Gerard Van Koten
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Gerard Van Kotenchemistry Degrees
Chemistry
#5685
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Inorganic Chemistry
#319
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#335
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Chemistry
Gerard Van Koten's Degrees
- PhD Chemistry University of Amsterdam
- Masters Chemistry University of Amsterdam
- Bachelors Chemistry University of Amsterdam
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(Suggest an Edit or Addition)Gerard Van Koten's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Platinum Group Organometallics Based on "Pincer" Complexes: Sensors, Switches, and Catalysts. (2001) (1105)
- Mononuclear non-heme iron enzymes with the 2-His-1-carboxylate facial triad: recent developments in enzymology and modeling studies. (2008) (388)
- The mechanism of the modified Ullmann reaction. (2010) (291)
- The use of ultra- and nanofiltration techniques in homogeneous catalyst recycling. (2002) (199)
- Ligand-free copper-catalyzed C-S coupling of aryl iodides and thiols. (2008) (192)
- Cyclometalated ruthenium complexes for sensitizing nanocrystalline TiO2 solar cells. (2007) (139)
- Consequences of N,C,N'- and C,N,N'-coordination modes on electronic and photophysical properties of cyclometalated aryl ruthenium(II) complexes. (2009) (134)
- Metallasupramolecular architectures, an overview of functional properties and applications. (2006) (132)
- Hexacationic Dendriphos ligands in the Pd-catalyzed Suzuki-Miyaura cross-coupling reaction: scope and mechanistic studies. (2009) (105)
- Selective Hydrovinylation of Styrene in a Membrane Reactor: Use of Carbosilane Dendrimers with Hemilabile P,O Ligands. (1999) (100)
- "Click" 1,2,3-triazoles as tunable ligands for late transition metal complexes. (2007) (89)
- Catalytic performance of symmetrical and unsymmetrical sulfur-containing pincer complexes: synthesis and tandem catalytic activity of the first PCS-pincer palladium complex. (2008) (81)
- Iron(II) complexes with bio-inspired N,N,O ligands as oxidation catalysts: olefin epoxidation and cis-dihydroxylation. (2008) (81)
- A highly fluorous room-temperature ionic liquid exhibiting fluorous biphasic behavior and its use in catalyst recycling. (2002) (80)
- Synthesis and properties of para-substituted NCN-pincer palladium and platinum complexes. (2004) (79)
- Lipase active-site-directed anchoring of organometallics: metallopincer/protein hybrids. (2005) (77)
- Aminoarenethiolate-copper(I)-catalyzed amination of aryl bromides. (2005) (75)
- Modeling the 2-His-1-carboxylate facial triad: iron-catecholato complexes as structural and functional models of the extradiol cleaving dioxygenases. (2007) (75)
- Selective liquid-phase semihydrogenation of functionalized acetylenes and propargylic alcohols with silica-supported bimetallic palladium-copper catalysts. (2001) (74)
- Shape-persistent nanosize organometallic complexes: synthesis and application in a nanofiltration membrane reactor. (2003) (73)
- Bifunctional pincer-type organometallics as substrates for organic transformations and as novel building blocks for polymetallic materials. (2002) (71)
- Hetero-aggregate compounds of aryl and alkyl lithium reagents: a structurally intriguing aspect of organolithium chemistry. (2005) (68)
- New peptide labels containing covalently bonded platinum(II) centers as diagnostic biomarkers and biosensors. (2000) (62)
- SPR Studies of Carbohydrate–Protein Interactions: Signal Enhancement of Low‐Molecular‐Mass Analytes by Organoplatinum(II)‐Labeling (2005) (60)
- Steric, electronic, and secondary effects on the coordination chemistry of ionic phosphine ligands and the catalytic behavior of their metal complexes. (2011) (59)
- Zeolite framework stabilized copper complex inspired by the 2-His-1-carboxylate facial triad motif yielding oxidation catalysts. (2006) (53)
- Ionic core-shell dendrimers with an octacationic core as noncovalent supports for homogeneous catalysts. (2006) (50)
- Multiple use of soluble metallodendritic materials as catalysts and dyes. (2001) (49)
- Synthesis and supramolecular association of immobilized NCN-pincer platinum(II) complexes on hyperbranched polyglycerol supports. (2004) (48)
- Probing the mer- to fac-isomerization of tris-cyclometallated homo- and heteroleptic (C,N)3 iridium(III) complexes. (2008) (48)
- Redox chemistry and electronic properties of 2,3,5,6-tetrakis(2-pyridyl)pyrazine-bridged diruthenium complexes controlled by N,C,N'-biscyclometalated ligands. (2009) (45)
- A Homologous Series of Homoleptic Zinc Bis(1,4-di-tert-butyl-1,4-diaza-1,3-butadiene) Complexes: K(x)[Zn(t-BuNCHCHN-t-Bu)(2)], Zn(t-BuNCHCHN-t-Bu)(2), and [Zn(t-BuNCHCHN-t-Bu)(2)](OTf)(x) (x = 1, 2). (1998) (43)
- Macrocycle synthesis by olefin metathesis on a nanosized, shape-persistent tricationic platinum template. (2003) (43)
- Tuning the reactivity of metals held in a rigid ligand environment (1989) (42)
- Polycationic (mixed) core-shell dendrimers for binding and delivery of inorganic/organic substrates. (2001) (42)
- Diorganoruthenium complexes incorporating noninnocent [C(6)H(2)(CH(2)ER(2))(2)-3,5](2)(2-) (E = N, P) bis-pincer bridging ligands: synthesis, spectroelectrochemistry, and DFT studies. (2007) (41)
- Vanadium(IV) and -(V) complexes with O,N-chelating aminophenolate and pyridylalkoxide ligands. (2000) (41)
- Synthesis and resolution of planar-chiral ruthenium-palladium complexes with ECE' pincer ligands. (2009) (41)
- Covalently bonded platinum(II) complexes of alpha-amino acids and peptides as a potential tool for protein labeling. (2002) (40)
- Detection of ppm quantities of gaseous SO2 by o9rganoplatinum dendritic sites immobilised on a quartz microbalance. (2001) (40)
- Copper(I) thiolate catalysts in asymmetric conjugate addition reactions. (2004) (38)
- Monomeric Bis(eta(2)-alkyne)copper(I) and -silver(I) Halides, Pseudohalides, and Arenethiolates. (1996) (38)
- Mono(NCN-pincer palladium)-metalloporphyrin catalysts: evidence for supramolecular bimetallic catalysis. (2010) (38)
- Iron(III)-catecholato complexes as structural and functional models of the intradiol-cleaving catechol dioxygenases. (2007) (37)
- A polycationic dendrimer as noncovalent support for anionic organometallic complexes. (2002) (36)
- Synthesis and self-assembly of giant porphyrin discs. (2004) (35)
- A novel heteroditopic terpyridine-pincer ligand as building block for mono- and heterometallic Pd(II) and Ru(II) complexes. (2006) (33)
- Organoplatinum(II) complexes as a color biomarker in solid-phase peptide chemistry and screening. (2003) (32)
- Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand. (2002) (32)
- C(arenium)-C(alkyl) bond making and breaking: key process in the platinum-mediated C(aryl)-C(alkyl) bond formation. Analogies to organic electrophilic aromatic substitution. (2001) (30)
- Diastereopure Fe(II) and Zn(II) complexes derived from a tridentate N,N',N-bis(methyl-L-prolinate)-substituted pyridine ligand. (2006) (30)
- Solid-state structural characterization of cutinase-ECE-pincer-metal hybrids. (2009) (30)
- Chemistry of Bis(aryloxo)palladium(II) Complexes with N-Donor Ligands: Structural Features of the Palladium-to-Oxygen Bond and Formation of O-H.O Bonds. (1996) (29)
- The first homologous series of self-assembled aryl bromo- and aryl cyanocuprates, -argentates, and -aurates; MLi(2)XAr(2) (M = Cu(I), Ag(I), Au(I); X = Br, C(triple bond)N; Ar = [C(6)H(4)CH(2)N(Et)CH(2)CH(2)NEt(2)-2]-). (2002) (28)
- Dendritic supports in organic synthesis. (2002) (28)
- Sulfato-bridged ECE-pincer palladium(II) complexes: structures in the solid-state and in solution, and catalytic properties. (2009) (28)
- sigma-Bond Metathesis Reactions Involving Palladium(II) Hydride and Methyl Complexes: A Theoretical Assessment. (1997) (26)
- Pincer-porphyrin hybrids. (2004) (26)
- Homogeneous Reactions in Supercritical Carbon Dioxide Using a Catalyst Immobilized by a Microporous Silica Membrane. (2001) (25)
- Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III) alkylperoxo complex. (2007) (24)
- A new, easily recyclable arylating agent based on a diphosphino-digold(I) complex. (2007) (23)
- The monoanionic pincer-metal platform: a scaffold for meeting challenges in catalysis and materials research. (2011) (23)
- One-dimensional, cofacial porphyrin polymers formed by self-assembly of meso-tetrakis(ERE donor) zinc(II) porphyrins. (2007) (23)
- Cu K-edge EXAFS characterisation of copper(I) arenethiolate complexes in both the solid and liquid state: detection of Cu-Cu coordination. (2002) (23)
- Selective para-halogenation and dimerization of N,C,N'-arylruthenium(II) and -(III) 2,2':6',2''-terpyridine cations. (2010) (23)
- New Pt …︁ HN bonds characterized by 15N‐filtered and 2D NOESY 1H NMR spectroscopy (1992) (22)
- Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines. (2011) (21)
- 119Sn NMR study of organotin compounds having intramolecular Sn—N coordination (1991) (21)
- One-pot synthesis and immobilisation of sulfonate-tethered N-heterocyclic carbene complexes on polycationic dendrimers. (2009) (20)
- Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. (2006) (20)
- Transcyclometalation, a versatile methodology for multiple metal-carbon bond formation with multisite ligands. (2002) (20)
- Oxidative double dehalogenation of tetrachlorocatechol by a bio-inspired CuII complex: formation of chloranilic acid. (2008) (19)
- Functionalized carbosilane dendritic species as soluble supports in organic synthesis. (2000) (19)
- Formation of organolithium hetero-aggregates [Li4Ar2(nBu)2] (Ar=C6H4CH(Me)NMe2-2) during the directed ortho-lithiation of [1-(dimethylamino)ethyl]benzene. (2004) (18)
- Enzymatic immobilization of organometallic species: biosilification of NCN- and PCP-pincer metal species using demosponge axial filaments. (2009) (18)
- Platinum Group Organometallics Based on "Pincer" Complexes: Sensors, Switches, and Catalysts In memory of Prof. Dr. Luigi M. Venanzi and his pioneering work in organometallic chemistry, particularly in PCP pincer chemistry. (2001) (18)
- SCS-pincer palladium-catalyzed auto-tandem catalysis using dendritic catalysts in semi-permeable compartments. (2011) (18)
- Dialyzable carbosilane dendrimers as soluble supports for the functionalization of pyridine fragments via palladium-catalyzed coupling reactions. (2005) (18)
- Construction of a monoanionic S,N,S-pincer ligand with a pyrrole core by sequential [1,2] phospho-Fries rearrangement. Characterization of palladium and silver coordination complexes. (2010) (18)
- Mono N,C,N-pincer complexes of titanium, vanadium and niobium. Synthesis, structure and catalytic activity in olefin polymerisation. (2011) (17)
- Synthesis and Catalytic Properties of Di- and Trinuclear Palladium Complexes with PCP-Pincer Ligands (2003) (16)
- Organometallic benzylidene anilines: donor-acceptor features in NCN-pincer Pt(ii) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent. (2014) (16)
- Synthesis of and evidence for electronic communication within heteromultimetallic tetrakis(NCN-pincer metal)-(metallo)porphyrin hybrids. (2010) (16)
- Directed ortho-lithiation: observation of an unexpected 1-lithio to 3-lithio conversion of 1-lithio-naphthyllithium compounds with an ortho-directing 2-(dimethylamino)methyl group. (2013) (15)
- 183W NMR spectroscopy of W(VI) imidoaryl and imidoalkyl complexes using inverse detection based on non‐specific long‐range interactions (1994) (14)
- Structural Aspects of Lithium Arenethiolate Complexes with Intramolecular Coordinating Amine Donors. (1996) (13)
- A Mixed (Arenethiolato)copper(I)/Copper Bromide Aggregate: X-ray Structure of Octanuclear [Cu(8){SC(6)H(3)(CH(2)NMe(2))(2)-2,6}(3)Br(5)]. (1996) (13)
- Neutral pyridyl-functionalized C,N-ortho-chelated aminoaryl platinum(II) corner building blocks for application in coordination reactions. (2005) (13)
- Platinum- and palladium-catalysed Kocheshkov redistribution of dialkyltin dichlorides or tetraalkyltins with tin tetrachloride. (2001) (12)
- Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium. (2008) (12)
- AXAFS as a probe of charge redistribution within organometallic complexes. (2004) (11)
- 1H,1H,2H,2H-perfluoroalkyl-functionalization of Ni(II), Pd(II), and Pt(II) mono- and diphosphine complexes: minimizing the electronic consequences for the metal center. (2003) (11)
- Diastereoselective self-assembly of chiral diamine-chelated aryllithiums to dimeric aggregates. (2004) (11)
- Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate (2007) (10)
- Parallel synthesis and study of fluorous biphasic partition coefficients of 1H,1H,2H,2H-perfluoroalkylsilyl derivatives of triphenylphosphine: a statistical approach. (2004) (10)
- Palladium(II) Arenethiolates with Chelating Diamines: Formation of N-H.S Hydrogen Bonds with Protonated N,N,N',N'-Tetramethylethylenediamine. (1996) (10)
- SO2-binding properties of cationic η6,η1-NCN-pincer arene ruthenium platinum complexes: spectroscopic and theoretical studies. (2011) (9)
- Template-Directed Synthesis of Macroheterocycles by Ring-Closing Metathesis of Olefin-Substituted Pyridines in the Coordination Sphere of a Triplatinum Complex (2003) (8)
- Mechanistic studies on the SCS-pincer palladium(II)-catalyzed tandem stannylation/electrophilic allylic substitution of allyl chlorides with hexamethylditin and benzaldehydes. (2013) (7)
- A [4Fe-4S] cluster dimer bridged by bis(2,2':6',2''-terpyridine-4'-thiolato)iron(II). (2008) (6)
- Synthesis of multimetallic dendrimers through non-covalent interactions. (2012) (5)
- Imidazolylidene Cu(II) Complexes: Synthesis Using Imidazolium Carboxylate Precursors and Structure Rearrangement Pathways. (2019) (5)
- (3R,4S)-3-phenyl-1-[(R)-1-phenylethyl]-4-[(R)-1-phenylethyliminomethyl] azetidin-2-one. (2000) (5)
- Octupolar organometallic Pt(II) NCN-pincer complexes; Synthesis, electronic, photophysical, and NLO properties (2017) (5)
- Novel aspects of η'-diiodine coordination and diiodine oxidative addition to platinum(II) and halide transfer oxidation reactions of organo-platinum(II) with CuIIX2 (1990) (4)
- Hybrid POCZP Aryl Pincer Metal Complexes and their Catalytic Applications (2020) (4)
- Replacing the Z-phenyl Ring in Tamoxifen® with a para-Connected NCN Pincer-Pt-Cl Grouping by Post-Modification † (2021) (1)
- The assembling of a catalytic active copper site, in solution, followed by EXAFS. (1999) (1)
- Multipole refinement of 2-(indol-3-yl)-1,1,3,3-tetramethylthiouronium nitrate. (2008) (1)
- Indole-3-thiouronium nitrate (2007) (1)
- Asymmetric catalysis with chiral organocopper-copper arenethiolates (1994) (1)
- Indole-3-thiouronium iodide (2007) (0)
- Bimetallic complexes that merge metallocene and pincer-metal building blocks: synthesis, stereochemistry and catalytic reactivity. (2022) (0)
- Homogeneous vanadium-based catalysts for the Ziegler-Natta polymerization of alpha-olefins. (2002) (0)
- A Proposal for Positive Cooperativity in Anion-Cation Binding in Yttrium and Lutetium Complexes Based on o-Amino-Substituted Phenolate Ligands. On the Way to Coordination Polymers by Self-Assembly. Molecular Structures of [ClLu(OAr)(3)Na] (X-ray) and [ClY(OAr')(3)Y(OAr')(3)Na] (X-ray and (89)Y-NMR). (1996) (0)
- Organic transformations on sigma-aryl organometallic complexes. (2007) (0)
- Synthesis and Characterization of Bis(arenethiolato)magnesium Complexes with Intramolecular Coordination. X-ray Structure of [Mg{S(C(6)H(4)-2-CH(2)NMe(2))}(2)](2). (1996) (0)
- Influence of Intramolecular Coordination on the Aggregation of Sodium Phenolate Complexes. X-ray Structures of [NaOC(6)H(4)(CH(2)NMe(2))-2](6) and [Na(OC(6)H(2)(CH(2)NMe(2))(2)-2,6-Me-4)(HOC(6)H(2)(CH(2)NMe(2))(2)-2,6-Me-4)](2). (1996) (0)
- List of Contributors (2019) (0)
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