Gregory Fu
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Professor of organic chemistry at the California Institute of Technology
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Chemistry
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#935
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Organic Chemistry
#69
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#99
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#29
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Chemistry
Why Is Gregory Fu Influential?
(Suggest an Edit or Addition)According to Wikipedia, Gregory C. Fu is a Professor of organic chemistry at the California Institute of Technology and the Norman Chandler Professor of Chemistry. The current research interests of the Fu laboratory include metal-catalyzed coupling reactions and the design of chiral catalysts. In particular, the group is focused on the development of nickel-catalyzed enantioselective cross-couplings of alkyl electrophiles and on photoinduced, copper-catalyzed carbon–heteroatom bond-forming reactions. The group works in collaboration with the laboratory of Professor Jonas C. Peters.
Gregory Fu's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Palladium-catalyzed coupling reactions of aryl chlorides. (2002) (1997)
- Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions (2000) (1120)
- Substrate-directable chemical reactions (1993) (991)
- Ring-Closing Metathesis and Related Processes in Organic Synthesis (1995) (686)
- The development of versatile methods for palladium-catalyzed coupling reactions of aryl electrophiles through the use of P(t-Bu)3 and PCy3 as ligands. (2008) (602)
- A Convenient and General Method for Pd-Catalyzed Suzuki Cross-Couplings of Aryl Chlorides and Arylboronic Acids. (1998) (501)
- A versatile catalyst for Heck reactions of aryl chlorides and aryl bromides under mild conditions. (2001) (486)
- Asymmetric copper-catalyzed C-N cross-couplings induced by visible light (2016) (434)
- Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry (2017) (420)
- Air-stable trialkylphosphonium salts: simple, practical, and versatile replacements for air-sensitive trialkylphosphines. Applications in stoichiometric and catalytic processes. (2001) (411)
- Catalytic ring-closing metathesis of functionalized dienes by a ruthenium carbene complex (1993) (391)
- Nickel‐Catalyzed Cross‐Couplings of Unactivated Alkyl Halides and Pseudohalides with Organometallic Compounds (2004) (386)
- Asymmetric catalysis with "planar-chiral" derivatives of 4-(dimethylamino)pyridine. (2004) (340)
- Photoinduced Ullmann C–N Coupling: Demonstrating the Viability of a Radical Pathway (2012) (329)
- Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis. (2016) (327)
- The first applications of carbene ligands in cross-couplings of alkyl electrophiles: sonogashira reactions of unactivated alkyl bromides and iodides. (2003) (317)
- Pd(PhCN)(2)Cl(2)/P(t-Bu)(3): a versatile catalyst for Sonogashira reactions of aryl bromides at room temperature. (2000) (316)
- Enantioselective nucleophilic catalysis with "Planar-Chiral" heterocycles. (2000) (311)
- Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides. (2002) (308)
- Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes (2017) (299)
- A versatile method for Suzuki cross-coupling reactions of nitrogen heterocycles. (2006) (294)
- The first general method for palladium-catalyzed Negishi cross-coupling of aryl and vinyl chlorides: use of commercially available Pd(P(t-Bu)(3))(2) as a catalyst. (2001) (292)
- Room-temperature alkyl-alkyl Suzuki cross-coupling of alkyl bromides that possess beta hydrogens. (2001) (292)
- Heck Reactions in the Presence of P(t-Bu)(3): Expanded Scope and Milder Reaction Conditions for the Coupling of Aryl Chlorides. (1999) (280)
- Catalytic asymmetric synthesis of piperidine derivatives through the [4 + 2] annulation of imines with allenes. (2005) (273)
- Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation (2014) (271)
- Boronic acids: new coupling partners in room-temperature Suzuki reactions of alkyl bromides. Crystallographic characterization of an oxidative-addition adduct generated under remarkably mild conditions. (2002) (253)
- Synthesis of functionalized cyclopentenes through catalytic asymmetric [3+2] cycloadditions of allenes with enones. (2006) (252)
- Nickel-catalyzed carbon-carbon bond-forming reactions of unactivated tertiary alkyl halides: Suzuki arylations. (2013) (244)
- Cross-couplings of unactivated secondary alkyl halides: room-temperature nickel-catalyzed Negishi reactions of alkyl bromides and iodides. (2003) (242)
- Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon-boron bonds. (2012) (241)
- A new family of nucleophiles for photoinduced, copper-catalyzed cross-couplings via single-electron transfer: reactions of thiols with aryl halides under mild conditions (O °C). (2013) (235)
- A new copper-catalyzed [3 + 2] cycloaddition: enantioselective coupling of terminal alkynes with azomethine imines to generate five-membered nitrogen heterocycles. (2003) (235)
- Amino alcohols as ligands for nickel-catalyzed suzuki reactions of unactivated alkyl halides, including secondary alkyl chlorides, with arylboronic acids. (2006) (233)
- Asymmetric nickel-catalyzed Negishi cross-couplings of secondary alpha-bromo amides with organozinc reagents. (2005) (231)
- Suzuki cross-couplings of unactivated secondary alkyl bromides and iodides. (2004) (228)
- The application of catalytic ring-closing olefin metathesis to the synthesis of unsaturated oxygen heterocycles (1992) (224)
- Palladium-catalyzed negishi cross-coupling reactions of unactivated alkyl iodides, bromides, chlorides, and tosylates. (2003) (211)
- Effective Kinetic Resolution of Secondary Alcohols with a Planar−Chiral Analogue of 4-(Dimethylamino)pyridine. Use of the Fe(C5Ph5) Group in Asymmetric Catalysis (1997) (206)
- Photoinduced, Copper-Catalyzed Decarboxylative C-N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement. (2017) (206)
- Umpolung of Michael acceptors catalyzed by N-heterocyclic carbenes. (2006) (205)
- Catalytic enantioselective Negishi reactions of racemic secondary benzylic halides. (2005) (201)
- Catalytic enantioselective synthesis of oxindoles and benzofuranones that bear a quaternary stereocenter. (2003) (197)
- Catalytic asymmetric Hiyama cross-couplings of racemic alpha-bromo esters. (2008) (197)
- The synthesis of nitrogen heterocycles via catalytic ring-closing metathesis of dienes (1992) (195)
- Nickel-catalyzed asymmetric negishi cross-couplings of secondary allylic chlorides with alkylzincs. (2008) (193)
- Alkyl-alkyl suzuki cross-couplings of unactivated secondary alkyl halides at room temperature. (2007) (188)
- Rhodium(I)- and iridium(I)-catalyzed hydroboration reactions: scope and synthetic applications (1992) (187)
- Nickel/bis(oxazoline)-catalyzed asymmetric Kumada reactions of alkyl electrophiles: cross-couplings of racemic alpha-bromoketones. (2010) (186)
- New directing groups for metal-catalyzed asymmetric carbon-carbon bond-forming processes: stereoconvergent alkyl-alkyl Suzuki cross-couplings of unactivated electrophiles. (2012) (183)
- Catalytic enantioselective O-H insertion reactions. (2006) (180)
- Enantioselective alkyl-alkyl Suzuki cross-couplings of unactivated homobenzylic halides. (2008) (180)
- Catalytic Enantioconvergent Couplings of Secondary and Tertiary Electrophiles with Olefins (2018) (178)
- Phosphine-catalyzed enantioselective synthesis of oxygen heterocycles. (2009) (178)
- Intramolecular Heck reactions of unactivated alkyl halides. (2007) (173)
- Enantioselective Construction of Quaternary Stereocenters: Rearrangements of O-Acylated Azlactones Catalyzed by a Planar-Chiral Derivative of 4-(Pyrrolidino)pyridine (1998) (168)
- Catalytic Asymmetric Addition of ZnPh2 to Ketones: Enantioselective Formation of Quaternary Stereocenters (1998) (165)
- Application of a new chiral phosphepine to the catalytic asymmetric synthesis of highly functionalized cyclopentenes that bear an array of heteroatom-substituted quaternary stereocenters. (2011) (164)
- Copper-Catalyzed Asymmetric N−H Insertion Reactions: Couplings of Diazo Compounds with Carbamates to Generate α-Amino Acids (2007) (162)
- Transition-metal-catalyzed alkylations of amines with alkyl halides: photoinduced, copper-catalyzed couplings of carbazoles. (2013) (160)
- Enantioselective Staudinger Synthesis of β-Lactams Catalyzed by a Planar-Chiral Nucleophile1 (2002) (156)
- Photoinduced, copper-catalyzed alkylation of amides with unactivated secondary alkyl halides at room temperature. (2014) (155)
- Kinetic resolutions of azomethine imines via copper-catalyzed [3 + 2] cycloadditions. (2005) (154)
- Method for palladium-catalyzed cross-couplings of simple alkyl chlorides: Suzuki reactions catalyzed by [Pd2(dba)3]/PCy3. (2002) (151)
- Nickel-catalyzed asymmetric cross-couplings of racemic propargylic halides with arylzinc reagents. (2008) (150)
- Suzuki cross-couplings of alkyl tosylates that possess beta hydrogen atoms: synthetic and mechanistic studies. (2002) (149)
- Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene‐Catalyzed Ring‐Closing Metathesis. (1994) (149)
- Catalytic asymmetric γ-alkylation of carbonyl compounds via stereoconvergent Suzuki cross-couplings. (2011) (149)
- Stereoconvergent amine-directed alkyl-alkyl Suzuki reactions of unactivated secondary alkyl chlorides. (2011) (148)
- Asymmetric Suzuki cross-couplings of activated secondary alkyl electrophiles: arylations of racemic alpha-chloroamides. (2010) (148)
- Nickel-catalyzed cross-couplings of organosilicon reagents with unactivated secondary alkyl bromides. (2004) (147)
- Room-temperature Hiyama cross-couplings of arylsilanes with alkyl bromides and iodides. (2003) (146)
- Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents. (2005) (146)
- Nickel/bis(oxazoline)-catalyzed asymmetric Negishi arylations of racemic secondary benzylic electrophiles to generate enantioenriched 1,1-diarylalkanes. (2013) (144)
- Asymmetric alkyl-alkyl cross-couplings of unactivated secondary alkyl electrophiles: stereoconvergent Suzuki reactions of racemic acylated halohydrins. (2010) (144)
- Phosphine-catalyzed formation of carbon-sulfur bonds: catalytic asymmetric synthesis of gamma-thioesters. (2010) (144)
- Rhodium(I)-catalyzed hydroboration of olefins. The documentation of regio- and stereochemical control in cyclic and acyclic systems (1988) (143)
- Applications of planar-chiral heterocycles as ligands in asymmetric catalysis. (2006) (143)
- A versatile approach to Ullmann C-N couplings at room temperature: new families of nucleophiles and electrophiles for photoinduced, copper-catalyzed processes. (2013) (142)
- Synthesis of Cycloalkenes via Alkylidene‐Mediated Olefin Metathesis and Carbonyl Olefination. (1993) (142)
- Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents. (2012) (141)
- Kinetic Resolution of Arylalkylcarbinols Catalyzed by a Planar-Chiral Derivative of DMAP: A New Benchmark for Nonenzymatic Acylation (1998) (141)
- A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters (2016) (140)
- Planar-Chiral Heterocycles as Ligands in Metal-Catalyzed Processes: Enantioselective Addition of Organozinc Reagents to Aldehydes. (1997) (139)
- Cu(I)/bis(azaferrocene)-catalyzed enantioselective synthesis of beta-lactams via couplings of alkynes with nitrones. (2002) (138)
- Enantioconvergent cross-couplings of racemic alkylmetal reagents with unactivated secondary alkyl electrophiles: catalytic asymmetric Negishi α-alkylations of N-Boc-pyrrolidine. (2013) (134)
- Asymmetric carbon-carbon bond formation gamma to a carbonyl group: phosphine-catalyzed addition of nitromethane to allenes. (2009) (133)
- Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles (2014) (132)
- Kinetic resolutions of indolines by a nonenzymatic acylation catalyst. (2006) (132)
- Catalytic asymmetric synthesis of secondary nitriles via stereoconvergent Negishi arylations and alkenylations of racemic α-bromonitriles. (2012) (131)
- Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex (2000) (130)
- Toward an improved understanding of the unusual reactivity of Pd0/trialkylphosphane catalysts in cross-couplings of alkyl electrophiles: quantifying the factors that determine the rate of oxidative addition. (2003) (127)
- Hiyama reactions of activated and unactivated secondary alkyl halides catalyzed by a nickel/norephedrine complex. (2007) (125)
- Catalytic enantioselective synthesis of beta-lactams: intramolecular Kinugasa reactions and interception of an intermediate in the reaction cascade. (2003) (123)
- Mechanistic Study of the Rhodium(I)-Catalyzed Hydroboration Reaction (1992) (121)
- Parallel kinetic resolution of 4-alkynals catalyzed by Rh(I)/Tol-BINAP: synthesis of enantioenriched cyclobutanones and cyclopentenones. (2003) (121)
- Elucidating reactivity differences in palladium-catalyzed coupling processes: the chemistry of palladium hydrides. (2004) (118)
- Catalytic asymmetric Staudinger reactions to form beta-lactams: an unanticipated dependence of diastereoselectivity on the choice of the nitrogen substituent. (2005) (117)
- Planar-chiral pyridine N-oxides, a new family of asymmetric catalysts: exploiting an eta(5)-C(5)Ar(5) ligand to achieve high enantioselectivity. (2001) (116)
- Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic α,α-Dihaloketones (2014) (115)
- Nonenzymatic Kinetic Resolution of Propargylic Alcohols by a Planar−Chiral DMAP Derivative: Crystallographic Characterization of the Acylated Catalyst (1999) (115)
- A straightforward and mild synthesis of functionalized 3-alkynoates. (2004) (115)
- Dynamic Kinetic Resolutions Catalyzed by a Planar-Chiral Derivative of DMAP: Enantioselective Synthesis of Protected α-Amino Acids from Racemic Azlactones (1998) (114)
- Enantioselective alkenylation via nickel-catalyzed cross-coupling with organozirconium reagents. (2010) (108)
- A versatile new catalyst for the enantioselective isomerization of allylic alcohols to aldehydes: scope and mechanistic studies. (2001) (108)
- Kinetic Resolution of Amines by a Nonenzymatic Acylation Catalyst. (2001) (106)
- Catalytic asymmetric cross-couplings of racemic alpha-bromoketones with arylzinc reagents. (2009) (102)
- Application of a new family of P,N ligands to the highly enantioselective hydrosilylation of aryl alkyl and dialkyl ketones. (2002) (102)
- Catalytic asymmetric C-N bond formation: phosphine-catalyzed intra- and intermolecular γ-addition of nitrogen nucleophiles to allenoates and alkynoates. (2013) (102)
- A New Class of Planar−Chiral Ligands: Synthesis of a C2-Symmetric Bisazaferrocene and Its Application in the Enantioselective Cu(I)-Catalyzed Cyclopropanation of Olefins (1998) (101)
- Alkyl-alkyl Suzuki cross-coupling of unactivated secondary alkyl chlorides. (2010) (100)
- A surprisingly mild and versatile method for palladium-catalyzed Suzuki cross-couplings of aryl chlorides in the presence of a triarylphosphine. (2001) (99)
- Copper-catalyzed asymmetric [4+1] cycloadditions of enones with diazo compounds to form dihydrofurans. (2007) (99)
- A versatile new method for the synthesis of cyclopentenones via an unusual rhodium-catalyzed intramolecular trans hydroacylation of an alkyne. (2001) (99)
- Nucleophile-catalyzed asymmetric acylations of silyl ketene imines: application to the enantioselective synthesis of verapamil. (2005) (98)
- Academic cross-fertilization by public screening yields a remarkable class of protein phosphatase methylesterase-1 inhibitors (2011) (95)
- Asymmetric synthesis of highly substituted beta-lactones by nucleophile-catalyzed [2+2] cycloadditions of disubstituted ketenes with aldehydes. (2004) (95)
- Conjugate reduction of .alpha.,.beta.-unsaturated carbonyl compounds by catecholborane (1990) (94)
- Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones (2014) (93)
- Enantioselective addition of amines to ketenes catalyzed by a planar-chiral derivative of PPY: possible intervention of chiral Brønsted-acid catalysis. (2002) (92)
- Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens. (2003) (92)
- Use of a new spirophosphine to achieve catalytic enantioselective [4 + 1] annulations of amines with allenes to generate dihydropyrroles. (2015) (91)
- Nickel-catalyzed enantioselective cross-couplings of racemic secondary electrophiles that bear an oxygen leaving group. (2012) (88)
- Copper-Catalyzed Alkylation of Aliphatic Amines Induced by Visible Light. (2017) (88)
- A mild, palladium-catalyzed method for the dehydrohalogenation of alkyl bromides: synthetic and mechanistic studies. (2012) (87)
- The kinetic resolution of allylic alcohols by a non-enzymatic acylation catalyst; application to natural product synthesis (2000) (87)
- Design of a Photoredox Catalyst that Enables the Direct Synthesis of Carbamate-Protected Primary Amines via Photoinduced, Copper-Catalyzed N-Alkylation Reactions of Unactivated Secondary Halides. (2017) (85)
- Photoinduced, Copper-Catalyzed Carbon-Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature. (2015) (84)
- Catalyst-controlled doubly enantioconvergent coupling of racemic alkyl nucleophiles and electrophiles (2020) (84)
- Enantioselective Addition of Alcohols to Ketenes Catalyzed by a Planar-Chiral Azaferrocene: Catalytic Asymmetric Synthesis of Arylpropionic Acids (1999) (83)
- Biphenyl-derived phosphepines as chiral nucleophilic catalysts: enantioselective [4+1] annulations to form functionalized cyclopentenes. (2014) (83)
- Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones in the presence of planar-chiral phosphaferrocene-oxazoline ligands. (2002) (83)
- Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF3 and an Alkyl Group. (2015) (81)
- Phosphine-catalyzed asymmetric additions of malonate esters to γ-substituted allenoates and allenamides (2010) (81)
- Nickel-catalyzed Negishi cross-couplings of secondary nucleophiles with secondary propargylic electrophiles at room temperature. (2008) (81)
- Catalytic asymmetric synthesis of esters from ketenes. (2005) (80)
- Phosphine-Catalyzed Enantioselective Intramolecular [3+2] Annulations To Generate Fused Ring Systems (2015) (79)
- Catalytic enantioselective synthesis of quaternary stereocenters via intermolecular C-acylation of silyl ketene acetals: dual activation of the electrophile and the nucleophile. (2003) (79)
- Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex. (2019) (78)
- The First Application of a Planar-Chiral Phosphorus Heterocycle in Asymmetric Catalysis: Enantioselective Hydrogenation of Dehydroamino Acids (1998) (75)
- Nonenzymatic dynamic kinetic resolution of secondary alcohols via enantioselective acylation: synthetic and mechanistic studies. (2012) (74)
- Bu3SnH-Catalyzed Barton−McCombie Deoxygenation of Alcohols (1997) (74)
- Enantioselective synthesis of cyclopentenones via rhodium-catalyzed kinetic resolution and desymmetrization of 4-alkynals. (2002) (74)
- Silicon-Carbon Bond Formation via Nickel-Catalyzed Cross-Coupling of Silicon Nucleophiles with Unactivated Secondary and Tertiary Alkyl Electrophiles. (2016) (72)
- The chemistry of borabenzenes (1986–2000) (2001) (67)
- Enantioselective nucleophilic catalysis: the synthesis of aza-beta-lactams through [2+2] cycloadditions of ketenes with azo compounds. (2008) (67)
- Catalytic asymmetric cycloaddition of ketenes and nitroso compounds: enantioselective synthesis of alpha-hydroxycarboxylic acid derivatives. (2009) (67)
- Stereoselective phosphine-catalyzed synthesis of highly functionalized diquinanes. (2010) (66)
- Asymmetric Michael reactions of 3,5-dihydro-4H-dinaphth[2,1-c:1',2'-e]azepine with methyl crotonate (1986) (65)
- Ligands for palladium-catalyzed cross-couplings of alkyl halides: use of an alkyldiaminophosphane expands the scope of the Stille reaction. (2003) (65)
- Amide-directed, iridium-catalyzed hydroboration of olefins : documentation of regio- and stereochemical control in cyclic and acyclic systems (1991) (65)
- Photoinduced, Copper-Catalyzed Alkylation of Amines: A Mechanistic Study of the Cross-Coupling of Carbazole with Alkyl Bromides. (2017) (63)
- Catalytic enantioselective construction of all-carbon quaternary stereocenters: synthetic and mechanistic studies of the C-acylation of silyl ketene acetals. (2005) (61)
- Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives (2015) (61)
- Nucleophilic Catalysis with π-Bound Nitrogen Heterocycles: Synthesis of the First Ruthenium Catalysts and Comparison of the Reactivity and the Enantioselectivity of Ruthenium and Iron Complexes (1998) (61)
- Chemistry of Borabenzene: Efficient and General Synthesis of New Neutral Borabenzene−Ligand Complexes (1996) (60)
- Synthesis, resolution and crystallographic characterization of a new C2-symmetric planar-chiral bipyridine ligand: application to the catalytic enantioselective cyclopropanation of olefins (2000) (59)
- Oxygen nucleophiles as reaction partners in photoinduced, copper-catalyzed cross-couplings: O-arylations of phenols at room temperature (2014) (58)
- Cross-couplings of alkyl electrophiles under "ligandless" conditions: Negishi reactions of organozirconium reagents. (2004) (57)
- Catalytic asymmetric couplings of ketenes with aldehydes to generate enol esters. (2005) (56)
- Asymmetric [3 + 2] annulations catalyzed by a planar-chiral derivative of DMAP. (2006) (56)
- Enantioselective Nucleophile-Catalyzed Synthesis of Tertiary Alkyl Fluorides via the α-Fluorination of Ketenes: Synthetic and Mechanistic Studies (2014) (55)
- Enantioselective Carbon-Sulfur Bond Formation: γ Additions of Aryl Thiols to Allenoates Catalyzed by a Chiral Phosphepine. (2011) (55)
- Visible-Light-Induced, Copper-Catalyzed Three-Component Coupling of Alkyl Halides, Olefins, and Trifluoromethylthiolate to Generate Trifluoromethyl Thioethers. (2018) (53)
- The rhodium-catalyzed hydroboration of olefins: a mechanistic investigation (1990) (53)
- Photoinduced copper-catalysed asymmetric amidation via ligand cooperativity (2021) (52)
- Applications of planar-chiral heterocycles in enantioselective catalysis: Cu(I)/bisazaferrocene-catalyzed asymmetric ring expansion of oxetanes to tetrahydrofurans (2001) (52)
- Diphenylphosphidoboratabenzene: An Anionic Analogue of Triphenylphosphine (1996) (51)
- A new benchmark for the non-enzymatic enantioselective acylation of amines: use of a planar-chiral derivative of 4-pyrrolidinopyridine as the acylating agent (2000) (51)
- Highly enantioselective desymmetrization of anhydrides by carbon nucleophiles: reactions of Grignard reagents in the presence of (-)-sparteine. (2002) (50)
- Nucleophilic Aromatic Substitution Reactions of Borabenzene-Trimethylphosphine: A Versatile Route to 1-Substituted Boratabenzenes (1996) (50)
- pi-Bound Phosphorus Heterocycles as Catalysts: Ring Opening of Epoxides with TMSCl in the Presence of a Phosphaferrocene. (1997) (50)
- Bu3SnH-Catalyzed Reduction of Nitroalkanes to Alkanes (1998) (47)
- Organotin Hydride-Catalyzed Conjugate Reduction of alpha,beta-Unsaturated Ketones. (1996) (46)
- Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water. (2010) (46)
- A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide (2016) (46)
- Metal Hydride Mediated Intramolecular Pinacol Coupling of Dialdehydes and Ketoaldehydes (1995) (45)
- Development of Bu3SnH-Catalyzed Processes: Efficient Reduction of Azides to Amines (1998) (44)
- Convergent Catalytic Asymmetric Synthesis of Esters of Chiral Dialkyl Carbinols. (2020) (43)
- Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent. (2015) (43)
- Competitive activity-based protein profiling identifies aza-β-lactams as a versatile chemotype for serine hydrolase inhibition. (2012) (43)
- Control of Vicinal Stereocenters through Nickel-Catalyzed Alkyl-Alkyl Cross-Coupling. (2017) (43)
- Organotin Hydride Catalyzed Carbon−Carbon Bond Formation: Radical-Mediated Reductive Cyclization of Enals and Enones (1996) (43)
- Rhodium-catalyzed synthesis of cyclohexenones via a novel [4 + 2] annulation. (2002) (40)
- Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles. (2018) (39)
- Hydroboration of Olefins with Catecholborane at Room Temperature in the Presence of N,N-Dimethylacetamide (1996) (38)
- Enantioconvergent Cross-Couplings of Alkyl Electrophiles: The Catalytic Asymmetric Synthesis of Organosilanes. (2019) (38)
- Enantioselective synthesis of protected amines by the catalytic asymmetric addition of hydrazoic acid to ketenes. (2007) (38)
- Convenient and efficient conversion of aldehydes to acylated cyanohydrins using tributyltin cyanide as catalyst (1995) (35)
- A Boron Analogue of Benzene: Synthesis, Structure, and Reactivity of 1-H-Boratabenzene (1995) (35)
- Catalytic asymmetric synthesis of tertiary alkyl chlorides. (2007) (35)
- Bu3SnH-Mediated Pinacol Coupling of 1,5- and 1,6-Dicarbonyl Compounds: Synthetic and Mechanistic Studies (1998) (34)
- First Synthesis and Structural Characterization of an Enantiomerically Pure Planar-Chiral Lewis Acid Complex. (1997) (34)
- Synthesis and Resolution of Planar‐Chiral Derivatives of 4‐(Dimethylamino)pyridine (2007) (34)
- A mild, convenient, and inexpensive method for converting imines into amines: Tin-catalyzed reduction with polymethylhydrosiloxane (PMHS) (1997) (33)
- Catalytic Enantioselective Carbon-Oxygen Bond Formation: Phosphine-Catalyzed Synthesis of Benzylic Ethers via the Oxidation of Benzylic C-H Bonds. (2016) (32)
- Versatile Catalysts for the Suzuki Cross‐Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions. (2000) (31)
- Exploiting η5- to η3-Indenyl Ring Slippage to Access a Directed Reaction: Ether-Directed, Rhodium-Catalyzed Olefin Hydroboration (1998) (31)
- Enantioconvergent Alkylations of Amines by Alkyl Electrophiles: Copper-Catalyzed Nucleophilic Substitutions of Racemic α-Halolactams by Indoles. (2019) (29)
- A Novel Rhodium‐Catalyzed Reduction–Oxidation Process: Reaction of 4‐Alkynals with Phenol to Provide cis‐4‐Alkenoates (2002) (27)
- Recent Advances in Rhodium(I)‐Catalyzed Asymmetric Olefin Isomerization and Hydroacylation Reactions (2005) (26)
- Direct Crystallographic Comparison of P−B and N−B π-Bonding: Structural Studies of Diphenylphosphido- and Diphenylamidoboratabenzene (1997) (25)
- Synthesis, resolution, and aldol reactions of a planar-chiral Lewis acid complex. (2005) (25)
- From the design of a chiral Lewis acid catalyst to metal-catalyzed coupling reactions. (2004) (24)
- 1,2-azaborolyls, isoelectronic analogues of the ubiquitous cyclopentadienyl ligand: synthesis of B-heteroatom-substituted 1,2-azaborolyl complexes and an assessment of their electronic features. (2002) (24)
- Alkyl—Alkyl Suzuki Cross‐Couplings of Unactivated Secondary Alkyl Halides at Room Temperature. (2007) (24)
- The First General Method for the Synthesis of Transition-Metal π Complexes of an Electronically Diverse Family of 1,2-Azaborolyls (2002) (23)
- Quaternary stereocentres via catalytic enantioconvergent nucleophilic substitution reactions of tertiary alkyl halides by alkenylmetal reagents (2020) (23)
- Synthesis, Structure, and Reactivity of C2-Symmetric Bis(phospholyl)zirconium and Bis(phospholyl)hafnium Complexes (2001) (23)
- Defining the Conformation of Lewis Acid/Lewis Base Complex: Crystallographic Evidence for Simultaneous σ and π Donation by a Carbonyl Group to a Divalent Boron Lewis Acid (1997) (20)
- Synthesis, Resolution, and Crystallographic Characterization of a C2-Symmetric Diphosphaferrocene (1998) (20)
- The Asymmetric Synthesis of Amines via Nickel-Catalyzed Enantioconvergent Substitution Reactions. (2021) (19)
- Room-Temperature Alkyl—Alkyl Suzuki Cross-Coupling of Alkyl Bromides that Possess β Hydrogens. (2002) (19)
- Diastereoselective Synthesis of beta-Amino Alcohols via Bu(3)SnH-Mediated Reductive Cyclization of Carbonyl-Oxime Ethers. (1998) (18)
- Enantioselective Alkyl—Alkyl Suzuki Cross-Couplings of Unactivated Homobenzylic Halides. (2008) (17)
- Photoinduced, Copper-Catalyzed Enantioconvergent Alkylations of Anilines by Racemic Tertiary Electrophiles: Synthesis and Mechanism. (2022) (16)
- Asymmetric Synthesis of Protected Unnatural α-Amino Acids via Enantioconvergent Nickel-Catalyzed Cross-Coupling. (2021) (16)
- Tributyltin Cyanide-Catalyzed Addition of Triethylsilyl Cyanide to Aldehydes (1994) (16)
- A New Method for Generating Sn-H Bonds: Reactions of Tin Amides with Silicon Hydrides. (1997) (16)
- First synthesis and resolution of a planar-chiral tetrahydroindolyl complex of iron: electronic tuning of reactivity and enantioselective nucleophilic catalysis. (2000) (15)
- Catalytic Enantioselective Synthesis of β-Lactams: Intramolecular Kinugasa Reactions and Interception of an Intermediate in the Reaction Cascade. (2003) (15)
- Hydroxyl-Directed, Stereoselective Olefination of Ketones by Transition Metal Alkylidenes (1995) (15)
- Caution in the Use of Nonlinear Effects as a Mechanistic Tool for Catalytic Enantioconvergent Reactions: Intrinsic Negative Nonlinear Effects in the Absence of Higher-Order Species. (2017) (15)
- Synthesis and Structure of Borabenzene−4-Phenylpyridine, a Heterocyclic Analogue of p-Terphenyl (1997) (15)
- Asymmetric Nickel‐Catalyzed Negishi Cross‐Coupling of Secondary α‐Bromo Amides with Organozinc Reagents. (2005) (15)
- Catalytic Asymmetric Cross‐Couplings of Racemic α‐Bromoketones with Arylzinc Reagents. (2009) (15)
- The development of a new catalytic process: Bu3SnH-catalyzed reductive cyclization of enals and enones (1999) (13)
- Catalytic Asymmetric Hiyama Cross‐Couplings of Racemic α‐Bromo Esters. (2008) (12)
- Heck Reactions in the Presence of P(t‐Bu)3: Expanded Scope and Milder Reaction Conditions for the Coupling of Aryl Chlorides. (1999) (12)
- Effective Kinetic Resolution of Secondary Alcohols with a Planar- Chiral Analogue of 4-(Dimethylamino)pyridine. Use of the Fe(C5Ph5) Group in Asymmetric Catalysis. (1997) (12)
- Heck reactions of aryl chlorides catalyzed by palladium/TRI-tert-butylphosphine: (E)-2-Methyl-3-phenylacrylic acid butyl ester and (E)-4-(2-phenylethenyl)benzonitrile: [2-propenoic acid, 2-methyl-3-phenyl-, butyl ester and benzonitrile, 4-[(1e)-2-phenylethenyl]] (2005) (12)
- The synthesis of an enantiopure planar-chiral Lewis acid complex via kinetic resolution and its application in stereoselective additions to imines (2006) (11)
- Palladium‐Catalyzed Cross‐Coupling Reactions of Unactivated Alkyl Electrophiles with Organometallic Compounds (2006) (11)
- Nucleophilic Addition γ to the Carbonyl Group (2009) (11)
- Enantioconvergent Cross‐Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α‐Alkylations of N‐Boc‐Pyrrolidine. (2014) (10)
- A unique rhodium-catalyzed rearrangement process: isomerization of an alkyne to a 1,3-diene with concomitant migration of a formyl group. An expeditious route to dienals from readily available 4-alkynals. (2002) (10)
- Asymmetric Synthesis of Highly Substituted β‐Lactones by Nucleophile‐Catalyzed [2 + 2] Cycloadditions of Disubstituted Ketenes with Aldehydes. (2005) (10)
- Transition Metal‐Catalyzed Hydroboration of Olefins (2008) (9)
- Chiral pi-Complexes of Heterocycles with Transition Metals: A Versatile New Family of Nucleophilic Catalysts. (1997) (9)
- Asymmetric catalysis with "planar-chiral" heterocycles (2001) (9)
- Transition‐Metal‐Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper‐Catalyzed Couplings of Carbazoles. (2013) (8)
- Cu(I)/Bis(azaferrocene)-Catalyzed Enantioselective Synthesis of β-Lactams via Couplings of Alkynes with Nitrones. (2002) (8)
- Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins (2018) (8)
- Applications of Aza‐ and Phosphaferrocenes and Related Compounds in Asymmetric Catalysis (2010) (8)
- Investigation of the C-N Bond-Forming Step in a Photoinduced, Copper-Catalyzed Enantioconvergent N-Alkylation: Characterization and Application of a Stabilized Organic Radical as a Mechanistic Probe. (2022) (7)
- Umpolung of Michael Acceptors Catalyzed by N‐Heterocyclic Carbenes. (2006) (7)
- Asymmetric Catalysis with “Planar‐Chiral” Derivatives of 4‐(Dimethylamino)pyridine (2004) (7)
- NICKEL-CATALYZED ENANTIOSELECTIVE NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY α-BROMO AMIDES WITH ALKYLZINC REAGENTS: (S)-N-BENZYL-7-CYANO-2-ETHYL-N-PHENYLHEPTANAMIDE. (2010) (7)
- Nonenzymatic Kinetic Resolution of Propargylic Alcohols by a Planar−Chiral DMAP Derivative: Crystallographic Characterization of the Acylated Catalyst [J. Am. Chem. Soc. 1999, 121, 5091−5092]. (1999) (7)
- Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides, Including Secondary Alkyl Chlorides with Arylboronic Acids. (2006) (7)
- Pd(PhCN)2Cl2/P(t-Bu)3: A Versatile Catalyst for Sonogashira Reactions of Aryl Bromides at Room Temperature. (2000) (6)
- The Application of Catalytic Ring-Closing Olefin Metathesis to the Synthesis of Unsaturated Oxygen Heterocycles. (1992) (6)
- Enantioselective Nucleophilic Catalysis: The Synthesis of Aza‐β‐lactams Through [2 + 2] Cycloadditions of Ketenes with Azo Compounds. (2008) (6)
- Tributylstannane (Bu3SnH)-Catalyzed Barton-McCombie Deoxygenation of Alcohols: 3-Deoxy-1,2:5,6-Bis-O-(1-Methylethylidene)-α-D-Ribo-Hexofuranose (2003) (6)
- The First General Method for Palladium‐Catalyzed Negishi Cross‐Coupling of Aryl and Vinyl Chlorides: Use of Commercially Available Pd(P(t‐Bu)3)2 as a Catalyst. (2001) (6)
- Air‐Stable Trialkylphosphonium Salts: Simple, Practical, and Versatile Replacements for Air‐Sensitive Trialkylphosphines. Applications in Stoichiometric and Catalytic Processes. (2002) (6)
- Enantioselective Isomerization of Allylic Alcohols Catalyzed by a Rhodium/Phosphaferrocene Complex. (2001) (6)
- A Versatile Method for Suzuki Cross‐Coupling Reactions of Nitrogen Heterocycles. (2006) (5)
- Catalytic Asymmetric Staudinger Reactions to Form β-Lactams: An Unanticipated Dependence of Diastereoselectivity on the Choice of the Nitrogen Substituent. (2005) (5)
- Kinetic Resolution of Arylalkylcarbinols Catalyzed by a Planar-Chiral Derivative of DMAP: A New Benchmark for Nonenzymatic Acylation. (1998) (5)
- Nucleophilic Catalysis with π-Bound Nitrogen Heterocycles: Synthesis of the First Ruthenium Catalysts and Comparison of the Reactivity and the Enantioselectivity of Ruthenium and Iron Complexes J. Am. Chem. Soc. 1998, 120, 7479−7483 (1998) (5)
- Conjugate Reduction of a,@-Unsaturated Carbonyl Compounds by Catecholborane (1990) (5)
- Heck Reactions of Aryl Chlorides Catalyzed by Palladium/Tri‐tert‐butylphosphine: (E)‐2‐Methyl‐3‐Phenylacrylic Acid Butyl Ester and (E)‐4‐(2‐Phenylethenyl)benzonitrile (2005) (5)
- A New Class of Planar—Chiral Ligands: Synthesis of a C2-Symmetric Bisazaferrocene and Its Application in the Enantioselective Cu(I)-Catalyzed Cyclopropanation of Olefins. (2010) (4)
- Chapter 3. Pinacol Coupling (2007) (4)
- Oxygen Nucleophiles as Reaction Partners in Photoinduced, Copper‐Catalyzed Cross‐Couplings: O‐Arylations of Phenols at Room Temperature. (2014) (4)
- Applications of "planar-chiral" heterocycles in asymmetric catalysis (2001) (4)
- PALLADIUM-CATALYZED ALKYL-ALKYL SUZUKI CROSS-COUPLINGS OF PRIMARY ALKYL BROMIDES AT ROOM-TEMPERATURE: (13-CHLOROTRIDECYLOXY)TRIETHYLSILANE [Silane, [(13-chlorotridecyl)oxy]triethyl-]. (2010) (4)
- Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic α,α-Dihaloketones. (2014) (4)
- Catalytic Asymmetric C—N Bond Formation: Phosphine‐Catalyzed Intra‐ and Intermolecular γ‐Addition of Nitrogen Nucleophiles to Allenoates and Alkynoates. (2013) (4)
- SYNTHESIS OF CHIRAL PYRIDINE BIS(OXAZOLINE) LIGANDS FOR NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: 2,6-BIS[(4S)-4,5-DIHYDRO-4-(2-PHENYLETHYL)-2-OXAZOLYL]-PYRIDINE. (2011) (4)
- Asymmetric Copper‐Catalyzed C—N Cross‐Couplings Induced by Visible Light. (2016) (4)
- ChemInform Abstract: A Method for Palladium-Catalyzed Cross-Couplings of Simple Alkyl Chlorides: Suzuki Reactions Catalyzed by [Pd2(dba)3]/PCy3. (2002) (4)
- Planar‐Chiral Pyridine N‐Oxides, a New Family of Asymmetric Catalysts: Exploiting an η5‐C5Ar5 Ligand to Achieve High Enantioselectivity. (2001) (3)
- Metal—Catalyzed Hydroboration Reactions (2008) (3)
- Copper-Catalyzed Asymmetric [4 + 1] Cycloadditions of Enones with Diazo Compounds to Form Dihydrofurans. (2007) (3)
- Suzuki Cross-Couplings of Alkyl Tosylates that Possess β Hydrogen Atoms: Synthetic and Mechanistic Studies. (2003) (3)
- Catalytic Asymmetric Addition of ZnPh2 to Ketones: Enantioselective Formation of Quaternary Stereocenters. (1998) (3)
- Nickel-Catalyzed Alkyl—Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds Having a Perfluoroalkyl Substituent. (2015) (3)
- Titelbild: Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter (Angew. Chem. 33/2003) (2003) (3)
- Nickel-Catalyzed Asymmetric Negishi Cross-Coupling of Secondary Allylic Chlorides with Alkylzincs. (2008) (3)
- Hydroboration of Olefins with Catecholborane at Room Temperature in the Presence of N,N‐Dimethylacetamide. (1996) (3)
- Development of Bu3SnH‐Catalyzed Processes: Efficient Reduction of Azides to Amines. (1998) (3)
- Convenient and Efficient Conversion of Aldehydes to Acylated Cyanohydrins Using Tributyltin Cyanide as a Catalyst. (1996) (3)
- Enantioselective Addition of Alcohols to Ketenes Catalyzed by a Planar‐Chiral Azaferrocene: Catalytic Asymmetric Synthesis of Arylpropionic Acids. (1999) (3)
- Synthesis of Functionalized Cyclopentenes Through Catalytic Asymmetric [3 + 2] Cycloadditions of Allenes with Enones. (2006) (3)
- NICKEL-CATALYZED ASYMMETRIC NEGISHI CROSS-COUPLINGS OF RACEMIC SECONDARY ALLYLIC CHLORIDES WITH ALKYLZINCS: (S,E)-ETHYL 6-(1,3-DIOXOLAN-2-YL)-4-METHYLHEX-2-ENOATE. (2011) (3)
- Planar—Chiral Heterocycles as Enantioselective Organocatalysts (2008) (2)
- Enantioselective Staudinger synthesis of beta-lactams catalyzed by a planar-chiral nucleophile. (2002) (2)
- Copper-catalyzed asymmetric N-H insertion reactions: couplings of diazo compounds with carbamates to generate alpha-amino acids. (2007) (2)
- Suzuki Cross‐Couplings of Unactivated Secondary Alkyl Bromides and Iodides. (2004) (2)
- New applications of organometallic catalysts in organic chemistry (2002) (2)
- Suzuki Cross-Coupling Reaction Between Unactivated Alkyl Halides and Alkyl Borates (2007) (2)
- π‐Bound Phosphorus Heterocycles as Catalysts: Ring Opening of Epoxides with TmsCl in the Presence of a Phosphaferrocene (1997) (2)
- Probe Development Efforts to Identify Novel Inhibitors of Protein Phosphatase Methylesterase-1 (PME-1) (2011) (2)
- Alkyl—Alkyl Suzuki Cross-Coupling of Unactivated Secondary Alkyl Chlorides. (2011) (2)
- The First Application of a Planar-Chiral Phosphorus Heterocycle in Asymmetric Catalysis: Enantioselective Hydrogenation of Dehydroamino Acids. (1998) (2)
- Rhodium(I)-Catalyzed Hydroboration of Olefins. The Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems. (1989) (2)
- Palladium‐Catalyzed Negishi Cross‐Coupling Reactions of Unactivated Alkyl Iodides, Bromides, Chlorides, and Tosylates. (2004) (2)
- Enantioselective Synthesis of α-Aminoboronic Acid Derivatives via Copper-Catalyzed N-Alkylation. (2023) (2)
- Nickel-Catalyzed Asymmetric Negishi Cross-Couplings (2008) (2)
- Catalytic Enantioselective α-Alkylation of Amides by Unactivated Alkyl Electrophiles. (2022) (2)
- Room-Temperature Stille Cross-Couplings of Alkenyltin Reagents and Functionalized Alkyl Bromides that Possess β Hydrogens. (2003) (2)
- Amine-Directed Alkyl-Alkyl Suzuki Reactions (2011) (1)
- Catalytic Enantioselective O—H Insertion Reactions. (2006) (1)
- Asymmetric Catalysis with “Planar‐Chiral” Heterocycles (2001) (1)
- Metal Hydride Mediated Intramolecular Pinacol Coupling of Dialdehydes and Ketoaldehydes. (1995) (1)
- Catalytic Enantioselective Cyclization/Cross‐Coupling with Alkyl Electrophiles. (2014) (1)
- The Development of a New Catalytic Process: Bu3SnH-Catalyzed Reductive Cyclization of Enals and Enones. (1999) (1)
- Cover Picture: Catalytic Enantioselective Synthesis of Oxindoles and Benzofuranones That Bear a Quaternary Stereocenter (Angew. Chem. Int. Ed. 33/2003) (2003) (1)
- PALLADIUM-CATALYZED ALKYL-ALKYL SUZUKI CROSS-COUPLINGS OF PRIMARY ALKYL BROMIDES AT ROOM-TEMPERATURE: (13-CHLOROTRIDECYLOXY)TRIETHYLSILANE [Silane, [(13-chlorotridecyl)oxy]triethyl-] (2010) (1)
- Applications of Planar‐Chiral Heterocycles in Enantioselective Catalysis: Cu(I)/Bisazaferrocene‐Catalyzed Asymmetric Ring Expansion of Oxetanes to Tetrahydrofurans. (2001) (1)
- Synthesis and Application of Planar-Chiral Phosphaferrocene-Oxazolines, a New Class of P,N-Ligands. (2001) (1)
- A novel rhodium-catalyzed reduction-oxidation process: reaction of 4-alkynals with phenol to provide cis-4-alkenoates. (2002) (1)
- Hydroxyl‐Directed, Stereoselective Olefination of Ketones by Transition Metal Alkylidenes. (1995) (1)
- Probe Development Efforts to Identify Novel Inhibitors of ABHD10 (2013) (1)
- Chemistry of Borabenzene: Efficient and General Synthesis of New Neutral Borabenzene‐Ligand Complexes. (1996) (1)
- Asymmetric Michael Reactions of 3,5-Dihydro-4H-dinaphth(2,1-c:1′,2′-e)azepine with Methyl Crotonate. (1987) (1)
- Phosphine-Catalyzed Synthesis of Diquinanes (2010) (1)
- Organocatalytic Asymmetric Synthesis of Tertiary Alkyl Chlorides (2007) (1)
- Synthesis of chiral diamine ligands for nickel-catalyzed asymmetric cross-couplings of alkylchloroboronate esters with alkylzincs: (1R,2R)-N,N'-dimethyl-1,2-bis(2-methylphenyl)-1,2-diaminoethane. (2019) (1)
- Synthesis of Nitrogen Heterocycles via Catalytic Ring-Closing Metathesis of Dienes. (1992) (1)
- Organotin Hydride Catalyzed Carbon‐Carbon Bond Formation: Radical‐ Mediated Reductive Cyclization of Enals and Enones. (1996) (1)
- Diastereoselective Synthesis of β-Amino Alcohols via Bu3SnH-Mediated Reductive Cyclization of Carbonyl—Oxime Ethers. (1998) (1)
- Nickel-Catalyzed Cross-Coupling of Organosilicon Reagents with Unactivated Secondary Alkyl Bromides. (2004) (1)
- A Versatile New Method for the Synthesis of Cyclopentenones via an Unusual Rhodium‐Catalyzed Intramolecular trans Hydroacylation of an Alkyne. (2002) (1)
- Metal-catalyzed cross-coupling reactions of alkyl electrophiles (2015) (1)
- Bu3SnH-Catalyzed Reduction of Nitroalkanes to Alkanes. (1998) (1)
- Csp3-Csp3 SuzukiCross-Coupling Using Unactivated Secondary Alkyl Chlorides (2010) (1)
- Synthesis, Resolution, and Aldol Reactions of a Planar‐Chiral Lewis Acid Complex. (2006) (0)
- Enantioselective Cross-Coupling of Activated Secondary AlkylElectrophiles (2010) (0)
- Correction to "Enantioconvergent Alkylations of Amines by Alkyl Electrophiles: Copper-Catalyzed Nucleophilic Substitutions of Racemic α-Halolactams by Indoles". (2020) (0)
- Organotin Hydride Catalyzed Conjugate Reduction of α,β- Unsaturated Ketones. (1997) (0)
- Recent advances in palladium-catalyzed coupling reactions (2003) (0)
- Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones. (2015) (0)
- Mechanistic insights into photo-induced, copper-catalyzed alkylations of amines (2015) (0)
- ConvergentCatalytic Asymmetric Synthesis of Estersof Chiral Dialkyl Carbinols (2020) (0)
- Amide-Directed, Iridium-Catalyzed Hydroboration of Olefins: Documentation of Regio- and Stereochemical Control in Cyclic and Acyclic Systems. (1991) (0)
- Phosphine-Catalyzed Enantioselective Intramolecular [3 + 2] Annulations to Generate Fused Ring Systems. (2015) (0)
- Asymmetric Suzuki Cross-Coupling of Secondary Alkyl Electrophiles (2010) (0)
- Enantioselective Suzuki Coupling of Unactivated Alkyl Halides (2008) (0)
- Formal Synthesis of Fluvirucinine A1 (2008) (0)
- Figure 9, In Situ inhibition of PME-1 activity (A) and PME-1-mediated PP2A demethylation (B) by probe compound 1 (SID 99206500) and compound 3 (SID 99206503) (2011) (0)
- Cu-Catalyzed [4+1] Cycloadditions of Enones with Diazo Compounds (2007) (0)
- Bu3SnH‐Catalyzed Barton‐McCombie Deoxygenation of Alcohols. (1997) (0)
- The Chemistry of Borabenzenes (1986-2000) (2001) (0)
- Enantioselective Construction of Quaternary Stereocenters: Rearrangements of O-Acylated Azlactones Catalyzed by a Planar-Chiral Derivative of 4-(Pyrrolidino)pyridine. (1999) (0)
- Catalytic cross-coupling with copper and light (2014) (0)
- Synthesis of Aryl Alkyl Sulfides by γ-Addition ofAryl Thiols to Allenoates (2011) (0)
- Enantioselective Nucleophile‐Catalyzed Synthesis of Tertiary Alkyl Fluorides via the α‐Fluorination of Ketenes: Synthetic and Mechanistic Studies. (2015) (0)
- A New Method for Generating Sn—H Bonds: Reactions of Tin Amides with Silicon Hydrides. (1998) (0)
- Nickel-Catalyzed Cross-Coupling of α-Bromoketoneswith Arylzinc Reagents (2009) (0)
- Intramolecular β-Alkylation of Michael Acceptors (2006) (0)
- Nickel-Catalyzed Suzuki Reaction of Unactivated Alkyl Halides (2006) (0)
- A Versatile Approach to Ullmann C—N Couplings at Room Temperature: New Families of Nucleophiles and Electrophiles for Photoinduced, Copper‐Catalyzed Processes. (2014) (0)
- Non-Enzymatic Kinetic Resolution of Propargylic Alcohols by a Planar—Chiral DMAP Derivative: Crystallographic Characterization of the Acylated Catalyst. (1999) (0)
- Synthesis of Chiral Diamine Ligands for Nickel‐Catalyzed Asymmetric Cross‐Couplings of Alkylchloroboronate Esters with Alkylzincs: (1 R ,2 R )‐ N , N ′‐Dimethyl‐1,2‐Bis(2‐Methylphenyl)‐1,2‐Diaminoethane (2020) (0)
- ΑΖΑ-β-LACTAM COMPOUNDS AND METHODS OF USING (2013) (0)
- Pd/P(t‐Bu)3: A Mild and General Catalyst for Stille Reactions or Aryl Chlorides and Aryl Bromides. (2002) (0)
- Catalytic Asymmetric Cycloaddition of Ketenes and NitrosoCompounds (2009) (0)
- Substrate‐Directable Chemical Reactions (1993) (0)
- Photoinduced, copper-catalyzed coupling reaction (2015) (0)
- Bu(3)SnH-Mediated Pinacol Coupling of 1,5- and 1,6-Dicarbonyl Compounds: Synthetic and Mechanistic Studies. (1998) (0)
- Pd/P(t-Bu)(3)-Catalyzed Suzuki Cross-Couplings in the Presence of Water. (2010) (0)
- CCDC 1579916: Experimental Crystal Structure Determination (2017) (0)
- Tributyltin Cyanide Catalyzed Addition of Triethylsilyl Cyanide to Aldehydes. (1995) (0)
- Applications of Planar‐Chiral Heterocycles as Ligands in Asymmetric Catalysis (2007) (0)
- A New Benchmark for the Non-enzymatic Enantioselective Acylation of Amines: Use of a Planar-Chiral Derivative of 4-Pyrrolidinopyridine as the Acylating Agent. (2000) (0)
- Enantioselective Addition of Amines to Ketenes Catalyzed by a Planar-Chiral Derivative of PPY: Possible Intervention of Chiral Broensted-Acid Catalysis. (2003) (0)
- Phosphine-Catalyzed Enantioselective Formation of γ-Mercapto α,β-Unsaturated Esters from Activated Allenes (2010) (0)
- Synthesis, Resolution, and Crystallographic Characterization of a New C2-Symmetric Planar-Chiral Bipyridine Ligand: Application to the Catalytic Enantioselective Cyclopropanation of Olefins. (2000) (0)
- Phosphine-Mediated Synthesis of Oxygen-Containing Heterocycles (2009) (0)
- Bu3SnH‐Mediated Pinacol Coupling of 1,5‐ and 1,6‐Dicarbonyl Compounds: Synthetic and Mechanistic Studies. (1999) (0)
- The First Method for Achieving Palladium-Catalyzed Cross- Couplings of Simple Alkyl Chlorides: Suzuki Reactions Catalyzed by Pd2(dba)3/PCy3 (2002) (0)
- Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4 + 1] Annulations to Form Functionalized Cyclopentenes. (2015) (0)
- Nickel-Catalyzed Hiyama Cross-Coupling Reaction of α-Bromo Esters (2008) (0)
- 1,3‐Pentadien‐1‐yl‐5‐ylidene (trimethyl‐phosphine) boron (2002) (0)
- Catalytic Asymmetric Synthesis of Aza-β-Lactams (2008) (0)
- Enantioselective Synthesis of Cyclopentenones via Rhodium‐Catalyzed Kinetic Resolution and Desymmetrization of 4‐Alkynals. (2003) (0)
- A Novel Rhodium-Catalyzed Reduction–Oxidation Process: Reaction of 4-Alkynals with Phenol to Provide cis-4-Alkenoates Support has been provided by Mitsubishi Chemical (postdoctoral fellowship support for K.T.), Bristol-Myers Squibb, Novartis, and Pfizer. Funding for the MIT Department of Chemistry I (2002) (0)
- New Directing Groups for Metal-Catalyzed Asymmetric Carbon–Carbon Bond-Forming Processes: Stereoconvergent Alkyl–Alkyl Suzuki Cross-Couplings of Citation (2012) (0)
- A Mild, Convenient, and Inexpensive Method for Converting Imines into Amines: Tin-Catalyzed Reduction with Polymethylhydrosiloxane (PMHS). (1998) (0)
- A Surprisingly Mild and Versatile Method for Palladium‐Catalyzed Suzuki Cross‐Couplings of Aryl Chlorides in the Presence of a Triarylphosphine. (2002) (0)
- Catalytic asymmetric synthesis of alkylsilanes enabled by stereoconvergent nickel-catalyzed cross-coupling (2017) (0)
- Phosphine-Catalyzed Carbon-Sulfur Bond Formation (2010) (0)
- Enantioselective Nucleophilic Catalysis with “Planar-Chiral” Heterocycles (2000) (0)
- Nonenzymatic Kinetic Resolution of Indolines (2007) (0)
- [(1,2,3,4,5‐η)‐1,2,3,4,5‐Pentamethyl‐2,4‐cyclopentadien‐1‐yl]‐[(4a,5,6,7,7a‐η)‐4‐(1‐pyrrolidinyl)‐5H‐cyclopenta[1,2‐b]]pyridin‐5‐yl]iron (2010) (0)
- Rhodium‐Catalyzed Synthesis of Cyclohexenones via a Novel [4 + 2] Annulation. (2002) (0)
- [(1,2,3,4,5-η)-2-[(Diphenylphosphino)-methyl]-3,4-dimethyl-1H-phosphol-1-yl][(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]iron (2002) (0)
- The Kinetic Resolution of Allylic Alcohols by a Non-enzymatic Acylation Catalyst; Application to Natural Product Synthesis. (2000) (0)
- Rhodium(I)- and Iridium(I)-Catalyzed Hydroboration Reactions: Scope and Synthetic Applications. (1992) (0)
- From the Design of a Chiral Lewis Acid Catalyst to Metal‐Catalyzed Coupling Reactions (2004) (0)
- Ni-Catalyzed Coupling of Aryl Trifluorosilanes and Secondary Alkyl Halides (2007) (0)
- Award Address (Herbert C. Brown Award for Creative Research in Synthetic Methods sponsored by the Purdue Borane Research Fund and the Herbert C. Brown Award Endowment). Nucleophilic substitution reactions: A radical alternative to S_N1 and S_N2 reactions (2018) (0)
- FUNDAMENTAL STUDIES OF CARBON OXYGEN BOND ACTIVATION IN NICKEL DIPHOSPHINE ETHER COMPLEXES (2014) (0)
- Catalytic Enantioselective γ-Alkylation of CarbonylCompounds (2011) (0)
- A Versatile Method for Suzuki Cross-Coupling of Nitrogen Heterocycles (2006) (0)
- [(4a,5,6,7,7a‐η)‐4‐(Dimethylamino)‐1H‐1‐pyridin‐5‐yl][1,2,3,4,5‐η)‐1,2,3,4,5‐penta‐phenyl‐2,4‐cyclopentadien‐1‐yl]iron (2002) (0)
- Phosphine‐Catalyzed Doubly Stereoconvergent γ‐Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α‐Disubstituted α‐Amino Acid Derivatives. (2015) (0)
- Asymmetric Kumada Couplings of α-BromoKetones (2010) (0)
- Cross‐Couplings of Unactivated Secondary Alkyl Halides: Room‐Temperature Nickel‐Catalyzed Negishi Reactions of Alkyl Bromides and Iodides. (2004) (0)
- Dynamic Kinetic Resolutions Catalyzed by a Planar-Chiral Derivative of DMAP: Enantioselective Synthesis of Protected α-Amino Acids from Racemic Azlactones. (1998) (0)
- Enantioselective α-Oxygenation ofα-Diazoesters (2006) (0)
- Transition-Metal-Catalyzed Construction of Alkyl–Alkyl Bonds: Another Dimension in Cross-Coupling Chemistry (2017) (0)
- Catalytic Asymmetric Synthesis of Secondary Nitriles via Stereoconvergent Negishi Arylations and Alkenylations of Racemic α‐Bromonitriles. (2012) (0)
- Copper‐Catalyzed Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones in the Presence of Planar‐Chiral Phosphaferrocene‐Oxazoline Ligands. (2003) (0)
- Nickel/Bis(oxazoline)‐Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1‐Diarylalkanes. (2014) (0)
- Rhodium ( I )-and Iridium ( 1 )-Catalyzed Hydroboration Reactions : Scope and Synthetic Applications (0)
- Nucleophile-Catalyzed Asymmetric Acylations of Silyl Ketene Imines: Application to the Enantioselective Synthesis of Verapamil (X). (2005) (0)
- Non-Enzymatic Dynamic Kinetic Resolution of Secondary Alcohols via Enantioselective Acylation : Synthetic and Mechanistic Studies (2012) (0)
- Copper‐Catalyzed Asymmetric N—H Insertion Reactons: Couplings of Diazo Compounds with Carbamates to Generate α‐Amino Acids. (2008) (0)
- Figure 8, Comparative profiling of enantiomeric pairs: Compounds 1 vs. 2 and 3 vs. 4 (2011) (0)
- Copper-Catalyzed Enantioconvergent Alkylation of Oxygen Nucleophiles. (2023) (0)
- Figure 10, Cytotoxicity of probe and probe analogs in serum-free (A) and serum-supplemented (B) media (2011) (0)
- 5.13 Organic Chemistry II, Spring 2003 (2003) (0)
- A General, Modular Method for the Catalytic Asymmetric Synthesis of Alkylboranes (2017) (0)
- A Versatile New Method for the Synthesis of Cyclopentenones via an Unusual Rhodium-Catalyzed Intramolecular Trans Hydroacylation of an Alkyne [J. Am. Chem. Soc. 2001, 123, 11492−11493]. (2002) (0)
- Cross‐Couplings of Alkyl Electrophiles under “Ligandless” Conditions: Negishi Reactions of Organozirconium Reagents. (2004) (0)
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