Geoffrey W. Coates
American polymer chemist
Geoffrey W. Coates's AcademicInfluence.com Rankings
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Chemistry
Geoffrey W. Coates's Degrees
- PhD Chemistry Stanford University
Why Is Geoffrey W. Coates Influential?
(Suggest an Edit or Addition)According to Wikipedia, Geoffrey "Geoff" William Coates is an American chemist and the Tisch University Professor in the department of chemistry and chemical biology at Cornell University. Early life and education Coates was born in 1966 in Evansville, Indiana. He received a B.A. degree in chemistry from Wabash College in 1989. He entered graduate school at Stanford University where he worked with Robert M. Waymouth as a Hertz Fellow. His thesis work investigated the stereoselectivity of metallocene-based Ziegler-Natta catalysts. He was awarded a Ph.D. in organic chemistry in 1994. Coates then was a NSF Postdoctoral Fellow with Robert H. Grubbs at the California Institute of Technology. At Caltech, Coates worked on ring-closing metathesis reactions to functionalize polyolefins, and supramolecular phenyl-perfluorophenyl pi-stacking interactions.
Geoffrey W. Coates's Published Works
Published Works
- Discrete metal-based catalysts for the copolymerization of CO2 and epoxides: discovery, reactivity, optimization, and mechanism. (2004) (937)
- Polymerization of lactide with zinc and magnesium beta-diiminate complexes: stereocontrol and mechanism. (2001) (920)
- Precise control of polyolefin stereochemistry using single-site metal catalysts. (2000) (891)
- Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries. (2014) (619)
- Stereochemistry of lactide polymerization with chiral catalysts: new opportunities for stereocontrol using polymer exchange mechanisms. (2002) (587)
- Living alkene polymerization : New methods for the precision synthesis of polyolefins (2007) (479)
- Single-Site Catalysts for Ring-Opening Polymerization: Synthesis of Heterotactic Poly(lactic acid) from rac-Lactide (1999) (474)
- Catalysts for the living insertion polymerization of alkenes: access to new polyolefin architectures using Ziegler-Natta chemistry. (2002) (415)
- Tunable high performance cross-linked alkaline anion exchange membranes for fuel cell applications. (2010) (407)
- Single-site beta-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides: catalyst synthesis and unprecedented polymerization activity. (2001) (398)
- Cobalt catalysts for the alternating copolymerization of propylene oxide and carbon dioxide: combining high activity and selectivity. (2005) (394)
- Phosphonium-functionalized polyethylene: a new class of base-stable alkaline anion exchange membranes. (2012) (387)
- Stereoselective Ring-Opening Polymerization of meso-Lactide: Synthesis of Syndiotactic Poly(lactic acid) (1999) (383)
- Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene (1995) (369)
- Mechanism of the alternating copolymerization of epoxides and CO2 using beta-diiminate zinc catalysts: evidence for a bimetallic epoxide enchainment. (2003) (353)
- Catalytic Reactions Involving C1 Feedstocks: New High-Activity Zn(II)-Based Catalysts for the Alternating Copolymerization of Carbon Dioxide and Epoxides (1998) (345)
- PHENYL-PERFLUOROPHENYL STACKING INTERACTIONS : TOPOCHEMICAL 2+2 PHOTODIMERIZATION AND PHOTOPOLYMERIZATION OF OLEFINIC COMPOUNDS (1998) (344)
- Small-molecule inhibition of APT1 affects Ras localization and signaling. (2010) (336)
- Alternating copolymerization of limonene oxide and carbon dioxide. (2004) (335)
- Cobalt-based complexes for the copolymerization of propylene oxide and CO2: active and selective catalysts for polycarbonate synthesis. (2003) (318)
- Chemical recycling to monomer for an ideal, circular polymer economy (2020) (308)
- Single-Site β-Diiminate Zinc Catalysts for the Ring-Opening Polymerization of β-Butyrolactone and β-Valerolactone to Poly(3-hydroxyalkanoates) (2002) (305)
- Combining polyethylene and polypropylene: Enhanced performance with PE/iPP multiblock polymers (2017) (303)
- Imidazolium Cations with Exceptional Alkaline Stability: A Systematic Study of Structure-Stability Relationships. (2015) (296)
- Phenyl–Perfluorophenyl Stacking Interactions: A New Strategy for Supermolecule Construction (1997) (289)
- A new catalyst for highly syndiospecific living olefin polymerization: homopolymers and block copolymers from ethylene and propylene. (2001) (285)
- Stereoselective epoxide polymerization and copolymerization. (2014) (282)
- Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides with Discrete Metal Complexes: Structure-Property Relationships. (2016) (270)
- High-activity, single-site catalysts for the alternating copolymerization of CO2 and propylene oxide. (2002) (223)
- Alternating copolymerization of epoxides and cyclic anhydrides: an improved route to aliphatic polyesters. (2007) (216)
- Electronic and steric effects on catalysts for CO2/epoxide polymerization: subtle modifications resulting in superior activities. (2002) (209)
- Polymerization of enantiopure monomers using syndiospecific catalysts: a new approach to sequence control in polymer synthesis. (2009) (209)
- Ring-opening copolymerization of maleic anhydride with epoxides: a chain-growth approach to unsaturated polyesters. (2011) (204)
- A scanning tip electrospinning source for deposition of oriented nanofibres (2003) (201)
- A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer. (2009) (199)
- Stereoselective ring‐opening polymerization of rac‐lactide with a single‐site, racemic aluminum alkoxide catalyst: Synthesis of stereoblock poly(lactic acid) (2000) (192)
- α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts (1996) (180)
- Alkaline-stable anion exchange membranes: A review of synthetic approaches (2020) (178)
- Enantioselective cyclopolymerization of 1,5-hexadiene catalyzed by chiral zirconocenes: a novel strategy for the synthesis of optically active polymers with chirality in the main chain (1993) (171)
- A Virtual Issue of Macromolecules: “Polymers from Renewable Resources” (2009) (170)
- A C2-Symmetric, Living α-Diimine Ni(II) Catalyst: Regioblock Copolymers from Propylene (2005) (164)
- Homogeneous Ziegler-Natta polymerization of functionalized monomers catalyzed by cationic group IV metallocenes (1992) (162)
- Pre-rate-determining selectivity in the terpolymerization of epoxides, cyclic anhydrides, and CO2: a one-step route to diblock copolymers. (2008) (157)
- Enantioselective cyclopolymerization: optically active poly(methylene-1,3-cyclopentane) (1991) (156)
- Semi-Crystalline Polar Polyethylene: Ester-Functionalized Linear Polyolefins Enabled by a Functional-Group-Tolerant, Cationic Nickel Catalyst. (2016) (154)
- Polymerization catalysis at the millennium: frontiers in stereoselective, metal-catalyzed polymerization (2002) (152)
- Systematic Computational and Experimental Investigation of Lithium-Ion Transport Mechanisms in Polyester-Based Polymer Electrolytes (2015) (150)
- Formation of nanoparticles by intramolecular cross-linking: following the reaction progress of single polymer chains by atomic force microscopy. (2007) (149)
- Mechanism of propylene insertion using bis(phenoxyimine)-based titanium catalysts: an unusual secondary insertion of propylene in a group IV catalyst system. (2002) (144)
- Enantiomerically-enriched organic reagents via polymer synthesis: enantioselective copolymerization of cycloalkene oxides and CO2 using homogeneous, zinc-based catalysts (2000) (141)
- Synthesis and characterization of polyolefin–silicate nanocomposites: a catalyst intercalation and in situ polymerization approach† (1999) (139)
- Synthesis of beta-lactones: a highly active and selective catalyst for epoxide carbonylation. (2002) (134)
- Catalytic upcycling of high-density polyethylene via a processive mechanism (2020) (132)
- Enantioselective polymerization of epoxides: a highly active and selective catalyst for the preparation of stereoregular polyethers and enantiopure epoxides. (2008) (129)
- Designing Polymer Electrolytes for Safe and High Capacity Rechargeable Lithium Batteries. (2017) (129)
- Living polymerization of α-olefins with an α-diimine Ni(II) catalyst : Formation of well-defined ethylene-propylene copolymers through controlled chain-walking (2006) (127)
- New phenoxyketimine titanium complexes: combining isotacticity and living behavior in propylene polymerization. (2004) (121)
- Stereocomplexed poly(limonene carbonate): a unique example of the cocrystallization of amorphous enantiomeric polymers. (2015) (119)
- Secondary alkene insertion and precision chain-walking: a new route to semicrystalline "polyethylene" from α-olefins by combining two rare catalytic events. (2014) (117)
- Alternating copolymerization of propylene oxide with biorenewable terpene-based cyclic anhydrides: a sustainable route to aliphatic polyesters with high glass transition temperatures. (2015) (117)
- New facets of an old ligand: titanium and zirconium complexes of phenylenediamine bis(phenolate) in lactide polymerisation catalysis. (2009) (116)
- Poly(propylene succinate): a new polymer stereocomplex. (2014) (113)
- Solvent Processable Tetraalkylammonium-Functionalized Polyethylene for Use as an Alkaline Anion Exchange Membrane (2010) (113)
- Alternating copolymerization of propylene oxide and carbon dioxide with highly efficient and selective (salen)Co(III) catalysts: Effect of ligand and cocatalyst variation (2006) (110)
- Chromium(III) octaethylporphyrinato tetracarbonylcobaltate: a highly active, selective, and versatile catalyst for epoxide carbonylation. (2005) (109)
- Enantioselective epoxide polymerization using a bimetallic cobalt catalyst. (2010) (107)
- [Lewis acid]+[Co(CO)(4)]- complexes: a versatile class of catalysts for carbonylative ring expansion of epoxides and aziridines. (2002) (107)
- Copolymerization of cyclohexene oxide and carbon dioxide using (salen)Co(III) complexes: synthesis and characterization of syndiotactic poly(cyclohexene carbonate). (2006) (104)
- Insertion/isomerization polymerization of 1,5-hexadiene: synthesis of functional propylene copolymers and block copolymers. (2002) (100)
- Polymerization of Ureidopyrimidinone-Functionalized Olefins by Using Late-Transition Metal Ziegler-Natta Catalysts: Synthesis of Thermoplastic Elastomeric Polyolefins. (2001) (98)
- Alternating Copolymerization of Propylene Oxide and Cyclohexene Oxide with Tricyclic Anhydrides: Access to Partially Renewable Aliphatic Polyesters with High Glass Transition Temperatures (2016) (97)
- Semicrystalline thermoplastic elastomeric polyolefins: Advances through catalyst development and macromolecular design (2006) (96)
- Development of Highly Active and Regioselective Catalysts for the Copolymerization of Epoxides with Cyclic Anhydrides: An Unanticipated Effect of Electronic Variation. (2016) (96)
- Electronic Effects of Aluminum Complexes in the Copolymerization of Propylene Oxide with Tricyclic Anhydrides: Access to Well-Defined, Functionalizable Aliphatic Polyesters. (2016) (96)
- Fluorinated bis(phenoxyketimine)titanium complexes for the living, isoselective polymerization of propylene: multiblock isotactic polypropylene copolymers via sequential monomer addition. (2008) (94)
- Tailored Living Block Copolymerization: Multiblock Poly(cyclohexene carbonate)s with Sequence Control (2011) (93)
- A highly active, isospecific cobalt catalyst for propylene oxide polymerization. (2005) (93)
- Metal-catalyzed synthesis of alternating copolymers. (2011) (91)
- Nanofluidic channels with elliptical cross sections formed using a nonlithographic process (2003) (89)
- Controlled Chain Walking for the Synthesis of Thermoplastic Polyolefin Elastomers: Synthesis, Structure, and Properties (2016) (86)
- Mechanistic Insights into the Alternating Copolymerization of Epoxides and Cyclic Anhydrides Using a (Salph)AlCl and Iminium Salt Catalytic System. (2017) (85)
- Practical β-Lactone Synthesis: Epoxide Carbonylation at 1 atm (2006) (84)
- Synthesis and Characterization of Alternating and Multiblock Copolymers from Ethylene and Cyclopentene (2002) (84)
- Titanium Catalysts with Ancillary Phenoxyketimine Ligands for Living Ethylene Polymerization (2003) (83)
- Compatibilization of Isotactic Polypropylene (iPP) and High-Density Polyethylene (HDPE) with iPP–PE Multiblock Copolymers (2018) (82)
- Heat-depolymerizable polycarbonates as electron beam patternable sacrificial layers for nanofluidics (2001) (81)
- Catalytic double carbonylation of epoxides to succinic anhydrides: catalyst discovery, reaction scope, and mechanism. (2007) (80)
- Highly conductive and chemically stable alkaline anion exchange membranes via ROMP of trans-cyclooctene derivatives (2019) (80)
- Two-dimensional double metal cyanide complexes: highly active catalysts for the homopolymerization of propylene oxide and copolymerization of propylene oxide and carbon dioxide. (2006) (80)
- Carbonylation of heterocycles by homogeneous catalysts. (2007) (79)
- Sustainable Polyester Elastomers from Lactones: Synthesis, Properties, and Enzymatic Hydrolyzability. (2018) (78)
- The mechanism of epoxide carbonylation by [Lewis Acid]+[Co(CO)4]- catalysts. (2006) (77)
- Effect of Metal on the Stereospecificity of 2-Arylindene Catalysts for Elastomeric Polypropylene (1997) (75)
- Chemically recyclable thermoplastics from reversible-deactivation polymerization of cyclic acetals (2021) (75)
- C2-Symmetric Ni(II) α-Diimines Featuring Cumyl-Derived Ligands: Synthesis of Improved Elastomeric Regioblock Polypropylenes (2008) (74)
- Polymerization of α-Olefins with Pyridylamidohafnium Catalysts: Living Behavior and Unexpected Isoselectivity from a Cs-Symmetric Catalyst Precursor (2007) (74)
- Structure and reactivity of mono- and dinuclear diiminate zinc alkyl complexes (2003) (73)
- Optimizing Ion Transport in Polyether-Based Electrolytes for Lithium Batteries (2018) (72)
- Synthesis of Alkaline Anion Exchange Membranes with Chemically Stable Imidazolium Cations: Unexpected Cross-Linked Macrocycles from Ring-Fused ROMP Monomers (2018) (72)
- Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies. (2022) (68)
- Copolymerization of CO2 and meso epoxides using enantioselective β-diiminate catalysts: a route to highly isotactic polycarbonates (2014) (67)
- Gel permeation chromatography as a combinatorial screening method: identification of highly active heteroligated phenoxyimine polymerization catalysts. (2004) (67)
- Enantioselective polymerization of epoxides using biaryl-linked bimetallic cobalt catalysts: a mechanistic study. (2013) (67)
- Optically Transparent and High Molecular Weight Polyolefin Block Copolymers toward Self-Assembled Photonic Band Gap Materials (2006) (67)
- Tetraarylborate polymer networks as single-ion conducting solid electrolytes† †Electronic supplementary information (ESI) available: Adsorption isotherms, IR spectra, synthetic procedures, characterization data, equivalent circuit diagrams and additional SEM images. See DOI: 10.1039/c5sc02052b Click (2015) (64)
- Chiral anilines: development of C2-symmetric, late-transition metal catalysts for isoselective 2-butene polymerization. (2003) (63)
- Mechanism-Inspired Design of Bifunctional Catalysts for the Alternating Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides. (2019) (63)
- Controlling the Shape of Molecular Weight Distributions in Coordination Polymerization and its Impact on Physical Properties. (2019) (61)
- Investigating polypropylene-poly(ethylene oxide)-polypropylene triblock copolymers as solid polymer electrolytes for lithium batteries☆ (2014) (60)
- Synthesis of Allyl-Terminated Syndiotactic Polypropylene: Macromonomers for the Synthesis of Branched Polyolefins (2005) (59)
- Carbonylative polymerization of propylene oxide: a multicatalytic approach to the synthesis of poly(3-hydroxybutyrate). (2010) (58)
- Synthetic Biodegradable Polymers (2012) (58)
- Effect of monomer structure on ionic conductivity in a systematic set of polyester electrolytes (2016) (56)
- A readily synthesized and highly active epoxide carbonylation catalyst based on a chromium porphyrin framework: expanding the range of available beta-lactones. (2004) (56)
- Universal Relationship between Conductivity and Solvation-Site Connectivity in Ether-Based Polymer Electrolytes (2016) (56)
- Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. (2007) (55)
- Multicomponent Nanomaterials with Complex Networked Architectures from Orthogonal Degradation and Binary Metal Backfilling in ABC Triblock Terpolymers (2015) (54)
- Mechanoactivation of Spiropyran Covalently Linked PMMA: Effect of Temperature, Strain Rate, and Deformation Mode (2015) (53)
- Morphology and Thermodynamic Behavior of Syndiotactic Polypropylene-Poly(ethylene-co-propylene) Block Polymers Prepared by Living Olefin Polymerization (2005) (52)
- Single polymer growth dynamics (2017) (50)
- Structure–property study of cross-linked hydrocarbon/poly(ethylene oxide) electrolytes with superior conductivity and dendrite resistance† †Electronic supplementary information (ESI) available: Synthetic procedures, characterization data, electrochemical impedance spectra and additional SEM images. (2016) (50)
- Suspended glass nanochannels coupled with microstructures for single molecule detection (2005) (48)
- Highly effective poly(ethylene glycol) architectures for specific inhibition of immune receptor activation. (2003) (48)
- Acid-catalyzed ortho-alkylation of anilines with styrenes: an improved route to chiral anilines with bulky substituents. (2005) (47)
- Synthesis and Polymerization of Norbornenyl-Terminated Multiblock Poly(cyclohexene carbonate)s: A Consecutive Ring-Opening Polymerization Route to Multisegmented Graft Polycarbonates (2012) (46)
- Total Synthesis of Tetrahydrolipstatin and Stereoisomers via a Highly Regio- and Diastereoselective Carbonylation of Epoxyhomoallylic Alcohols (2014) (46)
- Quantitative Ring-Closing Metathesis of Polyolefins (1996) (46)
- Phenothiazine-Based Polymer Cathode Materials with Ultrahigh Power Densities for Lithium Ion Batteries (2018) (46)
- Regioselective carbonylation of trans-disubstituted epoxides to β-lactones: a viable entry into syn-aldol-type products. (2013) (45)
- A Comprehensive Understanding of Polyester Stereocomplexation. (2019) (45)
- A new multicomponent reaction catalyzed by a [Lewis Acid](+)[Co(CO)(4)](-) catalyst: stereospecific synthesis of 1,3-oxazinane-2,4-diones from epoxides, isocyanates, and CO. (2007) (44)
- Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated iridium complexes. (2005) (43)
- Understanding the Insertion Pathways and Chain Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin Polymerization: A 13C NMR Spectroscopic Investigation (2017) (43)
- Allyl-Terminated Polypropylene Macromonomers: A Route to Polyolefin Elastomers with Excellent Elastic Behavior (2015) (41)
- On the mechanism of isospecific epoxide polymerization by salen cobalt(III) complexes: evidence for solid-state catalysis. (2009) (41)
- Isospecific polymerization of racemic epoxides: a catalyst system for the synthesis of highly isotactic polyethers. (2010) (41)
- Nickel Catalysts for the Dehydrative Decarbonylation of Carboxylic Acids to Alkenes (2016) (40)
- Isospecific, Chain Shuttling Polymerization of Propylene Oxide Using a Bimetallic Chromium Catalyst: A New Route to Semicrystalline Polyols. (2017) (40)
- Cross metathesis functionalization of polyolefins. (2004) (39)
- An electrochemical quartz crystal microbalance study of a prospective alkaline anion exchange membrane material for fuel cells: anion exchange dynamics and membrane swelling. (2014) (39)
- Catalytic Carbonylation of β-Lactones to Succinic Anhydrides (2004) (39)
- Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters (2018) (38)
- Synthesis of Semicrystalline Polyolefin Materials: Precision Methyl Branching via Stereoretentive Chain Walking. (2018) (38)
- Crystallization of Alternating Limonene Oxide/Carbon Dioxide Copolymers: Determination of the Crystal Structure of Stereocomplex Poly(limonene carbonate) (2015) (37)
- A SANS Study of the Self-Assembly in Solution of Syndiotactic Polypropylene Homopolymers, Syndiotactic Polypropylene-block-poly(ethylene-co-propylene) Diblock Copolymers, and an Alternating Atactic−Isotactic Multisegment Polypropylene (2004) (37)
- Synthesis and characterization of amphiphilic poly(ethylene oxide)-block-poly(hexyl methacrylate) copolymers (2003) (36)
- Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf-C bond of a neutral pyridylamidohafnium trimethyl complex. (2008) (36)
- Tough and Elastic Thermoplastic Organogels and Elastomers Made of Semicrystalline Polyolefin-Based Block Copolymers (2012) (35)
- Protocol for the Quantitative Assessment of Organic Cation Stability for Polymer Electrolytes (2019) (35)
- Enabling Room-Temperature Mechanochromic Activation in a Glassy Polymer: Synthesis and Characterization of Spiropyran Polycarbonate. (2019) (35)
- Chiral polymers via cyclopolymerization (1992) (35)
- Degradation of Organic Cations under Alkaline Conditions. (2020) (34)
- Chemistry for a sustainable future. (2007) (34)
- Isotactic Polypropylene with (3,1) Chain-Walking Defects: Characterization, Crystallization, and Melting Behaviors (2011) (33)
- Combined Experimental and Theoretical Approach for Living and Isoselective Propylene Polymerization (2017) (33)
- Stereospecific cyclopolymerization with group 4 metallocenes (1991) (33)
- Tetrakis(dialkylamino)phosphonium Polyelectrolytes Prepared by Reversible Addition-Fragmentation Chain Transfer Polymerization. (2016) (33)
- Processing‐structure‐mechanical property relationships of semicrystalline polyolefin‐based block copolymers (2010) (33)
- Exploration of Cocatalyst Effects on a Bimetallic Cobalt Catalyst System: Enhanced Activity and Enantioselectivity in Epoxide Polymerization (2011) (32)
- Alternating copolymerization of dihydrocoumarin and epoxides catalyzed by chromium salen complexes: a new route to functional polyesters. (2014) (32)
- Syndiospecific living catalysts for propylene polymerization: Effect of fluorination on activity, stereoselectivity, and termination (2002) (32)
- Step-Cycle Mechanical Processing of Gels of sPP-b-EPR-b-sPP Triblock Copolymer in Mineral Oil (2010) (32)
- Synthesis and Ring-Opening Metathesis Polymerization of Norbornene-Terminated Syndiotactic Polypropylene (2012) (31)
- Regioselective Isomerization of 2,3-Disubstituted Epoxides to Ketones: An Alternative to the Wacker Oxidation of Internal Alkenes. (2015) (30)
- Meinwald-type rearrangement of monosubstituted epoxides to methyl ketones using an [Al porphyrin]+[Co(CO)4]− catalyst (2015) (29)
- Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes (2004) (29)
- Carbonylation of Ethylene Oxide to β-Propiolactone: A Facile Route to Poly(3-hydroxypropionate) and Acrylic Acid (2016) (29)
- Enzymatic surface-initiated polymerization: a novel approach for the in situ solid-phase synthesis of biocompatible polymer poly(3-hydroxybutyrate). (2004) (28)
- Defining the Macromolecules of Tomorrow through Synergistic Sustainable Polymer Research. (2022) (27)
- Bimetallic Chromium Catalysts with Chain Transfer Agents: A Route to Isotactic Poly(propylene oxide)s with Narrow Dispersities. (2018) (27)
- Reversible-deactivation anionic alternating ring-opening copolymerization of epoxides and cyclic anhydrides: access to orthogonally functionalizable multiblock aliphatic polyesters† †Electronic supplementary information (ESI) available: Synthetic, polymerization, and functionalization procedures, an (2017) (27)
- Bifunctional Catalysis Prevents Inhibition in Reversible-Deactivation Ring-Opening Copolymerizations of Epoxides and Cyclic Anhydrides. (2020) (26)
- Synthesis of amphiphilic ABC triblock copolymers with PEO as the middle block (2004) (26)
- Enantioenriched β-lactone and aldol-type products from regiodivergent carbonylation of racemic cis-epoxides (2014) (26)
- Rheological behavior of chain-straightened poly(α-olefin)s (2007) (25)
- Rapid Analysis of Tetrakis(dialkylamino)phosphonium Stability in Alkaline Media (2017) (25)
- Fluorinated β-Lactones and Poly(β-hydroxyalkanoate)s: Synthesis via Epoxide Carbonylation and Ring-Opening Polymerization. (2008) (25)
- De novo asymmetric synthesis of fridamycin E. (2011) (25)
- Cyclopolymerization of Nonconjugated Dienes with a Tridentate Phenoxyamine Hafnium Complex Supported by an sp(3) -C Donor: Isotactic Enchainment and Diastereoselective cis-Ring Closure. (2009) (25)
- Compatibilization of iPP/HDPE Blends with PE-g-iPP Graft Copolymers. (2020) (25)
- Poly(dicyclopentadiene) Submicron Fibers Produced by Electrospinning (2006) (24)
- Analysis of Polymeric Methylaluminoxane (MAO) via Small Angle Neutron Scattering (2007) (24)
- Switchable living nickel(ii) α-diimine catalyst for ethylene polymerisation. (2019) (24)
- Poly(ethylene-co-propylene macromonomer)s: Synthesis and Evidence for Starlike Conformations in Dilute Solution (2008) (23)
- Oriented Microstructures of Crystalline–Crystalline Block Copolymers Induced by Epitaxy and Competitive and Confined Crystallization (2016) (23)
- Catalytic synthesis of beta3-amino acid derivatives from alpha-amino acids. (2008) (22)
- Improved Li+ Transport in Polyacetal Electrolytes: Conductivity and Current Fraction in a Series of Polymers (2021) (21)
- Chirality-Directed Regioselectivity: An Approach for the Synthesis of Alternating Poly(Lactic-co-Glycolic Acid). (2021) (21)
- Structure and Physical Properties of Syndiotactic Polypropylene from Living Polymerization with Bis(phenoxyimine)-Based Titanium Catalysts (2004) (21)
- A catalytic route to ampakines and their derivatives. (2011) (20)
- Report of the Basic Energy Sciences Roundtable on Chemical Upcycling of Polymers (2019) (20)
- Carbonylation of Epoxides to Substituted 3-Hydroxy-δ-Lactones (2007) (20)
- Access to oxetane-containing psico-nucleosides from 2-methyleneoxetanes: a role for neighboring group participation? (2011) (20)
- Regioselective Carbonylation of 2,2-Disubstituted Epoxides: An Alternative Route to Ketone-Based Aldol Products. (2019) (19)
- High Morphological Order in a Nearly Precise Acid-Containing Polymer and Ionomer. (2017) (19)
- Designing Polymeric Interphases for Stable Lithium Metal Deposition. (2020) (18)
- Beta-amidoaldehydes via oxazoline hydroformylation. (2009) (18)
- Achieving Uniform Lithium Electrodeposition in Cross-Linked Poly(ethylene oxide) Networks: “Soft” Polymers Prevent Metal Dendrite Proliferation (2020) (18)
- Mechanically robust and reprocessable imine exchange networks from modular polyester pre-polymers (2020) (17)
- Carbonylative enantioselective meso-desymmetrization of cis-epoxides to trans-β-lactones: effect of salen-ligand electronic variation on enantioselectivity. (2014) (16)
- Carbon dioxide as a renewable C1 feedstock : Synthesis and characterization of polycarbonates from the alternating copolymerization of epoxides and CO2 (2006) (16)
- Rapid prototyping of nanofluidic systems using size-reduced electrospun nanofibers for biomolecular analysis. (2010) (16)
- Modifying Li+ and Anion Diffusivities in Polyacetal Electrolytes: A Pulsed-Field-Gradient NMR Study of Ion Self-Diffusion (2021) (16)
- Isotactic Poly(propylene oxide): A Photodegradable Polymer with Strain Hardening Properties. (2020) (15)
- Carbonylation of cis-disubstituted epoxides to trans-β-lactones: catalysts displaying steric and contrasteric regioselectivity. (2014) (15)
- Real-time analysis of enzymatic surface-initiated polymerization using surface plasmon resonance (SPR). (2006) (15)
- Catalytic post-modification of alkene polymers: Chemistry and kinetics of dehydrogenation of alkene polymers and oligomers with pincer Ir complexes (2006) (14)
- Mechanistic Insight into Thiophene Catalyst-Transfer Polymerization Mediated by Nickel Diimine Catalysts (2017) (14)
- Carbonylative, Catalytic Deoxygenation of 2,3-Disubstituted Epoxides with Inversion of Stereochemistry: An Alternative Alkene Isomerization Method. (2020) (14)
- Miscible Polyether/Poly(ether-acetal) Electrolyte Blends. (2020) (13)
- Synthesis and polymerization of bicyclic ketals: a practical route to high-molecular weight polyketals. (2013) (12)
- Insight in the role of bovine serum albumin for promoting the in situ surface growth of polyhydroxybutyrate (PHB) on patterned surfaces via enzymatic surface-initiated polymerization. (2007) (12)
- Nucleophilic ring opening of trans-2,3-disubstituted epoxides to β-amino alcohols with catalyst-controlled regioselectivity. (2018) (11)
- Morphology of Isotactic Polypropylene–Polyethylene Block Copolymers Driven by Controlled Crystallization (2020) (11)
- 12.1 – Transition Metals in Polymer Synthesis: Ziegler–Natta Reaction (1995) (11)
- Chemical Upcycling of Polyethylene to Value-Added α,ω-Divinyl-Functionalized Oligomers (2021) (11)
- Crystal structure of alternating isotactic ethylene-cyclopentene copolymer (2005) (11)
- α‐Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts (1996) (10)
- Dual catalysis for the copolymerisation of epoxides and lactones. (2019) (10)
- End-functionalization of poly(3-hydroxybutyrate)via genetic engineering for solid surface modification. (2005) (10)
- Trials and tribulations of designing multitasking catalysts for olefin/thiophene block copolymerizations (2018) (9)
- Small angle X-ray scattering investigation of norbornene-terminated syndiotactic polypropylene and corresponding comb-like poly(macromonomer). (2013) (9)
- Propylene polymerization byC1-symmetric {ONNO′}-type salan zirconium complexes (2013) (9)
- Homogeneous Catalyst Design for the Synthesis of Aliphatic Polycarbonates and Polyesters (2010) (9)
- Alkene Polymerization Catalysts Bearing Tridentate Phenoxyamine Ligands with sp3 C Donors (2009) (9)
- High power organic cathodes using thin films of electropolymerized benzidine polymers. (2015) (8)
- Rapid Determination of Polymer Stereoregularity Using Band-Selective 2D HSQC. (2016) (8)
- Upgrading Carbonate Electrolytes for Ultra-stable Practical Lithium Metal Batteries. (2021) (8)
- Polymerization of 1-Octene by a Pyridylamidohafnium Catalyst: A SEC, 1H-NMR and Small Angle Neutron Scattering Study (2009) (8)
- Living Transition Metal-Catalyzed Alkene Polymerization: Polyolefin Synthesis and New Polymer Architectures (2010) (8)
- Synthesis of β-Lactones: A Highly Active and Selective Catalyst for Epoxide Carbonylation. (2002) (8)
- Catalytic Synthesis of β3‐Amino Acid Derivatives from α‐Amino Acids (2008) (7)
- Direct Electron-Beam Patterning of Surface Coatings and Sacrificial Layers for Micro-Total Analysis Systems (2002) (7)
- A Readily Synthesized and Highly Active Epoxide Carbonylation Catalyst Based on a Chromium Porphyrin Framework: Expanding the Range of Available β-Lactones. (2004) (7)
- Fabrication of Blended Polyphenylenevinylene Nanowires By Scanned Electrospinning (2004) (7)
- Chemically Recyclable Ester-Linked Polypropylene. (2022) (7)
- Mechanistic Study of Isotactic Poly(propylene oxide) Synthesis using a Tethered Bimetallic Chromium Salen Catalyst. (2020) (7)
- Single-site beta-diiminate zinc catalysts for the ring-opening polymerization of beta-butyrolactone and beta-valerolactone to poly(3-hydroxyalkanoates). (2002) (7)
- Alternating isotactic ethylene-cyclopentene copolymer: a crystalline engineering plastomer including high amounts of structural disorder. (2005) (6)
- Multifunctional Catalysts for Ring-Opening Copolymerizations (2022) (6)
- Living Alkene Polymerization for Polyolefin Architectures (2011) (6)
- Electrogenerated Chemiluminescence of Bithiophenes with Methylthio Functionalities (2014) (6)
- Nucleophilic Transformations of Lewis Acid-Activated Disubstituted Epoxides with Catalyst-Controlled Regioselectivity. (2020) (6)
- Basic Research Needs for Catalysis Science to Transform Energy Technologies: Report from the U.S. Department of Energy, Office of Basic Energy Sciences Workshop May 8–10, 2017, in Gaithersburg, Maryland (2017) (6)
- Viewpoint : Chemistry for a Sustainable Future (2009) (6)
- Hybrid Organic Electrodes: The Rational Design and Synthesis of High-Energy Redox-Active Pendant Functionalized Polypyrroles for Electrochemical Energy Storage (2017) (6)
- Upgrading Carbonate Electrolytes for Ultra‐stable Practical Lithium Metal Batteries (2021) (5)
- Catalysts for the Living Insertion Polymerization of Alkenes: Access to New Polyolefin Architectures Using Ziegler—Natta Chemistry (2002) (5)
- Generation of an (alkoxycarbonyl)rhodium complex in an alcohol analog of the water-gas shift reaction (1993) (4)
- Ring‐Expanding Carbonylation of Epoxides (2015) (4)
- Stereoselective Ring-Opening Polymerization of Epoxides (2012) (4)
- Titanium(IV) catalysts with ancillary imino-spiroketonato ligands: synthesis, structure and olefin polymerization. (2015) (4)
- Coordination Polymerization: Synthesis of New Homo‐ and Copolymer Architectures from Ethylene and Propylene Using Homogeneous Ziegler–Natta Polymerization Catalysts (2011) (4)
- Low Pressure Carbonylation of Epoxides to β‐Lactones (2009) (4)
- Crystal structures of (η5-C5Me5)(η5-2,4-C7H11)Cr and (η5-C5Me5)-(η5-2,4-C7H11)CrCO. An example of ‘S’ 2,4-dimethylpentadienyl ligand geometry (1993) (4)
- Stereocomplexation of Stereoregular Aliphatic Polyesters: Change from Amorphous to Semicrystalline Polymers with Single Stereocenter Inversion. (2022) (4)
- Synthesis of an epoxide carbonylation catalyst: Exploration of contemporary chemistry for advanced undergraduates (2005) (4)
- Discrete Catalysts for Stereoselective Epoxide Polymerization (2007) (4)
- Single-chain polymerization dynamics and conformational mechanics of conjugated polymers (2021) (3)
- Structure and morphology of isotactic polypropylene–polyethylene block copolymers prepared with living and stereoselective catalyst (2022) (3)
- Catalyst-Controlled Regioselective Carbonylation of Isobutylene Oxide to Pivalolactone (2020) (3)
- Practical β‐Lactone Synthesis: Epoxide Carbonylation at 1 atm. (2006) (3)
- Chain polymerization of vinyl monomers (2012) (3)
- Enantioselective Cyclopolymerization of 1,5‐Hexadiene Catalyzed by Chiral Zirconocenes: A Novel Strategy for the Synthesis of Optically Active Polymers with Chirality in the Main Chain. (1993) (3)
- Precise Control of Polyolefin Stereochemistry Using Single‐Site Metal Catalysts (2000) (2)
- Challenges and Opportunities in Sustainable Polymers. (2022) (2)
- β‐Amidoaldehydes via Oxazoline Hydroformylation. (2010) (2)
- Exploring the Ion Solvation Environments in Solid-State Polymer Electrolytes through Free-Energy Sampling (2021) (2)
- Regioselective Carbonylation of trans‐Disubstituted Epoxides to β‐Lactones: A Viable Entry into syn‐Aldol‐Type Products. (2014) (1)
- Catalytic Synthesis of β3-Amino Acid Derivatives from α-Amino Acids. (2008) (1)
- Catalytic carbonylation of beta-lactones to succinic anhydrides. (2004) (1)
- Zirconium-Catalyzed C–H Alumination of Polyolefins, Paraffins, and Methane (2023) (1)
- A New Multicomponent Reaction Catalyzed by a [Lewis Acid]+[Co(CO)4]‐ Catalyst: Stereospecific Synthesis of 1,3‐Oxazinane‐2,4‐diones from Epoxides, Isocyanates, and CO. (2007) (1)
- Cover Picture: Macromol. Rapid Commun. 22/2004 (2004) (1)
- Tuning Single-Polymer Growth via Hydrogen Bonding in Conformational Entanglements (2022) (1)
- Catalytic Chemical Recycling of Post-Consumer Polyethylene. (2022) (1)
- Regioselective Isomerization of 2,3‐Disubstituted Epoxides to Ketones: An Alternative to the Wacker Oxidation of Internal Alkenes. (2016) (1)
- Systematic computational and experimental investigation of lithium-ion transport mechanisms in polymer electrolytes (2016) (1)
- Anion Exchange Membrane Water Electrolysis: The Future of Green Hydrogen (2023) (1)
- Complete Electrochemical Characterization and Limiting Current of Polyacetal Electrolytes (2022) (1)
- Bionanofabrication polyhydroxyalkanoates (PHAS) micro-/nano-structures on solid surfaces and its applications in nanobiotechnology (2006) (1)
- A C2-symmetric, living alpha-diimine Ni(II) catalyst: regioblock copolymers from propylene. (2005) (1)
- Mechanism of Propylene Insertion Using Bis(phenoxyimine)-Based Titanium Catalysts: An Unusual Secondary Insertion of Propylene in a Group IV Catalyst System. [J. Am. Chem. Soc. 2002, 124, 3614−3621]. (2002) (1)
- Chain-Straightening Polymerization of Olefins to Form Polar Functionalized Semicrystalline Polyethylene (2022) (1)
- Living polymerization of alpha-olefins with an alpha-diimine Ni(II) catalyst: formation of well-defined ethylene-propylene copolymers through controlled chain-walking. (2006) (1)
- [Lewis Acid]+[Co(CO)4]‐ Complexes: A Versatile Class of Catalysts for Carbonylative Ring Expansion of Epoxides and Aziridines. (2002) (1)
- Bionanofabrication polyhydroxyalkanoates (PHAS) micro-/nanostructures on solid surfaces and its applications in nanobiotechnology (2007) (1)
- Practical beta-lactone synthesis: epoxide carbonylation at 1 atm. (2006) (1)
- Copolymerization of ethylene oxide and carbon dioxide (2015) (1)
- Melting and Crystalline Properties of Isotactic Poly(propylenes) with 1,3 Defects (2010) (0)
- A Catalytic Route to Ampakines and Their Derivatives (2011) (0)
- Glass Nanofiber Fabrication and Devices (2005) (0)
- Solution and Melt Rheology of Polypropylene Comb and Star Polymers (2006) (0)
- The Effect of Structural Modifications on Ionic Conductivity in Newly-Designed Polyester Electrolytes (2015) (0)
- Step Cycle Deformation Processing of Elastomers and Gels Based on Semicrystalline Polyolefin-based Block Copolymers (2009) (0)
- Heterocyclic catalytic carbonylation three and four members. (2002) (0)
- CCDC 1001988: Experimental Crystal Structure Determination : (mu~2~-3,3'-bis((2-((3,5-Di-t-butyl-2-oxybenzylidene)amino)cyclohexyl)carbonoimidoyl)biphenyl-2,2'-diolato)-bis(pyridine)-di-cobalt dichloride unknown solvate (2014) (0)
- Direct Insertion Polymerization of Ionic Monomers: Rapid Production of Anion Exchange Membranes. (2023) (0)
- Ion Transport in Ether-Based Polymer Electrolytes (2020) (0)
- Structural changes of semicrystalline polyolefin block copolymer elastomers during step cycle mechanical processing (2010) (0)
- Unraveling substituent effects on the glass transition temperatures of biorenewable polyesters (2018) (0)
- Catalytic Carbonylation of β-Lactones to Succinic Anhydrides. (2004) (0)
- 3.01 – Introduction and Overview: Chain Polymerization of Vinyl Monomers (2012) (0)
- Relationship between Ion Transport and Phase Behavior in Acetal-Based Polymer Blend Electrolytes Studied by Electrochemical Characterization and Neutron Scattering (2022) (0)
- Synthesis of functionalized poly({alpha}-olefins) via Ziegler-Natta catalysis: Homo- and copolymers (1993) (0)
- Origin of the Toughness and the Elastomeric Properties of Gels from Block Copolymers with Semicrystalline Syndiotactic Polypropylene Blocks (2011) (0)
- Ultra-High-Molecular-Weight Poly(Dioxolane): Enhancing the Mechanical Performance of a Chemically Recyclable Polymer. (2023) (0)
- Synthesis and Characterization of Amphiphilic Poly(ethylene oxide)-block-poly(hexyl methacrylate) (2003) (0)
- Title Effect of monomer structure on ionic conductivity in a systematic set of polyester electrolytes Permalink (2016) (0)
- Synthesis of β3-Amino Acid Derivativesvia Co-Catalyzed Carbonylation of Oxazolines (2008) (0)
- Rapid Prototyping of Nanofl uidic Systems Using Size-Reduced Electrospun Nanofi bers for Biomolecular Analysis (2010) (0)
- Stereospecific polymerization with metallocenes: Macromolecular design via catalysis (1995) (0)
- Low Dose Mapping of Semicrystallinity in Polymer Membranes with cryogenic 4D-STEM (2021) (0)
- Organic-inorganic nanostructured materials through self assembly of a new set of amphiphilic block copolymers (2003) (0)
- Multicomponent Reaction of Epoxides, Isocyanates, and CO (2007) (0)
- Suppressing Crossover in Nonaqueous Redox Flow Batteries with Polyethylene-Based Anion-Exchange Membranes (2022) (0)
- Systematic Experimental and Computational Investigation of Ion Transport in Novel Polyether Electrolytes (2016) (0)
- OBTANED BY USING THE SAME AS RAW MATERAL (2017) (0)
- Polymer Synthesis and Stereochemistry with Transition Metal Catalysts (1996) (0)
- Nature-inspired methylated polyhydroxybutyrates from C1 and C4 feedstocks. (2023) (0)
- Entrepreneurship in Polymer Chemistry. (2021) (0)
- Low pressure carbonylation of heterocycles (2009) (0)
- CCDC 1001989: Experimental Crystal Structure Determination : (mu~2~-3,3'-bis((2-((3,5-Di-t-butyl-2-oxybenzylidene)amino)cyclohexyl)carbonoimidoyl)-1,1'-binaphthalene-2,2'-diolato)-tetrakis(pyridine)-di-cobalt dichloride pyridine unknown solvate (2014) (0)
- CCDC 601862: Experimental Crystal Structure Determination (2006) (0)
- Living Transition Metal-Catalyzed Alkene Polymerization (2012) (0)
- Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism (2005) (0)
- Tailored Living Block Copolymerization (2012) (0)
- Relationship between mechanical properties and chain architectures of semicrystalline thermoplastic elastomeric triblock polyolefins (2007) (0)
- Influence of Ion-Exchange Capacity on the Solubility, Mechanical Properties, and Mass Transport of Anion-Exchange Ionomers for Alkaline Fuel Cells (2023) (0)
- Quaternary Ammonium-Functionalized Polyethylene-Based Anion Exchange Membranes: Balancing Performance and Stability (2023) (0)
- Weighing Paper Substitute (2005) (0)
- Carbonylation of epoxides to substituted 3-hydroxy-delta-lactones. (2007) (0)
- Enantioenriched β‐Lactone and Aldol‐Type Products from Regiodivergent Carbonylation of Racemic cis‐Epoxides. (2014) (0)
- Supporting Information: New Routes to Diblock Copolymers: Pre-Rate-Determining Selectivity in the Terpolymerization of Epoxides, Cyclic Anhydrides and CO2 (2008) (0)
- POLYCARBONATES FROM LIMONENE OXIDE AND CO2 (2005) (0)
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