Holger Braunschweig
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German chemist
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Holger Braunschweigchemistry Degrees
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Chemistry
Holger Braunschweig's Degrees
- PhD Chemistry University of Würzburg
Why Is Holger Braunschweig Influential?
(Suggest an Edit or Addition)According to Wikipedia, Holger Braunschweig is Head and Chair of Inorganic Chemistry at the Julius-Maximilians-University of Würzburg in Würzburg, Germany. He is best known for founding the field of transition metal-boron multiple bonding , the synthesis of the first stable compounds containing boron-boron and boron-oxygen triple bonds, the isolation of the first non-carbon/nitrogen main-group dicarbonyl, and the first fixation of dinitrogen at an element of the p-block of the periodic table. By modifying a strategy pioneered by Prof. Gregory Robinson of the University of Georgia, Braunschweig also discovered the first rational and high-yield synthesis of neutral compounds containing boron-boron double bonds . In 2016 Braunschweig isolated the first compounds of beryllium in the oxidation state of zero.
Holger Braunschweig's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Nitrogen fixation and reduction at boron (2018) (654)
- High-performance air-stable n-channel organic thin film transistors based on halogenated perylene bisimide semiconductors. (2009) (553)
- Electron-precise coordination modes of boron-centered ligands. (2010) (423)
- Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond (2012) (415)
- Transition-metal complexes of boron-new insights and novel coordination modes. (2006) (269)
- Transition metal complexes of boron — synthesis, structure and reactivity (2001) (266)
- Multiple complexation of CO and related ligands to a main-group element (2015) (219)
- Outstanding short-circuit currents in BHJ solar cells based on NIR-absorbing acceptor-substituted squaraines. (2009) (217)
- Transition metal complexes of boron (1998) (215)
- Constrained geometry complexes—Synthesis and applications (2006) (209)
- Metal-only Lewis pairs with transition metal lewis bases. (2012) (188)
- Recent developments in the chemistry of antiaromatic boroles. (2011) (180)
- Synthesis and structure of a carbene-stabilized pi-boryl anion. (2010) (167)
- Single, double, triple bonds and chains: the formation of electron-precise B-B bonds. (2013) (165)
- Transition metal borylene complexes. (2013) (163)
- Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds. (2017) (163)
- Transition metals as Lewis bases: "Z-type" boron ligands and metal-to-boron dative bonding. (2011) (152)
- Oxoboryl Complexes: Boron−Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum (2010) (145)
- Synthesis and Structure of the First Terminal Borylene Complexes. (1998) (143)
- Structural evidence for antiaromaticity in free boroles. (2008) (138)
- sp(2)-sp(3) diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis. (2015) (136)
- Übergangsmetallkomplexe des Bors – Neue Erkenntnisse und neuartige Koordinationstypen (2006) (128)
- Metallomimetic Chemistry of Boron. (2019) (124)
- Übergangsmetallkomplexe des Bors (1998) (123)
- Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond. (2013) (122)
- The reductive coupling of dinitrogen (2019) (122)
- Base-stabilized diborenes: selective generation and η2 side-on coordination to silver(I). (2012) (119)
- An isolable radical anion based on the borole framework. (2012) (117)
- Neutral zero-valent s-block complexes with strong multiple bonding. (2016) (117)
- Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene. (2014) (114)
- Generation of a carbene-stabilized bora-borylene and its insertion into a C-H bond. (2011) (112)
- Recent Developments in Azaborinine Chemistry (2017) (112)
- Bond-strengthening π backdonation in a transition-metal π-diborene complex. (2013) (111)
- Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron. (2017) (110)
- Trapping the elusive parent borylene. (2011) (109)
- Electron Delocalization in Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene. (2015) (109)
- Synthesis and Structure of the First Transition Metal Borylene Complexes (1995) (106)
- Direct hydroboration of B=B bonds: a mild strategy for the proliferation of B-B bonds. (2014) (106)
- Synthesis, Electronic Structure, and Novel Reactivity of Strained, Boron-Bridged [1]Ferrocenophanes (2000) (104)
- Boron radical cations from the facile oxidation of electron-rich diborenes. (2014) (102)
- Boron as a powerful reductant: synthesis of a stable boron-centered radical-anion radical-cation pair. (2015) (102)
- Antiaromaticity to aromaticity: from boroles to 1,2-azaborinines by ring expansion with azides. (2014) (100)
- Borylenes as Ligands to Transition Metals (2004) (98)
- Interaction between d- and p-block metals: synthesis and structure of platinum-alane adducts. (2007) (97)
- Synthese und Struktur der ersten terminalen Borylenkomplexe (1998) (97)
- Boron–Boron Multiple Bonding: From Charged to Neutral and Back Again (2014) (96)
- Metal-mediated synthesis of 1,4-di-tert-butyl-1,4-azaborine. (2012) (96)
- Evidence for extensive single-electron-transfer chemistry in boryl anions: isolation and reactivity of a neutral borole radical. (2014) (96)
- A T-shaped platinum(II) boryl complex as the precursor to a platinum compound with a base-stabilized borylene ligand. (2005) (94)
- The Chemistry of Borylene Complexes (2003) (93)
- Experimental studies on the trans-influence of boryl ligands in square-planar platinum(II) complexes. (2007) (93)
- Boron: Its Role in Energy‐Related Processes and Applications (2020) (92)
- Controlled homocatenation of boron on a transition metal. (2012) (90)
- Synthese und Reaktivität von Verbindungen mit elektronenpräzisen B‐B‐Einfach‐ und B‐B‐Mehrfachbindungen (2017) (90)
- Formation of BN Isosteres of Azo Dyes by Ring Expansion of Boroles with Azides. (2015) (90)
- Experimental assessment of the strengths of B-B triple bonds. (2015) (88)
- The Synthesis of B2(SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes. (2015) (86)
- Synthese und Struktur der ersten Borylenübergangsmetallkomplexe (1995) (83)
- Einfach-, Doppel-, Dreifachbindungen und Ketten: Knüpfung elektronenpräziser B-B-Bindungen (2013) (82)
- Selective Photocatalytic C-F Borylation of Polyfluoroarenes by Rh/Ni Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters. (2018) (81)
- Reactivity of terminal transition metal borylene complexes (2005) (81)
- Terminal Borylene Complexes as a Source for the Borylene B-N(SiMe(3))(2): Alternative Synthesis and Structure of (2001) (81)
- Synthesis and Characterisation of N,N′‐Disubstituted 1,2‐phenylenebis(amido)tin(II) Compounds; X‐Ray structures of 1,2‐ and of [1,2‐ (tmeda) (1995) (81)
- Synthesis of borirenes by photochemical borylene transfer from [(OC)5M==BN(SiMe3)2] (M=Cr, Mo) to alkynes. (2005) (80)
- Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds. (2016) (80)
- Non-iron [n]metalloarenophanes. (2010) (79)
- [(η5‐C5H5)(OC)3VBN(SiMe3)2: A Half‐Sandwich Complex with a Terminal Borylene Ligand (2003) (78)
- Synthese und Struktur eines Carben‐stabilisierten π‐Boryl‐Anions (2010) (78)
- The pentaphenylborole-2,6-lutidine adduct: a system with unusual thermochromic and photochromic properties. (2011) (78)
- From an electron-rich bis(boraketenimine) to an electron-poor diborene. (2015) (77)
- Direct functionalization at the boron center of antiaromatic chloroborole. (2008) (77)
- Metal-mediated diboration of alkynes with [2]borametalloarenophanes under stoichiometric, homogeneous, and heterogeneous conditions. (2006) (76)
- Complexes with dative bonds between d- and s-block metals: synthesis and structure of [(Cy3P)2Pt-Be(Cl)X] (X = Cl, Me). (2009) (76)
- A linear, anionic dimetalloborylene complex. (2008) (75)
- Impact of molecular flexibility on binding strength and self-sorting of chiral π-surfaces. (2011) (75)
- Direct synthetic route to functionalized 1,2-azaborinines. (2014) (75)
- Terminal borylene complexes stabilized by a transition-metal base. (2005) (73)
- Borylene-based direct functionalization of organic substrates: synthesis, characterization, and photophysical properties of novel pi-conjugated borirenes. (2009) (71)
- Introducing [Mn(CO)3(tpa-κ(3)N)](+) as a novel photoactivatable CO-releasing molecule with well-defined iCORM intermediates - synthesis, spectroscopy, and antibacterial activity. (2014) (71)
- The reduction chemistry of ferrocenylborole. (2010) (70)
- Reactivity of Pt0 complexes toward gallium(III) halides: synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0. (2008) (70)
- Incorporation of a First Row Element into the Bridge of a Strained Metallocenophane: Synthesis of a Boron‐Bridged [1]Ferrocenophane (1997) (70)
- Boron in the coordination spheres of three transition-metal atoms: syntheses and structures of metalloborylenes stabilized by a transition-metal base. (2006) (69)
- Aminoborylene complexes of group 6 elements and iron: a synthetic, structural, and quantum chemical study. (2007) (69)
- The Chemistry of Bridged Borylene Complexes (2000) (68)
- Axially chiral beta,beta'-bisporphyrins: synthesis and configurational stability tuned by the central metals. (2008) (68)
- Pyrene Molecular Orbital Shuffle-Controlling Excited State and Redox Properties by Changing the Nature of the Frontier Orbitals. (2017) (67)
- Chemical reduction and dimerization of 1-chloro-2,3,4,5-tetraphenylborole. (2010) (67)
- Borylene Transfer from Transition Metal Borylene Complexes (2008) (67)
- Late-transition-metal complexes as tunable Lewis bases. (2010) (66)
- Lithiumboryl--a synthon for a nucleophilic boryl anion. (2007) (65)
- Synthesis and characterization of palladium and platinum iminoboryl complexes. (2005) (65)
- Synthesis and electronic structure of a terminal alkylborylene complex. (2007) (64)
- 1-Heteroaromatic-substituted tetraphenylboroles: π-π interactions between aromatic and antiaromatic rings through a B-C bond. (2012) (63)
- Synthesis, structure and reactivity of complexes containing a transition metal–bismuth bond (2011) (63)
- Ein T‐förmiger Platin(II)borylkomplex als Vorstufe für einen Platinkomplex mit einem basenstabilisierten Borylenliganden (2005) (63)
- Selektive Herstellung Basen‐stabilisierter Diborene und deren η2‐Side‐on‐Koordination an Silber(I) (2012) (62)
- Photoinduced Borylation for the Synthesis of Organoboron Compounds. (2021) (62)
- [(OC)5 Cr=BSi(SiMe3 )3 ]: A Terminal Borylene Complex with an Electronically Unsaturated Boron Atom. (2001) (62)
- T-shaped platinum boryl complexes: synthesis and structure. (2008) (62)
- Quaternizing diboranes(4): highly divergent outcomes and an inorganic Wagner-Meerwein rearrangement. (2013) (62)
- Bor‐Radikalkationen durch Oxidation elektronenreicher Diborene (2014) (62)
- Synthesis of ansa-[2]boracyclopentadienylcycloheptatrienylchromium and its reaction to the ansa-platinabis(boryl) complex by oxidative addition of the boron-boron bond. (2005) (61)
- Unwinding Antiaromaticity in 1-Bromo-2,3,4,5-tetraphenylborole (2011) (60)
- Reversible photochemical and thermal isomerization of azaboratabisnorcaradiene to azaborabenzotropilidene. (2014) (60)
- Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles (2015) (59)
- Convenient synthesis of K[(C5H4MeMnH(CO)2] and reactions with Cl2B[N(SiMe3)2] and B2R2Cl2 (R = Me2N, Me3C) (1997) (59)
- Molecular structure and cluster formation of a tert-butylborylene complex. (2006) (59)
- Direkte Hydroborierung von BB‐Bindungen: eine milde Methode zum Aufbau von BB‐Bindungen (2014) (58)
- Facile Syntheses of Trovacene, the Formation of [n]Boratrovacenophanes (n = 1, 2), and Their Reactivity toward [Pt(PEt3)4] (2006) (58)
- Synthesis and reactivity studies of iminoboryl complexes. (2008) (58)
- Struktureller Nachweis der Antiaromatizität in freien Borolen (2008) (58)
- Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition. (2016) (58)
- A boryl bridged complex: an unusual coordination mode of the BR2 ligand. (2005) (57)
- Synthesis and structure of [Cr{(η6-C6H5)2B{NtBu(SiMe3)}}] and [Cr{(η6-C6H5)2(BNMe2)2}], the first boron-bridged metalloarenophanes (2004) (57)
- Observation of elementary steps in the catalytic borane dehydrocoupling reaction. (2012) (57)
- Platinum substituted boroles. (2010) (57)
- Highly Strained Heterocycles Constructed from Boron-Boron Multiple Bonds and Heavy Chalcogens. (2016) (57)
- NHC-stabilized 1-hydro-1H-borole and its nondegenerate sigmatropic isomers. (2011) (56)
- Preparation and Structural Characterization of Transition Metal Complexes Featuring the Ferrocenyl(bromo)boryl Ligand (2004) (56)
- [(η5‐C5H5)(OC)3VBN(SiMe3)2]: ein Halbsandwichkomplex mit einem terminalen Borylenliganden (2003) (56)
- From classical to nonclassical metal-boron bonds: synthesis of a novel metallaborane. (2002) (55)
- Perylene Bisimide Radicals and Biradicals: Synthesis and Molecular Properties. (2015) (54)
- Borylene transfer under thermal conditions: synthesis and structure of a tetrarhodium bisborylene complex. (2006) (54)
- A New Perspective on Borane Chemistry: The Nucleophilicity of the B-H Bonding Pair Electrons. (2019) (54)
- Terminale Borylenkomplexe als Quelle für das Borylen B−N(SiMe3)2: alternative Synthese und Struktur von [(OC)5Cr=B=N(SiMe3)2] (2001) (54)
- Synthesis and electronic structure of a ferroborirene. (2007) (54)
- Synthesis of ansa-[n]silacyclopentadienyl-cycloheptatrienyl-chromium complexes (n = 1, 2): novel precursors for polymers bearing chromium in the backbone. (2006) (54)
- Synthesis and structure of a cationic platinum borylene complex. (2007) (54)
- B═B and B≡E (E = N and o) multiple bonds in the coordination sphere of late transition metals. (2014) (53)
- Boron as a bridging ligand. (2005) (53)
- Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square. (2016) (53)
- Synthese und Charakterisierung von bergangsmetallbase-stabilisierten terminalen Borylenkomplexen (2005) (53)
- Heterodinuclear bridged borylene complexes. (2005) (53)
- CO2 Binding and Splitting by Boron-Boron Multiple Bonds. (2018) (53)
- Diborabutatrien: ein elektronenarmes Cumulen (2014) (53)
- Reactivity of a Dihydrodiborene with CO: Coordination, Insertion, Cleavage, and Spontaneous Formation of a Cyclic Alkyne. (2017) (52)
- Electron-density investigation of metal-metal bonding in the dinuclear "borylene" complex [{Cp(CO)2Mn}2(mu-BtBu)]. (2008) (52)
- Transition-metal-catalyzed synthesis of diboranes(4). (2011) (52)
- Borylene metathesis through [2+2] cycloaddition. (2007) (52)
- Boron as a bridging ligand. (2005) (51)
- Synthese von Borirenen durch photochemischen Borylentransfer von [(OC)5MBN(SiMe3)2] (M=Cr, Mo) auf Alkine (2005) (51)
- Multiple reduction of 2,5-bis(borolyl)thiophene: isolation of a negative bipolaron by comproportionation. (2013) (51)
- Zur Addition von Alkyldichlorboranen an Bis(η5‐cyclopentadienyl)dihydridowolfram (1994) (50)
- Diboran(4)yl Groups as Ligands to Transition Metals (1996) (50)
- Monoborane NHC Adducts in the Coordination Sphere of Transition Metals (2010) (50)
- Recent advances in boron-centered ligands and their transition metal complexes (2019) (49)
- Bor in der Koordinationssphäre von drei Übergangsmetallen – Synthese und Strukturen von Metall‐Base‐stabilisierten Metalloborylenkomplexen (2006) (49)
- Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base. (2016) (49)
- Ein isolierbares Borol‐basiertes Radikalanion (2012) (48)
- Unexpected luminescence behavior of coinage metal π-diborene complexes. (2015) (48)
- Bor als verbrückender Ligand (2005) (48)
- Preparation, Properties, and Structures of the Radical Anions and Dianions of Azapentacenes. (2017) (47)
- [(OC)5Cr=BSi(SiMe3)3]: Ein terminaler Borylenkomplex mit elektronisch ungesättigtem Boratom (2001) (47)
- Bor als überaus starkes Reduktionsmittel: Synthese eines Bor‐ zentrierten Radikalanionen‐Radikalkationen‐Paares (2015) (46)
- A trimetallic gold boride complex with a fluxional gold-boron bond. (2009) (46)
- Jozimine A2: the first dimeric Dioncophyllaceae-type naphthylisoquinoline alkaloid, with three chiral axes and high antiplasmodial activity. (2013) (46)
- Unprecedented Borane, Diborane(3), Diborene, and Borylene Ligands via Pt-Mediated Borane Dehydrogenation. (2016) (46)
- Metall‐vermittelte Synthese von 1,4‐Di‐tert‐butyl‐1,4‐azaborin (2012) (46)
- Stepwise intermetal borylene transfer: synthesis and structure of mono- and dinuclear cobalt-borylene complexes. (2007) (46)
- Die Synthese von B2(SIDip)2 und seine Reaktivität zwischen denen von Diboracumulenen und Diborinen (2015) (45)
- The first silyl- and germylboryl complexes: synthesis from novel (dichloro)silyl- and (dichloro)germylboranes, structure and reactivity (2002) (45)
- Synthesis of cyclic diborenes with unprecedented cis-configuration. (2015) (45)
- Boryl‐ and Bridging Boryleneiron Complexes from Aminodichloroboranes (1998) (45)
- Selective dimetalation of [Mn(eta5-C5H5)(eta6-C6H6)]: crystal structure and conversion to strained [n]metalloarenophanes. (2007) (45)
- Cyclodimerization of an oxoboryl complex induced by trans ligand abstraction. (2010) (45)
- Free Boroles: The Effect of Antiaromaticity on Their Physical Properties and Chemical Reactivity (2013) (45)
- The reactivities of iminoboranes with carbenes: BN isosteres of carbene-alkyne adducts. (2015) (44)
- Ring Expansions of Boroles with Diazo Compounds: Steric Control of C or N Insertion and Aromatic/Nonaromatic Products. (2015) (44)
- Reactivity of transition-metal borylene complexes: recent advances in B-C and B-B bond formation via borylene ligand coupling. (2015) (44)
- High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex. (2012) (44)
- Synthesis, reactivity, and electronic structure of [n]vanadoarenophanes: an experimental and theoretical study. (2008) (43)
- Unsymmetrical, Cyclic Diborenes and Thermal Rearrangement to a Borylborylene. (2018) (43)
- Ein linearer anionischer Dimetallborylenkomplex (2008) (43)
- Isolierung eines neutralen, Bor‐haltigen Radikals, stabilisiert durch ein cyclisches (Alkyl)(amino)carben (2014) (43)
- Reactivity of a terminal chromium borylene complex towards olefins: insertion of a borylene into a C-H bond. (2008) (43)
- Building Electron‐Precise BoronBoron Single Bonds: Imposing Monogamy on a Promiscuous Element (2015) (43)
- Isolation of diborenes and their 90°-twisted diradical congeners (2018) (42)
- Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds. (2015) (42)
- Synthese von ansa‐[2]Boracyclopentadienylcycloheptatrienylchrom und Reaktion zum ansa‐Platinabis(boryl)‐Komplex durch oxidative Addition der Bor‐Bor‐Bindung (2005) (42)
- Ditopic ambiphilicity of an anionic dimetalloborylene complex. (2013) (42)
- Beryllium bis(diazaborolyl): old neighbors finally shake hands. (2015) (41)
- Interaction of (benzylidene-hydrazono)-1,4-dihydropyridines with beta-amyloid, acetylcholine, and butyrylcholine esterases. (2010) (41)
- Stoichiometric and homogeneous-catalytic diboration of the n=n double bond of azobenzene. (2008) (41)
- Deutliche Belege für Ein‐Elektronen‐Übertragungen in der Boryl‐Anionenchemie: Isolierung und Reaktivität eines neutralen Borolradikals (2014) (41)
- The chemistry of (1)borametallocenophanes and related compounds (2003) (41)
- Ansa [1]trochrocenophanes and their related unstrained 1,1'-disubstituted counterparts: synthesis and electronic structure. (2007) (41)
- Diborane(4)yl Complexes of Molybdenum and Ruthenium (1999) (40)
- Synthesis and Reactivity of Semibridging Borylene Complexes (2006) (40)
- Von einem elektronenreichen Bis(boraketenimin) zu einem elektronenarmen Diboren (2015) (39)
- Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis-Configuration. (2017) (39)
- Reactivity of an oxoboryl complex toward fluorinated aryl boron reagents. (2010) (39)
- Engineering a Small HOMO-LUMO Gap and Intramolecular C-H Borylation by Diborene/Anthracene Orbital Intercalation. (2017) (39)
- Borylentransfer unter thermischen Bedingungen: Synthese und Struktur eines Tetrarhodium‐Bisborylenkomplexes (2006) (38)
- Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron. (2016) (38)
- Strongly Phosphorescent Transition Metal π-Complexes of Boron-Boron Triple Bonds. (2017) (38)
- An early-late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy(3)P)(2)Pt-ZrCl(4)]. (2010) (38)
- The Triboracyclopropenyl Dianion: The Lightest Possible Main-Group-Element Hückel π Aromatic. (2015) (38)
- Struktur und Clusterbildung eines tert-Butylborylenkomplexes† (2006) (38)
- Borylene transfer under thermal conditions for the synthesis of rhodium and iridium borylene complexes. (2008) (38)
- Phosphine adducts of 1,2-dibromo-1,2-dimesityldiborane(4): between bridging halides and rearrangement processes. (2012) (38)
- Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes. (2016) (37)
- Synthesis and reactivity of boron-, silicon-, and tin-bridged ansa-cyclopentadienyl-cycloheptatrienyl titanium complexes (troticenophanes). (2010) (37)
- Metallvermittelte Diborierung von Alkinen mit [2]Borametalloarenophanen unter stöchiometrischen, homogen‐ und heterogenkatalytischen Bedingungen (2006) (37)
- Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring (1994) (36)
- Reactivity of a platinum iminoboryl complex toward Lewis and Brønsted acids. (2007) (36)
- Boryl and Bridged Borylene Complexes of Iron and Ruthenium (1999) (36)
- Synthesis and Reactivity of Dihaloboryl Complexes (2006) (36)
- Synthesis, coordination behavior, and reduction chemistry of cymantrenyl-1,3-bis(2,3,4,5-tetraphenyl)borole. (2012) (36)
- Synthesis of [(η5-C5H5)Fe(CO)2BCl2·NC5H4-4-Me] from [(η5-C5H5)Fe(CO)2BCl2]: First Preparation of a Lewis Acid−Base Adduct from a Boryl Complex (2004) (36)
- B+ in the coordination sphere of two transition metals. (2008) (36)
- Synthese und Elektronenstruktur eines terminalen Alkylborylenkomplexes (2007) (36)
- Synthesis, structure, and reactivity of borole-functionalized ferrocenes. (2012) (36)
- Wechselwirkung zwischen d- und p-Block-Metallen: Synthese und Struktur von Platin-Alan-Addukten† (2007) (36)
- Lewis Acid–Base Adducts of 1‐Mesityl‐ and 1‐Chloro‐2,3,4,5‐tetraphenylborole (2013) (36)
- Platinum complexes containing pyramidalized germanium and tin dihalide ligands bound through σ,σ M=E multiple bonds. (2014) (36)
- Synthese und Struktur eines kationischen Platinborylenkomplexes (2007) (35)
- Ein verbr?ckter Borylkomplex: ungew?hnlicher Koordinationsmodus f?r den BR2-Liganden (2005) (35)
- Selektive Generierung und Abfangreaktion eines NHC-stabilisierten B-H-Borylens† (2011) (35)
- Hole Transfer Processes in meta- and para-Conjugated Mixed Valence Compounds: Unforeseen Effects of Bridge Substituents and Solvent Dynamics. (2017) (35)
- One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element (2020) (35)
- Si–H Bond Activation at the Boron Center of Pentaphenylborole (2013) (35)
- Reduktion von Ferrocenylborol (2010) (34)
- Synthese BN‐isosterer Verbindungen von Azofarbstoffen durch Ringerweiterung von Borolen mit Aziden (2015) (34)
- Monomeric 16-Electron π-Diborene Complexes of Zn(II) and Cd(II). (2017) (34)
- Extending unsupported metal-only Lewis pairs to palladium. (2011) (34)
- O,N,B-Containing eight-membered heterocycles by ring expansion of boroles with nitrones. (2015) (33)
- Metathesis reactions of a manganese borylene complex with polar heteroatom-carbon double bonds: a pathway to previously inaccessible carbene complexes. (2013) (33)
- trans-[Pt(BCat')Me(PCy3)2]: an experimental case study of reductive elimination processes in Pt-Boryls through associative mechanisms. (2011) (33)
- Lithiumboryl – ein Synthon für das nucleophile Borylanion (2007) (33)
- Direkte Synthese von funktionalisierten 1,2‐Azaborininen (2014) (33)
- Ortho-methylated tribenzotriquinacenes--paving the way to curved carbon networks. (2012) (33)
- The First Boron-Tellurium Double Bond: Direct Insertion of Heavy Chalcogens into a Mn=B Double Bond. (2017) (33)
- Comparative analysis of electron-density and electron-localization function for dinuclear manganese complexes with bridging boron- and carbon-centered ligands. (2009) (33)
- Einbau eines Elements der ersten Achterperiode in die Brücke eines gespannten Metallocenophans: Synthese eines borverbrückten [1]Ferrocenophans (1997) (32)
- Synthesis and structure-activity relationships of new quinolone-type molecules against Trypanosoma brucei. (2012) (32)
- Syntheses of mono- and dinuclear diiodoboryl complexes of platinum. (2007) (32)
- Unexpected cluster formation upon hydroboration of a neutral diborene with 9-BBN. (2014) (32)
- Scope of the Thermal Ring-Expansion Reaction of Boroles with Organoazides. (2017) (32)
- Komplexe mit dativen Bindungen zwischen d‐ und s‐Block‐Metallen: Synthese und Struktur von [(Cy3P)2Pt‐Be(Cl)X] (X=Cl, Me) (2009) (32)
- From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species. (2017) (32)
- Electronic and structural effects of stepwise borylation and quaternization on borirene aromaticity. (2013) (31)
- Molecular Structure of [CpFe(CO)(2)](2)AlAr (Ar = 2-[(Dimethylamino)methyl]phenyl): An Alanediyl Complex with Two Fe-Al Bonds. (1996) (31)
- Reversible intramolecular coupling of the terminal borylene and a carbonyl ligand of [Cp(CO)2Mn=B-tBu]. (2013) (31)
- Ring Expansion of 7-Boranorbornadienes by Coordination with an N-Heterocyclic Carbene (2013) (31)
- Das Pentaphenylborol-2,6-Lutidin-Addukt: ein System mit ungewöhnlichen thermo- und photochromen Eigenschaften† (2011) (31)
- Reactivity of Lewis basic platinum complexes towards fluoroboranes. (2013) (31)
- Oxidative addition of boron trifluoride to a transition metal. (2011) (31)
- Ferrocenylalanes: solid-state and solution structures of some new aluminum-bridged ansa-ferrocenes. (2005) (31)
- Borylene-based functionalization of iron-alkynyl-σ-complexes and stepwise reversible metal-boryl-to-borirene transformation: synthesis, characterization, and density functional theory studies. (2011) (31)
- Oligo(borolyl)benzenes--synthesis and properties. (2012) (31)
- Unsupported boron–carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation (2012) (31)
- Borylen‐Metathese über eine [2+2]‐Cycloaddition (2007) (30)
- Dehydrocoupling of catecholborane catalyzed by group 4 compounds (2012) (30)
- Herausragende Kurzschlussströme in BHJ‐Solarzellen auf Basis NIR‐absorbierender, akzeptorsubstituierter Squaraine (2009) (30)
- Reactivity Enhancement of a Zerovalent Diboron Compound by Desymmetrization. (2018) (30)
- Synthesis and Structure of [1]Borametallocenophanes of Titanium, Zirconium, and Hafnium (1999) (30)
- Spying on the boron–boron triple bond using spin–spin coupling measured from 11B solid-state NMR spectroscopy (2015) (30)
- Gauging metal Lewis basicity of zerovalent iron complexes via metal-only Lewis pairs (2014) (30)
- Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity. (2016) (30)
- Reductive borylene-CO coupling with a bulky arylborylene complex. (2013) (30)
- Near-Infrared Quadrupolar Chromophores Combining Three-Coordinate Boron-Based Superdonor and Superacceptor Units. (2019) (30)
- Unexpected bonding mode of the diboran(4)yl ligand: combining the boryl motif with a dative Pt-B interaction. (2011) (29)
- Synthesis and Structure of the First [1]Boratitanocenophanes (1999) (29)
- Synthese und Charakterisierung von Iminoborylkomplexen des Palladiums und Platins (2006) (29)
- Bromination Improves the Electron Mobility of Tetraazapentacene. (2018) (29)
- Borylene transfer from an iron bis(borylene) complex: synthesis of 1,4-diboracyclohexadiene and 1,4-dibora-1,3-butadiene complexes. (2012) (29)
- Synthesis of a paramagnetic polymer by ring-opening polymerization of a strained [1]vanadoarenophane. (2008) (29)
- Towards homoleptic borylene complexes: incorporation of two borylene ligands into a mononuclear iridium species. (2010) (28)
- Synthesis of zwitterionic cobaltocenium borate and borata-alkene derivatives from a borole-radical anion. (2013) (28)
- Syntheses and Structures of Mono- and Dinuclear Cationic Base-Stabilized Platinum Borylene Complexes (2008) (28)
- Regioselective Catalytic and Stepwise Routes to Bulky, Functional-Group-Appended, and Luminescent 1,2-Azaborinines. (2016) (28)
- Zur Umsetzung von Bis(η5-cyclopentadienyl)dihydridowolfram mit Halogenboranen / On the Reaction of Bis(η5-cyclopentadienyl)tungstendihydride with Boran Halides (1996) (28)
- A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes. (2015) (28)
- Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule. (2015) (28)
- Diborane(4)yl and bridged borylene complexes from 1,2-dipyrrolidino- and 1,2-dipiperidinodiborane(4) derivatives (1999) (27)
- Synthese und Elektronenstruktur eines Ferroborirens (2007) (27)
- 1,1-Diboration of Isocyanides with [2]Borametalloarenophanes (2010) (27)
- Synthesis of 1-aza-2-borabutatriene rhodium complexes by thermal borylene transfer from [(OC)5Mo=BN(SiMe3)2]. (2011) (27)
- Synthesis and coordination chemistry of 1-cymantrenyl-2,3,4,5-tetraphenylborole. (2011) (27)
- Synthesis and structure of a ferrocenylboron dication. (2008) (27)
- 1,2,3-Diazaborinine: A BN Analogue of Pyridine Obtained by Ring Expansion of a Borole with an Organic Azide. (2018) (27)
- New metal-only Lewis pairs: elucidating the electronic influence of N-heterocyclic carbenes and phosphines on the dative Pt-Al bond. (2012) (27)
- Oxidative Addition of B–Br Bonds to Pd0: Synthesis and Structure of trans‐Bromo(boryl)palladium Complexes (2008) (27)
- Synthesis and Trapping of Iminoboranes by M=B/C=N Bond Metathesis. (2017) (26)
- Heterodiatomic Multiple Bonding in Group 13: A Complex with a Boron-Aluminum π Bond Reduces CO2. (2019) (26)
- New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions. (2019) (26)
- Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}]. (2010) (26)
- CO2‐Fixierung und Spaltung durch unpolare Mehrfachbindungen (2018) (26)
- Low-coordinate boride ligands: a true trimetalloborane. (2009) (26)
- Reactivity of Boryl Complexes: Synthesis and Structure of New Neutral and Cationic Platinum Boryls and Borylenes (2012) (26)
- Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)]. (2009) (26)
- Hochgespannte Heterocyclen, gebildet aus Bor‐Bor‐Mehrfachbindungen und höheren Homologen der Chalcogene (2016) (26)
- Nature of bonding in terminal borylene, alylene, and gallylene complexes of vanadium and niobium [(η(5)-C5H5)(CO)3M(ENR2)] (M = V, Nb; E = B, Al, Ga; R = CH3, SiH3, CMe3, SiMe3): a DFT study. (2011) (26)
- Phosphine-triggered co-catenation of :BR and CO on an iron atom. (2013) (25)
- Reversible insertion of platinum into coinage group metal-halogen bonds. (2012) (25)
- σ-Donor-σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt(0) and Pb(II) fragments. (2012) (25)
- Reaktivität eines Dihydrodiborens gegen CO: Koordination, Insertion, Spaltung und spontane Bildung eines cyclischen Alkins (2017) (25)
- Synthesis, Crystal Structure, EPR and DFT Studies, and Redox Properties of [2]Tetramethyldisilacobaltocenophane (2008) (25)
- DFT Study on Alkyl‐ and Haloborylene Complexes of Manganese and Rhenium: Structure and Bonding Energy Analysis in [(η5‐C5H5)(CO)2M(BR)] and [(η5‐C5H5)(CO)2M(BX)] (M = Mn, Re; R = Me, Et, iPr, tBu; X = F, Cl, Br, I) (2011) (25)
- Übergangsmetall‐katalysierte Synthese von Diboranen(4) (2011) (25)
- A theoretical study of the aromaticity in neutral and anionic borole compounds. (2015) (25)
- Selektive Dimetallierung von [Mn(η5‐C5H5)(η6‐C6H6)]: Struktur im Kristall und Umsetzung zu gespannten [n]Metalloarenophanen (2007) (25)
- Stufenweiser Intermetallborylentransfer: Synthese und Struktur von ein‐ und zweikernigen Cobaltborylenkomplexen (2007) (24)
- Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane. (2019) (24)
- Erzeugung zweifach koordinierter Bor(I)‐Einheiten durch Fragmentierung eines molekularen Tetra‐Bor(I)‐Quadrats (2016) (24)
- Visible-Light-Induced Ni-Catalyzed Radical Borylation of Chloroarenes. (2020) (24)
- Bottleable Neutral Analogues of [B2 H5 ]- as Versatile and Strongly Binding η2 Donor Ligands. (2018) (24)
- Simple solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts. (2017) (24)
- Synthesis, Molecular Structure, and Reactivity of the First Strained [2]Silanickelocenophane (2007) (24)
- Unravelling the Dramatic Electrostructural Differences Between N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Stabilized Low-Valent Main Group Species. (2018) (24)
- Bonding in a borylene complex investigated by photoionization and dissociative photoionization. (2012) (24)
- Ein dreikerniger Boridkomplex mit einer fluktuierenden Gold‐Bor‐Bindung (2009) (24)
- [2]Borametallocenophanes of Zr and Hf: synthesis, structure, and polymerization activity. (2005) (24)
- Synthesis of a bicyclic diborane by selective boron carbon bond formation. (2013) (24)
- Structure and bonding energy analysis of M-Ga bonds in dihalogallyl complexes trans-[X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I). (2010) (24)
- Das Triboracyclopropenyl‐Dianion: der leichteste Hückel‐π‐Aromat aller Hauptgruppenelemente (2015) (24)
- Reduktive Insertion von elementaren Chalkogenen in Bor‐Bor‐ Mehrfachbindungen (2015) (24)
- Ni-catalyzed traceless, directed C3-selective C-H borylation of indoles. (2020) (23)
- Organometallic Probe for the Electronics of Base-Stabilized Group 11 Metal Cations. (2015) (23)
- Reversible photochemische und thermische Isomerisierung von Azaboratabisnorcaradien zu Azaborabenzotropyliden (2014) (23)
- Neutrale Dibor‐Analoga von archetypischen aromatischen Verbindungen durch spontane Cycloaddition (2016) (23)
- Dilithiation of Bis(benzene)molybdenum and subsequent isolation of a molybdenum-containing paracyclophane. (2007) (23)
- Silver(I) and thallium(I) cations as unsupported bridges between two metal bases. (2014) (23)
- Probing antiaromaticity: resonance Raman investigation of a series of differently substituted boroles (2010) (23)
- Synthesis of eta1-borazine complexes of palladium and platinum. (2008) (23)
- A paramagnetic heterobimetallic polymer: synthesis, reactivity, and ring-opening polymerization of tin-bridged homo- and heteroleptic vanadoarenophanes. (2015) (23)
- Diboryldiborenes: π-Conjugated B4 Chains Isoelectronic to the Butadiene Dication. (2018) (23)
- Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: synthesis and characterisation of high molecular weight poly(phosphinoboranes). (2016) (23)
- Thermischer Borylentransfer zur Synthese von Rhodium- und Iridiumborylenkomplexen† (2008) (23)
- Formation, structure and reactivity of boryloxycarbyne complexes of group 6 metals. (2003) (23)
- cAAC‐Stabilized 9,10‐diboraanthracenes—Acenes with Open‐Shell Singlet Biradical Ground States (2020) (23)
- Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions. (2019) (23)
- Increasing the Reactivity of Diborenes: Derivatization of NHC-Supported Dithienyldiborenes with Electron-Donor Groups. (2018) (23)
- Reactivity of Platinum Iminoboryl Complexes toward Covalent Element−Hydrogen Bonds of Opposing Polarity (2010) (23)
- Dimanganese Bridging Borylene Complexes and their Reactions with Unsaturated Palladium(0) Complexes – Syntheses, Structures and Calculated Properties (2008) (23)
- Unerwartetes Lumineszenzverhalten von Münzmetall‐π‐Diboren‐Komplexen (2015) (22)
- A DINUCLEAR TIN(II) AMIDE, A META-STANNYLAMINOCYCLOPHANE AND ITS ORTHOSTANNYLATED DERIVATIVE, A DIMERIC TRINUCLEAR TIN(II) CLUSTER (1997) (22)
- Synthesis, structure and reactivity of disila- and distanna ansa half-sandwich complexes of molybdenum and tungsten. (2009) (22)
- Reaktionen von [(η5-C5R5)2WH2] mit Boranen / Reactions of [(η5-C5R5)2WH2] with Boranes (1999) (22)
- Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN‐Isostere von Carben‐Alkin‐Addukten (2015) (22)
- Selective dilithiation of [Ti(η(5)-C5H5)(η(8)-C8H8)] and subsequent conversion into neutral and cationic ansa-complexes. (2011) (22)
- Monomeric Cp3tAl(i): synthesis, reactivity, and the concept of valence isomerism (2019) (22)
- Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds. (2019) (22)
- Synthesis, Photophysical, and Electrochemical Properties of Pyrenes Substituted with Donors or Acceptors at the 4- or 4,9-Positions. (2018) (22)
- Dative Wechselwirkungen einer Bor‐zentrierten Lewis‐Base mit Gruppe‐13‐Elementen (2016) (21)
- The first monomeric prochiral tin(II) complexes Sn[N(SiMe3)2]X [X = OC6H2But2-2,6-Me-4, 1 or NCMe2(CH2)3CME2, 2]; the X-ray structure of 1 and oxidative addition reactions of 2 (1992) (21)
- Isolation of the key intermediates of base-promoted borylene–carbonyl coupling reactions (2014) (21)
- Half-Sandwich Complexes of an Extremely Electron-Donating, Redox-Active η6-Diborabenzene Ligand. (2018) (21)
- Aluminum(I)/Boron(III) Redox Reactions. (2019) (21)
- Synthesis and structure of aminobis(η1-cyclopentadienyl)boranes and related compounds (2001) (21)
- Chelated Diborenes and Their Inverse-Electron-Demand Diels-Alder Reactions with Dienes. (2018) (21)
- Trihapto ligation of a borirene to a single metal atom: a heterocyclic analogue of the η³-cyclopropenyl ligand. (2014) (21)
- Elektronendichteuntersuchung der Metall-Metall-Bindung im zweikernigen “Borylen”-Komplex [{Cp(CO)2Mn}2(μ-BtBu)]† (2008) (21)
- Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning (2020) (21)
- Zur Reaktivität eines terminalen Chromborylenkomplexes gegenüber Olefinen – Boryleneinschub in eine C-H-Bindung† (2008) (21)
- Synthesis and structure of the first boron-bridgedconstrained geometry complexes (2000) (20)
- Diboration of Dialkynes with [2]Boraferrocenophanes (2011) (20)
- Intramolecular activation of a disila[2]molybdenocenophanedihydride: synthesis and structure of a [1],[1]metalloarenophane. (2008) (20)
- Synthesis and structure of boron-bridged constrained geometry complexes of titanium. (2004) (20)
- Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes. (2017) (20)
- Synthesis, Photophysical and Electronic Properties of New Red‐to‐NIR Emitting Donor–Acceptor Pyrene Derivatives (2019) (20)
- Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium (2010) (20)
- Synthesis of catechol-, pinacol-, and neopentylglycolborane through the heterogeneous catalytic B-B hydrogenolysis of diboranes(4). (2013) (20)
- Synthesis of Chloro Boryl Complexes by Oxidative Addition of B–Cl Bonds (2009) (20)
- Mehrfache Reduktion von 2,5‐Bis(borolyl)thiophen: Isolierung eines negativen Bipolarons durch Komproportionierung (2013) (20)
- Reduktive Borylen‐CO‐Kupplung an einem sterisch anspruchsvollen Arylborylenkomplex (2013) (20)
- Dibora[2]ferrocenophan: ein carbenstabilisiertes Diboren in einer gespannten cis-Konfiguration (2017) (20)
- N-Heterocyclic Silylenes in Boron Chemistry: Facile Formation of Silylboranes and Silaborinines. (2016) (19)
- Elucidating the Reactivity of Vicinal Dicarbenoids: From Lewis Adduct Formation to B-C Bond Activation. (2016) (19)
- [1.1]Ferrocenophanes and bis(ferrocenyl) species with aluminum and gallium as bridging elements: synthesis, characterization, and electrochemical studies. (2012) (19)
- {[Bis(dimethylamino) boryl]methyl} dimethylphosphane as ligand in transition metal complexes (1997) (19)
- Alternative synthesis and crystal structure of a [2]boraferrocenophane (2007) (19)
- Isolable Phospha- and Arsaalumenes. (2021) (19)
- Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor (2017) (18)
- Release of Isonitrile- and NHC-Stabilized Borylenes from Group VI Terminal Borylene Complexes. (2018) (18)
- Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity (2018) (18)
- Dialumination of unsaturated species with a reactive bis(cyclopentadienyl) dialane. (2018) (18)
- B+ in der Koordinationssphäre zweier Übergangsmetalle (2008) (18)
- Boron: Its role in energy related research and applications (2020) (18)
- Synthesis and Characterisation of Semi‐Bridging Molybdenum Borylene Complexes (2007) (18)
- Photoionization and pyrolysis of a 1,4-azaborinine: retro-hydroboration in the cation and identification of novel organoboron ring systems. (2014) (18)
- Reversible sigma-borane-to-borylene transformation: a little something for everyone. (2009) (18)
- Koordination von Phosphanen an 1,2‐Dibrom‐1,2‐dimesityldiboran(4) – zwischen Halogenbrücken und Umlagerungsprozessen (2012) (17)
- Unsymmetrische, cyclische Diborene und thermische Umlagerung zu einem Borylborylen (2018) (17)
- Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II). (2013) (17)
- Construction of Linear and Branched Tetraboranes by 1,1- and 1,2-Diboration of Diborenes. (2018) (17)
- [n]Borametalloarenophanes (n = 1, 2): Strained Systems with Uncommon Reactivity Patterns (2012) (17)
- Heterodiatomare Mehrfachbindung zwischen Elementen der Gruppe 13: Ein Komplex mit B‐Al‐π‐Bindung reduziert CO 2 (2019) (17)
- Vom Boran zum Borylen ohne Reduktion: Ambiphiles Verhalten einer monovalenten Silylisonitril‐Borverbindung (2017) (17)
- Borole-Derived Spirocyclic Tetraorganoborate (2012) (17)
- σ-Coordination of metal-boryl bonds to gold(I). (2013) (17)
- Direct access to a cAAC-supported dihydrodiborene and its dianion. (2018) (17)
- Syntheses of Group 4 ansa-trovacene complexes and conversion of [1]silatrovacenophanes into paramagnetic metallopolymers by ring-opening polymerization. (2011) (17)
- High photocatalytic activity of a NiO nanodot-decorated Pd/SiC catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and chlorides in air under visible light (2020) (17)
- Facile Access to Unprecedented Electron-Precise Monohydrodiboranes(4), cis-1,2-Dihydrodiboranes(4), and a 1,1-Dihydrodiborane(5). (2017) (17)
- Phosphan‐induzierte Verkettung von :BR und CO an einem Eisenatom (2013) (17)
- Unprecedented oxidative addition and metal-only Lewis pair chemistry of antimony trihalides. (2015) (17)
- Transmetallation between metal-only Lewis pairs: a new rhodium alane complex. (2012) (17)
- Highly Stable, Readily Reducible, Fluorescent, Trifluoromethylated 9‐Borafluorenes (2020) (17)
- Generierung einer kleinen HOMO‐LUMO‐Lücke und intramolekulare C‐H‐Borylierung durch Diboren‐Anthracen‐Orbitalinterkalation (2017) (17)
- Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials. (2008) (17)
- Lewis Acid Binding and Transfer as a Versatile Experimental Gauge of the Lewis Basicity of Fe(0) , Ru(0) , and Pt(0) Complexes. (2015) (17)
- [1]Borahafnocenophanes: Synthesis, Structure and Catalytic Activity (2005) (16)
- Transition-Metal π-Ligation of a Tetrahalodiborane. (2018) (16)
- Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides. (2013) (16)
- Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions† †Electronic supplementary information (ESI) available. CCDC 1881912. For ESI and crystallographic data in CIF or other electronic format see (2019) (16)
- A Bromide‐bridged Platinum(II) Complex as Precursor to a Neutral Platinum Compound with a Base‐Stabilized Borylene Ligand (2009) (16)
- Unprecedented Reactivity of the Bridged Borylene Complexes [μ-BCl{(η5-C5H4Me)Mn(CO)2}2] toward Pyridine (2003) (16)
- Synthesis and structure of heterodinuclear rhodium and iridium borylene complexes. (2009) (16)
- A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode. (2013) (16)
- Planar four-coordinate boron: a single, flat boron atom as a ligand for four metals. (2012) (16)
- Complexation and Release of N-Heterocyclic Carbene-Aminoborylene Ligands from Group VI and VIII Metals. (2018) (16)
- Atropodiastereoselective Cleavage of Configurationally Unstable Biaryl Lactones with Amino Acid Esters (2006) (16)
- Reversible intramolekulare Kupplung von terminalen Borylen‐ und Carbonylliganden in [Cp(CO)2MnB‐tBu] (2013) (16)
- Dynamic, Reversible Oxidative Addition of Highly Polar Bonds to a Transition Metal. (2016) (16)
- Facile Synthesis of a Stable Dihydroboryl {BH2 }- Anion. (2018) (16)
- Niederkoordinierte Boridliganden: ein “echtes” Trimetalloboran (2009) (16)
- [2+2]‐Cycloaddition vo Iminoboranen mit einem Neopentylidentantal‐Komplex (1990) (16)
- A B-C double bond unit coordinated to platinum: an alkylideneboryl ligand that is isoelectronic to neutral aminoborylene Ligands. (2014) (16)
- Carbonyl complexes of platinum(0): synthesis and structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]. (2011) (15)
- A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge. (2019) (15)
- Spontaneous Metal-Free Transfer Hydrogenation of Iminoboranes with Ammonia Borane and Amine Boranes. (2018) (15)
- Two-Dimensional, but not Flat: An All-Boron Graphene with a Corrugated Structure. (2016) (15)
- Reaction of Dihalodiboranes(4) with a N-Heterocyclic Silylene: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes. (2017) (15)
- Reactivity of a platinum-substituted borirene. (2011) (15)
- Base-stabilized boryl and cationic haloborylene complexes of iron. (2013) (15)
- Neutral and anionic transition-metal-base-stabilized metalloborylene complexes. (2010) (15)
- Single and double activation of acetone by isolobal B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds. (2018) (15)
- CuOTf-mediated intramolecular diborene hydroarylation. (2017) (14)
- Aryldihydroborane Coordination to Iridium and Osmium Hydrido Complexes (2015) (14)
- A combined experimental and theoretical study on the isomers of 2,3,4,5-tetracarba-nido-hexaborane(6) derivatives and their photophysical properties. (2015) (14)
- DFT Studies on the Reactions of Boroles with Alkynes. (2018) (14)
- Evidence for a strong trans influence of the diboran(4)yl ligand. (2012) (14)
- Oxidative Addition von BF3 an ein Übergangsmetall (2011) (14)
- Synthesis and Structure of the First ?1-Borazine Complexes (1998) (14)
- A Boradiselenirane and a Boraditellurirane: Isolable Heavy Analogs of Dioxiranes and Dithiiranes. (2018) (14)
- Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions. (2019) (14)
- Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments (2015) (14)
- Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit. (2019) (14)
- Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes. (2015) (14)
- Boranchemie aus einer neuen Perspektive: Nukleophilie der B-H-Bindungselektronen (2019) (14)
- Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes. (2013) (14)
- Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers. (2011) (13)
- Weitere Reaktionen der Iminoborane RB≡NR′ mit Neopentylidentantal‐Komplexen (1993) (13)
- Intramolekulare Aktivierung eines Disila[2]molybdänocenophandihydrids – Synthese und Struktur eines [1],[1]Metalloarenophans (2008) (13)
- Synthesis of half-sandwich tungsten chlorogermyl and chlorostannyl complexes (2007) (13)
- Ein neuer Typ von Umlagerung bei Oxicarbinkomplexen: Synthese und Struktur neuartiger Diboran(4)ylkomplexe (1999) (13)
- [1]Borametallocenophanes as Catalysts for Ethene Polymerization† (2005) (13)
- Structural characterization of the anionic halfsandwich complex [Li(TMEDA)2][Mo(η5-C5H5)(CO)3][Li(TMEDA)2][Mo(η5-C5H5)(CO)3] and its reactivity towards stannanes and distannanes (2009) (13)
- Synthese von 1‐Aza‐2‐borabutatrien‐Rhodiumkomplexen durch thermischen Borylentransfer von [(OC)5MoBN(SiMe3)2] (2011) (13)
- Hydridoborylene complexes and di-, tri-, and tetranuclear borido complexes with hydride ligands. (2013) (13)
- Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene. (2014) (13)
- Heteroleptic [n]chromoarenophanes: ansa complexes derived from [Cr(η(5)-C5H5)(η(6)-C6H6)]. (2013) (13)
- Phosphanstabilisierte Diioddiborene: Isolierbare Diborene mit sechs labilen Bindungen (2019) (13)
- On the relation of energy and electron transfer in multidimensional chromophores based on polychlorinated triphenylmethyl radicals and triarylamines. (2015) (13)
- Fashionably late: synthesis and characterization of transition-metal-fluoroborylene complexes. (2010) (13)
- An iridium N-heterocyclic carbene complex [IrCl(CO)2(NHC)] as a carbon monoxide-releasing molecule (CORM) (2015) (13)
- Conversion of trans-Bromoboryl Platinum Complexes into their cis-Analogues upon Treatment with Chelating Bisphosphines (2008) (13)
- Synthese, Strukturen und Reaktionen zweier Bis(diaminostannylene) und eines Bis(diaminogermylens) mit zentralem C6‐Ring (1994) (13)
- Weitere Reaktionen des Amino(imino)borans Me3Si(tBu)N*B*NtBu und des Alkyliden(amino)borans Me3Si(tBu)N=B=CHtBu (1993) (13)
- Recent Advances in the Synthesis and Reactivity of Transition Metal σ-Borane/Borate Complexes. (2021) (13)
- A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation (2019) (13)
- Kombination aus Boryl- und dativer Pt-B-Bindung: ein unerwarteter Koordinationsmodus für den Diboran(4)yl-Liganden† (2011) (13)
- Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity. (2019) (13)
- Lewis-Base-Induced Disproportionation of a Dialane. (2018) (13)
- Synthese eines paramagnetischen Polymers durch ringöffnende Polymerisation eines gespannten [1]Vanadoarenophans† (2008) (12)
- Platinum trans-Bis(borirene) complexes displaying coplanarity and communication across a platinum metal center. (2015) (12)
- N ‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Titanium(IV) and Titanium(III) (2020) (12)
- Dreifach koordiniertes Bor als Superdonor und ‐akzeptor für quadrupolare Nahinfrarot‐Chromophore (2019) (12)
- High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle. (2011) (12)
- Chelatisierte Diborene und ihre Diels‐Alder‐Reaktionen mit Dienen unter inversem Elektronenbedarf (2018) (12)
- Chemoselective boron-carbon bond cleavage by hydroboration of borirenes. (2009) (12)
- New [2]Boraferrocenophane and Diferrocenyldiborane(4) Derivatives (2010) (12)
- Reactivity of Tetrahalo- and Difluorodiboranes(4) toward Lewis Basic Platinum(0): Bis(boryl), Borylborato, and Doubly Boryl-Bridged Platinum Complexes. (2018) (12)
- Reactions of Digallanes with p- and d-Block Lewis Bases: Adducts, Bis(gallyl) Complexes, and Naked Ga+ as Ligand. (2018) (12)
- Synthesis and characterization of a mercury-containing trimetalloboride. (2014) (12)
- Controlling Regiochemistry in the Syntheses of Boraindanes from Diborane(4) Starting Materials. (2016) (11)
- Electronic structure and reactivity of a [1],[1]disilamolybdenocenophane. (2010) (11)
- Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex. (2016) (11)
- Anionic Boron- and Carbon-Based Hetero-Diradicaloids Spanned by a p-Phenylene Bridge. (2021) (11)
- Insertion vs Ligand Exchange: Reactivity of Distanna Ansa Half-Sandwich Complexes of Molybdenum and Tungsten toward Isocyanide and Phosphine Complexes of Nickel and Palladium (2011) (11)
- A Neutral Beryllium(I) Radical (2021) (11)
- Hexahalodiborate Dianions: A New Family of Binary Boron Halides (2019) (11)
- Auf dem Weg zu homoleptischen Borylenkomplexen – eine einkernige Iridiumverbindung mit zwei Borylenliganden (2010) (11)
- Stable Organic (Bi)Radicals by Delocalization of Spin Density into the Electron-Poor Chromophore Core of Isoindigo. (2018) (11)
- Oxidation, Coordination, and Nickel‐Mediated Deconstruction of a Highly Electron‐Rich Diboron Analogue of 1,3,5‐Hexatriene (2020) (11)
- Platinum oxoboryl complexes as substrates for the formation of 1:1, 1:2, and 2:1 Lewis acid-base adducts and 1,2-dipolar additions. (2015) (11)
- 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group. (2015) (11)
- Direct Conversion from Terminal Borylene into Terminal Phosphinidene. (2016) (11)
- New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives. (2016) (11)
- Paracyclophanes as model compounds for strongly interacting π-systems, part 3: influence of the substitution pattern on photoabsorption properties. (2011) (11)
- Borabicyclo[3.2.0]heptadiene: A Fused Bicyclic Isomer of Borepin. (2018) (11)
- f-Block Ansa Complexes in the Solid State: [3]Thoro- and [3]Uranocenophanes. (2015) (11)
- Borylentransfer mit einem Eisenbis(borylen)komplex: Synthese von 1,4‐Diboracyclohexadien‐ und 1,4‐Dibora‐1,3‐butadienkomplexen (2012) (11)
- Eine Bor‐Tellur‐Doppelbindung: direkte Insertion in eine Mn=B‐Doppelbindung (2017) (11)
- Diboryldiborene: π-konjugierte B4 -Ketten isoelektronisch zum Butadien-Dikation (2018) (11)
- Phenylpyridyl‐Fused Boroles: A Unique Coordination Mode and Weak B−N Coordination‐Induced Dual Fluorescence (2020) (11)
- Activation of boryl-, borylene and metalloborylene complexes by isonitriles. (2015) (11)
- Tetrabromtetraazapentacen: erhöhte Elektronenbeweglichkeit (2018) (11)
- Redoxreaktionen zwischen Aluminium(I)- und Bor(III)-Verbindungen (2019) (11)
- Partially and Fully Reversible Solvation-Controlled Borylene Swapping and Metal-Only Lewis Pair Formation (2014) (11)
- Twisting versus Delocalization in CAAC‐ and NHC‐Stabilized Boron‐Based Biradicals: The Roles of Sterics and Electronics (2020) (10)
- Reactivity of the bridged borylene complex [μ-BCl{η5-C5H4Me)Mn(CO)2}2] (2004) (10)
- Reduction and Rearrangement of a Boron(I) Carbonyl Complex (2020) (10)
- Metal-Only Lewis Pairs Based on Zerovalent Osmium (2016) (10)
- 1,1'-Diborylferrocenes from [2]Boraferrocenophanes by Boron-Boron Exchange (2009) (10)
- Isolation and Characterization of Crystalline, Neutral Diborane(4) Radicals. (2018) (10)
- Synthesis and reactions of {o‐{[bis(dimethylamino)boryl]methyl}phenyl}diphenylphosphane (1997) (10)
- Interaction of dilithiated ferrocene with AlMe2Cl reagents (2007) (10)
- Synthesis of Functionalized Hydrazines: Facile Homogeneous (N‐Heterocyclic Carbene)‐Palladium(0)‐Catalyzed Diboration and Silaboration of Azobenzenes (2016) (10)
- Boron Clusters with a Ferrocenylalkynyl Group Bonded to Boron: Synthesis, Characterization, and Electrochemical Trends† (2015) (10)
- Complete and partial 1,2-additions across transition metal-boron double bonds. (2014) (10)
- Borido complexes via intermetallic metalloborylene transfer. (2011) (10)
- Luminescent Mono‐, Di‐, and Triradicals: Bridging Polychlorinated Triarylmethyl Radicals by Triarylamines and Triarylboranes (2019) (10)
- Isolation of a Reactive Cyclopropane Intermediate via a Unique Catalyst-Free Spontaneous Cyclopropanation Step at 0 °C. (2017) (10)
- A Binuclear 1,1'-Bis(boratabenzene) Complex: Unprecedented Intramolecular Metal-Metal Communication through a B-B Bond. (2016) (10)
- Monohaloboryls (BHX-) as bridging ligands: observable dinuclear σ-(halo)boranyl intermediates in the synthesis of metalloborylenes. (2012) (10)
- Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes (2019) (10)
- Metal-only Lewis pairs by reversible insertion of ruthenium and osmium fragments into metal-boron double bonds. (2014) (10)
- An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers (2020) (10)
- N‐Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D–π–A Compounds (2019) (9)
- Synthesis and structure of novel organocycloborates. (2005) (9)
- Steric Control between Neutral Metal-Only Lewis Pairs and Metal-Stabilized Gallenium and Gallinium Cations (2016) (9)
- Exklusiver π‐Einschluss leichter Alkalimetallkationen durch ein neutrales Molekül (2015) (9)
- Half-Sandwich Tungsten Complexes with Metal- and η5-Cyclopentadienyl-Bound Functional Stannyl Groups and Their Transformation into Ansa Complexes† (2010) (9)
- Spontaneous trans-Selective Transfer Hydrogenation of Apolar Boron-Boron Double Bonds. (2019) (9)
- Synthesis and Structure of an o‐Carboranyl‐Substituted Three‐Coordinate Borane Radical Anion (2021) (9)
- Cyclodimerisierung eines Oxoborylkomplexes durch trans‐Ligandabstraktion (2010) (9)
- Synthesis and Hydroboration of a Mixed‐Donor Iminoboryl Complex of Platinum (2015) (9)
- Synthese und Nachweis von Iminoboranen durch M=B/C=N-Bindungsmetathese (2017) (9)
- Alkylideneborate zwitterions and C-C coupling by atypical diboration of electron-rich alkynes. (2017) (9)
- Boron—A Meeting Point (2005) (9)
- Reversible σ‐Boran‐Borylen‐Umwandlung: etwas für jeden Geschmack (2009) (9)
- Manganese-σ-Borane Complexes from Dihaloboranes (2010) (9)
- Bottleable neutral analogues of [ B 2 H 5 ] as versatile and strongly binding eta 2 donor ligands (2019) (9)
- Cyclization of a 1,4-diborabutadiene ligand with both atoms of CO. (2015) (9)
- Boryl- and Silyl-Substituted Mixed Sandwich Compounds of Scandium. (2018) (9)
- Konstruktion linearer und verzweigter Tetraborane durch 1,1- und 1,2-Diborierung von Diborenen (2018) (9)
- Simultaneous fragmentation and activation of white phosphorus. (2013) (9)
- An electron-precise, tetrahedral μ3 boride complex. (2013) (8)
- Synthesis and structure of [Zr{η5:η1-C9H6B(NiPr2)NPh}2]: a new complex with a boron-bridged amido-indenyl ligand (2003) (8)
- DFT Studies of Dimerization Reactions of Boroles. (2017) (8)
- [2]borametallocenophanes of group 4 metals: synthesis and structure. (2008) (8)
- Abnormal Tin-Boron Exchange in the Attempted Synthesis of a Borylated Borole. (2017) (8)
- A metal-mediated boron-centred isomerisation reaction via C-H activation. (2015) (8)
- Conversion of trans-diboran(4)yl platinum complexes into their cis-bisboryl analogues. (2013) (8)
- Unexpected generation of diastereomers by double diboration of a dialkyne. (2011) (8)
- Synthesis and Structure of Trinuclear Boryloxycarbyne Complexes (1999) (8)
- Towards the catalytic activation of inert small molecules by main-group ambiphiles (2020) (8)
- Dithiophene‐Fused Oxadiborepins and Azadiborepins: A New Class of Highly Fluorescent Heteroaromatics (2021) (8)
- Difluorenyl[2]borametallocenophanes of Group 4 Metals: Synthesis and Structure (2009) (8)
- Uranium Hydridoborates: Synthesis, Magnetism, and X-ray/Neutron Diffraction Structures. (2015) (7)
- cAAC‐stabilisierte 9,10‐Diboraanthracene – offenschalige Singulettbiradikale (2020) (7)
- Stabilization of delphinidin in a complex with sulfobutylether-β-cyclodextrin allows for antinociception in inflammatory pain. (2020) (7)
- Short Survey of the Chemical Reduction Behavior of the Base-Stabilized Iron Dichloroboryl Complexes [(η5-C5Me5)Fe(CO)2BCl2(LB)] (2014) (7)
- Selective one- and two-electron reductions of a haloborane enabled by a π-withdrawing carbene ligand. (2018) (7)
- Metal-Enriched [3]Trochrocenophanes: Bimetallic Metalloarenophanes by Coordination to Chelating Bis(phosphanyls) (2011) (7)
- Boron-Metallated Borirenes and Bis(Borirenes). (2016) (7)
- Diboran(4)yl platinum(II) complexes. (2013) (7)
- Visible-light-driven graphene supported Cu/Pd alloy nanoparticle-catalyzed borylation of alkyl bromides and chlorides in air (2021) (7)
- [{Br2B(η5‐C5H4)}Mn(CO)3] – A versatile Precursor for Boron‐based Ligands (2007) (7)
- Synthesis and molecular structure of boron-bridged constrained geometry complexes of zirconium and hafnium (2005) (7)
- Functionalization of N2 via Formal 1,3‐Haloboration of a Tungsten(0) σ‐Dinitrogen Complex (2020) (7)
- Synthesis and Structure of Trisilane‐1,3‐diyl ansa Half‐Sandwich Complexes of Group 6 Metals (2010) (7)
- Spontaner metallfreier Wasserstofftransfer zwischen Amminboranen und Iminoboranen (2018) (7)
- Milde und vollständige Spaltung eines Carbonylliganden innerhalb eines einkernigen Übergangsmetallkomplexes (2016) (7)
- Strained ansa half-sandwich complexes of ruthenium and osmium and a non-iron metallopolymer by ring-opening polymerization (2014) (7)
- Ansa-bridged bis(benzene) titanium complexes. (2015) (7)
- Reactivity of [1],[1]disilamolybdenocenophane toward zerovalent platinum complexes. (2010) (7)
- Übergangsmetall‐π‐Komplexierung eines Tetrahalogendiborans (2018) (7)
- Direkte Umwandlung eines terminalen Borylen‐ in einen terminalen Phosphinidenkomplex (2016) (7)
- Maximierung von koordinativer und elektronischer Ungesättigtheit: dreifach koordinierte dikationische Platinkomplexe (2013) (7)
- 1,2,3-Diazaborinin: ein BN-Analogon des Pyridins durch Borol-Ringerweiterung mit einem organischen Azid (2018) (7)
- Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters (2015) (7)
- Einfacher Zugang zum ersten stabilen {BH 2 } − Dihydroborylanion (2018) (7)
- Synthesis and Reactivity of Palladium- and Platinum-Bridged Heterobimetallic [3]Trochrocenophanes (2012) (6)
- Isolierbare, neutrale Analoga des [B2H5]−‐Ions als vielseitige und stark bindende η2‐Donorliganden (2018) (6)
- Trihapto‐Koordination eines Borirens an ein einzelnes Metallatom: ein heterocyclisches Analogon des η3‐Cyclopropenylliganden (2014) (6)
- Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum–nitrogen heterocycles† †Electronic supplementary information (ESI) available. CCDC 1987117–1987122. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d0sc02032j (2020) (6)
- Planar Cyclopenten‐4‐yl Cations: Highly Delocalized π Aromatics Stabilized by Hyperconjugation (2020) (6)
- Electronically Driven Regioselective Iridium‐Catalyzed C−H Borylation of Donor‐π‐Acceptor Chromophores Containing Triarylboron Acceptors (2020) (6)
- Investigation of Steric Factors Involved in the Formation of Terminal Cationic Platinum Arylborylene Complexes (2015) (6)
- Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry (2021) (6)
- Synthesis and structure of the first heterodinuclear bis(borylene) complexes. (2013) (6)
- Fundamental Differences between Group 8 Metals: Unexpected Oxidation State Preferences and Mechanisms in Ruthenium Borylene Complex Formation. (2016) (6)
- Isolation and Reactivity of an Antiaromatic s‐Block Metal Compound (2020) (6)
- Single, Double, Triple Bonds and Chains: The Formation of Electron-Precise B—B Bonds. (2013) (6)
- Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne. (2019) (6)
- {N′,N′′-Bis[2,6-bis(1-methylethyl)phenyl]-N,N-dimethylguanidinato-κ2 N′,N′′}dibromidoborane (2010) (6)
- Piperidino Substituted [1]Borametallocenophanes. Synthesis, Reactivity, and Structure (2006) (6)
- A Simple Decarbonylative Route to Heterodinuclear Alkylborylene Complexes (2014) (6)
- Cyclopentadienyl(diamino)boranes and their Derivatives — a Family of Versatile Ligand Precursors for Constrained Geometry Complexes (2003) (6)
- 1,2-Disilabicyclo[1.1.1]pentan-4-ones from a Disilenide and Acryloyl Chlorides (2013) (6)
- Derivatisation of boryl substituted titanium half-sandwich complexes -molecular structures of [Ti{(η5-C5H4)B(NiPr2)N(H)tBu}Cl2(NMe2)] and[{TiCl2(μ-{OB(NHMe2)-η5-C5H4})}2-μ-O] (2006) (6)
- Synthesis and Reactivity of Diborane(4)yl Complexes (2002) (6)
- Substituted Ferrocenylboranes – Potential Ligand Precursors for ansa‐ Metallocenes, Constrained Geometry Complexes and ansa‐Diamido Complexes (2006) (6)
- Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes (2019) (6)
- Trapping of a Borirane Intermediate in the Reductive Coupling of an Arylborane to a Diborene. (2020) (6)
- Highly Strained Metallocenophanes: Synthesis and Ring-Opening of Sulfur-, Selenium- and Boron- Bridged [1]Ferrocenophanes (1997) (6)
- Isolation and Reactivity of an s-Block Metal Antiaromatic. (2020) (6)
- Synthesis of the first heteroaryl-substituted boryl complexes: strong stabilizing effects of boron-aryl π-conjugation. (2015) (6)
- 6H,13H-Pyrazino[1,2-a;4,5-a']diindole analogs: probing the pharmacophore for allosteric ligands of muscarinic M2 receptors. (2006) (6)
- Ein zweikerniges-Zinn(II)-Amid, ein meta-Stannylaminocyclophan, und dessen ortho-Stannierungsprodukt, ein dreikerniger Zinn(II)-Cluster† (1997) (6)
- Iron ansa half sandwich complexes bearing a bridging distannadiyl moiety (2012) (6)
- Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group. (2016) (6)
- Mild synthesis of diboryldiborenes by diboration of B–B triple bonds (2019) (5)
- Bond-Strengthening Backdonation in Aminoborylene-Stabilized-Aminoborylenes: at the Intersection of Borylenes and Diborenes. (2019) (5)
- Structure and reactivity of distanna[2]metallocenophanes of ruthenium and osmium. (2013) (5)
- Cyclisation of biscarbenoids - a novel mode of cyclobutadiene stabilisation. (2016) (5)
- Zweidimensional, aber nicht flach: Borophen – ein “Graphen aus Bor” mit gewellter Struktur (2016) (5)
- Formation of a stable radical by oxidation of a tetraorganoborate. (2016) (5)
- Notizen: Die Reaktion von (Butadien)zirconocen mit Iminoboran / The Reaction of (Butadiene)zirconocene with Iminoborane (1990) (5)
- B−B Cleavage and Ring‐Expansion of a 1,4,2,3‐Diazadiborinine with N‐Heterocyclic Carbenes (2019) (5)
- Toward Transition‐Metal‐Templated Construction of Arylated B4 Chains by Dihydroborane Dehydrocoupling (2019) (5)
- Eine neue Strukturklasse neutraler borhaltiger Diradikale verbrückt über zwei Kohlenstoffatome (2019) (5)
- Synthesis and structure of distanna and tristanna ansa half-sandwich complexes of ruthenium and nickel. (2012) (5)
- Synthesis, structure, and bonding of novel homodinuclear cobalt and nickel borylene complexes. (2009) (5)
- Spontaneous trans-Selective Transfer Hydrogenation of Apolar B=B Double Bonds (2019) (5)
- Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations (2018) (5)
- Wolfphos in Sheep's Clothing: The First Trinuclear Triboryl‐ and Other Boryl Platinum Complexes Featuring a Flexible Phosphine Ligand (2013) (5)
- Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substitutedortho-perylenes displaying four reversible oxidations or reductions (2019) (5)
- Synthesis and structures of [Yb {η5‐(C5H4)B(NiPr2)NHtBu} 2 {N(SiMe3)2} ] and [Zr {η5‐(C9H6)B(N(SiMe3)2)(C9H7)} Cl2] (2003) (5)
- Formation of a Trifluorophosphane Platinum(II) Complex by P-F Bond Activation of Phosphorus Pentafluoride with a Pt0 Complex. (2017) (5)
- Generation of 1,2-azaboretidines via reduction of ADC borane adducts (2015) (5)
- Novel organocycloborates via Grignard reagents. (2004) (5)
- Facile Access to Substituted 1,4‐Diaza‐2,3‐Diborinines (2020) (5)
- Linear dicoordinate beryllium: a 9Be solid-state NMR study of a discrete zero-valent s-block beryllium complex (2018) (5)
- 2‐ and 2,7‐Substituted para‐N‐Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double‐Stranded (ds) DNA (2020) (5)
- Ein planar vierfach koordiniertes Boratom als Ligand für vier Metalle (2012) (5)
- Highly Colored Boron‐Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates (2021) (5)
- Reversible Insertion von Platin in Münzmetall-Halogen-Bindungen† (2012) (5)
- Bithiophene‐Cored, mono‐, bis‐, and tris‐(Trimethylammonium)‐Substituted, bis‐Triarylborane Chromophores: Effect of the Number and Position of Charges on Cell Imaging and DNA/RNA Sensing (2021) (5)
- Coligand role in the NHC nickel catalyzed C–F bond activation: investigations on the insertion of bis(NHC) nickel into the C–F bond of hexafluorobenzene† (2020) (5)
- Preparation and structural characterization of transition-metal complexes featuring the cymantrenyl(bromo)boryl ligand. (2006) (5)
- sp2—sp3 Diboranes: Astounding Structural Variability and Mild Sources of Nucleophilic Boron for Organic Synthesis (2015) (5)
- Stable Actinide π Complexes of a Neutral 1,4‐Diborabenzene (2020) (5)
- Synthesis and Structural Characterization of the Dinuclear Beryllium Species [Be2Cl2(μ-Cl)2(PCy3)2] (2011) (5)
- MeCAAC=N−: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand (2019) (5)
- Enantioselective synthesis of tricyclic amino acid derivatives based on a rigid 4-azatricyclo[5.2.1.02,6]decane skeleton (2009) (4)
- Correction to "Pyrene-Fused [7]Helicenes Connected via Hexagonal and Heptagonal Rings: Stereospecific Synthesis and Chiroptical Properties". (2022) (4)
- Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium. (2013) (4)
- Evidence for Borylene Carbonyl (LHB═C═O) and Base-Stabilized (LHB═O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2. (2022) (4)
- Boranediyl‐ and Diborane(4)‐1,2‐diyl‐Bridged Platinum A‐Frame Complexes (2020) (4)
- Tuning phenoxyl-substituted diketopyrrolopyrroles from quinoidal to biradical ground states through (hetero-)aromatic linkers (2020) (4)
- Mono- and Dianion of a Bis(benzobuta)tetraazapentacene Derivative. (2019) (4)
- Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens. (2019) (4)
- Isolierung und Charakterisierung von kristallinen, neutralen Diboran(4)‐Radikalen (2018) (4)
- Molybdenum-Boron Bonds in the Crystal – Structural Characterization of K[(η5-C5H5)Mo(CO)3] and[(η5-C5H5) (OC)3Mo-{B(NMe2)-B(NMe2)Br}] (2010) (4)
- Aufbau einer B‐C‐Doppelbindung in der Koordinationssphäre des Platins: ein Alkylidenborylligand, der isoelektronisch zu neutralen Aminoborylenen ist (2014) (4)
- Synthesis and Structure of New [3]Silametallocenophanes of Group 8 Metals (2012) (4)
- Isolierung und Reaktivität eines s‐Block‐Metall‐Antiaromaten (2021) (4)
- Synthesis and Structure of Group IV Distanna[2]metallocenophanes (2014) (4)
- Borylene Complexes as Reagents in Organic and Organometallic Synthesis (2010) (4)
- Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling (2019) (4)
- A Base-stabilized Iodoborylene Complex of Platinum(II) (2013) (4)
- Electrochemical Behavior and Redox Chemistry of Boroles (2015) (4)
- First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies. (2019) (4)
- Oxoboryl Complexes: Boron—Oxygen Triple Bonds Stabilized in the Coordination Sphere of Platinum. (2010) (4)
- Transition-Metal Complexes of Boron — New Insights and Novel Coordination Modes (2006) (4)
- Spät aber mit Stil: Synthese und Charakterisierung der ersten Übergangsmetall‐Fluorborylenkomplexe (2010) (4)
- Sterically demanding hetero-substituted [2]borametallocenophanes of group IV metals: synthesis, structure and reactivity. (2011) (4)
- Hexahalogendiborat‐Dianionen: Eine neue Klasse binärer Borhalogenide (2019) (4)
- Enhanced Optical Properties of Azaborole Helicenes by Lateral and Helical Extension (2022) (4)
- NHC-Stabilized 1,2-Dihalodiborenes: Synthesis, Characterization, and Reactivity Toward Elemental Chalcogens. (2021) (3)
- Intensiv farbige Bor‐dotierte Thiazolthiazole durch reduktive Dimerisierung von Borisothiocyanaten (2021) (3)
- The Dimethylbismuth Cation: Entry Into Dative Bi−Bi Bonding and Unconventional Methyl Exchange (2021) (3)
- C–C versus C–H Activation: Understanding How the Carbene π-Accepting Ability Controls the Intramolecular Reactivities of Mono(carbene)-Stabilized Borylenes (2021) (3)
- Zinc‐[7]helicenocyanine and Its Discrete π‐Stacked Homochiral Dimer (2021) (3)
- Ein zweikerniger 1,1′‐Bis(boratabenzol)‐Komplex: beispiellose intramolekulare Metall‐Metall‐Kommunikation durch eine B‐B‐Bindung (2016) (3)
- Inside Back Cover: Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical (Angew. Chem. Int. Ed. 21/2014) (2014) (3)
- Tin-Bridged ansa-Metallocenes of the Late Transition Metals Cobalt and Nickel: Preparation, Molecular and Electronic Structures, and Redox Chemistry (2014) (3)
- Boron-Doped α-Oligo- and Polyfurans: Highly Luminescent Hybrid Materials, Color-Tunable through the Doping Density (2021) (3)
- Phosphine-Substituted Diborane(4)yl Complexes of Tungsten (2006) (3)
- Cleavage of BN triple bonds by main group reagents. (2018) (3)
- Selective mono- and dimetallation of a group 3 sandwich complex. (2019) (3)
- trans‐Selective Insertional Dihydroboration of a cis‐Diborene: Synthesis of Linear sp3‐sp2‐sp3‐Triboranes and Subsequent Cationization (2019) (3)
- Synthesis of Catechol‐, Pinacol‐, and Neopentylglycolborane Through the Heterogeneous Catalytic B—B Hydrogenolysis of Diboranes(4). (2014) (3)
- Synthesis and Crystal Structure of 1,3-Diphenyl-2-ferrocenyl-1,3,2-diazabora-[ 3]ferrocenophane (2008) (3)
- Crystal structure of (3S*,4R*)-4-fluoro-3-(4-methoxyphenyl)-1-oxo-2-phenyl-1,2,3,4-tetrahydroisoquinoline-4-carboxylic acid (2017) (3)
- Intriguing migrations in transient iminoborane adducts: two new pathways to aminoboranes. (2018) (3)
- Investigations on Chemical Vapour Deposition of Magnesium‐Boron‐Containing Metal‐Organic Precursors (2007) (3)
- Reduktion und Umlagerung eines Bor(I)‐Carbonylkomplexes (2020) (3)
- Cyclisierung eines 1,4‐Diborabutadienliganden mit CO unter Einbeziehung beider Atome (2015) (3)
- Synthesis, Photophysical and Electronic Properties of Mono‐, Di‐, and Tri‐Amino‐Substituted Ortho‐Perylenes, and Comparison to the Tetra‐Substituted Derivative (2020) (3)
- Rein metallische Lewis‐Paare (MOLPs) durch reversible Insertion von Ruthenium‐ und Osmiumfragmenten in Metall‐Bor‐Doppelbindungen (2014) (3)
- Synthesis of polyheterocyclic 1,1-diboryltriazenes by γ-nitrogen insertion of azides into activated B-B single bonds. (2020) (3)
- Electron‐Precise Coordination Modes of Boron‐Centered Ligands (2010) (3)
- Cover Picture: Bonding in a Borylene Complex Investigated by Photoionization and Dissociative Photoionization (Chem. Eur. J. 15/2012) (2012) (2)
- Conjugated Bis(triarylboranes) with Disconnected Conjugation (2021) (2)
- Phosphinoborylenes as stable sources of fleeting borylenes† (2020) (2)
- 1,2-Bis(dimethylamino)-1,2-bis(2,4,6-triisopropylphenyl)diborane(4) (2010) (2)
- Catalytic Activity of [2]Borametallocenophanes (2011) (2)
- Bor in energiebezogenen Prozessen und Anwendungen (2020) (2)
- Ein neutrales 1,4‐Diborabenzol als π‐Ligand in Actinoidkomplexen (2020) (2)
- 2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent. (2020) (2)
- Rethinking Borole Cycloaddition Reactivity (2021) (2)
- Cyclo‐Dipnictadialanes (2021) (2)
- Isolation of Neutral, Mono‐, and Dicationic B2P2 Rings by Diphosphorus Addition to a Boron−Boron Triple Bond (2021) (2)
- Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations. (2021) (2)
- Diborane(4) Azides: Surprisingly Stable Sources of Transient Iminoboranes (2020) (2)
- Synthesis of a bimetallic platinum-tungsten complex with a bridging micro-diboranyl-oxycarbyne moiety. (2008) (2)
- Hydrophosphination of boron–boron multiple bonds (2019) (2)
- Synthesis and Reactivity of a Dilithiated Molybdenum Half‐Sandwich Complex (2011) (2)
- Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties. (2019) (2)
- α,α'-Diamino-p-tetrafluoroquinodimethane: Stability of One- and Two-Electron Oxidized Species and Fixation of Molecular Oxygen. (2021) (2)
- Electronic structures of mixed sandwich ansa-complexes of chromium as studied by gas-phase absorption spectroscopy and quantum chemistry (2009) (2)
- Silylosmium Anions for the Synthesis of Borylosmium(II) Complexes by Salt Elimination (2016) (2)
- Single and double activation of acetone by isolobal B ^ N and B ^ B triple bonds † (2018) (2)
- Transition Metals as Lewis Bases: “Z-Type” Boron Ligands and Metal-to-Boron Dative Bonding (2011) (2)
- Boryl-functionalized σ-alkynyl and vinylidene rhodium complexes: synthesis and electronic properties. (2014) (2)
- π‐Complexes of Diborynes with Main Group Atoms (2020) (2)
- Oxidative addition of arsenic halides to platinum(0). (2019) (2)
- Innenrücktitelbild: Deutliche Belege für Ein‐Elektronen‐Übertragungen in der Boryl‐Anionenchemie: Isolierung und Reaktivität eines neutralen Borolradikals (Angew. Chem. 21/2014) (2014) (2)
- Innenrücktitelbild: Reversible photochemische und thermische Isomerisierung von Azaboratabisnorcaradien zu Azaborabenzotropyliden (Angew. Chem. 34/2014) (2014) (1)
- Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species (2022) (1)
- Base‐Mediated Radical Borylation of Alkyl Sulfones (2021) (1)
- Synthesis and characterisation of boranediyl- and diboranediyl-bridged diplatinum A-frame complexes. (2021) (1)
- Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes (2019) (1)
- Disclosing Cyclic(Alkyl)(Amino)Carbenes as One‐Electron Reductants: Synthesis of Acyclic(Amino)(Aryl)Carbene‐Based Kekulé Diradicaloids (2022) (1)
- Tetraiododiborane(4) (B2I4) is a Polymer Based on sp3 Boron in the Solid State (2019) (1)
- Insertion of Chalcogens and Bis(tert-butylisonitrile)palladium(0) into a Strained Ruthenium Half-sandwich Complex (2012) (1)
- Ansa-Complexes of [Mn(η(5) -C5 H5 )(η(6) -C6 H6 )]: Preparation, Characterization, and Reactivity of [n]Manganoarenophanes (n=1, 2, 3). (2015) (1)
- An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry (2021) (1)
- Reversible σ‐Borane‐to‐Borylene Transformation: A Little Something for Everyone (2009) (1)
- Rhodium‐Mediated Stoichiometric Synthesis of Mono‐, Bi‐, and Bis‐1,2‐Azaborinines: 1‐Rhoda‐3,2‐azaboroles as Reactive Precursors (2021) (1)
- Lithiumboryl — A Synthon for a Nucleophilic Boryl Anion (2007) (1)
- cyclo-Tri-μ-oxido-tris{[(η5,η5)-1,2-bis(cyclopentadienyl)-1,1,2,2-tetramethyldisilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene (2011) (1)
- Synthesis and Reactivity of Bora‐ and Borata‐Benzenes (2019) (1)
- Methyl Viologens of Bis‐(4’‐Pyridylethynyl)Arenes – Structures, Photophysical and Electrochemical Studies, and their Potential Application in Biology (2022) (1)
- Crystal structure of μ-1κC:2(η2)-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chloridoborylene-1:2κ2 B:B-[1(η5)-pentamethylcyclopentadienyl](tricyclohexylphosphane-2κP)iron(II)platinum(II) benzene monosolvate (2014) (1)
- Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond (2020) (1)
- Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene (2022) (1)
- Electron‐Rich EDOT Linkers in Tetracationic bis‐Triarylborane Chromophores: Influence on Water Stability, Biomacromolecule Sensing, and Photoinduced Cytotoxicity (2022) (1)
- NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions (2022) (1)
- Single and double activation of acetone by isolobal BN and BB triple bonds (2018) (1)
- Platinum‐Templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3‐Dienes and a Butatriene (2021) (1)
- Small HOMO-LUMO Gap and Intramolecular B – B Hydroarylation by Diborene / Anthracene Orbital Intercalation (2017) (1)
- mmetrical B 2 E 2 and B 2 E 3 heterocycles by borylene insertion into boradichalcogeniranes † (2019) (1)
- Backbone-controlled LUMO energy induces intramolecular C–H activation in ortho-bis-9-borafluorene-substituted phenyl and o-carboranyl compounds leading to novel 9,10-diboraanthracene derivatives (2022) (1)
- Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding. (2022) (1)
- Hybrid Inorganic-Organic Cross-Metathesis between Diborenes and Acetylene. (2021) (1)
- Inside Back Cover: Reversible Photochemical and Thermal Isomerization of Azaboratabisnorcaradiene to Azaborabenzotropilidene (Angew. Chem. Int. Ed. 34/2014) (2014) (1)
- Bifuran-bridged bisboranes: highly luminescent B-doped oligohetarenes (2020) (1)
- Synthesis and reactivity of [2]disilaniobocenophanes (2011) (1)
- Isolierung neutraler, mono‐ und dikationischer B 2 P 2 ‐Ringe durch Addition eines Diphosphans an eine Bor‐Bor‐Dreifachbindung (2021) (1)
- ZUR UMSETZUNG VON BIS(ETA 5-CYCLOPENTADIENYL)DIHYDRIDOWOLFRAM MIT HALOGENBORANEN (1996) (1)
- Ein elektronenpräziser μ3‐Boridkomplex mit tetraedrischer Struktur (2013) (1)
- Modulation of the Naked‐Eye and Fluorescence Color of a Protonated Boron‐Doped Thiazolothiazole by Anion‐Dependent Hydrogen Bonding (2022) (1)
- Building Electron‐Precise Boron‐Boron Single Bonds: Imposing Monogamy on a Promiscuous Element (2015) (1)
- Spontane trans ‐selektive Transferhydrierung von unpolaren B=B‐Doppelbindungen (2019) (1)
- Diboran(4)azide als stabile Quelle für kurzlebige Iminoborane (2020) (1)
- Titelbild: Ein T‐förmiger Platin(II)borylkomplex als Vorstufe für einen Platinkomplex mit einem basenstabilisierten Borylenliganden (Angew. Chem. 35/2005) (2005) (1)
- Stabilisierung planarer Cyclopenten‐4‐yl‐Kationen durch Hyperkonjugation und π‐Delokalisierung (2020) (1)
- Trans ‐selektive Dihydroborierung eines cis ‐Diborens durch Insertion: Synthese eines linearen sp 3 ‐sp 2 ‐sp 3 ‐Triborans und anschließende Kationisierung (2020) (1)
- Addukte des Stammboraphosphaketens H 2 BPCO und deren Insertionsreaktionen mittels Decarbonylierung (2021) (1)
- Diphosphino‐Functionalized 1,8‐Naphthyridines: a Multifaceted Ligand Platform for Boranes and Diboranes (2021) (1)
- Synthesis of a Bicyclic Diborane (III) by Selective Boron Carbon Bond Formation. (2013) (0)
- Thetrans-influence of the boryl ligand in square-planar platinum(II) complexes (2012) (0)
- Dicyclohexyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine–dichlorophenylborane (2009) (0)
- Synthesis and characterization of diborane compounds (2012) (0)
- Innenrücktitelbild: Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN‐Isostere von Carben‐Alkin‐Addukten (Angew. Chem. 5/2015) (2015) (0)
- Frontispiz: Das Dimethylbismut‐Kation: Zugang zu dativen Bi‐Bi‐Bindungen und unkonventionellem Methylaustausch (2021) (0)
- Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage (2022) (0)
- Metal-metal bonding in the μ-BMn2triangular motif of [μ-BtBu (η5-C5H5)Mn(CO)22] (2007) (0)
- Bindungsstärkende Rückbindung in Aminoborylen‐stabilisierten Aminoborylenen: an der Grenze zwischen Borylenen und Diborenen (2019) (0)
- Fusion of Aza‐ and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials (2022) (0)
- On the Reactivity of Mes*P(PMe3) towards Aluminum(I) Compounds - Evidence for the intermediate Formation of Phosphaalumenes. (2023) (0)
- On the Reactivity of Phosphaalumenes towards C-C Multiple Bonds. (2022) (0)
- Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes? (2022) (0)
- Group VI Metal Aminoborylene Complex‐Catalyzed Demercuration Reactions of Bis(alkynyl)mercurials. (2008) (0)
- Inside Back Cover: The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene–Alkyne Adducts (Angew. Chem. Int. Ed. 5/2015) (2015) (0)
- Boron‐ versus Nitrogen‐Centered Nucleophilic Reactivity of (Cyano)hydroboryl Anions: Synthesis of Cyano(hydro)organoboranes and 2‐Aza‐1,4‐diborabutatrienes (2021) (0)
- CCDC 1500457: Experimental Crystal Structure Determination (2016) (0)
- 1,2-Dialkynyldiboranes(4): B-B versus CC bond reactivity. (2022) (0)
- CCDC 278304: Experimental Crystal Structure Determination (2006) (0)
- Chromoarenophanes : ansa Complexes Derived from [ Cr ACHTUNGTRENNUNG ( h 5C 5 H 5 ) ACHTUNGTRENNUNG ( h 6C 6 H 6 ) ] (2012) (0)
- N-Heterocyclic carbene and cyclic (alkyl)(amino)carbene complexes of vanadium(III) and vanadium(V). (2022) (0)
- Metal‐Free Intermolecular C−H Borylation of N‐Heterocycles at B−B Multiple Bonds (2022) (0)
- Ein neutrales Beryllium(I)‐Radikal (2021) (0)
- Dibortetraiodid (B 2 I 4 ) ist im Festkörper ein Polymer aus sp 3 ‐hybridisiertem Bor (2020) (0)
- Probing the Potential of Hitherto Unexplored Base-Stabilized Borylenes in Dinitrogen Binding. (2022) (0)
- Cover Feature: Synthesis, Photophysical and Electronic Properties of New Red‐to‐NIR Emitting Donor–Acceptor Pyrene Derivatives (Chem. Eur. J. 2/2020) (2020) (0)
- Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds. (2020) (0)
- One- and two-electron reduction of triarylborane-based helical donor–acceptor compounds (2021) (0)
- Stable Two‐Legged Parent Piano‐Stool and Mixed Diborabenzene‐E4 (E=P, As) Sandwich Complexes of Group 8 (2022) (0)
- The Radical Anion, Dianion and Electron Transport Properties of Tetraiodotetraazapentacene (2022) (0)
- Cover Feature: Recent Developments in Azaborinine Chemistry (Eur. J. Inorg. Chem. 38‐39/2017) (2017) (0)
- Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes. (2020) (0)
- -Triboranes and Subsequent Cationization (2019) (0)
- Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species. (2020) (0)
- Recent Developments in the Chemistry of Antiaromatic Boroles (2012) (0)
- SYNTHESIS AND STRUCTURE OF 1BORAMETALLOCENOPHANES OF TITANIUM, ZIRCONIUM, AND HAFNIUM (1999) (0)
- Cover Picture: A T‐Shaped Platinum(II) Boryl Complex as the Precursor to a Platinum Compound with a Base‐Stabilized Borylene Ligand (Angew. Chem. Int. Ed. 35/2005) (2005) (0)
- Organometallic Chemistry in Europe (2018) (0)
- Carbodicarbenes and Striking Redox Transitions of their Conjugate Acids: Influence of NHC versus CAAC as Donor Substituents (2022) (0)
- CCDC 737852: Experimental Crystal Structure Determination (2010) (0)
- The Search for Enhanced σ‐Donor Ligands to Stabilize Boron‐Boron Multiple Bonds (2023) (0)
- Synthesis, structure and insertion reactivity of Lewis acidic 9-aluminafluorenes. (2021) (0)
- REAKTIONEN VON (ETA 5-C5R5)2WH2 MIT BORANEN (1999) (0)
- ron – boron triple bond using spin – spin coupling measured from 11 B solid-state NMR spectroscopy † (2015) (0)
- Diverse ring-opening reactions of rhodium η4-azaborete complexes† (2020) (0)
- Bis(μ-diisopropylphosphanido-κ2 P:P)bis[hydrido(triisopropylphosphane-κP)platinum(II)] (2012) (0)
- N,N-Diethylpyrrolidinium pentachloro(tetrahydrofuran)zirconate(IV) (2006) (0)
- Aromatic 1,2-Azaborinin-1-yls as Electron-Withdrawing Anionic Nitrogen Ligands for Main Group Elements. (2022) (0)
- Excited states and spin-orbit coupling in chalcogen substituted perylene diimides and their radical anions. (2022) (0)
- Frontispiece: The Dimethylbismuth Cation: Entry Into Dative Bi−Bi Bonding and Unconventional Methyl Exchange (2021) (0)
- SYNTHESIS AND STRUCTURE OF THE FIRST ETA 1-BORAZINE COMPLEXES (1998) (0)
- CO2 Binding and Splitting by Non-Polar Multiple Bonds (2018) (0)
- Controlled Synthesis of Oligomers Containing Main‐Chain B(sp2)‐B(sp2) Bonds (2021) (0)
- Rydberg state mediated multiphoton ionization of (η7-C7H7)(η5-C5H5)Cr: DFT-supported experimental insights into the molecular and electronic structures of excited sandwich complexes. (2019) (0)
- Reactions of a [1],[1]Disilamolybdenocenophane with Unsaturated Compounds (2013) (0)
- CCDC 1042593: Experimental Crystal Structure Determination (2016) (0)
- Reactivity of cyano- and isothiocyanatoborylenes: metal coordination, one-electron oxidation and boron-centred Brønsted basicity† (2021) (0)
- SYNTHESIS AND STRUCTURE OF THE FIRST 1BORATITANOCENOPHANES (1999) (0)
- A bis-NHC–CAAC dimer derived dicationic diradical (2022) (0)
- Nitronyl Nitroxide Bifunctionalized Electron-Poor Chromophores: Synthesis of Stable Dye Biradicals by Lewis Acid Promoted Desilylation. (2021) (0)
- Facile synthesis of a stable dihydroboryl (2019) (0)
- Structure and bonding of proximity‐enforced main‐group dimers stabilized by a rigid naphthyridine diimine ligand (2022) (0)
- Unprecedented reactivity of the bridged borylene complexes [mu-BCl((eta(5)-C(5)H(4)Me)Mn(CO)(2))(2)] toward pyridine. (2003) (0)
- Harnessing the electronic differences between CAAC-stabilised 1,4-diborabenzene and 9,10-diboraanthracene for synthesis. (2021) (0)
- Synthesis , structure and insertion reactivity of Lewis acidic 9-alumina fl uorenes † (2021) (0)
- The Radical Anion and Dianion of Benzo[3,4]cyclobuta[1,2-b]phenazine. (2023) (0)
- rac‐(Diisopropylamino)(1‐indenyl)(isopropylamino)borane (2005) (0)
- Contents list. (2017) (0)
- Air and Moisture Stable para- and ortho-Quinodimethane Derivatives Derived from bis-N-Heterocyclic Olefins. (2023) (0)
- CCDC 749579: Experimental Crystal Structure Determination (2010) (0)
- Diboramacrocycles: reversible borole dimerisation–dissociation systems (2022) (0)
- The Reaction of (Butadiene)zirconocene with Iminoborane. (1991) (0)
- CCDC 719794: Experimental Crystal Structure Determination (2010) (0)
- Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and CC triple bond scission (2021) (0)
- Transition Metal Borylene Complexes (2013) (0)
- CCDC 1582242: Experimental Crystal Structure Determination (2018) (0)
- Direct Synthetic Route to Functionalized 1,2‐Azaborinines. (2014) (0)
- Front Cover: Twisting versus Delocalization in CAAC‐ and NHC‐Stabilized Boron‐Based Biradicals: The Roles of Sterics and Electronics (Chem. Eur. J. 16/2021) (2021) (0)
- [n]Borametalloarenophanes (n = 1, 2): Strained Systems with Uncommon Reactivity Patterns Unexpected Outcomes of the Oxidation of (Pentafluorophenyl)triphenylphosphanegold(I) The Question of cis versus trans Configuration in Octahedral Metal Diketonates: A (2012) (0)
- Trapping of a Transient Base-Stabilised Alumylene and Alumylene-type Reactivity of a Self-Stabilising Dialumene towards Organic Azides. (2023) (0)
- Dialkynyldiboranes(4) and the selectable reactivity of their C-H, C[triple bond, length as m-dash]C and B-B bonds. (2021) (0)
- Insights into structure–property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides (2023) (0)
- Synthesis and Crystal Structure of (2008) (0)
- The First Monomeric Prochiral Tin(II) Complexes Sn(N(SiMe3)2)X (X = OC6H2But2-2,6-Me-4, 1 or cyclicNCMe2(CH2)3CMe2, 2). The X-Ray Structure of 1 and Oxidative Addition Reaction of 2. (1992) (0)
- Synthesis and Fluorescence Studies of Diborene Coinage Metal Complexes. (2022) (0)
- A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor. (2022) (0)
- Spontaneous N2-diboranylation of [W(N2)2(dppe)2] with B2Br4(SMe2)2. (2022) (0)
- Heron 8: Reaktive Intermediate und ungewöhnliche Moleküle (2019) (0)
- Die Reaktion von (Butadien)zirconocen mit Iminoboran (1990) (0)
- Highly Strained Metallocenophanes: Synthesis and Ring-Opening of Sulfur-, Selenium- and Boron-Bridged [1]Ferrocenophanes (1998) (0)
- (2 + 2) Cycloaddition of Iminoboranes to a Neopentylidenetantalum Complex. (1990) (0)
- Synthesis and reactivity of NHC-coordinated phosphinidene oxide. (2021) (0)
- Probing the Boundaries between Lewis‐Basic and Redox Behavior of a Parent Borylene (2021) (0)
- ortho-Methylated Tribenzotriquinacenes — Paving the Way to Curved Carbon Networks. (2012) (0)
- CCDC 737851: Experimental Crystal Structure Determination (2010) (0)
- CCDC 719791: Experimental Crystal Structure Determination (2010) (0)
- rac-(tert-Butylamino)(diisopropylamino)(9-fluorenyl)borane (2005) (0)
- Nichtmetalle neu aufgelegt: Chemie der Nichtmetalle. Von R. Steudel Y. Drozdova. De Gruyter, Berlin, 1998. 575 S., geb., 138,‐ OM. ISBN 3‐1102‐5902‐3 (2000) (0)
- 1,2-Disilabicyclo[1.1.1]pentan-4-ones from a Disilenide and Acryloyl Chlorides. (2014) (0)
- Azide-alkyne cycloadditions with an electronically activated alkyne: indole formation via 1-aryl-1,2,3-triazole-derived imino carbenes. (2022) (0)
- Generation of a transient base-stabilised arylalumylene for the facile deconstruction of aromatic molecules (2022) (0)
- Twisting versus Delocalization in CAAC- and NHC-Stabilized Boron-Based Biradicals: The Roles of Sterics and Electronics. (2021) (0)
- Very High Short-Circuit Currents in Squaraine Solar Cells (2010) (0)
- Construction of a Diverse Range of Boron Heterocycles via Ring Expansion of a Carboranyl-Substituted 9-Borafluorene. (2023) (0)
- Cover Picture: Platinum trans‐Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center (Chem. Eur. J. 6/2015) (2015) (0)
- CCDC 719793: Experimental Crystal Structure Determination (2010) (0)
- Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission. (2021) (0)
- BIS(DIMETHYLAMINO)BORYLMETHYLDIMETHYLPHOSPHANE AS LIGAND IN TRANSITION METAL COMPLEXES (1997) (0)
- Highly Strained Arene-Fused 1,2-Diborete Biradicaloid. (2022) (0)
- Reactivity of Terminal Iron Borylenes and Bis(borylenes) with Carbodiimides: Cycloaddition, Metathesis, Insertion and C−H Activation Pathways (2021) (0)
- Platin‐vermittelte Kupplung von B=N‐Einheiten: Synthese von BNBN‐Analoga von 1,3‐Dienen und Butatrien (2021) (0)
- CCDC 719790: Experimental Crystal Structure Determination (2010) (0)
- Frontispiece: Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ ME Multiple Bonds (2014) (0)
- Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes? (2018) (0)
- Metallfreie intermolekulare C‐H‐Borylierung von N ‐Heterocyclen an B‐B‐Mehrfachbindungen (2022) (0)
- Synthesis of novel six-, seven- and eight-membered aluminum-containing rings by alumole ring expansion. (2021) (0)
- Transition-Metal Boryl and Borylene Complexes (1997) (0)
- Zur Bildung eines Fe2(CO)6‐Komplexes mit (Boryloxy)allyl‐Brücke (1994) (0)
- Two derivatives of phenylpyridyl-fused boroles with contrasting electronic properties: decreasing and enhancing the electron accepting ability. (2020) (0)
- Treatment of actinomycosis in Cattle with special reference to bone actinomycosis. (1964) (0)
- CCDC 719792: Experimental Crystal Structure Determination (2010) (0)
- Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study. (2023) (0)
- Correction to 2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent. (2020) (0)
- Isolation of diborenes and their 90°-twisted diradical congeners (2018) (0)
- Cover Picture: Antiaromaticity to Aromaticity: From Boroles to 1,2‐Azaborinines by Ring Expansion with Azides (Chem. Eur. J. 32/2014) (2014) (0)
- C-C and C-N Bond Activation, Lewis-Base Coordination and One- and Two-Electron Oxidation at a Linear Aminoborylene. (2022) (0)
- Cover Picture: Atropodiastereoselective Cleavage of Configurationally Unstable Biaryl Lactones with Amino Acid Esters (Eur. J. Org. Chem. 19/2006) (2006) (0)
- Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring. (1994) (0)
- Photoelectron Photoion Coincidence Spectroscopy of NCl3 and NCl2 (2021) (0)
- Bis(η6-trimethylsilylbenzene)chromium(0) (2006) (0)
- Die Verkettung zweier Stickstoffmoleküle (2020) (0)
- Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium. (2023) (0)
- Das Dimethylbismut‐Kation: Zugang zu dativen Bi‐Bi‐Bindungen und unkonventionellem Methylaustausch (2021) (0)
- Frontispiece: An Iterative Divergent Approach to Conjugated Starburst Borane Dendrimers (2020) (0)
- [(Eta5-C5H5)(OC)3V=B=N(SiMe3)2: a half-sandwich complex with a terminal borylene ligand. (2003) (0)
- CCDC 1822145: Experimental Crystal Structure Determination (2018) (0)
- CCDC 821488: Experimental Crystal Structure Determination (2011) (0)
- Further reactions of iminoboranes RB.tplbond.NR' with neopentylidenetantalum complexes. (1993) (0)
- Achieving Control over the Reduction/Coupling Dichotomy of N2 by Boron Metallomimetics. (2023) (0)
- Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide. (2022) (0)
- Herstellung von Boranaloga von Enaminen über Hydroaminierung einer Bor‐Bor‐Dreifachbindung (2020) (0)
- Heterogen aber empfehlenswert: Moderne Anorganische Chemie. Von C. Janiak, T. M. Klapötke und H.-J. Meyer. De Gruyter, Berlin, 1998. 750 S., geb., 128,- DM. ISBN 3-1101-5672-5. (2000) (0)
- Evidence for Borylene Carbonyl (LHBCO) and Base-Stabilized (LHBO) and Base-Free Oxoborane (RBO) Intermediates in the Reactions of Diborenes with CO2 (2022) (0)
- Thienyl-Substituted Diboranes(4): Electronic Stabilization of Radicals versus Increased Reactivity towards Bond Activation. (2023) (0)
- Fashionably Late: Synthesis and Characterization of Transition‐Metal—Fluoroborylene Complexes (2010) (0)
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