Gilbert Stork
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Belgian American chemist
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Chemistry
Why Is Gilbert Stork Influential?
(Suggest an Edit or Addition)According to Wikipedia, Gilbert Stork was an organic chemist. For a quarter of a century he was the Eugene Higgins Professor of Chemistry Emeritus at Columbia University. He is known for making significant contributions to the total synthesis of natural products, including a lifelong fascination with the synthesis of quinine. In so doing he also made a number of contributions to mechanistic understanding of reactions, and performed pioneering work on enamine chemistry, leading to development of the Stork enamine alkylation. It is believed he was responsible for the first planned stereocontrolled synthesis as well as the first natural product to be synthesised with high stereoselectivity.
Gilbert Stork's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The Enamine Alkylation and Acylation of Carbonyl Compounds (1963) (822)
- The Stereochemistry of Polyene Cyclization (1955) (303)
- Isolation of ketone enolates as trialkylsilyl ethers (1968) (269)
- A stereoselective synthesis of (Z)-1-iodo-1-alkenes (1989) (257)
- Stereocontrolled synthesis of disaccharides via the temporary silicon connection (1992) (210)
- A New Method for the Alkylation of Ketones and Aldehydes: the C-Alkylation of the Magnesium Salts of N-Substituted Imines (1963) (205)
- A simple method of dethioacetalization (1989) (200)
- A catalytic tin system for trapping of radicals from cyclization reactions. Regio- and stereocontrolled formation of two adjacent chiral centers (1986) (194)
- Regiospecific alkylation of cyclic .beta.-diketone enol ethers. General synthesis of 4-alkylcyclohexenones (1973) (192)
- A NEW SYNTHESIS OF 2-ALKYL AND 2-ACYL KETONES (1954) (184)
- Alkylation and Michael additions of glycine ethyl ester. Use in alpha-amino acid synthesis and as acyl carbanion equivalent. (1976) (182)
- The Total Synthesis of dl-Aspidospermine and of dl-Quebrachamine (1963) (158)
- Cyclization of vinyl radicals: a versatile method for the construction of five- and six-membered rings (1982) (156)
- Free-radical cyclization of bromo acetals. Use in the construction of bicyclic acetals and lactones (1983) (153)
- Alkylation and Carbonation of Ketones by Trapping the Enolates from the Reduction of α,β-Unsaturated Ketones (1965) (148)
- Generation, nuclear magnetic resonance spectra, and alkylation of enolates from trialkylsilyl enol ethers (1968) (145)
- The first stereoselective total synthesis of quinine. (2001) (145)
- Stereocontrol in homogeneous catalytic hydrogenation via hydroxyl group coordination (1983) (137)
- Control of ring junction stereochemistry via radical cyclization (1985) (134)
- Vinyl radical cyclizations mediated by the addition of stannyl radicals to triple bonds (1987) (131)
- Ring size in epoxynitrile cyclization. General synthesis of functionally substituted cyclobutanes. Application to (+-)-grandisol (1974) (128)
- Anions of protected cyanohydrins as acyl carbanion equivalents and their use in a new synthesis of ketones (1971) (127)
- Vinyl radical cyclization. 2. Dicyclization via selective formation of unsaturated vinyl radicals by intramolecular addition to triple bonds. Applications to the synthesis of butenolides and furans (1983) (126)
- Chiral synthesis of prostaglandins (PGE1) from D-glyceraldehyde. (1977) (126)
- .alpha.-Silylated vinyl ketones. New class of reagents for the annelation of ketones (1973) (119)
- New synthesis of aldehydes via vinylsilanes (1971) (115)
- Radical cyclization-trapping in the synthesis of natural products. A simple, stereocontrolled route to prostaglandin F2.alpha. (1986) (110)
- Five vs six membered ring formation in the vinyl radical cyclization (1986) (109)
- INTRAMOLECULAR CYCLIZATION OF UNSATURATED DIAZOKETONES (1961) (107)
- Regiospecific trapping of radicals from cyclization reactions. Cyclic nitriles via isocyanide trapping (1983) (102)
- A NEW RING ENLARGEMENT SEQUENCE (1956) (99)
- The temporary silicon connection method in the control of regio- and stereochemistry. Applications to radical-mediated reactions. The stereospecific synthesis of C-glycosides (1991) (96)
- Concise total synthesis of (+)-(9S)-dihydroerythronolide A (1987) (93)
- A NEW ALKYLATION OF CARBONYL COMPOUNDS. II1 (1956) (89)
- Total synthesis of prostaglandin F2.alpha. by chirality transfer from D-glucose (1978) (87)
- Letter: A simple total synthesis of prostaglandins from 4-cumyloxy-2-cyclopentenone. (1975) (87)
- Epoxynitrile cyclization. General method of ring formation (1974) (86)
- Letter: Chiral synthesis of prostaglandins from carbohydrates. Synthesis of (+)-15-(S)-prostaglandin A2. (1976) (84)
- Radical cyclization of allylic haloacetamides a route to cis-fused 2-pyrrolidones and piperidones (1989) (82)
- A Stereospecific Synthesis of Cantharidin (1953) (81)
- A simplified total synthesis of cytochalasins via an intramolecular Diels-Alder reaction (1983) (80)
- Stereospecific reductive methylation via a radical cyclization-desilylation process (1986) (79)
- Total synthesis of cytochalasin B (1978) (79)
- A highly stereoselective osmium tetroxide-catalyzed hydroxylation of γ-hydroxy α,β-usaturated esters (1983) (78)
- Vinylsilanes as carbonyl precursors. Use in annelation reactions (1974) (78)
- REGIOSPECIFIC MICHAEL REACTIONS IN APROTIC SOLVENTS WITH ALPHA-SILYLATED ELECTROPHILIC OLEFINS, APPLICATION TO ANNELATION REACTIONS (1974) (77)
- Conjugate addition of acyl carbanion equivalents via the protected cyanohydrin method (1974) (76)
- The total synthesis of dl-camptothecin. (1971) (75)
- The Stereochemistry of the SN2' Reaction. II1 (1956) (73)
- Cedrol: Stereochemistry and Total Synthesis (1961) (73)
- Synthetic routes to halomethyl vinylsilanes (1974) (71)
- The Total Synthesis of a Natural Cardenolide: (+)-Digitoxigenin (1996) (70)
- The stereospecific total synthesis of dl-lycopodine. (1968) (70)
- Letter: A general approach to prostaglandins via methylenecyclopentanones. Total synthesis of (+/- prostaglandin F2 alpha. (1975) (64)
- Spiroannelation of enol ethers of cyclic 1,3-diketones. Simple stereospecific synthesis of .beta.-vetivone (1973) (64)
- Regiospecific aldol condensations of the kinetic lithium enolates of methyl ketones (1974) (62)
- Condensation of formaldehyde with regiospecifically generated anions (1974) (62)
- Monoalkylation of .alpha.,.beta.-unsaturated ketones via metalloenamines (1971) (61)
- Iterative butenolide construction of polypropionate chains (1987) (60)
- Total syntheses of (-)-histrionicotoxin and (-)-histrionicotoxin 235A (1990) (60)
- Regiospecific and stereoselective syntheses of (+/-) morphine, codeine, and thebaine via a highly stereocontrolled intramolecular 4 + 2 cycloaddition leading to a phenanthrofuran system. (2009) (59)
- STEREOCHEMICAL CONTROL OF THE INTERNAL MICHAEL REACTION. A NEW CONSTRUCTION OF TRANS-HYDRINDAN SYSTEMS (1982) (58)
- THE α-ALKYLATION OF ENOLATES FROM THE LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES (1961) (58)
- Allylic radicals in cyclization reactions (1988) (57)
- Synthesis of d,l-muscone from cyclododecanone (1975) (56)
- Letter: Highly stereoselective total syntheses of prostaglandins via stereospecific sulfenate-sulfoxide transformations. 13-Cis-15beta-prostaglandins E1 to prostaglandins E1. (1974) (56)
- Isoxazole annelation reaction. Method for the construction of cyclohexenone rings in polycyclic systems (1967) (56)
- A New Synthesis of 1,4- and 1,5-Diketones (1964) (55)
- Regiospecific and stereoselective syntheses of (+/-)-reserpine and (-)-reserpine. (2005) (55)
- Vinyl radical cyclization in the synthesis of natural products: seychellene (1985) (54)
- 3-Benzyloxyisoxazole system in construction of tetracyclines (1978) (53)
- The stereospecific synthesis of reserpine (1989) (52)
- A New Cyclization. 2-Methylenecyclopentanols by the Chemical Reduction of γ-Ethinyl Ketones (1965) (51)
- Radical Cyclization in the Control of Regio- and Stereochemistry (1988) (51)
- Stereoselective total syntheses of (plus minus)-yohimbine, (plus minus)-psi-yohimbine, and (plus minus)- -yohimbine. (1972) (51)
- Total synthesis of lupeol (1971) (51)
- Stereospecific total synthesis of steroids via isoxazole annelation. dl-D-Homotestosterone and dl-progesterone (1967) (50)
- Stereocontrolled Synthesis of (±)-12a-Deoxytetracycline (1996) (50)
- Stereoselective synthesis of the chiral sequence of erythronolide A (1982) (50)
- The temporary silicon connection in the control of the regiochemistry of 4 + 2 cycloadditions (1992) (50)
- Progress in the synthesis of polycyclic natural products: The total synthesis of lycopodine (1968) (48)
- A New Synthesis of Cyclohexenones: The Double Michael Addition of Vinyl Ethynyl Ketones to Active Methylene Compounds. Application to the Total Synthesis of dl-Griseofulvin (1964) (48)
- Large-ring lactones by internal ketophosphonate cyclizations (1979) (44)
- Stereochemical control of intramolecular conjugate addition. A short, highly stereoselective synthesis of adrenosterone (1982) (44)
- The Stereochemistry of the SN2' Reaction. I. Preparation of Pure trans-6-Alkyl-2-cyclohexen-1-ols (1956) (44)
- Regiocontrol by electron withdrawing groups in the Rh-catalyzed CH insertion of α-diazoketones (1988) (44)
- Versatile synthesis of cyclopentenones (1971) (43)
- STEREOCHEMISTRY OF THE LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES (1960) (41)
- Synthesis of allylic halides and 1,5-dienes from allylic alcohols (1969) (41)
- Reductive cyclization of ethynyl ketones in the construction of a significant tricyclic intermediate for the synthesis of gibberellic acid (1979) (40)
- The Total Synthesis of Cedrol and Cedrene (1955) (39)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. III. Formation of the bicyclo[2.2.1]heptane system (1969) (39)
- 2-Substituted tetrahydrofurans of known absolute stereochemistry by ScN' chirality transfer (1983) (38)
- The Total Synthesis ofdl-Dehydroabietic Acid (1962) (38)
- THE STRUCTURE OF CEDRENE (1953) (38)
- Six-membered rings via olefin participation in the opening of acylcyclopropanes (1969) (37)
- Four-Membered Sulfones From Enamines and Aliphatic Sulfonyl Halides (1962) (37)
- The Base Effect in Catalytic Hydrogenation. A Simple Synthesis of 6-Methoxy-α-tetralone (1947) (36)
- Cine substitution in vinylstannane cross-coupling reactions (1990) (36)
- Enantioselective synthesis of an intermediate for the intramolecular Diels-Alder construction of 11-ketosteroids (1987) (35)
- The use of kinetically generated unstable enolate ions in the regiospecific formation of carbonxarbon bonds. Specific applications to annelation processes (1975) (35)
- Letter: A route to prostaglandins via a general synthesis of 4-hydroxycyclopentenones. (1975) (34)
- New route to 11-oxygenated steroids (1981) (34)
- Aryl participation in concerted cyclization of cyclopropyl ketones (1969) (33)
- Temporary Magnesium and Aluminum Connections in [4 + 2] Cycloadditions (1995) (33)
- .alpha.-Alkylation and arylation of .alpha.,.beta.-unsaturated ketones (1976) (33)
- CANTHARIDIN. A STEREOSPECIFIC TOTAL SYNTHESIS (1951) (33)
- The Ene reaction as a route to 3-hydroxycyclopentanone derivatives. Application to the prostaglandins. (1976) (32)
- THE STEREOCHEMISTRY OF THE Sn2' REACTION (1953) (30)
- A New Synthesis of Vinylogous Aldols and Polyenones (1976) (30)
- CONCERTED INTRAMOLECULAR DISPLACEMENT WITH REARRANGEMENT IN ALLYLIC SYSTEMS. DISPLACEMENT OF AN ALLYLIC ESTER WITH A CARBANION (1979) (30)
- Haloketal cyclization. General method for the synthesis of functionalized cis bicyclic ketones (1973) (30)
- Mechanism and stereochemical control in the .alpha.-haloketal cyclization. Remarkable effect of metal cations (1973) (30)
- Stereochemistry of the SN2' reaction. "Concerted" allylic displacement in an acyclic system: anti displacement with thiolate anion (1977) (29)
- Additions and Corrections - A Stereocontrolled Synthesis of the (±) Djerassi-Prelog Lactonic Acid (1979) (29)
- STEREOCHEMISTRY OF THE SN2′ REACTION IN CYCLOHEXENYL SYSTEMS (1977) (28)
- Introduction of angular methyl groups via radical cyclization (1989) (28)
- Synthesis and Reactions of Glycidonitriles. Transformation into α-Haloacyl Compounds and Aminoalcohols (1960) (28)
- The Synthesis of Substituted 1-Methylcyclohexanecarboxylic Acids and the Stereochemistry of the Favorski[UNK]i Rearrangement (1960) (28)
- Optical Rotatory Dispersion Studies. XCII.1 Some Observations on the Conformation of cis-10-Methyl-2-decalones2 (1964) (28)
- Efficient de novo construction of the indanepropionic acid precursor of 11-oxo steroids. An improved internal Diels-Alder sequence (1982) (27)
- Mechanism of the isoxazole annelation (1967) (27)
- REDUCTIVE ALKYLATION OF ENEDIONES. 1 (1980) (27)
- General synthesis of 4-isoxazolecarboxylic acids (1967) (27)
- N,N-diethylaminoacetonitrile a generally useful latent acyl carbanion (1978) (27)
- A NEW ROUTE TO HYDROPHENANTHRENE KETONES. THE SYNTHESIS OF THE C18 KETONE DERIVED FROM DEHYDROABIETIC ACID (1951) (27)
- A Stereospecific Total Synthesis of 18-Substituted Steroids. Application to the Synthesis of dl-Conessine (1962) (27)
- The allylic epoxide cyclization. A method for the control of regiochemistry and stereochemistry in cyclohexane systems (1990) (26)
- Stereochemical control in the construction of vicinally substituted cyclopentanes and cyclohexanes. Intramolecular conjugate addition of β-ketoester anions. (1983) (25)
- THE TOTAL SYNTHESIS OF dl-DEHYDROABIETIC ACID (1956) (25)
- An efficient synthesis of alkenyl and alkynyl silyl ethers (1989) (25)
- An approach to gelsemine (1987) (25)
- STEROIDS. XCIII.1 INTRODUCTION OF THE CORTICAL HORMONE SIDE-CHAIN (1958) (25)
- A Stereospecific Total Synthesis of Griseofulvin (1962) (25)
- A simple, stereospecific synthesis of the skeleton of the lycorine alkaloids (1979) (24)
- Reductive alkylation of enediones. 2. Synthesis of corticosteroids (1980) (23)
- Total Synthesis of Polycyclic Triterpenes: The Total Synthesis of (+)--Onocerin (2002) (23)
- A GENERAL APPROACH TO PROSTAGLANDINS VIA METHYLENECYCLOPENTANONES, TOTAL SYNTHESIS OF (+-)-PROSTAGLANDIN F(2ALPHA) (1975) (22)
- Five- and six-membered-ring formation from olefinic .alpha.,.beta.-epoxy ketones and hydrazine (1977) (22)
- Piperidine derivatives; the preparation of l-benzoyl-3-carbethoxy-4-piperidone; a synthesis of guvacine. (1946) (22)
- A Synthesis of cis-Jasmone (1964) (22)
- LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES. II. FORMATION AND ALKYLATION OF A β-CARBANION INTERMEDIATE (1961) (22)
- Pyridine synthesis via 4-(3-oxoalkyl)isoxazoles (1971) (20)
- A total synthesis of rac-patchouli alcohol (1995) (18)
- An Enantioselective Construction of the ABC System of Taxol (1998) (18)
- Transformation of 4-(3-oxoalkyl)isoxazoles into pyridines (1967) (18)
- Regiospecificity in the cyclization of 6-(1-hydroxyalkyl) geraniol derivatives. A simple route to the taxol a-ring system (1994) (18)
- Deprotonation of Chelating Enamines. Direct Formation of β-Lithio Enamines (1986) (18)
- Sex hormones; a synthesis of 1-keto-7-methoxy-1,2,3,4-tetrahydrophenanthrene and of 1-keto-7-methoxy-1,2,3,4,9,10-hexahydrophenanthrene. (1947) (18)
- Carboxy beta-lactams by photochemical ring contraction. (1974) (17)
- A general synthesis of esters of acryloyl acetic acid and their homologs. (1972) (17)
- Total synthesis of (+-)-byssochlamic acid (1972) (17)
- The Stereospecific Synthesis of dl-Alloyohimbane and dl-3-Epialloyohimbane1 (1954) (17)
- A TOTAL SYNTHESIS OF 1-OXYGENATED STEROIDS1 (1956) (17)
- An intramolecular diels-alder approach to the galanthan ring system (1979) (17)
- STEROIDS. XXVIII.1 INTRODUCTION OF THE 11-KETO AND 11α-HYDROXY GROUPS INTO RING C UNSUBSTITUTED STEROIDS (PART 2) (1951) (17)
- The SN2' Reaction. III. Structure and SN2' Reactions of the Halocodides (1956) (16)
- The Stobbe Condensation with Cyclohexanone (1948) (16)
- An isomerization—claisen rearrangement route to olefinic dicarbonyl starting materials for conjugate cyclization (1982) (16)
- THE STEREOCHEMISTRY OF GIBBERELLIC ACID (1959) (16)
- Synthesis of small rings via the protected cyanohydrin method. (1975) (15)
- A ROUTE TO PROSTAGLANDINS VIA A GENERAL SYNTHESIS OF 4-HYDROXYCYCLOPENTENONES (1975) (15)
- Progress in the synthesis of polycyclic natural products (1964) (15)
- Piperidine derivatives; C-alkylation of l-benzoyl-3-carbethoxy-4-piperidone; synthesis of ethyl 3-ethyl-4-piperidylacetate (d1-ethyl cincholoiponate). (1946) (15)
- Modified ollgonucleotides. Effect of 4 vs 5-atom chimeric internucleoside linkages on duplex stability (1995) (14)
- Acid catalyzed intramolecular conjugate addition as a route to trans hydrindane systems (1983) (14)
- Iterative butenolide construction of polypropionate chains. Application to an efficient synthesis of (+)(9S)-dihydroerythronolide A (1987) (14)
- The Reduction of Thebaine (1952) (13)
- Stereochemistry of the SN2' reaction in cyclohexenyl systems (1977) (13)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. IV. Cyclization of 5-methyl-6--(-3-pentenyl)bicyclo(3.1.0)hexan-2-one. (1971) (13)
- Highly stereoselective axial addition of ethynyl carbanions to the carbonyl of cyclohexenones (1984) (13)
- A method for the transformation of cyclic ketones to homologous α,β-unsaturated ketones (1966) (13)
- Monoalkylation of α,β‐Unsaturated Ketones via Metalloenamines: 1‐Butyl‐10‐methyl‐Δ1(9)‐2‐octalone (2003) (12)
- THE TOTAL SYNTHESIS OF A NATURALLY OCCURRING PENTACYCLIC TRITERPENE SYSTEM (1959) (12)
- Use of a Lithiolactone in the Enantioselective Constructions of A/C seco-B and of A/B seco-C proTaxol Systems (1997) (12)
- A general method for the stereocontrolled synthesis of polypropionate-derived sequences (1986) (11)
- SYNTHESIS OF 17,18-BISNORSTEROIDS (1958) (11)
- Synthese stereoselective des barcis et bartrans carboxy-4 (1983) (11)
- Comprehensive organic chemistry, volume 3 (sulphur, selenium, silicon, boron, organometallic compounds): Edited by D. Neville Jones (1979) (11)
- Steroids. XXXI.1Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (Part 4).2Saturated 7,11-Diones (1952) (11)
- THE STEREOCHEMISTRY OF ALLOGIBBERIC ACID AND OF GIBBERIC ACID (1959) (11)
- A New Approach to the Stereospecific Synthesis of Angularly Substituted Polycyclic Systems (1969) (10)
- AN UNUSUALLY SIMPLE CONSTRUCTION OF RING A OF GIBBERELLIC ACID (1979) (10)
- Synthesis and Reactions of 1-Methyl-2-vinyl-4-hydroxycyclohexene (1953) (10)
- A convenient route to and trisubstituted olefins from geraniol and nerol (1969) (10)
- Theoretical studies of the lithiation of enamines (1988) (9)
- organocuprate reactions of enone lactones. I. Synthesis of trans-fused rings via conjugate addition. (1979) (9)
- Multiple Carbon Bond Formation Via the Radical Cyclization of Cycloalkenol Acetals. Application to trans Hydrindan Steroid Precursors (1992) (9)
- A general synthesis of alkyl-pyrrolones and dihydro-pyridones (1970) (8)
- Synthetic Study toward Total Synthesis of (±)-Germine: Synthesis of (±)-4-Methylenegermine. (2017) (8)
- TOTAL SYNTHESIS OF THE CEPHALOSPORIN ANTIBIOTICS. I. THE DIHYDROTHIAZINE SYSTEM OF CEPHALOSPORIN CC. (1965) (8)
- CHIRAL SYNTHESIS OF PROSTAGLANDINS FROM CARBOHYDRATES. SYNTHESIS OF (+)-15-(S)-PROSTAGLANDIN A2 (1976) (8)
- ALKYLATION AND MICHAEL ADDITIONS OF GLYCINE ETHYL ESTER. USE IN α-AMINO ACID SYNTHESIS AND AS ACYL CARBANION EQUIVALENT (1977) (8)
- AN EFFICIENT SYNTHESIS OF () METHYL EPIJASMONATE VIA THE RADICAL-MEDIATED HALOACETAL CYCLIZATION (1992) (8)
- Elaboration of the 1-Substituted 7,8-Dimethoxy-2-tetralones Toward the 13-Alkyl Hydrophenanthrene System of Morphine (1951) (8)
- THE STRUCTURE OF PHENOLIC DIHYDROTHEBAINE AND OF β-DIHYDROTHEBAINE (1951) (7)
- Additions and Corrections - Concerning the Stereochemistry of the SN2' Reaction in Cyclohexenyl Systems (1977) (7)
- The alkylation of enamines from α,β-unsaturated ketones1 (1961) (7)
- STEREOCHEMISTRY OF THE SN2′ REACTION. ′CONCERTED′ ALLYLIC DISPLACEMENT IN AN ACYCLIC SYSTEM- ANTI DISPLACEMENT WITH THIOLATE ANION (1977) (7)
- X-ray crystal structure of N-(2-lithiocyclohexenyl)-N,N′,N′-trimethyl-1,3-propanediamine: A pentavalent lithium? (1984) (7)
- THE STRUCTURE OF METOPON (1953) (7)
- Preparation of Ethyl β-Benzylaminopropionate and Benzyl-di-(β-carbethoxyethyl)-amine (1947) (6)
- CARBOXY BETA‐LACTAMS BY PHOTOCHEMICAL RING CONTRACTION (1974) (6)
- R. B. Woodward, 1917–1979 (1980) (6)
- THE REARRANGEMENT OF BROMONORCEDRENEDICARBOXYLIC ACID (1953) (6)
- A construction of the angularly hydroxylated cis 1,8-naphthalenedione system typical of the tetracyclines (1984) (6)
- Steroids. XXXII.1Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (Part 5). Δ8-7-Ketones (1952) (6)
- Simple preparation of a useful c/d-ring fragment for the construction of 11-keto steroids (1984) (6)
- Stereocontrolled Synthesis of Disaccharides via the Temporary Silicon Connection. (1992) (5)
- A STEREOSPECIFIC REACTION OF CARBON MONOXIDE (1960) (5)
- The Preparation of β-Tetralone by the Catalytic Reduction of β-Naphthol (1946) (5)
- A General Synthesis of cis Perhydro 3,6-Isoquinolinediones Related to the Alloyohimbane Alkaloids (1987) (5)
- A HIGHLY STEREOSELECTIVE OSMIUM TETROXIDE-CATALYZED HYDROXYLATION OF Γ-HYDROXY α,β-UNSATURATED ESTERS (1984) (4)
- The First Stereoselective Total Synthesis of Quinine [J. Am. Chem. Soc. 2001, 123 (14), 3239−3242]. (2001) (4)
- Radical Cyclization-Trapping in the Synthesis of Natural Products. A Simple, Stereocontrolled Route to Prostaglandin F2α. (1987) (4)
- Unusual regiospecificity in the enolization of a ketone as the result of differences in energy to achieve the best overlap of an alpha hydrogen (1979) (4)
- Elaboration of a tricyclic gibberellic acid intermediate (1980) (4)
- VINYL AND BETA-ALKOXY RADICALS IN ORGANIC SYNTHESIS (1983) (4)
- THE SYNTHESIS OF 3,4-DIAMINOCARBETHOXYFURAN (1945) (4)
- Simple total synthesis of prostaglandins from 4-cumyloxy-2-cyclopentenone (1976) (4)
- Radical-mediated Cyclization Processes (1985) (4)
- The Synthesis of Some 1-Substituted 7,8-Dimethoxy-2-tetralones (1951) (3)
- Routes to bicyclo [X.3.0] ring systems: stereoselective syntheses of and -8-methylhydrindans (1979) (3)
- Allylic Chlorides from Allylic Alcohols: Geranyl Chloride (2003) (3)
- Steroid Reactions, An Outline for Organic Chemists. (1964) (3)
- Comprehensive organic chemistry The synthesis and reactions of organic compounds: Volume 3 (Sulphur, Selenium, Silicon, Boron, Organometallic compounds; edited by D. Neville Jones, Sheffield) (1979) (3)
- The intramolecular Michael addition as a route to angularly substituted cis-hydrindanes (1978) (3)
- Heterocyclic Silyllithium Reagents as Precursors of Masked Hydroxyl Groups. Preliminary Results (1996) (2)
- FIVE- AND SIX-MEMBERED-RING FORMATION FROM OLEFINIC α,β-EPOXY KETONES AND HYDRAZINE (1978) (2)
- Enantioselective Synthesis of a trans-Hydrindane System for the Preparation of Vitamin D Metabolites. (1997) (2)
- Concise Total Synthesis of (+)‐(9S)‐Dihydroerythronolide A. (1987) (2)
- Temporary Magnesium and Aluminum Connections in (4 + 2) Cycloadditions. (1995) (2)
- A Simple Method of Dethioacetalization. (1989) (2)
- α-ALKYLATION AND ARYLATION OF α,β-UNSATURATED KETONES (1976) (1)
- Configuration of the C/D Ring Junction in Equilenin and Other Steroids (1950) (1)
- The Temporary Silicon Connection in the Control of the Regiochemistry of (4 + 2) Cycloadditions. (1993) (1)
- Chapter 7 The Morphine Alkaloids (1960) (1)
- CHIRAL SYNTHESIS OF PROSTAGLANDINS (PGE1) FROM D-GLYCERALDEHYDE (1977) (1)
- Additions and Corrections - Concerning the Stereochemistry of the SN2' Reaction. "Concerted" Allylic Displacement in an Acyclic System: Anti Displacement with Thiolate Anion (1977) (1)
- Efficient Regio- and Stereocontrolled Synthesis of Highly Functionalized Polycyclic Systems Using the Diels-Alder Addition of Stannyl-Substituted Vinylketeneacetals (1989) (1)
- The Temporary Silicon Connection Method in the Control of Regio- and Stereochemistry. Applications to Radical-Mediated Reactions. The Stereospecific Synthesis of C-Glycosides. (1991) (1)
- Preface (This volume is dedicated to Prof. Barry M. Trost on the occasion of his 65th birthday) (2006) (1)
- Additions and Corrections - A Synthesis of d,l-Muscone from Cyclododecanone (1976) (1)
- SYNTHESIS OF SMALL RINGS VIA THE PROTECTED CYANOHYDRIN METHOD (1975) (1)
- N,N-DIETHYLAMINOACETONITRILE, A GENERALLY USEFUL LATENT ACYL CARBANION (1979) (1)
- Vereinfachtes Additionsverfahren in der Atomabsorptionsspektrometrie (1976) (1)
- RING SIZE IN EPOXYNITRILE CYCLIZATION, A GENERAL SYNTHESIS OF FUNCTIONALLY SUBSTITUTED CYCLOBUTANES, APPLICATION TO (+-)-GRANDISOL (1974) (1)
- Radical Cyclization of Allylic Haloacetamides. A Route to cis‐Fused 2‐Pyrrolidones and Piperidones. (1989) (1)
- Chiral induction in the construction of vicinally substituted cyclopentanones via the intramolecular conjugate addition of chiral β-ketoesters (1987) (1)
- The synthesis and reactions of organic compounds: Chairman of the Editorial Board: Sir Derek Barton, FRS Deputy Chairman: W. David Ollis, FRS Volume 1 (Stereochemistry, Hydrocarbons, Halo Compounds, Oxygen Compounds; edited by J. F. Stoddart, Sheffield) (1979) (0)
- SPIROANNELATION OF ENOL ETHERS OF CYCLIC 1,3-DIKETONES, A SIMPLE STEREOSPECIFIC SYNTHESIS OF BETA-VETIVONE (1973) (0)
- rational design of propionaldehy de enolate equivalents, ranging from anions of propionic acid derivatives to those of butene.' (1986) (0)
- Iterative Butenolide Construction of Polypropionate Chains. (1987) (0)
- HIGHLY STEREOSELECTIVE TOTAL SYNTHESES OF PROSTAGLANDINS VIA STEREOSPECIFIC SULFENATE-SULFOXIDE TRANSFORMATIONS, 13CIS-15BETA-PROSTAGLANDINS E(1) TO PROSTAGLANDINS E(1) (PGE(1)) (1974) (0)
- SYNTH. VON ALKYL‐PYRROLONEN UND DIHYDRO‐PYRIDONEN (1970) (0)
- A course in modern techniques of organic chemistry By , and , Academic Press Inc., New York, 1955. 190 pp. Price $5.00 (1956) (0)
- 2-SUBSTITUTED TETRAHYDROFURANS OF KNOWN ABSOLUTE STEREOCHEMISTRY BY SCN′ CHIRALITY TRANSFER (1983) (0)
- Stereocontrolled Synthesis of (.+-.)-12a-Deoxytetracycline. (1996) (0)
- Alkylations of Aldehydes via Reaction of the Magnesioenamine Salt of an Aldehyde: 2,2‐Dimethyl‐3‐Phenylpropionaldehyde (2003) (0)
- ClosingL PROBLEMS AND PROGRESS IN REGIO AND STEREOCONTROLLED SYNTHESIS--RESERPINE (1988) (0)
- A General Synthesis of cis Perhydro-3,6-isoquinolinediones Related to the Alloyohimbane Alkaloids. (1987) (0)
- Substances Naturelles de Synthese. (1954) (0)
- Iterative Butenolide Construction of Polypropionate Chains. Application to an Efficient Synthesis of (+)(9S)‐Dihydroerythronolide A (I). (1987) (0)
- Regiospecificity in the Cyclization of 6‐(1‐Hydroxyalkyl) Geraniol Derivatives. A Simple Route to the Taxol A‐Ring System. (1994) (0)
- STEREOSELEKTIVE TOTALSYNTH. VON (+‐)‐YOHIMBIN, (+‐)‐PSI‐YOHIMBIN UND (+‐)‐BETA‐YOHIMBIN (1972) (0)
- ORGANOCUPRATE REACTIONS OF ENONE LACTONES. I. SYNTHESIS OF TRANS-FUSED RINGS VIA CONJUGATE ADDITION (1980) (0)
- TOTALSYNTH. VON DL-CAMPTOTHECIN (1971) (0)
- Samuel Marion McElvain: December 9, 1897-April 11, 1973. (1983) (0)
- Cine Substitution in Vinylstannane Cross‐Coupling Reactions. (1991) (0)
- [Organic synthesis]. (2000) (0)
- AN ISOMERIZATION-CLAISEN REARRANGEMENT ROUTE TO OLEFINIC DICARBONYL STARTING MATERIALS FOR CONJUGATE CYCLIZATION (1982) (0)
- Total Syntheses of (-)-Histrionicotoxin and (-)-Histrionicotoxin 235 A. (1990) (0)
- Regiocontrol by Electron Withdrawing Groups in the Rh-Catalyzed C-H Insertion of α-Diazoketones. (1988) (0)
- The synthesis and reactions of Organic compounds: Volume 3 (Sulphur, Selenium, Silicon, Boron, orgenometalllc compounds; edited by D. Neville Jones. Sheffield) (1978) (0)
- A course in modern techniques of organic chemistry: By R. P. Linstead, J. A. Elvidge, and Margaret Whalley, Academic Press Inc., New York, 1955. 190 pp. Price $5.00 (1956) (0)
- Vinyl Radical Cyclizations Mediated by the Addition of Stannyl Radicals to Triple Bonds. (1987) (0)
- A Total Synthesis of rac‐Patchouli Alcohol. (1996) (0)
- Chapter VIII Part II The Morphine Alkaloids. II (1952) (0)
- of secondary methyl—secondary hydroxyl sequences. (1987) (0)
- ACID-CATALYZED INTERMOLECULAR CONJUGATE ADDITION AS A ROUTE TO TRANS-HYDRINDAN SYSTEMS (1984) (0)
- Topics in Organic Chemistry. Louis F. Fieser and Mary Fieser. Chapman and Hall, London; Reinhold, New York, 1963. xii + 668 pp. Illus. $10 (1963) (0)
- Use of a Lithiolactone in the Enantioselective Constructions of A/C seco-B and of A/B seco-C proTaxol Systems. (1998) (0)
- The Allylic Epoxide Cyclization. A Method for the Control of Regiochemistry and Stereochemistry in Cyclohexane Systems. (1990) (0)
- Volume 3 Sulphur, Selenium, Silicon, Boron, Organometallic Compounds; : edited by D. Neville Jones, Sheffield (1979) (0)
- ALPHA-SILYLATED VINYL KETONES, A NEW CLASS OF REAGENTS FOR THE ANNELATION OF KETONES (1973) (0)
- A Stereoselective Synthesis of Z‐1‐Iodo‐1‐alkenes. (1989) (0)
- ROUTES TO BICYCLO (X.3.0) RING SYSTEMS: STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-8-METHYLHYDRINDANS (1979) (0)
- DEREK H. R. BARTON — THE LIGHTER SIDE (2000) (0)
- STEREOCHEMICAL CONTROL IN THE CONSTRUCTION OF VICINALLY SUBSTITUTED CYCLOPENTANES AND CYCLOHEXANES. INTRAMOLECULAR CONJUGATE ADDITION OF β-KETOESTER ANIONS (1983) (0)
- [Enzymatic galactose determination without deproteinization and centrifugation in very small blood samples (10 mul)]. (1970) (0)
- Patented Oct . 24 , 1950 2 , 526 , 859 UNITED STATES PATENT OFFICE (2017) (0)
- THE USE OF KINETICALLY GENERATED UNSTABLE ENOLATE IONS IN THE REGIOSPECIFIC FORMATION OF CARBON-CARBON (2007) (0)
- Adventures in Selectivity (1995) (0)
- Allylic Radicals in Cyclization Reactions. (1989) (0)
- Vinyl Radical Cyclization in the Synthesis of Natural Products: Seychellene. (1986) (0)
- A survey of the radical-mediated cyclization of α-haloacetals of cyclic allyl alcohols as a general route to the control of vicinal regio- and stereochemistry (1990) (0)
- Multiple Carbon Bond Formation via the Radical Cyclization of Cycloalkenol Acetals. Application to trans Hydrindan Steroid Precursors. (1992) (0)
- An Efficient Synthesis of Alkenyl and Alkynyl Silyl Ethers. (1990) (0)
- An Enantioselective Construction of the ABC System of Taxol. (1998) (0)
- Theoretical Studies of the Lithiation of Enamines. (1989) (0)
- A SYNTHESIS OF D,L-MUSCONE FROM CYCLODECANONE (1975) (0)
- Enantioselective Synthesis of an Intermediate for the Intramolecular Diels-Alder Construction of 11-Ketosteroids. (1987) (0)
- EPOXYNITRILE CYCLIZATION, A GENERAL METHOD FOR RING FORMATION (1974) (0)
- OLEFIN-WECHSELWIRKUNG BEI DER SAEURE-KATALYSIERTEN RINGOEFFNUNG VON ACYLCYCLOPROPANEN 4. MITT. CYCLISIERUNG VON 5-METHYL-6-ENDO-(TRANS-3-PENTENYL)-BICYCLO(3,1,0)HEXAN-2-ON (1971) (0)
- Five vs Six Membered Ring Formation in the Vinyl Radical Cyclization. (1987) (0)
- A Catalytic Tin System for Trapping of Radicals from Cyclization Reactions. (1986) (0)
- Regiospecific and Stereoselective Syntheses of (.+‐.)‐Reserpine and (‐)‐Reserpine. (2006) (0)
- The ene reaction as a route to 3-hydroxycyclopentanone derivatives. Application to the prostaglandins (1977) (0)
- Cost-benefit analysis (0)
- Deprotonation of Chelating Enamines. Direct Formation of β‐Lithio Enamines. (2002) (0)
- Efficient Regio- and Stereocontrolled Synthesis of Highly Functionalized Polycyclic Systems Using the Diels-Alder Addition of Stannyl-Substituted Vinylketeneacetals. (1990) (0)
- Introduction of Angular Methyl Groups via Radical Cyclization. (1990) (0)
- Sulphur, selenium, silicon, boron, organometallic compounds: Volume 3; edited by D. Neville Jones, Sheffield (1978) (0)
- SYNTH. VON CYCLOPENTENONEN (1971) (0)
- Some Contributions to Regio- and Stereocontrol: From Cincholoipon and Cantharidin to the Present (1999) (0)
- Total Synthesis of a Natural Cardenolide: (+)-Digitoxigenin (XIV). (1997) (0)
- TOTALSYNTH. VON (+-)-BYSSOCHLAMSAEURE (1972) (0)
- FREE‐RADICAL CYCLIZATION OF BROMO ACETALS. USE IN THE CONSTRUCTION OF BICYCLIC ACETALS AND LACTONES (1983) (0)
- (Dl) -13-substituted sulfinyl prostaglandinartige compounds and methods for their preparation (1975) (0)
- STEREOSELECTIVE SYNTHESIS OF CIS- AND TRANS-4-CARBOXY-3A,4,5,6-TETRAHYDROINDAN-1-ONES (1983) (0)
- Simplified addition method in atomic absorption spectrometry (1976) (0)
- Stereospecific Reductive Methylation via a Radical Cyclization-Desilylation Process. (1987) (0)
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