Huw Davies
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Most Influential Person Now
British chemist
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Chemistry
Huw Davies 's Degrees
- Bachelors Chemistry University of Oxford
- PhD Chemistry University of Oxford
Why Is Huw Davies Influential?
(Suggest an Edit or Addition)According to Wikipedia, Huw M. L. Davies FRSC is a Welsh chemist who has been Asa Griggs Candler Professor of Organic Chemistry at Emory University since 2008. Born in Aberystwyth, Wales he graduated with a first-class degree in chemistry from Cardiff University in 1977 and completed his PhD at the University of East Anglia in 1980. After a post-doctoral position at Princeton University he joined the faculty at Wake Forest University where he became a full professor. He subsequently joined the University at Buffalo where he held the positions of UB Distinguished Professor and Larkin Professor of Organic Chemistry. In 2008, he moved to Emory University.
Huw Davies 's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion (2008) (1668)
- Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion. (2003) (1149)
- Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes. (2011) (703)
- C-H functionalization in organic synthesis. (2011) (391)
- Recent Advances in C-H Functionalization. (2016) (381)
- Application of donor/acceptor-carbenoids to the synthesis of natural products. (2009) (324)
- Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles. (2014) (318)
- Asymmetric Cyclopropanations by Rhodium(II) N-(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2-Phenylcyclopropan-1-amino Acid (1996) (307)
- Catalytic asymmetric synthesis of pyrroloindolines via a rhodium(II)-catalyzed annulation of indoles. (2013) (291)
- Catalytic Asymmetric C−H Activation of Alkanes and Tetrahydrofuran (2000) (246)
- The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis. (2012) (223)
- Site-selective and stereoselective functionalization of unactivated C–H bonds (2016) (221)
- Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids. (2007) (207)
- Rhodium-catalyzed [3 + 2] annulation of indoles. (2010) (207)
- Recent advances in catalytic intramolecular C-H aminations. (2005) (204)
- Rhodium-catalyzed conversion of furans to highly functionalized pyrroles. (2013) (189)
- Recent advances in catalytic enantioselective intermolecular C-H functionalization. (2006) (180)
- High Symmetry Dirhodium(II) Paddlewheel Complexes as Chiral Catalysts. (2008) (178)
- Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations. (2006) (174)
- Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds (2017) (169)
- Gold(I)-catalyzed asymmetric cyclopropenation of internal alkynes. (2012) (157)
- One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles. (2008) (154)
- Novel aromatase inhibitors by structure-guided design. (2012) (143)
- D2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: design, synthesis and application. (2011) (143)
- Computational study on the selectivity of donor/acceptor-substituted rhodium carbenoids. (2009) (142)
- Diazotransfer Reactions with p-Acetamidobenzenesulfonyl Azide (1987) (140)
- Combined C-H activation/cope rearrangement as a strategic reaction in organic synthesis: total synthesis of (-)-colombiasin a and (-)-elisapterosin B. (2006) (139)
- Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex (2013) (138)
- Conversion of cyclic ketones to 2,3-fused pyrroles and substituted indoles. (2013) (137)
- Asymmetric synthesis of tropanes by rhodium-catalyzed [4 + 3] cycloaddition. (2007) (136)
- Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols. (2012) (135)
- ASYMMETRIC INTERMOLECULAR CARBENOID C-H INSERTIONS CATALYZED BY RHODIUM(II) (S)-N-(P-DODECYLPHENYL)SULFONYLPROLINATE (1997) (134)
- Collective Approach to Advancing C–H Functionalization (2017) (130)
- Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization (2019) (129)
- Tandem cyclopropanation/cope rearrangement: a general method for the construction of seven-membered rings (1993) (128)
- Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions. (2006) (126)
- Highly Regio-, Diastereo-, and Enantioselective C−H Insertions of Methyl Aryldiazoacetates into Cyclic N-Boc-Protected Amines. Asymmetric Synthesis of Novel C2-Symmetric Amines and threo-Methylphenidate (1999) (118)
- Enhancement of cyclopropanation chemistry in the silver-catalyzed reactions of aryldiazoacetates. (2007) (117)
- Role of sterically demanding chiral dirhodium catalysts in site-selective C-H functionalization of activated primary C-H bonds. (2014) (116)
- Asymmetric [4 + 3] cycloadditions between vinylcarbenoids and dienes: application to the total synthesis of the natural product (-)-5-epi-vibsanin E. (2009) (112)
- Sequential C-H functionalization reactions for the enantioselective synthesis of highly functionalized 2,3-dihydrobenzofurans. (2013) (110)
- Mild aminoacylation of indoles and pyrroles through a three-component reaction with ynol ethers and sulfonyl azides. (2014) (108)
- Asymmetric Synthesis of Highly Functionalized 8-Oxabicyclo[3.2.1]octene Derivatives (1996) (106)
- Synthesis of (.+-.)-ferruginine and (.+-.)-anhydroecgonine methyl-ester by a tandem cyclopropanation/Cope rearrangement (1991) (104)
- Self-administration of cocaine analogs by rats (1999) (102)
- Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations. (2003) (102)
- Rhodium-catalyzed tandem cyclopropanation/Cope rearrangement of 4-alkenyl-1-sulfonyl-1,2,3-triazoles with dienes. (2013) (99)
- Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C–H bonds (2018) (98)
- Concise syntheses of dictyodendrins A and F by a sequential C-H functionalization strategy. (2015) (96)
- Expanding the scope of donor/acceptor carbenes to N-phthalimido donor groups: diastereoselective synthesis of 1-cyclopropane α-amino acids. (2012) (95)
- Enantioselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and allylic alcohols. (2010) (90)
- Late-stage C–H functionalization of complex alkaloids and drug molecules via intermolecular rhodium-carbenoid insertion (2015) (90)
- Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes. (2013) (88)
- Enantioselective synthesis of trifluoromethyl-substituted cyclopropanes. (2007) (88)
- Highly enantioselective Rh2(S-DOSP)4-catalyzed cyclopropenation of alkynes with styryldiazoacetates. (2010) (88)
- Enantioselective Gold(I)-catalyzed vinylogous [3 + 2] cycloaddition between vinyldiazoacetates and enol ethers. (2013) (87)
- .alpha.-Hydroxy esters as chiral auxiliaries in asymmetric cyclopropanations by rhodium(II)-stabilized vinylcarbenoids (1993) (87)
- Dirhodium(II) tetra(N-(dodecylbenzenesulfonyl)prolinate) catalyzed enantioselective cyclopropenation of alkynes. (2004) (86)
- New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to nitrogen as a surrogate for the mannich reaction. (2003) (86)
- Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations (1996) (86)
- Blue light-promoted photolysis of aryldiazoacetates (2018) (84)
- Tandem Asymmetric Cyclopropanation/Cope Rearrangement. A Highly Diastereoselective and Enantioselective Method for the Construction of 1,4-Cycloheptadienes (1998) (84)
- Enantioselective Synthesis of (−)-Maoecrystal V by Enantiodetermining C–H Functionalization (2014) (83)
- Enantioselective Synthesis of Functionalized Tropanes by Rhodium(II) Carboxylate-Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Pyrroles (1997) (82)
- Catalytic asymmetric cyclopropanation of heteroaryldiazoacetates. (2001) (82)
- Asymmetric intramolecular C_H insertions of aryldiazoacetates. (2001) (82)
- Enantioselective synthesis of vinylcyclopropanes by rhodium(II) catalyzed decomposition of vinyldiazomethanes in the presence of alkenes (1993) (82)
- Catalytic Enantioselective Synthesis of 2-Amino Acids. (2002) (81)
- Intermolecular C-H Insertions of Donor/Acceptor-Substituted Rhodium Carbenoids: A Practical Solution for Catalytic Enantioselective C-H Activation (2004) (80)
- Rhodium(II)-catalyzed cross-coupling of diazo compounds. (2011) (80)
- 2,2,2-Trichloroethyl aryldiazoacetates as robust reagents for the enantioselective C-H functionalization of methyl ethers. (2014) (80)
- Dirhodium Tetra(N‐arylsulfonylprolinates) as Chiral Catalysts For Asymmetric Transformations of Vinyl‐ and Aryldiazoacetates (1999) (80)
- Rh2(R-TPCP)4-catalyzed enantioselective [3+2]-cycloaddition between nitrones and vinyldiazoacetates. (2013) (78)
- Recent progress in asymmetric intermolecular CH activation by rhodium carbenoid intermediates (2001) (77)
- Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol. (2010) (76)
- Silver triflate-catalyzed cyclopropenation of internal alkynes with donor-/acceptor-substituted diazo compounds. (2011) (76)
- Effect of Rhodium Carbenoid Structure on Cyclopropanation Chemoselectivity (2000) (73)
- Direct synthesis of furans by 3+2 cycloadditions between rhodium(II) acetate stabilized carbenoids and acetylenes (1988) (73)
- Potential antidepressant effects of novel tropane compounds, selective for serotonin or dopamine transporters. (1997) (73)
- Investigation into factors influencing stereoselectivity in the reactions of heterocycles with donor-acceptor-substituted rhodium carbenoids. (2006) (72)
- Asymmetric Synthesis of 2,3-Dihydrofurans by Reaction of Rhodium-Stabilized Vinylcarbenoids with Vinyl Ethers. (1998) (72)
- On the mechanism and selectivity of the combined C-H activation/Cope rearrangement. (2011) (72)
- Social Dominance in Female Monkeys: Dopamine Receptor Function and Cocaine Reinforcement (2012) (71)
- Direct synthesis of (+)-erogorgiaene through a kinetic enantiodifferentiating step. (2005) (71)
- The Reinforcing Efficacy of Psychostimulants in Rhesus Monkeys: The Role of Pharmacokinetics and Pharmacodynamics (2003) (71)
- Catalytic asymmetric benzylic C-H activation by means of carbenoid-induced C-H insertions. (2002) (70)
- Rh2(S-biTISP)2-catalyzed asymmetric functionalization of indoles and pyrroles with vinylcarbenoids. (2012) (70)
- Novel 2-substituted cocaine analogs: uptake and ligand binding studies at dopamine, serotonin and norepinephrine transport sites in the rat brain. (1995) (69)
- Diversity-oriented synthesis as a tool for identifying new modulators of mitosis (2014) (69)
- Enantioselective reactions of donor/acceptor carbenoids derived from alpha-aryl-alpha-diazoketones. (2009) (69)
- Simple strategy for the immobilization of dirhodium tetraprolinate catalysts using a pyridine-linked solid support. (2004) (69)
- Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization (2018) (68)
- Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes (1991) (67)
- Vinylogous reactivity of silver(I) vinylcarbenoids (2011) (67)
- Universal strategy for the immobilization of chiral dirhodium catalysts. (2005) (65)
- Rhodium-catalyzed enantioselective vinylogous addition of enol ethers to vinyldiazoacetates. (2012) (63)
- Highly diastereoselective and enantioselective C-H functionalization of 1,2-dihydronaphthalenes: a combined C-H activation/Cope rearrangement followed by a retro-Cope rearrangement. (2004) (62)
- Rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed asymmetric insertions of vinyl- and phenylcarbenoids into the SiH bond (1997) (62)
- Intermolecular Metal‐Catalyzed Carbenoid Cyclopropanations (2004) (62)
- Asymmetric [4+3] cycloadditions between benzofuranyldiazoacetates and dienes: formal synthesis of (+)-frondosin B. (2008) (61)
- Functionalization of carbon-hydrogen bonds through transition metal carbenoid insertion. (2010) (61)
- Carbenoid versus Vinylogous Reactivity in Rhodium(II)-Stabilized Vinylcarbenoids (1994) (61)
- Catalytic asymmetric C-H activation of silyl enol ethers as an equivalent of an asymmetric Michael reaction. (2001) (60)
- Synthesis of 2 beta-acyl-3 beta-aryl-8-azabicyclo[3.2.1]octanes and their binding affinities at dopamine and serotonin transport sites in rat striatum and frontal cortex. (1994) (59)
- Dirhodium tetraprolinate-catalyzed asymmetric cyclopropanations with high turnover numbers. (2003) (59)
- Silica-immobilized chiral dirhodium(II) catalyst for enantioselective carbenoid reactions. (2013) (58)
- Asymmetric intermolecular C-H activation, using immobilized dirhodium tetrakis((S)-N-(dodecylbenzenesulfonyl)- prolinate) as a recoverable catalyst. (2003) (57)
- Double C-H activation strategy for the asymmetric synthesis of C2-symmetric anilines. (2004) (57)
- Catalytic asymmetric synthesis of highly functionalized cyclopentenes by a [3 + 2] cycloaddition. (2001) (56)
- The reinforcing and discriminative stimulus effects of the novel cocaine analog 2beta-propanoyl-3beta-(4-tolyl)-tropane in rhesus monkeys. (1997) (56)
- Novel dirhodium tetraprolinate catalysts containing bridging prolinate ligands for asymmetric carbenoid reactions (1999) (55)
- Intermolecular C–H activation at benzylic positions: synthesis of (+)-imperanene and (−)-α-conidendrin (2003) (55)
- Solvent-free catalytic enantioselective C–C bond forming reactions with very high catalyst turnover numbers (2010) (54)
- Stereoselective synthesis of epoxides by reaction of donor/acceptor-substituted carbenoids with α,β-unsaturated aldehydes (2001) (54)
- Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols. (2012) (54)
- Efficient route to 4H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids. (2008) (54)
- Novel 2-substituted cocaine analogs: binding properties at dopamine transport sites in rat striatum. (1993) (53)
- New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to oxygen as a surrogate to the aldol reaction. (2003) (53)
- Combined experimental and computational studies of heterobimetallic Bi-Rh paddlewheel carboxylates as catalysts for metal carbenoid transformations. (2009) (52)
- Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids. (2005) (52)
- Asymmetric synthesis of (+)-indatraline using rhodium-catalyzed C–H activation (2002) (51)
- Rh2(S-PTAD)4-catalyzed asymmetric cyclopropenation of aryl alkynes (2011) (51)
- Metal-free N-H insertions of donor/acceptor carbenes. (2012) (50)
- Catalytic asymmetric allylic C-H activation as a surrogate of the asymmetric Claisen rearrangement. (2001) (50)
- Thermally induced cycloadditions of donor/acceptor carbenes. (2011) (50)
- Stereoselective cyclopropanations with vinylcarbenoids (1989) (49)
- Mechanistic aspects of formal [3 + 4] cycloadditions between vinylcarbenoids and furans (1987) (49)
- Catalytic Asymmetric Synthesis of Syn-Aldol Products from Intermolecular C−H Insertions between Allyl Silyl Ethers and Methyl Aryldiazoacetates (1999) (48)
- Metal carbene-promoted sequential transformations for the enantioselective synthesis of highly functionalized cycloheptadienes. (2005) (48)
- Balance between allylic C-H activation and cyclopropanation in the reactions of donor/acceptor-substituted rhodium carbenoids with trans-alkenes. (2007) (48)
- Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles. (2010) (47)
- Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction. (2011) (46)
- [3 + 4] Cycloaddition reactions of vinyl carbenoids with furans (1985) (45)
- Rapid complexity generation in natural product total synthesis (2009) (45)
- Reversal of the regiochemistry in the rhodium-catalyzed [4+3] cycloaddition between vinyldiazoacetates and dienes. (2014) (45)
- Silver-catalyzed vinylogous fluorination of vinyl diazoacetates. (2013) (45)
- Type II intramolecular annulations between vinylcarbenoids and furans (1997) (45)
- Enantioselective Intermolecular C-H Functionalization of Allylic and Benzylic sp(3) C-H Bonds Using N-Sulfonyl-1,2,3-triazoles. (2016) (44)
- C-H activation as a strategic reaction: enantioselective synthesis of 4-substituted indoles. (2006) (44)
- Catalytic asymmetric CH activation of sp3 hybridized CH bonds by means of carbenoid CH insertions: applications in organic synthesis (2002) (44)
- Scope and stereochemistry of the tandem intramolecular cyclopropanation/cope rearrangement sequence (1989) (44)
- Anomalous reactivity of mono substituted rhodium stabilized vinylcarbenoids (1990) (44)
- Catalyst-Controlled Selective Functionalization of Unactivated C-H Bonds in the Presence of Electronically Activated C-H Bonds. (2018) (43)
- α-hydroxy esters as inexpensive chiral auxiliaries in rhodium(II)-catalyzed cyclopropanations with vinyldiazomethanes (1991) (43)
- Lewis acid induced tandem Diels-Alder reaction/ring expansion as an equivalent of a [4 + 3] cycloaddition. (2004) (43)
- Scope of the Reactions of Indolyl- and Pyrrolyl-Tethered N-Sulfonyl-1,2,3-triazoles: Rhodium(II)-Catalyzed Synthesis of Indole- and Pyrrole-Fused Polycyclic Compounds. (2017) (43)
- PaaSicats: Powerful catalysts for asymmetric epoxidation of enones. Novel syntheses of α-arylpropanoic acids including (S)-fenoprofen (1999) (43)
- Composite polymer/oxide hollow fiber contactors: versatile and scalable flow reactors for heterogeneous catalytic reactions in organic synthesis. (2015) (42)
- Tandem cyclopropanation/Cope rearrangement sequence. Stereospecific [3 + 4] cycloaddition reaction of vinylcarbenoids with cyclopentadiene (1987) (42)
- Asymmetric synthesis of 1,4-cycloheptadienes and bicyclo[3.2.1]octa-2,6-dienes by rhodium(II) N-(p-(tert-butyl)phenylsulfonyl)prolinate catalyzed reactions between vinyldiazomethanes and dienes (1994) (42)
- Metal-Free C-H Functionalization of Alkanes by Aryldiazoacetates. (2017) (41)
- Total Synthesis of (+/-)-Tremulenolide A and (+/-)-Tremulenediol A via a Stereoselective Cyclopropanation/Cope Rearrangement Annulation Strategy. (1998) (41)
- ASYMMETRIC SYNTHESIS OF CYCLOPENTENES BY 3 + 2 ANNULATIONS BETWEEN VINYLCARBENOIDS AND VINYL ETHERS (1998) (41)
- Influence of Electron-Deficient Ruthenium(I) Carbonyl Carboxylates on the Vinylogous Reactivity of Metal Carbenoids (2008) (41)
- Catalytic asymmetric cyclopropanation using bridged dirhodium tetraprolinates on solid support. (2002) (40)
- Rh(II)-Catalyzed Cyclopropanation of Furans and Its Application to the Total Synthesis of Natural Product Derivatives. (2017) (40)
- Stereoselective construction of nitrile-substituted cyclopropanes. (2008) (40)
- Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and their Application to Catalyst-Controlled C-H Functionalization. (2019) (40)
- Catalytic asymmetric reactions for organic synthesis: the combined C-H activation/Cope rearrangement. (2004) (40)
- Highly stereoselective [3 + 2] annulations by cyclopropanation of vinyl ethers with rhodium(II)-stabilized vinylcarbenoids followed by a formally forbidden 1,3-sigmatropic rearrangement (1992) (39)
- Asymmetric intermolecular C-H functionalization of benzyl silyl ethers mediated by chiral auxiliary-based aryldiazoacetates and chiral dirhodium catalysts. (2005) (38)
- Iridium(III)-bis(oxazolinyl)phenyl catalysts for enantioselective C–H functionalization (2013) (38)
- Enantioselective synthesis of beta-amino esters and its application to the synthesis of the enantiomers of the antidepressant Venlafaxine. (2006) (38)
- Controlling factors for C-H functionalization versus cyclopropanation of dihydronaphthalenes. (2010) (38)
- SYNTHESIS AND CHEMISTRY OF DONOR/ACCEPTOR-SUBSTITUTED CYCLOPROPENES (1995) (38)
- Stereoselectivity of methyl aryldiazoacetate cyclopropanations of 1,1-diarylethylene. Asymmetric synthesis of a cyclopropyl analogue of tamoxifen. (2000) (37)
- An exploratory study of type II [3 + 4] cycloadditions between vinylcarbenoids and dienes. (2000) (37)
- The Reinforcing Efficacy of the Dopamine Reuptake Inhibitor 2β-Propanoyl-3β-(4-tolyl)-tropane (PTT) as Measured by a Progressive-Ratio Schedule and a Choice Procedure in Rhesus Monkeys (2002) (37)
- An Immobilized-Dirhodium Hollow-Fiber Flow Reactor for Scalable and Sustainable C-H Functionalization in Continuous Flow. (2018) (37)
- Enantioselective Synthesis of Fused Cycloheptadienes by a Tandem Intramolecular Cyclopropanation/Cope Rearrangement Sequence (1999) (37)
- Enantioselective synthesis of cyclopropylphosphonates containing quaternary stereocenters using a D2-symmetric chiral catalyst Rh2(S-biTISP)2. (2004) (37)
- Asymmetric Synthesis of Highly Functionalized Cyclopentanes by a Rhodium- and Scandium-Catalyzed Five-Step Domino Sequence. (2011) (37)
- Guiding Principles for Site Selective and Stereoselective Intermolecular C—H Functionalization by Donor/Acceptor Rhodium Carbenes (2011) (36)
- Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes (2018) (36)
- Versatile synthesis of tropones by reaction of rhodium(II)-stabilized vinylcarbenoids with 1-methoxy-1-[(trimethylsilyl)oxy]buta-1,3-diene (1991) (36)
- Guide to Enantioselective Dirhodium(II)-Catalyzed Cyclopropanation with Aryldiazoacetates. (2013) (36)
- Novel entry to the tropane system by reaction of rhodium(II) acetate stabilized vinylcarbenoids with pyrroles (1989) (35)
- Asymmetric synthesis of the tremulane skeleton by a tandem cyclopropanation/cope rearrangement (1996) (35)
- Intermolecular C–H functionalization versus cyclopropanation of electron rich 1,1-disubstituted and trisubstituted alkenes (2009) (35)
- Sequential rhodium-, silver-, and gold-catalyzed synthesis of fused dihydrofurans. (2011) (33)
- Rhodium(II) acetate-catalyzed reaction of ethyl 2-diazo-3-oxopent-4-enoates: Simple routes to 4-aryl-2-hydroxy-1-naphthoates and β,β-unsaturated esters. The dianion of ethyl 4-(diethylphosphono)acetoacetate as a propionate homoenolate equivalent (1983) (33)
- Lewis acid-catalyzed tandem Diels-Alder reaction/retro-Claisen rearrangement as an equivalent of the inverse electron demand hetero Diels-Alder reaction. (2005) (33)
- Effect of carbenoid structure on the reactivity of rhodium-stabilized carbenoids (1998) (32)
- Regulation of Rat Dopamine Transporter mRNA and Protein by Chronic Cocaine Administration (1999) (32)
- Asymmetric C–H insertion of Rh(II) stabilized carbenoids into acetals: A C–H activation protocol as a Claisen condensation equivalent (2005) (32)
- Enantioselective Dirhodium(II)-Catalyzed Cyclopropanations with Trimethylsilylethyl and Trichloroethyl Aryldiazoacetates. (2015) (32)
- Enantioselective synthesis of tropanes by reaction of rhodium-stabilized vinylcarbenoids with pyrroles (1992) (31)
- Sequential cycloaddition approach to the tricyclic core of vibsanin E. Total synthesis of (+/-)-5-epi-10-epi-vibsanin E. (2005) (31)
- Catalytic asymmetric C-H activation by methyl thiophen-3-yldiazoacetate applied to the synthesis of (+)-cetiedil (2002) (31)
- Rhodium-Catalyzed Intermolecular C-H Functionalization as a Key Step in the Synthesis of Complex Stereodefined β-Arylpyrrolidines. (2018) (31)
- Rhodium(II)‐Stabilized Carbenoids Containing Both Donor and Acceptor Substituents (2005) (31)
- Role of ortho-substituents on rhodium-catalyzed asymmetric synthesis of β-lactones by intramolecular C-H insertions of aryldiazoacetates. (2014) (31)
- Stereoselective convergent synthesis of hydroazulenes via an intermolecular cyclopropanation/Cope rearrangement (1991) (30)
- Synthesis of methylphenidate analogues and their binding affinities at dopamine and serotonin transport sites. (2004) (30)
- Enantioselective synthesis of 2-arylbicyclo[1.1.0]butane carboxylates. (2013) (30)
- Using IR vibrations to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C–H functionalization (2015) (30)
- Highly Stereoselective Synthesis of Cyclopentanes bearing Four Stereocenters by a Rhodium Carbene–Initiated Domino Sequence (2014) (30)
- Catalytic asymmetric reactions for organic synthesis: the combined C-H activation/siloxy-cope rearrangement. (2004) (30)
- Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene (2000) (30)
- Comparison of a novel tropane analog of cocaine, 2 beta-propanoyl-3 beta-(4-tolyl) tropane with cocaine HCl in rats: nucleus accumbens extracellular dopamine concentration and motor activity. (1995) (30)
- Synthesis of Donor/Acceptor-Substituted Diazo Compounds in Flow and Their Application in Enantioselective Dirhodium-Catalyzed Cyclopropanation and C-H Functionalization. (2017) (30)
- Synthesis of 3 beta-aryl-8-azabicyclo[3.2.1]octanes with high binding affinities and selectivities for the serotonin transporter site. (1996) (29)
- Rhodium(II)-Catalyzed C-H Functionalization of Electron-Deficient Methyl Groups. (2016) (29)
- Application of the combined C–H activation/Cope rearrangement as a key step in the total syntheses of the assigned structure of (+)-elisabethadione and a (+)-p-benzoquinone natural product (2006) (29)
- Kinetic resolution and double stereodifferentiation in catalytic asymmetric C-H activation of 2-substituted pyrrolidines. (2001) (28)
- Enantioselective C–H functionalization of bicyclo[1.1.1]pentanes (2020) (28)
- Divergent Pathways in the Intramolecular Reactions between Rhodium-Stabilized Vinylcarbenoids and Pyrroles: Construction of Fused Tropanes and 7-Azabicyclo[4.2.0]octadienes (1996) (27)
- Computationally guided stereocontrol of the combined C-H functionalization/Cope rearrangement. (2011) (27)
- Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C-H Functionalizations. (2016) (27)
- Catalytic asymmetric solid-phase cyclopropanation. (2001) (27)
- Sequential transformations to access polycyclic chemotypes: asymmetric crotylation and metal carbenoid reactions. (2011) (26)
- In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings (2020) (26)
- Mechanistic studies of UV assisted [4 + 2] cycloadditions in synthetic efforts toward vibsanin E. (2007) (26)
- Rhodium carboxylate catalyzed decomposition of vinyldiazoacetates in the presence of heterodienes: enantioselective synthesis of the 6-azabicyclo[3.2.2]nonane and 6-azabicyclo[3.2.2]nonanone ring systems. (2002) (26)
- Alkynoate synthesis through the vinylogous reactivity of rhodium(II) carbenoids. (2012) (25)
- Influence of a β-Alkoxy Substituent on the CH Activation Chemistry of Alkyl Ethers (2003) (25)
- Synthesis and evaluation of a novel dirhodium tetraprolinate catalyst containing bridging prolinate ligands (1997) (25)
- Harnessing the β-Silicon Effect for Regioselective and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization by Donor/Acceptor Carbenes Derived from 1-Sulfonyl-1,2,3-triazoles. (2018) (25)
- Synthesis of highly functionalized tropolones by rhodium(II)-catalyzed reactions of vinyldiazomethanes with oxygenated dienes (1994) (25)
- Rhodium- and Non-Metal-Catalyzed Approaches for the Conversion of Isoxazol-5-ones to 2,3-Dihydro-6H-1,3-oxazin-6-ones. (2017) (25)
- Synthesis of fused 1,2-diazetidinones via an intramolecular Horner-Emmons reaction (1986) (24)
- Synthetic and isolation studies related to the marine natural products (+)-elisabethadione and (+)-elisabethamine. (2007) (24)
- Synthesis and pyrolysis of cyclic sulfonium ylides (1987) (24)
- Synthesis of 2β‐Acyl‐3β‐aryl‐8‐azabicyclo(3.2.1)octanes and Their Binding Affinities at Dopamine and Serotonin Transport Sites in Rat Striatum and Frontal Cortex. (1994) (23)
- Self-administration of two long-acting monoamine transport blockers in rhesus monkeys (2000) (23)
- Formation of monocyclic and bicyclic aza-.beta.-lactams and other novel heterocycles from 1-(diphenylmethylene)-3-oxo-1,2-diazetidinium inner salt (1981) (23)
- Novel approach to seven membered rings by the intramolecular tandem cyclopropanation cope rearrangement sequence (1988) (23)
- Divergent reaction pathways between rhodium(II)-stabilized vinylcarbenoids and benzenes (1992) (22)
- Catalytic Enantioselective Synthesis of β2-Amino Acids This work was supported by the National Science Foundation (CHE 0092490) and the National Institutes of Health (GM57425). (2002) (22)
- Comparison of Reactivity and Enantioselectivity between Chiral Bimetallic Catalysts: Bismuth–Rhodium- and Dirhodium-Catalyzed Carbene Chemistry (2018) (22)
- Further evaluation of the reinforcing effects of the novel cocaine analog 2β-propanoyl-3β-(4-tolyl)-tropane (PTT) in rhesus monkeys (1998) (22)
- Asymmetric synthesis of 1-alkynylcyclopropane-1-carboxylates (2000) (22)
- Effect of catalyst on the diastereoselectivity of methyl phenyldiazoacetate cyclopropanations (1998) (22)
- B-protected haloboronic acids for iterative cross-coupling (2009) (22)
- Characterization of a tropane radioligand, [(3)H]2beta-propanoyl-3beta-(4-tolyl) tropane ([(3)H]PTT), for dopamine transport sites in rat brain. (2000) (22)
- Formal enantioselective [4+3] cycloaddition by a tandem diels-alder reaction/ring expansion (2006) (21)
- Approaches to the synthesis of aza analogs of the .beta.-lactam antibiotics: some anomalous rhodium(II)-catalyzed carbene insertion reactions (1984) (21)
- Synthesis of 2β-Acyl-3β-(substituted naphthyl)-8-azabicyclo[3.2.1]octanes and Their Binding Affinities at Dopamine and Serotonin Transport Sites (2001) (21)
- C-H functionalization: collaborative methods to redefine chemical logic. (2014) (21)
- Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate† †Electronic supplementary information (ESI) available: Experimental procedures and computational details are provided. CCDC 1408224. For ESI and crystallographic data in CIF or other el (2016) (21)
- Convenient Synthesis of Vinyldiazomethanes from α-Diazo-β-Keto Esters and Related Systems (1992) (21)
- Regiochemistry of molybdenum-catalyzed O–H insertions of vinylcarbenoids (2000) (20)
- Stereoselective synthesis of highly substituted cyclohexanes by a rhodium-carbene initiated domino sequence. (2015) (20)
- Ring expansion of tert-butyl 1-vinylcyclopropane-1-carboxylates to .alpha.-ethylidenebutyrolactones (1992) (20)
- Enantioselective double C-H activation of dihydronaphthalenes. (2005) (19)
- Catalytic Enantioselective C—H Activation by Means of Metal—Carbenoid-Induced C—H Insertion (2003) (18)
- Diastereoselectivity enhancement in cyclopropanation and cyclopropenation reactions of chiral diazoacetate esters catalyzed by chiral dirhodium(II) carboxamides (1993) (18)
- Functionalization of Piperidine Derivatives for the Site‐Selective and Stereoselective Synthesis of Positional Analogues of Methylphenidate (2019) (18)
- Rhodium-Stabilized Diarylcarbenes Behaving as Donor/Acceptor Carbenes (2020) (18)
- Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton. (2012) (18)
- Long-acting blockade of biogenic amine transporters in rat brain by administration of the potent novel tropane 2beta-propanoyl-3beta-(2-Naphthyl)-tropane. (1998) (17)
- 3-Oxo-1,2-diazetidinium tosylate (1981) (17)
- Total Synthesis of (±)-Vibsanin E. (2009) (17)
- Effect of tether position on the intramolecular reaction between rhodium stabilized carbenoids and furans (1997) (17)
- Rh(II)-Catalyzed Monocyclopropanation of Pyrroles and Its Application to the Synthesis Pharmaceutically Relevant Compounds. (2019) (17)
- Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions. (2006) (16)
- Synthesis of 2,2,2,-Trichloroethyl Aryl- and Vinyldiazoacetates by Palladium-Catalyzed Cross-Coupling. (2017) (16)
- Synthesis of Complex Hexacyclic Compounds via a Tandem Rh(II)-Catalyzed Double-Cyclopropanation/Cope Rearrangement/Diels–Alder Reaction (2014) (15)
- Behavioral effects of the novel tropane analog, 2β-propanoyl-3β-(4-toluyl)-tropane (PTT) (1994) (15)
- Diastereoselective kinetic protonation of exocyclic enolates derived from bicyclic ketones: control of stereochemistry mediated by bridging heteroatoms. (2001) (15)
- N- vs. O-acylation of 1,2-diazetidin-3-one: 4,5-dihydro-1,3-oxadiazin-6-ones by ring enlargement (1984) (15)
- Direct synthesis of methyl 2-diazo-4-aryl-3-butenoates and their application to the enantioselective synthesis of 4 -aryl -4 -(1 -naphthyl ) -2 -butenoates (2006) (15)
- Rhodium(II)-catalyzed decomposition of vinyldiazomethanes in the presence of 1,2-dihydropyridines: Synthesis of the 6-azabicyclo[3.2.2]nonane nucleus (1998) (15)
- Behavioral and local cerebral metabolic effects of the novel tropane analog, 2 beta-propanoyl-3 beta-(4-tolyl)-tropane. (1995) (14)
- Regio- and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization of Organosilanes by Donor/Acceptor Carbenes Derived from Aryldiazoacetates. (2019) (14)
- Application of Donor/Acceptor‐Carbenoids to the Synthesis of Natural Products (2010) (14)
- Facile formation of chloro-η3-allyl complexes by reaction of vinyldiazoacetates and ruthenium(II) arene complexes (2002) (13)
- Synthesis of cyclic azomethine imines from aza .beta.-lactams. Conversion of 3-oxo-1,2-diazetidinium tosylates into 1-substituted 3-oxo-1,2-diazetidinium inner salts (1983) (13)
- Distal Allylic/Benzylic C-H Functionalization of Silyl Ethers Using Donor/Acceptor Rhodium(II) Carbenes. (2020) (13)
- Influence of an internal trifluoromethyl group on the rhodium(II)-catalyzed reactions of vinyldiazocarbonyl compounds. (2013) (13)
- Optimized immobilization strategy for dirhodium (II) carboxylate catalysts for C-H functionalization and their implementation in a packed bed flow reactor. (2020) (13)
- Rhodium(II)-catalyzed stereoselective synthesis of allylsilanes. (2013) (13)
- Catalytic Asymmetric Synthesis of Diarylacetates and 4,4-Diarylbutanoates. A Formal Asymmetric Synthesis of (+)-Sertraline (1999) (13)
- Organic chemistry: Synthetic lessons from nature (2009) (12)
- Addition of Ketocarbenes to Alkenes, Alkynes and Aromatic Systems (1991) (12)
- Rhodium-Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes. (2020) (12)
- Rhodium-Catalyzed [4+3] Cycloaddition to Furans: Direct Access to Functionalized Bicyclo[5.3.0]decane Derivatives (2016) (11)
- Synthesis and reactions of some 1-substituted 1,2-diazetidinones (1984) (11)
- Regio- and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization of Cyclobutanes. (2020) (11)
- Reactions of Indoles with Metal-Bound Carbenoids (2013) (11)
- Rhodium(II) catalyzed intramolecular reactions between vinyldiazomethanes and pyrroles. Novel synthesis of fused 7-azabicyclo[4.2.0]octadienes (1994) (11)
- Synthesis and reactions of some 1,2-disubstituted 1,2-diazetidin-3-ones: an intramolecular aldol approach to bicyclic systems (1986) (11)
- Copper-Catalyzed Oxidation of Hydrazones to Diazo Compounds Using Oxygen as the Terminal Oxidant (2021) (11)
- Conformational analysis and stereochemical assignments of products derived from CH activation at secondary sites (2001) (11)
- Effects of the dopamine reuptake inhibitor PTT on reinstatement and on food- and cocaine-maintained responding in rhesus monkeys (2004) (10)
- Role of Sterically Demanding Chiral Dirhodium Catalysts in Site‐Selective C—H Functionalization of Activated Primary C—H Bonds. (2015) (10)
- Effect of HD-23, a potent long acting cocaine-analog, on cocaine self-administration in rats (2003) (10)
- Synthesis of ether analogues of (±)-acetomycin (1993) (10)
- Synthesis of Furans via Rhodium(II) Acetate‐Catalyzed Reaction of Acetylenes with α‐Diazocarbonyls: Ethyl 2‐Methyl‐5‐Phenyl‐3‐Furancarboxylate (2003) (10)
- Dihydro- and tetrahydrofuran ring-opening reactions directed towards the synthesis of CP-263,114 (2000) (10)
- Direct gas-phase interaction of aryldiazoacetates and dirhodium catalysts (2003) (10)
- Time-Dependent Changes in Receptor/G-Protein Coupling in Rat Brain following Chronic Monoamine Transporter Blockade (2005) (10)
- Synthesis of [3a,7a]-Dihydroindoles by a Tandem Arene Cyclopropanation/3,5-Sigmatropic Rearrangement Reaction. (2018) (9)
- Cation induced rearrangement of 8-azabicyclo[3.2.1]octa-2,6-dienes to 6-azabicyclo[3.2.1]oct-2-enes (1998) (9)
- Asymmetric Synthesis through C–H Activation (2010) (9)
- Intermolecular C–H Insertions of Carbenoids (2011) (9)
- Formation of Tertiary Alcohols from the Rhodium-Catalyzed Reactions of Donor/Acceptor Carbenes with Esters. (2018) (9)
- 1-Naphthyl and 4-indolyl arylalkylamines as selective monoamine reuptake inhibitors. (2009) (9)
- An Immobilized‐Dirhodium Hollow‐Fiber Flow Reactor for Scalable and Sustainable C−H Functionalization in Continuous Flow (2018) (8)
- Synthesis of 3β-Aryl-8-azabicyclo(3.2.1)octanes with High Binding Affinities and Selectivities for the Serotonin Transporter Site. (1996) (8)
- Rhodium Carbenoid InducedIntermolecular C-H Functionalization at TertiaryC-H Bonds (2008) (8)
- Comparison of 1,2-Diarylcyclopropanecarboxylates with 1,2,2-Triarylcyclopropanecarboxylates as Chiral Ligands for Dirhodium-Catalyzed Cyclopropanation and C-H Functionalization. (2020) (8)
- C-H Functionalization Approach for the Synthesis of Chiral C2-Symmetric 1,5-Cyclooctadiene Ligands. (2019) (8)
- Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity (2020) (7)
- Control of carbenoid reactivity through neighboring group participation (1995) (7)
- Synthesis and Reactions of Some 1,2-Disubstituted 1,2-Diazetidin-3-ones: An Intramolecular Aldol Approach to Bicyclic Systems. (1986) (7)
- Effects of long-term biogenic amine transporter blockade on receptor/G-protein coupling in rat brain (2005) (7)
- Enantioselective Synthesis of β-Amino Esters and Its Application to the Synthesis of the Enantiomers of the Antidepressant Venlafaxine. (2006) (7)
- In Vivo Characterization of a Novel Phenylisothiocyanate Tropane Analog at Monoamine Transporters in Rat Brain (2008) (7)
- Copper(II) Acetate-Induced Oxidation of Hydrazones to Diazo Compounds under Flow Conditions Followed by Dirhodium-Catalyzed Enantioselective Cyclopropanation Reactions. (2021) (7)
- Prolonged dopamine and serotonin transporter inhibition after exposure to tropanes (1998) (7)
- Influence of Aryl Substituents on the Alignment of Ligands in the Dirhodium Tetrakis(1,2,2‐Triarylcyclopropane‐ carboxylate) Catalysts (2021) (6)
- Studies in Natural Products Chemistry, Vol. 18, Stereoselective Synthesis (Part K) Edited by Atta-ur-Rahman (University of Karachi). Elsevier Science, Tarrytown, NY. 1996. xiv + 1094 pp. 16.5 × 24 cm. $656.25. ISBN 0-444-82458-8. (1997) (6)
- Synthesis and monoamine transporter affinity of 3β-(4-(2-pyrrolyl)phenyl)-8-azabicyclo[3.2.1]octanes and 3β-(5-Indolyl)-8-azabicyclo[3.2.1]octanes (2001) (6)
- Regioselective [3 + 2] annulations with rhodium(ii)-stabilized vinylcarbenoids (1992) (6)
- Asymmetric Cyclopropanations by Rhodium(II) N‐(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2‐Phenylcyclopropan‐1‐amino Acid. (1996) (6)
- Combined C—H functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction. (2012) (6)
- Catalytic Asymmetric Synthesis of syn‐Aldol Products from Intermolecular C—H Insertions Between Allyl Silyl Ethers and Methyl Aryldiazoacetates. (2010) (6)
- Enantioselective Reactions of Donor/Acceptor Carbenoids Derived from α‐Aryl‐α‐diazoketones. (2009) (6)
- Rh2(R-TPCP)4-Catalyzed Enantioselective [3 + 2]-Cycloaddition Between Nitrones and Vinyldiazoacetates. (2014) (6)
- Effects of 2beta-propanoyl-3beta-(4-tolyl)-tropane (PTT) on the self-administration of cocaine, heroin, and cocaine/heroin combinations in rats. (2004) (6)
- Transition Metal‐Catalyzed C ? H Functionalization: Synthetically Enabling Reactions for Building Molecular Complexity (2012) (6)
- 10.04 – Synthetic Reactions via C–H Bond Activation: Carbene and Nitrene C–H Insertion (2007) (6)
- Rhodium‐Catalyzed [3 + 2] Annulation of Indoles. (2010) (5)
- A cocaine analog, 2β-propanoyl-3β-(4-tolyl)-tropane (PTT), reduces tyrosine hydroxylase in the mesolimbic dopamine pathway (2000) (5)
- Alterations in behavior and opioid gene expression induced by the novel tropane analog WF-31. (1997) (5)
- Intermolecular Metal—Catalyzed Carbenoid Cyclopropanations (2003) (5)
- C–H Functionalization (2012) (5)
- Recent Progress in Asymmetric Intermolecular C—H Activation by Rhodium Carbenoid Intermediates (2001) (5)
- Thallium in Organic Synthesis. 67 Intramolecular Capture of Aromatic Radical Cations by An N-Tosyl Group (1986) (5)
- 2,2,2-Trichloroethyl Aryldiazoacetates as Robust Reagents for the Enantioselective C—H Functionalization of Methyl Ethers. (2015) (5)
- Synthesis of iodinated 3beta-aryltropanes with selective binding to either the dopamine or serotonin transporters. (2002) (5)
- Highly Stereoselective C—C Bond Formation by Rhodium‐Catalyzed Tandem Ylide Formation/[2,3]‐Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols. (2012) (5)
- α-Hydroxy Esters as Chiral Auxiliaries in Asymmetric Cyclopropanations by Rhodium(II)-Stabilized Vinylcarbenoids. (1994) (4)
- Catalytic Asymmetric C—H Activation of sp3-Hybridized C—H Bonds by Means of Carbenoid C—H Insertions: Applications in Organic Synthesis (2003) (4)
- A comparison of the behavioral effects of the repeated administration of PTT, 2β-propanoyl-3β-(4-tolyl)tropane and cocaine (2000) (4)
- Sequential C—H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans. (2013) (4)
- Asymmetric Intermolecular Carbenoid C—H Insertions Catalyzed by Rhodium(II) (S)‐N‐(p‐Dodecylphenyl)sulfonylprolinate. (1998) (4)
- Enantioselective C—C Bond Formation by Rhodium‐Catalyzed Tandem Ylide Formation/[2,3]‐Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Allylic Alcohols. (2010) (4)
- Rh2(S‐biTISP)2‐Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids. (2012) (4)
- Influence of a β-Alkoxy Substituent on the C—H Activation Chemistry of Alkyl Ethers. (2004) (4)
- Irreversible binding of a novel phenylisothiocyanate tropane analog to monoamine transporters in rat brain. (2007) (4)
- Mechanistically Guided Workflow for Relating Complex Reactive Site Topologies to Catalyst Performance in C-H Functionalization Reactions. (2022) (4)
- Rhodium(II) (S)-N-(Arylsulfonyl)prolinate Catalyzed Asymmetric Insertions of Vinyl- and Phenylcarbenoids into the Si-H Bond. (1997) (4)
- [3 + 4] Annulations Between Rhodium‐Stabilized Vinylcarbenoids and Dienes (1999) (4)
- Tandem Asymmetric Cyclopropanation/Cope Rearrangement. A Highly Diastereoselective and Enantioselective Method for the Construction of 1,4‐Cycloheptadienes. (1998) (4)
- New Strategic Reactions for Organic Synthesis: Catalytic Asymmetric C—H Activation α to Nitrogen as a Surrogate for the Mannich Reaction. (2003) (4)
- Rh2(S-PTAD)4-Catalyzed Asymmetric Cyclopropenation of Aryl Alkynes. (2011) (3)
- Expanding the Scope of Donor/Acceptor Carbenes to N‐Phthalimido Donor Groups: Diastereoselective Synthesis of 1‐Cyclopropane α‐Amino Acids. (2013) (3)
- Novel Dirhodium Tetraprolinate Catalysts Containing Bridging Prolinate Ligands for Asymmetric Carbenoid Reactions. (1999) (3)
- Effect of Rhodium Carbenoid Structure on Cyclopropanation Chemoselectivity. (2000) (3)
- Dirhodium Tetraprolinate Catalyzed Asymmetric Cyclopropanations with High Turnover Numbers. (2003) (3)
- Rhodium‐Catalyzed Conversion of Furans to Highly Functionalized Pyrroles. (2013) (3)
- Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition Between Vinyldiazoacetates and Enol Ethers (2014) (3)
- Effect of Catalyst on the Diastereoselectivity of Methyl Phenyldiazoacetate Cyclopropanations. (1999) (3)
- Synthesis of Trifluoromethyl-Substituted Cyclopropanes (2007) (3)
- Dirhodium Tetracarboxylates Derived from Adamantylglycine as Chiral Catalysts for Enantioselective C—H Aminations. (2007) (3)
- Highly Stereoselective (3 + 2)Annulations by Cyclopropanation of Vinyl Ethers with Rhodium(II)-Stabilized Vinylcarbenoids Followed by a Formally Forbidden 1,3-Sigmatropic Rearrangement. (1992) (3)
- Copper-Catalyzed, Aerobic Oxidation of Hydrazone in a Three-Phase Packed Bed Reactor (2021) (3)
- Dirhodium(II) Tetrakis[N‐phthaloyl‐(S)‐tert‐leucinate] (2006) (3)
- Total synthesis: expanding the art of synthesis. (2009) (3)
- Stereoselective Construction of Nitrile-Substituted Cyclopropanes (2008) (3)
- C-H Transformation at Unfunctionalized Alkanes (2008) (3)
- Tandem Cyclopropanation/Cope Rearrangement: A General Method for the Construction of Seven‐Membered Rings (1993) (3)
- Direct Synthesis of Methyl 2-Diazo-4-aryl-3-butenoates and Their Application to the Enantioselective Synthesis of 4-Aryl-4-(1-naphthyl)-2-butenoates. (2006) (3)
- Distal Allylic/Benzylic C−H Functionalization of Silyl Ethers Using Donor/Acceptor Rhodium(II) Carbenes (2020) (2)
- Tandem Cyclopropanation/Cope Rearrangement Sequence. Stereospecific (3+4)Cycloaddition Reaction of Vinylcarbenoids with Cyclopentadiene. (1987) (2)
- Leveraging Regio- and Stereoselective C(sp3)-H Functionalization of Silyl Ethers to Train a Logistic Regression Classification Model for Predicting Site-Selectivity Bias. (2022) (2)
- Metal Carbene Promoted Sequential Transformations for the Enantioselective Synthesis of Highly Functionalized Cycloheptadienes. (2005) (2)
- Rhodium‐Stabilized Vinylcarbenoid Intermediates in Organic Synthesis (1999) (2)
- One‐Flask Synthesis of Methyl Arylvinyldiazoacetates and their Application in Enantioselective C‐H Functionalization: Synthesis of (E)‐Methyl 2‐Diazo‐4‐Phenylbut‐3‐Enoate and (S,E)‐Methyl 2‐((R)‐4‐Methyl‐1,2‐Dihydronaphthalen‐2‐YL)‐4‐Phenylbut‐3‐Enoate (2007) (2)
- Functionalization of Carbon—Hydrogen Bonds Through Transition Metal Carbenoid Insertion (2011) (2)
- Role of ortho‐Substituents on Rhodium‐Catalyzed Asymmetric Synthesis of β‐Lactones by Intramolecular C—H Insertions of Aryldiazoacetates. (2014) (2)
- Catalytic Enantioselective Synthesis of β2-Amino Acids. (2002) (2)
- Towards the Total Synthesis of 3-Hydroxyvibsanin E. (2009) (2)
- Silver Triflate Catalyzed Cyclopropenation of Internal Alkynes with Donor-/Acceptor-Substituted Diazo Compounds. (2011) (2)
- Highly Regio-, Diastereo-, and Enantioselective C—H Insertions of Methyl Aryldiazoacetates into Cyclic N-Boc-Protected Amines. Asymmetric Synthesis of Novel C2-Symmetric Amines and threo-Methylphenidate. (1999) (2)
- Rhodium-Stabilized Vinylcarbenoid Intermediates in Organic Synthesis (1998) (2)
- Role of Additives to Overcome Limitations of Intermolecular Rhodium-Catalyzed Asymmetric Cyclopropanation (2021) (2)
- A C-H Functionalization Strategy Enables an Enantioselective Formal Synthesis of (-)-Aflatoxin B2. (2021) (2)
- Asymmetric synthesis of pharmaceutically relevant 1-aryl-2-heteroaryl- and 1,2-diheteroarylcyclopropane-1-carboxylates (2021) (2)
- Donor-Acceptor-Acceptor 1,3-Bisdiazo Compounds: An Exploration of Synthesis and Stepwise Reactivity. (2020) (2)
- Carbenoid versus Vinylogous Reactivity in Rhodium(II)‐Stabilized Vinylcarbenoids. (1995) (2)
- Catalytic asymmetric carbene transfer reactions (2003) (2)
- C—H Activation as a Strategic Reaction: Enantioselective Synthesis of 4‐Substituted Indoles. (2006) (2)
- Stereoselective Synthesis of Epoxides by Reaction of Donor/Acceptor-Substituted Carbenoids with α,β-Unsaturated Aldehydes. (2002) (2)
- Effect of the Diazoalkane Structure on the Stereoselectivity of Rhodium(II) (S)‐N‐(Arylsulfonyl)prolinate Catalyzed Cyclopropanations. (1996) (2)
- Intermolecular C—H Insertions of Donor/Acceptor-Substituted Rhodium Carbenoids: A Practical Solution for Catalytic Enantioselective C—H Activation (2005) (2)
- Asymmetric Cyclopropanation with 4-Aryloxy-1-sulfonyl-1,2,3-triazoles: Expanding the Range of Rhodium-Stabilized Donor/Acceptor Carbenes to Systems with an Oxygen Donor Group. (2022) (1)
- APPROACHES TO THE SYNTHESIS OF AZA ANALOGS OF THE β-LACTAM ANTIBIOTICS: SOME ANOMALOUS RHODIUM(II)-CATALYZED CARBENE INSERTION REACTIONS (1984) (1)
- Catalytic Asymmetric Allylic C—H Activation as a Surrogate of the Asymmetric Claisen Rearrangement. (2002) (1)
- Divergent Pathways in the Intramolecular Reactions Between Rhodium- Stabilized Vinylcarbenoids and Pyrroles: Construction of Fused Tropanes and 7-Azabicyclo(4.2.0)octadienes. (1996) (1)
- Mild Aminoacylation of Indoles and Pyrroles Through a Three‐Component Reaction with Ynol Ethers and Sulfonyl Azides. (2015) (1)
- A comparison of the behavioral effects of the repeated administration of PTT, 2beta-propanoyl-3beta-(4-tolyl)tropane and cocaine. (2000) (1)
- Rhodium‐Catalyzed Enantioselective [4+2] Cycloadditions of Vinylcarbenes with Dienes (2020) (1)
- Dirhodium(II) Tetraoctanoate (2006) (1)
- A cocaine analog, 2beta-propanoyl-3beta-(4-tolyl)-tropane (PTT), reduces tyrosine hydroxylase in the mesolimbic dopamine pathway. (2000) (1)
- Effect of Tether Position on the Intramolecular Reaction Between Rhodium-Stabilized Carbenoids and Furans. (1997) (1)
- Reaction of Metal-Stabilized Carbenoids with Pyrroles (1995) (1)
- Asymmetric Synthesis of Cyclopentenes by [3 + 2] Annulations Between Vinylcarbenoids and Vinyl Ethers. (1999) (1)
- Combined C—H Activation/Cope Rearrangement as a Strategic Reaction in Organic Synthesis: Total Synthesis of (‐)‐Colombiasin A (I) and (‐)‐Elisapterosin B (II). (2006) (1)
- Continuous Process to Safely Manufacture an Aryldiazoacetate and Its Direct Use in a Dirhodium-Catalyzed Enantioselective Cyclopropanation (2022) (1)
- Convenient Synthesis of Vinyldiazomethanes from α‐Diazo β‐ Keto Esters and Related Systems. (1992) (1)
- Design, Synthesis, and Evaluation of Extended C4–Symmetric Dirhodium Tetracarboxylate Catalysts (2022) (1)
- Further evaluation of the reinforcing effects of the novel cocaine analog 2beta-propanoyl-3beta-(4-tolyl)-tropane (PTT) in rhesus monkeys. (1998) (1)
- Metal‐Free N—H Insertions of Donor/Acceptor Carbenes. (2012) (1)
- Recent Advances in C—H Functionalization (2016) (1)
- Asymmetric Synthesis of 1-Alkynylcyclopropane-1-carboxylates. (2001) (1)
- Highly Diastereoselective and Enantioselective C—H Functionalization of 1,2-Dihydronaphthalenes: A Combined C—H Activation/Cope Rearrangement Followed by a Retro-Cope Rearrangement. (2004) (1)
- Diversity Synthesis Using the Complimentary Reactivity of Rhodium(II)‐ and Palladium(II)‐Catalyzed Reactions. (2006) (1)
- Synthesis and Monoamine Transporter Affinity of 3β‐(4‐(2‐Pyrrolyl)phenyl)‐8‐azabicyclo[3.2.1]octanes and 3β‐(5‐Indolyl)‐8‐azabicyclo[3.2.1]octanes. (2001) (1)
- Asymmetric [4 + 3] Cycloadditions Between Benzofuranyldiazoacetates and Dienes: Formal Synthesis of (+)-Frondosin B. (2008) (1)
- Asymmetric Synthesis of the Tremulane Skeleton by a Tandem Cyclopropanation/Cope Rearrangement. (1996) (1)
- Catalytic enantioselective synthesis of beta3-amino acids. (2002) (1)
- Catalytic Asymmetric C—H Activation of Alkanes and Tetrahydrofuran. (2000) (1)
- Lewis Acid Induced Tandem Diels—Alder Reaction/Ring Expansion as an Equivalent of a [4 + 3] Cycloaddition. (2004) (1)
- Enantioselective Synthesis of Vinylcyclopropanes by Rhodium(II) Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. (1994) (1)
- Synthesis of (-)-5-epi-VibsaninE (2009) (1)
- Rhodium(II)‐Catalyzed Decomposition of Vinyldiazomethanes in the Presence of 1,2‐Dihydropyridines: Synthesis of the 6‐Azabicyclo[3.2.2]nonane Nucleus. (1998) (1)
- A New Class of Chiral Lewis Acid Catalysts for Highly Enantioselective Hetero‐Diels—Alder Reactions: Exceptionally High Turnover Numbers from Dirhodium(II) Carboxamidates. (2010) (1)
- Application of the Combined C—H Activation/Cope Rearrangement as a Key Step in the Total Syntheses of the Assigned Structure of (+)-Elisabethadione (V) and a (+)-p-Benzoquinone Natural Product (VI). (2007) (1)
- C—H Insertion Reactions, Cycloadditions, and Ylide Formation of Diazo Compounds (2004) (1)
- Rhodium(II) Tetracarboxylate-Catalyzed Enantioselective C-H Functionalization Reactions (2019) (1)
- Synthesis and Evaluation of a Novel Dirhodium Tetraprolinate Catalyst Containing Bridging Prolinate Ligands. (1997) (1)
- Behavioral effects of the novel tropane analog, 2 beta-propanoyl-3 beta-(4-toluyl)-tropane (PTT). (1994) (1)
- New directions in natural product synthesis. (2018) (1)
- Asymmetric Intramolecular C—H Insertions of Aryldiazoacetates. (2001) (1)
- Convenient Method for the Functionalization of the 4‐ and 6‐Positions of the Androgen Skeleton. (2012) (1)
- Catalytic Asymmetric C—H Activation of Silyl Enol Ethers as an Equivalent of an Asymmetric Michael Reaction. (2001) (1)
- Sequential Rhodium‐, Silver‐, and Gold‐Catalyzed Synthesis of Fused Dihydrofurans. (2011) (1)
- Versatile Synthesis of Tropones by Reaction of Rhodium(II)-Stabilized Vinylcarbenoids with 1-Methoxy-1-((trimethylsilyl)oxy)buta-1,3-diene. (1992) (1)
- Enantioselective Synthesis of Tropanes by Reaction of Rhodium- Stabilized Vinylcarbenoids with Pyrroles. (1993) (1)
- Enantioselective Intermolecular C-H Functionalization of Allylic and Benzylic sp3 C-H Bonds Using N-Sulfonyl-1,2,3-triazoles. (2016) (1)
- C–H Functionalization Approach for the Synthesis of Chiral C2 Symmetric 1,5-Cyclooctadienes Ligands (2019) (1)
- RHODIUM(II) ACETATE‐CATALYZED REACTION OF ETHYL 2‐DIAZO‐3‐OXOPENT‐4‐ENOATES: SIMPLE ROUTES TO 4‐ARYL‐2‐HYDROXY‐1‐NAPHTHOATES AND β,Γ‐UNSATURATED ESTERS. THE DIANION OF ETHYL 4‐(DIETHYLPHOSPHONO)ACETOACETATE AS A PROPIONATE HOMOENOLATE EQUIVALENT (1984) (1)
- Dirhodium(II) Tetrakis(trifluoroacetate) (2006) (1)
- Absolute configuration of C20H30O6Si, a species with a (1R,5R)-8-oxabicyclo[3.2.1]octa-2,6-diene core produced selectivity by the rhodium(II) octanoate catalyzed decomposition of a chiral vinyldiazomethane in the presence of furan (1999) (1)
- Optimized Immobilization Strategy for Dirhodium(II) Carboxylate Catalysts for C−H Functionalization and Their Implementation in a Packed Bed Flow Reactor (2020) (1)
- Organometallics in heterocyclic chemistry (2007) (1)
- Methyl 2‐Diazo‐3‐butenoate (2008) (1)
- Absolute configuration of C23H34O8Si, the product of an asymmetric synthesis involving the Rh(II) catalyzed reaction of a chiral vinyldiazomethane with methyl-2-methyl-3-furoate (1999) (1)
- Erratum: Regio- and Stereoselective Rhodium(II)-Catalyzed C-H Functionalization of Cyclobutanes. (2020) (0)
- Control of Carbenoid Reactivity Through Neighboring Group Participation. (1996) (0)
- Methyl (E)‐4‐Phenyl‐2‐diazo‐3‐butenoate (2011) (0)
- Effect of Carbenoid Structure on the Reactions of Rhodium-Stabilized Carbenoids with Cycloheptatriene. (2010) (0)
- Combined C-H Functionalization/CopeRearrangement with Vinyl Ethers (2011) (0)
- Recent Advances in Catalytic Enantioselective Intermolecular C—H Functionalization. (2007) (0)
- Enantioselective Synthesis of Oxazolidinones (2007) (0)
- Intramolecular Synthesis of Lactones by Activation of sp C—H Bonds (2011) (0)
- Dirhodium(II) Tetra(N‐(dodecylbenzenesulfonyl)prolinate) Catalyzed Enantioselective Cyclopropenation of Alkynes. (2004) (0)
- 2‐Diazo‐3‐[[(1,1‐dimethylethyl)dimethylsilyl]oxy]‐3‐butenoic Acid, Methyl Ester (2010) (0)
- Total Synthesis of (.+-.)-Tremulenolide A and (.+-.)-Tremulenediol A via a Stereoselective Cyclopropanation/Cope Rearrangement Annulation Strategy. (1998) (0)
- Asymmetric Synthesis of Highly Functionalized 8‐Oxabicyclo(3.2.1) octene Derivatives. (1997) (0)
- Balance Between Allylic C—H Activation and Cyclopropanation in the Reactions of Donor/Acceptor-Substituted Rhodium Carbenoids with trans-Alkenes. (2008) (0)
- Direct Synthesis of Furans by (3 + 2) Cycloadditions Between Rhodium(II) Acetate Stabilized Carbenoids and Acetylenes. (1988) (0)
- Reactions of Metallocarbenes Derived from N-Sulfonyl-1,2,3-triazoles (2014) (0)
- Synthesis and monoamine transporter affinity of 3beta-(4-(2-pyrrolyl)phenyl)-8-azabicycl. (2001) (0)
- Cyclopropanation: Silver-Catalyzed Reactions of Aryldiazoacetates (2007) (0)
- Chapter 11 Total syntheses of natural products using the combine C-H activation/cope rearrangement as the key step (2008) (0)
- Thermally-Induced Cycloadditions of Diazo Compounds and Alkenes (2011) (0)
- Asymmetric Intermolecular C—H Functionalization of Benzyl Silyl Ethers Mediated by Chiral Auxiliary Based Aryldiazoacetates and Chiral Dirhodium Catalysts. (2006) (0)
- Recent Advances in Catalytic Intramolecular C—H Aminations (2005) (0)
- Type II Intramolecular Annulations Between Vinylcarbenoids and Furans. (1997) (0)
- Synthesis of (S)-Venlafaxine (2006) (0)
- Enantioselective Synthesis of Cyclopropylphosphonates Containing Quaternary Stereocenters Using a D2-Symmetric Chiral Catalyst Rh2(S-biTlSP)2. (2004) (0)
- Synthesis of (-)-Colombiasin A and(-)-Elisapterosin B (2006) (0)
- Stereoselective Convergent Synthesis of Hydroazulenes via an Intermolecular Cyclopropanation/Cope Rearrangement. (1991) (0)
- Stereocontrol of the Combined C-H Functionalization/CopeRearrangement (2011) (0)
- Key Selectivity Controlling Elements in Rhodium-Catalyzed C–H Functionalization with Donor/Acceptor Carbenes (2022) (0)
- Synthesis of Carbocyclic Derivatives by Activation of sp C—H Bonds (2011) (0)
- Intermolecular Activation of C—H Bonds α to Nitrogen (2011) (0)
- Stereoselective Synthesis By Robert S. Atkinson, University of Leicester. John Wiley & Sons, Inc., New York, NY. 1995. xii + 529 pp. 15 × 23 cm. $59.95. ISBN 0-471-954195. (1996) (0)
- Hexafluoroisopropanol for the Selective Deactivation of Poisonous Nucleophiles Enabling Catalytic Asymmetric Cyclopropanation of Complex Molecules (2022) (0)
- Treatment of neurodegenerative disease (1993) (0)
- Dirhodium C–H Functionalization of Hole-Transport Materials (2023) (0)
- Catalytic Asymmetric C—H Activation by Methyl Thiophen‐3‐yldiazoacetate Applied to the Synthesis of (+)‐Cetiedil. (2002) (0)
- Enantioselective Double C-H Activation of Dihydronaphthalenes (2005) (0)
- Asymmetric Synthesis Through C—H Activation (2011) (0)
- Scope and Stereochemistry of the Tandem Intramolecular Cyclopropanation/Cope Rearrangement Sequence. (1989) (0)
- Intermolecular C—H Activation at Benzylic Positions: Synthesis of (+)-Imperanene and (-)-α-Conidendrin. (2003) (0)
- Intermolecular Activation of Benzylic C—H Bonds (2011) (0)
- Synthesis of (+)-Barekoxide and (-)-Barekol (2010) (0)
- Enantioselective Synthesis of Functionalized Tropanes by Rhodium(II) Carboxylate-Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Pyrroles. (1997) (0)
- Asymmetric C-H Activation of a Benzyl Silyl Ethers (2006) (0)
- Synthesis of Highly Functionalized Tropolones by Rhodium(II)-Catalyzed Reactions of Vinyldiazomethanes with Oxygenated Dienes. (1995) (0)
- Synthetic Applications of Carbene and Nitrene C H Insertion (2022) (0)
- In Situ Kinetic Studies of Rh(II)-Catalyzed C–H Functionalization to Achieve High Catalyst Turnover Numbers (2022) (0)
- Directed sp C—H Bond Insertion (2011) (0)
- Kinetic Resolution and Double Stereodifferentiation in Catalytic Asymmetric C—H Activation of 2-Substituted Pyrrolidines. (2001) (0)
- Intermolecular Reactions of Electron-Rich Heterocycles with Copper and Rhodium Carbenoids (2007) (0)
- Intermolecular Activation of sp C—H bonds (2011) (0)
- Intermolecular C—C Bond Formation by C—H Activation (2011) (0)
- [3 + 4]Cycloaddition Reactions of Vinyl Carbenoids with Furans. (1986) (0)
- Characterization of chiral tamoxifen analogs (2005) (0)
- Novel Approach to Seven-Membered Rings by the Intramolecular Tandem Cyclopropanation/Cope Rearrangement Sequence. (1988) (0)
- Ammonium, Oxonium and Sulfonium Ylides—Generation of Sulfur Ylides from Metal Carbenoids (2004) (0)
- Dirhodium (II) Tetrakis(triphenylacetate) (2006) (0)
- Synthesis of Carbocyclic Derivatives by Benzylic C—H Bond Insertion (2011) (0)
- Synthetic and Isolation Studies Related to the Marine Natural Products (+)-Elisabethadione (I) and (+)-Elisabethamine (II). (2007) (0)
- Enantioselective Synthesis of Fused Cycloheptadienes by a Tandem Intramolecular Cyclopropanation/Cope Rearrangement Sequence. (2000) (0)
- Characterization of a Tropane Radioligand, [ 3 H]2 b -Propanoyl-3 b -(4-tolyl) Tropane ([ 3 H]PTT), for Dopamine Transport Sites in Rat Brain 1 (2000) (0)
- Solvent-Free Catalytic Enantioselective C—C Bond Forming Reactions with Very High Catalyst Turnover Numbers. (2010) (0)
- Sequential Cycloaddition Approach to the Tricyclic Core of Vibsanin E. Total Synthesis of (.+-.)-5-epi-10-epi-Vibsanin E. (2006) (0)
- CCDC 827302: Experimental Crystal Structure Determination (2011) (0)
- Synthesis and Chemistry of Donor/Acceptor-Substituted Cyclopropenes. (1996) (0)
- Synthesis of Iodinated 3β-Aryltropanes with Selective Binding to Either the Dopamine or Serotonin Transporters. (2002) (0)
- Effect of Carbenoid Structure on the Reactivity of Rhodium-Stabilized Carbenoids. (2010) (0)
- Rhodium-Catalyzed Stereoselective Synthesis of Nitrile-Substituted Cyclopropanes (2008) (0)
- Rhodium(II) Catalyzed Intramolecular Reactions Between Vinyldiazomethanes and Pyrroles. Novel Synthesis of Fused 7‐Azabicyclo( 4.2.0)octadienes. (1994) (0)
- Enantioselective Dirhodium(II)‐Catalyzed Cyclopropanations with Trimethylsilylethyl and Trichloroethyl Aryldiazoacetates. (2015) (0)
- Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization (2018) (0)
- Regiochemistry of Molybdenum-Catalyzed O—H Insertions of Vinylcarbenoids. (2000) (0)
- Asymmetric Rhodium-Catalyzed [4+3] Cycloaddition (2007) (0)
- Silver‐Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates. (2014) (0)
- Asymmetric Intermolecular C—H Activation, Using Immobilized Dirhodium Tetrakis((S)‐N‐(dodecylbenzenesulfonyl)prolinate) as a Recoverable Catalyst. (2003) (0)
- Iridium(III)‐Bis(oxazolinyl)phenyl Catalysts for Enantioselective C—H Functionalization. (2013) (0)
- Stereoselective Cyclopropanation with Vinylcarbenoids. (1990) (0)
- Rhodium-Catalyzed [4 + 3] Cycloaddition to Furans: Direct Access to Functionalized Bicyclo[5.3.0]decane Derivatives. (2016) (0)
- A New Collaborative Approach For Chemists (2016) (0)
- PaaSicats: Powerful Catalysts for Asymmetric Epoxidation of Enones. Novel Syntheses of α-Arylpropanoic Acids Including (S)-Fenoprofen. (1999) (0)
- Synthesis and Pyrolysis of Cyclic Sulfonium Ylides. (1987) (0)
- Tetrakis[1‐[[4‐dodecylphenyl]sulfonyl]‐(2S)‐prolinate] Dirhodium (2006) (0)
- Synthesis of Nitrogen Heterocycles by Benzylic C—H Bond Insertion (2011) (0)
- Stereoselective Synthesis of Seven‐Membered Carbocycles by a Tandem Cyclopropanation/Cope Rearrangement between Rhodium(II)‐Stabilized Vinylcarbenoids and Dienes. (1991) (0)
- Synthesis of Pyridines via Rh-Catalyzed Ring Expansion ofIsoxazoles (2008) (0)
- Dirhodium(II) Tetrakis[N‐phthaloyl‐(S)‐adamantylglycine] (2009) (0)
- Rhodium‐Catalyzed Enantioselective Cyclopropanation of Electron‐Deficient Alkenes. (2013) (0)
- Formal Enantioselective [4 + 3] Cycloaddition by a Tandem Diels—Alder Reaction/Ring Expansion. (2007) (0)
- Reactions of Rhodium Carbenoids Derived from α-Aryl-α-Diazoketones (2009) (0)
- Synthesis of Nitrogen Heterocycles by Activation of sp C—H Bonds (2011) (0)
- Intermolecular Activation of Allylic C—H Bonds (2011) (0)
- Catalytic asymmetric synthesis of diarylacetate and 4,4-diarylbutanoates. A formal asymmetric synthesis of (+)-sertraline. (1999) (0)
- Synthesis of 2beta-acyl-3beta-(substituted naphthyl)-8-azabicyclo[3.2.1]octanes and their binding affinities at dopamine and serotonin transport sites. (2001) (0)
- Site-Selective C–H Functionalization of N-Aryl and N-Heteroaryl Piperidines, Morpholines, and Piperazines Controlled by a Chiral Dirhodium Tetracarboxylate Catalyst (2023) (0)
- C—C Bond Formation by C—H Bond Activation (2011) (0)
- Regioselective (3 + 2)Annulations with Rhodium(II)-Stabilized Vinylcarbenoids. (1992) (0)
- Stereoselective Synthesis of Highly Substituted Cyclohexanes by a Rhodium‐Carbene Initiated Domino Sequence. (2015) (0)
- Catalytic and enantioselective allylic CH activation with donoracceptor-substituted carbenoids (2006) (0)
- Lewis Acid Catalyzed Tandem Diels—Alder Reaction/Retro-Claisen Rearrangement as an Equivalent of the Inverse Electron Demand Hetero Diels—Alder Reaction. (2005) (0)
- Cation Induced Rearrangement of 8‐Azabicyclo[3.2.1]octa‐2,6‐dienes to 6‐Azabicyclo[3.2.1]oct‐2‐enes. (1998) (0)
- Asymmetric Synthesis of Tropans by Rhodium-Catalyzed [4 + 3] Cycloaddition. (2008) (0)
- Absolute configuration of C27H41NO8Si, the diastereoselective product of the rhodium(II) octanoate catalyzed decomposition of a chiral vinyldiazomethane in the presence of 2-acetylpyrrole: A structural study rendered difficult by disorder of a “heavy” atom (1999) (0)
- Double C—H Activation Strategy for the Asymmetric Synthesis of C2‐Symmetric Anilines. (2004) (0)
- Asymmetric Catalytic C—H Activation Applied to the Synthesis of syn-Aldol Products. (2001) (0)
- Dirhodium(II) Tetraacetate (2006) (0)
- SYNTHESIS OF CYCLIC AZOMETHINE IMINES FROM AZA β-LACTAMS. CONVERSION OF 3-OXO-1,2-DIAZETIDINIUM TOSYLATES INTO 1-SUBSTITUTED 3-OXO-1,2-DIAZETIDINIUM INNER SALTS (1984) (0)
- Synthesis of Carbocycles by Activation of sp C—H Bonds (2011) (0)
- FORMATION OF MONOCYCLIC AND BICYCLIC AZA-β-LACTAMS AND OTHER NOVEL HETEROCYCLES FROM 1-(DIPHENYLMETHYLENE)-3-OXO-1,2-DIAZETIDINIUM INNER SALT (1982) (0)
- Unearthing the Subtleties of Rhodium(II)-Catalyzed Carbenoid Cycloadditions to Furans with an N-Sulfonyl-1,2,3-triazole Probe. (2022) (0)
- Rh(II)-Catalyzed Stereoselective Cross-Coupling of DiazoCompounds (2011) (0)
- Influence of an Internal Trifluoromethyl Group on the Rhodium(II)‐Catalyzed Reactions of Vinyldiazocarbonyl Compounds. (2013) (0)
- Bulky Chiral Ligand for Rh-Catalyzed Carbenoid Reactions (2006) (0)
- Metabolic mapping methods for the identification of the neural substrates of the effects of novel tropane analogs. (1994) (0)
- Dirhodium(II)-Catalyzed Carbene C—H Insertion (2011) (0)
- Asymmetric Synthesis of 1,4-Cycloheptadienes and Bicyclo(3.2.1)octa-2, 6-dienes by Rhodium(II) N-(p-(tert-Butyl)phenylsulfonyl)prolinate Catalyzed Reactions Between Vinyldiazomethanes and Dienes. (1995) (0)
- Ring Expansion of tert‐Butyl 1‐Vinylcyclopropane‐1‐carboxylates to . alpha.‐Ethylidenebutyrolactones. (1992) (0)
- Thallium in Organic Synthesis. Part 67. Intramolecular Capture of Aromatic Radical Cations by an N-Tosyl Group. (1986) (0)
- Characterization of newly synthesized, chiral tamoxifen analogs. (2004) (0)
- Enantioselective [4+3] Cycloadditions (2008) (0)
- Novel Entry to the Tropane System by Reaction of Rhodium(II) Acetate-Stabilized Vinylcarbenoids with Pyrroles. (1990) (0)
- Catalyst Controlled Site- and Stereoselective Rhodium(II) Carbene C(sp3)-H Functionalization of Allyl Boronates. (2022) (0)
- α‐Hydroxy Esters as Inexpensive Chiral Auxiliaries in Rhodium(II) ‐Catalyzed Cyclopropanations with Vinyldiazomethanes. (1992) (0)
- Enantioselective Tandem Diels-Alder and Ring Expansion (2007) (0)
- Enantioselective Cyclopropanation at ppm Catalyst Loading (2010) (0)
- Rhodium‐Catalyzed Enantioselective Vinylogous Addition of Enol Ethers to Vinyldiazoacetates. (2013) (0)
- Heteroatom-Directed C—H Functionalization (2011) (0)
- Intermolecular C-H Insertions of Carbenoids (2012) (0)
- Bis‐{1,3‐[N,N′‐di(4‐dodecyl‐benzenesulfonyl)‐(2S,2′S),(5R,5′R)‐5,5′‐prolinate]benzene}dirhodium(II) (2006) (0)
- Catalytic Asymmetric Reactions for Organic Synthesis: The Combined C—H Activation/Siloxy‐Cope Rearrangement. (2005) (0)
- to quantitatively describe and predict site-selectivity in multivariate Rh-catalyzed C – H functionalization † (2015) (0)
- Oxidative Palladium(II)-Catalyzed sp C—H Bond Activation (2011) (0)
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