Henk Buck
#41,949
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Dutch chemist
Henk Buck's AcademicInfluence.com Rankings
Henk Buckchemistry Degrees
Chemistry
#811
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#1343
Historical Rank
Organic Chemistry
#167
World Rank
#214
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Chemistry
Henk Buck's Degrees
- Bachelors Chemistry University of Amsterdam
- Masters Chemistry University of Amsterdam
- PhD Chemistry Delft University of Technology
Why Is Henk Buck Influential?
(Suggest an Edit or Addition)According to Wikipedia, Henk Buck is an organic chemist. He studied at the University of Leiden where he received his PhD in 1959. He got a lectorship at the university in Theoretical Organic Chemistry in 1964. For his research he received the Golden Medal of the Royal Netherlands Chemical Society in 1967. In 1970 he was appointed as professor of Physical Organic Chemistry and Organic Chemistry at the University of Technology in Eindhoven. Because there was no chair for Theoretical Chemistry and Biochemistry he gave lectures in organic chemistry, physical organic chemistry, theoretical organic chemistry, biochemistry and biotechnology. From 1988 to 1991 he was Dean of the Chemical Faculty. For his scientific contributions he became a member of the Royal Netherlands Academy of Arts and Sciences in 1979. During his scientific career he published more than 300 scientific papers spread over a large area of the chemical field. Under his supervision 43 chemical engineers obtained their PhD. The end of his career came prematurely because of a publication in Science in 1990 that had to be retracted because of flawed research.
Henk Buck's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Phosphate-methylated DNA aimed at HIV-1 RNA loops and integrated DNA inhibits viral infectivity. (1990) (45)
- Regiospecific inhibition of DNA duplication by antisense phosphate-methylated oligodeoxynucleotides. (1989) (34)
- The different influences of ether and ester phospholipids on the conformation of gramicidin A. A molecular modelling study. (1989) (29)
- B-Z transition in methylated DNA. A quantum-chemical study. (1983) (22)
- PHOTOIONIZATION OF AROMATIC MOLECULES DISSOLVED IN BORIC ACID GLASS (1963) (20)
- The mechanisms of action of cAMP. A quantum chemical study. (1982) (20)
- Inhibition of HIV-1 infectivity by phosphate-methylated DNA: retraction. (1990) (20)
- The mechanism of the thermal [1,5]-H shift in cis-1,3-pentadiene. Kinetic isotope effect and vibrationally assisted tunneling (1986) (17)
- Peptide-induced parallel DNA duplexes for oligopyrimidines. Stereospecificity in complexation for oligo(L-lysine) and oligo(L-ornithine). (1990) (15)
- The pentamethylbenzyl-carbonium ion as a strong electrophilic agent in proton acids. Reactions with hydrogen, alkanes and aromatic hydrocarbons (1964) (15)
- Asymmetric induction in the synthesis of thiophene-containing steroidlike molecules via olefinic cyclization. Precoiling as model description for the stereochemical course of the reaction. (1977) (15)
- THE HYDRIDE-DONATION REACTION OF REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE. 2. INDO/3 AND STO-3G CALCULATIONS ON THE ROLE OF THE CARBAMOYL GROUP IN ENZYMIC IC REACTIONS (1982) (14)
- Why do all lariat RNA introns have adenosine as the branch-point nucleotide? Conformational study of naturally-occurring branched trinucleotides and its eleven analogues by 1H-, 31P-NMR and CD spectroscopy. (1989) (14)
- A combined experimental, theoretical, and Van't Hoff model study for identity methyl, proton, hydrogen atom, and hydride exchange reactions. Correlation with three-center four-, three-, and two-electron systems (2008) (13)
- The system Lewis acid - nitro compound as a strong electron acceptor (1960) (12)
- NAD+ and NAD+ analogues in horse liver alcohol dehydrogenase. Relationship between reactivity and conformation simulated with molecular mechanics. (1990) (12)
- An ab initio SCF/CI study on the role of C2v transition states in thermal and photochemical sigmatropic shifts (1986) (12)
- Conformational transmission in the glyceryl backbone of phospholipid model compounds, induced by a P(4-coordinated) into trigonal bipyramidal P(5-coord) transition. (1986) (12)
- A single-crystal ESR study on radicals derived from rac- and meso-1,2-dimethyl-1,2-diphenyldiphosphine disulfide: stereochemical selection in radical formation. (1988) (11)
- Paramagnetism in molecular compounds (1958) (11)
- Molecular mechanics studies of parallel and antiparallel phosphate‐methylated DNA (1987) (10)
- A linear three‐center four electron bonding identity nucleophilic substitution at carbon, boron, and phosphorus. A theoretical study in combination with van't Hoff modeling (2009) (10)
- Mechanistic models for the intramolecular hydroxycarbene–formaldehyde conversion and their intermolecular interactions: Theory and chemistry of radicals, mono‐, and dications of hydroxycarbene and related configurations (2012) (10)
- The Chemical and Biochemical Properties of Methylphosphotriester DNA (2004) (10)
- A model investigation of ab initio geometries for identity and nonidentity substitution with three-center four- and three-electron transition states (2011) (9)
- Dna Systems for B-Z Transition and Their Significance as Epigenetic Model: The Fundamental Role of the Methyl Group (2011) (9)
- Symmetry restrictions as starting point for the determination of geometric representations and the dynamics of cyclic ? systems (2000) (9)
- Molecular mechanics calculation of geometries of NAD+ derivatives, modified in the nicotinamide group, in a ternary complex with horse liver alcohol dehydrogenase. (1988) (9)
- Elementary addition–substitution reactions. Hückel approach for the description of aromatic and antiaromatic arylmethyl cations (2001) (8)
- A stable antiparallel cytosine–thymine base pair occurring only at the end of a duplex (1991) (8)
- A conformational B-Z DNA study monitored with phosphatemethylated DNA as a model for epigenetic dynamics focused on 5-(hydroxy)methylcytosine (2013) (8)
- Odd-memberedC2? ?-cyclic mono- and dications with internal cross-linking. A Hckel approach for the description of antiaromaticity (2000) (7)
- Charge at the migrating hydrogen in the transition state of hydride transfer reactions from CH groups to hydride acceptors. Dynamics of the redox-couple NADH-NAD (2005) (7)
- The Chemical and Biochemical Properties of Methylphosphotriester DNA and RNA in Comparison with Their Corresponding Methylphosphonates. A Dynamic Model Description (2007) (6)
- An Adjusted Model for Simple 1,2-Dyotropic Reactions. Ab Initio MO and VB Considerations (2013) (6)
- Nicotinamide Adenine Dinucleotide a Unique Compound for Theoretical and Synthetic Model Studies: Chirality as Source for High Stereospecificity (2003) (6)
- A NEW STRATEGY FOR DNA INHIBITION WITH BACKBONE SUBSTITUTED DNA ANALOGUES (1999) (6)
- On the oxidation mechanism of aromatic proton complexes (1965) (5)
- Protonation as a driving force for pentacoordination of phosphorus (1979) (5)
- Steric effects in proton and hydride transfer processes in strongly acidic solvents (1968) (5)
- New information about acid catalysis in friedel-crafts type reactions (1964) (5)
- Calculated geometries of dications of bis odd‐membered π‐ring systems containing a NCN fragment and related π‐systems. An opposite out‐of‐plane rotation of the 4n π‐ring subsystems (2002) (5)
- ESR of positive radical ions of triphenylphosphonium methylides: (Short communication) (2010) (4)
- Trigonal pyramidal carbon geometry as model for electrophilic addition–substitution and elimination reactions and its significance in enzymatic processes (2007) (4)
- Conformational transmission in condensed lipid model compounds. Chain packing modification by head-group-induced conformational changes in the glyceryl backbone. (1989) (4)
- CNDO/2 and INDO calculations of a reaction pathway for the sigmatropic [1, 5] H-shift in cyclopentadiene (1973) (4)
- Substituent effects in 13C NMR spectra of 6-endo substituted 9-thiabicyclo[3.3.1]non-2-enes (1980) (4)
- Quantum chemical study of alternating N/B and N/C π bonds in (un)charged even‐membered 4n and 4n+2 cyclic systems and their related open systems (2005) (4)
- The Biochemical Significance of Parallel DNA Duplexes (2003) (4)
- Protein complexation with DNA phosphates as a cause for DNA duplex destabilization: A thermodynamic model (1989) (3)
- A non-Woodward and Hoffmann reaction path for photochemical sigmatropic rearrangements (1985) (3)
- Modified RNA with a Phosphate-Methylated Backbone. A Serious Omission in Our (Retracted) Study at HIV-1 RNA Loops and Integrated DNA. Specific Properties of the (Modified) RNA and DNA Dimers (2016) (3)
- Calculated geometries and charge distributions of 4n and 4n + 2 π‐ring systems linked with −CH 2+: An asymmetric versus symmetric π‐delocalization (2002) (3)
- Retracted HIV Study Provides New Information about the Status of the in Vitro Inhibition of DNA Replication by Backbone Methylation (2015) (3)
- ANTIAROMATIC INTERACTION IN THE 9‐METHOXYBICYCLO(4.2.1)NONA‐2,4,7‐TRIEN‐9‐YL CATION. EVIDENCE OF ORBITAL SYMMETRY CONTROL OVER 4Π‐ELECTRON INTERACTIONS (1978) (3)
- Different models for phosphate anion shielding in DNA duplexes: An elaboration with ab initio and molecular mechanics calculations (2005) (3)
- Critical evaluation of the bond order concept with application to thermal hydrogen shifts (2004) (3)
- INDO calculations on the sigmatropic [1, 5] H-Shift in 1,3-cyclohexadiene and 1,3,5-cycloheptatriene A homo-cyclopentadienyl transition state model (1975) (3)
- Formation of trimethylcarbonium ion by hydride abstraction from isobutane with pentamethylbenzyl cation (2010) (3)
- Thermodynamics of polymolecular duplexes between phosphate‐methylated DNA and natural DNA (1990) (3)
- Three-Center Configuration with Four,Three, and Two Electrons for Carbon,Boron, Hydrogen, and Halogen Exchange. A Model and Theoretical Study with Experimental Evidence (2014) (3)
- Application of the conformational transmission effect for the assignment of diastereotopic proton resonances (1987) (3)
- Modeling of NAD+ Analogues in Horse Liver Alcohol Dehydrogenase a (1990) (2)
- The Risk of the Preparation of Artificial DNAs via an Interrupted Automated Solid-Phase Triester Method (2015) (2)
- A model description for the initiation of conformational changes in DNA via the P(IV) residues. Part I (2010) (2)
- Mechanism for the conversion of right-handed DNA helices into the left-handed isomers. Part II (2010) (2)
- Aromaticity in Four-Membered Rings (2001) (2)
- An experimental study on the mechanism and stereochemistry of a photochemical [1,3]-oh shift. A non-woodward and hoffmann reaction path for photochemic (1988) (2)
- Solvent Dependence of the Rotamer Population Around the Interglycosidic C(5)-C(6) Bond of (1→ 6)-β-Linked Digalactopyranosides (1987) (1)
- A NEW MECHANISTIC MODEL FOR HYDRIDE TRANSFER RELATED TO THE REDOX COUPLE NADH/NAD+. CRITICISM ON THE QUANTUM-CHEMICAL MO APPROACH (2010) (1)
- THE ROLE OF THE CARBOXAMIDE GROUP IN NICOTINAMIDE ADENINE DINUCLEOTIDE IN RELATION TO HYDRIDE TRANSFER: THE REDUCED FORM OF THE DINUCLEOTIDE AS REMEDY IN THE MODULATION OF NEUROTRANSMISSION (2005) (1)
- Interconversion between Planar-Triangle, Trigonal-Pyramid and Tetrahedral Configurations of Boron (B(OH)3 -B(OH)4- ), Carbon (CH3+ -CH3X) and for the Group 15 Elements as Nitrogen (NH3-NH4+ ). A Modelling Description with Ab Initio Results and Pressure-Induced Experimental Evidence (2015) (1)
- Mechanism of the Thermal [1,5]-H Shift in cis-1,3-Pentadiene. Kinetic Isotope Effect and Vibrationally Assisted Tunneling. (1986) (1)
- A Molecular Description of Superconductivity of Sulfur Hydride and Related Systems under High-Pressure Conditions (2017) (1)
- A QUANTUM-CHEMICAL MODEL DESCRIPTION FOR THE FUNCTION OF CYCLIC AMP. ITS DEGRADATION AND ACTIVATION OF PROTEIN KINASE (1981) (1)
- A QUANTUMCHEMICAL STUDY OF THE C6H5+ POTENTIAL ENERGY SURFACE. EVIDENCE FOR A NONCLASSICAL PYRAMIDAL CARBENIC SPECIES (1977) (0)
- X‐RAY STRUCTURE DETERMINATION OF THE PHOSPHITE TRIESTER OF METHYL β‐D‐RIBOPYRANOSIDE; CNDO‐2 CALCULATION (1980) (0)
- PREPARATION OF A 6α‐SUBSTITUTED OPTICALLY PURE STEROID WITH THIOPHENE AS THE A RING VIA ASYMMETRIC INDUCTION. A CIRCULAR DICHROISM STUDY (1981) (0)
- PHOSPHATE SHIELDING UNDER DIFFERENT CONDITIONS RESULTS IN AN ENHANCED DNA DUPLEX STABILITY (2005) (0)
- A new mechanistic approach for carbon inversion in nucleophilic displacement reactions. II (1993) (0)
- CATIONIC DERIVATIVES OF BICYCLO(4.2.1)NONA-2,4,7-TRIENE AS MODEL SYSTEMS FOR GROUND-STATE MOEBIUS AROMATICITY (1983) (0)
- PENTA CO-ORDINATED ORGANO-PHOSPHORUS COMPOUNDS AS MODEL SUBSTANCES FOR SIMULATION OF BIOCHEMICAL CONVERSIONS PART 1, A MODEL DESCRIPTION FOR THE SPEZIFIC INTERACTION T-RNA SYNTHETASE-AMINO ACID, A SELECTION PROCEDURE (1974) (0)
- ESR and geometries of alkylphosphine selenide radical anions (1993) (0)
- The SPCl 2 F-radical : an ESR and ab initio quantum chemical study (2001) (0)
- HYDRIDE-DONATION REACTION OF REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE. 1. MINDO/3 AND STO-3G CALCULATIONS ON ANALOG REACTIONS WITH CYCLOPROPENE, TROPYLIDENE, AND 1,4-DIHYDROPYRIDINE AS HYDRIDE DONORS AND THE CYCLOPROPENIUM CATION AS (1982) (0)
- An ab initio SCF/CI Study on the Role of C2v Transition States in Thermal and Photochemical Sigmatropic Shifts ( (1986) (0)
- Configuration-Dependent Conformational Transmission in Trigonal-Bipyramidal P(V) Compounds. Enhanced Gauche (-) Population Around the C(5)-C(6) Linkage in 6-P(V) Phosphorylated Tetramethyl-α-D-galactopyranoside. (1986) (0)
- One-Electron-Addition to Pentavalent Phosphorus with the Phosphorus-Chlorine Bond as Acceptor Introducing a Fundamental Distinction in Substitution Mechanism between SN2(P) and SN2(C) (2019) (0)
- Corrections to SPINCIP (QCPE 376) (1985) (0)
- The nature of three-electron phosphorus-sulfur bonds studied by ESR (2001) (0)
- A 31P and 1H NMR Study of the Conformations of a Series of Diastereomeric 3-Substituted trans-2,4-Dioxa-3-oxo- and trans-2,4-Dioxa-3-thioxo- 3-phosphabicyclo(4.3.0)nonanes as Model Compounds for Cyclic Nucleotides. (1988) (0)
- DNA-Like Duplex Structures Derived from Chemistry Based on 2’-Deoxy-Cytidine: A New Model for Base-Specific Inhibition of G and C on DNA and RNA Level (2018) (0)
- STEREOSPECIFIC REACTIONS OF THE BICYCLO(5.4.1)DODECAPENTAENYL CATION (1985) (0)
- Silver ion assisted ring expansions of some geminal dibromobicyclo [ n . 1 . 0 ] alkanes . Evidence for free cationic intermediates (2001) (0)
- Interconversion between Planar-Triangle , Trigonal-Pyramid and Tetrahedral Configurations of Boron ( ) ( ) ( )-3 4 B OH B OH (2015) (0)
- O-ALKYLATION OF CARBOXYLIC ACIDS AND PHENOLS WITH OXAPHOSPHOLENES (1974) (0)
- Influence of Phosphorus Derivatization on the Conformational Behavior of Model Compounds for 3′,5′-xylo-cAMP Studied by 1H-NMR Spectroscopy. (1988) (0)
- Radical anion formation from pentavalent organo-phosphorus compounds by X-irradiation of single crystals. A critical evaluation (1993) (0)
- Structure of C 3 v phosphoranyl and C 4 v phosphorane anion radicals . A quantum chemical study (2001) (0)
- SYNTHESIS OF 1,5-CYCLODIENES. BIS(1,5-CYCLOOCTADIENE)NICKEL AS AN ALTERNATIVE FOR TETRACARBONYLNICKEL IN INTRAMOLECULAR COUPLING REACTIONS (1978) (0)
- ESR POSITIVER RADIKALIONEN VON TRIPHENYLPHOSPHONIUM-METHYLIDEN (1971) (0)
- THE REACTION OF TERVALENT PHOSPHINES WITH THE 7-NORBORNADIENYL CATION (1974) (0)
- Hydrogen atom transfer from alkanes and aromatic proton complexes to aromatic cations and quinones (2010) (0)
- THE SWI,F- PHOSPHORS RADICAL. AN ESR AND AB INITIO QUA~U~ CHEMICAL STUDY (1986) (0)
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