Gregory S. Girolami
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American inorganic chemist
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Gregory S. Girolamichemistry Degrees
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Inorganic Chemistry
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Chemistry
Gregory S. Girolami's Degrees
- PhD Inorganic Chemistry University of California, Berkeley
- Bachelors Chemistry University of California, Berkeley
Why Is Gregory S. Girolami Influential?
(Suggest an Edit or Addition)According to Wikipedia, Gregory S. Girolami is the William H. and Janet G. Lycan Professor of Chemistry at the University of Illinois Urbana-Champaign. His research focuses on the synthesis, properties, and reactivity of new inorganic, organometallic, and solid state species. Girolami has been elected a fellow of the American Association for the Advancement of Science, the Royal Society of Chemistry, and the American Chemical Society.
Gregory S. Girolami's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Sol−Gel Synthesis of KVII[CrIII(CN)6]·2H2O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 °C (1999) (472)
- High-Temperature Molecular Magnets Based on Cyanovanadate Building Blocks: Spontaneous Magnetization at 230 K (1995) (450)
- Three-dimensional self-assembled photonic crystals with high temperature stability for thermal emission modification (2013) (198)
- New Three-Dimensional Ferrimagnetic Materials: K2Mn[Mn(CN)6], Mn3[Mn(CN)6]2.cntdot.12H2O, and CsMn[Mn(CN)6].cntdot.1/2H2O (1994) (137)
- Titanium, zirconium, and hafnium tetrahydroborates as "tailored" CVD precursors for metal diboride thin films (1988) (112)
- Surface-Initiated Ring-Opening Metathesis Polymerization on Si/SiO2 (2000) (111)
- Mechanistic Studies of Copper Thin-Film Growth from CuI and CuII β-Diketonates (1993) (104)
- Patterned polymer growth on silicon surfaces using microcontact printing and surface-initiated polymerization (1999) (99)
- Infrared studies of the surface and gas phase reactions leading to the growth of titanium nitride thin films from tetrakis(dimethylamido)titanium and ammonia (1992) (89)
- Remote-plasma chemical vapor deposition of conformal ZrB2 films at low temperature: A promising diffusion barrier for ultralarge scale integrated electronics (2002) (83)
- “Tailored” organometallics as precursors for the chemical vapor deposition of high-purity palladium and platinum thin films (1988) (79)
- A Simple "Back of the Envelope" Method for Estimating the Densities and Molecular Volumes of Liquids and Solids (1994) (78)
- Are d0 ML6 complexes always octahedral? The x-ray structure of trigonal-prismatic [Li(tmed)]2[ZrMe6] (1989) (76)
- Role of Pressure in the Growth of Hexagonal Boron Nitride Thin Films from Ammonia-Borane (2016) (76)
- Consequences of a linear two-coordinate geometry for the orbital magnetism and Jahn-Teller distortion behavior of the high spin iron(II) complex Fe[N(t-Bu)2]2. (2009) (74)
- Chemical Vapor Deposition of MoS2 and TiS2 Films From the Metal−Organic Precursors Mo(S-t-Bu)4 and Ti(S-t-Bu)4 (1997) (72)
- Magnetic Prussian Blue Analogs (2005) (72)
- Synthesis and properties of a fifteen-coordinate complex: the thorium aminodiboranate [Th(H3BNMe2BH3)4]. (2010) (71)
- Surface-selective deposition of palladium and silver films from metal-organic precursors: a novel metal-organic chemical vapor deposition redox transmetalation process (1993) (70)
- Organometallic Route to the Chemical Vapor Deposition of Titanium Carbide Films at Exceptionally Low Temperatures (1987) (69)
- A Static Agostic .alpha.-CH.cntdot..cntdot..cntdot.M Interaction Observable by NMR Spectroscopy: Synthesis of the Chromium(II) Alkyl [Cr2(CH2SiMe3)6]2- and Its Conversion to the Unusual "Windowpane" Bis(metallacycle) Complex [Cr(.kappa.2-C,C'-CH2SiMe2CH2)2]2- (1994) (69)
- Hafnium diboride thin films by chemical vapor deposition from a single source precursor (2005) (62)
- Mechanistic Studies of Palladium Thin Film Growth from Palladium(II) β-Diketonates. 1. Spectroscopic Studies of the Reactions of Bis(hexafluoroacetylacetonato)palladium(II) on Copper Surfaces (1996) (61)
- Chemical Vapor Deposition of Copper and Copper Oxide Thin Films from Copper(I) tert-Butoxide (1989) (60)
- Selective chemical vapor deposition of platinum and palladium directed by monolayers patterned using microcontact printing (1997) (58)
- Nanoenergetic materials: boron nanoparticles from the pyrolysis of decaborane and their functionalisation. (2009) (57)
- Molecular Magnets Constructed from Cyanometalate Building Blocks (1995) (56)
- HfB2 and Hf–B–N hard coatings by chemical vapor deposition (2006) (54)
- Synthesis and properties of the divalent 1,2-bis(dimethylphosphino)ethane (dmpe) complexes MCl2(dmpe)2 and MMe2(dmpe)2 (M=Ti, V, Cr, Mn, or Fe). X-ray crystal structures of MCl2(dmpe)2 (M=Ti, V, or Cr), MnBr2(dmpe)2, TiMe1.3Cl0.7(dmpe)2, and CrMe2(dmpe)2 (1985) (54)
- Mechanistic Studies of the Thermolysis of Tetraneopentyltitanium(IV). 1. Solution Evidence That Titanium Alkylidenes Activate Saturated Hydrocarbons (1997) (53)
- Synthesis and characterization of actinide mono- and bis(porphyrin) complexes (1987) (49)
- Nanosoldering carbon nanotube junctions by local chemical vapor deposition for improved device performance. (2013) (49)
- Divalent titanium chemistry. Synthesis, reactivity, and X-ray and neutron diffraction studies of Ti(BH4)2(dmpe)2 and Ti(CH3)2(dmpe)2 (1987) (48)
- Actinide bis (porphyrinate) π-radical cations and dications, including the X-ray crystal structure of [(TPP)2Th][SbCl6] (1988) (46)
- Electronic states and optical properties of porphyrins in van der Waals contact: thorium(IV) sandwich complexes (1992) (45)
- Catalytic Amplification of Patterning via Surface-Confined Ring-Opening Metathesis Polymerization on Mixed Primer Layers Formed by Contact Printing (2003) (42)
- Volatile magnesium octahydrotriborate complexes as potential CVD precursors to MgB2. Synthesis and characterization of Mg(B3H8)2 and its etherates. (2007) (41)
- Crystal structure of [CF3CFC(CF3)Ag]4 and its use as a chemical vapor deposition precursor for silver films (1993) (41)
- Synthesis of the long-sought unsubstituted aminodiboranate Na(H3B-NH2-BH3) and its N-alkyl analogs. (2010) (40)
- Observation of a new low-energy fluorescent sup 1 (. pi. ,. pi. *) excited state in strongly coupled porphyrin dimers (1990) (40)
- Synthesis and characterization of the octahydrotriborate complexes Cp*V(B3H8)2 and Cp*Cr(B3H8)2 and the unusual cobaltaborane cluster Cp*2Co2(B6H14). (2006) (39)
- CVD Growth Kinetics of HfB2 Thin Films from the Single-Source Precursor Hf(BH4)4 (2006) (39)
- Metal-alkane complexes. Rapid exchange of hydrogen atoms between hydride and methyl ligands in [(C5Me5)Os(dmpm)(CH3)H+] (1998) (38)
- BIS(PORPHYRIN)ACTINIDE COMPLEXES AND THEIR RADICAL CATIONS AND DICATIONS (1994) (38)
- Hydrido, alkyl, and ethylene 1,2-bis(dimethylphosphino)ethane complexes of manganese and the crystal structures of MnBr2(dmpe)2, [Mn(AlH4)(dmpe)2]2 and MnMe2(dmpe)2 (1983) (38)
- Additive fabrication of integrated ferroelectric thin‐film capacitors using self‐assembled organic thin‐film templates (1997) (38)
- Synthesis and structure of transition-metal bis(porphyrinato) complexes. Characterization of Zr(TPP)2 and Zr(OEP)2 (1991) (38)
- Field-directed sputter sharpening for tailored probe materials and atomic-scale lithography (2012) (37)
- Synthesis and Characterization of Coordinately Unsaturated Phosphine Complexes of Divalent V, Cr, Mn, Fe, and Co. Crystal Structures of [CrCl2(dippe)]2 and FeCl2(dippe) (1988) (36)
- A new class of CVD precursors to metal borides: Cr(B3H8)2 and related octahydrotriborate complexes. (2004) (35)
- TWO-DIMENSIONAL MELTING TRANSITIONS OF ROD-LIKE MOLECULES ANALYZED BY REFLECTION-ABSORPTION INFRARED SPECTROSCOPY (1995) (35)
- Lanthanide N,N-dimethylaminodiboranates: highly volatile precursors for the deposition of lanthanide-containing thin films. (2010) (34)
- Zirconium and Hafnium Polyhydrides. Preparation and Characterization of M2H3(BH4)5(PMe3)2, MH(BH4)3(dmpe), and MH2(BH4)2(dmpe)2 (1991) (33)
- Titanium diboride thin films by low-temperature chemical vapor deposition from the single source precursor Ti (BH4 )3 (1,2 -dimethoxyethane) (2007) (33)
- Ring-Opening Metathesis Polymerization of Norbornene by Cp*2Os2Br4 and Related Compounds (1999) (33)
- Alkyl, hydride, and dinitrogen 1,2-bis(dimethylphosphino)ethane complexes of chromium. Crystal structures of Cr(CH3)2(dmpe)2, CrH4(dmpe)2, and Cr(N2)2(dmpe)2 (1983) (32)
- Fourteen-Electron Organoiron Species: Synthesis and Characterization of High-Spin Iron (II) Alkyls and the Crystal Structure of the Benzyl Derivative Fe(CH2C6H4CH3)2(dippe) (1987) (32)
- Lanthanide N,N-dimethylaminodiboranates as a new class of highly volatile chemical vapor deposition precursors. (2012) (32)
- Synthesis and technique in inorganic chemistry : a laboratory manual (1999) (32)
- Synthesis and X-ray Crystal Structure of the New Palladium(I) Dimer [Pd2(PMe3)6][hfac]2 and Its Conversion to [PdMe(PMe3)3][hfac] via Activation of Phosphorus-Carbon Bonds (1994) (32)
- Donor–Acceptor Properties of Bidentate Phosphines. DFT Study of Nickel Carbonyls and Molecular Dihydrogen Complexes (2012) (31)
- Sequential Dehydrogenation of Unsaturated Cyclic C5 and C6 Hydrocarbons on Pt(111) (1998) (31)
- Enhanced Electrical and Mechanical Properties of Chemically Cross-Linked Carbon Nanotube-Based Fibers and Their Application in High-Performance Supercapacitors. (2019) (31)
- Structural Models and Thermal Desorption Energetics for Multilayer Assemblies of the n-Alkanes on Pt(111) (2000) (31)
- The Hexacyanotitanate Ion: Synthesis and Crystal Structure of [NEt4]3[TiIII(CN)6]·4MeCN (1997) (31)
- Thirteen-Electron Manganese(II) Tetraalkyls. Synthesis, Characterization, and X-ray Crystal Structures of [Li(tmed)]2[MnMe4] and the “β-Unstable” Species [Li(tmed)]2[MnEt4] and [Li(tmed)]2[Mn(CH2CH2-t-Bu)4] (1989) (31)
- Copper(I) alkyls. Synthesis and characterization of tertiary phosphine adducts and the crystal structure of the dimethylcuprate complex [Cu(PMe3)4][CuMe2] (1988) (31)
- Synthesis of a Novel Volatile Platinum Complex for Use in CVD and a Study of the Mechanism of Its Thermal Decomposition in Solution (1996) (31)
- Carbon−Carbon Bond Formation Promoted by Organoruthenium Complexes. The First Unsubstituted π-Metallabenzene Complex, Cp*2Ru2(η2:η5-C5H5)(SiMe3), and Synthesis of the Tetramethyleneethane Complex Cp*2Ru2(η3:η3-C6H8)Cl4 (1997) (29)
- Chromium diboride thin films by low temperature chemical vapor deposition (2005) (28)
- Mechanistic Studies of Palladium Thin Film Growth from Palladium(II) β-Diketonates. 2. Kinetic Analysis of the Transmetalation Reaction of Bis(hexafluoroacetylacetonato)palladium(II) on Copper Surfaces (1996) (28)
- Twelve-electron organochromium species: synthesis and characterization of high-spin square-planar chromium(II) alkyls and aryls (1988) (28)
- Synthesis, characterization, and x-ray crystal structures of the divalent titanium complex Ti(.eta.2-BH4)2(dmpe)2 and the unidentate tetrahydroborate complex V(.eta.1-BH4)2(dmpe)2 (1989) (28)
- A DFT and ab initio benchmarking study of metal-alkane interactions and the activation of carbon-hydrogen bonds. (2010) (27)
- Synthesis and single crystal structure of sodium octahydrotriborate, NaB3H8. (2014) (27)
- Titanium(III) tetrahydroborates. Preparation and crystal structure of Ti(BH4)3(PMe3)2 containing an unusual Ti.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.B agostic interaction (1988) (27)
- Tertiary phosphine adducts of manganese(II) dicyclopentadienide. Magnetic studies and structural characterization of tilted cyclopentadienyl rings (1984) (27)
- A reversible silicon-carbon bond cleavage process. Dynamics and reactivity of Cp*2Ru2(μ-CH2)(SiMe3)(μ-Cl) (1994) (27)
- Comparing the 2,2'-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium. (2016) (27)
- Synthesis and characterization of the homoleptic octahydrotriborate complex Cr(B3H8)2 and its Lewis base adducts. (2007) (27)
- Synthesis, characterization, and structures of uranium(III) N,N-dimethylaminodiboranates. (2010) (26)
- Growth kinetics and morphology of self-assembled monolayers formed by contact printing 7-octenyltrichlorosilane and octadecyltrichlorosilane on Si(100) wafers. (2004) (26)
- Shrinking the Synchrotron: Tabletop Extreme Ultraviolet Absorption of Transition-Metal Complexes. (2016) (26)
- Growth inhibition to enhance conformal coverage in thin film chemical vapor deposition. (2008) (26)
- Crystalline texture in hafnium diboride thin films grown by chemical vapor deposition (2006) (25)
- Coordination chemistry of 2,2'-biphenylenedithiophosphinate and diphenyldithiophosphinate with U, Np, and Pu. (2015) (25)
- Melting of Rodlike Molecules on Pt(111). Infrared Spectroscopic Studies of Isotopically Labeled n-Alkanes (1998) (25)
- Solution-mediated selective nanosoldering of carbon nanotube junctions for improved device performance. (2015) (24)
- Rare Example of a Monomeric Aryllithium Complex. X-ray Crystal Structure of (2,4,6-Triphenylphenyl)lithium-Bis(diethyl ether) (1992) (24)
- Seven-coordinate titanium and vanadium carbonyls. Synthesis and x-ray crystal structures of [Me3CSi(CH2PMe2)3]Ti(CO)4 and [Me3CSi(CH2PMe2)3]V(CO)3H (1987) (24)
- On the .pi.-donor ability of early transition metals: evidence that trialkylphosphines can engage in .pi.-back-bonding and x-ray structure of the titanium(II) phenoxide Ti(OPh)2(dmpe)2 (1990) (24)
- Mono(cyclopentadienyl)titanium(II) Complexes with Hydride, Alkyl, and Tetrahydroborate Ligands: Synthesis, Crystal Structures, and Ethylene Dimerization and Trimerization Catalysis (2008) (24)
- Metal-Organic Chemical Vapor Deposition of Copper and Copper(I) Oxide from Copper(I) Tert-Butoxide (1992) (23)
- HIGH-PRESSURE EFFECTS ON A MANGANESE HEXACYANOMANGANATE FERRIMAGNET WITH TN = 29 K (1998) (23)
- Alkyl, hydrido, and tetrahydroaluminato complexes of manganese with 1,2-bis(dimethylphosphino)ethane (dmpe). X-Ray crystal structures of Mn2(µ-C6H11)2(C6H11)2(µ-dmpe), (dmpe)2Mn(µ-H)2AlH(µ-H)2AlH(µ-H)2-Mn(dmpe)2, and Li4{MnH(C2H4)[CH2(Me)PCH2CH2PMe2]2}2·2Et2O (1985) (23)
- Synthesis, characterization, and structures of divalent europium and ytterbium N,N-dimethylaminodiboranates. (2010) (23)
- Synthesis of Hydride and Alkyl Compounds Containing the Cp*Os(NO) Fragment. Crystal Structure of [Cp*Os(μ-NO)]2 (1999) (23)
- Mechanistic Studies of CVD Metallization Processes: Reactions of Rhodium and Platinum β-Diketonate Complexes on Copper Surfaces (2000) (23)
- Synthesis and Characterization of (C5Me5)2Os2Br4 and the Osmium Polyhydride (C5Me5)OsH5: A New Synthetic Entry into Mono(pentamethylcyclopentadienyl)osmium Chemistry (1994) (23)
- Permethylmanganates. Synthesis and characterization of divalent [MnMe42-], trivalent [MnMe52-], and tetravalent [MnMe62-]. (1988) (23)
- Highly volatile magnesium complexes with the aminodiboranate anion, a new chelating borohydride. Synthesis and characterization of Mg(H(3)BNMe(2)BH(3))(2) and related compounds. (2010) (23)
- Coordination complexes of tetrakis(trifluoroacetato)dimolybdenum. A solution proton, fluorine-19, and phosphorus-31 nuclear magnetic resonance and infrared spectroscopic study (1980) (22)
- Unidentate vs bidentate acyl coordination: reactions of high-spin iron(II) alkyls with carbon monoxide and the crystal structure of the bidentate acyl Fe(η2-COC6H2Me3)Br(CO)(dippe) (1988) (22)
- Reversible carbon-silicon bond cleavage in the methylene/silyl complex Cp*2Ru2(.mu.-CH2)(.mu.-Cl)(SiMe3) (1993) (22)
- Mechanistic Studies of the Thermolysis of Tetraneopentyltitanium(IV). 2. Solid State and Ultra-High-Vacuum Studies of the Chemical Vapor Deposition of TiC Films (1997) (22)
- High-Valent Organomanganese Chemistry. 1. Synthesis and Characterization of Manganese(III) and -(IV) Alkyls (1991) (22)
- Quadruply bonded tetramethyltetrakis(trialkylphosphine)dimolybdenum compounds: phosphine exchange kinetics, acetone formation with carbon monoxide and crystal structure of Mo2Me4(PMe3)4 (1981) (22)
- Synthesis and characterisation of 1,2-bis(dimethylphosphino)ethane (dmpe) complexes of chromium-(0) and -(IV): X-ray crystal structures of trans-Cr(N2)2(dmpe)2, cis-Cr(CO)2(dmpe)2, Cr(C2Ph2)2(dmpe), and CrH4(dmpe)2 (1985) (22)
- Origin of the Terms Pnictogen and Pnictide (2009) (22)
- Highly conformal magnesium oxide thin films by low-temperature chemical vapor deposition from Mg(H3BNMe2BH3) 2 and water (2013) (21)
- Electronically Asymmetric Bis(porphyrin) Sandwich Complexes (1994) (21)
- Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III). (2010) (21)
- Titanium-catalyzed dehydrocoupling of silanes: direct conversion of primary monosilanes to titanium(0) oligosilane complexes with agostic alpha-Si-H...Ti interactions. (2007) (20)
- Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia (2014) (20)
- In situ spectroscopic ellipsometry analyses of hafnium diboride thin films deposited by single-source chemical vapor deposition (2007) (20)
- Superconformal chemical vapor deposition of thin films in deep features (2014) (20)
- Reaction of Binuclear Carboxylate Complexes of Molybdenum, Rhenium, Ruthenium, and Rhodium with tert-Butyl Isocyanide: Metal-Metal Bond Cleavage vs. Bond Retention (1981) (20)
- Ultrafast electronic deactivation and vibrational dynamics of photoexcited uranium(IV) porphyrin sandwich complexes (1993) (20)
- Growth Inhibitor To Homogenize Nucleation and Obtain Smooth HfB2 Thin Films by Chemical Vapor Deposition (2013) (20)
- Tailored Organometallics as Low-Temperature CVD Precursors to Thin Films (1988) (20)
- Structural characterization of bimetallic nanomaterials with overlapping x-ray absorption edges (2009) (20)
- Structure-reactivity correlations in the reactions of hydrocarbons on transition metal surfaces. 1. Ring contraction of cyclooctene, 1,3-cyclooctadiene, 1,5-cyclooctadiene, and cyclooctatetraene to benzene on a platinum(111) surface (1994) (19)
- Synthesis and characterization of volatile monomeric copper(II) fluoroalkoxides (1992) (19)
- Synthesis and characterization of a zinc metal–organic framework with chiral nano-pores (2012) (19)
- Zirconium and hafnium polyhydrides. 2. Preparation and characterization of M3H6(BH4)6(PMe3)4 and M2H4(BH4)4(dmpe)2 (1992) (18)
- Titanium(0) Arene Complexes: Synthesis and X‐ray Crystal Structure of [η6‐C10H8Ti{tBuSi(CH2PMe2)3}] (1988) (18)
- Tertiary phosphine adducts of manganese(II) dialkyls. Part 2. Synthesis, properties, and structures of monomeric complexes (1984) (18)
- A Zirconium Bis(porphyrinate) Sandwich Complex with an Appended Quinone (1996) (17)
- Vanadium(III) tetrahydroborates. Preparation, reaction chemistry, and crystal structures of V(BH4)3(PMe3)2 and the oxo dimer [V(BH4)2(PMe3)2]2O (1989) (17)
- Nonagostic M···H–C Interactions. Synthesis, Characterization, and DFT Study of the Titanium Amide Ti2Cl6[N(t-Bu)2]2 (2012) (16)
- Direct writing of sub-5 nm hafnium diboride metallic nanostructures. (2010) (16)
- SYNTHESIS AND REACTIVITY OF THE OSMIUM METHYLIDENE COMPLEX (C5ME5)OS(=CH2)(DPPM)OTF (1999) (16)
- Synthesis and characterization of osmium(II) trispyrazolylborate complexes. (2006) (16)
- Preparation, Catalytic Reactivity, and X-ray Crystal Structure of the First Group 4 Alkyl/Alkene Complexes. The First Structural Models of the Key Ziegler-Natta Catalytic Intermediate (1993) (16)
- Thermal Atomic Layer Etching of Copper by Sequential Steps Involving Oxidation and Exposure to Hexafluoroacetylacetone (2018) (15)
- A square-planar oxo-alkyl of manganese(III). Synthesis and X-ray crystal structure of {Li2[MnOMe3]·2Li2(Meacac)·tmed}2 (1988) (15)
- Electronic and steric effects on molecular dihydrogen activation in [CpOsH4(L)]+ (L = PPh3, AsPh3, and PCy3). (2005) (15)
- New strategies for conformal, superconformal, and ultrasmooth films by low temperature chemical vapor deposition (2020) (15)
- Ethylene Complexes of the Early Transition Metals: Crystal Structures of [HfEt4(C2H4)2−] and the Negative-Oxidation-State Species [TaHEt(C2H4)33−] and [WH(C2H4)43−] (2008) (15)
- A compound with a hafnium-hafnium bond. The first structurally characterized hafnium(III) complex: hexachlorobis(1,2-bis(diisopropylphosphino)ethane)dihafnium (1990) (15)
- Structures and Properties of Copper Alkene Complexes. Preorganization Effects and the Binding of Different Isomers of Cyclododecatriene to Copper Triflate (2009) (15)
- High-Valent Organomanganese Chemistry. 2. Synthesis and Characterization of Manganese(III) Aryls (1991) (15)
- Volatilities of Actinide and Lanthanide N,N-Dimethylaminodiboranate Chemical Vapor Deposition Precursors: A DFT Study (2012) (15)
- Synthesis and Catalytic Activity of Mono(cyclopentadienyl)titanium(II) Complexes: X-ray Crystal Structures of CpTiX(Me2PCH2CH2PMe2)2 (X = Cl, Me, H) and Cp*Ti(.eta.2-BH4)[.eta.2-(Me2PCH2)3Si(t-Bu)] (1994) (15)
- New prussian blue analogues constructed from the [Cr(CN)5NO3-] and [Cr(CN)64-] anions. A building block approach to high TN ferrimagnets (1997) (15)
- SYNTHESIS AND CHARACTERIZATION OF OSMIUM(II) COMPOUNDS OF STOICHIOMETRY (C5ME5)OSL2BR, (C5ME5)OSL2H, AND (C5ME5)OS(NO)BR2 (1996) (15)
- Bis(cyclooctatetraenyl)zirconium: X-ray Crystal Structure and Solution and Solid-State NMR Spectra (1991) (14)
- Isolation and characterization of the first .sigma.-organomanganese(III) complex. Crystal and molecular structure of (2,4,6-trimethylphenyl)dibromobis(trimethylphosphine)manganese(III) (1987) (14)
- Synthesis and Characterization of Osmium Polyhydrides. X-ray Crystal Structures of (C5Me5)OsH5 and (C5Me5)2Os2H4 (2007) (14)
- Low Temperature MoCVD Routes to Thin Films from Transition Metal Precursors (1989) (13)
- Butadiene Complexes of Titanium(II) and Titanium(0): Synthesis, Butadiene Dimerization Catalysis, and Crystal Structures of TiMe2(η4-1,4-C4H4Ph2)(dmpe) and Ti(η4-C4H6)2(dmpe) (1997) (13)
- Synthesis and characterization of the cycloheptatrienyl tantalum "mixed-sandwich" compounds (c5r5)ta(c7h7). (2008) (13)
- Ring contraction of cyclooctene, 1,3-cyclooctadiene, 1,5-cyclooctadiene, and cyclooctatetraene to benzene on platinum(111) surfaces (1993) (13)
- Vanadium tetrahydroborates: preparation and characterization of V(.eta.2-BH4)3(PMe3)2 and the unusual unidentate BH4- complex V(.eta.1-BH4)2(dmpe)2 (1988) (13)
- Chemical vapor deposition of TiO2 thin films from a new halogen-free precursor (2014) (13)
- Synthesis and crystal structures of the chromium(II) and chromium(III) hexafluoroacetylacetonate complexes trans-Cr(hfac)2(thf)2 and Cr(hfac)3 (2007) (13)
- Synthesis and crystal structures of two (cyclopentadienyl)titanium(III) hydroborate complexes, [Cp*TiCl(BH4)]2 and Cp2Ti(B3H8) (2008) (13)
- The C−H···M Interaction and Reactivity Differences of n-Octane on the (1×1) and (5×20) Surfaces of Pt(100) (1998) (12)
- Iron(0) arene and iron(II) hydride complexes from the hydrogenation or thermolysis of high-spin iron(II) alkyls (1995) (12)
- Crystal Structure of "(Li(Et2O))4(FePh4)": Corrigendum and Reformulation. A Remarkable Example of a False Solution in a Wrong Space Group (1998) (12)
- Phosphine complexes of trivalent early transition metals. X-ray crystal structure of the d1-d1 (1,2-bis(diisopropylphosphino)ethane)trichlorotitanium dimer and synthesis of the alkyl (1,2-bis(diisopropylphosphino)ethane)dichloro(methyl)(THF)chromium (1990) (12)
- X-ray crystal structure of the tetra(tert-butyl)erbate anion and attempts to prepare tetravalent organolanthanide complexes (2007) (12)
- 1,2-Bis(dimethylphosphino)ethane (dmpe) alkyl compounds of zirconium(IV) and hafnium(IV). Crystal structures of ZrMe4(dmpe)2 and Zr(CH2PH)4(dmpe) (1985) (12)
- Reactions of Primary Organosilanes on Transition Metal Surfaces. Identification of the First Surface-Bound Silylynes (1994) (12)
- Synthesis and characterization of calcium N,N-dimethylaminodiboranates as possible chemical vapor deposition precursors. (2014) (11)
- Superconformal coating and filling of deep trenches by chemical vapor deposition with forward-directed fluxes (2018) (11)
- Quadruply bonded dimolybdenum compounds of the type Mo2(O2CR)2X2(PR3)2: evidence for kinetic and structural trans effects (1982) (11)
- Synthesis and structural diversity of barium (N,N-dimethylamino)diboranates. (2012) (11)
- The first unsubstituted metallabenzene complex [Ru2(η5-C5Me5)2(η2,η5-C5H5)(SiMe3)] (1993) (11)
- Synthesis and Reactivity of the Osmium(III) Pentamethylcyclopentadienyl Complex (C5Me5)2Os2Br4. X-ray Crystal Structures of (C5Me5)2Os2Br4, (C5Me5)2Os2(μ-O)Br4, and (C5Me5)2Os2(μ-NPh)2Br2 (2007) (11)
- Transition metal tetrahydridoborates as models of methane activation: synthesis and structure of Ti(BH4)3(PMe3)2 (1986) (11)
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- Structure-reactivity correlations in the reactions of hydrocarbons on transition metal surfaces. 2. Hydrogenation of norbornene and bicyclo[2.2.2]octene on platinum(111) (1995) (10)
- Iron CVD from iron pentacarbonyl: Growth inhibition by CO dissociation and use of ammonia to restore constant growth (2016) (10)
- Synthesis of hydride and alkyl compounds containing the Cp*Os({eta}{sup 3}-allyl) fragment. Crystal structures of Cp*Os({eta}{sup 3}-C{sub 8}H{sub 13})Br{sub 2} and [Cp*Os({eta}{sup 3}-C{sub 4}H{sub 7})Me(H{sub 2}O)][BF{sub 4}] (1999) (10)
- Surface-selective chemical vapor deposition of copper films through the use of a molecular inhibitor (2015) (10)
- Seamless fill of deep trenches by chemical vapor deposition: Use of a molecular growth inhibitor to eliminate pinch-off (2019) (10)
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- Metal-to-Metal Silyl Migration and Silicon−Carbon Bond Cleavage/Re-formation Processes in the Methylene/Silyl Complexes Cp*2Ru2(μ-CH2)(SiR3)(μ-Cl) (1999) (10)
- Synthesis and characterization of zirconium pentafluorophenyl complexes: X-ray crystal structures of [ZrCl2(C6F5)42-] and [ZrF2(C6F5)53-] (1999) (10)
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- Synthesis and Reactivity of New Ruthenium Alkyls and Hydrides. Protonation of Cp*Ru(Me2PCH2PMe2)Me and X-ray Crystal Structure of Cp*2Ru2(μ-Ph2PCH2PPh2)(AlH5) (1997) (9)
- Structures and Reactivities of Cycloheptane, Cycloheptene, 1,3-Cycloheptadiene, and Cycloheptatriene on Pt(111) (1999) (9)
- Chemical Vapor Deposition of Copper: Use of a Molecular Inhibitor to Afford Uniform Nanoislands or Smooth Films (2014) (9)
- Synthesis and characterization of new titanium(II) carbonyls of stoichiometry TiX2(CO)2(dmpe)2: an NMR study (1994) (9)
- Chemical vapor deposition of zinc from diallyl zinc precursors (1994) (9)
- Removal of Tin from Extreme Ultraviolet Collector Optics by In-Situ Hydrogen Plasma Etching (2017) (9)
- η5-Cyclopentadienyl and η5-methylcyclopentadienyl 1,2-bis(dimethylphosphino)ethane complexes of titanium(II). The crystal structure of Ti(C5H4Me)2(dmpe) (1984) (9)
- Synthesis and Characterization of [(C5Me5)2OsH]2[Os2Br8]. The Eclipsed Rotamer of the Triply-Bonded Os2Br82‒ Anion (1995) (9)
- Crystal structure of the axial (orange-yellow) isomer of bis(methyldiphenylphosphine)tetrakis(trifluoroacetato)dimolybdenum (1982) (9)
- Additive fabrication and the mechanisms of nucleation and growth in chemical vapor deposition processes. (2000) (9)
- Area selective CVD of metallic films from molybdenum, iron, and ruthenium carbonyl precursors: Use of ammonia to inhibit nucleation on oxide surfaces (2018) (9)
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- Bio-Inspired Iron and Nickel Complexes: Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates (2010) (8)
- Alkyl and hydrido derivatives of tetrakis(trimethylphosphine)osmium(II). X-ray crystal structure of the metallacycle Os[(CH2)2SIMe2](PMe3)4 (1984) (8)
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- Synthesis and Reactivity of Dinuclear Platinum Complexes. NMR Spectra of [Pt2(PMe3)6][hfac]2 and an Unusual β-Diketonate Bridging Mode in [Pt2(μ-hfac)(PMe3)4][hfac] (1997) (8)
- The first tris(n-butyl) transition metal complex. Synthesis and structures of the fifteen electron chromium(III) alkyls [ButSi(CH2PMe2)3]CrMe3 and [ButSi(CH2PMe2)3]CrBun3 (1987) (8)
- Nonbornadiene on Pt(111) is not bound as an n2: n2 diene: characterization of an unexpected n2:n1 bonding mode involving an agostic Pt···H--C interaction (1995) (8)
- Titanium(II) and titanium(III) tetrahydroborates. Crystal structures of [Li(Et2O)2][Ti2(BH4)5(PMe2Ph)4], Ti(BH4)3(PMe2Ph)2, and Ti(BH4)3(PEt3)2. (2006) (8)
- The energy landscape of glassy dynamics on the amorphous hafnium diboride surface. (2014) (7)
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- Synthesis and characterization of phosphine adducts of thorium borohydride, Th(BH4)4: Crystal structures of Th(BH4)4(PEt3)2 and Th(BH4)4(Me2PCH2CH2PMe2)2 (2010) (7)
- Synthesis, x-ray crystal structure, and phosphine-exchange reactions of the hafnium(III)-hafnium(III) dimer Hf2Cl6(PEt3)4 (1993) (6)
- John C. Bailar, Jr. (1904–1991): father of coordination chemistry in the United States (1993) (6)
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- Amorphous Titanium Carbide Films Produced by Low‐Temperature Organometallic CVD (1987) (6)
- Nanosoldering carbon nanotube junctions with metal via local chemical vapor deposition for improved device performance (2012) (6)
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- Crystal structure of the uranium oxo borohydride complex U2(μ-O)(BH4)6(dme)2 (dme = 1,2-dimethoxyethane) and reformulation of U2(μ-H)2(BH4)6(dme)2 (2012) (6)
- Salt elimination reactions do not always eliminate. Mechanistic study of the reaction of NdCl3 with sodium N,N-dimethylaminodiboranate (2019) (6)
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- Nanocomposite of a chromium Prussian blue with TiO2. Redox reactions and the synthesis of Prussian blue molecule-based magnets (2007) (5)
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- An unusual norbornadiene coupling product: synthesis, characterization, and structure of the ruthenocene (C5Me5)Ru(η5-C5H4C9H11) (1999) (5)
- Preparation OF (t-BuNC)5 MoX2 (X = O2 CCF3, Cl) and (t-BuNC)5 ReCl by cleavage of the quadruple bond in Mo2 (O2 CCF3 )4, K4 MO2 C18, and Re2 (O2CMe)4, Cl2 (1979) (4)
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- New Three-Dimensional Ferrimagnetic Materials: K2Mn[Mn(CN)6], Mn3[Mn(CN)6]2.cntdot.12H2O, and CsMn[Mn(CN)6.cntdot. 1/2H2O. [Erratum to document cited in CA121:270418] (1995) (4)
- Platinum ω-Alkenyl Compounds as Chemical Vapor Deposition Precursors: Synthesis and Characterization of Pt[CH2CMe2CH2CH═CH2]2 and the Impact of Ligand Design on the Deposition Process (2020) (4)
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- Chemical vapor deposition of MnxNy films from bis(2,2,6,6-tetramethylpiperidido)manganese(II) and ammonia (2016) (3)
- X-ray Crystallography (2015) (3)
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- From Alchemy to Chemistry: Five Hundred Years of Rare and Interesting Books (2000) (2)
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- Synthesis and Reactivity of the Osmium ( III ) Pentamethylcyclopentadienyl Complex ( C 5 Me 5 ) 2 Os 2 Br 4 . X-ray Crystal Structures of ( C 5 Me 5 ) 2 Os 2 Br (0)
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- Structure of the Benzyl Derivative Fe(CH,C6H,CH,),(dippe) (1987) (0)
- Synthesis and Characterization of Coordinately Unsaturated Phosphine Complexes of Divalent V, Cr, Mn, Fe, and Co. Crystal Structures of (CrCl2(dippe))2 and FeCl2(dippe). (1988) (0)
- Actinoid Bis(porphyrinate) π-Radical Cations and Dications, Including the X-Ray Crystal Structure of ((TPP)2Th) (SbCl6). (1988) (0)
- Permethyl Manganates. Synthesis and Characterization of Divalent (MnMe2‐ 4), Trivalent (MnMe2‐ 5), and Tetravalent (MnMe2‐ 6). (1988) (0)
- Using metal precursors to passivate oxides for area selective deposition (2023) (0)
- Iron ( o ) Arene and Iron ( ii ) Hydride Complexes from the Hydrogenation or Thermolysis of High-spin Iron ( ii ) Alkyls t (2003) (0)
- Crystal structure of tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)hafnium(IV) (2018) (0)
- Cumulative Formula Index: Volumes 31-36 (2014) (0)
- Cumulative Contributor Index: Volumes 31-36 (2014) (0)
- Phosphine Complexes of Trivalent Early Transition Metals. X-Ray Crystal Structure of the d1-d1 Dimer (TiCl3(dippe))2 and Synthesis of the Alkyl CrMeCl2(dippe)(THF). (1990) (0)
- Calorimetric measurements of phase transformations in thin films of amorphous Te alloys used for optical data storage (2014) (0)
- Steric and Electronic Analyses of Ligand Effects on the Stability of σ-Methane Coordination Complexes: A DFT Study (2022) (0)
- Mono(η5‐Pentamethylcyclopentadienyl) Complexes of Osmium (2014) (0)
- Are do ML 6 Complexes Always Octahedral ? The X-ray Structure of Trigonal-Prismatic [ Li ( tmed ) 12 [ ZrMe 6 ] (0)
- Erratum: New three-dimensional ferrimagnetic materials: K2Mn-[Mn(CN)6], Mn3[Mn(CN)6]2·12H2O, and CsMnMn(CN)6· 1/2H2O (Inorganic Chemistry (1994) 33, (5165-5166)) (1995) (0)
- Chemical Vapor Deposition of MoS2 and TiS2 Films from the Metal‐ Organic Precursors Mo(S‐tBu)4 and Ti(S‐tBu)4. (1997) (0)
- X-Ray Crystal Structure of the Metallacycle Os [ ( CH 2 ) 2 SiMe 2 ] ( PMe & t (2003) (0)
- Carbon-Carbon Bond Formation Promoted by Organoruthenium Complexes. The First Unsubstituted π-Metallabenzene Complex, Cp*2Ru2(η:η-C5H5)(SiMe3), and Synthesis of the Tetramethyleneethane Complex Cp*2Ru2(η:η-C6H8)Cl4 (1997) (0)
- ALKYL AND HYDRIDO DERIVATIVES OF TETRAKIS(TRIMETHYLPHOSPHINE)OSMIUM(II). X-RAY CRYSTAL STRUCTURE OF THE METALLACYCL (2,2-DIMETHYL-2-SILAPROPANE-1,3-DIYL)TETRAKIS(TRIMETHYLPHOSPHINE)OSMIUM(II) (1984) (0)
- Editors’ Introduction (2021) (0)
- Synthesis and crystal structures of two ( cyclopentadienyl ) titanium ( III ) hydroborate complexes , [ Cp * TiCl ( BH 4 ) ] 2 and Cp 2 Ti ( B 3 H 8 ) (2008) (0)
- SYNTHESIS AND PROPERTIES OF THE DIVALENT 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE (DMPE) COMPLEXES MCL2(DMPE)2 AND MME2(DMPE)2 (M = TITANIUM, VANADIUM, CHROMIUM, MANGANESE OR IRON). X-RAY CRYSTAL STRUCTURES OF MCL2(DMPE)2 (M = TI, V, OR CR), (1985) (0)
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