992) (0)
THE KNOEVENAGEL REACTION OF MALONONITRILE WITH SOME CYCLIC BETA-KETO-ESTERS PART 2, MECHANISM OF FORMATION OF HETEROCYCLIC REACTION PRODUCTS (1974) (0)
Di-Grignard Compounds and Metallacycles (1988) (0)
In My Element : Carbon (2018) (0)
Cover Feature: Ion‐Pair SN2 Reaction of OH− and CH3Cl: Activation Strain Analyses of Counterion and Solvent Effects (Chem. Asian J. 9/2018) (2018) (0)
Bis(bromomagnesio)trimethylsilylmethane. (1987) (0)
Mechanism of Formation and Fragmentation of (8)Paracyclophane in the Gas Phase. (1990) (0)
Activation of the C-X bond by palladium: Direct oxidative insertion vs. SN2 and the importance of relativistic and solvent effects (2006) (0)
(Ph(4)P)S(6)-A Compound Containing the Cyclic Radical Anion S(6)(.-) We thank the Deutsche Forschungsgemeinschaft (DFG) and the Fonds der Chemischen Industrie (FCI) for financial support. A.D. thanks the FCI for a doctoral stipendium. F.M.B. thanks the DFG for a Habilitation fellowship. (2000) (0)
8,11-Dichloro[5]metacyclophane. [5]Metacyclophanes. A Spectroscopic and Theoretical Investigation of Structure and Conformation. (1983) (0)
d-ML2 Transition-Metal Complexes (2019) (0)
Synthesis and Structure of (Phosphaalkenyl)mercury Compounds. (1993) (0)
Intramolecularly alkylated salen complexes: new models for coenzyme B12 with a cobalt-to-ligand carbon bridge (1993) (0)
Front Cover: Proton Transfer and S N 2 Reactions as Steps of Fast Selenol and Thiol Oxidation in Proteins: A Model Molecular Study Based on GPx (ChemPlusChem 4/2021) (2021) (0)
Addition of isopropyllithium to unconjugated double bonds of alkenyl ethers :(Preliminary Communication) (2010) (0)
Biphenyls, Bond Paths and Repulsions: Do the Ortho and Ortho' Substituents in Biphenyls Repel or Attract (Bind to) Each Other? (2008) (0)
Front Cover: Role of the Chalcogen (S, Se, Te) in the Oxidation Mechanism of the Glutathione Peroxidase Active Site (ChemPhysChem 21/2017) (2017) (0)
Through-Space Polar-π Interactions in 2,6-Diarylthiophenols. (2020) (0)
ORGN 39-Nonexistance of hydrogen-hydrogen bonding in planar biphenyl and the failure of Atoms-In-Molecules (AIM) theory (2006) (0)
SYNTHETIC STUDIES RELATED TO 1,4‐DITHIOCIN (1977) (0)
Di- and Polyfunctional Organomagnesium Compounds (2000) (0)
Origin of the ethane rotational barrier: Steric repulsion or hyperconjugation? (2005) (0)
Cover Feature: Dual Activation of Aromatic Diels–Alder Reactions (Chem. Eur. J. 42/2019) (2019) (0)
Synthesis and Conformational Analysis of Halolm[n.3.1]propellanes. (1985) (0)
Conjugated Exocyclic Dienes by Addition of 2-(Benzyloxymethyl)-3-(bromozincmethyl)-1,3-butadiene to Aldehydes, Ketones, and Imines Followed by Pd(0)-Catalyzed Cyclization. (1990) (0)
The Formation of 1,3-Di-Grignard Reagents from Small-Ring 1,3-Dibromides. (1988) (0)
2-Alkoxy-3-Methylenetetrahydrofurans by Addition of 2-(Bromozincmethyl)-3,3-dialkoxy-1-propenes to Aldehydes and Ketones Followed by Pd(0)-Catalyzed Cyclization. (1990) (0)
The Stereochemistry of the 1,4-Addition of Dibromocarbene to 1,2-Dimethylenecycloheptane. (1990) (0)
Multistep cluster chemistry involved in SN2@P reaction systems (2007) (0)
Issue Information (2020) (0)
From the Formation of Adducts Between Conjugated Hydrocarbons and the Metal in the Presence of Donor Solvents (2007) (0)
SYNTH. DES 9-MESITYL-10-PHENYL-9-BORAANTHRACEN-ANIONS (1973) (0)
3-Methyl-2-chloro-2-hydroxy-2-phosphanaphthalene. A stable p-hydroxy-λ5-phosphorin (2010) (0)
Spotlights on our sister journals: Chem. Eur. J. 45/2015. (2015) (0)
ORGN 38-alpha-Stabilization of carbanions: Fluorine outperforms the heavier halogens (2006) (0)
3‐METHYL‐2‐CHLORO‐2‐HYDROXY‐2‐PHOSPHANAPHTHALENE. A STABLE P‐HYDROXY‐Λ5‐PHOSPHORIN (1979) (0)
Allylmetallation of 1‐Silylalkynes by 2‐(Bromozincmethyl)‐2‐alkenyl Ethers Followed by Pd(0)‐Catalyzed Cyclization: A One‐Pot Synthesis of 4‐Methylenecyclopentenes. (1992) (0)
DIELS‐ALDER REACTIONS OF (5)METACYCLOPHANE (1982) (0)
MESITYL(DIPHENYLMETHYLENE)ARSINE (1979) (0)
Rational design of catalysts: How the interplay of activation strain and TS interaction determines barrier heights (2006) (0)
THE FORMATION OF GRIGNARD COMPOUNDS PART 4, DIRECT PROOF FOR THE FORMATION OF RMGX AS PRIMARY PRODUCT IN THE REACTION OF ORGANIC HALIDES WITH MAGNESIUM (1975) (0)
Book Review: Valence Bond Methods—Theory and Applications. By Gordon A. Gallup (2003) (0)
4)Paracyclophane Intercepted. (1987) (0)
Selective Lithiation of 1-Bromo-2-((trimethylstannyl)methyl)benzene: Synthesis of 1-Bromo-2-(lithiomethyl)benzene, 1-Lithio-2-(( trimethylstannyl)methyl)benzene, and α,2-Dilithiotoluene. (1991) (0)
THE MEAN BOND DISSOCIATION ENERGY OF THE CARBON-MAGNESIUM BOND IN BIS(2,2-DIMETHYLPROPYL)MAGNESIUM (1983) (0)
1,4-DITHIOCINYL-(6)-ACETAT (1974) (0)
Formation of a distibacyclooctane; X‐ray crystal structure of 1,5‐dichloro‐1,3,3,5,7,7‐hexamethyl‐9‐oxa‐1,5‐distibabicyclo[3.3.1]nonane hydrochloride (2010) (0)
Developments in the Synthesis of Triptycenes Containing Metals of Group 14 and 15. (1997) (0)
Buchbesprechung: Computational Chemistry. A Practical Guide for Applying Techniques to Real World Problems. Von David Young (2002) (0)
KNOEVENAGEL‐KONDENSATION MIT EINIGEN CYCLISCHEN BETA‐KETOSAEUREESTERN, EINE BERICHTIGUNG (1970) (0)
SILVER(I)-CATALYZED REARRANGEMENT OF BICYCLOPROPENYLS. STEPWISE MECHANISM (1976) (0)
A New Type of Organometallic Spiro Compounds: 2,2,6,6-Tetracyclopentadienyl-4-sila-2,6-dititanaspiro[3,3]heptane. (1986) (0)
1,4-Diphosphabutadiyne: A Realistic Target for Synthesis? A Theoretical Investigation of C2P2, C2N2, [Cr(CO)5PCCP], and [(CO)5Cr(PCCP)Cr(CO)5]. (1999) (0)
Oxygen and Nitrogen Heterocycles by Intramolecular Magnesium- and Zinc-Ene Reactions. Methylenecyclopentanes by Pd(0)-Catalyzed Isomerization of 5-(Bromozincmethyl)-3-methyleneoxacycloalkanes. (1988) (0)
Metal-mediated base pairs with 6-substituted purines: A combined experimental and computational approach (2014) (0)
Some Investigations on [6]Metacyclophanes. (2002) (0)
1,4-Diphosphabutadiyne: A Realistic Target for Synthesis? A Theoretical Investigation of C2P2, C2N2, [Cr(CO)5PCCP], and [(CO)5Cr(PCCP)Cr(CO)5]. (1999) (0)
Flash Vacuum Thermolysis and Mass Spectroscopy of 9,10-Dihydro-9-silaanthracenes. (1990) (0)
Synthesis and Reactions of P-Supermesityl-C-halophosphaalkenes. (1992) (0)
BICYCLO(2,2,2)OCT-1-ENE, FORMATION FROM 1-ETHOXYBICYCLO(2,2,2)OCT-2-YL-LITHIUM AND REACTION WITH T-BUTYL-LITHIUM (1973) (0)
SYNTH. VON 1,1′-DIMETHYL-BICYCLOPROPENYL (1971) (0)
Tricarbonylchromium Complexes of [5]‐ and [6]‐Metacyclophane: An Experimental and Theoretical Study. (2009) (0)
THE REACTION OF GRIGNARD REAGENTS WITH 1,3-DIOXOLANES. III. A NOVEL SYNTHETIC C ROUTE TO β-HYDROXYALKYL ENOL ETHERS (1978) (0)
12,15-Dichloro[3.0]orthometacyclophane: A Highly Strained Biphenylophane. (1998) (0)
dienyl)titanium(IV) (2006) (0)
Flash Vacuum Thermolysis of 1-Chloro-4-methylene[2.m]alkanes. (1986) (0)
Tricarbonylchromium Complexes of [5]‐ and [6]‐Metacyclophane: An Experimental and Theoretical Study. (2009) (0)
DARST. VON FUENF- UND SECHSGLIEDRIGEN KOHLENSTOFF-BOR-HETEROCYCLEN DURCH PYROLYSE VON PYRIDIN-ARYLBORANEN (1973) (0)
BIFUNKTIONELLE UND CYCLISCHE ORGANOMAGNESIUM-VERBINDUNGEN 1. MITT. PENTAMETHYLENBIS-(MAGNESIUMBROMID) UND MAGNESIACYCLOHEXAN (1970) (0)
METHYLENEDIMAGNESIUM DIBROMIDE AS PRECURSOR OF METAL CARBENE COMPLEXES; PREPARATION OF TITANACYCLOBUTANES (1984) (0)
Cover Feature: Alkali Metal Cation Affinities of Anionic Main Group-Element Hydrides Across the Periodic Table (Chem. Asian J. 19/2017) (2017) (0)
Solvolysis of endo‐bicyclo[3.2.1]octa‐2,6‐dien‐8‐yl derivatives (2010) (0)
COMP 81-Reaction path analysis: Approximations and applications (2008) (0)
The short N [bond] F bond in N(2)F(+) and how Pauli repulsion influences bond lengths. Theoretical study of N(2)X(+), NF(3)X(+), and NH(3)X(+) (X [double bond] F, H). (2002) (0)
The Synthetic Potential of C-Halophosphaalkenes (1997) (0)
INOR 581-Phosphine ligand effects on the palladium oxidative-insertion reaction (2008) (0)
From Acidic Hydrocarbons to Evolve H2 (2007) (0)
Palladium(0)-Catalyzed Nonconcerted Cope Rearrangement. (1992) (0)
INVESTIGATION OF THE STRUCTURE OF PHENARSAZINE. MASS SPECTROSCOPICAL EVIDENCE FOR THE THERMAL FORMATION OF PHENARSAZINE (1976) (0)
THE CONSTITUTION OF THE GRIGNARD REAGENT PART 8, THE STRUCTURE OF COMPLEXES BETWEEN ETHYLMAGNESIUM BROMIDE AND 1‐ETHOXY‐2‐METHYLBUTANE (1973) (0)
ORGN 393-Ball-in-a-box model of hypervalence: Carbon vs. silicon (2007) (0)
Cover Picture: Type‐I Dyotropic Reactions: Understanding Trends in Barriers (Chem. Eur. J. 39/2012) (2012) (0)
DIE DURCH SILBERIONEN KATALYSIERTE VALENZISOMERISIERUNG VON 1,1′-DIMETHYL-BICYCLOPROPENYL (1972) (0)
Inside Back Cover: Understanding the Reactivity of Ion‐Encapsulated Fullerenes (Chem. Eur. J. 46/2017) (2017) (0)
DIE KONSTIT. DES GRIGNARD‐REAGENZES 7. MITT. DER ASSOZIATIONSGRAD VON AETHYLMAGNESIUM‐VERBINDUNGEN IN DIISOPROPYLAETHER (1972) (0)
Glucose as non natural nucleobase (2016) (0)
Theoretical Investigation of the Reiative Stabilities of X S S X and X , SS Isomers (2004) (0)
11‐TERT‐BUTYL‐8‐CHLORO(5)METACYCLOPHANE (1984) (0)
Glucose as a nuclease mimic in DNA (2016) (0)
Synthesis of Metallacyclobutanes and Metallacyclobutabenzenes of Molybdenum and Tungsten. (1988) (0)
Through-Space Stabilization of an Imidazolium Cation by Aromatic Rings. (2022) (0)
Arylic C–X Bond Activation by Palladium Catalysts: Activation Strain Analyses of Reactivity Trends (2018) (0)
Small [N]Cyclophanes. Where is the Limit? (1989) (0)
Front Cover: B‐DNA Structure and Stability: The Role of Nucleotide Composition and Order (ChemistryOpen 2/2022) (2022) (0)
Ring-Opening Reactions Regioselectivity of Epoxide Ring-Openings via S N 2 Reactions Under Basic and Acidic Conditions (2020) (0)
CCDC 728543: Experimental Crystal Structure Determination (2010) (0)
Palladium-catalyzed activation of HnA–AHn bonds (AHn = CH3, NH2, OH, F) (2023) (0)
Cover Picture: Nonlinear d10-ML2 Transition-Metal Complexes (ChemistryOpen 3/2013) (2013) (0)
The formation of derivatives of sila‐anthracene on electron impact: (Preliminary communication) (2010) (0)
Catalytic methane activation by d(10) transition metal complexes (2013) (0)
Additions and Corrections: The Structure of Chaksine, a Monoterpene Alkaloid. (1958) (0)
On the Structural Variability of Exocyclic Amino Groups in Free and Metalated Cytosine Nucleobases (2014) (0)
Archetypal backside SN2 reactions: Effects of nucleophilicity and leaving-group ability (2007) (0)
Reading and erasing of the phosphonium analogue of trimethyllysine by epigenetic proteins (2022) (0)
Probing Noncovalent Interactions in [3,3]Metaparacyclophanes. (2022) (0)
Attempted synthesis of a [5](2,5)pyridinophan‐6‐one from its Dewar isomer (2010) (0)
B-DNA Structure and Stability: The Role of Nucleotide Composition and Order. (2022) (0)
Insertion of CO2 and CS2 into Bi–N bonds enables catalyzed CH-activation and light-induced bismuthinidene transfer (2023) (0)
Nonlinear d10-ML2 Transition-Metal Complexes (2013) (0)
The Synthesis of Hetero-bridged [5](3,6)Oxepinophanes. (1986) (0)
Corrigendum: Chemoselectivity of Tertiary Azides in Strain-Promoted Alkyne-Azide Cycloadditions. (2022) (0)
Activation strain model: Rational design of catalysts (2005) (0)
Dipolar repulsion in α-halocarbonyl compounds revisited (2021) (0)
The Formation of Titanocenemethylene Complexes from 1,3-Dititanacyclobutanes. (1987) (0)
Understanding chemical reactivity using the activation strain model (2020) (0)
A Convenient Synthesis of 2-Halo-5-chloro-m-xylenes. (1985) (0)
Issue Information (2022) (0)
Inside Back Cover: Origin of the α‐Effect in S N 2 Reactions (Angew. Chem. Int. Ed. 38/2021) (2021) (0)
One‐Pot Preparation of 3‐Methylenepyrrolidines with High Diastereomeric Excess. (1993) (0)
Unusual reactivity of small cyclophanes: nucleophilic attack on 11-chloro- and 8,11-dichloro[5]metacyclophane [Erratum to document cited in CA113(13):114434b] (1991) (0)
Probing Polar-π Interactions Between Tetrazoles and Aromatic Rings. (2023) (0)
THE REACTION OF GRIGNARD REAGENTS WITH 1,3-DIOXOLANES, INFLUENCE OF SOLVATION, KINETICS AND MECHANISM (1975) (0)
The preparation of unracemized optically active 2-butoxy derivatives: (Short communication) (2010) (0)
Cover Picture: Factors Controlling β‐Elimination Reactions in Group 10 Metal Complexes (Chem. Eur. J. 41/2015) (2015) (0)
Reading and erasing of the phosphonium analogue of trimethyllysine by epigenetic proteins. (2022) (0)
THE SYNTHESIS OF CIS‐ AND TRANS‐1,2‐DIBROMOCYCLOPROPANE (1982) (0)
Glucose-nucleobase pairs within DNA: impact of hydrophobicity, alternative linking unit and DNA polymerase nucleotide insertion studies† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc04850e (2018) (0)
The abnormally long and weak methylidyne C–H bond (2022) (0)
Addition of 2-(Chloromagnesiomethyl)-2-alkenyl Ethers to Epoxides Followed by Pd(0)-Catalyzed Cyclization: A One-Pot Synthesis of 3- Methylenetetrahydropyrans. (1993) (0)
New Routes to (E)-halophosphaalkenes. (1996) (0)
PHYS 587-Origin of reaction barriers and rational design in catalysis (2008) (0)
2 Theories , Models and Methods (2016) (0)
(Ph4P)S6 — A Compound Containing the Cyclic Radical Anion S6×-. (2001) (0)
Synthesis and X-Ray Crystal Structure of 11-Bromo-endo-9-chloro-7- ethoxybicyclo(5.3.1)undec-1(11)-ene. A Stable, Highly Strained anti- Bredt Olefin. (1993) (0)
Inside Back Cover: Six‐Coordinate Group 13 Complexes: The Role of d Orbitals and Electron‐Rich Multi‐Center Bonding (Angew. Chem. Int. Ed. 41/2015) (2015) (0)
DNA Replication. Polymerase-Induced Steric Fit in Concert with Watson-Crick Hydrogen Bonding (2008) (0)
Cover Feature: Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length (Chem. Eur. J. 24/2021) (2021) (0)
Front Cover: Through‐Space Polar‐π Interactions in 2,6‐Diarylthiophenols (ChemPhysChem 11/2020) (2020) (0)
Diels‐Alder Reactions of Trichlorophosphaethene. (1996) (0)
ase pairs within DNA : impact of hydrophobicity , alternative linking unit and DNA polymerase nucleotide insertion studies † (2018) (0)
ORGN 209-Nucleophilic substitution at carbon, silicon and phosphorus: How solvation affects the shape of reaction profiles (2008) (0)
Unusual Reactivity of Small Cyclophanes: Nucleophilic Attack on 11-Chloro- and 8,11-Dichloro(5)metacyclophane (I). (1990) (0)
Intramolecular Zinc-Ene Reactions of Alkynes: Preparation of 1,5-Annulated 4-Methylenecyclopentenes. (1992) (0)
Glucose-nucleobase pairs within DNA: impact of hydrophobicity, alternative linking unit and DNA polymerase nucleotide insertion studies † ChemicalScience EDGE ARTICLE (2018) (0)
STUDIES ON THE FORMATION OF (5)METACYCLOPHANE (1982) (0)
Editorial for PCCP themed issue "Developments in Density Functional Theory". (2016) (0)
The Reaction of 4,4-dimethyl-1-phenylisochroman with hydriodic acid and phosphorus (2010) (0)
Innenrücktitelbild: Origin of the α‐Effect in S N 2 Reactions (Angew. Chem. 38/2021) (2021) (0)
CHED 317-Chemistry with ADF: From understanding to design (2008) (0)
How Ionization Catalyzes Diels-Alder Reactions. (2022) (0)
A COMPARATIVE INVESTIGATION OF 1,4-PENTAMETHYLENE AND 1,4-HEXAMETHYLENE DEWAR BENZENE. EVIDENCE FOR THE INTERMEDIATE FORMATION OF (5)PARACYCLOPHANE (1985) (0)
Cover image (2010) (0)
The electronic structure of a λ3‐phosphaphenanthrene; a direct indication of the similarity of electronic effects produced by sp2 hybridized carbon and phosphorus atoms (Preliminary communication) (2010) (0)
The Search for Enhanced σ‐Donor Ligands to Stabilize Boron‐Boron Multiple Bonds (2023) (0)
Inside Back Cover: Ion‐Pair SN2 Substitution: Activation Strain Analyses of Counter‐Ion and Solvent Effects (Chem. Eur. J. 13/2016) (2016) (0)
Graphical Abstract: ChemistryOpen 3/2013 (2013) (0)
Molecular Fragment Affinities (2013) (0)
Cover Image (2007) (0)
Ketene Thioacetals by "Peterson Carbonyl Olefination"") with Metalated Formyl Trimethylsilyl Thioacetals("*' (1972) (0)
How Bases Catalyze Diels‐Alder Reactions (2022) (0)
Bite angles in catalytic bond activation: Steric and electronic tuning (2013) (0)
INOR 585-Covalency in highly polar bonds (2006) (0)
Innentitelbild: Das Distortion/Interaction‐Activation‐Strain‐Modell zur Analyse von Reaktionsgeschwindigkeiten (Angew. Chem. 34/2017) (2017) (0)
d Regime, s Regime and Intrinsic Bite-Angle Flexibility: New Concepts for Designing d10-MLn Catalysts (2014) (0)
EXAFS and DFT studies on iridium catalysts for SABRE (2014) (0)
Asymmetric Addition of B-(2-(Phenoxymethyl)-2-propenyl)bis(2- isocaranyl)borane to Aldehydes and Further Cyclization to Chiral 3- Methylenetetrahydrofurans. (1993) (0)
Thermal Generation and Dimerization of (4)Metacyclophane. (1988) (0)
New Low Coordination Phosphorus Heterocycles (2010) (0)
Palladium(II)-Catalyzed Claisen Rearrangement of Allyl Vinyl Ethers. (1987) (0)
Twisted Phenanthrene and Other Molecular Victims of Steric Repulsion (2010) (0)
THE STRUCTURE OF THE GRIGNARD REAGENT PART 9, THE CRYSTAL STRUCTURE OF THE DIMERIC ETHYLMAGNESIUM BROMIDE/DIISOPROPYL ETHER COMPLEX (1974) (0)
ORGN 36-The effect of steric bulk on Pd(0)-catalyzed C-H bond activation: Perspectives from an extended Activation Strain model (2006) (0)
The formation of 1,3‐di‐Grignard reagents from small‐ring 1,3‐dibromides (2010) (0)
Cover Feature: Bifunctional Hydrogen Bond Donor‐Catalyzed Diels–Alder Reactions: Origin of Stereoselectivity and Rate Enhancement (Chem. Eur. J. 16/2021) (2021) (0)
The Synthesis and Some Applications of New 1,3-Dilithiopropanes: Dimethylbis(α-lithiobenzyl)silane and Its Germanium Analogue. (1988) (0)
SYNTHESIS AND STRUCTURE OF 6-EXO-HYDROXY-1,2-DIPHENYL-1-PHOSPHONIATRICYCLO(3.3.1.13,7)DECANE IODIDE, A DERIVATIVE OF 1-PHOSPHAADAMANTANE (1983) (0)
A stereospecific anionic reduction of gem‐bromohalocyclopropanes by the dimsyl anion (2010) (0)
Hypervalent vs. nonhypervalent carbon: Disk-between-balls model (2009) (0)
3-Methylenetetrahydrofurans and 3-Methylenepyrrolidines by Addition of 2-Bromozincmethyl-2-propenyl Ethers to Aldehydes, Ketones, and Imines Followed by Pd(0)-Catalyzed Cyclization. (1988) (0)
EQUILIBRIUM CH-ACIDITY IN CYCLOHEXYLAMINE, THE AROMATIC 9-MESITYL-9-BORAANTHRACENE ANION (1974) (0)
Aromaticity of Highly Bent Benzene Rings. An Investigation by High Field Deuterium NMR of [5]Metacyclophane and Model Compounds. (1986) (0)
Inside Back Cover: Understanding the Reactivity of Endohedral Metallofullerenes: C78 versus Sc3N@C78 (Chem. Eur. J. 15/2015) (2015) (0)
COMPOUNDS CONTAINING LOCALIZED CARBON-PHOSPHORUS DOUBLE BONDS. I. DIELS-ALDER REACTION OF 3-METHYL-2-PHOSPHANAPHTHALENE WITH HEXAFLUOROBUT-2-YNE (1978) (0)
Rational Catalyst Design : Selective C – H and C – C Bond Activation (2016) (0)
Explorations on the Synthesis of Symmetrical Trimetallated Benzene. (1997) (0)
[4+2] Cycloaddition reactions of triarylphosphaalkenes (1984) (0)
Synthesis and Silver Ion Catalyzed Reactions of 3,3′-Ethylenebicyclopropenyl. (1987) (0)
Computational Study on the Structure and Replication of DNA (2005) (0)
1,2-Bis(halomagnesio)ethane. (1988) (0)
SYNTH.‐VERSUCH VON DIBENZO(B,E)BORIN (9‐BORAANTHRACEN) UND DESSEN BLDG. UNTER ELEKTRONENBESCHUSS (1971) (0)
Clarifying notes on the bonding analysis adopted by the energy decomposition analysis. (2022) (0)
Structure of 1,3-xylyl-18-crown-5 (1989) (0)
Synthesis and Characterization of β-Phosphaenones. An Investigation on the Conjugative Properties of the P=C Bond. (1995) (0)
2,4,6-TRI-TERT-BUTYLPHENYLPHOSPHENEDIMESITYLSILENE; THE FIRST PHOSPHASILAALKENE (1984) (0)
7,8-Dimethoxycarbonyl-10,11-dimethyl[5]paracyclophane. (1986) (0)
[η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentacyclopentadienyl)titanium(IV) (2006) (0)
DARST. UND HOFMANNSCHER ABBAU VON 1,1′-DIMETHYL-2,2′-BIS-(TRIMETHYLAMMONIO)-BICYCLOPROPYL-DIHYDROXID (1971) (0)
Syntheses of 1,3‐Dimetallacyclobutanes with the Methylene‐di‐Grignard Reagent. (1986) (0)
The Short N—F Bond in N2F+ and How Pauli Repulsion Influences Bond Lengths. Theoretical Study of N2X+, and NF3X+ and NH3X+ (X: F, H) (2002) (0)
Alkalimetal Controlled DNA Nanoswitch (2014) (0)
ORGN 204-E2 vs. SN2: How to tune the competition (2008) (0)
7,14‐Dichloro[1.1]metacyclophane: A Highly Strained Aromatic Intermediate. (1998) (0)
Reactivity of 8,11‐Dihalo(5)metacyclophanes. (1991) (0)
Cover Feature: A Unified Framework for Understanding Nucleophilicity and Protophilicity in the S N 2/E2 Competition (Chem. Eur. J. 67/2020) (2020) (0)
Reaction of Photochemically Generated Dibromocarbene with 1,2-Dimethylenecycloalkanes. 1,4 Addition Is Real. (1990) (0)
Aza-1 , 3-Dipolar Cycloadditions Elucidating the Trends in Reactivity of Aza-1 , 3-Dipolar Cycloadditions (2019) (0)
(2,6-DIMETHYLPHENYL)(9-FLUORENYLIDENE)PHOSPHINE (1984) (0)
The Activation Strain Model of Chemical Reactivity (2010) (0)
An Investigation of the Di-Grignard Approach to Metallabenzocyclobutenes of Group 14. (1988) (0)
Oxidative addition of methane, silane and heavier AH4 congeners to palladium (2006) (0)
The Synthesis of Four-Membered Spiro Compounds of Silicon and Germanium: 2,2,6,6-Tetramethyl-4-metallaspiro(3.3)heptanes. (1987) (0)
A Direct Synthesis of 1,3-Bis(bromomagnesio)propane. (1982) (0)
Pentacyclo(4.3.1.01,6.07,9.08,10)decane: A Cyclopropane Edge‐Bridged Prismane and Its Rearrangement to a Fulvene. (1987) (0)
Cover Feature: Structural Distortion of Cycloalkynes Influences Cycloaddition Rates both by Strain and Interaction Energies (Chem. Eur. J. 25/2019) (2019) (0)
Five Years of Polling the Computational Chemistry Community (2014) (0)
Multiple Bonds Between Main Group Elements and Transition Metals. Part 35. First Four-Membered Metallacycles of Rhenium. (1987) (0)

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Friedrich Matthias Bickelhaupt is affiliated with the following schools:

Swinburne University of Technology
Radboud University Nijmegen
Universidad de Guanajuato
University of Calgary
University of Marburg
Vrije Universiteit Amsterdam
Bowdoin College
University of Girona
Budapest University of Technology and Economics
Cornell University
University of Padua
University of Groningen
Delft University of Technology

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