Gerard Van Koten

Gerard Van Koten's AcademicInfluence.com Rankings

Gerard Van Koten

Chemistry

#1653

World Rank

#2424

Historical Rank

Inorganic Chemistry

#63

World Rank

#72

Historical Rank

chemistry Degrees

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Chemistry

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Gerard Van Koten's Published Works

Number of citations in a given year to any of this author's works

Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Homogeneous catalysts based on silane dendrimers functionalized with arylnickel(II) complexes (1994) (513)
Organoplatinum crystals for gas-triggered switches (2000) (398)
Diaminoarylnickel(II) “Pincer” Complexes: Mechanistic Considerations in the Kharasch Addition Reaction, Controlled Polymerization, and Dendrimeric Transition Metal Catalysts (1998) (269)
Fluorous phase separation techniques in catalysis (1999) (232)
1,4-Diaza-1,3-butadiene (a-diimine) ligands: their coordination modes and the reactivity of their metal complexes (1982) (226)
Tuning the reactivity of metals held in a rigid ligand environment (1989) (225)
Activation of Unreactive Bonds and Organic Synthesis (1999) (225)
Organometallic Pincer Chemistry (2013) (199)
Dimethyl(N,N,N',N'-tetramethylethanediamine)palladium(II) and dimethyl[1,2-bis(dimethylphosphino)ethane]palladium(II): syntheses, x-ray crystal structures, and thermolysis, oxidative-addition and ligand-exchange reactions (1989) (182)
Homogeneous vanadium-based catalysts for the Ziegler–Natta polymerization of α-olefins (2002) (180)
Syntheses of 3-amino-2-azetidinones: A literature survey (1991) (162)
Where Organometallics and Dendrimers Merge: The Incorporation of Organometallic Species into Dendritic Molecules (2004) (138)
Mechanisms of d8 organometallic reactions involving electrophiles and intramolecular assistance by nucleophiles (1995) (136)
The copper catalysed reaction of sodium methoxide with aryl bromides. A mechanistic study leading to a facile synthesis of anisole derivatives (1989) (120)
Cyclometalated Organoruthenium Complexes for Application in Dye-Sensitized Solar Cells (2010) (119)
Triorganotin cations stabilized by intramolecular SnN coordination; synthesis and characterization of { C , N , N ′-2,6-bis[(dimethylamino)methyl]phenyl}diorganotin bromides (1978) (119)
A novel type of Pt–C interaction and a model for the final stage in reductive elimination processes involving C–C coupling at Pt; synthesis and molecular geometry of [1,N,N′-η-2,6-bis{(dimethylamino)methyl}-toluene]iodoplatinum(II) tetrafluoroborate (1978) (106)
Synthesis of C,Sn-chiral triorganotin halides via C-chiral arylcopper and arylgoldlithium intermediates. Crystal and molecular structure of one [2-[1-(S)-(dimethylamino)ethyl]phenyl]methylphenyltin bromide diastereomer (1978) (104)
Rigid five- and six-membered C,N,N' bound aryl, benzyl, and alkyl organopalladium complexes : sp2 vs. sp3 C-H activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halides (1993) (103)
Intramolecular Coordination in Organotin Chemistry (1993) (99)
The Monoanionic ECE-Pincer Ligand: A Versatile Privileged Ligand Platform—General Considerations (2013) (98)
Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates (1991) (93)
Chiral arenethiolatocopper(I) catalyzed substitution reactions of acyclic allylic substrates with Grignard reagents (1995) (92)
Design and Performance of Rigid Nanosize Multimetallic Cartwheel Pincer Compounds as Lewis-Acid Catalysts (2001) (91)
Unique stable organometallic Ni(III) complexes: Syntheses and the molecular structure of Ni[C6H3(CH2NMe2)2-o,o']I2] (1983) (91)
Models for the Initial Stages of Oxidative Addition : Synthesis, Characterization and Mechanistic Investigation of N1-I2 Organometallic 'Pincer' Complexes of Platinum : X-ray Crystal Structures of [Ptl(C6H3{CH2NMe2}2-2,6)(N1-I2)] and exo-meso-[Pt(N1-I3)(N1-I2)(C6H3{CH2N-(t-Bu)Me}2-2,6) (1999) (91)
Fluorous Versions of Wilkinson's Catalyst : Activity in Fluorous Hydrogenation of 1-Alkenes and Recycling by Fluorous Biphasic Separation (2000) (91)
Recent Advances in the Organometallic Chemistry of Aryldiamine Anions That Can Function as N,C,N′- and C,N,N′-Chelating Terdentate “Pincer” Ligands: An Overview (1997) (88)
Recent Findings in Cyclometallation of meta‐Substituted Aryl Ligands by Platinum Group Metal Complexes by Caryl–R Bond Activation (R=H, CR3, SiR3) (1998) (88)
The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications (2016) (86)
Arenethiolatocopper(I) Complexes as Homogeneous Catalysts for Michael Addition Reactions (1994) (85)
A New Class of Organocopper and Organocuprate Compounds Derived from Copper( I) Arenethiolates (1992) (85)
Trans 2,6-bis[(dimethylamino)methyl]phenyl-N,N,C complexes of Pd(II) and Pt(II). Crystal structure of [PtI(MeC6H3(CH2NMe2)2-o,o)]BF4: A cyclohexadienyl carbonium ion with a s-bonded metal substituent, (1982) (84)
Mechanistic Aspects of the Kharasch Addition Reaction Catalyzed by Organonickel(II) Complexes Containing the Monoanionic Terdentate Aryldiamine Ligand System [C6H2(CH2NMe2)2-2,6-R-4]-† (1997) (82)
Synthesis and characterization of {2,6-bis[d(dimethylamino)methyl][phenyl}tin(II) chloride and {2,6-Bis{(dimethylamino)methyl]phenyl}(4-tolyl)tin(II) the first example of a mixed diaryltin(II) compound (1989) (82)
NCN–pincer palladium complexes with multiple anchoring points for functional groups (2004) (81)
Intramolecularly chelated di- and tetranuclear aryllithium compounds; crystal structure of Li4(C6H4CH2NMe2-2)4 containing four-centre two-electron bonded C(aryl) atoms and heptacoordinate lithium atoms (1982) (80)
Ruthenium-complex catalyzed N-(cyclo)alkylation of aromatic amines with diols. Selective synthesis of N-(n-hydroixyalkyl)anilines of type PhNH(CH2)nOH and of some bioactive arylpiperazines, (1998) (79)
Pincer ligands as powerful tools for catalysis in organic synthesis (2013) (78)
Electronic Tuning of Arylnickel(II) Complexes by Para Substitution of the Terdentate Monoanionic 2,6-Bis[(dimethylamino)methyl]phenyl Ligand (1994) (78)
Novel chiral triorganotin halides. Stabilization of optically active tin centers by intramolecular coordination (1976) (77)
Syntheses and characterization of unique organometallic Ni(III) aryl species: ESR and electrochemical studies and the X-Ray molecular structure of square pyramidal Ni{C6H3(CH2NMe2)2-o,o'}I2 (1988) (76)
Transcyclometalation Processes with Late Transition Metals: CarylH Bond Activiation via Noncovalent CHCl Interactions (2000) (75)
Encapsulation of Hydrophilic Pincer-Platinum(II) Complexes in Amphiphilic Hyperbranched Polyglycerol Nanocapsules (2002) (74)
Synthetic aspects of tetraorganotins and organotin(IV) halides (2004) (74)
Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses (1983) (73)
Structural characterization of some 2-(dimethylamino)methyl-substituted phenylcopper compounds R4Cu4 (1975) (72)
Alkene and carbon monoxide insertion reactions of nitrogen-coordinated monoorganopalladium(II) complexes: The stepwise construction of alternating copolymers of CO and alkenes on a palladium center (1995) (72)
Optimized palladium catalyst systems for the selective liquid-phase hydrogenation of functionalyzed alkynes (2003) (72)
Novel bonding modes of a-diimines. Synthesis and characterization of [MCl2L(a-diimine)] and [MCl2(a-diimine)n] (M = Pd, Pt; L = phosphine or arsine; n = 1, 2) containing s,s-N,N, sN, or s-N´´sN, bonded a-diimines (1980) (71)
Crystal and molecular structure of C, N-{2-[(dimethylamino)methyl]phenyl} diphenyltin bromide (1976) (70)
ortho-Chelating Arenethiolatocopper(I) Complexes as Versatile Catalysts in the Regioselective Cross-Coupling of Allylic Derivatives with nBuMgI—An Example of Reversed Reactivity of Leaving Groups (1995) (70)
Model for the initial stage in the oxidative addition of I2 to organoplatinum(II) compounds. X-ray structure of square-pyramidal [PtIII{C6H3(CH2NMe2)2-o,o'} (h1-I2)] containing a linear Pt-I-I arrangement (1986) (70)
Replacement of a cyclometalated terdentate diamino ligand by a phosphorus analogue. Isolation and crystallographic characterization of an intermediate in aryl C-H bond activation in models of dendrimer-bound organometallic catalysts (1997) (70)
Palladium Colloid Stabilized by Block Copolymer Micelles as an Efficient Catalyst for Reactions of C−C and C−Heteroatom Bond Formation (2006) (70)
A Bis(ortho-amine)aryl-Gold(I) Compound as an Efficient, Nontoxic, Arylating Reagent (2002) (69)
Organic Transformations on σ‐Aryl Organometallic Complexes (2007) (69)
Carbon-oxygen bond formation at metal(IV) centers: Reactivity of palladium(II) and platinum(II) complexes of the [2,6-(dimethylaminomethyl)phenyl-N, C, N]- (pincer) ligand toward iodomethane and dibenzoyl peroxide; structural studies of M(II) and M(IV) complexes (2004) (68)
Controlled radical polymerization of styrene in the presence of lithium molybdate(V) complexes and benzylic halides (1999) (66)
Metal-chelating capacities attached to fullerenes (2002) (66)
Organonickel(II) complexes of the terdentate monoanionic ligand o,o'-bis[(dimethyl-amino)methyl] phenyl (N-C-N). Syntheses and X-ray crystal structure of the stable nickel(II) formate [Ni(N-C-N)O2CH] (1984) (65)
Monomeric bis(h2-alkyne) complexes of copper(I) and silver(I) with h1-bonded alkyl, vinyl, and aryl ligands (1996) (65)
“Click” Immobilization of Organometallic Pincer Catalysts for C−C Coupling Reactions (2009) (65)
On the way to chiral copper(I) arenethiolate catalysts for the enantioselective conjugate addition of methyl lithium and methyl magnesium iodide to benzylideneacetone (1991) (65)
Synthesis and Characterization of the Bis-Cyclometalating Ligand 3,3‘,5,5‘-Tetrakis[(dimethylamino)methyl]biphenyl and Its Use in the Preparation of Bimetallic M(II), M(IV) (M = Pt, Pd), and Mixed-Valence Pt(II)−Pt(IV) Complexes via a Dilithio-Derivative. Crystal Structure of the Pd Dimer [ClPd{2,6- (1998) (64)
Chiral platinum and palladium complexes containing functionalized C2-symmetric bisaminoaryl ‘Pincer’ ligands (2001) (62)
Copper(II)-Mediated Oxidative Coupling of Bis(dimethylaminomethyl)arylruthenium Complexes to give [(terpy)RuIII(pincer-pincer)-RuIII(terpy)](CuCl2)4 (1994) (62)
Palladium and platinum diphenoxide and aryl phenoxide complexes with amine donors : Effect of hydrogen bonding on structure and properties (1992) (61)
INTRAMOLECULAR COORDINATION IN GROUP 3 AND LANTHANIDE CHEMISTRY. AN OVERVIEW (1996) (61)
Asymmetric Induction in the Arenethiolatocopper(I)-Catalyzed Substitution Reaction of Grignard Reagents with Allylic Substrates (2000) (60)
Comparative Rates of Ligand Substitution Reactions of Pt-C-Bonded Complexes in Aqueous Solution and the X-ray Crystal Structure of (Pt{C6H3(CH2NMe2)2-2,6}(OH2))(OSO2CF3) (1996) (59)
Gas Sensor Materials Based on Metallodendrimers (1999) (59)
Stereochemistry of Arylmetal-1B, aryllithium, and arylmetal-1b-lithium clusters Ar4M2Li2 (M = Cu, Ag, or Au). Detection of rotation of three-center two-electron bonded aryl groups around the C(1)-C(4) axis (1979) (59)
Ligand-free copper(I) catalyzed N- and O-arylation of aryl halides (2007) (59)
Organoplatinum building blocks for one-dimensional hydrogen bonded polymeric structures (1996) (58)
Synthesis and properties of trimeric ortho-chelated (arenethiolato)copper(I) complexes (1991) (57)
Crystal structure of the neutral diaryl cuprate Cu2Li2(C6H4CH2NMe2-2)4: the asymmetric bonding configuration of organo groups bridging Cu and Li (1985) (57)
Synthesis and properties of some 2-(dimethylamino)methyl-substituted arylcopper compounds (1975) (57)
2,6-Bis(oxazolinyl)phenylnickel(II) bromide and 2,6-bis(ketimine)phenylnickel(II) bromide: Synthesis, structural features, and redox properties (2007) (57)
Self-assembled Organoplatinum(II) Supermolecules as Crystalline, SO2 Gas-triggered Switches (2000) (57)
Synthesis and spectroscopic studies of silver rhodium mono- and poly- nuclear complexes with multidentate phosphines (Ph2P)2CHR (R = H, Me, PPh2) (1981) (56)
A view of organocopper compound and cuprates (1990) (56)
‘Click’ silica immobilisation of metallo-porphyrin complexes and their application in epoxidation catalysis (2009) (56)
Optically Active Hyperbranched Polyglycerol as Scaffold for Covalent and Noncovalent Immobilization of Platinum(II) NCN-Pincer Complexes. Catalytic Application and Recovery (2004) (56)
A model structure for the resting state of cyanocuprate reagents R2Cu(CN)Li2. The X-ray Crystal Structure of [Ar2Cu(CN)Li2(THF)4] (1998) (55)
A hydrogen atom in an organoplatinum-amine system. 1. Synthesis and spectroscopic and crystallographic characterization of novel zwitterionic complexes with a Pt(II)[sup [minus]][center dot][center dot][center dot]H-N[sup +] unit (1992) (55)
Ionic 4,4‘-Biphenylene-Bridged Bis-ruthenium Complexes [Ru2(4,4‘-{C6H2(CH2NMe2)2-2,6}2)(terpy)2]n+ (n = 2 and 4) and Their Reversible Redox Interconversion: A Molecular Switch (1998) (55)
Development of the First P‐Stereogenic PCP Pincer Ligands, Their Metallation by Palladium and Platinum, and Preliminary Catalysis (2001) (54)
Substituted 4,4′-Stilbenoid NCN-Pincer Platinum(II) Complexes. Luminescence and Tuning of the Electronic and NLO Properties and the Application in an OLED (2008) (53)
16- 18-electron ruthenium(II) complexes of the neutral, potentially tridentate triamine logand 2,6-[bis(dimethylamino)methyl]pyridine (NN'N) (1998) (53)
Novel P-Stereogenic PCP Pincer-Aryl Ruthenium(II) Complexes and Their Use in the Asymmetric Hydrogen Transfer Reaction of Acetophenone (2005) (52)
Application of N,S-chelating chiral zinc bis(arenethiolate) complexes as new precursor catalysts in the enantioselective addition of diethylzinc to aldehydes (1994) (52)
Oxygenation of cyclopalladated N,N-dimethylbenzylamine complexes by inorganic and organic peroxides : Oxygen insertion into the palladium-carbon bond (1993) (52)
Cyclopalladation of 2-[(Dimethylamino)methyl]-Substituted Naphtalenes : 1- vs 3-Palladation. Crystal Structures of [Hydrotris(pyrazoly)borato][2-[(dimethylamino)methyl]-3-naphthyl]palladium and trans-[4,4-Dimethyl-2-(2-naphthyl)oxazoline]palladium Dichloride (1994) (51)
1,2-Methyl shift between Pt and coordinated aryl group in the reaction of methyl iodide with 2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of Pt(II). X-ray crystal structure of the arenonium-platinum compound [Pt(o-tolyl)(Me C6H3(CH2NMe2)2-o,o')]I (1985) (50)
Soluble organic supports for the non-covalent immobilization of homogeneous catalysts; modular approaches towards sustainable catalysts (2005) (50)
PCP- and SCS-pincer palladium complexes immobilized on mesoporous silica: application in C-C bond formation reactions (2007) (49)
Versatile N,C,N Coordiantion Behaviour of a Monoanionic Aryldiamine Ligand in Ruthenium(II) Complexes: Syntheses and Crystal structures of [RuII{C6H3(CH2NMe2)2-2,6}X(L)](L=Norbornadiene, X=Cl, SO3CF3; L=PPh3, X=I) and [RuII{C6H3(CH2NMe2)2-2,6}(2,2':6',2'-terpyridine)]Cl (1996) (49)
Incorporating ECE-pincer metal complexes as functional building blocks in semisynthetic metalloenzymes, supramolecular polypeptide hybrids, tamoxifen derivatives, biomarkers and sensors (2009) (49)
Diazabutadienes as ligands.I. Compounds of aluminium: coordination of diazabutadienes to Al(CH3)3 and subsequent intramolecular insertion and rearrangement reactions leading to [(CH3)2Al(RNCH(CH3)C(R')=NR)] (R' = H, CH3) and (CH3)2AlRNCH2C(CH3) =NR (1979) (49)
Group IB Organometallic chemistry : XV. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. One-step synthesis of triorganotin halides of the type Ar3SnX and Ar3-nRnSnX (1975) (49)
Cross-coupling versus homo-coupling in the reactions of dimethyl(N,N,N'N'-tetramethylethanediamine)palladium with organic halides (1990) (49)
Periphery-functionalized organometallic dendrimers for homogeneous catalysis (1999) (48)
Novel tridentate diamino organomanganese(II) complexes as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon-carbon bond forming reactions (1998) (48)
Facile and rapid immobilization of copper(II) bis(oxazoline) catalysts on silica: application to Diels-Alder reactions, recycling, and unexpected effects on enantioselectivity (2004) (47)
Stable arylsilver compounds containing dimethylamino, (dimethylamino)methyl or methoxy groups at the aryl nucleus (1973) (46)
Group IB Organometallic Chemistry. XVI. Complex formation between 2-(dimethy- lamino)phenylcopper with copper(I) or silver halides. Synthesis and structural characterization of hexanuclear (2-Me2NC6H4)4Cu6-nMnX2 (M = Cu or Ag) cluster compounds (1975) (46)
New homogeneous catalysts in the addition of polyhalogeno alkanes to olefins; organonickel(II) complexes [Ni{C6H3(CH2NMe2)2-o,o'}X] (X = CL, Br, I) (1988) (46)
Copper(I) Bromide/N-(n-Octyl)-2-pyridylmethanimine−Mediated Living-Radical Polymerization of Methyl Methacrylate Using Carbosilane Dendritic Initiators (2000) (45)
Aminoarenethiolato-copper(I) as (pre-)catalyst for the synthesis of diaryl ethers from aryl bromides and sequential C-O/C-S and C-N/C-S cross coupling reactions (2010) (45)
Synthesis and structural investigation of mesityldiphenylmethylenephosphine bis(triphenylphosphine)platinum(0) (1982) (45)
Oxidative-addition-reductive-elimination reactions of mono- and bis(aryl)platinum(II) complexes with two amino ligands in fixed trans positions. X-ray crystal structures of (2,6-bis[(dimethylamino)methyl]phenyl)(4-tolyl)platinum(IV)diiodide and (2,6-bis[(dimethylamino)methyl]phenyl)platinum(IV) tric (1990) (45)
Metal Heterodiene Complexes (1985) (45)
Pentacoordinate [8-(dimethylamino)naphthyl]diorganotin halides containing a rigid, flat NCCCSn chelate ring. An unexpected redistribution reaction between [8-(dimethylamino)naphthyl]trimethyltin and trimethyltin halide (1983) (45)
1,6 Addition of Organolithium to Acceptor-Substituted Enyes Catalysed by a Copper(I) Arenethiolate (1993) (44)
Phenylpalladium(IV) Chemistry : Selectivity in Reductive Eli mination from Palladium(IV) Complexes and Alkyl Halide Transfer from Palladium(IV) to Palladium(II) (1994) (44)
Intramolecularly Stabilized 1,4-Phenylene-Bridged Homo- and Heterodinuclear Palladium and Platinum Organometallic Complexes Containing N,C,N-Coordination Motifs (1998) (44)
Methyl-, acetyl- and allyl-palladium and -platinum complexes containing the novel chiral phosphorus-imine 2-(diphenylphosphino)- benzylidene-S( - )-a-methyl-benzylamine ligand (1996) (44)
Synthesis and characterization of arylcopper compounds containing the methoxy or dimethylamino group as a built-in ligand (1975) (43)
Arylnickel(III) species containing NO3, NO2 and NCS ligands. ESR data and the X-ray crystal structure of hexacoordinate (pyridine)bis(isothiocyanato)[o,o'-bis{(dimethylamino) methyl}phenylnickel(III) (1986) (43)
Hetero-multimetallic Tetrakis(SCS-pincer palladium)-(Metallo)porphyrin Hybrids. Tunable Precatalysts in a Heck Reaction (2008) (43)
Single-Site Catalysts on a Cylindrical Support Beyond Nanosize (2003) (43)
Membrane reactor for homogeneous catalysis in supercritical carbon dioxide (2003) (43)
Bimetallic η6,η1 SCS- and PCP-Pincer Ruthenium Palladium Complexes: Synthesis, Structure, and Catalytic Activity (2010) (43)
X-Ray and NMR Study of the Structural Features of SCS-Pincer Metal Complexes of the Group 10 Triad (2008) (43)
Silver complexes containing an Ag4O8 core imposed by multidentate ligands having fixed geometry. Crystal structure of**[bis(1,8-naphthalenedicarboxylato)] [tetrakis(triphenylphosphine)silver(I)] dibenzene (1979) (43)
Transcyclometalation : A Novel Route to (Chiral) Bis-Ortho-Chelated Bisphosphinoaryl Ruthenium(II) Complexes (2000) (42)
New Ruthenium(II) Complexes of Functionalized Monoanionic Aryldiamine N,C,N'‐Terdentate Ligands: Syntheses of [RuII{2,6‐(Me2NCH2)2‐4‐R‐C6H2}‐(terpy)]+Cl‐; X‐ray Structure of a Dimeric Organolithium Compound, [Li{2,6‐(Me2NCH2)2‐4‐Ph‐C6H2}]2 (1996) (42)
para-Functionalized NCN-Pincer Palladium(II) Complexes: Synthesis, Catalysis and DFT Calculations (2003) (42)
Electronic Effects in PCP-Pincer Ru(II)-Based Hydrogen Transfer Catalysis (2007) (42)
An Efficient (2‐Aminoarenethiolato)copper(I) Complex for the Copper‐Catalysed Huisgen Reaction (CuAAC) (2009) (42)
Designing Ionic Liquids: 1-Butyl-3-Methylimidazolium Cations with Substituted Tetraphenylborate Counterions (2003) (41)
Halide-Assisted Macrocyclic Ring Formation in Cyclometalated Carbosilane Dendrimers with 1-[C6H3(CH2NMe2)-4-(PdCl)-3] Peripheral Groups: Application as Aldol Condensation Catalysts (2001) (41)
Synthesis and reactivity towards diiodine of palladium(II) and platinum(II) complexes with non-cyclic and cyclic ligands (C6H3{CH2NR1R2}2-2,6)−. End-on diiodine-platinum(II) bonding in macrocyclic [PtI(C6H3{CH2NMe(CH2)7MeNCH2}-2,6)(η1-I2)] (1990) (41)
Asymmetric catalysis with chiral organocopper-copper arenethiolates (1994) (41)
Chiral induction in the sysnthesis of 4,4-dimethyl-1-phenylpenta-1,2-diene (1-Ph-3-t-Bu-allene) catalyzed by chiral phosphine complexes of palladium (1989) (41)
Novel enantiopure non-C2-symmetric NCN-pincer palladium complexes with l-proline chiral auxiliaries: mer η3-N,C,N versus square planar η4-N,C,N,O coordination (2006) (41)
Novel aspects of η'-diiodine coordination and diiodine oxidative addition to platinum(II) and halide transfer oxidation reactions of organo-platinum(II) with Cu II X 2 (1990) (41)
Application of a homogeneous dodecakis (NCN-PdII) catalyst in a nanofiltration membrane reactor under continuous reaction conditions (2003) (41)
Aspects of transmetallation reactions of 2-Me2NCH2C6H4- and 2,6-(Me2NCH2)C6H3-Metal (Pd, Pt, Hg, Tl) complexes with metal carboxylates and low-valent metal (Pd, Pt) complexes (1981) (41)
Synthesis and characterization of a stable bis-naphthyltin(II) compound. Bis[8-(dimethylamino)-1-naphthyl-C,N]tin(II) and its W(CO)5 adduct☆ (1989) (40)
Comparison of free and metal coordinated 1,4-disubstituted-1,4-diaza-1,3-butadienes. Crystal and molecular structures of 1,4-dicyclohexyl-1,4-diaza-1,3-butadiene and trans-[dichloro(triphenylphosphine)(1,4-di-tert-butyl-1,4-diaza-1,3-butadiene)Palladium (II)] (1983) (40)
2,4,6-Triisopropylphenylcopper, a new tetranuclear organocopper aggregate with unsymmetrically bridging s-p bonded aryl ligands (1989) (40)
Mechanistic aspects of the reversible binding of SO2 on arylplatinum complexes: Experimental and ab initio studies (2001) (40)
Hypercoordinate Aryltrialkylsilanes and -stannanes and Their Use in the Synthesis of Homodinuclear Organometallic Complexes with a 1,4-Phenylene Bridge† (1997) (40)
Five-coordinate [PtIICl2(h2-olefin)L2] (L2 = s,s-N,N' bonded a-diimine or N,N'-disubstituted-1,2-diaminoethane) complexes. Solution conformation, h2-olefin rotational barriers (NMR) and X-ray molecular structure of [PtCl2(h2-styrene) (t-Bu-N=CHCH=N=t-Bu)] (1981) (40)
Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents (2008) (40)
Synthesis and molecular structures of novel α-amino organoaluminum ester enolates. Key intermediates in the selective formation of trans-3-amino-2-azetidinones (1991) (40)
Transition Metal Dendrimer Catalysts (2006) (40)
Organozinc α-diimine radicals. Synthesis and reactivity toward alkyl halides (1994) (40)
Fast Suzuki–Miyaura Cross-Coupling Reaction with Hexacationic Triarylphosphine Bn-Dendriphos as Ligand (2008) (39)
Reversible binding of SO2 to arylplatinum(II) and -nickel(II) complexes. X-ray crystal structure of the five-coordinate platinum(II) sulphur dioxide complex [PtBr{C6H3(CH2NMe2)2-o,o'}(h'-SO2)] (1986) (39)
Sulfur dioxide gas detection by reversible η1-SO2–Pt bond formation as a novel application for periphery functionalised metallo-dendrimers‡ (1998) (39)
Intramolecular penta- and hexa-coordinate tetraorganotin compounds containing the 8-(dimethylamino)-1-naphthyl ligand (1991) (39)
Organopalladium complexes with bidentate phosphorus and nitrogen containing ligands (1988) (39)
Versatility in phenolate bonding in organoaluminum complexes containing Mono- and Bis(ortho)-chelating phenolate ligands. X-ray structures of Al{OC6H2(CH2NMe2)2-2,6-Me-4}3, Al(Me)2{OC6H2(CH2NMe2-2,6-Me-4} N-AlMe3, and Al(Me)2{OC6H2(CH2NMe2)2-2,6-Me-4} N-AlMe3O-AlMe3 (1995) (39)
Complexes of Bis-ortho-cyclometalated Bisphosphinoaryl Ruthenium(II) Cations with Neutral Meta-bisphosphinoarene Ligands Containg an Agostic C-HRu Interaction (2000) (39)
Application of S,N-Chelating Chiral Zinc Bis(aminoarenethiolates) as New Precursor Catalysts in the Enantioselective Addition of Dialkylzincs to Aldehydes† (1997) (38)
Polynuclear aryl copper species and neutral aryl cuprates with a chiral CH(Me)NMe2 ortho substituent (1989) (38)
Synthesis and structural studies of phenyl( iodo) - and methyl( phenyl) palladium( II) complexes of bidentate nitrogen donor ligands (1994) (38)
Orthometalation of m-bis(dimethylaminomethyl)benzene: crystal structure and chemistry of trans-Rh(III)Cl2[C6H3(CH2NMe2)2-o,o'](H2O) (1988) (38)
Syntheses and structural aspects of rigid aryl- palladium(II) and -platinum(II) complexes. X-ray crystal structure of o,o′-bis[(dimethylamino)methyl]phenyl- platinum(II) bromide (1986) (38)
Chiral Amino Alcohol Derived Bis-phosphoramidite Pincer Palladium Complexes and Their Applications in Asymmetric Allylation of Aldimines (2010) (38)
Stereoselective one-pot syntheses of trans-3-amino-β-lactams from zinc enolates of N-protected α-aminoacid esters and imines (1988) (38)
Chemistry of P,N-Ligated Methylpalladium(II) Alkoxide Complexes: Syntheses, Structural Features in the Solid State and in Solution, and Hydrogen-Bond Formation (1996) (38)
Well-Defined 2:1 and 2:2 Arylcopper−Copper Bromide Aggregates and Selective Biaryl Formation (1996) (37)
Enantioselective Synthesis of 3-Amino-2-azetidinones via the Ester Enolate-Imine Condensation (1992) (37)
New arylruthenium(II) complexes of the P,C,P'-Coordinating terdentate monoanionic aryl ligands [C6H2(CH2PPh2)2-2,6-R-4]- (PCP-R-4; R = Ph, H). Synthesis of 16-electron species [RuIIX(PCP-R-4)(PPh3)] (X = Cl, L, OTf) and their reactivity toward the neutral terdentate N-donor ligand 2,2':6',2''-terpyr (1996) (37)
s2-N,m2-N,h2-C=N coordination as the activating step in the C-C bond formation between two a-diimines in dinuclear ruthenium carbonyl complexes. X-ray structure of tetracarbonyl[glyoxalbis(isopropylimine)]diruthenium (1980) (37)
Separation of kinetics and mass-transport effects for a fast reaction: the selective hydrogenation of functionalized alkynes (2003) (37)
Binuclear metal carbonyl dab complexes : II. The syntheses and coordination properties of Mn(CO)5M′(CO)3DAB (M′ = Mn, Re; DAB = 1,4-diazabutadiene) (1981) (36)
Reactivity of organopalladium compounds towards molybdenum peroxides : Oxygen insertion versus C-Cl and C-O coupling : Evidence for Palladium(IV) molybdate intermediates (1993) (36)
Dinuclear five-coordinate diorgano[(2-pyridyl)methoxyl]aluminum compounds: dynamic behaviour in solution (1H-, 13C- and 27Al-NMR) and molecular geometry of [i-Bu2AlOCH2-2-C5H4N]2 (X-ray) (1985) (36)
PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions (2010) (36)
New aspects of chiral heteroorganocuprates and an x-ray crystal structure with unprecedented magnesium-sulfur bonds (1990) (36)
Synthesis and molecular geometry of [trans-PtCl2PBu3]2(di-t-Bu-diimine) containing a σ,σ′-N,N′ bridging diimine with a planar anti-(trans-PPNCCNPtPtrans)- skeleton (1980) (36)
BINAP-Ru and -Rh catalysts covalently immobilised on silica and their repeated application in asymmetric hydrogenation (2008) (36)
The use of dimethyl sulfide in organocopper chemistry; X-ray crystal structures of cyclo-tetrakis-(m-2-methylphenyl)bis(dimethylsulphide)tetracopper(I) and of the polymeric copper bromide adduct bromo(dimethyl sulphide)-copper(I) (1991) (35)
Group IB Organometallic Chemistry 18. Novel routes to stable hexanuclear copper-silver, silver-gold and copper-gold cluster compounds starting from polymeric 2-(dimethylamino)phenylcopper and from bis-[2-(dimethylamino)phenyl]goldlithium dimer (1977) (35)
Synthesis of 8-(dimethylamino)-1-naphthyllithium etherate. Its structure in the solid (X-ray) and in Solution (7Li and 1H NMR) (1983) (35)
General Approach for Template‐Directed Synthesis of Macroheterocycles by Ring‐Closing Metathesis (RCM) (2005) (35)
2 – Copper and Silver (1995) (35)
Vanadium(III) and -(IV) Complexes with O,N-Chelating Aminophenolate Ligands: Synthesis, Characterization and Activity in Ethene/Propene Copolymerization (2001) (35)
Mono- and bis-ortho-chelated lithium and sodium phenolates. Molecular structures of the first lithium phenolate with a stable, trinuclear structure and of a tetranuclear sodium analog, [MOC6H2(CH2NMe2)2-2,6-Me-4]x (M = Li, x = 3; M = Na, x = 4) (1993) (35)
Carbon tetrachloride free benzylic brominations of methyl aryl halides (2003) (35)
Chemistry of Diamino Ligated Methylpalladium(II) Alkoxide Complexes: Syntheses, X-Ray Crystal Structures and Hydrogen-Bond Formation (1995) (35)
INTRAMOLECULARLY CHELATED DI‐ AND TETRANUCLEAR ARYLLITHIUM COMPOUNDS: CRYSTAL STRUCTURE OF LI4(C6H4(2‐CH2NME2))4 CONTAINING 4‐CENTER 2‐ELECTRON‐BONDED C(ARYL) ATOMS AND HEPTACOORDINATE LITHIUM ATOMS (1983) (34)
The reactions of 2-[(dimethylamino)methyl]phenylcopper and -lithium tetramer with cuprous and cupric halides (1975) (34)
Fluorous derivatives of [Rh(COD)(dppe)]BX4 (X=F, Ph): synthesis, physical studies and application in catalytic hydrogenation of 1-alkenes and 4-alkynes (2002) (34)
Influence of the amino substituents of potentially bis ortho chelating aryl ligands (2,6-{R1R2NCH2}2C6H3)- on the synthesis and properties of their organonickel(II) complexes (1991) (33)
Synthesis and Coordination Chemistry of Gold(I) Acetylides. The Solid-State Structure of {[η2-(Ph3P)AuC⋮CFc]Cu(μ-Cl)}2 (2001) (33)
Alkylation Reactions of dialkylzinc Compounds with 1,4-Diaza-1,3-butadienes : Cationic and Radical Anionic Organozinc intermediates. Molecular Structure of the Cationic Organozinc Species [MeZn(t-BuN=CHCH=N-t-Bu)]O3SCF3 and Me2Zn(bpy)(bpy = 2,2-Bipyridine) (1994) (33)
The Effect of the Trimethylsilyl Group on Electrophilic Cyclopalladation; A study of Caryl -Si versus Caryl-H Selective Bond Activation with 2,6-(Me2NCH2)2C6H3R (R=H or SiMe3) (1998) (33)
Organocopper Compounds: From Elusive to Isolable Species, from Early Supramolecular Chemistry with RCuI Building Blocks to Mononuclear R2–nCuII and R3–mCuIII Compounds. A Personal View (2012) (33)
Group IB organometallic chemistry : XXXII. Arylcopper compounds ArnCun as intermediates in organometallic synthesis. Single-step synthesis and dynamic NMR spectroscopy of diorganotin dihalides Ar2-nRnSnX2 (Ar 2-Me2NCH2C6H4 or (S)-2-Me2NCHMeC6H4; n 0 or 1) (1979) (33)
A STABLE BIMETALLIC COPPER(I) TITANIUM ACETYLIDE (1995) (33)
A chiral coordination polymer of silver(I) and a polydentate ligand with one asymmetric centre: X-ray structure of the (1:1) complex of AgO3SCF3 and [N-(5-methyl-2-thienylmethylidene)-L-methionyl]histamine (1989) (33)
Group 1B organometallic chemistry. Part 25. Crystal and molecular structure of 1,2,3;1,4,5;2,3,6;4,5,6-tetrakis-µ3-2-dimethylaminophenyl-2,5;3,4-bis-µ2-4-tolylethynyl-octahedro-hexacopper(I) (1978) (33)
The synthesis and properties of novel (organo)zinc enoaltes of N,N-disubstituted glycine esters : Molecular structure of [EtZnOC(OMe)=C(H)N(t-Bu)Me]4 (1991) (32)
Acetylene-bridged P,C,P′-ligands and corresponding cyclopalladated compounds (2000) (32)
Bimetallic η6,η1 NCN-pincer ruthenium palladium complexes with η6-RuCp coordination: synthesis, X-ray structures, and catalytic properties (2009) (32)
Organotin(IV) compounds 2-(Me2NCHR)C6H4(SnR′R″Br) with a fixed s-cis arrangement of the chiral carbon and tin centers. Crystal structure of 2-(Me2NCHBut)C6H4SnMePhBr (1991) (32)
Stabilization and reaction behaviour of a terminal phosphido unit on a mononuclear Pt(II) centre. Synthesis and X-ray structure of a cationic diphenylphosphine complex [Pt{C6H3(CH2NMe2)2-2,6}(PHPh2)][OSO2CF3] and a diphenylphosphido-bridged Pt(II)/Pd(II) complex [Pt{C6H3(CH2NMe2)2-2,6}(μ-PPh2)Pd(C6H (1995) (32)
RING-OPENING METATHESIS POLYMERIZATION OF NORBORNENE CATALYZED BY A RU(II)-VINYLIDENE COMPLEX (1999) (32)
Oxidative-addition reactions of molecular diiodine and dibromine to divalent organotin compounds. Crystal structures of bis(8-( dimethylamino)-1-naphthyl)tin( IV) dibromide and { 2,6-(bis( dimethylamino)methyl)phenyl} - (4-tolyl) tin( IV) diodide (1991) (32)
Oxidative-addition reactions of cyclometallated platinum(II) compounds with mercury(II) carboxylates. X-ray, crystal and molecular structure of rac-[a-(m-MeCO2)-cf,de-(2-Me2NCH2C6H4)2PtHg(O2CMe)] (1982) (32)
Use of an aryldiamine pincer ligand in the study of tantalum alkylidene-centered reactivity: tantalum-mediated alkene synthesis via reductive rearrangements and Wittig-type reactions (1992) (32)
Copper(I), lithium, and magnesium thiolate complexes: An overview with due mention of selenolate and tellurolate analogues and related silver(I) and gold(I) species (1997) (32)
The use of ortho-chelating arenethiolate non-transferable groups in the copper(I) catalyzed selective α or γ substitution of acyclic allylic substrates with grignard reagents (1994) (31)
SYNTHESIS AND CATALYTIC APPLICATION OF AMINO ACID BASED DENDRITIC MACROMOLECULES (1999) (31)
The unusual solid state structures of the pentasubstituted bis(cyclopentadienyl)zinc compounds bis(pentamethylcyclopentadienyl)zinc and bis(tetramethylphenylcyclopentadienyl)zinc (1989) (31)
Determination of the Degree of Aggregation of Organocopper Compounds by Cryoscopy in Tetrahydrofuran (1997) (31)
The role of neutral and radical anionic organozinc complexes in the alkylation reactions of 1,4-diaza-1,3-butadienes with diorganozinc compounds (1997) (31)
Structural investigation of aryllithium clusters in solution I. A 13C and 7Li NMR study of phenyllithium and some methyl-substituted phenyllithium derivatives (1988) (31)
n1- and n2-Coordination in a (phosphoalkene)platinum(0) complex (1983) (31)
Novel silica immobilized NCN-pincer palladium(II) and platinum(II) complexes: Application as Lewis acid catalysts (2006) (31)
Unusual isomerization of ortho chelated aryliridum(I) complexes, involving a unique sequence of intramolecular C-H bond making and breaking processes. X-ray structure of IrI[C6H3(CH2NMe2)2-2,4](COD) (1988) (31)
Ortho-chelated arylrhodium(I) complexes. X-ray structure of RhI[C6H3(CH2NMe2)2-o,o'-C,N](COD) (1988) (31)
Crystal structure and molecular geometry of a square-pyramidal platinum(II) complex,[{2,6-(Me2NCH2)2C6H3}Pt(m-{(p-tol)NC(H)N(i-Pr)}HgBrCl], containing a PtII- to HgII donor bond (1982) (31)
Group 1B organometallic chemistry XXIX. Synthetic and structural aspects of polynuclear arylcopperlithium compounds Ar4Cu2Li2 ('arylcuprates') and interaggregate exchange phenomena in Ar4Cu4/Ar4Li4/Ar4Cu2Li2 systems (1979) (31)
Metal-Mediated C-C Bond Making and Breaking : First Direct Evidence for a Reversible Migration of a Benzyl Group Along a Metal-Carbon Bond (1999) (30)
TRANS-2,6-BIS((DIMETHYLAMINO)METHYL)PHENYL-N,N′,C COMPLEXES OF PALLADIUM(II) AND PLATINUM(II). CRYSTAL STRUCTURE OF (PTI(MEC6H3(CH2NME2)2-O,O′))BF4: A CYCLOHEXADIENYL CARBONIUM ION WITH A Σ-BONDED METAL SUBSTITUENT (1983) (30)
Synthesis and Structural Characterization of Lithium and Trimethyltin Complexes of 2,6-Bis(oxazolinyl)phenyl (2005) (30)
Unexpected metal base-dependent inversion of the enantioselectivity in the asymmetric synthesis of α-amino acids using phase-transfer catalysts derived from cinchonidine (2002) (30)
A new and efficient route to 3-amino-2-azetidinones via zinc enolates of (N,N-disubstituted)glycine esters (1991) (30)
A Redox Asymmetric, Cyclometalated Ruthenium Dimer: Toward Upconversion Dyes in Dye-Sensitized TiO2 Solar Cells (2010) (30)
Formation of mixed aryl-, alkyl-lithium aggregates in the heteroatom assisted lithiation of a,a'-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene (1998) (29)
Dinuclear silver(I) and copper(I) complexes with neutral N2S2 donor ligands and their reactivities towards CO. Structures in solution (1H and INEPT 109Ag NMR) and in the solid (X-ray) of [Ag2{μ-(R)(S)-1,2-(thiophene-2–CHN)2cyclohexane}2](O3SCF3)2 (1985) (29)
Synthesis and molecular structure of copper(I) and organozinc(II) arylthiolates with chelating amino and ether groups: X-ray structure of [CuSC6H4(CH2N(Me)-CH2CH2OMe)-2]4 and [Zn(Me){SC6H4(R)-CH(Me)NMe2}]2 (1991) (29)
Structural investigations of aryllithium clusters in solution. II. A 13C and 7Li NMR study of substituted phenyllithium compounds containing ortho-directing -NMe2 and-CH2NMe2 groups (1988) (29)
Synthesis of cyclometalated (8-methoxynaphthyl)- and [8-(dimethylamino)naphthyl]platinum compounds and their reactivity toward electrophiles. X-ray molecular structures of square-planar (8-methoxynaphthyl)platinum(II) chloride bis(diethyl sulfide) and bis(8-methoxynaphthyl)platinum(II) diethyl sulfi (1988) (29)
Arylpalladium compounds containing an alcohol functionality : Hindered rotation around the Pd-C bond and reactivity towards styrene and carbon monoxide : Comments on C-O bond shortening in late transition metal alkoxides (1993) (29)
Magnetic silica colloids for catalysis (2007) (29)
Binuclear metal-carbonyl DAB complexes VI. Synthesis and spectroscopic properties of MCo(CO)5(m2-CO)(DAB) (M = Mn, Re; DAB = 1,4-diazabutadiene).X-Ray structure of [s2-N,s2-N,h2-C=N-[glyoxal[bis(t-butylimine)]]hexacarbonylcobalt-manganese (1981) (29)
Silver(I) and copper(I) bis(pyridine-2-carbaldehyde-imine) triflate complexes studied in solution by 1H, 1H-{109Ag}, INEPT 15N and INEPT 109Ag NMR (1984) (29)
Bis(1-methylimidazol-2-yl)propionates and Bis(1-methylbenzimidazol-2-yl)propionates: A New Family of Biomimetic N,N,O Ligands - Synthesis, Structures and CuII Coordination Complexes (2005) (29)
The .eta.1- and .eta.2-coordination in a (phosphaalkene)platinum(0) complex (1984) (29)
Regioselective ethyl transfer reactions between Diethylzinc and 1,4-Dialkyl-1,4-diaza-1,3-butadienes: Synthesis of EtZn[R(et)NCHCHNR] (1982) (29)
Tungsten(VI) Phenylimido Alkylidene complexes containing a Monoanionic O,N-Chelating Ligand and Their Isolated Precursor Complexes: X-ray Structures of W(CH2SiMe3)3(=NPh)[OCPh2(2-py)] and W(=CHSiMe3)(CH2SiMe3)(=NPh)[OCPh2(2-py)] (1994) (29)
Bis-ortho-chelated Diaminoaryl Platinum Compounds with s-Acetylene Substituents : Investigations into Their Stability and Subsequent Construction of Multimetallic Systems : The Crystal Structure of [(m2-[h2-NCN)Pt(h1-CO)C=CSiMe3])Co2(CO)6] (NCN=2,6-Bis[(dimethylamino),ethyl]phenyl) (2000) (29)
A hydrogen atom in an organoplatinum-amine system : Part 2: The first isolated aryl Pt(IV) hydrides : Synthestic and theoretical study (SCF and CAS-SCF calculations) on model complexes with a N-M(IV)-H / M(II)-.H-N+ unit (M = Pd or Pt) (1992) (28)
Palladium(0)-Alkene Bis(triarylphosphine) Complexes as Catalyst Precursors for the Methoxycarbonylation of Styrene (2005) (28)
Functionally substituted arylcopper compounds: synthesis, structure, and reactivity of (2-(2-oxazolinyl)aryl)copper(I) species (1988) (28)
Copper(I)aryl bonds in cluster complexes: The structure of [Cu(2-Me2NH6H4)]4(CuBr)2·1.5C6H6 (1972) (28)
Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes (1998) (28)
Novel aryl-bridged tetranuclear copper–lithium cluster compounds: synthesis and characterization by 13C and 1H nuclear magnetic resonance spectroscopy of bis-{2-[(dimethylamino)methyl]phenyl}copper(I) lithium (1972) (28)
Multiphase Systems for the Recycling of Alkoxycarbonylation Catalysts (2006) (28)
Organotin(IV) compounds derived from 2-Me2NC6H4CH2Li and its chiral a-Me3Si-derivative. X-ray structure of penta-coordinate [{2-(dimethylamino)phenyl}(trimethyl-silyl)methyl-C,N]methylphenyltin bromide having a chiral Sn center (1986) (28)
Bonding mode variations in palladium(II) and platinum(II) azaphosphole complexes; Identification by 1H-, 31P- and 195Pt-NMR of N- and P- coordination, Pt-Cl addition to P and dimerization (1988) (28)
An aryllithium complex with intramolecular coordination of an ortho-diamine substituent : X-ray and solution NMR structure of dimeric [Li{C6H4(Ch2N(Me)CH2CH2NMe2)-2}]2 (1994) (27)
Luminescent and Electronic Properties of Stilbenoid NCN‐Pincer PtII Compounds (2007) (27)
Metal—metal bonded compounds V . Compounds with Ir(Rh)Hg bonds containing a bridging and a chelating triazenido group, which interconvert intramolecularly (1980) (27)
Syntheses and characterization of neutral complexes of Zn(II) with mono- and dianionic pyrrole-2-imine ligands [(pyrrole-2-CHN)nR]n− (n = 1, 2) (1984) (27)
Synthesis of Polyaryl Rigid-Core Carbosilane Dendrimers for Supported Organic Synthesis (2009) (27)
Organonickel(II) complexes containing aryl ligands with chiral pyrrolidinyl ring systems; syntheses and use as homogeneous catalysts for the Kharasch addition reaction (1994) (27)
Selective formation of biaryls via interaction of polynuclear arylcopper compounds with copper(I) trifluoromethane sulphonate [(copper(I) triflate)] (1977) (27)
Reactivity of 1-aza-4-oxo-1,3-butadienes (a-iminoketones) towards diorganozinc reagents: Regio- and chemoselective transfer of organo groups in the ZnR2/R1N=C(R2)C(R3)=O system and X-ray structure of [EtZn(Et)(t-Bu)NC(H)= =C(Me)O]2 (1987) (27)
High-presure NMR and ab initio computational studies on the insertion mechanism of carbon monoxide into cationic monoorganopalladium(II) complexes bearing tridentate nitrogen donor ligands (1995) (27)
Structural features of silver(I) and copper(I) bis(thiophene-2-carbaldehyde-imine) trifluoromethanesulfonate complexes in the solid state and in solution: Crystal structures of [Ag[Th-2-Ch=N-(S)-CHMePh]2](O3SCF3) and [Cu{5-Me-Th-2CH=N-i-Pr}2](O3SCF3) and a 1H, 19F and 109Ag NMR study (1991) (27)
Synthesis and Structural Studies of Ionic Monoorganopalladium(II) Complexes with Tridentate Nitrogen-Donor Ligands (1994) (27)
Mixed Metal Acetylides: The PtII Aryl Acetylide “[PtC6H2(CH2NMe2)22,6‐(C≡C)‐4]” as a Connective Fragment (2000) (27)
Palladium(II) pincer complexes of α-amino acids: towards the synthesis of catalytically active artificial peptides (2002) (27)
Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling (1992) (26)
Iron and ruthenium complexes [M2(CO)6(pyridine-2-carbaldehyde-imine)] having a σ-N,μ2-N′, η2-CN′ bonded 6-R1-py-2-C(R2)NR ligand; x-ray structure of [Ru2(CO)5 &{1,2-bis(μ-isopropylamido)-1,2-bis(2-pyridyl)ethane}] containing two C|C linked pyridine-2-carbaldehyde-imine ligands (1986) (26)
The homogeneously catalysed addition reaction of polyhalogenoalkanes to olefins by divalent arylnickel complexes: comparative reactivity and some important mechanistic leads (1989) (26)
(Perfluoro)alkylsilyl-Substituted 2-[Bis(4-aryl)phosphino]pyridines: Synthesis and Comparison of Their Palladium Complexes in Methoxycarbonylation of Phenylacetylene in Regular Solvents and Supercritical CO2 (2005) (26)
The Suzuki cross-coupling reaction: a powerful tool for the attachment of organometallic 'NCN'-pincer units to biological scaffolds (2003) (26)
A tetranuclear cluster complex of copper(I) with bridging aryl ligands: the crystal structure of (4-methyl-2-cupriobenzyl)dimethylamine (1972) (26)
METHYL-, ACETYL- AND ALLYL-PALLADIUM AND -PLATINUM COMPLEXES CONTAINING NOVEL TERDENTATE PNS AND NN'S LIGANDS (1996) (26)
Sequential C-H and C-Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with (1998) (26)
Dentritic Carbosilanes Containing Silicon-Bonded 1-[C6H2(CH2NMe2)2-3,5-Li-4] or 1-[C6H3(CH2NMe2)-4-Li-3] Mono-and Bis(amino)aryllithium End Groups: Structure of {[CH2SiMe2C6H3(CH2NMe2)-4-Li-3]2}2 (1999) (26)
Novel phosphite palladium complexes and their application in C–P cross-coupling reactions (2010) (26)
Chiroptical properties and applications in PTC of new dendritic cinchonidine-derived ammonium salts (2003) (26)
Homo- and heterodinuclear platinum and palladium complexes with a single unsupported monoatomic bridging group. Crystal structure of the 2,6-bis[(dimethylamino)methyl] phenylpalladium(II) derivative [Pd{C6H3(CH2NMe2)2-o,o })2(m-Cl)]BF4 (1982) (26)
Site-Selective Ser-Hydrolase Labelling with a Luminescent Organometallic NCN–Platinum Complex (2010) (26)
The role of mixed organocopper cluster compounds RnR'mCun+m in selective C-C coupling reactions of 2- and 4-(dimethylamino)phenylcopper with copper arylacetylides (1977) (26)
The formation of a mixed organolithium aggregate Li4R2nBu2 during the heteroatom assisted lithiation of 1,3-bis(dimethylaminomethyl)-2,4,6-trimethylbenzene(R=2,6- (CH2NMe2)2-3,5 Me2C6HCH2) (1995) (25)
Carbon–hydrogen and C–X (X = Cl or SiMe3) bond activation. 1-Cyclopalladation and oxidation of some derivatives of 2-[(dimethylamino)methyl]naphthalene (1994) (25)
Stable arylcopper compounds containing methoxy, dimethylamino, diphenylphosphino, or dimethylsulfamoyl groups at the aryl nucleus (1971) (25)
A comparative study of platinum di(t-butyl)(15N2)diimine) and trans-[PtCl2(N-ligand)PBu3)] complexes by 195Pt-, 31P- and 15N-NMR (1981) (25)
New ' Bucky- ligands'. Potentially Monoanionic Terdentate Diamino Aryl Pincer Ligands Anchored to C60 (1998) (25)
Five-coordinate platinum olefin complexes. Synthesis and high resolution 1H(250, 360 MHz) and 13C (20 MHz) NMR study of the interligand chiral recognition in the formation of diastereomeric [PtCl2( h2-olefin)(6-R'-py-2-CH=NR)] (1981) (25)
Fluorous biphasic hydrogenation of 1-alkenes using novel fluorous derivatives of Wilkinson's catalyst (1999) (25)
New Soluble Polysiloxane Polymers containing a Pendent Terdentate Aryliamine Ligand substituent Holding a Highly Catalytical Active Organometallic Nickel(II) Centre (1994) (25)
Recycling of Rodium-Based Hydrosilylation Catalysts; A Flourous Approach (2001) (25)
Group IB Organometallic Chemistry XXXIII: ArAuPPh3, ArAu(CNR), (ArAu)n and Ar4Cu2Au2 compounds in which the aryl group contains 2-MeO, 2,6-(MeO)2, 2-Me2N, 2-Me2NCH2 and (S)- or (R)-2-Me2NCHMe substituents as potential ligands (1979) (25)
Organozinc complexes with monoanionic chelating phenolates or 2-pyridylmethanolates. Molecular structure of [Zn(CH2SiMe3){OCH2(2-Py)}]4 (1993) (25)
Synthesis and reactivity of tantalum alkylidene complexes containing the C,N,N'-chelating aryldiamine ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2- (CNN). X-ray structurs of [TaCl2(=CH-t-Bu) (CNN)], [Ta{CH2)3-1,3}(CNN)(O-t-Bu)2], and [Ta(CNN)(O-t-Bu)2(H2C=CH2)] (1997) (24)
Prediction of partition coefficients of fluorous and nonfluorous solutes in fluorous biphasic solvent systems by mobile order and disorder theory (2004) (24)
Double Cyclometalation via Carbon−Silicon Bond Cleavage by Palladium(II) Acetate. X-ray Structure of a Cationic 1,4-Dipalladated Benzene Ring and Selective Synthesis of Heterobimetallic 1,4-Phenylene-Bridged Platinum(II)−Palladium(II) Complexes (1997) (24)
Binuclear metal carbonyl DAB complexes X. Activation of h2-C=N coordinated DAB ligands towards C-C bond formation with alkynes. The X-ray structure of {2-phenyl-3-(tert-butylamino)-4-(tertbutyl-imino)-1-butene-1-yl}Ru2(CO)5. Application to the catalytic cyclotrimerization of alkynes (1981) (24)
Arylmercury(II) compounds involving intramolecular coordination via 2-Me2NCH2- and chiral (S)-2-Me2NCHMe-ring substituents (1981) (24)
Carbosilane Molecules with Mono- and Bis(amino)arylmetal End Groups: Structures of {NiI(C6H2(CH2NMe2)2-2,6-SiMe3-4)} and Tetranuclear {(CH2Si(Me)2C6H3(CH2NMe2)-4-(PdCl)-3)2}2 (1999) (24)
8-(DIMETHYLAMINO)NAPHTHYLCOPPER(I), A NOVEL STABLE ORGANOCOPPER COMPOUND WITH UNUSUAL STRUCTURAL FEATURES. ITS SYNTHESIS, CRYSTAL STRUCTURE (X-RAY), AND REACTIVITY * (1987) (24)
The influence of intramolecular coordination on the aggregation of sodium phenolate complexes. X-ray structures of [NaOC6H4(CH2NMe2)-2]6 and [Na(OC6H2(CH2NMe2)2-2,6-Me-4)(HOC6H2NMe2)2-2,6-Me-4)]2 (1996) (24)
A Novel Trimeric Chiral Copper(I) Thiophenolate with Intramolecular Coordination (1989) (24)
Oxidation of organoplatinum(II) halides with halogens or copper(II) halides. Syntheses and molecular structure of [Pt(IV)Cl3(C6H3(CH2NMe2)2-o,o')] (1983) (24)
A hydrogen atom in an organoplatinum-amine system. 2. The first isolated arylplatinum(IV) hydrides: synthetic and theoretical study (SCF and CAS-SCF calculations) on model complexes with a N-M(IV)-H/M(II)-.cntdot..cntdot..cntdot.H-N+ unit (M = Pd, Pt) (1992) (24)
Tetrakis {3,5-bis(perfluorohexyl)phenyl}borate: a highly fluorous anion (2001) (24)
1:1 and 2:1 Lithium Zincates with Intramolecular Coordination. Structures of Li(thf)Zn(C6H4CH2NMe2-2)3 and Li2Zn(C6H4CH2NMe2-2)4 (1997) (24)
The unexpected formation of trans-b-lactams in the reaction of a-iminoesters (R-N=C(H)C(=O)OR') with diethylzinc. Crystal structure of trans-1-(N-t-butyl)-3-(N-t-butyl-N-ethylamino)-4-methoxycarbonylazetidin-2-one (1987) (23)
Fluorous Zirconocene(IV) Complexes and Their Olefin Polymerization Activity in Toluene and Fluorous Biphasic Solvent Systems. (2005) (23)
Enhanced Hydrogenation Activity and Recycling of Cationic Rhodium Diphosphine Complexes through the Use of Highly Fluorous and Weakly‐Coordinating Tetraphenylborate Anions (2003) (23)
An unexpected ethyl transfer reaction between Et2Zn and DI(t-Butyl)-glyoxaldiimine (t-BuDAB). Studies of the persistent [EtZn(t-BuDAB)] radical which is in equilibrium with its CC coupled dimer (1981) (23)
Novel trinuclear and hexanuclear heteroorganocopper compounds with phosphine ligands, bridging alkynyls, and intramolecularly coordinating bridging arylthiolates : X-ray structures of [Cu3{SC6H4(CH(R)NMe2)-2}2-(C_Ct-Bu)]2 (R = H, Me) (1992) (23)
Ortho-metalation of m-(Me2NCH2)2C6H4; crystal structure and chemistry of trans-RhIIICl2(C6H3(CH2NMe2)2-o,o')(H2O) (1988) (23)
Preparation and electrochemical behaviour of dinuclear platinum complexes containing NCN ligands (NCN=[C6H3(Me2NCH2)2-2,6]−). The crystal structure of [C6H3(Me2NCH2)2-1,3-(CC)-5]2 (2001) (23)
NOVEL ARYLTITANIUM(IV) COMPLEXES CONTAINING ETA 3-NCN-PSEUDOFACIAL- AND ETA 3-NCN-MERIDIONAL-BONDED C6H3(CH2NME2)2-2,6- (ABBREVIATED AS NCN) LIGANDS. THE CRYSTAL STRUCTURES OF TICL2(ETA 3-FAC-NCN)(O-I-PR), TICL(ETA 3-MER-NCN) (O-I-PR)(OTF) CONTAINING AN ETA 1-O-BONDED TRIFLATE ANION, AND THE SEVEN-C (1997) (23)
Copper(I) arenethiolates with intramolecular coordination and the formation of mixed organo(arenethiolate) copper(I) aggregates. X-ray structures of trimeric [Cu(S-1-C10H6NMe2-8)]9, and hexanuclear [Cu3(S-1-C10H6NMe2-8)2(C_CtBu)]2 (1996) (23)
Bis ortho chelated arylcopper compounds; Synthesis and X-ray crystal structure of Cu4Br2[C6H3(CH2NMe2)2-o,o']2 (1989) (23)
Synthesis of a New Multidentate Phosphane Ligand C6H2(CH2PPh2)4‐1,2,4,5 − X‐ray Structure of a Dinuclear Ruthenium(II)‐Bridged Complex: [{RuCl2(PPh3)}2{C6H2(CH2PPh2)4‐1,2,4,5‐P,P′,P′′,P′′′}] (1998) (23)
Construction of Supported Organometallics Using Cycloplatinated Arylamine Ligands (2002) (23)
Reactions of the homo- and heterodinuclear complexes M2(CO)6(N,N'-diisopropyl-1,4-diaza-1,3-butadiene) [M2=Fe2, FeRu, Ru2] with (N,N-diethylamino)-1-propyne (1989) (23)
Synthesis of Arylzinc Thiolates Containing Perfluoroalkyl Chains : Model Catalyst Precursors for the Enantioselective Zinc-Mediated 1,2-Addition of Dialkylzincs to Aldehydes in Fluorous Biphase Systems (1999) (22)
Quadridentate nitrogen donor ligands acting as bridging di-bidentates; X-ray crystal and molecular structure of [Ag2{µ-(R)(S)-1,2-[(2-C5H4N)-C(H)N]2-cyclohexane}2][O3SCF3]2 and the observation of 3J(107,109Ag-1H) in the 1H n.m.r. spectrum of the dinuclear [Ag2L2]2+ cation (1980) (22)
Coordination chemistry of sulfines I. Synthesis and characterization of the complexes Pt(PPh3)2(XYCSO) (X,Y = aryl, S-aryl, S-alkyl, Cl). Coordination via the C=S-p- bond (1979) (22)
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes.5. Syntheses, spectroscopic properties and reactivity of Ru2(CO)5(alkyl-DAB), a key intermediate in the Ru3(CO)12-alkyl-DAB reaction. Crystal and molecular structure of (1,4-diisopropyl-1,4-diaza-1,3-butadiene)pentacarbonyldiruthenium, Ru2 (1984) (22)
Selective intramolecular cleavage of the carbon-silicon bond by palladium salts (1994) (22)
Regio- and stereospecific nucleophilic additions to a metal substituted carbonium ion [PtI{MeC6H3(CH2NMe2)2-o,o'}]BF4. A unique reversible aryl-to-cyclohexadiene conversion at a Pt(II) center (1982) (22)
Ortho-bis(amino)arylnickel(II) halide complexes containing perfluoroalkyl chains as model catalyst precursors for use in fluorous biphase systems (1998) (22)
Electron-Poor Pentafluorophenyl-substituted PCP-Palladium Pincer Complexes (2005) (22)
The Hurtley reaction II. Novel complexes of disubstituted acetylenes with copper(I) benzoates having a reactive ortho C-Cl or C-Br bond. X-ray structural characterization of tetrakis(2-chlorobenzoato)bis(diethylacetylenedicarboxylate tetracopper(I) (1989) (22)
Organometallic polymers: an infinite organoplatinum chain in the solid state formed by (CCH⋯ClPt) hydrogen bonds (1996) (22)
Synthesis of Marasin and 9-Me-Marasin, (Nona- and Deca-6,8-diyne-3,4-dienol). (1988) (22)
The metallation of N,N-dimethylaminotoluene by palladium acetate. Evidence for a trinuclear species (1985) (22)
Alkene insertion reactions of nitrogen-coordinated acylpalladium(II) complexes. The crystal structure of the dicyclopentadiene insertion product [Pd(C10H12COMe)(bpy)]SO3CF3 (1992) (22)
η6-Coordination of a Ruthenium(II) Organometallic Fragment to the Arene Ring of N,C,N-Pincer Metal Complexes (2008) (22)
A Ruthenium(II) Complex Stabilized by a Highly Fluorinated PCP Pincer Ligand (2005) (22)
Stable tetranuclear 4-tolyl-copperlithium (“cuprate”) and -goldlithium (“aurate”) compounds (1977) (21)
Syntheses and NMR studies of five-co-ordinate rhodium(I) complexes with α-diimines (RNC(H)C(H)NR): [RhCl(CO)(η2-C2H4)(α-diimine)] and [RhCl(L)2(α-diimine)] (R = t−Bu, EtMe2C−; L = CO,PF3) (1981) (21)
The stereoselective synthesis of cis- and trans-b-lactams via α-amino ester enolates and 1-aza-4-hetero-1,3-butadiene systems. Molecular structure of EtOC(O)C(H)Net2)C(H)(NH)(-t-Bu)C(H)=N(t-Bu)ZnCl2: an unexpectedly isolated intermediate (1991) (21)
C-N Coupling of nitrogen nucleophiles with aryl and heteroaryl bromides using aminoarenethiolato-copper(I) (pre-)catalyst (2010) (21)
Influence of fluorine on aromatic interactions (1995) (21)
Reversible carbonylation of cationic palladium 2,6‐bis[(dimethylamino)methyl]pyridine complexes: The first X‐ray structure of a cationic aroyl‐palladium complex (1991) (21)
Pd catalysed intramolecular coupling between tertiary amines and allylic groups; synthesis of 3-hydro-1H-2-benzazepinium salts (1994) (21)
Field desorption mass spectrometry of a series of various metal carbonyl 1,4-diazabutadiene compounds (1981) (21)
Synthesis and structure of [2-(4,4-dimethyl-2-oxazoline)-5-methylphenyl] methylphenyltin bromide : A novel triorganotin halide having a configurationally stable chiral tin center (1991) (21)
Synthesis of novel terdentate N,C,N′-coordinated butyltin(IV) complexes and their redistribution reactions with SnCl4 (2006) (21)
Synthetic strategies towards new para-functionalised NCN-pincer palladium(II) and platinum(II) complexes (2002) (21)
Role of Cation-Anion Interactions in Ionic Complexes Containing [Pd{C6H3(CH2NMe2)2-2,6}(OH2)]+ and [{Pd(C6H3(CH2NMe2)2-2,6)}2(m-C1)]+ Cations (2004) (20)
The unexpected formation of a lithium-enolate from bis2-[(dimethylamino)methyl]phenyl copper lithium. X-ray structure of Li4[OC(CH2)C6H4CH2NMe2-2]4☆ (1985) (20)
Stable arylcopper compounds containing 2-(dimethylamino)methyl or 2-methoxymethyl groups at the aryl nucleus (1970) (20)
Pyrenoxy-Based NCN-Pincer Palladium(II) Molecular Tweezers: Synthesis, Properties in Solution and Catalysis (2003) (20)
A novel enantiopure proline-based organonickel(III) halide monocation with a pentadentate C, N2, O2-bonded bis(ortho-chelating) aryldiamine ligand☆ (1995) (20)
Synthesis of novel dinuclear formamidino and triazanido compounds {[2,6(Me2NCH2)2C6H3] p-tolNYNR)PtAgBr} (Y = Ch, N) containing a platinum-silver bond (1982) (20)
Alkene and Alkyne Reactivity Towards a Bisruthenium (II) µ2-Dinitrogen Complex Containing the 'Pincer' ligand 2,6-Bis[(dimethylamino)methyl]pyridine(NN'N). The X-ray Crystal Structures of [Ru(=C=CHPh)Cl2(NN'N)] and [Ru(=C=CHPh)(OTf)(NN'N)(PPh3)][OTf] (OTf =Trifluoromethane Sulfonate) (1999) (20)
THE REGIO- AND STEREOSPECIFIC SYNTHESIS OF DIARYLPROPENYLLITHIUM COMPOUNDS FROM DIMETHYLAMINO- AND DIMETHYLAMINOMETHYL-SUBSTITUTED DIARYLACETYLENES VIA TRANSMETALLATION REACTIONS INVOLVING DIARYLPROPENYLMAGNESIUM AND -TIN COMPOUNDS (1979) (20)
Metal-metal bonded compounds: VI. Rhodium-mercury bonded complexes [(Diene){RNC(Y)NR′}2RhHgCl]2 containing interchanging metal-metal bridging and chelating amidino groups (1976) (20)
Five-Coordinate Tungsten(VI) Phenylimido Alkylidene Complexes, and Isolated Precursors, Containing a Chelating Arylamine Ligand as Active ROMP Catalysts : Molecular Structure of W(C6H4CH2NMe2-2)(-CHSiMe3)(CH2SiMe3)(=NPh) (1993) (20)
Ring closing metathesis employing organometallic substrates and the templated synthesis of macrocycles (2006) (20)
Phosphorus coordination of di- and tri-azaphospholes in platinum(0) complexes: x-ray molecular structure of tris(triphenylphospine)-1,5-dimethyl-1,2,4,3-triazaphosphole platinum(0) [Pt(PPh3)3] (1983) (20)
Four-co-ordinate rhodium(I) complexes [{Rh(CO)2Cl}n(α-diimine)] (n = 1, 2) with σ,σ-N,N′ chelate or σ-N, σ-N′ bridge bonded RNC(R′)C(R″)NR ligands. Influence of the branching at Cα of R on the RhIα-diimine interaction (1981) (20)
Structural investigations of benzocyclopentadienylzinc compounds. Crystal structure of the bis(tetrahydrofuran) complex of difluorenylzinc (1989) (20)
Metathesis of olefin-substituted pyridines: the metalated NCN-pincer complex in a dual role as protecting group and scaffold. (2002) (20)
Non-Tethered Organometallic Phosphonate Inhibitors for Lipase Inhibition: Positioning of the Metal Center in the Active Site of Cutinase (2008) (20)
Transmetalation of Aryl Units from Gold(I) to Cobalt(III): A Clean Route to the Synthesis of Anion Cobaltoreceptors (2005) (20)
Mono-arylcobalt(II) compounds stabilized by bis ortho chelation (1986) (20)
Syntheses and characterization of dinuclear palladium and platinum complexes with a single unsupported bridging group. Crystal structure of [{C6H3(CH2NMe2)2-o,o′}Pd(µ-Cl)Pd{C6H3(CH2NMe2)2-o,o′}]BF4 (1987) (20)
Selective detection of SO2 at room temperature based on organoplatinum functionalized single-walled carbon nanotube field effect transistors (2009) (20)
The Hurtley Reaction I. Synthesis and characterization of copper(I) benzoates containing reactive ortho C-X (X = Cl, Br) bonds and their reactivity towards organocopper(I) compounds. Crystal structure of a thermally stable trinuclear hetero-copper(I) cluster, bis(benzoato)(mesityl)tricopper(I) (1989) (20)
An easy entry to novel early–late oligonuclear transition metal complexes containing π-conjugated systems (1999) (20)
Synthesis and specific intramolecular C–C coupling reactions of novel hexanuclear copper cluster complexes Ar4R2Cu6 (1974) (20)
Selectivity in reductive elimination and organohalide transfer from methyl(aryl) benzylpalladium(IV) complexes of bidentate nitrogen donor ligands, PdBrMe(Ar)(CH2Ph)(L2) (1997) (20)
Recyclable nanosize homogeneous catalysts (2003) (19)
Conjugated G0 metallo-dendrimers, functionalized with tridentate ‘pincer’-type ligands (2000) (19)
Flyover bridge formation via a reversible C-C coupling in reactions of diruthenium pyridine-2-carbaldimine complexes with alkynes (1989) (19)
Titanium σ-acetylides as building blocks for heterobimetallic transition metal complexes: synthesis and redox behaviour of π-conjugated organometallic systems (1999) (19)
Amine-thioether and amine-pyridine complexes of palladium(II) and the reactivity of the methyl complexes towards CO and allenes (1996) (19)
The first lithium phenolate with a trinuclear structure and the tetranuclear product of 1 : 1 addition of lithium iodide; X-ray structures of [LiOAr]3 and [Li2(OAr)I]2[OAr = OC6H2(CH2NMe2)2-2,6-Me-4] (1992) (19)
Reactivity of 1-aza-4-oxo-1,3-butadienes (a-iminoketones) towards triorganoaluminum reagents I. X-ray crystal structures of [(AlMe3)2{s,s-N,O-(MeN=C(Ph)C(Ph)=O}],with a N,O-bridge bonded a-iminoketone, and of Me2Al(t-Bu)N= CHC(Me)2OAlMe3, a carbonyl alkylated product which is O-coordinated to AlMe3 (1986) (19)
Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the N-Thienylidene-L/D-methionine Methyl Ester Ligand (1996) (19)
Covalent anchoring of a racemization catalyst to CALB-beads: towards dual immobilization of DKR catalysts (2011) (19)
Synthesis and characterization of platinum(II)-terminated dendritic carbosilanes: X-ray crystal structure of the model species [PtCl(C6H3{CH2NMe2}-2-SiMe3-5)(PPh3)] (2001) (19)
Synthesis of cyclometallated naphthylpalladium complexes via transmetallation reactions of naphthylmercury with palladium species. Crystal structure determination of [{Pd(mxn)(O2CMe)}2] (1988) (19)
A comparative study of thermal- and radiation-induced single electron transfer in reactions of 1,4-diaza-1,3-butadienes with dialkylzinc compounds (1994) (19)
A bimetallic tantalum-zinc complex with an ancillary aryldiamine ligand as precursor for a reactive alkylidyne species : Alkylidyne-mediated C-H activation and a palladium-mediated alkylidyne functionalizing (1993) (19)
Synthesis of C60-attached SCS pincer palladium(II) complexes (2003) (19)
Synthesis, Crystal Structure, and Redox and Photophysical Properties of Novel Bisphosphinoaryl RuII-Terpyridine Complexes (2004) (19)
Mononuclear tungsten(VI) phenylimido phenoxide and alkoxide complexes with intramolecular amine coordination : molecular structure of WCl3(=NPh)(OC6H2(CH2NMe2)2-2,6-Me-4] (1993) (18)
Configurational Preferences and Alkylidene-Centered Reactivity of Tantalum Alkoxide Complexes Containing an Aryldiamine Spectator Ligand? (1994) (18)
ASYMMETRIC SYNTHESIS OF BETA -LACTAMS VIA THE ZINC-MEDIATED GLYCINE ESTER ENOLATE-IMINE CONDENSATION REACTION USING ALPHA -AMINO ESTERS AS THE CHIRAL AUXILIARY (1995) (18)
Proton and INEPT nitrogen-15 and silver-109 NMR studies of the structural and dynamic features in solution of some silver(I) and copper(I) complexes with polydentate N4-donor ligands, (RS)-1,2-(6-R-py-2-CH:N)2Cy and 1,2-(6-R-py-2-CH:N)2ethane (Cy = cyclohexane, R = H or Me) (1984) (18)
A hydrogen atom in an organoplatinum-amine system: tautomers having either a bridging hydrogen with platinum(II) or a hydride on platinum(IV). The X-ray crystal structure at 100 K of [Pt{C10H6(NMe2)-8-C,N}{C10H6(NHMe2)-8-C}(Br)] (1990) (18)
Solid state structure of [Au2Li2(C6H4CH2NMe2-2)4]. A model for the reactive structure of organocuprates (1984) (18)
Design and synthesis of tris[bis(benzylammonium)aryl]phosphines with bulky meta-substituents (2003) (18)
Dualistic Reactivity of Lithium and Zinc Dienolates with Imines: Effects of Counter Ion, Termperature and Substituents on a- and g-Coupling (1994) (18)
Towards Organometallic Polymers with High Directionality Containing Bis-ortho-Chelating Ligands (2001) (18)
Coordination Behaviour of the New Multidentate Ligand 3,5‐Bis(dimethylaminomethyl)pyridine with Palladium(II) and Platinum(II) Metal Centres (1998) (18)
Bis(ortho)-Chelated Bis(phosphanyl)aryl Ruthenium(II) Complexes Containing an η1-P-Monodentate or μ-Bridging η1-P,η1-P′ Bonded R−PCHP Arene Ligand, 1-R-3,5-(CH2PPh2)2C6H3 [R = H, Br, or, Si(n-CH2CH2C8F17)3] — Cyclometalation Reaction Intermediates and Potential Catalysts for Use in Fluorinated Bipha (2001) (18)
Solid-state structure of tetrakis[2-(N,N-dimethylaminomethyl)phenyl]-dilithium-digold cluster ([Au2Li2(C6H4CH2NMe2-2)4]): a model for the reactive structure of organocuprates (1984) (18)
Self-assembly of para-OH functionalized ECE-metalated pincer complexes (2008) (18)
Fluxionality and bonding in formamidine and formamidinate complexes of Pt(II) and Pd(II) containing the 2,6-bis[(dimethylamino)methyl]phenyl ligand; A proton nuclear magnetic resonance study with X-ray crystal structure of [Pt{C6H3(CH2NMe2)2-2,6}{p-MeC6H4N=CHN(H)C6H4Me-p}][CF3SO3] [Pt{C6H3(CH2NMe2)2 (1986) (18)
Evidence for hexacoordinate tin centers in trioganotin halides containing two 8-(dimethylamino)-1-naphthyl ligands (1992) (18)
Synthesis and structure of a bis-ortho-chelated aryllithium compound: 2,3,5,6-tetrakis[(dimethylamino)methyl]phenyllithium dimer (1988) (18)
Reactivity of cyclopalladated compounds. 13. Organopalladium compounds with a chiral palladated carbon atom. Facile isolation of optically active cyclopalladated complexes containing the (S)- or (R)-[2-Me2NC6H4CH(SiMe3)] monoanion. Molecular structure of [2-[1-(S)-(dimethylamino)ethyl]phenyl][2-(dim (1987) (18)
Hexakis(PCP-platinum and -ruthenium) complexes by the transcyclometalation reaction and their use in catalysis (2002) (18)
(Tetraazadiene)platinum complexes. X-ray crystal and molecular structure of thetriethylphosphine nucleophilic addition product [Pt{1,4-(4-NO2C6H4)2N4} {CHC(PEt3)H(CH2CH=CHCH2CH2}(PEt3)]; a novel five-coordinate blue mononuclear platinum species (1982) (17)
Anion-controlled oligomerization of carbon monoxide and norbornene on a palladium(II) centre (1993) (17)
Increasing the Lipophilic Character of Tetraphenylborate Anions through Silyl Substituents (2001) (17)
C,N-2-((Dimethylamino)methyl)phenylplatinum Complexes Functionalized with C60 as Macromolecular Building Blocks (2001) (17)
FIVE-COORDINATE PLATINUM-OLEFIN COMPLEXES. SYNTHESIS AND HIGH-RESOLUTION HYDROGEN-(250, 360 MHZ) AND CARBON-13 (20 MHZ) NMR STUDY OF THE INTERLIGAND CHIRAL RECOGNITION IN THE FORMATION OF DIASTEREOMERIC (PTCL2(η2-OLEFIN)(6-R′-PY-2-CH= (1981) (17)
Haloalkane C-X Bond Activation by a Ruthenium(II) Complex: X-ray Characterization of a Ruthenium(III) Intermediate Species in the Atom Transfer Radical Polymerization of Methyl Methacrylate (2000) (17)
Organopalladium-Functionalized Dendrimers: Insertion of Palladium(0) into Peripheral Carbon−Iodine Bonds of Carbosilane Dendrimers Derived from Polyols. Crystal Structure of Si{(CH2)3O2CC6H4I-4}4 (1997) (17)
Organomolybdenum(VI) and Lithium Organomolybdate(VI) and -(V) Complexes with C,N-Chelating Aminoaryl Ligands (1999) (17)
A proposal for positive cooperation in anion-cation binding in yttrium and lutetium complexes based on o-amino-substituted phenolate ligands. On the way to coordination polymers by self-assembly. Molecular structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR) (1996) (17)
Synthesis of [Ru2(CO)5{1,2-bis(m-alkylamido)-1,2-bis(2-pyridyl)ethane}] and Ru2(CO)4{pyridine-2-carbaldehyde-N-alkylimine}2] and the molecular structure of bis(pyridine-2-carbaldehyde-N-isopropylimine)tetracarbonyldiruthenium UnprecedentedCO-induced carbon-carbon bond formation between two pyridine- (1987) (17)
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) reaction sequence: Reversible CO addition to a trinuclear species without rupture of a metal-metal bond. Molecular structure of [1,4-dicyclohexyl-1,4-diaza-1,3-butadiene]nonacarbonyltriruthenium, Ru3(CO)9(c-Hx-DAB). A unique 50e trinuclear compound (1985) (17)
Advances in the Synthesis of Multimetallic Systems: Hydroxyl Group Protection in (Aryldiamine)platinum Species (1997) (17)
Intramolecular rearrangements of sulfines coordinated to platinum. A unique equilibrium between oxidative-addition stereoisomers cis-(E)- and cis-(Z)-bis(triphenyl-phosphine) (methylthio)(arylsulfine)platinum(II) and the two stereoisomers of the reductive coupling product. Bis(triphenylphosphine) [a (1981) (17)
Platinum-pincer introduction using active ester chemistry (2002) (17)
Insertion of Isocyanides into the Palladium-Carbon Bond of Cyclopalladated Complexes (1994) (17)
Synthesis and Characterization of O,N-Chelated Vanadium (IV) Oxo Phenolate Complexes : the Electronic Effect of meta- and para Substituents on the Vanadium Center (1999) (17)
P′CP′-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines (2009) (17)
Synthesis, reactivity and crystal structure of [1,4-bis(4-tolyl)tetraazadiene] (h5-cyclopentadienyl)nickel (1982) (17)
Induction of Chirotopicity in the Self-Assembly Process of Heterocuprates: Structual and Stereochemical Aspects of Neutral Culi2BrAryl2 Aggregates (2002) (16)
Heterotrinuclear Complexes of the Platinum Group Metals with 2,2′-Biimidazole as a Bridging Ligand (2003) (16)
An octa-cationic core-shell dendrimer as a molecular template for the assembly of anionic fullerene derivatives (2005) (16)
Binuclear metal carbonyl DAB complexes 9. Synthesis and X-ray structure of (m-acetylene)[s-N, s-N', h2-C=N, h2-C=N'-glyoxalbis(isopropylimine)] tetracarbonyl diruthenium. First example of the 8e donating DAB ligand (DAB= 1,4-diazabutadiene) (1981) (16)
Influence of bulky substituents on the regioselective group-transfer reactions of diorganozinc compounds with N,N'-bis(2,6-di-isopropylphenyl)-1,4-diaza-1,3-butadiene (1994) (16)
Reactivity of [2,6-Bis((dimethylamino)methyl)phenyl]gold(I), an Unusual Intermolecularly Stabilized Bis(amino)aryl−Gold(I) Dimer, toward Alkyl Halides. X-ray Crystal Structures of Its Iodomethane and Methylene Diiodide Adducts† (2000) (16)
The syntheses of β-lactams from zinc enolates of N,N-disubstituted α-aminoacid esters and imines: Substituent and solvent effects (1989) (16)
Novel aryl-bridged tetranuclear gold-lithium and gold-copper cluster compounds R4Au2M2 (M = Li or Cu) (1974) (16)
Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)2-C,P}{(pz)3BH-N,N'} and Pd{C6H4C5H4N-C2,N'}{(pz)3BH-N,N'} (1998) (16)
GROUP IB ORGANOMETALLIC CHEMISTRY. 21. SELECTIVE FORMATION OF BIARYLS VIA INTERACTION OF POLYNUCLEAR ARYLCOPPER COMPOUNDS WITH COPPER(I) TRIFLUOROMETHANESULFONATE (COPPER(I) TRIFLATE) (1977) (16)
Group IB organometallic Chemistry. XXXV. Crystal and molecular structure of [Cu4{4-MeC6H4)MeC=C(C6H4NMe2-2)}2(C6H4NMe2-2)2], a tetranuclear organo-copper compound containing bridging alkenyl and aryl groups (1982) (16)
Group IB organometallic chemistry : XIX. Synthesis and characterization of mixed-organocopper cluster compounds R4R′2Cu6 containing aryl and acetylide ligands☆ (1977) (16)
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru2(CO)5(R-DAB) towards molecular hydrogen. Molecular structure of H2Ru4(CO)8(R-DAB)2, containing a unique linear chain of four ruthenium atoms (1985) (16)
New Coordinatively Unsaturated Lutetium Mono- and Bis(alkyl) Complexes with a Bis(ortho)-Chelating Aryldiamine Ligand—Crystal Structures of [LuCl2{2,6-(Me2NCH2)2C6H3}(μ-Cl)(μ-Li(thf)2)]2 and [Lu(μ-Cl){2,6-(Me2NCH2)2C6H3}(CH2SiMe3)]2 (1995) (16)
Synthesis and Characterization of 1-Iminopropan-2-one and 2-Iminobutan-3-one Compounds, RC(O)C(NR')R (1978) (16)
Monomeric bis(η2-alkyne) complexes of (η1-mesityl)copper(I) and (η1-mesityl)silver(I) obtained from a bis(alkynyl)titanocene; X-ray structure of [(η5-C5H4SiMe3)2Ti(CCSiMe3)2]Cu(η1-Mes)(Mes = C6H2Me3-2,4,6) (1995) (15)
Synthesis of a key reactive unit for use in the divergent or convergent synthesis of carbosilane dendrimers (1998) (15)
UNIQUE STABLE ORGANOMETALLIC NICKEL(III) COMPLEXES; SYNTHESES AND THE MOLECULAR STRUCTURE OF (NI(C6H3(CH2NME2)2-2,6)I2) (1983) (15)
Dendritic Host Molecules with a Polycationic Core and an Outer Shell of Dodecyl Groups (2007) (15)
Dendritic Polymer Applications: Catalysts (2001) (15)
Periphery-Palladated Carbosilane Dendrimers: Synthesis and Reactivity of Organopalladium(II) and -(IV) Dendritic Complexes. Crystal Structure of (PdMe(C6H4(OCH2Ph)-4)(bpy)) (bpy ) 2,2'-Bipyridine) (1999) (15)
Kupfer(II)‐vermittelte oxidative Kupplung eines Bis(dimethylaminomethyl)arylruthenium‐komplexes zu [(terpy)RuIII(pincer‐pincer)‐RuIII(terpy)] (CuCl2)4 (1994) (15)
Dinuclear formamidino and triazenido compounds [{2,6-(Me2NCH2)2C6H3} (p-tolylNYNR)PtHgBrCl] (Y CH, N) containing a platinum-to-mercury donor bond (1982) (15)
A new mixed alkoxo aryloxo palladium complex with a bidentate nitrogen donor system (1993) (15)
Binuclear metal carbonyl dab complexes : VIII. The syntheses of Os2(CO)6(DAB) complexes (DAB = 1,4-diazabutadiene). Spectroscopic characterization and comparison with analogous iron and ruthenium complexes (1981) (15)
SYNTHESIS OF METHYLTRIOXORHENIUM(VII) ARYLAMINE COMPLEXES AND MONO-AND BIS(ORTHO)-CHELATED ARYLAMINORHENIUM(VII) TRIOXIDES (1997) (15)
The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes (2011) (15)
Ruthenium(II) arene complexes with oligocationic triarylphosphine ligands: Synthesis, DNA interactions and in vitro properties (2011) (15)
Influence of steric factors on the coordination mode (h1 or h2) of phosphaalkenes to zerovalent Pt0L2 centres. X-ray structure of bis(triphenylphosphine){2,6-dimethyl phenyl)-9-fluorenylidenephosphine}platinum(0)-toluene (1986) (15)
The crystal structure of a hexanuclear mixed thiophenolato-alkynyl copper(I) complex: [Cu3{SC6H4(CH2NMe2)-2}2(CCBut)]2: a model for electron deficient organocopper(I) complexes with cuprate reactivity (1989) (15)
Structures and Reactivities of Organocopper Compounds (2002) (15)
Synthesis of novel trialkyl(trichlorostannyl)platinum(IV) complexes through SnCl2 insertion into the Pt-Cl bond (2003) (15)
Diamino-ligated platinum(II) and platinum(IV) phenoxide complexes; syntheses and crystal structures (1997) (14)
Complexes of N,N′-substituted formamidines I. Compounds [M(RNC(H)NR′)]n (M = CuI, AgI; R = p-TOLYL; R′ = ALKYL; n = 2,4); and study of the dimerdimer and dimertetramer equilibria in solution (1979) (14)
Direct alkoxylation of organopalladium compounds based on a new type of C-O coupling mediated by molybdenum peroxides. (1991) (14)
Study of the stereochemistry of silver(I) bis(pyridine-2-carbaldehyde-imine) triflate complexes in solution: application of inept 109Ag and 1H-{109Ag}NMR (1982) (14)
Oxidation state of platinum in oxidative-addition reactions and eta1-iodine products from dihalogen reactions with organoplatinum(II) complexes, as inferred from monochromatic X-ray photoelectron spectroscopy (1992) (14)
Introduction to the Ennobling a Base Metal: Presenting Copper in Organometallic Chemistry Issue (2012) (14)
Σ2-N′, μ2-N, η2-C:N COORDINATION AS THE ACTIVATING STEP IN THE CARBON-CARBON BOND FORMATION BETWEEN TWO α-DIIMINES IN DINUCLEAR RUTHENIUM CARBONYL COMPLEXES. X-RAY STRUCTURE OF TETRACARBONYLBIS(GLYOXALBIS(ISOPROPYLIMINE))DIRUTHENIUM (1981) (14)
Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(μ-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy = 2,2'-bipyridine) (2002) (14)
Synthesis of a bis-(Cyclopentadienyl)lanthanum aryl complex with a pseudofacially, bis(ortho)-chelating aryldiamine ligand. X-ray structure of (h5-C5H5)2La(C6H3{CH2NMe2}2-2,6) (1996) (14)
Rh(I) coordination chemistry of hexacationic Dendriphos ligands and their application in hydroformylation catalysis (2010) (14)
Coordination Chemistry in Water of a Free and a Lipase-Embedded Cationic NCN-Pincer Platinum Center with Neutral and Ionic Triarylphosphines (2012) (14)
C-C and C-N couplings and alkyl C-H activation in reactions of (s,s-(N,N')-N,N'-diisopropyl-1,4-diaza-1,3-butadiene)-(m2, h2-dimethyl acetylenedicarboxylate)diiron pentacarbonyl (1989) (14)
A Novel Phenol for Use in Convergent and Divergent Dendrimer Synthesis: Access to Core Functionalisable Trifurcate Carbosilane Dendrimers—The X‐ray Crystal Structure of [1,3,5‐Tris{4‐(triallylsilyl)phenylester}benzene] (1999) (14)
A novel synthetic route to tantalum-zinc neophylidyne complexes stabilized by ortho-chelating arylamine ligands : The X-ray structure of [TaCl2(m-C6H4CH2NMe2-2)(m-CCMe2Ph)ZnCl(THF)] (1997) (14)
Alkylidene-centered rearrangement of a tantalum alkylidene alkoxide species with the N,C,N,-bis-ortho-chelated 1,2,6-trisubstituted aryldiamine ligand [C6H3(CH2NMe2)2-2,6]- to a product with a C,N-mono-ortho-chelated 1,2,4-trisubstituted aryldiamine ligand. X-ray molecular structure of [TaCl(=Ch-t-B (1997) (14)
Cooperative binding of Na+ and Cl- in Na{M[OC6H2(CH2NMe2)2-2,6-Me-4]3Cl}: Synthesis (M = Lu, Y) and X-Ray Structure (M = Lu) of New Heterometallic Complexes of Lutetium and Yttrium Containing bis(ortho)-Amino Phenolate Ligands (1994) (14)
Cavities for Binding Two Metal Atoms: A Novel Pentanuclear Copper(I) Complex with an Anionic, Pentadentate Aryl Ligand with Two ortho-Chelating Diamine Substituents† (1993) (14)
Activation of an aliphatic C-H bond at room temperature. Conversion on a cluster of a stable s-bonded alkyl group to a m2-alkylidene ligand. Synthesis and crystal structure determination of HOs3(6-CH2C5H3N-2-C(H)=N-i-Pr)(CO)9 andH2Os3(6-CH-C5H3N-2-C(H)=N-i-Pr)(CO)8 (1988) (14)
Characterization of soluble [RuCl2P2]2 (P = PPh3), a species which has been postulated to be present in solutions of RuCl2P3; its synthesis from various Ru compounds via a novel catalytic process involving pyridylketones (1978) (14)
Diastereopure Cationic NCN-Pincer Palladium Complexes with Square Planar η4-N,C,N,O Coordination (2006) (14)
Group IB Organometallic Chemistry XXXI. Synthesis and characterization of tetranuclear Me2N- and Me2NCH2-substituted diarylpropenylcopper-copper anion compounds (Vi2Cu4X2) containing bridging propenyl ligands. Isolation of a thermally stable mixed diarylpropenyl/arylcopper compound (Vi2Cu4Ar2) (1979) (14)
An unexpected 1,2-alkyl shift within a chelate bonded organoaluminium-enamine (1993) (13)
Synthesis and structural characterization of the homoleptic magnesium bis zinc ate complex Mg(thf) 6[Zn(CH2Ph)3]2 (1997) (13)
A new homobimetallic arenediyl diplatinum(II) unit as building block for macromolecular synthesis. X-ray crystal structure of [C6H2{CH2NMe2}2-1,5-{PtCl(PPh3)}2-2,4] (2001) (13)
CRYSTAL STRUCTURE OF THE NEUTRAL DIARYLCUPRATE CU2LI2(C6H4CH2NME2-2)4: THE ASYMMETRIC BONDING CONFIGURATION OF ORGANO GROUPS BRIDGING COPPER AND LITHIUM (1985) (13)
C–H activation of a MeN grouping in one of the CH2NMe2 ortho substituents of a NCN ‘pincer’ ligand in tungsten chemistry: X-ray structure of [WCl2(NPh)(C6H3{CH2NMeCH2}-2-{CH2NMe2}-6)] (1999) (13)
Oxidation of Heteroleptic Diarylpalladium Compounds with tert-Butyl Hydroperoxide. Substituent Effects in Aromatic Oxidation Reactions (1996) (13)
O,N-Chelated boron aminophenolate complexes. Crystal structure of BPh2(OC6H4(CH2NMe2)-2) (2000) (13)
Intramolecular CH activation and oxidative addition reactions of iridium complexes containing arylamines with bulky substituents on n itrogen; X-ray structures of [IrI(C6H4CH2NEt2-2-C,C)] and [IrIII(C6H4CH2Net(CHMe)-2-C,N,C′)I(cod)] (cod = cycloocta-1,-5-diene) (1996) (13)
Synthesis of some dinuclear Fe and Ru complexes containing an 8e donating α-diimine ligand and μ2-bridging alkyne; crystal structure of (σ,σ-N,N′,η2,η2-CN,CN′-1,4-diisopropyl-1,4-diaza-1,3-butadiene)(μ2-methyl propynoate) tetracarbonyl di-iron (1989) (13)
Ionic core–shell dendrimers with a polycationic core: structural aspects and host–guest binding properties (2007) (13)
Crystal structure of zinc[bis[3-(dimethylamino)propyl-C,N]tin]bis(dibenzoylmethanato)-(SnZn). The first example of a dialkyltin(II) compound stabilized by SnZn coordination (1990) (13)
Group IB organometallic Chemistry XXIII. Reaction of Ar4Cu2Li2 with RhI complexes; Synthesis of 2-[(dimethylamino)methyl] phenylrhodium dicarbon monoxide and electron-transfer induced selective formation of diarylketones ArC(O)Ar (1978) (13)
Reactivity of 1-aza-4-oxo-1,3-butadienes (a-iminoketones) towards triorganoaluminum reagents II. Syntheses of triorganoaluminum-a-iminoketone coordination complexes diorganoaluminum(a-imino)alkoxides and diorganoaluminum(a-imino)enolates and study of their dynamic behaviour in solution (1H and 13C N (1987) (13)
Structure of m-[1,2-bis(tert-butylamino-1:2kN)-1,2-di(2-pyridyl-kN)ethane]-bis (ethylzinc) (1987) (13)
Synthesis and characterization of two isomers of Os3(CO)10(C5H4N-2-C(H)NR) and the conversion to ortho-metallated HOs3(C5H3N-2-C(H)NR)(CO)9. Part III. X-ray Structure of HOs3(C5H3N-2-C(H)Ni-Pr)(CO)9 (1988) (13)
Molybdenum(VI) Bisimidoaryl Phenoxide and Alkoxide Complexes: Molecular Structures of [Mo(NAr)2(OCMe2‐2‐py)(CH2SiMe3)] and [{Mo(NAr)2Me(OMe)}2] (1999) (13)
X-ray crystal structure of the hexameric lithium enolate of ethyl N,N-diethylglycinate (1988) (13)
Highly selective hydrocarboxylation of styrene with oxalic acid or water using palladium ortho-amino arenethiolates with intramolecular coordinating nitrogen Lewis bases (1998) (13)
Supramolecular Dendriphores: Anionic Organometallic Phosphors Embedded in Polycationic Dendritic Species (2009) (13)
{2,6-Bis[(dimethylamino-κN)methyl]phenyl-κC}iodopalladium(II) bis(diiodine) (2002) (13)
Reactivity of a binuclear Ru(II) N2-bridged complex towards phosphines: facile access to novel mono and binuclear phosphorous derivatives. X-ray structural characterization of two unusual binuclear complexes containing ‘pincer’ ligands: [{RuCl2(η3-NN′N)}2(μ-η2-P2)] (NN′N=2,6-bis[(dimethylamino)methy (1999) (12)
A PCP‐Pincer RuII–Terpyridine Building Block as a Potential “Antenna Unit” for Intramolecular Sensitization (2007) (12)
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru2(CO)6(R-DAB) towards hetero-allenes L(L = carbodiimide, sulphine), resulting in CC bond formation. X-ray molecular structure of Ru2(CO)5 (t=BuNCHC(H)(N-t-Bu)C(N-p-Tol)N-p-Tol) and of Ru2(CO)5(i-PrNCHC(H)(N-i-Pr)C(S)C12H8) (1985) (12)
(R)-2-phenylglycine as a chiral auxiliary in the asymmetric synthesis of 2-azetidinones (1993) (12)
New ring-opening metathesis polymerization catalyst based on a five-coordinate tungsten(VI) alkylidene complex containing an ortho-chelating arylamine ligand; X-ray structure of [W{C6H4(CH2NMe2)-2}(NPh)(CHSiMe3)(CH2SiMe3)] (1992) (12)
Group IB Organometallic Chemistry, XIV. Intramolecular ring-closure reactions of novel arylcopper compounds RCuI2. Synthesis of 7,8-dihydrodibenzo[f,h] [1,4]diox-ecin and 7,8-dihydrobenzo-6,9-dimethyl[f,h][1,4]diazecin (1976) (12)
Chemistry of diamino-ligated methylpalladium(II) alkoxides and aryloxides (Part II): methoxide formation and carbonylation reactions (1996) (12)
Conversion of 48e Os3(CO)10(R-DAB(4e)) via 50e Os3(CO)10(R-DAB(6e)) to 50e Os3(CO)9(R-DAB(8e)) (R-DAB:RN:C(H)C(H):NR). X-ray structure of Os3(CO)9(i-Pr-DAB(8e)), with two elongated Os-Os bonds (1988) (12)
Ferrocene-bridged Pd-NCN-pincer complexes (2003) (12)
Novel five-co-ordinate diorganorhodium compounds. X-ray structure of bis-ortho-chelated [RhIII(Me)I{C6H3(CH2NMe2)2-2,6}] (1989) (12)
Mono- and Heterodimetallic FeII and RuII Complexes Based on a Novel Heteroditopic 4′-{Bis(phosphanyl)aryl}-2,2′:6′,2″-terpyridine Ligand (2007) (12)
α-Diimines as monodentate or bridging ligands, synthesis and characterization of Palladium(II) and Rhodium(I) di(t-butyl)diimine complexes (1977) (12)
Functionalized Homoleptic cis- and trans-C,N-ortho-Chelated Aminoaryl Platinum(II) Complexes (2005) (12)
Reactions of sulfurdiimines and sulfinylanilines with [AlMe3]2 (1981) (12)
Interaction of arylmetal compounds of group 1B with copper(I) and silver(I) trifluoromethanesulphonate; a novel biaryl synthesis and a route to hexanuclear aryl–CuAg, –AgAu, and –CuAu clusters (1977) (11)
Condensation reactions of α-amino-zincenamines with aldehydes : application to indolizines (1992) (11)
Structure of {2,6‐bis[(dimethylamino)methyl]phenyl}dichloroiron(III), [Fe(C12H19N2)Cl2] (1985) (11)
A novel aryllithium · lithium bromide complex containing an anionic pentadentate organylpolyamine system enfolding two lithium centres (1993) (11)
Selective synthesis of monoorganotin trihalides: the direct reaction of allylic halides with tin(II) halides catalyzed by platinum and palladium complexes (2003) (11)
Trapping of three-center Ir-Sn-X intermediates in the reaction of IrI(C6H4(CH2NMe2))-2(COD) with (organo)tin(IV) halides. X-ray structure of [2-(Me2NCH2)C6H4](COD)Ir(Br)SnMe2Br (1988) (11)
Synthesis of Arylplatinum(II) Complexes with Chiral Monoanionic Aryldiamine ligands. The X-ray Crystal Structure of)[(1R)2,6bis{1(dimethylamino)propyl}phenyl]chloroplatinum, (1998) (11)
Binuclear metal carbonyl R-DAB complexes. Part XIII. Reduction of coordinated 1,4-diaza-1,3-butadiene to dianionic 1,2-diaminoethane by [HFe(CO)4]−. Molecular structure of [(μ-H)FeMn(CO)6{μ,μ′-N(p-Tol)CH2CH2N(p-Tol)}], a pseudo-symmetrical hetero-dinuclear species (1985) (11)
Modern Organometallic Multidentate Ligand Design Strategies: The Birth of the Privileged “Pincer” Ligand Platform (2015) (11)
Copper‐Mediated Cross‐Coupling Reactions. Editors: Gwilherm Evano and Nicolas Blanchard (2014) (11)
Reactivity of mixed cyclometallated palladium compounds containing the [2-Me2NC6H4C(H)SiMe3] monoanion. Transmetallation reactions and formation of a novel m-alkylidene compound (X-ray) (di-m-chloro)bis{m-C,s-N-[2-(dimethylamino) benzylidene](m-chloro)(diethyl sulfide)dipalladium(II)} (1986) (11)
The Presence of [Ar2Cu]- and [(RC⋮C)2Cu]- Homocuprate Moieties in the Neutral Mixed Cuprate [Cu2Li2(C⋮CR)2Ar2] (Ar = C6H4{CH2N(Me)CH2CH2NMe2}-2; R = C6H4Me-4 or C6H4SiMe3-4) (2003) (11)
Intramolecular In-N coordination. Synthesis and NMR study of four-coordinate {2-Me2NCH(Z)C6H4}Me2In and five-coordinate [2-Me2NCH(Z)C6H4]2InCl (Z = H or (S)-CH3 (1982) (11)
The twinned structure of the μ-isopropoxidodiisopropoxido(p-tolylimido)vanadium(V) dimer, twin refinement against CCD area-detector data (1999) (11)
Reactivity of cyclopalladated compounds. 19. Regioselective formation of .eta.3-allylic ligands via the reaction of alkynes with [cyclic] [{Pd(CH(SiMe3)C6H4NMe2-2)(.mu.-Cl)}2] (1989) (11)
Organometallic Zwitterions: Arylpalladium(II) (Pincer) Complexes with a Tethered Sulfato Group as para-Substituent (2005) (11)
Metal—metal bonded compounds : IV. Stabilization of metal—metal bonding by bridging asymmetric formamidino ligands in complexes [Ph3P)2(CO)IrM(RNC(H)NR′)Cl] (M Cu, Ag; R alkyl; R′ p-tolyl) (1979) (11)
Fast water exchange on a Pt(II) center: variable temperature and pressure17O NMR study at 14.1 tesla of the ionic arylplatinum species [PtC6H3(CH2NMe2)2-2,6 (OH2)]+ (OSO2CF3)− (1998) (11)
HYDROGEN BONDING AND CONFORMATIONAL ANALYSIS OF CHELATE-STABILIZED ALKOXOPALLADIUM(II) COMPLEXES DERIVED FROM AMINO ALCOHOL LIGANDS (1997) (11)
Oxime-substituted NCN-pincer palladium and platinum halide polymers through non-covalent hydrogen bonding (NCN = [C6H2(CH2NMe2)2-2,6]−) (2008) (11)
Application of a base-induced [1,2]-rearrangement to synthesize thiophosphonate bidentate S(sp2)–N monoanionic ligand: Characterization of its silver and palladium complexes (2009) (11)
Selective coupling of an α-diimine ligand and CO and methyl propynoate molecules to give Fe2(CO)n{(R)N=C(H)C(H)N(R)C(O)C(H)=CC(O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with X-ray crystal structures (n=5, R=i-Pr; n=6, R=c-Hex) (1989) (11)
The first eight electron bonded t-Bu-DAB complex. C-C coupling of two t-Bu-DAB ligands on Mn. X-ray structure of Mn2(CO)6(t-Bu-IAE), hexacarbonylbis[1-tert-butyl- imino-2-ter-butyl-amino-ethane]dimanganese, containing a novel asymmetrically bridging, eight electron donating IAE ligand (1985) (10)
Reactions of dinuclear metal carbonyl .alpha.-diimine complexes with alkynes. Part 6. Reactions of (N,N'-diisopropyl-1,4-diaza-1,3-butadiene)ironruthenium hexacarbonyl with alkynes (1989) (10)
Stereoselective oxidative-addition reactions of dihalogens and copper(II) halides to square-planar organoplatinum(II) complexes containing hard N and C donor atoms. Molecular structures of [bc,de-bis(8-dimethylamino-1-naphthyl)]-af-diiodoplatinum(IV) and ab-dibromo[cf,de-bis(8-dimethylamino-1-naphth (1991) (10)
Self-Assembly of p-Nitro NCN-Pincer Palladium Complexes into Dimers through Electron Donor−Acceptor Interactions (2003) (10)
Synthesis and spectroscopic properties of CpRuCl(R-DAB(4e)) and CpRuCo(CO)3(R-DAB(6e)). Part XVII. X-ray structure determination of CpRuCo(CO)3(t-Bu-DAB(6e)) (1988) (10)
Synthesis of cyclometalated aryltantalum(V) complexes: Amine C-H activation via [sigma]-bond metathesis (1993) (10)
A recyclable nanosize aminoarenethiolato copper(I) catalyst for C–C coupling reactions (2004) (10)
Formation of octahedral iridium(III) dihydrides from the reaction of ortho-chelated aryliridium(I) compounds with dihydrogen (1988) (10)
Arylgold(I) and aryl(triphenylphosphine)gold(I) compounds (1974) (10)
Molybdenum (VI) Bis(imidoaryl) Complexes Containing the Bis (amonimethyl)aryl 'Pincer' Ligand (1999) (10)
Reactions of (N,N'-diisopropyl-1,4-diaza-1,3-butadiene)ironruthenium hexacarbonyl with alkynes, Organometallic (1989) (10)
Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru3(CO)8(R-DAB) toward diazomethane. Addition of a methylene fragment to a trinuclear species with concomitant rupture of a single Ru-Ru bond. Molecular structure of octacarbonyl(1,4-dineopentyl-1,4-diaza-1,3-butadiene)(m-me (1985) (10)
Ligand substitution reactions in new square-planar iridium, rhodium and platinum complexes containing a potentially terdentate C,N,N′ ligand system; crystal structure of [Ir{C6H4CH2N(Me)CH2CH2NMe2-2-C,N,N′}(cod)](cod = cycloocta-1,5-diene) (1994) (10)
MonodentateN coordination of 1aza4oxo1,3butadienes [R1NC(R2)C(R3)O] to platinum(II). X-ray structure of trans-[PtCl2(PEt3){σ-N-(t-BuNCHC(Me)O)}] (1986) (10)
Binuclear metal carbonyl R-DAB complexes. Conversion of coordinated 1,4-diaza-1,3-butadienes into 3-amino-1-azaallyl monoanions by interaction with [HFe(CO)4]-. Molecular structure of [FeMn(CO)6{(t-Bu)N=CH=CHN(H)(t-Bu)}], containing an h3-1-azaallyl moiety bonded to Fe (1984) (10)
Novel rhodate and iridate complexes containing C,N chelating arylamine ligand systems (1993) (10)
A stable trinuclear mixed (organic)(organo) copper cluster: synthesis and structure of bis(benzoato)(mesityl)tricopper(I) (1985) (10)
(2,2'-Bipyridyl-N,N')dibromopalladium(II) (1997) (10)
Stereochemical Aspects of Enantiopure and Racemic Organolithium Aggregates Li4Ar4 {Ar=C6H4[CH(Me)NMe2]-2} (2004) (10)
An nmr study of the interaction of α-diimines (rnchchnr) with cyclometallated palladium(ii) compounds [{2-me2nch(z)c6h4pdx}2] (z h or (s)-me; x cl, br) (1981) (10)
Monomeric and dendritic second generation Grubbs- and Hoveyda-Grubbs-type catalysts for olefin metathesis Metallodendrimers Special Issue (2014) (10)
Ruthenium-to-Platinum Interactions in η6,η1 NCN-Pincer Arene Heterobimetallic Complexes: An Experimental and Theoretical Study (2010) (10)
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts (2010) (10)
Cyclometallated Organolithium Compounds (1989) (10)
GROUP IB ORGANOMETALLIC CHEMISTRY. 20. THE ROLE OF MIXED ORGANOCOPPER CLUSTER R COMPOUNDS RNR′MCUN+M IN SELECTIVE CARBON-CARBON COUPLING REACTIONS OF 2- AND 4-(DIMETHYLAMINO)PHENYLCOPPER WITH COPPER ARYLACETYLIDES (1977) (10)
The structure of bis[(R,S)-N,N'-bis(5-methyl-2-thienylmethylene)-1,2-cyclohexanediamine]copper(I) trifluoromethanesulfonate, C36H44CuN4S4+.CF3SO3− (1985) (10)
(P-Bis(pentafluorophenyl) substituted) PCP-pincer Ru(II) complexes : A theoretical study of the molecular structure and electronic properties (2006) (10)
Complex-forming reactions of an arylcopper(I) cluster compound with organophosphines. An unexpected C(alkyl)–P bond cleavage in 1,2-bis(diphenylphosphino)ethane (1972) (9)
Oxidative addition reactions of bis-aryl cyclometallated platinum(II) compounds with mercury(II) carboxylates. X-Ray crystal and molecular structure of the binuclear platinum–mercury compound rac-a-(µ-acetato-O,O′)-b-(O-acetatomercurio)-cf,de-bis[2-(dimethylaminomethyl)-phenyl-N,C]platinum (1980) (9)
Synthesis and crystal structure of the new mixed metal mixed ligand cluster compound Zn4Ni2(C5H5)4(C5Me5)2 (1989) (9)
Transmetalation reactions with nitrogen-containing 'pincer' -class ligands on platinum(II) centers (2001) (9)
A thermally stable nickel(II) metalloformate and its platinum(II) analogue (1984) (9)
Atomic XAFS as a probe of electron transfer within organometallic complexes: Data analysis and theoretical calculations (2004) (9)
Facile High Yield Synthesis of 1-Methyl-2-p-Tolyl-Indole and Its 3-Iodo Derivative (1977) (9)
Synthesis of a tri(organoplatinum) complex via the double directed lithiation of a mono(organoplatinum) precursor (1996) (9)
Platinum Group Organometallics Based on 'Pincer' Ligands: Sensors, Switchs and Catalys (2001) (9)
Biferrocene NCN pincer metal-d8 complexes: Synthesis, reaction chemistry and cyclovoltammetric studies (2006) (9)
Self-assembling of bis-ortho chelated diaminobenzyl- (NC′N) and butyl-lithium units to give 2:2 mixed alkyllithium aggregates (NC′N)Li2Bu2Li2(NC′N) with a ladder structure (1997) (9)
Towards organometallic conducting polymers containing bis-cyclometallating bridging ligands (1994) (9)
Linear homobimetallic 4-thioacetyl-substituted NCN pincer palladium(II) and platinum(II) complexes with N-bidentate connecting units (NCN = [C6H2(CH2NMe2)2-2,6-R-4]-) (2008) (9)
Insertion of norbornene into aryl–palladium(II) bonds: mechanistic aspects of the subsequent C–H activation (1992) (9)
Isolation and crystal structure (130 K) of the first example of an η1-O coordinated sulphine-metal complex: SnMe2Cl2[η1-O-{Me(Ph)NC(Ph)SO}] (1985) (9)
Thiol end-capped one-dimensional platinum and palladium complexes (2006) (9)
A novel olefin bridged dinuclear arylpalladium compound. X-ray crystal structure of NMe2CH2C6H4Pd-m-{C(CF3)=C(CF3)=C(CF3)=C(CF3)}PdCH(SiMe3)-C6H4NMe2 (1984) (9)
Intramolecular dynamics of 3c2e bonded aryl groups in polynuclear aryl-copper, -silver and -gold derivatives (1979) (9)
σ,σ′-N,N′ bridging and σ,σ-N,N chelating α diimines. Molecular geometries of [PtCl2PBu3]2(t-BuNCHCHNBu-t) and PtCl2(styrene)(t-BuNCHCHNBu-t) (1979) (9)
CONVERSION OF ARYL AZIDES ON NICKEL CENTERS INTO TETRAAZADIENE-NICKEL COMPLEXES (NI0(AR2N4)2), (CPNII(AR2N4)), AND ((RNC)2NI0(AR2N4)). CRYSTAL STRUCTURE OF (NI0(1,4-(3,5-ME2C6H3)2N4)2) (1980) (9)
Structure of dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II) dichloromethane solvate (1987) (8)
Copper(I) and silver(I) ions in unusual poly donor-atom environments; X-ray crystal and molecular structures of [M{(R)(S)-1,2-(5-Me-thiophene-2-CHz.dbnd;N)2-cyclohexane}2](O3SCF3), M = CuI or AgI (1983) (8)
Reactions of stable [PtCl2(η2-C2H4)(t-BuNCHCHNt-Bu)]. retention of the pentacoordinate structure upon halogen exchange and ligand substitution with olefins, α-diimines and N,N′-disubstituted 1,2-diaminoethanes (1980) (8)
Coordination chemistry of sulphines VI. Coordination of sulphines XYC=S=O (X,Y = aryl, S-aryl, Cl) to Pd0 and IrI complexes. Oxidative addition of the C-Cl side bond of (E)-(RS)ClC=S=O and (Z)-PhClC=S=O to Pd0 (1981) (8)
Synthesis, coordination chemistry, and metal complex reactivity of (dimethylamino)methyl-substituted triarylphosphanes; X-ray study on [AuCl(PPh3-nArn)] (Ar = 1-C6H3(CH2NMe2)2-3,5, n = 1, 3; Ar = 1-C6H4(CH2NMe2)-4, n = 3) (2006) (8)
Mössbauer study of the solid state configuration of triorganotin derivatives with intramolecular coordination (1980) (8)
TANTALACYCLOBUTANE COMPLEXES CONTAINING THE POTENTIALLY C,N,N'-COORDINATING LIGAND C6H4(CH2N(ME)CH2CH2NME2)-2- (CNN) AND THEIR REACTIVITY WITH CARBON MONOXIDE AND TERT-BUTYL ISOCYANIDE. X-RAY MOLECULAR STRUCTURES OF TACH2CH(M E)CH2-1,3(CNN)(O-T-BU)2, TACH2CH(PH)CH2-1,3(CNNO)(O-T-BU)2, AND TAC(=N-T-B (1997) (8)
A new type of tungsten(VI) phenylimido alkylidene complex and its triorganotungsten precursor with an O,N-chelating ligand; molecular structures of [W(CH2SiMe3)3(NPh){OCPh2(2-py)}] and [W{CHSiMe3(CH2SiMe3)(NPh){OCPh2(2-py)}](py = pyridine) (1993) (8)
Structure of {2,3,5,6‐tetrakis[(dimethylamino)methyl]phenyl‐C,N,N'}lithium dimer (1987) (8)
Coordination of 3-substituted 1-aza-4-oxo-1,3-butadienes (a-iminoesters and amides) to aluminum and zinc chloride and to dimethylzinc. Selective reduction in theZnEt2-R1N=CHC(NEt2)=O system and crystal structure of[EtZn(t-Bu)NCH2C(NEt2)=O]2 (X-ray) (1987) (8)
Novel reactions of substituted 1-aza-4-oxobutadienes )(a-iminoketones) with diorganozinc reagents. Selective ethyl transfer in the Et2Zn/t-BuN=C(H)-C(Me)=O system and X-ray crystal structure of [EtZn(Et)(t-Bu)NC(H)=C(Me)O]2 (1983) (8)
Synthesis and structure of some di-iron α-diimine complexes containing a ferracyclopentadienyl system resulting from the CC coupling of two alkynes (1989) (8)
Structure and Reactivity of Cyanocuprates Containing the Monoanionic C,N-Chelating Aminoaryl Ligand [C6H4CH2NMe2-2] (2000) (8)
Crystal and molecular structure of SnMePh[C10H5(OMe-5)(CH2NMe2-8)]Br and proton nuclear magnetic resonance study of the puckering of the chelate ring in five-co-ordinate triorganotin halides SnRR′-[C10H5(OMe-5)(CH2NMe2-8)]X and SnRR′[CH2C6H4(CH2NMe2-2)]X (1980) (8)
Thermally stable aryltungsten(VI) oxo and phenylimido complexes containing phenyl ligands with ortho-chelating tertiary amine substituents: molecular structures of W[(R)-C6H4CH(Me)NMe2-2]Cl3(:O) and W(C6H4CH2NMe2-2)Cl2(:NPh)(OCMe3) (1993) (8)
An unexpected dinuclear zwitterionic PtII cation [Pt2{C6H3(CH2NHMe2)2-2,6}2I4]2+ and alcohols from the reaction of an aryl(diamine)(aquo)PtII complex with alkyl iodides; X-ray and n.m.r. studies (1989) (8)
Enantioselective dialkylation of 1,2-phthalicdicarboxaldehyde (2001) (8)
Co-ordination chemistry of sulphines. Part 4. Influence of the phosphine cone angle on both the oxidative addition of carbon–sulphur and carbon–chlorine side bonds in [Pt0(PR3)2(XYCSO)] complexes and the (E)–(Z) isomerization (1981) (8)
α-Cupriobenzylideneamines, a novel class of thermally stable organocopper compounds (1972) (8)
Enantioselective synthesis of a chiral intermediate for aztreonam and related monobactam antibiotics (1990) (8)
Stereoselective Isomerization in Organoiridium(III) Complexes Induced by the Presence of Rigid C,N Chelating Ligands (1993) (8)
Functionally substituted arylcopper compounds; crystal structure of the copper bromide complex of [2-(4,4-dimethyl-2-oxazoline)-4-methylphenylcopper] (1986) (8)
Chiral ortho-Palladated and -Platinated Arylphosphite Complexes (2009) (8)
Synthesis, Solid-state and Solution Structures of Bis{N,NE'-bis[2-thienyl)methylene]-1,2-diaminoethane}-silver(I) and -copper(I) Trifluoromthanesulfonate Complexes (1995) (8)
Synthesis of metal-tetraazadiene complexes via Ar2N4 ligand transfer. Evidence for a stable tetraazadiene-bridged intermediate (1982) (8)
Group ib organometallic chemistry : XXXIV. Thermal behaviour and chemical reactivity of tetranuclear Me2N-substituted diarypropenylcopper-copper anion (Vi2Cu4X2) and mixed diarylpropenyl/organocopper (Vi2Cu4R2) compounds (1980) (7)
Trimetallic FePd2 and FePt2 4-ferrocenyl-NCN pincer complexes (2006) (7)
Reversible CC coupling reactions between alkynes and CO ligands on di-iron α-diimine complexes (1989) (7)
Binuclear metal carbonyl DAB complexes. III. Activation of a CN double bond in Ru2(CO)6(DAB) complexes (DAB = 1, 4-diazabutadiene). C C bond formation between two DAB ligands (1979) (7)
A phenoxydicopper(I) complex containing a bridging oxygen atom:Cu2(m-Br)[m-{OC6H3(CH2NMe2)2-o,o'}][P(OMe)3]2 (1987) (7)
Heterobimetallic Fe-Pd and Fe-Pt NCN pincer complexes (NCN = [C6H2 (CH2NMe2)2-2,6]-) (2006) (7)
Reactions of stable [PtCl2(η2-olefin)(α-di-imine)] complexes. Retention of the five-co-ordinate structure upon halogen exchange and ligand substitution with olefins, α-di-imines, and N,N′-disubstituted 1,2-diaminoethanes (1981) (7)
Synthesis and X-ray structure of the chiral, polydentate cation binder N-[N-[(5-methyl-2-thienyl)methylidene]-L-methionyl]histamine (1991) (7)
Diastereoselective Condensation Reactions with an Easily Accesible Intramolecularly Coordinated Zinc-Enamine : Molecular Structure of a Self-Assembled Polymer of Diethylzinc and Zinc-Aldolates (1993) (7)
Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [NC-4-C6H2(CH2NMe2)2-2,6]−) (2008) (7)
Are arylcopper compounds intermediates in the exchange reaction between aryl halides and copper(I) salts (1976) (7)
Reactions of dinuclear metal carbonyl α-diimine complexes with alkynes. Part 9. Metal-Metal Bond Fission and Formation and C-C Couplings in Reactions of Diruthenium 1,4-Diaza-1,3-butadiene Complexes with Alkynes (1989) (7)
Reversible C-N bond formation and fission between an α-diimine ligand and a methyl propynoate molecule on a dinuclear iron carbonyl moiety. X-ray crystal structures of Fe(CO)6{(i-Pr)NC(H)C(H)N(i-Pr)C(H)CC(O)OMe} and Fe2(CO)4{(i-Pr)NC(H)C(H)N(i-Pr)C(H)CC(O)OMe} (1989) (7)
Coordination of a Ru(II)-complex to a tetrafunctional P-ligand : a model for Ru-P carbosilane dendrimers (2000) (7)
Detection of Scalar 6Li, 15N Coupling across Coordinative LiN Bonds (1997) (7)
Solid–Gas Interactions Between Small Gaseous Molecules and Transition Metals in the Solid State. Toward Sensor Applications (2003) (7)
X-ray structure and dynamic behaviour in solution of N-methylthio-N'-2,6-dimethylphenyl).2,6-dimethyl-1,4-quinonediimine formed by the alcoholysis of [Me2 Al{2,6-Me2C6H3NS(Me)NC6H3Me2-2,6}]2 (1981) (7)
Highlights of 45 years of research: A personal account (2017) (6)
Synthesis of the diphenylacetylene-based, tetra-amine ligand 1,2-bis(3,5-bis[(dimethylamino)methyl]phenyl)acetylene by palladium-catalysed cross-coupling: isolation and crystal structure of the catalyst trans-(3,5-bis[(dimethylamino)methyl]phenyl)bis(triphenylphosphine)palladium(II) iodide (2000) (6)
Heteroleptic metallacyclic potassium organodiamido zincate complex. Synthesis and structure of polymeric {[K(thf)][MeZn(ButNCHCHNBut)]}n (1995) (6)
Novel organomanganese(II) complexes active as homogeneous catalysts in manganese(II)/copper(I) catalyzed carbon‐carbon bond formation reactions (2010) (6)
Formation of novel 'phosphite' metallacycles via selective ring opening of Pt(II) or Pd(II) coordinated tri- and di-azaphospholes (1984) (6)
Structure of bis[N-(2-pyrrolylmethylene)-tert-butylamine]zinc(II), Zn(C9H13N2)2 (1983) (6)
1H, 31P and 195Pt NMR characterization, and X-ray molecular structures of five- and six-membered platinum(II) and palladium(II) metallacycles from the alcoholysis of di- and triazaphosphole complexes (1997) (6)
Regioselective introduction of functional groups in α‐diimines by means of dialkylzinc compounds. Synthesis of functionalized 2‐ and 3‐pyrrolidinone derivatives (1993) (6)
N-Substituted indole-3-thiolate [4Fe–4S] clusters with a unique and tunable combination of spectral and redox properties (2008) (6)
Synthesis and characterization of two new "pincer" complexes of zinc(II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{η3-NN'N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me) (2000) (6)
Synthesis and Characterization of Bis(arenethiolato)magnesium Complexes with Intramolecular Coordination. X-ray Structure of (Mg{S(C6H4-2-CH2NMe2)}2)2 (1996) (6)
Electronic and electrochemical properties of platinum(II) and platinum-mercury-carboxylato complexes containing 2-Me2NCH2C6H4-, 2,6-(Me2NCH2)2C6H3- and 2-Me2NC6H4CH2 ligands (1982) (6)
Binuclear metal carbonyl R-DAB complexes. Synthesis and spectroscopic properties of novel heterodinuclear a-diimine (R-DAB and R-Pyca) complexes, containing an asymmetric bridging hydride. Molecular structure of [(m-H)FeMn(CO)6 C5H4N-2-CH=N-t-Bu)] (1985) (6)
Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group? (2002) (6)
Mononuclear Nonheme Iron Enzymes with the 2‐His‐1‐carboxylate Facial Triad: Recent Developments in Enzymology and Modeling Studies (2009) (6)
Carbonylation of diamino-ligated methylpalladium(II) methoxide complexes (1995) (6)
A General Survey and Recent Advances in the Activation of Unreactive Chemical Bonds by Metal Complexes (2000) (6)
Stable Divalent Triarylstannates R3SnLi Derived from 2-[(Dimethylamino)methyl]phenyllithium and SnCl2 or R2Sn (2015) (6)
SYNTHESIS OF NOVEL DINUCLEAR FORMAMIDINO AND TRIAZENIDO COMPOUNDS ((2,6-(ME2NCH2)2C6H3)(P-TOLNYNR)PTAGBR) (Y = CH, N) CONTAINING A PLATINUM-SILVER BOND (1982) (6)
Comment on “Theoretical studies on the ground states in [M(terpyridine)2]2+ and [M(4-(4-(t-butyl)phenyl)terpyridine)2]2+ (M = Fe, Ru, Os) and excited states in [Ru(terpyridine)2]2+ using density functional theory” (2008) (6)
Synthesis and reactivity towards Ni(COD)2 of substituted dicyclopentadienylzinc compounds; crystal structures of zinc-nickel clusters Zn4Ni2(h5-C5H4t-Bu)4 (h1-C5H4t-Bu)2 and Zn4Ni2(h5-C5H4SiMe3)2(h3-C5H4SiMe3)2(h1-C5H4SiMe3)2 (1989) (5)
Interaction of metal centres with the 1,4‐diaza‐1,3‐butadiene (α‐diimine) ligand. Versatile coordination chemistry and applications in organic synthesis and catalysis (2010) (5)
Synthesis of Novel Divalent Organotin Compounds Containing the Chiral C,N(2-(Dimethylamino)phenyl)(trimethylsilyl)methyl or 2-(1-(Dimethylamino)ethyl)phenyl Chelating Ligand. (1992) (5)
Palladium arenethiolates with intramolecularly coordinating nitrogen lewis bases (1996) (5)
A Tin(IV) Porphyrin with Two Axial Organometallic NCN-Pincer Platinum Units† (2007) (5)
From ferrocenyl selenoesters to diferrocenyl methanols (2018) (5)
Palladium-Mediated Intramolecular C-N bond Formation between Tertiary amines and Alkenes (1994) (5)
Structural Organocopper Chemistry (2011) (5)
Displacement reactions of cis-[PtIICl(R′SCSO)(PR3)2] (R = Ph, C6H11; R′ = aryl) with nucleophiles. Formation with R′S− of an η2-CS coordinated sulphine (R′S)2CSO by reductive coupling [1] (1982) (5)
Synthesis, X - ray crystal structure and reactions of dimethyl(N,N,N′,N′- tetramethylethanediamine)palladium† (2010) (5)
Inter- and intra-molecular ligand-exchange and -rearrangement reactions of tetra-azadiene complexes of nickel, platinum, and cobalt (1982) (5)
Dendrimer Catalysis (2017) (5)
Reactivity of the binuclear ruthenium ‘Pincer’ complex [{RuCl2(η3-NN′N)}2(μ-N2)] towards N-donor ligands. The X-ray crystal structure of [RuCl2(η3-NN′N)(NCPh)] (NN′N=2,6-bis[(dimethylamino)methyl]pyridine) (2000) (5)
X‐Ray crystal structure of the ethylzinc enolate of 1‐(2,4‐cyclopentadienyl)‐2‐(diethylamino)‐1‐ethanone, the unexpected reaction product from cyclopentadienyl(ethyl)zinc and ethyl N,N‐diethylglycinate (2010) (5)
Bisphenolate iron(II) complexes with intramolecularly coordinating nitrogen Lewis bases (1999) (5)
Co-ordination chemistry of sulphines. Part 3. Oxidative addition of the carbon–chlorine bond of (E)-chloro(arylthio)-sulphine, (E)-(RS)CICSO, to tetrakis(triphenylphosphine) platinum(0) and of a carbon–sulphur bond in [Pt0(PPh3)2{(RS)2CSO}] by an intramolecular process. X-Ray crystal and molecular s (1981) (5)
SYNTHESIS AND REACTIVITY OF BIS(1,4-DIARYLTETRAAZABUTADIENE)NICKEL COMPLEXES. CRYSTAL AND MOLECULAR STRUCTURE OF BIS(1,4-BIS(3,5-DIMETHYLPHENYL)TETRAAZABUTADIENE)NICKEL (1982) (5)
The zinc mediated condensation of amino acid esters with imines t β-lactams (1993) (5)
Synthesis of metal—tetraazadiene complexes via ligand transfer; two routes to nickel—or platinum—tetraazadiene complexes [M(Ar2N4)(L)2] (1981) (5)
Lightly fluorous (Pd(OAc)2{P(C6H4-p-SiMe2CH2CH2C6F13)3}2) in the methoxycarbonylation of styrene: Formation, performance and stability of the catalyst system (2006) (5)
Novel C–C and C–N coupling reactions on a di-iron–α-di-imine complex in the reaction of Fe2(CO)6{RNC(H)C(H)NR} with methyl propynoate; X-ray crystal structures of Fe2(CO)5{(c-C6H11)NCHCHN(c-C6H11)C(O)CHCCO2Me}, Fe2(CO)6{PriNCHCHN(Pri)CHCCO2Me} and Fe2(CO)4{PriNCHCHN(Pri)CHCCO2Me} (1986) (4)
Pincer Chemistry and Catalysis (2020) (4)
Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of 1 -I2 Organometallic "Pincer" Complexes of Platinum. X-ray Crystal (1999) (4)
Coordination and activation of the NS bond in sulfurdiimines RNSNR and sulfinylanilines RNSO by metal atoms (2010) (4)
Structural Organomagnesium Chemistry (2009) (4)
Structural Investigation in Solution of a Series of Five‐Coordinate Bisphosphanylaryl Ruthenium(II) Complexes (2000) (4)
Efficient recycling of fluorous versions of highly enantioselective S,N-chelated zinc aminoarene thiolate catalysts for the 1,2-addition of diethylzinc to benzaldehydes (2008) (4)
Structural Features and Dynamical Behavior of Heteroleptic trans-C,C-Bisaryl-Platinum(II) and -Palladium(II) Complexes (2005) (4)
Selectivity in reductive elimination from dialkyl(aryl)palladium(IV) complexes, and the observation of benzyl halide transfer from palladium(IV) to palladium(II). The X‐ray structure of methyl(phenyl)(2,2′‐bipyridyl)palladium(II) (2010) (4)
Intramolecular rearrangements of sulphines co-ordinated to Pt involving insertion and reductive coupling reactions. X-Ray crystal and molecular structure of (E)-[PtII(PhS)(PPh3)2(PhSCSO)]·C6H6, a new type of heterocumulene–metal complex (1979) (4)
The influence of electronic and steric factors on the coordination and on the cluster breakdown of polynuclear ruthenium carbonyl compounds (1982) (4)
Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents (2010) (4)
Organometallics in Process Chemistry (2004) (4)
Synthesis and characterization of ruthenium ‘pincer’ complexes containing sulfur atom donor ligands. The X-ray crystal structure of [RuCl2(η3-NN′N)(SMe2)] (NN′N={2,6-(Me2NCH2)2C5H3N}) (1999) (4)
Formation of a N–C bond between co-ordinated α-di-imine and a novel diketene fragment; X-ray crystal structure of {Ru2(CO)5[PriNC(H)(H)C–N(Pri)C(O)CH2C(O)CH2]}containing an η3-aza-allyl to Ru bonded moiety (1983) (4)
Computational Analysis of Mesomerism in para-Substituted mer-NCN Pincer Platinum(II) Complexes, including its Relationships with Hammett σp Substituent Parameters. (2020) (4)
Chiral pentacoordinate triorganotin halides (1977) (4)
2-(1-(Dimethylamino)ethyl)phenylpalladium(II) complexes 5-functionalized with fluorous silyl tails (2006) (4)
Synthesis and characterization of polynuclear organocopper compounds (1974) (3)
The synthesis of 3‐alkyl‐ and 3‐aryl‐β‐lactams from zinc enolates and imines (2010) (3)
Aryltitanium(IV) complexes with the η3-C,N,N′-pseudofacially coordinating ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]−. The X-ray crystal structure of [TiCl2(CNN)(O-i-Pr)] (1997) (3)
Synthesis of novel binuclear palladiumthallium carboxylates of the type PdTI(O2CR)5 and their structural characterization based on observation of J(203, 205Tl1H and J(203, 205Tl13C) (1980) (3)
Homogeneous Vanadium‐Based Catalysts for the Ziegler—Natta Polymerization of α‐Olefins (2003) (3)
Cover Picture: Silver Baits for The “Miraculous Draught” of Amphiphilic Lanthanide Helicates / A Multistate Switchable [3]Rotacatenane / Heuristic Chemistry-Addition Reactions / Steric, Electronic, and Secondary Effects on the Coordination Chemistry of Io (2011) (3)
Nitrogen-based pincers: a versatile platform for organometallic chemistry (2007) (3)
Synthesis of aminoarenethiolato-copper(I) complexes (2008) (3)
Structure of a-chloro-b-dichloromethylstannio-[dc,ef-bis(8-dimethylamino-1-naphthyl)]platinum(IV) (1992) (3)
Electron and ligand transfer reactions between cyclometallated platinum(II) compounds and thallium(III) carboxylates (1982) (3)
A Zinc Mediated Route from α-Imino Esters to β-Lactams (1987) (3)
Co-ordination chemistry of sulphines. Part 5. σ-S and η3-SCS co-ordination of sulphines to rhodium(I). Fluxional behaviour of [RhICl(PR3)(XYCSO)](R = alkyl; X, Y = aryl, S-aryl, S-alkyl, or Cl) complexes and influence of sulphine geometry on the formation of [RhICl(PR3)2(XYCSO)] (1982) (3)
The Pincer Ligand: Its Chemistry And Applications (2012) (3)
Simple preparation of bimetallic palladium-copper catalysts for selective liquid phase semihydrogenation of functionalized acetylenes and propargylic alcohols (1997) (3)
Synthesis and reactivity of (thioamido S-oxide)(diene)rhodium(I) complexes. X-ray structure of Rh(I)[(p-Tol)(p-TolN)CSO](NBD) (1987) (3)
Selective formation of 1,3,4-trisubstituted and 3,4-disubstituted trans-β-lactams from zinc enolates and imines (2010) (2)
SYNTHESIS, REACTIVITY, AND CRYSTAL STRUCTURE OF (1,4-BIS(4-TOLYL)TETRAAZABUTADIENE)(η5-CYCLOPENTADIENYL)NICKEL (1983) (2)
Dinuclear copper(I) benzoato quinoline complexes as intermediates in the copper‐quinoline decarboxylation reaction (2010) (2)
INTERACTION OF METAL CENTERS WITH THE 1,4-DIAZA-1,3-BUTADIENE (α-DIIMINE) LIGAND. VERSATILE COORDINATION CHEMISTRY AND APPLICATIONS IN ORGANIC SYNTHESIS AND CATALYSIS (1981) (2)
Organic Chemistry and Catalysis (2009) (2)
Pincers and other hemilabile ligands (2011) (2)
Structures of [N-(p-methoxyphenyl)-2-(p-methoxyphenylimino)propylamino-N,N']dimethylaluminium (I) and dimethyl[N-(p-tolyl)-2-(p-tolylimino)propylamino-N,N']aluminium (II) (1988) (2)
Dendritic Supports in Organic Synthesis (2002) (2)
Palladacycles on Dendrimers and Star‐Shaped Molecules (2008) (2)
Novel Aryltitanium(IV) Complexes Containing 3 -NCN-Pseudofacial- and 3 -NCN-Meridional-Bonded (1997) (2)
Structural Organozinc Chemistry (2009) (2)
Homogeneous Catalysis with Transition Metal Complexes (1994) (2)
trans-Dichlorobis(tris{4-((dimethylamino)- methyl)phenyl}phosphine)platinum(II) (2005) (2)
Copper(I), silver(I) and zinc(II) cations in multifunctionalized donor-atom environments comprising two imidazole N-, two thioether S-, and two amide O-atoms (1991) (2)
(TETRAAZABUTADIENE)PLATINUM COMPLEXES. X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF THE TRIETHYLPHOSPHINE NUCLEOPHILIC ADDITION PRODUCT (PT(1,4-(4-O2NC6H4)2N4)(CHC(PET3)H(CH2)2CH:CHCH2CH2)(PET3)), A NOVEL FIVE-COORDINATE BLUE MONONUCLEAR (1982) (2)
Structure of [ad,be-Bis(8-dimethylamino-1-napthyl)]-f-ethyl-c-iodo-platinum(IV) (1992) (2)
Structure of {2,6-bis[(dimethylamino)methyl]phenyl}iodoplatinum(II) (1987) (2)
Aryl Metal Complexes Stabilized by Intramolecular Coordination (2000) (2)
Fast Atom Bombardment Tandem Mass Spectrometry of Orgnometallic Palladium Complexes Containing Terdentate Nitrogen Ligands (1995) (2)
Group IB organometallic chemistry. 30. Stereochemistry of arylmetal-1B, aryllithium, and arylmetal-1B-lithium clusters Ar4M2Li2(M = copper, silver, or gold). Detection of rotation of three-center two-electron bonded aryl groups around the C(1)-C(4) axis (1980) (2)
New routes toward metallated methanofullerene terdentate bisaminoaryl ligands (2002) (2)
trans-3-Amino-1-methyl-4-phenyl-2-azetidinone, C10H12N2O (1994) (2)
The Copper‐Catalyzed Reaction of Sodium Methoxide with Aryl Bromides. A Mechanistic Study Leading to a Facile Synthesis of Anisole Derivatives. (1989) (2)
Highly functionalized β-enamino esters via C-C coupling reactions of lithium enolates of protected glycine esters and isothiocyanates (1995) (2)
Dynamics of 3c−2e Bonded Aryl Groups in Arylcopper, -Silver and -Gold Cluster Derivatives (1979) (2)
Synthesis and characterization of the polynuclear organocopper—compper halide compound [(4-MeC6H4)MeCC(C6H4NMe2-2)]2 Cu4Br2 containing bridging vinyl groups (1978) (2)
Structures and reactivities of copper(I) and silver(I) complexes of potentially quadridentate N4 and N2S2 donor ligands. (1983) (2)
Metallasupramolecular Architectures, an Overview of Functional Properties and Applications (2006) (2)
Atom Transfer Radical Polymerization of Methyl Methacrylate Initiated by Carbosilane Dendritic Species (1999) (2)
[mer,trans-(NN′N)RuCl2(NC5H5)]·C7H8 {NN′N = 2,6-bis-[(dimethylamino)methyl]pyridine} (2001) (2)
Ligand‐Free Copper(I) Catalyzed N‐ and O‐Arylation of Aryl Halides. (2008) (2)
The oxygenation of cyclopalladated N,N-dimethylbenzylamine derivatives with tert-butyl hydroperoxide (2010) (2)
A Novel Type of Pt-C Interaction and a Model for the Final Stage in Reductive Elimination Processes Involving C-C Coupling at Pt; Synthesis and Molecular Geometry of [1,N,N′-η-2,6-Bis((dimethylamino)methyl)-toluene]iodoplatinum(II) Te (1978) (2)
Synthesis of organozinc enolates of N,N-disubstituted glycine esters. Crystal structure of [EtZnOC(OMe)=C(H)N(t-Bu)Me]4 (1990) (2)
Bio-inspired manipulation of catalytic sites via immobilization of metal ion complexes in zeolites (2007) (2)
Mass spectra of some tetra‐alkylgermanium compounds (2010) (1)
BINAP‐Ru and ‐Rh Catalysts Covalently Immobilized on silica and Their Repeated Application in Asymmetric Hydrogenation. (2008) (1)
Selective Product Formation with Organometallic Radicals of Nickel and Zinc (1997) (1)
Unexpected Metal Base‐Dependent Inversion of the Enantioselectivity in the Asymmetric Synthesis of α‐Amino Acids Using Phase‐Transfer Catalysts Derived from Cinchonidine. (2003) (1)
Influence of Steric Factors on the Coordination Mode (η1 or η2) of Phosphaalkenes to Zerovalent Pt0L2 Centers. X-Ray Structure of Bis(triphenylphosphine)((2,6-dimethylphenyl)-9-fluorenylidenephosphine)platinum(0)-Toluene. (1987) (1)
A View of Organo‐Copper Compounds and Cuprates (1991) (1)
Bis(ortho-)Chelated Monoanionic Bisphosphinoaryl Ruthenium(II) Complexes: Synthesis, Characterization and Reactivity (2002) (1)
Dichloro(di-2-pyridylamine)zinc(II): a redetermination at 110 K (2005) (1)
Chemistry in a Spin: Multinuclear Magnetic Resonance (1990) (1)
Some synthetic and structural aspects of neutral organocuprate reagents CunLimRn+m; the asymmetric bonding configuration of the bridging organo group (1987) (1)
Thermally Stable Arylpalladium Diamine Complexes as Versatile Precursors in Organopalladium Chemistry; Synthesis and X‐Ray Molecular Structure of PdIPh(tmeda) and its Conversion to PdMePh(tmeda) {tmeda = Me2N(CH2)2NMe2} (2010) (1)
C-N Coupling of Nitrogen Nucleophiles with Aryland Heteroaryl Bromides (2010) (1)
SILVER COMPLEXES CONTAINING AN AG4O8 CORE IMPOSED BY MULTIDENTATE LIGANDS HAVING FIXED GEOMETRY. CRYSTAL STRUCTURE OF (BIS(1,8-NAPHTHALENEDICARBOXYLATO))(TETRAKIS(TRIPHENYLPHOSPHINES)SILVER(I))-DIBENZENE (1979) (1)
Synthesis of O,O-diethyl arylthiophosphonate from O-Aryl-O,O-diethylthiophosphate (2008) (1)
Silica-Supported Palladium Catalysts for Aldol Reaction (2008) (1)
Solid-gas interactions between small gaseous molecules and transition metals in the solid stateTowards sensor applications in perspectives in supramolecular chemistry (2003) (1)
The crystal structure of dicyclopentadienylmercury (2010) (1)
Advances in Catalysis with Organonickel(II) Complexes Anchored to Dendrimers and Polymers (1996) (1)
A view on organocopper compounds an cuprates (1990) (1)
Tuning of tantalum alkylidene reactivity with a terdentate aryl amine ligand: Synthesis structure and reactivity of [TaCl2{C6H3(CH2NMe2)2-2,6}(CHBut)] (2010) (1)
O,N-Chelated Vanadium(IV) Oxo Aminophenolate Complexes: the Effect of Steric Bulk on the Vanadium Coordination Geometry. Can this Influence be detected Spectroscopically? (2004) (1)
The Hurtley reaction III. A reactivity study of copper(I) 2‐halobenzoates either as pure reagents, or under Hurtley reaction conditions, and as a part of mixed (benzoato)(mesityl)copper(I) clusters (2010) (1)
Intramolecular amine coordination versus NMe C‐H Activation: The stereoselective synthesis of a tantala(V)azacyclopropane complex (2010) (1)
Novel Aspects of η′-Diiodine Coordination and Diiodine Oxidative Addition to Platinum(II) and Halide Transfer Oxidation Reactions of Organoplatinum(II) with CuIIX2 (1990) (1)
A 3:1 site-differentiated [4Fe-4S] cluster immobilized on a self-assembled monolayer (2008) (1)
NOVEL BONDING MODES OF α-D (1980) (1)
Determination by microwave titration of the stoichiometry of phosphine and amine complexes of cuprous trifluoromethanesulphonate (copper triflate) (1977) (1)
Selective Formation of 1,3,4-Trisubstituted and 3,4-Disubstituted trans-β-Lactams from Zinc Enolates and Imines. (1988) (1)
STRUCTURAL INVESTIGATIONS OF SILVER(I) AND COPPER(I) COMPLEXES WITH NEUTRAL NITROGEN (N4) DONOR LIGANDS: X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF THE DIMER (AG2(μ-(R)(S)-1,2-(PY-2-CH:N)2CY)2)(O3SCF3)2 AND PROTON, CARBON-13, AND INEPT (1984) (1)
Synthesis of Marasin and 9-Methylmarasin, (Nona- and Deca-6,8-diyne-3,4-dienol). (1989) (1)
Mono‐ and Heterodimetallic FeII and RuII Complexes Based on a Novel Heteroditopic 4′‐{Bis(phosphanyl)aryl}‐2,2′:6′,2″‐terpyridine Ligand (Eur. J. Inorg. Chem. 15/2007) (2007) (1)
Unusual Isomerization of Ortho-Chelated Aryliridium(I) Complexes, Involving a Unique Sequence of Intramolecular C-H Bond-Making and -Breaking Processes. X-Ray Structure of Ir(I)(C6H3(CH2NMe2)2-2,4)(COD). (1988) (1)
Carbosilane Dendrimers: Molecular Supports and Containers for Homogeneous Catalysis and Organic Synthesis (2009) (1)
Dendrimers incorporating metallopincer functionalities: synthesis and applications (2007) (1)
X-Ray Crystal Structure of the Hexameric Lithium Enolate of Ethyl N,N-Diethylglycinate. (1988) (1)
14 – Copper and Silver (1982) (1)
The Monoanionic ECE-Pincer Ligand: A Versatile Privileged Ligand Platform — General Considerations (2013) (1)
Model for the Initial Stage in the Oxidative Addition of I2 to Organoplatinum (II) Compounds. (1986) (1)
3,5-Bis[(dimethylamino)methyl]-1-nitro-4-(trimethylsilyl)benzene (2007) (1)
Diastereo- and enantio-selective synthesis of trans-3-phenyl- and trans-3-styryl-2-azetidinones via zinc ester enolates and imines (2010) (1)
New Developments in Zinc-mediated Organic Synthesis (1993) (1)
Erratum to: “Chiral platinum and palladium complexes containing functionalized C2-symmetric bisaminoaryl ‘Pincer’ ligands”: Journal of Organometallic Chemistry 624 (2001) 271–286 (2001) (1)
RUTHENIUM CARBONYL 1,4-DIAZA-1,3-BUTADIENE (R-DAB) COMPLEXES. 5. SYNTHESES, SPECTROSCOPIC PROPERTIES, AND REACTIVITY OF RU2(CO)5(ALKYL-DAB), A KEY INTERMEDIATE IN THE RU3(CO)12-ALKYL-DAB REACTION. CRYSTAL AND MOLECULAR STRUCTURE OF (1 (1984) (1)
Supramolecular aryl transition metal catalysts; Selective product formation with organometallic radicals (1997) (1)
Synthesis of Cyclometalated (8-Methoxynaphthyl)- and (8-(Dimethylamino)naphthyl)platinum Compounds and Their Reactivity Toward Electrophiles. X-Ray Molecular Structures of Square-Planar (8-Methoxynaphthyl)platinum(II) Chloride Bis(die (1989) (1)
Organometallic complexes with chiral cyclometallated ligands. The synthesis of cyclo-platinated complexes containing the (S)- or (R)-[2-NMe2C6H4CH(SiR3)](R= Me, Ph) monoanion. X-ray crystal and molecular structure of [PtCl[Ch(SiMe3)C6H4-2-NMe2](ET2S)] (2010) (1)
Activation of an Aliphatic C-H Bond at Room Temperature. Part 4. Conversion on a Cluster of a Stable σ-Bonded Alkyl Group to a μ2-Alkylidene Ligand. Synthesis and Crystal Structure Determination of HOs3(6-CH2C5H3N-2-C(H)=N-i-Pr)(CO)9 (1988) (0)
The Syntheses of β-Lactams from Zinc Enolates of N,N-Disubstituted α-Amino Acid Esters and Imines: Substituent and Solvent Effects. (1989) (0)
Site-Specific Covalent Immobilization of a Racemization Catalyst onto Lipase-containing Beads (2009) (0)
Structural Investigations of Benzocyclopentadienylzinc Complex of Difluorenylzinc Compounds. Crystal Structure of the Bis(tetrahydr0furan) (2001) (0)
XV*. ARYLCOPPER COMPOUNDS ArJ!u, AS INTERMEDIATES IN ORGANOMETALLIC SYNTHESIS. ONE-STEP SYNTHESIS OF TRIORGANO. TIN HALIDES OF THE TYPE Ar,SnX AND Ar&R,SnX (1975) (0)
Reactivity of Cyclopalladated Compounds. Part 19. Regioselective Formation of η3-Allylic Ligands via the Reaction of Alkynes with Cyclic ((Pd(CH(SiMe3)C6H4NMe2-2)(μ-Cl))2). (1989) (0)
Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of η-I2 Organometallic “Pincer” Complexes of Platinum. X-ray Crystal Structures (1999) (0)
Syntheses and Characterization of Unique Organometallic Nickel(III) Aryl Species. ESR and Electrochemical Studies and the X-Ray Molecular Study of Square-Pyramidal (Ni(C6H3(CH2NMe2)2-o,o′)I2). (1988) (0)
A COMPARATIVE STUDY OF PLATINUM DI(TERT-BUTYL)(15N2)DIIMINE) AND TRANS-(PTCL2(N-LIGAND)PBU3)) COMPLEXES BY PLATINUM-195, PHOSPHORUS-31 AND NITROGEN-15 NMR (1981) (0)
Organometallic Complexes with Chiral Cyclometalated Ligands. The Synthesis of Cycloplatinated Complexes Containing the (S)- or (R)-2-NMe2C6H4CH(SiR3) (R: Me, Ph) Monoanion. X-Ray Crystal and Molecular Structure of (PtCl(CH(SiMe3)C6H4- (1989) (0)
Bonding Mode Variations in Palladium(II) and Platinum(II) Azaphosphole Complexes: Identification by 1H, 31P, and 195Pt NMR of N‐ and P‐Coordination, Pt‐Cl Addition to P, and Dimerization. (1988) (0)
XXXIV *. THERMAL BEHAVIOUR AND CHEWICAL REACTIVITY OF TETRANUCLEAR Me,N-SUBSTITUTED DIARYLPROPENYLCOPPER-COPPER ANION (VizCuqX2) AND MIXED DIARYLPROPENYL/ORGANOCOPPER (Vi,Cu,Rz) COMPOUNDS $ (1980) (0)
1-tert-Butyl-2-(tert-butylaminomethylidene)-3-pyrrolidinone, C13H24N2O (1994) (0)
Diastereocontrol via Cosolvents in the Zinc Ester Enolate-Imine Condensation Route to β-Lactams. (1995) (0)
Bis-ortho-Chelated Arylcopper Compounds. Synthesis and X-Ray Crystal Structure of Cu4Br2(C6H3(CH2NMe2)2-o,o′)2. (1989) (0)
Direct Alkoxylation of Organopalladium Compounds Based on a New Type of C‐O Coupling Mediated by Molybdenum Peroxides. (1991) (0)
REACTIONS OF SULFURDIIMINElS AND SULFINYLANILINES WITH I~%12 (1981) (0)
α-DIIMINES AS MONODENTATE OR BRIDGING LIGANDS, SYNTHESIS AND CHARACTERIZATION OF PALLADIUM(II) AND RHODIUM(I) DI(TERT-BUTYL)DIIMINE COMPLEXES (1977) (0)
FIVE-COORDINATE (PT(II)CL2(η(2)-OLEFIN)L2) (L2 = Σ,ΣN,N′-BONDES α-DIIMINE OR N,N′-DISUBSTITUTED 1,2-DIAMINOETHANE) COMPLEXES. SOLUTION CONFORMATION, η(2)-OLEFIN ROTATIONAL BARRIERS (NMR), AND THE X-RAY MOLECULAR STRUCTURE OF (PTCL2(η( (1981) (0)
Metallodendritic catalysis Recyclable nanosize homogeneous catalysts (2003) (0)
Stereo-selective oxidation catalysis (2006) (0)
Enantioselective Dialkylation of 1,2‐Phthalicdicarboxaldehyde. (2001) (0)
On the Two Closely Related Phases of [Ru(C5Me5)(η6-1,3-(Me2NCH2)2C6H4)](BF4) and the Reversible Solid–Solid Order–Disorder Phase Transition (2010) (0)
COORDINATION CHEMISTRY OF SULFINES. PART 2. INTRAMOLECULAR REARRANGEMENTS OF SULFINES COORDINATED TO PLATINUM. A UNIQUE EQUILIBRIUM BETWEEN OXIDATIVE-ADDITION STEREOISOMERS CIS-(E)- AND CIS-(Z)-BIS(TRIPHENYLPHOSPHINE)(METHYLTHIO)(ARYL (1981) (0)
XXX11 *. ARYLCOPPER COMPOUNDS Ar,Cu,, AS INTERMEDIATEE IN ORGANOMETALLIC SYNTHESIS. SINGLE-STEP SYNTHESIS AND DYNAMIC NMR SPECTROSCOPY OF DIORGANOTIN DIHALIDES h 2_,z R,SnX, (Ar = 2-Me,NCH,C,H, OR (S)-2-Me,NCHMeC6H4; ?z = 0 OR 1) ** (1979) (0)
Cover Picture: Lipase Active-Site-Directed Anchoring of Organometallics: Metallopincer/Protein Hybrids (Chem. Eur. J. 23/2005) (2005) (0)
/ Synthesis and reactivity of poly pyrazol-1-yl borate derivatives of cyclopalladation systems, including structural studies of (1998) (0)
Synthesis and Molecular Structures of Novel α‐Amino Organoaluminum Ester Enolates. Key Intermediates in the Selective Formation of trans‐3‐Amino‐2‐azetidinones. (1991) (0)
BINUCLEAR METAL CARBONYL DAB COMPLEXES. 10. ACTIVATION OF η2-C = N-COORDINATED DAB LIGANDS TOWARD CARBON-CARBON BOND FORMATION WITH ALKYNES. X-RAY STRUCTURE OF (2-PHENYL-3-(TERT-BUTYLAMINO)-4-(TERT-BUTYLIMINO)-1-BUTEN-1-YL)DIRUTHENIUM (1982) (0)
Trapping intermediates in electron transfer reactions of square planar organometallic d8species (1989) (0)
STEREOSBLECHVE ONE-PCyT SYNTHESES OF @anr-3-AMINO-PLACTAMS FROM ZINC BNOLATES OF N-PROTECTED ~L~MJNOACID ESTERS AND JMJNES. (1988) (0)
s,s'-N,N' bridging and s,s-N,N chelating a-diimines. Molecular geometries of[PtCl2PBu3]2 (t-BuN=CHCH=NBu-t) and PtCl2 (styrene)(t-BuN=CHCH=NBu-t) (1979) (0)
RN=c(H)c(H)=NR).' X-ray Structure of Os3(CO),(i-Pr-DAB(8e)), with Two Elongated Os-Os Bonds (1988) (0)
Hexacationic Dendriphos-Pd Complexes for Suzuki-MiyauraReaction (2009) (0)
Alkene and Alkyne Reactivity Toward a Bisruthenium(II) μ2-Dinitrogen Complex Containing the “Pincer” Ligand 2,6-Bis[(dimethylamino)methyl]pyridine (NN′N). The X-ray Crystal Structures of [Ru(dCdCHPh)- (1999) (0)
Reactivity of organopalladium compounds towards early transition metal peroxides: O-insertion vs. C-X-coupling (1991) (0)
From the Group‐IB Metals and Alloys (2007) (0)
Synthesis and Characterization of Two Isomers of Os3(CO)10(C5H4N-2-C(H)=N-R) and the Conversion to ortho-Metalated HOs3(C5H3N-2-C(H)=N-R)(CO)9. Part 3. X-Ray Structure of HOs3(C5H3N-2-C(H)=N-iPr)(CO)9. (1988) (0)
Thermally Stable Arylpalladium Diamine Complexes as Versatile Precursors in Organopalladium Chemistry. Synthesis and X-Ray Molecular Structure of PdIPh(tmeda) and Its Conversion to PdMePh(tmeda) (tmeda: Me2N(CH2)2NMe2). (1989) (0)
Synthesis of Heterodinuclear FeRu( CO),( R-DAB(6e)).( R-DAB = RN=C(H)C(H)=NR) Part XV. Comparison of the Reactivities of Heterodinuclear FeRu( CO),( R-DAB(6e)) and Homodinuclear Analogues M2(C0)6( R-DAB(6e)) (M = Fe, Ru). Singlecrystal X-ray Structures of FeRu(CO),(i-Pr-DAB(6e)) and FeRu(CO)5(i-Pr-D (1988) (0)
Dynamic Stereochemistry of Chiral Compounds (2008) (0)
Synthesis and Reactivity of (Thioamido S-oxide)(diene)rhodium(I) Complexes. X-Ray Structure of Rh(I)((p-Tol)(p-TolN)C=S=O) (NBD). (1987) (0)
Facile formation of amide bonds between fragments containing unmasked imidazole‐ring systems. Synthesis of N‐[N‐[[[(5‐methyl‐4‐imidazolyl)methyl]thio]acetyl]‐L‐methionyl]histamine (2010) (0)
1,g-Addition of Organolithium Compounds to Acceptor-Substituted Enynes Catalyzed by a Copper(1) Arenethiolate (2001) (0)
Chem. Eur. J. 2000. Polycationic (Mixed) Core-shell Dendrimers for Binding And Delivery of (In)Organic Substrates (2000) (0)
Conversion of 48e Os3(CO)10(R-DAB(4e)) via 50e Os3(CO)10(R-DAB(6e)) to 50e Os3(CO)9(R-DAB(8e)) (R-DAB: RN=C(H)C(H)=NR). Part 2. X-Ray Structure of Os3(CO)9(iPr-DAB(8e)), with Two Elongated Os-Os Bonds. (1989) (0)
GROUP 11 METAL IONS IN POLY(DONOR ATOM) ENVIRONMENTS: X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF (M((R,S)-1,2-(5-R-THIO-2-CH:N)2-C-HX)2)(O3SCF3) (M = AG(I), R = ME, THIO = THIOPHENE, C-HX = CYCLOHEXANE) AND SILVER(I) AND COPPER(I) COORD (1985) (0)
Group llt Metal Ions in Poly(donor atom) Environments: X-ray Crystal and Molecular Structure of (M((R,S)-~,~-(~- R-~~~O-~-CH=N)~-~-HX)~)(O,SCF~) (1985) (0)
Synthesis and X-ray Structure of the Chiral, Polydentate Cation Binder N-[N-[ (5-Met hyl-2-t hieny1)met hylidene]-~-methionyl] histamine (2001) (0)
REGIOSELECTIVE ETHYL TRANSFER REACTIONS BETWEEN DIETHYLZINC AND 1,4-DIALKYL-1,4-DIAZA-1,3-BUTADIENES: SYNTHESIS OF ETZN(R(ET)NCH = CHNR) (1982) (0)
NOVEL ARYL-BRIDGED TETRANUCLEAR GOLD-LITHIUM AND GOLD-COPPER CLUSTER COMPOUNDS R4AU2M2 (M=LI OR CU) (1975) (0)
SILVER(I) AND COPPER(I) BIS(PYRIDINE-2-CARBALDEHYDE-IMINE) TRIFLATE COMPLEXES STUDIED IN SOLUTION BY PROTON, PROTON-(SILVER-109), INEPT NITROGEN-15 AND INEPT SILVER-109 NMR (1985) (0)
SYNTHESIS AND SPECTROSCOPIC STUDIES OF SILVER AND RHODIUM MONO- AND POLYNUCLEAR COMPLEXES WITH MULTIDENTATE PHOSPHINES (PH2P)2CHR (R = H, ME, PPH2) (1982) (0)
UvA-DARE (Digital Academic Repository) Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the N- Thienylidene-L/D-methionine Methyl Ester Ligand Ankersmit, (1997) (0)
The application of manganese(II) complexes stabilized by a tridentate mono-anionic diamine ligand in various organic reactions (1995) (0)
Oxidative-addition reactions of molecular diiodine and dibromine to divalent organotin compounds. Crystal structures of bis[8-( dimethylamino)-1-naphthyl]tin( IV) (2001) (0)
MOESSBAUER STUDY OF THE SOLID STATE CONFIGURATION OF TRIORGANOTIN DERIVATIVES WITH INTRAMOLECULAR COORDINATION (1980) (0)
BINUCLEAR METAL CARBONYL DAB COMPLEXES. 9. SYNTHESES AND X-RAY STRUCTURE OF (μ-ACETYLENE)-(Σ-N,Σ-N′,η2-C=N,η2-C=N′-GLYOXAL BIS(ISOPROPYLIMINE))(μ2-ACETYLENE)TETRACARBONYLDIRUTHENIUM. FIRST EXAMPLE OF THE 8E-DONATING DAB LIGAND (DAB = (1981) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 6. Reactions of (N,N′-Diisopropyl-1,4-diaza-1,3-butadiene)ironruthenium Hexacarbonyl with Alkynes. (1989) (0)
Organoplatinum supermolecules for gas-triggered crystalline switches (2002) (0)
STRUCTURAL CHARACTERIZATION OF SOME 2-(DIMETHYLAMINO)-METHYL SUBSTITUTED PHENYLCOPPER COMPOUNDS R4CU4, GROUP IB ORGANOMETALLIC CHEMISTRY PART 11 (1975) (0)
Synthesis and reaction chemistry of 4-nitrile-substituted NCN-pincer palladium(II) and platinum(II) complexes (NCN = [N „ C-4-C 6 H 2 (CH 2 NMe 2 ) 2 -2,6] (cid:2) ) Journal of Organometallic Chemistry (2008) (0)
Copper(I), Lithium, and Magnesium Thiolate Complexes: An Overview with Due Mention of Selenolate and Tellurolate Analogues and Related Silver( I) and Gold(I) Species (1997) (0)
Synthesis and Characterization of (2,6-Bis((dimethylamino)methyl)phenyl)tin(II) Chloride and (2,6-Bis((dimethylamino)methyl)phenyl)4-tolyltin(II), the First Example of a Mixed Diaryltin(II) Compound. (1989) (0)
and Copper(I) Bis( pyridine-2_carbaldehyde-imine) Triflate Complexes Studied in Solution by 'H, 'H-{ lo9Ag} , INEPT 15N and INEPT losAg NMR (1984) (0)
Bis{2-[(dimethylamino-?N)methyl]-benzenethiolato-?S}zinc(II) (2007) (0)
CCDC 609800: Experimental Crystal Structure Determination (2006) (0)
POLYNUCLEAR ARYL-COPPER SPECIES AND NEUTRAL ARYL-CUPRATES WITH A CHIRALX MWNMe,? oRTHosuBsr~ (1989) (0)
1,6-Addition of Organolithium Compounds to Acceptor-Substituted Enynes Catalyzed by a Copper(I) Arenethiolate. (1994) (0)
Computational study of bridge-splitting, aryl halide oxidative addition to PtII, and reductive elimination from PtIV: a route to pincer-PtII reagents with chemical and biological applications. (2021) (0)
COORDINATION AND ACTIVATION OF THE N:S BOND IN SULFURDIIMINES RN:S:NR AND SULFINYLANILINES RN:S:O BY METAL ATOMS (1980) (0)
Trapping Intermediates in Electron Transfer Reactions of Square Planar Organometallic d8 Species (1990) (0)
COORDINATION CHEMISTRY OF SULFINES. PART 4. INFLUENCE OF THE PHOSPHINE CONE ANGLE ON BOTH THE OXIDATIVE ADDITION OF CARBON-SULFUR AND CARBON-CHLORINE SIDE BONDS IN (PT0(PR3)2(XYC=S=O)) COMPLEXES AND THE (E)-(Z) ISOMERIZATION (1981) (0)
GROUP 1B ORGANOMETALLIC CHEMISTRY. PART 25. CRYSTAL AND MOLECULAR STRUCTURE OF 1,2,3;1,4,5;2,3,6;4,5,6-TETRAKIS-μ3-2-DIMETHYLAMINOPHENYL-2,5;3,4-BIS-μ2-# 4-TOLYLETHYNYL-OCTAHEDRO-HEXACOPPER(I) (1979) (0)
The Hurtley Reaction. Part 2. Novel Complexes of Disubstituted Acetylenes with Copper(I) Benzoates Having a Reactive Ortho C-Cl or C-Br Bond. X-Ray Structural Characterization of Tetrakis(2-chlorobenzoato)bis(diethyl acetylenedicarbox (1990) (0)
Self-assembly catalysis and copper reagents (1999) (0)
New Mono‐ and Tricyclopalladated Dendritic Systems with Encapsulated Catalytic Sites. (2002) (0)
PROTON NUCLEAR MAGNETIC RESONANCE AND X-RAY STUDY OF DIHEDRAL BOND ANGLES IN THE GAUCHE OCH2CH2O MOIETY OF CYCLIC 7,8-DIHYDRODIBENZO(F,H)(1,4)DIOXECIN (1978) (0)
GROUP 1B ORGANOMETALLIC CHEMISTRY. XIV. INTRAMOLECULAR RING-CLOSURE REACTIONS S OF NOVEL ARYLCOPPER COMPOUNDS RCU12. SYNTHESIS OF 7,8-DIHYDRODIBENZO(F,H)(1,4)DIOXECIN AND 7,8-DIHYDRODIBENZO-6,9-DIMETHYL(F,H)(1,4)DIAZECIN (1976) (0)
AN UNEXPECTED ETHYL TRANSFER REACTION BETWEEN DIETHYLZINC AND DI-TERT-BUTYLGLYOXALDIMINE (T-BUDAB). STUDIES OF THE PERSISTENT (ETZN(T-BUDAB)) RADICAL WHICH IS IN EQUILIBRIUM WITH ITS C-C COUPLED DIMER (1981) (0)
[2,6-Bis[(dimethylamino-kappaN)methyl]phenyl-kappaC]iodopalladium(II) bis(diiodine). (2002) (0)
REACTIONS OF SULFURDIIMINES AND SULFINYLANILINES WITH (ALME3)2 (1981) (0)
INTERACTION OF ARYLMETAL COMPOUNDS OF GROUP IB WITH COPPER(I) AND SILVER(II TRIFLUOROMETHANESULFONATE, A NOVEL BIARYL SYNTHESIS AND A ROUTE TO HEXANUCLEAR ARYL-CUAG, -AGAU, AND -CUAU CLUSTERS (1977) (0)
Synthesis and Spectroscopic Properties of CpRuCl(R-DAB(4e)) and CpRuCo(CO)3(R-DAB(6e)). Part 17. X-Ray Structure Determination of CpRuCo(CO)3(tBu-DAB(6e)). (1988) (0)
Synthesis and Properties of Trimeric Ortho-Chelated (Arenethiolato)copper(I) Complexes. (1991) (0)
Dendritic supports for non-covalent binding of homogeneous catalysts and anionic substrates (1999) (0)
By Forming Adducts with Unsaturated Hydrocarbons (2007) (0)
Development of time-resolved XAFS techniques for the in situ determination of (homogeneous) reaction intermediates (2000) (0)
Synthesis and Characterization of a Stable Bis(naphthyl)tin(II) Compound. Bis(dimethylaminonaphthyl)tin(II) and Its W(CO)5 Adduct. (1989) (0)
SYNTHESES AND NMR STUDIES OF FIVE-COORDINATE RHODIUM(I) COMPLEXES WITH α-DIIMINES (R-N:C(H)C(H):N-R): (RHCL(CO)(η2-C2H4)(α-DIIMINE)) AND (RHCL(L)2(α-DIIMINE)) (R = TERT-BU, ETME2C-; L = CO, PF3) (1982) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 4. Synthesis and Structure of Some Diiron α-Diimine Complexes Containing a Ferracyclopentadienyl System Resulting from the C-C Coupling of Two Alkynes. (1989) (0)
Design and Synthesis of Tris[bis(benzylammonium)aryl]phosphines with Bulky meta‐Substituents. (2003) (0)
"Pincer" Ligand 2,6-Bis((dimethylamino)methyl)pyridine (NNN). The X-ray Crystal Structures of (Ru(dCdCHPh)- Cl2(NNN)) and (Ru(dCdCHPh)(OTf)(NNN)(PPh3))(OTf) (OTf ) Trifluoromethane Sulfonate) (1999) (0)
Solid-state Structure of (Au~L~~(C~H~CH~N M~~-~)~): A Model for the Reactive Structure of Organocuprates (1984) (0)
SYNTHESES AND CHARACTERIZATION OF NEUTRAL COMPLEXES OF ZINC(II) WITH MONO- AND DIANIONIC PYRROLE-2-IMINE LIGANDS ((PYRROLE-2-CH:N)NR)N- (N = 1, 2) (1985) (0)
Self-assembling of bis- ortho chelated diaminobenzyl- (NC A N) and butyl-lithium units to give 2 : 2 mixed alkyllithium aggregates (NC A N)Li 2 Bu 2 Li 2 (NC A N) with a ladder structure (1996) (0)
THE REGIO- AND STEREOSPECIFIC SYNTHESIS OF DIARYLPROPENYLLITHIUM COMPOUNDS FROM DIMETHYLAMINO- AND DIMETHYLAMINOMETHYL-SUBSTITUTED DIARYLACETYLENES VIA TRANSMETALATION REACTIONS INVOLVING DIARYLPROPENYLMAGNESIUM AND -TIN COMPOUNDS (1979) (0)
Crystal Structure of Zinc(bis(3-(dimethylamino)propyl-C,N)tin)bis(dibenzoylmethanato)-(Sn-Zn). The First Example of a Dialkyltin(II) Compound Stabilized by Sn-Zn Coordination. (1990) (0)
THE REACTIONS OF 2-((DIMETHYLAMINO)METHYL)PHENYLCOPPER AND -LITHIUM TETRAMER WITH CUPROUS AND CUPRIC HALIDES, GROUP IB ORGANOMETALLIC CHEMISTRY PART 13 (1975) (0)
A Novel, Trimeric, Chiral Copper(I) Thiophenolate with Intramolecular Coordination. (1989) (0)
Computational Study of Bridge Splitting, Aryl Halide Oxidative Addition to Pt II , and Reductive Elimination from Pt IV : Route to Pincer‐Pt II Reagents with Chemical and Biological Applications (2021) (0)
Synthesis of arylplatinum(II) complexes with chiral monoanionic aryldiamine ligands.: The X-ray crystal structure of (−)-[(1R,1′R)-2,6-bis{1-(dimethylamino)propyl}phenyl]chloroplatinum(II)1Dedicated to Professor Peter Maitlis in admiration of his contributions to organometallic and homogeneous catal (1998) (0)
Arylpalladium Compounds Containing an Alcohol Functionality: Hindered Rotation around the Pd-C Bond and Reactivity toward Styrene and Carbon Monoxide (2001) (0)
Enantioselective Synthesis of a Chiral Intermediate for Aztreonam and Related Monobactam Antibiotics. (1990) (0)
A zinc mediated route from a-imino esters to b-lactams, Organometallics in organic synthesis. (1987) (0)
1:1 and 2:1 Lithium Zincates with Intramolecular Coordination. Structures of Li(thf)Zn(C 6 H 4 CH 2 NMe 2 -2) 3 and Li 2 Zn(C 6 H 4 CH 2 NMe 2 -2) 4 (1997) (0)
A 119Sn NMR study of petacoordinate triorganotin halides having intramolecular Sn-N Coordination (1991) (0)
Mono(aryl)cobalt(II) Compounds Stabilized by Bis Ortho Chelation. (1987) (0)
Synthesis of Cyclometalated Naphthylpalladium Complexes via Transmetalation Reactions of Naphthylmercury with Palladium Species. Crystal Structure Determination of ((Pd(mxn)(O2CMe))2). (1989) (0)
Stereoselective Synthesis of cis- and trans-β-Lactams via α-Amino Ester Enolates and 1-Aza-4-hetero-1,3-butadiene Systems. Molecular Structure of EtOC(O)C(H)(NEt2)C(H)(N(H)-t-Bu)(C(H)=N(t-Bu)ZnCl2): An Unexpectedly Isolated Aldolate. (1992) (0)
Synthesis of Arylzinc Thiolates Containing Perfluoroalkyl Chains. Model Catalyst Precursors for the Enantioselective Zinc‐Mediated 1,2‐Addition of Dialkylzincs to Aldehydes in Fluorous Biphase Systems. (1999) (0)
Preliminary communication SYNTHESIS OF METAL-TETRAAZADIENE COMPLEXES VIA LIGAND TRANSFER; TWO ROUTES TO NICKEL- OR PLATINUM-TETRAAZADIENE COMPLEXES [M(Ar,N,) (L),] (2000) (0)
A Homologous Series of Homoleptic Zinc Bis(1,4-di- tert-butyl-1,4-diaza-1,3-butadiene) Complexes: Kx[Zn( t-BuNCHCHN- t-Bu)2], Zn(t-BuNCHCHN- t-Bu)2, and [Zn( (1998) (0)
Asymmetric Synthesis of β‐Lactams via the Zinc‐Mediated Glycine Ester Enolate‐Imine Condensation Reaction Using α‐Amino Esters as the Chiral Auxiliary. (1995) (0)
Synthesis and Characterization of Two Isomers of Decacarbonyl(1,4-dialkyl-1,4-diaza-1,3-butadiene)triosmium: Os3(CO)10(R-DAB). Part 1. Fluxional Behavior of Os3(CO)10(iPr-DAB(4e)). Molecular Structures of the 48e Cluster Os3(CO)10(iPr (1989) (0)
BINUCLEAR METAL CARBONYL DAB COMPLEXES. 6. SYNTHESES AND SPECTROSCOPIC PROPERTIES OF MCO(CO)5(μ2-CO)(DAB) (M = MANGANESE, RHENIUM; DAB = 1,4-DIAZABUTADIENE). X-RAY STRUCTURE OF (Σ2-N,Σ2-N′,η2-C:N-(GLYOXAL BIS(TERT-BUTYLIMINE)))HEXACAR (1981) (0)
GROUP 1B ORGANOMETALLIC CHEMISTRY. 18. NOVEL ROUTES TO STABLE HEXANUCLEAR COPPER-SILVER, SILVER-GOLD, AND COPPER-GOLD CLUSTER COMPOUNDS STARTING FROM POLYMERIC 2-(DIMETHYLAMINO)PHENYLCOPPER AND FROM BIS((2-DIMETHYLAMINO)PHENYL)GOLDLIT (1977) (0)
Intramolecular Amine Coordination versus NMe C-H Activation: The Stereoselective Synthesis of a Tantala(V)azacyclopropane Complex. (1990) (0)
DIAZABUTADIENES AS LIGANDS. I. AL (1980) (0)
COORDINATION CHEMISTRY OF SULFINES. PART 5. Σ-S AND η3-SCS COORDINATION OF SULFINES TO RHODIUM(I). FLUXIONAL BEHAVIOR OF (RHCL(PR3)(XYCSO)) (R = ALKYL; X, Y = ARYL, S-ARYL, S-ALKYL, OR CL) COMPLEXES AND INFLUENCE OF SULFINE GEOMETRY O (1982) (0)
Chiral Induction in the Synthesis of 4,4-Dimethyl-1-phenylpenta-1,2-diene (1-Ph-3-tBu-Allene) Catalyzed by Chiral Phosphine Complexes of Palladium. (1990) (0)
1 Structures and Reactivities of Organocopper Compounds (2002) (0)
Communications to the Editor (1986) (0)
TRIORGANOTIN CATIONS STABILIZED BY INTRAMOLECULAR TIN-NITROGEN COORDINATION, SYNTHESIS AND CHARACTERIZATION OF (C,N,N′-2,6-BIS((DIMETHYLAMINO)METHYL)PHENYL)DIORGANOTIN BROMIDES (1978) (0)
BINUCLEAR METAL CARBONYL R-DAB COMPLEXES. PART XIII. REDUCTION OF COORDINATED D 1,4-DIAZA-1,3-BUTADIENE TO DIANIONIC 1,2-DIAMINOETHANE BY (HFE(CO)4)-. MOLECULAR STRUCTURE OF ((μ-H)FEMN(CO)6(μ,μ′-N(P-TOL)CH2CH2N(P-TOL))), A PSEUDO-SYMM (1985) (0)
XXXIII *. ArAuPPh3, ArAu(CNR), (A~Au)~ AND A.r&u~Au, COMPOUNDS IN WHICH THR ARYL GROUP CONTAINS 2-MeO, 2,6-(MeO)*, 2-Me*N, 2-Me2NCHz AND (S)- OR (R)-2-Me,NCHMe SUI3STlTURNTS AS POTENTIAL IJGANDS (1980) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 6. C-C and C-N Couplings and Alkyl C-H Activation in Reactions of (σ,σ(N,N′)-N,N′-Diisopropyl-1,4-diaza-1,3-butadiene)(μ2,η2-d# imethyl acetylenedicarboxylat (1989) (0)
COORDINATION CHEMISTRY OF SULFINES. 7. DISPLACEMENT REACTIONS OF CIS-(PT(II)CL(R′SCSO)(PR3)2) (R = PH, C6H11; R′ = ARYL) WITH NUCLEOPHILES. FORMATION WITH R′S- OF AN η2-CS COORDINATED SULFINE (R′S)2C:S:O BY REDUCTIVE COUPLING (1982) (0)
Alcohols and an unexpected dinuclear Zwitterionic Pt(II) cation [Pt2 {C6H3 (CH2NHMe2)2-2,6}2I4-]2+ from the reaction of alkyl halides with an aryl(diamine)(aquo)Pt(II) complex; X-ray and N.M.R. Studies (1989) (0)
Reactivity of Mixed Cyclometalated Palladium Compounds Containing the [2-Me2NC6H4C(H)SiMe3] Monoanion. (1986) (0)
Reactivity of Organopalladium Compounds toward Molybdenum Peroxides: Oxygen Insertion versus C-Cl and Intermediates C-0 Coupling. Evidence for Palladium( IV) Molybdate (2001) (0)
A second polymorph of 2,2'-bipyridyl-(methyl)(phenyl)palladium(II) (1996) (0)
Chemistry in a Spin: Multinuclear Resonance (1990) (0)
Electronic and Electrochemical Properties of Platinum(H) and Platinum- mercury-carboxylato Complexes Containing 2-Me2NCH&H4-, 2,6-(Me,NCH,),- C,H,- and 2-Me2NC,H,CH, Ligands (1982) (0)
ortho Metalation of m-(Me2NCH2)2C6H4: Crystal Structure and Chemistry of trans-Rh(III)Cl2(C6H3(CH2NMe2)2-o,o′)(H2O). (1988) (0)
MONOMERIC BIS(ETA 2-ALKYNE) COMPLEXES OF (ETA 1-MESITYL)COPPER(I) AND (ETA1-MESITYL)SILVER(I) OBTAINED FROM A BIS(ALKYNYL)TITANOCENES ; X-RAY STRUCTU RE OF (ETA 5-C5H4SIME3)2TI(CCSIME3)2CU(ETA 1-MES) (MES = C6H2ME3-2,4,6) (1995) (0)
FORMATION OF NOVEL PHOSPHITE METALLACYCLES VIA SELECTIVE RING OPENING OF PLATINUM(II)- OR PALLADIUM(II)-COORDINATED TRI- AND DIAZAPHOSPHOLES (1984) (0)
A Chiral Ag(I) Coordination Polymer with a Polydentate Chiral Ligand; Crystal Structure of the 1:1 Complex of CF3SO3Ag and N-(N-(5-Methylthenylidene)-L-methionyl)histamine. (1990) (0)
Diastereo- and Enantioselective Synthesis of trans-3-Phenyl- and trans- 3-Styryl-2-azetidinones via Zinc Ester Enolates and Imines. (1993) (0)
Intramolecular Facilitation of Aryl-Transfer from Tin in Palladium- Catalyzed, Cross-Coupling. (1993) (0)
PROTON AND INEPT NITROGEN-15 AND SILVER-109 NMR STUDIES OF THE STRUCTURAL AND DYNAMIC FEATURES IN SOLUTION OF SOME SILVER(I) AND COPPER(I) COMPLEXES WITH POLYDENTATE N4-DONOR LIGANDS, (RS)-1,2-(6-R-PY-2-CH:N)2CY AND 1,2-(6-R-PY-2-CH:N (1985) (0)
From the Group IB Metals and their Alloys : From the Metal Salts: the s- and h2-group IB-C bond (1988) (0)
By Metal–Metal Exchange with Another Organometallic (2007) (0)
Synthesis and Structure of a Bis-ortho-Chelated Aryllithium Compound: 2,3,5,6-Tetrakis((dimethylamino)methyl)phenyllithium Dimer. (1988) (0)
Condensation Reactions of α‐Amino Zinc Enamines with Aldehydes. Application to Indolizines. (1993) (0)
New flourous media and processes for cleaner and safer chemistry (2004) (0)
X-Ray Crystal Structure of the Ethylzinc Enolate of 1-(2,4-Cyclopentadienyl)-2-(diethylamino)-1-ethanone, the Unexpected Reaction Product from Cyclopentadienyl(ethyl)zinc and Ethyl N,N-Diethylglycinate. (1988) (0)
Synthesis of a New Multidentate Phosphane Ligand C6H2 (CH2PPh2)4-1,2,4,5 — X-Ray Structure of a Dinuclear Ruthenium(II)-Bridged Complex: [{RuCl2(PPh3)}2{C6H2 (CH2PPh2)4-1,2,4,5-P,P′,P′′,P′′′}]. (1998) (0)
Controlled and efficient synthesis of biodegradable polyesters (2005) (0)
The Oxygenation of Cyclopalladated N,N‐Dimethylbenzylamine Derivatives with tert.‐Butyl Hydroperoxide. (1991) (0)
Regioselective Introduction of Functional Groups in α-Diimines by Means of Dialkylzinc Compounds. Synthesis of Functionalized 2- and 3-Pyrrolidinone Derivatives. (1994) (0)
A New and Efficient Route to 3-Amino-2-azetidinones via Zinc Enolates of N,N-Disubstituted Glycine Esters. (1992) (0)
Homocuprate Moieties in the Neutral Mixed Cuprate [Cu2Li2(CtCR)2Ar2] (Ar ) C6H4{CH2N(Me)CH2CH2NMe2}-2; R ) C6H4Me-4 or C6H4SiMe3-4) (0)
l-tert-Butyl-2-(tert-butylamino- methylidene)-3-pyrrolidinone, Ct3H24N20 (1994) (0)
Comparative Rates of Ligand Substitution Reactions of Pt - C-Bonded Complexes in Aqueous Solution and the X-ray Crystal Structure of [Pt { C 6 H 3 (CH NMe ) -2,6 } (OH 2 )][OSO CF 3 ] (1997) (0)
By Addition, Decarboxylation (2007) (0)
A n Aryllithium Complex with Intramolecular Coordination of an o-Diamine Substituent. X-ray and Solution NMR Structures of Dimeric [Li( CsH4(CH2N(Me)CH2CH2Ne2)=2}12 (2001) (0)
By Metal—Halogen Exchange (2007) (0)
CRYSTAL AND MOLECULAR STRUCTURE OF SNMEPH(C10H5(OME-5)(CH2NME2-8))BR AND PROTON NUCLEAR MAGNETIC RESONANCE STUDY OF THE PUCKERING OF THE CHELATE RING IN FIVE-COORDINATE TRIORGANOTIN HALIDES SNRR′(C10H5(OME-5)(CH2NME2-8))X AND SNRR′(CH (1980) (0)
Synthesis and Structure of (2‐(4,4‐Dimethyl‐2‐oxazoline)‐5‐ methylphenyl)methylphenyltin Bromide. A Novel Triorganotin Halide Having a Configurationally Stable Chiral Tin Center. (1991) (0)
C—N Coupling of Nitrogen Nucleophiles with Aryl and Heteroaryl Bromides Using Aminoarenethiolato—Copper(I) (Pre-)Catalyst. (2010) (0)
Modelling the structural features of the reduced blue copper protein active site: CU(I) and AG(I) coordination complexes with chiral [N-(5-R-thienylmethylidene)-L- methionyl]-histamine ligands (1989) (0)
Synthesis and Crystal Structure of the New Mixed-Metal, Mixed-Ligand Cluster Compound Zn4Ni2(C5H5)4(C5Me5)2. (1989) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 1. Synthesis of Some Dinuclear Fe and Ru Complexes Containing an 8e Donating α-Diimine Ligand and a μ2-Bridging Alkyne; Crystal Structure of (σ,σ-N,N′,η2,η2- (1989) (0)
PHOSPHORUS COORDINATION OF DI- AND TRI-AZAPHOSPH0LF.S IN PLATINUM(O) COMPLEXES X-RAY MOLECULAR STRUCTURE OF (1983) (0)
Platinum- and Palladium-Catalyzed Kocheshkov Redistribution of Dialkyltin Dichlorides or Tetraalkyltins with Tin Tetrachloride. (2002) (0)
Cover Picture: Solid‐State Structural Characterization of Cutinase–ECE‐Pincer–Metal Hybrids (Chem. Eur. J. 17/2009) (2009) (0)
A NOVEL OLEFIN BRIDGED DINUCLEAR ARYLPALLADIUM COMPOUND. X-RAY CRYSTAL STRUCTURE OF (CYCLIC) (NME2CH2C6H4PD-μ-(C(CF3):C(CF3)C(CF3):C(CF3))PDCH(SIME3)C6H4NME2) (1985) (0)
FOUR-COORDINATE RHODIUM(I) COMPLEXES ((RH(CO)2CL)N(α-DIIMINE)) (N = 1, 2) WITH Σ,Σ-N,N′ CHELATE OR Σ-N, Σ-N′ BRIDGE BONDED RN:C(R′)C(R“):NR LIGANDS. INFLUENCE OF THE BRANCHING AT Cα OF R ON THE RHODIUM(I)-α-DIIMINE INTERACTION (1982) (0)
Reductive elimination and organohalide transfer from methyl(aryl)benzylpalladium(IV) complexes of bidentate nrogen donor ligans, PdBrMe(Ar)(CH 2 Ph)(L 2 ) (1996) (0)
SYNTHESIS OF 8‐(DIMETHYLAMINO)‐1‐NAPHTHYLLITHIUM ETHERATE: ITS STRUCTURE IN THE SOLID (X‐RAY) AND IN SOLUTION (LITHIUM‐7 AND PROTON NMR) (1983) (0)
Modular Approaches Towards Metallodendritic Homogeneous Catalysis (2003) (0)
GROUP IB ORGANOMETALLIC CHEMISTRY. XV. ARYLCOPPER COMPOUNDS ARNCUN AS INTERMEDIATES IN ORGANOMETALLIC SYNTHESIS. ONE-STEP SYNTHESIS OF TRIORGANOTIN HALIDES OF THE TYPE AR3SNX AND AR3-NRNSNX (1976) (0)
Linear homobimetallic 4-thioacetyl-substituted NCN pincer palladium(II) and platinum(II) complexes with N -bidentate connecting units (NCN = [C 6 H 2 (CH 2 NMe 2 ) 2 -2,6-R-4] (cid:2) ) (2008) (0)
HOMO- AND HETERODINUCLEAR PLATINUM AND PALLADIUM COMPLEXES WITH A SINGLE UNSUPPORTED MONOATOMIC BRIDGING GROUP. CRYSTAL STRUCTURE OF THE 2,6-BIS((DIMETHYLAMINO)METHYL)PHENYLPALLADIUM(II) DERIVATIVE ((PD(C6H3(CH2NME2)2-O,O′))2(μ-CL))BF (1982) (0)
Stereoselective One-Pot Syntheses of trans-3-Amino-β-lactams from Zinc Enolates of N-Protected α-Amino Acid Esters and Imines. (1988) (0)
An Efficient (2‐Aminoarenethiolato)copper(I) Complex for the Copper‐Catalyzed Huisgen Reaction (CuAAC). (2010) (0)
Synthesis and Characterization of Bis(arenethiolato)magnesium Complexes with Intramolecular Coordination. X-ray Structure of [Mg { S(C H -2-CH NMe ) (1997) (0)
The Unexpected Formation of trans-β-Lactams in the Reaction of α-Iminoesters (R-N=C(H)C(=O)OR′) with Diethylzinc. Crystal Structure of trans-1-(N-t-Butyl)-3-(N-t-butyl-N-ethylamino)-4-methoxycarbonylazetidin-2-one. (1987) (0)
of styrene with oxalic acid or water using pallaalum orty1o-ammo arenethiolates with intramolecular coordinating nitrogen Lewis bases (1998) (0)
XXX1 *. SYNTHESIS AND CHARACTERIZATION OF TETRANUCLEAR Me2N- AND Me2NCH,-SUBSTITUTED DIARYLPROPENYLCOPPER-COPPER ANION COMPOUNDS (VizCu4X2) CONTAINING BRIDGING PROPENYL LIGANDS. ISOLATION OF A THERMALLY STABLE MIXED DIARYLPROPENYL/ARYLCOPPER COMPOUND (Vi2Cu4Ar2) (1979) (0)
1,2-METHYL SHIFT BETWEEN PLATINUM AND THE COORDINATED ARYL GROUP IN THE REACTION OF METHYL IODIDE WITH 2,6-BIS((DIMETHYLAMINO)METHYL)PHENYL-N,N′,C COMPLEXES OF PLATINUM(II). X-RAY CRYSTAL STRUCTURE OF THE ARENONIUM-PLATINUM COMPOUND ( (1985) (0)
Conclusions and Personal Comment (2018) (0)
Versatility in Phenolate Bonding in Organoaluminum Complexes Containing Mono- and Bis-ortho-Chelating Phenolate Ligands. X-ray Structures of and (2001) (0)
Intramolecular Coordination in Organotin Chemistry. (1994) (0)
Formation of mixed aryl–, alkyl–lithium aggregates in the heteroatom assisted lithiation of α,α′-dialkyl substituted 1,3-bis[(dimethylamino)methyl]benzene1These results were presented in part at the Symposium `Frontiers in Organometallic Chemistry' at the Spring 1997 American Chemical Society meetin (1998) (0)
Synthesis of Marasln and ~-me-Ms~asfn, (Nona- and Deca6,8diyne-3,4-dlenal). (1988) (0)
SYNTHESIS AND MOLECULAR GEOMETRY OF (TRANS-PTCL2PBU3)2(DI-T-BU-DIIMINE) CONTAINING A Σ,Σ′-N,N′ BRIDGING DIIMINE WITH A PLANAR ANTI-(TRANS-P-PT-NCCN-PT-P-TRANS)-SKELETON (1980) (0)
XXIX *. SYNTHETIC AND STRUCTURAL ASPECTS OF POLYNUCLEAR ARYLCOPPERLITHIUM COMPOUNDS Ar4Cu2Li2 ("ARYLCUPRATES") AND INTERAGGREGATE EXCHANGE PHENOMENA IN Ar4CuJAr4Li4/Ar4CuzLiz SYSTEMS (1979) (0)
Mixed Metal Acetylides: The Pt II Aryl Acetylide ‘‘[PtC 6 H 2 (CH 2 NMe 2 ) 2 -2,6-(C (cid:59) C)-4]’’ as a Connective Fragment (0)
Synthesis, X-Ray Crystal Structure and Reactions of Dimethyl(N,N,N′,N′-tetramethylethanediamine)palladium. (1988) (0)
(R)‐2‐[1‐(Dimethylamino)ethyl]benzenethiol (2002) (0)
ortho‐Bis(amino)arylnickel(II) Halide Complexes Containing Perfluoroalkyl Chains as Model Catalyst Precursors for Use in Fluorous Biphase Systems. (1998) (0)
Synthesis and Catalytic Properties of Di- and Trinuclear Palladium Complexes with PCP-Pincer Ligand (2003) (0)
Chiroptical Properties and Applications in PTC of New Dendritic Cinchonidine-Derived Ammonium Salts. (2004) (0)
COPPER(I) AND SILVER(I) IONS IN UNUSUAL POLY DONOR-ATOM ENVIRONMENTS; X-RAY CRYSTAL AND MOLECULAR STRUCTURES OF (M((R)(S)-1,2-(5-ME-THIOPHENE-2-CH:N)2CYCLOHEXANE)2)(O3SCF3), M = CUI OR AGI (1983) (0)
Synthesis and Catalytic Properties of Di- and Trinuclear Palladium Complexes with PCP-Pincer Ligands. (2004) (0)
On the Way to Chiral Copper(I) Arenethiolate Catalysts for the Enantioselective Conjugate Addition of Methyl Lithium and Methyl Magnesium Iodide to Benzylideneacetone. (1992) (0)
Ruthenium Carbonyl 1,4-Diaza-1,3-butadiene (R-DAB) Complexes. Part 7. Reactivity of Ru2(CO)6 (R-DAB) Towards Hetero-allenes L (L: Carbodiimide, Sulphine), Resulting in C-C Bond Formation. X-Ray Molecular Structure of Ru2(CO)5(tBuN=CCH (1985) (0)
Catalytic Performance of Symmetrical and Unsymmetrical Sulfur‐Containing Pincer Complexes: Synthesis and Tandem Catalytic Activity of the First PCS‐Pincer Palladium Complex. (2008) (0)
REACTIONS OF STABLE DICHLOROPLATINUM η2-OLEFIN α-DIIMINE COMPLEXES. RETENTION OF THE FIVE-COORDINATE STRUCTURE UPON HALOGEN EXCHANGE AND LIGAND SUBSTITUTION WITH OLEFINS, α-DIIMINES, AND N,N′-DISUBSTITUTED 1,2-DIAMINOETHANES (1982) (0)
Hetero‐Aggregate Compounds of Aryl and Alkyl Lithium Reagents: A Structurally Intriguing Aspect of Organolithium Chemistry (2005) (0)
Synthesis and 119Sn NMR of η1-O-Coordinated Sulfine-Dimethyltin Dichloride Complexes and Thermal C=S and S=O Bond Cleavage Reactions. X-Ray Structure (130 K) of Me2SnCl2(η1-O-(Me(Ph)NC(Ph)=S=O)). (1987) (0)
Heterobimetallic Fe–Pd and Fe–Pt NCN pincer complexes (NCN = [C 6 H 2 (CH 2 NMe 2 ) 2 -2,6] (cid:2) ) (2006) (0)
1H nuclear magnetic resonance and x-ray study of dihedral bond angles in the gauche O·CH2·CH2·O moiety of cyclic 7,8-dihydrodibenzo[f,h]-[1,4]dioxecin (1977) (0)
1H NMR and X-Ray study of the dihedral bond angles in the rigid gauche -O-CH2CH2-O moiety of cyclic 7,8-dihydrodibenzo[f,h][1,4]dioxecin (1977) (0)
Chemistry of Bis(aryloxo)palladium(II) Complexes with N-Donor Ligands: Structural Features of the Palladium-to-Oxygen Bond and Formation of O - H (cid:226)(cid:226)(cid:226) O Bonds (1997) (0)
2-Carboxy-4-(hydroxymethyl)pyridinium chloride hemihydrate (2007) (0)
2,6-Bis(oxazolinyl)phenylnickel(II) Bromide and 2,6-Bis(ketimine)phenylnickel(II) Bromide: Synthesis, Structural Features, and Redox Properties g (0)
Electronic and Electrochemical Properties of Platinum(II) and Platinum-mercurycarboxylato Complexes Containing 2-Me2NCH2C5H4-, 2,6-(Me2NCH2)2C6H3- and 2-Me2NC6H4CH, Ligands. (1982) (0)
Apparatus for sampling air and moisture sensitive single crystals for X-ray analysis (1973) (0)
GROUP IB ORGANOMETALLIC CHEMISTRY. XXIII. REACTIONS OF AR4CU2LI2 AND AR4AU2LI2 WITH RHODIUM(I) COMPLEXES- SYNTHESIS OF 2-((DIMETHYLAMINO)METHYL)PHENYLRHODIUM DICARBON MONOXIDE, AND ELECTRON-TRANSFER INDUCED SELECTIVE FORMATION OF DIAR (1978) (0)
Monodentate-N Coordination of 1-Aza-4-oxo-1,3-butadienes (1986) (0)
Aminoarenethiolato—Copper(I) as (Pre-)Catalyst for the Synthesis of Diaryl Ethers from Aryl Bromides and Sequential C—O/C—S and C—N/C—S Cross Coupling Reactions. (2011) (0)
1,2-Methyl Shift between Pt and the Coordinated Aryl Group in the Reaction of Methyl Iodide with (1985) (0)
Syntheses and Characterization of Dinuclear Palladium and Platinum Complexes with a Single Unsupported Bridging Group. Crystal Structure of ((C6H3(CH2NMe2)2-o,o′)Pd(μ-Cl)Pd(C6H3(CH2NMe2)2-o,o′))BF4. (1987) (0)
SYNTHESIS AND CHARACTERIZATION OF 1-IMINOPROPAN-2-ONE AND 2-IMINOBUTAN-3-ONE COMPOUNDS, RC(O)C(NR′)R′ (1978) (0)
Coordination Chemistry of Sulphines. Part IV. Influence of the phosphine cone angle on both the oxidative addition of C-S and C-Cl side bonds in [Pt0(PtR3)2(XYC=S=O)] complexes and the (E)-(Z) isomerization (1981) (0)
SO 2-binding properties of cationic g 6 , g 1-NCN-pincer arene ruthenium platinum complexes : spectroscopic and theoretical studies † (2011) (0)
Development of periphery palladated dendrimers (1999) (0)
BINUCLEAR METAL CARBONYL DAB COMPLEXES. III. ACTIVATION OF A CARBON-NITROGEN DOUBLE BOND IN RU2(CO)6(DAB) COMPLEXES (DAB = 1,4-DIAZABUTADIENE). CARBON-CARBON BOND FORMATION BETWEEN TWO DAB LIGANDS (1980) (0)
Synthesis of some Dinuclear Fe and Ru Complexes Containing an 8e Donating wEirnine Ligand and a PTBridging Alkyne; Crystal Structure of ,4-Diisopropyl-1 Tetracarbonyl D&iron* (2000) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 5. Reversible C-C Coupling Reactions Between Alkynes and CO Ligands on Diiron α-Diimine Complexes. (1989) (0)
Thermally Stable Aryltungsten(V1) Oxo and Phenylimido Complexes Containing Phenyl Ligands with ortho-Chelating Tertiary Amine Substituents: Molecular Structures (2001) (0)
GROUP IB ORGANOMETALLIC CHEMISTRY. XIX. SYNTHESIS AND CHARACTERIZATION OF MIXED-ORGANOCOPPER CLUSTER COMPOUNDS R4R′2CU6 CONTAINING ARYL AND ACETYLIDE LIGANDS (1977) (0)
Preliminary communication Carbonylation of diamino-ligated methylpalladium(IIj methoxide complexes (1995) (0)
Syntheses and Characterization of Neutral Complexes of Zn(I1) with Mono-and Dianionic Pyrrole-Zimine Ligands (pyrrole-2-CH=N),-RI”-(n = 1,2) (2000) (0)
a redetermination at 110 K (2005) (0)
The Synthesis of 3-Alkyl- and 3-Aryl-β-lactams from Zinc Enolates and Imines. (1995) (0)
NCN-Pincer Organometallics in Bioorganometallic Chemistry (2019) (0)
From the Metal Salts (2007) (0)
P′CP′-Pincer Palladium Complex-Catalyzed Allylation of N,N-Dimethylsulfamoyl-Protected Aldimines. (2009) (0)
Syntheses and NMR Studies of Five-co-ordinate Rhodium(I) Complexes with cy-Diimines (R-N=C( H)C( H)=N-R): ( RhCI( C0)(q2-C2H,)(adiimine)) and ( Rla L),(~ iimine)) (R = t-Bu, EtMe,C-; L = CO, PF,) (1981) (0)
Tuning of Tantalum Alkylidene Reactivity with a Terdentate Aryl Amine Ligand: Synthesis, Structure and Reactivity of (TaCl2(C6H3(CH2NMe2)2-2,6)(CHtBu)). (1990) (0)
CHARACTERIZATION OF SOLUBLE B (1978) (0)
INTER- AND INTRAMOLECULAR LIGAND EXCHANGE AND REARRANGEMENT REACTIONS OF TETRAAZADIENE COMPLEXES OF NICKEL, PLATINUM, AND COBALT (1982) (0)
OXIDATIVE-ADDITION REACTIONS OF CYCLOMETALATED PLATINUM(II) COMPOUNDS WITH MERCURY(II) CARBOXYLATES. X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF RAC-(A-(μ-MECO2)-CF,DE-(2-ME2NCH2C6H4)2PTHG(O2CME)) (1982) (0)
Carbon-Oxygen Bond Formation at Metal(IV) Centres: Reactivity of Palladium(II) and Platinum(II) Complexes of the 'NCN-Pincer' LIgand Toward Idomethane and Dibenzoyl Peroxide (2003) (0)
{4-Allyloxy-2,6-bis[(dimethylamino)methyl]phenyl-κ3C1,N,N'}iodidopalladium(II) (2007) (0)
Reactions of Dinuclear Metal Carbonyl α-Diimine Complexes with Alkynes. Part 8. Reactions of the Homo- and Heterodinuclear Complexes M2(CO)6(N,N′-diisopropyl-1,4-diaza-1,3-butadiene) (M2: Fe2, FeRu, Ru2) with (N,N-Diethylamino)-1-prop (1989) (0)
Influence of Bulky Substituents on the Regioselective Group-Transfer Reactions of Diorganozinc Compounds with N,N′-Bis(2,6-di- isopropylphenyl)-1,4-diaza-1,3-butadiene. (1994) (0)
2,4,6-Triisopropylphenylcopper, a Novel Tetranuclear Organocopper Aggregate with Asymmetrically Bridging, σ,π Bound Aryl Ligands. (1989) (0)
DINUCLEAR SILVER(I) AND COPPER(I) COMPLEXES WITH NEUTRAL N2S2 DONOR LIGANDS AND THEIR REACTIVITIES TOWARDS CARBON MONOXIDE. STRUCTURES IN SOLUTION (PROTON AND INEPT SILVER-109 NMR) AND IN THE SOLID (X-RAY) O (AG2(μ-(R)(S)-1,2-(THIOPHE (1985) (0)
I. A 13C and 'Li NMR study of phenyllithium and some methyl-substituted phenyllithium derivatives (1988) (0)
A New Class of Organocopper and Organocuprate Compounds Derived from Copper(I) Arenethiolates. (1992) (0)
Zelf-assemblage katalyse en koper-reagentia (1999) (0)
I. COMPOUNDS OF ALUMINIUM: COORDINATION OF DIAZABUTADIENES TO Al(CH& AND SUsSEQUENT INTRKvIOLECULAR INSERTION AND REARRANGEMENT REACTIONS LEADING TO (1979) (0)
FORMATION BETWEEN 2-(DIMETHYLAMINO)-PHENYLCOPPER WITH COPPER(I) OR SILVER HALIDES. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF HEXANUCLEAR (2-Me2NC6H4)4Cu6_nMnX2 (M = Cu OR Ag) CLUSTER COMPOUNDS (2000) (0)
(2‐Acetylbicyclo[2.2.1]heptyl‐C3,O)(2,2'‐bipyridyl)palladium(II) Trifluoromethanesulfonate 0.5‐Diethyl Ether Solvate (1995) (0)
COORDINATION CHEMISTRY OF SULFINES. 3. OXIDATIVE ADDITION OF THE CARBON-CHLORINE BOND OF (E)-(RS)CLCSO TO TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0) AND OF A CARBON-SULFUR BOND IN (PT(PPH3)2((RS)2CSO)) BY AN INTRAMOLECULAR PROCESS. X-RAY (1981) (0)
SYNTHESIS AND PROPERTIES OF SOME 2-(DIMETHYLAMINO)-METHYL SUBSTITUTED ARYLCOPPER COMPOUNDS, GROUP IB ORGANOMETALLIC CHEMISTRY PART 10 (1975) (0)
AN EXTRAORDINARY LARGE QUADRUPOLE SPLITTING OBSERVED IN A GOLD1(d10) COMPOUND (1976) (0)
Homogeneous catalysis in the interior of dendrimers (2000) (0)
er Compounds Starting from (1977) (0)
Fluxionality and Bonding in Formamidine and Formamidinate Complexes of Pt(II) and Pd(II) Containing the 2,6-Bis[(dimethylamino)methyl]phenyl Ligand: A Proton NMR Study with X-Ray Crystal Structures of [Pt{C6H3(CH2NMe2)2-2,6}{p-MeC6H4N (1986) (0)
Fluorous Palladium Complexes for Carbonylation Reactions of Alkenes and Alkynes (2000) (0)
@ EXsevier Sequdia.S.A;, Lausanne - Printed in The Netherlands (1978) (0)
Ring-Opening Metathesis Polymerization of Norbornene Catalyzed by a Ru(II)-Vinylidene Complex. (2010) (0)
Novel Organomanganese(II) Complexes Active as Homogeneous Catalysts in Manganese(II)/Copper(I)‐Catalyzed Carbon‐Carbon Bond Formation Reactions. (1997) (0)
Synthesis and properties of novel organozinc enolates of N, N-disubstituted glycine esters. Molecular structure of [cyclic][EtZnOC(OMe):C(H)N(tert-Bu)Me]4 [Erratum to document cited in CA115(15):159303r] (1991) (0)
SYNTHESIS AND SPECIFIC INTRAMOLECULAR C‐C‐COUPLING REACTIONS OF NOVEL HEXANUCLEAR COPPER CLUSTER COMPLEXES AR4R2CU6 (1974) (0)
SYNT~SrS OF S~D~ETHYL~~O)-l-N~~H~LIT~~ ETHERATE: ITS STRUCTURE IN THE SOLID (X-RAY) AND IN SOLUTION (‘Li AND ‘H NMR)* (2001) (0)
Anchoring of transition metal complexes on (soluble) supports: application of new catalytic systems in organic synthesis (2003) (0)
Pincer-porphyrin hybrids: metalloporphyrins as catalyst modulating substituents (2001) (0)
The Crystal Structure of Dicyclopentadienylmercury. (1988) (0)
RUTHENIUM CARBONYL 1,4-DIAZA-1,3-BUTADIENE COMPLEXES. PART 6. RUTHENIUM CARBONYL 1,4-DIAZA-1,3-BUTADIENE (R-DAB) REACTION SEQUENCE. REVERSIBLE CARBONYL ADDITION TO A TRINUCLEAR SPECIES WITHOUT RUPTURE OF A METAL-METAL BOND. MOLECULAR (1985) (0)
STABLE I&DIAZA-1,3-BUTADIENE(a-DIIMlNE)-ZINC AND -ALUMINIUM RADICALS FORMED IN SINGLE ELECTRON TRANSFER REACTIONS: (1983) (0)
Complexes Containing the (S)- or (I?)-( 2-NMe2C6H4CH(SiMe,)) Monoanion.' Molecular Structure of 12-( I-( S )-( Dimethylamino)ethyl)phenyl)( 24 dimethylam1no)-a- (trimethylsilyl) benzyl)palladium( I I) Atom. Facile Isolation of Optically Active Cyclopalladated (1987) (0)
Correction to NCN-Pincer Metal Complexes (Ti, Cr, V, Zr, Hf, and Nb) of the Phebox Ligand (S,S)-2,6-Bis(4′-isopropyl-2′-oxazolinyl)phenyl (2011) (0)
The first example of a dialkyltin ( I 1 ) compound stabilized by Sn-Zn coordination (2001) (0)
Isolation and Crystal Structure (130 K) of the First Example of an q'-0 coordinated Sulphine-Metal Complex: SnMe2C12(q1-0-{Me(Ph)NC(Ph)=S=O} ) (1985) (0)
Structure and Properties Complexes with Amine Donors: Effect of Hydrogen Bonding on (1992) (0)
Enantioselective Synthesis of 3-Amino-2-azetidinones via the Ester Enolate-Imine Condensation. (1992) (0)
DETERMINATION BY MICROWAVE TITRATION OF THE STOICHIOMETRY OF PHOSPHINE AND AMINE COMPLEXES OF CUPROUS TRIFLUOROMETHANESULFONATE (COPPER TRIFLATE) (1977) (0)

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