Hiroshi Shinokubo

Hiroshi Shinokubo's AcademicInfluence.com Rankings

Hiroshi Shinokubo

Chemistry

#4658

World Rank

#5744

Historical Rank

Organic Chemistry

#773

World Rank

#870

Historical Rank

chemistry Degrees

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Chemistry

Hiroshi Shinokubo's Degrees

PhD Chemistry University of Tokyo
Masters Chemistry University of Tokyo
Bachelors Chemistry University of Tokyo

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Hiroshi Shinokubo's Published Works

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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author

Published Works

Synthesis and Functionalization of Porphyrins through Organometallic Methodologies. (2017) (264)
Metalation of expanded porphyrins: a chemical trigger used to produce molecular twisting and Möbius aromaticity. (2008) (223)
Water enables direct use of allyl alcohol for Tsuji-Trost reaction without activators. (2004) (191)
A directly fused tetrameric porphyrin sheet and its anomalous electronic properties that arise from the planar cyclooctatetraene core. (2006) (183)
Unambiguous identification of Möbius aromaticity for meso-aryl-substituted [28]hexaphyrins(1.1.1.1.1.1). (2008) (176)
Selective halogen-magnesium exchange reaction via organomagnesium ate complex. (2001) (171)
Transition Metal‐Catalyzed Carbon−Carbon Bond Formation with Grignard Reagents − Novel Reactions with a Classic Reagent (2004) (155)
Powerful Solvent Effect of Water in Radical Reaction: Triethylborane-Induced Atom-Transfer Radical Cyclization in Water (2000) (145)
Synthesis of directly connected BODIPY oligomers through Suzuki-Miyaura coupling. (2011) (140)
A porphyrin nanobarrel that encapsulates C(60). (2010) (140)
Nitrogen-embedded buckybowl and its assembly with C60 (2015) (136)
Highly Regioselective Ir-Catalyzed β-Borylation of Porphyrins via C−H Bond Activation and Construction of β−β-Linked Diporphyrin (2005) (133)
Gram-scale synthesis of nickel(II) norcorrole: the smallest antiaromatic porphyrinoid. (2012) (129)
Synthesis and biradicaloid character of doubly linked corrole dimers. (2006) (125)
Facile synthesis of biphenyl-fused BODIPY and its property. (2012) (124)
Intermolecular oxidative annulation of 2-aminoanthracenes to diazaacenes and aza[7]helicenes. (2012) (121)
Synthesis of arylated perylene bisimides through C-H bond cleavage under ruthenium catalysis. (2009) (118)
Marriage of porphyrin chemistry with metal-catalysed reactions. (2009) (117)
Photoelectrochemical Properties of Doubly β-Functionalized Porphyrin Sensitizers for Dye-Sensitized Nanocrystalline-TiO2 Solar Cells (2008) (108)
Regioselective Ru-catalyzed direct 2,5,8,11-alkylation of perylene bisimides. (2009) (107)
An antiaromatic electrode-active material enabling high capacity and stable performance of rechargeable batteries. (2014) (107)
Iridium-catalyzed direct tetraborylation of perylene bisimides. (2011) (89)
Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids. (2003) (89)
Triethylborane-induced bromine atom-transfer radical addition in aqueous media: study of the solvent effect on radical addition reactions. (2001) (86)
Cobalt-catalyzed three-component coupling reaction of alkyl halides, 1,3-dienes, and trimethylsilylmethylmagnesium chloride. (2003) (86)
Figuration of bowl-shaped π-conjugated molecules: properties and functions (2018) (82)
Triethylborane-Mediated Atom Transfer Radical Cyclization Reaction in Water (1998) (82)
Disulfidation of alkynes and alkenes with gallium trichloride. (2004) (81)
Synthesis of Doubly β‐to‐β 1,3‐Butadiyne‐Bridged Diporphyrins: Enforced Planar Structures and Large Two‐Photon Absorption Cross Sections (2007) (79)
Palladium-catalyzed cross-coupling reaction of organoindiums with aryl halides in aqueous media. (2001) (75)
Synthesis of brominated directly fused diporphyrins through gold(III)-mediated oxidation. (2006) (75)
Rhodium-catalyzed [2 + 2 + 2] cyclotrimerization in an aqueous-organic biphasic system. (2003) (74)
A stable non-Kekulé singlet biradicaloid from meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1). (2010) (71)
Porphyrin pincer complexes: peripherally cyclometalated porphyrins and their catalytic activities controlled by central metals. (2007) (71)
Doubly β-Functionalized Meso−Meso Directly Linked Porphyrin Dimer Sensitizers for Photovoltaics (2009) (71)
Highly-conducting molecular circuits based on antiaromaticity (2017) (71)
Stacked antiaromatic porphyrins (2016) (70)
Synthesis of corrole derivatives through regioselective Ir-catalyzed direct borylation. (2005) (69)
Synthetic Radical Reactions in Aqueous Media (2002) (68)
Unusual interchromophoric interactions in beta,beta' directly and doubly linked corrole dimers: prohibited electronic communication and abnormal singlet ground states. (2009) (67)
Azabuckybowl-Based Molecular Tweezers as C60 and C70 Receptors. (2018) (67)
Functionalization of boron dipyrrin (BODIPY) dyes through iridium and rhodium catalysis: a complementary approach to alpha- and beta-substituted BODIPYs. (2009) (65)
Hydrosilylation of alkynes with a cationic rhodium species formed in an anionic micellar system. (2004) (62)
Intramolecular [4 + 2] cycloadditions of benzynes with conjugated enynes, arenynes, and dienes. (2005) (62)
Reversible Carbon-Carbon Bond Breaking and Spin Equilibria in Bis(pyrimidinenorcorrole). (2016) (59)
Synthesis of diazo-bridged BODIPY dimer and tetramer by oxidative coupling of β-amino-substituted BODIPYs. (2014) (56)
Synthesis of highly twisted and fully π-conjugated porphyrinic oligomers. (2015) (56)
Trialkylmanganate-Induced Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and alpha-Iodo Acetal. (1997) (55)
Simple and Efficient TiCl4-Mediated Synthesis of Biaryls via Arylmagnesium Compounds (2000) (54)
Dimeric assemblies from 1,2,3-triazole-appended Zn(II) porphyrins with control of NH-tautomerism in 1,2,3-triazole. (2008) (54)
TiCl4−n-Bu4NI as a Reducing Reagent: Pinacol Coupling and Enolate Formation from α-Haloketones (2000) (53)
Boron trifluoride-catalyzed reaction of alkyl fluoride with silyl enolate, allylsilane, and hydrosilane (2004) (53)
Reaction of α,α-Dibromo Oxime Ethers with Grignard Reagents: Alkylative Annulation Providing a Pyrimidine Core (2002) (52)
Triethylborane-mediated hydrogallation and hydroindation: novel access to organogalliums and organoindiums. (2003) (52)
Pt(II)- and Pt(IV)-bridged cofacial diporphyrins via carbon-transition metal sigma-bonds. (2008) (51)
Metal-mediated synthesis of antiaromatic porphyrinoids from a BODIPY precursor. (2011) (50)
tert-Butyldimethylsilyldihalomethyllithium as a dihalomethylene dianion synthon. 1,3-Rearrangement and 1,4-rearrangement of silyl group from carbon to oxide (1996) (50)
Synthesis of nickel(II) azacorroles by Pd-catalyzed amination of α,α'-dichlorodipyrrin Ni(II) complex and their properties. (2012) (50)
Reversible σ-Bond Formation in Bowl-Shaped π-Radical Cations: The Effects of Curved and Planar Structures. (2018) (50)
Oxidative annulation of β-aminoporphyrins into pyrazine-fused diporphyrins. (2012) (49)
Intermolecular rhodium-catalyzed carbometalation/Heck-type reaction in water. (2006) (48)
Regioselective borylation of porphyrins by C-H bond activation under iridium catalysis to afford useful building blocks for porphyrin assemblies. (2007) (48)
Enolate formation from cyclopropyl ketones via iodide-induced ring opening and its use for stereoselective aldol reaction (2001) (48)
Directly Pd(II)-bridged porphyrin belts with remarkable curvatures. (2010) (48)
2,5-Thienylene-bridged triangular and linear porphyrin trimers. (2008) (47)
Phosphane-free rhodium catalyst in an anionic micellar system for [4+2] annulation of dienynes. (2004) (47)
Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous Media (2001) (47)
Facile peripheral functionalization of porphyrins by Pd-catalyzed [3+2] annulation with alkynes. (2006) (45)
Cobalt-mediated Mizoroki-Heck-type reaction of epoxide with styrene (2004) (44)
Intramolecular tandem Michael-type addition/aldol cyclization induced by TiCl(4)-R(4)NX combinations. (2002) (44)
Triethylborane-induced radical reactions with gallium hydride reagent HGaCl2. (2001) (44)
Et3B-induced radical addition of N,N-dichlorosulfonamide to alkenes and pyrrolidine formation via radical annulation. (2003) (43)
Biaryl synthesis from two different aryl halides with tri(2-furyl)germane. (2002) (43)
A stable organic radical delocalized on a highly twisted pi system formed upon palladium metalation of a Möbius aromatic hexaphyrin. (2010) (42)
Radical [3+2] annulation of N-allyl-N-chlorotosylamide with alkenes via atom-transfer process. (2001) (42)
Bis-rhodium hexaphyrins: metalation of [28]hexaphyrin and a smooth Hückel aromatic-antiaromatic interconversion. (2009) (42)
Functionalization of a simple dithienylethene via palladium-catalyzed regioselective direct arylation. (2011) (42)
Intramolecular Radical Cyclization of 2-Haloethanal Allyl Acetal and Allyl 2-Halophenyl Ether with a Grignard Reagent in the Presence of Iron(II) Chloride (1998) (40)
Synthesis of oxygen-substituted hexa-peri-hexabenzocoronenes through Ir-catalyzed direct borylation. (2012) (40)
Reactions of gem-dibromo compounds with trialkylmagnesate reagents to yield alkylated organomagnesium compounds. (2002) (40)
Three-dimensional aromaticity in an antiaromatic cyclophane (2019) (39)
Synthetic protocol for diarylethenes through Suzuki-Miyaura coupling. (2011) (39)
Large porphyrin squares from the self-assembly of meso-triazole-appended L-shaped meso-meso-linked Zn(II)-triporphyrins: synthesis and efficient energy transfer. (2010) (38)
Triethylborane-induced radical reactions with gallium- and indium hydrides (2003) (37)
Isolation of a 1,4-diketone intermediate in oxidative dimerization of 2-hydroxyanthracene and its conversion to oxahelicene. (2015) (36)
Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator in Aqueous Media: Facile Synthesis of γ -Lactones (2001) (36)
meso-Aryl substituted rubyrin and its higher homologues: structural characterization and chemical properties. (2008) (35)
Radical Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and 2-Iodoethanal Acetal by Means of Trialkylmanganate(II) (1997) (35)
meso-Thiaporphyrinoids revisited: missing of sulfur by small metals. (2012) (35)
Alkylative Preparation of α-Silylalkylmagnesium from R3 SiCHBr2 Using a Magnesate Reagent. (2001) (34)
Mesoporous organosilica hybrids consisting of silica-wrapped π-π stacking columns. (2012) (34)
Near-IR absorbing nickel(II) porphyrinoids prepared by regioselective insertion of silylenes into antiaromatic nickel(II) norcorrole. (2014) (34)
Regioselective Nucleophilic Functionalization of Antiaromatic Nickel(II) Norcorroles. (2015) (33)
Highly Stereoselective Coupling Reaction of Acrolein or Vinyl Ketone with Aldehydes (1999) (33)
Synthesis of chiral porphyrins through Pd-catalyzed [3+2] annulation and heterochiral self-assembly. (2008) (33)
Synthesis of a pyridine-fused porphyrinoid: oxopyridochlorin. (2009) (33)
ALLYLMANGANATION AND DIALLYLATION OF ACETYLENIC COMPOUNDS (1997) (32)
Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol (2000) (32)
Remarkable rate acceleration of Pd(0)-catalyzed hydrogermylation of alkynes and dienes in water. (2001) (32)
RADICAL ADDITION OF 2-IODOALKANAMIDE OR 2-IODOALKANOIC ACID TO ALKENOLS USING A WATER-SOLUBLE RADICAL INITIATOR IN WATER. A FACILE SYNTHESIS OF GAMMA -LACTONES (1999) (31)
Reaction of Titanate-Type Aldehyde Enolate with Ketones To Provide 3-Hydroxyaldehydes (1999) (31)
Dialkylation of gem-dibromocyclopropanes with trialkylmanganate and manganese(II) chloride-catalyzed reaction with alkylmagnesium bromide (1996) (31)
TiCl4-n-Bu4NX (X = I, Br, and Cl) combination-induced coupling of alpha,beta-unsaturated ketones with aldehydes. (2001) (30)
MANGANESE-CATALYZED PHENYLATION OF ACETYLENIC COMPOUNDS WITH A PHENYL GRIGNARD REAGENT (1998) (29)
Porphyrin "Lego block" strategy to construct directly meso-beta doubly linked porphyrin rings. (2010) (29)
A highly effective aldol reaction mediated by Ti(O-n-Bu)(4)/t-BuOK combined reagent (2000) (29)
tert-Butyldimethylsilyldichloromethyllithium as a dichloromethylene dianion synthon. 1,3-rearrangement of silyl group from carbon to oxide (1993) (29)
The Importance of a β–β Bond for Long‐Range Antiferromagnetic Coupling in Directly Linked Copper(II) and Silver(II) Diporphyrins (2005) (29)
Anthracene-bridged z-shaped [26]hexaphyrin(1.1.1.1.1.1.1) dimer from the regioselective Diels-Alder reaction of a hexaphyrin with bis-o-xylylene equivalents. (2005) (28)
A room temperature Kharasch reaction catalyzed by Pd(0) in a heterogeneous aqueous system (2002) (28)
Selective synthesis of a [32]octaphyrin(1.0.1.0.1.0.1.0) bis(palladium) complex by a metal-templated strategy. (2013) (28)
An Unprecedented Coupling Reaction of Arylmagnesium Compounds with Tetrahydrofuran Providing 2-Aryltetrahydrofuran Mediated by an Iodoalkane-EtMgBr System (1999) (28)
Olefin Inversion: Stereospecific Olefin Synthesis from Vicinal Alkoxyiodoalkanes with Butyllithium by an E2 Syn Mechanism. (1996) (28)
Lewis Acid-Induced Chemo- and Stereoselective Allylation of α-Iodo Mixed Acetal with Allylsilane (1997) (27)
Energy and electron transfer from fluorescent mesostructured organosilica framework to guest dyes. (2012) (27)
Conformational changes of meso-aryl substituted expanded porphyrins upon protonation: effects on photophysical properties and aromaticity. (2009) (27)
Oxidation of 2-amino-substituted BODIPYs providing pyrazine-fused BODIPY trimers. (2014) (27)
Regioselective allylmetalation of allenes with tetraallylmanganate or allylmagnesium chloride under MnCl2 catalysis. (2003) (27)
Functionalization of hexa-peri-hexabenzocoronenes: investigation of the substituent effects on a superbenzene. (2013) (27)
A facile preparation of alkenyl- and allenylmetallic compounds by means of iodine-metal exchange and their use in organic synthesis* (1995) (26)
Metathesis-like splitting reactions of metallated [36]octaphyrins(1.1.1.1.1.1.1.1): experimental and computational investigations. (2009) (26)
A β-to-β 2,5-thienylene-bridged cyclic porphyrin tetramer: its rational synthesis and 1 : 2 binding mode with C60 (2011) (26)
MANGANESE-CATALYZED REACTION OF GEM-DIBROMOALKANES WITH GRIGNARD REAGENTS.SELECTIVE SYNTHESIS OF ALKENYLSILANES (1997) (26)
Porphyrin synthesis in water provides new expanded porphyrins with direct bipyrrole linkages: isolation and characterization of two heptaphyrins. (2006) (25)
Shaping Antiaromatic π-Systems by Metalation: Synthesis of a Bowl-Shaped Antiaromatic Palladium Norcorrole. (2017) (25)
Aggregation-Induced Emission of Nitrogen-Bridged Naphthalene Monoimide Dimers. (2019) (25)
Synthesis of Tetraaza[8]circulenes from Tetrathia[8]circulenes through an SNAr-Based Process. (2017) (25)
Double cleavage of sp2 C-H and sp3 C-H bonds on one metal center: DMF-appended cyclometalated platinum(II) and -(IV) porphyrins. (2009) (24)
TRIETHYLBORANE-INDUCED RADICAL ADDITION OF HALOGENATED COMPOUNDS TO ALKENES AND ALKYNES IN WATER (1998) (24)
Synthesis and oxidation of cyclic tetraindole (2012) (24)
Novel [2+2+2]annulation of 1,6-diynes mediated by methallylchromate or methallylmagnesium chloride under CrCl3 catalysis. (2001) (24)
Transition metal catalyzed borylation of functional π-systems (2014) (24)
From alkenylsilanes to ketones with air as the oxidant. (2003) (24)
Reaction of tert-Butyl Dibromoacetate or N,N-Diethyldibromoacetamide with Trialkylmanganate Providing an Alkylated Manganese Enolate (1998) (24)
Direct preparation of allylic zirconium reagents from zirconocene-olefin complexes and alkenes. (2004) (24)
Chemo- and Regioselective Reduction of 5,15-Diazaporphyrins Providing Antiaromatic Azaporphyrinoids. (2016) (24)
A new strategy for the preparation of an active Mn(0) and its use for radical cyclization reactions (1999) (23)
Intramolecular iodosilyletherization of alkenylsilanols with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate (1996) (23)
Platinum(II) and Platinum(IV) Porphyrin Pincer Complexes: Synthesis, Structures, and Reactivity (2010) (23)
Strategic synthesis of 2,6-pyridylene-bridged beta-to-beta porphyrin nanorings through cross-coupling. (2010) (22)
Enolate Formation from α-Iodoaldehydes and α-Iodoketones by Means of Allylsilane−Titanium Tetrachloride and Its Application to an Aldol Reaction (1998) (22)
Ensemble and single-molecule spectroscopic study on excitation energy transfer processes in 1,3-phenylene-linked perylenebisimide oligomers. (2012) (22)
Synthesis of medium- and large-sized lactones in an aqueous-organic biphasic system. (2005) (22)
Reduction of Organic Halides with Tri-2-Furanylgermane: Stoichiometric and Catalytic Reaction (1999) (22)
Synthesis of pyrrolidine-fused [34]- and [36]octaphyrins via 1,3-dipolar cycloaddition. (2006) (22)
Reaction of gem-Dibromocyclopropanes or Iodobenzofuran with Trialkylmanganate (2000) (21)
Transformation of zirconocene-olefin complexes into zirconocene allyl hydride and their use as dual nucleophilic reagents: reactions with acid chloride and 1,4-diketone. (2004) (21)
Highly selective cleavage of prenyl ethers by means of a TiCl4-n-Bu4NI mixed reagent (1999) (21)
Synthesis and Photodynamics of Tetragermatetrathia[8]circulene. (2018) (21)
Palladium-catalyzed dimerization of meso-bromoporphyrins: highly regioselective meso-beta coupling through unprecedented remote C-H bond cleavage. (2009) (21)
Pyrrole-bridged porphyrin nanorings. (2010) (21)
Facile synthesis of acylsilanes via aerobic oxidation of gem-disilylalkylcopper compounds. (2001) (20)
NIR mechanochromic behaviours of a tetracyanoethylene-bridged hexa-peri-hexabenzocoronene dimer and trimer through dissociation of C–C bonds (2017) (20)
Efficient rhodium-catalyzed installation of unsaturated ester functions onto porphyrins: site-specific Heck-type addition versus conjugate addition. (2008) (20)
Allylation of Carbonyl Compounds with Allylic Gallium Reagents (2002) (20)
Benzonorcorrole NiII Complexes: Enhancement of Paratropic Ring Current and Singlet Diradical Character by Benzo-Fusion. (2018) (19)
Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C-H Bonds. (2017) (19)
Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo Carbonyl Compounds (2002) (19)
Systematic Synthesis of Tetrathia[8]circulenes: The Influence of Peripheral Substituents on the Structures and Properties in Solution and Solid States. (2020) (19)
Determinant Factors of Three-Dimensional Aromaticity in Antiaromatic Cyclophanes. (2021) (19)
A Stable Organic π-Radical of a Zinc(II)-Copper(I)-Zinc(II) Complex of Decaphyrin. (2015) (19)
Diversity-oriented synthesis of tetrathia[8]circulenes by sequential C-H borylation and annulation. (2015) (18)
Supramolecular assemblies of a nitrogen-embedded buckybowl dimer with C60† †Electronic supplementary information (ESI) available. CCDC 1579079 and 1579080. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04453d (2017) (18)
Synthesis of a figure-eight azahelicene dimer with high emission and CPL properties (2017) (18)
Enhancing the low-energy absorption band and charge mobility of antiaromatic NiII norcorroles by their substituent effects. (2017) (18)
A 3-pyridyl-5,15-diazaporphyrin nickel(II) complex as a bidentate metalloligand for transition metals. (2014) (18)
A Facile Synthesis of 1,1-Disilylethenes via Me3MgLi-Induced Monomethylation of Dibromodisilylmethanes (2001) (18)
Reduction of Organic Halides with Tri-2-furylgermane: Stoichiometric and Catalytic Reduction (2001) (18)
Peripherally cyclometalated iridium complexes of dipyridylporphyrin. (2011) (18)
Synthesis of meso,meso'-pyrrole-bridged diporphyrins by Cu(I)-mediated annulation. (2010) (18)
Reaction of silyldihalomethyllithiums with nitriles: formation of alpha-keto acylsilanes via azirines and 1,3-rearrangement of silyl group from C to N. (2004) (18)
Pd(0)-catalyzed reaction of alkynes with trifurylgermane and CO providing acylgermanes: the example of hydrometalcarbonylation of alkynes. (2002) (18)
Stereoselective Synthesis of Allyl Vinyl Ethers from Silyl Enol Ethers (1996) (18)
Assembled structures of dipyrrins and their oligomers bridged by dioxy-boron moieties. (2013) (18)
Preparation of organomanganese reagents from organic halides with activated manganese (2001) (18)
Stereospecific conversion of iodohydrin derivatives into alkenes by means of an allylsilane-titanium tetrachloride system and its application to stereoretentive deoxygenation of epoxides (1997) (17)
Base‐Induced Condensation of α‐Chloro Oxime Derivatives Furnishes Alkynes (2003) (17)
Dinaphthothiepine Bisimide and Its Sulfoxide: Soluble Precursors for Perylene Bisimide. (2020) (17)
Inserting Nitrogen: An Effective Concept to Create Non-Planar and Stimuli-Responsive Perylene Bisimide Analogues. (2019) (17)
A meso-spiro[cyclopentadiene-isoporphyrin] from a phenylethynyl porphyrin platinum(II) pincer complex. (2012) (17)
Triethylborane-induced radical allylation reaction with zirconocene-olefin complex. (2004) (17)
Synthesis of a diimidazolylporphyrin pincer palladium complex (2011) (16)
Synthesis of trisubstituted and tetrasubstituted alkenes via a manganate-induced migration–elimination process (2001) (16)
Coupling of Vinylcyclopropanes with Aldehydes Induced by a TiCl4/n-Bu4NI Combination: Synthesis of Conjugated Dienols (2002) (16)
Eta2-porphyrin Ru(II) pi complexes. (2010) (16)
Adsorption characteristic of self‐assembled corrole dimers on HOPG (2009) (16)
Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1) (2008) (15)
Synthesis of cyclopropanols via cyclopropanation of zinc enolates (1998) (15)
Synthesis of meso-5-azaindolyl-appended Zn(II) porphyrins via Pd-catalyzed annulation. (2007) (15)
Synthesis of directly and doubly linked dioxoisobacteriochlorin dimers. (2008) (15)
Manganese(II) Chloride-Catalyzed Alkylmagnesation of 2-Alkynylphenol (1998) (15)
Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species: Formation of Cyclopropane Derivatives (2002) (14)
Soluble and Planar 2,9-Diazaperopyrenes through Reductive Aromatization of Perylene Diimides: Tunable Emission and Aggregation Behaviors. (2019) (14)
Reaction of Trialkyl(dibromomethyl)silanes or 1,2-Bis(dibromomethyl)benzene with Triorganomanganates. A Facile and Selective Synthesis of Alkenylsilanes and 1,2-Diaryl-1,2-dihydrobenzocyclobutenes. (2000) (14)
Excess polarizability reveals exciton localization/delocalization controlled by linking positions on porphyrin rings in butadiyne-bridged porphyrin dimers. (2010) (14)
meso,meso'-Bis(5-azaindol-2-yl)-appended meso-meso-linked Zn(II) diporphyrin: a discrete fluorescent assembly. (2009) (14)
Carbolithiation of meso-aryl-substituted 5,15-diazaporphyrin selectively provides 3-alkylated diazachlorins. (2013) (14)
Ni(II) 10-Phosphacorrole: A Porphyrin Analogue Containing Phosphorus at the Meso Position. (2019) (14)
β-to-β 2,5-Pyrrolylene-Linked Cyclic Porphyrin Oligomers. (2016) (14)
NEW METHOD FOR THE PREPARATION OF AN ACTIVE MANGANESE SPECIES AND ITS USE FOR RADICAL CYCLIZATION REACTIONS (1998) (14)
Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons (1998) (14)
Nucleophilic addition of tri-2-furylgermane to aldehydes and α,β-unsaturated carbonyl compounds in the presence of a catalytic amount of base (2001) (13)
Conversion of acid chloride into homoallylic alcohol via allylic C [bond] H bond activation of alkene with a zirconocene complex. (2001) (13)
Generation and regioselective reactions of α, α-bis(silyl)-substituted allylcopper reagents: synthesis of 1,1-disilylalkenes (2002) (13)
Synthesis of Free-Base 10-Azacorroles. (2016) (13)
The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes. (2018) (13)
γ-Regioselective reaction of metaloxysilyl-substituted allyllithium derived from allyldiphenylsilanol (1997) (13)
Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes (1997) (13)
π-Extended Dihydrophenazines with Three-State NIR Electrochromism Involving Large Conformational Changes. (2017) (13)
Sequential carbon-carbon bond formation reaction using 1-silyl-2-propenyllithium (1998) (12)
Ni(II) tetrahydronorcorroles: antiaromatic porphyrinoids with saturated pyrrole units. (2016) (12)
Zwitterionic corroles: regioselective nucleophilic pyridination of a doubly linked biscorrole. (2009) (12)
Porphyrin Derivatives with Carbon-Metal Bonds (2009) (12)
Acid-Mediated Migration of Bromide in an Antiaromatic Porphyrinoid: Preparation of Two Regioisomeric Ni(II) Bromonorcorroles. (2017) (12)
Formation of manganese–alkyne complexes mediated by trialkylmanganates and their application (2003) (12)
Highly diastereoselective tandem reduction-allylation reactions of 1,4-diketones with zirconocene-olefin complexes. (2003) (12)
Synthesis of Pyrimidines via Base-induced Condensation of α-Chloro Oxime Derivatives (2004) (11)
Radical Cyclization of N-Allyl-2-halo Amide in Water (2000) (11)
Control of Conformation and Chirality of Nonplanar π-Conjugated Diporphyrins Using Substituents and Axial Ligands. (2016) (11)
Direct amination of the antiaromatic NiII norcorrole (2017) (11)
10-Silacorroles Exhibiting Near-Infrared Absorption and Emission. (2017) (11)
Cyclization of 1,6-enynes with allylic chromate species. (2002) (11)
Synthesis of pyridine-fused perylene imides with an amidine moiety for hydrogen bonding. (2013) (11)
Synthesis of cyclopropanes via iodine–magnesium exchange between 3-iodomethyl-1-oxacyclopentanes and organomagnesium reagents (2004) (10)
Selective Oxidation of Propargylic Alcohols into α,β-Acetylenic Aldehydes with a TiCl4/Et3N System (2001) (10)
Post-modification of meso-meso-linked porphyrin arrays by iridium and rhodium catalyses for tuning of energy gap. (2009) (10)
A room temperature preparation of alkenyllithiums by lithium-halogen exchange between alkenyl iodides and n-BuLi in hydrocarbon solvents (1994) (10)
Structures of the Heme Acquisition Protein HasA with Iron(III)-5,15-Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group. (2017) (10)
Silylethynyl substituents as porphyrin protecting groups for solubilization and selectivity control. (2014) (10)
Facile Preparation of Vicinal Allylsiloxy- and Vinylsiloxyhaloalkanes and Their Radical Cyclization Reaction (1997) (10)
Preparation of Alkyl Silyl Acetals from Carboxylic Esters with tert-Butyldimethylsilyldihalomethyllithium. 1,3-Rearrangement of Silyl Group from Carbon to Oxygen (1995) (9)
Efficient Pd(0)-Catalyzed Hydrosilylation of Alkynes with Triorganosilanes (2002) (9)
Cover Picture: Transition Metal‐Catalyzed Carbon−Carbon Bond Formation with Grignard Reagents − Novel Reactions with a Classic Reagent (Eur. J. Org. Chem. 10/2004) (2004) (9)
Bithiophene-porphyrin hybrid nanorings. (2010) (9)
Manganese-Catalyzed Carbomagnesation of Alkynes (2003) (9)
Triethylborane Induced Radical Reaction of Gallium Enolates with α-Halo Esters (2002) (9)
Generation of allylic manganates from trimethylmanganate and allylic stannanes and their reactions with epoxides (1997) (9)
The synthesis of Ni(II) and Al(III) 10-azacorroles through coordination-induced cyclisation involving 1,2-migration. (2016) (9)
Design and Synthesis of Tunable Ligands with 4,4′-Bipyridyl as an Electron-Accepting Unit and Their Rhenium Complexes (2017) (9)
Photodynamics of [26]- and [28]hexaphyrin-bodipy hybrids. (2014) (9)
Consecutive double 1,2-migration of two different groups in silyl(dichloromethyl)cuprates. (2004) (9)
A Hexameric Porphyrin Triangle Constructed by Suzuki-Miyaura Cross-coupling Reaction (2011) (9)
Synthesis of highly distorted π-extended [2.2]metacyclophanes by intermolecular double oxidative coupling. (2013) (9)
PREPARATION OF TRIBUTYLSTANNYLMANGANATE AND ITS ADDITION TO PROPARGYLIC ALCOHOLS WITH HIGH REGIO-AND STEREOSELECTIVITIES (1999) (9)
Oxidation of gem-borylsilylalkylcoppers to acylsilanes with air. (2006) (9)
Radical addition of triphenylgermane to vinyloxiranes: Its application to synthesis of 4-vinyltetrahydro-2-furanones (2001) (8)
X-Shaped Cyclobutane-Linked Tetraporphyrins through a Thermal [2+2] Cycloaddition of Etheno-Fused Diporphyrins. (2018) (8)
First self-assembly study of large π-conjugated corrole dimers on solid substrates (2009) (8)
Rearrangement of β-tertbutyldimethylsiloxy carbenoids. Regio- and stereoselective synthesis of (Z)-1-Halo-2-tert-butyldimethylsiloxy-1-alkenes (1993) (8)
One-pot synthesis of α,β-unsaturated ketones from tert-butyldimethylsilyldibromomethane and two different aldehydes (1994) (8)
Facile synthesis of ketones from 1,1-disilylethenes via oxidation of gem-disilylalkanes. (2002) (8)
Synthesis of meso-Alkyl-Substituted Norcorrole-NiII Complexes and Conversion to 5-Oxaporphyrins(2.0.1.0). (2019) (8)
Stereoselective allylation of acetals through intramolecular transfer of an allylsilane (1999) (8)
Synthesis of silyl aziridines and alpha-amino acylsilanes with silyldibromomethyllithium. (2004) (8)
as-Indaceno[3,2,1,8,7,6-ghijklm]terrylene as a near-infrared absorbing C70-fragment (2020) (8)
Reactions of Antiaromatic Norcorrole Ni(II) Complex with Carbenes. (2020) (7)
Diazachlorin and diazabacteriochlorin for one- and two-photon photodynamic therapy. (2018) (7)
Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one or Cyclohexanecarbaldehyde (1997) (6)
Organic Synthesis Using Organomanganese Compounds (1999) (6)
Transformation of tetrahydropyranyl ether of allylic alcohol into 7-octene-1,5-diol by means of trialkylmanganate (1999) (6)
Synthesis and Crystal Packing Structures of 2,7-Diazapyrenes with Various Alkyl Groups at 1,3,6,8-Positions (2020) (6)
Porphyrin Analogues That Consist of Indole, Benzofuran, and Benzothiophene Subunits (2013) (6)
Synthesis, reactivity and property of 5,15-dithiaporphyrin copper(II) complex (2014) (6)
Regioselective Reaction of Dilithiated 1-Alkynylsilanol with Electrophiles (1998) (6)
Tributylmanganate(II)-Mediated Cyclization of Enynes (2000) (6)
Development of Novel Synthetic Reactions with Organomagnesium Reagents (2003) (6)
Preparation of α-silyl- or α,α-bis(silyl)-substituted alkylcopper reagents and their synthetic use (2005) (6)
Palladium-Catalyzed [3+2] Annulation of meso-Bromoporphyrin with Silylacetylenes and Desilylation of 8a-Silyl-7,8-dehydropurpurin (2015) (6)
Theoretical Study on Open-Shell Singlet Character and Second Hyperpolarizabilities in Cofacial π-Stacked Dimers Composed of Weak Open-Shell Antiaromatic Porphyrins. (2018) (6)
Acridino[2,1,9,8-klmna]acridine Bisimides: An Electron-Deficient π-System for Robust Radical Anions and n-Type Organic Semiconductors. (2021) (6)
Facile syntheses of α-bromo-α-silyl ketones and α-bromoacylsilanes from tert-butyldimethylsilyldibromomethane and carbonyl compounds (1996) (6)
A Facile Generation of a Cyclopropylzinc Compound from an Alkenylzinc Derivative and Its Reaction with Electrophiles. (1998) (6)
Synthesis and Properties of meso-Arylated Corrphycenes. (2017) (6)
Iodotrimethylsilane-induced cyclization of 6-alkynal acetals (2001) (5)
Indolylindolinone: Easily Accessible, Tunable, and Wide-Range Absorbing Dyes (2015) (5)
Syntheses and Properties of Antiaromatic Porphyrinoids (2016) (5)
Highly diastereoselective addition of silyldihalomethyllithiums to chiral alkyl esters. (2003) (5)
Synthesis and Properties of an 18π Aromatic Norcorrole P(V) Complex. (2021) (5)
Dual Emission of a Free-Base 5-Oxaporphyrinium Cation from its cis- and trans-NH Tautomers. (2020) (5)
Synthesis and Characterization of 16π Antiaromatic 2,7-Dihydrodiazapyrenes: Antiaromatic Polycyclic Hydrocarbons with Embedded Nitrogen. (2021) (5)
Synthesis of Dihydropyrazine-fused Porphyrin Dimers (2019) (5)
A synthesis of novel expanded porphyrinoids: NiII-induced nitrile cyclization of dicyanovinylene-bis(meso-aryl)dipyrrin. (2017) (5)
Stereospecific or Stereoselective Elimination of vicinal-Alkoxyiodoalkanes by Means of Organometallic Reagents (2001) (5)
Ni(II) 10-Boracorrole: An Antiaromatic Porphyrinoid Containing a Boron Atom at the meso-Position (2019) (4)
Synthesis of doubly beta-to-beta 1,3-butadiyne-bridged diporphyrins: enforced planar structures and large two-photon absorption cross sections. (2007) (4)
Aggregation-Induced Emission in Tetrathia[8]circulene Octaoxides via Restriction of the Dynamic Motion of their Negatively Curved π-Frameworks. (2020) (4)
Nickel (II) pyrrocorphin: Enhanced binding ability in a highly reduced porphyrin complex. (2018) (4)
Hetero[8]circulenes: synthetic progress and intrinsic properties. (2020) (4)
Reaction of 1, 3-Dihalopropene with Trialkylmanganate (1998) (4)
Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material (2019) (4)
1,2-Migration of phosphorus-centered anions on ate-type copper carbenoids and its application for the synthesis of new potent phosphine ligands. (2005) (4)
5,5,15,15-Tetraoxo-5,15-Dithiaporphyrin as a Highly Electron-Deficient Porphyrinic Ligand. (2019) (4)
Stereoselective transformation of 1-alkeny ether (R1CH=CHOMe) into alkene (R1CH=CHR2) based on stereospecific elimination of the vicinal iodo(methoxy)alkane (1999) (4)
A new method for the synthesis of acyltitanium complexes and their application to copper-mediated acylmetallation of carbon-carbon multiple bonds in aqueous media. (2005) (3)
Synthesis of Hydroxyisooxophlorins by Oxidative Degradation of meso-Hydroxyporphyrins. (2019) (3)
Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s. (2019) (3)
Oxidation of hydroquinones with meso-hexakispentafluorophenyl [26]hexaphyrin(1.1.1.1.1.1). (2006) (3)
Stereospecific Conversion of Iodohydrin Derivatives into Alkenes by Means of an Allylsilane‐Titanium Tetrachloride System and Its Application to Stereoretentive Deoxygenation of Epoxides. (1997) (3)
Isolation and Structure Analysis of a Ni(II) Norcorrole Radical Anion (2022) (3)
A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles. (2021) (3)
Fully-substituted 1,3-Butadienes as π-Conjugated Linkers between Pyrenes (2016) (3)
Facile Synthesis of Nitrogen-containing Polycyclic Aromatic Hydrocarbons from Perylene Bisimides (2014) (3)
Synthesis of bright red-emissive dicyanoetheno-bridged hexa-peri-hexabenzocoronene dimers. (2017) (3)
Synthesis of Curved Hexa- peri -hexabenzocoronenes (2014) (3)
Antiaromatic 1,5-Diaza-s-indacenes. (2021) (3)
A Hexameric Porphyrin Triangle Constructed by Suzuki—Miyaura Cross‐Coupling Reaction. (2012) (2)
Innentitelbild: Metalation of Expanded Porphyrins: A Chemical Trigger Used To Produce Molecular Twisting and Möbius Aromaticity (Angew. Chem. 4/2008) (2008) (2)
Dinaphtho[1,8‐ bc :1′,8′‐ fg ][1,5]dithiocine Bisimide (2021) (2)
Diversity-Oriented Synthesis of Tetrathia[8]circulenes by Sequential C—H Borylation and Annulation. (2016) (2)
Efficient Pd(0)‐Catalyzed Hydrosilylation of Alkynes with Triorganosilanes. (2002) (2)
Selective Halogen—Magnesium Exchange Reaction via Organomagnesium Ate Complex. (2001) (2)
Dual-ion charge–discharge behaviors of Na–NiNc and NiNc–NiNc batteries (2021) (2)
Non-Planar Perylene Bisimide Analogues with Inserted Carbonyl and Methylene Subunits. (2021) (2)
A Heme-Acquisition Protein Reconstructed with a Cobalt 5-Oxaporphyrinium Cation and Its Growth-Inhibition Activity Toward Multidrug-Resistant Pseudomonas aeruginosa. (2021) (2)
Transition Metal Catalyzed Carbon—Carbon Bond Formation with Grignard Reagents — Novel Reactions with a Classic Reagent (2004) (2)
Et3B‐Induced Radical Addition of N,N‐Dichlorosulfonamide to Alkenes and Pyrrolidine Formation via Radical Annulation. (2003) (2)
Synthesis of Tetrasilatetrathia[8]circulenes through C–I and C–H Silylation (2021) (2)
Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst. (2017) (2)
Dual Emission of a Free‐Base 5‐Oxaporphyrinium Cation from its cis ‐ and trans ‐NH Tautomers (2020) (2)
Dual‐Ion NiNc Battery: A Sustainable Revolution for Sodium Organic Batteries (2021) (2)
TiCl4—n-Bu4NX (X: I, Br, and Cl) Combination-Induced Coupling of α,β-Unsaturated Ketones with Aldehydes. (2002) (2)
Iron(III) 5,15-Diazaporphyrin Catalysts for the Direct Oxidation of C(sp3)-H Bonds. (2020) (2)
Inside Cover: Metalation of Expanded Porphyrins: A Chemical Trigger Used To Produce Molecular Twisting and Möbius Aromaticity (Angew. Chem. Int. Ed. 4/2008) (2008) (2)
Quadruply BN-Fused Tetrathia[8]circulenes with Flexible Frameworks: Synthesis, Structures and Properties. (2021) (2)
Regioselective Double Cyclization of 5,15-Bis(trimethylsilylethynyl)porphyrin to Produce Di(oxoethano)porphyrin (2014) (2)
Intramolecular Tandem Michael‐Type Addition/Aldol Cyclization Induced by TiCl4—R4NX Combinations. (2003) (2)
Reaction of Titanate-Type Aldehyde Enolate with Ketones to Provide 3-Hydroxyaldehydes. (2000) (2)
Synthesis and electron-transport properties of a stable antiaromatic NiII norcorrole with the smallest meso-substituent. (2020) (2)
Synthesis of Novel Porphyrinoids through Organometallic Means (2014) (1)
Reaction of 1,3-Dihalopropene with Trialkylmanganate. (1998) (1)
Synthesis of Novel Porphyrinoids from Dipyrrins (2015) (1)
Halogen—Magnesium Exchange via Trialkylmagnesates for the Preparation of Aryl- and Alkenylmagnesium Reagents. (2000) (1)
Protonation-Induced Antiaromaticity in Octaaza[8]circulenes: Cyclooctatetraene Scaffolds Constrained with Four Amidine Moieties. (2022) (1)
Synthesis of Silyl Aziridines and α‐Amino Acylsilanes with Silyldibromomethyllithium. (2005) (1)
Acridino[2,1,9,8‐ klmna ]acridine Bisimides: An Electron‐Deficient π‐System for Robust Radical Anions and n‐Type Organic Semiconductors (2021) (1)
Regioselective Desilylation of a π-Extended Aza[5]helicene (2019) (1)
Triethylborane‐Induced Radical Addition of Halogenated Compounds to Alkenes and Alkynes in Water. (1999) (1)
Highly Stereoselective Coupling Reaction of Acrolein or Vinyl Ketone with Aldehydes. (2000) (1)
Enolate Formation from α-Iodoaldehydes and α-Iodoketones by Means of Allylsilane—Titanium Tetrachloride and Its Application to an Aldol Reaction. (1998) (1)
Cationic Nickel(II) Pyridinophane Complexes: Synthesis, Structures and Catalytic Activities for C–H Oxidation (2021) (1)
Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol. (2000) (1)
Peripherally Arylated 2,8-Diazaperylenes from Anthracene Diimide: Synthesis and Oxidative Annulation. (2021) (1)
Nitrogen Extrusion of Diazacorrphycenes to Azacorroles and Synthesis of Two Types of Copper 10-Azacorrole Complexes (2022) (1)
Enthalpically and Entropically Favorable Self-Assembly: Synthesis of C4h-Symmetric Tetraazatetrathia[8]circulenes by Regioselective Introduction of Pyridine Rings. (2020) (1)
Synthesis of Norbornane-BridgedDiporphyrins via Palladium-Catalyzed [3+2] AnnulationStrategy (2009) (1)
Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous Media. (2001) (1)
Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination. (2020) (1)
Complexation of 2,7-diazapyrene with boron for structural and electronic tuning. (2020) (1)
Triethylborane-induced hydrogermylation of alkenes with tri-2-furylgermane (2001) (1)
Realization of Stacked-Ring Aromaticity in a Water-Soluble Micellar Capsule (2022) (1)
Transformation of Zirconocene—Olefin Complexes into Zirconocene Allyl Hydride and Their Use as Dual Nucleophilic Reagents: Reactions with Acid Chloride and 1,4‐Diketone. (2004) (1)
Site-Selective N-Methylation of 5,15-Diazaporphyrins: Reactive Cationic Porphyrinoids that Provide Isoporphyrin Analogues. (2019) (1)
Macrocyclic dipyrrin dimer bridged by ethylene and dioxyphenylene linkers (2015) (1)
Triethylborane‐Mediated Atom Transfer Radical Cyclization Reaction in Water. (1999) (1)
D-Mannose-appended 5,15-diazaporphyrin for photodynamic therapy. (2022) (1)
Regioselective Functionalization of Perylene through C-HBond Activation (2009) (1)
Synthesis and Characterization of 16π Antiaromatic 2,7‐Dihydrodiazapyrenes: Antiaromatic Polycyclic Hydrocarbons with Embedded Nitrogen (2021) (1)
meso-Diazacorrphycenes: Neighboring Effect of Two Nitrogen Atoms. (2020) (1)
Synthesis of a Pyridine‐Fused Porphyrinoid: Oxopyridochlorin. (2009) (1)
Porphyrin Derivatives with Carbon—Metal Bonds (2010) (1)
Reaction of alpha,alpha-dibromo oxime ethers with Grignard reagents: alkylative annulation providing a pyrimidine core. (2002) (1)
Triethylborane‐Mediated Hydrogallation and Hydroindation: Novel Access to Organogalliums and Organoindiums. (2003) (1)
A 2-to-2' 18-to-18' doubly linked Ni(ii) norcorrole dimer: an effectively conjugated antiaromatic dyad. (2020) (1)
Preparation of α-Silyl- or α,α-Bis(silyl)-Substituted Alkylcopper Reagents and Their Synthetic Use. (2005) (0)
Preparation of Allylic Germanes with Tri(2-furyl)germane via π-Allylpalladium Species. (2003) (0)
Nucleophilic Addition of Tri-2-furylgermane to Aldehydes and α,β-Unsaturated Carbonyl Compounds in the Presence of a Catalytic Amount of Base. (2002) (0)
1,3-Butadiyne-Bridged Diporphyrins (2007) (0)
Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2‐Cyclohexen‐1‐one or Cyclohexanecarbaldehyde. (1998) (0)
Simple and Efficient TiCl4‐Mediated Synthesis of Biaryls via Arylmagnesium Compounds. (2001) (0)
CCDC 1542190: Experimental Crystal Structure Determination (2017) (0)
FACILE SYNTHESES OF ALPHA -BROMO-ALPHA -SILYL KETONES AND ALPHA -BROMOACYLSILANES FROM TERT-BUTYLDIMETHYLSILYLDIBROMOMETHANE AND CARBONYL COMPOUNDS (1996) (0)
Intramolecular Radical Cyclization of 2-Haloethanal Allyl Acetal and Allyl 2-Halophenyl Ether with a Grignard Reagent in the Presence of Iron(II) Chloride. (2010) (0)
Preparation of alpha-silyl- or alpha,alpha-bis(silyl)-substituted alkylcopper reagents and their synthetic use (2005) (0)
Preparation of Organomanganese Reagents from Organic Halides with Activated Manganese. (2010) (0)
Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s. (2019) (0)
Synthesis of Heteroatom-Containing Curved π-Conjugated Molecules (2018) (0)
An anti-aromaticapproach to enhanced molecular charge-transport (2016) (0)
Inside Cover: Control of Conformation and Chirality of Nonplanar π-Conjugated Diporphyrins Using Substituents and Axial Ligands (Chem. Asian J. 6/2016) (2016) (0)
Highly soluble Ni(II) dithienylnorcorrole (2022) (0)
Preparation of Alkyl Silyl Acetals from Carboxylic Esters with tert- Butyldimethylsilyldihalomethyllithium. 1,3-Rearrangement of Silyl Group from Carbon to Oxygen. (1995) (0)
Cover Feature: Enthalpically and Entropically Favorable Self‐Assembly: Synthesis of C 4 h ‐Symmetric Tetraazatetrathia[8]circulenes by Regioselective Introduction of Pyridine Rings (Chem. Eur. J. 18/2021) (2021) (0)
Solubilization and Optical Tuning of Graphene Quantum Dots through Decarboxylative-Arylation (2016) (0)
Generation and Regioselective Reactions of α,α-Bis(silyl)-substituted Allylcopper Reagents — Synthesis of 1,1-Disilylalkenes. (2002) (0)
Conversion of Acid Chloride into Homoallylic Alcohol via Allylic C—H Bond Activation of Alkene with a Zirconocene Complex. (2002) (0)
Triethylborane‐Induced Radical Allylation Reaction with Zirconocene—Olefin Complex. (2004) (0)
Lewis Acid-Induced Chemo- and Stereoselective Allylation of α-Iodo Mixed Acetal with Allylsilane. (1998) (0)
Invited) Strongly Antiaromatic Porphyrins with Singlet Biradical Character (2018) (0)
The importance of a beta-beta bond for long-range antiferromagnetic coupling in directly linked copper(II) and silver(II) diporphyrins. (2005) (0)
Norbornane-Bridged Diporphyrins (2009) (0)
Formation of Manganese—Alkyne Complexes Mediated by Trialkylmanganates and Their Application. (2004) (0)
Highly Diastereoselective Tandem Reduction—Allylation Reactions of 1,4-Diketones with Zirconocene—Olefin Complexes. (2003) (0)
Alkylative Preparation of alpha-Silylalkylmagnesium from R(3)SiCHBr(2) Using a Magnesate Reagent This work was supported by a Grant-in-Aid for Scientific Research (Nos. 09450341 and 10208208) from the Ministry of Education, Culture, Sports, Science, and Technology. A.I. acknowledges the JSPS Researc (2001) (0)
Rhodium‐Catalyzed [2 + 2 + 2] Cyclotrimerization in an Aqueous‐Organic Biphasic System. (2003) (0)
Remarkable Rate Acceleration of Pd(0)‐Catalyzed Hydrogermylation of Alkynes and Dienes in Water. (2001) (0)
New Method for the Preparation of an Active Manganese Species and Its Use for Radical Cyclization Reactions. (1999) (0)
Iron hexamesityl-5,15-diazaporphyrin: synthesis, structure and catalytic use for direct oxidation of sp3 C-H bonds. (2021) (0)
Inside Cover: Strategic Synthesis of 2,6‐Pyridylene‐Bridged β‐to‐β Porphyrin Nanorings through Cross‐Coupling (Chem. Eur. J. 10/2010) (2010) (0)
Diazazethrene bisimide: a strongly electron-accepting π-system synthesized via the incorporation of both imide substituents and imine-type nitrogen atoms into zethrene (2022) (0)
Sequential Carbon—Carbon Bond Formation Reaction Using 1‐Silyl‐2‐propenyllithium. (1998) (0)
Planarization of a Bowl-Shaped Molecule by Triple-Decker Stacking (2022) (0)
Invited) Synthesis and Properties of Antiaromatic Porphyrins (2016) (0)
Stereoselective Transformation of 1-Alkenyl Ether (R1CH=CHOMe) into Alkene (R1CH=CHR2) Based on Stereospecific Elimination of the Vicinal Iodo(methoxy)alkane. (1999) (0)
CCDC 1542192: Experimental Crystal Structure Determination (2017) (0)
TiCl4—n-Bu4NI as a Reducing Reagent: Pinacol Coupling and Enolate Formation from α-Haloketones. (2000) (0)
Facile Preparation of Vicinal Allylsiloxy‐ and Vinylsiloxyhaloalkanes and Their Radical Cyclization Reaction. (1998) (0)
Synthesis of Cyclopropanols via Cyclopropanation of Zinc Enolates. (1998) (0)
Innenrücktitelbild: Structures of the Heme Acquisition Protein HasA with Iron(III)‐5,15‐Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group (Angew. Chem. 48/2017) (2017) (0)
What's Cooking in Chemistry: Hiroshi Shinokubo (2013) (0)
Manganese‐Catalyzed Carbomagnesation of Alkynes (2004) (0)
Manganese-Catalyzed Phenylation of Acetylenic Compounds with a Phenyl Grignard Reagent. (2010) (0)
Triethylborane-Induced Radical Reactions with Gallium- and Indium Hydrides. (2003) (0)
Antiaromatic 1,5‐Diaza‐ s ‐indacenes (2021) (0)
Preparation of Allylic Germanes with Tri(2-furyl)germane via π-Allylpalladium Species (2002) (0)
Stepwise N-Methylation of Ruthenium and Cobalt 5,15-Diazaporphyrins: Post-Functionalization of Porphyrinoid Catalysts. (2022) (0)
Iodotrimethylsilane-Induced Cyclization of 6-Alkynal Acetals. (2010) (0)
Highly regioselective Ir-catalyzed beta-borylation of porphyrins via C-H bond activation and construction of beta-beta-linked diporphyrin. (2005) (0)
(Invited) Synthesis, Structures, and Properties of Stacked Antiaromatic Porphyrins (2017) (0)
Radical [3 + 2] Annulation of N-Allyl-N-chlorotosylamide with Alkenes via Atom-Transfer Process. (2010) (0)
Synthesis of Dibenzo[h,t]rubicene through Its Internally Dimethoxy-Substituted Precursor (2022) (0)
Reduction of Organic Halides with Tri‐2‐furanylgermane: Stoichiometric and Catalytic Reaction. (2010) (0)
Cover Picture: π‐Extended Dihydrophenazines with Three‐State NIR Electrochromism Involving Large Conformational Changes (Chem. Asian J. 17/2017) (2017) (0)
Et3B-Induced Hydrogermylation of Alkenes and Silyl Enol Ethers. (2000) (0)
Boron Trifluoride Catalyzed Reaction of Alkyl Fluoride with Silyl Enolate, Allylsilane, and Hydrosilane. (2004) (0)
Intermolecular Rhodium‐Catalyzed Carbometalation/Heck‐Type Reaction in Water. (2007) (0)
Water Enables Direct Use of Allyl Alcohol for Tsuji—Trost Reaction Without Activators. (2005) (0)
Photoindued Charge Separation of Directly Linked Zinc Porphyrin-Fullerene Dyads (2008) (0)
Base‐Induced Condensation of α‐Chloro Oxime Derivatives Furnishes Alkynes. (2004) (0)
A New Method for the Synthesis of Acyltitanium Complexes and Their Application to Copper‐Mediated Acylmetalation of Carbon—Carbon Multiple Bonds in Aqueous Media. (2005) (0)
Inside Back Cover: Intermolecular Oxidative Annulation of 2‐Aminoanthracenes to Diazaacenes and Aza[7]helicenes (Angew. Chem. Int. Ed. 41/2012) (2012) (0)
Cover Picture: meso‐Aryl Substituted Rubyrin and Its Higher Homologues: Structural Characterization and Chemical Properties (Chem. Eur. J. 9/2008) (2008) (0)
Synthesis, Properties, and Reactivities of Ruthenium(II) Carbonyl 5,15-Diazaporphyrins (2017) (0)
Synthesis of Cyclopropanes via Iodine—Magnesium Exchange Between 3-Iodomethyl-1-oxacyclopentanes and Organomagnesium Reagents. (2004) (0)
Reaction of gem-Dibromocyclopropanes or Iodobenzofuran with Trialkylmanganate. (2000) (0)
Allylation of Carbonyl Compounds with Allylic Gallium Reagents. (2002) (0)
Synthesis and Biradicaloid Character of Doubly Linked Corrole Dimers (2006) (0)
Indeno[1,2,3,4-pqra]perylene: A Medium-Sized Aromatic Hydrocarbon Exhibiting Full-Range Visible-Light Absorption. (2021) (0)
Reaction of Trialkyl(dibromomethyl)silanes or 1,2‐Bis(dibromomethyl)benzene with Triorganomanganates. A Facile and Selective Synthesis of Alkenylsilanes and 1,2‐Diaryl‐1,2‐dihydrobenzocyclobutenes. (2000) (0)
Generation of Allylic Manganates from Trimethylmanganate and Allylic Stannanes and Their Reactions with Epoxides. (2010) (0)
Highly Selective Cleavage of Prenyl Ethers by Means of a TiCl4-n-Bu4NI Mixed Reagent. (2000) (0)
A Facile Preparation of Alkenyl- and Allenylmetallic Compounds by Means of Iodine-Metal Exchange and Their Use in Organic Synthesis. (1996) (0)
Intramolecular Aryl Migration from Tin to Carbon via a Radical Atom‐Transfer Process. (2000) (0)
Frontispiece: 10‐Silacorroles Exhibiting Near‐Infrared Absorption and Emission (2017) (0)
Front Cover: Regioselective Oxidative Ring Cleavage of Antiaromatic Nickel(II) Norcorrole to Dialkoxybis(dipyrrin)s (ChemPlusChem 6/2019) (2019) (0)
Manganese(III) 5,15-diazaporphyrins: Synthesis, properties, and catalytic use for benzylic C–H fluorination (2021) (0)
Regioselective Reaction of Dilithiated 1-Alkynylsilanol with Electrophiles. (1999) (0)
Inside Cover: Pyrrole‐Bridged Porphyrin Nanorings (Chem. Eur. J. 45/2010) (2010) (0)
Tributylmanganate(II)‐Mediated Cyclization of Enynes. (2001) (0)
5-Thiaporphyrinium cation: effect of sulphur incorporation on excited state dynamics. (2022) (0)
Radical Addition of Triphenylgermane to Vinyloxiranes: Its Application to Synthesis of 4-Vinyltetrahydro-2-furanones. (2010) (0)
Facile Synthesis of Ketones from 1,1‐Disilylethenes via Oxidation of gem‐Disilylalkanes. (2002) (0)
A Highly Effective Aldol Reaction Mediated by Ti(O‐n‐Bu)4/t‐BuOK Combined Reagent. (2000) (0)
Redox-induced reversible [2 + 2] cycloaddition of an etheno-fused diporphyrin† (2021) (0)
Synthesis and Properties of 10-Heterocorroles (2017) (0)
A Room Temperature Preparation of Alkenyllithiums by Lithium-Halogen Exchange between Alkenyl Iodides and n-BuLi in Hydrocarbon Solvents. (1994) (0)
Stereoselective Allylation of Acetals Through Intramolecular Transfer of an Allylsilane. (1999) (0)
Preparation of Tributylstannylmanganate and Its Addition to Propargylic Alcohols with High Regio- and Stereoselectivities. (1999) (0)
Cover Feature: meso ‐Diazacorrphycenes: Neighboring Effect of Two Nitrogen Atoms (Chem. Eur. J. 37/2020) (2020) (0)
Radical Cyclization of N‐Allyl‐2‐halo Amide in Water. (2001) (0)
Bringing Porphyrine into the NIR Region (2009) (0)
Synthesis of Nitrogen-Embedded Curved-π Molecule and Its Association with C 60 (2016) (0)
Direct Preparation of Allylic Zirconium Reagents from Zirconocene—Olefin Complexes and Alkenes. (2004) (0)
One-dimensional stacking array of 10,20-diphenyl-5,15-diazaporphyrin metal complexes (2022) (0)
A Room Temperature Kharasch Reaction Catalyzed by Pd(0) in a Heterogeneous Aqueous System. (2010) (0)
Novel [2 + 2 + 2] Annulation of 1,6‐Diynes Mediated by Methallylchromate or Methallylmagnesium Chloride under CrCl3 Catalysis. (2001) (0)
Facile Syntheses of α-Bromo-α-silyl Ketones and α- Bromoacylsilanes from tert-Butyldimethylsilyldibromomethane and Carbonyl Compounds. (1997) (0)
Triallylmanganate-Mediated Cyclization of Diyne, Enyne, and Diene. An Unprecedented Bicyclization Reaction into Bicyclo[5.3.0]decane and Bicyclo[4.3.0]nonane Skeletons. (2010) (0)
One‐Pot Synthesis of α,β‐Unsaturated Ketones from tert‐ Butyldimethylsilyldibromomethane and Two Different Aldehydes. (1994) (0)
Inside Back Cover: Structures of the Heme Acquisition Protein HasA with Iron(III)‐5,15‐Diphenylporphyrin and Derivatives Thereof as an Artificial Prosthetic Group (Angew. Chem. Int. Ed. 48/2017) (2017) (0)
Oxidative Heck-Type Reaction Involving Cleavage of a Carbon—Phosphorus Bond of Arylphosphonic Acids. (2003) (0)
Non‐Planar Perylene Bisimide Analogues with Inserted Carbonyl and Methylene Subunits (2021) (0)
Triethylborane‐Induced Radical Reactions with Gallium Hydride Reagent HGaCl2. (2001) (0)
Easily Switchable 18π-, 19π-, and 20π-Conjugation of Diazaporphyrin Double-Pincer Bispalladium Complexes. (2023) (0)
Chemistry of a Stable Singlet Biradical (2009) (0)
A New Strategy for the Preparation of an Active Mn(0) and Its Use for Radical Cyclization Reactions. (1999) (0)
tert‐Butyldimethylsilyldichloromethyllithium as a Dichloromethylene Dianion Synthon. 1,3‐Rearrangement of Silyl Group from Carbon to Oxide. (1993) (0)
Enolate Formation from Cyclopropyl Ketones via Iodide-Induced Ring Opening and Its Use for Stereoselective Aldol Reaction. (2001) (0)
Synthesis of Pyrimidines via Base-Induced Condensation of α-Chloro Oxime Derivatives. (2004) (0)
Radical Cyclization of Allyl 2‐Iodophenyl Ether, N,N‐Diallyl‐2‐iodoaniline, and 2‐Iodoethanal Acetal by Means of Trialkylmanganate(II). (1998) (0)
Dinaphthooxepine Bisimide Undergoes Oxygen Extrusion Reaction upon Electron Injection at Room Temperature. (2023) (0)
Cover Feature: Theoretical Study on Open-Shell Singlet Character and Second Hyperpolarizabilities in Cofacial π-Stacked Dimers Composed of Weak Open-Shell Antiaromatic Porphyrins (ChemPhysChem 21/2018) (2018) (0)
Radical Addition of α‐Halo Ester to Homoallylic Gallium or Indium Species: Formation of Cyclopropane Derivatives. (2002) (0)
Cover Feature: Dual‐Ion NiNc Battery: A Sustainable Revolution for Sodium Organic Batteries (Batteries & Supercaps 10/2021) (2021) (0)
Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo Carbonyl Compounds. (2003) (0)
Studies on Sequential Carbon-Carbon Bond Formation Reaction Using Silyldihalomethyllithium (1998) (0)
Reaction of tert‐Butyl Dibromoacetate or N,N‐Diethyldibromoacetamide with Trialkylmanganate Providing an Alkylated Manganese Enolate. (1998) (0)
An Unprecedented Coupling Reaction of Arylmagnesium Compounds with Tetrahydrofuran Providing 2‐Aryltetrahydrofuran Mediated by a Iodoalkane—EtMgBr System. (2000) (0)
Indolylindolinone: Easily Accessible, Tunable, and Wide‐Range Absorbing Dyes. (2016) (0)
ChemInform Abstract: Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator in Aqueous Media: Facile Synthesis of γ-Lactones. (2002) (0)
Synthesis and properties of 5-aza-15-thiaporphyrins (2020) (0)
Symmetry-breaking charge separation in a nitrogen-bridged naphthalene monoimide dimer. (2022) (0)
Metalation-Triggered Möbius Aromaticity (2008) (0)
Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenols Using a Water-Soluble Radical Initiator in Water. A Facile Synthesis of γ-Lactones. (1999) (0)
Innenrücktitelbild: Intermolecular Oxidative Annulation of 2‐Aminoanthracenes to Diazaacenes and Aza[7]helicenes (Angew. Chem. 41/2012) (2012) (0)
PALLADIUM-CATALYZED [3+2] ANNULATION OF meso-BROMOPORPHYRINS WITH SILYLACETYLENES AND DESILYLATION OF 8[a]-SILYL-7,8-DEHYDROPURPURIN (Dedicated to Professor Isao Kuwajima on the occasion of his 77th birthday) (2015) (0)
γ‐Regioselective Reaction of Metaloxysilyl‐Substituted Allyllithium Derived from Allyldiphenylsilanol. (1997) (0)
Phosphane-Free Rhodium Catalyst in an Anionic Micellar System for [4 + 2] Annulation of Dienynes. (2004) (0)
Intramolecular Iodosilyletherization of Alkenylsilanols with Bis(2,4,6‐ trimethylpyridine)iodine(I) Hexafluorophosphate. (1996) (0)
Near-Infrared-Responsive Hydrocarbons Designed by π-Extension of Indeno[1,2,3,4-pgra]perylene at the 1,2,12-Positions. (2023) (0)
Triethylborane Induced Radical Reaction of Gallium Enolates with α‐Halo Esters. (2003) (0)
Diverse Crystal Structures of Ion Pairs Consisting of Oxaporphyrinium Cations and Pentacyanocyclopentadienide (2022) (0)
Reaction of Silyldihalomethyllithiums with Nitriles: Formation of α-Keto Acylsilanes via Azirines and 1,3-Rearrangement of Silyl Group from C to N. (2004) (0)
Manganese(II) Chloride-Catalyzed Alkylmagnesation of 2-Alkynylphenol. (2010) (0)
Transformation of Tetrahydropyranyl Ether of Allylic Alcohol into 7-Octene-1,5-diol by Means of Trialkylmanganate. (1999) (0)
Trialkylmanganate-Induced Cyclization of Allyl 2-Iodophenyl Ether, N,N-Diallyl-2-iodoaniline, and α-Iodo Acetal. (1997) (0)
Gram‐Scale Diversity‐Oriented Synthesis of Dinaphthothiepine Bisimides as Soluble Precursors for Perylene Bisimides (2022) (0)
Reactions of gem‐Dibromo Compounds with Trialkylmagnesate Reagents to Yield Alkylated Organomagnesium Compounds. (2002) (0)
CCDC 843982: Experimental Crystal Structure Determination (2011) (0)
tert-Butyldimethylsilyldihalomethyllithium as a Dihalomethylene Dianion Synthon. 1,3-Rearrangement and 1,4-Rearrangement of Silyl Group from Carbon to Oxide. (2010) (0)
CCDC 1542191: Experimental Crystal Structure Determination (2017) (0)
Synthetic Protocol for Diarylethenes Through Suzuki—Miyaura Coupling. (2011) (0)
Rearrangement of β-tert-Butyldimethylsiloxy Carbenoids. Regio- and Stereoselective Synthesis of Z-1-Halo-2-tert-butyldimethylsiloxy-1- alkenes. (1993) (0)
Marriage of Porphyrin Chemistry with Metal‐Catalyzed Reactions (2009) (0)
CCDC 843983: Experimental Crystal Structure Determination (2011) (0)
Fused Porphyrin Rings (2010) (0)
Dialkylation of gem‐Dibromocyclopropanes with Trialkylmanganate and Manganese(II) Chloride‐Catalyzed Reaction with Alkylmagnesium Bromide. (1996) (0)
Base-induced condensation of alpha-chloro oxime derivatives furnishes alkynes. (2003) (0)
Alkylative Preparation of α-Silylalkylmagnesium from R3SiCHBr2 Using a Magnesate Reagent. (2001) (0)
Synthesis of Medium- and Large-Sized Lactones in an Aqueous—Organic Biphasic System. (2005) (0)
Pd(0)‐Catalyzed Reaction of Alkynes with Trifurylgermane and CO Providing Acylgermanes: The Example of Hydrometalcarbonylation of Alkynes. (2002) (0)
Synthesis of Trisubstituted and Tetrasubstituted Alkenes via a Manganate‐Induced Migration—Elimination Process. (2002) (0)
Allylmanganation and Diallylation of Acetylenic Compounds. (1997) (0)
Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals. (2000) (0)
ChemInform Abstract: Coupling of Vinylcyclopropanes with Aldehydes Induced by a TiCl4/n-Bu4NI Combination: Synthesis of Conjugated Dienols. (2002) (0)
Cover Picture: Regioselective Borylation of Porphyrins by CH Bond Activation under Iridium Catalysis to Afford Useful Building Blocks for Porphyrin Assemblies (Chem. Asian J. 7/2007) (2007) (0)
A Facile Synthesis of 1,1‐Disilylethenes via Me3MgLi‐Induced Monomethylation of Dibromodisilylmethanes. (2002) (0)
Manganese‐Catalyzed Reaction of gem‐Dibromoalkanes with Grignard Reagents. Selective Synthesis of Alkenylsilanes. (1997) (0)
A Supramolecular Polymer Constituted of Antiaromatic Ni(II) Norcorroles (2021) (0)
Synthesis and Tautomerization of 5-Azaporphyrinium Cations (2022) (0)
Manganese‐Catalyzed Silylmagnesiation of Acetylenes and 1,3‐Dienes. (1997) (0)
Frontispiece: Synthesis of Tetrasilatetrathia[8]circulenes by a Fourfold Intramolecular Dehydrogenative Silylation of C−H Bonds (2017) (0)
Photoinduced Charge Separation of Directly Linked Porphyrin- and Phthalocyanine-Fullerene Dyads (2009) (0)
Selective Oxidation of Propargylic Alcohols into α,β‐Acetylenic Aldehydes with a TiCl4/Et3N System. (2001) (0)

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What Schools Are Affiliated With Hiroshi Shinokubo?

Hiroshi Shinokubo is affiliated with the following schools:

University of Tokyo
Nagoya University
Institute of Science Tokyo
Massachusetts Institute of Technology
Kyoto University