Holger Dau
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(Suggest an Edit or Addition)Holger Dau's Published Works
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Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis (2010) (1357)
- Oxygen Evolution Reaction Dynamics, Faradaic Charge Efficiency, and the Active Metal Redox States of Ni-Fe Oxide Water Splitting Electrocatalysts. (2016) (724)
- A Janus cobalt-based catalytic material for electro-splitting of water. (2012) (699)
- Reversible amorphization and the catalytically active state of crystalline Co3O4 during oxygen evolution (2015) (554)
- A fluorometric method for the differentiation of algal populations in vivo and in situ (2004) (515)
- Tracking Catalyst Redox States and Reaction Dynamics in Ni-Fe Oxyhydroxide Oxygen Evolution Reaction Electrocatalysts: The Role of Catalyst Support and Electrolyte pH. (2017) (392)
- Photosynthetic O2 Formation Tracked by Time-Resolved X-ray Experiments (2005) (392)
- Electrosynthesis, functional, and structural characterization of a water-oxidizing manganese oxide (2012) (373)
- A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis (2015) (350)
- The manganese complex of photosystem II in its reaction cycle—Basic framework and possible realization at the atomic level (2008) (346)
- Principles, efficiency, and blueprint character of solar-energy conversion in photosynthetic water oxidation. (2009) (315)
- MOLECULAR MECHANISMS AND QUANTITATIVE MODELS OF VARIABLE PHOTOSYSTEM II FLUORESCENCE (1994) (283)
- Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction (2018) (276)
- Artificial Photosynthesis as a Frontier Technology for Energy Sustainability (2013) (252)
- X-ray absorption spectroscopy to analyze nuclear geometry and electronic structure of biological metal centers—potential and questions examined with special focus on the tetra-nuclear manganese complex of oxygenic photosynthesis (2003) (252)
- Synthetic manganese–calcium oxides mimic the water-oxidizing complex of photosynthesis functionally and structurally (2011) (252)
- Cobalt-oxo core of a water-oxidizing catalyst film. (2009) (251)
- Active mixed-valent MnO(x) water oxidation catalysts through partial oxidation (corrosion) of nanostructured MnO particles. (2013) (233)
- Noncovalent modification of carbon nanotubes with pyrene-functionalized nickel complexes: carbon monoxide tolerant catalysts for hydrogen evolution and uptake. (2011) (229)
- Electrochemical water splitting by layered and 3D cross-linked manganese oxides: correlating structural motifs and catalytic activity (2013) (228)
- Layered manganese oxides for water-oxidation: alkaline earth cations influence catalytic activity in a photosystem II-like fashion (2012) (226)
- High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity (2015) (225)
- Structural models of the manganese complex of photosystem II and mechanistic implications. (2012) (207)
- Water oxidation by amorphous cobalt-based oxides: in situ tracking of redox transitions and mode of catalysis (2015) (193)
- Recent developments in research on water oxidation by photosystem II. (2012) (186)
- The tetra-manganese complex of photosystem II during its redox cycle - X-ray absorption results and mechanistic implications. (2001) (185)
- Rapid Loss of Structural Motifs in the Manganese Complex of Oxygenic Photosynthesis by X-ray Irradiation at 10–300 K* (2006) (171)
- On the structure of the manganese complex of photosystem II: extended-range EXAFS data and specific atomic-resolution models for four S-states (2008) (166)
- Eight steps preceding O-O bond formation in oxygenic photosynthesis--a basic reaction cycle of the Photosystem II manganese complex. (2007) (162)
- Water oxidation by amorphous cobalt-based oxides: volume activity and proton transfer to electrolyte bases. (2014) (159)
- Alternating electron and proton transfer steps in photosynthetic water oxidation (2012) (157)
- Heterogeneous water oxidation: surface activity versus amorphization activation in cobalt phosphate catalysts. (2015) (146)
- X-ray absorption spectroscopy on layered photosystem II membrane particles suggests manganese-centered oxidation of the oxygen-evolving complex for the S0-S1, S1-S2, and S2-S3 transitions of the water oxidation cycle. (1998) (142)
- Water oxidation by electrodeposited cobalt oxides--role of anions and redox-inert cations in structure and function of the amorphous catalyst. (2012) (139)
- A structurally versatile nickel phosphite acting as a robust bifunctional electrocatalyst for overall water splitting (2018) (137)
- Energetics of primary and secondary electron transfer in Photosystem II membrane particles of spinach revisited on basis of recombination-fluorescence measurements. (2005) (129)
- Fragments of layered manganese oxide are the real water oxidation catalyst after transformation of molecular precursor on clay. (2014) (119)
- Helical cobalt borophosphates to master durable overall water-splitting (2019) (118)
- An oxocobalt(IV) complex stabilized by Lewis acid interactions with scandium(III) ions. (2011) (117)
- Spectroscopic identification of active sites for the oxygen evolution reaction on iron-cobalt oxides (2017) (117)
- Uncovering the prominent role of metal ions in octahedral versus tetrahedral sites of cobalt–zinc oxide catalysts for efficient oxidation of water (2016) (109)
- Direct Electrolytic Splitting of Seawater: Activity, Selectivity, Degradation, and Recovery Studied from the Molecular Catalyst Structure to the Electrolyzer Cell Level (2018) (106)
- Nickel-oxido structure of a water-oxidizing catalyst film. (2011) (99)
- Chlorophyll fluorescence transients of Photosystem II membrane particles as a tool for studying photosynthetic oxygen evolution (2004) (97)
- Structural consequences of ammonia binding to the manganese center of the photosynthetic oxygen-evolving complex: an X-ray absorption spectroscopy study of isotropic and oriented photosystem II particles. (1995) (95)
- New trends in photobiology: Short-term adaptation of plants to changing light intensities and its relation to Photosystem II photochemistry and fluorescence emission (1994) (95)
- New aspects of operando Raman spectroscopy applied to electrochemical CO2 reduction on Cu foams. (2019) (93)
- The photosystem II‐associated Cah3 in Chlamydomonas enhances the O2 evolution rate by proton removal (2008) (92)
- Experimental and quantum chemical characterization of the water oxidation cycle catalysed by [RuII(damp)(bpy)(H2O)]2+ (2012) (89)
- Preparation protocols for high-activity photosystem II membrane particles of green algae and higher plants, pH dependence of oxygen evolution and comparison of the S2-state multiline signal by X-band EPR spectroscopy. (2000) (87)
- The structure of the manganese complex of Photosystem II in its dark-stable S1-state?EXAFS results in relation to recent crystallographic data (2004) (83)
- Uncovering The Role of Oxygen in Ni-Fe(OxHy) Electrocatalysts using In situ Soft X-ray Absorption Spectroscopy during the Oxygen Evolution Reaction (2019) (81)
- Water oxidation catalysis – role of redox and structural dynamics in biological photosynthesis and inorganic manganese oxides (2016) (75)
- Morphology and mechanism of highly selective Cu(II) oxide nanosheet catalysts for carbon dioxide electroreduction (2021) (74)
- Seven steps of alternating electron and proton transfer in photosystem II water oxidation traced by time-resolved photothermal beam deflection at improved sensitivity. (2015) (72)
- Extended protein/water H-bond networks in photosynthetic water oxidation. (2012) (71)
- Exciton equilibration and Photosystem II exciton dynamics — a fluorescence study on Photosystem II membrane particles of spinach (1996) (71)
- Structural Basis of Cyanobacterial Photosystem II Inhibition by the Herbicide Terbutryn* (2011) (70)
- The D1-D61N mutation in Synechocystis sp. PCC 6803 allows the observation of pH-sensitive intermediates in the formation and release of O₂ from photosystem II. (2012) (68)
- Structural and oxidation-state changes at its nonstandard Ni-Fe site during activation of the NAD-reducing hydrogenase from Ralstonia eutropha detected by X-ray absorption, EPR, and FTIR spectroscopy. (2005) (68)
- Spare quinones in the QB cavity of crystallized photosystem II from Thermosynechococcus elongatus. (2007) (62)
- Valinomycin sensitivity proves that light-induced thylakoid voltages result in millisecond phase of chlorophyll fluorescence transients. (2002) (62)
- Reactivity Determinants in Electrodeposited Cu Foams for Electrochemical CO2 Reduction. (2018) (61)
- Room-Temperature Energy-Sampling Kβ X-ray Emission Spectroscopy of the Mn4Ca Complex of Photosynthesis Reveals Three Manganese-Centered Oxidation Steps and Suggests a Coordination Change Prior to O2 Formation. (2016) (60)
- Structure and orientation of the oxygen-evolving manganese complex of green algae and higher plants investigated by X-ray absorption linear dichroism spectroscopy on oriented photosystem II membrane particles. (1998) (59)
- Correlation between structure and magnetic spin state of the manganese cluster in the oxygen-evolving complex of photosystem II in the S2 state: determination by X-ray absorption spectroscopy. (1994) (58)
- Screen-printed calcium-birnessite electrodes for water oxidation at neutral pH and an "electrochemical harriman series". (2014) (58)
- Bromide does not bind to the Mn4Ca complex in its S1 state in Cl(-)-depleted and Br(-)-reconstituted oxygen-evolving photosystem II: evidence from X-ray absorption spectroscopy at the Br K-edge. (2006) (58)
- Electronic structure of oxidized complexes derived from cis-[Ru(II)(bpy)2(H2O)2]2+ and its photoisomerization mechanism. (2011) (57)
- Light‐harvesting in Acaryochloris marina – spectroscopic characterization of a chlorophyll d‐dominated photosynthetic antenna system (1997) (57)
- H/D Isotope Effects Reveal Factors Controlling Catalytic Activity in Co-Based Oxides for Water Oxidation. (2019) (55)
- A noble metal-free proton-exchange membrane fuel cell based on bio-inspired molecular catalysts† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c4sc03774j Click here for additional data file. (2015) (54)
- Photosynthetic water oxidation at elevated dioxygen partial pressure monitored by time-resolved X-ray absorption measurements (2008) (52)
- Structural insights into the light-driven auto-assembly process of the water-oxidizing Mn4CaO5-cluster in photosystem II (2017) (52)
- Stepwise transition of the tetra-manganese complex of photosystem II to a binuclear Mn2(micro -O)2 complex in response to a temperature jump: a time-resolved structural investigation employing x-ray absorption spectroscopy. (2003) (51)
- A neodymium oxide nanoparticle-doped carbon felt as promising electrode for vanadium redox flow batteries (2018) (51)
- Electric field effect on the picosecond fluorescence of Photosystem II and its relation to the energetics and kinetics of primary charge separation (1992) (51)
- From molecular copper complexes to composite electrocatalytic materials for selective reduction of CO2 to formic acid (2015) (51)
- Functional Characterization and Quantification of the Alternative PsbA Copies in Thermosynechococcus elongatus and Their Role in Photoprotection* (2010) (51)
- Electrodeposited AgCu Foam Catalysts for Enhanced Reduction of CO2 to CO. (2019) (50)
- Shining light on integrity of a tetracobalt-polyoxometalate water oxidation catalyst by X-ray spectroscopy before and after catalysis. (2014) (50)
- Water oxidation by photosystem II: H(2)O-D(2)O exchange and the influence of pH support formation of an intermediate by removal of a proton before dioxygen creation. (2010) (49)
- Time-resolved X-ray spectroscopy leads to an extension of the classical S-state cycle model of photosynthetic oxygen evolution (2007) (49)
- Photosynthetic dioxygen formation studied by time-resolved delayed fluorescence measurements--method, rationale, and results on the activation energy of dioxygen formation. (2007) (48)
- Artificial Photosynthesis: Beyond Mimicking Nature. (2017) (47)
- Sequential and Coupled Proton and Electron Transfer Events in the S2 → S3 Transition of Photosynthetic Water Oxidation Revealed by Time-Resolved X-ray Absorption Spectroscopy. (2016) (47)
- Electric field effect on chlorophyll fluorescence and its relation to Photosystem II charge separation reactions studied by a salt-jump technique (1991) (47)
- Intermediates in assembly by photoactivation after thermally accelerated disassembly of the manganese complex of photosynthetic water oxidation. (2006) (42)
- Thermodynamic Limitations of Photosynthetic Water Oxidation at High Proton Concentrations* (2011) (42)
- Reduction of Unusual Iron-Sulfur Clusters in the H2-sensing Regulatory Ni-Fe Hydrogenase from Ralstonia eutropha H16* (2005) (40)
- Bridging-type changes facilitate successive oxidation steps at about 1 V in two binuclear manganese complexes--implications for photosynthetic water-oxidation. (2006) (40)
- Comparison of light induced and cell cycle dependent changes in the photosynthetic apparatus: A fluorescence induction study on the green alga Scenedesmus obliquus (1999) (40)
- Relationship between Photosynthesis and Plasmalemma Transport (1987) (39)
- The first room‐temperature X‐ray absorption spectra of higher oxidation states of the tetra‐manganese complex of photosystem II (2002) (39)
- Sulfido and cysteine ligation changes at the molybdenum cofactor during substrate conversion by formate dehydrogenase (FDH) from Rhodobacter capsulatus. (2015) (39)
- Nickel-iron catalysts for electrochemical water oxidation – redox synergism investigated by in situ X-ray spectroscopy with millisecond time resolution (2018) (39)
- Specific loss of the extrinsic 18 KDa protein from Photosystem II upon heating to 47 °C causes inactivation of oxygen evolution likely due to Ca release from the Mn-complex (2005) (39)
- Water oxidation by manganese oxides formed from tetranuclear precursor complexes: the influence of phosphate on structure and activity. (2014) (38)
- Protonation states in a cobalt-oxide catalyst for water oxidation: fine comparison of ab initio molecular dynamics and X-ray absorption spectroscopy results. (2011) (37)
- Formation of unexpectedly active Ni-Fe oxygen evolution electrocatalysts by physically mixing Ni and Fe oxyhydroxides. (2019) (37)
- Bromine K‐edge EXAFS studies of bromide binding to bromoperoxidase from Ascophyllum nodosum (1999) (37)
- Photosynthetic water oxidation at high O2 backpressure monitored by delayed chlorophyll fluorescence. (2005) (36)
- Evolving Highly Active Oxidic Iron(III) Phase from Corrosion of Intermetallic Iron Silicide to Master Efficient Electrocatalytic Water Oxidation and Selective Oxygenation of 5‐Hydroxymethylfurfural (2021) (36)
- The Molybdenum Active Site of Formate Dehydrogenase Is Capable of Catalyzing C-H Bond Cleavage and Oxygen Atom Transfer Reactions. (2016) (35)
- Does the structure of the water-oxidizing photosystem II-manganese complex at room temperature differ from its low-temperature structure? A comparative X-ray absorption study. (2000) (35)
- Geometric distortions in nickel (oxy)hydroxide electrocatalysts by redox inactive iron ions (2018) (35)
- Hydrophobic Nanoreactor Soft‐Templating: A Supramolecular Approach to Yolk@Shell Materials (2015) (35)
- The manganese complex of oxygenic photosynthesis: conversion of five-coordinated Mn(III) to six-coordinated Mn(IV) in the S2-S3 transition is implied by XANES simulations (2005) (34)
- Atomistic Texture of Amorphous Manganese Oxides for Electrochemical Water Splitting Revealed by Ab Initio Calculations Combined with X-ray Spectroscopy. (2015) (34)
- Principles, Efficiency, and Blueprint Character of Solar-Energy Conversion in Photosynthetic Water Oxidation (2010) (34)
- Water and bromide in the active center of vanadate-dependent haloperoxidases. (2000) (33)
- Electrosynthesis of Biomimetic Manganese-Calcium Oxides for Water Oxidation Catalysis--Atomic Structure and Functionality. (2016) (32)
- Operando Raman spectroscopy tracks oxidation-state changes in an amorphous Co oxide material for electrocatalysis of the oxygen evolution reaction. (2020) (32)
- Considerations on the mechanism of photosynthetic water oxidation – dual role of oxo-bridges between Mn ions in (i) redox-potential maintenance and (ii) proton abstraction from substrate water (2005) (32)
- Detecting structural transformation of cobalt phosphonate to active bifunctional catalysts for electrochemical water-splitting (2020) (32)
- [NiFe] and [FeS] cofactors in the membrane-bound hydrogenase of Ralstonia eutropha investigated by X-ray absorption spectroscopy: insights into O(2)-tolerant H(2) cleavage. (2011) (31)
- Adaptation of the Photosynthetic Apparatus of Anacystis nidulans to Irradiance and CO2-Concentration (1993) (31)
- Carboxylate Shifts Steer Interquinone Electron Transfer in Photosynthesis* (2010) (31)
- Substrate binding to vanadate-dependent bromoperoxidase from Ascophyllum nodosum: a vanadium K-edge XAS approach. (2004) (31)
- Temperature Dependence of the Catalytic Two- versus Four-Electron Reduction of Dioxygen by a Hexanuclear Cobalt Complex. (2017) (30)
- Hydrogen-induced structural changes at the nickel site of the regulatory [NiFe] hydrogenase from Ralstonia eutropha detected by X-ray absorption spectroscopy. (2003) (30)
- Photo-assisted water oxidation by high-nuclearity cobalt-oxo cores: tracing the catalyst fate during oxygen evolution turnover (2017) (30)
- Theory of the Linear Dichroism in the Extended X-ray Absorption Fine Structure (EXAFS) of Partially Vectorially Ordered Systems* (1998) (30)
- Cyanamide route to calcium-manganese oxide foams for water oxidation. (2013) (29)
- Combination of Highly Efficient Electrocatalytic Water Oxidation with Selective Oxygenation of Organic Substrates using Manganese Borophosphates (2021) (29)
- Light-driven formation of manganese oxide by today’s photosystem II supports evolutionarily ancient manganese-oxidizing photosynthesis (2020) (28)
- A high-valent heterobimetallic [Cu(III)(μ-O)2Ni(III)]2+ core with nucleophilic oxo groups. (2013) (28)
- Eukaryotically Encoded and Chloroplast-located Rubredoxin Is Associated with Photosystem II* (2000) (27)
- Assembly of light harvesting complexes II (LHC-II) in the absence of lutein (1997) (26)
- Understanding the formation of bulk- and surface-active layered (oxy)hydroxides for water oxidation starting from a cobalt selenite precursor (2020) (26)
- Biogenic Manganese–Calcium Oxides on the Cell Walls of the Algae Chara Corallina: Elemental Composition, Atomic Structure, and Water‐Oxidation Catalysis (2014) (25)
- Water-Oxidation Electrocatalysis by Manganese Oxides: Syntheses, Electrode Preparations, Electrolytes and Two Fundamental Questions (2020) (25)
- Kα X-ray Emission Spectroscopy on the Photosynthetic Oxygen-Evolving Complex Supports Manganese Oxidation and Water Binding in the S3 State. (2018) (25)
- The involvement of spillover changes in State 1-State 2 transitions in intact leaves at low light intensities (1988) (25)
- Nickel–Vanadium Layered Double Hydroxide under Water-Oxidation Reaction: New Findings and Challenges (2019) (25)
- The role of zinc in the methylation of the coenzyme M thiol group in methanol:coenzyme M methyltransferase from Methanosarcina barkeri. (2002) (24)
- EFFECT OF LIGHT-INDUCED CHANGES IN THYLAKOID VOLTAGE ON CHLOROPHYLL FLUORESCENCE OF AEGOPODIUM PODAGRARIA LEAVES (1991) (23)
- Fast structural changes (200-900ns) may prepare the photosynthetic manganese complex for oxidation by the adjacent tyrosine radical. (2012) (23)
- A novel BioXAS technique with sub-millisecond time resolution to track oxidation state and structural changes at biological metal centers. (2005) (22)
- Electromodified NiFe Alloys as Electrocatalysts for Water Oxidation: Mechanistic Implications of Time-Resolved UV/Vis Tracking of Oxidation State Changes. (2019) (22)
- A study on the energy-dependent quenching of chlorophyll fluorescence by means of photoacoustic measurements (1990) (21)
- Studies on the adaptation of intact leaves to changing light intensities by a kinetic analysis of chlorophyll fluorescence and oxygen evolution as measured by the photoacoustic signal (1989) (21)
- Self-supported Ni(OH)2/MnO2 on CFP as a flexible anode towards electrocatalytic urea conversion: The role of composition on activity, redox states and reaction dynamics (2019) (20)
- Structure and mechanism leading to formation of the cysteine sulfinate product complex of a biomimetic cysteine dioxygenase model. (2015) (20)
- Efficiency and role of loss processes in light-driven water oxidation by PSII. (2007) (20)
- Enthalpy changes during photosynthetic water oxidation tracked by time-resolved calorimetry using a photothermal beam deflection technique. (2008) (20)
- Stoichiometric formation of an oxoiron(IV) complex by a soluble methane monooxygenase type activation of O2 at an iron(II)-cyclam centre. (2020) (19)
- Revisiting Metal-Organic Frameworks for Oxygen Evolution: A Case Study. (2020) (19)
- Axial Ligation and Redox Changes at the Cobalt Ion in Cobalamin Bound to Corrinoid Iron-Sulfur Protein (CoFeSP) or in Solution Characterized by XAS and DFT (2016) (19)
- X-ray absorption spectroscopy to watch catalysis by metalloenzymes: status and perspectives discussed for the water-splitting manganese complex of photosynthesis. (2003) (18)
- Linear analysis applied to the comparative study of the I-D-P phase of chlorophyll fluorescence as induced by actinic PS-II light, PS-I light and changes in CO2-concentration (1991) (18)
- Evaporated manganese films as a starting point for the preparation of thin-layer MnOx water-oxidation anodes (2017) (18)
- Crystallographic and Computational Analysis of the Barrel Part of the PsbO Protein of Photosystem II: Carboxylate-Water Clusters as Putative Proton Transfer Relays and Structural Switches. (2016) (17)
- Active Mixed‐Valent MnOx Water Oxidation Catalysts Through Partial Oxidation (Corrosion) of Nanostructured MnO Particles. (2014) (16)
- Facile Formation of Nanostructured Manganese Oxide Films as High-Performance Catalysts for the Oxygen Evolution Reaction. (2018) (16)
- Origin of the heat-induced improvement of catalytic activity and stability of MnOx electrocatalysts for water oxidation (2019) (16)
- Towards a comprehensive X-ray approach for studying the photosynthetic manganese complex-XANES, Kα/Kβ/Kβ-satellite emission lines, RIXS, and comparative computational approaches for selected model complexes (2009) (16)
- Characterisation of a water-oxidizing Co-film by XAFS (2009) (16)
- The location of calcium in the manganese complex of oxygenic photosynthesis studied by x-ray absorption spectroscopy at the Ca k-edge (2005) (16)
- Merging Structural Information from X-ray Crystallography, Quantum Chemistry, and EXAFS Spectra: The Oxygen-Evolving Complex in PSII. (2016) (15)
- Electronic Supplementary Information (2004) (14)
- The relation between the photochemical yield and variable fluorescence of photosystem II in the green alga Scenedesmus obliquus (1996) (14)
- Cationic screening of charged surface groups (carboxylates) affects electron transfer steps in photosystem-II water oxidation and quinone reduction. (2014) (14)
- Bias from H2 cleavage to production and coordination changes at the Ni-Fe active site in the NAD+-reducing hydrogenase from Ralstonia eutropha. (2006) (14)
- Carbon fibre paper coated by a layered manganese oxide: a nano-structured electrocatalyst for water-oxidation with high activity over a very wide pH range (2019) (14)
- X-Ray Absorption Linear Dichroism Spectroscopy (XALDS) on the Photosystem II Manganese Complex: Radiation Damage and S1-State K-edge Spectra (1997) (13)
- Protein-protein complex formation affects the Ni-Fe and Fe-S centers in the H2-sensing regulatory hydrogenase from Ralstonia eutropha H16. (2010) (12)
- Energetics and Kinetics of S-State Transitions Monitored by Delayed Chlorophyll Fluorescence (2019) (12)
- Modelling the (Essential) Role of Proton Transport by Electrolyte Bases for Electrochemical Water Oxidation at Near-Neutral pH (2019) (11)
- Operando tracking of oxidation-state changes by coupling electrochemistry with time-resolved X-ray absorption spectroscopy demonstrated for water oxidation by a cobalt-based catalyst film (2021) (11)
- Inhibitory and Non-Inhibitory NH3 Binding at the Water-Oxidizing Manganese Complex of Photosystem II Suggests Possible Sites and a Rearrangement Mode of Substrate Water Molecules. (2017) (11)
- Water oxidation by a manganese-potassium cluster: Mn oxide as a kinetically dominant “true” catalyst for water oxidation (2018) (10)
- Activation energies for two steps in the S2→ S3 transition of photosynthetic water oxidation from time-resolved single-frequency infrared spectroscopy. (2020) (10)
- SHORT‐TERM ADAPTATION OF HIGHER PLANTS TO CHANGING LIGHT INTENSITIES AND EVIDENCE FOR THE INVOLVEMENT OF PHOSPHORYLATION OF THE LIGHT HARVESTING CHLOROPHYLL alb PROTEIN COMPLEX OF PHOTOSYSTEM II (1984) (10)
- Anion Binding and Oxidative Modification at the Molybdenum Cofactor of Formate Dehydrogenase from Rhodobacter capsulatus Studied by X-ray Absorption Spectroscopy. (2019) (10)
- Energetics and kinetics of photosynthetic water oxidation studied by photothermal beam deflection (PBD) experiments (2009) (10)
- Exploring the Limits of Self-Repair in Cobalt Oxide Films for Electrocatalytic Water Oxidation (2020) (9)
- From manganese oxidation to water oxidation: assembly and evolution of the water-splitting complex in photosystem II (2022) (9)
- Nanostructured Intermetallic Nickel Silicide (Pre)Catalyst for Anodic Oxygen Evolution Reaction and Selective Dehydrogenation of Primary Amines (2022) (9)
- A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C−H Bond Oxidation Reactions (2020) (9)
- A mononuclear cobalt complex for water oxidation: new controversies and puzzles. (2018) (9)
- Structural and functional role of anions in electrochemical water oxidation probed by arsenate incorporation into cobalt-oxide materials. (2019) (8)
- The pH-dependence of the photosystem II fluorescence: Cooperative transition to a quenching state (1996) (8)
- First steps towards time-resolved BioXAS at room temperature: state transitions of the manganese complex of oxygenic photosynthesis. (2002) (8)
- A soft molecular 2Fe–2As precursor approach to the synthesis of nanostructured FeAs for efficient electrocatalytic water oxidation† (2020) (8)
- pH‐Dependent Protonation of Surface Carboxylate Groups in PsbO Enables Local Buffering and Triggers Structural Changes (2020) (8)
- Electrochemical alcohols oxidation mediated by N-hydroxyphthalimide on nickel foam surface (2020) (8)
- On the relation between absorption and fluorescence emission spectra of photosystems: Derivation of a Stepanov relation for pigment culsters (1996) (8)
- Identification of YdhV as the First Molybdoenzyme Binding a Bis-Mo-MPT Cofactor in Escherichia coli. (2019) (8)
- Unexpected capacity for organic carbon assimilation by Thermosynechococcus elongatus, a crucial photosynthetic model organism (2016) (8)
- Indication of transthylakoid proton-fluxes in Aegopodium podagraria L. by light-induced changes of plasmalemma potential, chlorophyll fluorescence and light-scattering (1988) (8)
- In situ profiles of phytoplankton: algal composition and biomass determined fluorometrically. In: Hallegraeff, G., Blackburn, S.I., Bolch, C.J. & Lewis, R.J. (eds.), HAB2000 Proceedings volume (2001) (7)
- Copper Carbonate Hydroxide as Precursor of Interfacial CO in CO2 Electroreduction (2022) (7)
- A New Method for Determination of the Edge Position of X-ray Absorption Spectra (1998) (7)
- Tryptophan regulates Drosophila zinc stores (2022) (7)
- Water Splitting: Unexpected Fe(VI) Trapped by Manipulation of Reaction Kinetics (2018) (6)
- On the long-wavelength spectral forms of chlorophyll a in Photosystem I: Spectroscopic and immunological investigations on a greening mutant of the green alga Scenedesmus obliquus (2004) (6)
- Tuning cobalt eg occupation of Co-NCNT by manipulation of crystallinity facilitates more efficient oxygen evolution and reduction (2020) (6)
- The Involvement of LHC 2 Phosphorylation in the Adaptation of Higher Plants to Changing Light Intensities and Some Results on the Regulation of LHC 2 Phosphorylation in Vivo (1990) (5)
- Impact of energy limitations on function and resilience in long-wavelength Photosystem II (2022) (5)
- Water Oxidation by Co‐Based Oxides with Molecular Properties (2014) (5)
- In situ synthesis of manganese oxide as an oxygen-evolving catalyst: A new strategy. (2020) (5)
- Linear dichroism in the XANES of partially oriented samples: theory and application to the photosynthetic manganese complex. (2010) (5)
- Rapid depth-profiling of the distribution of "spectral groups" of microalgae in lakes, rivers and the sea. (1998) (5)
- Water Oxidation in Photosystem II: Energetics and Kinetics of Intermediates Formation in the S2→S3 and S3→S0 Transitions Monitored by Delayed Chlorophyll Fluorescence (2013) (5)
- Protein crystallization and initial neutron diffraction studies of the photosystem II subunit PsbO. (2017) (5)
- Non-standard structures of the Ni-Fe cofactor in the regulatory and the NAD-reducing hydrogenases from Ralstonia eutropha. (2005) (5)
- A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions. (2016) (5)
- Simulation of XANES spectra for protein-bound metal centers: analysis of linear dichroism data (2005) (4)
- Photosynthesis water oxidation: Structural insights to the catalytic manganese complex (1995) (4)
- investigated by X-ray absorption spectroscopy: insights into O2-tolerant H2-cleavage (2011) (4)
- Recent Advances Toward A Structural Model for the Photosynthetic Oxygen-Evolving Manganese Cluster (1996) (4)
- Oxygen Evolution Activity of Amorphous Cobalt Oxyhydroxides: Interconnecting Precatalyst Reconstruction, Long‐Range Order, Buffer‐Binding, Morphology, Mass Transport, and Operation Temperature (2022) (4)
- The Manganese Complex of Photosystem II: Extended-Range EXAFS Data and Specific Structural Models for Four S-States (2008) (4)
- Selected applications of operando Raman spectroscopy in electrocatalysis research (2022) (4)
- Investigating the Structure and Dynamics of Apo‐Photosystem II (2019) (3)
- Resonant inelastic X-ray scattering on synthetic nickel compounds and Ni-Fe hydrogenase protein (2009) (3)
- A bioinspired oxoiron(IV) motif supported on a N2S2 macrocyclic ligand. (2021) (3)
- The binuclear nickel center in the A-cluster of acetyl-CoA synthase (ACS) and two biomimetic dinickel complexes studied by X-ray absorption and emission spectroscopy (2016) (3)
- Kinetic Analysis of the Photoacoustically Measured Photosynthetic Oxygen Response to Additional Blue and Far-Red Light (1988) (3)
- Ammonia as a substrate-water analogue in photosynthetic water oxidation: Influence on activation barrier of the O2-formation step. (2019) (3)
- A synthetic manganese-calcium cluster similar to the catalyst of Photosystem II: challenges for biomimetic water oxidation. (2020) (3)
- Spectroscopic Characterization of a Reactive [Cu2(μ‐OH)2]2+ Intermediate in Cu/TEMPO Catalyzed Aerobic Alcohol Oxidation Reaction (2021) (3)
- Experimental and quantum chemical characterization of the water oxidation cycle catalysed by [ RuII ( damp ) ( bpy ) ( H 2 O ) ] 2 + † (2012) (3)
- Time-Resolved Delayed Chlorophyll Fluorescence to Study the Influence of Bicarbonate on a Green Algae Mutant Photosystem II (2008) (3)
- The manganese complex of Photosystem II : A structural model for the S 1 , S 2 , and S 3 oxidation states derived from linear dichroism EXAFS spectroscopy at 20 K and at room temperature (2001) (2)
- In Situ Detection of Iron in Oxidation States ≥ IV in Cobalt‐Iron Oxyhydroxide Reconstructed during Oxygen Evolution Reaction (2023) (2)
- Ligand binding at the A-cluster in full-length or truncated acetyl-CoA synthase studied by X-ray absorption spectroscopy (2017) (2)
- SHORT‐TERM ADAPTATION OF HIGHER PLANTS TO CHANGING LIGHT INTENSITIES AND EVIDENCE FOR THE INVOLVEMENT OF PHOSPHORYLATION OF THE LIGHT HARVESTING CHLOROPHYLL alb PROTEIN COMPLEX OF PHOTOSYSTEM II (1992) (2)
- On the structure and orientation of the oxygen evolving complex: X-ray absorption and dichroism spectroscopy of the ammonia-modified manganese complex of photosystem II (1995) (2)
- The Photosystem II Manganese Complex in Its S3-State (1998) (2)
- Coordination Changes of Carboxyl Ligands at the Q A FeQ B Triad in Photosynthetic Reaction Centers Studied by Density-Functional Theory (2013) (2)
- A Correlation Method for Quantification of the Magnitude of the S 2 -State Multiline EPR Signal (1998) (1)
- Light-driven formation of high-valent manganese oxide by photosystem II supports evolutionary role in early bioenergetics (2020) (1)
- Stepwise transition of the tetra-manganese complex of Photosystem II to a binuclear Mn2(µ-O)2 complex in response to a temperature jump: an X-ray absorption spectroscopy study (2001) (1)
- On the Mechanism of the Non-Photochemical Fluorescence Quenching in the Wildtype and a Chlorophyll b-Less Mutant of Scenedesmus Obliquus (1995) (1)
- The Photosynthetic Mn Complex in Its Reaction Cycle: An Attempt to Obtain Pure FTIR Difference Spectra for the Four Transitions Between Semi-Stable S-States and for QB Redox Transitions (2008) (1)
- Formation of cobalt-oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(II) center. (2021) (1)
- Bimetallic Mn, Fe, Co, and Ni Sites in a Four-Helix Bundle Protein: Metal Binding, Structure, and Peroxide Activation. (2021) (1)
- O2 evolution electrocatalysis:Electronic, atomic, and nanoscale dynamics matter (2021) (1)
- A chemical evolution‐like method to synthesize a water‐oxidizing catalyst (2021) (1)
- The manganese complex of Photosystem II: A structural model of the S2, and S3 oxidation states derived from linear dichoism EXAFS spectrums. (2001) (1)
- Three overlooked photosynthesis papers of Otto Warburg (1883–1970), published in the 1940s in German and in Russian, on light-driven water oxidation coupled to benzoquinone reduction (2021) (1)
- Comparison of structure and function of the photosynthetic oxygen-evolving complex of spinach and the green alga Scenedesmus obliquus (1995) (1)
- Comparative Spectroscopic Study Revealing Why the CO2 Electroreduction Selectivity Switches from CO to HCOO– at Cu–Sn- and Cu–In-Based Catalysts (2022) (1)
- Molecular Dynamics and Structural Studies of Zinc Chloroquine Complexes (2022) (1)
- Comparison of electron paramagnetic resonance lineshape, orientation and power saturation of the TyrD radical from spinach and the green alga Scenedesmus obliquus (1996) (1)
- Catalytic dioxygen reduction mediated by a tetranuclear cobalt complex supported on a stannoxane core. (2020) (1)
- Local Cycle of Photosynthesis and Quasi-Aerobic Respiration Facilitated by Manganese Oxides — A Hypothesis on the Evolution of Phototrophy (2019) (1)
- Towards time resolved characterization of electrochemical reactions: electrochemically-induced Raman spectroscopy (2022) (1)
- The Structure of a Partially Assembled, Di-Nuclear PS II Manganese Complex Investigated by EPR- and Exafs on a New Core Complex Preparation (1998) (1)
- The electron-proton bottleneck of photosynthetic oxygen evolution. (2022) (1)
- Titelbild: A High‐Valent Heterobimetallic [CuIII(μ‐O)2NiIII]2+ Core with Nucleophilic Oxo Groups (Angew. Chem. 21/2013) (2013) (1)
- Functional Photosystem I without Long-Wavelength Fluorescence Emission in a Low-Light Grown Greening Mutant of the Green Alga Scenedesmus Obliquus (1995) (1)
- Reviving Oxygen Evolution Electrocatalysis of Bulk La–Ni Intermetallics via Gaseous Hydrogen Engineering (2022) (1)
- Hydrogen Bubble Templated Electrodeposited Cu As CO 2 Reduction Catalyst: Substrate Effect (2017) (0)
- Photosystem II depleted of the Mn4CaO5 cluster at 2.55 A resolution (2017) (0)
- rominent role of metal ions in octahedral versus tetrahedral sites of cobalt – zinc oxide catalysts for e ffi cient oxidation of water † (2016) (0)
- A Thiolate-Bound Dimanganese Cluster as a Structural and Functional Model for Class Ib Ribonucleotide Reductases. (2022) (0)
- Front Cover: pH‐Dependent Protonation of Surface Carboxylate Groups in PsbO Enables Local Buffering and Triggers Structural Changes (ChemBioChem 11/2020) (2020) (0)
- Spectral fingerprinting for specific algal groups in vertical profiles of phytoplankton communities, in situ (1999) (0)
- Method for preparing a catalyst in which half the H2 evolution, said catalyst and uses thereof (2012) (0)
- Oxygen Evolution Reaction by Silicate-Stabilized Manganese Oxide (2023) (0)
- PsbO subunit of Photosystem II, beta barrel domain at 100K, pH 10 (2016) (0)
- The energetics of the two types of far-red Photosystem II (2022) (0)
- The influence of secondary interactions on the [Ni(O2)]+ mediated aldehyde oxidation reactions (2021) (0)
- Electrocatalytic Water Oxidation at Neutral pH–Deciphering the Rate Constraints for an Amorphous Cobalt‐Phosphate Catalyst System (2022) (0)
- Spectroscopic Properties of a Biologically Relevant [Fe2(μ-O)2] Diamond Core Motif with a Short Iron-Iron distance. (2022) (0)
- X-ray Absorption Linear Dichroism Spectroscopy (Xalds) on the PS II Manganese Complex — Methodical Aspects (1995) (0)
- Evidence of Sulfur Non‐Innocence in [CoII(dithiacyclam)]2+‐Mediated Catalytic Oxygen Reduction Reactions (2022) (0)
- copper complexes to composite electrocatalytic materials for selective reduction of CO 2 to formic acid † (2015) (0)
- The Structure of a Water-oxidizing Cobalt Oxide Film and Comparison to the Photosynthetic Manganese Complex (2013) (0)
- Modelling the coordination environment in α‐ketoglutarate dependent oxygenases – a comparative study on the effect of N‐ vs. O‐ligation (2022) (0)
- Spectroscopic identification of active sites for the oxygen evolution reaction on iron-cobalt oxides (2017) (0)
- Tuning electrocatalytic water oxidation by MnOx through the incorporation of abundant metal cations (2022) (0)
- Redox Energetics and Kinetics of Water Oxidation in Neutral versus Alkaline Electrolyte: an In-Operando Time-Resolved X-Ray Absorption Study (2019) (0)
- Bridging-mode changes in response to manganese oxidation in two binuclear manganese complexes : implications for photosynthetic water-oxidation (2005) (0)
- Publisher Correction: Light-driven formation of manganese oxide by today’s photosystem II supports evolutionarily ancient manganese-oxidizing photosynthesis (2021) (0)
- Cover Picture: A High‐Valent Heterobimetallic [CuIII(μ‐O)2NiIII]2+ Core with Nucleophilic Oxo Groups (Angew. Chem. Int. Ed. 21/2013) (2013) (0)
- Cover Feature: In Situ Synthesis of Manganese Oxide as an Oxygen‐Evolving Catalyst: A New Strategy (Chem. Eur. J. 4/2021) (2021) (0)
- t-induced improvement of catalytic activity and stability of MnO x electrocatalysts for water oxidation † (2019) (0)
- Uncovering The Role of Oxygen in Ni-Fe(OxHy) Electrocatalysts using In situ Soft X-ray Absorption Spectroscopy during the Oxygen Evolution Reaction (2019) (0)
- S 13-007 Stepwise transition of the tetra-manganese complex of Photosystem II to a binuclear Mn 2 ( μ-O ) 2 complex in response to a temperature jump : an X-ray absorption spectroscopy study (2001) (0)
- Substrate binding by a vanadium-bromoperoxidase investigated by XAFS at the Br K-edge (1999) (0)
- Publisher Correction: Light-driven formation of manganese oxide by today’s photosystem II supports evolutionarily ancient manganese-oxidizing photosynthesis (2021) (0)
- Electrochemical Water Oxidation by MnOx/CFP – pH Dependence of the Catalytic Activity (2018) (0)
- Role of Protons in Photosynthetic Water Oxidation: pH Influence on the Rate Constants of the S-state Transitions and Hypotheses on the S2→S3 Transition (2013) (0)
- Photosynthetic Dioxygen Formation Monitored by Time‐Resolved X‐Ray Spectroscopy (2007) (0)
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