Geoffrey Cloke
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British chemist
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Geoffrey Clokechemistry Degrees
Chemistry
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Inorganic Chemistry
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Chemistry
Geoffrey Cloke's Degrees
- PhD Chemistry University of Sussex
- Bachelors Chemistry University of Sussex
Why Is Geoffrey Cloke Influential?
(Suggest an Edit or Addition)According to Wikipedia, Geoffrey Nethersole Cloke FRS is a British chemist, and professor at University of Sussex. Honours and awards 1988 Corday-Morgan Prize of the Royal Institute of Chemistry1998 Tilden Prize of the Royal Institute of Chemistry2007 Elected Fellow of the Royal Society
Geoffrey Cloke's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Reductive Cyclotrimerization of Carbon Monoxide to the Deltate Dianion by an Organometallic Uranium Complex (2006) (220)
- Mechanistic studies on the reductive cyclooligomerisation of CO by U(III) mixed sandwich complexes; the molecular structure of [(U(eta-C8H6{Si(i)Pr3-1,4}2)(eta-Cp*)]2(mu-eta1:eta1-C2O2). (2008) (125)
- Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex. (2002) (124)
- Zero oxidation state compounds of scandium, yttrium, and the lanthanides (1993) (122)
- Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation. (2004) (119)
- Reductive Cyclotetramerization of CO to Squarate by a U(III) Complex: The X-ray Crystal Structure of [(U (η-C8H6{SiiPr3-1,4}2)(η-C5Me4H)]2(μ-η2: η2-C4O4) (2006) (117)
- Unexpected reactivity of two-coordinate palladium carbene complexes; synthetic and catalytic implications (2001) (110)
- Reductive Cleavage of Dinitrogen by a Vanadium Diamidoamine Complex: the Molecular Structures of [V(Me3SiN\{CH2CH2NSiMe3\}2)( m -N)]2 and K[V(Me3SiN\{CH2CH2NSiMe3)2) m -N)]2 (1999) (109)
- Synthetic, structural, and mechanistic studies on the oxidative addition of aromatic chlorides to a palladium (N-heterocyclic carbene) complex: relevance to catalytic amination. (2003) (103)
- The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring (1996) (103)
- Suzuki–Miyaura cross-coupling of aryl and alkyl halides using palladium/imidazolium salt protocols (2004) (101)
- Metal vapor synthesis as a straightforward route to group 10 homoleptic carbene complexes (1999) (91)
- The organometallic chemistry of pentalene (2006) (91)
- Tuning the reactivity of dirhodium(II) complexes with axial N-heterocyclic carbene ligands: the arylation of aldehydes. (2007) (90)
- An experimental and theoretical investigation of the electronic structure of Pd and Pt bis(carbene) complexes (1997) (87)
- Lipophilic strontium and calcium alkyls, amides and phenoxides; X-ray structures of the crystalline square-planar [{trans-Sr(NR′2)2(µ-1,4-dioxane)}∞] and tetrahedral [CaR2(1,4-dioxane)2]; R′= SiMe3, R = CH(SiMe3)2] (1991) (83)
- Synthesis and Characterization of the First Sandwich Complex of Trivalent Thorium: A Structural Comparison with the Uranium Analogue (1999) (72)
- An improved synthesis of bis(1,3-di- N - tert -butylimidazol-2-ylidene)palladium(0) and its use in C–C and C–N coupling reactions (2001) (72)
- The first example of simple oxidative addition of an aryl chloride to a discrete palladium (n-heterocyclic carbene) amination precatalyst (2002) (70)
- Axial coordination of NHC ligands on dirhodium(II) complexes: generation of a new family of catalysts. (2008) (69)
- Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes (2013) (67)
- On the efficiency of two-coordinate palladium(0) N-heterocyclic carbene complexes in amination and Suzuki–Miyaura reactions of aryl chlorides (2005) (64)
- Facile conversion of CO/H2 into methoxide at a uranium(III) center. (2011) (58)
- Novel zirconium complexes derivedfrom C2-symmetric diamide ligands; the X-ray crystal structure of [Zr(η1-CH2Ph)(η2-CH2Ph){(C6H3)2-2,2′-(NCH2C6H4Ph-4)2-6, 6′-Me2}] (1996) (57)
- Metal−Ligand Bonding and Bonding Energetics in Zerovalent Lanthanide, Group 3, Group 4, and Group 6 Bis(arene) Sandwich Complexes. A Combined Solution Thermochemical and ab Initio Quantum Chemical Investigation (1996) (54)
- Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes** (2015) (54)
- On the stability and bonding in bis(η-arene)ianthanide complexes (1989) (48)
- U(III)-induced reductive co-coupling of NO and CO to form U(IV) cyanate and oxo derivates. (2010) (45)
- The first stable scandocene: synthesis and characterisation of bis(η-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)scandium(II) (1998) (45)
- Synthesis of bis(η-1,3,5-tri-t-butylbenzene) sandwich complexes of yttrium(0) and gadolinium(0); the X-ray crystal structure of the first authentic lanthanide(0) complex, [Gd(η-But3C6H3)2] (1987) (45)
- Synthesis of zerovalent bis(η-arene) compounds of zirconium, hafnium, niobium, tantalum, and tungsten using the metal vapours (1981) (45)
- Stabilization of low-oxidation-state early transition-metal complexes bearing 1,2,4-triphosphacyclopentadienyl ligands: structure of [[Sc(P3C2tBu2)2]2]; ScII or mixed oxidation state? (2003) (44)
- Cerium(III) and Cerium(IV) Bis(η8-pentalene) Sandwich Complexes: Synthetic, Structural, Spectroscopic, and Theoretical Studies (2007) (44)
- The First Delocalized Phosphole Containing a Planar Tricoordinate Phosphorus Atom: 1-[Bis(trimethylsilyl)methyl]-3,5-bis(trimethylsilyl)-1,2,4-triphosphole. (1998) (43)
- Organometallic pentalene complexes (2001) (43)
- Titanium(IV) complexes incorporating the aminodiamide ligand [(SiMe3)N CH2CH2 N(SiMe3)]2−(L) ; the X-ray crystal structures of [TiMe2(L) ] and [TiClCH(SiMe3)(L)] (1995) (42)
- Electronic structure of [U2(µ2-N2)(n5-C5Me5)2(n8-C8H4(SiPri3)2)2] (2004) (41)
- Trimethylsilyl derivatives of cyclooctatetraene (1993) (41)
- Scandium, yttrium, uranium, and thorium derivatives of the 1,4-bis(trimethylsilyl)cyclo-octatetraene dianion; the X-ray crystal structure of [Sc2(η-C8H6{1,4-(SiMe3)2})2(µ-Cl)2(µ-thf)](thf = tetrahydrofuran) (1989) (40)
- Activation of Small Molecules by U(III) Cyclooctatetraene and Pentalene Complexes (2008) (39)
- Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U(III) complex. (2009) (39)
- Electron spin resonance and photoelectron studies of neutral bis(.eta.-arene)metal compounds (metal = Ti, V, Nb, Ta, Mo, and W) (1983) (38)
- Anti-Bimetallic Complexes of Divalent Lanthanides with Silylated Pentalene and Cyclooctatetraenyl Bridging Ligands as Molecular Models for Lanthanide-Based Polymers (2009) (38)
- Organo-f-element bonding energetics. Large magnitudes of metal arene bond enthalpies in zero-valent lanthanide sandwich complexes (1992) (37)
- Hexakis(trimethylphosphine)molybdenum chemistry: dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives (1985) (37)
- (Phosphacyclopentadienyl)indium(I) Derivatives: Synthesis and X-ray Crystal Structure of [In(η5-P3C2But2)] (1999) (37)
- Activation of P4 by U(η5-C5Me5)(η8-C8H6(SiiPr3)2-1,4)(THF); the X-ray structure of [U(η5-C5Me5)(η8-C8H6(SiiPr3)2-1,4)]2(μ-η2:η2-P4) (2011) (36)
- Steric control of redox events in organo-uranium chemistry: synthesis and characterisation of U(v) oxo and nitrido complexes (2016) (36)
- Synthesis and CO2 Insertion Chemistry of Uranium(IV) Mixed-Sandwich Alkyl and Hydride Complexes (2013) (36)
- Zirconium complexes incorporating the new tridentate diamide ligand [(Me3 Si)N{CH2CH2N(SiMe3)}2]2–(L); the crystal structures of [Zr(BH4)2L] and [ZrCl{CH(SiMe3)2}L] (1995) (35)
- Bonding in pentalene complexes and their recent applications (2017) (35)
- Development of a practical Buchwald-Hartwig amine arylation protocol using a conveniently prepared (NHC)Pd(R-allyl)Cl catalyst. (2008) (35)
- Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation (2003) (33)
- The first structurally authenticated divalent lanthanide stannyl derivative (1991) (33)
- Bis(η-pentamethylcyclopentadienyl) complexes of molybdenum, tungsten and rhenium via metal vapour synthesis (1991) (32)
- Computational insight into the reductive oligomerisation of CO at uranium(III) mixed-sandwich complexes. (2012) (31)
- The Reductive Activation of CO2 Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies (2015) (31)
- Decamethylrhenocene, (.eta.5-C5Me5)2Re (1988) (31)
- Synthesis and Characterization of the First Compounds Containing a Stable Phosphirenyl Cation: Crystal and Molecular Structure of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)W(CO)5]† (1994) (31)
- Trialkylsilyl-substituted pentalene ligands (2000) (31)
- Reduction of carbon monoxide by binuclear tantalum hydride complexes (1983) (31)
- η-Arene complexes of scandium(0) and scandium(II) (1991) (31)
- Yttrium complexes incorporating the chelating diamides [ArN(CH2)xNAr]2- (Ar = C6H3-2,6-iPr2, x= 2, 3) and their unusual reaction with phenylsilane. (2004) (31)
- Alkylpalladium N-Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties (2008) (30)
- Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR')(mu-I)2]3(mu3-O) (CpRR' = C5Me5, C5Me4H, C5H4SiMe3). (2008) (30)
- Synthesis and X-ray crystal structure of the first homoleptic main group diazadiene complex, bis(1,4-di-t-butyl-1,4-diazabuta-1,3-diene) gallium (1989) (30)
- The first structurally authenticated zerovalent heteroarene complexof a lanthanide; synthesis and X-ray structure ofbis(2,4,6-tri-tert-butyl- phosphorin)holmium(O) (1997) (29)
- Mn2 bis(pentalene): a mixed-spin bimetallic with two extremes of bonding within the same molecule. (2007) (29)
- A Dichromium(II) Bis(η8-pentalene) Double-Sandwich Complex with a Spin Equilibrium: Synthetic, Structural, Magnetic, and Theoretical Studies (2008) (28)
- Synthesis, magnetic susceptibility and X-ray crystal structure of (tBuNCHCHNtBu)3Yb (1995) (28)
- A Non-Metallocene Hydride of Titanium(III) (1999) (27)
- Bis(pentalene)di-titanium: a bent double-sandwich complex with a very short Ti-Ti bond. (2013) (27)
- Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand (2017) (27)
- Remarkable Transformation of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-Tri-tert-butyl-1,3-diphosphacyclopentadienide Anion (2000) (26)
- Synthesis, crystal structures and some reactions of zero-valent tris[bis-1,2-(dimethylphosphino)ethane]derivatives of chromium, molybdenum, tungsten, vanadium, niobium and tantalum (1984) (26)
- Co-condensation of molybdenum atoms with the bulky tertiary diphosphine 1,2-bis(di-isopropylphosphino)ethane: the molecular structure of [MoH4(Pri2PCH2CH2PPri2)2] (1988) (26)
- Studies on high-temperature amination reactions of aromatic chlorides using discrete Palladium-N-Heterocyclic Carbene (NHC) complexes and in situ palladium/imidazolium salt protocols (2004) (25)
- Bonding in Bis(pentalene)dimolybdenum: Density Functional Calculations on Mo2(C8H6)2 and Photoelectron Spectroscopy of Mo2(C8H4(1,4-SiPri3)2)2 (1999) (25)
- Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex. (2014) (24)
- Theoretical investigation of the pathway for reductive cleavage of dinitrogen by a vanadium diamidoamine complex (2000) (24)
- Metal vapour synthesis of phospha-organometallic compounds via reaction of cobalt atoms with the phospha-alkyne tBuC☰P: synthesis and structural characterisation of the sandwich compounds [Co(η5-P3C2tBu2)(η4-P2C2tBu2)], [Co(η5-P2C3tBu3)(η4-P2C2tBu2)] and the protonated tetraphospha-barrelene complex (2001) (24)
- Single-molecule magnet properties of a monometallic dysprosium pentalene complex. (2018) (24)
- Synthesis of Tris(tetramethylcyclopentadienyl) Derivatives of the Actinide Metals: Molecular Structure of [UCl(.eta.-C5Me4H)3] (1994) (23)
- Cycloaddition reactions of the titanium imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe 3)2}(py)] with ButCP and MeCN (2000) (23)
- The first mononuclear η8-coordinated pentalenecomplex: synthesis and molecular structure of[Ta{η8-C8H4(SiMe3)2-1,4}Cl3] (1997) (23)
- Homoleptic diazadiene complexes of titanium, yttrium, and some lanthanoid elements (1986) (22)
- 1,4-Bis(trimethylsilyl)but-2-ene-1,4-diyl Complexes of Lithium, Magnesium, Aluminum, and Gallium (1995) (22)
- Synthesis and Reactivity of a Mixed-Sandwich Uranium(IV) Primary Amido Complex (2015) (21)
- Synthesis, structure and reactivity of the hexaphospha-titanocene, bis-(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)titanium(II) (1999) (21)
- Reductive coupling of carbon monoxide by U(III) complexes--a computational study. (2011) (21)
- Synthesis of zerovalent bis-areneniobium compounds using niobium vapour (1978) (20)
- A study of the molecular and electronic structure of iron(II)and ruthenium(II) 1,3-di- and 1,2,4-tri-phospholyl sandwich compoundsby photoelectron spectroscopy and density functional theory (2001) (20)
- Photoelectron spectroscopy and electronic structure of the hexaphosphatitanocene [Ti(η5-P3C2But2)2] (2000) (20)
- A study of the molecular and electronic structures of the indium(I) phospholyls [In(η5-P2C3But3)] and [In(η5-P3C2But2)] by X-ray diffraction, photoelectron spectroscopy and density functional theory (2000) (19)
- Synthesis of zerovalent bis-(η-arene)(trimethylphosphine)-hafnium and -zirconium compounds using metal vapours (1979) (19)
- Electronic structure and photoelectron spectroscopy of Al(Me3CNCHCHNCMe3)2 and Ga(Me3CNCHCHNCMe3)2 (1991) (19)
- Synthesis and Molecular Structures of Uranium and Thorium Diamidoamine Complexes (2003) (19)
- Electronic structure and photoelectron spectra of bispentalene complexes of thorium and uranium (1999) (19)
- Synthetic, structural and theoretical studies on new aromatic 1,2,4-azadiphosphole ring systems: crystal and molecular structure of P2C2But2NPh (1999) (18)
- Arene–tungsten chemistry: bis(arene)tungsten hydride derivatives; co-condensation of tungsten atoms from an electron gun source with aromatic hydrocarbons (1978) (18)
- Direct detection of individual bis(arene) rotational isomers in the gas phase by mass-analyzed threshold ionization spectroscopy. (2007) (17)
- Bonding in Complexes of Bis(pentalene)dititanium, Ti2(C8H6)2 (2015) (17)
- Yttrium iodide and bis(trimethylsilyl)methyl complexes of the chelating diamide [ArN(CH2)3NAr]2- (Ar = 2,6-iPr2C6H3) (2002) (17)
- Synthesis and molecular structure of tris(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)molybdenum(0) (1994) (17)
- Synthesis and structure of the first η6-pyrazine complex [V(η6-Me4pyrazine)2] and related studies (1993) (17)
- Titanium and niobium imido complexes derived from diamidoamine ligands. (2000) (17)
- Mononuclear tantalum (V) pentalene complexes: synthesis of [Ta{η8-C8H4(1,4-SiiPr3)2}X3] (X = CH3, Cl, I) and the X-ray crystal structures of [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)3], [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)2Cl], [Ta{η8-C8H4(1,4-SiiPr3)2}(CH3)Cl2] and [Ta{η8-C8H4(1,4-SiiPr3)2}I3] (2004) (16)
- Double-Sandwich Pentalene Complexes M2(pent†)2 (M = Rh, Pd; pent† = 1,4-Bis(triisopropylsilyl)pentalene): Synthesis, Structure, and Bonding (2012) (16)
- Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity. (2015) (16)
- Synthesis and reactivity of alkyl-palladium N-heterocyclic carbene complexes. (2007) (16)
- Activation of carbon dioxide by new mixed sandwich uranium(III) complexes incorporating cyclooctatetraenyl and pyrrolide, phospholide, or arsolide ligands (2015) (16)
- Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)}2]2– [N{N″}2]2–. Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N″}2)}2(µ-H)2] (1999) (16)
- Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study. (2014) (15)
- Studies on Pd/imidazolium salt protocols for aminations of aryl bromides and iodides using lithium hexamethyldisilazide (LHMDS) (2005) (15)
- Molecular and electronic structures of bis[1,4-bis(trimethylsilyl)cyclooctatetraene] sandwich complexes of titanium and zirconium (1994) (15)
- Synthesis of bis(η-1,3,5-tri-t-butylbenzene) sandwich complexes of titanium, zirconium, and hafnium, and of the hafnium(0) carbonyl complex [Hf(η-But3C6H3)2(CO)] (1987) (15)
- Synthesis, crystal and molecular structures of the novel, structurally different, cage compounds P6C4But4SiI2 and P6C4But4GeI2, resulting from intra-molecular coupling of two 1,2,4-triphospholyl rings (2000) (15)
- Synthesis and structural characterisation of lanthanide and actinide phosphaorganometallic complexes derived from the 3,5-di-tert-butyl-1,2,4-triphospholyl ring anion, P3C2But−2: Crystal and molecular structures of [M(η5-P3C2But2)2(η2-P3C2But2)] (M = Sc, Y, Tm, and U) (2008) (15)
- Synthesis, characterisation and fluxional behaviour of [Ni(η5-P2C3Bu3t) (η3-P2C3Bu3t)] (1995) (15)
- Samarium(III) Pentalene Sandwich Compounds [Sm(η8-C8H4{SiiPr3-1,4}2)(Cp*)] and [Sm(η8-C8H4{SiiPr3-1,4}2)(η5-C8H5{SiiPr3-1,4}2)] and a Mixed-Valence Hexasamarium Cluster Derived from Sm(II)-Based Solvent Activation (2008) (15)
- Reactions of tBuC≡P with cyclooctatetraene-supported titanium imido complexes (2006) (14)
- Carbon–Silicon Bond Activation by [Pd(ItBu)2] – the Molecular Structures of [Pd(Me3Si)(ItBu)(μ-I)]2 and [Pd(CH2ItBu)I2] (2009) (14)
- The First Example of the Two‐Electron Reduction of a Phosphaalkyne – Synthesis and Structural Characterisation of the Diuranium(IV) Pentalene Complex [(U{η5‐C5Me5}{η8‐C8H4(SiiPr3‐1,4)2})2(μ‐η2:η1‐tBuCP)] (2013) (14)
- Synthesis, spectroscopic properties and molecular structure of the paramagnetic complex [(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)]vanadium(II) (1995) (14)
- Oxidation and reduction chemistry of bis(η-arene)niobium compounds; the X-ray crystal structure of bis(η-toluene)(trimethylphosphine)niobium tetrafluoroborate (1988) (13)
- One- and two-step [2 + 2] cycloaddition reactions of group 4 imides with the phosphaalkyne ButCP. Crystal and molecular structures of [Zr(η5-C5H5)2(PCButNC6H3Me2-2,6)] and [TiCl2(P2C2But2NBut)(py)] (py) = pyridine) (1999) (13)
- Syntheses of complexes containing the novel 1,2,3-azadiphosphole and 1,2,5-azadiphosphole ring systems: crystal and molecular structure of [Ir(η5-C5Me5)(η4-(ButCPNButPCBut)] (2000) (13)
- Ethene Activation and Catalytic Hydrogenation by a Low-Valent Uranium Pentalene Complex. (2019) (13)
- Activation of linear and cyclic saturated hydrocarbons involving arene–rhenium compounds: crystal structure of µ-dihydrido-µ-neopentylidene-bis(η-benzene)-dirhenium (1984) (13)
- Zero kinetic energy spectroscopy: mass-analyzed threshold ionization spectra of chromium sandwich complexes with alkylbenzenes, (η(6)-RPh)(2)Cr (R = Me, Et, i-Pr, t-Bu). (2010) (13)
- Reactivity of a Dititanium Bis(pentalene) Complex toward Heteroallenes and Main-Group Element–Element Bonds (2017) (13)
- Sterically encumbered mixed sandwich compounds of uranium(III): Synthesis and reactivity with small molecules (2017) (13)
- Novel zirconium borohydride complexes: syntheses and molecular structures of [Zr(.eta.-C8H6(SiMe3)2)(.eta.3-BH4)(.eta.2-BH4)] and [(.eta.-C8H6(SiMe3)2)Zr(.mu.-.eta.6:.eta.4-C8H6(SiMe3)2)(.mu.-H)Zr(.eta.3-BH4)] (1995) (13)
- Bis(η-cyclopentadienyl)molybdenum chemistry: synthesis and reactions of ring-functionalised compounds (1983) (13)
- Synthesis of chromium(0) and molybdenum(0) bis (η6-arene) derivatives and their monoelectronic oxidation to [M(η6-arene)2]+ cations (2006) (13)
- Electrical double layer perturbation by light absorption at the interface (1974) (12)
- Vibrational and electronic structure of the dinuclear bis(mu-nitrido) vanadium(v) complex [V(N{N"}2)(mu-N)]2: spectroscopic properties of the M2(mu-N)2 diamond core. (2005) (12)
- Synthesis and X-ray crystal structure of the ring-functionalised bis-η-cyclopentadienylmolybdenum compound [Mo(η-C5H4CH2CH2I)2I2] and of [Mo(η-C5H4CH2CH2)2] (1981) (12)
- Tris(pyrazolyl)borate half-sandwich complexes of trivalent uranium incorporating the [C8H6{SiiPr3-1,4}2]2− and [C8H4{SiiPr3-1,4}2]2− ligands (2010) (12)
- Trigonal Prismatic Structure of Tris(butadiene)molybdenum and Related Complexes Revisited: Diolefin or Metallacyclopentene Coordination? (2002) (12)
- Synthesis of zerovalent tris[bis(1,2-(dimethylphosphino)ethane] compounds of chromium, molybdenum, tungsten, vanadium, niobium and tantalum using the metal vapours (1980) (12)
- Synthesis of hexakis (trimethylphosphine) molybdenum using molybdenum atoms and its X-ray crystal structure (1982) (11)
- The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes. (2019) (11)
- A base-free synthetic route to anti-bimetallic lanthanide pentalene complexes. (2017) (11)
- Metal atom synthesis and photochemistry of bis(η-pentamethylcyclopentadienyl)-tungsten dihydride (1985) (11)
- Mixed sandwich imido complexes of Uranium(V) and Uranium(IV): Synthesis, structure and redox behaviour (2017) (10)
- Bis(trimethyltin)bis-(η-toluene)-hafnium and -zirconium; X-ray crystal structure of the hafnium compound (1981) (10)
- Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes. (2009) (10)
- Bis(η-heteroarene) titanium complexes derived from 2,4,6-tri-tert-butylpyridine and 2,4,6-tri-tert-butylphosphorin: Conformational preference in solution and redox activity (1997) (10)
- Tetrakis(trimethylphosphine)nickel(0) (1988) (9)
- Synthesis and characterisation of Ti, Cr, Mo and W bis(fluorene) complexes (1997) (9)
- Butadiene ‘sandwich compounds’: synthesis of bis(η-1,4-di-tert-butylbuta-1,3-diene) complexes of titanium and vanadium (1991) (9)
- Synthesis and characterisation of a novel macrocyclic vinylsiloxane-based tris(alkene)nickel(0) complex (1995) (9)
- Preparation of (Nb(eta/sup 5/-C/sub 5/Me/sub 5/)Cl/sub 2/)/sub 2/ and Nb(eta/sup 5/-C/sub 5/Me/sub 5/)(3-hexyne)Cl/sub 2/ (1984) (9)
- Group 3 complexes incorporating (furyl)-substituted disilazide ligands (2010) (8)
- Synthesis of chloro-carbonyl derivatives of rhenium, ruthenium, rhodium, iridium and platinum via reaction of the metal atoms with oxalyl chloride (1985) (8)
- Influence of the plane of polarization on the photoemission of electrons (1974) (8)
- Synthesis of binuclear and trinuclear cluster halides of molybdenum and rhenium, and of carbonyl halides of rhenium, iridium, ruthenium, and platinum using metal atoms (1982) (8)
- Metal-vapour synthesis of phospha-organometallic compounds: reaction of nickel atoms with the phospha-alkyne tBuCP. Structural characterisation of [Ni(η3-PC2tBu2)(η5-P3C2tBu2)], a derivative of the novel, aromatic phosphirenyl cation (2004) (8)
- Synthesis and reactivity of bis(η-1,4-di-tert-butylbuta-1,3-diene)cobalt; the X-ray crystal structure of the anionic butadiene sandwich complex [K(18-crown-6)(thf)2][Co(η-C4H4But2)2] (1993) (8)
- Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system (2018) (8)
- Activation of carbon suboxide (C3O2) by U(iii) to form a cyclobutane-1,3-dione ring. (2018) (7)
- Synthesis of hetero-binuclear derivatives of the tetrathiolato complexes [Mo(η-C5H5CH2SR)2)], R = Prn and Ph, with platinum, palladium, and rhodium (1985) (7)
- [(C3tBu3)V(CO)4] : partial insertion of vanadium into the cyclopropenyl ring (1994) (7)
- C-H and H-H activation at a di-titanium centre. (2017) (7)
- Mass spectrometric studies of some bis(η5-pentamethylcyclopentadienyl)metal derivatives, and related complexes (1989) (7)
- η-Arenetungsten chemistry: η-allyl, η-butadiene, tertiary phosphine, and hydrido derivatives (1983) (6)
- Facile formation of a bridging cyclooctatrieneyne ligand; synthesis and molecular structure of [{η-C8H6(SiMe3)2}Zr{CH(SiMe3)2}{µ-η8 : η2-C8H4(SiMe3)2}Zr{CH(SiMe3)2}] (1994) (6)
- Main group complexes incorporating 1,3-bis(furyl)-1,1,3,3-tetramethyldisilazide ligands (2007) (6)
- Synthesis of bis(η-pentamethylcyclopentadienyl)rhenium hydride and its photochemical conversion into decamethylrhenocene (1985) (5)
- Synthesis of η-methylallylbis(η-butadiene)-niobium and -tantalum using the metal atoms (1980) (5)
- First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(PriNH)2CH2But}2] (2000) (4)
- Metal vapour synthesis and conformational analysis of bis(2-trimethylsilyl-3-methyl-phosphobenzene (2000) (4)
- Mixed-sandwich complexes of zirconium(III) and hafnium(III): Potential analogues of [U(η-C8H6{SiiPr3-1,4}2)(η-Cp∗)] for cyclooligomerisation of CO (2010) (4)
- Structural studies of group 1 metal 4-azapentalenyl complexes. (2005) (4)
- Comparison of the Reactivity of the Low Buried-Volume Carbene Complexes (ITMe)2Pd(PhC≡CPh) and (ITMe)2Pd(PhN═NPh) (2018) (3)
- Bis(pentalene)dititanium chemistry: C-H, C-X and H-H bond activation. (2018) (3)
- Reductive cyclotetramerization of CO to squarate by a U(III) complex: the X-ray crystal structure of [(U (eta-C8H6{SiiPr3-1,4}2)(eta-C5Me4H)]2(mu-eta2: eta2-C4O4). (2006) (3)
- Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalytic cis‐Bis(silyl)ations of Alkynes with Unactivated Disilanes. (2015) (3)
- Téarmaíocht don Aontas Eorpach. Taithí na hÉireann: Tionscadal GA IATE/ Terminology for the European Union. The Irish Experience: The GA IATE Project (2013) (3)
- Syntheses, structural studies, photoelectron spectra and density functional theory calculations of the "pseudo" tetraphospha-metallocenes [M(eta-P2C3Bu(t)3)(2)], (M = Ni, Pd, Pt). (2009) (3)
- Activation of sp3 carbon–hydrogen bonds of alkylbenzenes by rhenium forming binuclear µ-arylidene derivatives (1983) (2)
- Group 4 metal compounds incorporating the amide ligand, [N(SiMe2{C6H4-2-OMe})2](-). (2015) (2)
- Bis{1, 4-bis(trimethylsilyl) buta-1, 3-diene} cobalt: synthesis and molecular structure (1996) (2)
- Complexes of Iron(II) with silylated pentalene ligands; building blocks for homo- and heterobimetallics (2016) (2)
- Lipophilic Strontium and Calcium Alkyls, Amides, and Phenoxides. X-Ray Structures of the Crystalline Square-Planar ((trans-Sr(NR′2)2(μ-1,4- dioxane))∞) and Tetrahedral (CaR2(1,4-dioxane)2); R′ = SiMe3, R = CH(SiMe3)2. (2010) (2)
- Trimethylsilyl Derivatives of Cyclooctatetraene. (1994) (1)
- Bis(1,2-Bis(Dimethylphosphano)Ethane)Tricarbonyltitanium(0) and Hexacarbonyltitanate(2-) (2014) (1)
- Decamethylrhenocene, (η5-C5Me5)2Re (1988) (1)
- Low oxidation state complexes of group 3 elements. The first isolated examples of scandium in formal oxidation states of (I) and (II). (1997) (1)
- SYNTHESIS OF ZEROVALENT BIS(η-ARENE) COMPOUNDS OF ZIRCONIUM, HAFNIUM, NIOBIUM, TANTALUM, AND TUNGSTEN USING THE METAL VAPORS (1981) (0)
- The First Structurally Authenticated Divalent Lanthanoid Stannyl Derivative. (1992) (0)
- Tetrakis(trimethylphosphine)nickel(0). (1988) (0)
- SYNTHESIS, CHARACTERIZATION AND FLUXIONAL BEHAVIOUR OF NI(ETA 5-P2C3BU3T)(ETA 3-P2C3BU3T) (1995) (0)
- ARENE-TUNGSTEN CHEMISTRY- BIS(ARENE)TUNGSTEN HYDRIDE DERIVATIVES, CO-CONDENSATION OF TUNGSTEN ATOMS FROM AN ELECTRON GUN SOURCE WITH AROMATIC HYDROCARBONS (1978) (0)
- Alkylpalladium N‐Heterocyclic Carbene Complexes: Synthesis, Reactivity, and Catalytic Properties. (2009) (0)
- THE FIRST MONONUCLEAR ETA 8-COORDINATED PENTALENE COMPLEX : SYNTHESIS AND MOLECULAR STRUCTURE OF TAETA 8-C8H4(SIME3)2-1,4CL3 (1997) (0)
- Correction: C-H and H-H activation at a di-titanium centre. (2018) (0)
- CCDC 607082: Experimental Crystal Structure Determination (2007) (0)
- Introducing the 4-Azapentalenyl Anion: a ç-Bound Heterocyclic Anion with Potential Far Beyond the Cyclopentadienyl Anion! (2003) (0)
- Development of a Practical Buchwald—Hartwig Amine Arylation Protocol Using a Conveniently Prepared (NHC)Pd(R-Allyl)Cl Catalyst. (2008) (0)
- Developing 'New Look' Metallocenes: The Use of р-Bound Heterocyclic Anions (2002) (0)
- Bonding in Pentalene Complexes and Recent Applications. (2017) (0)
- Studies on Pd/Imidazolium Salt Protocols for Aminations of Aryl Bromides and Iodides Using Lithium Hexamethyldisilazide (LHMDS). (2006) (0)
- New horizons in organo-f-block chemistry. (2010) (0)
- Arene Complexes of the Group 3 Metals and Lanthanides (2021) (0)
- Unsolvated Samarium Complexes (2004) (0)
- 1.08 – Metal Vapor Synthesis: Principles and Practice (2007) (0)
- Synthesis, Crystal and Molecular Structures of the Novel, Structurally Different, Cage Compounds P6C4tBu4SiI2 and P6C4tBu4GeI2, Resulting from intra‐Molecular Coupling of Two 1,2,4‐Triphospholyl Rings. (2000) (0)
- Contents of volume 7 (2004) (0)
- Reactions of a Bis(pentalene)dititanium Complex with Alkenes; the Molecular Structure of the Butadiene complex [Ti2(µ: η5,η5-Pn††)2(μ: η2,η2-s-trans-C4H6)] (Pn†† = 1,4-(Si Pr3)2-C8H4) (2021) (0)
- Synthesis of an ( NHC ) 2 Pd ( SiMe 3 ) 2 ( NHC = N-Heterocyclic Carbene ) Complex . Catalytic , cis-Bis-Silylations of Internal Alkynes with Unactivated Disilanes (2017) (0)
- The First Delocalized Phosphole Containing a Planar Tricoordinate Phosphorus Atom: 1‐[Bis(trimethylsilyl)methyl] ‐3,5‐bis(trimethylsilyl)‐1,2,4‐triphosphole. (1998) (0)
- Synthetic, Structural and Theoretical Studies on New Aromatic 1,2,4-Azadiphosphole Ring Systems: Crystal and Molecular Structure of P2C2tBu2NPh. (2000) (0)
- Introduction to cluster chemistry (1992) (0)
- Preface (2019) (0)
- Cocondensation of Molybdenum Atoms with the Bulky Tertiary Diphosphine 1,2-Bis(diisopropylphosphino)ethane: The Molecular Structure of (MoH4(iPr2PCH2CH2PiPr2)2). (1988) (0)
- BIS(η-CYCLOPENTADIENLY)MOLYBDENUM CHEMISTRY: SYNTHESIS AND REACTIONS OF RING-FUNCTIONALIZED COMPOUNDS (1983) (0)
- New Horizons in Organo-f-element Chemistry (2010) (0)
- Gmelin Handbook of Inorganic Chemistry. 8th Edition. Ti—Organotitanium Compounds: Part 3, Mononuclear Compounds. : Springer-Verlag, Berlin/Heidelberg/New York, 1984, ix + 268 pages, DM 880. ISBN 3-540-93494-4. (1985) (0)
- Oxidation and Reduction Chemistry of Bis(η-arene)niobium Compounds: X-Ray Crystal Structure of Bis(η-toluene)(trimethylphosphine)niobium Tetrafluoroborate. (1988) (0)
- Synthesis of chromium(0) and molybdenum(0) bis (eta(6)-arene) derivatives and their monoelectronic oxidation to [M(eta(6)-arene)(2)](+) cations. (2006) (0)
- PREPARATION OF (NB(η5-C5ME5)CL2)2 AND NB(η5-C5ME5)(3-HEXYNE)CL2 (1984) (0)
- Suzuki—Miyaura Cross‐Coupling of Aryl and Alkyl Halides Using Palladium/Imidazolium Salt Protocols. (2004) (0)
- Efficiency of Two‐Coordinate Palladium(0) N‐Heterocyclic Carbene Complexes in Amination and Suzuki—Miyaura Reactions of Aryl Chlorides. (2006) (0)
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