Hideki Sakurai
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Chemistry
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(Suggest an Edit or Addition)Hideki Sakurai's Published Works
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Published Works
- Chemistry of organosilicon compounds (1976) (308)
- Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to .alpha.,.beta.-enones. A New method of stereoselective introduction of the angular allyl group in fused cyclic .alpha.,.beta.-enones (1977) (257)
- Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride☆ (1976) (253)
- Reactions of allylsilanes and application to organic synthesis (1982) (190)
- Novel anionic polymerization of masked disilenes to polysilylene high polymers and block copolymers (1989) (131)
- ALLYLSILANES AS SYNTHETIC INTERMEDIATES. II. SYNTHESES OF HOMOALLYL ETHERS FROM ALLYLSILANES AND ACETALS PROMOTED BY TITANIUM TETRACHLORIDE (1976) (125)
- The missing hexasilaprismane : synthesis, X-ray analysis, and photochemical reactions (1993) (101)
- Chemistry of organosilicon compounds. 293. Preparation, characterization, and crystal structures of octasilacubanes and octagermacubanes (1992) (100)
- Chemistry of organosilicon compounds. 287. Synthesis and x-ray structure of the first dicoordinate dialkylstannylene that is monomeric in the solid state (1991) (99)
- Spectra and some reactions of organopolysilanes (1980) (98)
- Chemistry of organosilicon compounds. 79. Novel [.sigma. + .pi.]reactions of hexaorganodisilanes with acetylenes catalyzed by palladium complexes (1975) (88)
- Chemistry of organosilicon compounds 113 chemoselective allylation of carbonyl compounds with allylsilanes promoted by tetra-n-butylammonium fluoride. A new synthesis of homoallyl alcohols (1978) (87)
- Preparation of Nanometer-Sized Hollow Particles by Photochemical Degradation of Polysilane Shell Cross-Linked Micelles and Reversible Encapsulation of Guest Molecules1 (2000) (84)
- Highly stereoselective C-allylation of glycopyranosides with allylsilanes catalyzed by silyl triflate or iodosilane (1984) (79)
- Preparation of some polysilicon halides by aluminum halide catalyzed interchange of methyl and halogen on silicon (1970) (77)
- Regiospecific allylation of acetals with allylsilanes catalyzed by iodotrimethylsilane. Synthesis of homoallylethers (1981) (77)
- Stable Tetrakis(trialkylsilyl)disilenes; Synthesis, X‐Ray Structures, and UV/VIS Spectra (1994) (73)
- Antiallergic activities of rabdosiin and its related compounds: chemical and biochemical evaluations. (1998) (73)
- Chemistry of organosilicon compounds. 240. Pentacoordinate allylsilicates: characterization and highly stereoselective reaction with aldehydes (1988) (73)
- Chemistry of organosilicon compounds. 98. Photochemical generation of silacyclopropene (1977) (72)
- Chemistry of organosilicon compounds. 292. An NMR study of the formation of silyloxonium ions by using tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as counteranion (1992) (70)
- Aluminium chloride-catalyzed reactions of organosilicon compounds II. Facile syntheses of alkylchlorosilanes, -germanes, and -stannanes☆ (1966) (68)
- The Ultraviolet Spectra of Some Polysilanes (1964) (65)
- Cyclotrigermenes: A New Unsaturated Ring System (1995) (64)
- Regiospecific and highly stereoselective allylation of aldehydes with allyltrifluorosilane activated by fluoride ions. (1987) (64)
- Dual fluorescence of aryldisilanes and related compounds: evidence for the formation of 1(.sigma..pi.*) orthogonal intramolecular charge-transfer states (1990) (63)
- [(Me3Si)2CHGe]6, the First Hexagermaprismane (1989) (63)
- Silole-Incorporated Polysilanes1a (1998) (62)
- Chemistry of organosilicon compounds. 106. .alpha.-Siloxyallylsilanes as homoenolate anion equivalents. A novel synthesis of .gamma.-keto aldehydes (1978) (62)
- Intermolecular donation of a .sigma.-electron from group IVb catenates to tetracyanoethylene. Evidence of electron paramagnetic resonance and charge-transfer spectra (1973) (62)
- Silyl radicals. II. Stereochemical course of the reaction of an optically active hydrosilane with carbon tetrachloride by a free-radical mechanism. Retention of configuration (1969) (57)
- Stereohomogeneous synthesis of (E)- and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes (1989) (56)
- 2-Alkoxycarbonylallyltrimethylsilanes as new reagents of 2-alkoxycarbonylallylation of electrophiles (1980) (52)
- Chemistry of organosilicon compounds. 263. Synthesis, properties, and molecular structure of highly distorted hexakis(trimethylsilyl)benzene (1990) (52)
- Highly ordered high-molecular weight alternating polysilylene copolymer prepared by anionic polymerization of masked disilene (1990) (52)
- Stereoselective synthesis of 3-(d-glycopyranosyl)propenes by use of allylsilanes (1987) (51)
- Chemistry of organosilicon compounds—165 : 2-Trimethylsilyl-methyl-1, 3-Butadiene—A versatile building block for terpene synthesis (1983) (50)
- SYNTHESIS AND STRUCTURE OF A STABLE CYCLIC DIALKYLGERMYLENE (1999) (49)
- Tetrakis(trialkylsilyl)digermenes. Salient Effects of Trialkylsilyl Substituents on Planarity around the GeGe Bond and Remarkable Thermochromism (1996) (49)
- Chemistry of organosilicon compounds. 300. .sigma..pi.* Orthogonal intramolecular charge-transfer (OICT) excited states and photoreaction mechanism of trifluoromethyl-substituted phenyldisilanes (1993) (47)
- An NMR study of the formation of silyloxonium ions by using tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as counteranion (1992) (46)
- Reduction of carbonyl compounds with pentacoordinate hydridosilicates (1987) (46)
- Chemistry of organosilicon compounds : LXXX. Useful modifications in the preparation of trimethylsilylsodium and trimethylsilylpotassium (1975) (43)
- The first nonconjugated mononuclear benzene dianion. Isolation and characterization of bis[(tetrahydrofuran)lithium(I)] hexakis(trimethylsilyl)benzenide (1991) (43)
- Chemistry of organosilicon compounds. 260. Allylation of .alpha.-hydroxy ketones with allyltrifluorosilanes and allyltrialkoxysilanes in the presence of triethylamine. Stereochemical regulation involving chelated bicyclic transition states (1989) (42)
- Bis[(dimethoxyethane)lithium(I)] 1,2,4,5-tetrakis(trimethylsilyl)benzenide. The first 6C-8.pi. antiaromatic benzene dianion (1991) (41)
- Isolation and characterization of 1,2-dilithio[tetrakis(trimethylsilyl)]ethane. The first crystal structure of nonconjugated 1,2-dilithioethane (1989) (41)
- Evidence for a strong .sigma.,.pi. interaction in 3,4,7,8-tetrasilacycloocta-1,5-diyne and 3,4,7,8,11,12-hexasilacyclododeca-1,5,9-triyne (1985) (41)
- Latent acetonylation of α,β -enones with allyltrimethylsilane or 2-methyl-2-propenyltrimethylsilane: synthesis of 1,5-diketones and annelation to fused cyclohexenones (1980) (41)
- A Novel Oxidation Reaction of Organodisilanes with Perbenzoic Acid (1965) (40)
- Chemistry of organosilicon compounds. 109. trans- and cis-1,2-Dimethyl-1,2-diphenyldisilene. Is Silicon:silicon a true double bond? (1979) (40)
- Chemistry of organosilicon compounds. 297. Lithium pentakis(dimethylsilyl)cyclopentadienide and formation of isolable coordination complexes with ketones: [(R2C:O)Li.{C5(SiMe2H)5}] (1993) (39)
- N-(TRIMETHYLSILYLMETHYL)AMINOMETHYL ETHERS AS AZOMETHINE YLIDE SYNTHONS. A NEW AND CONVENIENT ACCESS TO PYRROLIDINE DERIVATIVES (1984) (39)
- Highly stereoselective allylation of aldehydes with pentacoordinate allylsilicates in hydroxylic media. Discrimination between linear and .alpha.-branched alkanals (1990) (38)
- Siloxycarbenium Tetrakis[3,5-bis(trifluoromethyl)phenyl]borates and Their Role in Reactions of Ketones with Nucleophiles (1992) (38)
- Facile preparation of 2,3-benzo-1,4-diphenyl-7-silanorbornadiene derivatives and the first clear evidence of silylene-to-disilene thermal rearrangement (1982) (38)
- Silyl anions. IV. New convenient method of producing radical anions involving one-electron transfer from trimethylsilylsodium (1973) (38)
- Encapsulation of polysilane into shell cross-linked micelles (1999) (37)
- Chemistry of Organosilicon Compounds. 314. Preparation of (Pentamethyldisilanyl)lithium and Two Isomers of (Heptamethyltrisilanyl)lithium. Structural Characterization of (CH3)5Si2Li (1995) (37)
- Polar and Solvent Effects on Homolytic Abstraction of Benzylic Hydrogen of Substituted Toluenes by t-Butoxy Radical (1967) (37)
- Cage and Cluster Compounds of Silicon, Germanium, and Tin (1995) (37)
- Chemistry of organosilicon compounds. 167. 3,4,7,8-Tetrasilacycloocta-1,5-diyne, 3,6,7-trisilacyclohepta-1,4-diyne and related compounds. New class of cyclic compounds composed of polysilanes and acetylenes (1983) (37)
- 3‐Bromo‐3‐methyl‐2‐trimethylsiloxy‐1‐butene—A New Cycloaddition Reagent (1979) (37)
- Addition of trichloromethyl radicals to alkenylsilanes (1969) (36)
- Electronic spectra of 1,1,2,3-tetramethyl-3,4-benzo-1,2-disilacyclo-3-pentene and related compounds. stereoelectronic verification of .sigma.-.pi. conjugation between silicon-silicon .sigma. bonds and benzenoid .pi. systems (1972) (36)
- Chemistry of organosilicon compounds: CC. Allyl coupling reactions of allylsilanes and allylstannanes with allylic halides, ethers and acetates promoted by a Lewis acid (1985) (36)
- Crystal structure of tetrakis(trimethylsilyl)ethylene at -70.degree.C (1982) (36)
- Chemistry of organosilicon compounds: CCXVI. Sterically crowded silanes (1986) (35)
- Pentadienylsilanes as new reagents of the siteselective dienylmethylation of electrophiles promoted by a Lewis acid (1980) (35)
- New method of preparing silyl substituted carbanions by base catalyzed cleavage of carbon silicon bonds. Application to syntheses of olefins (1973) (34)
- The chemistry of organosilicon compounds. 302. Regio- and stereochemistry and kinetics in the addition reactions of alcohols to phenyl-substituted disilenes (1993) (34)
- Metal Nanoparticles Derived from Polysilane Shell Cross-linked Micelle Templates (2003) (33)
- Photochemistry of dibenzo-1,1,2,2-tetramethyl-1,2-disilacyclohexa-3,5-diene and the germanium analogue. Exclusive extrusion of the divalent species (1983) (33)
- Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents (1998) (33)
- SELECTIVE ALLYLATIONS OF α,β-UNSATURATED ACETALS WITH ALLYLSILANES IN THE PRESENCE OF LEWIS ACID (1978) (33)
- Trimethylsilylsodium. A new preparation and some reactions involving a facile electron transfer from trimethylsilyl anion to naphthalene (1971) (32)
- Photochemistry of 1,2-disila-3,5-cyclohexadienes (1974) (32)
- Chemistry of organosilicon compounds: CLXXXVIII. Reaction of organodisilanes with dienes catalyzed by transition metal complexes. Preparation of 1,8-bis(trimethylsilyl)octa-2,6-diene and its use in the synthesis of dl-muscone (1984) (32)
- Stepwise conversion of oxiranes to allylic alcohols by iodotrimethylsilane and DBU (1980) (32)
- Chemistry of organosilicon compounds. 108. Efficient trapping of silylenes through disilene intermediates (1979) (31)
- Aluminum chloride-catalyzed reactions of organosilicon compounds Part III. Synthesis of some polychloro-substituted methylpolysilanes (1967) (31)
- A novel aminomethylation of silyl enol ethers with aminomethyl ethers catalyzed by iodotrimethylsilane or trimethylsilyl trifluoromethanesulfonate (1982) (30)
- Stereochemistry and mechanism for the addition of alcohols to a cyclic silene (1991) (30)
- Chemistry of organosilicon compounds 118. Novel ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls (1979) (30)
- Silyl radicals. VIII. Directive effects and relative reactivities of the pentamethyldisilyl radical in homolytic aromatic silyation (1971) (30)
- Selective carbon-carbon bond formation based on organosilicon reagents: origin and application (1985) (30)
- Stereoselective Cross-Aldol Reactions of Silyl Enol Ethers with Acetals Catalyzed by Iodotrimethylsilane (1983) (29)
- Radical ions : XXVIII. Tris(trimethylsilylmethyl)aminium, N(CH2Si(CH3)3)3: A stable fluxional aminium radical cation☆ (1979) (29)
- The First Silatriafulvene Derivative: Generation, Unusually Low Reactivity toward Alcohols, and Isomerization to Silacyclobutadiene (1997) (29)
- Preparation and reactions of 1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl dianion (1988) (29)
- Electron spin resonance studies on tris(3,5-di-tert-butylphenyl)silyl and germyl radicals (1980) (29)
- Organogermanium compounds VI. Electron spin resonance spectra of aryl-substituted germyl radicals. (1977) (29)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 191. ACETALIZATION OF CARBONYL COMPOUNDS WITH ALKOXYSILANES CATALYZED BY IODOTRIMETHYLSILANE. ONE-POT ALLYLATION REACTIONS OF CARBONYL COMPOUNDS TO HOMOALLYL ETHERS USING AN ALLYLSILANE (1984) (29)
- Chemistry of organosilicon compounds XCVI. The SiSi/SiSi Metathesis reaction catalyzed by palladium complexes☆ (1977) (29)
- Chemistry of organosilicon compounds. 255. Preparation and x-ray crystal structure of the first pentacoordinate silylsilicates (1989) (28)
- [Me(PhMe2Si)2SiLi] and [Ph(Me3Si)2SiLi]: Preparation, Characterization, and Evidence for an Intramolecular LiPh Interaction† (1997) (28)
- The Pyrolysis of Organodisilanes (1966) (28)
- 2-dimethylaminomethyl-3-trimethylsilylmethyl-1,3-butadiene as 2,2′-biallyl diradical synthon. A new and facile entry to 1,2-dimethylenecyclohexanes, and [6.6] and (6.7] ring systems☆ (1986) (27)
- Highly regioselective diels-alder reactions of 2-trimethylsilylmethyl- 1,3-butadiene catalyzed by a lewis acid and applications to syntheses of terpenes☆ (1982) (27)
- Chemistry of organosilicon compounds. 131. Substituent effects by deuterium and alkyl groups and carbon-13 hyperfine coupling constants of cyclopentadienyl radicals as studied by electron spin resonance (1980) (27)
- PROTECTION OF ALCOHOLS AND ACIDS WITH ALLYLSILANES CATALYZED BY IODINE OR IODOTRIMETHYLSILANE IN CHLORINATED HYDROCARBON (1981) (27)
- Synthesis, structures, and magnetic properties of novel Roddlesden–Popper homologous series Srn+1ConO3n+1 (n=1,2,3,4, and ∞) (2005) (27)
- Molecular and crystal structure of 1,1-bis(tert-butyldimethylsilyl)-2,2-bis(trimethylsilyl)ethylene, the most twisted known olefin, and unusual rearrangement during its preparation (1982) (26)
- Hexakis(fluorodimethylsilyl)benzene, Hexakis(methoxydimethylsilyl)benzene, and Related Compounds. Novel Neutral Pentacoordinate Structures for Silicon and Merry-Go-Round Degenerate Fluorine Migration (1994) (26)
- Novel 1,2-Dilithiodisilanes Derived from Reduction of Stable Tetrakis(trialkylsilyl)disilenes with Lithium Metal (2001) (26)
- Highly regioselective diels-alder reactions of 2-trimethylsilylmethyl- and 2-trimethylstannylmethyl-1,3-butadiene (1980) (26)
- A new mode of a transition metal catalyzed intramolecular dimerization of alkynes. The first synthesis of a methylenecyclopropene complex (1987) (26)
- Self-Assembled Micelles of Amphiphilic Polysilane Block Copolymers1 (1999) (25)
- Organogermanium compounds : II. Reduction of organic halides with hydrogermanes (1972) (25)
- Lithium and Sodium Complexes of a Tetrasilylethylene Dianion (1995) (25)
- Tetrakis(trimethylsilyl)ethylene and related compounds, crowded olefins☆ (1980) (25)
- Allylation reactions by using allylstannanes in the presence of a Lewis acid. (1979) (25)
- Chloromethyl trimethylsilylmethyl sulphide as a parent thiocarbonyl ylide synthon. A simple synthesis of dihydro- and tetrahydro-thiophenes (1986) (25)
- Chemistry of organosilicon compounds. 93. New photochemical reactions of vinyldisilanes through silaethene or silacyclopropane intermediates (1976) (25)
- Chemistry of organosilicon compounds. 178. Electron spin resonance and chemical studies on the 6-(trimethylsilyl)cyclohexadienyl and related radicals (1983) (25)
- Rhodium-Catalyzed Insertion of Carbenoids into beta C-H Bonds of Silacycloalkanes: A Facile and General Approach to Functionalized Silacycloalkanes. (1998) (25)
- Charge-transfer spectra and peracid oxidation of 1,2-disilacycloalkanes. Rate-charge-transfer relation in the electrophilic reaction at .sigma.-bonds (1974) (25)
- Photochemistry of acyloxymethyl(benzyl)silanes. Evidence for the primary formation of a benzyl-silyl radical pair and mechanism of free-radical 1,2-(carbon .fwdarw. silicon)-acyloxy migration (1985) (25)
- The reaction of π-cyclopentadienyldicarbonylcobalt with silyl-substituted acetylenes (1972) (24)
- Relative Reactivities in the Addition of Free Trichloromethyl Radicals to Substituted Styrenes. An Attempt to Separate Polar and Resonance Effects (1971) (24)
- Remarkably high regioselective deprotonation and alkylation of unsymmetrical imines at the more substituted .alpha.-carbon atom (1982) (24)
- Synthesis and oxidation of 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disila-3,4-cyclohexadiene (1973) (24)
- High-pressure synthesis, structure and novel photochemical reactions of 7,7,8,8-tetramethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene (1991) (24)
- A New Oxygen-Insertion Reaction into Silicon-Silicon Bonds with Tertiary Amine Oxides (1971) (24)
- Chemistry of organosilicon compounds. 193. Intramolecular cyclotrimerization of macrocylic and acyclic triynes with Group 6 metal carbonyls. The formation of fulvene and benzene (1984) (23)
- Regiospecific cycloaddition reactions using functionalized isoprenylsilane and related compounds (1985) (23)
- Chemistry of organosilicon compounds : XC. The reaction of the trimethylchlorosilanelithium-aliphatic ketone mixture in 1,3-dimethyl-2-imidazolidinone (1976) (23)
- Generation and Trapping of Bis(dialkylamino)silylenes : Experimental Evidence for Bridged Structure of Diaminosilylene Dimers (1997) (23)
- Discovery of a potent, metabolically stabilized resorcylic lactone as an anti-inflammatory lead. (2009) (22)
- Chemistry of organosilicon compounds. 100. Substituent effects on the electron spin resonance spectra of cyclopentadienyl radicals. Removal of degeneracy by organosilyl groups (1977) (22)
- Charge-transfer spectra of some phenyl and naphthyl derivatives. Relative importance of .sigma.-.pi. and n-.pi. conjugation involving the .pi. silicon-silicon system (1974) (22)
- Chemistry of organosilicon compounds. 181. Silylene-to-disilene and disilene-to-silylene rearrangements (1983) (22)
- Preparation, reactions and stereochemistry at silicon of (2,3,4,5-tetraphenyl-1-silacyclopentadiene)iron tricarbonyls (1976) (22)
- Acetalization of carbonyl compounds with alkoxysilanes catalyzed by iodotrimethylsilane: one-potλ2 allylation reactions of carbonyl compounds to homoallyl ethers using an allylsilane (1984) (22)
- New conformationally stable 4-tert-butyl-1-silacyclohexanes and stereochemistry of insertion of dimethylsilylenes into the silicon-hydrogen bond (1972) (22)
- 4,8-Dichloroocta-t-butyltetracyclo[3.3.0.02,7.03,6]octagermane (1989) (22)
- Unusually Rapid cis‐trans Isomerization of a Tetrasilylated Ethylene: Generation of Free Radicals During the Rotation (1980) (21)
- Optically active polymers. I. Polymerization of 4‐methyl‐7‐isopropyl‐2‐oxohexamethyleneimine (1961) (21)
- CHLORINATIVE CLEAVAGE OF PERMETHYLPOLYSILANES INITIATED BY PHOTO-INDUCED ELECTRON TRANSFER (1985) (21)
- A Statistical Model for the Cooperative Thermochromic Transition of Polysilanes1 (1999) (21)
- Chemistry of organosilicon compounds : CXXIX. Evidence for formation of free silyl radicals in the photolysis of aryldisilanes (1980) (21)
- Chemistry of organosilicon compounds. 148. 3-Chloro-2-(trimethylsiloxy)-1-propene as an electrophilic acetonyl equivalent. Novel regioselective synthesis of 1,4-dicarbonyl compounds (1981) (20)
- Charge-transfer spectra of some p-substituted phenylpentamethyldisilanes. Substituent effects on the relative intensities of two charge-transfer bands (1975) (20)
- 1,1,2,2-Tetrakis(dimethylsilyl)-1,2-ethanediylithium-bis(diethyl ether):Observation of a SiHLi Agostic Interaction† (1997) (20)
- FACILE PREPARATION OF γ-CHLORO-SUBSTITUTED ALLYLMETALLIC REAGENTS AND THEIR REACTIONS. STEREOSELECTIVE ACCESS TO CIS-VINYLOXIRANES (1987) (20)
- Syntheses and photochemistry of 1,2,3-trisilacycloheptane derivatives. Precursors for tailor-made organosilylenes (1971) (20)
- Chemistry of organosilicon compounds. 185. ESR study of twisting of trimethylsilyl-substituted alkene cation radicals (1983) (20)
- Oxidative cleavage of silicon-carbon bond with trimethylamine-N-oxide. New access to primary alcohols and aldehydes from terminal alkenes and alkynes (1986) (20)
- Organogermanium compounds. V. Electron spin resonance study of alkyl- and aryl-substituted germyl radicals (1975) (20)
- A Convenient Synthesis of Iodotrimethylsilane and its Use in the Preparation of Silylketenes (1979) (20)
- Mass spectroscopy of organosilicon compounds: Fragmentation patterns of linear organopolysilanes (1973) (20)
- Structure of (tropolonato)4M-Type Compounds (M = Si, Ge, Sn) (1998) (20)
- Preparation of (π-Cyclopetadienyl)[π-Tetrakis(Trimethylsilyl)Cyclobutadiene]Cobalt (1974) (19)
- Planar Hexasilylbenzene Dianion with Thermally Accessible Triplet State (1998) (19)
- An NMR Study of the Formation of N-Silylacetonitrilium Ions by Using Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate as Counteranion (1993) (19)
- Pentamethyldisilanyl-substituted phenol and acetophenone (1969) (19)
- Synthesis of α,α-dimethylallylsilanes, a reagent of regiospecific prenylation of acetals and carbonyl compounds☆ (1978) (19)
- Chemistry of organosilicon compounds. 95. .eta.3-1-Silapropenyltricarbonyliron complexes. The first stable compound of doubly bonded silicon (1976) (19)
- Dehydrogenative silylation of ketones with hydrosilanes. A clean and convenient method of preparing silyl eniol ethers (1977) (19)
- Reactions of allylsilanes with quinones. Synthesis of allyl-substituted hydroquinones☆ (1977) (18)
- Alkylation and arylation of 2-trimethylsiloxyallyl halides. A new regiospecific route to silyl enol ethers (1980) (18)
- Octamethyltetrasila[2.2]paracyclophane. Cyclophanes Bridged by Polysilanes (1986) (18)
- Organic electroluminescence of silole-incorporated polysilane (2000) (18)
- Preparation and structure of silacycloheptatriene (1991) (18)
- The Reaction of Disilylacetylenes with Cyclopentadienyl Manganese. Formation of Vinylidene Complexes by 1,2-Silyl Shift (1992) (18)
- Chemistry of organosilicon compounds. 277. Conformational analysis of phenylpentamethyldisilane and related compounds as studied by free-jet laser spectroscopy (1991) (18)
- REGIOSELECTIVE CYCLOADDITION REACTIONS OF ALLYLSILANES AND SILYL ENOL ETHERS WITH NITRONES AND NITRILE OXIDES. SYNTHESIS OF HOMOALLYLAMINES (1985) (18)
- Diastereoselective reaction of crotylsilanes with acetals. Importance of the electronic effect in acyclic stereoselection. (1986) (18)
- Two-Dimensional Piezochromism and Orientational Modulations in Polysilane Monolayer (1997) (18)
- Organogermanium compounds : III. Reduction of substituted benzyl chlorides with triethylgermane☆ (1972) (17)
- Chemistry of organosilicon compounds. 171. Isoprenylation of carbonyl compounds with 2-[(trimethylsilyl)methyl]-1,3-butadiene initiated by a catalytic amount of tetra-n-butylammonium fluoride. The most convenient route to ipsenol and ipsdienol (1983) (17)
- A convenient and novel synthesis of 1,1-dichloroalkenes using α-lithiated dichloromethyltrimethylsilane and aldehydes☆ (1983) (17)
- Photochemical generation of tetramethyldisilene and photoinduced 1,2-silyl-migration☆ (1981) (17)
- PREPARATION AND REACTIONS OF DODECAMETHYL-3,4,7,8,11,12-HEXASILACYCLODODECA-1,5,9-TRIYNE (1984) (17)
- Conformationally Stable 1-Substituted 1-Methyl-4-t-butyl-1-silacyclohexanes, a New Organosilicon System Suitable for Stereochemical Studies (1976) (17)
- Dianion Dialkali Metals of 2,2′,5,5′-Tetrasilabicyclopentylidene. Synthesis and Crystal Structures (1995) (17)
- Carbon-silicon bond cleavage of organotrialkoxysilanes and organosilatranes with m-chloroperbenzoic acid and N-bromosuccinimide. New route to phenols, primary alcohols and bromides. (1981) (16)
- A novel synthesis of 3-alkyl-substituted isoprenylsilanes (1987) (16)
- New synthesis of a stable dialkylstannylene and its reversible complexation with tetrahydrofuran (2001) (16)
- Polysilane–Silica Hybrid Nanoparticles (2005) (16)
- Silyl radicals. IX. Cleavage of silicon-silicon and germanium-germanium bonds with 1,2-dibromoethane by a free-radical mechanism. Evidence for bimolecular homolytic substitution at silicon and germanium (1972) (16)
- Novel π-electron systems derived from silicon-containing macrocyclic polyacetylenes (1996) (16)
- Stereoselective Anionic Polymerization of Amino-Substituted Masked Disilenes (2005) (16)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS CXVI. FLUORIDE ION-PROMOTED ISOMERIZATION OF METHYL-SUBSTITUTED ALLYLSILANES. REGIOSELECTIVE SYNTHESES OF ALLYLSILANES (1978) (16)
- Lithiosilanes with Si–Si Bonds: Synthesis and 6Li, 7Li, and 29Si NMR Studies (1998) (16)
- Silyl radicals. VII. Novel intramolecular aryl migrations from carbon to silicon by a free-radical mechanism. Migration vs. cyclization (1970) (16)
- Hexakis(trialkylsilyl)cyclotrisilanes and photochemical generation of bis(trialkylsilyl)silylenes (2002) (16)
- Photochemical reaction of dibenzotetramethyldisilacyclohexadiene through charge-transfer complex. (1984) (15)
- Substituent effects on methyl proton chemical shifts in substituted phenyltrimethylsilanes and tert-butylbenzenes (1968) (15)
- Alkoxide initiation of anionic polymerization of masked disilenes to polysilanes (2000) (15)
- 3‐Brom‐3‐methyl‐2‐(trimethylsiloxy)‐1‐buten – ein neues Cycloadditionsreagens (1979) (15)
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- Temperature dependent electron spin resonance spectra of cyclohexadienyl and silyl-substituted cyclohexadienyl radicals. The conformation of the radicals (1977) (15)
- Sigma/pi interactions in [2.2]paracyclophanes. PE investigations on octamethyltetrasila[2.2]paracyclophane and octamethyltetrasila[2.2](2,5)thiophenophane and -furanophane (1988) (15)
- Highly Twisted Ethylene Dianion Dilithium Stabilized by Phenyl and Silyl Groups. (1995) (15)
- α-Carboxylation reaction of carbonyl compounds with bromomagnesium ureide-carbon dioxide adducts (1980) (15)
- NEW [2.2]ORTHOCYCLOPHANES AND [2.2]METACYCLOPHANE HAVING SILICON- SILICON BONDS AS BRIDGING UNITS (1982) (15)
- Vinyl-substituted Polysilanes (1966) (14)
- A novel and convenient regio-controlled synthesis of α-halogen-substituted allylsilanes: stereoselective synthesis of Z-alkenyl halides (1984) (14)
- Synthesis of Disilacycloalkenes by Ruthenium Alkylidene Catalyzed Ring-Closing Metathesis (RCM) Reaction of α,ω-Bis(allyldimethylsilyl)-Substituted Compounds (1999) (14)
- Peresters. VIII. Di-tert-butyl Monoperoxyoxalate (1962) (14)
- EVIDENCE FOR A STRONG Σ,Π INTERACTION IN 3,4,7,8-TETRASILACYCLOOCTA-1,5-DIYNE AND 3,4,7,8,11,12-HEXASILACYCLODODECA-1,5,9-TRIYNE (1985) (14)
- The Substituent Effect on the Ultraviolet Spectrum of 1,2-Diphenyltetramethyldisilane (1965) (14)
- Photochemically induced [2 + 2] cycloaddition of a silacyclopentadiene with carbon disulfide (1992) (14)
- Photochemistry of dibenzo-1,1,2,2,3,3-hexamethyl-1,2,3-trisilacyclohepta-4,6-diene and the germanium analog. Generation of tetramethyldisilene by free-radical disproportionation and the first spectroscopic detection of dimethylgermylene. (1984) (14)
- Cage Compounds of Si and Ge: Synthesis and Structures (1994) (14)
- Chemistry of organosilicon compounds : CXXIII. New photochemical and thermal degradation reactions of vinyldisilanes to vinylsilanes through (η3-1-silapropenyl)tricarbonyliron complexes (1980) (14)
- STEREOCHEMISTRY OF THERMAL [2+2] CYCLOADDITION OF DISILENE WITH ACETYLENE (1985) (13)
- PHOTOCHEMISTRY OF DI(9-ANTHRYL)DIMETHYLSILANE AND -GERMANE (1985) (13)
- Metamorphosis of Synthetic Strategies with Allylic Silanes: Tetracoordinated Allylic Silanes into Pentacoordinated Allylic Silicates (1989) (13)
- The first matrix-isolation and electronic structure of vinyl-substituted silylenes (1992) (13)
- Photochemical isomerization of 1-sila-2,4-cyclohexadienes (1974) (13)
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- Chemistry of organosilicon compounds. 261. Photochemical 1,3-silyl migration in allylsilanes occurring with inversion of silyl configuration (1989) (13)
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- Anionic polymerization of masked disilenes. Regioselective synthesis of monomers, structures of polymers and mechanism of initiation for polysilylenes of the type (R1R2SiSiMe2)n (1994) (13)
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- SYNTHESIS AND REACTIONS OF NEUTRAL HYPERCOORDINATE ALLYLSILICON COMPOUNDS HAVING A TROPOLONATO LIGAND (1996) (13)
- Functional transformation of poly(dialkylaminotrimethyldisilene) prepared by anionic polymerization of the masked disilenes. The preparation of a true polysilastyrene (2003) (13)
- Oxidative SIC bond cleavage of organotrifluorosilanes involving organic-group migration from hypercoordinate silicon to oxygen☆ (1989) (13)
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- Chemistry of Polysilanes and Development of New Preparations (1989) (12)
- 1-Methyl-1-boracyclohepta-2,4,6-triene, the First C-Unsubstituted Borepin (1987) (12)
- Silyl Radicals. XV. Stereochemical Course of Chlorine Abstraction by 1-Methyl-4-t-butyl-1-silacyclohexyl Radicals from Polychloroalkane (1977) (12)
- 2-Dimethylaminomethyl-3-trimethylsilylmethylbuta-1,3-diene as a synthetic equivalent of 2,2′-biallyl zwitterionic species (1987) (12)
- Synthesis of Cyclotetragermanes of the Type of [R(Ph)Ge]4 and Conversion to [R(Cl)Ge]4. The First Functionalized Cyclotetragermanes (1992) (12)
- Trialkyltin cation in solution (1994) (12)
- Chemistry of organosilicon compounds : LXXXVIII. Mass spectroscopy of organosilicon compounds. Part 2. Methoxymethyldisilanes☆ (1976) (11)
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- Chemistry of Organosilicon Compounds. Part 223. Silicon in Organic Synthesis (1986) (11)
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- Chemistry of organosilicon compounds. 92. An electron spin resonance study on the spiro cyclohexadienyl radicals (1976) (11)
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- Crystal Structures of Unsolvated Lithiosilanes with Si–Si Bonds (1999) (10)
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- Chemistry of organosilicon compounds. 262. ESR study of 2-substituted 2-adamantyl radicals. Configuration and long-range hyperfine interaction (1989) (10)
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- Chemistry of organosilicon compounds: CIV. Syntheses of novel organoelement heterocycles containing titanium and silicon (1977) (8)
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- Preparation and Some Reactions of Dibenzo-7-silanorbornadiene Derivatives (1986) (8)
- Extraordinary Large Red Shift of the n(Si)→3p(Si) Transition of Silylenes Caused by Trimethylsilyl and Trimethylgermyl Substituents (1993) (8)
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- REACTIONS OF α-HETEROATOM-SUBSTITUTED ETHERS AND SULFIDES WITH SILYL ENOL ETHERS. CHEMOSELECTIVITY IN THE CLEAVAGE OF HETEROATOM–CARBON BONDS BY IODOTRIMETHYLSILANE AND TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE (1983) (7)
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- 1,1,2,2,9,9,10,10-Octamethyl-1,2,9,10- tetragerma[2.2]paracyclophane: the first [2.2]paracyclophane bridged by two GeGe bonds (1990) (6)
- Stereoselective Allylation of β-Hydroxy- and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems (1995) (6)
- Synthesis of Polysilanes by New Procedures: Part 1 Ring-Opening Polymerisations and the Polymerisation of Masked Disilenes (2000) (6)
- Anionic Ring Opening Polymerization of Octamethyltetrasilacyclopentane (1997) (6)
- Thermolysis of pentamethyldisilane and 1H-heptamethyltrisilane (1969) (6)
- Mass Spectral Fragmentations of Polysilanylalkanols. The Analogies between Mass Spectrometry and Photo-Induced Electron Transfer (1991) (6)
- Phosphorescence from the delocalized triplet state of polysilylenes (1993) (6)
- Tris(t-butyldimethylsilyl)trimethylsilylethylene and Tetrakis(dimethylsilyl)ethylene. The Most Twisted and Untwisted Tetrasilylethylenes (1988) (5)
- Novel Syntheses of Bis(trialkylsilyl)amines by Reductive Trialkylsilylation of Azo Compounds (1987) (5)
- Photochemistry of organosilicon compounds I. Photodimerization of 1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene (1971) (5)
- Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds (2002) (5)
- The vapour-phase thermolysis of allyltrimethylsilane to vinyltrimethylsilane: a novel methylene-transfer reaction (1970) (5)
- Preparation, Structure, and Photochemistry of 2-Disilanyl-1,4-benzoquinones (2002) (5)
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- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 167. 3,4,7,8‐TETRASILACYCLOOCTA‐1,5‐DIYNE, 3,6,7‐TRISILACYCLOHEPTA‐1,4‐DIYNE AND RELATED COMPOUNDS. NEW CLASS OF CYCLIC COMPOUNDS COMPOSED OF POLYSILANES AND ACETYLENES (1983) (5)
- Molecular and crystal structures of cis- and trans-(π-cyclopentadienyl)[π-bis(trimethylsilyl)diphenylcyclobutadiene] cobalt (1972) (5)
- THE AZULENE RADICAL ANION PRODUCED BY ONE-ELECTRON TRANSFER FROM TRIMETHYLSILYLSODIUM (1973) (5)
- Chemistry of organosilicon compounds : LXXXV. An electron spin resonance study on photo-induced radicals of (p-nitrobenzyl)trimethylsilane and related nitrobenzene derivatives (1976) (5)
- Photochemistry of aryldisilanes and disilanylquinones: novel photochemical process from intramolecular charge-transfer states (1992) (5)
- Thermal SiSi/SiSi redistribution of hexaorganodisilane. A new thermally 'forbidden' molecular reaction (1972) (5)
- A convenient and efficient metallation of methylsilane. Carbonyl methylenations using metallated (2-aminoalkoxy)trimethylsilane (1987) (5)
- Persilylated Dimethylenecyclobutene Dianion Dilithium as the First 6C-8π Allyl Anion System (1996) (5)
- Network Polysilanes with Amino Groups: Synthesis from By-Products in the Industrially Operated Direct Synthesis of Chloromethylsilanes and their Photophysical Properties (2007) (5)
- Syntheses of Dialkali Metal Complexes of Tetrakis(dimethylsilyl)ethylene: [(HMe2Si)2C=C(SiMe2H)2]2−[M+(ligand)n]2. Evidence for SiH–Alkali Metal Agostic Interactions (1999) (5)
- Organogermanium compounds : IV. Novel phenyl migrations from carbon to germanium and from germanium to carbon (1974) (5)
- Charge-transfer energies of benzylic compounds with tetracyanoethylene. Convenient method to estimate the .sigma.* values (1970) (5)
- Consecutive disilanylsilylene to silyldisilene rearrangements (2006) (5)
- Silyl radicals V : Novel cyclization reactions involving homolytic aromatic silylation (1969) (5)
- Abstraction of Methyl Hydrogen of Organosilicon Compounds by t -Butoxy Radicals (1971) (5)
- Addition of Free Me2Ge: to Alkenes and Alkynes on Glass Surfaces in the Presence of Water (1989) (5)
- 1,5-DIBROMO- 3-tert-BUTYLPENTANE (1973) (5)
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- Silyl radicals IV : Homolytic aromatic silylations with hydrosilanes (1969) (5)
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- A LINEAR RELATIONSHIP BETWEEN 13CNMR CHEMICAL SHIFT OF VINYL CARBONS AND ELECTRONIC ABSORPTION WAVELENGTH IN POLYSILYLETHYLENES (1982) (4)
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- REACTIONS OF SILYLENES WITH 1,4-DIPHENYL-1,3-BUTADIENE AND 1-METHYL-1,2,3,4,5-PENTAPHENYLSILOLE. A NOVEL SILYLENE-SILYLENE EXCHANGE REACTION (1983) (4)
- Hydroxyindole derivatives as inhibitors of IL-1 generation. I. Synthesis and pharmacological activities of (E)-3-(4-hydroxy-5-methoxyindole-7-yl)-2-methylpropenoic acid derivatives (1995) (4)
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- Synthesis, Structure, and Photochemistry of Tetrakis(trimethylsilyl)-p-benzoquinone (2000) (4)
- Intramolecular Dimerization of Silylenes Leading to Novel Cyclic Disilenes. (2002) (4)
- Structure of 1,2-Dilithio[tetrakis(trimethylsilyl)]ethane in Solution. Observation of Lithium–Bridged Structures and Unexpected Anionic Rearrangement (1993) (4)
- Novel Photochemical Reactions of Dibenzodisilacyclohexadiene with Ketones (1987) (4)
- Dynamics of Polysilane Chain in Dilute Solution as Studied by Spin Labeling (1995) (4)
- Preparations and thermal isomerization of some tricarbonyl(1-silacyclohexadiene) iron complexes. Silyl and hydrogen migration in the diene and the diene complex. (1986) (4)
- Silyl anions. VII. Electron transfer from trimethylsilylpotassium to benzophenone and naphthalene. Generation of anion radicals in nonpolar solvents such as n-hexane. (1977) (4)
- A Novel Synthesis of 2,4,10-Trioxa-3-silaadamantanes (1984) (4)
- Microbiological production of radioisotopically labelled 16 alpha-hydroxylated steroids in trace quantities. (1979) (4)
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- Effect of the Chiral Center Position of an Optically Active Terminal Group on the Induction of Optical Activity in Polysilanes (2007) (4)
- Silyl-Substituted Dilithium Salt of Fulvene Dianion with 6 Center/8 Electron π-System: Synthesis and Characterization (1999) (4)
- REACTIONS OF ALLYLSILANES WITH α-CHLORO ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS (1983) (4)
- A New Route to Iodomethyl-substituted Methylpolysilanes (1968) (3)
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- Chemistry of organosilicon compounds: CL. Preparation and UV spectra of nitrophenylpolysilanes (1982) (3)
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- A double-minimum skeletal torsion in 1-silabicyclo[2.2.2]octane by microwave spectroscopy (1980) (3)
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- POLAR EFFECTS ON THE CLEAVAGE REACTION OF SILICON-SILICON BONDS OF 1,2-DIARYLTETRAMETHYLDISILANE WITH 1,2-DIBROMOETHANE. STRUCTURE AND REACTIVITY IN SH2 REACTION (1972) (3)
- The ultraviolet spectra of p-bis(pentamethyldisilanyl)benzene and related compounds (1968) (3)
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- REGIOSELECTIVE SYNTHESIS OF 3-ALKENYLSILANES AND 3-ALKENYLSTANNANES BY SILICON- AND TIN-DIRECTED ELIMINATION FROM γ-SILYL AND γ-STANNYL SUBSTITUTED SULFOXIDES AND SULFILIMINES1) (1983) (2)
- Synthesis of 14C-labelled ER-30346, a novel antifungal triazole (1997) (2)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 195. N-(TRIMETHYLSILYLMETHYL)AMINOMETHYL ETHERS AS AZOMETHINE YLIDE SYNTHONS. A NEW AND CONVENIENT ACCESS TO PYRROLIDINE DERIVATIVES (1985) (2)
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- CHEMISTRY OF ORGANOSILICON COMPOUNDS: 175. A NOVEL SYNTHESIS OF 2,4,10-TRIOXA-3-SILAADAMANTANES (1984) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 198. A NOVEL AND CONVENIENT REGIO-CONTROLLED SYNTHESIS OF α-HALOGEN-SUBSTITUTED ALLYLSILANES. STEREOSELECTIVE SYNTHESIS OF Z-ALKENYL HALIDES (1985) (0)
- ORGANOGERMANIUM COMPOUNDS PART 4, NOVEL PHENYL MIGRATIONS FROM CARBON TO GERMANIUM AND FROM GERMANIUM TO CARBON (1975) (0)
- Synthesis, structures, and magnetic properties of novel Roddlesdenâ•fiPopper homologous series Srn+1ConO3n+1 (n=1,2,3,4, and [infinity]) (2014) (0)
- Chemistry of Organosilicon Compounds. Part 356. Molecular Structure and Photochemical Reactions of Trimethylsilylmethyl-Substituted Masked Disilene. (1998) (0)
- Chemistry of Organosilicon Compounds. Part 225. Preparation and Some Reactions of Dibenzo-7-silanorbornadiene Derivatives. (1987) (0)
- Chemistry of Organo‐Silicon Compounds. Part 308. Matrix Isolation and Electronic Structure of Vinyl‐Substituted Silylenes and Their Complexes with Bases. (1995) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. PART 125. A CONVENIENT SYNTHESIS OF IODOTRIMETHYLSILANE AND ITS USE IN THE PREPARATION OF SILYLKETENES (1979) (0)
- Chemistry of Organosilicon Compounds. Part 305. Hexakis( fluorodimethylsilyl)benzene, Hexakis(methoxydimethylsilyl)benzene, and Related Compounds. Novel Neutral Pentacoordinate Structures for Silicon and Merry‐Go‐Round Degenerate Fluorine Migration. (2010) (0)
- Recent Developments in Synthetic Strategies with Allylsilanes: from Tetracoordinate to Pentacoordinate Allylsilanes (1993) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. CXVI. FLUORIDE ION-PROMOTED ISOMERIZATION OF METHYL-SUBSTITUTED ALLYLSILANES. REGIOSELECTIVE SYNTHESES OF ALLYLSILANES (1979) (0)
- Highly Regio- and Stereoselective Allylation of α-Diketones via the Fluorosilicate Route. (1996) (0)
- Chemistry of Organosilicon Compounds. Part 350. Highly Selective Mono- and Polyallylation of Polychlorosilanes and Polychlorodisilanes. (1999) (0)
- Photochemistry of Disilanylcyclohexenones. ESR Detection of a Novel Silatrimethylenemethane Intermediate (1992) (0)
- CHARGE-TRANSFER SPECTRA AND PERACID OXIDATION OF 1,2-DISILACYCLOALKANES, A RATE-CHARGE-TRANSFER RELATIONSHIP IN THE ELECTROPHILIC REACTION AT SIGMA-BONDS (1974) (0)
- Chemistry of Organosilicon Compounds. Part 288. Bis((dimethoxyethane) lithium(I)) 1,2,4,5-Tetrakis(trimethylsilyl)benzenide. The First 6C-8. pi. Antiaromatic Benzene Dianion (1991) (0)
- Chemistry of Organosilicon Compounds. Part 235. A New Mode of Transition-Metal-Catalyzed Intramolecular Dimerization of Alkynes. The First Synthesis of a Methylenecyclopropene Complex. (1988) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS PART 80, USEFUL MODIFICATIONS IN THE PREPARATION OF TRIMETHYLSILYLSODIUM AND TRIMETHYLSILYLPOTASSIUM (1975) (0)
- Catalyst, same method of preparation and olefin polymerization process using the same. (1990) (0)
- 2‐Trimethylsilylmethyl‐1,3‐butadiene (2001) (0)
- A Convenient and Efficient Metalation of Methylsilane. Carbonyl Methylenations Using Metallated (2-Aminoalkoxy)trimethylsilane. (1987) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 92. AN ELECTRON SPIN RESONANCE STUDY ON N THE SPIRO CYCLOHEXADIENYL RADICALS (1977) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 204. STEREOCHEMISTRY OF THERMAL (2 + 2) ) CYCLOADDITION OF DISILENE WITH ACETYLENE (1985) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 196. PHOTOCHEMICAL REACTION OF DIBENZOTETRAMETHYLDISILACYCLOHEXADIENE THROUGH CHARGE-TRANSFER COMPLEX (1985) (0)
- Chemistry of Organosilicon Compounds. Part 293. Preparation, Characterization, and Crystal Structures of Octasilacubanes and Octagermacubanes. (1992) (0)
- Chemistry of Organosilicon Compounds. Part 261. Photochemical 1,3-Silyl Migration in Allylsilanes Occurring with Inversion of Silyl Configuration. (1990) (0)
- 2-Dimethylaminomethyl-3-trimethylsilylmethylbuta-1,3-diene as a Synthetic Equivalent of 2,2′-Biallyl Zwitterionic Species. (1987) (0)
- Synthesis of poly (ethylene oxide)-b-polysilane by anionic polymerization of masked disilenes using a macroinitiator method (2003) (0)
- Chemistry of Organosilicon Compounds. Part 216. Sterically Crowded Silanes. (1986) (0)
- Synthesis and mesomorphism of 1,10-dialkylpermethyl-decasilanes (1999) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 106. α‐SILOXYALLYLSILANES AS HOMOENOLATE ANION EQUIVALENTS. A NOVEL SYNTHESIS OF Γ‐KETO ALDEHYDES (1978) (0)
- CYCLOADDITION REACTION OF TROPONE WITH 1,1‐DIMETHYL‐2,5‐DIPHENYL‐1‐SILACYCLOPENTADIENE (1974) (0)
- PROTECTION OF ALCOHOLS AND ACIDS WITH ALLYLSILANES CATALYZED BY IODINE OR IODOTRIMETHYLSILANE IN CHLORINATED HYDROCARBONS (1981) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. XCIV. PREPARATIONS OF 8‐SILATRICYCLO(3.2.1.02,4)OCT‐6‐ENES, NEW PHOTOCHEMICAL SILYLENE GENERATORS (1977) (0)
- 2‐Trimethylstannylmethyl‐1,3‐butadiene (2001) (0)
- Chemistry of Organosilicon Compounds. Part 232. Novel Photochemical Reactions of Dibenzodisilacyclohexadiene with Ketones. (1987) (0)
- ALLYLATION REACTIONS BY USING ALLYLSTANNANES IN THE PRESENCE OF A LEWIS ACID (1980) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 170. PHOTOOXYGENATION OF SILACYCLOPENTADIENES: A NOVEL OXYGENATION PRODUCT, 2,4-DIOXA-3-SILABICYCLO(3.2.0)HEPT-6-ENE, AND ITS CYCLOREVERSION REACTIONS (1983) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 176. REVERSIBILITY IN THE HOMOLYTIC AROMATIC SUBSTITUTION WITH SILYL AND GERMYL RADICALS (1983) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS PART 79, NOVEL (SIGMA + PI)REACTIONS OF HEXAORGANODISILANES WITH ACETYLENES CATALYZED BY PALLADIUM COMPLEXES (1975) (0)
- Reactive Intermediates and Mechanistic Aspects of Organosilicon Photoreactions (1991) (0)
- 1-Methyl-1-boracyclohepta-2,4,6-triene (III), the First C-Unsubstituted Borepin. (1988) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 203. PHOTOCHEMISTRY OF BIS(9-ANTHRYL)DIMETHYLSILANE AND -GERMANE (1985) (0)
- Chemistry of Organosilicon Compounds. Part 326. Stereoselective Allylation of β‐Hydroxy‐ and β‐Amino‐α,β‐enones with Allyltrifluorosilane/Triethylamine Systems. (1995) (0)
- Bimolecular Reactions of Tetrakis(trialkylsilyl)disilenes with Various Reagents. (1999) (0)
- Chemistry of Organo-Silicon Compounds. Part 287. Synthesis and X-Ray Structure of the First Dicoordinate Dialkylstannylene That Is Monomeric in the Solid State. (1992) (0)
- Process for the preparation of a medicament useful naphthalene derivatives (1989) (0)
- Reduction of Carbonyl Compounds with Pentacoordinate Hydridosilicates. (1987) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 139. UNUSUALLY FAST CIS-TRANS ISOMERIZATION OF A TETRASILYLATED ETHYLENE; RADICAL FORMATION DURING THE ROTATION (1980) (0)
- Organosilicon Compounds. Part 255. Preparation and X-Ray Crystal Structure of the First Pentacoordinate Silylsilicates. (1989) (0)
- Synthesis of (Z)‐3‐[4‐(acetyloxy)‐5‐ethyl‐3‐methoxy‐1‐NAPH‐thalenyl]‐2‐methyl‐2‐ propenoic‐2‐14C acid (14C‐E5090) (1991) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. XC. THE REACTION OF THE TRIMETHYLCHLOROSILANE-LITHIUM-ALIPHATIC KETONE MIXTURE IN 1,3-DIMETHYL-2-IMIDAZOLIDINONE (1976) (0)
- 2‐Dimethylaminomethyl‐3‐trimethylsilylmethyl‐1,3‐butadiene as 2,2′‐Biallyl Diradical Synthon. (1986) (0)
- Regiospecific Cycloaddition Reactions Using Functionalized Isoprenylsilane and Related Compounds. (1986) (0)
- Organo‐Silicon Compounds. Part 252. ((Me3Si)2CHGe)6, the First Hexagermaprismane. (1989) (0)
- GENERATION, CHARACTERIZATION AND QUENCHING OF THE DIANION OF TETRAKIS(TRIMETHYLSILYL)ETHYLENE (1982) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 137. ALKYLATION AND ARYLATION OF 2-TRIMETHYLSILOXYALLYL HALIDES. A NEW REGIOSPECIFIC ROUTE TO SILYL ENOL ETHERS (1980) (0)
- A NOVEL INHIBITOR OF IL-1 GENERATION, E5090 : SYNTHESIS AND STRUCTURE ACTIVITY RELATIONSHIPS OF 3-(4-HYDROXY-1-NAPHTHALENYL)-2-PROPENOIC ACIDS (1991) (0)
- σ/π Interactions in (2.2)Paracyclophanes. PE Investigations on Octamethyltetrasila(2.2)paracyclophane and Octamethyltetrasila(2.2)(2,5)thiophenophane and -furanophane. (1988) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 138. STEPWISE CONVERSION OF OXIRANES TO O ALLYLIC ALCOHOLS BY IODOTRIMETHYLSILANE AND 1,8-DIAZABICYCLO(5.4.0)UNDEC-7-ENE (1980) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 153. A NOVEL AMINOMETHYLATION OF SILYL ENOL ETHERS WITH AMINOMETHYL ETHERS CATALYZED BY IODOTRIMETHYLSILANE OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE (1982) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 186. PHOTOLYSIS AND THERMOLYSIS OF 1,2,3-TRISILACYCLOPENTENE. REGIOSPECIFIC AND NON-REGIOSPECIFIC SILYLENE EXTRUSION. (1984) (0)
- Regiospecific and Enantioselective Polymerization to Poly[(dibutylamino)(trimethyldisilene)] by the Masked Disilene Method (2008) (0)
- Preparation, Structure, and Photochemistry of 2-Disilanyl-1,4-benzoquinones. (2003) (0)
- Chemistry of Organosilicon Compounds. Part 251. Tris(tert-butyldimethylsilyl)trimethylsilylethylene and Tetrakis(dimethylsilyl)ethylene. The Most Twisted and Untwisted Tetrasilylethylenes. (1988) (0)
- Chemistry of Organo‐Silicon Compounds. Part 331. Polymerization of in situ Generated Disilenes. (1997) (0)
- Silole‐Core Dendrimers: A Facile Synthesis and Photophysical Properties. (2005) (0)
- Organosilicon Compounds. Part 302. Regio‐ and Stereochemistry and Kinetics in the Addition Reactions of Alcohols to Phenyl‐Substituted Disilenes. (1994) (0)
- 1,5-DIBROMO-3-TERT.-BUTYLPENTANE (1973) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 184. REGIOSELECTIVE SYNTHESIS OF 3-ALKENYLSILANES AND 3-ALKENYLSTANNANES BY SILICON- AND TIN-DIRECTED ELIMINATION FROM Γ-SILYL AND Γ-STANNYL SUBSTITUTED SULFOXIDES AND SULFILIMINES (1984) (0)
- Catalyst, the same process for the preparation and polymerization of olefins under the same application. (1990) (0)
- Chemistry of Organosilicon Compounds. Part 228. Octamethyltetrasila-(2.2)paracyclophane. Cyclophanes Bridged by Polysilanes. (1987) (0)
- Ring-Opening Polymerization of Carbacyclic Silanes. (1992) (0)
- Synthesis, Structure, and Photochemistry of 2,3,5,6-Tetrasilyl-1,4-benzoquinones and Related Compounds. (2003) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 160. A CONVENIENT AND NOVEL SYNTHESIS OF 1,1-DICHLOROALKENES USING α-LITHIATED DICHLOROMETHYLTRIMETHYLSILANE AND ALDEHYDES (1984) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 179. STEREOSELECTIVE CROSS-ALDOL REACTIONS OF SILYL ENOL ETHERS WITH ACETALS CATALYZED BY IODOTRIMETHYLSILANE (1984) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 134. (2-ALKOXYCARBONYLALLYL)TRIMETHYLSILANES AS NEW REAGENTS OF 2-ALKOXYCARBONYLALLYLATION OF ELECTROPHILES (1980) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 115. DIMETHYLSILANEDIYLIRON COMPLEXES (1978) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 173. REACTIONS OF α-HETEROATOM-SUBSTITUTED ETHERS AND SULFIDES WITH SILYL ENOL ETHERS. CHEMOSELECTIVITY IN THE CLEAVAGE OF HETEROATOM-CARBON BONDS BY IODOTRIMETHYLSILANE AND TRIMETHYLSILYL TRIFLUO (1983) (0)
- Regioselective Cycloaddition Reactions of Allylsilanes and Silyl Enol Ethers with Nitrones and Nitrile Oxides. (1986) (0)
- PREPARATION OF (PI-CYCLOPENTADIENYL)(PI-TETRAKIS(TRIMETHYLSILYL)CYCLOBUTADIENE)COBALT (1974) (0)
- CHEMISTRY OF ORGANOSILICON COMPOUNDS. 95. η3-1-SILAPROPENYLTRICARBONYLIRON COMPLEXES. THE FIRST STABLE COMPOUND OF DOUBLY BONDED SILICON (1977) (0)
- CRYSTAL STRUCTURE OF TETRAKIS(TRIMETHYLSILYL)ETHYLENE AT -70°C (1982) (0)
- Oxidative Si‐C Bond Cleavage of Organotrifluorosilanes (I) Involving Organic Group Migration from Hypercoordinate Silicon to Oxygen. (1990) (0)
- Hydroxyindole Derivatives as Inhibitors of IL‐1 Generation. Part 1. Synthesis and Pharmacological Activities of (E)‐3‐(4‐Hydroxy‐5‐ methoxyindole‐7‐yl)‐2‐methylpropenoic Acid Derivatives. (1995) (0)
- Chemistry of Organosilicon Compounds. Part 263. Synthesis, Properties, and Molecular Structure of Highly Distorted Hexakis(trimethylsilyl)benzene. (1990) (0)
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