Gilbert Stork
#13,087
Most Influential Person
Belgian chemist
Why Is Gilbert Stork Influential?
(Suggest an Edit or Addition)According to Wikipedia, Gilbert Stork was an organic chemist. For a quarter of a century he was the Eugene Higgins Professor of Chemistry Emeritus at Columbia University. He is known for making significant contributions to the total synthesis of natural products, including a lifelong fascination with the synthesis of quinine. In so doing he also made a number of contributions to mechanistic understanding of reactions, and performed pioneering work on enamine chemistry, leading to development of the Stork enamine alkylation. It is believed he was responsible for the first planned stereocontrolled synthesis as well as the first natural product to be synthesised with high stereoselectivity.
Gilbert Stork's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Papers
- The Enamine Alkylation and Acylation of Carbonyl Compounds (1963) (822)
- The Stereochemistry of Polyene Cyclization (1955) (301)
- Isolation of ketone enolates as trialkylsilyl ethers (1968) (267)
- A stereoselective synthesis of (Z)-1-iodo-1-alkenes (1989) (257)
- Stereocontrolled synthesis of disaccharides via the temporary silicon connection (1992) (210)
- A New Method for the Alkylation of Ketones and Aldehydes: the C-Alkylation of the Magnesium Salts of N-Substituted Imines (1963) (205)
- A simple method of dethioacetalization (1989) (199)
- A catalytic tin system for trapping of radicals from cyclization reactions. Regio- and stereocontrolled formation of two adjacent chiral centers (1986) (193)
- Regiospecific alkylation of cyclic .beta.-diketone enol ethers. General synthesis of 4-alkylcyclohexenones (1973) (192)
- Alkylation and Michael additions of glycine ethyl ester. Use in alpha-amino acid synthesis and as acyl carbanion equivalent. (1976) (182)
- A NEW SYNTHESIS OF 2-ALKYL AND 2-ACYL KETONES (1954) (182)
- The Total Synthesis of dl-Aspidospermine and of dl-Quebrachamine (1963) (158)
- Cyclization of vinyl radicals: a versatile method for the construction of five- and six-membered rings (1982) (155)
- Free-radical cyclization of bromo acetals. Use in the construction of bicyclic acetals and lactones (1983) (153)
- Alkylation and Carbonation of Ketones by Trapping the Enolates from the Reduction of α,β-Unsaturated Ketones (1965) (147)
- Generation, nuclear magnetic resonance spectra, and alkylation of enolates from trialkylsilyl enol ethers (1968) (145)
- The first stereoselective total synthesis of quinine. (2001) (141)
- Stereocontrol in homogeneous catalytic hydrogenation via hydroxyl group coordination (1983) (137)
- Control of ring junction stereochemistry via radical cyclization (1985) (133)
- Vinyl radical cyclizations mediated by the addition of stannyl radicals to triple bonds (1987) (130)
- Ring size in epoxynitrile cyclization. General synthesis of functionally substituted cyclobutanes. Application to (+-)-grandisol (1974) (128)
- Vinyl radical cyclization. 2. Dicyclization via selective formation of unsaturated vinyl radicals by intramolecular addition to triple bonds. Applications to the synthesis of butenolides and furans (1983) (126)
- Chiral synthesis of prostaglandins (PGE1) from D-glyceraldehyde. (1977) (126)
- Anions of protected cyanohydrins as acyl carbanion equivalents and their use in a new synthesis of ketones (1971) (126)
- .alpha.-Silylated vinyl ketones. New class of reagents for the annelation of ketones (1973) (119)
- New synthesis of aldehydes via vinylsilanes (1971) (115)
- Radical cyclization-trapping in the synthesis of natural products. A simple, stereocontrolled route to prostaglandin F2.alpha. (1986) (110)
- Five vs six membered ring formation in the vinyl radical cyclization (1986) (109)
- INTRAMOLECULAR CYCLIZATION OF UNSATURATED DIAZOKETONES (1961) (107)
- Regiospecific trapping of radicals from cyclization reactions. Cyclic nitriles via isocyanide trapping (1983) (101)
- A NEW RING ENLARGEMENT SEQUENCE (1956) (98)
- The temporary silicon connection method in the control of regio- and stereochemistry. Applications to radical-mediated reactions. The stereospecific synthesis of C-glycosides (1991) (96)
- Concise total synthesis of (+)-(9S)-dihydroerythronolide A (1987) (93)
- A NEW ALKYLATION OF CARBONYL COMPOUNDS. II1 (1956) (89)
- Total synthesis of prostaglandin F2.alpha. by chirality transfer from D-glucose (1978) (87)
- Letter: A simple total synthesis of prostaglandins from 4-cumyloxy-2-cyclopentenone. (1975) (87)
- Epoxynitrile cyclization. General method of ring formation (1974) (86)
- Letter: Chiral synthesis of prostaglandins from carbohydrates. Synthesis of (+)-15-(S)-prostaglandin A2. (1976) (84)
- Radical cyclization of allylic haloacetamides a route to cis-fused 2-pyrrolidones and piperidones (1989) (82)
- A Stereospecific Synthesis of Cantharidin (1953) (81)
- A simplified total synthesis of cytochalasins via an intramolecular Diels-Alder reaction (1983) (80)
- Total synthesis of cytochalasin B (1978) (79)
- A highly stereoselective osmium tetroxide-catalyzed hydroxylation of γ-hydroxy α,β-usaturated esters (1983) (78)
- Vinylsilanes as carbonyl precursors. Use in annelation reactions (1974) (78)
- Stereospecific reductive methylation via a radical cyclization-desilylation process (1986) (78)
- REGIOSPECIFIC MICHAEL REACTIONS IN APROTIC SOLVENTS WITH ALPHA-SILYLATED ELECTROPHILIC OLEFINS, APPLICATION TO ANNELATION REACTIONS (1974) (77)
- Conjugate addition of acyl carbanion equivalents via the protected cyanohydrin method (1974) (76)
- The total synthesis of dl-camptothecin. (1971) (74)
- Cedrol: Stereochemistry and Total Synthesis (1961) (73)
- Synthetic routes to halomethyl vinylsilanes (1974) (71)
- The Stereochemistry of the SN2' Reaction. II1 (1956) (71)
- The Total Synthesis of a Natural Cardenolide: (+)-Digitoxigenin (1996) (70)
- The stereospecific total synthesis of dl-lycopodine. (1968) (69)
- Spiroannelation of enol ethers of cyclic 1,3-diketones. Simple stereospecific synthesis of .beta.-vetivone (1973) (64)
- Letter: A general approach to prostaglandins via methylenecyclopentanones. Total synthesis of (+/- prostaglandin F2 alpha. (1975) (63)
- Regiospecific aldol condensations of the kinetic lithium enolates of methyl ketones (1974) (62)
- Condensation of formaldehyde with regiospecifically generated anions (1974) (62)
- Monoalkylation of .alpha.,.beta.-unsaturated ketones via metalloenamines (1971) (61)
- Total syntheses of (-)-histrionicotoxin and (-)-histrionicotoxin 235A (1990) (60)
- Iterative butenolide construction of polypropionate chains (1987) (60)
- Regiospecific and stereoselective syntheses of (+/-) morphine, codeine, and thebaine via a highly stereocontrolled intramolecular 4 + 2 cycloaddition leading to a phenanthrofuran system. (2009) (58)
- STEREOCHEMICAL CONTROL OF THE INTERNAL MICHAEL REACTION. A NEW CONSTRUCTION OF TRANS-HYDRINDAN SYSTEMS (1982) (58)
- THE α-ALKYLATION OF ENOLATES FROM THE LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES (1961) (58)
- Allylic radicals in cyclization reactions (1988) (57)
- Letter: Highly stereoselective total syntheses of prostaglandins via stereospecific sulfenate-sulfoxide transformations. 13-Cis-15beta-prostaglandins E1 to prostaglandins E1. (1974) (56)
- Isoxazole annelation reaction. Method for the construction of cyclohexenone rings in polycyclic systems (1967) (56)
- Synthesis of d,l-muscone from cyclododecanone (1975) (56)
- Regiospecific and stereoselective syntheses of (+/-)-reserpine and (-)-reserpine. (2005) (55)
- A New Synthesis of 1,4- and 1,5-Diketones (1964) (55)
- Vinyl radical cyclization in the synthesis of natural products: seychellene (1985) (54)
- 3-Benzyloxyisoxazole system in construction of tetracyclines (1978) (52)
- The stereospecific synthesis of reserpine (1989) (52)
- Stereoselective total syntheses of (plus minus)-yohimbine, (plus minus)-psi-yohimbine, and (plus minus)- -yohimbine. (1972) (51)
- Radical Cyclization in the Control of Regio- and Stereochemistry (1988) (51)
- Total synthesis of lupeol (1971) (51)
- A New Cyclization. 2-Methylenecyclopentanols by the Chemical Reduction of γ-Ethinyl Ketones (1965) (51)
- Stereoselective synthesis of the chiral sequence of erythronolide A (1982) (50)
- Stereospecific total synthesis of steroids via isoxazole annelation. dl-D-Homotestosterone and dl-progesterone (1967) (50)
- Stereocontrolled Synthesis of (±)-12a-Deoxytetracycline (1996) (50)
- The temporary silicon connection in the control of the regiochemistry of 4 + 2 cycloadditions (1992) (50)
- A New Synthesis of Cyclohexenones: The Double Michael Addition of Vinyl Ethynyl Ketones to Active Methylene Compounds. Application to the Total Synthesis of dl-Griseofulvin (1964) (48)
- Progress in the synthesis of polycyclic natural products: The total synthesis of lycopodine (1968) (48)
- Large-ring lactones by internal ketophosphonate cyclizations (1979) (44)
- Regiocontrol by electron withdrawing groups in the Rh-catalyzed CH insertion of α-diazoketones (1988) (44)
- Stereochemical control of intramolecular conjugate addition. A short, highly stereoselective synthesis of adrenosterone (1982) (44)
- The Stereochemistry of the SN2' Reaction. I. Preparation of Pure trans-6-Alkyl-2-cyclohexen-1-ols (1956) (44)
- Versatile synthesis of cyclopentenones (1971) (43)
- STEREOCHEMISTRY OF THE LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES (1960) (41)
- Synthesis of allylic halides and 1,5-dienes from allylic alcohols (1969) (41)
- Reductive cyclization of ethynyl ketones in the construction of a significant tricyclic intermediate for the synthesis of gibberellic acid (1979) (40)
- The Total Synthesis of Cedrol and Cedrene (1955) (39)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. III. Formation of the bicyclo[2.2.1]heptane system (1969) (39)
- 2-Substituted tetrahydrofurans of known absolute stereochemistry by ScN' chirality transfer (1983) (38)
- The Total Synthesis ofdl-Dehydroabietic Acid (1962) (38)
- THE STRUCTURE OF CEDRENE (1953) (38)
- Four-Membered Sulfones From Enamines and Aliphatic Sulfonyl Halides (1962) (37)
- Six-membered rings via olefin participation in the opening of acylcyclopropanes (1969) (37)
- The Base Effect in Catalytic Hydrogenation. A Simple Synthesis of 6-Methoxy-α-tetralone (1947) (36)
- Cine substitution in vinylstannane cross-coupling reactions (1990) (36)
- Enantioselective synthesis of an intermediate for the intramolecular Diels-Alder construction of 11-ketosteroids (1987) (35)
- The use of kinetically generated unstable enolate ions in the regiospecific formation of carbonxarbon bonds. Specific applications to annelation processes (1975) (35)
- Letter: A route to prostaglandins via a general synthesis of 4-hydroxycyclopentenones. (1975) (34)
- New route to 11-oxygenated steroids (1981) (34)
- .alpha.-Alkylation and arylation of .alpha.,.beta.-unsaturated ketones (1976) (33)
- CANTHARIDIN. A STEREOSPECIFIC TOTAL SYNTHESIS (1951) (33)
- Aryl participation in concerted cyclization of cyclopropyl ketones (1969) (33)
- Temporary Magnesium and Aluminum Connections in [4 + 2] Cycloadditions (1995) (33)
- The Ene reaction as a route to 3-hydroxycyclopentanone derivatives. Application to the prostaglandins. (1976) (32)
- Mechanism and stereochemical control in the .alpha.-haloketal cyclization. Remarkable effect of metal cations (1973) (30)
- A New Synthesis of Vinylogous Aldols and Polyenones (1976) (30)
- Haloketal cyclization. General method for the synthesis of functionalized cis bicyclic ketones (1973) (30)
- CONCERTED INTRAMOLECULAR DISPLACEMENT WITH REARRANGEMENT IN ALLYLIC SYSTEMS. DISPLACEMENT OF AN ALLYLIC ESTER WITH A CARBANION (1979) (30)
- Additions and Corrections - A Stereocontrolled Synthesis of the (±) Djerassi-Prelog Lactonic Acid (1979) (29)
- THE STEREOCHEMISTRY OF THE Sn2' REACTION (1953) (29)
- Stereochemistry of the SN2' reaction. "Concerted" allylic displacement in an acyclic system: anti displacement with thiolate anion (1977) (29)
- Optical Rotatory Dispersion Studies. XCII.1 Some Observations on the Conformation of cis-10-Methyl-2-decalones2 (1964) (28)
- Synthesis and Reactions of Glycidonitriles. Transformation into α-Haloacyl Compounds and Aminoalcohols (1960) (28)
- Introduction of angular methyl groups via radical cyclization (1989) (28)
- The Synthesis of Substituted 1-Methylcyclohexanecarboxylic Acids and the Stereochemistry of the Favorski[UNK]i Rearrangement (1960) (28)
- STEREOCHEMISTRY OF THE SN2′ REACTION IN CYCLOHEXENYL SYSTEMS (1977) (28)
- A NEW ROUTE TO HYDROPHENANTHRENE KETONES. THE SYNTHESIS OF THE C18 KETONE DERIVED FROM DEHYDROABIETIC ACID (1951) (27)
- N,N-diethylaminoacetonitrile a generally useful latent acyl carbanion (1978) (27)
- Mechanism of the isoxazole annelation (1967) (27)
- REDUCTIVE ALKYLATION OF ENEDIONES. 1 (1980) (27)
- A Stereospecific Total Synthesis of 18-Substituted Steroids. Application to the Synthesis of dl-Conessine (1962) (27)
- General synthesis of 4-isoxazolecarboxylic acids (1967) (27)
- Efficient de novo construction of the indanepropionic acid precursor of 11-oxo steroids. An improved internal Diels-Alder sequence (1982) (27)
- The allylic epoxide cyclization. A method for the control of regiochemistry and stereochemistry in cyclohexane systems (1990) (26)
- An efficient synthesis of alkenyl and alkynyl silyl ethers (1989) (25)
- THE TOTAL SYNTHESIS OF dl-DEHYDROABIETIC ACID (1956) (25)
- STEROIDS. XCIII.1 INTRODUCTION OF THE CORTICAL HORMONE SIDE-CHAIN (1958) (25)
- An approach to gelsemine (1987) (25)
- Stereochemical control in the construction of vicinally substituted cyclopentanes and cyclohexanes. Intramolecular conjugate addition of β-ketoester anions. (1983) (25)
- A simple, stereospecific synthesis of the skeleton of the lycorine alkaloids (1979) (24)
- A Stereospecific Total Synthesis of Griseofulvin (1962) (24)
- Total Synthesis of Polycyclic Triterpenes: The Total Synthesis of (+)--Onocerin (2002) (23)
- Reductive alkylation of enediones. 2. Synthesis of corticosteroids (1980) (23)
- Piperidine derivatives; the preparation of l-benzoyl-3-carbethoxy-4-piperidone; a synthesis of guvacine. (1946) (22)
- Five- and six-membered-ring formation from olefinic .alpha.,.beta.-epoxy ketones and hydrazine (1977) (22)
- A Synthesis of cis-Jasmone (1964) (22)
- LITHIUM-AMMONIA REDUCTION OF α,β-UNSATURATED KETONES. II. FORMATION AND ALKYLATION OF A β-CARBANION INTERMEDIATE (1961) (21)
- A GENERAL APPROACH TO PROSTAGLANDINS VIA METHYLENECYCLOPENTANONES, TOTAL SYNTHESIS OF (+-)-PROSTAGLANDIN F(2ALPHA) (1975) (21)
- Pyridine synthesis via 4-(3-oxoalkyl)isoxazoles (1971) (20)
- Transformation of 4-(3-oxoalkyl)isoxazoles into pyridines (1967) (18)
- Deprotonation of Chelating Enamines. Direct Formation of β-Lithio Enamines (1986) (18)
- Sex hormones; a synthesis of 1-keto-7-methoxy-1,2,3,4-tetrahydrophenanthrene and of 1-keto-7-methoxy-1,2,3,4,9,10-hexahydrophenanthrene. (1947) (18)
- Regiospecificity in the cyclization of 6-(1-hydroxyalkyl) geraniol derivatives. A simple route to the taxol a-ring system (1994) (18)
- A total synthesis of rac-patchouli alcohol (1995) (18)
- An intramolecular diels-alder approach to the galanthan ring system (1979) (17)
- STEROIDS. XXVIII.1 INTRODUCTION OF THE 11-KETO AND 11α-HYDROXY GROUPS INTO RING C UNSUBSTITUTED STEROIDS (PART 2) (1951) (17)
- An Enantioselective Construction of the ABC System of Taxol (1998) (17)
- A TOTAL SYNTHESIS OF 1-OXYGENATED STEROIDS1 (1956) (17)
- Total synthesis of (+-)-byssochlamic acid (1972) (17)
- The Stereospecific Synthesis of dl-Alloyohimbane and dl-3-Epialloyohimbane1 (1954) (17)
- A general synthesis of esters of acryloyl acetic acid and their homologs. (1972) (17)
- Carboxy beta-lactams by photochemical ring contraction. (1974) (16)
- THE STEREOCHEMISTRY OF GIBBERELLIC ACID (1959) (16)
- Some contributions to regio and stereo control: From cincholoipon and cantharidin to the present (1999) (16)
- The Stobbe Condensation with Cyclohexanone (1948) (16)
- The SN2' Reaction. III. Structure and SN2' Reactions of the Halocodides (1956) (16)
- An isomerization—claisen rearrangement route to olefinic dicarbonyl starting materials for conjugate cyclization (1982) (16)
- A ROUTE TO PROSTAGLANDINS VIA A GENERAL SYNTHESIS OF 4-HYDROXYCYCLOPENTENONES (1975) (15)
- Piperidine derivatives; C-alkylation of l-benzoyl-3-carbethoxy-4-piperidone; synthesis of ethyl 3-ethyl-4-piperidylacetate (d1-ethyl cincholoiponate). (1946) (15)
- Synthesis of small rings via the protected cyanohydrin method. (1975) (15)
- A total synthesis of calcitriol (1992) (15)
- Progress in the synthesis of polycyclic natural products (1964) (15)
- Acid catalyzed intramolecular conjugate addition as a route to trans hydrindane systems (1983) (14)
- Iterative butenolide construction of polypropionate chains. Application to an efficient synthesis of (+)(9S)-dihydroerythronolide A (1987) (14)
- Olefin participation in the acid-catalyzed opening of acylcyclopropanes. IV. Cyclization of 5-methyl-6--(-3-pentenyl)bicyclo(3.1.0)hexan-2-one. (1971) (13)
- Stereochemistry of the SN2' reaction in cyclohexenyl systems (1977) (13)
- A method for the transformation of cyclic ketones to homologous α,β-unsaturated ketones (1966) (13)
- Highly stereoselective axial addition of ethynyl carbanions to the carbonyl of cyclohexenones (1984) (13)
- Modified ollgonucleotides. Effect of 4 vs 5-atom chimeric internucleoside linkages on duplex stability (1995) (13)
- The Reduction of Thebaine (1952) (13)
- THE TOTAL SYNTHESIS OF A NATURALLY OCCURRING PENTACYCLIC TRITERPENE SYSTEM (1959) (12)
- Use of a Lithiolactone in the Enantioselective Constructions of A/C seco-B and of A/B seco-C proTaxol Systems (1997) (12)
- Comprehensive organic chemistry, volume 3 (sulphur, selenium, silicon, boron, organometallic compounds): Edited by D. Neville Jones (1979) (12)
- Monoalkylation of α,β‐Unsaturated Ketones via Metalloenamines: 1‐Butyl‐10‐methyl‐Δ1(9)‐2‐octalone (2003) (12)
- THE STEREOCHEMISTRY OF ALLOGIBBERIC ACID AND OF GIBBERIC ACID (1959) (11)
- Synthese stereoselective des barcis et bartrans carboxy-4 (1983) (11)
- Steroids. XXXI.1Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (Part 4).2Saturated 7,11-Diones (1952) (11)
- A general method for the stereocontrolled synthesis of polypropionate-derived sequences (1986) (11)
- SYNTHESIS OF 17,18-BISNORSTEROIDS (1958) (11)
- A convenient route to and trisubstituted olefins from geraniol and nerol (1969) (10)
- A New Approach to the Stereospecific Synthesis of Angularly Substituted Polycyclic Systems (1969) (10)
- Synthesis and Reactions of 1-Methyl-2-vinyl-4-hydroxycyclohexene (1953) (10)
- AN UNUSUALLY SIMPLE CONSTRUCTION OF RING A OF GIBBERELLIC ACID (1979) (10)
- organocuprate reactions of enone lactones. I. Synthesis of trans-fused rings via conjugate addition. (1979) (9)
- Multiple Carbon Bond Formation Via the Radical Cyclization of Cycloalkenol Acetals. Application to trans Hydrindan Steroid Precursors (1992) (9)
- Theoretical studies of the lithiation of enamines (1988) (9)
- AN EFFICIENT SYNTHESIS OF () METHYL EPIJASMONATE VIA THE RADICAL-MEDIATED HALOACETAL CYCLIZATION (1992) (8)
- Elaboration of the 1-Substituted 7,8-Dimethoxy-2-tetralones Toward the 13-Alkyl Hydrophenanthrene System of Morphine (1951) (8)
- A general synthesis of alkyl-pyrrolones and dihydro-pyridones (1970) (8)
- TOTAL SYNTHESIS OF THE CEPHALOSPORIN ANTIBIOTICS. I. THE DIHYDROTHIAZINE SYSTEM OF CEPHALOSPORIN CC. (1965) (8)
- CHIRAL SYNTHESIS OF PROSTAGLANDINS FROM CARBOHYDRATES. SYNTHESIS OF (+)-15-(S)-PROSTAGLANDIN A2 (1976) (8)
- THE STRUCTURE OF PHENOLIC DIHYDROTHEBAINE AND OF β-DIHYDROTHEBAINE (1951) (7)
- STEREOCHEMISTRY OF THE SN2′ REACTION. ′CONCERTED′ ALLYLIC DISPLACEMENT IN AN ACYCLIC SYSTEM- ANTI DISPLACEMENT WITH THIOLATE ANION (1977) (7)
- THE STRUCTURE OF METOPON (1953) (7)
- Additions and Corrections - Concerning the Stereochemistry of the SN2' Reaction in Cyclohexenyl Systems (1977) (7)
- The alkylation of enamines from α,β-unsaturated ketones1 (1961) (7)
- Synthetic Study toward Total Synthesis of (±)-Germine: Synthesis of (±)-4-Methylenegermine. (2017) (7)
- X-ray crystal structure of N-(2-lithiocyclohexenyl)-N,N′,N′-trimethyl-1,3-propanediamine: A pentavalent lithium? (1984) (7)
- ALKYLATION AND MICHAEL ADDITIONS OF GLYCINE ETHYL ESTER. USE IN α-AMINO ACID SYNTHESIS AND AS ACYL CARBANION EQUIVALENT (1977) (7)
- Preparation of Ethyl β-Benzylaminopropionate and Benzyl-di-(β-carbethoxyethyl)-amine (1947) (6)
- CARBOXY BETA‐LACTAMS BY PHOTOCHEMICAL RING CONTRACTION (1974) (6)
- THE REARRANGEMENT OF BROMONORCEDRENEDICARBOXYLIC ACID (1953) (6)
- Simple preparation of a useful c/d-ring fragment for the construction of 11-keto steroids (1984) (6)
- Steroids. XXXII.1Introduction of the 11-Keto and 11α-Hydroxy Groups into Ring C Unsubstituted Steroids (Part 5). Δ8-7-Ketones (1952) (6)
- A construction of the angularly hydroxylated cis 1,8-naphthalenedione system typical of the tetracyclines (1984) (6)
- R. B. Woodward, 1917–1979 (1980) (6)
- Stereocontrolled Synthesis of Disaccharides via the Temporary Silicon Connection. (1992) (5)
- A STEREOSPECIFIC REACTION OF CARBON MONOXIDE (1960) (5)
- A General Synthesis of cis Perhydro 3,6-Isoquinolinediones Related to the Alloyohimbane Alkaloids (1987) (5)
- The Preparation of β-Tetralone by the Catalytic Reduction of β-Naphthol (1946) (5)
- A HIGHLY STEREOSELECTIVE OSMIUM TETROXIDE-CATALYZED HYDROXYLATION OF Γ-HYDROXY α,β-UNSATURATED ESTERS (1984) (4)
- Radical Cyclization-Trapping in the Synthesis of Natural Products. A Simple, Stereocontrolled Route to Prostaglandin F2α. (1987) (4)
- Radical-mediated Cyclization Processes (1985) (4)
- Elaboration of a tricyclic gibberellic acid intermediate (1980) (4)
- VINYL AND BETA-ALKOXY RADICALS IN ORGANIC SYNTHESIS (1983) (4)
- The First Stereoselective Total Synthesis of Quinine [J. Am. Chem. Soc. 2001, 123 (14), 3239−3242]. (2001) (4)
- Unusual regiospecificity in the enolization of a ketone as the result of differences in energy to achieve the best overlap of an alpha hydrogen (1979) (4)
- THE SYNTHESIS OF 3,4-DIAMINOCARBETHOXYFURAN (1945) (4)
- The intramolecular Michael addition as a route to angularly substituted cis-hydrindanes (1978) (3)
- Routes to bicyclo [X.3.0] ring systems: stereoselective syntheses of and -8-methylhydrindans (1979) (3)
- Comprehensive organic chemistry The synthesis and reactions of organic compounds: Volume 3 (Sulphur, Selenium, Silicon, Boron, Organometallic compounds; edited by D. Neville Jones, Sheffield) (1979) (3)
- Allylic Chlorides from Allylic Alcohols: Geranyl Chloride (2003) (3)
- Steroid Reactions, An Outline for Organic Chemists. (1964) (3)
- Simple total synthesis of prostaglandins from 4-cumyloxy-2-cyclopentenone (1976) (3)
- The Synthesis of Some 1-Substituted 7,8-Dimethoxy-2-tetralones (1951) (3)
- Temporary Magnesium and Aluminum Connections in (4 + 2) Cycloadditions. (1995) (2)
- FIVE- AND SIX-MEMBERED-RING FORMATION FROM OLEFINIC α,β-EPOXY KETONES AND HYDRAZINE (1978) (2)
- Enantioselective Synthesis of a trans-Hydrindane System for the Preparation of Vitamin D Metabolites. (1997) (2)
- A Simple Method of Dethioacetalization. (1989) (2)
- Heterocyclic Silyllithium Reagents as Precursors of Masked Hydroxyl Groups. Preliminary Results (1996) (2)
- Concise Total Synthesis of (+)‐(9S)‐Dihydroerythronolide A. (1987) (2)
- SYNTHESIS OF SMALL RINGS VIA THE PROTECTED CYANOHYDRIN METHOD (1975) (1)
- Radical Cyclization of Allylic Haloacetamides. A Route to cis‐Fused 2‐Pyrrolidones and Piperidones. (1989) (1)
- RING SIZE IN EPOXYNITRILE CYCLIZATION, A GENERAL SYNTHESIS OF FUNCTIONALLY SUBSTITUTED CYCLOBUTANES, APPLICATION TO (+-)-GRANDISOL (1974) (1)
- Efficient Regio- and Stereocontrolled Synthesis of Highly Functionalized Polycyclic Systems Using the Diels-Alder Addition of Stannyl-Substituted Vinylketeneacetals (1989) (1)
- Configuration of the C/D Ring Junction in Equilenin and Other Steroids (1950) (1)
- The Temporary Silicon Connection Method in the Control of Regio- and Stereochemistry. Applications to Radical-Mediated Reactions. The Stereospecific Synthesis of C-Glycosides. (1991) (1)
- Additions and Corrections - A Synthesis of d,l-Muscone from Cyclododecanone (1976) (1)
- Chiral induction in the construction of vicinally substituted cyclopentanones via the intramolecular conjugate addition of chiral β-ketoesters (1987) (1)
- The Temporary Silicon Connection in the Control of the Regiochemistry of (4 + 2) Cycloadditions. (1993) (1)
- N,N-DIETHYLAMINOACETONITRILE, A GENERALLY USEFUL LATENT ACYL CARBANION (1979) (1)
- Additions and Corrections - Concerning the Stereochemistry of the SN2' Reaction. "Concerted" Allylic Displacement in an Acyclic System: Anti Displacement with Thiolate Anion (1977) (1)
- Chapter 7 The Morphine Alkaloids (1960) (1)
- CHIRAL SYNTHESIS OF PROSTAGLANDINS (PGE1) FROM D-GLYCERALDEHYDE (1977) (1)
- Preface (This volume is dedicated to Prof. Barry M. Trost on the occasion of his 65th birthday) (2006) (1)
- α-ALKYLATION AND ARYLATION OF α,β-UNSATURATED KETONES (1976) (1)
- Vereinfachtes Additionsverfahren in der Atomabsorptionsspektrometrie (1976) (1)
- Sulphur, selenium, silicon, boron, organometallic compounds: Volume 3; edited by D. Neville Jones, Sheffield (1978) (0)
- 2-SUBSTITUTED TETRAHYDROFURANS OF KNOWN ABSOLUTE STEREOCHEMISTRY BY SCN′ CHIRALITY TRANSFER (1983) (0)
- Vinyl Radical Cyclizations Mediated by the Addition of Stannyl Radicals to Triple Bonds. (1987) (0)
- ACID-CATALYZED INTERMOLECULAR CONJUGATE ADDITION AS A ROUTE TO TRANS-HYDRINDAN SYSTEMS (1984) (0)
- Cine Substitution in Vinylstannane Cross‐Coupling Reactions. (1991) (0)
- Theoretical Studies of the Lithiation of Enamines. (1989) (0)
- rational design of propionaldehy de enolate equivalents, ranging from anions of propionic acid derivatives to those of butene.' (1986) (0)
- A Stereoselective Synthesis of Z‐1‐Iodo‐1‐alkenes. (1989) (0)
- Allylic Radicals in Cyclization Reactions. (1989) (0)
- A General Synthesis of cis Perhydro-3,6-isoquinolinediones Related to the Alloyohimbane Alkaloids. (1987) (0)
- Substances Naturelles de Synthese. (1954) (0)
- DEREK H. R. BARTON — THE LIGHTER SIDE (2000) (0)
- HIGHLY STEREOSELECTIVE TOTAL SYNTHESES OF PROSTAGLANDINS VIA STEREOSPECIFIC SULFENATE-SULFOXIDE TRANSFORMATIONS, 13CIS-15BETA-PROSTAGLANDINS E(1) TO PROSTAGLANDINS E(1) (PGE(1)) (1974) (0)
- (Dl) -13-substituted sulfinyl prostaglandinartige compounds and methods for their preparation (1975) (0)
- Samuel Marion McElvain: December 9, 1897-April 11, 1973. (1983) (0)
- An Enantioselective Construction of the ABC System of Taxol. (1998) (0)
- Use of a Lithiolactone in the Enantioselective Constructions of A/C seco-B and of A/B seco-C proTaxol Systems. (1998) (0)
- STEREOSELECTIVE SYNTHESIS OF CIS- AND TRANS-4-CARBOXY-3A,4,5,6-TETRAHYDROINDAN-1-ONES (1983) (0)
- A Catalytic Tin System for Trapping of Radicals from Cyclization Reactions. (1986) (0)
- The ene reaction as a route to 3-hydroxycyclopentanone derivatives. Application to the prostaglandins (1977) (0)
- A course in modern techniques of organic chemistry By , and , Academic Press Inc., New York, 1955. 190 pp. Price $5.00 (1956) (0)
- Vinyl Radical Cyclization in the Synthesis of Natural Products: Seychellene. (1986) (0)
- SPIROANNELATION OF ENOL ETHERS OF CYCLIC 1,3-DIKETONES, A SIMPLE STEREOSPECIFIC SYNTHESIS OF BETA-VETIVONE (1973) (0)
- STEREOSELEKTIVE TOTALSYNTH. VON (+‐)‐YOHIMBIN, (+‐)‐PSI‐YOHIMBIN UND (+‐)‐BETA‐YOHIMBIN (1972) (0)
- Five vs Six Membered Ring Formation in the Vinyl Radical Cyclization. (1987) (0)
- Total Synthesis of a Natural Cardenolide: (+)-Digitoxigenin (XIV). (1997) (0)
- Volume 3 Sulphur, Selenium, Silicon, Boron, Organometallic Compounds; : edited by D. Neville Jones, Sheffield (1979) (0)
- AN ISOMERIZATION-CLAISEN REARRANGEMENT ROUTE TO OLEFINIC DICARBONYL STARTING MATERIALS FOR CONJUGATE CYCLIZATION (1982) (0)
- The Allylic Epoxide Cyclization. A Method for the Control of Regiochemistry and Stereochemistry in Cyclohexane Systems. (1990) (0)
- Adventures in Selectivity (1995) (0)
- ClosingL PROBLEMS AND PROGRESS IN REGIO AND STEREOCONTROLLED SYNTHESIS--RESERPINE (1988) (0)
- Regiospecificity in the Cyclization of 6‐(1‐Hydroxyalkyl) Geraniol Derivatives. A Simple Route to the Taxol A‐Ring System. (1994) (0)
- TOTALSYNTH. VON (+-)-BYSSOCHLAMSAEURE (1972) (0)
- [Enzymatic galactose determination without deproteinization and centrifugation in very small blood samples (10 mul)]. (1970) (0)
- Multiple Carbon Bond Formation via the Radical Cyclization of Cycloalkenol Acetals. Application to trans Hydrindan Steroid Precursors. (1992) (0)
- Enantioselective Synthesis of an Intermediate for the Intramolecular Diels-Alder Construction of 11-Ketosteroids. (1987) (0)
- SYNTH. VON CYCLOPENTENONEN (1971) (0)
- of secondary methyl—secondary hydroxyl sequences. (1987) (0)
- The synthesis and reactions of Organic compounds: Volume 3 (Sulphur, Selenium, Silicon, Boron, orgenometalllc compounds; edited by D. Neville Jones. Sheffield) (1978) (0)
- The synthesis and reactions of organic compounds: Chairman of the Editorial Board: Sir Derek Barton, FRS Deputy Chairman: W. David Ollis, FRS Volume 1 (Stereochemistry, Hydrocarbons, Halo Compounds, Oxygen Compounds; edited by J. F. Stoddart, Sheffield) (1979) (0)
- Topics in Organic Chemistry. Louis F. Fieser and Mary Fieser. Chapman and Hall, London; Reinhold, New York, 1963. xii + 668 pp. Illus. $10 (1963) (0)
- FREE‐RADICAL CYCLIZATION OF BROMO ACETALS. USE IN THE CONSTRUCTION OF BICYCLIC ACETALS AND LACTONES (1983) (0)
- Alkylations of Aldehydes via Reaction of the Magnesioenamine Salt of an Aldehyde: 2,2‐Dimethyl‐3‐Phenylpropionaldehyde (2003) (0)
- Total Syntheses of (-)-Histrionicotoxin and (-)-Histrionicotoxin 235 A. (1990) (0)
- TOTALSYNTH. VON DL-CAMPTOTHECIN (1971) (0)
- EPOXYNITRILE CYCLIZATION, A GENERAL METHOD FOR RING FORMATION (1974) (0)
- Stereocontrolled Synthesis of (.+-.)-12a-Deoxytetracycline. (1996) (0)
- A Total Synthesis of rac‐Patchouli Alcohol. (1996) (0)
- Chapter VIII Part II The Morphine Alkaloids. II (1952) (0)
- OLEFIN-WECHSELWIRKUNG BEI DER SAEURE-KATALYSIERTEN RINGOEFFNUNG VON ACYLCYCLOPROPANEN 4. MITT. CYCLISIERUNG VON 5-METHYL-6-ENDO-(TRANS-3-PENTENYL)-BICYCLO(3,1,0)HEXAN-2-ON (1971) (0)
- ROUTES TO BICYCLO (X.3.0) RING SYSTEMS: STEREOSELECTIVE SYNTHESIS OF CIS AND TRANS-8-METHYLHYDRINDANS (1979) (0)
- ALPHA-SILYLATED VINYL KETONES, A NEW CLASS OF REAGENTS FOR THE ANNELATION OF KETONES (1973) (0)
- An Efficient Synthesis of Alkenyl and Alkynyl Silyl Ethers. (1990) (0)
- Cost-benefit analysis (0)
- THE USE OF KINETICALLY GENERATED UNSTABLE ENOLATE IONS IN THE REGIOSPECIFIC FORMATION OF CARBON-CARBON (2007) (0)
- ORGANOCUPRATE REACTIONS OF ENONE LACTONES. I. SYNTHESIS OF TRANS-FUSED RINGS VIA CONJUGATE ADDITION (1980) (0)
- Iterative Butenolide Construction of Polypropionate Chains. Application to an Efficient Synthesis of (+)(9S)‐Dihydroerythronolide A (I). (1987) (0)
- Efficient Regio- and Stereocontrolled Synthesis of Highly Functionalized Polycyclic Systems Using the Diels-Alder Addition of Stannyl-Substituted Vinylketeneacetals. (1990) (0)
- A course in modern techniques of organic chemistry: By R. P. Linstead, J. A. Elvidge, and Margaret Whalley, Academic Press Inc., New York, 1955. 190 pp. Price $5.00 (1956) (0)
- Simplified addition method in atomic absorption spectrometry (1976) (0)
- Stereospecific Reductive Methylation via a Radical Cyclization-Desilylation Process. (1987) (0)
- Regiocontrol by Electron Withdrawing Groups in the Rh-Catalyzed C-H Insertion of α-Diazoketones. (1988) (0)
- Regiospecific and Stereoselective Syntheses of (.+‐.)‐Reserpine and (‐)‐Reserpine. (2006) (0)
- A survey of the radical-mediated cyclization of α-haloacetals of cyclic allyl alcohols as a general route to the control of vicinal regio- and stereochemistry (1990) (0)
- [Organic synthesis]. (2000) (0)
- Patented Oct . 24 , 1950 2 , 526 , 859 UNITED STATES PATENT OFFICE (2017) (0)
- Deprotonation of Chelating Enamines. Direct Formation of β‐Lithio Enamines. (2002) (0)
- STEREOCHEMICAL CONTROL IN THE CONSTRUCTION OF VICINALLY SUBSTITUTED CYCLOPENTANES AND CYCLOHEXANES. INTRAMOLECULAR CONJUGATE ADDITION OF β-KETOESTER ANIONS (1983) (0)
- A SYNTHESIS OF D,L-MUSCONE FROM CYCLODECANONE (1975) (0)
- Some Contributions to Regio- and Stereocontrol: From Cincholoipon and Cantharidin to the Present (1999) (0)
- Introduction of Angular Methyl Groups via Radical Cyclization. (1990) (0)
- SYNTH. VON ALKYL‐PYRROLONEN UND DIHYDRO‐PYRIDONEN (1970) (0)
- Iterative Butenolide Construction of Polypropionate Chains. (1987) (0)
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