James Cullen Martin
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Most Influential Person Now
American chemist
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Chemistry
James Cullen Martin's Degrees
- Bachelors Chemistry University of California, Berkeley
Why Is James Cullen Martin Influential?
(Suggest an Edit or Addition)According to Wikipedia, James Cullen Martin was an American chemist. Known in the field as "J.C.", he specialized in physical organic chemistry with an emphasis on main group element chemistry. Martin received his undergraduate and master's degree at Vanderbilt University. His PhD work was conducted with Paul Bartlett at Harvard. Most of his professional career was at the University of Illinois at Urbana-Champaign, where he was a colleague of Roger Adams, Speed Marvel, David Y. Curtin, Nelson J. Leonard, and Reynold C. Fuson. Late in his career, he moved back to Vanderbilt, but soon succumbed to poor health.
James Cullen Martin's Published Works
Number of citations in a given year to any of this author's works
Total number of citations to an author for the works they published in a given year. This highlights publication of the most important work(s) by the author
Published Works
- Readily accessible 12-I-5 oxidant for the conversion of primary and secondary alcohols to aldehydes and ketones (1983) (2322)
- A useful 12-I-5 triacetoxyperiodinane (the Dess-Martin periodinane) for the selective oxidation of primary or secondary alcohols and a variety of related 12-I-5 species (1991) (1625)
- Sulfuranes. VI. Reactions involving the alkoxy ligands of dialkoxydiarylsulfuranes. Formation of olefins and ethers (1972) (139)
- Directed ortho-lithiation of lithium thiophenolate. New methodology for the preparation of ortho-substituted thiophenols and related compounds (1989) (85)
- Directed dilithiation of hexafluorocumyl alcohol - formation of a reagent for the facile introduction of a stabilizing bidentate ligand in compounds of hypervalent sulfur (10-S-4), phosphorus (10-P-5), silicon (10-Si-5), and iodine (10-I-3) (1981) (83)
- Pseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivity (1985) (67)
- Facile syntheses of isolable organic derivatives of hypervalent sulfur, phosphorus, and silicon. Introduction of a stabilizing bidentate ligand via its dilithio derivative (1979) (59)
- Sulfuranes. I. Stable tetracoordinate tetracovalent sulfur compound in solution (1971) (55)
- Perpendicularly twisted cyclopropylcarbinyl and allyl cations. Acetolysis of some 2-substituted derivatives of 1-adamantyl tosylate (1970) (51)
- Kinetic studies of reactions leading to cyclopropylcarbinyl radicals. Cyclopropyl-substituted azomethanes and hexacyclopropylethane (1970) (51)
- Nondissociative permutational isomerization of an octahedral derivative of a nonmetallic element, a 12-Te-6 species (1984) (47)
- Sulfuranes. XV. Crystal and molecular structures of a spirodiaryldialkoxysulfurane oxide and its parent sulfurane (1974) (42)
- The Synthesis and Solvolysis of the 2-Halo-1,4-endoxocyclohexanes1 (1957) (40)
- Ketenes. V. Reactions of Ketenes with Dienes and Olefins1 (1965) (40)
- Ketenes I. Cycloaddition of Ketene and Dialkylketenes to Enamines (1963) (38)
- Sulfuranes. II. Isolation and characterization of a crystalline dialkoxydiarylsulfurane (1971) (36)
- Sulfuranes. 35. Synthesis, reactions, and crystal and molecular structure of a sulfurane with two apical nitrogen-centered ligands: a spirodiazasulfurane (1978) (35)
- N-bromosuccinimide. Mechanisms of allylic bromination and related reactions (1970) (32)
- Sulfuranes. XII. Relative reactivities of acyclic, cyclic and spirobicyclic sulfuranes and sulfurane oxides (1974) (30)
- Ketenes. XIV. Adducts of dimethylketene with C:N compounds (1971) (29)
- Chemistry of Dimethylketene Dimer. I. Catalytic Hydrogenation and Ring Cleavage by Alcohols (1961) (29)
- Ketenes. VIII. Some Reactions of 1-(Dimethylamino)-4-methyl-1-penten-3-one1 (1966) (29)
- Sulfuranes. V. Chemistry of sulfur(IV) compounds. Dialkoxydiarylsulfuranes (1972) (27)
- Silane inversion catalyzed by weak nucleophiles: pseudorotation of 10-Si-5 intermediates (1985) (26)
- Ketenes. VI. The Stereospecific Cycloaddition of Dimethylketene to cis- and trans-Butenyl Ethyl Ethers1,2 (1965) (25)
- Cage recombination of benzoyloxy radicals: an important pathway in the decomposition of benzoyl peroxide (1969) (25)
- The Chemistry of Dimethylketene Dimer. IV. The Polyester and β-Lactone Dimer of Dimethylketene1 (1962) (25)
- The Decomposition of Acetyl Peroxide in Olefinic Solvents. The Acetyl Peroxide-Cyclohexene Reaction (1967) (25)
- The dissociative stereoisomerization of persulfuranes via 10-S-5 persulfonium salts. Geometrical isomers of octahedral 12-S-6 species (1982) (25)
- Steric effects in ortho-substituted triarylmethanes (1969) (24)
- CAGE REACTIONS IN THE THERMAL DECOMPOSITION OF ACETYL PEROXIDE. (1967) (23)
- Reaction of Secondary and Tertiary Aldehydes with Ammonia (1961) (21)
- Sulfuranes. VII. Crystal and molecular structure of a diaryldialkoxysulfurane (1972) (21)
- Synthesis, reactions, and crystal structure of a stable 10-I-4 periodonium ion (1993) (21)
- SULFURANES. 39. SYNTHESES AND STRUCTURE STUDIES OF STABLE DIFLUORO- AND DICHLOROSULFURANES. APICOPHILICITY ORDERS IN SULFURANES (1979) (19)
- Reactions of trichloroacetyl isocyanate with unsaturated ethers (1971) (19)
- Dehydrocyclopentadienyl anion. New aryne (1971) (19)
- Ketenes. XIII. Reactions of ketenes with heterocumulenes (1971) (19)
- Sulfuranes. VIII. Isolation and characterization of a dialkoxydiarylsulfurane oxide, a crystalline, pentacoordinate sulfur(VI) species (1972) (19)
- The Cage Recombination of Acetoxy Radicals to Yield Acetyl Peroxide (1966) (18)
- Ketenes. III. Cycloaddition of Ketenes to Acetylenic Ethers1 (1964) (18)
- A periodonium trifluoromethanesulfonate. An isolable 10-I-4 organoiodine species (1982) (17)
- The Chemistry of Dimethylketene Dimer. III.1 Reactions with Ammonia and Amines (1961) (15)
- Sulfuranes. IV. X-ray crystal structure of a diaryldialkoxysulfurane (1971) (15)
- Inversion at tetracoordinate silicon in nucleophilic media. Ligand permutation in 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)spirobi[2,1-benzoxasilole] (1982) (14)
- Ketenes. II. Cycloaddition of Dialkyl Ketenes to Vinyl Ethers1 (1964) (13)
- Destabilization of a tert-alkyl cation by an .alpha.-cyclopropyl substituent. Perpendicularly twisted cyclopropylcarbinyl and allylic tosylates (1969) (12)
- Ketenes. XV. Synthesis and reactions of 3,3-dimethyl-1-oxaspiro[3.5]nona-5,8-diene-2,7-dione (1971) (12)
- Ketenes. IV. Reactions of Ketenes with Ketene O,N-Acetals and Ketene N,N-Acetals1 (1964) (12)
- Reactions of tetramethylallene (1971) (11)
- Ketenes. X. Heterocyclic Systems Derived from Dimethylmalonyl Chloride1 (1966) (11)
- Ketenes. XVI. Reactions of dimethylketene with .alpha.-dicarbonyl and related compounds (1971) (11)
- Synthetic routes to cyclopropyl-substituted azoalkanes. Some reactions of cyclopropylcarbinyl cyanates, isocyanates, benzoates, and p-nitrobenzoates (1968) (11)
- Cis-trans isomers of 12-S-6 species--dissociative permutational isomerization of a persulfurane (1981) (10)
- Sulfuranes. XI. X-ray crystal structure of a diaryldialkoxysulfurane oxide (1974) (9)
- Ketenes. IX. Reactions of Ketenes with Various Substituted Enamines1 (1966) (8)
- Stereochemistry of the radical addition of polyhalomethanes to bicyclo[2.2.1]heptenyl systems (1969) (7)
- Reactions of Alkanesulfonyl Chlorides with Ketene N,N- and O,N-Acetals (1965) (7)
- Ketenes. 17. Reaction of thiophosgene with dimethylketene, a stable thio acid chloride (1981) (6)
- Adducts of dimethylketene with CN containing compounds (1965) (6)
- Cyclopropylcarbinyl free radicals, hexacyclopropylethane (1967) (5)
- Sulfurances. 32. Substituent and geometry dependence of the degenerate ligand exchange of dialkoxysulfuranes with hexafluoro-2-phenyl-2-propanol. Sulfuranes and sulfilimines derived from thianthrene, phenothiazine, and phenoxathiin (1977) (5)
- Ketenes. VII. Some Reactions of 3-Ethoxy-2,2-dimethylcyclobutanone with Aromatic Amines1 (1965) (5)
- Sulfuranes. 38. Evidence from x-ray crystallography for the diequatorial disposition of a five-membered ring in a sulfurane (1979) (5)
- Synthesis of a stable cyclic sulphenate by thermal decomposition of a chlorosulphurane in the crystalline state (1977) (5)
- Ketenes. XII. Structure of ketene-enamine cycloadducts (1967) (4)
- Notes-The Reaction Product of Hydroxypivalaldehyde and Ammonia (1961) (3)
- Chemistry of dimethylketene dimer. VI. Reactions of the .beta.-lactone dimer of dimethylketene with enamines (1967) (3)
- Directed ortho-Lithiation of Lithium Thiophenolate. New Methodology for the Preparation of ortho-Substituted Thiophenols and Related Compounds. (1989) (3)
- Methanol Decomposition Through Rich Oxidation in a Self-Ignited Catalytic Reactor (1990) (1)
- SULFURANES PART 12, RELATIVE REACTIVITIES OF ACYCLIC, CYCLIC, AND SPIROBICYCLIC SULFURANES AND SULFURANE OXIDES (1974) (1)
- A Stable Monocyclic Triarylalkoxyhydridophosphorane: A 10-P-5 Species with an Apical P-H Bond (1981) (1)
- Polar solvent effects on the homolytic decomposition of a perester (1962) (1)
- Silane Inversion Catalyzed by Weak Nucleophiles: Pseudorotation of 10-Si-5 Intermediates (kinetic evidence for the mechanism of nucleophile-catalyzed inversion of silane (I). (1986) (0)
- Domestic Waste Treatment in the Offshore Environment (1973) (0)
- DEHYDROCYCLOPENTADIENYLANION, EIN NEUES ARIN (1971) (0)
- SULFURANCES. 32. SUBSTITUENT AND GEOMETRY DEPENDENCE OF THE DEGENERATE LIGAND D EXCHANGE OF DIALKOXYSULFURANES WITH HEXAFLUORO-2-PHENYL-2-PROPANOL. SULFURANES AND SULFILIMINES DERIVED FROM THIANTHRENE, PHENOTHIAZINE, AND PHENOXATHIIN (1978) (0)
- Conversion of methanol-fueled 16-valve, 4-cylinder engine to operation on gaseous 2H2/CO fuel (1992) (0)
- LNEAR POLYESTERS AND POLY ESTER-AM DES FRGM 2 , 2 , 4 , 4-TETRAALKYL-1 , 3-CYCLOBUTANE DOLS (0)
- THE EFFECT OF MOLECULAR STRUCTURE ON THE CLEAVAGE OF OXYGEN-OXYGEN BONDS. (1963) (0)
- Organosilicon und Related Organo-Nonmetallic Species: Ligand Effects on Stereochemistry und Reactivity (1986) (0)
- SULFURANES. 38. EVIDENCE FROM X‐RAY CRYSTALLOGRAPHY FOR THE DIEQUATORIAL DISPOSITION OF A FIVE‐MEMBERED RING IN A SULFURANE (1979) (0)
- SULFURANES PART 15, CRYSTAL AND MOLECULAR STRUCTURES OF A SPIRODIARYLDIALKOXYSULFURANE OXIDE AND ITS PARENT SULFURANE (1974) (0)
- SULFURANES PART 11, X-RAY CRYSTAL STRUCTURE OF A DIARYLDIALKOXYSULFURANE OXIDE (I) (1974) (0)
- KETENES. 17. REACTION OF THIOPHOSGENE WITH DIMETHYLKETENE, A STABLE THIO ACID D CHLORIDE (1982) (0)
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